National Library of Energy BETA

Sample records for fr flue gas

  1. System of treating flue gas

    DOE Patents [OSTI]

    Ziegler, D.L.

    1975-12-01

    A system is described for treating or cleaning incinerator flue gas containing acid gases and radioactive and fissionable contaminants. Flue gas and a quench solution are fed into a venturi and then tangentially into the lower portion of a receptacle for restricting volumetric content of the solution. The upper portion of the receptacle contains a scrub bed to further treat or clean the flue gas.

  2. Mercury sorbent delivery system for flue gas

    DOE Patents [OSTI]

    Klunder; ,Edgar B.

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  3. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  4. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, Kwan H.; Ahluwalia, Rajesh K.

    1985-01-01

    A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

  5. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  6. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers Citation Details In-Document Search Title: Recovery of Water from Boiler Flue Gas Using ...

  7. Flue gas injection control of silica in cooling towers. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Flue gas injection control of silica in cooling towers. Citation Details In-Document Search Title: Flue gas injection control of silica in cooling towers. ...

  8. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  9. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  10. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  11. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  12. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  13. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  14. Flue gas injection control of silica in cooling towers. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Flue gas injection control of silica in cooling towers. Citation Details In-Document Search Title: Flue gas injection control of silica in cooling towers. You are accessing a ...

  15. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Bush, P.V.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ask properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  16. Flue gas desulfurization wastewater treatment primer

    SciTech Connect (OSTI)

    Higgins, T.E.; Sandy, A.T.; Givens, S.W.

    2009-03-15

    Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.

  17. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; CASCADE IMPACTORS; PERFORMANCE TESTING; FLUE GAS; PARTICLE SIZE; ...

  18. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power...

    Office of Scientific and Technical Information (OSTI)

    Flue Gas Purification - Power Plant Performance Citation Details In-Document Search Title: Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance A ...

  19. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power...

    Office of Scientific and Technical Information (OSTI)

    Flue Gas Purification - Power Plant Performance Citation Details In-Document Search Title: Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance You ...

  20. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  1. Utility flue gas mercury control via sorbent injection

    SciTech Connect (OSTI)

    Chang, R.; Carey, T.; Hargrove, B.

    1996-12-31

    The potential for power plant mercury control under Title III of the 1990 Clean Air Act Amendments generated significant interest in assessing whether cost effective technologies are available for removing the mercury present in fossil-fired power plant flue gas. One promising approach is the direct injection of mercury sorbents such as activated carbon into flue gas. This approach has been shown to be effective for mercury control from municipal waste incinerators. However, tests conducted to date on utility fossil-fired boilers show that it is much more difficult to remove the trace species of mercury present in flue gas. EPRI is conducting research in sorbent mercury control including bench-scale evaluation of mercury sorbent activity and capacity with simulated flue gas, pilot testing under actual flue gas conditions, evaluation of sorbent regeneration and recycle options, and the development of novel sorbents. A theoretical model that predicts maximum mercury removals achievable with sorbent injection under different operating conditions is also being developed. This paper presents initial bench-scale and model results. The results to date show that very fine and large amounts of sorbents are needed for mercury control unless long residence times are available for sorbent-mercury contact. Also, sorbent activity and capacity are highly dependent on flue gas composition, temperature, mercury species, and sorbent properties. 10 refs., 4 figs., 2 tabs.

  2. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  3. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  4. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, John B. L.; Doctor, Richard D.; Wingender, Ronald J.

    1986-01-01

    A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

  5. BUILDING MATERIALS MADE FROM FLUE GAS DESULFURIZATION BY-PRODUCTS

    SciTech Connect (OSTI)

    Michael W. Grutzeck; Maria DiCola; Paul Brenner

    2006-03-30

    Flue gas desulphurization (FGD) materials are produced in abundant quantities by coal burning utilities. Due to environmental restrains, flue gases must be ''cleaned'' prior to release to the atmosphere. They are two general methods to ''scrub'' flue gas: wet and dry. The choice of scrubbing material is often defined by the type of coal being burned, i.e. its composition. Scrubbing is traditionally carried out using a slurry of calcium containing material (slaked lime or calcium carbonate) that is made to contact exiting flue gas as either a spay injected into the gas or in a bubble tower. The calcium combined with the SO{sub 2} in the gas to form insoluble precipitates. Some plants have been using dry injection of these same materials or their own Class C fly ash to scrub. In either case the end product contains primarily hannebachite (CaSO{sub 3} {center_dot} 1/2H{sub 2}O) with smaller amounts of gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). These materials have little commercial use. Experiments were carried out that were meant to explore the feasibility of using blends of hannebachite and fly ash mixed with concentrated sodium hydroxide to make masonry products. The results suggest that some of these mixtures could be used in place of conventional Portland cement based products such as retaining wall bricks and pavers.

  6. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  7. Direct fired absorption machine flue gas recuperator

    DOE Patents [OSTI]

    Reimann, Robert C.; Root, Richard A.

    1985-01-01

    A recuperator which recovers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine. The recuperator includes a housing with liquid flowing therethrough, the liquid being in direct contact with the combustion gas for increasing the effectiveness of the heat transfer between the gas and the liquid.

  8. Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture

  9. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas

  10. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Thomas Nelson; Raghubir P. Gupta

    2005-01-01

    This report describes research conducted between October 1, 2004 and December 31, 2004 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Two supported sorbents were tested in a bench scale fluidized bed reactor system. The sorbents were prepared by impregnation of sodium carbonate on to an inert support at a commercial catalyst manufacturing facility. One sorbent, tested through five cycles of carbon dioxide sorption in an atmosphere of 3% water vapor and 0.8 to 3% carbon dioxide showed consistent reactivity with sodium carbonate utilization of 7 to 14%. A second, similarly prepared material, showed comparable reactivity in one cycle of testing. Batches of 5 other materials were prepared in laboratory scale quantities (primarily by spray drying). These materials generally have significantly greater surface areas than calcined sodium bicarbonate. Small scale testing showed no significant adsorption of mercury on representative carbon dioxide sorbent materials under expected flue gas conditions.

  11. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W.; Granite, Evan J.; Freeman, Mark C.; Hargis, Richard A.; O'Dowd, William J.

    2003-02-18

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  12. Flue gas cleanup using the Moving-Bed Copper Oxide Process (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: Flue gas cleanup using the Moving-Bed Copper Oxide Process Citation Details In-Document Search Title: Flue gas cleanup using the Moving-Bed Copper Oxide Process The use of copper oxide on a support had been envisioned as a gas cleanup technique to remove sulfur dioxide (SO{sub 2}) and nitric oxides (NO{sub x}) from flue gas produced by the combustion of coal for electric power generation. In general, dry, regenerable flue gas cleanup techniques

  13. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  14. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  15. Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas

    SciTech Connect (OSTI)

    Dexin Wang

    2012-03-31

    The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

  16. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  17. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  18. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T.; Pennline, Henry W.

    2007-08-14

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  19. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  20. Separation of flue-gas scrubber sludge into marketable products

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1997-08-31

    A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium sulfite/sulfate material can be oxidized into a synthetic gypsum that can be used in several markets which include: wallboard manufacturing, plaster, portland cement, and as a soil conditioner. Single stage water-only cycloning removed nearly 50% of the limestone by weight from the scrubber sludge and maintained a weight recovery of 76%. Froth flotation produced a calcium sulfite/sulfate that contained 4.30% limestone by weight with a 71% weight recovery. These methods were successful in removing some of the limestone impurity, but were not able to meet the specifications needed. However, the combination of water-only cycloning and froth flotation provided a clean, useful calcium sulfite/sulfate material with a limestone grade of 1.70% by weight and a total weight recovery of nearly 66%.

  1. Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic ... conditions relevant to removal of CO2 from air, and 3.14 mmolg (12.1 wt %) at 0.15 bar ...

  2. Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Catalysts for Oxidation of Mercury in Flue Gas National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 7776780.pdf (365 KB) Technology Marketing Summary Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb

  3. Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas

    SciTech Connect (OSTI)

    Huang, Hann-Sheng; Livengood, Charles David

    1997-12-01

    A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

  4. Dry FGD (flue-gas desulfurization) at Argonne National Laboratory

    SciTech Connect (OSTI)

    Livengood, C.D.

    1990-01-01

    Flue-gas desulfurization (FGD) systems based on spray drying are a relatively recent addition to the spectrum of sulfur dioxide (SO{sub 2}) control options available to utility and industrial boiler operators. Such systems appear to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. These advantages have promoted rapid acceptance of dry scrubbers for applications using western low-sulfur coal, but uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. At Argonne National Laboratory (ANL) we have had more than eight years of operating experience with an industrial-scale dry scrubber used with a boiler firing high-sulfur (3.5%) midwestern coal. This paper describes our operating experience with that system and summarizes several research programs that have utilized it. 7 refs., 15 figs., 6 tabs.

  5. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  6. Separation of Flue-Gas Scrubber Sludge into Marketable Products

    SciTech Connect (OSTI)

    1998-02-28

    The reduction of sulfur oxides from high sulfur coal burning utility companies has resulted in the production of huge quantities of wet flue-gas desulfurization scrubber sludge. A typical 400 MW power station burning a coal containing 3.5% sulfur by weight and using a limestone absorbent would produce approximately 177,000 tons (dry weight) of scrubber sludge per year. This brownish colored, finely divided material contains calcium sulfite (CaSO{sub 3} {center_dot} 1/2 H{sub 2}O), calcium sulfate (CaSO{sub 4} {center_dot} 2H{sub 2}O), unreacted limestone (CaCO{sub 3}), and various other impurities such as fly-ash and iron oxide particles. The physical separation of the components of scrubber sludge would result in the re-use of this material. The primary use would be conversion to a highly pure synthetic gypsum. This technical report concentrates on the effect of baffle configuration on the separation of calcium sulfite/sulfate from limestone. The position of the baffles as they related to the feed inlet, and the quantity of the baffles were examined. A clean calcium sulfite/sulfate (less than 2.0% limestone by weight) was achieved with the combination of water-only cyclone and horizontally baffled column.

  7. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  8. CO₂ Capture Membrane Process for Power Plant Flue Gas

    SciTech Connect (OSTI)

    Toy, Lora; Kataria, Atish; Gupta, Raghubir

    2011-09-30

    Because the fleet of coal-fired power plants is of such importance to the nation's energy production while also being the single largest emitter of CO₂, the development of retrofit, post-combustion CO₂ capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO₂ from plant flue gas with 95% captured CO₂ purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO₂-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft²) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO₂, NOx, etc.). Specific objectives were: - Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO₂ over N₂ and CO₂ permeance greater than 300 gas permeation units (GPU) targeted; - Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO₂ permeance than current commercial polycarbonate membranes; - Development and fabrication of membrane hollow fibers and modules from candidate polymers; - Development of a CO₂ capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and - Techno-economic evaluation of the "best" integrated CO₂ capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO₂ capture with 95% captured CO₂ purity.

  9. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    SciTech Connect (OSTI)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions, produce high purity CO{sub 2} relatively free of trace impurities and achieve ~99% CO{sub 2} capture rate while lowering the CO{sub 2} capture costs.

  10. In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas

    SciTech Connect (OSTI)

    2008-04-01

    A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

  11. Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2012-11-06

    Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

  12. Novel Application of Carbonate Fuel Cell for Capturing Carbon Dioxide from Flue Gas Streams

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Willman, Carl; Patel, Dilip; DiNitto, M.; Marina, Olga A.; Pederson, Larry R.; Steen, William A.

    2015-09-30

    To address concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s Direct FuelCell® products. The system separates the CO2 from the flue gas of other plants and produces electric power using a supplementary fuel. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of Pulverized Coal (PC) power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from the flue gas with no more than 35% increase in the cost of electricity. The project activities include: 1) laboratory scale operational and performance tests of a membrane assembly, 2) performance tests of the membrane to evaluate the effects of impurities present in the coal plant flue gas, in collaboration with Pacific Northwest National Laboratory, 3) techno-economic analysis for an ECM-based CO2 capture system applied to a 550 MW existing PC plant, in partnership with URS Corporation, and 4) bench scale (11.7 m2 area) testing of an ECM-based CO2 separation and purification system.

  13. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris CO2 capture membrane was scaled up with MTRs commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Services Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  14. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  15. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  16. pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (801 KB) Technology Marketing SummaryIncreased recycling of power plant cooling water calls for low-cost means of preventing the formation of calcium carbonate and silicate scale. Hardness (Ca and Mg) and silica are two of

  17. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  18. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  19. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  20. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  1. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M.; Saccani, C.

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  2. Catalysts for oxidation of mercury in flue gas

    DOE Patents [OSTI]

    Granite, Evan J.; Pennline, Henry W.

    2010-08-17

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  3. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and low-cost CO{sub 2} compression equipment, an incremental LCOE of $33/MWh at 90% capture can be achieved (40% lower than the advanced MEA case). Even with lower cost compression, it appears unlikely that a membrane process using high feed compression (>5 bar) can be competitive with amine absorption, due to the capital cost and energy consumption of this equipment. Similarly, low vacuum pressure (<0.2 bar) cannot be used due to poor efficiency and high cost of this equipment. High membrane permeance is important to reduce the capital cost and footprint of the membrane unit. CO{sub 2}/N{sub 2} selectivity is less important because it is too costly to generate a pressure ratio where high selectivity can be useful. A potential cost ?sweet spot? exists for use of membrane-based technology, if 50-70% CO{sub 2} capture is acceptable. There is a minimum in the cost of CO{sub 2} avoided/ton that membranes can deliver at 60% CO{sub 2} capture, which is 20% lower than the cost at 90% capture. Membranes operating with no feed compression are best suited for lower capture rates. Currently, it appears that the biggest hurdle to use of membranes for post-combustion CO{sub 2} capture is compression equipment cost. An alternative approach is to use sweep membranes in parallel with another CO{sub 2} capture technology that does not require feed compression or vacuum equipment. Hybrid designs that utilize sweep membranes for selective CO{sub 2} recycle show potential to significantly reduce the minimum energy of CO{sub 2} separation.

  4. Compression Stripping of Flue Gas with Energy Recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  5. Compression stripping of flue gas with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  6. An experimental study of flue gas desulfurization in a pilot spray dryer

    SciTech Connect (OSTI)

    Ollero, P.; Salvador, L.; Canadas, L.

    1997-12-31

    More than 45 experimental tests have been conducted on a 10,000 Nm{sup 3}/h spray-drying desulfurization pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/S ratio, approach to saturation temperature, unit load changes, and the utilization of seawater as make-up water on both spray dryer behavior and treated flue gas properties were analyzed. This experimental study allows us to reach some conclusions about how to achieve optimum operating conditions and to assess the impact of spray drying on a downstream ESP. 5 refs., 14 figs., 2 tabs.

  7. Model for flue-gas desulfurization in a circulating dry scrubber

    SciTech Connect (OSTI)

    Neathery, J.K.

    1996-01-01

    A simple model was developed to describe the absorption of SO{sub 2} in a circulating dry scrubbing (CDS) process, which is a semi dry, lime-based, flue-gas desulfurization (FGD) process that utilizes a circulating fluidized bed arrangement for contacting a sorbent with SO{sub 2}-laden flue gas under coolside conditions. The reaction chemistry is thought to be similar to that of spray-drying absorption. The liquid-phase mass-transfer coefficient was successfully modeled as a function of the sorbent particle spacing on the wetted surfaces. Gas-phase mass-transfer resistances were assumed to be insignificant. Due to the high surface area available in a CDS reactor, the evaporation rate of water from the slurry was modeled as constant-rate drying according to classic spray-dryer theory. However, the falling-rate and diffusion evaporation stages were negligible in CDS since sorbent particle bunching at the surface of the slurry is nonexistent.

  8. Sodium-based dry regenerable sorbent for carbon dioxide capture from power plant flue gas

    SciTech Connect (OSTI)

    Lee, J.B.; Ryu, C.K.; Baek, J.I.; Lee, J.H.; Eom, T.H.; Kim, S.H.

    2008-07-15

    Dry regenerable sorbent technology is one of the emerging technologies as a cost-effective and energy-efficient technology for CO{sub 2} capture from flue gas. Six sodium-based dry regenerable sorbents were prepared by spray-drying techniques. Their physical properties and reactivities were tested to evaluate their applicability to a fluidized-bed or fast transport-bed CO{sub 2} capture process. Each sorbents contained 20-50 wt% of Na{sub 2}CO{sub 3} or NaHCO{sub 3}. All sorbents except for Sorb NX30 were insufficient with either attrition resistance or reactivity, or both properties. Sorb NX30 sorbent satisfied most of the physical requirements for a commercial fluidized-bed reactor process along with good chemical reactivity. Sorb NX30 sorbent had a spherical shape, an average size of 89 {mu}m, a size distribution of 38-250 {mu}m, and a bulk density of approximately 0.87 g/mL. The attrition index (AI) of Sorb NX30 reached below 5% compared to about 20% for commercial fluidized catalytic cracking (FCC) catalysts. CO{sub 2} sorption capacity of Sorb NX30 was approximately 10 wt% (>80% sorbent utilization) in the simulated flue gas condition compared with 6 of 30 wt% MEA solution (33% sorbent utilization). All sorbents showed almost-complete regeneration at temperatures less than 120{sup o}C.

  9. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  10. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  11. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  12. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    PH adjustment of power plant cooling water with flue gasfly ash Citation Details In-Document Search Title: PH adjustment of power plant cooling water with flue gasfly ash A...

  13. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    1995-09-01

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  14. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  15. PH adjustment of power plant cooling water with flue gas/fly ash

    DOE Patents [OSTI]

    Brady, Patrick V.; Krumhansl, James L.

    2015-09-22

    A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and the condenser; and a diverter coupled to the flue to direct a portion of an exhaust from the flue to contact with a cooling medium for the condenser water. A method including diverting a portion of exhaust from a flue of a vessel; modifying the pH of a cooling medium for a condenser with the portion of exhaust; and condensing heated fluid from the vessel with the pH modified cooling medium.

  16. OpenEI Community - natural gas+ condensing flue gas heat recovery...

    Open Energy Info (EERE)

    groupincrease-natural-gas-energy-efficiency

  17. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2015-06-30

    The objective of this project was to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This final report details all development, analysis, design and testing of the project. Also included in the final report are an updated Techno-Economic Analysis and CO2 Lifecycle Analysis. The subsystems included in the pilot demonstration plant are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant was proven to be capable of capturing CO2 from various sources (gas and coal) and mineralizing it into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The final report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. The report also discusses the results of the fully integrated operation of the facility. Fiber cement boards have been produced in this facility exclusively using reactive calcium carbonate from captured CO2 from flue gas. These boards meet all US and China appropriate acceptance standards. Use demonstrations for these boards are now underway.

  18. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  19. JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas

    SciTech Connect (OSTI)

    Ye Zhuang; Christopher Martin; John Pavlish

    2009-03-31

    This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

  20. Status of spray-dryer flue-gas desulfurization. Final report

    SciTech Connect (OSTI)

    Ireland, P.A.

    1982-01-01

    Utility interest and commitment to spray drying for SO/sub 2/ and particulate control has increased dramatically in response to vendor claims (lower costs, dry wastes, lower energy requirements, and simplicity) and newly promulgated federal emission regulations that allow lower SO/sub 2/ removal requirements (70%) for low-sulfur coals. Unfortunately, limited data are available from which to evaluate vendor claims prior to commercial commitment or to improve the cost and reliability of this potentially important flue gas desulfurization (FGD) option. Accordingly, EPRI is conducting a pilot-scale project (RP1870) to provide a systematic evaluation of the technology unconstrained by specific vendor designs, operating philosophy, or commercial limitation. It will result in guidelines for system design and optimization in order to ensure reliable utility operation at minimum cost. This final report (TPS 80-741) contains a review of the design practices for the full-scale systems ordered and a discussion of the important spray-drying FGD process variables. Other EPRI work in this area includes a cost study with the Tennessee Valley Authority (RP1180-7) and a spray-dryer waste solids characterization (RP1870-2). The EPA has published a similar status document, which, in addition to spray drying, also covers dry injection and burning coal-alkali mixtures. However, the EPA document is not as detailed on either the design of full-scale systems or the technical issues.

  1. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  2. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    Krumhansl, James L. A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and...

  3. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  4. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  5. CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents

    SciTech Connect (OSTI)

    Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

    2012-08-31

    The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

  6. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energys National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of staining upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  7. Effects of flue gas components on the reaction of Ca(OH){sub 2} with SO{sub 2}

    SciTech Connect (OSTI)

    Liu, C.F.; Shih, S.M.

    2006-12-20

    A differential fixed-bed reactor was employed to study the effects of the flue gas components, H{sub 2}O, CO{sub 2}, NOx, and O{sub 2}, on the reaction between Ca(OH){sub 2} and SO{sub 2} under conditions similar to those in the bag filters of a spray-drying flue gas desulfurization (FGD) system. The presence of CO{sub 2} with SO{sub 2} in the gas phase enhanced the sulfation of Ca(OH){sub 2} only when NOx was also present. When either NOx (mainly NO) or O{sub 2} was present with SO{sub 2}, the enhancement effect was slight, but became great when both NOx and O{sub 2} were present, and was even greater when CO{sub 2} was also present. The great enhancement effect exerted by the presence of NOx/O{sub 2} resulted from the rise in the NO{sub 2} concentration, which enhanced the oxidation of HSO{sub 3}- and SO{sub 3}{sup 2-} to SO{sub 4}{sup 2-} in the water layer adsorbed on Ca(OH){sub 2} surface and the formation of deliquescent salts of calcium nitrite and nitrate. The enhancement effect due to the presence of NOx/O{sub 2} was more pronounced when the relative humidity was above that at which the salts deliquesced; the extent of sulfation was more than twice that obtained when SO{sub 2} alone was present. The presence of H{sub 2}O, CO{sub 2}, NOx, and O{sub 2} in the flue gas is beneficial to the SO{sub 2} capture in the low-temperature dry and semidry FGD processes. The presence of NOx/O{sub 2} also enhanced CO{sub 2} removal when SO{sub 2} was absent.

  8. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  9. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  10. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  11. CO[sub 2] capture from the flue gas of conventional fossil-fuel-fired power plants

    SciTech Connect (OSTI)

    Wolsky, A.M.; Daniels, E.J.; Jody, B.J. )

    1994-08-01

    Research has been conducted at Argonne National Laboratory to identify and evaluate the advantages and deficiencies of several technologies, both commercially available and alternative technologies, for capturing CO[sub 2] from the flue gas of utility boilers that use air as an oxidant (the current universal practice). The technologies include chemical solvent, cryogenic, membrane, physical absorption, and physical adsorption methods. In general, technologies for capturing CO[sub 2] are expensive and energy-intensive. Therefore, they result in a substantial overall increase in the cost of power generation. Research to improve the performance and economics of these technologies is discussed. 20 refs., 6 figs., 1 tab.

  12. Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  13. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  14. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  15. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  16. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  17. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  18. Fundamental mechanisms in flue gas conditioning. Topical report No. 2, Literature review and assembly of theories on the interactions of ash and conditioning agents

    SciTech Connect (OSTI)

    Bush, P.V.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ask properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  19. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping . E-mail: zzhong@seu.edu.cn; Jin Baosheng; Huang Yaji; Zhou Hongcang; Lan Jixiang

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  20. Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Fogash, Kevin

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  1. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  2. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  3. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  4. Development of a Novel Gas Pressurized Stripping Process-Based Technology for CO₂ Capture from Post-Combustion Flue Gases

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2015-09-30

    A novel Gas Pressurized Stripping (GPS) post-combustion carbon capture (PCC) process has been developed by Carbon Capture Scientific, LLC, CONSOL Energy Inc., Nexant Inc., and Western Kentucky University in this bench-scale project. The GPS-based process presents a unique approach that uses a gas pressurized technology for CO₂ stripping at an elevated pressure to overcome the energy use and other disadvantages associated with the benchmark monoethanolamine (MEA) process. The project was aimed at performing laboratory- and bench-scale experiments to prove its technical feasibility and generate process engineering and scale-up data, and conducting a techno-economic analysis (TEA) to demonstrate its energy use and cost competitiveness over the MEA process. To meet project goals and objectives, a combination of experimental work, process simulation, and technical and economic analysis studies were applied. The project conducted individual unit lab-scale tests for major process components, including a first absorption column, a GPS column, a second absorption column, and a flasher. Computer simulations were carried out to study the GPS column behavior under different operating conditions, to optimize the column design and operation, and to optimize the GPS process for an existing and a new power plant. The vapor-liquid equilibrium data under high loading and high temperature for the selected amines were also measured. The thermal and oxidative stability of the selected solvents were also tested experimentally and presented. A bench-scale column-based unit capable of achieving at least 90% CO₂ capture from a nominal 500 SLPM coal-derived flue gas slipstream was designed and built. This integrated, continuous, skid-mounted GPS system was tested using real flue gas from a coal-fired boiler at the National Carbon Capture Center (NCCC). The technical challenges of the GPS technology in stability, corrosion, and foaming of selected solvents, and environmental, health and safety risks have been addressed through experimental tests, consultation with vendors and engineering analysis. Multiple rounds of TEA were performed to improve the GPS-based PCC process design and operation, and to compare the energy use and cost performance of a nominal 550-MWe supercritical pulverized coal (PC) plant among the DOE/NETL report Case 11 (the PC plant without CO₂ capture), the DOE/NETL report Case 12 (the PC plant with benchmark MEA-based PCC), and the PC plant using GPS-based PCC. The results reveal that the net power produced in the PC plant with GPS-based PCC is 647 MWe, greater than that of the Case 12 (550 MWe). The 20-year LCOE for the PC plant with GPS-based PCC is 97.4 mills/kWh, or 152% of that of the Case 11, which is also 23% less than that of the Case 12. These results demonstrate that the GPS-based PCC process is energy-efficient and cost-effective compared with the benchmark MEA process.

  5. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Lippert, Thomas E.

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  6. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  7. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the U.S. Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SITJC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC-30252). Under the agreement SIUC will develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mine workings, and assess the environmental impact of such underground placements. This report discusses the technical progress achieved during the period October 1 - December 31, 1995. Rapid Aging Test columns were placed in operation during the second quarter of 1995, and some preliminary data were acquired during this quarter. These data indicate that the highly caustic pH is initially generated in the pneumatic mix, but that such pH is short lived. The initial pH rapidly declines to the range of 8 to 9. Leachates in this pH range will have little or no effect on environmental concerns. Dedicated sampling equipment was installed in the groundwater monitoring wells at the proposed placement site at the Peabody Number 10 mine. Also, the groundwater monitoring wells were {open_quotes}developed{close_quotes} during the quarter to remove the fines trapped in the sand pack and screen. A new procedure was used in this process, and proved successful. A series of tests concerning the geotechnical characteristics of the pneumatic mixes were conducted. Results show that both moisture content and curing time have a direct effect on the strength of the mixes. These are, of course, the expected general results. The Christmas holidays and the closing of the University during an extended period affected the progress of the program during the quarter. However, the program is essentially on schedule, both technically and fiscally, and any delays will be overcome during the first quarter of 1996.

  8. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-11-01

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  9. Simulation of spray drying absorber for removal of HC1 in flue gas from incinerators

    SciTech Connect (OSTI)

    Uchida, S.; Tsuchiga, K.

    1984-04-01

    A theoretical study on the spray drying absorber in an HC1 removal process by lime slurries has been performed with a mathematical model which describes heat and mass transfer and fluid flows in the absorber. From heat and mass balances and a force balance for a moving droplet in the absorber, a set of first-order, nonlinear differential equations relating the amount of water, the gas and droplet temperatures, the drop velocity, the HC1 partial pressure, etc., along the axial direction of the tower was formulated. These relationships were numerically solved to give characteristic profiles in the tower. The results of the simulation based on this model were compared with experimental data and showed satisfactory agreement.

  10. Influence of CO{sub 2} and O{sub 2} on the reaction of Ca(OH){sub 2} under spray-drying flue gas desulfurization conditions

    SciTech Connect (OSTI)

    Ho, C.S.; Shih, S.M.; Lee, C.D.

    1996-11-01

    The influence of CO{sub 2} and O{sub 2} in the flue gas on the reaction of hydrated lime sorbent with SO{sub 2} was studied using a fixed-bed differential reactor under conditions prevailing in the spray-drying flue gas desulfurization process. With the presence of CO{sub 2}, the sulfation and carbonation reactions of Ca(OH){sub 2} took place simultaneously until Ca(OH){sub 2} ceased to react. The CaCO{sub 3} produced reacted further to form CaSO{sub 3}{center_dot}{1/2}H{sub 2}O. The apparent sulfation rate, total reaction rate, and final total conversion of Ca(OH){sub 2} were greater than those for the case without CO{sub 2}. The final total conversion was about 1.45 times that for the latter case at the conditions of 1,000 ppm SO{sub 2}, 60 C, and 70% relative humidity. The same effect was observed whether CO{sub 2} was present with O{sub 2} or not. Kinetic expressions obtained by assuming chemical reaction control and considering the surface coverage by product crystals best represented the kinetic data.

  11. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon’s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  12. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes. Volume 2, Duct spray drying: Final report

    SciTech Connect (OSTI)

    Jozewicz, W.; Rochelle, G.T.

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  13. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  14. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-12-31

    This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

  15. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 12, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    1994-12-31

    The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from the flue gas of a coal-fired utility boiler. In the process, the SO{sub 2} is reduced to sulfur by-product and the NO{sub x} is reduced to nitrogen and oxygen. It is predicted that the process can economically remove 90% of the acid rain precursor gases from the flue gas stream in a retrofit or new facility. The objective of the NOXSO Demonstration Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process. The effectiveness of the process will be demonstrated by achieving significant reductions in emissions of sulfur and nitrogen oxides. In addition, sufficient operating data will be obtained to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is presently in the project definition and preliminary design phase. Data obtained during pilot plant testing which was completed on July 30, 1993 is being incorporated in the design of the commercial size plant. A suitable host site to demonstrate the NOXSO process on a commercial scale is presently being sought. The plant general arrangement has been revised to incorporate principles used in the design of fluidized catalytic cracking (FCC) plants. A NOXSO plant availability analysis was prepared using operating experience from the recently completed pilot plant as a basis. The impact of water desorption in the sorbent heater and water adsorption in the sorbent cooler has been quantified and incorporated into the NOXSO process simulator. NOXSO process economics has been updated based on the present design. Capital cost for a 500 MW plant designed to remove 98% of the SO{sub 2} and 85% of the NO{sub x} is estimated at $247/kW.

  16. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  17. Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas

    DOE Patents [OSTI]

    Chang, Shih-Ger; Liu, David K.; Griffiths, Elizabeth A.; Littlejohn, David

    1988-01-01

    The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

  18. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

  19. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  20. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  1. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect (OSTI)

    Sublette, K.L.

    1992-12-31

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  2. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  3. Development of a Novel Gas Pressurized Process-Based Technology for CO2 Capture from Post-Combustion Flue Gases Preliminary Year 1 Techno-Economic Study Results and Methodology for Gas Pressurized Stripping Process

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2013-03-01

    Under the DOE’s Innovations for Existing Plants (IEP) Program, Carbon Capture Scientific, LLC (CCS) is developing a novel gas pressurized stripping (GPS) process to enable efficient post-combustion carbon capture (PCC) from coal-fired power plants. A technology and economic feasibility study is required as a deliverable in the project Statement of Project Objectives. This study analyzes a fully integrated pulverized coal power plant equipped with GPS technology for PCC, and is carried out, to the maximum extent possible, in accordance to the methodology and data provided in ATTACHMENT 3 – Basis for Technology Feasibility Study of DOE Funding Opportunity Number: DE-FOA-0000403. The DOE/NETL report on “Cost and Performance Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity (Original Issue Date, May 2007), NETL Report No. DOE/NETL-2007/1281, Revision 1, August 2007” was used as the main source of reference to be followed, as per the guidelines of ATTACHMENT 3 of DE-FOA-0000403. The DOE/NETL-2007/1281 study compared the feasibility of various combinations of power plant/CO2 capture process arrangements. The report contained a comprehensive set of design basis and economic evaluation assumptions and criteria, which are used as the main reference points for the purpose of this study. Specifically, Nexant adopted the design and economic evaluation basis from Case 12 of the above-mentioned DOE/NETL report. This case corresponds to a nominal 550 MWe (net), supercritical greenfield PC plant that utilizes an advanced MEAbased absorption system for CO2 capture and compression. For this techno-economic study, CCS’ GPS process replaces the MEA-based CO2 absorption system used in the original case. The objective of this study is to assess the performance of a full-scale GPS-based PCC design that is integrated with a supercritical PC plant similar to Case 12 of the DOE/NETL report, such that it corresponds to a nominal 550 MWe supercritical PC plant with 90% CO2 capture. This plant has the same boiler firing rate and superheated high pressure steam generation as the DOE/NETL report’s Case 12 PC plant. However, due to the difference in performance between the GPS-based PCC and the MEA-based CO2 absorption technology, the net power output of this plant may not be exactly at 550 MWe.

  4. Increase Natural Gas Energy Efficiency | OpenEI Community

    Open Energy Info (EERE)

    Blog entry Discussion Document Event Poll Question Keywords Author Apply There is no matching content in the group. Group links The technology of Condensing Flue Gas Heat Recovery...

  5. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, Chang Y.

    1993-01-01

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.

  6. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons

    SciTech Connect (OSTI)

    Hajizadeh, Yaghoub; Onwudili, Jude A.; Williams, Paul T.

    2011-06-15

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275 deg. C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 {mu}g I-TEQ kg{sup -1} toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 {mu}g I-TEQ kg{sup -1} in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  7. Method and apparatus for forming flues on tubular stock

    DOE Patents [OSTI]

    Beck, D.E.; Carson, C.

    1979-12-21

    The present invention is directed to a die mechanism utilized for forming flues on long, relatively narrow tubular stock. These flues are formed by displacing a die from within the tubular stock through perforations previously drilled through the tubular stock at selected locations. The drawing of the die upsets the material to form the flue of the desired configuration. The die is provided with a lubricating system which enables the lubricant to be dispensed uniformly about the entire periphery of the die in contact with the material being upset so as to assure the formation of the flues. Further, the lubricant is dispensed from within the die onto the peripheral surface of the latter at pressures in the range of about 2000 to 10,000 psi so as to assure the adequate lubrication of the die during the drawing operation. By injecting the lubricant at such high pressures, low viscosity liquid, such as water and/or alcohol, may be efficiently used as a lubricant and also provides a mechanism by which the lubricant may be evaporated from the surface of the flues at ambient conditions so as to negate the cleansing operations previously required prior to joining the flues to other conduit mechanisms by fusion welding and the like.

  8. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    These comparisons were used to evaluate the two instruments at their present state of development. Authors: Montagna, J C ; Smith, G W ; Teats, F G ; Voge, G J ; Jonke, A A ...

  9. Ranking low cost sorbents for mercury capture from simulated flue gases

    SciTech Connect (OSTI)

    H. Revata Seneviratne; Cedric Charpenteau; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-12-15

    Coal fired utility boilers are the largest anthropogenic source of mercury release to the atmosphere, and mercury abatement legislation is already in place in the USA. The present study aimed to rank low cost mercury sorbents (char and activated carbon from the pyrolysis of scrap tire rubber and two coal fly ashes from UK power plants) against Norit Darco HgTM for mercury retention by using a novel bench-scale reactor. In this scheme, a fixed sorbent bed was tested for mercury capture efficiency from a simulated flue gas stream. Experiments with a gas stream of only mercury and nitrogen showed that while the coal ashes were the most effective in mercury capture, char from the pyrolysis of scrap tire rubber was as effective as the commercial sorbent Norit Darco HgTM. Tests conducted at 150{sup o}C, with a simulated flue gas mix that included N{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, SO{sub 2} and HCl, showed that all the sorbents captured approximately 100% of the mercury in the gas stream. The introduction of NO and NO{sub 2} was found to significantly improve the mercury capture, possibly by reactions between NOx and the mercury. Since the sorbents' efficiency decreased with increasing test temperature, physical sorption could be the initial step in the mercury capture process. As the sorbents were only exposed to 64 ng of mercury in the gas stream, the mercury loadings on the samples were significantly less than their equilibrium capacities. The larger capacities of the activated carbons due to their more microporous structure were therefore not utilized. Although the sorbents have been characterized by BET surface area analysis and XRD analysis, further analysis is needed in order to obtain a more conclusive correlation of how the characteristics of the different sorbents correlate with the observed variations in mercury capture ability. 34 refs., 8 figs., 6 tabs.

  10. Load Preheating Using Flue Gases from a Fuel-Fired Heating System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Load Preheating Using Flue Gases from a Fuel-Fired Heating System This tip sheet discusses ... PROCESS HEATING TIP SHEET 9 PDF icon Load Preheating Using Flue Gases from a Fuel-Fired ...

  11. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2014-08-19

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  12. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2010-11-09

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  13. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, C.Y.

    1993-09-21

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

  14. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, Evan J.; Pennline, Henry W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  15. 2011 | Center for Gas SeparationsRelevant to Clean Energy Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Co-assembly of Nanotube Subunits and Block Copolymers Link to article Sep 6, 2012 Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas Link to article Sep 6, 2012...

  16. Promising Technology: Condensing Gas Water Heaters

    Broader source: Energy.gov [DOE]

    Condensing water heaters achieve higher efficiencies than conventional water heaters by capturing the latent heat from water vapor contained in the flue gases. Combustion gases are exhausted through a secondary heat exchanger where the latent heat of water vapor in the exhaust gas is transferred to the stored water. This technology enables the water heater to achieve thermal efficiencies up to 99%.

  17. High potential recovery -- Gas repressurization

    SciTech Connect (OSTI)

    Madden, M.P.

    1998-05-01

    The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

  18. GAS INJECTION/WELL STIMULATION PROJECT

    SciTech Connect (OSTI)

    John K. Godwin

    2005-12-01

    Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

  19. DEVELOPMENT OF A NOVEL GAS PRESSURIZED STRIPPING (GPS)-BASED TECHNOLOGY FOR CO2 CAPTURE FROM POST-COMBUSTION FLUE GASES Topical Report: Techno-Economic Analysis of GPS-based Technology for CO2 Capture

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2015-09-30

    This topical report presents the techno-economic analysis, conducted by Carbon Capture Scientific, LLC (CCS) and Nexant, for a nominal 550 MWe supercritical pulverized coal (PC) power plant utilizing CCS patented Gas Pressurized Stripping (GPS) technology for post-combustion carbon capture (PCC). Illinois No. 6 coal is used as fuel. Because of the difference in performance between the GPS-based PCC and the MEA-based CO2 absorption technology, the net power output of this plant is not exactly 550 MWe. DOE/NETL Case 11 supercritical PC plant without CO2 capture and Case 12 supercritical PC plant with benchmark MEA-based CO2 capture are chosen as references. In order to include CO2 compression process for the baseline case, CCS independently evaluated the generic 30 wt% MEA-based PCC process together with the CO2 compression section. The net power produced in the supercritical PC plant with GPS-based PCC is 647 MW, greater than the MEA-based design. The levelized cost of electricity (LCOE) over a 20-year period is adopted to assess techno-economic performance. The LCOE for the supercritical PC plant with GPS-based PCC, not considering CO2 transport, storage and monitoring (TS&M), is 97.4 mills/kWh, or 152% of the Case 11 supercritical PC plant without CO2 capture, equivalent to $39.6/tonne for the cost of CO2 capture. GPS-based PCC is also significantly superior to the generic MEA-based PCC with CO2 compression section, whose LCOE is as high as 109.6 mills/kWh.

  20. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    SciTech Connect (OSTI)

    Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

    2014-11-01

    Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

  1. DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS

    Office of Scientific and Technical Information (OSTI)

    ... Granite fed 2.2 % methanol in helium over the partial oxidation catalyst oxides bismuth oxide, yttria-bismuth oxide, and yttria-stabilized zirconia at 545F, and was able to form ...

  2. Application of holographic neural networks for flue gas emissions prediction in the Burnaby incinerator

    SciTech Connect (OSTI)

    Zheng, L.; Dockrill, P.; Clements, B.

    1997-12-31

    This article describes the development of a parametric prediction system (PPS) for various emission species at the Burnaby incinerator. The continuous emissions monitoring system at the Burnaby incinerator is shared between three boilers and therefore actual results are only available 5 minutes out of every 15 minutes. The PPS was developed to fill in data for the 10 minutes when the Continuous Emission Monitor (CEM) is measuring the other boilers. It bases its prediction on the last few actual readings taken and parametrically predicts CO, SO2 and NOx. The Burnaby Incinerator is located in the commercial/industrial area of South Burnaby, British Columbia. It consists of three separate lines, each burning ten tonnes of garbage per hour and producing about three tonnes of steam for every tonne of garbage burned. The air pollution control system first cools the combustion products with water injection and then scrubs them with very fine hydrated lime. Carbon is added to the lime to enhance the scrubbing of the combustion products. The CEM monitors the levels of oxygen, carbon monoxide, nitrogen oxides, sulphur dioxide and opacity. In 1996, an expert system was installed on one of boilers at the Burnaby Incinerator plant to determine if it could improve the plant=s operations and reduce overall emission. As part of the expert system, the PPS was developed. Holographic Neural Technology (HNeT), developed by AND Corporation of Toronto, Ontario, is a novel neural network technology using complex numbers in its architecture. Compared to the traditional neural networks, HNeT has some significant advantage. It is more resilient against converging on local minima; is faster training and executing; less prone to over fitting; and, in most cases, has significantly lower error. Selection of independent variabs, training set preparation, testing neural nets and other related issue will be discussed.

  3. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect (OSTI)

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  4. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Brent Constantz; Randy Seeker; Martin Devenney

    2010-06-30

    Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

  5. Baseload gas turbine to meet utility requirements for reliability and availability

    SciTech Connect (OSTI)

    Grevstad, P.E.; Smith, M.J.; Duncan, R.L.

    1982-04-01

    The coal gasifier-gas turbine, combined cycle is described as a superior baseload electric generating system. It promises lower fuel cost, lower operating and maintenance cost, and superior siting and environmental characteristics over conventional steam systems with flue gas clean up and fluidized bed combined cycle systems. Two major new components are required: 1) the coal gasifier, and 2) the baseload gas turbine. 10 refs.

  6. Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions

    SciTech Connect (OSTI)

    Lee, Joo-Youp

    2013-09-30

    A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high pH and temperatures.

  7. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  8. Characterization and control of exhaust gas from diesel engine firing coal-water mixture

    SciTech Connect (OSTI)

    Samuel, E.A.; Gal, E.; Mengel, M.; Arnold, M.

    1990-03-01

    Exhaust from the GE-TS single cylinder diesel engine, fitted with hardened metal, and diamond-tipped metal fuel injection nozzles, and firing coal-water mixture (CWM) has been characterized with respect to gas composition, particulate size distribution, and particulate filtration characteristics. The measured flue gas compositions are roughly in keeping with results from combustion calculations. The time variations of the hydrocarbon, CO, and NO[sub x] concentrations are also understood in terms of known reaction mechanisms.

  9. Characterization and control of exhaust gas from diesel engine firing coal-water mixture

    SciTech Connect (OSTI)

    Samuel, E.A.; Gal, E.; Mengel, M.; Arnold, M.

    1990-03-01

    Exhaust from the GE-TS single cylinder diesel engine, fitted with hardened metal, and diamond-tipped metal fuel injection nozzles, and firing coal-water mixture (CWM) has been characterized with respect to gas composition, particulate size distribution, and particulate filtration characteristics. The measured flue gas compositions are roughly in keeping with results from combustion calculations. The time variations of the hydrocarbon, CO, and NO{sub x} concentrations are also understood in terms of known reaction mechanisms.

  10. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1994-10-01

    Preliminary environmental risk assessment on the FGD by-products to be placed underground is virtually complete. The initial mixes for pneumatic and hydraulic placement have been selected and are being subject to TCLP, ASTM, and modified SLP shake tests as well as ASTM column leaching. Results of these analyses show that the individual coal combustion residues, and the residues mixes, are non-hazardous in character. Based on available information, including well logs obtained from Peabody Coal Company, a detailed study of the geology of the placement site was completed. The study shows that the disposal site in the abandoned underground mine workings at depths of between 325 and 375 feet are well below potable groundwater resources. This, coupled with the benign nature of the residues and residues mixtures, should alleviate any concern that the underground placement will have adverse effects on groundwater resources. Seven convergence stations were installed in the proposed underground placement area of the Peabody Coal Company No. 10 mine. Several sets of convergence data were obtained from the stations. A study of materials handling and transportation of coal combustion residues from the electric power plant to the injection site has been made. The study evaluated the economics of the transportation of coal combustion residues by pneumatic trucks, by pressure differential rail cars, and by SEEC, Inc. collapsible intermodal containers (CICs) for different annual handling rates and transport distances. The preliminary physico-chemical characteristics and engineering properties of various FBC fly ash-spent bed mixes have been determined, and long-term studies of these properties are continuing.

  11. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.

    1997-12-31

    The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

  12. Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility

    SciTech Connect (OSTI)

    Metz, Paul; Bolz, Patricia

    2013-03-25

    With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

  13. CO.sub.2 separation from low-temperature flue gases

    DOE Patents [OSTI]

    Dilmore, Robert; Allen, Douglas; Soong, Yee; Hedges, Sheila

    2010-11-30

    Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

  14. Promising Technology: Condensing Gas Boilers

    Broader source: Energy.gov [DOE]

    Condensing boilers achieve higher efficiencies than conventional boilers by capturing the latent heat from water vapor contained in the flue gases.

  15. California Natural Gas Number of Gas and Gas Condensate Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) California Natural Gas Number of Gas and ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) California Natural ...

  16. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  17. An industrial FT-IR process gas analyzer for stack gas cems analysis

    SciTech Connect (OSTI)

    Welch, G.M.; Herman, B.E.

    1995-12-31

    This paper describes utilizing Fourier Transform Infrared (FT-IR) technology to meet and exceed EPA requirements to Continuously Monitor Carbon Monoxide (CO) and Sulfur Dioxide (SO){sub 2} in an oil refinery. The application consists of Continuous Emission Monitoring (CEMS) of two stacks from a Fluid Catalytic Cracking unit (FCCU). The discussion will follow the project from initial specifications, installation, start-up, certification results (RATA, 7 day drift), Cylinder Gas Audit (CGA) and the required maintenance. FT-IR is a powerful analytical tool suitable for measurement of stack component gases required to meet CEMS regulations, and allows simultaneous multi-component analysis of complex stack gas streams with a continuous sample stream flow through the measurement cell. The Michelson Interferometer in a unique {open_quotes}Wishbone{close_quotes} design and with a special alignment control enables standardized configuration of the analyzer for flue gas analysis. Normal stack gas pollutants: NO{sub x}, SO{sub 2}, and CO; as well as water soluble pollutants such as NH{sub 3} and HCI may be accurately determined and reported even in the presence of 0-31 Vol % water vapor concentrations (hot and wet). This FT-IR analyzer has been operating with EPA Certification in an oil refinery environment since September 1994.

  18. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  19. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  20. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  1. Nebraska Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  2. Missouri Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  3. Michigan Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  4. Kentucky Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  5. Mississippi Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  6. Maryland Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  7. Louisiana Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  8. Research | Center for Gas SeparationsRelevant to Clean Energy Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Blandine Jerome Research Previous Next List The overall aim of the CGS is to develop the science, i.e., novel synthetic routes combined with novel characterization and computational methods, that will enable us to "tailor-make" a material that has the best possible performance for a given gas separation problem. The focus of the first phase of the Center was on carbon dioxide capture from the flue gases of power plants. In the renewal, we propose to continue the portions of that

  9. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  10. The structural design of air and gas ducts for power stations and industrial boiler applications

    SciTech Connect (OSTI)

    Schneider, R.L.

    1996-10-01

    The purpose of this paper is to discuss the new American Society of Civil Engineers (ASCE) book entitled, The Structural Design of Air and Gas Ducts for Power Stations and Industrial Boiler Applications. This 312 page book was published by the ASCE in August of 1995. This ASCE publication was created to assist structural engineers in performing the structural analysis and design of air and flue-gas ducts. The structural behavior of steel ductwork can be difficult to understand for structural engineers inexperienced in ductwork analysis and design. Because of this needed expertise, the ASCE committee that created this document highly recommends that the structural analysis and design of ducts be performed by qualified structural engineers, not be technicians, designers or drafters. There is a history within the power industry of failures and major degradation of flue-gas ductwork. There are many reasons for these failures or degradation, but in many cases, the problems may have been voided by a better initial design. This book attempts to help the structural engineer with this task. This book is not intended to be used to size or configure ductwork for flow and pressure drop considerations. But it does recommend that the ductwork system arrangement consider the structural supports and the structural behavior of the duct system.

  11. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  12. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, ... Analysis of Technology and Policy Tradeoffs, Energy Policy, ...

  13. Gas magnetometer

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2016-05-03

    Measurement of a precessional rate of a gas, such as an alkali gas, in a magnetic field is made by promoting a non-uniform precession of the gas in which substantially no net magnetic field affects the gas during a majority of the precession cycle. This allows sensitive gases that would be subject to spin-exchange collision de-phasing to be effectively used for extremely sensitive measurements in the presence of an environmental magnetic field such as the Earth's magnetic field.

  14. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  15. High volume - high value usage of Flue Gas Desulfurization (FGD) by-products in underground mines. Quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    The amount of dry FGD materials produced in the U.S. has not been increasing at the high rate originally anticipated. This has been due to a number of economic factors affecting the utility industry. Technologies for the disposal of large amounts of materials are not going to be implemented in the near term. In light of this development the target application for this project is being changed from highwall adit filling to the filling of auger holes to allow for highwall mining. This application focuses on using the dry FGD material to recover coal isolated by excessive augering. It produces 10 or more times the amount of coal per ton of dry FGD utilized than the originally proposed methodology. It also does not require extensive equipment development and, if applied to abandoned mine lands, may have substantially more significant environmental benefit. We also propose to use a spray dryer material for the demonstration instead of the fluidized bed material originally proposed. The spray dryer material is already slacked eliminating problems associated with heat generation at the mine site. Auger hole grouting with FGD material is also best performed by hydraulic emplacement methods.

  16. Solid-Fueled Pressurized Chemical Looping with Flue-Gas Turbine Combined Cycle for Improved Plant Efficiency and CO{sub 2} Capture

    SciTech Connect (OSTI)

    Liu, Kunlei; Chen, Liangyong; Zhang, Yi; Richburg, Lisa; Simpson, James; White, Jay; Rossi, Gianalfredo

    2013-12-31

    The purpose of this document is to report the final result of techno-economic analysis for the proposed 550MWe integrated pressurized chemical looping combustion combined cycle process. An Aspen Plus based model is delivered in this report along with the results from three sensitivity scenarios including the operating pressure, excess air ratio and oxygen carrier performance. A process flow diagram and detailed stream table for the base case are also provided with the overall plant energy balance, carbon balance, sulfur balance and water balance. The approach to the process and key component simulation are explained. The economic analysis (OPEX and CAPX) on four study cases via DOE NETL Reference Case 12 are presented and explained.

  17. High-volume, high-value usage of Flue Gas Desulfurization (FGD) by-products in underground mines Phase 1: Laboratory investigations. Quarterly report, July 1994--September 1994

    SciTech Connect (OSTI)

    1994-12-01

    During the quarter a second series of samples were collected and partially characterized chemically and mineralogically. The samples were collected at the disposal site operated by Freeman United Coal Co. The second collection was necessary because of deterioration due to hydration of the original samples. A study of the hydration characteristics was completed during the quarter. Important reactions included the immediate formation of ettringite and portlandite. The hydration and transformation was found to be a slow process. A second phase of gypsum formation from ettringite deterioration was identified. The slow hydration of anhydrite with its resultant swell is a potential problem which will be addressed further. Geotechnical characterization, during the quarter included completion of the preliminary characterization, analysis of the findings, experimentation with sample preparation for the final characterization/mix design, and design of the final experimental program. The analysis of the coals collected during the core drilling and hydrologic planning were completed. Also during the quarter a meeting was held with representatives of the shotcrete industry to discuss transport systems for emplacement. The pros and cons of pneumatic and hydraulic systems were discussed and plans formulated for further investigations.

  18. Fundamental study of the NOXSO combined NO/sub x//SO/sub 2/ flue gas treatment process: corrosion and its prevention

    SciTech Connect (OSTI)

    Perng, T.P.

    1984-07-31

    The high temperature corrosion behavior (oxidation, sulfidation, and hot corrosion) of a number of Ni-base and Fe-base alloys has been discussed. Ni-base alloys are found to be incompatible with the compounds involved in the NOXSO Process regeneration reactions. Austenitic stainless steels are susceptible to sensitization and to a limited extent, hot corrosion. Type 446 ferritic stainless steel with high Cr content and no Ni performs satisfactorily under the service conditions. Improvement of high temperature corrosion resistance can be achieved by surface coatings such as aluminizing, chromizing, MCrAlY overlay coatings, or ceramic coatings. Aluminized 316L stainless steel has proven effective against the corrosion attack. Other base materials such as low alloy steels, low Cr-content ferritic stainless steels, or low carbon austenitic stainless steels may also be considered, provided good surface coatings are applied. 11 references, 8 figures, 9 tables.

  19. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Environmental information volume

    SciTech Connect (OSTI)

    1998-12-31

    The Clean Coal Technology (CCT) Demonstration Program is a $5 billion technology demonstration program that was legislated by Congress to be funded jointly by the federal government and industrial or other sector participants. The goal of the Program is to make available to the U.S. energy marketplace a number of advanced, more efficient, reliable, and environmentally responsive coal utilization and environmental control technologies. These technologies are intended to reduce or eliminate the economic and environmental impediments that limit the full consideration of coal as a future energy resource. Over the next decade, the Program will advance the technical, environmental and economic performance of these advanced technologies to the point where the private sector will be able to introduce them into the commercial marketplace. Each of these demonstrations is in a scale large enough to generate sufficient design, construction and operation data for the private sector to judge the technology`s commercial potential and to make informed confident decisions on its commercial readiness. The strategy being implemented to achieve the goal of the CCT Demonstration Program is to conduct a multi-phase effort consisting of at least five separate solicitations for projects, each with individual objectives that, when integrated, will make technology options available on a schedule consistent with the demands of the energy market and responsive to the relevant environmental considerations. This paper describes a commercial demonstration project to be fielded in support of this program.

  20. Reduction of air in-leakage and flue gas by-passing in the penthouse of Duke Power-Marshall Unit No. 4

    SciTech Connect (OSTI)

    Campbell, R.; Rush, T.

    1995-12-31

    After a year of operation, the penthouse was inspected and found to be {open_quotes}lightly dusted{close_quotes} with barely sufficient accumulation to show footprints. This is contrasted with previous five foot deep ash dunes. The savings in maintenance repairs are estimated at $65,000 for vacuuming that was not required, and $80,000 in maintenance personnel weld repairs. The history of repairs was such that vacuuming and weld repair costs were predictable, and before the IOSMEMBRANE{reg_sign} installation, always expected as recurring maintenance costs. The heat rate improvement of reducing air in-leakage is well known, and significant. The principal quantified savings are in reduced maintenance costs, more expedient repairs (reduced cool down time for repairs in the penthouse), and safety. The heat rate improvements, though not quantified yet, are expected to be significant. The success of the ISOMEMBRANE{reg_sign} on Unit No. 4 has resulted in similar plans for Unit No. 3 and other units in the Duke Power system.

  1. Natural Gas Regulation

    Broader source: Energy.gov [DOE]

    The Natural Gas Act of 1938, as amended, requires any person who wishes to import and/or export natural gas, (including liquefied natural gas, compressed natural gas, compressed gas liquids, etc.)...

  2. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{sub 2} capture on an existing air-fired CFB plant. ALSTOM received a contract award from the DOE to conduct a project entitled 'Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control', under Cooperative Agreement DE-FC26-04NT42205 that is the subject of this topical report.

  3. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; Summers, Cathy A.; Gerdemann, Steve; Oryshchyn, Danylo B.; Turner, Paul; Patrick, Brian R.

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  4. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  5. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  6. GAS SEAL

    DOE Patents [OSTI]

    Monson, H.; Hutter, E.

    1961-07-11

    A seal is described for a cover closing an opening in the top of a pressure vessel that may house a nuclear reactor. The seal comprises a U-shaped trough formed on the pressure vessel around the opening therein, a mass of metal in the trough, and an edge flange on the cover extending loosely into the trough and dipping into the metal mass. The lower portion of the metal mass is kept melted, and the upper portion, solid. The solid pontion of the metal mass prevents pressure surges in the vessel from expelling the liquid portion of the metal mass from the trough; the liquld portion, thus held in place by the solid portion, does not allow gas to go through, and so gas cannot escape through shrinkage holes in the solid portion.

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas demand, thereby contributing to larger net injections of natural gas into storage. Other Market Trends: EIA Releases The Natural Gas Annual 2006: The Energy...

  8. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  9. Texas Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Texas Natural Gas in Underground Storage (Working Gas) ... Underground Working Natural Gas in Storage - All Operators Texas Underground Natural Gas ...

  10. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

  11. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    1998-09-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, especially NOX. The project involved operating gas reburning technology combined with low NO, burner technology (GR-LNB) on a coal-fired utility boiler. Low NOX burners are designed to create less NOX than conventional burners. However, the NO, control achieved is in the range of 30-60-40, and typically 50%. At the higher NO, reduction levels, CO emissions tend to be higher than acceptable standards. Gas Reburning (GR) is designed to reduce the level of NO. in the flue gas by staged fuel combustion. When combined, GR and LNBs work in harmony to both minimize NOX emissions and maintain an acceptable level of CO emissions. The demonstration was performed at Public Service Company of Colorado's (PSCO) Cherokee Unit 3, located in Denver, Colorado. This unit is a 172 MW. wall-fired boiler that uses Colorado bituminous, low-sulfur coal and had a pre GR-LNB baseline NOX emission of 0.73 lb/1 Oe Btu. The target for the project was a reduction of 70 percent in NOX emissions. Project sponsors included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation (EER). EER conducted a comprehensive test demonstration program over a wide range of boiler conditions. Over 4,000 hours of operation were achieved. Intensive measurements were taken to quantify the reductions in NOX emissions, the impact on boiler equipment and operability, and all factors influencing costs. The results showed that GR-LNB technology achieved excellent emission reductions. Although the performance of the low NOX burners (supplied by others) was somewhat less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 180A. The performance goal of 70% reduction was met on many test runs, but at higher gas heat inputs. The impact on boiler equipment was determined to be very minimal. Toward the end of the testing, the flue gas recirculation (used to enhance gas penetration into the furnace) system was removed and new high pressure gas injectors were installed. Further, the low NOX burners were modified and gave better NO. reduction performance. These modifications resulted in a similar NO, reduction performance (64%) at a reduced level of gas heat input (-13Yo). In addition, the OFA injectors were re-designed to provide for better control of CO emissions. Although not a part of this project, the use of natural gas as the primary fuel with gas reburning was also tested. The gas/gas reburning tests demonstrated a reduction in NOX emissions of 43% (0.30 lb/1 OG Btu reduced to 0.17 lb/1 OG Btu) using 7% gas heat input. Economics are a key issue affecting technology development. Application of GR-LNB requires modifications to existing power plant equipment and as a result, the capital and operating costs depend largely on site-specific factors such as: gas availability at the site, gas to coal delivered price differential, sulfur dioxide removal requirements, windbox pressure, existing burner throat diameters, and reburn zone residence time available. Based on the results of this CCT project, EER expects that most GR-LNB installations will achieve at least 60% NOX control when firing 10-15% gas. The capital cost estimate for installing a GR-LNB system on a 300 MW, unit is approximately $25/kW. plus the cost of a gas pipeline (if required). Operating costs are almost entirely related to the differential cost of the natural gas compared to coal.

  12. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  13. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  14. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-09-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

  15. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-06-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

  16. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

  17. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A.

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  18. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    SciTech Connect (OSTI)

    Hsu, F.E.

    1995-08-01

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  19. Natural Gas Regulation - Other Gas-Related Information Sources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Regulation - Other Gas-Related Information Sources Natural Gas Regulation - Other Gas-Related Information Sources The single largest source of energy information...

  20. Shale gas is natural gas trapped inside

    Energy Savers [EERE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary rocks that can be rich sources of petroleum and natural gas. Just a few years ago, much of this resource was considered uneconomical to produce. But Office of Fossil Energy (FE) research helped refine cost-effective horizontal drilling and hydraulic fracturing technologies, protective environmental practices and data development, making hundreds of trillions of cubic feet of gas technically recoverable where

  1. Gas amplified ionization detector for gas chromatography

    DOE Patents [OSTI]

    Huston, Gregg C.

    1992-01-01

    A gas-amplified ionization detector for gas chromatrography which possesses increased sensitivity and a very fast response time. Solutes eluding from a gas chromatographic column are ionized by UV photoionization of matter eluting therefrom. The detector is capable of generating easily measured voltage signals by gas amplification/multiplication of electron products resulting from the UV photoionization of at least a portion of each solute passing through the detector.

  2. Natural Gas Modernization Clearinghouse

    Broader source: Energy.gov [DOE]

    This Natural Gas Modernization Clearinghouse provides information about the implications of natural gas infrastructure modernization, including strategies and technologies that increase public safety, improve environmental performance and enhance natural gas deliverability.

  3. Future of Natural Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts * ...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of the Alaska gas pipeline. The opening of ANWR might reduce the gas resource risk of building an Alaska gas pipeline, as the area has an estimated 3.6 trillion cubic...

  5. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    cooling demand for natural gas. Meanwhile, it became increasingly clear that Hurricane Frances likely would not pose a significant threat to natural gas production in the Gulf of...

  7. Oil and Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  8. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J.; Lowrie, Robert S.; Sease, John D.

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Market Trends: MMS Announces New Incentives for Gulf Gas Production: The Minerals Management Service (MMS) unveiled proposed new incentives to increase deep gas production...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas vehicles. The Department of Energys Office of Energy Efficiency and Renewable Energy reports that there were 841 compressed natural gas (CNG) fuel stations and 41...

  11. Natural Gas Citygate Price

    U.S. Energy Information Administration (EIA) Indexed Site

    From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas ... Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports ...

  12. Natural Gas Industrial Price

    U.S. Energy Information Administration (EIA) Indexed Site

    From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas ... Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports ...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 6, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, October 29) Natural gas...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2008 Next Release: June 26, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 11, natural gas spot prices...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prices using spot prices from producing areas, plus an allowance for interstate natural gas pipeline and local distribution company charges to transport the gas to market. Such a...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    ability to process gas. The company's Main Pass 260 line to Pascagoula Gas Plant in Jackson, Mississippi, will not be available for transportation services. While the plant is...

  17. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5, 2009 Next Release: July 2, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 24, 2009) Natural gas...

  20. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  1. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  2. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    more from the system than they nominate. Other pipeline companies, such as CenterPoint Energy Gas Transmission Company and Southern Star Central Gas Pipeline Corporation, both...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    that had been in place since February 1. Other pipeline companies, such as CenterPoint Energy Gas Transmission Company and Southern Star Central Gas Pipeline Corporation, both...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 12, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Spot gas at most market locations (outside the Rocky Mountain Region) traded...

  7. CONTINUOUS GAS ANALYZER

    DOE Patents [OSTI]

    Katz, S.; Weber, C.W.

    1960-02-16

    A reagent gas and a sample gas are chemically combined on a continuous basis in a reaction zone maintained at a selected temperature. The reagent gas and the sample gas are introduced to the reaction zone at preselected. constant molar rates of flow. The reagent gas and the selected gas in the sample mixture combine in the reaction zone to form a product gas having a different number of moles from the sum of the moles of the reactants. The difference in the total molar rates of flow into and out of the reaction zone is measured and indicated to determine the concentration of the selected gas.

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    , 2008 Next Release: July 10, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 25, natural gas spot prices...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Sources & Uses Petroleum & Other Liquids Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas...

  10. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  11. Improving Gas Furnace Performance: A Field and Laboratory Study at End of Life

    SciTech Connect (OSTI)

    Brand, L.; Yee, S.; Baker, J.

    2015-02-01

    In 2010, natural gas provided 54% of total residential space heating energy the U.S. on a source basis, or 3.5 Quadrillion Btu. Natural gas burned in furnaces accounted for 92% of that total, and boilers and other equipment made up the remainder. A better understanding of installed furnace performance is a key to energy savings for this significant energy usage. In this project, the U.S. Department of Energy Building America team Partnership for Advanced Residential Retrofit examined the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces over the life of the product, as measured by steady-state efficiency and annual efficiency. The team identified 12 furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines, Iowa, metropolitan area and worked with a local heating, ventilation, and air conditioning contractor to retrieve furnaces and test them at the Gas Technology Institute laboratory for steady-state efficiency and annual efficiency. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace as installed in the house.

  12. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  13. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J.; Wozniak, John J.

    2001-01-01

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  14. Asian natural gas

    SciTech Connect (OSTI)

    Klass, D.L. ); Ohashi, T. )

    1989-01-01

    This book presents an overview of the present status and future development in Asia of domestic and export markets for natural gas and to describes gas utilization technologies that will help these markets grow. A perspective of natural gas transmission, transport, distribution, and utilization is presented. The papers in this book are organized under several topics. The topics are : Asian natural gas markets, Technology of natural gas export projects, Technology of domestic natural gas projects, and Natural gas utilization in power generation, air conditioning, and other applications.

  15. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil fuels used in power production.The United States is endowed with an abundance of natural gas resources, so increasing use of natural gas power can help strengthen domestic energy security. NETL research efforts enhance technologies that reduce the cost, increase the efficiency, and reduce the environmental risk of

  16. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  17. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K.; Chang, Shih-Ger

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  18. Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  19. Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  20. Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  1. Thomas McDonald | Center for Gas SeparationsRelevant to Clean...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    groups. My goal is to understand the relationship between pore surfaces and adsorption of gases present in coal power plant flue stacks. I have chosen to focus on...

  2. Variable leak gas source

    DOE Patents [OSTI]

    Henderson, Timothy M.; Wuttke, Gilbert H.

    1977-01-01

    A variable leak gas source and a method for obtaining the same which includes filling a quantity of hollow glass micro-spheres with a gas, storing said quantity in a confined chamber having a controllable outlet, heating said chamber above room temperature, and controlling the temperature of said chamber to control the quantity of gas passing out of said controllable outlet. Individual gas filled spheres may be utilized for calibration purposes by breaking a sphere having a known quantity of a known gas to calibrate a gas detection apparatus.

  3. World Natural Gas Model

    Energy Science and Technology Software Center (OSTI)

    1994-12-01

    RAMSGAS, the Research and Development Analysis Modeling System World Natural Gas Model, was developed to support planning of unconventional gaseoues fuels research and development. The model is a scenario analysis tool that can simulate the penetration of unconventional gas into world markets for oil and gas. Given a set of parameter values, the model estimates the natural gas supply and demand for the world for the period from 1980 to 2030. RAMSGAS is based onmore » a supply/demand framwork and also accounts for the non-renewable nature of gas resources. The model has three fundamental components: a demand module, a wellhead production cost module, and a supply/demand interface module. The demand for gas is a product of total demand for oil and gas in each of 9 demand regions and the gas share. Demand for oil and gas is forecast from the base year of 1980 through 2030 for each demand region, based on energy growth rates and price-induced conservation. For each of 11 conventional and 19 unconventional gas supply regions, wellhead production costs are calculated. To these are added transportation and distribution costs estimates associated with moving gas from the supply region to each of the demand regions and any economic rents. Based on a weighted average of these costs and the world price of oil, fuel shares for gas and oil are computed for each demand region. The gas demand is the gas fuel share multiplied by the total demand for oil plus gas. This demand is then met from the available supply regions in inverse proportion to the cost of gas from each region. The user has almost complete control over the cost estimates for each unconventional gas source in each year and thus can compare contributions from unconventional resources under different cost/price/demand scenarios.« less

  4. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  5. EIA - Natural Gas Pipeline Network - Natural Gas Pipeline Mileage...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mileage by State About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Estimated Natural Gas Pipeline Mileage in the ...

  6. EIA - Natural Gas Pipeline Network - Natural Gas Transmission...

    U.S. Energy Information Administration (EIA) Indexed Site

    Transmission Path Diagram About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Natural Gas Transmission Path Natural ...

  7. ,"Oregon Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  8. ,"Nevada Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ... Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)",1,"Monthly","1...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    heating-related demand for natural gas that limited the size of the net addition to storage. The economic incentives for storing natural gas for next winter are considerably...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage was 2,414 Bcf as of Friday, January 9,...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage was 821 Bcf as of May 2, according to...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Natural gas stocks stood at 2,155 Bcf as of Friday, July 9,...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage as of September 2 totaled 2,669 Bcf,...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    The report provides an overview of U.S. international trade in 2008 as well as historical data on natural gas imports and exports. Net natural gas imports accounted for only 13...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of 1 Tcf from the 1994 estimate of 51 Tcf. Ultimate potential for natural gas is a science-based estimate of the total amount of conventional gas in the province and is an...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    10 (next release 2:00 p.m. on March 17) Natural gas spot prices increased this week (Wednesday to Wednesday, March 2-9) as a late season cold front moved into major gas-consuming...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    next heating season. Net injections reported in today's release of EIA's Weekly Natural Gas Storage Report brought natural gas storage supplies to 2,163 Bcf as of Friday, June 1,...

  18. ,"Texas Natural Gas Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas Natural Gas Prices",8,"Monthly","2... 6:46:23 AM" "Back to Contents","Data 1: Texas Natural Gas Prices" "Sourcekey","N3050TX3"...

  19. Shale Gas Production

    Gasoline and Diesel Fuel Update (EIA)

    Notes: Shale Gas production data collected in conjunction with proved reserves data on Form EIA-23 are unofficial. Official Shale Gas production data from Form EIA-895 can be found ...

  20. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    while the OFO was in effect. Pacific Gas and Electric Company extended a systemwide high-inventory OFO on its California Gas Transmission system through Saturday, July 5. It was...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the OFO customers who delivered more than 110 percent of their actual gas usage into the system would be assessed for charges. Pacific Gas and Electric Company issued a...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    gas in combination with water. Gas hydrate is thought to exist in great abundance in nature and has the potential to be a significant new energy source to meet future energy...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the Northeast were expected to be in the single digits. Prices off Transcontinental Gas Pipe Line in New York and Algonquin Gas Transmission in the New England region yesterday...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas into storage. However, shut-in natural gas production in the Gulf of Mexico reduced available current supplies, and so limited net injections during the report...

  5. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    delivery volumes. Northern Natural Gas Company issued a system overrun limitation (SOL) for all market-area zones for gas day February 21, 2008. The SOL was the result of...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage...

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Btu per cubic foot as published in Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    gas in storage, as well as decreases in the price of crude oil. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage increased to 2,905 Bcf as of...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of natural gas into storage, despite robust inventories. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage increased to 3,258 Bcf as of...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    to withdraw natural gas from storage to meet current demand. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage decreased to 2,406 Bcf as of...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas inventories...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Working gas in storage was 3,121 Bcf as of Friday, Oct 24, 2003, according to the Energy Information Administration (EIA) Weekly Natural Gas Storage Report. This is 2.7...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    withdrawal from working gas storage reported last Thursday. A contributing factor to the run-up in natural gas prices could be climbing crude oil prices, which rallied late last...

  16. ,"Pennsylvania Natural Gas Summary"

    U.S. Energy Information Administration (EIA) Indexed Site

    ..."N3035PA3","N3045PA3" "Date","Natural Gas Citygate Price in Pennsylvania (Dollars per Thousand Cubic Feet)","Pennsylvania Price of Natural Gas Delivered to Residential Consumers ...

  17. ,"Oklahoma Natural Gas Summary"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...OK3","N3035OK3","N3045OK3" "Date","Natural Gas Citygate Price in Oklahoma (Dollars per Thousand Cubic Feet)","Oklahoma Price of Natural Gas Delivered to Residential Consumers (Dollars ...

  18. ,"Iowa Natural Gas Summary"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...20IA3","N3035IA3","N3045IA3" "Date","Natural Gas Citygate Price in Iowa (Dollars per Thousand Cubic Feet)","Iowa Price of Natural Gas Delivered to Residential Consumers (Dollars ...

  19. ,"Illinois Natural Gas Summary"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...IL3","N3035IL3","N3045IL3" "Date","Natural Gas Citygate Price in Illinois (Dollars per Thousand Cubic Feet)","Illinois Price of Natural Gas Delivered to Residential Consumers (Dollars ...

  20. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  1. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, J.F.

    1992-02-25

    A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

  2. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M.

    1996-01-01

    A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

  3. Natural gas annual 1996

    SciTech Connect (OSTI)

    1997-09-01

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    by 14.4 percent. During this period, U.S. manufacturers used less petroleum and coal in manufacturing processes. This expansion of gas use occurred although natural gas prices to...

  5. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, John F.

    1992-01-01

    A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.217 per MMBtu on Wednesday. The natural gas rotary rig...

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.315 per MMBtu on Wednesday. The natural gas rotary rig...

  8. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    week's gas markets. As of Friday, May 11, 2001, the spot price of natural gas at the Henry Hub dropped 0.24 from the previous Friday to 4.25 per MMBtu. The NYMEX price of...

  9. EIA - Natural Gas Publications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    these data from 2005 to 2009 are presented for each State. (12282010) U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves: 2009 National and State...

  10. offshore_gas.pdf

    U.S. Energy Information Administration (EIA) Indexed Site

    Source: Energy Information Administration based on data from MMS, HPDI, CA Dept of Oil , Gas & Geothermal Updated: April 8, 2009 Alabama 20 0 m Gas Production, Last Reported Year ...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on Thursday, May 9, 2002. A sample of EIA's report can be seen at: Weekly Gas Storage Test Page. The Natural Gas Weekly Market Update report will convert to the new data series...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels | Prices | States | International | Country Analysis...

  13. Natural gas annual 1995

    SciTech Connect (OSTI)

    1996-11-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  14. Natural gas annual 1994

    SciTech Connect (OSTI)

    1995-11-17

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Independence Avenue, SW Washington, DC 20585 . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels |...

  16. Natural Gas Citygate Price

    Gasoline and Diesel Fuel Update (EIA)

    Data for 2014 Natural Gas Glossary › FAQS › Overview Data Summary Prices Exploration & reserves Production Imports/exports Pipelines Storage Consumption All natural gas data reports Analysis & Projections Major Topics Most popular Consumption Exploration & reserves Imports/exports & pipelines Prices Production Projections Recurring Storage All reports Browse by Tag Alphabetical Frequency Tag Cloud ‹ See All Natural Gas Reports Natural Gas Annual With Data for 2014 |

  17. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M.

    2012-07-31

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  18. Landfill Gas | Open Energy Information

    Open Energy Info (EERE)

    Gas Jump to: navigation, search TODO: Add description List of Landfill Gas Incentives Retrieved from "http:en.openei.orgwindex.php?titleLandfillGas&oldid267173...

  19. Natural gas industry directory

    SciTech Connect (OSTI)

    1999-11-01

    This directory has information on the following: associations and organizations; exploration and production; gas compression; gas processors; gathering and transmission companies; liquefied natural gas; local distribution companies; marketing firms; regulatory agencies; service companies; suppliers and manufacturers; and regional buyer`s guide.

  20. Static gas expansion cooler

    DOE Patents [OSTI]

    Guzek, J.C.; Lujan, R.A.

    1984-01-01

    Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

  1. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, C.A.; Rurbage, C.H.

    1982-03-17

    The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  2. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  3. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A.; Luong, Amy Khai; Kulp, Thomas J.; Devdas, Sanjay

    2008-05-20

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  4. Gas revenue increasingly significant

    SciTech Connect (OSTI)

    Megill, R.E.

    1991-09-01

    This paper briefly describes the wellhead prices of natural gas compared to crude oil over the past 70 years. Although natural gas prices have never reached price parity with crude oil, the relative value of a gas BTU has been increasing. It is one of the reasons that the total amount of money coming from natural gas wells is becoming more significant. From 1920 to 1955 the revenue at the wellhead for natural gas was only about 10% of the money received by producers. Most of the money needed for exploration, development, and production came from crude oil. At present, however, over 40% of the money from the upstream portion of the petroleum industry is from natural gas. As a result, in a few short years natural gas may become 50% of the money revenues generated from wellhead production facilities.

  5. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1985-12-31

    An apparatus is disclosed for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area. 3 figs.

  6. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, Daniel

    1985-01-01

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  7. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1984-06-05

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  8. GAS METERING PUMP

    DOE Patents [OSTI]

    George, C.M.

    1957-12-31

    A liquid piston gas pump is described, capable of pumping minute amounts of gas in accurately measurable quantities. The pump consists of a flanged cylindrical regulating chamber and a mercury filled bellows. Sealed to the ABSTRACTS regulating chamber is a value and having a gas inlet and outlet, the inlet being connected by a helical channel to the bellows. A gravity check valve is in the gas outlet, so the gas passes through the inlet and the helical channel to the bellows where the pumping action as well as the metering is accomplished by the actuation of the mercury filled bellows. The gas then flows through the check valve and outlet to any associated apparatus.

  9. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Energy Savers [EERE]

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows: *How does exported liquefied natural gas (LNG) from the U.S. compare

  10. EIA - Natural Gas Pipeline Network - Intrastate Natural Gas Pipeline

    U.S. Energy Information Administration (EIA) Indexed Site

    Segment Intrastate Natural Gas Pipeline Segment About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Intrastate Natural Gas Pipeline Segment Overview Intrastate natural gas pipelines operate within State borders and link natural gas producers to local markets and to the interstate pipeline network. Approximately 29 percent of the total miles of natural gas pipeline in the U.S. are intrastate pipelines. Although an intrastate

  11. EIA - Natural Gas Pipeline Network - Natural Gas Pipeline Compressor

    U.S. Energy Information Administration (EIA) Indexed Site

    Stations Compressor Stations Illustration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates U.S. Natural Gas Pipeline Compressor Stations Illustration, 2008 Map of U.S. Natural Gas Pipeline Compressor Stations Source: Energy Information Administration, Office of Oil & Gas, Natural Gas Division, Natural Gas Transportation Information System. The EIA has determined that the informational map displays here do not raise security

  12. Pulsed gas laser

    DOE Patents [OSTI]

    Anderson, Louis W.; Fitzsimmons, William A.

    1978-01-01

    A pulsed gas laser is constituted by Blumlein circuits wherein space metal plates function both as capacitors and transmission lines coupling high frequency oscillations to a gas filled laser tube. The tube itself is formed by spaced metal side walls which function as connections to the electrodes to provide for a high frequency, high voltage discharge in the tube to cause the gas to lase. Also shown is a spark gap switch having structural features permitting a long life.

  13. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, Charles A.; Burbage, Charles H.

    1984-01-01

    The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  14. Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    Rothgeb, S.; Brand, L.

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  15. Technology Solutions Case Study: Improving the Field Performance of Natural Gas Furnaces

    SciTech Connect (OSTI)

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  16. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  17. Gas-recovery system

    DOE Patents [OSTI]

    Heckman, R.A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  18. Gas-Recovery System

    DOE Patents [OSTI]

    Heckman, R. A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  19. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Gas Efficient recovery of our nation's fossil fuel resources in an environmentally safe manner requires the development and application of new technologies that address the ...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    over the next few days. To avoid penalties, Northwest requested that customers stay within their scheduled volumes, and asked customers who owe gas to Northwest north of...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Upward pressure on prices at the NYMEX also appears related to concerns over events in Japan that could affect energy markets. Japan, the worlds largest liquefied natural gas...

  2. Shale Gas Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Production (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Other Market Trends: MMS Issues Final Notice of Western Gulf Lease Sale: The Minerals Management Service (MMS) will offer several incentives to increase domestic oil and gas...

  4. compressed-gas storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage ...

  5. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    oil and gas resources will be necessary even as efficiency improvements reduce demand and renewable sources become more available. In order to retain public trust environmentally...

  7. Breathable gas distribution apparatus

    DOE Patents [OSTI]

    Garcia, Elmer D.

    1985-01-01

    The disclosure is directed to an apparatus for safely supplying breathable gas or air through individual respirators to personnel working in a contaminated area.

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: July 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 2, 2009) Since...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6, 2008 Next Release: November 14, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, November 5) Since...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    0, 2009 Next Release: August 6, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 29, 2009) Since...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    7, 2008 Next Release: July 24, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview The report week ended July 16 registered significant...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 7, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 16, 2009)...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: November 5, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 28, 2009)...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 24, 2010)...

  15. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, April 28, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 20, 2011) Natural...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 6, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 15, 2010)...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the technology that drove Enron's North American wholesale electricity and natural gas trading unit. That technology, together with reportedly over 600 former Enron...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, August 26, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 18, 2010) Natural...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: April 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 1, 2009) Despite a...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2009 Next Release: February 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 11, 2009)...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, November 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 27, 2010) As the...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 20, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, November 5, to Thursday, November 13)...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, October 28, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 20, 2010)...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 3, 2008) Released: January 4, 2008 Next release: January 10, 2008 Natural gas spot and futures prices increased this report week (Wednesday to Thursday, December 26,...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Wednesday, November 10, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 3, 2010) Price...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, August 19, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 11, 2010) Summer...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: October 23, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For week ending Wednesday, October 15) Since Wednesday,...

  8. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, February 3, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 26, 2011)...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    requested by Secretary of Energy Spencer Abraham in an effort to enhance natural gas market information and efficiency. Survey respondents would include all operators of...

  10. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, December 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 8, 2010) In...

  11. Breathable gas distribution apparatus

    DOE Patents [OSTI]

    Garcia, E.D.

    The disclosure is directed to an apparatus for safely supplying breathable gas or air through individual respirators to personnel working in a contaminated area.

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Storage Estimates Database. Other Market Trends: EIA Releases New Report on the Fundamentals of Natural Gas Storage: EIA prepared a new report to provide general background...

  13. Oil & Gas Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    needed to predict and quantify potential risks associated with oil and gas resources in shale reservoirs that require hydraulic fracturing or other engineering measures to produce. ...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    constraint. Pacific Gas and Electric Company issued a systemwide Stage 2 high-inventory OFO for Saturday, May 5, because of projections that linepack on the California...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the New York Mercantile Exchange (NYMEX), futures prices also increased this week in tandem with the crude oil prices. The natural gas futures contract for delivery in June...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Market Trends: The Minerals Management Service Reports Royalty Gas Sale for the First Time in Offshore Louisiana. On November 4, the Minerals Management Service (MMS) of the...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    data to EIA. The number of companies reporting increased by 3 from 2008, to include Alon USA, Chalmette Refining LLC, and Western Refining, Inc. Natural Gas Transportation Update...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Inventory of Onshore Federal Lands' Oil and Gas Resources and the Extent and Nature of Restrictions or Impediments to Their Development. The report, which was...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Accounting Standards Board. The changes will allow FERC an understanding of the nature and extent to which hedging activities are used by electric utilities and gas...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    storm activity has been above average this year, there has been little impact on natural gas markets. Tropical Depression 6 showed up in the eastern Caribbean early this...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: December 11, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, December 3, 2008) Since...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2009 Next Release: March 26, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 18, 2009) Warmer...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    P.M. Next Release: October 29, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 21, 2009) Since...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: October 2, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, September 17, to Wednesday, September 24)...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, January 20, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 12, 2011)...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    with hopes for the eventual return of winter was likely the catalyst enabling natural gas prices to recapture the 4 mark this week despite an environment of negative...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, May 19, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 11, 2011) Natural...

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Thursday, September 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 8, 2010) Price...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thursday, September 23, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 15, 2010)...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, May 12, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 4, 2011) Wholesale...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, April 15, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 7, 2010) Since...

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, February 25, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 17, 2010)...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, March 18, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 10, 2010) Since...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 24, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 16, 2011) With...

  15. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Other Market Trends EIA Proposes Extending Oil and Natural Gas Reserves Survey Forms. The Energy Information Administration (EIA) on July 15 published a notice in the Federal...

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    As of February 14, Northern Natural Gas implemented a system overrun limitation (SOL) affecting all market area zones. These zones are located in the northern part of the...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Gas Company, for example, on Tuesday, October 21, issued a system overrun limitation (SOL) that allows for penalties on variances between flows and nominations. The SOL is in...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Government Accountability Office into specific leases that excluded price threshold language and a court action by Kerr-McGee Oil and Gas Corporation challenging the Department...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on December 9, falling from somewhat higher intraweek levels. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage dropped 64 Bcf during the...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    and October 2010 contracts all fell by less than 1 cent. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas inventories set a new record,...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    recorded last year. Other Market Trends: FERC Releases Report on Underground Natural Gas Storage: The Federal Energy Regulatory Commission (FERC) issued a report last week that...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Estimates Database. Other Market Trends: Comments Received on Proposed Weekly Natural Gas Storage Report Revision Policy: The Energy Information Administration (EIA) solicited...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    compared with its settlement price a week ago, ending yesterday at 5.974 per MMBtu. The Energy Information Administration (EIA) reported that natural gas inventories in...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    storage facilities. Other Market Trends: EIA Releases Report on Underground Natural Gas Storage Developments: The Energy Information Administration (EIA) released a special...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 7, 2009) Since Wednesday, December...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    March 12, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 4, 2009) A late winter cold spell in...

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    planning information that will assist in maintaining the operational integrity and reliability of pipeline service, as well as providing gas-fired power plant operators with...

  8. Polyport atmospheric gas sampler

    DOE Patents [OSTI]

    Guggenheim, S. Frederic

    1995-01-01

    An atmospheric gas sampler with a multi-port valve which allows for multi, sequential sampling of air through a plurality of gas sampling tubes mounted in corresponding gas inlet ports. The gas sampler comprises a flow-through housing which defines a sampling chamber and includes a gas outlet port to accommodate a flow of gases through the housing. An apertured sample support plate defining the inlet ports extends across and encloses the sampling chamber and supports gas sampling tubes which depend into the sampling chamber and are secured across each of the inlet ports of the sample support plate in a flow-through relation to the flow of gases through the housing during sampling operations. A normally closed stopper means mounted on the sample support plate and operatively associated with each of the inlet ports blocks the flow of gases through the respective gas sampling tubes. A camming mechanism mounted on the sample support plate is adapted to rotate under and selectively lift open the stopper spring to accommodate a predetermined flow of gas through the respective gas sampling tubes when air is drawn from the housing through the outlet port.

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    kept up significant downward pressure on both cash and futures prices. Lower prices may eventually lead to fewer rigs exploring for gas, thereby stemming the growth in production....

  10. Natural gas annual 1997

    SciTech Connect (OSTI)

    1998-10-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  11. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    average, the general price level in the natural gas market has shown surprising resilience over the past few weeks. After an extended price decline since mid December, spot...

  13. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Historical Natural Gas Annual . 1996 Published October 1997 1997 Published October 1998 1998 Published October 1999 1999 Published October 2000 2000 Published December 2001

  14. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2009 Next Release: August 13, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 5, 2009) Natural...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, July 1, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 23, 2010)...

  16. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 9, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 1,...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, January 14, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 6,...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, November 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 11,...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, June 17, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 9, 2010)...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 12, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 4, 2010)...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 2, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 25,...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 5, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 28, 2010)...

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, May 13, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 5, 2010)...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2009 Next Release: April 16, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 8, 2009) Since...

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Next Release: January 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 14, 2009) In...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16, 2009 Next Release: April 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 15, 2009) Since...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 to Wednesday, December 12) Released: December 13 Next release: December 20, 2007 Natural gas spot and futures prices increased this report week (Wednesday to Wednesday,...

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Significant New Deepwater Oil and Natural Gas Discovery: A successful production test in the deepwater Gulf of Mexico has confirmed a significant new oil play in the lower...

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    which summarizes the likely demand, supply, and prices for natural gas, heating oil, propane, and electricity during the upcoming winter (October 2004 - March 2005). According to...

  10. Multiple complementary gas distribution assemblies

    DOE Patents [OSTI]

    Ng, Tuoh-Bin; Melnik, Yuriy; Pang, Lily L; Tuncel, Eda; Nguyen, Son T; Chen, Lu

    2016-04-05

    In one embodiment, an apparatus includes a first gas distribution assembly that includes a first gas passage for introducing a first process gas into a second gas passage that introduces the first process gas into a processing chamber and a second gas distribution assembly that includes a third gas passage for introducing a second process gas into a fourth gas passage that introduces the second process gas into the processing chamber. The first and second gas distribution assemblies are each adapted to be coupled to at least one chamber wall of the processing chamber. The first gas passage is shaped as a first ring positioned within the processing chamber above the second gas passage that is shaped as a second ring positioned within the processing chamber. The gas distribution assemblies may be designed to have complementary characteristic radial film growth rate profiles.

  11. Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Bai, T.; Yeboah, Y.D.; Sampath, R.

    1995-10-01

    The objective of this investigation is to characterize the operation of fan powered infrared burner (PIR) at various gas compositions and ambient conditions and develop design guidelines for appliances in containing PIR burners for satisfactory performance. During this period, experimental setup with optical and electronic instrumentation that is necessary for measuring the radiant heat output and the emission gas output of the burner has been established. The radiation measurement instrument, an FTIR, has been purchased and installed in the porous burner experimental system. The radiation measurement capability of the FTIR was tested and found to be satisfactory. A standard blackbody source, made by Graseby Infrared, was employed to calibrate the FTIR. A collection duct for emission gas measurement was fabricated and connected to the existing Horiba gas analyzer. Test runs are being conducted for flue gas analysis. A number of published research papers on modeling of porous burners were reviewed. The physical mechanism and theoretical analysis of the combustion process of the PIR burner was formulated. The numerical modeling, and implementation of a PIR burner code at CAU`s computing facility is in progress.

  12. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, J.L.

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  13. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, John E.

    1984-01-01

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  14. Louisiana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 159,456 166,570 164,270 166,973 161,280 163,799 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  15. Indiana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  16. Maryland Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  17. Nevada Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  18. Illinois Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  19. Kentucky Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  20. Pennsylvania Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 398,737 408,325 396,931 404,431 403,683 429,251 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  1. Wyoming Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 168,548 167,539 162,880 167,555 163,345 165,658 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  2. Missouri Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  3. Illinois Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    0 0 0 0 0 1967-2014 Marketed Production 1,443 1,702 2,121 2,125 2,887 2,626 1967-2014 Natural Gas Processed 164 5,393 294 1967-2014 Natural Gas Processed 294 2014-2014 NGPL...

  4. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  5. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P.; Novaresi, Mark A.; Cornelius, Charles C.

    2007-11-13

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  6. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.; Hayden, M.; Radebaugh, R.; Wollan, J.

    1996-07-01

    This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop a natural-gas-powered natural-gas liquefier that has absolutely no moving parts and requires no electrical power. It should have high efficiency, remarkable reliability, and low cost. The thermoacoustic natural-gas liquefier (TANGL) is based on our recent invention of the first no-moving-parts cryogenic refrigerator. In short, our invention uses acoustic phenomena to produce refrigeration from heat, with no moving parts. The required apparatus comprises nothing more than heat exchangers and pipes, made of common materials, without exacting tolerances. Its initial experimental success in a small size lead us to propose a more ambitious application: large-energy liquefaction of natural gas, using combustion of natural gas as the energy source. TANGL was designed to be maintenance-free, inexpensive, portable, and environmentally benign.

  7. HIGH PRESSURE GAS REGULATOR

    DOE Patents [OSTI]

    Ramage, R.W.

    1962-05-01

    A gas regulator operating on the piston and feedback principle is described. The device is particularly suitable for the delicate regulation of high pressure, i.e., 10,000 psi and above, gas sources, as well as being perfectly adaptable for use on gas supplies as low as 50 psi. The piston is adjustably connected to a needle valve and the movement of the piston regulates the flow of gas from the needle valve. The gas output is obtained from the needle valve. Output pressure is sampled by a piston feedback means which, in turn, regulates the movement of the main piston. When the output is other than the desired value, the feedback system initiates movement of the main piston to allow the output pressure to be corrected or to remain constant. (AEC)

  8. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis; Harvey, III, Albert Destrehan; Vinegar, Harold J.

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  9. California--State Offshore Natural Gas Withdrawals from Gas Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Wells (Million Cubic Feet) California--State Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  10. Federal Offshore California Natural Gas Withdrawals from Gas...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Wells (Million Cubic Feet) Federal Offshore California Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  11. Pennsylvania Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Pennsylvania Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 352,686 ...

  12. Kentucky Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Kentucky Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 7,021 6,303 6,870 ...

  13. Kentucky Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Kentucky Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 105,889 105,889 ...

  14. Missouri Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals from Gas Wells (Million Cubic Feet) Missouri Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 1 ...

  15. Alabama Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Alabama Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 499 497 ...

  16. Oklahoma Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Oklahoma Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 167,385 163,458 ...

  17. Alabama Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Alabama Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 880 880 880 880 ...

  18. Ohio Natural Gas Withdrawals from Gas Wells (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Ohio Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 13,138 11,794 12,855 ...

  19. Montana Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Montana Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 4,561 3,826 4,106 ...

  20. Oklahoma Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Oklahoma Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 7,051 6,368 ...

  1. Minnesota Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Minnesota Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 1,708 ...

  2. Indiana Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Indiana Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 22,371 ...

  3. Oregon Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Oregon Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 3,291 3,291 3,291 ...

  4. Missouri Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Missouri Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 21,600 21,600 ...

  5. Louisiana Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Louisiana Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 425,704 369,500 ...

  6. Florida Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Florida Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - ...

  7. Ohio Natural Gas Gross Withdrawals from Shale Gas (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Ohio Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 1 1 1 1 1 1 1 1 1 1 ...

  8. Ohio Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Ohio Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 100,467 ...

  9. Illinois Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Illinois Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 40 37 39 38 37 36 35 ...

  10. Nebraska Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Nebraska Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 27,312 27,312 ...

  11. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    U.S. Energy Information Administration (EIA) Indexed Site

    Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural ...

  12. Tennessee Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Tennessee Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0 0 0 ...

  13. Colorado Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Colorado Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 27,491 ...

  14. Nebraska Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Nebraska Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 55,226 ...

  15. Iowa Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Iowa Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 74,086 66,477 ...

  16. Indiana Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals from Gas Wells (Million Cubic Feet) Indiana Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 21 18 ...

  17. Iowa Natural Gas in Underground Storage (Base Gas) (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Iowa Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 153,933 153,933 ...

  18. California Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) California Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 243,944 ...

  19. California Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) California Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 13,569 12,155 ...

  20. California Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) California Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 10,998 9,933 ...

  1. Michigan Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Michigan Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 9,579 8,593 ...

  2. Tennessee Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Tennessee Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 ...

  3. Louisiana Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Louisiana Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 115,418 ...

  4. Missouri Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Missouri Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 8,081 ...

  5. Texas Natural Gas Gross Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Texas Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 507,274 440,015 ...

  6. Maryland Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Maryland Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 4,303 ...

  7. Minnesota Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Minnesota Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 4,655 4,655 ...

  8. Louisiana Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Louisiana Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 262,136 ...

  9. Oklahoma Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Oklahoma Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 163,978 147,543 ...

  10. Oregon Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Oregon Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 3,705 2,366 ...

  11. Pennsylvania Natural Gas in Underground Storage (Working Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Pennsylvania Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 ...

  12. Montana Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Montana Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 1,239 1,119 1,239 ...

  13. Kentucky Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Kentucky Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 58,567 ...

  14. Maryland Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals from Gas Wells (Million Cubic Feet) Maryland Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 5 ...

  15. Indiana Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Indiana Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 74,572 74,572 ...

  16. Michigan Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Michigan Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 11,582 10,461 ...

  17. Illinois Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Illinois Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 571,959 571,959 ...

  18. Mississippi Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Mississippi Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 46,050 ...

  19. Arkansas Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Arkansas Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 19,202 19,202 ...

  20. Michigan Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Michigan Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 311,360 ...

  1. Kansas Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Kansas Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 65,683 ...

  2. Arkansas Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Arkansas Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 8,676 ...

  3. Kansas Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Kansas Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 179,462 179,462 ...

  4. Louisiana Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Louisiana Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 1,273 1,150 ...

  5. Michigan Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Michigan Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 395,529 395,529 ...

  6. Montana Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    in Underground Storage (Working Gas) (Million Cubic Feet) Montana Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct ...

  7. Oregon Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    from Gas Wells (Million Cubic Feet) Oregon Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 246 244 232 ...

  8. Colorado Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Colorado Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 11,749 10,612 ...

  9. Oklahoma Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Oklahoma Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 129,245 ...

  10. Ohio Natural Gas in Underground Storage (Base Gas) (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Ohio Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 338,916 338,916 ...

  11. Mississippi Natural Gas in Underground Storage (Working Gas)...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Mississippi Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 33,234 ...

  12. Mississippi Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Mississippi Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 14,797 13,076 ...

  13. California Natural Gas in Underground Storage (Working Gas) ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) California Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 125,898 ...

  14. Texas Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Texas Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 134,707 134,707 ...

  15. Pennsylvania Natural Gas Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Pennsylvania Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 13,538 12,153 ...

  16. Colorado Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Colorado Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 15,390 18,697 ...

  17. Pennsylvania Natural Gas Gross Withdrawals from Shale Gas (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    from Shale Gas (Million Cubic Feet) Pennsylvania Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 0 0 0 0 ...

  18. Texas Natural Gas Gross Withdrawals from Shale Gas (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Shale Gas (Million Cubic Feet) Texas Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 107,415 97,020 ...

  19. Illinois Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Illinois Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 234,149 ...

  20. Nebraska Natural Gas Withdrawals from Gas Wells (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Nebraska Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 9 10 11 6 9 8 10 9 8 ...