National Library of Energy BETA

Sample records for fr flue gas

  1. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  2. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  3. Final Flue Gas Cleaning (FFGC) 

    E-Print Network [OSTI]

    Stinger, D. H.; Romero, M. H.

    2006-01-01

    -scale FFGC plant. I. EMISSION REDUCTION TECHNOLOGIES Pollution reduction technologies addressed in this document can be used to clean up any type of flue gas including the high pollution levels from untreated coal fired power plants. A typical... tons by 2010 and at 15 tons by 2018. Although coal fired industry representatives state, “there still is no mercury control technology that exists today that can achieve the reduction levels finalized by the Clean Air Mercury rule”( g ), WOW...

  4. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  5. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy efficiency+ power plant...

  6. The Gonzaga desulfurization flue gas process

    SciTech Connect (OSTI)

    Kelleher, R.L.; O'Leary, T.J.; Shirk, I.A.

    1984-01-01

    The Gonzaga desulfurization flue gas process removes sulfur dioxide from a flue by cold water scrubbing. Sulfur dioxide is significantly more soluable in cold water (35/sup 0/F to 60/sup 0/F) than in warm water (100/sup 0/F). Sulfur dioxide reacts in water similarly as carbon dioxide reacts in water, in that both gasses are released from the water as the temperature of the water increases. The researchers at the Gonzaga University developed this process from the observations and techniques used in studying the acid and aldehyde concentrations in flue gasses with varying of fuel to air ratios. The apparatus was fixed to a stationary engine and a gas/oil fired boiler. The flue gas was cooled to the dew point temperature of the air entering the combustion chamber on the pre-air heater. The system is described in two parts: the energies required for cooling in the scrubbing section and the energies required in the treatment section. The cold flue gas is utilized in cooling the scrubber section.

  7. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  8. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  9. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  10. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  11. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    IMPACTORS; PERFORMANCE TESTING; FLUE GAS; PARTICLE SIZE; FLUIDIZED-BED COMBUSTION; AIR FILTERS; DISTRIBUTION; MEASURING INSTRUMENTS; SORTING; CHEMICAL REACTIONS; COMBUSTION;...

  12. Evaluation of the Energy Saving Potential from Flue Gas Pressurization 

    E-Print Network [OSTI]

    Stanton, E. H.

    1980-01-01

    The potential for recovering energy from low pressure furnace flue products is limited when standard heat recovery equipment is utilized. Efficient energy recovery can be accomplished by providing a flue gas side pressure drop across a heat...

  13. Fundamental mechanisms in flue-gas conditioning

    SciTech Connect (OSTI)

    Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  14. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  15. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Bush, P.V.

    1992-04-27

    This project is divided into four tasks. The Management Plan was developed in task 1. Task 2, Evaluation of Mechanisms in FGD Sorbent and Ash Interactions, focuses on the characteristics of binary mixtures of these distinct powders. Task 3, Evaluation of Mechanisms in Conditioning Agents and Ash, is designed to examine the effects of various conditioning agents on fine ash particles to determine the mechanisms by which these agents alter the physical properties of the ash. Tasks 2 and 3 began with an extensive literature search and the assembly of existing theories. This phase of the project is now complete. During the past quarter, initial preparations of laboratory equipment for laboratory testing have been made. A plan for initial laboratory tests has been submitted to the Project Manager for review. Laboratory testing will commence once these laboratory plans have been formally approved. The results of the work performed under task 2 and 3 will be included in a Flue Gas Conditioning Model that will be issued under task 4. The Final Report for the project will also be prepared under task 4.

  16. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  17. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  18. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

    2005-07-01

    This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

  19. BUILDING MATERIALS MADE FROM FLUE GAS DESULFURIZATION BY-PRODUCTS

    SciTech Connect (OSTI)

    Michael W. Grutzeck; Maria DiCola; Paul Brenner

    2006-03-30

    Flue gas desulphurization (FGD) materials are produced in abundant quantities by coal burning utilities. Due to environmental restrains, flue gases must be ''cleaned'' prior to release to the atmosphere. They are two general methods to ''scrub'' flue gas: wet and dry. The choice of scrubbing material is often defined by the type of coal being burned, i.e. its composition. Scrubbing is traditionally carried out using a slurry of calcium containing material (slaked lime or calcium carbonate) that is made to contact exiting flue gas as either a spay injected into the gas or in a bubble tower. The calcium combined with the SO{sub 2} in the gas to form insoluble precipitates. Some plants have been using dry injection of these same materials or their own Class C fly ash to scrub. In either case the end product contains primarily hannebachite (CaSO{sub 3} {center_dot} 1/2H{sub 2}O) with smaller amounts of gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). These materials have little commercial use. Experiments were carried out that were meant to explore the feasibility of using blends of hannebachite and fly ash mixed with concentrated sodium hydroxide to make masonry products. The results suggest that some of these mixtures could be used in place of conventional Portland cement based products such as retaining wall bricks and pavers.

  20. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  1. EPRICON: Agentless flue gas conditioning for electrostatic precipitators

    SciTech Connect (OSTI)

    Bibbo, P.P. [Research-Cottrell, Inc., Branchburg, NJ (United States)

    1995-09-01

    Achieving efficient particulate control in coal burning electric utility plants is becoming an increasingly difficult proposition, giver, the variety of regulatory, technical, operating and environmental pressures that exist in the US. For most powerplants, particulate control is achieved by an electrostatic precipitator (ESP). Under optimal conditions, modern ESPs are capable of achieving particulate removal efficiencies of 99.7 %. Unfortunately, optimal conditions are not always present. ESP`s are sensitive to flue gas conditions, and those conditions may change dramatically after a fuel switch or the installation of some types of emissions control technology upstream of the ESP. Gas conditioning has been shown to be an effective means of returning flue gas to the ``optimal`` conditions required for efficient ESP operation following a fuel switch to a low, or at least, lower sulfur coal. Borrowing technology common in conventional soap-making plants around the turn of the century, sulfur-burning SO3 gas conditioning has been the solution to may difficult fuels in electrostatic precipitators. Although it has contributed most to improved ESP performance after a fuel switch, conventional gas conditioning has significant drawbacks. In an effort to develop an alternative to conventional SO{sub 3} gas conditioning, the Electric Power Research Institute (EPRI) initiated a research and development project that has produced an alternative and modem technology for flue gas conditioning, now called EPRICON, and licensed it to Research-Cottrell. This article describes the EPRICON process and its performance in pilot and demonstration plants.

  2. Dry scrubber reduces SO sub 2 in calciner flue gas

    SciTech Connect (OSTI)

    Brown, G.W. (Refining Consulting Services, Englewood, CO (US)); Roderick, D. (Western Slope Refining Co., Fruita, CO (US)); Nastri, A. (NATEC Resources Inc., Dallas, TX (US))

    1991-02-18

    This paper discusses the installation of a dry sulfur dioxide scrubber for an existing petroleum coke calciner at its Fruita, Colo., refinery. The dry scrubbing process was developed by the power industry to help cope with the acid rain problem. It is the first application of the process in an oil refinery. The process could also remove SO{sub 2} from the flue gas of a fluid catalytic cracker, fluid coker, or other refinery sources.

  3. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

    2003-02-18

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  4. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  5. Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum

    SciTech Connect (OSTI)

    Hensman, Carl, E., P.h.D; Baker, Trevor

    2008-06-16

    Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

  6. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  7. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2005-08-01

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

  8. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  9. Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas

    SciTech Connect (OSTI)

    Dexin Wang

    2012-03-31

    The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

  10. The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas 

    E-Print Network [OSTI]

    Henderson, W. R.; DeBiase, J. F.

    1983-01-01

    The Beckett Heat Recovery is a series of techniques for recovering low-grade waste heat from flue gas. Until the cost of fossil fuels began rising rapidly, flue gas below 600 F was considered economically unworthy of reclaim. This paper...

  11. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  12. Flue gas conditioning for improved particle collection in electrostatic precipitators

    SciTech Connect (OSTI)

    Durham, M.D.

    1992-10-14

    By injecting high concentrations of SO[sub 3] (80 to 100 ppM) it was possible to reduce the particle resistivity from 10[sup 11] to 10[sup 7] ohm-cm. However, it was very difficult to consistently obtain intermediate levels of resistivity. This was because of the steep relationships between gas phase SO[sub 3] and resistivity. It only takes a few ppM of SO[sub 3] to provide an order of magnitude change in resistivity. This is demonstrated by the curves in Figure 2. The water dew point for a gas stream with a moisture content of 10%, which is typical of coal fired boilers, is approximately 120[degrees]F. However, in a flue gas with only 2 ppM of SO[sub 3], sulfuric acid will begin to condense at 270[degrees]F. The effect of the rapid rise in acid dew point is reflected by the corresponding rapid decrease in resistivity. With no gas phase SO[sub 3] present the resistivity is in the high 10[sup 11] ohm-cm range. However with only 10 ppM of SO[sub 3], the resistivity drops three orders of magnitude. Therefore, intermediate levels of resistivity can only be obtained by controlling the SO[sub 3] concentration within 1 or 2 ppM.

  13. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

    2007-08-14

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  14. CO? Capture Membrane Process for Power Plant Flue Gas

    SciTech Connect (OSTI)

    Toy, Lora; Kataria, Atish; Gupta, Raghubir

    2011-09-30

    Because the fleet of coal-fired power plants is of such importance to the nation's energy production while also being the single largest emitter of CO?, the development of retrofit, post-combustion CO? capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO? from plant flue gas with 95% captured CO? purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO?-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft˛) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO?, NOx, etc.). Specific objectives were: - Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO? over N? and CO? permeance greater than 300 gas permeation units (GPU) targeted; - Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO? permeance than current commercial polycarbonate membranes; - Development and fabrication of membrane hollow fibers and modules from candidate polymers; - Development of a CO? capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and - Techno-economic evaluation of the "best" integrated CO? capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO? capture with 95% captured CO? purity.

  15. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  16. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01

    removal from flue gas of coal-fired power plants. Environ.Speciation in a 100-MW Coal-Fired Boiler with Low-NOxControl Technologies for Coal-Fired Power Plants, DOE/NETL

  17. Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams

    E-Print Network [OSTI]

    Latcham, Jacob G. (Jacob Greco)

    2009-01-01

    An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

  18. New Developments in Closed Loop Combustion Control Using Flue Gas Analysis 

    E-Print Network [OSTI]

    Nelson, R. L.

    1981-01-01

    New developments in closed loop combustion control are causing radical changes in the way combustion control systems are implemented. The recent availability of in line flue gas analyzers and microprocessor technology are teaming up to produce...

  19. Flue gas desulfurization : cost and functional analysis of large-scale and proven plants

    E-Print Network [OSTI]

    Tilly, Jean

    1983-01-01

    Flue Gas Desulfurization is a method of controlling the emission of sulfurs, which causes the acid rain. The following study is based on 26 utilities which burn coal, have a generating capacity of at least 50 Megawatts ...

  20. Analysis of Halogen-Mercury Reactions in Flue Gas

    SciTech Connect (OSTI)

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

    2010-01-01

    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

  1. Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J

    2008-07-01

    The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

  2. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  3. Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-08-31

    The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

  4. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  5. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    SciTech Connect (OSTI)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

  6. Effect of connate water on miscible displacement of reservoir oil by flue gas 

    E-Print Network [OSTI]

    Maxwell, H. D.

    1960-01-01

    EFFECT OF CONNATE WATER ON MISCIBLE DISPLACEMENT OF RESERVOIR OIL BY FLUE GAS A Thesis By H. D. MAXWELL, JR. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE Au gus t, 19 60 Major Subject: PETROLEUM ENGINEERING EFFECT OF CONNATE WATER ON MISCIBLE DISPLACEMENT OF RESERVOIR OIL BY FLUE GAS A Thesis H. D. MAXWELL, JR. Approved as to style and content by: haxrman of ommitte...

  7. Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using flue gas

    E-Print Network [OSTI]

    Subramanian, Venkat

    Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using]. Besides physical and chemical methods for sequestration of CO2 from flue gas [2], microalgae culture holds great potential for converting flue gas to biomass. Microalgae can capture solar energy more efficiently

  8. Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2012-11-06

    Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

  9. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  10. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; John DuPoint

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

  11. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  12. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  13. Pilot-Scale Demonstration of hZVI Process for Treating Flue Gas Desulfurization Wastewater at Plant Wansley, Carrollton, GA 

    E-Print Network [OSTI]

    Peddi, Phani 1987-

    2011-12-06

    The hybrid Zero Valent Iron (hZVI) process is a novel chemical treatment platform that has shown great potential in our previous bench-scale tests for removing selenium, mercury and other pollutants from Flue Gas Desulfurization (FGD) wastewater...

  14. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  15. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  16. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  17. Catalysts for oxidation of mercury in flue gas

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2010-08-17

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  18. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M. [DIEM, Department of Mechanical Engineering, Faculty of Engineering, University of Bologna, Viale Risorgimento 2, 40136 Bologna (Italy); Saccani, C. [DIEM, Department of Mechanical Engineering, Faculty of Engineering, University of Bologna, Viale Risorgimento 2, 40136 Bologna (Italy)], E-mail: cesare.saccani@unibo.it

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  19. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  20. Compression stripping of flue gas with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); O'Connor, William K. (Lebanon, OR)

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  1. Compression Stripping of Flue Gas with Energy Recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  2. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  3. EPA reports advances in scrubber technology at Flue Gas Desulfurization symposium

    SciTech Connect (OSTI)

    Smock, R.

    1982-07-01

    The overall message of the recent Symposium on Flue Gas Desulfurization was that the technology for sulfur dioxide scrubbing has matured enough for discussions to focus on future improvements rather than whether scrubbers work at all. The Environmental Protection Agency (EPA) regulations will not change in the near future, however, unless there are changes in the Clean air Act to deal with acid rain, despite the improvements in performance data. The symposium covered reports on dual-alkali scrubbing, organic buffer additives, the probability that scrubber wastes will not be classified as hazardous, simultaneous removal of nitrogen oxides and sulfur dioxide, and continuous monitoring programs. 3 figures, 4 tables. (DCK)

  4. Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

    SciTech Connect (OSTI)

    David A Lesch

    2010-06-30

    UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

  5. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    Patent: PH adjustment of power plant cooling water with flue gasfly ash Citation Details In-Document Search Title: PH adjustment of power plant cooling water with flue gasfly ash...

  6. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    PH adjustment of power plant cooling water with flue gasfly ash Citation Details In-Document Search Title: PH adjustment of power plant cooling water with flue gasfly ash A...

  7. Mercury oxidation in flue gas using gold and palladium catalysts on fabric filters

    SciTech Connect (OSTI)

    Jason A. Hrdlicka; Wayne S. Seames; Michael D. Mann; Darrin S. Muggli; Carol A. Horabik [University of North Dakota, Grand Forks, ND (United States). Department of Chemical Engineering

    2008-09-01

    The feasibility of oxidizing elemental mercury in coal combustion flue gas using catalytic material impregnated onto fabric filters was explored. TiO{sub 2}, Au/TiO{sub 2}, and Pd/Al{sub 2}O{sub 3} were studied based on promising results in previous research. Several fabric coating methods were investigated to determine the best way to load a filter. A spray coat method was found to have the highest initial loading and had the lowest losses after simulated pulse-jet cleaning. The oxidation performance of the catalyst-coated filters was tested using a simulated flue gas in a bench-scale reactor under conditions similar to those found in a baghouse. Au/TiO{sub 2} and Pd/Al{sub 2}O{sub 3} were effective, yielding mercury oxidation ranges of 40-60% and 50-80%, respectively. A 19 kW research combustor equipped with a baghouse was used to fire a range of coals and further test the performance of Pd/Al{sub 2}O{sub 3}. Results obtained warrant further development of this technique as a means of mercury pollution control. 19 refs., 2 figs., 5 tabs.

  8. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  9. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  10. The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG -this gas typically contains a high

    E-Print Network [OSTI]

    The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG - this gas typically contains a high

  11. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  12. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  13. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

  14. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate the performance of low-cost activated carbon sorbents for removing mercury. In addition, the effects of the dual flue gas conditioning system on mercury removal performance were evaluated as part of short-term parametric tests on Unit 2. Based on the parametric test results, a single sorbent (e.g., RWE Super HOK) was selected for a 30-day continuous injection test on Unit 1 to observe long-term performance of the sorbent as well as its effects on ESP and FGD system operations as well as combustion byproduct properties. A series of parametric tests were also performed on Shawville Unit 3 over a three-week period in which several activated carbon sorbents were injected into the flue gas duct just upstream of either of the two Unit 3 ESP units. Three different sorbents were evaluated in the parametric test program for the combined ESP 1/ESP 2 system in which sorbents were injected upstream of ESP 1: RWE Super HOK, Norit's DARCO Hg, and a 62:38 wt% hydrated lime/DARCO Hg premixed reagent. Five different sorbents were evaluated for the ESP 2 system in which activated carbons were injected upstream of ESP 2: RWE Super HOK and coarse-ground HOK, Norit's DARCO Hg and DARCO Hg-LH, and DARCO Hg with lime injection upstream of ESP 1. The hydrated lime tests were conducted to reduce SO3 levels in an attempt to enhance the mercury removal performance of the activated carbon sorbents. The Plant Yates and Shawville studies provided data required for assessing carbon performance and long-term operational impacts for flue gas mercury control across small-sized ESPs, as well as for estimating the costs of full-scale sorbent injection processes.

  15. PH adjustment of power plant cooling water with flue gas/fly ash

    DOE Patents [OSTI]

    Brady, Patrick V.; Krumhansl, James L.

    2015-09-22

    A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and the condenser; and a diverter coupled to the flue to direct a portion of an exhaust from the flue to contact with a cooling medium for the condenser water. A method including diverting a portion of exhaust from a flue of a vessel; modifying the pH of a cooling medium for a condenser with the portion of exhaust; and condensing heated fluid from the vessel with the pH modified cooling medium.

  16. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2011-03-01

    A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ÂşF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

  17. High Pressure Superheater 1 (HPSH1) is the first heat exchange tube bank inside the Heat Recovery Steam Generator (HRSG) to encounter exhaust flue gas from the gas turbine of a Combined Cycle Power Plant. Steam

    E-Print Network [OSTI]

    Steam Generator (HRSG) to encounter exhaust flue gas from the gas turbine of a Combined Cycle Power Plant. Steam flowing through the HPSH1 gains heat from the flue gas prior to entering the steam turbine changes that occurred, especially in the steam temperature at the HPSH1 entry, and the different rates

  18. JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas

    SciTech Connect (OSTI)

    Ye Zhuang; Christopher Martin; John Pavlish

    2009-03-31

    This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

  19. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2003-07-30

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

  20. PH adjustment of power plant cooling water with flue gas/fly...

    Office of Scientific and Technical Information (OSTI)

    Krumhansl, James L. A system including a vessel including a heat source and a flue; a turbine; a condenser; a fluid conduit circuit disposed between the vessel, the turbine and...

  1. Manganese oxide/titania materials for removal of NOx and elemental mercury from flue gas

    SciTech Connect (OSTI)

    Lei Ji; Pavani M. Sreekanth; Panagiotis G. Smirniotis; Stephen W. Thiel; Neville G. Pinto [University of Cincinnati, Cincinnati, OH (United States). Department of Chemical & Materials Engineering

    2008-07-15

    A novel catalyst for low temperature selective catalytic reduction (SCR) using CO as reductant, MnOx supported on titania, has been shown to be effective for both elemental mercury capture and low temperature SCR. In low temperature (200{sup o}C) SCR trials using an industrially relevant space velocity (50 000 h{sup -1}) and oxygen concentration (2 vol %), nearly quantitative reduction of NOx was obtained using CO as the reductant. Fresh catalyst used as an adsorbent for elemental mercury from an inert atmosphere showed remarkable mercury capture capacity, as high as 17.4 mg/g at 200{sup o}C. The catalyst effectively captured elemental mercury after use in NOx reduction. Mercury capture efficiency was not affected by the presence of water vapor. Mercury capacity was reduced in the presence of SO{sub 2}. Manganese loading and bed temperature, which influence surface oxide composition, were found to be important factors for mercury capture. X-ray photoelectron spectroscopy (XPS) results reveal that the mercury is present in its oxidized form (HgO) in spent catalyst, indicating the participation of lattice oxygen of the catalyst in the reaction. These results suggest that a single-step process integrating low temperature SCR and mercury capture from flue gas might be feasible. 42 refs., 10 figs., 2 tabs.

  2. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  3. Fundamental mechanisms in flue gas conditioning. Quarterly report, January 1992--March 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Bush, P.V.

    1992-04-27

    This project is divided into four tasks. The Management Plan was developed in task 1. Task 2, Evaluation of Mechanisms in FGD Sorbent and Ash Interactions, focuses on the characteristics of binary mixtures of these distinct powders. Task 3, Evaluation of Mechanisms in Conditioning Agents and Ash, is designed to examine the effects of various conditioning agents on fine ash particles to determine the mechanisms by which these agents alter the physical properties of the ash. Tasks 2 and 3 began with an extensive literature search and the assembly of existing theories. This phase of the project is now complete. During the past quarter, initial preparations of laboratory equipment for laboratory testing have been made. A plan for initial laboratory tests has been submitted to the Project Manager for review. Laboratory testing will commence once these laboratory plans have been formally approved. The results of the work performed under task 2 and 3 will be included in a Flue Gas Conditioning Model that will be issued under task 4. The Final Report for the project will also be prepared under task 4.

  4. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  5. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  6. CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents

    SciTech Connect (OSTI)

    Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

    2012-08-31

    The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

  7. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of “staining” upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  8. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  9. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  10. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  11. Screening of carbon-based sorbents for the removal of elemental mercury from simulated combustion flue gas

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemically activated hardwood, chemically activated bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective sorbent, showing over 99% mercury removal according to U.S. Environmental Protection Agency (EPA) Method 101A. Data indicate that adding O{sub 2} at 4 vol% reduced the effectiveness of the steam-activated lignite, chemically activated hardwood, and sulfur- impregnated steam-activated bituminous coal. Adding SO{sub 2} at 500 ppm improved the mercury removal of the sulfur-impregnated carbon. Further, the presence of HCl gas (at 50 ppm) produced an order of magnitude increase in mercury removal with the chemically activated and sulfur-impregnated bituminous coal-based carbons.

  12. Screening of carbon-based sorbents for the removal of elemental mercury from simulated combustion flue gas

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemical-activated hardwood and bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective carbon, showing over 99% mercury removal according to EPA Method 101A. Data indicate that O{sub 2} (4 vol%) and SO{sub 2} (500 ppm) improved the mercury removal of the other carbons for tests at 150{degrees}C using 100 {mu}g/m{sup 3} Hg{sup 0}. Further, the presence of HCl (at 50 ppm) produced a magnitude increase in mercury removal for the steam-activated and sulfur-impregnated bituminous coal-based carbons.

  13. Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  14. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  15. Status of flue-gas treatment technologies for combined SO[sub 2]/NO[sub x] reduction

    SciTech Connect (OSTI)

    Livengood, C.D. (Argonne National Lab., IL (United States). Energy Systems Div.); Markussen, J.M. (USDOE Pittsburgh Energy Technology Center, PA (United States))

    1993-01-01

    Enactment of the Clean Air Act Amendments and passage of state legislation leading to more stringent nitrogen oxides (NO.) regulations have fueled research and development efforts on the technologies for the combined control of sulfur dioxide (SO[sub 2]) and NO[sub x]. The integrated removal of both SO[sub 2] and NO[sub x] in a single system can offer significant advantages over the use of several separate processes, including such factors as reduced system complexity, better operability, and lower costs. This paper reviews the status of a number of integrated flue-gas-cleanup systems that have reached a significant stage of development, focusing on post-combustion processes that have been tested or are ready for testing at the pilot scale or larger. A brief process description, a summary of the development status and performance achieved to date, pending commercialization issues, and process economics (when available) are given for each technology.

  16. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  17. Flue gas conditioning for improved particle collection in electrostatic precipitators. Quarterly technical report, July 1--September 30, 1992

    SciTech Connect (OSTI)

    Durham, M.D.

    1992-10-14

    By injecting high concentrations of SO{sub 3} (80 to 100 ppM) it was possible to reduce the particle resistivity from 10{sup 11} to 10{sup 7} ohm-cm. However, it was very difficult to consistently obtain intermediate levels of resistivity. This was because of the steep relationships between gas phase SO{sub 3} and resistivity. It only takes a few ppM of SO{sub 3} to provide an order of magnitude change in resistivity. This is demonstrated by the curves in Figure 2. The water dew point for a gas stream with a moisture content of 10%, which is typical of coal fired boilers, is approximately 120{degrees}F. However, in a flue gas with only 2 ppM of SO{sub 3}, sulfuric acid will begin to condense at 270{degrees}F. The effect of the rapid rise in acid dew point is reflected by the corresponding rapid decrease in resistivity. With no gas phase SO{sub 3} present the resistivity is in the high 10{sup 11} ohm-cm range. However with only 10 ppM of SO{sub 3}, the resistivity drops three orders of magnitude. Therefore, intermediate levels of resistivity can only be obtained by controlling the SO{sub 3} concentration within 1 or 2 ppM.

  18. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  19. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  20. Fundamental mechanisms in flue-gas conditioning. Topical report No. 1, Literature review and assembly of theories on the interactions of ash and FGD sorbents

    SciTech Connect (OSTI)

    Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

    1992-01-09

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  1. Effects of HCl and SO{sub 2} concentration on mercury removal by activated carbon sorbents in coal-derived flue gas

    SciTech Connect (OSTI)

    Ryota Ochiai; M. Azhar Uddin; Eiji Sasaoka; Shengji Wu [Okayama University, Okayama (Japan). Faculty of Environmental Science and Technology

    2009-09-15

    The effect of the presence of HCl and SO{sub 2} in the simulated coal combustion flue gas on the Hg{sup 0} removal by a commercial activated carbon (coconut shell AC) was investigated in a laboratory-scale fixed-bed reactor in a temperature range of 80-200{sup o}C. The characteristics (thermal stability) of the mercury species formed on the sorbents under various adsorption conditions were investigated by the temperature-programmed decomposition desorption (TPDD) technique. It was found that the presence of HCl and SO{sub 2} in the flue gas affected the mercury removal efficiency of the sorbents as well as the characteristics of the mercury adsorption species. The mercury removal rate of AC increased with the HCl concentration in the flue gas. In the presence of HCl and the absence of SO{sub 2} during Hg{sup 0} adsorption by AC, a single Hg{sup 0} desorption peak at around 300{sup o}C was observed in the TPDD spectra and intensity of this peak increased with the HCl concentration during mercury adsorption. The peak at around 300{sup o}C may be derived from the decomposition and desorption of mercury chloride species. The presence of SO{sub 2} during mercury adsorption had an adverse effect on the mercury removal by AC in the presence of HCl. In the presence of both HCl and SO{sub 2} during Hg{sup 0} adsorption by AC, the major TPDD peak temperatures changed drastically depending upon the concentration of HCl and SO{sub 2} in flue gas during Hg{sup 0} adsorption. 16 refs., 7 figs.

  2. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  3. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  4. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  5. Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Fogash, Kevin

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  6. The use of wet limestone systems for combined removal of SO sub 2 and NO sub x from flue gas

    SciTech Connect (OSTI)

    Lee, G.C. (Bechtel Corp., San Francisco, CA (USA)); Shen, D.X.; Littlejohn, D.; Chang, S.G. (Lawrence Berkeley Lab., CA (USA))

    1990-03-01

    A new approach by utilizing yellow phosphorus in conventional wet limestone systems for high efficiency control of SO{sub 2} and NO{sub x} emissions from power plants has been developed. The addition of yellow phosphorus in the system induces the production of O{sub 3} which subsequently oxidizes NO to NO{sub 2}. The resulting NO{sub 2} dissolves readily and can be reduced to form ammonium ions by dissolved SO{sub 2} under appropriate conditions. Yellow phosphorus is oxidized to yield P{sub 2}O{sub 5} which picks up water to form H{sub 3}PO{sub 4} mists and can be collected as a valuable product. Proof of concept experiments have been performed using a 20 acfm bench-scale system. The results show that better than 90% of SO{sub 2} and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained. This ratio depends on operating conditions as well as the process configuration. A conceptual process flow diagram has been proposed. A preliminary cost evaluation of this approach appears to indicate great economic potential. 22 refs., 8 figs., 1 tab.

  7. Alternative flue gas treatment technologies for integrated SO{sub 2} and NO{sub x} control

    SciTech Connect (OSTI)

    Markussen, J.M. [USDOE Pittsburgh Energy Technology Center, PA (United States); Livengood, D.D. [Argonne National Lab., IL (United States)

    1995-06-01

    Enactment of the 1990 Clean Air Act Amendments, as well as passage of legislation at the state level has raised the prospect of more stringent nitrogen oxides (NO{sub x}) emission regulations and has fueled research and development efforts on a number technologies for the combined control of sulfur dioxide (SO{sub 2}) and NO{sub x}. The integrated removal of both SO{sub 2} and NO{sub x} in a single system can offer significant advantages over the use of several separate processes, including such factors as reduced system complexity, better operability, and lower costs. This paper reviews the status of a number of integrated flue gas cleanup systems that have reached a significant stage of development, focusing on post-combustion processes that have been tested or are ready for testing at the pilot scale or larger. A brief process description, a summary of the development status and performance achieved to date, pending commercialization issues, and process economics (when available) are given for each technology.

  8. Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  9. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  10. Development of a Novel Gas Pressurized Stripping Process-Based Technology for CO? Capture from Post-Combustion Flue Gases

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2015-09-30

    A novel Gas Pressurized Stripping (GPS) post-combustion carbon capture (PCC) process has been developed by Carbon Capture Scientific, LLC, CONSOL Energy Inc., Nexant Inc., and Western Kentucky University in this bench-scale project. The GPS-based process presents a unique approach that uses a gas pressurized technology for CO? stripping at an elevated pressure to overcome the energy use and other disadvantages associated with the benchmark monoethanolamine (MEA) process. The project was aimed at performing laboratory- and bench-scale experiments to prove its technical feasibility and generate process engineering and scale-up data, and conducting a techno-economic analysis (TEA) to demonstrate its energy use and cost competitiveness over the MEA process. To meet project goals and objectives, a combination of experimental work, process simulation, and technical and economic analysis studies were applied. The project conducted individual unit lab-scale tests for major process components, including a first absorption column, a GPS column, a second absorption column, and a flasher. Computer simulations were carried out to study the GPS column behavior under different operating conditions, to optimize the column design and operation, and to optimize the GPS process for an existing and a new power plant. The vapor-liquid equilibrium data under high loading and high temperature for the selected amines were also measured. The thermal and oxidative stability of the selected solvents were also tested experimentally and presented. A bench-scale column-based unit capable of achieving at least 90% CO? capture from a nominal 500 SLPM coal-derived flue gas slipstream was designed and built. This integrated, continuous, skid-mounted GPS system was tested using real flue gas from a coal-fired boiler at the National Carbon Capture Center (NCCC). The technical challenges of the GPS technology in stability, corrosion, and foaming of selected solvents, and environmental, health and safety risks have been addressed through experimental tests, consultation with vendors and engineering analysis. Multiple rounds of TEA were performed to improve the GPS-based PCC process design and operation, and to compare the energy use and cost performance of a nominal 550-MWe supercritical pulverized coal (PC) plant among the DOE/NETL report Case 11 (the PC plant without CO? capture), the DOE/NETL report Case 12 (the PC plant with benchmark MEA-based PCC), and the PC plant using GPS-based PCC. The results reveal that the net power produced in the PC plant with GPS-based PCC is 647 MWe, greater than that of the Case 12 (550 MWe). The 20-year LCOE for the PC plant with GPS-based PCC is 97.4 mills/kWh, or 152% of that of the Case 11, which is also 23% less than that of the Case 12. These results demonstrate that the GPS-based PCC process is energy-efficient and cost-effective compared with the benchmark MEA process.

  11. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  12. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  13. Inorganic hazardous air pollutants before and after a limestone flue gas desulfurization system as a function of <10 micrometer particle sizes and unit load

    SciTech Connect (OSTI)

    Maxwell, D.P.; Williams, W.A.; Flora, H.B. II [Radian Corp., Austin, TX (United States)

    1995-12-31

    Radian Corporation collected size-fractionated particulate samples from stack gas at a unit burning high sulfur coal with a venturi scrubber FGD system. Independent sample fractions were collected under high-load and low-load operating conditions and subjected to various techniques designed to measure the total composition and surface-extractable concentrations of selected trace elements. The relationships between unit load, particle-size distribution, total composition, and surface-extractable inorganic species are reported and compared to show the availability of trace elements relevant to potential health risks from flue gas particulate emissions.

  14. Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecovery ActToolsForNorthfor GasConference

  15. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture | Center for Gas

  16. Scrubber strategy: the how and why of flue gas desulfurization. [Analysis of 20 US scrubbing systems in 1980

    SciTech Connect (OSTI)

    Baviello, M.A.

    1982-01-01

    In this report, INFORM provides facts that will help the non-technical decisionmakers in the US understand a technology that can significantly reduce the polluting effects of burning coal. Those decisionmakers include legislators, regulators and utility executives, public interest groups, concerned community organizations and environmentalists who have been involved in the debate over the broader use of our most abundant fossil fuel - coal. The use of this resource, especially in large industrial and utility plants, has created widespread and intense public controversy. For the past four years INFORM has turned its research capabilities to defining cleaner and more economical ways of using US coal supplies. We have focused on finding out what cleaning coal and using flue gas desulfurization systems (called scrubbers) can contribute to reducing the polluting effects of burning coal in utility plants. All in all, both scrubbers and coal cleaning offer exciting and important possibilities for putting more coal to work in generating power in this country more economically and still meeting critical air quality standards that have been set to protect public health. The need for accurate and clear information concerning these technologies is evident: 80% of the sulfur dioxide emissions in the US now come from utility power plant operations, and over 140 existing oil-fired power plants are candidates for conversion to coal use. We hope that this documentation of the technologies of scrubber systems along with INFORM's companion study of coal cleaning, may help government and business planners and concerned citizens chart intelligent future courses and set realistic goals for meeting our energy needs in an environmentally sound manner.

  17. Field testing of a probe to measure fouling in an industrial flue gas stream

    SciTech Connect (OSTI)

    Sohal, M.S.

    1990-11-01

    The US Department of Energy, Office of Industrial Technology sponsors work in the area of measuring and mitigating fouling in heat exchangers. This report describes the design and fabrication of a gas-side fouling measuring device, and its testing in an industrial environment. The report gives details of the probe fabrication, material used, controllers, other instrumentation required for various measurements, and computer system needed for recording the data. The calibration constants for measuring the heat flux with the heat fluxmeter were determined. The report also describes the field test location, the tests performed, the data collected, and the data analysis. The conclusions of the tests performed were summarized. Although fouling deposits on the probe were minimal, the tests proved that the probe is capable of measuring the fouling in a harsh industrial environment. 17 refs., 19 figs., 5 tabs.

  18. Global evaluation of mass transfer effects: In-duct injection flue gas desulfurization

    SciTech Connect (OSTI)

    Cole, J.A.; Newton, G.H.; Kramlich, J.C.; Payne, R.

    1990-09-30

    Sorbent injection is a low capital cost, low operating cost approach to SO{sub 2} control targeted primarily at older boilers for which conventional fuel gas desulfurization is not economically viable. Duct injection is one variation of this concept in which the sorbent, either a dry powder or a slurry, is injected into the cooler regions of the boiler, generally downstream of the air heaters. The attractiveness of duct injection is tied to the fact that it avoids much of the boiler heat transfer equipment and thus has minimal impact of boiler performance. Both capital and operating cost are low. This program has as its objectives three performance related issues to address: (1) experimentally identify limits on sorbent performance. (2) identify and test sorbent performance enhancement strategies. (3) develop a compute model of the duct injection process. Two major tasks are described: a laboratory-scale global experiment and development of process model. Both are aimed at understanding and quantifying the rate-limiting processes which control SO{sub 2} capture by lime slurry during boiler duct injection. 29 refs., 35 figs., 4 tabs.

  19. Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs 

    E-Print Network [OSTI]

    Nogueira de Mago, Marjorie Carolina

    2005-11-01

    Previous experiments - injecting pure CO2 into carbonate cores - showed that the process is a win-win technology, sequestrating CO2 while recovering a significant amount of hitherto unrecoverable natural gas that could help defray the cost of CO2...

  20. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 15, September 1, 1994--November 30, 1994

    SciTech Connect (OSTI)

    NONE

    1997-01-01

    The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

  1. Adsorption and desorption of sulfur dioxide on novel adsorbents for flue gas desulfurization. Final report, September 1, 1994--February 29, 1996

    SciTech Connect (OSTI)

    Lin, Y.S.; Deng, S.G.

    1996-08-05

    A sol-gel granulation method was developed to prepare spherical {gamma}-alumina granular supports and supported CuO granular sorbents for flue gas desulfurization. The prepared {gamma}-alumina supported CuO sorbents exhibit desirable pore structure and excellent mechanical properties. The sorbents contain higher loading (30-40 wt. %) of CuO dispersed in the monolayer or sub-monolayer form, giving rise to a larger SO{sub 2} sorption capacity ({gt}20 wt.%) and a faster sorption rate as compared to similar sorbents reported in the literature. With these excellent sulfation and mechanical properties, the sol-gel derived {gamma}-alumina supported CuO granular sorbents offer great potential for use in the dry, regenerative flue gas desulfurization process. Research efforts were also made to prepare DAY zeolite supported sorbents with various CuO contents by the microwave and conventional thermal dispersion methods at different conditions. Monolayer or sub-monolayer coating of Cu(NO{sub 3})sub 2 or CuO was achieved on several DAY supported sorbents by the microwave heating method but not by the conventional thermal dispersion method. The DAY zeolite supported CuO sorbents prepared by the microwave heating method can adsorb up to 15 wt.% of SO{sub 2}. The results obtained have demonstrated the feasibility of effective preparation of zeolite supported CuO sorbents by the microwave heating method.

  2. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  3. FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS

    SciTech Connect (OSTI)

    Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

    2003-10-31

    With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC baghouse. Activated carbon was injected between the ESP and COHPAC units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC unit. The test also showed that activated carbon was effective in removing both forms of mercury-elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

  4. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  5. Study on multiphase flow and mixing in semidry flue gas desulfurization with a multifluid alkaline spray generator using particle image velocimetry

    SciTech Connect (OSTI)

    Zhou, Y.G.; Wang, D.F.; Zhang, M.C. [Shanghai Jiao Tong University, Shanghai (China)

    2009-06-15

    Particle image velocimetry (PIV) technique was used to measure the velocity fields of gas-droplet-solid multiphase flow in the experimental setup of a novel semidry flue gas desulfurization process with a multifluid alkaline spray generator. The flow structure, mixing characteristic, and interphase interaction of gas-droplet-solid multiphase flow were investigated both in the confined alkaline spray generator and in the duct bent pipe section. The results show that sorbent particles in the confined alkaline spray generator are entrained into the spray core zone by a high-speed spray jet and most of the sorbent particles can be effectively humidified by spray water fine droplets to form aqueous lime slurry droplets. Moreover, a minimum amount of air stream in the generator is necessary to achieve higher collision humidification efficiency between sorbent particles and spray water droplets and to prevent the possible deposition of fine droplets on the wall. The appropriate penetration length of the slurry droplets from the generator can make uniform mixing between the formed slurry droplets and main air stream in the duct bent pipe section, which is beneficial to improving sulfur dioxide removal efficiency and to preventing the deposition of droplets on the wall.

  6. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 12, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    1994-12-31

    The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from the flue gas of a coal-fired utility boiler. In the process, the SO{sub 2} is reduced to sulfur by-product and the NO{sub x} is reduced to nitrogen and oxygen. It is predicted that the process can economically remove 90% of the acid rain precursor gases from the flue gas stream in a retrofit or new facility. The objective of the NOXSO Demonstration Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process. The effectiveness of the process will be demonstrated by achieving significant reductions in emissions of sulfur and nitrogen oxides. In addition, sufficient operating data will be obtained to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is presently in the project definition and preliminary design phase. Data obtained during pilot plant testing which was completed on July 30, 1993 is being incorporated in the design of the commercial size plant. A suitable host site to demonstrate the NOXSO process on a commercial scale is presently being sought. The plant general arrangement has been revised to incorporate principles used in the design of fluidized catalytic cracking (FCC) plants. A NOXSO plant availability analysis was prepared using operating experience from the recently completed pilot plant as a basis. The impact of water desorption in the sorbent heater and water adsorption in the sorbent cooler has been quantified and incorporated into the NOXSO process simulator. NOXSO process economics has been updated based on the present design. Capital cost for a 500 MW plant designed to remove 98% of the SO{sub 2} and 85% of the NO{sub x} is estimated at $247/kW.

  7. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  8. Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (Oakland, CA); Griffiths, Elizabeth A. (Neston, GB2); Littlejohn, David (Oakland, CA)

    1988-01-01

    The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

  9. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

  10. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  11. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  12. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Bush, P.V.

    1993-01-20

    We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test the samples. Plans are under way to condition selected samples with (NH[sub 4])[sub 2]SO[sub 4], NH[sub 4]HSO[sub 4], CaCl[sub 2], organosiloxane, and SO[sub 3]. Pending approval, we will begin these conditioning experiments, and subsequent analyses of the conditioned samples.

  13. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.

    1992-07-27

    SEM pictures of the three mixtures of sorbent and ash from the DITF and the base line ESP hopper ash from Muskingum are shown in Figures 1 through 4. The effects of sorbent addition on particle morphology are evident in Figures 2 through 4 by the presence of irregularly shaped particles and deposits on the surfaces of the spherical fly ash particles. In contrast, the base Ene ash particles have the characteristic relatively smooth, spherical morphology normally associated with pulverized-coal (PC) fly ashes. Resistivity determinations made on these four ashes in ascending and descending temperature modes. These data are shown in Figures 5 and 6. Sorbent injection processes performed at the DITF lowered the duct temperature to around 165{degrees}F from about 350{degrees}F for base line operation. Consequently, during collection in the ESP, the particulate matter from the sorbent injection processes had a significantly lower resitivity (approximately 4 {times} 10{sup 7} {Omega}-cm) than the base line ash (approximately 3 {times} 10{sup 11} {Omega}-cm at 350{degrees}F). Specific surface areas and true particle densities have been measured for the four samples obtained from the DOE/PETC Duct Injection Test Facility. These data are summarized in Table 4. The primary difference indicated by these initial analyses of these four samples is the significant increase in specific surface area due to sorbent addition. The specific surface areas of the three sorbent and ash mixtures from the DITF are quite similar.

  14. Flue gas desulfurization gypsum and fly ash

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

  15. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  16. Development of a Novel Gas Pressurized Process-Based Technology for CO2 Capture from Post-Combustion Flue Gases Preliminary Year 1 Techno-Economic Study Results and Methodology for Gas Pressurized Stripping Process

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2013-03-01

    Under the DOE’s Innovations for Existing Plants (IEP) Program, Carbon Capture Scientific, LLC (CCS) is developing a novel gas pressurized stripping (GPS) process to enable efficient post-combustion carbon capture (PCC) from coal-fired power plants. A technology and economic feasibility study is required as a deliverable in the project Statement of Project Objectives. This study analyzes a fully integrated pulverized coal power plant equipped with GPS technology for PCC, and is carried out, to the maximum extent possible, in accordance to the methodology and data provided in ATTACHMENT 3 – Basis for Technology Feasibility Study of DOE Funding Opportunity Number: DE-FOA-0000403. The DOE/NETL report on “Cost and Performance Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity (Original Issue Date, May 2007), NETL Report No. DOE/NETL-2007/1281, Revision 1, August 2007” was used as the main source of reference to be followed, as per the guidelines of ATTACHMENT 3 of DE-FOA-0000403. The DOE/NETL-2007/1281 study compared the feasibility of various combinations of power plant/CO2 capture process arrangements. The report contained a comprehensive set of design basis and economic evaluation assumptions and criteria, which are used as the main reference points for the purpose of this study. Specifically, Nexant adopted the design and economic evaluation basis from Case 12 of the above-mentioned DOE/NETL report. This case corresponds to a nominal 550 MWe (net), supercritical greenfield PC plant that utilizes an advanced MEAbased absorption system for CO2 capture and compression. For this techno-economic study, CCS’ GPS process replaces the MEA-based CO2 absorption system used in the original case. The objective of this study is to assess the performance of a full-scale GPS-based PCC design that is integrated with a supercritical PC plant similar to Case 12 of the DOE/NETL report, such that it corresponds to a nominal 550 MWe supercritical PC plant with 90% CO2 capture. This plant has the same boiler firing rate and superheated high pressure steam generation as the DOE/NETL report’s Case 12 PC plant. However, due to the difference in performance between the GPS-based PCC and the MEA-based CO2 absorption technology, the net power output of this plant may not be exactly at 550 MWe.

  17. Greenhouse Gas Mitigation Options in ISEEM Global Energy Model: 2010-2050 Scenario Analysis for Least-Cost Carbon Reduction in Iron and Steel Sector

    E-Print Network [OSTI]

    Karali, Nihan

    2014-01-01

    systems in EAF plants Variable speed drives for flue gas control, pumps, fans in integrated steel mills Cogeneration

  18. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  19. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Control of pollutants in flue gases and fuel gases Ron Zevenhoven Helsinki University of Technology Programme Solid Fuel Committee Ĺs, Norway Helsinki University of Technology Espoo, Finland #12;limited . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3 Chapter 2 Flue gases and fuel gases 2.1 Introduction

  20. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons

    SciTech Connect (OSTI)

    Hajizadeh, Yaghoub; Onwudili, Jude A.; Williams, Paul T.

    2011-06-15

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275 deg. C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 {mu}g I-TEQ kg{sup -1} toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 {mu}g I-TEQ kg{sup -1} in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  1. Flue Gas Desulfurization Market Research Report 2018 | OpenEI...

    Open Energy Info (EERE)

    that have the ability to reduce compliance costs. Sulfur dioxide (SO2) used at coal-fired electric plants has a theoretically uncertain impact on pollution emissions....

  2. Combined Flue Gas Heat Recovery and Pollution Control Systems 

    E-Print Network [OSTI]

    Zbikowski, T.

    1979-01-01

    in the field of heat recovery now make it possible to recover a portion of the wasted heat and improve the working conditions of the air purification equipment. Proper design and selection of heat recovery and pollution control equipment as a combination...

  3. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    the two instruments at their present state of development. Authors: Montagna, J C ; Smith, G W ; Teats, F G ; Voge, G J ; Jonke, A A Publication Date: 1977-01-01 OSTI...

  4. Ranking low cost sorbents for mercury capture from simulated flue gases

    SciTech Connect (OSTI)

    H. Revata Seneviratne; Cedric Charpenteau; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-12-15

    Coal fired utility boilers are the largest anthropogenic source of mercury release to the atmosphere, and mercury abatement legislation is already in place in the USA. The present study aimed to rank low cost mercury sorbents (char and activated carbon from the pyrolysis of scrap tire rubber and two coal fly ashes from UK power plants) against Norit Darco HgTM for mercury retention by using a novel bench-scale reactor. In this scheme, a fixed sorbent bed was tested for mercury capture efficiency from a simulated flue gas stream. Experiments with a gas stream of only mercury and nitrogen showed that while the coal ashes were the most effective in mercury capture, char from the pyrolysis of scrap tire rubber was as effective as the commercial sorbent Norit Darco HgTM. Tests conducted at 150{sup o}C, with a simulated flue gas mix that included N{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, SO{sub 2} and HCl, showed that all the sorbents captured approximately 100% of the mercury in the gas stream. The introduction of NO and NO{sub 2} was found to significantly improve the mercury capture, possibly by reactions between NOx and the mercury. Since the sorbents' efficiency decreased with increasing test temperature, physical sorption could be the initial step in the mercury capture process. As the sorbents were only exposed to 64 ng of mercury in the gas stream, the mercury loadings on the samples were significantly less than their equilibrium capacities. The larger capacities of the activated carbons due to their more microporous structure were therefore not utilized. Although the sorbents have been characterized by BET surface area analysis and XRD analysis, further analysis is needed in order to obtain a more conclusive correlation of how the characteristics of the different sorbents correlate with the observed variations in mercury capture ability. 34 refs., 8 figs., 6 tabs.

  5. Millimeter Wave Observations of the Core-Jet and Molecular Gas in the FR I Radio Galaxy NGC 3801

    E-Print Network [OSTI]

    Mousumi Das; Stuart N. Vogel; Gijs A. Verdoes Kleijn; Christopher P. O'Dea; Stefi A. Baum

    2005-05-13

    We present BIMA 3 mm observations of the radio continuum source and the molecular gas disk in the radio loud Fanaroff & Riley Type I (FR I)galaxy NGC3801.We have detected a continuum source in the nucleus and determined that it has a flat millimeter-wave spectrum, suggesting that the emission is non-thermal and due to an AGN; the radio core is not evident in existing VLA observations. We also map the extended 3 mm emission from the previously known radio jets. In addition, we detect CO (1--0) emission associated with the dust disk observed in previous HST images. A velocity gradient is observed, indicating a two kpc radius rotating gas ring or disk oriented roughly perpendicular to the radio jets. The inferred molecular gas mass of the disk is $M(H_{2})=3\\times10^{8}M_{\\odot}$, about 1% of the dynamical mass. We also find a $\\sim 10^8$ M$_\\odot$ molecular gas clump not associated with the gas disk. There is evidence that this gas is associated with a merger and is infalling. This suggests that FR I type activity is related to merger activity, as is thought to be the case for FR II type radio galaxies. We also find indications that one of the radio jets is entraining gas from the infalling molecular gas.

  6. Feasibility of an alpha particle gas densimeter for stack sampling applications 

    E-Print Network [OSTI]

    Johnson, Randall Mark

    1983-01-01

    , for conceivable ranges of flue gas composition, the maximum error in density due to the uncertainty in gas composition is less than 2%. ACKNOWLEDGEMENTS I wish to express my appreciation to Dr. R. A. Fjeld and Dr. A. R. McFarland for their patience... LISTING APPENDIX C TABULATED RESULTS 58 60 72 VI TA 84 Vi LIST OF TABLES TABLE P age I Typical Flue Gas Compositions II Model Flue Gas Compositions 35 Coeff icients for Alpha particle Stopping Power Functions 59 Computed and Experimental...

  7. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2014-08-19

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  8. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

    2010-11-09

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  9. natural gas+ condensing flue gas heat recovery+ water creation+ CO2

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan)data book Homefuelleasing Homemapsmockups

  10. OpenEI Community - natural gas+ condensing flue gas heat recovery+ water

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly Smart Grid Data available for download onst,/0Thoughts after

  11. Evaluating energy dissipation during expansion in a refrigeration cycle using flue pipe acoustic resonators

    E-Print Network [OSTI]

    Luckyanova, Maria N. (Maria Nickolayevna)

    2008-01-01

    This research evaluates the feasibility of using a flue pipe acoustic resonator to dissipate energy from a refrigerant stream in order to achieve greater cooling power from a cryorefrigeration cycle. Two models of the ...

  12. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  13. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, C.Y.

    1993-09-21

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

  14. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-01-01

    Condensate Return Automatic Steam Trap Monitoring Flue Gas Heat Recoveryheat recovery Blowdown steam Recovery Steam trap maintenance Automatic steam trap monitoring Leak repair Condensateheat recovery Blowdown steam recovery Steam trap maintenance Automatic steam trap monitoring Leak repair Condensate

  15. Promising Technology: Condensing Gas Water Heaters

    Broader source: Energy.gov [DOE]

    Condensing water heaters achieve higher efficiencies than conventional water heaters by capturing the latent heat from water vapor contained in the flue gases. Combustion gases are exhausted through a secondary heat exchanger where the latent heat of water vapor in the exhaust gas is transferred to the stored water. This technology enables the water heater to achieve thermal efficiencies up to 99%.

  16. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    Flue Flue Fuel oil Natural gas Natural gas Gas turbine Gasturbine Gas turbine Coal IGCC Flue Flue Flue Flue Fuel IEA,oil, natural gas, and gas turbine power plants. As shown,

  17. High potential recovery -- Gas repressurization

    SciTech Connect (OSTI)

    Madden, M.P.

    1998-05-01

    The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

  18. Predictive Modeling of Mercury Speciation in Combustion Flue Gases Using GMDH-Based Abductive Networks

    E-Print Network [OSTI]

    Abdel-Aal, Radwan E.

    and boiler operating conditions. Prediction performance compares favourably with neural network models for future work to further improve performance. Index Terms: Mercury speciation, Flue gases, Boiler emissions activities are coal-fired electric utility boilers, where speciation depends on the operating conditions

  19. GAS INJECTION/WELL STIMULATION PROJECT

    SciTech Connect (OSTI)

    John K. Godwin

    2005-12-01

    Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

  20. Sulfur Dioxide Treatment from Flue Gases Using a Biotrickling

    E-Print Network [OSTI]

    ), and several episodes in London (1). All fuels used by humans such as coal, oil, natural gas, peat, wood s for a concentration range of 300-1000 ppmv. All the absorbed SO2 was recovered in the biotrickling filter liquid of sulfite). The biotrickling filter liquid effluent was further processed biologically in a single post

  1. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-5 4.3 Emission standards for NOx . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-9 2.6 Emission standards and exhaust gas composition . . . . . . . . . . . . . . . . . 2-10 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  2. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Brent Constantz; Randy Seeker; Martin Devenney

    2010-06-30

    Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

  3. The utilization of flue gas desulfurization waste by-products in construction brick 

    E-Print Network [OSTI]

    Berryman, Charles Wayne

    1992-01-01

    Millions of tons of waste by-products from Texas coal burning plants are produced each year. Two common byproducts are the fuel ashes and calcium sulfate (gypsum). Fuel ashes result from the burning of coal. Gypsum is a byproduct of the air...

  4. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  5. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers 

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01

    create the EPA as a separate agency reporting dir ectly to the President, but it established schedules and a regulatory mechanism to treat air quality on a national basis. Although the initial reaction to this law by coal burners was the switch...

  6. Separation of Carbon Dioxide from Nitrogen and Water in Flue Gas Streams 

    E-Print Network [OSTI]

    Mera, Hilda 1989-

    2012-04-12

    coefficients of carbon dioxide, nitrogen, and water in MOFs. The metal-organic frameworks studied are copper trimesate (Cu-BTC), zinc terephthalate (IRMOF1), and MIL-47, which belongs to the Materials of the Institute Lavoisier series. Diffusion coefficients...

  7. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01

    0 removal in the presence of fly ash or powdered activatedash,24mg only (adsorption) Fly ash, 24 mg only (adsorption)Fly ash,24mg;[SCl2],24ppm Fly ash, Flyash,24mg; 24 mg; [SCl

  8. Fundamental mechanisms in flue gas conditioning. Quarterly report, October 1992--December 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Bush, P.V.

    1993-01-20

    We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test the samples. Plans are under way to condition selected samples with (NH{sub 4}){sub 2}SO{sub 4}, NH{sub 4}HSO{sub 4}, CaCl{sub 2}, organosiloxane, and SO{sub 3}. Pending approval, we will begin these conditioning experiments, and subsequent analyses of the conditioned samples.

  9. SOx-NOx-Rox Box Flue Gas Cleanup Demonstration: A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2000-12-15

    The SNRB{trademark} test program demonstrated the feasibility of controlling multiple emissions from a coal-fired boiler in a single processing unit. The degree of emissions removals for SO{sub 2}, NO{sub x}, and particulates all exceeded the project goals. A high degree of removal for HAPs was also achieved. The SNRB system offers low space requirements, control of multiple pollutants, and operating flexibility. The pneumatic SO{sub 2} sorbent and ammonia injection systems are expected to have high reliability because of their mechanical simplicity. Despite these advantages, the SNRB process may not be an economic choice for applications involving SO{sub 2} removals above about 85%. For lower levels of SO{sub 2} removal, the projected economics for SNRB appear to be more favorable than those of existing processes which involve separate units for the same degree of control for SO{sub 2}, NO{sub x} , and particulates. Specific findings are summarized as follows: (1) SO{sub 2} removal of 85-90% was achieved at a calcium utilization of 40-45%, representing a significant improvement in performance over other dry lime injection processes. (2) When firing 3-4% sulfur coal, compliance with the 1990 CAAA Phase I SO{sub 2} emissions limit of 2.5 lb/10{sup 6} Btu was achieved with a Ca/S molar ratio of less than 1.0. For the Phase II SO{sub 2} emissions limit of 1.2 lb/10{sup 6} Btu, compliance was achieved with a Ca/S molar ratio as low as 1.5. Phase II compliance is the more relevant emissions limit. (3) When using NaHCO{sub 3} as the sorbent, the Phase II SO{sub 2} emissions limit was achieved at a Na{sub 2}/S molar ratio of less than 2.0 (NSR < 1.0). (4) Compliance with the Phase I NO{sub x} emissions limit of 0.45 lb/10{sup 6} Btu for Group 1 boilers was achieved at an NH{sub 3}/NO{sub x} ratio of 0.85, with an ammonia slip of 5 ppm or less. (5) Particulate collection efficiency averaged 99.9%, corresponding to an average emissions rate of 0.018 lb/10{sup 6} Btu. This is significantly lower than the NSPS value of 0.03 lb/10{sup 6} Btu. The high-temperature baghouse design incorporating an SCR catalyst for NO{sub x} reduction was demonstrated successfully. The technology is ready for commercial application. The key feature of the technology is control of SO{sub 2}, NO{sub x}, and particulates in a single process unit. However, this limits its commercial market to applications requiring control of all three components. Also, although the testing demonstrated greater than 90% SO{sub 2} capture, this was achieved at high sorbent/sulfur ratios. For applications requiring a high percentage of sulfur removal, a modern conventional FGD unit with LNBs for NO{sub x} control may be the preferred option.

  10. Fundamental mechanisms in flue gas conditioning. Quarterly report, April 1993--June 1993

    SciTech Connect (OSTI)

    Snyder, T.R.

    1993-07-13

    The experiments we have been performing are primarily designed to define the extent to which water affects key properties of ashes, powders, and mixtures of sorbents and ashes. We have included selected data from prior quarterly reports in this report for the sake of completeness, and for comparisons with newly-acquired data. In several places in this report samples are referred to by their identification (SID) numbers. Table I provides a brief description of all the samples we have used in this project along with their SID numbers. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and surface chemistry. Our recent laboratory efforts were primarily directed toward the determination of the effects of adsorbed water on the tensile and cohesive strengths of powders, the development of apparatus for SO{sub 3} and organosiloxane conditioning, and the conditioning of powders and ashes with organosiloxane.

  11. Fundamental mechanisms in flue gas conditioning. Quarterly report, July 1992--September 1993

    SciTech Connect (OSTI)

    Snyder, T.R.

    1993-10-26

    As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and surface chemistry. Our recent laboratory efforts were directed primarily toward the determination of the effects of adsorbed water on the tensile and cohesive strengths of powders, and the conditioning of powders and ashes with SO{sub 3} and organosiloxane. Details of these conditioning methods are discussed under section 3.5.

  12. Fundamental mechanisms in flue gas conditioning. Quarterly report, April 1992--June 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.

    1992-07-27

    SEM pictures of the three mixtures of sorbent and ash from the DITF and the base line ESP hopper ash from Muskingum are shown in Figures 1 through 4. The effects of sorbent addition on particle morphology are evident in Figures 2 through 4 by the presence of irregularly shaped particles and deposits on the surfaces of the spherical fly ash particles. In contrast, the base Ene ash particles have the characteristic relatively smooth, spherical morphology normally associated with pulverized-coal (PC) fly ashes. Resistivity determinations made on these four ashes in ascending and descending temperature modes. These data are shown in Figures 5 and 6. Sorbent injection processes performed at the DITF lowered the duct temperature to around 165{degrees}F from about 350{degrees}F for base line operation. Consequently, during collection in the ESP, the particulate matter from the sorbent injection processes had a significantly lower resitivity (approximately 4 {times} 10{sup 7} {Omega}-cm) than the base line ash (approximately 3 {times} 10{sup 11} {Omega}-cm at 350{degrees}F). Specific surface areas and true particle densities have been measured for the four samples obtained from the DOE/PETC Duct Injection Test Facility. These data are summarized in Table 4. The primary difference indicated by these initial analyses of these four samples is the significant increase in specific surface area due to sorbent addition. The specific surface areas of the three sorbent and ash mixtures from the DITF are quite similar.

  13. Fundamental mechanisms in flue gas conditioning. Quarterly report, January 1993--March 1993

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.

    1993-04-20

    Our recent laboratory efforts were primarily directed toward the determination of the effects of adsorbed water on the tensile strength of powders and the development of apparatus for Experiment 3.5. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show that, for many of the samples we have analyzed, a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. Under Experiment 3.5, which began during this last quarter, we have been developing a system capable of conditioning selected samples with (NH{sub 4}){sub 2}SO{sub 4}, NH{sub 4}HSO{sub 4}CaCl{sub 2}, organosiloxane, and SO{sub 3}.

  14. Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports fromSheetsCascadia AnalysisCatalysis and

  15. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street Lighting Host Site: City ofNovel CO 2

  16. DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report: Achievements ofCOMPOSITION OF VAPORSSeries)Supported Researcher Is

  17. Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecovery Act Recovery ActARM Overview ToFuelSign up to be

  18. Flue gas cleanup using the Moving-Bed Copper Oxide Process (Journal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) |production atmeasurementComparison StudyAdvancedArticle) | SciTech

  19. pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m m m port m fm f m Tomega( ( ( ( ( ( (

  20. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    SciTech Connect (OSTI)

    Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

    2014-11-01

    Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

  1. Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions

    SciTech Connect (OSTI)

    Lee, Joo-Youp

    2013-09-30

    A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high pH and temperatures.

  2. Cement kiln flue dust as a source of lime and potassium in four East Texas soils 

    E-Print Network [OSTI]

    Poole, Warren David

    1975-01-01

    (18) a 5. 3 (84) a 4. 8 (76) a 4. 2 (66) a 3. 8 (61) a 5. 2 (82) a 4. 1 (64) a 5. 0 (80) a *Duncan's Multiple Range Test. ? = . 05. Differences in yield due to rate of applied lime material followed by the same letter are not significantly...CEMENT KILN FLUE DUST AS A SOURCE OF LIME AND POTASSIUM IN FOUR EAST TEXAS SOILS A Thesis by WARREN DAVID POOLE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER...

  3. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  4. CO.sub.2 separation from low-temperature flue gases

    DOE Patents [OSTI]

    Dilmore, Robert (Irwin, PA); Allen, Douglas (Salem, MA); Soong, Yee (Monroeville, PA); Hedges, Sheila (Bethel Park, PA)

    2010-11-30

    Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

  5. Gas Separations using Ceramic Membranes

    SciTech Connect (OSTI)

    Paul KT Liu

    2005-01-13

    This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

  6. Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility

    SciTech Connect (OSTI)

    Metz, Paul; Bolz, Patricia

    2013-03-25

    With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

  7. Corrosion in gas conditioning plants - An overview

    SciTech Connect (OSTI)

    Pearce, B.; Dupart, M.

    1987-01-01

    Since the early 1800's, fuel gases of various sorts (acetylene, blast furnace gas, flue water gas, carbureted water gas, coal gas, coke oven gas and producer gas) were transmitted at low pressures in pipelines and were conditioned for contaminate removal. The removal of such contaminates as H/sub 2/S was usually accomplished by solid absorbents such as iron oxide, a process that is still in use today. The discovery in the late 20's of a regenerative process employing alkanolamines was instrumental in rapid increase in the use of natural gas in large volumes. Also at this time, the development of wide diameter pipelines that could handle 500-700 psi gas pressure provided the means of handling these large volumes of gas. The protection of the pipeline from corrosion depended upon contaminate removal of water, carbon dioxide and hydrogen sulfide. In the process of contaminant removal, the process equipment suffered severe corrosion damage. Corrosion test methods and inhibitors were applied to those early processes and have advanced from weep holes and coupons to the present way of electronic and physical test methods. The trend is away from the primary amine at either low strength or inhibited at high concentration to less corrosive, ''tailor-made'' solvents that can be designed or formulated to perform a given task at acceptable corrosion rates and at much lower energy levels.

  8. Promising Technology: Condensing Gas Boilers

    Broader source: Energy.gov [DOE]

    Condensing boilers achieve higher efficiencies than conventional boilers by capturing the latent heat from water vapor contained in the flue gases.

  9. Integrated test of the TRD Gas System electronics

    E-Print Network [OSTI]

    Roma "La Sapienza", Universitŕ di

    Integrated test of the TRD Gas System electronics A. Bartoloni, B. Borgia, F. Bucci, F.R. Spada: the August '04 tests 2 3.1 Test setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 3.2 Low level tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 3

  10. Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center for GasPhysics PhysicsFlue

  11. Large-Scale Optimization of Complex Separator and Reactor Networks

    E-Print Network [OSTI]

    Ghougassian, Paul Gougas

    2013-01-01

    Capturing from Power Plant Flue Gases: Energetic ComparisonCapturing from Power Plant Flue Gases: Energetic Comparisondesign, the flue gas leaving the power plant’s boiler is

  12. Gas Source Declaration with a Mobile Robot Achim Lilienthal, Holger Ulmer, Holger Frohlich, Andreas Stutzle, Felix Werner, Andreas Zell

    E-Print Network [OSTI]

    Zell, Andreas

    Gas Source Declaration with a Mobile Robot Achim Lilienthal, Holger Ulmer, Holger Fr¨ubingen, Germany Abstract-- As a sub-task of the general gas source localisation problem, gas source declaration character of gas transport in a natural indoor environment, it is not sufficient to search for instantaneous

  13. A Simulation Study of Diffusion in Microporous Materials

    E-Print Network [OSTI]

    Abouelnasr, Mahmoud Kamal Forrest

    2013-01-01

    separation. stream Coal power plant flue gas Natural Gas AirCO 2 from a coal power plant flue gas stream have recentlyThe flue gas of a hydrocarbon-combustion power plant is

  14. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  15. Novel Use of P- and S-Wave Seismic Attenuation for Deep Natural Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech Connect Nanomechanical switchFlue Gas Streams (Journal Article) |

  16. Novel Use of P- and S-Wave Seismic Attenuation for Deep Natural Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech Connect Nanomechanical switchFlue Gas Streams (Journal Article) |Exploration and

  17. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  18. The structural design of air and gas ducts for power stations and industrial boiler applications

    SciTech Connect (OSTI)

    Schneider, R.L.

    1996-10-01

    The purpose of this paper is to discuss the new American Society of Civil Engineers (ASCE) book entitled, The Structural Design of Air and Gas Ducts for Power Stations and Industrial Boiler Applications. This 312 page book was published by the ASCE in August of 1995. This ASCE publication was created to assist structural engineers in performing the structural analysis and design of air and flue-gas ducts. The structural behavior of steel ductwork can be difficult to understand for structural engineers inexperienced in ductwork analysis and design. Because of this needed expertise, the ASCE committee that created this document highly recommends that the structural analysis and design of ducts be performed by qualified structural engineers, not be technicians, designers or drafters. There is a history within the power industry of failures and major degradation of flue-gas ductwork. There are many reasons for these failures or degradation, but in many cases, the problems may have been voided by a better initial design. This book attempts to help the structural engineer with this task. This book is not intended to be used to size or configure ductwork for flow and pressure drop considerations. But it does recommend that the ductwork system arrangement consider the structural supports and the structural behavior of the duct system.

  19. Environ. Scl. Technol. 1994, 28, 277-283 Effects of Salts on Preparation and Use of Calcium Silicates for Flue Gas

    E-Print Network [OSTI]

    Rochelle, Gary T.

    areacalciumsilicatehydratesthat arehighly reactive with SO2 can be made by slurrying fly ash and lime in water at elevated

  20. Solid-Fueled Pressurized Chemical Looping with Flue-Gas Turbine Combined Cycle for Improved Plant Efficiency and CO{sub 2} Capture

    SciTech Connect (OSTI)

    Liu, Kunlei; Chen, Liangyong; Zhang, Yi; Richburg, Lisa; Simpson, James; White, Jay; Rossi, Gianalfredo

    2013-12-31

    The purpose of this document is to report the final result of techno-economic analysis for the proposed 550MWe integrated pressurized chemical looping combustion combined cycle process. An Aspen Plus based model is delivered in this report along with the results from three sensitivity scenarios including the operating pressure, excess air ratio and oxygen carrier performance. A process flow diagram and detailed stream table for the base case are also provided with the overall plant energy balance, carbon balance, sulfur balance and water balance. The approach to the process and key component simulation are explained. The economic analysis (OPEX and CAPX) on four study cases via DOE NETL Reference Case 12 are presented and explained.

  1. Reduction of air in-leakage and flue gas by-passing in the penthouse of Duke Power-Marshall Unit No. 4

    SciTech Connect (OSTI)

    Campbell, R.; Rush, T.

    1995-12-31

    After a year of operation, the penthouse was inspected and found to be {open_quotes}lightly dusted{close_quotes} with barely sufficient accumulation to show footprints. This is contrasted with previous five foot deep ash dunes. The savings in maintenance repairs are estimated at $65,000 for vacuuming that was not required, and $80,000 in maintenance personnel weld repairs. The history of repairs was such that vacuuming and weld repair costs were predictable, and before the IOSMEMBRANE{reg_sign} installation, always expected as recurring maintenance costs. The heat rate improvement of reducing air in-leakage is well known, and significant. The principal quantified savings are in reduced maintenance costs, more expedient repairs (reduced cool down time for repairs in the penthouse), and safety. The heat rate improvements, though not quantified yet, are expected to be significant. The success of the ISOMEMBRANE{reg_sign} on Unit No. 4 has resulted in similar plans for Unit No. 3 and other units in the Duke Power system.

  2. Separation of flue-gas scrubber sludge into marketable products. Third quarterly technical progress report, March 1, 1994--May 31, 1994

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.; Shoop, K.

    1994-06-01

    Column flotation represents a significant improvement over conventional flotation for many applications. This improvement consists of increased selectivity between hydrophobic and hydrophilic particles, which allows the column to produce higher-purity products. A schematic of the column used is given in Figure 1. The basic procedure for the flotation column experiments was as follows: 500 grams of the sludge from Plant A (prepared as described in the Second Quarterly Report) was suspended at 40% solids in distilled water, to produce 1600 ml of slurry. Reagents were added, and the slurry was agitated vigorously for 1 minute. Frother was added to all of the water to be added to the column, at a rate of 0.03 grams/liter (approximately 0.4 kilograms per metric ton, Kg/mt). The frother used was Dowfroth 200 (a mixture of polypropylene glycol methyl ethers, with a mean molecular weight of 200). The column was started, all of the water flowrates were set as desired, and the drain valve was closed. As soon as the water level had reached the base of the feed inlet tube (approximately 1 minute after closing the drain valve), the 1600 ml feed slurry was added over a 15 second interval. This allowed the feed to be added to the column with a minimum of disturbance to the froth layer, and without causing either surging of the pulp level or large losses to the sinks product. Flotation was carried out for 9 minutes after closing the drain valve. Froth and sinks products were collected, filtered, dried at 45{degrees}C, weighed, and analyzed by thermogravimetic analysis. It is readily seen that, when no collector is added, the column produces a product that is markedly higher purity than that produced by conventional flotation. The addition of oleic acid collector to the column feed is not able to produce any further improvement in product quality, and only results in a loss of product recovery.

  3. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Environmental information volume

    SciTech Connect (OSTI)

    1998-12-31

    The Clean Coal Technology (CCT) Demonstration Program is a $5 billion technology demonstration program that was legislated by Congress to be funded jointly by the federal government and industrial or other sector participants. The goal of the Program is to make available to the U.S. energy marketplace a number of advanced, more efficient, reliable, and environmentally responsive coal utilization and environmental control technologies. These technologies are intended to reduce or eliminate the economic and environmental impediments that limit the full consideration of coal as a future energy resource. Over the next decade, the Program will advance the technical, environmental and economic performance of these advanced technologies to the point where the private sector will be able to introduce them into the commercial marketplace. Each of these demonstrations is in a scale large enough to generate sufficient design, construction and operation data for the private sector to judge the technology`s commercial potential and to make informed confident decisions on its commercial readiness. The strategy being implemented to achieve the goal of the CCT Demonstration Program is to conduct a multi-phase effort consisting of at least five separate solicitations for projects, each with individual objectives that, when integrated, will make technology options available on a schedule consistent with the demands of the energy market and responsive to the relevant environmental considerations. This paper describes a commercial demonstration project to be fielded in support of this program.

  4. Enhancing the use of coals by gas reburning-sorbent injection: Volume 3 -- Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x} and SO{sub 2} from a wall fired unit at Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the as found baseline of 0.98 lb/MBtu and to reduce emissions of SO{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an SO{sub 2} limit of 1.8 lb/MBtu, the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with SO{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The system was designed to inject sorbent at a rate corresponding to a calcium (sorbent) to sulfur (coal) molar ratio of 2.0. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  5. Gas Mask 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    The gas industry fostered more efficient energy utilization long before the idea of energy conservation became fashionable. It became apparent in the late '60's that misguided Federal Legislation was discouraging necessary search for new gas...

  6. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  7. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (SOsub 2) and nitric oxides (NOsub x) from flue gas produced by the combustion of coal for electric power generation. In general, dry, regenerable flue gas cleanup...

  9. REACTIONS OF SULFITE AND NITRITE IONS IN AQUEOUS SOLUTIONS

    E-Print Network [OSTI]

    Chang, S.G.

    2013-01-01

    technology for power plant flue gas desulfurization (FGD).so 2 so 2 Because power plant flue gas contains hundreds of

  10. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01

    low-temperature, catalytic dioxin formation DRAFT policiestime for the flue gas at the dioxin formation temperature700 -200 C) increases dioxin formation. Flue gas cooling

  11. $P-V$ criticality of AdS black hole in $f(R)$ gravity

    E-Print Network [OSTI]

    Songbai Chen; Xiaofang Liu; Changqing Liu

    2013-05-31

    We study thermodynamics of a charged AdS black hole in the special $f(R)$ correction with the constant Ricci scalar curvature. Our results show that the the $f(R)$ correction influences the Gibbs free energy and the phase transition of system. The ratio $\\rho_c$ occurred at the critical point increases monotonically with the derivative term $f'(R_0)$. We also disclose that the critical exponents are the same as those of the liquid-gas phase transition in the Van der Waals model, which does not depend on the $f(R)$ correction considered here.

  12. Plant-Wide NOx Reduction Strategies 

    E-Print Network [OSTI]

    Baukal, C.; Waibel, D.; Webster, T.

    2006-01-01

    flue gases into the flame is a proven technique for reducing NOx emissions (see Figure 6). There are two common ways to recirculate combustion exhaust products through a flame – flue gas recirculation (FGR) and internal flue gas recirculation... reduces NOx. Garg (1992) estimated NOx reductions of up to 50% using flue gas recirculation [7]. combustor burner fuel recirculated combustion products air ID fan to atmosphere Figure 7. Schematic of flue gas recirculation [8]. Internal flue gas...

  13. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  14. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  15. Oil and Gas Science and Technology, 2009, 64(5), 629-636, doi: 10.2516/ogst/2009042 DDDiiissscccuuussssssiiiooonnn ooofff aaagggggglllooommmeeerrraaatttiiiooonnn mmmeeeccchhhaaannniiisssmmmsss bbbeeetttwwweeeeeennn hhhyyydddrrraaattteee

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oil and Gas Science and Technology, 2009, 64(5), 629-636, doi: 10.2516/ogst/2009042 1. KKeeyywwoorrddss:: gas hydrate formation ; water/oil emulsions ; hydrate slurry ; agglomeration ; Population@emse.fr hal-00480033,version1-3May2010 Author manuscript, published in "Oil & Gas Science and Technology 64, 5

  16. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  17. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  18. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  19. Gas hydrates

    SciTech Connect (OSTI)

    Not Available

    1985-04-01

    There is a definite need for the US government to provide leadership for research in gas hydrates and to coordinate its activities with academia, industry, private groups, federal agencies, and their foreign counterparts. In response to this need, the DOE Morgantown Energy Technology Center implemented a gas hydrates R and D program. Understanding the resource will be achieved through: assessment of current technology; characterization of gas hydrate geology and reservoir engineering; and development of diagnostic tools and methods. Research to date has focused on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for future detailed investigation. Initial research activities involved the development of the Geologic Analysis System (GAS); which will provide, through approximately 30 software packages, the capability to manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. Preliminary mapping of hydrate prospects for the Alaskan North Slope is underway. Geological research includes physical system characterization which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran, consolidated rock cores, frost base mixtures, water/ice base mixtures, and water base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by METC. More recently, a natural hydrate sample from the Gulf of Mexico was also acquired and testing of this sample is currently underway. In addition to the development of GAS, modeling and systems analysis work focused on the development of conceptual gas hydrate production models. 16 figs., 6 tabs.

  20. Managing Your Energy: An ENERGY STAR(R) Guide for Identifying Energy Savings in Manufacturing Plants

    E-Print Network [OSTI]

    Worrell, Ernst

    2010-01-01

    heat recovery Reduction of flue gas quantities Condensate return Reduction of excess air Blowdown steam

  1. Productivity benefits of industrial energy efficiency measures

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    maintenance Energy monitoring and management systems Variable speed drives for flue gas control, pumps,

  2. Partnerships for Clean Development and Climate: Business and Technology Cooperation Benefits

    E-Print Network [OSTI]

    Sathaye, Jayant A.; Price, Lynn; Kumar, Satish; de la Rue du Can, Stephane; Warfield, Corina; Padmanabhan, S.

    2006-01-01

    maintenance Energy monitoring and management systems Variable speed drives for flue gas control, pumps,

  3. Incorporating the productivity benefits into the assessment of cost effective energy savings potential using conservation supply curves

    E-Print Network [OSTI]

    Laitner, John A.; Ruth, Michael; Worrell, Ernst

    2001-01-01

    maintenance Energy monitoring and management systems Variable speed drives for flue gas control, pumps,

  4. Productivity benefits of industrial energy efficiency measures

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    systems Variable speed drives for flue gas control, pumps, and fans (integrated only) Cogeneration (

  5. Incorporating the productivity benefits into the assessment of cost effective energy savings potential using conservation supply curves

    E-Print Network [OSTI]

    Laitner, John A.; Ruth, Michael; Worrell, Ernst

    2001-01-01

    systems Variable speed drives for flue gas control, pumps, and fans (integrated only) Cogeneration (

  6. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    plants Variable speed drives for flue gas control, pumps, fans in integrated steel mills Cogeneration

  7. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    COMPOSITION OF FLUE GAS STREAMS AND CO 2 SEPARATION 43 3.3. NATURALcompositions by volume of flue (and fuel) gases from selected coal, fuel oil, natural

  8. Gas Drill 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    .C. Wang, B.T. Lovell, Program, Summary Report TE4258-5-84, J. McCrank, "Topping of a Combined Gas DOE/ET/11292, Oct. 1984. and Steam Turbine Powerplant using a TAM Combustor," Thermo Electron [4J Final Report: "Thermionic Energy Report No. 4258... for each Btu fired in the burners has been cal culated with the process gas temperature as a variable. It was shown [2 ] that the maximum thermionic power produced is 18 kW per million Btu fired per hour. All com bustors are similar but progressively...

  9. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-09-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

  10. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-06-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

  11. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  12. Enhancing the use of coals by gas reburning-sorbent injection. Volume 3, Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company

    SciTech Connect (OSTI)

    NONE

    1994-10-01

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x}, and SO{sub 2} from a wall fired unit. A GR-SI system was designed for Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The unit is rated at 117 MW(e) (net) and is front wall fired with a pulverized bituminous coal blend. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the ``as found`` baseline of 0.98 lb/MBtu (420 mg/MJ), and to reduce emissions of S0{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an S0{sub 2} limit Of 1.8 lb/MBtu (770 mg/MJ), the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. The design natural gas input corresponds to 18% of the total heat input. Burnout (overfire) air is injected at a higher elevation to burn out fuel combustible matter at a normal excess air level of 18%. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with S0{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  13. A Planar Anode -Supported Solid Oxide Fuel Cell Model with Internal Reforming of Natural Gas

    E-Print Network [OSTI]

    Boyer, Edmond

    1 A Planar Anode - Supported Solid Oxide Fuel Cell Model with Internal Reforming of Natural Gas.brault@univ-orleans.fr Abstract Solid Oxide Fuel Cells (SOFCs) are of great interest due to their high energy efficiency, low, a mathematical model of a co - flow planar anode - supported solid oxide fuel cell with internal reforming

  14. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  15. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  16. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  17. Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,Energy Office

  18. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Li, Mo

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  19. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  20. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    cushion gas for natural gas storage, Energy and Fuels, 17(RECOVERY AND NATURAL GAS STORAGE Curtis M. Oldenburg Eartheffective cushion gas for gas storage reservoirs. Thus at

  1. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  2. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  3. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  4. Pennsylvania's Natural Gas Future

    E-Print Network [OSTI]

    Lee, Dongwon

    1 Pennsylvania's Natural Gas Future Penn State Natural Gas Utilization Workshop Bradley Hall sales to commercial and industrial customers ­ Natural gas, power, oil · Power generation ­ FossilMMBtuEquivalent Wellhead Gas Price, $/MMBtu Monthly US Spot Oil Price, $/MMBtu* U.S. Crude Oil vs. Natural Gas Prices, 2005

  5. Sorption Mechanisms for Mercury Capture in Warm Post-Gasification Gas Clean-Up Systems

    SciTech Connect (OSTI)

    Jost Wendt; Sung Jun Lee; Paul Blowers

    2008-09-30

    The research was directed towards a sorbent injection/particle removal process where a sorbent may be injected upstream of the warm gas cleanup system to scavenge Hg and other trace metals, and removed (with the metals) within the warm gas cleanup process. The specific objectives of this project were to understand and quantify, through fundamentally based models, mechanisms of interaction between mercury vapor compounds and novel paper waste derived (kaolinite + calcium based) sorbents (currently marketed under the trade name MinPlus). The portion of the research described first is the experimental portion, in which sorbent effectiveness to scavenge metallic mercury (Hg{sup 0}) at high temperatures (>600 C) is determined as a function of temperature, sorbent loading, gas composition, and other important parameters. Levels of Hg{sup 0} investigated were in an industrially relevant range ({approx} 25 {micro}g/m{sup 3}) although contaminants were contained in synthetic gases and not in actual flue gases. A later section of this report contains the results of the complementary computational results.

  6. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  7. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  8. Future of Natural Gas

    Energy Savers [EERE]

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts *...

  9. Gas Kick Mechanistic Model 

    E-Print Network [OSTI]

    Zubairy, Raheel

    2014-04-18

    Gas kicks occur during drilling when the formation pressure is greater than the wellbore pressure causing influx of gas into the wellbore. Uncontrolled gas kicks could result in blowout of the rig causing major financial ...

  10. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  11. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  12. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  13. Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. Iron and Steel sector

    E-Print Network [OSTI]

    Worrell, Ernst; Martin, N.; Price, L.

    1999-01-01

    cogeneration units are gas turbine based, using either a simple cycle system (system Cogeneration Variable speed drive: flue gas control,systems Variable speed drives for flue gas control, pumps, and fans Cogeneration

  14. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    Hydrogen production from natural gas, sequestration ofunderground storage of natural gas, Jour. Petrol. Tech. 943,dioxide as cushion gas for natural gas storage, Energy and

  15. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  16. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

    2001-01-01

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  17. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Strathclyde, University of

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  18. Technology Solutions Case Study: Improving the Field Performance of Natural Gas Furnaces

    SciTech Connect (OSTI)

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  19. Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    Rothgeb, S.; Brand, L.

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  20. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  1. WEBSITE: https://www.adum.fr/as/ed/GEET Director: Pr. Maria David

    E-Print Network [OSTI]

    Bordenave, Charles

    .david@laplace.univ-tlse.fr SCIENTIFIC DOMAINS New Power electron devices, integration, modeling and processing Materials for energy electromagnetic issues Sensors and Microsystems for gas and live species detection Dielectric materials, processing-and reliability Materials and plasma applications, modeling and processing Medical radiophysics

  2. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    State, 1980-1998 PDF 12 Supplemental Gas Supplies by State, 1980-1998 PDF 13 Natural Gas Production, Transmission, and Consumption by State, 1967-1998 PDF 14 Consumption of...

  3. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    State, 1980-1997 PDF 12 Supplemental Gas Supplies by State, 1980-1997 PDF 13 Natural Gas Production, Transmission, and Consumption by State, 1967-1997 PDF 14 Consumption of...

  4. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    State, 1980-1996 PDF 12 Supplemental Gas Supplies by State, 1980-1996 PDF 13 Natural Gas Production, Transmission, and Consumption by State, 1967-1996 PDF 14 Consumption of...

  5. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  6. EIA - Natural Gas Publications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    these data from 2005 to 2009 are presented for each State. (12282010) U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves: 2009 National and State...

  7. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

    1992-01-01

    A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

  8. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, J.F.

    1992-02-25

    A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

  9. Natural gas annual 1996

    SciTech Connect (OSTI)

    1997-09-01

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  10. Natural gas annual 1995

    SciTech Connect (OSTI)

    1996-11-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  11. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M. (Peralta, NM)

    2012-07-31

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  12. Natural gas annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-11-17

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

  13. Natural gas industry directory

    SciTech Connect (OSTI)

    1999-11-01

    This directory has information on the following: associations and organizations; exploration and production; gas compression; gas processors; gathering and transmission companies; liquefied natural gas; local distribution companies; marketing firms; regulatory agencies; service companies; suppliers and manufacturers; and regional buyer`s guide.

  14. Gas Chromatography -Mass Spectrometry

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    GCMS - 1 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS OF ETHANOL AND BENZENE IN GASOLINE Last updated: June 17, 2014 #12;GCMS - 2 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS). The goal of this experiment is to separate the components in a sample of gasoline using Gas Chromatography

  15. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, C.A.; Rurbage, C.H.

    1982-03-17

    The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  16. Static gas expansion cooler

    DOE Patents [OSTI]

    Guzek, J.C.; Lujan, R.A.

    1984-01-01

    Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

  17. Renewable Natural Gas (Biomethane)

    E-Print Network [OSTI]

    California at Davis, University of

    to Landfill Owner $6.18 Total Cost Per MMBtu #12;Index Price of Natural Gas NYMEX Natural Gas Futures PricesRenewable Natural Gas (Biomethane) #12;Critical Barriers Impeding RNG as a Transportation Fuel-developer of largest RNG production project in U.S. at McCommas Bluff Landfill in Dallas, Texas · Chairman and co

  18. Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. Iron and Steel sector

    E-Print Network [OSTI]

    Worrell, Ernst; Martin, N.; Price, L.

    1999-01-01

    maintenance Energy monitoring and management system Cogeneration Variable speed drive: flue gas control, pumps,maintenance Energy monitoring and management systems Variable speed drives for flue gas control, pumps,

  19. Energy Efficiency Improvement and Cost Saving Oportunities for the Concrete Industry

    E-Print Network [OSTI]

    Kermeli, Katerina

    2013-01-01

    maintenance Flue gas heat recovery Condensate return BlowEnercase, Condensate and Flue Gas Heat Recovery. Canadianheat and reducing the need for fresh treated feed water. The recovery of condensate

  20. Demonstration of Heat Recovery in the Meat Industry 

    E-Print Network [OSTI]

    Molczan, T. J.; Scriven, A. P.; Magro, J.

    1984-01-01

    Canada Packers Inc. has successfully demonstrated condensing flue gas heat recovery and rendering vapour heat recovery under the Federal/Provincial Conservation and Renewable Energy Demonstration Agreement. The condensing flue gas heat recovery...

  1. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01

    Summary of transportation greenhouse gas mitigation optionsof alternative fuels. Low greenhouse gas fuels Mixing ofMAC) refrigerant replacement. Greenhouse gas budgets for

  2. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  3. HYBRID SELECTIVE NON-CATALYTIC REDUCTION (SNCR)/SELECTIVE CATALYTIC REDUCTION (SCR) DEMONSTRATION FOR THE REMOVAL OF NOx FROM BOILER FLUE GASES

    SciTech Connect (OSTI)

    Jerry B. Urbas

    1999-05-01

    The U. S. Department of Energy (DOE), Electric Power Research Institute (EPRI), Pennsylvania Electric Energy Research Council, (PEERC), New York State Electric and Gas and GPU Generation, Inc. jointly funded a demonstration to determine the capabilities for Hybrid SNCR/SCR (Selective Non-Catalytic Reduction/Selective Catalytic Reduction) technology. The demonstration site was GPU Generation's Seward Unit No.5 (147MW) located in Seward Pennsylvania. The demonstration began in October of 1997 and ended in December 1998. DOE funding was provided through Grant No. DE-FG22-96PC96256 with T. J. Feeley as the Project Manager. EPRI funding was provided through agreements TC4599-001-26999 and TC4599-002-26999 with E. Hughes as the Project Manager. This project demonstrated the operation of the Hybrid SNCR/SCR NO{sub x} control process on a full-scale coal fired utility boiler. The hybrid technology was expected to provide a cost-effective method of reducing NO{sub x} while balancing capital and operation costs. An existing urea based SNCR system was modified with an expanded-duct catalyst to provide increased NO{sub x} reduction efficiency from the SNCR while producing increased ammonia slip levels to the catalyst. The catalyst was sized to reduce the ammonia slip to the air heaters to less than 2 ppm while providing equivalent NO{sub x} reductions. The project goals were to demonstrate hybrid technology is capable of achieving at least a 55% reduction in NO{sub x} emissions while maintaining less than 2ppm ammonia slip to the air heaters, maintain flyash marketability, verify the cost benefit and applicability of Hybrid post combustion technology, and reduce forced outages due to ammonium bisulfate (ABS) fouling of the air heaters. Early system limitations, due to gas temperature stratification, restricted the Hybrid NO{sub x} reduction capabilities to 48% with an ammonia slip of 6.1 mg/Nm{sup 3} (8 ppm) at the catalyst inlet. After resolving the stratification problem, the catalyst did not have sufficient activity in order to continue the planned test program. Arsenic poisoning was found to be the cause of premature catalyst deactivation.

  4. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  5. Higher order corrections of the extended Chaplygin gas cosmology with varying $G$ and $?$

    E-Print Network [OSTI]

    E. O. Kahya; M. Khurshudyan; B. Pourhassan; R. Myrzakulov; A. Pasqua

    2014-12-11

    In this paper, we study two different models of dark energy based on Chaplygin gas equation of state. The first model is the variable modified Chaplygin gas while the second one is the extended Chaplygin gas. Both models are considered in the framework of higher order $f(R)$ modified gravity. We also consider the case of time varying gravitational constant $G$ and $\\Lambda$ for both models. We investigate some cosmological parameters such as the Hubble, the deceleration and the equation of state parameters. Then we showed that the model that we considered, extended Chaplygin gas with time-dependent $G$ and $\\Lambda$, is consistent with the observational data. Finally we conclude with the discussion of cosmological perturbations of our model.

  6. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1984-06-05

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  7. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1985-12-31

    An apparatus is disclosed for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area. 3 figs.

  8. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, Daniel (Los Alamos, NM)

    1985-01-01

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  9. Thermodynamics of Chaplygin gas

    E-Print Network [OSTI]

    Yun Soo Myung

    2011-05-11

    We clarify thermodynamics of the Chaplygin gas by introducing the integrability condition. All thermal quantities are derived as functions of either volume or temperature. Importantly, we find a new general equation of state, describing the Chaplygin gas completely. We confirm that the Chaplygin gas could show a unified picture of dark matter and energy which cools down through the universe expansion without any critical point (phase transition).

  10. Pulsed gas laser

    DOE Patents [OSTI]

    Anderson, Louis W. (Madison, WI); Fitzsimmons, William A. (Madison, WI)

    1978-01-01

    A pulsed gas laser is constituted by Blumlein circuits wherein space metal plates function both as capacitors and transmission lines coupling high frequency oscillations to a gas filled laser tube. The tube itself is formed by spaced metal side walls which function as connections to the electrodes to provide for a high frequency, high voltage discharge in the tube to cause the gas to lase. Also shown is a spark gap switch having structural features permitting a long life.

  11. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, Charles A. (Oak Ridge, TN); Burbage, Charles H. (Oak Ridge, TN)

    1984-01-01

    The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  12. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    gas reservoirs for carbon sequestration and enhanced gasproduction and carbon sequestration, Society of Petroleumfeasibiilty of carbon sequestration with enhanced gas

  13. Compressed Gas Cylinder Policy

    E-Print Network [OSTI]

    of pressure from a compressed gas cylinder and pose a serious threat to life and property. To minimize risk cylinders to and from a designated work are

  14. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  15. String Gas Baryogenesis

    E-Print Network [OSTI]

    G. L. Alberghi

    2010-02-19

    We describe a possible realization of the spontaneous baryogenesis mechanism in the context of extra-dimensional string cosmology and specifically in the string gas scenario.

  16. Natural gas annual 1997

    SciTech Connect (OSTI)

    1998-10-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  17. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  18. Home Safety: Radon Gas 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Denny, Monica L.

    1999-11-12

    Every home should be tested for radon, an invisible, odorless, radioactive gas that occurs naturally. This publication explains the health risks, testing methods, and mitigation and reduction techniques....

  19. Shale Gas Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Production (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012...

  20. This is an author-deposited version published in: http://oatao.univ-toulouse.fr/ Eprints ID: 6175

    E-Print Network [OSTI]

    Mailhes, Corinne

    -oatao@listes.diff.inp-toulouse.fr #12;Biomass steam gasification in fluidized bed of inert or catalytic particles: Comparison between been showed to substitution fuels synthesis from biomass steam gasification, such as methanation and "Biomass To Fischer­Tropsch Liquids". For those processes, the gas produced by gasification, called syngas

  1. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, John E. (Alamo, CA)

    1984-01-01

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  2. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    , oil and gas, and geothermal activities and accomplishments in Nevada: production statistics Products 23. Sloan dolomite quarry 24. Weiser gypsum quarry Oil Fields 1. Blackburn field 2. North WillowMetals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada

  3. Integrated Operation of INL HYTEST System and High-Temperature Steam Electrolysis for Synthetic Natural Gas Production

    SciTech Connect (OSTI)

    Carl Marcel Stoots; Lee Shunn; James O'Brien

    2010-06-01

    The primary feedstock for synthetic fuel production is syngas, a mixture of carbon monoxide and hydrogen. Current hydrogen production technologies rely upon fossil fuels and produce significant quantities of greenhouse gases as a byproduct. This is not a sustainable means of satisfying future hydrogen demands, given the current projections for conventional world oil production and future targets for carbon emissions. For the past six years, the Idaho National Laboratory has been investigating the use of high-temperature steam electrolysis (HTSE) to produce the hydrogen feedstock required for synthetic fuel production. High-temperature electrolysis water-splitting technology, combined with non-carbon-emitting energy sources, can provide a sustainable, environmentally-friendly means of large-scale hydrogen production. Additionally, laboratory facilities are being developed at the INL for testing hybrid energy systems composed of several tightly-coupled chemical processes (HYTEST program). The first such test involved the coupling of HTSE, CO2 separation membrane, reverse shift reaction, and methanation reaction to demonstrate synthetic natural gas production from a feedstock of water and either CO or a simulated flue gas containing CO2. This paper will introduce the initial HTSE and HYTEST testing facilities, overall coupling of the technologies, testing results, and future plans.

  4. A TECHNICAL, ECONOMIC AND ENVIRONMENTAL ASSESSMENT OF AMINE-BASED CO2 CAPTURE TECHNOLOGY FOR POWER PLANT GREENHOUSE GAS CONTROL

    SciTech Connect (OSTI)

    Edward S. Rubin; Anand B. Rao

    2002-10-01

    Capture and sequestration of CO{sub 2} from fossil fuel power plants is gaining widespread interest as a potential method of controlling greenhouse gas emissions. Performance and cost models of an amine (MEA)-based CO{sub 2} absorption system for post-combustion flue gas applications have been developed, and integrated with an existing power plant modeling framework that includes multi-pollutant control technologies for other regulated emissions. The integrated model has been applied to study the feasibility and cost of carbon capture and sequestration at both new and existing coal-burning power plants. The cost of carbon avoidance was shown to depend strongly on assumptions about the reference plant design, details of the CO{sub 2} capture system design, interactions with other pollution control systems, and method of CO{sub 2} storage. The CO{sub 2} avoidance cost for retrofit systems was found to be generally higher than for new plants, mainly because of the higher energy penalty resulting from less efficient heat integration, as well as site-specific difficulties typically encountered in retrofit applications. For all cases, a small reduction in CO{sub 2} capture cost was afforded by the SO{sub 2} emission trading credits generated by amine-based capture systems. Efforts are underway to model a broader suite of carbon capture and sequestration technologies for more comprehensive assessments in the context of multi-pollutant environmental management.

  5. GAS EXPLORATION Winter 2006 GasTIPS 5

    E-Print Network [OSTI]

    Rubin, Yoram

    GAS EXPLORATION Winter 2006 · GasTIPS 5 T he prediction of reservoir parameters such as gas or oil, but is particularly challenging in the case of gas exploration. Current seismic imaging technol- ogy cannot accurately discriminate between economic and non-eco- nomic concentrations of gas. This is primarily because

  6. Shale gas production: potential versus actual greenhouse gas emissions*

    E-Print Network [OSTI]

    Shale gas production: potential versus actual greenhouse gas emissions* Francis O Environ. Res. Lett. 7 (2012) 044030 (6pp) doi:10.1088/1748-9326/7/4/044030 Shale gas production: potential gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level

  7. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.; Hayden, M.; Radebaugh, R.; Wollan, J.

    1996-07-01

    This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop a natural-gas-powered natural-gas liquefier that has absolutely no moving parts and requires no electrical power. It should have high efficiency, remarkable reliability, and low cost. The thermoacoustic natural-gas liquefier (TANGL) is based on our recent invention of the first no-moving-parts cryogenic refrigerator. In short, our invention uses acoustic phenomena to produce refrigeration from heat, with no moving parts. The required apparatus comprises nothing more than heat exchangers and pipes, made of common materials, without exacting tolerances. Its initial experimental success in a small size lead us to propose a more ambitious application: large-energy liquefaction of natural gas, using combustion of natural gas as the energy source. TANGL was designed to be maintenance-free, inexpensive, portable, and environmentally benign.

  8. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  9. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  10. Natural Gas Prices Forecast Comparison--AEO vs. Natural Gas Markets

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle; Lekov, Alex; Dale, Larry

    2005-01-01

    Natural Gas Prices . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Natural Gas Prices . . . . . . . . . . . . . . . . . . . . . . . . . .versus AEO and Henry Hub Natural Gas Prices . . . . . .

  11. Shale gas production: potential versus actual greenhouse gas emissions

    E-Print Network [OSTI]

    O’Sullivan, Francis Martin

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  12. Baltimore Gas & Electric Company (Gas)- Residential Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    The Baltimore Gas & Electric Company (BGE) offers Natural Gas Connection program to residential customers to switch from electric to natural gas for heat. The program waives connection charge (...

  13. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    Gasoline and Diesel Fuel Update (EIA)

    with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural Gas Pipeline Transportation Corridors, 2008 U.S. Natural Gas Transporation Corridors out of Major...

  14. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  15. Gas only nozzle

    DOE Patents [OSTI]

    Bechtel, William Theodore (15 Olde Coach Rd., Scotia, NY 12302); Fitts, David Orus (286 Sweetman Rd., Ballston Spa, NY 12020); DeLeonardo, Guy Wayne (60 St. Stephens La., Glenville, NY 12302)

    2002-01-01

    A diffusion flame nozzle gas tip is provided to convert a dual fuel nozzle to a gas only nozzle. The nozzle tip diverts compressor discharge air from the passage feeding the diffusion nozzle air swirl vanes to a region vacated by removal of the dual fuel components, so that the diverted compressor discharge air can flow to and through effusion holes in the end cap plate of the nozzle tip. In a preferred embodiment, the nozzle gas tip defines a cavity for receiving the compressor discharge air from a peripheral passage of the nozzle for flow through the effusion openings defined in the end cap plate.

  16. Oregon Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+Elements) Gas and Gas4.00 4.92 1979-2010

  17. Oil and gas outlook

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural GasEIARegionalMethodologyNorth093 *Oil andOil and

  18. ,"Federal Offshore California Natural Gas Withdrawals from Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Federal Offshore California Natural Gas Withdrawals from Gas Wells (MMcf)",1,"Annual",2014 ,"Release...

  19. ,"New Mexico Natural Gas Gross Withdrawals from Gas Wells (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas Gross Withdrawals from Gas Wells (MMcf)",1,"Annual",2014 ,"Release...

  20. Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Using noble gas isotopes to develop a mechanistic understanding of shale gas relevance to the oil and gas industry: 10 weeks in Year 1 and 5 weeks each in Years 2 and 3. Instructors will be both from expert academics from across the CDT and also experienced oil and gas industry professionals

  1. What is shale gas? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    What is shale gas? What is shale gas? What is shale gas? More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary Natural Gas Study Guide -...

  2. EIA - Natural Gas Publications & Analysis

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Publications & Analysis Weekly Natural Gas Storage Report Estimates of natural gas in underground storage for the U.S. and three regions of the U.S. Natural Gas Weekly Update...

  3. The Gas/Electric Partnership 

    E-Print Network [OSTI]

    Schmeal, W. R.; Royall, D.; Wrenn, K. F. Jr.

    1997-01-01

    The electric and gas industries are each in the process of restructuring and "converging" toward one mission: providing energy. Use of natural gas in generating electric power and use of electricity in transporting natural gas will increase...

  4. Gas Water Heater Energy Losses

    E-Print Network [OSTI]

    Biermayer, Peter

    2012-01-01

    forty gallon residential gas-fired storage water heater wasthat could replace a gas-fired storage water heater with adefined a baseline gas-fired storage water heater that meets

  5. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  6. Natural Gas Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation title 805 promulgates the rules and regulations pertaining to natural gas production in Kentucky. In addition to KAR title 405, chapter 30, which pertains to any...

  7. Gas Separation Using Membranes 

    E-Print Network [OSTI]

    Koros, W. J.; Paul, D. R.

    1984-01-01

    Commercial membrane-based gas separator systems based upon high-flux, asymmetric polysulfone hollow fibers were first introduced in 1977 by Monsanto. These systems were packaged in compact modules containing large amounts of permeation surface area...

  8. Gas Turbine Emissions 

    E-Print Network [OSTI]

    Frederick, J. D.

    1990-01-01

    Historically, preliminary design information regarding gas turbine emissions has been unreliable, particularly for facilities using steam injection and other forms of Best Available Control Technology (BACT). This was probably attributed to the lack...

  9. Gas-separation process

    DOE Patents [OSTI]

    Toy, Lora G. (San Francisco, CA); Pinnau, Ingo (Palo Alto, CA); Baker, Richard W. (Palo Alto, CA)

    1994-01-01

    A process for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material.

  10. Natural gas monthly

    SciTech Connect (OSTI)

    1996-05-01

    This document highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Data presented include volume and price, production, consumption, underground storage, and interstate pipeline activities.

  11. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    2013-01-01

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  12. US crude oil, natural gas, and natural gas liquids reserves

    SciTech Connect (OSTI)

    Not Available

    1990-10-05

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1989, and production volumes for the year 1989 for the total United States and for selected states and state sub-divisions. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), its two major components (nonassociated and associated-dissolved gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, two components of natural gas liquids, lease condensate and natural gas plant liquids, have their reserves and production reported separately. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. 28 refs., 9 figs., 15 tabs.

  13. Landfill Gas Fueled HCCI Demonstration System

    E-Print Network [OSTI]

    Blizman, Brandon J.; Makel, Darby B.; Mack, John Hunter; Dibble, Robert W.

    2006-01-01

    operations with natural gas: Fuel composition implications,”of Natural gas testing LANDFILL GAS COMPOSITION Tapping into

  14. Modeling Leaking Gas Plume Migration

    E-Print Network [OSTI]

    Silin, Dmitriy; Patzek, Tad; Benson, Sally M.

    2008-01-01

    GAS PLUME MIGRATION t = 64.0 [day] Depth [m] Depth [m] t =GAS PLUME MIGRATION t = 160.0 [day] Depth [m] Depth [m] t =

  15. EIA - Natural Gas Analysis Basics

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas industry restructuring in each state, focusing on the residential customer class. About U.S. Natural Gas Pipelines State Energy Profiles What role does liquefied...

  16. Shale gas - what happened? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale gas - what happened? Shale gas - what happened? It seems like shale gas came out of nowhere - what happened? More Documents & Publications Natural Gas from Shale: Questions...

  17. Shale Gas Glossary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Shale Gas Glossary Shale Gas Glossary More Documents & Publications Natural Gas from Shale: Questions and Answers Modern Shale Gas Development in the United States: A...

  18. ComEd, Nicor Gas, Peoples Gas & North Shore Gas- Small Business Energy Savings Program

    Broader source: Energy.gov [DOE]

    ComEd, Nicor Gas, Peoples Gas, and North Shore Gas fund the Small Business Energy Savings program in which an energy advisor conducts a free on-site energy assessment and provides free installati...

  19. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    M. F. , Northern California oil and gas field production.California, Division of Oil, Gas and Geothermal Resources;Beaumont EA, eds. , Atlas of Oil and Gas Fields, Structural

  20. Natural Gas Gross Withdrawals from Gas Wells

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,4896-2015 Illinois NA NA NA

  1. Natural Gas Gross Withdrawals from Gas Wells

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,4896-2015 Illinois NA NA

  2. Shale gas is natural gas trapped inside

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo.Hydrogen4 » Searchwith FirstatOpportunitiesDOE forSevenShale gas is

  3. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  4. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouille; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-01-28

    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  5. FlueGen Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskey flatsInformationFlint GeothermalSilver PeakWister

  6. Gas-powered integration

    SciTech Connect (OSTI)

    Hawrylyshyn, G.

    1993-05-01

    Popularly known as the Brazil/Bolivia Gas Deal, the project consists of a 20-year agreement to supply Bolivian natural gas to heavily industrialized southern Brazil. This is an inter-regional undertaking comparable in scope and significance to pipeline projects in Europe and the gas networks between the USA and Canada and Mexico. The Brazil/Boliviz agreement call foe a 10-month period to obtain financing and 30 months to build the 1,376 mile main pipeline, a job that will be undertaken individually by each country within its territory. The pipelines will meet at the border in Corumba. Aside from the main gasline, the 20-year agreement will also require the laying of 1,184 kilometers (736 miles) of additional feeder and distribution pipelines in Brazil, raising the total pipe mileage to 3,389 kilometers. Then there is the need to build the whole infrastructure for gas distribution facilities and to switch to gas to power the equipment in thousands of industrial plants, commercial establishments and residences. The total investment in this undertaking is estimated to surpass US$10 billion.

  7. REVISED NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION REVISED NATURAL GAS MARKET ASSESSMENT In Support of the 2007's natural gas market. It covers natural gas demand, supply, infrastructure, price, and possible alternative and the related Scenarios Project, and additional updated information. California natural gas demand growth

  8. Gas intrusion into SPR caverns

    SciTech Connect (OSTI)

    Hinkebein, T.E.; Bauer, S.J.; Ehgartner, B.L.; Linn, J.K.; Neal, J.T.; Todd, J.L.; Kuhlman, P.S.; Gniady, C.T. [Sandia National Labs., Albuquerque, NM (United States). Underground Storage Technology Dept.; Giles, H.N. [Dept. of Energy, Washington, DC (United States). Strategic Petroleum Reserve

    1995-12-01

    The conditions and occurrence of gas in crude oil stored in Strategic Petroleum Reserve, SPR, caverns is characterized in this report. Many caverns in the SPR show that gas has intruded into the oil from the surrounding salt dome. Historical evidence and the analyses presented here suggest that gas will continue to intrude into many SPR caverns in the future. In considering why only some caverns contain gas, it is concluded that the naturally occurring spatial variability in salt permeability can explain the range of gas content measured in SPR caverns. Further, it is not possible to make a one-to-one correlation between specific geologic phenomena and the occurrence of gas in salt caverns. However, gas is concluded to be petrogenic in origin. Consequently, attempts have been made to associate the occurrence of gas with salt inhomogeneities including anomalies and other structural features. Two scenarios for actual gas intrusion into caverns were investigated for consistency with existing information. These scenarios are gas release during leaching and gas permeation through salt. Of these mechanisms, the greater consistency comes from the belief that gas permeates to caverns through the salt. A review of historical operating data for five Bryan Mound caverns loosely supports the hypothesis that higher operating pressures reduce gas intrusion into caverns. This conclusion supports a permeability intrusion mechanism. Further, it provides justification for operating the caverns near maximum operating pressure to minimize gas intrusion. Historical gas intrusion rates and estimates of future gas intrusion are given for all caverns.

  9. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  10. Gas turbine sealing apparatus

    DOE Patents [OSTI]

    Wiebe, David J; Wessell, Brian J; Ebert, Todd; Beeck, Alexander; Liang, George; Marussich, Walter H

    2013-02-19

    A gas turbine includes forward and aft rows of rotatable blades, a row of stationary vanes between the forward and aft rows of rotatable blades, an annular intermediate disc, and a seal housing apparatus. The forward and aft rows of rotatable blades are coupled to respective first and second portions of a disc/rotor assembly. The annular intermediate disc is coupled to the disc/rotor assembly so as to be rotatable with the disc/rotor assembly during operation of the gas turbine. The annular intermediate disc includes a forward side coupled to the first portion of the disc/rotor assembly and an aft side coupled to the second portion of the disc/rotor assembly. The seal housing apparatus is coupled to the annular intermediate disc so as to be rotatable with the annular intermediate disc and the disc/rotor assembly during operation of the gas turbine.

  11. Gas separation membrane module assembly

    DOE Patents [OSTI]

    Wynn, Nicholas P (Palo Alto, CA); Fulton, Donald A. (Fairfield, CA)

    2009-03-31

    A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.

  12. Optimization of condensing gas drive 

    E-Print Network [OSTI]

    Lofton, Larry Keith

    1977-01-01

    - cal, undersaturated reservoir with gas being injected into the crest and oil being produced from the base of the structure. Fractional oil re- covery at gas breakthrough proved to be less sensitive to changes in oil withdrawal rates as the gas... injection pressure was increased. The validity of the model was established by accurately simulating several low pressure gas drives conducted in the laboratory. Oil recoveries at gas breakthrough using the model compared closely with those recoveries...

  13. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, Curtis D. (Albuquerque, NM); Blair, Dianna S. (Albuquerque, NM); Rodacy, Philip J. (Albuquerque, NM); Reber, Stephen D. (Corrales, NM)

    1999-01-01

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute.

  14. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, Billy Joe (Winter Park, FL); Whidden, Graydon Lane (Great Blue, CT)

    1999-01-01

    A method of converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit.

  15. Gas turbine combustor transition

    DOE Patents [OSTI]

    Coslow, B.J.; Whidden, G.L.

    1999-05-25

    A method is described for converting a steam cooled transition to an air cooled transition in a gas turbine having a compressor in fluid communication with a combustor, a turbine section in fluid communication with the combustor, the transition disposed in a combustor shell and having a cooling circuit connecting a steam outlet and a steam inlet and wherein hot gas flows from the combustor through the transition and to the turbine section, includes forming an air outlet in the transition in fluid communication with the cooling circuit and providing for an air inlet in the transition in fluid communication with the cooling circuit. 7 figs.

  16. Indiana Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion CubicOctober 2015Elements) GasYear

  17. Alaska Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements) Gas andYear Jan Feb

  18. Arizona Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - Natural GasYear Jan Feb Mar Apr May Jun19

  19. Colorado Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) GasBarrels)Kansas (MillionYear21

  20. Shale Gas Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996 2.003 1990-2016November 20001:Gas Production

  1. Wyoming Natural Gas Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural Gas Reserves Adjustments (BillionYear (MillionCubicCubic3.40

  2. Life-cycle analysis of shale gas and natural gas.

    SciTech Connect (OSTI)

    Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M.

    2012-01-27

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

  3. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Shen, Ming-Shing (Rocky Point, NY)

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  4. Polymide gas separation membranes

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz

    2004-09-14

    Soluble polyamic acid salt (PAAS) precursors comprised of tertiary and quaternary amines, ammonium cations, sulfonium cations, or phosphonium cations, are prepared and fabricated into membranes that are subsequently imidized and converted into rigid-rod polyimide articles, such as membranes with desirable gas separation properties. A method of enhancing solubility of PAAS polymers in alcohols is also disclosed.

  5. Gas turbine diagnostic system

    E-Print Network [OSTI]

    Talgat, Shuvatov

    2011-01-01

    In the given article the methods of parametric diagnostics of gas turbine based on fuzzy logic is proposed. The diagnostic map of interconnection between some parts of turbine and changes of corresponding parameters has been developed. Also we have created model to define the efficiency of the compressor using fuzzy logic algorithms.

  6. Gas-separation process

    DOE Patents [OSTI]

    Toy, L.G.; Pinnau, I.; Baker, R.W.

    1994-01-25

    A process is described for separating condensable organic components from gas streams. The process makes use of a membrane made from a polymer material that is glassy and that has an unusually high free volume within the polymer material. 6 figures.

  7. Natural Gas Purchasing Options 

    E-Print Network [OSTI]

    Watkins, G.

    1988-01-01

    As a result of economic and regulatory changes, the natural gas marketplace now offers multiple options for purchasers. The purpose of this panel is to discuss short-term purchasing options and how to take advantage of these options both to lower...

  8. NETL Studies High Throughput Membrane Screening | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and economical method for gas separations from power plant flue gas streams. Polymer membranes and supported liquid membranes show great promise to solve problems in the...

  9. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A; Taylor, Margaret R

    2007-01-01

    technologies applicable to power plant gas streams) and thecapacity of power plants whose flue gases are treated withat some power plants burning oil or natural gas, including

  10. 100 Hour test of the pressurized woodchip-fired gravel bed combustor

    SciTech Connect (OSTI)

    Ragland, K.W.; Aerts, D.J.

    1994-08-01

    Combustion of wood chips in a packed bed combustor for a gas turbine cogeneration system is described. A discussion on flue gas emissions and mass balances is included.

  11. Exact solutions in a model of vertical gas migration

    E-Print Network [OSTI]

    Silin, Dmitriy B.; Patzek, Tad W.; Benson, Sally M.

    2006-01-01

    gas leaking from seasonal gas storage, or for modeling ofmigration resulting from a gas storage leak, the gas ?owsof gas, created by a leaking gas storage reservoir, migrates

  12. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.W.

    1997-05-01

    Cryenco and Los Alamos are collaborating to develop a natural-gas-powered natural-gas liquefier that will have no moving parts and require no electrical power. It will have useful efficiency, remarkable reliability, and low cost. The liquefaction of natural gas, which occurs at only 115 Kelvin at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 invention of the thermoacoustically driven orifice pulse-tube refrigerator (TA-DOPTR) provides cryogenic refrigeration with no moving parts for the first time. In short, this invention uses acoustic phenomena to produce refrigeration from heat. The required apparatus consists of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. In the Cryenco-Los Alamos collaboration, the authors are developing a version of this invention suitable for use in the natural-gas industry. The project is known as acoustic liquefier for short. The present program plans call for a two-phase development. Phase 1, with capacity of 500 gallon per day (i.e., approximately 40,000 scfd, requiring a refrigeration power of about 7 kW), is large enough to illuminate all the issues of large-scale acoustic liquefaction without undue cost, and to demonstrate the liquefaction of 60--70% of input gas, while burning 30--40%. Phase 2 will target versions of approximately 10{sup 6} scfd = 10,000 gallon per day capacity. In parallel with both, they continue fundamental research on the technology, directed toward increased efficiency, to build scientific foundations and a patent portfolio for future acoustic liquefiers.

  13. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

  14. Status of pulse combustion applications in (1) steam reforming of coal, (2) fluid bed combustion of coal, and (3) direct coal fired gas turbine

    SciTech Connect (OSTI)

    Durai-Swamy, K. [ThermoChem, Inc., Santa Fe Springs, CA (United States); Chandran, R.; Said, H.; Steedman, W.

    1994-12-31

    ThermoChem, Inc. has designed a 450 T/D wet coal gasification by indirect, pulse-combustor-heated, steam reforming process. The plant site is Gillette, Wyoming. Products from the demo project are: (1) High pressure steam for a K-Fuel coal upgrading plant and (2) Medium Btu syngas, which could be used for power generation or methanol production. The indirect heated steam reformer could also produce a char by-product (if desired) that could be used as a reductant in direct iron making (DRI) process. There has been interest for char production as well. ThermoChem is constructing a pulse assisted, atmospheric pressure fluid bed combustor unit (PAFBC) to produce 50,000 lb/hr of steam, at Clemson University in South Carolina. MTCI`s developing a pressurized pulse coal combustor coupled with bimodal ash agglomeration, sulfur capture and solids removal features, such that the hot flue gas can be directly expanded in a gas turbine to generate power. The status of these Clean Coal Technologies is presented in this paper.

  15. Natural gas monthly, March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-03-22

    The Natural Gas Monthly (NGM) is prepared in the Data Operations Branch of the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA), US Department of energy (DOE). The NGM highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  16. Acidic gas capture by diamines

    DOE Patents [OSTI]

    Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

    2011-05-10

    Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

  17. Natural gas monthly, August 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-25

    The Natural Gas Monthly (NGM) is prepared in the Data Operations Branch of the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA), US Department of Energy (DOE). The NGM highhghts activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  18. Natural gas monthly, September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The Natural Gas Monthly (NGM) is prepared in the Data Operations Branch of the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA), US Department of Energy (DOE). The NGM highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  19. Natural gas monthly, April 1999

    SciTech Connect (OSTI)

    NONE

    1999-05-06

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. There are two feature articles in this issue: Natural gas 1998: Issues and trends, Executive summary; and Special report: Natural gas 1998: A preliminary summary. 6 figs., 28 tabs.

  20. Natural gas monthly, October 1996

    SciTech Connect (OSTI)

    NONE

    1996-10-01

    The Natural Gas Monthly (NGM) is prepared in the Data Operations Branch of the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA), U.S. Department of Energy (DOE). The NGM highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  1. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    SciTech Connect (OSTI)

    Charles Mones

    2006-12-01

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

  2. Gas-controlled dynamic vacuum insulation with gas gate

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

    1994-06-07

    Disclosed is a dynamic vacuum insulation comprising sidewalls enclosing an evacuated chamber and gas control means for releasing hydrogen gas into a chamber to increase gas molecule conduction of heat across the chamber and retrieving hydrogen gas from the chamber. The gas control means includes a metal hydride that absorbs and retains hydrogen gas at cooler temperatures and releases hydrogen gas at hotter temperatures; a hydride heating means for selectively heating the metal hydride to temperatures high enough to release hydrogen gas from the metal hydride; and gate means positioned between the metal hydride and the chamber for selectively allowing hydrogen to flow or not to flow between said metal hydride and said chamber.

  3. Gas-controlled dynamic vacuum insulation with gas gate

    DOE Patents [OSTI]

    Benson, D.K.; Potter, T.F.

    1994-06-07

    Disclosed is a dynamic vacuum insulation comprising sidewalls enclosing an evacuated chamber and gas control means for releasing hydrogen gas into a chamber to increase gas molecule conduction of heat across the chamber and retrieving hydrogen gas from the chamber. The gas control means includes a metal hydride that absorbs and retains hydrogen gas at cooler temperatures and releases hydrogen gas at hotter temperatures; a hydride heating means for selectively heating the metal hydride to temperatures high enough to release hydrogen gas from the metal hydride; and gate means positioned between the metal hydride and the chamber for selectively allowing hydrogen to flow or not to flow between said metal hydride and said chamber. 25 figs.

  4. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel Morrison; Elizabeth Wood; Barbara Robuck

    2010-09-30

    The EMS Energy Institute at The Pennsylvania State University (Penn State) has managed the Gas Storage Technology Consortium (GSTC) since its inception in 2003. The GSTC infrastructure provided a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. The GSTC received base funding from the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) Oil & Natural Gas Supply Program. The GSTC base funds were highly leveraged with industry funding for individual projects. Since its inception, the GSTC has engaged 67 members. The GSTC membership base was diverse, coming from 19 states, the District of Columbia, and Canada. The membership was comprised of natural gas storage field operators, service companies, industry consultants, industry trade organizations, and academia. The GSTC organized and hosted a total of 18 meetings since 2003. Of these, 8 meetings were held to review, discuss, and select proposals submitted for funding consideration. The GSTC reviewed a total of 75 proposals and committed co-funding to support 31 industry-driven projects. The GSTC committed co-funding to 41.3% of the proposals that it received and reviewed. The 31 projects had a total project value of $6,203,071 of which the GSTC committed $3,205,978 in co-funding. The committed GSTC project funding represented an average program cost share of 51.7%. Project applicants provided an average program cost share of 48.3%. In addition to the GSTC co-funding, the consortium provided the domestic natural gas storage industry with a technology transfer and outreach infrastructure. The technology transfer and outreach were conducted by having project mentoring teams and a GSTC website, and by working closely with the Pipeline Research Council International (PRCI) to jointly host technology transfer meetings and occasional field excursions. A total of 15 technology transfer/strategic planning workshops were held.

  5. Retained Gas Sampling Results for the Flammable Gas Program

    SciTech Connect (OSTI)

    J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

    1999-11-18

    The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

  6. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  7. Easing the Natural Gas Crisis: Reducing Natural Gas Prices Through Electricity Supply Diversification -- Testimony

    E-Print Network [OSTI]

    Wiser, Ryan

    2005-01-01

    present concerns about natural gas prices and the findingsEconomy (ACEEE). 2003. Natural Gas Price Effects of EnergyGas Crisis: Reducing Natural Gas Prices Through Electricity

  8. Reducing gas generators and methods for generating a reducing gas

    SciTech Connect (OSTI)

    Scotto, Mark Vincent; Perna, Mark Anthony

    2015-11-03

    One embodiment of the present invention is a unique reducing gas generator. Another embodiment is a unique method for generating a reducing gas. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for generating reducing gas. Further embodiments, forms, features, aspects, benefits, and advantages of the present application will become apparent from the description and figures provided herewith.

  9. Gas supplies of interstate/natural gas pipeline companies 1989

    SciTech Connect (OSTI)

    Not Available

    1990-12-18

    This publication provides information on the interstate pipeline companies' supply of natural gas during calendar year 1989, for use by the FERC for regulatory purposes. It also provides information to other Government agencies, the natural gas industry, as well as policy makers, analysts, and consumers interested in current levels of interstate supplies of natural gas and trends over recent years. 5 figs., 18 tabs.

  10. Automated gas chromatography

    DOE Patents [OSTI]

    Mowry, C.D.; Blair, D.S.; Rodacy, P.J.; Reber, S.D.

    1999-07-13

    An apparatus and process for the continuous, near real-time monitoring of low-level concentrations of organic compounds in a liquid, and, more particularly, a water stream. A small liquid volume of flow from a liquid process stream containing organic compounds is diverted by an automated process to a heated vaporization capillary where the liquid volume is vaporized to a gas that flows to an automated gas chromatograph separation column to chromatographically separate the organic compounds. Organic compounds are detected and the information transmitted to a control system for use in process control. Concentrations of organic compounds less than one part per million are detected in less than one minute. 7 figs.

  11. Gas turbine sealing apparatus

    DOE Patents [OSTI]

    Marra, John Joseph; Wessell, Brian J.; Liang, George

    2013-03-05

    A sealing apparatus in a gas turbine. The sealing apparatus includes a seal housing apparatus coupled to a disc/rotor assembly so as to be rotatable therewith during operation of the gas turbine. The seal housing apparatus comprises a base member, a first leg portion, a second leg portion, and spanning structure. The base member extends generally axially between forward and aft rows of rotatable blades and is positioned adjacent to a row of stationary vanes. The first leg portion extends radially inwardly from the base member and is coupled to the disc/rotor assembly. The second leg portion is axially spaced from the first leg portion, extends radially inwardly from the base member, and is coupled to the disc/rotor assembly. The spanning structure extends between and is rigidly coupled to each of the base member, the first leg portion, and the second leg portion.

  12. Hydrogen gas relief valve

    DOE Patents [OSTI]

    Whittlesey, Curtis C. (Birmingham, MI)

    1985-01-01

    An improved battery stack design for an electrochemical system having at least one cell from which a gas is generated and an electrolyte in communication with the cell is described. The improved battery stack design features means for defining a substantially closed compartment for containing the battery cells and at least a portion of the electrolyte for the system, and means in association with the compartment means for selectively venting gas from the interior of the compartment means in response to the level of the electrolyte within the compartment means. The venting means includes a relief valve having a float member which is actuated in response to the level of the electrolyte within the compartment means. This float member is adapted to close the relief valve when the level of the electrolyte is above a predetermined level and open the relief valve when the level of electrolyte is below this predetermined level.

  13. Produce diesel from gas

    SciTech Connect (OSTI)

    Singleton, A.H.; Regier, S.

    1983-05-01

    The Gulf Badger process converts natural gas directly to hydrocarbon liquids by a catalytic chemical route. Fischer-Tropsch process--which is a carbon monoxide polymerization/ hydrogenation process--is used. Because the process is exothermal, heat removal by either tubular fixed bed, fluidized bed, or slurry are considered. A wax build up of high molecular weight material is removed by hydro-stripping two-bed system. The demonstration plant flow diagram shows the process to be: natural gas is compressed, recycled with CO/sub 2/, sulfur is removed in a zinc oxide drum, CO is removed in amine scrubbers, H/sub 2//CO ratio is adjusted to produce a hydrogen rich stream, and stabilization and distribution follow. A monitoring system using computers is part of the demonstration unit.

  14. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, B.T.; Arasteh, D.K.; Selkowitz, S.E.

    1993-12-14

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation. 18 figures.

  15. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, Brent T. (Berkeley, CA); Arasteh, Dariush K. (Oakland, CA); Selkowitz, Stephen E. (Piedmont, CA)

    1993-01-01

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation.

  16. Gas turbine premixing systems

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Varatharajan, Balachandar; Evulet, Andrei Tristan; Yilmaz, Ertan; Lacy, Benjamin Paul

    2013-12-31

    Methods and systems are provided for premixing combustion fuel and air within gas turbines. In one embodiment, a combustor includes an upstream mixing panel configured to direct compressed air and combustion fuel through premixing zone to form a fuel-air mixture. The combustor includes a downstream mixing panel configured to mix additional combustion fuel with the fule-air mixture to form a combustion mixture.

  17. Alabama Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade

  18. Historical Natural Gas Annual 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    State, 1980-1999 PDF 12 Supplemental Gas Supplies by State, 1980-1999 PDF 13 Natural Gas Production, Transmission, and Consumption by State, 1967-1999 PDF 14 Consumption of...

  19. Natural Gas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Natural Gas Many heavy-duty fleets depend on diesel fuel. But an increasing number of trucking companies are transitioning their vehicles to run on liquefied natural...

  20. Natural Gas Exports from Iran

    Reports and Publications (EIA)

    2012-01-01

    This assessment of the natural gas sector in Iran, with a focus on Iran’s natural gas exports, was prepared pursuant to section 505 (a) of the Iran Threat Reduction and Syria Human Rights Act of 2012 (Public Law No: 112-158). As requested, it includes: (1) an assessment of exports of natural gas from Iran; (2) an identification of the countries that purchase the most natural gas from Iran; (3) an assessment of alternative supplies of natural gas available to those countries; (4) an assessment of the impact a reduction in exports of natural gas from Iran would have on global natural gas supplies and the price of natural gas, especially in countries identified under number (2); and (5) such other information as the Administrator considers appropriate.

  1. Gas Code of Conduct (Connecticut)

    Broader source: Energy.gov [DOE]

    The Gas Code of Conduct sets forth the standard of conduct for transactions, direct or indirect, between gas companies and their affiliates. The purpose of these regulations is to promote...

  2. Primer on gas integrated resource planning

    SciTech Connect (OSTI)

    Goldman, C.; Comnes, G.A.; Busch, J.; Wiel, S. [Lawrence Berkeley Lab., CA (United States)

    1993-12-01

    This report discusses the following topics: gas resource planning: need for IRP; gas integrated resource planning: methods and models; supply and capacity planning for gas utilities; methods for estimating gas avoided costs; economic analysis of gas utility DSM programs: benefit-cost tests; gas DSM technologies and programs; end-use fuel substitution; and financial aspects of gas demand-side management programs.

  3. Natural gas monthly, August 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-24

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  4. Natural gas monthly, November 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-29

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground state data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  5. Natural gas monthly, May 1999

    SciTech Connect (OSTI)

    NONE

    1999-05-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time the NGM features articles designed to assist readers in using and interpreting natural gas information. 6 figs., 27 tabs.

  6. Natural gas monthly, July 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01

    This document presents information pertaining to the natural gas industry. Data are included on production, consumption, distribution, and pipeline activities.

  7. Natural gas monthly, June 1993

    SciTech Connect (OSTI)

    Not Available

    1993-06-22

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  8. Natural gas monthly, April 1994

    SciTech Connect (OSTI)

    Not Available

    1994-04-26

    The National Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  9. Natural gas monthly: September 1996

    SciTech Connect (OSTI)

    NONE

    1996-09-01

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. 6 figs., 24 tabs.

  10. Natural gas monthly: December 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. Articles are included which are designed to assist readers in using and interpreting natural gas information.

  11. Natural gas monthly, September 1995

    SciTech Connect (OSTI)

    1995-09-27

    The (NGM) Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  12. Natural Gas Monthly, March 1996

    SciTech Connect (OSTI)

    NONE

    1996-03-25

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  13. Natural gas monthly, June 1998

    SciTech Connect (OSTI)

    NONE

    1998-06-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. 6 figs., 27 tabs.

  14. Natural gas monthly, July 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-27

    The Natural Gas Monthly NGM highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information.

  15. Natural gas monthly, November 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. 6 figs., 27 tabs.

  16. Natural gas monthly, February 1999

    SciTech Connect (OSTI)

    NONE

    1999-02-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. 6 figs., 28 tabs.

  17. Gas Slow Control System Specifications

    E-Print Network [OSTI]

    Roma "La Sapienza", Universitŕ di

    AMS-02 TRD Gas Slow Control System Specifications v 4.2 26-06-2006 A. Bartoloni, B. Borgia, F. Bucci, F. R. Spada INFN Sezione di Roma 1- Roma, Italy #12;2/45 #12;3/45 1. ABSTRACT 5 2. GAS SYSTEM FUNCTIONAL DESCRIPTION 5 3. GAS CONTROL SYSTEM 8 4. CONTROL SYSTEM COMPONENTS 12 a. Universal Control System

  18. LIQUEFIED NATURAL GAS IN CALIFORNIA

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION LIQUEFIED NATURAL GAS IN CALIFORNIA: HISTORY, RISKS, AND SITING Tyler Contributors Dave Maul Manager NATURAL GAS & SPECIAL PROJECTS OFFICE Terrence O'Brien, Deputy Commissioner and Leader of the Governor's Natural Gas Working Group #12;This paper was prepared as the result

  19. greenhouse gas inve green developmen

    E-Print Network [OSTI]

    Collins, Gary S.

    greenhouse gas inve green developmen energy conservation transportation carbon offs student facult;greenhouse gas inventory green development energy conservation transportation carbon offsets student faculty. Changi natural gas as a primary fuel allowed us to find cleaner and more effici university. Both in 1988

  20. Natural gas monthly, January 1999

    SciTech Connect (OSTI)

    NONE

    1999-02-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. 6 figs., 28 tabs.

  1. jean-philippe.babau@insa-lyon.fr INSA de Lyon

    E-Print Network [OSTI]

    Brest, Université de

    1 jean-philippe.babau@insa-lyon.fr INSA de Lyon jean-philippe.babau@univ-brest.fr UBO Programmation.univ-brest.fr/pages_perso/babau/ DĂ©partement Informatique, UFR Sciences, UBO Laboratoire Lab-STICC jean-philippe.babau@insa-lyon.fr INSA de Lyon jean-philippe.babau@univ-brest.fr UBO #12;2 jean-philippe.babau@insa-lyon.fr INSA de Lyon jean

  2. Gas sensor incorporating a porous framework

    DOE Patents [OSTI]

    Yaghi, Omar M; Czaja, Alexander U; Wang, Bo; Galatsis, Kosmas; Wang, Kang L; Furukawa, Hiroyasu

    2014-05-27

    The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

  3. Molecular Gas in Early-type Galaxies

    E-Print Network [OSTI]

    Alatalo, Katherine Anne

    2012-01-01

    toward the center (first seen in the molecular gas in A+3.4 Molecular Gas Mass . . . . . . .of the molecular gas . . . . . . . . . . 2.4.3 Mass of

  4. Gas sensor incorporating a porous framework

    DOE Patents [OSTI]

    Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Furukawa, Hiroyasu; Galatsis, Kosmas; Wang, Kang L.

    2013-07-09

    The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

  5. Natural Gas Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    must be stored onboard a vehicle in either a compressed gaseous (compressed natural gas, CNG) or liquefied (liquefied natural gas, LNG) state. Compressed Natural Gas To provide...

  6. Notice of Availability, Federal Register, 64 FR 3492, January...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    64 FR 3492, January 22, 1999 Notice of Availability, Federal Register, 64 FR 3492, January 22, 1999 Document displays a notice of availability pertaining to the Availability of...

  7. Natural gas monthly, October 1997

    SciTech Connect (OSTI)

    NONE

    1997-10-01

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article in this issue is a special report, ``Comparison of Natural Gas Storage Estimates from the EIA and AGA.`` 6 figs., 26 tabs.

  8. Natural gas monthly, June 1996

    SciTech Connect (OSTI)

    NONE

    1996-06-24

    The natural gas monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article for this month is Natural Gas Industry Restructuring and EIA Data Collection.

  9. Natural Gas Monthly, October 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-10

    The (NGM) Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. This month`s feature articles are: US Production of Natural Gas from Tight Reservoirs: and Expanding Rule of Underground Storage.

  10. Natural gas monthly, June 1994

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article this month is the executive summary from Natural Gas 1994: Issues and Trends. 6 figs., 31 tabs.

  11. Natural gas monthly, May 1997

    SciTech Connect (OSTI)

    1997-05-01

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article this month is ``Restructuring energy industries: Lessons from natural gas.`` 6 figs., 26 tabs.

  12. Natural gas monthly, December 1997

    SciTech Connect (OSTI)

    1997-12-01

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The article this month is entitled ``Recent Trends in Natural Gas Spot Prices.`` 6 figs., 27 tabs.

  13. Natural gas monthly, March 1997

    SciTech Connect (OSTI)

    1997-03-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article is entitled ``Natural gas analysis and geographic information systems.`` 6 figs., 27 tabs.

  14. Natural gas monthly, April 1997

    SciTech Connect (OSTI)

    1997-04-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are present3ed each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The feature article is entitled ``Natural gas pipeline and system expansions.`` 6 figs., 27 tabs.

  15. Fundamentals of gas measurement II

    SciTech Connect (OSTI)

    Smith, J.P.

    1995-12-01

    A knowledge of the Fundamentals of Gas Measurement is essential for all technicians and engineers that are called upon to perform gas volume calculations. These same people must have at least a working knowledge of the fundamentals to perform their everyday jobs including equipment calibrations, specific gravity tests, collecting gas samples, etc. To understand the fundamentals, one must be familiar with the definitions of the terms that are used in day-to- day gas measurement operations. They also must know how to convert some values from one quantity as measured to another quantity that is called for in the gas purchase or sales contracts or transportation agreements.

  16. Natural gas monthly, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-24

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. This month`s feature article is on US Natural Gas Imports and Exports 1994.

  17. Natural gas monthly, April 1998

    SciTech Connect (OSTI)

    NONE

    1998-04-01

    This issue of the Natural Gas Monthly presents the most recent estimates of natural gas data from the Energy Information Administration (EIA). Estimates extend through April 1998 for many data series. The report highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, feature articles are presented designed to assist readers in using and interpreting natural gas information. This issue contains the special report, ``Natural Gas 1997: A Preliminary Summary.`` This report provides information on natural gas supply and disposition for the year 1997, based on monthly data through December from EIA surveys. 6 figs., 28 tabs.

  18. Natural Gas Gross Withdrawals

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion CubicEnergyUnderground StorageWellhead Price6,167,371throughthrough 1996)Week Of Period:

  19. Ceramic gas turbine shroud

    DOE Patents [OSTI]

    Shi, Jun; Green, Kevin E.

    2014-07-22

    An example gas turbine engine shroud includes a first annular ceramic wall having an inner side for resisting high temperature turbine engine gasses and an outer side with a plurality of radial slots. A second annular metallic wall is positioned radially outwardly of and enclosing the first annular ceramic wall and has a plurality of tabs in communication with the slot of the first annular ceramic wall. The tabs of the second annular metallic wall and slots of the first annular ceramic wall are in communication such that the first annular ceramic wall and second annular metallic wall are affixed.

  20. Chemoresistive gas sensor

    DOE Patents [OSTI]

    Hirschfeld, T.B.

    1987-06-23

    A chemoresistive gas sensor is provided which has improved sensitivity. A layer of organic semiconductor is disposed between two electrodes which, in turn, are connected to a voltage source. High conductivity material is dispersed within the layer of organic semiconductor in the form of very small particles, or islands. The average interisland spacing is selected so that the predominant mode of current flow is by way of electron funneling. Adsorption of gaseous contaminant onto the layer of organic semiconductor modulates the tunneling current in a quantitative manner. 2 figs.

  1. Total Working Gas Capacity

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan3 November18.5 385.5Dry Production602 1,397 125 Q 69 0.11 Monthly

  2. Oil and Gas

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996How to ApplytheExecutive71.1 OMB Field Element0 -Technology

  3. Natural Gas Data Publications

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar AprThousand CubicDecadeDecade Year-0

  4. Natural Gas Imports (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in NevadaYear-Month Week3,751,360 3,740,757

  5. Natural Gas Processed (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in NevadaYear-Month802 827 788Proved, as of

  6. Nebraska Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in155 13,348Feet) YearFuelThousand4.71 NA

  7. Nevada Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in155DecadeFeet) YearMay-15 Jun-15 Jul-15

  8. Ohio Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubic Feet) Year Jan Feb Mar Apr2009Year2009 2010 2011

  9. Oklahoma Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubic Feet) Year JanIndustrial

  10. Oregon Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubic Feet) YearYear Jan FebIndustrial Consumers2009

  11. Pennsylvania Natural Gas Prices

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubic Feet) AnnualProved ReservesFuelVirginia2009 2010

  12. Florida Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWells (MillionProved ReservesYear JanProcessed inWellhead

  13. Georgia Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWells (MillionProved% of TotalInputImports 3.73 4.39 4.20

  14. Hawaii Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet) Havre, MTCitygate 17.82 22.94

  15. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet) Havre, MTCitygateYearAnnual .

  16. Idaho Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet)

  17. Kansas Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillionReserves (BillionYearKansas

  18. Kentucky Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential Consumers (Number of Elements) KentuckyKentuckyYear JanNA

  19. Louisiana Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential Consumers (Number of33Cubic Foot)YearYear Jan Feb

  20. Maine Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUM FOR: JOHNThousand Cubic Feet)Imports

  1. Maryland Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUM FOR:Decade Year-0Wellhead NA NA

  2. Massachusetts Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUM FOR:DecadeCubicper Thousand

  3. Michigan Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUMProved ReservesDecadeYear(MillionWellhead

  4. Alabama Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32 4.46 1967-2010 Pipeline and

  5. Arkansas Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear Jan Feb Mar Apr May Jun43 3.84

  6. California Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 ArizonaResidential Consumers (Number

  7. Connecticut Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet)Cubic1992Thousand Cubic

  8. Delaware Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet)Cubic1992Thousand9)%Year Jan Feb

  9. Natural Gas Wellhead Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,2226 (next release 2:00 p.m.,9,7,3, 2011 at 2:001NA

  10. Natural Gas Wellhead Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,2226 (next release 2:00 p.m.,9,7,3, 2011 at

  11. Natural Gas Wellhead Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,2226 (next release 2:00 p.m.,9,7,3, 2011 atWellhead

  12. Nebraska Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,2226 (next release 2:00DecadeResidentialYear

  13. Nevada Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,2226 (nextNet Withdrawals (MillionThousandNA NA

  14. Ohio Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+ Lease CondensateDecade(Million

  15. Oklahoma Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+ LeaseWellhead%Texas (Million Cubic

  16. Pennsylvania Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+Elements)Barrels)PennsylvaniaYear

  17. Minnesota Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUMProvedFeet)Year Jan Feb Mar Apr

  18. Mississippi Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014Proved Reserves (Billionoff)Year Janin73 4.17

  19. Missouri Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014Proved ReservesFoot)Year Jan Feb Mar Apr May Jun

  20. Montana Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb Mar Apr MayYear Jan Feb Mar Apr16

  1. Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,Energy Office

  2. Natural Gas Citygate Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,Energy

  3. Natural Gas Citygate Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,EnergyPipeline

  4. Natural Gas Citygate Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL

  5. Natural Gas Consumption

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan FebYear Jan Feb Mar Apr

  6. Natural Gas Consumption

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan FebYear Jan Feb Mar Apr Monthly

  7. Natural Gas Dry Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough

  8. Natural Gas Dry Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,489 2,249,187 2,334,573

  9. Natural Gas Dry Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,489 2,249,187 2,334,573 Gross

  10. Natural Gas Gross Withdrawals

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,489 2,249,187Week

  11. Natural Gas Industrial Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,4896-2015 Illinois2007-2015

  12. Natural Gas Industrial Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,4896-2015 Illinois2007-2015

  13. Natural Gas Industrial Price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYearthrough2,290,4896-2015

  14. Natural Gas Marketed Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,222 2,389,991 2,480,107 2,473,618 2,407,387

  15. Natural Gas Monthly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,222 2,389,991 2,480,107 2,473,618 2,407,387

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2,2,435,222 2,389,991 2,480,107averagethe1-2015Analysis

  17. Tennessee Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1Plant Processing DefinitionsThousand Cubic Feet)3.83 4.35

  18. Texas Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1PlantSeparation,% of Total ResidentialYearYear Jan Feb Mar1

  19. Total Working Gas Capacity

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved Reserves (BillionProduction(MillionGrossJarrett2009

  20. Utah Natural Gas Summary

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData20092009Reserves Based38 4.23 1967-2010 Pipeline