National Library of Energy BETA

Sample records for fossil-fuel co2 emissions

  1. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01

    interannual variations in fossil fuel emissions. J. Geophys.Treat CO 2 from fossil fuel burning: global distribution ofdioxide emissions from fossil fuel consumption and cement

  2. Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements

    E-Print Network [OSTI]

    Ray, Jaideep

    for source locations #12;Background on ffCO2 inversion · Unlike biogenic CO2 emissions, anthropogenicWavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements J. Ray1, V: Develop a technique to estimate anthropogenic (fossil- fuel) CO2 emissions from sparse observations

  3. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    E-Print Network [OSTI]

    Gurney, Kevin R.

    2010-01-01

    1 distribution of carbon dioxide emissions from fossil fuelcycle of fossil-fuel carbon dioxide emissions in the Unitedspatial patterns of carbon dioxide emissions from national

  4. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01

    dioxide emissions from fossil fuel consumption and cementindependent budgeting of fossil fuel CO 2 over Europe by COregional, and national fossil fuel CO 2 emissions, Carbon

  5. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known ‘signal-to-noise’ problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  6. CO2 emissions mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine V.; Wada, Kenichi; Van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher and decrease with mitigation. A first deviation from the optimal transition pathway relaxes global emission targets until 2030, in accordance with the Copenhagen pledges and regionally-specific low-carbon technology targets. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger - twice and more - than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear cut across models, as we find carbon leakage effects ranging from positive to negative because leakage and substitution patterns of coal, oil, and gas differ. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  7. CO2 emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Méjean, Aurélie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; et al

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increasesmore »strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.« less

  8. Analysis of CO2 Emissions from Fossil Fuel in Korea: 19611994 Ki-Hong Choi

    E-Print Network [OSTI]

    .......................................................................................................7 3.2 Energy Consumption and CO2 Emissions ................................................................8 3.2.1 Energy Consumption Pattern Appendix 3. Emission Coefficient of Electricity

  9. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect (OSTI)

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  10. Seasonal and latitudinal variability of troposphere ?14CO2: Post bomb contributions from fossil fuels, oceans, the stratosphere, and the terrestrial biosphere

    E-Print Network [OSTI]

    Randerson, J. T; Enting, I. G; Schuur, E. A. G; Caldeira, K.; Fung, I. Y

    2002-01-01

    CO 2 Emissions From Fossil-Fuel Burning, Hydraulic Cementof seasonal variation in fossil fuel CO 2 emissions, Tellus,contributions from fossil fuels, oceans, the stratosphere,

  11. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    E-Print Network [OSTI]

    2015-01-01

    in CO 2 emissions from fossil fuel consumption and cementwith CDIAC estimates of fossil fuel carbon dioxide emission.emissions from fossil-fuel combustion. Biogeosciences 9,

  12. Supplement to: The CO2 release and Oxygen uptake from Fossil Fuel Emission

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Consumption for non-energy uses F80 Fossil fuel use: Oil production, transmission and handling, gas flaring , C. Minejima2,4 , H. Mukai2 1 Max Planck Institute for Biogeochemistry, Jena, Germany 2 Center to observations at the station Ochsenkopf in Germany. #12;EDGAR 3.2 usage type Corresponding UN usage type(s) code

  13. Device for separating CO2 from fossil-fueled power plant emissions

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Judkins, Roddie R. (Knoxville, TN); Wilson, Kirk A. (Knoxville, TN)

    2002-04-23

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  14. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01

    changes resulting from fossil-fuel CO 2 release and cosmic-for recently added fossil fuel CO 2 in the atmosphere anddioxide emissions from fossil fuel consumption and cement

  15. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    dioxide emis- sions from fossil-fuel use in North America,S. : High resolution fossil fuel combustion CO 2 emissionP. P. : Linking emissions of fossil fuel CO 2 and other

  16. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    emissions from traded fossil fuels; Top), production (F Pr )Regional, and National Fossil-Fuel CO 2 Emissions (Carbonfrom the burning of fossil fuels are conventionally

  17. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    emissions from fossil-fuel combustion R. J. Andres 1 , T. A.resolution fossil fuel combustion CO 2 emission fluxes forCO 2 emissions from fuel combustion, 2010 edition, OECD/IEA,

  18. Towards constraints on fossil fuel emissions from total column carbon dioxide

    E-Print Network [OSTI]

    Keppel-Aleks, G.; Wennberg, P. O; O'Dell, C. W; Wunch, D.

    2013-01-01

    G. Keppel-Aleks et al. : Fossil fuel constraints from X CO 2P. P. : Assess- ment of fossil fuel carbon dioxide and otherstrong localized sources: fossil fuel power plant emissions

  19. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    E-Print Network [OSTI]

    2015-01-01

    CO 2 Emissions from Fuel Combustion (IEA, 2013). Olivier, J.emissions from fossil-fuel combustion. Biogeosciences 9,Associated Rocks And Coal Combustion Products Collected For

  20. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation’s CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

  1. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01

    independent budgeting of fossil fuel CO 2 over Europe by (CO2008 Where do fossil fuel carbon dioxide emissions frompatterns and mixing of fossil fuel-derived CO 2 is important

  2. A movable trigger: Fossil fuel CO2 and the onset of the next David Archer

    E-Print Network [OSTI]

    A movable trigger: Fossil fuel CO2 and the onset of the next glaciation David Archer Department from fossil fuel combustion will remain in the atmosphere for thousands of years, and $7% will remain beyond one hundred thousand years (Archer, 2005). We predict that a carbon release from fossil fuels

  3. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    impose a price on the carbon in their own fossil fuels forprice A nthropogenic climate change is driven by CO 2 emissions from the burning of fossil fuels (fossil fuel resources are suf?ciently concentrated such that, if the relatively few countries that extract the most fuels imposed a price

  4. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01

    dioxide emissions from fossil fuel consumption and cementannual variations in fossil fuel emissions, J. Geophys.including land, ocean and fossil fuel surface fluxes, have

  5. Fate of fossil fuel CO2 in geologic time David Archer

    E-Print Network [OSTI]

    climate perturbation may have time to interact with ice sheets, methane clathrate deposits, and glacial of public awareness and concern as does the production of long-lived nuclear wastes, for example. [3] Potential sources of new CO2 to the ocean/atmosphere carbon pools include fossil fuel carbon, changes

  6. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air

    E-Print Network [OSTI]

    2011-01-01

    Recent decreases in fossil-fuel emissions of ethane andp.p.b. since 1900 28 . Fossil-fuel, biofuel and biomass-the total emissions. The fossil-fuel emission histories for

  7. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    Riley, W.J.

    2008-01-01

    of radiocarbon and fossil fuel-derived CO2 in surface airindependent budgeting of fossil fuel CO2 over Europe by (contributions from fossil fuels, oceans, the stratosphere,

  8. Towards constraints on fossil fuel emissions from total column carbon dioxide

    E-Print Network [OSTI]

    Keppel-Aleks, G.; Wennberg, P. O; O'Dell, C. W; Wunch, D.

    2013-01-01

    spatial patterns of carbon dioxide emissions from nationalRotty, R. M. : Carbon-dioxide Emissions From Fossil-fuels –Dis- tribution of Carbon Dioxide Emissions From Fossil Fuel

  9. North American CO2 exchange: Inter comparison of modeled estimates with results from a fine scale atmospheric inversion

    E-Print Network [OSTI]

    Gourdji, Sharon M.

    2013-01-01

    2009),  High  resolution  fossil  fuel   combustion  CO 2  high-­?resolution  global  fossil  fuel  CO 2  emission  biospheric   Prior  –  fossil   fuels   Winds  &  

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    do Fossil Fuel Carbon Dioxide Emissions from California Go?Figure 1. 2004 Carbon Dioxide Emissions from Fuel CombustionImproving the Carbon Dioxide Emission Estimates from the

  11. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01

    do fossil fuel carbon dioxide emissions from California go?do fossil fuel carbon dioxide emissions from California go?1° distribution of carbon dioxide emissions from fossil fuel

  12. Direct Experiments on the Ocean Disposal of Fossil Fuel CO2

    SciTech Connect (OSTI)

    Barry, James, P.

    2010-05-26

    Funding from DoE grant # FG0204-ER63721, Direct Experiments on the Ocean Disposal of Fossil Fuel CO2, supposed several postdoctoral fellows and research activities at MBARI related to ocean CO2 disposal and the biological consequences of high ocean CO2 levels on marine organisms. Postdocs supported on the project included Brad Seibel, now an associate professor at the University of Rhode Island, Jeff Drazen, now an associate professor at the University of Hawaii, and Eric Pane, who continues as a research associate at MBARI. Thus, the project contributed significantly to the professional development of young scientists. In addition, we made significant progress in several research areas. We continued several deep-sea CO2 release experiments using support from DoE and MBARI, along with several collaborators. These CO2 release studies had the goal of broadening our understanding of the effects of high ocean CO2 levels on deep sea animals in the vicinity of potential release sites for direct deep-ocean carbon dioxide sequestration. Using MBARI ships and ROVs, we performed these experiments at depths of 3000 to 3600 m, where liquid CO2 is heavier than seawater. CO2 was released into small pools (sections of PVC pipe) on the seabed, where it dissolved and drifted downstream, bathing any caged animals and sediments in a CO2-rich, low-pH plume. We assessed the survival of organisms nearby. Several publications arose from these studies (Barry et al. 2004, 2005; Carman et al. 2004; Thistle et al. 2005, 2006, 2007; Fleeger et al. 2006, 2010; Barry and Drazen 2007; Bernhard et al. 2009; Sedlacek et al. 2009; Ricketts et al. in press; Barry et al, in revision) concerning the sensitivity of animals to low pH waters. Using funds from DoE and MBARI, we designed and fabricated a hyperbaric trap-respirometer to study metabolic rates of deep-sea fishes under high CO2 conditions (Drazen et al, 2005), as well as a gas-control aquarium system to support laboratory studies of the effects of high CO2 waters on marine animals (Barry et al. 2008). This system is capable of controlling oxygen, pH, and temperature of seawater for use in studies of the physiological responses of animals under acidified conditions. We have investigated the tolerance of deep- and shallow-living crabs to high CO2 levels (Pane and Barry 2007; Pane et al. 2008), and are now working on brachiopods (Barry et al. in prep.) and a comparison of deep and shallow living sea urchins. This research program, supported in part by DoE has contributed to a number of other publications authored or co-authored by Barry (Caldeira et al. 2005; Brewer and Barry 2008; Barry et al. 2006, 2010a,b,c; National Research Council, in press; Hoffman et al. in press) as well as over 40 invited talks since 2004, including Congressional briefings and testimony at U.S. Senate Hearings on Ocean Acidification. Through the grant period, the research emphasis shifted from studies of the effects of direct deep-sea carbon dioxide sequestration on deep-sea animals, to a broader conceptual framework of the effects of ocean acidification (whether purposeful or passive) on the physiology and survival of deep and shallow living marine animals. We feel that this has been a very productive program and are grateful to DoE for its support.

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  14. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  15. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01

    independent budgeting of fossil fuel CO 2 over Europe by (COcontributions from fossil fuels, oceans, the stratosphere,15 of 16 G04002 RILEY ET AL. : FOSSIL FUEL CO 2 TRANSPORT IN

  16. Evaluation of KDOT's Vehicle Fleet's CO2 Emissions and Possible Energy Reductions

    E-Print Network [OSTI]

    Nielsen, Eric

    2012-12-31

    Increasing energy demands require more energy extraction from fossil fuels. The energy is extracted through combustion and results in mainly CO2 emissions as well as other trace emissions. Reducing energy usage can save money and CO2 emissions...

  17. An Intergrated Hydrogen Production-CO2 Capture Process from Fossil Fuel

    SciTech Connect (OSTI)

    Z. Wang; K. B. Bota

    2006-03-15

    The major project objective is to determine the feasibility of using the char from coal and/or biomass pyrolysis, ammonia and CO2 emissions at smokestacks to produce clean hydrogen and a sequestered carbon fertilizer. During this work period, the project plan, design and test schedules were made on the basis of discussion with partner in experimental issues. Installation of pilot scale units was finished and major units tests were fully performed. Modification of the pyrolyzer, reformer and gas absorption tank have been done. Integration testing is performing recently. Lab scale tests have been performed. Field tests of char/fertilizer have been conducted.

  18. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    US power-plant carbon dioxide emissions data sets, Environ.Andres et al. : A synthesis of carbon dioxide emissions doi:A synthesis of carbon dioxide emissions from fossil-fuel

  19. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01

    1° distribution of carbon dioxide emissions from fossil fuelfossil fuel CO 2 emissions, Carbon Dioxide Inf. Anal.1995 emissions, scaled uniformly based on the Carbon Dioxide

  20. An Integrated Hydrogen Producton-CO2 Capture Process from Fossil Fuel

    SciTech Connect (OSTI)

    Z. Wang; K.B. Bota; D. Day

    2005-12-01

    The major project objective is to determine the feasibility of using the char from coal and/or biomass pyrolysis, ammonia and CO2 emissions at smokestacks to produce clean hydrogen and a sequestered carbon fertilizer. During this work period, literature review has been completed. The project plan, design and test schedules were made on the basis of discussion with partner in experimental issues. Installation of pilot scale units was finished and major units tests were fully performed. Modification of the pyrolyzer, reformer and gas absorption tank have been done. Integration testing is performing recently. Lab scale tests have been performed. Field tests of char/fertilizer have been conducted. The experimental results are discussed in this paper.

  1. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  2. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect (OSTI)

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  3. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air

    E-Print Network [OSTI]

    2011-01-01

    distribution and budget of ethane. J. Geophys. Res.Y. et al. Global budget of ethane and regional constraintsin fossil-fuel emissions of ethane and methane derived from

  4. Impacts of Renewable Generation on Fossil Fuel Unit Cycling: Costs and Emissions (Presentation)

    SciTech Connect (OSTI)

    Brinkman, G.; Lew, D.; Denholm, P.

    2012-09-01

    Prepared for the Clean Energy Regulatory Forum III, this presentation looks at the Western Wind and Solar Integration Study and reexamines the cost and emissions impacts of fossil fuel unit cycling.

  5. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    2008-01-01

    south and west of California), transport within and acrossFOSSIL FUEL CO 2 TRANSPORT IN CALIFORNIA EIA (2003), StateFOSSIL FUEL CO 2 TRANSPORT IN CALIFORNIA Stephens, B. , et

  6. Final Progress Report: Direct Experiments on the Ocean Disposal of Fossil Fuel CO2.

    SciTech Connect (OSTI)

    James P. Barry; Peter G. Brewer

    2004-05-25

    OAK-B135 This report summarizes activities and results of investigations of the potential environmental consequences of direct injection of carbon dioxide into the deep-sea as a carbon sequestration method. Results of field experiments using small scale in situ releases of liquid CO2 are described in detail. The major conclusions of these experiments are that mortality rates of deep sea biota will vary depending on the concentrations of CO2 in deep ocean waters that result from a carbon sequestration project. Large changes in seawater acidity and carbon dioxide content near CO2 release sites will likely cause significant harm to deep-sea marine life. Smaller changes in seawater chemistry at greater distances from release sites will be less harmful, but may result in significant ecosystem changes.

  7. An Integrated Hydrogen Production-CO2 Capture Process from Fossil Fuel

    SciTech Connect (OSTI)

    Zhicheng Wang

    2007-03-15

    The new technology concept integrates two significant complementary hydrogen production and CO{sub 2}-sequestration approaches that have been developed at Oak Ridge National Laboratory (ORNL) and Clark Atlanta University. The process can convert biomass into hydrogen and char. Hydrogen can be efficiently used for stationary power and mobile applications, or it can be synthesized into Ammonia which can be used for CO{sub 2}-sequestration, while char can be used for making time-release fertilizers (NH{sub 4}HCO{sub 3}) by absorption of CO{sub 2} and other acid gases from exhaust flows. Fertilizers are then used for the growth of biomass back to fields. This project includes bench scale experiments and pilot scale tests. The Combustion and Emission Lab at Clark Atlanta University has conducted the bench scale experiments. The facility used for pilot scale tests was built in Athens, GA. The overall yield from this process is 7 wt% hydrogen and 32 wt% charcoal/activated carbon of feedstock (peanut shell). The value of co-product activated carbon is about $1.1/GJ and this coproduct reduced the selling price of hydrogen. And the selling price of hydrogen is estimated to be $6.95/GJ. The green house experimental results show that the samples added carbon-fertilizers have effectively growth increase of three different types of plants and improvement ability of keeping fertilizer in soil to avoid the fertilizer leaching with water.

  8. Air Pollution Control Regulations: No. 13- Particulate Emissions from Fossil Fuel Fired Steam or Hot Water Generating Units (Rhode Island)

    Broader source: Energy.gov [DOE]

    The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and wood-fired steam or hot water generating units.

  9. Atmospheric benzenoid emissions from plants rival those from fossil fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Misztal, P. K.; Hewitt, C. N.; Wildt, J.; Blande, J. D.; Eller, A. S.D.; Fares, S.; Gentner, D. R.; Gilman, J. B.; Graus, M.; Greenberg, J.; et al

    2015-07-13

    Despite the known biochemical production of a range of aromatic compounds by plants and the presence of benzenoids in floral scents, the emissions of only a few benzenoid compounds have been reported from the biosphere to the atmosphere. Here, using evidence from measurements at aircraft, ecosystem, tree, branch and leaf scales, with complementary isotopic labeling experiments, we show that vegetation (leaves, flowers, and phytoplankton) emits a wide variety of benzenoid compounds to the atmosphere at substantial rates. Controlled environment experiments show that plants are able to alter their metabolism to produce and release many benzenoids under stress conditions. The functionsmore »of these compounds remain unclear but may be related to chemical communication and protection against stress. We estimate the total global secondary organic aerosol potential from biogenic benzenoids to be similar to that from anthropogenic benzenoids (~10 Tg y-1), pointing to the importance of these natural emissions in atmospheric physics and chemistry.« less

  10. CO? emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Méjean, Aurélie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine; Wada, Kenichi; van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  11. CO? emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Méjean, Aurélie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; et al

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increasesmore »strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.« less

  12. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    by electricity generation/CHP facilities by distillate fuelFossil Fuel Consumption for Electricity and Heat GenerationFossil Fuel Consumption for Electricity and Heat Generation

  13. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1997-05-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  14. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1996-01-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  15. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    In almost all cases, the emissions related to traded fuelsextraction (F Er ) and production (F Pr ) emissions (i.e. ,the net effect of emissions from traded fossil fuels; Top),

  16. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    2 from combustion of fossil fuels by existing infrastructureas well as estimates of fossil fuel emissions produced di-the combustion of fossil fuels by existing infrastructure

  17. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    E-Print Network [OSTI]

    2015-01-01

    CO 2 emissions from China’s cement production: methodologiesfossil fuel consumption and cement production. Geophys. Res.NTNU, 2006). 27. China Cement Association. China Cement

  18. Regional patterns of radiocarbon and fossil fuel-derived CO 2 in surface air across North America

    E-Print Network [OSTI]

    Hsueh, Diana Y; Krakauer, Nir Y; Randerson, James T; Xu, Xiaomei; Trumbore, Susan E; Southon, John R

    2007-01-01

    carbon sources. Possible future applications include testing for leaks from subterranean CO 2 sequestration

  19. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    International Energy Agency (OECD/IEA): CO 2 emissions fromcombustion, 2010 edition, OECD/IEA, Paris, 2010. Kashiwagi,data are generated by the IEA and are a no- table feature of

  20. GEOPHYSICAL RESEARCH LETTERS, VOL. 28, NO. 13, PAGES 2637-2640, JULY 1, 2001 Ocean release of fossil fuel CO2: A case study

    E-Print Network [OSTI]

    Drange, Helge

    of Norway at 65o N (see Fig. 3). The CO2 source can be deep water installations on the shelf or point sources on land [Eliasson et al., 1999; Broecker, 1997]. In both cases liquid CO2 can be piped or shipped are 200, 400 and 800 Gg-CO2, corresponding to CO2 emissions from conventional 55-220 MW gas power plants

  1. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  2. `Capture ready' regulation of fossil fuel power plants Betting the UK's carbon emissions on promises of future technology

    E-Print Network [OSTI]

    Haszeldine, Stuart

    power stations licensed in 2009 have had to set off land adjacent to the power plant as a capture ready`Capture ready' regulation of fossil fuel power plants ­ Betting the UK's carbon emissions interest in investing in new fossil fuelled power plants. The question is whether capture ready policy can

  3. Atmospheric Lifetime of Fossil Fuel Carbon Dioxide

    E-Print Network [OSTI]

    Atmospheric Lifetime of Fossil Fuel Carbon Dioxide David Archer,1 Michael Eby,2 Victor Brovkin,3 released from combustion of fossil fuels equilibrates among the various carbon reservoirs of the atmosphere literature on the atmospheric lifetime of fossil fuel CO2 and its impact on climate, and we present initial

  4. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01

    2004. Experience curves for power plant emission controlassessments of fossil fuel power plants with CO 2 capturethe future cost of power plants with CO 2 capture Edward S.

  5. Misrepresentation of the IPCC CO2 emission scenarios

    SciTech Connect (OSTI)

    Manning, Martin; Edmonds, James A.; Emori, S.; Grubler, Arnulf; Hibbard, Kathleen A.; Joos, Fortunat; Kainuma, M.; Keeling, Ralph; Kram, Tom; Manning, Andrew; Meinhausen, Malte; Moss, Richard H.; Nakicenovic, Nebojsa; Riahi, Keywan; Rose, Steven K.; Smith, Steven J.; Swart, Robert; Van Vuuren, Detlef

    2010-06-01

    Estimates of recent fossil fuel CO2 emissions have been compared with the IPCC SRES (Special Report on Emission Scenarios) emission scenarios that had been developed for analysis of future climate change, impacts and mitigation. In some cases this comparison uses averages across subgroups of SRES scenarios and for one category of greenhouse gases (industrial sources of CO2). That approach can be misleading and cause confusion as it is inconsistent with many of the papers on future climate change projections that are based on a specific subset of closely scrutinized SRES scenarios, known as illustrative marker scenarios. Here, we show that comparison between recent estimates of fossil fuel emissions trends and the SRES illustrative marker scenarios leads to the conclusion that recent trends are not outside the SRES range. Furthermore, the recent economic downturn appears to have brought actual emission back toward the middle of the SRES illustrative marker scenarios. We also note that SRES emission scenarios are designed to reflect potential alternative long-term trends in a world without climate policy intervention and the trend in the resulting climate change is not sensitive to short-term fluctuations.

  6. Commitment accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, SJ; Socolow, RH

    2014-01-01

    us My IOPscience Commitment accounting of CO2 emissions This9326/9/8/084018 Commitment accounting of CO 2 emissionsthe potential for ‘commitment accounting’ to inform public

  7. A bottom up approach to on-road CO2 emissions estimates: improved spatial accuracy and applications for regional

    E-Print Network [OSTI]

    Wing, Ian Sue

    point sources, but California's also sets future fuel economy standards for vehicles. Regulating-road transportation is responsible for 28% of all U.S. fossil-fuel CO2 emissions. Mapping vehicle emissions at regional scales is challenging due to data limitations. Existing emission inventories use spatial proxies

  8. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01

    Neutral Biosphere (NB) GFED NEP GFED Uncorrected Biomass2 (1) Best case = best ocean + GFED (NEP+best BB) + fossil2) Takahashi ocean + GFED (NEP+best BB) + fossil fuel (3)

  9. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward...

  10. A Bottom up Approach to on-Road CO2 Emissions Estimates: Improved Spatial Accuracy and Applications for Regional Planning

    E-Print Network [OSTI]

    Hutyra, Lucy R.

    targets for power plants and other point sources, but California's also sets future fuel economy standards Supporting Information ABSTRACT: On-road transportation is responsible for 28% of all U.S. fossil- fuel CO2 emissions. Mapping vehicle emissions at regional scales is challenging due to data limitations. Existing

  11. Patterns of Fossil-based CO2 Emissions from US Croplands Contact: Tris West, 865-574-7322, westto@ornl.gov

    E-Print Network [OSTI]

    Post, Wilfred M.

    fossil-fuel combustion. A method was developed to calculate on-site and off-site energy and CO2 emissionsPatterns of Fossil-based CO2 Emissions from US Croplands Contact: Tris West, 865-574-7322, westto@ornl.gov Funding: DOE Office of Science, Biological and Environmental Research; and DOE Office of Biomass

  12. Future climate trends from a first-difference atmospheric carbon dioxide regression model involving emissions scenarios for business as usual and for peak fossil fuel

    E-Print Network [OSTI]

    Leggett, L M W

    2014-01-01

    This paper investigates the implications of the future continuation of the demonstrated past (1960-2012) strong correlation between first-difference atmospheric CO2 and global surface temperature. It does this, for the period from the present to 2050, for a comprehensive range of future global fossil fuel energy use scenarios. The results show that even for a business-as-usual (the mid-level IPCC) fossil fuel use estimate, global surface temperature will rise at a slower rate than for the recent period 1960-2000. Concerning peak fossil fuel, for the most common scenario the currently observed (1998-2013)temperature plateau will turn into a decrease. The observed trend to date for temperature is compared with that for global climate disasters: these peaked in 2005 and are notably decreasing. The temperature and disaster results taken together are consistent with either a reduced business-as-usual fossil fuel use scenario into the future, or a peak fossil fuel scenario, but not with the standard business-as-usu...

  13. What are the likely roles of fossil fuels in the next 15, 50, and 100 years, with or without active controls on greenhouse gas emissions

    SciTech Connect (OSTI)

    Kane, R.L. (USDOE Assistant Secretary for Fossil Energy, Washington, DC (USA)); South, D.W. (Argonne National Lab., IL (USA))

    1990-01-01

    Since the industrial revolution, the production and utilization of fossil fuels have been an engine driving economic and industrial development in many countries worldwide. However, future reliance on fossil fuels has been questioned due to emerging concerns about greenhouse gas (GHG) emissions, particularly carbon dioxide (CO{sub 2}), and its potential contribution to global climate change (GCC). While substantial uncertainties exist regarding the ability to accurately predict climate change and the role of various greenhouse gases, some scientists and policymakers have called for immediate action. As a result, there have been many proposals and worldwide initiatives to address the perceived problem. In many of these proposals, the premise is that CO{sub 2} emissions constitute the principal problem, and, correspondingly, that fossil-fuel combustion must be curtailed to resolve this problem. This paper demonstrates that the worldwide fossil fuel resource base and infrastructure are extensive and thus, will continue to be relied on in developed and developing countries. Furthermore, in the electric generating sector (the focus of this paper), numerous clean coal technologies (CCTs) are currently being demonstrated (or are under development) that have higher conversion efficiencies, and thus lower CO{sub 2} emission rates than conventional coal-based technologies. As these technologies are deployed in new power plant or repowering applications to meet electrical load growth, CO{sub 2} (and other GHG) emission levels per unit of electricity generated will be lower than that produced by conventional fossil-fuel technologies. 37 refs., 14 figs., 11 tabs.

  14. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    on North American carbon dioxide ex- change: CarbonTracker,A synthesis of carbon dioxide emissions from fossil-fuelof two US power-plant carbon dioxide emissions data sets,

  15. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Emissions Monitoring Combined Heat and Power Carbon Dioxide18.7 to 36.8 *Combined Heat and Power (CHP) ** Uncertaintiesin electric and Combined Heat and Power (CHP) plants, diesel

  16. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    all countries where energy data and emission estimates existwith time due to increased energy data United 1752 is of thetime due to increased energy data availabil- ity and the

  17. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  18. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  19. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  20. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01

    be corrected by a net outgassing of $0.6 Pg C/yr from riverone of the major regions of oceanic CO 2 outgassing.El Nin˜o conditions, outgassing is decreased by a thickening

  1. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect (OSTI)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025. Other potential benefits of the demonstration include developing a passive technology for water treatment for trace metal and nutrient release reductions, using power plant by-products to improve coal mine land reclamation and carbon sequestration, developing wildlife habitat and green-space around production facilities, generating Total Maximum Daily Load (TMDL) credits for the use of process water, and producing wood products for use by the lumber and pulp and paper industry. Project activities conducted during the five year project period include: Assessing tree cultivation and other techniques used to sequester carbon; Project site assessment; Greenhouse studies to determine optimum plant species and by-product application; Designing, constructing, operating, monitoring, and evaluating the CCWESTRS system; and Reporting (ongoing). The ability of the system to sequester carbon will be the primary measure of effectiveness, measured by accessing survival and growth response of plants within the CCWESTRS. In addition, costs associated with design, construction, and monitoring will be evaluated and compared to projected benefits of other carbon sequestration technologies. The test plan involves the application of three levels each of two types of power plant by-products--three levels of FGD gypsum mulch, and three levels of ash pond irrigation water. This design produces nine treatment levels which are being tested with two species of hardwood trees (sweet gum and sycamore). The project is examining the effectiveness of applications of 0, 8-cm, and 15-cm thick gypsum mulch layers and 0, 13 cm, and 25 cm of coal fly ash water for irrigation. Each treatment combination is being replicated three times, resulting in a total of 54 treatment plots (3 FGD gypsum levels X 3 irrigation water levels x 2 tree species x 3 replicates). Survival and growth response of plant species in terms of sequestering carbon in plant material and soil will be the primary measure of effectiveness of each treatment. Additionally, the ability of the site soils and unsaturated zone subsurface m

  2. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    NONE

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  3. CO2 interaction with aquifer and seal on geological timescales: the Miller oilfield, UK North Sea 

    E-Print Network [OSTI]

    Lu, Jiemin

    2008-01-01

    Carbon Capture and Storage (CCS) has been identified as a feasible technology to reduce CO2 emissions whilst permitting the continued use of fossil fuels. Injected CO2 must remain efficiently isolated from the atmosphere ...

  4. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    emission and resource accounting. Ecol Econ 69:211–222. 12.Consumption-based accounting of CO 2 emissions Steven J.Consump- tion-based accounting of CO 2 emissions differs

  5. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    SciTech Connect (OSTI)

    Riley, W.J.; Hsueh, D.Y.; Randerson, J.T.; Fischer, M.L.; Hatch, J.G.; Pataki, D.E.; Wang, W.; Goulden, M.L.

    2008-05-01

    Characterizing flow patterns and mixing of fossil fuel-derived CO{sub 2} is important for effectively using atmospheric measurements to constrain emissions inventories. Here we used measurements and a model of atmospheric radiocarbon ({sup 14}C) to investigate the distribution and fluxes of atmospheric fossil fuel CO{sub 2} across the state of California. We sampled {sup 14}C in annual C{sub 3} grasses at 128 sites and used these measurements to test a regional model that simulated anthropogenic and ecosystem CO{sub 2} fluxes, transport in the atmosphere, and the resulting {sup 14}C of annual grasses ({Delta}{sub g}). Average measured {Delta}{sub g} in Los Angeles, San Francisco, the Central Valley, and the North Coast were 27.7 {+-} 20.0, 44.0 {+-} 10.9, 48.7 {+-} 1.9, and 59.9 {+-} 2.5{per_thousand}, respectively, during the 2004-2005 growing season. Model predictions reproduced regional patterns reasonably well, with estimates of 27.6 {+-} 2.4, 39.4 {+-} 3.9, 46.8 {+-} 3.0, and 59.3 {+-} 0.2{per_thousand} for these same regions and corresponding to fossil fuel CO{sub 2} mixing ratios (Cf) of 13.7, 6.1, 4.8, and 0.3 ppm. {Delta}{sub g} spatial heterogeneity in Los Angeles and San Francisco was higher in the measurements than in the predictions, probably from insufficient spatial resolution in the fossil fuel inventories (e.g., freeways are not explicitly included) and transport (e.g., within valleys). We used the model to predict monthly and annual transport patterns of fossil fuel-derived CO{sub 2} within and out of California. Fossil fuel CO{sub 2} emitted in Los Angeles and San Francisco was predicted to move into the Central Valley, raising Cf above that expected from local emissions alone. Annually, about 21, 39, 35, and 5% of fossil fuel emissions leave the California airspace to the north, east, south, and west, respectively, with large seasonal variations in the proportions. Positive correlations between westward fluxes and Santa Ana wind conditions were observed. The southward fluxes over the Pacific Ocean were maintained in a relatively coherent flow within the marine boundary layer, while the eastward fluxes were more vertically dispersed. Our results indicate that state and continental scale atmospheric inversions need to consider areas where concentration measurements are sparse (e.g., over the ocean to the south and west of California), transport within and across the marine boundary layer, and terrestrial boundary layer dynamics. Measurements of {Delta}{sub g} can be very useful in constraining these estimates.

  6. CO2 Emissions Mitigation and Technological Advance: An

    E-Print Network [OSTI]

    PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Updated Analysis of Advanced/2003) #12;PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Analysis of Advanced Technology, by itself, the scope or quantity of greenhouse gas emissions reductions needed to achiev

  7. Fossil fuel furnace reactor

    DOE Patents [OSTI]

    Parkinson, William J. (Los Alamos, NM)

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  8. Seasonal exchange of CO 2 and delta 18 O-CO 2 varies with postfire succession in boreal forest ecosystems

    E-Print Network [OSTI]

    Welp, L. R; Randerson, J. T; Liu, H. P

    2006-01-01

    shows no unidirectional, fossil fuel – controlled trend (asthe ocean, stratosphere, fossil fuels, and other terrestrialwhich the secular trend from fossil fuel emissions has been

  9. Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

    E-Print Network [OSTI]

    are a strong motivation to reduce CO2 emissions from industrial processes. Burning of fossil fuel to generate electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gasEnhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification Youn-Sang Bae

  10. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    gross world product, E is global energy consumption, Authorglobal consumption-based CO 2 emissions inventory and calcula- tions of associated consumption-based energyenergy consumption, and combustion-based CO 2 emissions of each region sector were all taken from Version 7 of the Global

  11. The Energy and CO2 Emissions Impact of

    E-Print Network [OSTI]

    The Energy and CO2 Emissions Impact of Renewable Energy Development in China Xiliang Zhang, Tianyu://globalchange.mit.edu/ Printed on recycled paper #12;1 The Energy and CO2 Emissions Impact of Renewable Energy Development Qi, and Valerie J. Karplus Report No. 242 April 2013 China Energy & Climate Project TSINGHUA - MIT

  12. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    is the largest source of NEU-CO2 emissions (233 Mt CO 2 ),black (another key source of NEU-CO2 emissions reported bysource and geographical distributions of NEU-CO2 emissions.

  13. An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2

    E-Print Network [OSTI]

    Hoffman, Forrest M.

    An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2 D. J. Erickson III,1,2 R. T. Mills,1 J. Gregg,3 T. J. Blasing,4 F. M. Hoffman,1 R. J. Andres,4 of anthropogenic CO2 are presented. Approximating the seasonal CO2 emission cycle using a 2-harmonic Fourier series

  14. The Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    2009-01-18

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH,

  15. Large historical changes of fossil-fuel black carbon aerosols T. Novakov,1

    E-Print Network [OSTI]

    Knowles, David William

    Large historical changes of fossil-fuel black carbon aerosols T. Novakov,1 V. Ramanathan,2 J. E the past century in response to changes of fossil-fuel utilization, technology developments, and emission controls. We estimate historical trends of fossil- fuel BC emissions in six regions that represent about

  16. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01

    China's 2008 Total CO 2 Emissions from Energy Consumption:10. China's 2008 Total CO 2 Emissions from Energy: Sectoral16 Table 11. China's 2008 CO 2 Emissions from Energy:

  17. Rapid growth in CO2 emissions after the 2008-2009 global financial crisis

    SciTech Connect (OSTI)

    Peters, Glen P.; Marland, Gregg; Le Quere, Corinne; Boden, Thomas A; Canadell, Josep; Raupach, Michael

    2011-01-01

    Global carbon dioxide emissions from fossil-fuel combustion and cement production grew 5.9% in 2010, surpassed 9 Pg of carbon (Pg C) for the first time, and more than offset the 1.4% decrease in 2009. The impact of the 2008 2009 global financial crisis (GFC) on emissions has been short-lived owing to strong emissions growth in emerging economies, a return to emissions growth in developed economies, and an increase in the fossil-fuel intensity of the world economy.

  18. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    and opportunities in accounting for non-energy use CO 2emissions (233 Mt CO 2 ), accounting for around one-third ofCO2 emissions? 3 Accounting challenges and opportunities

  19. GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2)

    E-Print Network [OSTI]

    Green, Donna

    GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2) from the combustion- related CO2 emissions have risen 130-fold since 1850--from 200 million tons to 27 billion tons a year--and are projected to rise another 60 percent by 2030 (see Figure 1).1 Most of the world's emissions come from

  20. Industrial CO2 emissions as a proxy for anthropogenic influence on lower tropospheric temperature trends

    E-Print Network [OSTI]

    Laat, Jos de

    Industrial CO2 emissions as a proxy for anthropogenic influence on lower tropospheric temperature­2001 are spatially correlated to anthropogenic surface CO2 emissions, which we use as a measure of industrialization change, CO2 emissions. Citation: de Laat, A. T. J., and A. N. Maurellis (2004), Industrial CO2 emissions

  1. Method for reducing CO2, CO, NOX, and SOx emissions

    DOE Patents [OSTI]

    Lee, James Weifu (Oak Ridge, TN); Li, Rongfu (Zhejiang, CH)

    2002-01-01

    Industrial combustion facilities are integrated with greenhouse gas-solidifying fertilizer production reactions so that CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions can be converted prior to emission into carbonate-containing fertilizers, mainly NH.sub.4 HCO.sub.3 and/or (NH.sub.2).sub.2 CO, plus a small fraction of NH.sub.4 NO.sub.3 and (NH.sub.4).sub.2 SO.sub.4. The invention enhances sequestration of CO.sub.2 into soil and the earth subsurface, reduces N0.sub.3.sup.- contamination of surface and groundwater, and stimulates photosynthetic fixation of CO.sub.2 from the atmosphere. The method for converting CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions into fertilizers includes the step of collecting these materials from the emissions of industrial combustion facilities such as fossil fuel-powered energy sources and transporting the emissions to a reactor. In the reactor, the CO.sub.2, CO, N.sub.2, SO.sub.x, and/or NO.sub.x are converted into carbonate-containing fertilizers using H.sub.2, CH.sub.4, or NH.sub.3. The carbonate-containing fertilizers are then applied to soil and green plants to (1) sequester inorganic carbon into soil and subsoil earth layers by enhanced carbonation of groundwater and the earth minerals, (2) reduce the environmental problem of NO.sub.3.sup.- runoff by substituting for ammonium nitrate fertilizer, and (3) stimulate photosynthetic fixation of CO.sub.2 from the atmosphere by the fertilization effect of the carbonate-containing fertilizers.

  2. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    as NEU-CO2 emissions (i.e. , a carbon storage fraction ofand stored fractions. It follows that, in practice, NEU-CO2

  3. REPORT OF THE FOSSIL FUELS REVIEW GROUP

    E-Print Network [OSTI]

    REPORT OF THE FOSSIL FUELS REVIEW GROUP APRIL 2015 1 #12;Table of Contents 1. Background.....................................................4 c. Evidence on Fossil Fuel Dependence, Mitigation Strategies and Relative Contributions by Fuel Divestment from All Energy Related Fossil Fuel Companies........... 13 4. Evaluating the Options

  4. Automobile Fuel; Economy and CO2 Emissions in Industrialized Countries: Troubling Trends through 2005/6

    E-Print Network [OSTI]

    Schipper, Lee

    2008-01-01

    related to fuel use or emissions than car ownership alone.Limiting CO2 Emissions from new cars promulgated by the EU (of 120 gm/km CO2 emissions from new cars, which corresponds

  5. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    Future CO 2 Emissions and Climate Change from Existing Energynon-energy emissions could diminish in the future. In viewfuture CO 2 emissions is much greater in China, because China’s energy

  6. Peak CO2? China's Emissions Trajectories to 2050

    SciTech Connect (OSTI)

    Zhou, Nan; Fridley, David G.; McNeil, Michael; Zheng, Nina; Ke, Jing; Levine, Mark

    2011-05-01

    As a result of soaring energy demand from a staggering pace of economic growth and the related growth of energy-intensive industry, China overtook the United States to become the world's largest contributor to CO{sub 2} emissions in 2007. At the same time, China has taken serious actions to reduce its energy and carbon intensity by setting both short-term energy intensity reduction goal for 2006 to 2010 as well as long-term carbon intensity reduction goal for 2020. This study focuses on a China Energy Outlook through 2050 that assesses the role of energy efficiency policies in transitioning China to a lower emission trajectory and meeting its intensity reduction goals. In the past years, LBNL has established and significantly enhanced the China End-Use Energy Model based on the diffusion of end-use technologies and other physical drivers of energy demand. This model presents an important new approach for helping understand China's complex and dynamic drivers of energy consumption and implications of energy efficiency policies through scenario analysis. A baseline ('Continued Improvement Scenario') and an alternative energy efficiency scenario ('Accelerated Improvement Scenario') have been developed to assess the impact of actions already taken by the Chinese government as well as planned and potential actions, and to evaluate the potential for China to control energy demand growth and mitigate emissions. It is a common belief that China's CO{sub 2} emissions will continue to grow throughout this century and will dominate global emissions. The findings from this research suggest that this will not likely be the case because of saturation effects in appliances, residential and commercial floor area, roadways, railways, fertilizer use, and urbanization will peak around 2030 with slowing population growth. The baseline and alternative scenarios also demonstrate that the 2020 goals can be met and underscore the significant role that policy-driven energy efficiency improvements will play in carbon mitigation along with a decarbonized power supply through greater renewable and non-fossil fuel generation.

  7. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    E-Print Network [OSTI]

    Riley, W.J.

    2008-01-01

    south and west of California), transport within and acrossCalifornia and their relationships with atmospheric transportfossil fuel CO 2 transport out of California. The figure

  8. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    He, et. al. 2005. “Oil consumption and CO2 emissions inHe, et. al. 2005. “Oil consumption and CO2 emissions inin all types of oil consumption are needed to reduce crude

  9. Diesel Engine CO2 and SOx Emission Compliance Strategy for the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 and SOx Emission Compliance Strategy for the Royal Navy (RN) and Royal Fleet Auxiliary (RFA) Flotillas Diesel Engine CO2 and SOx Emission Compliance Strategy for the Royal Navy...

  10. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  11. The dilemma of fossil fuel use and global climate change

    SciTech Connect (OSTI)

    Judkins, R.R.; Fulkerson, W. (Oak Ridge National Lab., TN (USA)); Sanghvi, M.K. (Amoco Corp., Chicago, IL (USA))

    1991-01-01

    The use of fossil fuels and relationship to climate change is discussed. As the use of fossil fuels has grown, the problems of protecting the environment and human health and safety have also grown, providing a continuing challenge to technological and managerial innovation. Today that challenge is to control atmospheric emissions from combustion, particularly those emissions that cause acidic deposition, urban pollution, and increasing concentrations of greenhouse gases. Technology for reducing acidic deposition is available and needs only to be adopted, and the remedies for urban pollution are being developed and tested. How effective or expensive these will be remains to be determined. The control of emissions of the greenhouse gas, CO{sub 2}, seems possible only be reducing the total amounts of fossil fuels used worldwide, and by substituting efficient natural gas technologies for coal. Long before physical depletion forces the transition away from fossil fuels, it is at least plausible and even likely that the greenhouse effect will impose a show-stopping constraint. If such a transition were soon to be necessary, the costs would be very high because substitute energy sources are either limited or expensive or undesirable for other reasons. Furthermore, the costs would be unevenly felt and would be more oppressive for developing nations because they would be least able to pay and, on average, their use rates of fossil fuels are growing much faster than those of many industrialized countries. It is prudent, therefore, to try to manage the use of fossil fuels as if a greenhouse constraint is an important possibility.

  12. TransCom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO 2 fluxes, 1988-2003

    E-Print Network [OSTI]

    2006-01-01

    dioxide emissions from fossil fuel consumption and cementthe consumption and flaring of fossil fuels, 1980 – present,of the increase: fossil fuel burning and deforestation.

  13. Estimation of CO2 Emissions from China's Cement Production: Methodologies and Uncertainties

    E-Print Network [OSTI]

    Ke, Jing

    2014-01-01

    emissions from electricity consumption. This paper examinesmainly from electricity consumption for cement production,CO 2 emissions from electricity consumption are usually

  14. Estakhri and Saylak 1 Potential for Reduced Greenhouse Gas Emissions in Texas Through the Use of

    E-Print Network [OSTI]

    emissions are from the transportation sector. The next largest source of CO2 emissions is from per cent of CO2 emissions come from the combustion of fossil fuels, and approximately 30% of those the manufacture of cement and account for approximately 10% of all CO2 emissions (1). When faced

  15. Policy Choice:Forest or Fuel? The demand for biofuels, driven by the desire to reduce fossil fuel use and CO2 emissions, has resulted in

    E-Print Network [OSTI]

    , the global production of palm oil increased 4.6-fold from 4.5 million to 20.9 million tonnes per year. (1). · Indonesia and Malaysia produce 88 % of the world's palm oil. · Nearly half of a projected 57% increase in palm oil production is due to biofuel demand (3) · Palm oil price is up 70% in 2007 (11

  16. Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source

    E-Print Network [OSTI]

    Boyer, Edmond

    Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source measurement, tube effects, CO2 infrared radiation 1. Introduction The knowledge of very high temperature for instance that the IR emission of the CO2 molecule remains predominant at temperatures as high as 4000 K [1

  17. Implications of "peak oil" for atmospheric CO2 and climate

    E-Print Network [OSTI]

    Kharecha, P A

    2007-01-01

    Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

  18. Disclosure of Permitted Communication Concerning Fossil Fuel...

    Energy Savers [EERE]

    Fossil Fuel Energy Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No. EERE-2010-BT-STD-0031; RIN 1904-AB96 Disclosure of Permitted...

  19. Hybrid solar-fossil fuel power generation

    E-Print Network [OSTI]

    Sheu, Elysia J. (Elysia Ja-Zeng)

    2012-01-01

    In this thesis, a literature review of hybrid solar-fossil fuel power generation is first given with an emphasis on system integration and evaluation. Hybrid systems are defined as those which use solar energy and fuel ...

  20. A Statistical Model to Assess Indirect CO2 Emissions of the UAE Residential Sector 

    E-Print Network [OSTI]

    Radhi, H.; Fikry, F.

    2010-01-01

    and increasing economic expenditure with huge architectural projects and population growth rates and a fairly low energy cost, the UAE?s energy consumption has increased tremendously, making it one of the highest energy consumers per capita in the world [1... ) Electricity CO2 emissions Figure 2 Increase in CO2 emissions relative to the use of energy [3] To tackle with CO2 emissions and global warming issues, UAE began planning regulation energy efficiency and environmental codes for buildings. Therefore, new...

  1. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    for preliminary cost–bene?t analyses of discrete NEU-CO2of the costs and bene?ts of various NEU-CO2 emissionscosts and GHG emissions reduction bene?ts as compared to competing options—will require greater NEU-CO2

  2. emissions: mineral carbonation and Finnish pulp and paper industry (CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use, utilisation and long-term storage of carbon dioxide (CO2) in the pulp and paper industry. The Geological of serpentinites in energy and metal industry (ECOSERP) Carl-Johan Fogelholm, Project leader, professor Sanni

  3. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Shearer, C; Bistline, J; Inman, M; Davis, SJ; Davis, SJ

    2014-01-01

    state-level cost and bene?t estimates of renewable portfoliostandards National Renewable Energy Laboratory Technicalnatural gas supply on US renewable energy and CO 2 emissions

  4. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy...

  5. Reading for Thursday Emissions scenario summary

    E-Print Network [OSTI]

    Schweik, Charles M.

    emissions, for year 2000 #12;USA ­ CO2 emissions from fossil fuel combustion (2005) US EPA #12;#12;#12;Decreasing 13C strongly suggests that the source of atmospheric CO2 is fossil carbon #12;Line of evidence #1Reading for Thursday · Emissions scenario summary: ­ Read pages 3-6 · IPCC Chapter 11 (Regional

  6. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  7. Regional GHG Emissions Stat s Greenhouse Gas and the Regional

    E-Print Network [OSTI]

    ,00070.0 Historical CO2 Emissions of the NW Power System CO2 Emissions Hydro Gen Fossil Fuel Gen (NG + Coal) Wind Gen6/5/2013 1 Regional GHG Emissions Stat s Greenhouse Gas and the Regional Power System Symposium power system All emissions are displayed in short tons (not metric tons) The Pacific Northwest (PNW

  8. Climatedependent CO2 emissions from lakes Sarian Kosten,1

    E-Print Network [OSTI]

    Cole, Jonathan J.

    in carbon dioxide partial pressure (pCO2) in 83 shallow lakes over a large climatic gradient in South influence lakes' metabolism as well. For instance through its effect on the hydraulic residence time, which

  9. Model limits on the role of volcanic carbon emissions in regulating glacialinterglacial CO2 variations

    E-Print Network [OSTI]

    Fortunat, Joos

    Model limits on the role of volcanic carbon emissions in regulating glacial­interglacial CO2 (2009) proposed that an increase in volcanic activity provoked by ice sheet melting contributed emissions in regulating glacial­interglacial CO2 variations, but uncertainties prevent a firm conclusion

  10. THE POTENTIAL FOR CO2 EMISSIONS TRADING IN TRANSPORT: THE CASE OF PERSONAL VEHICLES AND FREIGHT

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 THE POTENTIAL FOR CO2 EMISSIONS TRADING IN TRANSPORT: THE CASE OF PERSONAL VEHICLES AND FREIGHT, it is of some interest to explore the inclusion of road transport in emission trading schemes. Starting from

  11. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    in trade (EET) and therefore equals emissions embodied inexports (EEE) less emissions embodied in imports (EEI).re?ects the net export of emissions and a negative value

  12. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong David W. Keith April 11, 2003 Abstract Fossil fuels can be used with minimal atmospheric emissions of carbon diox, the cost of sequestration and the energy penalty (the energy necessary to capture, transport and inject

  13. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  14. Drivers of the US CO2 emissions 1997-2013

    E-Print Network [OSTI]

    2015-01-01

    drivers of regional carbon dioxide emissions for China. J.D. & Rose, A. Carbon dioxide emissions in the U.S. economy.Analysis of Carbon Dioxide Emission Changes in Germany -

  15. OPTIMAL OPERATION OF AN INTEGRATED ENERGY PARK INCLUDING FOSSIL FUEL POWER GENERATION,

    E-Print Network [OSTI]

    Stanford University

    OPTIMAL OPERATION OF AN INTEGRATED ENERGY PARK INCLUDING FOSSIL FUEL POWER GENERATION, CO2 CAPTURE combustion turbine, and wind generation. Energy park com- ponents are modeled using energy and mass balances. A formal optimization proce- dure is used to determine the optimal hourly dispatch of energy park

  16. Carbon capture technology: future fossil fuel use and mitigating climate change

    E-Print Network [OSTI]

    sources for countries heavily reliant on imported fuels4 . Why CCS is not just a synonym for `clean coal'? CCS technology is most frequently discussed in the context of capturing CO2 from coal-fired powerCarbon capture technology: future fossil fuel use and mitigating climate change DR N FloRiN aND DR

  17. Will Economic Restructuring in China Reduce Trade-Embodied CO2 Emissions?

    E-Print Network [OSTI]

    Qi, Tianyu

    We calculate CO2 emissions embodied in China’s net exports using a multi-regional input-output database. We find that the majority of China’s export-embodied CO2 is associated with production of machinery and equipment ...

  18. Gas-phase CO2 emission toward Cepheus A East: the result of shock activity?

    E-Print Network [OSTI]

    P. Sonnentrucker; E. González-Alfonso; D. A. Neufeld; E. A. Bergin; G. J. Melnick; W. J. Forrest; J. L. Pipher; D. M. Watson

    2006-09-05

    We report the first detection of gas-phase CO2 emission in the star-forming region Cepheus A East, obtained by spectral line mapping of the v2 bending mode at 14.98 micron with the Infrared Spectrograph (IRS) instrument onboard the Spitzer Space Telescope. The gaseous CO2 emission covers a region about 35'' x 25'' in extent, and results from radiative pumping by 15 micron continuum photons emanating predominantly from the HW2 protostellar region. The gaseous CO2 exhibits a temperature distribution ranging from 50 K to 200 K. A correlation between the gas-phase CO2 distribution and that of H2 S(2), a tracer of shock activity, indicates that the CO2 molecules originate in a cool post-shock gas component associated with the outflow powered by HW2. The presence of CO2 ice absorption features at 15.20 micron toward this region and the lack of correlation between the IR continuum emission and the CO2 gas emission distribution further suggest that the gaseous CO2 molecules are mainly sputtered off grain mantles -- by the passage of slow non-dissociative shocks with velocities of 15-30 km/s -- rather than sublimated through grain heating.

  19. Spatial Disaggregation of CO2 Emissions for the State of California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

    2008-06-11

    This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel dominating in other counties.The CO2 emissions data by county and source are available upon request.

  20. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground

    SciTech Connect (OSTI)

    Oldenburg

    2009-07-30

    July 21, 2009 Berkeley Lab summer lecture: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  1. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  2. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.

    2009-07-21

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  3. Long-term effects of anthropogenic CO2 emissions simulated with a complex earth system model

    E-Print Network [OSTI]

    Winguth, Arne

    Long-term effects of anthropogenic CO2 emissions simulated with a complex earth system model Uwe earth system model con- sisting of an atmospheric general circulation model, an ocean general

  4. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    Motor Vehicle Growth, Oil Demand and CO2 Emissions through61 4.3.2 Crude Oil Demand and Tradethe increase in crude oil demand is driven by a burgeoning

  5. Measurement Challenges and Metrology for Monitoring CO2 Emissions from Smokestacks

    E-Print Network [OSTI]

    Measurement Challenges and Metrology for Monitoring CO2 Emissions from Smokestacks NIST with an instrument that has the highest level of precision. The smaller the unit, or fraction of a unit

  6. Dynamics of Implementation of Mitigating Measures to Reduce CO2 Emissions from Commercial Aviation

    E-Print Network [OSTI]

    Kar, Rahul

    2010-07-13

    Increasing demand for air transportation and growing environmental concerns motivate the need to implement measures to reduce CO2 emissions from aviation. Case studies of historical changes in the aviation industry have ...

  7. Diesel Passenger Car Technology for Low Emissions and CO2 Compliance

    Broader source: Energy.gov [DOE]

    Cost effective reduction of legislated emissions (including CO2) is a major issue. NOx control must not be a limiting factor to the long term success of Diesel engines.

  8. Ris-R-1203(EN) The Feasibility of Domestic CO2 Emissions

    E-Print Network [OSTI]

    Risø-R-1203(EN) The Feasibility of Domestic CO2 Emissions Trading in Poland By Jochen Hauff Edited feasible in Poland. However, a pilot emissions trading system in the power and Combined Heat and Power (CHP future introduction of a comprehensive system and for the emerging international emissions trading system

  9. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    separation of production and consumption complicates theto compare production- and consumption-based emissions2008) From production-based to consumption-based national

  10. 12 Absolute versus Intensity Limits for CO2 Emission

    E-Print Network [OSTI]

    as a component of cli- mate policy in the UK Emissions Trading Scheme (UK DEFRA 2001),2 and in 2001 the Bush

  11. Drivers of the US CO2 emissions 1997-2013

    E-Print Network [OSTI]

    2015-01-01

    Analysis (2014). 12. EIA. International Energy Statistics.U.S. Energy Information Administration 13. Afsah, S. &decomposition analysis applied to energy and emissions: some

  12. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith Abstract Fossil fuels can be used with minimal atmo- spheric emissions of carbon dioxide, the cost of sequestration and the energy penalty (the energy necessary to capture, transport and inject

  13. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    the shares of AIS electricity generation by fuel. AIS powerhistorical electricity generation by primary fuel. ThermalNon-Fossil Fuel Electricity Generation (kgce/kWh) ..

  14. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    S3). Net exports of emissions from China, Russia, and theof exports from emerging markets such as China, Russia, andRussia, India, and the Middle East is consistently far less than that of their exports,

  15. Decarbonization and the time-delay between peak CO2 emissions and concentrations

    E-Print Network [OSTI]

    Seshadri, Ashwin K

    2015-01-01

    Carbon-dioxide (CO2) is the main contributor to anthropogenic global warming, and the timing of its peak concentration in the atmosphere is likely to govern the timing of maximum radiative forcing. While dynamics of atmospheric CO2 is governed by multiple time-constants, we idealize this by a single time-constant to consider some of the factors describing the time-delay between peaks in CO2 emissions and concentrations. This time-delay can be understood as the time required to bring CO2 emissions down from its peak to a small value, and is governed by the rate of decarbonizaton of economic activity. This decarbonization rate affects how rapidly emissions decline after having achieved their peak, and a rapid decline in emissions is essential for limiting peak radiative forcing. Long-term mitigation goals for CO2 should therefore consider not only the timing of peak emissions, but also the rate of decarbonization. We discuss implications for mitigation of the fact that the emissions peak corresponds to small bu...

  16. CO2 Emissions from Fuel Combustion | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEATCNAA Jump to:Emissions from

  17. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO 2 concentration data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ogle, Stephen; Davis, Kenneth J.; Lauvaux, Thomas; Schuh, Andrew E.; Cooley, Dan; West, Tristram O.; Heath, L.; Miles, Natasha; Richardson, S. J.; Breidt, F. Jay; et al

    2015-03-10

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Verification could include a variety of evidence, but arguably the most convincing verification would be confirmation of a change in GHG concentrations in the atmosphere that is consistent with reported emissions to the UNFCCC. We report here on a case study evaluating this option based on a prototype atmospheric CO2 measurement network deployed in the Mid-Continent Region of themore »conterminous United States. We found that the atmospheric CO2 measurement data did verify the accuracy of the emissions inventory within the confidence limits of the emissions estimates, suggesting that this technology could be further developed and deployed more widely in the future for verifying reported emissions.« less

  18. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  19. Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment of Carbon Capture and Storage Technologies

    E-Print Network [OSTI]

    Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment-emission electricity within one or two decades. Renewable generation is also planned to increase over similar time, it is therefore possible that large (~45%) reductions in CO2 emissions from UK electricity generation could

  20. Geologic carbon sequestration as a global strategy to mitigate CO2 emissions: Sustainability and environmental risk

    SciTech Connect (OSTI)

    Oldenburg, C.M.

    2011-04-01

    Fossil fuels are abundant, inexpensive to produce, and are easily converted to usable energy by combustion as demonstrated by mankind's dependence on fossil fuels for over 80% of its primary energy supply (13). This reliance on fossil fuels comes with the cost of carbon dioxide (CO{sub 2}) emissions that exceed the rate at which CO{sub 2} can be absorbed by terrestrial and oceanic systems worldwide resulting in increases in atmospheric CO{sub 2} concentration as recorded by direct measurements over more than five decades (14). Carbon dioxide is the main greenhouse gas linked to global warming and associated climate change, the impacts of which are currently being observed around the world, and projections of which include alarming consequences such as water and food shortages, sea level rise, and social disruptions associated with resource scarcity (15). The current situation of a world that derives the bulk of its energy from fossil fuel in a manner that directly causes climate change equates to an energy-climate crisis. Although governments around the world have only recently begun to consider policies to avoid the direst projections of climate change and its impacts, sustainable approaches to addressing the crisis are available. The common thread of feasible strategies to the energy climate crisis is the simultaneous use of multiple approaches based on available technologies (e.g., 16). Efficiency improvements (e.g., in building energy use), increased use of natural gas relative to coal, and increased development of renewables such as solar, wind, and geothermal, along with nuclear energy, are all available options that will reduce net CO{sub 2} emissions. While improvements in efficiency can be made rapidly and will pay for themselves, the slower pace of change and greater monetary costs associated with increased use of renewables and nuclear energy suggests an additional approach is needed to help bridge the time period between the present and a future when low-carbon energy is considered cheap enough to replace fossil fuels. Carbon dioxide capture and storage (CCS) is one such bridging technology (1). CCS has been the focus of an increasing amount of research over the last 15-20 years and is the subject of a comprehensive IPCC report that thoroughly covers the subject (1). CCS is currently being carried out in several countries around the world in conjunction with natural gas extraction (e.g., 2, 3) and enhanced oil recovery (17). Despite this progress, widespread deployment of CCS remains the subject of research and future plans rather than present action on the scale needed to mitigate emissions from the perspective of climate change. The reasons for delay in deploying CCS more widely are concerns about cost (18), regulatory and legal uncertainty (19), and potential environmental impacts (21). This chapter discusses the long-term (decadal) sustainability and environmental hazards associated with the geologic CO{sub 2} storage (GCS) component of large-scale CCS (e.g., 20). Discussion here barely touches on capture and transport of CO{sub 2} which will occur above ground and which are similar to existing engineering, chemical processing, and pipeline transport activities and are therefore easier to evaluate with respect to risk assessment and feasibility. The focus of this chapter is on the more uncertain part of CCS, namely geologic storage. The primary concern for sustainability of GCS is whether there is sufficient capacity in sedimentary basins worldwide to contain the large of amounts of CO{sub 2} needed to address climate change. But there is also a link between sustainability and environmental impacts. Specifically, if GCS is found to cause unacceptable impacts that are considered worse than its climate-change mitigation benefits, the approach will not be widely adopted. Hence, GCS has elements of sustainability insofar as capacity of the subsurface for CO{sub 2} is concerned, and also in terms of whether the associated environmental risks are acceptable or not to the public.

  1. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Cement Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    2012. Potential energy savings and CO 2 emissions reductiondesign code for energy saving, energy consumption auditingCement: Benchmarking and Energy Savings Tool for the Cement

  2. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    and 24 GW of installed solar capacity. Non-fossil fuels (1,900 GW in 2030. Solar installed capacity reaches 24 GW,2000-2030 Installed Capacity (GW) Solar Biomass and other

  3. Replace Fossil Fuels, Final Technical Report Roberts, William...

    Office of Scientific and Technical Information (OSTI)

    Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Roberts, William L 09 BIOMASS FUELS biofuels, glycerin, glycerol,...

  4. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings OIRA Comparison Document Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document...

  5. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-09-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  6. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-07-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRB and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  7. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-04-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming process, mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  8. On the Road to Climate Stability: The Parable of the Secretary A-Team Report on Prospects for Halting the Growth of CO2 Emissions

    E-Print Network [OSTI]

    Hansen, James E.

    for Halting the Growth of CO2 Emissions James Hansen1,2, Darnell Cain3, Robert Schmunk3 After President Bush) reducing non-CO2 climate forcings, and (2) getting CO2 emissions to level out in the near-term and decline for a path in which the United States achieves an energy and CO2 emissions pathway consistent

  9. Energy use and CO2 emissions of China’s industrial sector from a global perspective

    SciTech Connect (OSTI)

    Zhou, Sheng; Kyle, G. Page; Yu, Sha; Clarke, Leon E.; Eom, Jiyong; Luckow, Patrick W.; Chaturvedi, Vaibhav; Zhang, Xiliang; Edmonds, James A.

    2013-07-10

    The industrial sector has accounted for more than 50% of China’s final energy consumption in the past 30 years. Understanding the future emissions and emissions mitigation opportunities depends on proper characterization of the present-day industrial energy use, as well as industrial demand drivers and technological opportunities in the future. Traditionally, however, integrated assessment research has handled the industrial sector of China in a highly aggregate form. In this study, we develop a technologically detailed, service-oriented representation of 11 industrial subsectors in China, and analyze a suite of scenarios of future industrial demand growth. We find that, due to anticipated saturation of China’s per-capita demands of basic industrial goods, industrial energy demand and CO2 emissions approach a plateau between 2030 and 2040, then decrease gradually. Still, without emissions mitigation policies, the industrial sector remains heavily reliant on coal, and therefore emissions-intensive. With carbon prices, we observe some degree of industrial sector electrification, deployment of CCS at large industrial point sources of CO2 emissions at low carbon prices, an increase in the share of CHP systems at industrial facilities. These technological responses amount to reductions of industrial emissions (including indirect emission from electricity) are of 24% in 2050 and 66% in 2095.

  10. A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production 

    E-Print Network [OSTI]

    Hasanbeigi, A.; Price, L.; Lin, E.

    2012-01-01

    Globally, the cement industry accounts for approximately 5 percent of current man-made carbon dioxide (CO2) emissions. Development of new energy-efficiency and CO2 emission-reduction technologies and their deployment in the market will be key...

  11. Avoiding major climate change in a cleaner fossil fuels world -

    E-Print Network [OSTI]

    installed capacity Tidal/Wave/Ocean Currents: 2 TW gross Fossil Fuels: Current 12.5 TW Potential 25 TW together...and you! 2 #12;The Energy Landscape Solar: 1.2 x 105 TW on earth's surface, 36,000 TW on land ­ comparability with fossil fuels (+ CCS) · Availability ­ delivering sufficient capacity ­ eg landmass

  12. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    SciTech Connect (OSTI)

    G. Fridley, David; Zheng, Nina; T. Aden, Nathaniel

    2010-07-01

    After rapid growth in economic development and energy demand over the last three decades, China has undertaken energy efficiency improvement efforts to reduce its energy intensity under the 11th Five Year Plan (FYP). Since becoming the world's largest annual CO{sub 2} emitter in 2007, China has set reduction targets for energy and carbon intensities and committed to meeting 15% of its total 2020 energy demand with non-fossil fuel. Despite having achieved important savings in 11th FYP efficiency programs, rising per capita income and the continued economic importance of trade will drive demand for transport activity and fuel use. At the same time, an increasingly 'electrified' economy will drive rapid power demand growth. Greater analysis is therefore needed to understand the underlying drivers, possible trajectories and mitigation potential in the growing industrial, transport and power sectors. This study uses scenario analysis to understand the likely trajectory of China's energy and carbon emissions to 2030 in light of the current and planned portfolio of programs, policies and technology development and ongoing urbanization and demographic trends. It evaluates the potential impacts of alternative transportation and power sector development using two key scenarios, Continued Improvement Scenario (CIS) and Accelerated Improvement Scenario (AIS). CIS represents the most likely path of growth based on continuation of current policies and meeting announced targets and goals, including meeting planned appliance efficiency standard revisions, fuel economy standards, and industrial targets and moderate phase-out of subcritical coal-fired generation with additional non-fossil generation. AIS represents a more aggressive trajectory of accelerated improvement in energy intensity and decarbonized power and transport sectors. A range of sensitivity analysis and power technology scenarios are tested to evaluate the impact of additional actions such as carbon capture and sequestration (CCS) and integrated mine-mouth generation. The CIS and AIS results are also contextualized and compared to model scenarios in other published studies. The results of this study show that China's energy and CO{sub 2} emissions will not likely peak before 2030, although growth is expected to slow after 2020. Moreover, China will be able to meet its 2020 carbon intensity reduction target of 40 to 45% under both CIS and AIS, but only meet its 15% non-fossil fuel target by 2020 under AIS. Under both scenarios, efficiency remains a key resource and has the same, if not greater, mitigation potential as new technologies in transport and power sectors. In the transport sector, electrification will be closely linked the degree of decarbonization in the power sector and EV deployment has little or no impact on China's crude oil import demand. Rather, power generation improvements have the largest sector potential for overall emission mitigation while mine-mouth power generation and CCS have limited mitigation potential compared to fuel switching and efficiency improvements. Comparisons of this study's results with other published studies reveal that CIS and AIS are within the range of other national energy projections but alternative studies rely much more heavily on CCS for carbon reduction. The McKinsey study, in particular, has more optimistic assumptions for reductions in crude oil imports and coal demand in its abatement scenario and has much higher gasoline reduction potential for the same level of EV deployment. Despite these differences, this study's scenario analysis of both transport and power sectors illustrate the necessity for continued efficiency improvements and aggressive power sector decarbonization in flattening China's CO{sub 2} emissions.

  13. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    SciTech Connect (OSTI)

    Lew, D.; Brinkman, G.; Kumar, N.; Besuner, P.; Agan, D.; Lefton, S.

    2012-08-01

    High penetrations of wind and solar power will impact the operations of the remaining generators on the power system. Regional integration studies have shown that wind and solar may cause fossil-fueled generators to cycle on and off and ramp down to part load more frequently and potentially more rapidly. Increased cycling, deeper load following, and rapid ramping may result in wear-and-tear impacts on fossil-fueled generators that lead to increased capital and maintenance costs, increased equivalent forced outage rates, and degraded performance over time. Heat rates and emissions from fossil-fueled generators may be higher during cycling and ramping than during steady-state operation. Many wind and solar integration studies have not taken these increased cost and emissions impacts into account because data have not been available. This analysis considers the cost and emissions impacts of cycling and ramping of fossil-fueled generation to refine assessments of wind and solar impacts on the power system.

  14. The millennial atmospheric lifetime of anthropogenic CO2

    E-Print Network [OSTI]

    Cambridge, University of

    /ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, rangingThe millennial atmospheric lifetime of anthropogenic CO2 David Archer & Victor Brovkin Received: 19

  15. Analysis of Post-Kyoto CO2 Emissions Trading Using Marginal Abatement Curves A. Denny Ellerman and Annelne Decaux

    E-Print Network [OSTI]

    Analysis of Post-Kyoto CO2 Emissions Trading Using Marginal Abatement Curves A. Denny Ellerman the advantages of emissions trading. In this paper, the authors derive MACs from EPPA, the MIT Joint Program the benefits of emissions trading in achieving the emission reduction targets implied by the Kyoto Protocol

  16. Efficient 13.5 nm extreme ultraviolet emission from Sn plasma irradiated by a long CO2 laser pulse

    E-Print Network [OSTI]

    Najmabadi, Farrokh

    Efficient 13.5 nm extreme ultraviolet emission from Sn plasma irradiated by a long CO2 laser pulse 17 April 2008; accepted 4 June 2008; published online 23 June 2008 The effect of pulse duration on in with pulse durations from 25 to 110 ns. Employing a long pulse, for example, 110 ns, in a CO2 laser system

  17. Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and

    E-Print Network [OSTI]

    Lyatt Jaeglé

    combustion, biomass burning and soil emissions Lyatt Jaegle´ ,a Linda Steinberger,a Randall V. Martinbc anthropogenic emissions, mostly resulting from fossil fuel combustion and biomass burning, are superimposed estimates are 25% larger than a priori. A posteriori fuel combustion emissions are aseasonal

  18. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    8 Table 6. Sales of fossil fuel production from federal and Indian lands by statearea, FY 2003-13 trillion Btu State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 Alabama...

  19. Secondary organic aerosol formation from fossil fuel sources contribute majority of summertime organic mass at Bakersfield

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Secondary organic aerosol formation from fossil fuel sources contribute majority of summertime organic aerosol formation from fossil fuel sources contribute majority of summertime organic mass is fossil fuel combustion from gasoline- and diesel- powered vehicles and other industrial activities (e

  20. Inventory of Carbon Dioxide (CO2) Emissions at Pacific Northwest National Laboratory

    SciTech Connect (OSTI)

    Judd, Kathleen S.; Kora, Angela R.; Shankle, Steve A.; Fowler, Kimberly M.

    2009-06-29

    The Carbon Management Strategic Initiative (CMSI) is a lab-wide initiative to position the Pacific Northwest National Laboratory (PNNL) as a leader in science, technology and policy analysis required to understand, mitigate and adapt to global climate change as a nation. As part of an effort to walk the talk in the field of carbon management, PNNL conducted its first carbon dioxide (CO2) emissions inventory for the 2007 calendar year. The goal of this preliminary inventory is to provide PNNL staff and management with a sense for the relative impact different activities at PNNL have on the lab’s total carbon footprint.

  1. Modeling the release of CO2 in the deep ocean

    E-Print Network [OSTI]

    Liro, Christopher R.

    1991-01-01

    The idea of capturing and disposing of carbon dioxide (CO2) from the flue gas of fossil fuel-fired power plants has recently received attention as a possible mitigation strategy to counteract potential global warming due ...

  2. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of “staining” upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  3. Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

    Reports and Publications (EIA)

    2001-01-01

    At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

  4. Options for Near-Term Phaseout of CO2 Emissions from Coal Use in the United States

    E-Print Network [OSTI]

    Options for Near-Term Phaseout of CO2 Emissions from Coal Use in the United States P U S H K E R options for phasing out coal emissions in the United States by 2030. We focus on coal for physical science research in the past few years: The "safe" long-term level of atmospheric greenhouse gases (GHGs

  5. BioEnergy Landscape: From Photosynthesis to Fossil Fuels to Advanced Biofuels

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    BioEnergy Landscape: From Photosynthesis to Fossil Fuels to Advanced Biofuels - Fundamentals for substitution of fossil fuels since they are natural extensions of fossil fuels, and the existing energy in transportation to replace fossil fuels. Energy is the cause for all processes across all space and time scales

  6. Global impact of fossil fuel combustion on atmospheric NO x Larry W. Horowitz

    E-Print Network [OSTI]

    Jacob, Daniel J.

    Global impact of fossil fuel combustion on atmospheric NO x Larry W. Horowitz Advanced Study University, Cambridge, MA 02138 (email djj@io.harvard.edu) #12; Abstract. Fossil fuel combustion of fossil fuel combustion on the global distribution of NO x . In the model, we tag fossil fuel NO x and its

  7. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    14. International Energy Agency (IEA), CO 2 Emissionsfrom Fuel Combustion (IEA, Paris, 2009). 15. G. A. Meehl et

  8. The Effects on Developing Countries of the Kyoto Protocol and CO2 Emissions Trading A. Denny Ellerman, Henry D. Jacoby and Annelne Decaux*

    E-Print Network [OSTI]

    The Effects on Developing Countries of the Kyoto Protocol and CO2 Emissions Trading A. Denny by the scope of CO2 emissions trading, by various limitations that Annex I countries might place on emissions.1 Trade in Goods with No Emissions Trading

  9. Inventory of China's Energy-Related CO2 Emissions in 2008

    SciTech Connect (OSTI)

    Fridley, David; Zheng, Nina; Qin, Yining

    2011-03-31

    Although China became the world's largest emitter of energy-related CO{sub 2} emissions in 2007, China does not publish annual estimates of CO{sub 2} emissions and most published estimates of China's emissions have been done by other international organizations. Undertaken at the request of the Energy Information Administration (EIA) of the US Department of Energy, this study examines the feasibility of applying the EIA emissions inventory methodology to estimate China's emissions from published Chinese data. Besides serving as a proof of concept, this study also helps develop a consistent and transparent method for estimating China's CO{sub 2} emissions using an Excel model and identified China-specific data issues and areas for improvement. This study takes a core set of data from the energy balances published in the China Energy Statistical Yearbook 2009 and China Petrochemical Corporation Yearbook 2009 and applies the EIA's eight-step methodology to estimate China's 2008 CO{sub 2} emissions. First, China's primary and secondary fuel types and consumption by end use are determined with slight discrepancies identified between the two data sources and inconsistencies in product categorization with the EIA. Second, energy consumption data are adjusted to eliminate double counting in the four potential areas identified by EIA; consumption data from China's Special Administrative Regions are not included. Physical fuel units are then converted to energy equivalents using China's standard energy measure of coal equivalent (1 kilogram = 29.27 MJ) and IPCC carbon emissions coefficients are used to calculate each fuel's carbon content. Next, carbon sequestration is estimated following EIA conventions for other petroleum products and non-energy use of secondary fuels. Emissions from international bunker fuels are also subtracted under the 'reference' calculation of estimating apparent energy consumption by fuel type and the 'sectoral' calculation of summing emissions across end-use sectors. Adjustments for the China-specific conventions of reporting foreign bunkers and domestic bunkers fueling abroad are made following IPCC definitions of international bunkers and EIA reporting conventions, while the sequestration of carbon in carbon steel is included as an additional adjustment. Under the sectoral approach, fuel consumption of bunkers and other transformation losses as well as gasoline consumption are reallocated to conform to EIA sectoral reporting conventions. To the extent possible, this study relies on official energy data from primary sources. A limited number of secondary sources were consulted to provide insight into the nature of consumption of some products and to guide the analysis of carbon sequestered in steel. Beyond these, however, the study avoided trying to estimate figures where directly unavailable, such as natural gas flaring. As a result, the basic calculations should be repeatable for other years with the core set of data from National Bureau of Statistics and Sinopec (or a similarly authoritative source of oil product data). This study estimates China's total energy-related CO{sub 2} emissions in 2008 to be 6666 Mt CO{sub 2}, including 234.6 Mt of non-fuel CO{sub 2} emissions and 154 Mt of sequestered CO{sub 2}. Bunker fuel emissions in 2008 totaled 15.9 Mt CO{sub 2}, but this figure is underestimated because fuel use by Chinese ship and planes for international transportation and military bunkers are not included. Of emissions related to energy consumption, 82% is from coal consumption, 15% from petroleum and 3% from natural gas. From the sectoral approach, industry had the largest share of China's energy-related CO{sub 2} emissions with 72%, followed by residential at 11%, transport and telecommunications at 8%, and the other four (commerce, agriculture, construction and other public) sectors having a combined share of 9%. Thermal electricity and (purchased) heat (to a lesser degree) are major sources of fuel consumption behind sectoral emissions, responsible for 2533 Mt CO2 and 321 Mt CO{sub 2}, respec

  10. Yankee Ticket Prices and Fossil Fuels 10 April 2008

    E-Print Network [OSTI]

    Hansen, James E.

    Yankee Ticket Prices and Fossil Fuels 10 April 2008 When I was young, Yankee Stadium had ~70,000 when the stadium was remodeled in the 1970s. Most games sell out now, and prices have gone up. The new at guaranteeing sellouts, increasing demand, allowing the owners, in pretty short order, to hike prices to double

  11. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    to 336) Gt CO 2 from primary energy infrastructure beforemore numerous than primary energy infrastructure, monitoringare similar to those of primary energy infrastructure, which

  12. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Bistline, J; Inman, M; Davis, SJ

    2014-01-01

    standards National Renewable Energy Laboratory Technicalnatural gas supply on US renewable energy and CO 2 emissionsuse of both coal and renewable energy technologies in the

  13. Geologic carbon sequestration as a global strategy to mitigate CO2 emissions: Sustainability and environmental risk

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01

    from geologic carbon sequestration sites: unsaturated zone2 from geologic carbon sequestration sites: CO 2 migrationGeologic Carbon Sequestration as a Global Strategy to

  14. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Maine

    SciTech Connect (OSTI)

    2008-10-01

    Analysis of the expected impacts of 1000 MW of wind power in Maine, including economic benefits, CO2 emissions reductions, and water conservation.

  15. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions into the atmosphere2

    E-Print Network [OSTI]

    Boyer, Edmond

    dioxide sequestration process. The overall carbonation reaction includes the following steps: (1)23 CaCarbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions change.20 This study investigates experimentally the aqueous carbonation mechanisms of an alkaline paper

  16. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick,CalendarForkInformationSources |

  17. Consumption, Not CO2 emissions: Reframing Perspectives on Climate Change and Sustainability

    SciTech Connect (OSTI)

    Harriss, Robert; Shui, Bin

    2010-12-01

    A stunning documentary film titled “Mardi Gras: Made in China” provides an insightful and engaging perspective on the globalization of desire for material consumption. Tracing the life cycle of Mardi Gras beads from a small factory in Fuzhou, China to the streets of the Mardi Gras celebration in New Orleans the viewer grasps the near universal human desire to strive for an affluent lifestyle. David Redmon, an independent film maker, follows the beads' genealogy back to the industrial town of Fuzhou, China, to the factory that is the world's largest producer of Mardi Gras beads and related party trinkets. He explores how these frivolous and toxic products affect the people who make them and those who consume them. Redmon captures the daily reality of a Chinese manufacturing facility. It’s workforce of approximately 500 teenage girls, and a handful of boys, live like prisoners in a fenced-in compound. These young people, often working 16-hour days, are constantly exposed to styrene, a chemical known to cause cancer — all for about 10 cents an hour. In addition to indoor pollution, the decrepit coal-fired manufacturing facilities are symbolic of China’s fast rise to the world’s top producer of carbon dioxide (CO2) emissions.1 The process of industrialization and modernization in China is happening at an unprecedented rate and scale.

  18. Forest Sensitivity to Elevated Atmospheric CO2 and its Relevance to Carbon Management Richard J. Norby

    E-Print Network [OSTI]

    the airborne fraction of CO2 from fossil fuel combustion, and, therefore, the rate of increase of CO2Forest Sensitivity to Elevated Atmospheric CO2 and its Relevance to Carbon Management Richard J the responses of forest trees to rising concentrations of atmospheric CO2 has for the past two decades been

  19. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect (OSTI)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  20. An overview of alternative fossil fuel price and carbon regulation scenarios

    E-Print Network [OSTI]

    Wiser, Ryan; Bolinger, Mark

    2004-01-01

    of Alternative Fossil Fuel Price and Carbon Regulationthe past accuracy of fossil fuel price forecasts. We findfossil price scenarios, respectively, but in both cases these are integrated scenarios developed by altering numerous input assumptions, not just fuel price

  1. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    2009. CO 2 Capture in the Cement Industry. Energy Procedia2 Capture Technologies for Cement Industry. Energy Procedia,J.M. Makar, T. Sato. 2010. Cement and concrete nanoscience

  2. Spatial Disaggregation of CO2 Emissions for the State of California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2008-01-01

    Acronyms ATC BTS CALEB CARB CEC CHP CO 2 EEA EIA EMFAC FHWANatural Gas Electricity & CHP Plants On-road vehiclesRail Marine NG: Refining Coal: CHP Coal: Cement P: Cement P:

  3. SPECIAL REPORT 298: EFFECTS OF LAND DEVELOPMENT PATTERNS ON MOTORIZED TRAVEL, ENERGY, AND CO2 EMISSIONS

    E-Print Network [OSTI]

    Kockelman, Kara M.

    SPECIAL REPORT 298: EFFECTS OF LAND DEVELOPMENT PATTERNS ON MOTORIZED TRAVEL, ENERGY, AND CO2 land use changes, biofuels (especially advanced biofuels such as cellulosic ethanol) are a good

  4. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Shearer, C; Bistline, J; Inman, M; Davis, SJ; Davis, SJ

    2014-01-01

    natural gas supply on US renewable energy and CO 2 emissionsrenewable energy use compared to low supply—and the amountnatural gas supply decreased future renewable energy use and

  5. Automobile Fuel; Economy and CO2 Emissions in Industrialized Countries: Troubling Trends through 2005/6

    E-Print Network [OSTI]

    Schipper, Lee

    2008-01-01

    Price on New Car MPG, 1978-89,” The Energy Journal, vol. 11,reasons, new diesel cars show only slightly lower energy- orand rapid energy savings and CO2 restraint in new cars. Fuel

  6. CO2 utilization and storage in shale gas reservoirs: Experimental results and economic impacts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaef, Herbert T.; Davidson, Casie L.; Owen, Antionette Toni; Miller, Quin R. S.; Loring, John S.; Thompson, Christopher J.; Bacon, Diana H.; Glezakou, Vassiliki Alexandra; McGrail, B. Peter

    2014-12-31

    Natural gas is considered a cleaner and lower-emission fuel than coal, and its high abundance from advanced drilling techniques has positioned natural gas as a major alternative energy source for the U.S. However, each ton of CO2 emitted from any type of fossil fuel combustion will continue to increase global atmospheric concentrations. One unique approach to reducing anthropogenic CO2 emissions involves coupling CO2 based enhanced gas recovery (EGR) operations in depleted shale gas reservoirs with long-term CO2 storage operations. In this paper, we report unique findings about the interactions between important shale minerals and sorbing gases (CH4 and CO2) andmore »associated economic consequences. Where enhanced condensation of CO2 followed by desorption on clay surface is observed under supercritical conditions, a linear sorption profile emerges for CH4. Volumetric changes to montmorillonites occur during exposure to CO2. Theory-based simulations identify interactions with interlayer cations as energetically favorable for CO2 intercalation. Thus, experimental evidence suggests CH4 does not occupy the interlayer and has only the propensity for surface adsorption. Mixed CH4:CO2 gas systems, where CH4 concentrations prevail, indicate preferential CO2 sorption as determined by in situ infrared spectroscopy and X-ray diffraction techniques. Collectively, these laboratory studies combined with a cost-based economic analysis provide a basis for identifying favorable CO2-EOR opportunities in previously fractured shale gas reservoirs approaching final stages of primary gas production. Moreover, utilization of site-specific laboratory measurements in reservoir simulators provides insight into optimum injection strategies for maximizing CH4/CO2 exchange rates to obtain peak natural gas production.« less

  7. Ethical Corporation: By Invitation -Climate change: Calling the fossil fuel abolitionists EC Newsdesk

    E-Print Network [OSTI]

    Hoffman, Andrew J.

    Ethical Corporation: By Invitation - Climate change: Calling the fossil fuel abolitionists EC Newsdesk 28 May 08 Where is the green Wilberforce? By Invitation: Climate change: Calling the fossil fuel? The answer lies in the parallels between ending our dependence on fossil- fuels and the abolition of slavery

  8. Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz

    E-Print Network [OSTI]

    Jacob, Daniel J.

    Global impact of fossil fuel combustion on atmospheric NOx Larry W. Horowitz Advanced Study Program, MA 02138 (email djj@io.harvard.edu) #12;Abstract. Fossil fuel combustion is the largest global source-dimensional model of tropospheric chemistry and transport to study the impact of fossil fuel combustion

  9. DOES FOSSIL FUEL COMBUSTION LEAD TO GLOBAL WARMING? Stephen E. Schwartz

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    DOES FOSSIL FUEL COMBUSTION LEAD TO GLOBAL WARMING? Stephen E. Schwartz Environmental Chemistry of the United States Department of Energy, under Contract No. DE-AC02-76CH00016. #12;Schwartz--Fossil Fuel--Fri, Dec 1, 2006 DOES FOSSIL FUEL COMBUSTION LEAD TO GLOBAL WARMING? Stephen E. Schwartz Environmental

  10. A Method for the Preparation of NIST Traceable Fossil Fuel Standards with Concentrations

    E-Print Network [OSTI]

    A Method for the Preparation of NIST Traceable Fossil Fuel Standards with Concentrations for the Preparation of NIST Traceable Fossil Fuel Standards with Concentrations Intermediate to SRM Values W. Robert than either of the SRM components. Because the sulfur content of all fossil fuel SRMs was certified

  11. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    CIS Total and Power Sector Carbon Dioxide Emissions, 2005-Power Sector CIS and AIS Carbon Dioxide Emissions, 2005-Inter-scenario Carbon Dioxide Emissions Mitigation Potential

  12. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  13. North America's net terrestrial CO2 exchange with the atmosphere 1990–2009

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, Anthony W.; Andres, Robert; Davis, Kenneth J.; Hafer, M.; Hayes, Daniel J.; Huntzinger, Deborah N.; de Jong, Bernardus; Kurz, Werner; McGuire, A. David; Vargas, Rodrigo; et al

    2015-01-21

    Scientific understanding of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward that understanding and as a contribution to the REgional Carbon Cycle Assessment and Processes (RECCAP) project, this paper provides a synthesis of net land–atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990–2009. Only CO2 is considered, not methane or other greenhouse gases. This synthesis is based on results from three different methods: atmospheric inversion, inventory-based methods and terrestrial biosphere modeling. All methods indicate that the North Americanmore »land surface was a sink for atmospheric CO2, with a net transfer from atmosphere to land. Estimates ranged from -890 to -280 Tg C yr-1, where the mean of atmospheric inversion estimates forms the lower bound of that range (a larger land sink) and the inventory-based estimate using the production approach the upper (a smaller land sink). This relatively large range is due in part to differences in how the approaches represent trade, fire and other disturbances and which ecosystems they include. Integrating across estimates, \\"best\\" estimates (i.e., measures of central tendency) are -472 ± 281 Tg C yr-1 based on the mean and standard deviation of the distribution and -360 Tg C yr-1 (with an interquartile range of -496 to -337) based on the median. Considering both the fossil fuel emissions source and the land sink, our analysis shows that North America was, however, a net contributor to the growth of CO2 in the atmosphere in the late 20th and early 21st century. With North America's mean annual fossil fuel CO2 emissions for the period 1990–2009 equal to 1720 Tg C yr-1 and assuming the estimate of -472 Tg C yr-1 as an approximation of the true terrestrial CO2 sink, the continent's source : sink ratio for this time period was 1720:472, or nearly 4:1.« less

  14. DOE - Fossil Energy: How Fossil Fuels Were Formed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 GasDEVELOPMENTS E PProductionFossil Fuel

  15. PASSIVE WIRELESS SURFACE ACOUSTIC WAVE SENSORS FOR MONITORING SEQUESTRATION SITES CO2 EMISSION

    SciTech Connect (OSTI)

    Wang, Yizhong; Chyu, Minking; Wang, Qing-Ming

    2012-11-30

    University of Pittsburgh’s Transducer lab has teamed with the U.S. Department of Energy’s National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient CO2 measuring technologies for geological sequestration sites leakage monitoring. A passive wireless CO2 sensing system based on surface acoustic wave technology and carbon nanotube nanocomposite was developed. Surface acoustic wave device was studied to determine the optimum parameters. Delay line structure was adopted as basic sensor structure. CNT polymer nanocomposite was fabricated and tested under different temperature and strain condition for natural environment impact evaluation. Nanocomposite resistance increased for 5 times under pure strain, while the temperature dependence of resistance for CNT solely was -1375ppm/?. The overall effect of temperature on nanocomposite resistance was -1000ppm/?. The gas response of the nanocomposite was about 10% resistance increase under pure CO2. The sensor frequency change was around 300ppm for pure CO2. With paralyne packaging, the sensor frequency change from relative humidity of 0% to 100% at room temperature decreased from over 1000ppm to less than 100ppm. The lowest detection limit of the sensor is 1% gas concentration, with 36ppm frequency change. Wireless module was tested and showed over one foot transmission distance at preferred parallel orientation.

  16. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01

    energy efficiency measures in heavy industry in China, India, Brazil,and energy (including electricity) in 2003-2004 were about 0.65 t CO 2 /t of cement in Brazil,Brazil, 78% in Italy, 80% in Spain, 74% in China, and 91% in the United This article was originally published in “Energy

  17. First Direct Observation of CO2's Greenhouse Effect at the Earth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    North America. They attributed this upward trend to rising CO levels from fossil fuel emissions. The influence of atmospheric CO on the balance between incoming energy from...

  18. PCI INSTRUMENT FOR HYDROGENATION STUDIES As we are aware, earth is fast running out of fossil fuels. Additionally, use of fossil fuels

    E-Print Network [OSTI]

    Subramaniam, Anandh

    PCI INSTRUMENT FOR HYDROGENATION STUDIES As we are aware, earth is fast running out of fossil fuels. Additionally, use of fossil fuels contributes to pollution and global warming. Solar energy is envisaged as an eco-friendly alternative to traditional fuels. The multi-organization project "Generation, Storage

  19. The Future Trajectory of US CO2 Emissions: The Role of State vs. Aggregate Information

    E-Print Network [OSTI]

    Auffhammer, Maximilian; Steinhauser, Ralf

    2006-01-01

    R. A. : 1998, World carbon dioxide emissions 1950 - 2050,in per capita carbon dioxide emissions, Harvard Departmentof u.s. state-level carbon dioxide emissions, The Journal of

  20. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    SciTech Connect (OSTI)

    Krukowski, Elizabeth G [ORNL; Goodman, Angela [National Energy Technology Laboratory (NETL); Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Guthrie, George [National Energy Technology Laboratory (NETL); Bodnar, Robert [Virginia Polytechnic Institute and State University

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate for CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.

  1. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    carbon-intensive fossil fuel, increased by 4.8 percent. 2.8. Carbon dioxide emissions and carbon sequestration from nonfuel uses of energy inputs Nonfuel uses of fossil fuels (for...

  2. TransCom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO 2 fluxes, 1988-2003

    E-Print Network [OSTI]

    2006-01-01

    1° distribution of carbon dioxide emissions from fossil fuelH.1: World carbon dioxide emissions from the consumption andof A. L. Brenkert (Carbon dioxide emission estimates from

  3. Multi-criteria comparison of fuel policies: Renewable fuel mandate, fuel emission-standards, and fuel carbon tax

    E-Print Network [OSTI]

    Rajagopal, Deepak; Hochman, G.; Zilberman, D.

    2012-01-01

    is only one type of fossil fuel and one alternative fuel andGHG emissions and reducing fossil fuel use, and ?nd biofuelin GHG intensity of both fossil fuels and renewable fuels,

  4. Spatial Disaggregation of CO2 Emissions for the State of California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2008-01-01

    fuel and sector; following CARB convention, emissions from domestic and international air travel, and international shipping,

  5. Short-Term Energy Outlook Model Documentation: Carbon Dioxide (CO2) Emissions Model

    Reports and Publications (EIA)

    2009-01-01

    Description of the procedures for estimating carbon dioxide emissions in the Short-Term Energy Outlook

  6. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Cement Industry

    E-Print Network [OSTI]

    Morrow III, William R.

    2014-01-01

    energy challenge with ISO 50001, International Organizationgas emissions. Also, the ISO 50001 standard for Energy

  7. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  8. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled ``Clean Uses of Fossil Fuels.`` was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  9. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; George Farthing; Dan Rowley; Tim R. Armstrong; R.D. Carneim; P.F. Becher; C-H. Hsueh; Aaron L. Wagner; Jon P. Wagner

    2002-04-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur.

  10. Classification of fossil fuels according to structural-chemical characteristics

    SciTech Connect (OSTI)

    A.M. Gyul'maliev; G.S. Golovin; S.G. Gagarin [Institute for Fossil Fuels, Moscow (Russian Federation)

    2007-10-15

    On the basis of a set of linear equations that relate the amount of major elements n{sub E} (E = C, H, O, N, S) in the organic matter of fossil fuels to structural characteristics, such as the number of cycles R, the number of atoms n{sub E}, the number of mutual chemical bonds, the degree of unsaturation of the structure {delta}, and the extent of its reduction B, a structural-chemical classification of fossil coals that is closely related to the parameters of the industrial-genetic classification (GOST 25543-88) is proposed. Structural-chemical classification diagrams are constructed for power-generating coals of Russia; coking coals; and coals designed for nonfuel purposes including the manufacture of adsorbents, synthetic liquid fuel, ion exchangers, thermal graphite, and carbon-graphite materials.

  11. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  12. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01

    emissions are allocated to that sector accordingly. Biogas.The majority of biogas consumed in China is from rural

  13. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  14. Title: Strategic Investing for a Sustainable Future: A New Approach to the Campaign for Divestment in the Fossil Fuel Industry

    E-Print Network [OSTI]

    Walter, M.Todd

    in the Fossil Fuel Industry Host: Charles H. Greene, Director, Ocean Resources and Ecosystems Program to encourage university divestment in the fossil fuel industry is achieving national attention. Student groups to convince the fossil fuel industry that it must play a constructive role in the transition from fossil fuels

  15. Tracking uncertainties in the causal chain from human activities to climate

    E-Print Network [OSTI]

    2009-01-01

    CO 2 emissions from fossil-fuel burning, cement manufacture,CO 2 emissions due to fossil fuels, CO 2 emissions due to2 -equivalent per year. Fossil-fuel (FF) is used to describe

  16. Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale in a Mediterranean climate

    E-Print Network [OSTI]

    van Kessel, Chris

    Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale tillage may increase N2O emissions under certain circumstances, thereby offsetting C sequestration manage- ment accounted for almost 94% of total US N2O emissions from 1990 to 2004 (USEPA, 2006). In 2004

  17. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    recovery from waste ?ows of polymers and tires might lead to net GHG emissions reductions by offsetting fuels such as coal,

  18. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    emissions. The renewable energy base case assumes 296 GW of2007, pp.32-44. renewable energy sensitivity cases result in

  19. Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION...

    Office of Scientific and Technical Information (OSTI)

    carbon capture, utilisation, and storage Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION; POWER GENERATION; CARBON DIOXIDE; CAPTURE; STORAGE; USA; ENHANCED...

  20. N.R. 20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS...

    Office of Scientific and Technical Information (OSTI)

    20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; 14 SOLAR ENERGY; 15 GEOTHERMAL ENERGY; GEOTHERMAL POWER PLANTS; COMPUTERIZED SIMULATION; HEAT...

  1. Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    ACI Committee 229 Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; FLY ASH; WASTE PRODUCT UTILIZATION; BACKFILLING; THERMAL...

  2. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    SciTech Connect (OSTI)

    David Petti; J. Stephen Herring

    2010-03-01

    As described in the Department of Energy Office of Nuclear Energy’s Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled “Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors”, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: • Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, • Produce hydrogen for industrial processes and transportation fuels, and • Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nation’s energy security through more effective utilization of our country’s resources while simultaneously providing economic stability and growth (through predictable energy prices and high value jobs), in an environmentally sustainable and secure manner (through lower land and water use, and decreased byproduct emissions). The reduction in imported oil will also increase the retention of wealth within the U.S. economy while still supporting economic growth. Nuclear energy is the only non-fossil fuel that has been demonstrated to reliably supply energy for a growing industrial economy.

  3. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam Calihman; Andy Girard; Pamela M. Van Calcar; Richard Mackay; Tom Barton; Sara Rolfe

    2001-01-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. Membranes testing during this reporting period were greater than 1 mm thick and had the general perovskite composition AB{sub 1-x}B'{sub x}O{sub 3-{delta}}, where 0.05 {<=} x {<=} 0.3. These materials demonstrated hydrogen separation rates between 1 and 2 mL/min/cm{sup 2}, which represents roughly 20% of the target goal for membranes of this thickness. The sintered membranes were greater than 95% dense, but the phase purity decreased with increasing dopant concentration. The quantity of dopant incorporated into the perovskite phase was roughly constant, with excess dopant forming an additional phase. Composite materials with distinct ceramic and metallic phases, and thin film perovskites (100 {micro}m) also were successfully prepared, but have not yet been tested for hydrogen transport. Finally, porous platinum was identified as a excellent catalyst for evaluation of membrane materials, however, lower cost nickel catalyst systems are being developed.

  4. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Richard A. Mackay; Adam E. Calihman; Lyrik Y. Pitzman; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Mike J. Holmes; Aaron L. Wagner

    2001-07-30

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, ceramic, cermet (ceramic/metal), and thin film membranes were prepared, characterized, and evaluated for H{sub 2} transport. For selected ceramic membrane compositions an optimum range for transition metal doping was identified, and it was determined that highest proton conductivity occurred for two-phase ceramic materials. Furthermore, a relationship between transition metal dopant atomic number and conductivity was observed. Ambipolar conductivities of {approx}6 x 10{sup -3} S/cm were achieved for these materials, and {approx} 1-mm thick membranes generated H{sub 2} transport rates as high as 0.3 mL/min/cm{sup 2}. Cermet membranes during this quarter were found to have a maximum conductivity of 3 x 10{sup -3} S/cm, which occurred at a metal phase contact of 36 vol.%. Homogeneous dense thin films were successfully prepared by tape casting and spin coating; however, there remains an unacceptably high difference in shrinkage rates between the film and support, which led to membrane instability. Further improvements in high pressure membrane seals also were achieved during this quarter, and a maximum pressure of 100 psig was attained. CoorsTek optimized many of the processing variables relevant to manufacturing scale production of ceramic H{sub 2} transport membranes, and SCI used their expertise to deposit a range of catalysts compositions onto ceramic membrane surfaces. Finally, MTI compiled relevant information regarding Vision 21 fossil fuel plant operation parameters, which will be used as a starting point for assessing the economics of incorporating a H{sub 2} separation unit.

  5. Measurements of 222Rn, 220Rn, and CO Emissions in Natural CO2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

    SciTech Connect (OSTI)

    Kaszuba, John; Sims, Kenneth

    2014-09-30

    An integrated field-laboratory program evaluated the use of radon and CO2 flux measurements to constrain source and timescale of CO2 fluxes in environments proximate to CO2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensure 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or “tool” was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO2-bearing environments. The field program also identified issues with radon and CO2-flux measurements in soil gases at a natural CO2 analog. A systematic survey of radon and CO2 flux in soil gases at the LaBarge CO2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO2 flux may not be a robust method for monitoring the integrity of a CO2 storage reservoir. The field program was also not able to correlate radon and CO2 flux in the CO2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO2-bearing experiments is greater at all temperatures compared to the experiments without CO2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO2-rich waters.

  6. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Bistline, J; Inman, M; Davis, SJ

    2014-01-01

    leaks from North American natural gas systems Science 343of methane emissions at natural gas production sites in theUS exports of natural gas Energy Policy www.bipac.net/dow/

  7. Diesel Passenger Car Technology for Low Emissions and CO2 Compliance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the US Market Laboratory and Vehicle Demonstration of a "2nd-Generation" LNT+in-situ SCR Diesel NOx Emission Control Concept Light-Duty Diesel Market Potential in North America...

  8. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Shearer, C; Bistline, J; Inman, M; Davis, SJ; Davis, SJ

    2014-01-01

    leaks from North American natural gas systems Science 343of methane emissions at natural gas production sites in theThe effect of natural gas supply on US renewable energy and

  9. Supplementary Information for Refined Estimate of China's CO2 Emissions in

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    coal 0.93 (0.89-0.98); Gamma IPCC( 2006); Cai et al. (2009); Zhao et al (2012) Cleaned coal 0.96 (0.95-0.98); Weibull Other washed coal 0.96 (0.92-1); Triangular Briquettes 0.90 (0.89-0.98); Weibull IPCC( 2006); Coke provincial emissions Emission sector Type of activity data Proxy Industrial energy consumption Fuel

  10. Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Carl R. Evenson; Richard N. Kleiner; James E. Stephan; Frank E. Anderson

    2006-04-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this final quarter of the no cost extension several planar membranes of a cermet composition referred to as EC101 containing a high permeability metal and a ceramic phase were prepared and permeability testing was performed.

  11. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUELS PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart Schesnack; Scott Morrison; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-07-31

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This report presents hydrogen permeation data during long term tests and tests at high pressure in addition to progress with cermet, ceramic/ceramic, and thin film membranes.

  12. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Stewart Schesnack; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-04-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Currently, this project is focusing on four basic categories of dense membranes: (i) mixed conducting ceramic/ceramic composites, (ii) mixed conducting ceramic/metal (cermet) composites, (iii) cermets with hydrogen permeable metals, and (iv) hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This report describes resent results for long-term hydrogen permeation and chemical stability measurements, new mixed conducting cermets, progress in cermet, thin film, and thin-walled tube fabrication, hydrogen absorption measurements for selected compositions, and membrane facilitated alkane to olefin conversion.

  13. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  14. House Committee on Natural Resources The Future of Fossil Fuels: Geological and Terrestrial Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    and sequestration (CCS) is the critical enabling technology that would reduce CO2 emissions significantly while also at a large industrial source, such as a coal-fired power plant. By capture, it is meant isolating the CO2, thank you for the opportunity to appear before you today to discuss Carbon Dioxide (CO2) geological

  15. Review of cost estimates for reducing CO2 emissions. Final report, Task 9

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    Since the ground breaking work of William Nordhaus in 1977, cost estimates for reducing CO{sub 2} emissions have been developed by numerous groups. The various studies have reported sometimes widely divergent cost estimates for reducing CO{sub 2} emissions. Some recent analyses have indicated that large reductions in CO{sub 2} emissions could be achieved at zero or negative costs (e.g. Rocky Mountain Institute 1989). In contrast, a recent study by Alan Manne of Stanford and Richard Richels of the Electric Power Research Institute (Manne-Richels 1989) concluded that in the US the total discounted costs of reducing CO{sub 2} emissions by 20 percent below the 1990 level could be as much as 3.6 trillion dollars over the period from 1990 to 2100. Costs of this order of magnitude would represent about 5 percent of US GNP. The purpose of this briefing paper is to summarize the different cost estimates for CO{sub 2} emission reduction and to identify the key issues and assumptions that underlie these cost estimates.

  16. CO Cameron band and CO2+ UV doublet emissions in the dayglow of Venus: Role of CO in the Cameron band production

    E-Print Network [OSTI]

    Bhardwaj, Anil

    2013-01-01

    Present study deals with the model calculations of CO Cameron band and CO2+ ultraviolet doublet emissions in the dayglow of Venus. The overhead and limb intensities of CO Cameron band and CO2+ UV doublet emissions are calculated for low, moderate, and high solar activity conditions. Using updated cross sections, the impact of dierent e-CO cross section for Cameron band production is estimated. The electron impact on CO is the major source mechanism of Cameron band, followed by electron and photon impact dissociation of CO2. The overhead intensities of CO Cameron band and CO2+ UV doublet emissions are about a factor of 2 higher in solar maximum than those in solar minimum condition. The effect of solar EUV flux models on the emission intensity is ~30-40% in solar minimum condition and ~2-10% in solar maximum condition. At the altitude of emission peak (135 km), the model predicted limb intensity of CO Cameron band and CO2+ UV doublet emissions in moderate (F10.7 = 130) solar activity condition is about 2400 an...

  17. 2007-No54-BoilingPoint Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel

    E-Print Network [OSTI]

    Kammen, Daniel M.

    2007-No54-BoilingPoint Theme Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel Energy, but both the human health and envi- ronmental impacts associated with reliance on this fuel structure of fossil-fuel energy systems. These scenarios are analysed for various environmental and health impacts

  18. Variations in mid-ocean ridge CO2 emissions driven by glacial cycles

    E-Print Network [OSTI]

    Burley, Jonathan M A

    2015-01-01

    The geological record shows links between glacial cycles and volcanic productivity, both subaerially and at mid-ocean ridges. Sea-level-driven pressure changes could also affect chemical properties of mid-ocean ridge volcanism. We consider how changing sea-level could alter the \\cotwo{} emissions rate from mid-ocean ridges, on both the segment and global scale. We develop a simplified transport model for a highly incompatible element through a homogenous mantle; variations in the melt concentration the emission rate of the element are created by changes in the depth of first silicate melting. The model predicts an average global mid-ocean ridge \\cotwo{} emissions-rate of $53$~Mt/yr, in line with other estimates. We show that falling sea level would cause an increase in ridge \\cotwo{} emissions with a lag of about $100$~kyrs after the causative sea level change. The lag and amplitude of the response are sensitive to mantle permeability and plate spreading rate. For a reconstructed sea-level time series of the ...

  19. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2

    Reports and Publications (EIA)

    2001-01-01

    This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

  20. Modeling impacts of farming management alternatives on CO2, CH4, and N2O emissions: A case study for water management of rice

    E-Print Network [OSTI]

    emissions about 40%, or 5 Tg CH4 yrÀ1 , roughly 5­10% of total global methane emissions from rice paddies contribution to the net climate impact due to the low radiative potential of CO2. The change in water. Introduction [2] Food production contributes approximately 70% of global atmospheric input of nitrous oxide (N2

  1. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  2. MINIMIZING NET CO2 EMISSIONS BY OXIDATIVE CO-PYROLYSIS OF COAL / BIOMASS BLENDS

    SciTech Connect (OSTI)

    Todd Lang; Robert Hurt

    2001-12-23

    This study presents a set of thermodynamic calculations on the optimal mode of solid fuel utilization considering a wide range of fuel types and processing technologies. The technologies include stand-alone combustion, biomass/coal cofiring, oxidative pyrolysis, and straight carbonization with no energy recovery but with elemental carbon storage. The results show that the thermodynamically optimal way to process solid fuels depends strongly on the specific fuels and technologies available, the local demand for heat or for electricity, and the local baseline energy-production method. Burning renewable fuels reduces anthropogenic CO{sub 2} emissions as widely recognized. In certain cases, however, other processing methods are equally or more effective, including the simple carbonization or oxidative pyrolysis of biomass fuels.

  3. Energy, cost, and CO 2 emission comparison between radiant wall panel systems and radiator systems

    E-Print Network [OSTI]

    Milorad Boji?; Dragan Cvetkovi?; Marko Mileti?; Jovan Maleševi?; Harry Boyer

    2012-12-18

    The main goal of this paper is to evaluate the possibility of application or replacement of radiators with low-temperature radiant panels. This paper shows the comparison results of operations of 4 space heating systems: the low-temperature radiant panel system without any additional thermal insulation of external walls (PH-WOI), the low-temperature radiant panel system with additional thermal insulation of external walls (PH-WI), the radiator system without any additional thermal insulation of external walls (the classical heating system) (RH-WOI), and the radiator system with additional thermal insulation of external walls (RH-WI). The operation of each system is simulated by software EnergyPlus. The investigation shows that the PH-WI gives the best results. The RH-WOI has the largest energy consumption, and the largest pollutant emission. However, the PH-WI requires the highest investment.

  4. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart R. Schesnack; Scott R. Morrison; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-10-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Over the past 12 months, this project has focused on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. The ceramic/ceramic composites demonstrate the lowest hydrogen permeation rates, with a maximum of approximately 0.1 mL/min/cm{sup 2} for 0.5-mm thick membranes at 800 to 950 C. Under equivalent conditions, cermets achieve a hydrogen permeation rate near 1 mL/min/cm{sup 2}, and the metal phase also improves structural stability and surface catalysis for hydrogen dissociation. Furthermore, if metals with high hydrogen permeability are used in cermets, permeation rates near 4 mL/min/cm{sup 2} are achievable with relatively thick membranes. Layered composite membranes have by far the highest permeation rates with a maximum flux in excess of 200 mL {center_dot} min{sup -1} {center_dot} cm{sup -2}. Moreover, these permeation rates were achieved at a total pressure differential across the membrane of 450 psi. Based on these results, effort during the next year will focus on this category of membranes. This report contains long-term hydrogen permeation data over eight-months of continuous operation, and permeation results as a function of operating conditions at high pressure for layered composite membranes. Additional progress with cermet and thin film membranes also is presented.

  5. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam E. Calihman; Lyrik Y. Pitzman; Pamela M. Van Calcar; Richard A. Mackay; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Tim R. Armstrong; Mike J. Holmes; Aaron L. Wagner

    2001-04-30

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, it was demonstrated that increasing the transition metal loading in a model perovskite composition resulted in an increase in hydrogen flux. Improved flux corresponded to the emergence of additional phases in the ceramic membrane, and highest flux was achieved for a composite consisting of pseudo-cubic and rhombohedral perovskite phases. A 0.9-mm thick membrane of this material generated a hydrogen flux in excess of 0.1 mL/min/cm{sup 2}, which was approximately 35 times greater than analogs with lower transition metal levels. The dopant level and crystal structure also correlated with membrane density and coefficient of thermal expansion, but did not appear to affect grain size or shape. Additionally, preliminary ceramic-metal (cermet) composite membranes demonstrated a 10-fold increase in flux relative to analogous membranes composed of only the ceramic component. The hydrogen flux for these cermet samples corresponded to a conductivity of {approx} 10{sup -3} S/cm, which was consistent with the predicted proton conductivity of the ceramic phase. Increasing the sweep gas flow rate in test reactors was found to significantly increase hydrogen flux, as well as apparent material conductivity for all samples tested. Adding humidity to the feed gas stream produced a small increase in hydrogen flux. However, the catalyst on ceramic membrane surfaces did not affect flux, which suggested that the process was membrane-diffusion limited. Representative samples and fabrication processes were evaluated on the basis of manufacturing practicality. it was determined that optimum membrane densification occurs over a very narrow temperature range for the subject ceramics. Additionally, calcination temperatures currently employed result in powders that are difficult mill and screen. These issues must be addressed to improve large-scale fabricability.

  6. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Alexandra Z. LaGuardia; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Mike J. Holmes; Aaron L. Wagner

    2001-10-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, mixed proton/electron conductivity and hydrogen transport was measured as a function of metal phase content for a range of ceramic/metal (cermet) compositions. It was found that optimum performance occurred at 44 wt.% metal content for all compositions tested. Although each cermet appeared to have a continuous metal phase, it is believed that hydrogen transport increased with increasing metal content partially due to beneficial surface catalyst characteristics resulting from the metal phase. Beyond 44 wt.% there was a reduction in hydrogen transport most likely due to dilution of the proton conducting ceramic phase. Hydrogen separation rates for 1-mm thick cermet membranes were in excess of 0.1 mL/min/cm{sup 2}, which corresponded to ambipolar conductivities between 1 x 10{sup -3} and 8 x 10{sup -3} S/cm. Similar results were obtained for multiphase ceramic membranes comprised of a proton-conducting perovskite and electron conducting metal oxide. These multi-phase ceramic membranes showed only a slight improvement in hydrogen transport upon addition of a metal phase. The highest hydrogen separation rates observed this quarter were for a cermet membrane containing a hydrogen transport metal. A 1-mm thick membrane of this material achieved a hydrogen separation rate of 0.3 mL/min/cm{sup 2} at only 700 C, which increased to 0.6 mL/min/cm{sup 2} at 950 C.

  7. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Stewart R. Schesnack; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-01-30

    Eltron Research Inc., and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying composite membrane composition and microstructure to maximize hydrogen permeation without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, a composite metal membrane based on an inexpensive hydrogen permeable metal achieved permeation rates in excess of 25 mL/min/cm{sup 2}. Preliminary attempts to incorporate this metal into a cermet were successful, and a thick cermet membrane (0.83 mm) with 40 vol.% metal phase achieved a permeation rate of nearly 0.4 mL/min/cm{sup 2}. Increasing the metal phase content and decreasing membrane thickness should significantly increase permeation, while maintaining the benefits derived from cermets. Two-phase ceramic/ceramic composite membranes had low hydrogen permeability, likely due to interdiffusion of constituents between the phases. However, these materials did demonstrate high resistance to corrosion, and might be good candidates for other composite membranes. Temperature-programmed reduction measurements indicated that model cermet materials absorbed 2.5 times as much hydrogen than the pure ceramic analogs. This characteristic, in addition to higher electron conductivity, likely explains the relatively high permeation for these cermets. Incorporation of catalysts with ceramics and cermets increased hydrogen uptake by 800 to more than 900%. Finally, new high-pressure seals were developed for cermet membranes that maintained a pressure differential of 250 psi. This result indicated that the approach for high-pressure seal development could be adapted for a range of compositions. Other items discussed in this report include mechanical testing, new proton conducting ceramics, supported thin films, and alkane to olefin conversion.

  8. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; George Farthing; Dan Rowley; Tim R. Armstrong; M.K. Ferber; Aaron L. Wagner; Jon P. Wagner

    2002-07-30

    Eltron Research Inc. and their team members are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, new cermet compositions were tested that demonstrated similar performance to previous materials. A 0.5-mm thick membrane achieved at H{sub 2} transport rate of 0.2 mL/min/cm{sup 2} at 950 C, which corresponded to an ambipolar conductivity of 3 x 10{sup -3} S/cm. Although these results were equivalent to those for other cermet compositions, this new composition might be useful if it demonstrates improved chemical or mechanical stability. Ceramic/ceramic composite membranes also were fabricated and tested; however, some reaction did occur between the proton- and electron-conducting phases, which likely compromised conductivity. This sample only achieved a H{sub 2} transport rate of {approx} 0.006 mL/min/cm{sup 2} and an ambipolar conductivity of {approx}4 x 10{sup -4} S/cm. Chemical stability tests were continued, and candidate ceramic membranes were found to react slightly with carbon monoxide under extreme testing conditions. A cermet compositions did not show any reaction with carbon monoxide, but a thick layer of carbon formed on the membrane surface. The most significant technical accomplishment this quarter was a new high-pressure seal composition. This material maintained a pressure differential across the membrane of {approx} 280 psi at 800 C, and is still in operation.

  9. Long-Term US Industrial Energy Use and CO2 Emissions

    SciTech Connect (OSTI)

    Wise, Marshall A.; Sinha, Paramita; Smith, Steven J.; Lurz, Joshua P.

    2007-12-03

    We present a description and scenario results from our recently-developed long-term model of United States industrial sector energy consumption, which we have incorporated as a module within the ObjECTS-MiniCAM integrated assessment model. This new industrial model focuses on energy technology and fuel choices over a 100 year period and allows examination of the industrial sector response to climate policies within a global modeling framework. A key challenge was to define a level of aggregation that would be able to represent the dynamics of industrial energy demand responses to prices and policies, but at a level that remains tractable over a long time frame. In our initial results, we find that electrification is an important response to a climate policy, although there are services where there are practical and economic limits to electrification, and the ability to switch to a low-carbon fuel becomes key. Cogeneration of heat and power using biomass may also play a role in reducing carbon emissions under a policy constraint.

  10. A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission

    SciTech Connect (OSTI)

    Fang, Zhigang Zak

    2013-11-05

    The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO{sub 2} emission from the production of titanium dioxide (TiO{sub 2}) pigment. TiO{sub 2} is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO{sub 2} pigment is currently produced primarily by the use of the so called ?chloride process?. A key step of the chloride process relies on high temperature carbo-chlorination of TiO{sub 2} bearing raw materials, hence producing large quantities of CO{sub 2}. The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO{sub 2} from high-TiO{sub 2} slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO{sub 2} produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology. These objectives were successfully met and a new process for producing commercial quality TiO{sub 2} pigment was developed and experimentally validated. The process features a unique combination of established metallurgical processes, including alkaline roasting of titania slag followed by leaching, solvent extraction, hydrolysis, and calcination. The caustic, acidic, and organic streams in the process will also be regenerated and reused in the process, greatly reducing environmental waste. The purpose and effect of each of these steps in producing purified TiO{sub 2} is detailed in the report. The levels of impurities in our pigment meet the requirements for commercial pigment, and are nearly equivalent to those of two commercial pigments. Solvent extraction with an amine extractant proved to be extremely effective in achieving these targets. A model plant producing 100,000 tons TiO{sub 2} per year was designed that would employ the new method of pigment manufacture. A flow sheet was developed and a mass and energy balance was performed. A comparison of the new process and the chloride process indicate that implementation of the new process in the US would result in a 21% decrease in energy consumption, an annual energy savings of 42.7 million GJ. The new process would reduce CO{sub 2} emissions by 21% in comparison to the chloride process, an annual reduction of 2.70 million tons of CO{sub 2}. Since the process equipment employed in the new process is well established in other industrial processes and the raw materials for the two processes are identical we believe the capital, labor and materials cost of production of pigment grade TiO{sub 2} using the new method would be at least equivalent to that of the chloride process. Additionally, it is likely that the operating costs will be lower by using the new process because of the reduced energy consumption. Although the new process technology is logical and feasible based on its chemistry, thermodynamic principles, and experimental results, its development and refinement through more rigorous and comprehensive research at the kilogram scale is needed to establish it as a competitive industrial process. The effect of the recycling of process streams on the final product quality should also be investigated. Further development would also help determine if the energy efficiency and the environmental benefits of the new process are indeed significantly better than current commercial methods of pigment manufacture.

  11. Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, B; Balin, D F

    2012-09-06

    The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

  12. Deployment of CCS Technologies across the Load Curve for a Competitive Electricity Market as a Function of CO2 Emissions Permit Prices

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.

    2011-04-18

    Consistent with other published studies, the modelling presented here reveals that baseload power plants are the first aspects of the electricity sector to decarbonize and are essentially decarbonized once CO2 permit prices exceed a certain threshold ($90/ton CO2 in this study). The decarbonization of baseload electricity is met by significant expansions of nuclear power and renewable energy generation technologies as well as the application of carbon dioxide capture and storage (CCS) technologies applied to both coal and natural gas fired power plants. Relatively little attention has been paid thus far to whether intermediate and peaking units would respond the same way to a climate policy given the very different operational and economic context that these kinds of electricity generation units operate under. In this paper, the authors discuss key aspects of the load segmentation methodology used to imbed a varying electricity demand within the GCAM (a state-of-the-art Integrated Assessment Model) energy and economic modelling framework and present key results on the role CCS technologies could play in decarbonizng subpeak and peak generation (encompassing only the top 10% of the load) and under what conditions. To do this, the authors have modelled two hypothetical climate policies that require 50% and 80% reductions in US emissions from business as usual by the middle of this century. Intermediate electricity generation is virtually decarbonized once carbon prices exceed approximately $150/tonCO2. When CO2 permit prices exceed $160/tonCO2, natural gas power plants with CCS have roughly the same marketshare as conventional gas plants in serving subpeak loads. The penetration of CCS into peak load (upper 6% here) is minimal under the scenarios modeled here suggesting that CO2 emissions from this aspect of the U.S. electricity sector would persist well into the future even with stringent CO2 emission control policies in place.

  13. Carbon Capture and Storage from Fossil Fuel Use 1 Howard Herzog and Dan Golomb

    E-Print Network [OSTI]

    . Concise Definition of Subject One of the approaches for mitigating potential global climate change due, wind and solar energy). Currently, non-hydro renewable energy supplies less than 1% of the global the emissions of CO2 into the atmosphere, and thereby mitigating global climate change. The storage period

  14. The Case for Oueen's lJnrversitv Divestment of the Pooled Endowment Fund from the Fossil Fuel Industrv

    E-Print Network [OSTI]

    Fletcher, Robin

    The Case for Oueen's lJnrversitv Divestment of the Pooled Endowment Fund from the Fossil Fuel. The Case for the Fossil Fuel Industry Causing Social Injury 4. Divestment as a Moral Imperative 5 organization and institutions to divest from fossil fuels across Canada and the world. 3 #12;r.20 - oals

  15. fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED...

    Office of Scientific and Technical Information (OSTI)

    draft fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 42 ENGINEERING NOT INCLUDED IN OTHER...

  16. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  17. Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    Liquid-fluidized-bed heat exchanger flow distribution models Cole, L.T.; Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS; FLUIDIZED BED HEAT EXCHANGERS; DESIGN;...

  18. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M. [Karadeniz Technical University, Trabzon (Turkey)

    2008-07-01

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  19. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Broader source: Energy.gov [DOE]

    This paper was prepared in response to recent requests that the U.S. Energy Information Administration (EIA) provide updated summary information regarding fossil fuel production on federal and...

  20. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    of energy-efficiency measures, the actual energy savingsCO 2 ) Fuel Savings (PJ) Efficiency Measure*** Injection ofRank Fuel Savings (PJ) Efficiency Measure*** Injection of

  1. Capture and Sequestration of CO2 at the Boise White Paper Mill

    SciTech Connect (OSTI)

    B.P. McGrail; C.J. Freeman; G.H. Beeman; E.C. Sullivan; S.K. Wurstner; C.F. Brown; R.D. Garber; D. Tobin E.J. Steffensen; S. Reddy; J.P. Gilmartin

    2010-06-16

    This report documents the efforts taken to develop a preliminary design for the first commercial-scale CO2 capture and sequestration (CCS) project associated with biomass power integrated into a pulp and paper operation. The Boise Wallula paper mill is located near the township of Wallula in Southeastern Washington State. Infrastructure at the paper mill will be upgraded such that current steam needs and a significant portion of the current mill electric power are supplied from a 100% biomass power source. A new biomass power system will be constructed with an integrated amine-based CO2 capture plant to capture approximately 550,000 tons of CO2 per year for geologic sequestration. A customized version of Fluor Corporation’s Econamine Plus™ carbon capture technology will be designed to accommodate the specific chemical composition of exhaust gases from the biomass boiler. Due to the use of biomass for fuel, employing CCS technology represents a unique opportunity to generate a net negative carbon emissions footprint, which on an equivalent emissions reduction basis is 1.8X greater than from equivalent fossil fuel sources (SPATH and MANN, 2004). Furthermore, the proposed project will offset a significant amount of current natural gas use at the mill, equating to an additional 200,000 tons of avoided CO2 emissions. Hence, the total net emissions avoided through this project equates to 1,100,000 tons of CO2 per year. Successful execution of this project will provide a clear path forward for similar kinds of emissions reduction that can be replicated at other energy-intensive industrial facilities where the geology is suitable for sequestration. This project also represents a first opportunity for commercial development of geologic storage of CO2 in deep flood basalt formations. The Boise paper mill site is host to a Phase II pilot study being carried out under DOE’s Regional Carbon Partnership Program. Lessons learned from this pilot study and other separately funded projects studying CO2 sequestration in basalts will be heavily leveraged in developing a suitable site characterization program and system design for permanent sequestration of captured CO2. The areal extent, very large thickness, high permeability in portions of the flows, and presence of multiple very low permeability flow interior seals combine to produce a robust sequestration target. Moreover, basalt formations are quite reactive with water-rich supercritical CO2 and formation water that contains dissolved CO2 to generate carbonate minerals, providing for long-term assurance of permanent sequestration. Sub-basalt sediments also exist at the site providing alternative or supplemental storage capacity.

  2. Progress in Photovoltaics Research and Applications, 14:179-190, 2006 Energy Pay-Back and Life Cycle CO2 Emissions of the BOS in an

    E-Print Network [OSTI]

    an innovative PV installation program guided by design optimization and cost minimization. The advanced design. The total cost of the balance of system components was $940 US per kWp of installed PV, another milestone Cycle CO2 Emissions of the BOS in an Optimized 3.5 MW PV Installation J.M. Mason1 , V.M. Fthenakis2 , T

  3. Remote-sensing GIS based investigations of coal fires in northern China; global monitoring to support the estimation of CO2 emissions from spontaneous combustion of

    E-Print Network [OSTI]

    the development of coal fires (Figure 1) are: (1) the type of coal. Its vulnerability to spontaneous combustionRemote-sensing GIS based investigations of coal fires in northern China; global monitoring to support the estimation of CO2 emissions from spontaneous combustion of coal Freek van der Meer, Paul van

  4. Land and Water Use, CO2 Emissions, and Worker Radiological Exposure Factors for the Nuclear Fuel Cycle

    SciTech Connect (OSTI)

    Brett W Carlsen; Brent W Dixon; Urairisa Pathanapirom; Eric Schneider; Bethany L. Smith; Timothy M. AUlt; Allen G. Croff; Steven L. Krahn

    2013-08-01

    The Department of Energy Office of Nuclear Energy’s Fuel Cycle Technologies program is preparing to evaluate several proposed nuclear fuel cycle options to help guide and prioritize Fuel Cycle Technology research and development. Metrics are being developed to assess performance against nine evaluation criteria that will be used to assess relevant impacts resulting from all phases of the fuel cycle. This report focuses on four specific environmental metrics. • land use • water use • CO2 emissions • radiological Dose to workers Impacts associated with the processes in the front-end of the nuclear fuel cycle, mining through enrichment and deconversion of DUF6 are summarized from FCRD-FCO-2012-000124, Revision 1. Impact estimates are developed within this report for the remaining phases of the nuclear fuel cycle. These phases include fuel fabrication, reactor construction and operations, fuel reprocessing, and storage, transport, and disposal of associated used fuel and radioactive wastes. Impact estimates for each of the phases of the nuclear fuel cycle are given as impact factors normalized per unit process throughput or output. These impact factors can then be re-scaled against the appropriate mass flows to provide estimates for a wide range of potential fuel cycles. A companion report, FCRD-FCO-2013-000213, applies the impact factors to estimate and provide a comparative evaluation of 40 fuel cycles under consideration relative to these four environmental metrics.

  5. Reduction of green house gas emission by clean power Jinxu Ding and Arun Somani

    E-Print Network [OSTI]

    , fossil fuels play an important role. The estimation of Energy Information Administration [7] of Depart.8%, coal 26.6% and natural gas 22.9%. The total value of these sources is 86.3% share for fossil fuels in primary energy production in the world. Burning fossil fuels produces about 21.3 billion tons of CO2 every

  6. "Peak Oil"Paper Revised and Temperature Analysis Code (1) The paper"Implications of`Peak Oil'for Atmospheric CO2 and Climate", recently revised and

    E-Print Network [OSTI]

    Hansen, James E.

    "Peak Oil"Paper Revised and Temperature Analysis Code (1) The paper"Implications of`Peak Oil is phased out except where the CO2 is captured and stored, and use of unconventional fossil fuels

  7. Hydrogen milestone could help lower fossil fuel refining costs

    ScienceCinema (OSTI)

    Stephen Herring

    2010-01-08

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, lab

  8. Economic Benefits, Carbon Dioxide (CO2) Emissions Reduction, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Georgia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Georgia. We forecast the cumulative economic benefits from 1000 MW of development in Georgia to be $2.1 billion, annual CO2 reductions are estimated at 3.0 million tons, and annual water savings are 1,628 million gallons.

  9. Economic Benefits, Carbon Dioxide (CO2) Emissions reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in New York (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in New York. We forecast the cumulative economic benefits from 1000 MW of development in New York to be $1.3 billion, annual CO2 reductions are estimated at 2.5 million tons, and annual water savings are 1,230 million gallons.

  10. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Virginia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Virginia. We forecast the cumulative economic benefits from 1000 MW of development in Virginia to be $1.2 billion, annual CO2 reductions are estimated at 3.0 million tons, and annual water savings are 1,600 million gallons.

  11. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Michigan

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Michigan. We forecast the cumulative economic benefits from 1000 MW of development in Michigan to be $1.3 billion, annual CO2 reductions are estimated at 2.9 million tons, and annual water savings are 1,542 million gallons.

  12. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Nebraska (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Nebraska. We forecast the cumulative economic benefits from 1000 MW of development in Nebraska to be $1.1 billion, annual CO2 reductions are estimated at 4.1 million tons, and annual water savings are 1,840 million gallons.

  13. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Maryland (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Michigan. We forecast the cumulative economic benefits from 1000 MW of development in Maryland to be $1.2 billion, annual CO2 reductions are estimated at 3 million tons, and annual water savings are 1,581 million gallons.

  14. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Arkansas (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Arkansas. We forecast the cumulative economic benefits from 1000 MW of development in Arkansas to be $1.15 billion, annual CO2 reductions are estimated at 2.7 million tons, and annual water savings are 1,507 million gallons.

  15. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Ohio (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Ohio. We forecast the cumulative economic benefits from 1000 MW of development in Ohio to be $1.3 billion, annual CO2 reductions are estimated at 2.5 million tons, and annual water savings are 1,343 million gallons.

  16. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Kansas (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Kansas. We forecast the cumulative economic benefits from 1000 MW of development in Kansas to be $1.08 billion, annual CO2 reductions are estimated at 3.2 million tons, and annual water savings are 1,816 million gallons.

  17. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    E-Print Network [OSTI]

    Zhou, Nan

    2010-01-01

    3 (Table 6 and Figure 4), and LPG savings 13 million tonnes.electricity and 28 billion m 3 LPG, with a CO2 reduction ofGas WH* (billion m 3 ) LPG WH (million tonnes) Electric

  18. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01

    would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

  19. Multi-Channel Auto-Dilution System for Remote Continuous Monitoring of High Soil-CO2 Fluxes

    SciTech Connect (OSTI)

    Amonette, James E.; Barr, Jonathan L.

    2009-04-23

    Geological sequestration has the potential capacity and longevity to significantly decrease the amount of anthropogenic CO2 introduced into the atmosphere by combustion of fossil fuels such as coal. Effective sequestration, however, requires the ability to verify the integrity of the reservoir and ensure that potential leakage rates are kept to a minimum. Moreover, understanding the pathways by which CO2 migrates to the surface is critical to assessing the risks and developing remediation approaches. Field experiments, such as those conducted at the Zero Emissions Research and Technology (ZERT) project test site in Bozeman, Montana, require a flexible CO2 monitoring system that can accurately and continuously measure soil-surface CO2 fluxes for multiple sampling points at concentrations ranging from background levels to several tens of percent. To meet this need, PNNL is developing a multi-port battery-operated system capable of both spatial and temporal monitoring of CO2 at concentrations from ambient to at least 150,000 ppmv. This report describes the system components (sampling chambers, measurement and control system, and power supply) and the results of a field test at the ZERT site during the late summer and fall of 2008. While the system performed well overall during the field test, several improvements to the system are suggested for implementation in FY2009.

  20. Hydrogen milestone could help lower fossil fuel refining costs

    ScienceCinema (OSTI)

    McGraw, Jennifer

    2013-05-28

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, laboratory fellow and technical director of the INL High Temperature Electrolysis team, today announced that the latest fuel cell modification has set a new mark in endurance. The group's Integrated Laboratory Scale experiment has now operated continuously for 2,583 hours at higher efficiencies than previously attained. Learn more about INL research at http://www.facebook.com/idahonationallaboratory.

  1. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01

    2 0 Emissions form a Bubbling Fluidized Bed Combustor," Fuelcontrol SO emissions bubbling fluidized-bed coal combustor

  2. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01

    control SO emissions bubbling fluidized-bed coal combustorN 2 0 Emissions form a Bubbling Fluidized Bed Combustor,"

  3. New Automobile Regulations: Double the Fuel Economy, Half the CO2 Emissions, and Even Automakers Like It

    E-Print Network [OSTI]

    Lutsey, Nic

    2012-01-01

    ever taken to reduce oil consumption and carbon emissions inever taken to reduce oil consumption and carbon emissions in

  4. METHODOLOGIES FOR REVIEW OF THE HEALTH AND SAFETY ASPECTS OF PROPOSED NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL SITES AND FACILITIES. VOLUME 9 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01

    Specific Considerations Fossil Fuel Coal r. a. b. Normalliquid dominated) and fossil-fuel fired (either coal, oil,Specific Cons iderations Fossil Fuel Coal Oil 1. 1. 3. L 1

  5. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  6. Developing the Fuels of the Future Road transport accounts for 21% of the CO2 emissions of the UK

    E-Print Network [OSTI]

    ·Vast majority of vehicles are powered by hydrocarbon fuels ·Situation unlikely to change soon. Hydrogen required to develop new fuels, reducing NOx, CO2, unburned hydrocarbons and particulates. All new secondary. This allows measurement of the effects of exhaust gas recirculation (EGR), a strategy used to reduce NOx

  7. Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment of Carbon Capture and Storage Technologies

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Projections (UEP) [1] show a decrease over the next two decades, but at a reduced rate compared to the 1990's represent electricity supplies with no (historically) or low (UEP projections) UK CO2 reduction targets of alternative options to deliver at a lower price. Additional costs for the 'decarbonised electricity' options

  8. A synthesis of carbon in international trade

    E-Print Network [OSTI]

    Peters, G. P; Davis, S. J; Andrew, R.

    2012-01-01

    E. : CO 2 emissions from biomass combustion for bioenergy:Biomass total Livestock products Crops HWPs Fossil fuels ? Embodied carbon includes emissions from fossil fuel combustion,

  9. Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities

    E-Print Network [OSTI]

    Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities Biomass energy input basis in the upcoming calendar year? - Please check "yes" or "no." 12. Types of Biomass Fuel Used - Please report the quantity and supplier of the following types of biomass fuel used

  10. AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT RELATIVE TO FOSSIL FUEL

    E-Print Network [OSTI]

    Firestone, Jeremy

    AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT RELATIVE TO FOSSIL FUEL POWER. Jarvis All Rights Reserved #12;AN EVALUATION OF THE WILDLIFE IMPACTS OF OFFSHORE WIND DEVELOPMENT in offshore wind energy. I would also like to thank my committee members, Dr. Jeremy Firestone

  11. Essays on Efficiency of the Farm Credit System and Dynamic Correlations in Fossil Fuel Markets 

    E-Print Network [OSTI]

    Dang, Trang Phuong Th 1977-

    2012-11-28

    and natural gas prices, the three major fossil fuels, are examined. The Farm Credit system is a key lender in the U.S. agricultural sector, and its performance can influence the performance of the agricultural sector. However, its efficiency in providing...

  12. 55Home Power #21 February / March 1991 ALTERNATIVES TO FOSSIL FUELED

    E-Print Network [OSTI]

    alternative energy technologies to provide us with a contemporary standard of living, looking for more power is site specific and will not be available in many places. Alternative energy generation also55Home Power #21 · February / March 1991 Bio­Gas ALTERNATIVES TO FOSSIL FUELED ENGINE

  13. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B.

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  14. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Maine (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Maine. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Maine to be $1.3 billion, annual CO2 reductions are estimated at 2.8 million tons, and annual water savings are 1,387 million gallons.

  15. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in North Carolina (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-03-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in North Carolina. Although construction and operation of 1000 MW of wind power is a significant effort, seven states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in North Carolina to be $1.1 billion, annual CO2 reductions are estimated at 2.9 million tons, and annual water savings are 1,558 million gallons.

  16. AISI/DOE Technology Roadmap Program: Development of an O2-Enriched Furnace System for Reduced CO2 and NOx Emissions For the Steel Industry

    SciTech Connect (OSTI)

    Edward W. Grandmaison; David J. Poirier; Eric Boyd

    2003-01-20

    An oxygen-enriched furnace system for reduced CO2 and NOx emission has been developed. The furnace geometry, with a sidewall-mounted burner, was similar to configurations commonly encountered in a steel reheat furnace. The effect of stack oxygen concentration, oxygen enrichment level and air infiltration on fuel savings/CO2 reduction, NOx emissions and scale formation were investigated. The firing rate required to maintain the furnace temperature at 1100 C decreased linearly with increasing oxygen enrichment. At full oxygen enrichment a reduction of 40-45% in the firing rate was required to maintain furnace temperature. NOx emissions were relatively constant at oxygen enrichment levels below 60% and decreased concentration at all oxygen enrichment levels. Air infiltration also had an effect on NOx levels leading to emissions similar to those observed with no air infiltration but with similar stack oxygen concentrations. At high oxygen enrichment levels, there was a larger variation in the refractory surface-temperature on the roof and blind sidewall of the furnace. Scale habit, intactness, adhesion and oxidation rates were examined for five grades of steel over a range of stack oxygen concentrations and oxygen enrichment levels at 1100 degree C. The steel grade had the largest effect on scaling properties examined in this work. The stack oxygen concentration and the oxygen enrichment level had much smaller effects on the scaling properties.

  17. Quantum Alloys Offer Prospects for CO2 Management Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantum Alloys Offer Prospects for CO2 Mgt. Technologies Utilizing and Storing Carbon Dioxide Emissions Quantum Alloys Offer Unique Prospects for CO2 Management Technologies...

  18. A Future for Fossil Fuel By JOHN DEUTCH and ERNEST MONIZ March 15, 2007; Page A17

    E-Print Network [OSTI]

    Deutch, John

    much "cleaner" generation of electricity from coal since the Clean Air Act of 1970. Global warming and economic technologies and policies that permit the continued use of coal without increasing CO2 emissions-generating capacity; and (3) new technology to reduce C02 emissions from coal combustion will become economic

  19. Characterization of carbonaceous aerosols outflow from India and Arabia: Biomass/biofuel burning and fossil fuel combustion

    E-Print Network [OSTI]

    and fossil fuel combustion S. A. Guazzotti,1 D. T. Suess,2 K. R. Coffee,2,3 P. K. Quinn,4 T. S. Bates,4 A concentration of submicrometer carbon-containing particles with potassium (indicative of combustion sources the Arabian Peninsula, where dominance of fossil fuel combustion is suggested by results from single

  20. 1 Characterization of carbonaceous aerosols outflow from India and 2 Arabia: Biomass/biofuel burning and fossil fuel combustion

    E-Print Network [OSTI]

    Dickerson, Russell R.

    /biofuel burning and fossil fuel combustion 3 S. A. Guazzotti,1 D. T. Suess,1,2 K. R. Coffee,1,3 P. K. Quinn,4 T. S with potassium 17 (indicative of combustion sources), and mass concentration of submicrometer non-sea- 18 salt Peninsula, where dominance of fossil fuel combustion is suggested by 30 results from single

  1. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01

    965-976 (1987). Arthur D. Little, Inc. , Methane EmissionsAlphatania Group (1989) Arthur D. Little (1989) European gas

  2. nature geoscience | VOL 2 | NOVEMBER 2009 | www.nature.com/naturegeoscience 737 CO2 emissions from forest loss

    E-Print Network [OSTI]

    Jackson, Robert B.

    emissions from forest loss G. R. van der Werf,D. C. Morton, R. S. DeFries, J. G. J. Olivier, P. S as a notable carbon dioxide source. P rogrammes that aim to reduce the emissions from deforestation and forest degradation are being considered as a cost-effective way to mitigate anthropogenic greenhouse-gas emissions1

  3. Quantifying Regional Economic Impacts of CO2 Intensity Targets in China

    E-Print Network [OSTI]

    Zhang, Da

    2012-09-01

    To address rising energy use and CO2 emissions, China’s leadership has enacted energy and CO2 intensity

  4. Multiple Molecular Winds in Evolved Stars I. A Survey of CO(2-1) and CO(3-2) Emission from 45 Nearby AGB Stars

    E-Print Network [OSTI]

    G. R. Knapp; K. Young; E. Lee; A. Jorissen

    1997-11-12

    This paper describes observations of a new phenomenon in evolved mass-losing AGB stars: the presence of two winds with different expansion velocities. CO(2-1) and CO(3-2) line emission was observed for 45 AGB stars at high velocity resolution and double winds found in 20% of the sample. Highly asymmetric lines were found in six other stars. The data tentatively suggest that double winds occur when the star undergoes a change (pulsational mode, chemical composition) and that the very narrow components represent the onset of a new phase of mass loss.

  5. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wan -Hui; Himeda, Yuichiro; Muckerman, James T.; Manbeck, Gerald F.; Fujita, Etsuko

    2015-09-03

    In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in severalmore »ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.« less

  6. The relationship between policy choice and the size of the policy region: Why small jurisdictions may prefer renewable energy policies to reduce CO2 emissions

    E-Print Network [OSTI]

    Accordino, Megan H.; Rajagopal, Deepak

    2012-01-01

    may prefer renewable energy policies to reduce CO2 emissionsmay prefer renewable energy policies to reduce CO 2www.dsireusa.org Renewable Energy Policy Network, http://

  7. Municipal waste combustion assessment: Fossil fuel co-firing. Final report, October 1988-July 1989

    SciTech Connect (OSTI)

    Landrum, V.J.; Barton, R.G.

    1989-07-01

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; and describes the population of coal fired boilers that currently co-fire RDF, have previously co-fired RDF but have ceased to do so, and have been used in RDF co-firing demonstrations. (Fossil fuel co-firing, defined as the combustion of RDF with another fuel (usually coal) in a device designed primarily to burn the other fuel, is generally confined to commercial and utility boilers.) Model plants are developed and good combustion practices are recommended.

  8. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    Total primary energy saving energy saving in Chinese steelPower Enterprises Energy Savings and Emissions Reductioncost of the measures, and energy saving of the measures). It

  9. Assessment of a multi-stage underwater vehicle concept using a fossil-fuel Stirling engine

    SciTech Connect (OSTI)

    Reader, G.T.; Potter, I.J.

    1995-12-31

    The Stirling Engine because of its inherent closed-cycle operation can be readily modified to work in an airless environment even if the primary source of energy is a fossil fuel. Thus, Stirling engines are well suited for use in the underwater environment and have been operated successfully in manned military submarines since the early 1980s. In recent years fossil fueled Stirling systems have been also proposed for use in small unmanned underwater vehicles (UUVs). However, in this case the need to carry an onboard oxygen supply in a very confined space has presented a number of design difficulties. These are identified in the paper. However, if the oxidant supply to the engine is provided by the membrane extraction of dissolved oxygen from seawater and/or disposable fuel/oxidant pods are used then the UUV Stirling system becomes more attractive. If this latter concept is extended to include multi-stage vehicles then it can be shown that fossil fueled Stirlings could also be put to effective use in long range-long endurance underwater vehicular operations.

  10. Diesel Engine CO2 and SOx Emission Compliance Strategy for the Royal Navy (RN) and Royal Fleet Auxiliary (RFA) Flotillas

    Broader source: Energy.gov [DOE]

    Poster presentation from the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  11. Trends in the sources and sinks of carbon dioxide

    E-Print Network [OSTI]

    2009-01-01

    for updating global fossil fuel carbon dioxide emissions.in accounting for CO 2 from fossil fuels. J. Ind. Ecol. 12,budget. G.M. estimated the fossil fuel emissions and G.P.P.

  12. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01

    emissions from fossil-fuel com- bustion, Biogeosciences, 9,re- gional and national fossil-fuel CO 2 emissions, Carbontimes more carbon in fossil fuels than it emitted by burning

  13. Comparing large scale CCS deployment potential in the USA and China: a detailed analysis based on country-specific CO2 transport & storage cost curves

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Davidson, Casie L.; Dooley, James J.

    2011-04-18

    The United States and China are the two largest emitters of greenhouse gases in the world and their projected continued growth and reliance on fossil fuels, especially coal, make them strong candidates for CCS. Previous work has revealed that both nations have over 1600 large electric utility and other industrial point CO2 sources as well as very large CO2 storage resources on the order of 2,000 billion metric tons (Gt) of onshore storage capacity. In each case, the vast majority of this capacity is found in deep saline formations. In both the USA and China, candidate storage reservoirs are likely to be accessible by most sources with over 80% of these large industrial CO2 sources having a CO2 storage option within just 80 km. This suggests a strong potential for CCS deployment as a meaningful option to efforts to reduce CO2 emissions from these large, vibrant economies. However, while the USA and China possess many similarities with regards to the potential value that CCS might provide, including the range of costs at which CCS may be available to most large CO2 sources in each nation, there are a number of more subtle differences that may help us to understand the ways in which CCS deployment may differ between these two countries in order for the USA and China to work together - and in step with the rest of the world - to most efficiently reduce greenhouse gas emissions. This paper details the first ever analysis of CCS deployment costs in these two countries based on methodologically comparable CO2 source and sink inventories, economic analysis, geospatial source-sink matching and cost curve modeling. This type of analysis provides a valuable insight into the degree to which early and sustained opportunities for climate change mitigation via commercial-scale CCS are available to the two countries, and could facilitate greater collaboration in areas where those opportunities overlap.

  14. Contribution of Ocean, Fossil Fuel, Land Biosphere and Biomass Burning Carbon1 Fluxes to Seasonal and Interannual Variability in Atmospheric CO22

    E-Print Network [OSTI]

    Mahowald, Natalie

    1 Contribution of Ocean, Fossil Fuel, Land Biosphere and Biomass Burning Carbon1 Fluxes to Seasonal et al., 1989].18 Anthropogenic fossil fuel combustion and cement manufacture drive most of the recent by deforestation, discussed below) over the last 50 years. The fossil fuel plus4 cement input, in contrast

  15. www.biosciencemag.org November 2006 / Vol. 56 No. 11 BioScience 875 Green Plants, Fossil Fuels, and Now Biofuels

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    www.biosciencemag.org November 2006 / Vol. 56 No. 11 · BioScience 875 Green Plants, Fossil Fuels about 4.5 percent of the world population, the United States accounts for a quarter of total fossil fuel and distillation operations confirms that 29 percent more energy (derived from fossil fuels) is required to produce

  16. Byrne, et al., 2008. In Peter Droege eds. Urban Energy Transition: From Fossil Fuels to Renewable Power.

    E-Print Network [OSTI]

    Delaware, University of

    Byrne, et al., 2008. In Peter Droege eds. Urban Energy Transition: From Fossil Fuels to Renewable. Researchers at the Center for Energy and Environmental Policy (CEEP) have investi gated scenarios for large CO

  17. EA-1778: Proposed Rule, 10 CFR 433 and 435, Energy Conservation and Fossil Fuel-Generated Energy

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of DOE's Proposed Rule, 10 CFR Part 433, “Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Commercial and Multi-Family High-Rise Residential Buildings” and 10 CFR Part 435, “Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Low-Rise Residential Buildings”.

  18. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    SciTech Connect (OSTI)

    Zhou, Nan; Fridley, David; McNeil, Michael; Zheng, Nina; Letschert, Virginie; Ke, Jing

    2011-04-01

    China has implemented a series of minimum energy performance standards (MEPS) for over 30 appliances, voluntary energy efficiency label for 40 products and a mandatory energy information label that covers 19 products to date. However, the impact of these programs and their savings potential has not been evaluated on a consistent basis. This paper uses modeling to estimate the energy saving and CO{sub 2} emission reduction potential of the appliances standard and labeling program for products for which standards are currently in place, under development or those proposed for development in 2010 under three scenarios that differ in the pace and stringency of MEPS development. In addition to a baseline 'Frozen Efficiency' scenario at 2009 MEPS level, the 'Continued Improvement Scenario' (CIS) reflects the likely pace of post-2009 MEPS revisions, and the likely improvement at each revision step. The 'Best Practice Scenario' (BPS) examined the potential of an achievement of international best practice efficiency in broad commercial use today in 2014. This paper concludes that under 'CIS', cumulative electricity consumption could be reduced by 9503 TWh, and annual CO{sub 2} emissions of energy used for all 37 products would be 16% lower than in the frozen efficiency scenario. Under a 'BPS' scenario for a subset of products, cumulative electricity savings would be 5450 TWh and annual CO{sub 2} emissions reduction of energy used for 11 appliances would be 35% lower.

  19. POWER PLANT RELIABILITY-AVAILABILITY AND STATE REGULATION. VOLUME 7 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01

    and Related Standards for Fossil-Fuel and Geo- thermal Powerposed Nuclear, Geothermal, and Fossil-Fuel Sites and Facili-NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN

  20. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach 

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  1. Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China

    SciTech Connect (OSTI)

    Zhou, Nan; Fridley, David; McNeill, Michael; Zheng, Nina; Letschert, Virginie; Ke, Jing; Saheb, Yamina

    2010-06-07

    China is now the world's largest producer and consumer of household appliances and commercial equipment. To address the growth of electricity use of the appliances, China has implemented a series of minimum energy performance standards (MEPS) for 30 appliances, and voluntary energy efficiency label for 40 products. Further, in 2005, China started a mandatory energy information label that covers 19 products to date. However, the impact of these standard and labeling programs and their savings potential has not been evaluated on a consistent basis. This research involved modeling to estimate the energy saving and CO{sub 2} emission reduction potential of the appliances standard and labeling program for products for which standards are currently in place, or under development and those proposed for development in 2010. Two scenarios that have been developed differ primarily in the pace and stringency of MEPS development. The 'Continued Improvement Scenario' (CIS) reflects the likely pace of post-2009 MEPS revisions, and the likely improvement at each revision step considering the technical limitation of the technology. The 'Best Practice Scenario' (BPS) examined the potential of an achievement of international best practice MEPS in 2014. This paper concludes that under the 'CIS' of regularly scheduled MEPS revisions to 2030, cumulative electricity consumption could be reduced by 9503 TWh, and annual CO{sub 2} emissions would be 16% lower than in the frozen efficiency scenario. Under a 'BPS' scenario for a subset of products, cumulative electricity savings would be 5450 TWh and annual CO{sub 2} emissions reduction would be 35% lower than in the frozen scenario.

  2. Development of a Method for Measuring Carbon Balance in Chemical Sequestration of CO2

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pan, Wei-Ping; Riley, John T.

    2006-09-09

    Anthropogenic CO2 released from fossil fuel combustion is a primary greenhouse gas which contributes to “global warming.” It is estimated that stationary power generation contributes over one-third of total CO2 emissions. Reducing CO2 in the atmosphere can be accomplished either by decreasing the rate at which CO2 is emitted into the atmosphere or by increasing the rate at which it is removed from it. Extensive research has been conducted on determining a fast and inexpensive method to sequester carbon dioxide. These methods can be classified into two categories, CO2 fixation by natural sink process for CO2, or direct CO2 sequestration by artificial processes. In direct sequestration, CO2 produced from sources such as coal-fired power plants, would be captured from the exhausted gases. CO2 from a combustion exhaust gas is absorbed with an aqueous ammonia solution through scrubbing. The captured CO2 is then used to synthesize ammonium bicarbonate (ABC or NH4HCO3), an economical source of nitrogen fertilizer. In this work, we studied the carbon distribution after fertilizer is synthesized from CO2. The synthesized fertilizer in laboratory is used as a “CO2 carrier” to “transport” CO2 from the atmosphere to crops. After biological assimilation and metabolism in crops treated with ABC, a considerable amount of the carbon source is absorbed by the plants with increased biomass production. The majority of the unused carbon source percolates into the soil as carbonates, such as calcium carbonate (CaCO3) and magnesium carbonate (MgCO3). These carbonates are environmentally benign. As insoluble salts, they are found in normal rocks and can be stored safely and permanently in soil. This investigation mainly focuses on the carbon distribution after the synthesized fertilizer is applied to soil. Quantitative examination of carbon distribution in an ecosystem is a challenging task since the carbon in the soil may come from various sources. Therefore synthesized 14C tagged NH4HCO3 (ABC) was used. Products of ammonium bicarbonate (ABC) or long-term effect ammonium bicarbonate (LEABC) were tagged with 14C when they were synthesized in the laboratory. An indoor greenhouse was built and wheat was chosen as the plant to study in this ecosystem. The investigated ecosystem consists of plant (wheat), soils with three different pH values (alkaline, neutral and acid), and three types of underground water (different Ca2+ and Mg2+ concentrations). After biological assimilation and metabolism in wheat receiving ABC or LEABC, it was found that a considerable amount (up to 10%) of the carbon source is absorbed by the wheat with increased biomass production. The majority of the unused carbon source (up to 76%) percolated into the soil as carbonates, such as environmentally benign calcium carbonate (CaCO3). Generally speaking, alkaline soil has a higher capability to capture and store carbon. For the same soil, there is no apparent difference in carbon capturing capability between ABC fertilizer and LEABC fertilizer. These findings answer the question how carbon is distributed after synthesized fertilizer is applied into the ecosystem. In addition, a separate post-experiment on fertilizer carbon forms that exist in the soil was made. It was found that the up to 88% of the trapped carbon exists in the form of insoluble salts (i.e., CaCO3) in alkaline soils. This indicates that alkaline soil has a greater potential for storing carbon after the use of the synthesized fertilizer from exhausted CO2.

  3. Regional Analysis of Building Distributed Energy Costs and CO2 Abatement: A U.S. - China Comparison

    E-Print Network [OSTI]

    Mendes, Goncalo

    2014-01-01

    Analysis of Building Energy Costs and CO 2 Emissions, ACEEEDistributed   Energy  Costs  and  CO 2  Abatement:     A  of Building Distributed Energy Costs and CO 2 Abatement: A

  4. Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

    SciTech Connect (OSTI)

    Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

    2011-12-22

    The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

  5. Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil fuels such as coal, oil, and gas, have caused a substantial increase

    E-Print Network [OSTI]

    Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil-caused CO2 emissions and to remove CO2 from the atmosphere. 2.0 What is carbon sequestration? The term "carbon sequestration" is used to describe both natural and deliberate CARBON,INGIGATONSPERYEAR 1.5 Fossil

  6. Rethinking wedges

    E-Print Network [OSTI]

    Davis, Steven J; Cao, Long; Caldeira, Ken; Hoffert, Martin I

    2013-01-01

    M I 2010 Farewell to fossil fuels? Science 329 1292 [10]Regional, and National Fossil-Fuel CO 2 Emissions (Oakdemands and dependence on fossil-fuel energy effectively

  7. Perspectives on Carbon Capture and Sequestration in the United States

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle

    2011-01-01

    E A and Keith D W 1998 Fossil fuels without CO 2 emissionsCapture and Storage from Fossil Fuel Use,” contribution tocontinue using its vast fossil fuel resources and existing

  8. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    2006. “California Crude Oil Production and Imports” AprilProduction Report (Quarterly) EIA-856 Monthly Foreign Crude OilProduction Annual Report of Natural and Supplemental Gas Supply and Disposition Domestic Crude Oil

  9. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    2006. “California Crude Oil Production and Imports” Aprilwww.energy.ca.gov/oil/statistics/crude_oil_receipts.html desector shows inputs of crude oil, unfinished oil and

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    residual fuel oil, petroleum coke, and waste and other oil)residual fuel oil, petroleum coke, and waste and other oilOil Lubricants Naphtha Petroleum feedstocks Natural Gas Liquids Municipal Solid Waste

  11. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    IPP Kbbl kLBS kst kW LBNL LPG Mcf MECS MMBtu Mt MTBE MVSTAFFliquefied petroleum gas (LPG), or still gas. The secondhydrogen include natural gas, LPG, naphtha, and refinery

  12. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    fuels consumed for international maritime shipping as wellby intrastate marine shipping. Distillate fuel use by ocean-residual fuel, 3.5% was used by interstate marine shipping,

  13. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    International Energy Agency (IEA), 2003a. Energy Balancesof OECD Countries. Paris: IEA.International Energy Agency (IEA) , 2003b. Energy Balances

  14. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    Performance Monitoring System IEA International Energy Agency IPCC Intergovernmental Panel on Climate Change SCAQMD South Coast Air Quality Management District scf Standard cubic feet SEDS State Energy Data System by: Stephane de la Rue du Can Tom Wenzel Lynn Price Environmental Energy Technologies Division

  15. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    M. , Denning, A. S. , Rayner, P. J. , Baker, D. , Bousquet,35–52, 1995. Enting, I. G. , Rayner, P. J. , and Ciais, P. :P. , Chevallier, F. , Rayner, P. , Klonecki, A. , Houweling,

  16. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Standard cubic feet State Energy Data System U.S. Standardsources of California energy data, primarily from thesources of California energy data, primarily from the

  17. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    E-Print Network [OSTI]

    2015-01-01

    the coal used for exports, non-energy use and stock changes.energy consumption~domestic production z imports { exports +energy consumption ~ domestic production z imports { exports

  18. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Lubricants Asphalt Waxes Special Naphtha Petrochem feedstocks Other Petro Prods Coal Net reconciliation error Total Consumption

  19. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    petroleum products natural gas Refining** Oil/gas extractionpetroleum products natural gas Refining** Oil/gas extraction

  20. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    E-Print Network [OSTI]

    2012-01-01

    of a lack of energy-consumption data, most of the data atsets including sectoral energy consumption data, power plantrelated to energy consumption, but data collection and

  1. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Climate Change Independent Power Producer Thousand barrelsElectric Utilities Independent Power Producers CHP, Electric

  2. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    First Purchase Report Annual Underground Gas Storage ReportMonthly Underground Gas Storage Report Coordinated BulkUnderground Natural Gas Storage Report EIA-914 Monthly

  3. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    the case of oil and extraction, consumption of natural gasGas, Crude Oil and Distillates NGLs consumption in CALEBOil and Gas Extraction (Mcf) Re-pressuring Lease Fuel Consumption

  4. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    and sector. In California, the transport sector is by farAbout 95% of California’s 2000 transport-sector residualair transport, CALEB estimated that 39.9% of California’s

  5. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Transportation California Air Resources Board California EnergyTransportation Statistics British thermal unit California Conventional and Alternative Vehicle Response Simulator model California Energy

  6. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    E-Print Network [OSTI]

    2015-01-01

    in China. Renew. Sustain. Energy Rev. 34, 337–349 ( 2014).and uncertainties. Energy Policy 31. Le Que´re´, C. et al.36. Fridley, E. D. China Energy Databook—User Guide and

  7. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01

    Public Interest Energy Research Petroleum IndustryOther Energy Industries (1A1cii) Petroleum Refining (1A1b)factor (67%). Petroleum Product • Energy Use in Chemical

  8. Air Pollution Control Regulations: No. 13 - Particulate Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Regulations Provider Department of Environmental Management The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and...

  9. Direct measurements of marine aerosols to examine the influence of biological activity, anthropogenic emissions, and secondary processing on particle chemistry

    E-Print Network [OSTI]

    Gaston, Cassandra Jayne

    2012-01-01

    biomass burning, fossil fuel combustion, agricultural emissions,combustion when port and vehicular emissions were dominant and in Sacramento likely due to contributions from biomass

  10. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  11. Over the past years, an interest has arisen in resolving two major issues: increased carbon dioxide (CO2) emissions and depleting energy resources. A convenient solution would be a process that could simultaneously

    E-Print Network [OSTI]

    Over the past years, an interest has arisen in resolving two major issues: increased carbon dioxide (CO2) emissions and depleting energy resources. A convenient solution would be a process that could the photocatalyst titanium dioxide (TiO2) is such a process. However, this process is presently inefficient

  12. Biomass torrefaction and CO2 capture using mining wastes A new approach for reducing greenhouse gas emissions of co-firing plants

    E-Print Network [OSTI]

    Biomass torrefaction and CO2 capture using mining wastes ­ A new approach for reducing greenhouse: Biomass Torrefaction Carbon dioxide Sequestration Mining residues a b s t r a c t A novel combination. Torrefaction was combined with ultramafic mining residues to capture emitted CO2. Presence of CH4 and CO

  13. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/02

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions. (DMC)

  14. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/03

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions.

  15. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  16. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  17. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H; Parish, Esther S; Kline, Keith L

    2015-01-01

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  18. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  19. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  20. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    SciTech Connect (OSTI)

    Michael Petrik; Robert Ruhl

    2012-03-31

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled â??Small Scale SOFC Demonstration using Bio-based and Fossil Fuels.â? Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  1. WELL KNOWN . . . TO A FEW PEOPLE: ATTRIBUTION OF EXCESS ATMOSPHERIC CO2 AND RESULTING GLOBAL TEMPERATURE CHANGE TO

    E-Print Network [OSTI]

    century the major source of incremental atmospheric CO2 was not FF emissions but emissions from so to deforestation. LUC CO2 emissions have been a substantial fraction of anthropogenic CO2 emissions throughout the industrial period and even at present are about a third as great as FF emissions. Cumulative LUC CO2

  2. Quick Notes on CO2 Diagram and Energy Diagram For the ESRP 285 Website (Spring 2008)

    E-Print Network [OSTI]

    Ford, Andrew

    (CO2) emissions are the largest source of greenhouse gas emissions, accounting for over 80% of the emissions in the USA (EIA 2003, p. 35). CO2 emissions arise from the combustion of carbon fuels arrows are sized to represent emissions in million metric tons of CO2 equivalent, hereafter abbreviated

  3. 20th-Century Industrial Black Carbon Emissions Altered Arctic Climate Forcing

    E-Print Network [OSTI]

    2007-01-01

    biomass and fossil fuel combustion alters chemical and physical properties of the atmosphere and snow albedo, yet little is known about its emission

  4. A Comparative Evaluation of Greenhouse Gas Emission Reduction Strategies for the Maritime Shipping and Aviation Sectors

    E-Print Network [OSTI]

    Hansen, Mark; Smirti, Megan; Zou, Bo

    2008-01-01

    Vehicle Activity Network Efficiency GHG Emissions Operational Efficiency Alternative EnergyAlternative energy includes the substitution of fuels other than fossil fuels for vehicle

  5. Propane-Diesel Dual Fuel for CO2 and Nox Reduction | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Propane-Diesel Dual Fuel for CO2 and Nox Reduction Propane-Diesel Dual Fuel for CO2 and Nox Reduction Test results show significant CO2 and NOx emission reductions, fuel economy...

  6. Regulation, Allocation, and Leakage in Cap-and-Trade Markets for CO2

    E-Print Network [OSTI]

    Bushnell, Jim B; Chen, Yihsu

    2009-01-01

    and Philippe Quirion. Co2 abatement, competitiveness andDaniel Kahn. Allocation of co2 emissions al- lowances in theA short-run case analysis of co2 leakage and nox and so2

  7. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  8. Contribution of ocean, fossil fuel, land biosphere, and biomass burning carbon fluxes to seasonal and interannual variability in atmospheric CO 2

    E-Print Network [OSTI]

    2008-01-01

    Storhofdi Iceland Canary Islands Jubany Antarctica KeyGuam Halley Bay Antarctica Canary Islands Key Biscayne FL

  9. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  10. The Elephant in the Room: Dealing with Carbon Emissions from Synthetic Transportation Fuels Production

    SciTech Connect (OSTI)

    Parker, Graham B.; Dahowski, Robert T.

    2007-07-11

    Carbon dioxide (CO2), produced by conversion of hydrocarbons to energy, primarily via fossil fuel combustion, is one of the most ubiquitous and significant greenhouse gases (GHGs). Concerns over climate change precipitated by rising atmospheric GHG concentrations have prompted many industrialized nations to begin adopting limits on emissions to inhibit increases in atmospheric CO2 levels. The United Nations Framework Convention on Climate Change states as a key goal the stabilization of atmospheric CO2 at a level that prevents “dangerous anthropogenic interference” with the planet’s climate systems. This will require sharply reducing emissions growth rates in developing nations, and reducing CO2 emissions in the industrialized world to half current rates in the next 50 years. And ultimately, stabilization will require that annual emissions drop to almost zero.Recently, there has been interest in producing synthetic transportation fuels via coal-to-liquids (CTL) production, particularly in countries where there is an abundant supply of domestic coal, including the United States. This paper provides an overview of the current state of CTL technologies and deployment, a discussion of costs and technical requirements for mitigating the CO2 impacts associated with a CTL facility, and the challenges facing the CTL industry as it moves toward maturity.

  11. A brief study into the impact University of Bath has had on CO2 emissions and the cost of ownership of passenger cars.

    E-Print Network [OSTI]

    Burton, Geoffrey R.

    their expertise and resources are among the very best applicators of these tests in the UK and have been able of oil needed to protect the engine at any particular time thereby saving energy, fuel and reducing CO2 totalled 129,200 in Europe in 2012 and sales of this engine will soon reach 300,000 per year, coming from

  12. Estimates of the Global Indirect Energy-Use Emission Impacts of USA Biofuel Policy

    SciTech Connect (OSTI)

    Oladosu, Gbadebo A [ORNL

    2012-01-01

    This paper evaluates the indirect energy-use emission implications of increases in the use of biofuels in the USA between 2001 and 2010 as mandates within a dynamic global computable general equilibrium model. The study incorporates explicit markets for biofuels, petroleum and other fossil fuels, and accounts for interactions among all sectors of an 18-region global economy. It considers bilateral trade, as well as the dynamics of capital allocation and investment. Simulation results show that the biofuel mandates in the USA generate an overall reduction in global energy use and emissions over the simulation period from 2001 to 2030. Consequently, the indirect energy-use emission change or emission leakage under the mandate is negative. That is, global emission reductions are larger than the direct emission savings from replacing petroleum with biofuels under the USA RFS2 over the last decade. Under our principal scenario this enhanced the direct emission reduction from biofuels by about 66%. The global change in lifecycle energy-use emissions for this scenario was estimated to be about 93 million tons of CO2e in 2010, 45 million tons of CO2e in 2020, and an increase of 5 million tons of CO2e in 2030, relative to the baseline scenario. Sensitivity results of six alternative scenarios provided additional insights into the pattern of the regional and global effects of biofuel mandates on energy-use emissions.

  13. O P I N I O N Biogenic vs. geologic carbon emissions and forest

    E-Print Network [OSTI]

    Keeton, William S.

    O P I N I O N Biogenic vs. geologic carbon emissions and forest biomass energy production J O H N- versities articulated a concern over equating biogenic carbon (C) emissions with fossil fuel emissions the amount of carbon in circulation. In contrast, carbon dioxide released from fossil fuels increases

  14. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    SciTech Connect (OSTI)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D.

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  15. China's Energy and Carbon Emissions Outlook to 2050

    E-Print Network [OSTI]

    Zhou, Nan

    2011-01-01

    CO2 Emissions Reduction by Source ..67 AIS Power Sector CO2 Emissions Reduction by Source EnergyCO2 Emission Reduction under AIS by Fuel Source

  16. Coherence metric for optimal compressive J. Ray1 , J. Lee1 , S. Lefantzi1 and S. A. McKenna2

    E-Print Network [OSTI]

    Ray, Jaideep

    · Explanation of the physics-based linear inverse problem ­ Estimation of fossil-fuel CO2 (ffCO2) emissions in a physics inversion · Aim: Devise a method to estimate fossil-fuel CO2 (ff-CO2) emissions ­ Data: measurements of ff-CO2 concentrations at a sparse set of sensors · Motivation ­ Monitoring emission & cap

  17. An overview of alternative fossil fuel price and carbon regulation scenarios

    SciTech Connect (OSTI)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices, (3) externally generated oil price forecasts, and (4) the historical difficulty in accurately forecasting oil prices. Overall, a spread between the FE-EERE High Oil Price and Reference scenarios of well over $8/bbl is supported by the literature. We conclude that a wide range of carbon regulation scenarios are possible, especially within the time frame considered by EERE and FE (through 2050). The Working Group's Carbon Cap-and-Trade Scenario is found to be less aggressive than many Kyoto-style targets that have been analyzed, and similar in magnitude to the proposed Climate Stewardship Act. The proposed scenario is more aggressive than some other scenarios found in the literature, however, and ignores carbon banking and offsets and does not allow nuclear power to expand. We are therefore somewhat concerned that the stringency of the proposed carbon regulation scenario in the 2010 to 2025 period will lead to a particularly high estimated cost of carbon reduction. As described in more detail later, we encourage some flexibility in the Working Group's ultimate implementation of the Carbon Cap-and-Trade Scenario. We conclude by identifying additional scenarios that might be considered in future analyses, describing a concern with the proposed specification of the High Fuel Price Scenario, and highlighting the possible difficulty of implementing extreme scenarios with current energy modeling tools.

  18. Kalman-filtered compressive sensing for high resolution estimation of anthropogenic greenhouse gas emissions from sparse measurements.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-09-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. The limited nature of the measured data leads to a severely-underdetermined estimation problem. If the estimation is performed at fine spatial resolutions, it can also be computationally expensive. In order to enable such estimations, advances are needed in the spatial representation of ffCO2 emissions, scalable inversion algorithms and the identification of observables to measure. To that end, we investigate parsimonious spatial parameterizations of ffCO2 emissions which can be used in atmospheric inversions. We devise and test three random field models, based on wavelets, Gaussian kernels and covariance structures derived from easily-observed proxies of human activity. In doing so, we constructed a novel inversion algorithm, based on compressive sensing and sparse reconstruction, to perform the estimation. We also address scalable ensemble Kalman filters as an inversion mechanism and quantify the impact of Gaussian assumptions inherent in them. We find that the assumption does not impact the estimates of mean ffCO2 source strengths appreciably, but a comparison with Markov chain Monte Carlo estimates show significant differences in the variance of the source strengths. Finally, we study if the very different spatial natures of biogenic and ffCO2 emissions can be used to estimate them, in a disaggregated fashion, solely from CO2 concentration measurements, without extra information from products of incomplete combustion e.g., CO. We find that this is possible during the winter months, though the errors can be as large as 50%.

  19. Rate Determination of the CO2* Chemiluminescence Reaction CO + O + M = CO2* + M 

    E-Print Network [OSTI]

    Kopp, Madeleine Marissa, 1987-

    2012-10-15

    numerous works have monitored CO2* chemiluminescence, a full kinetic scheme for the species has yet to be developed. A series of shock-tube experiments was performed in H2-N2O-CO mixtures highly diluted in argon at conditions where emission from CO2... for eleven common collision partners. The final mechanism developed for CO2* consisted of 14 reactions and 13 species. The rate for R1 was determined based on low-pressure experiments performed in two different H2-N2O-CO-Ar mixtures. Final mechanism...

  20. Using the National Fire Research Laboratory as a Test Bed for Traceable CO2

    E-Print Network [OSTI]

    at the source ­ Predicted Emissions vs Direct Emissions #12;Hydrocarbon Fuels GHG: CO2 Hydrocarbon Fuels GHG: CO Research Laboratory · Goal: Measure CO2 emissions with ±1% uncertainty · Reconcile the carbon mass balanceUsing the National Fire Research Laboratory as a Test Bed for Traceable CO2 Measurements Rodney

  1. The urgency of the development of CO2 capture from ambient air

    E-Print Network [OSTI]

    Bergman, Keren

    their CO2 emissions. Point-source CCS could be implemented without significant changes for consumers, which, 11). Point-source CCS and air capture are not the only options for reducing CO2 emissions. Stationary as insurance against CO2 leaking from storage and furthermore may provide an option for dealing with emissions

  2. THE INCREASING CONCENTRATION OF ATMOSPHERIC CO2: HOW MUCH, WHEN, AND WHY?

    E-Print Network [OSTI]

    the world suggests that the atmospheric concentration of CO2 has varied considerably over geologic time consequence of the varying ratio of H to C is that different fuels have different rates of CO2 emissions per emissions when fuel consumption is expressed in energy units. Table 1: CO2 Emission Rates for Fossil

  3. BUILDING A CO2 STORAGE HUB IN

    E-Print Network [OSTI]

    Painter, Kevin

    , once at the forefront of this innovative technology that can give us clean energy from abundant fossil technology we have in the battle to reduce CO2 emissions from power and industrial sources. Without it we and global reliance on low-cost energy from coal and gas shows no sign of diminishing, the time has come

  4. Electrolysis byproduct D2O provides a third way to mitigate CO2

    SciTech Connect (OSTI)

    Schenewerk, William Ernest

    2009-09-01

    Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.

  5. Feasibility of a Perfluorocarbon tracer based network to support Monitoring, Verification, and Accounting of Sequestered CO2

    E-Print Network [OSTI]

    Johnson, Peter D.

    , New York, 11073-5000 *S Supporting Information ABSTRACT: Carbon capture and sequestration (CCS emissions from fossil fuel based energy production through carbon capture and sequestration (CCS). CCS energy based economy. The Department of Energy (DOE) target leak rate for sequestration reservoirs is 1

  6. Buildings, Commissioning, Efficiency, Comfort, and CO2 

    E-Print Network [OSTI]

    Claridge, D. E.

    2006-01-01

    .6% of world CO2 emissions)? US commercial sector use ~50% of world commercial use? Asia today 10-20% of world commercial use 2055200514 7 Billion of Tons of Carbon Emitted per Year 1955 0 C Flat path Historicalemissions 1.9 ?Æ?Æ 2105 14 GtC/y7 GtC/y Seven..., Commissioning, Efficiency, Comfort, and CO2 Asian Pacific Building Commissioning Conference ICEBONovember 8, 2006Shenzhen, ChinaPresented ByDavid E. ClaridgeEnergy Systems LaboratoryTexas A&M University Commissioning New Buildings Beginnings Building Handover...

  7. The relationship between policy choice and the size of the policy region: Why small jurisdictions may prefer renewable energy policies to reduce CO2 emissions

    E-Print Network [OSTI]

    Accordino, Megan H.; Rajagopal, Deepak

    2012-01-01

    a subsidy to zero-emissions generation, nuclear and hydrono taxes or subsidies there. If nuclear and hydro are usedtaxes and subsidies, denoted here by x. If nuclear and hydro

  8. CO2 Injection in the Subsurface Kjetil Haugen

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    (1015 BTU) Year Oil Coal Gas Hydro Nuclear Other Figure 1: World energy consumption by energy type. Thus, replacing oil and coal with less carbon-intensive natural gas, is probably the fastest way of achieving a significant reduction in CO2 emissions. CO2 Capture Natural gas is the most clean burning fossil

  9. SPECIAL ISSUE Multi-spectral imaging of vegetation for detecting CO2 leaking

    E-Print Network [OSTI]

    Shaw, Joseph A.

    vegetation near shallow subsurface CO2 releases during summers 2007 and 2008 at the Zero Emissions Research to the CO2 sink­source relationship and vegetation density. The data also show short-term effects of rain sequestration for reducing greenhouse gas emissions is accompanied by a need for methods to detect CO2

  10. Energy and CO2 efficient scheduling of smart appliances in active houses equipped with batteries

    E-Print Network [OSTI]

    Johansson, Karl Henrik

    Energy and CO2 efficient scheduling of smart appliances in active houses equipped with batteries the electricity bill and the CO2 emissions. Mathematically, the scheduling problem is posed as a multi that the new formulation can decrease both the CO2 emissions and the electricity bill. Furthermore, a survey

  11. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    SciTech Connect (OSTI)

    Hai Xiao; Junhang Dong; Jerry Lin; Van Romero

    2011-12-31

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project â??DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases.â? This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  12. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    clean sources of energy. Asturias, in northern Spain, is theThe CO 2 emissions in Asturias represent the 8% of total COsequestration in Asturias are deep saline aquifers and

  13. Canada’s Bitumen Industry Under CO2 Constraints

    E-Print Network [OSTI]

    Chen, Y.-H. Henry

    We investigate the effects of implementing CO2 emissions reduction policies on Canada’s oil sands industry, the largest of its kind in the world. The production of petroleum products from oils sands involves extraction of ...

  14. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    to all DER technologies, PV adoption increases, but only in2 Pricing Scheme on CHP/PV adoption and CO 2 emissions SinceCO 2 price, PV and solar thermal adoption increases in all

  15. CO2 migration in saline aquifers. Part 1. Capillary trapping under slope and groundwater flow

    E-Print Network [OSTI]

    MacMinn, Christopher W.

    Injection of carbon dioxide (CO2) into geological formations is widely regarded as a promising tool for reducing global atmospheric CO2 emissions. To evaluate injection scenarios, estimate reservoir capacity and assess ...

  16. Assessing velocity and impedance changes due to CO2 saturation using interferometry on repeated seismic sources.

    E-Print Network [OSTI]

    Boyer, Edmond

    , Barcelona : Spain (2010)" #12;Introduction The role played by the industrial emission of carbon dioxide (CO2) in climate change has been well documented. Geological sequestration is a process to store CO2

  17. Non-CO2, Non-Greenhouse, Non-Gas Forcing Stephen E. Schwartz

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    AEROSOLS: Non-CO2, Non-Greenhouse, Non-Gas Forcing Stephen E. Schwartz Symposium on Controlling Emissions of Non-CO2 Greenhouse Gases and Aerosols: Scientific and Policy Challenges http

  18. Impacts of CO2 Mandates for New Cars in the European Union

    E-Print Network [OSTI]

    Paltsev, S.

    CO2 emissions mandates for new light-duty passenger vehicles have recently been adopted in the European Union (EU), which require steady reductions to 95 g CO2/km in 2021. Using a computable general equilibrium (CGE) model, ...

  19. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  20. Surface controls on the characteristics of natural CO2 seeps: implications for engineered CO2 stores

    E-Print Network [OSTI]

    Haszeldine, Stuart

    be characterized to design the most effective monitoring strategy. Key words: carbon capture and storage, carbon are considering adoption of carbon capture and storage technology to meet carbon emission reduction targets of Edinburgh, Edinburgh, UK ABSTRACT Long-term security of performance of engineered CO2 storage is a principle

  1. CO2 interaction with geomaterials.

    SciTech Connect (OSTI)

    Guthrie, George D. (U.S. Department of Energy, Pittsburgh, PA); Al-Saidi, Wissam A. (University of Pittsburgh, Pittsburgh, PA); Jordan, Kenneth D. (University of Pittsburgh, Pittsburgh, PA); Voora, Vamsee, K. (University of Pittsburgh, Pittsburgh, PA); Romanov, Vyacheslav N. (U.S. Department of Energy, Pittsburgh, PA); Lopano, Christina L (U.S. Department of Energy, Pittsburgh, PA); Myshakin, Eugene M. (URS Corporation, Pittsburgh, PA); Hur, Tae Bong (University of Pittsburgh, Pittsburgh, PA); Warzinski, Robert P. (U.S. Department of Energy, Pittsburgh, PA); Lynn, Ronald J. (URS Corporation, Pittsburgh, PA); Howard, Bret H. (U.S. Department of Energy, Pittsburgh, PA); Cygan, Randall Timothy

    2010-09-01

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas No.3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2 molecules may remain trapped for several months following several hours of exposure to high pressure (supercritical conditions), high temperature (above boiling point of water) or both. Such trapping is well preserved in either inert gas or the ambient environment and appears to eventually result in carbonate formation. We performed computer simulations of CO2 interaction with free cations (normal modes of CO2 and Na+CO2 were calculated using B3LYP / aug-cc-pVDZ and MP2 / aug-cc-pVDZ methods) and with clay structures containing interlayer cations (MD simulations with Clayff potentials for clay and a modified CO2 potential). Additionally, interaction of CO2 with hydrated Na-montmorillonite was studied using density functional theory with dispersion corrections. The sorption energies and the swelling behavior were investigated. Preliminary modeling results and experimental observations indicate that the presence of water molecules in the interlayer region is necessary for intercalation of CO2. Our preliminary conclusion is that CO2 molecules may intercalate into interlayer region of swelling clay and stay there via coordination to the interlayer cations.

  2. Krakow clean fossil fuels and energy efficiency program. Phase 1 report

    SciTech Connect (OSTI)

    Butcher, T.; Pierce, B. [eds.

    1995-06-01

    Krakow is one of the largest and oldest cities in Poland. It is situated in the south of the country on the banks of the Vistula River. From the 11th until the 17th centuries, it was the capital of Poland. Today, Krakow is a city of 750,000 residents, one of the largest centers of higher education, an important industrial center, and is of particular importance because of the number and kinds of historic buildings and sites. For this reason, Krakow was included by the UNESCO in the list of the world`s cultural heritages. For about three decades, significant air pollution has been one of Krakow`s most serious problems. Because the city is situated in the Vistula River valley, it is poorly ventilated and experiences a high concentration of air pollutants. The quality of air in Krakow is affected mainly by industry (Sendzimir Steelworks, energy industry, chemical plants), influx from the Silesian industrial region (power plants, metallurgy), transboundary pollution (Ostrava - Czech Republic), and local sources of low pollution, i.e. more than 1,000 boiler houses using solid fuels and more than 100,000 coal-fired home stoves. These local sources, with low stacks and almost no pollution-control equipment, are responsible for about 35-40% of the air pollution. This report presents phase I results of a program to reduce pollution in krakow. Phase I was to gather information on emissions and costs, and to verify assumptions on existing heating methods and alternatives.

  3. POWER PLANT RELIABILITY-AVAILABILITY AND STATE REGULATION. VOLUME 7 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01

    AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy andELECTRIC GENERATION IN CALIFORNIA A project performed for the California Energy

  4. A REVIEW OF AIR QUALITY MODELING TECHNIQUES. VOLUME 8 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Rosen, L.C.

    2010-01-01

    AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy andELECTRIC GENERATION IN CALIFORNIA A project performed for the California Energy

  5. CONTROL OF POPULATION DENSITIES SURROUNDING NUCLEAR POWER PLANTS. VOLUME 5 OF THE FINAL REPORT ON HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, jA.V.

    2010-01-01

    AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA Energy andELECTRIC GENERATION IN CALIFORNIA A project performed for the California Energy

  6. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined less by the needs of the plant than by the availability in the soil solution; in addition to occurring naturally, Cl is present in excess as the anion complement in K fertilizer applications. An analysis was performed on existing data for switchgrass samples from ten different farms in the south-central portion of Iowa, with the goal of determining correlations between switchgrass elemental composition and geographical and seasonal changes so as to identify factors that influence the elemental composition of biomass. The most important factors in determining levels of various chemical compounds were found to be seasonal and geographical differences related to soil conditions. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions as well as fly ash. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures using cluster analysis were developed to characterize the inorganic material in these samples. Each of the biomass types exhibited different inorganic associations in the fuel as well as in the deposits and fly ash. Morphological analyses of the wheat straw show elongated 10-30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the organic structure of the biomass materials. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Although growing rapidly, the fouling deposits of the biomass and coal-biomass blends were significantly weaker than those of the coals. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similar

  7. The threat of running out of fossil fuels has increased demand for alternative fuel sources. Grain-based ethanol production is one such

    E-Print Network [OSTI]

    Rock, Chris

    The threat of running out of fossil fuels has increased demand for alternative fuel sources. Grain-based ethanol production is one such alternative fuel option, but it relies heavily on grains previously availability. With the growing legislative endorsement for alternative fuel sources, grain production

  8. Post-Combustion and Pre-Combustion CO2 Capture Solid Sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Stevens, R.W.; Robinson, Clark

    2007-11-01

    Combustion of fossil fuels is one of the major sources of the greenhouse gas CO2. Pressure swing adsorption/sorption (PSA/PSS) and temperature swing adsorption/sorption (TSA/TSS) are some of the potential techniques that could be utilized for removal of CO2 from fuel gas streams. It is very important to develop sorbents to remove CO2 from fuel gas streams that are applicable for a wide range of temperatures. NETL researchers have developed novel CO2 capture sorbents for low, moderate, and high temperature applications. A novel liquid impregnated solid sorbent was developed for CO2 removal in the temperature range of ambient to 60 °C. The sorbent is regenerable at 60 – 80 °C. The sorbent formulations were prepared to be suitable for various reactor configurations (i.e., fixed and fluidized bed). Minimum fluidization gas velocities were also determined. Multi-cycle tests conducted in an atmospheric bench scale reactor with simulated flue gas indicated that the sorbent retains its CO2 sorption capacity with a CO2 removal efficiency of approximately 99% and was unaffected by presence of water vapor. The sorbent was subsequently commercially prepared by Süd Chemie to determine the viability of the sorbent for mass production. Subsequent testing showed that the commercially-synthesized sorbent possesses the same properties as the lab-synthesized equivalent. An innovative solid sorbent containing mixture of alkali earth and alkali compounds was developed for CO2 removal at 200 – 315°C from high pressure gas streams suitable for IGCC systems. The sorbent showed very high capacity for CO2 removal from a gas streams containing 28% CO2 at 200 °C and at 20 atm during a lab scale reactor test. This sorbent can be regenerated at 20 atm and at 375 °C utilizing a gas stream containing steam. High pressure enhanced the CO2 sorption process. Bench scale testing showed consistent capacities and regenerability. A unique high temperature solid sorbent was developed for CO2 capture at temperatures of 500 – 700°C. Bench scale testing of the sorbent yielded very high CO2 capture capacity from a gas stream containing 10% CO2, 30% H2, 15% H2O, and 25% He. Regeneration of the sorbent is possible at 800 – 900 °C.

  9. Reducing Greenhouse Emissions and Fuel Consumption

    E-Print Network [OSTI]

    Shaheen, Susan; Lipman, Timothy

    2007-01-01

    out and "sequester" the CO2 emissions, though the cost andthe costs of stabiliz­ ing atmospheric CO2 concentrations at

  10. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  11. Quantifying emissions reductions from New England offshore wind energy resources

    E-Print Network [OSTI]

    Berlinski, Michael Peter

    2006-01-01

    Access to straightforward yet robust tools to quantify the impact of renewable energy resources on air emissions from fossil fuel power plants is important to governments aiming to improve air quality and reduce greenhouse ...

  12. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard

    1995-01-01

    Emissions of carbon dioxide form combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  13. World energy consumption and carbon dioxide emissions : 1950-2050

    E-Print Network [OSTI]

    Schmalensee, Richard.; Stoker, Thomas M.; Judson, Ruth A.

    Emissions of carbon dioxide from combustion of fossil fuels, which may contribute to long-term climate change, are projected through 2050 using reduced form models estimated with national-level panel data for the period ...

  14. Short-Term Energy Carbon Dioxide Emissions Forecasts August 2009

    Reports and Publications (EIA)

    2009-01-01

    Supplement to the Short-Term Energy Outlook. Short-term projections for U.S. carbon dioxide emissions of the three fossil fuels: coal, natural gas, and petroleum.

  15. ARE Update Volume11, No.3

    E-Print Network [OSTI]

    Kahrl, Fredrich; Roland-Holst, David; Rajagopal, Deepak; Zilberman, David D; Hardesty, Shermain

    2008-01-01

    the world’s atmospher- ic stock of fossil fuel CO2 emissionsCO2 emissions data are from the International Energy Agency and Worldworld’s dominant reliance on fossil fuels, significant growth of per capita CO2 emissions

  16. Obstacles to Global CO2 Trading: A Familiar Problem A. Denny Ellerman1

    E-Print Network [OSTI]

    obstacles to the development of an international CO2 emissions trading system, but the biggest is a feature emissions trading. The paper reviews the various instruments by which such the Kyoto target might be met. The development of an international system for CO2 emissions trading should not be expected to be either quick

  17. ENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 Jason J. Heinrich, Howard J. Herzog, David M. Reiner

    E-Print Network [OSTI]

    analogs: acid gas injection (AGI), enhanced oil recovery (EOR), natural gas storage, and CO2 transportENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 * Jason J. Heinrich, Howard J. Herzog, David M of reducing CO2 emissions. The storage of CO2 in underground geologic reservoirs is one such idea that employs

  18. Exposure to an enriched CO2 atmosphere alters carbon assimilation and allocation in a pine forest ecosystem

    E-Print Network [OSTI]

    Oren, Ram

    to reduce the rate at which atmospheric CO2 increases, the Kyoto Protocol has transformed CO2 emissions in a future CO2-enriched world is even greater (Houghton, 1997). For example, despite some downExposure to an enriched CO2 atmosphere alters carbon assimilation and allocation in a pine forest

  19. Free-Air CO2 Enrichment (FACE) Experiment PRINCIPAL INVESTIGATOR: Richard J. Norby

    E-Print Network [OSTI]

    is projected to reduce the airborne fraction of anthropogenic CO2 emissions. Coupled climate-carbon cycleFree-Air CO2 Enrichment (FACE) Experiment PRINCIPAL INVESTIGATOR: Richard J. Norby PARTICIPATING Free-Air CO2 Enrichment (FACE) project is to understand how the eastern deciduous forest

  20. Available online at www.sciencedirect.com Electrochemical conversion of CO2 to useful chemicals: current

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    ://dx.doi.org/10.1016/j.coche.2013.03.005 Introduction Carbon dioxide (CO2) emissions into the atmosphere will needAvailable online at www.sciencedirect.com Electrochemical conversion of CO2 to useful chemicals further undesirable climate change. Electrochemical reduction of CO2 into value-added chemicals using

  1. CO2 Enhanced Oil Recovery Feasibility Evaluation for East Texas Oil Field

    E-Print Network [OSTI]

    Lu, Ping

    2012-08-31

    Carbon dioxide enhanced oil recovery (CO2-EOR) has been undergoing for four decades and is now a proven technology. CO2-EOR increases oil recovery, and in the meantime reduces the greenhouse gas emissions by capture CO2 underground. The objectives...

  2. CO2 enhancement of forest productivity constrained by limited nitrogen availability

    E-Print Network [OSTI]

    CO2 enhancement of forest productivity constrained by limited nitrogen availability Richard J for review May 9, 2010) Stimulation of terrestrial plant production by rising CO2 concentra- tion is projected to reduce the airborne fraction of anthropogenic CO2 emissions. Coupled climate­carbon cycle

  3. ASummary for Policymakers Third Symposium on the Ocean in a High-CO2

    E-Print Network [OSTI]

    Huang, Wei

    O ASummary for Policymakers Third Symposium on the Ocean in a High-CO2 World #12;Scientific for Policymakers ­ Third Symposium on the Ocean in a High-CO2 World. International Geosphere-Biosphere Programme to affect food security and it limits the capacity of the ocean to absorb CO2 from human emissions

  4. An Investigation of CO2 Sequestration

    E-Print Network [OSTI]

    Saldin, Dilano

    An Investigation of CO2 Sequestration through Mineralization Conference on Sustainable Construction area and increased availability of CO2 for rapid carbonation. The hardened and carbonated materials Slag #12;Carbonation Chemistry Dissolution of CO2 in water. CO2(g) CO2(aq) Formation of carbonic acid

  5. Commitment accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, SJ; Socolow, RH

    2014-01-01

    International Energy Agency (IEA) for the years 1971–2011 [are within 42% of the IEA data over the period priorto 1975, within 29% of IEA data from 1975–1985, and within

  6. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    Russia, former Soviet states, the Middle East, and areas of Africa and South America). However, net exports

  7. THE CO2 ABATEMENT POTENTIAL OF CALIFORNIA'S MID-SIZED COMMERCIAL BUILDINGS

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    Electricity Generation from CHP by Building Types, Referenceimpact of mid-sized building CHP systems on CO 2 emissions.Electricity Generation from CHP by Building Types, Reference

  8. Outsourcing CO2 within China

    E-Print Network [OSTI]

    2013-01-01

    6. Lo AY (2012) Carbon emissions trading in China. Nat Climof interprovincial emissions trading (6–9). Additionally,the central coast. The emissions trading scheme being tested

  9. Outsourcing CO2 within China.

    E-Print Network [OSTI]

    2013-01-01

    6. Lo AY (2012) Carbon emissions trading in China. Nat Climof interprovincial emissions trading (6–9). Additionally,the central coast. The emissions trading scheme being tested

  10. CO2 | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEATCNAA Jump to:Emissions fromCO2

  11. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    E-Print Network [OSTI]

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01

    numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

  12. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    SciTech Connect (OSTI)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  13. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01

    E EPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE? CO2 2SE? CO2 2SE ? CO2 2SE ? CO2 2SE ? CO2 2SE a Surface excess CO

  14. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  15. Global Carbon Emissions in the Coming Decades: The Case of China

    E-Print Network [OSTI]

    Levine, Mark D.

    2008-01-01

    2006 GDP CO2 Population Source: LBNL, emissions are derivedCarbon Emissions Reductions, 2000-2020 Mt CO2 Source:CO 2 Emissions, 1950-2006 Mt CO2 USA PRC Source: Historical

  16. Final Report - "CO2 Sequestration in Cell Biomass of Chlorobium Thiosulfatophilum"

    SciTech Connect (OSTI)

    James L. Gaddy, PhD; Ching-Whan Ko, PhD

    2009-05-04

    World carbon dioxide emissions from the combustion of fossil fuels have increased at a rate of about 3 percent per year during the last 40 years to over 24 billion tons today. While a number of methods have been proposed and are under study for dealing with the carbon dioxide problem, all have advantages as well as disadvantages which limit their application. The anaerobic bacterium Chlorobium thiosulfatophilum uses hydrogen sulfide and carbon dioxide to produce elemental sulfur and cell biomass. The overall objective of this project is to develop a commercial process for the biological sequestration of carbon dioxide and simultaneous conversion of hydrogen sulfide to elemental sulfur. The Phase I study successfully demonstrated the technical feasibility of utilizing this bacterium for carbon dioxide sequestration and hydrogen sulfide conversion to elemental sulfur by utilizing the bacterium in continuous reactor studies. Phase II studies involved an advanced research and development to develop the engineering and scale-up parameters for commercialization of the technology. Tasks include culture isolation and optimization studies, further continuous reactor studies, light delivery systems, high pressure studies, process scale-up, a market analysis and economic projections. A number of anaerobic and aerobic microorgansims, both non-photosynthetic and photosynthetic, were examined to find those with the fastest rates for detailed study to continuous culture experiments. C. thiosulfatophilum was selected for study to anaerobically produce sulfur and Thiomicrospira crunogena waws selected for study to produce sulfate non-photosynthetically. Optimal conditions for growth, H2S and CO2 comparison, supplying light and separating sulfur were defined. The design and economic projections show that light supply for photosynthetic reactions is far too expensive, even when solar systems are considered. However, the aerobic non-photosynthetic reaction to produce sulfate with T. crunogena produces a reasonable return when treating a sour gas stream of 120 million SCFD containing 2.5 percent H2S. In this case, the primary source of revenue is from desulfurization of the gas stream. While the technology has significant application in sequestering carbon dioxide in cell biomass or single cell proten (SCP), perhaps the most immediate application is in desulfurizing LGNG or other gas streams. This biological approach is a viable economical alternative to existing hydrogen sulfide removal technology, and is not sensitive to the presence of hydrocarbons which act as catalyst poisons.

  17. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    facts: Average carbon dioxide emissions resulting fromcalculation of carbon dioxide (CO 2 ) emissions from fuel

  18. The CO2 Content of Consumption Across US Regions: A Multi-Regional Input-Output (MRIO) Approach

    E-Print Network [OSTI]

    Caron, J.

    We improve on existing estimates of the carbon dioxide (CO2) content of consumption across regions of the United States. Using a multi-regional input-output (MRIO) framework, we estimate the direct and indirect CO2 emissions ...

  19. Stragegies to Detect Hidden Geothermal Systems Based on Monitoringand Analysis of CO2 in the Near-Surface Environment

    SciTech Connect (OSTI)

    Lewicki, Jennifer L.; Oldenburg, Curtis M.

    2005-03-29

    We investigate the potential for CO2 monitoring in thenear-surface environment as an approach to exploration for hiddengeothermal systems. Numerical simulations of CO2 migration from a modelhidden geothermal system show that CO2 concentrations can reach highlevels in the shallow subsurface even for relatively low CO2 fluxes.Therefore, subsurface measurements offer an advantage over above-groundmeasurements which are affected by winds that rapidly disperse CO2. Tomeet the challenge of detecting geothermal CO2 emissions within thenatural background variability of CO2, we propose an approach thatintegrates available detection and monitoring techniques with statisticalanalysis and modeling.

  20. Air Pollution Control Regulations: No. 6- Continuous Emissions Monitors and Opacity Monitors (Rhode Island)

    Broader source: Energy.gov [DOE]

    Stationary sources, including fossil fuel fired steam or hot water generating units, may be required to install and operate a continuous emissions monitoring system equipped with an opacity monitor...

  1. Impact of CO2 quota allocation to new entrants in the electricity market

    E-Print Network [OSTI]

    of allocating free CO2 -allowances to new entrants in the EU emissions trading scheme for the Danish on a greenhouse gas emissions trading scheme (ETS) encompassing all major energy-producing units and the majority

  2. CO2 Reduction through Optimization of Steam Network in Petroleum Refineries: Evaluation of New Scenario 

    E-Print Network [OSTI]

    Manesh, M. H. K; Khodaie, H.; Amidpour, M.

    2008-01-01

    Steam network of petroleum refinery is energy intensive, and consequently contribute significantly to the greenhouse gases emissions. A simple model for the estimation of CO2 emissions associated with operation of steam network as encountered...

  3. Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes

    E-Print Network [OSTI]

    Short communication Satellite-derived surface water pCO2 and air­sea CO2 fluxes in the northern for the estimation of the partial pressure of carbon dioxide (pCO2) and air­sea CO2 fluxes in the northern South), respectively, the monthly pCO2 fields were computed. The derived pCO2 was compared with the shipboard pCO2

  4. India's challenge of improving the living standards of its growing population through a low-emission development calls for early adaptation of carbon capture and storage (CCS) though the available

    E-Print Network [OSTI]

    & storage owever efficiently fossil fuels are used, they still emit carbon dioxide Hto the atmosphere-emission development calls for early adaptation of carbon capture and storage (CCS) though the available storage to become clearer, and the only way to contain it is, if fossil fuels are used, to employ carbon capture

  5. Dealloying induced stress corrosion cracking is particularly relevant in energy conversion systems (both nuclear and fossil fuel) as many failures in alloys such as austenitic stainless steel and nickel-based systems

    E-Print Network [OSTI]

    (both nuclear and fossil fuel) as many failures in alloys such as austenitic stainless steel and nickel). The results of crack injection experiments were characterized using the dual-beam focused ion beam

  6. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Parag Kulkarni; Wei Wei; Arnaldo Frydman; Thomas McNulty; Roger Shisler

    2005-11-01

    It is expected that in the 21st century the Nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It will be necessary to improve both the process efficiency and environmental impact performance of fossil fuel utilization. GE Global Research is developing an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP module offers the potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions including NO{sub x}. GE was awarded a contract from U.S. DOE NETL to develop the UFP technology. Work on the Phase I program started in October 2000, and work on the Phase II effort started in April 2005. In the UFP technology, coal and air are simultaneously converted into separate streams of (1) high-purity hydrogen that can be utilized in fuel cells or turbines, (2) sequestration-ready CO{sub 2}, and (3) high temperature/pressure vitiated air to produce electricity in a gas turbine. The process produces near-zero emissions with an estimated efficiency higher than IGCC with conventional CO2 separation. The Phase I R&D program established the feasibility of the integrated UFP technology through lab-, bench- and pilot-scale testing and investigated operating conditions that maximize separation of CO{sub 2} and pollutants from the vent gas, while simultaneously maximizing coal conversion efficiency and hydrogen production. The Phase I effort integrated experimental testing, modeling and preliminary economic studies to demonstrate the UFP technology. The Phase II effort will focus on three high-risk areas: economics, sorbent attrition and lifetime, and product gas quality for turbines. The economic analysis will include estimating the capital cost as well as the costs of hydrogen and electricity for a full-scale UFP plant. These costs will be benchmarked with IGCC polygen costs for plants of similar size. Sorbent attrition and lifetime will be addressed via bench-scale experiments that monitor sorbent performance over time and by assessing materials interactions at operating conditions. The product gas from the third reactor (high-temperature vitiated air) will be evaluated to assess the concentration of particulates, pollutants and other impurities relative to the specifications required for gas turbine feed streams. This is the eighteenth quarterly technical progress report for the UFP program, which is supported by U.S. DOE NETL (Contract No. DE-FC26-00FT40974) and GE. This report summarizes program accomplishments for the Phase II period starting July 01, 2005 and ending September 30, 2005. The report includes an introduction summarizing the UFP technology, main program tasks, and program objectives; it also provides a summary of program activities and accomplishments covering progress in tasks including process modeling, scale-up and economic analysis.

  7. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Bergman, H.L.

    1980-01-04

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  8. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  9. Fluid flow and CO2fluidmineral interactions during CO2-storage in sedimentary basins

    E-Print Network [OSTI]

    Cambridge, University of

    mineral dissolution rates. Observations from CO2-EOR exper- iments and natural analogues suggestFluid flow and CO2­fluid­mineral interactions during CO2-storage in sedimentary basins Niko Kampman Natural CO2 analogues Modelling the progress of geochemical processes in CO2 storage sites is frustrated

  10. Supplementary Material for the ACP manuscript "CO2 and its1 correlation with CO at a rural site near Beijing: implications for2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ., Andres, R. J., and Marland, G.: China: Emissions pattern of the world2 leader in CO2 emissions from over China have a CO2/CO emission ratio of 21 mol/mol16 [Zhang et al., 2009; Gregg et al., 2008- 1 - Supplementary Material for the ACP manuscript "CO2 and its1 correlation with CO at a rural

  11. International Symposium on Site Characterization for CO2Geological Storage

    SciTech Connect (OSTI)

    Tsang, Chin-Fu

    2006-02-23

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  12. China Energy and Emissions Paths to 2030

    E-Print Network [OSTI]

    Fridley, David

    2012-01-01

    Potential by Source Power Sector CO2 Emissions (Mt CO2)CO2 Emissions Reference Agriculture Industrial Transport Commercial Residential Max Tech Agriculture Industrial Transport Commercial Residential In terms of fuel source,

  13. Reducing the negative human-health impacts of bioenergy crop emissions through region-specific crop selection

    E-Print Network [OSTI]

    Guenther, Alex

    An expected global increase in bioenergy-crop cultivation as an alternative to fossil fuels will have consequences on both global climate and local air quality through changes in biogenic emissions of volatile organic ...

  14. Technical/Peer Review Draft May 2006 PART II OVERVIEW1

    E-Print Network [OSTI]

    Management Activities:3 An Introduction to CO2 Emissions from Fossil Fuels4 5 Coordinating Lead Author: G Fossil fuels (coal, oil, and natural gas) are used primarily for their concentration of chemical energy,17 energy that is released as heat when the fuel is burned. Fossil fuels are composed primarily

  15. People's Climate Stewardship / Carbon Fee and Dividend Act of 2010: Proposed Findings

    E-Print Network [OSTI]

    Hansen, James E.

    of fossil fuels is increasing atmospheric CO2 levels which, along with emissions of other greenhouse gases of unmanageable catastrophic impacts to human civilization, 4. The False Economy of Cheap Fossil Fuels: Fossil generations. This false economy of cheap fossil fuels is obstructing an economy-wide transition to low carbon

  16. Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture

    SciTech Connect (OSTI)

    Vahdat, Nader

    2013-09-30

    The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project team’s approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

  17. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  18. Engineered yeast for enhanced CO2 mineralization

    E-Print Network [OSTI]

    Barbero, Roberto Juan

    2013-01-01

    In this work, a biologically catalysed CO2 mineralization process for the capture of CO2 from point sources was designed, constructed at a laboratory scale, and, using standard chemical process scale-up protocols, was ...

  19. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    and Fehsenfeld, F. C. : Emission sources and ocean uptake ofand No- vakov, T. : Emissions of trace gases and particlesGroot, W. J. : Future emissions from Canadian boreal forest

  20. CO2 Cycle du Fiche dtaille

    E-Print Network [OSTI]

    Dintrans, Boris

    CO2 ­ Cycle du Carbone Polluants Fiche détaillée Niveau (A partir de la 2nd) #12;I. Introduction Les origines du CO2 atmosphérique dépendent de l'échelle de temps que l'on considère. A l, ce cycle commence avec la dissolution du CO2 dans l'eau de pluie pour former de l'acide carbonique

  1. DOI: 10.1002/cssc.201200454 Mechanical Activation of CaO-Based Adsorbents for CO2

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    efforts to find less energy-intensive and more cost-effective ways for CO2 cap- ture, which accountsDOI: 10.1002/cssc.201200454 Mechanical Activation of CaO-Based Adsorbents for CO2 Capture Maryam-fuel-burning power plants account for approximately one third of anthropogenic CO2 emissions.[1,2] Carbon capture

  2. The impact of geologic variability on capacity and cost estimates for storing CO2 in deep-saline aquifers

    E-Print Network [OSTI]

    Jackson, Robert B.

    The impact of geologic variability on capacity and cost estimates for storing CO2 in deep States could store many de- cades worth of the nation's current annual CO2 emissions, the likely cost estimates for storage span three orders of magnitude and average>$100/tonne CO2. However, when the cost

  3. Carbon Dioxide Production Responsibility on the Basis of comparing in Situ and mean CO2 Atmosphere Concentration Data

    E-Print Network [OSTI]

    Mavrodiev, S Cht; Vachev, B

    2008-01-01

    The method is proposed for estimation of regional CO2 and other greenhouses and pollutants production responcibility. The comparison of CO2 local emissions reduction data with world CO2 atmosphere data will permit easy to judge for overall effect in curbing not only global warming but also chemical polution.

  4. The Greenness of Cities: Carbon Dioxide Emissions and Urban Development

    E-Print Network [OSTI]

    Glaeser, Edward L.; Kahn, Matthew E.

    2008-01-01

    of CO2 per Megawatt Hrs) Carbon Dioxide Emissions Cost ($of CO2 per Megawatt Hrs) Carbon Dioxide Emissions Cost MSA

  5. Leakage of CO2 from geologic storage: Role of secondaryaccumulation at shallow depth

    SciTech Connect (OSTI)

    Pruess, K.

    2007-05-31

    Geologic storage of CO2 can be a viable technology forreducing atmospheric emissions of greenhouse gases only if it can bedemonstrated that leakage from proposed storage reservoirs and associatedhazards are small or can be mitigated. Risk assessment must evaluatepotential leakage scenarios and develop a rational, mechanisticunderstanding of CO2 behavior during leakage. Flow of CO2 may be subjectto positive feedbacks that could amplify leakage risks and hazards,placing a premium on identifying and avoiding adverse conditions andmechanisms. A scenario that is unfavorable in terms of leakage behavioris formation of a secondary CO2 accumulation at shallow depth. This paperdevelops a detailed numerical simulation model to investigate CO2discharge from a secondary accumulation, and evaluates the role ofdifferent thermodynamic and hydrogeologic conditions. Our simulationsdemonstrate self-enhancing as well as self-limiting feedbacks.Condensation of gaseous CO2, 3-phase flow of aqueous phase -- liquid CO2-- gaseous CO2, and cooling from Joule-Thomson expansion and boiling ofliquid CO2 are found to play important roles in the behavior of a CO2leakage system. We find no evidence that a subsurface accumulation of CO2at ambient temperatures could give rise to a high-energy discharge, aso-called "pneumatic eruption."

  6. Just Say No to Carbon Emissions (LBNL Science at the Theater)

    ScienceCinema (OSTI)

    Ramesh, Ramamoorthy; Zhou, Nan; Oldenburg, Curt

    2011-04-28

    Learn about three efforts our grandchildren may thank us for: cheap solar energy, bringing energy efficiency to China, and learning how to store carbon deep underground. Can solar energy be dirt cheap? We're all potentially billionaires when it comes to solar energy. The trick is learning how to convert sunlight to electricity using cheap and plentiful materials. Ramamoorthy Ramesh, an innovative materials scientist at Berkeley Lab, will discuss how he and other researchers are working to make photovoltaic cells using the most abundant elements in the Earth's crust -- materials that are literally as common as dirt. Energy efficiency in China: Nan Zhou is a researcher with Berkeley Labs China Energy Group. She will speak about Chinas energy use and the policies that have been implemented to increase energy efficiency and reduce CO2 emission growth. Her work focuses on building China's capacity to evaluate, adopt and implement low-carbon development strategies. Zhou has an architecture degree from China, and a Master and Ph.D. in Engineering from Japan. Understanding geologic carbon sequestration: Even with continued growth of renewable energy sources such as wind and solar, fossil fuels will likely remain cheap and plentiful for decades to come. Geologist Curt Oldenburg, who heads Berkeley Lab's Geologic Carbon Sequestration Program, will discuss a strategy to reduce carbon emissions from coal and natural gas. It involves pumping compressed CO2 captured from large stationary sources into underground rock formations that can store it for geological time scales.

  7. Just Say No to Carbon Emissions (LBNL Science at the Theater)

    SciTech Connect (OSTI)

    Ramesh, Ramamoorthy; Zhou, Nan; Oldenburg, Curt

    2010-04-26

    Learn about three efforts our grandchildren may thank us for: cheap solar energy, bringing energy efficiency to China, and learning how to store carbon deep underground. Can solar energy be dirt cheap? We're all potentially billionaires when it comes to solar energy. The trick is learning how to convert sunlight to electricity using cheap and plentiful materials. Ramamoorthy Ramesh, an innovative materials scientist at Berkeley Lab, will discuss how he and other researchers are working to make photovoltaic cells using the most abundant elements in the Earth's crust -- materials that are literally as common as dirt. Energy efficiency in China: Nan Zhou is a researcher with Berkeley Labs China Energy Group. She will speak about Chinas energy use and the policies that have been implemented to increase energy efficiency and reduce CO2 emission growth. Her work focuses on building China's capacity to evaluate, adopt and implement low-carbon development strategies. Zhou has an architecture degree from China, and a Master and Ph.D. in Engineering from Japan. Understanding geologic carbon sequestration: Even with continued growth of renewable energy sources such as wind and solar, fossil fuels will likely remain cheap and plentiful for decades to come. Geologist Curt Oldenburg, who heads Berkeley Lab's Geologic Carbon Sequestration Program, will discuss a strategy to reduce carbon emissions from coal and natural gas. It involves pumping compressed CO2 captured from large stationary sources into underground rock formations that can store it for geological time scales.

  8. Using CO2 spatial variability to quantify representation errors of satellite CO2 retrievals

    E-Print Network [OSTI]

    Michalak, Anna M.

    global data of column- averaged CO2 dry-air mole fraction (XCO2) at high spatial resolutions. These dataUsing CO2 spatial variability to quantify representation errors of satellite CO2 retrievals A. A 2008; published 29 August 2008. [1] Satellite measurements of column-averaged CO2 dry- air mole

  9. CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE

    E-Print Network [OSTI]

    Bateman, Ian J.

    constraint to these relationships, with the carbon dioxide emissions from fossil fuel consumption pressingCARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson CSERGE GEC Working Paper 92-28 #12;CARBON EMISSIONS AND CARBON FIXING FROM AN ECONOMIC PERSPECTIVE by Dennis Anderson

  10. World Energy Consumption and Carbon Dioxide Emissions: 1950 2050

    E-Print Network [OSTI]

    World Energy Consumption and Carbon Dioxide Emissions: 1950 Ñ 2050 Richard Schmalensee, Thomas M. Stoker, andRuth A. Judson* Emissions of carbon dioxide from combustion of fossil fuels, which may-U" relation with a within- sample peak between carbon dioxide emissions (and energy use) per capita and per

  11. Five-years of microenvironment data along an urban-rural transect; temperature and CO2 concentrations in urban area at levels expected globally with climate change.

    SciTech Connect (OSTI)

    George, Kate; Ziska, Lewis H; Bunce, James A; Quebedeaux, Bruno

    2007-11-01

    The heat island effect and the high use of fossil fuels in large city centers is well documented, but by how much fossil fuel consumption is elevating atmospheric CO2 concentrations and whether elevations in both atmospheric CO2 and air temperature are consistent from year to year are less well known. Our aim was to record atmospheric CO2 concentrations, air temperature and other environmental variables in an urban area and compare it to suburban and rural sites to see if urban sites are experiencing climates expected globally in the future with climate change. A transect was established from Baltimore city center (Urban site), to the outer suburbs of Baltimore (suburban site) and out to an organic farm (rural site). At each site a weather station was set-up to monitor environmental variables annually for five years. Atmospheric CO2 was significantly increased on average by 66 ppm from the rural to the urban site over the five years of the study. Air temperature was significantly higher at the urban site (14.8 oC) compared to the suburban (13.6 oC) and rural (12.7 oC) sites. Relative humidity was not different between sites but vapor pressure deficit (VPD) was significantly higher at the urban site compared to the suburban and rural sites. During wet years relative humidity was significantly increased and VPD significantly reduced. Increased nitrogen deposition at the rural site (2.1 % compared to 1.8 and 1.2 % at the suburban and urban sites) was small enough not to affect soil nitrogen content. Dense urban areas with large populations and high vehicular traffic have significantly different microclimates compared to outlying suburban and rural areas. The increases in atmospheric CO2 and air temperature are similar to changes predicted in the short term with global climate change, therefore providing an environment suitable for studying future effects of climate change on terrestrial ecosystems.

  12. The CO2 Content of Consumption Across US Regions: A Multi-Regional

    E-Print Network [OSTI]

    than when attributed on a production basis. Second, when attributing emissions on a consumption basisThe CO2 Content of Consumption Across US Regions: A Multi-Regional Input-Output (MRIO) Approach: globalchange@mit.edu Website: http://globalchange.mit.edu/ #12;The CO2 Content of Consumption Across US Regions

  13. How much CO2 is too much? Nobody knows for sure, but sophisticated

    E-Print Network [OSTI]

    Haszeldine, Stuart

    the next 30 to 60 years than by capturing and storing CO2. Carbon capture and storage (CCS) is no panacea. Carbon capture and storage(CCS)offersoneofthemostdirectandrapidwaysofreducing CO2 emissions right now fuels provides most of the world's electrical energy. It also produces large amounts of carbon dioxide

  14. Temperature and peat type control CO2 and CH4 production in Alaskan permafrost peats

    E-Print Network [OSTI]

    Temperature and peat type control CO2 and CH4 production in Alaskan permafrost peats C . C . T R E poorly under- stood despite the potential for a significant positive feedback to climate change. Our dioxide (CO2) and methane (CH4) emissions from peat samples collected at active layer and permafrost

  15. Reproducedwith pennissionfrom PNL V ARIANTS OF A LOW CO2-EMITTING

    E-Print Network [OSTI]

    ~-~--- Reproducedwith pennissionfrom PNL ~ V ARIANTS OF A LOW CO2-EMITTING ENERGY SUPPLY SYSTEM for the LESS Constructions 4 Constructing Alternative Low CO2-Emitting Energy Supply Systems 6 The Comparable variants of a Low Emissions Energy Supply System (LESS) for the World, which were presented in Section 3

  16. 3 July 2008 Prime Minister Yasuo Fukuda

    E-Print Network [OSTI]

    Hansen, James E.

    amount. Fossil Fuel Facts. Oil slightly exceeds coal as a source of CO2 emissions today (Figure 1a). But fuel to 2007 CO2 emissions (a) and to excess CO2 in the air today (b) relative to pre-industrial CO2, because of the long atmospheric lifetime of past emissions, fully half of the excess CO2 in the air today

  17. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  18. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01

    A. : The Tropical Forest and Fire Emis- sions Experiment:W. M. : The Trop- ical Forest and Fire Emissions Experiment:A. : The tropical forest and fire emissions experiment:

  19. 15 September 2014 SENT TO LSU AGCENTER/LOUISIANA FOREST PRODUCTS DEVELOPMENT CENTER -FOREST SECTOR / FORESTY PRODUCTS INTEREST GROUP

    E-Print Network [OSTI]

    include the following: · using solid wood products avoids carbon dioxide (CO2) emissions from substitute needs to be built to reduce annual CO2 emissions by 14 to 31% and fossil fuel consumption by 12 to 19 is used to displace fossil fuels as energy source. · that young forest stands sequester energy more

  20. Impacts of proposed RCRA regulations and other related federal environmental regulations on Fossil Fuel-Fired Facilities: Final report, Volume 1

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    In order to fulfill its responsibilities, DOE contracted with Engineering-Science to perform a multi-phase engineering and economics study to evaluate the impact of the proposed RCRA regulations and other related federal environmental regulations on coal-fired utilities. This Interim Phase I report presents the findings of the impacts of proposed RCRA and related federal regulations on the utility sector fossil fuel-fired facilities. Subsequent phases involve parallel engineering studies on the industrial sector as well as economic evaluations. The framework of this study was based on the development and analysis (engineering and economic) of four regulatory scenarios for the disposal of fly ash, bottom ash and FGD sludge from the utility industry.