National Library of Energy BETA

Sample records for fossil fuels coal

  1. Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION...

    Office of Scientific and Technical Information (OSTI)

    carbon capture, utilisation, and storage Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION; POWER GENERATION; CARBON DIOXIDE; CAPTURE; STORAGE; USA; ENHANCED...

  2. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  3. DOE - Fossil Energy: Introduction to Coal Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduction An Energy Lesson Cleaning Up Coal COAL is our most abundant fossil fuel. The United States has more coal than the rest of the world has oil. There is still enough coal ...

  4. DOE - Fossil Energy: A Brief Overview of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview Fossil Energy Study Guides Coal - General Info America has more coal than any other fossil fuel resource. The United States also has more coal reserves than any other ...

  5. DOE - Fossil Energy: Coal Mining and Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mining Fossil Energy Study Guides Coal Mining and Transportation Coal Miners - One type of mining, called "longwall mining", uses a rotating blade to shear coal away from the ...

  6. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  7. DOE - Fossil Energy: How Fossil Fuels Were Formed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Fuel Formation Fossil Energy Study Guides How Fossil Fuels were Formed Contrary to what many people believe, fossil fuels are not the remains of dead dinosaurs. In fact,...

  8. Fossil Fuels Study Guide - High School | Department of Energy

    Energy Savers [EERE]

    Fuels Study Guide - High School Fossil Fuels Study Guide - High School PDF icon Fossil Fuels Study Guide - High School More Documents & Publications Coal Study Guide for Elementary School Coal Study Guide - Middle School Secondary Energy Infobook and Secondary Infobook Activities (19 Activities)

  9. No Fossil Fuel - Kingston | Open Energy Information

    Open Energy Info (EERE)

    Fossil Fuel - Kingston Jump to: navigation, search Name No Fossil Fuel - Kingston Facility No Fossil Fuel - Kingston Sector Wind energy Facility Type Commercial Scale Wind Facility...

  10. Fossil fuel is king with energy producers

    SciTech Connect (OSTI)

    Hansen, T.

    1996-11-01

    Worldwide energy consumption is expected to double today`s levels by 2020, according to the World Energy Council. As diverse energy needs develop, fossil fuels are expected to continue to be the major source for power generation throughout the world. In the United States, utility deregulation is making low-cost fuel and power plant efficiency more important than ever. Electricity generators see both natural gas and coal as the fuels that will allow them to best meet the nation`s future energy needs. Coal will see less increase in its share of electricity generation than natural gas due to the costs associated with meeting the Clean Air Act Amendments` (CAAA) requirements. According to Organizations for Economic Cooperation Development, coal in both the United States and Europe will experience a 12 percent growth by 2010. Even with this somewhat slow growth, coal will remain the nation`s number one fuel for electricity generation well into the next century.

  11. Advanced fossil fuel combustor

    SciTech Connect (OSTI)

    Rogers, B.

    1995-05-01

    Charged with enhancing the use of US fossil energy resources, the Morgantown Energy Technology Center (METC) is a federal Department of Energy research center that performs its own research and also manages the work of contractors. One interesting recent METC project is the effort to develop a ``multiannular swirl burner`` (MSB) for use in an advanced fossil fuel combustion system. The design is being developed by an outside contractor with funding and technical assistance from METC. Recently, EG and G Technical Services of West Virginia was asked to provide analytical support to the contractor developing the MSB. Design projects like this usually require building and testing a series of very expensive prototypes. Recent success with computational fluid dynamic (CFD) design techniques, however, have generated a great deal of excitement because of its ability to reduce research and development costs. Using FLUENT, a CFD package from Fluent Inc., EG and G was able to predict, with a high degree of accuracy, the performance of one of the MSB combustor prototypes. Furthermore, the model provided researchers with a more detailed understanding of the proposed design`s performance characteristics.

  12. Fossil fuel conversion--measurement and modeling

    SciTech Connect (OSTI)

    Solomon, P.R.; Smoot, L.D.; Serio, M.A.; Hamblen, D.G.; Brewster, B.S.; Radulovic, P.T.

    1994-10-01

    The main objective of this program is to understand the chemical and physical mechanisms in coal conversion processes and incorporate this knowledge in computer-aided reactor engineering technology for the purposes of development, evaluation, design, scale-up, simulation, control and feedstock evaluation in advanced coal conversion devices. To accomplish this objective, this program will: (1) provide critical data on the physical and chemical processes in fossil fuel gasifiers and combustors; (2) further develop a set of comprehensive codes; and (3) apply these codes to model various types of combustors and gasifiers (fixed-bed, transport reactor, and fluidized-bed for coal and gas turbines for natural gas).

  13. DOE - Fossil Energy: A Brief History of Coal Use in the United...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Fossil Energy Study Guides A Brief History of Coal Use Steam Locomotive - In the 1800s, one of the primary uses of coal was to fuel steam engines used to power locomotives. ...

  14. Fossil fuel furnace reactor

    DOE Patents [OSTI]

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  15. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  16. Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    ACI Committee 229 Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; FLY ASH; WASTE PRODUCT UTILIZATION; BACKFILLING; THERMAL...

  17. No Fossils in This Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plan for Environmental Teaching GM Environmental Science Club No Fossils in This Fuel Your PlanET Sixth through Eighth Grades (Can be easily adapted to any elementary/middle school level) Ingredients: Yeast, sugar ... what are you making? Sweet rolls? Not in Science Class! You're blending these ingredients to make an innovative form of fuel! That's right ... when these two simple ingredients are mixed, the yeast  a simple, living organism  breaks the sugar down into ethyl alcohol, or

  18. Optimization of fossil fuel sources: An exergy approach

    SciTech Connect (OSTI)

    Camdali, U.

    2007-02-15

    We performed linear programming for optimization of fossil fuel supply in 2000 in Turkey. For this, an exergy analysis is made because the second law of thermodynamics takes into account the quality of energy as well as quantity of energy. Our analyses showed that the interfuel substitution between different fossil fuels will lead to a best energy mix of the country. The total retail price of fossil fuels can be lowered to 11.349 billion US$ from 13.012 billion US$ by increasing the domestic production of oil, lignite, and hard coal and by decreasing imports. The remaining demand can be met by natural gas imports. In conclusion, our analysis showed that a reduction of 1.663 billion US$ in fossil fuel cost can be made possible by giving more emphasis on domestic production, particularly of oil, lignite and hard coal.

  19. Micronized coal-fired retrofit system for SO{sub x} reduction - Krakow Clean Fossil Fuels and Energy Efficiency Program.

    SciTech Connect (OSTI)

    1996-09-30

    the project proposes to install a new TCS micronized coal-fired heating plant for the Produkcja I Hodowla Roslin Ogrodniczych (PHRO) Greenhouse Complex, Krzeszowice, Poland (about 20 miles west of Krakow). PHRO currently utilizes 14 heavy oil-fired boilers to produce heat for its greenhouse facilities and also home heating to several adjacent apartment housing complexes. The boilers currently burn a high-sulfur content heavy crude oil, called Mazute. The micronized coal fired boiler would (1) provide a significant portion of the heat for PHRO and a portion of the adjacent apartment housing complexes, (2) dramatically reduce sulfur dioxide air pollution emission, while satisfying new Polish air regulations, and (3) provide attractive savings to PHRO, based on the quantity of displaced oil.

  20. U.S. DOE fossil energy fuel cell program

    SciTech Connect (OSTI)

    Wayne Surdoval

    2007-07-01

    The U.S. Department of Energy's Office of Fossil Energy's National Energy Technology Laboratory, in partnership with private industry, educational institutions, and national laboratories, is leading the research, development, and demonstration of high efficiency, fuel flexible solid oxide fuel cells (SOFCs) and coal based SOFC power generation systems for stationary markets. This Fuel Cell Program has three parts: Solid State Energy Conversion Alliance (SECA) cost reduction, SECA fuel cell coal based systems, and advanced SECA systems. The SECA cost reduction goal is to have SOFCs capable of being mass manufactured at $400 per kilowatt by 2010. Concurrently, the scale-up, aggregation, and integration of the technology will progress in parallel leading to prototype validation of megawatt class products by 2012 with potential testing at FutureGen. The SECA coal-based and advanced systems goals are the development of megawatt-class fuel cell power systems that will enable affordable, reliable, efficient, and environmentally-friendly electrical power from coal.

  1. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:March 2016 past issues All Issues » submit Greening up fossil fuels with carbon sequestration Researchers make progress fighting climate change by capturing carbon dioxide from power plants and storing it deep underground in geological reservoirs March 25, 2013 Greening up fossil fuels with carbon sequestration Most of the world's existing energy supply is stored underground in

  2. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  3. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect (OSTI)

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  4. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J.; Towle, David P.

    1992-01-01

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  5. An oxy-hydrocarbon model of fossil fuels

    SciTech Connect (OSTI)

    Fred D. Lang; Tom Canning

    2007-09-15

    This paper asserts a new method of analyzing fossil fuels, useful for sorting coals into well-defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multivariant approach for describing the lower ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high-energy ranks. In addition, for a few special cases, multiple low and high ranks are also well described by the multivariant approach. As useful as these techniques are for analyzing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems' Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time.

  6. DOE - Fossil Energy: Clean Coal Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Clean Coal Technology An Energy Lesson Cleaning Up Coal The Clean Coal Technology Program The Clean Coal Technology Program began in 1985 when the United States and Canada ...

  7. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy ...

  8. Synthetic fossil fuel technologies: health problems and intersociety...

    Office of Scientific and Technical Information (OSTI)

    Conference: Synthetic fossil fuel technologies: health problems and intersociety cooperation Citation Details In-Document Search Title: Synthetic fossil fuel technologies: health ...

  9. fossil fuels | OpenEI Community

    Open Energy Info (EERE)

    energy becomes more competitive with fossil fuels in OECD countries, reports of this nature can go a long way to supporting more and more development. The four new reports in...

  10. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 2 (Jan 2016) Archived Editions: Coal ...

  11. Municipal waste combustion assessment: Fossil fuel co-firing. Final report, October 1988-July 1989

    SciTech Connect (OSTI)

    Landrum, V.J.; Barton, R.G.

    1989-07-01

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; and describes the population of coal fired boilers that currently co-fire RDF, have previously co-fired RDF but have ceased to do so, and have been used in RDF co-firing demonstrations. (Fossil fuel co-firing, defined as the combustion of RDF with another fuel (usually coal) in a device designed primarily to burn the other fuel, is generally confined to commercial and utility boilers.) Model plants are developed and good combustion practices are recommended.

  12. Replace Fossil Fuels, Final Technical Report Roberts, William...

    Office of Scientific and Technical Information (OSTI)

    Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Roberts, William L 09 BIOMASS FUELS biofuels, glycerin, glycerol,...

  13. Norwegian carbon taxes and their implication for fossil fuels

    SciTech Connect (OSTI)

    Kaarstad, O.

    1995-12-31

    The Scandinavian countries, and in particular Norway and Sweden, have since 1990/91 taxed CO{sub 2}-emissions with carbon tax of about US $150 per ton of CO{sub 2}. One may therefore say that these countries have placed themselves in a role as {open_quotes}carbon tax laboratories{close_quotes}. These very high CO{sub 2}-taxes have been in place for about four years and the first lessons from this experience are reported. In general it would seem as if the taxation mechanism is less efficient than economists have expected. The CO{sub 2}-emissions are increasing in both Norway and Sweden and the stabilization goal to the year 2000 will not be achieved in spite of the high taxation. The fossil fuel industry will have to learn to live with the climate change question which is inherently hostile to fossil fuels. It is argued that a more informed and active participation by the fossil fuel industry is needed in the climate change discussion. In addition the image of fossil fuels will benefit from showing real and potential improvement in the area of greenhouse gas emissions in the whole energy chain from production to combustion. The R&D effort being done into CO{sub 2}-capture and -disposal is creating such an option for the future. It is argued that the image of the entire fossil fuel industry will benefit from the creation of a {open_quotes}CO{sub 2}-free{close_quote} option or vision for oil, gas and coal. A number of examples are shown where today (or in the near future) actual CO{sub 2}-disposal in underground formations are taking place.

  14. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  15. Fossil fuels in a sustainable energy future

    SciTech Connect (OSTI)

    Bechtel, T.F.

    1995-12-01

    The coal industry in the United States has become a world leader in safety, productivity, and environmental protection in the mining of coal. The {open_quotes}pick-and-shovel{close_quotes} miner with mangled limbs and black lung disease has been replaced by the highly skilled technicians that lead the world in tons per man-hour. The gob piles, polluted streams, and scared land are a thing of the past. The complementary efforts of the DOE and EPRI-funded programs in coal utilization R&D and the Clean Coal Technology Program commercial demonstrations, have positioned the power generation industry to utilize coal in a way that doesn`t pollute the air or water, keeps electrical power costs low, and avoids the mountains of waste material. This paper reviews the potential for advanced coal utilization technologies in new power generation applications as well as the repowering of existing plants to increase their output, raise their efficiency, and reduce pollution. It demonstrates the potential for these advanced coal-fueled plants to play a complementary role in future planning with the natural gas and oil fired units currently favored in the market place. The status of the US program to demonstrate these technologies at commercial scale is reviewed in some detail.

  16. American Clean Coal Fuels | Open Energy Information

    Open Energy Info (EERE)

    American Clean Coal Fuels Retrieved from "http:en.openei.orgwindex.php?titleAmericanCleanCoalFuels&oldid768408" Categories: Organizations Energy Generation Organizations...

  17. Fossil energy, clean coal technology, and FutureGen

    SciTech Connect (OSTI)

    Sarkus, T.A.

    2008-07-15

    Future fossil use will rely heavily on carbon sequestration. Clean coal technologies are being incorporated in the USA, including air pollution control, and will need to incorporate carbon capture and sequestration. The paper ends with an outline of the restructured FutureGen project. 7 figs.

  18. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-09-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  19. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-07-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRB and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  20. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-04-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming process, mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  1. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    Open Energy Info (EERE)

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  2. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine; Wada, Kenichi; van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  3. Mitigating environmental pollution and impacts from fossil fuels: The role of alternative fuels

    SciTech Connect (OSTI)

    Liu, L.; Cheng, S.Y.; Li, J.B.; Huang, Y.F.

    2007-07-01

    In order to meet the rising global demand for energy, rapid development of conventional fossil fuels (i.e., coal, oil, and natural gas) have been experienced by many nations, bringing dramatic economic benefit and prosperity to fossil-fuel industries as well as well being of human society. However, various fossil-fuel related activities emit huge quantities of gaseous, liquid, and solid waste materials, posing a variety of impacts, risks, and liabilities to the environment. Therefore, on the one hand, control measures are desired for effectively managing pollution issues; on the other hand, it becomes extremely critical to invest efforts in finding promising alternative energy sources as solutions to the possible energy shortage crisis in future. This article focuses on both aspects through: (1) a discussion of waste materials generated from fossil-fuel industries and waste management measures; and (2) an exploration of some well-recognized alternative fuels in terms of their nature, availability, production, handling, environmental performances, and current and future applications. The conclusion restates the urgency of finding replaceable long-term alternatives to the conventional fuels.

  4. CO2 emissions mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine V.; Wada, Kenichi; Van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher and decrease with mitigation. A first deviation from the optimal transition pathway relaxes global emission targets until 2030, in accordance with the Copenhagen pledges and regionally-specific low-carbon technology targets. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger - twice and more - than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear cut across models, as we find carbon leakage effects ranging from positive to negative because leakage and substitution patterns of coal, oil, and gas differ. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  5. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M.

    2008-07-01

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  6. US fossil fuel technologies for Thailand

    SciTech Connect (OSTI)

    Buehring, W.A.; Dials, G.E.; Gillette, J.L.; Szpunar, C.B.; Traczyk, P.A.

    1990-10-01

    The US Department of Energy has been encouraging other countries to consider US coal and coal technologies in meeting their future energy needs. Thailand is one of three developing countries determined to be a potentially favorable market for such exports. This report briefly profiles Thailand with respect to population, employment, energy infrastructure and policies, as well as financial, economic, and trade issues. Thailand is shifting from a traditionally agrarian economy to one based more strongly on light manufacturing and will therefore require increased energy resources that are reliable and flexible in responding to anticipated growth. Thailand has extensive lignite deposits that could fuel a variety of coal-based technologies. Atmospheric fluidized-bed combustors could utilize this resource and still permit Thailand to meet emission standards for sulfur dioxide. This option also lends itself to small-scale applications suitable for private-sector power generation. Slagging combustors and coal-water mixtures also appear to have potential. Both new construction and refurbishment of existing plants are planned. 18 refs., 3 figs., 7 tabs.

  7. Fossil Fuel-Generated Energy Consumption Reduction for New Federal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings and Major Renovations of Federal Buildings | Department of Energy Buildings Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in a Supplemental Notice of Proposed Rulemaking. File fossilfuel.docx More Documents & Publications Fossil Fuel-Generated Energy Consumption

  8. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Broader source: Energy.gov (indexed) [DOE]

    the Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in an OIRA Comparison Document. File ...

  9. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships (Redirected from Brazil-NETL Cooperation) Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation...

  10. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation AgencyCompany Organization National Energy...

  11. Micronized coal-fired retrofit system for SO{sub x} reduction Krakow clean fossil fuels and energy efficiency program. Final report

    SciTech Connect (OSTI)

    1997-04-01

    This report describes results of a technical, financial and environmental assessment study for a project, which would have included a new TCS micronized coal-fired heating plant for the Produkcja I Hodowla Roslin Ogrodniczych (PHRO) Greenhouse Complex; Krzeszowice, Poland. Project site is about 20 miles west of Krakow, Poland. During the project study period, PHRO utilized 14 heavy oil-fired boilers to produce heat for its greenhouse facilities and also home heating to several adjacent apartment housing complexes. The boilers burn a high-sulfur content heavy crude oil, called mazute, The project study was conducted during a period extended from March 1996 through February 1997. For size orientation, the PHRO Greenhouse complex grows a variety of vegetables and flowers for the Southern Poland marketplace. The greenhouse area under glass is very large and equivalent to approximately 50 football fields, The new micronized coal fired boiler would have: (1) provided a significant portion of the heat for PHRO and a portion of the adjacent apartment housing complexes, (2) dramatically reduced sulfur dioxide air pollution emissions, while satisfying new Polish air regulations, and (3) provided attractive savings to PHRO, based on the quantity of displaced oil.

  12. High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation

    SciTech Connect (OSTI)

    Steinberg, M; Cooper, J F; Cherepy, N

    2002-01-02

    Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power generation cycles are: (1) increased efficiency by a factor of up to 2 over many conventional fossil fuel steam plants, (2) reduced power generation cost, especially for increasing fossil fuel cost, (3) reduced CO2 emission per kWh, and (4) direct sequestration or reuse (e.g., in enhanced oil or NG recovery) of the CO{sub 2} product.

  13. Technical considerations in repowering a nuclear plant for fossil fueled operation

    SciTech Connect (OSTI)

    Patti, F.J.

    1996-03-01

    Repowering involves replacement of the reactor by a fossil fuel source of steam. This source can be a conventional fossil fueled boiler or the heat recovery steam generator (HRSG) on a gas turbine exhaust. The existing steam turbine plant is used to the extent possible. Alternative fuels for repowering a nuclear plant are coal, natural gas and oil. In today`s world oil is not usually an alternative. Selection of coal or natural gas is largely a matter of availability of the fuel near the location of the plant. Both the fossil boiler and the HRSG produce steam at higher pressures and temperatures than the throttle conditions for a saturated steam nuclear turbine. It is necessary to match the steam conditions from the new source to the existing turbine as closely as possible. Technical approaches to achieve a match range from using a topping turbine at the front end of the cycle to attemperation of the throttle steam with feedwater. The electrical output from the repowered plant is usually greater than that of the original nuclear fueled design. This requires consideration of the ability to use the excess electricity. Interfacing of the new facility with the existing turbine plant requires consideration of facility layout and design. Site factors must also be considered, especially for a coal fired boiler, since rail and coal handling facilities must be added to a site for which these were not considered. Additional site factors that require consideration are ash handling and disposal.

  14. Fossil Energy Announces New DAS for Clean Coal and Carbon Management

    Broader source: Energy.gov [DOE]

    The Department of Energy’s Office of Fossil Energy today announced the appointment of David Mohler as Deputy Assistant Secretary for Clean Coal and Carbon Management.

  15. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; et al

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increasesmore » strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.« less

  16. Coal Gasification and Transportation Fuels Magazine | netl.doe...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 2 (Jan 2016) Archived Editions: Coal ...

  17. Environmental review for the conversion of Bellefonte Nuclear Plant to fossil fuel

    SciTech Connect (OSTI)

    Carter, R.; Rucker, H.; Summers, R.

    1998-07-01

    The Tennessee Valley Authority recently issued for public review a Draft Environmental Impact Statement for the conversion of the unfinished Bellefonte Nuclear Plant to fossil fuel. The DEIS was structured to support three tiers of decision making. Tier 1 is to decide between the No-Action Alternative, which is to leave Bellefonte as a partially completed nuclear plant into the indefinite future, and the Proposed Action Alternative, which is to proceed with converting Bellefonte to fossil fuel. Tier 2 is to select one of five conversion options. In the DEIS, TVA indicated no preference among the five competing fossil conversion options. The five conversion pathways would fully repower the plant consistent with fossil fuel availability, would use commercially ready systems and technologies and be designed to fully utilize the capacity of transmission lines serving Bellefonte. Conversion options addressed were pulverized coal (PC), natural gas combined cycle (NGCC), integrated gasification combined cycle (IGCC), IGCC with joint production of electricity and chemicals, and an option, which combines elements of NGCC and IGCC with coproduction. Tier 3 involves decisions about eight sub-option choices, basically types of processes, equipment, and modes of operation, which is part of two or more conversion options. An example of a sub-option choice would be the type of gasifier that would be used in conversion options involving coal or petroleum coke gasification. Other sub-option choices addressed in the DEIS were natural gas pipeline corridors; fuels, feedstocks, and by-products transportation modes; types of combustion turbines; solid fuels; types of boilers for conventional coal-fired options; chemical production mixes; and modes of onsite solid fuel conveyance. The impact of constructing and operating each proposed fossil conversion option at Bellefonte were evaluated for 18 environmental resource and economic categories.

  18. Refractory failure in IGCC fossil fuel power systems

    SciTech Connect (OSTI)

    Dogan, Cynthia P.; Kwong, Kyei-Sing; Bennett, James P.; Chinn, Richard E.

    2001-01-01

    Current generation refractory materials used in slagging gasifiers employed in Integrated Gasification Combined Cycle (IGCC) fossil fuel power systems have unacceptably short service lives, limiting the reliability and cost effectiveness of gasification as a means to generate power. The short service life of the refractory lining results from exposure to the extreme environment inside the operating gasifier, where the materials challenges include temperatures to 1650 C, thermal cycling, alternating reducing and oxidizing conditions, and the presence of corrosive slags and gases. Compounding these challenges is the current push within the industry for fuel flexibility, which results in slag chemistries and operating conditions that can vary widely as the feedstock for the gasifier is supplemented with alternative sources of carbon, such as petroleum coke and biomass. As a step toward our goal of developing improved refractory materials for this application, we have characterized refractory-slag interactions, under a variety of simulated gasifier conditions, utilizing laboratory exposure tests such as the static cup test and a gravimetric test. Combining this information with that gained from the post-mortem analyses of spent refractories removed from working gasifiers, we have developed a better understanding of refractory failure in gasifier environments. In this paper, we discuss refractory failures in slagging gasifiers and possible strategies to reduce them. Emphasis focuses on the refractories employed in gasifier systems which utilize coal as the primary feedstock.

  19. Fossil Energy Program. Progress report for November 1979. [35 Wt % Illinois No. 6 coal with Wilsonville recycle solvent

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    This report - the sixty-fourth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, materials engineering, a coal equipment test program, an atmospheric fluid bed combustor for cogeneration, engineering studies and technical support, process and program analysis, environmental assessment studies, magnetic beneficiation of dry pulverized coal, technical support to the TVA fluid bed combustion program, coal cogeneration/district heating plant assessment, chemical research and development, and technical support to major liquefaction projects.

  20. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2012 ii This report...

  1. Fossil Fuel-Generated Energy Consumption Reduction for New Federal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings and Major Renovations of Federal Buildings OIRA Comparison Document | Department of Energy Buildings OIRA Comparison Document Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document Document details the Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in an OIRA Comparison Document. File fossilfuel_compare2014.docx More

  2. Disclosure of Permitted Communication Concerning Fossil Fuel Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No. EERE-2010-BT-STD-0031; RIN 1904-AB96 | Department of Energy Fossil Fuel Energy Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No. EERE-2010-BT-STD-0031; RIN 1904-AB96 Disclosure of Permitted Communication Concerning Fossil Fuel Energy Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No.

  3. DOE - Fossil Energy: The Cleanest Coal Technology - A Real Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5-Cleanest Coal Technology An Energy Lesson Cleaning Up Coal The Cleanest Coal Technology - a Real Gas Don't think of coal as a solid black rock. Think of it as a mass of atoms. ...

  4. Characterization and supply of coal based fuels

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  5. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  6. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  7. DOE - Fossil Energy: A Bed for Burning Coal?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4-Bed for Burning Coal An Energy Lesson Cleaning Up Coal A "Bed" for Burning Coal? It was a wet, chilly day in Washington DC in 1979 when a few scientists and engineers joined with ...

  8. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  9. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-10-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  10. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  11. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  12. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    1993-09-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  13. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  14. Novel Fuel Cells for Coal Based Systems

    SciTech Connect (OSTI)

    Thomas Tao

    2011-12-31

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  15. Table 3.1 Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu) Year Coal 1 Natural Gas 2 Crude Oil 3 Fossil Fuel Composite 4 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Percent Change 7 1949 0.21 1.45 0.05 0.37 0.44 3.02 0.26 1.81 – – 1950 .21 1.41 .06 .43 .43 2.95 [R] .26 1.74 -3.6 1951 .21 1.35 .06 .40 .44 2.78 .26 1.65 -5.4 1952 .21 1.31 [R] .07 .45 .44 2.73 .26 1.63 -1.0 1953 .21 1.29 .08 .50 .46 2.86 .27 1.69 3.3 1954 .19 1.18 .09 .55 .48 2.94 .28 1.70 .7 1955

  16. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1. Fossil fuel sales of production from federal lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 679 3,939 33.0% 93 347 14.7% 6,798 6,981 35.7% 436 8,960 40.6%

  17. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Table 2. Fossil fuel sales of production from Indian lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 10 59 0.5% 2 6 0.3% 283 291 1.5% 30 616 2.8% 972 1.7% 2004 10 58

  18. DOE - Fossil Energy: Knocking the NOx Out of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-Knocking Out NOx An Energy Lesson Cleaning Up Coal Knocking the NOx Out of Coal - How NOx Forms - Formation of NOx - Air is mostly nitrogen molecules (green in the above diagram) ...

  19. Fossil fuel combined cycle power system

    DOE Patents [OSTI]

    Labinov, Solomon Davidovich; Armstrong, Timothy Robert; Judkins, Roddie Reagan

    2006-10-10

    A system for converting fuel energy to electricity includes a reformer for converting a higher molecular weight gas into at least one lower molecular weight gas, at least one turbine to produce electricity from expansion of at least one of the lower molecular weight gases, and at least one fuel cell. The system can further include at least one separation device for substantially dividing the lower molecular weight gases into at least two gas streams prior to the electrochemical oxidization step. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  20. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect (OSTI)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  1. Table 1.14 Sales of Fossil Fuels Produced on Federal and American Indian Lands, Fiscal Years 2003-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Sales of Fossil Fuels Produced on Federal and American Indian Lands, Fiscal Years 2003-2011 Fiscal Year 7 Crude Oil and Lease Condensate Natural Gas Plant Liquids 1 Natural Gas 2 Coal 3 Total Fossil Fuels 4 Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Million Barrels Trillion Btu Percent

  2. Fossil fuel combined cycle power generation method

    DOE Patents [OSTI]

    Labinov, Solomon D [Knoxville, TN; Armstrong, Timothy R [Clinton, TN; Judkins, Roddie R [Knoxville, TN

    2008-10-21

    A method for converting fuel energy to electricity includes the steps of converting a higher molecular weight gas into at least one mixed gas stream of lower average molecular weight including at least a first lower molecular weight gas and a second gas, the first and second gases being different gases, wherein the first lower molecular weight gas comprises H.sub.2 and the second gas comprises CO. The mixed gas is supplied to at least one turbine to produce electricity. The mixed gas stream is divided after the turbine into a first gas stream mainly comprising H.sub.2 and a second gas stream mainly comprising CO. The first and second gas streams are then electrochemically oxidized in separate fuel cells to produce electricity. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  3. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  4. Advanced technologies for co-processing fossil and biomass resources for transportation fuels and power generation

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Y.

    2004-07-01

    Over the past few decades, a number of processes have been proposed or are under development for coprocessing fossil fuel and biomass for transportation fuels and power generation. The paper gives a brief description of the following processes: the Hydrocarb system for converting biomass and other carbonaceous fuels to elemental carbon and hydrogen, methane or methanol; the Hynol process where the second step of the Hydrocarb process is replaced with a methane steam reformer to convert methane to CO and H{sub 2}S without deposition of carbon; the Carnol process where CO{sub 2} from coal and the biomass power plants is reacted with hydrogen to produce methanol; and advanced biomass high efficiency power generator cycle where a continuous plasma methane decomposition reactor (PDR) is used with direct carbon fuel cell to produce power and carbon and hydrogen. 13 refs., 5 figs., 2 tabs.

  5. Table 1.15 Non-Combustion Use of Fossil Fuels, 1980-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Non-Combustion Use of Fossil Fuels, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5<//td> 1980 145 230 58 253 14 [R] 37 58 795 [R] 639 2.4 [ – –] [ – –] 1981 125 229 56 216 15 [R] 27 54 722 [R] 518 [R] 2.1 [ – –] [ – –] 1982 125 256 51 157 15 [R] 25 48 678 [R] 448 [R] 1.4 [ – –] [

  6. Evaluation of innovative fossil fuel power plants with CO{sub 2} removal

    SciTech Connect (OSTI)

    2000-07-15

    This interim report presents initial results of an ongoing study of the potential cost of electricity produced in both conventional and innovative fossil fueled power plants that incorporate carbon dioxide (CO{sub 2}) removal for subsequent sequestration or use. The baseline cases are natural gas combined cycle (NGCC) and ultra-supercritical pulverized coal (PC) plants, with and without post combustion CO{sub 2} removal, and integrated gasification combined cycle (IGCC) plants, with and without pre-combustion CO{sub 2} removal.

  7. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, R.G.

    1984-08-31

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  8. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, Ramkrishna G.

    1986-01-01

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  9. Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment

    SciTech Connect (OSTI)

    Sayer, J.H.

    1995-06-01

    The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

  10. Table 3.7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil 1 Petroleum Products 2 Total Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 1949 2,368 16,332 [R] 3,976 27,423 [R] 0 0 304,658 2,101,235 [R] 137,130 945,789 [R] 448,132 3,090,779 [R] 1950 2,624 17,904 [R] 5,297 36,142 [R] 0 0 369,208 2,519,159 [R] 214,629 1,464,445 [R] 591,758 4,037,650 [R] 1951 2,420 15,402 [R] 1,932 12,296 [R] 0 0 374,869

  11. Table 3.8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 297,179 2,049,652 [R] 8,323 57,404 [R] 1,823 12,573 [R] 98,425 678,840 [R] 461,439 3,182,557 [R] 867,189 5,981,026 [R] 1950 269,195 1,836,756 [R] 6,159 42,024 [R] 3,199 21,827 [R] 102,717 700,853 [R] 394,434 2,691,280 [R] 775,704 5,292,740 [R] 1951 586,056

  12. Table 3.9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 -294,811 -2,033,320 [R] -4,347 -29,981 [R] -1,823 -12,573 [R] 206,233 1,422,395 [R] -324,309 -2,236,768 [R] -419,057 -2,890,248 [R] 1950 -266,571 -1,818,852 [R] -862 -5,882 [R] -3,199 -21,827 [R] 266,491 1,818,306 [R] -179,805 -1,226,835 [R] -183,946

  13. Orimulsion conversion boosts prospects of `fourth` fossil fuel

    SciTech Connect (OSTI)

    1995-04-01

    This article describes how, by retrofitting a 100-MW oil-fired and a 215-MW coal-fired unit, one utility turned a plant destined for peaking service into a base-load asset with a predictable fuel bill and manageable emissions-even in environmentally sensitive Atlantic Canada. Six years ago, New Brunswick Power Corp (NB Power) found itself on the horns of a dilemma. For years, the utility had been searching for a powerplant fuel with a more stable price than oil, which at the time was fueling one-third of its generating capacity. Buying and burning more domestic coal-even at twice the price of offshore supplies-was the preferred option, because that would also help keep New Brunswick`s coal mines open. But by 1989, federal and provincial legislation had begun to plan for stringent limits on SO{sub 2} emissions that would take the local-coal card out of NB Power`s hand. Containing up to 8% sulfur, New Brunswick coal would be too dirty to burn by itself; emissions from a 200-MW unit would alone use up nearly half of the utility`s system-wide annual quota for SO{sub 2} emissions schedules for imposition in 1994. Enter Bitor America Corp, the Boca Raton (Fla) marketing subsidiary of the world`s third-largest oil company, Petroleos de Venezuela SA (PdVSA). Looking to further the fortunes of Orimulsion, a liquid emulsion of bitumen and water from the Orinoco region of Venezuela, Bitor funded and provided technical support for the first large-scale test burn of the fuel in the 100-MW Unit 1 of NB Power`s Dalhousie station in northern New Brunswick. After making the required modifications, NB Power burned Orimulsion in Unit 1 for two years. By 1991, the utility had cleanly converted more than a million barrels of the fuel to nearly half a million megawatt-hours of electricity-in the process finding few reasons not to commit to permanently converting Dalhousie`s Unit 1, as well as coal fired 215-MW Unit 2, to burn Orimulsion.

  14. Coal-fueled diesel locomotive test

    SciTech Connect (OSTI)

    Hsu, B.D.; McDowell, R.E.; Confer, G.L.; Basic, S.L.

    1993-01-01

    The biggest challenges to the development of a commercially-acceptable coal-fueled diesel-electric locomotive are integrating all systems into a working unit that can be operated in railroad service. This involves mainly the following three systems: (1) the multi-cylinder coal-fueled diesel engine, (2) the locomotive and engine controls, and (3) the CWS fuel supply system. Consequently, a workable 12-cylinder coal-fueled diesel engine was considered necessary at this stage to evolve the required locomotive support systems, in addition to gaining valuable multi-cylinder engine operating experience. The CWS fuel used during this project was obtained from Otisca, Inc. (Syracuse, NY). It was prepared from micronized and deashed Kentucky Blue Gem coal to 49.0% coal loading by weight, with less than 1% ash and 5 micron mean diameter particle size. Its higher heating value was analyzed at approximately 34630 kJ/k. Anti-agglomerating additive Triton X-114 was added to the CWS at GE Transportation Systems at 2% of coal weight. The nature of the Otisca CWS fuel makes it inherently more difficult to store, pump, and inject than diesel fuel, since concepts which govern Newtonian or normally viscous liquids do not apply entirely to CWS. Otisca CWS tends to be unstable and to settle in tanks and lines after a period of time, making it necessary to provide a means of agitation during storage. To avoid long term settling problems and to minimize losses, piping velocities were designed to be in the 60-90 m/min range.

  15. Coal slurry fuel supply and purge system

    DOE Patents [OSTI]

    McDowell, Robert E. (Fairview, PA); Basic, Steven L. (Hornell, NY); Smith, Russel M. (North East, PA)

    1994-01-01

    A coal slurry fuel supply and purge system for a locomotive engines is disclosed which includes a slurry recirculation path, a stand-by path for circulating slurry during idle or states of the engine when slurry fuel in not required by the engine, and an engine header fluid path connected to the stand-by path, for supplying and purging slurry fuel to and from fuel injectors. A controller controls the actuation of valves to facilitate supply and purge of slurry to and from the fuel injectors. A method for supplying and purging coal slurry in a compression ignition engine is disclosed which includes controlling fluid flow devices and valves in a plurality of fluid paths to facilitate continuous slurry recirculation and supply and purge of or slurry based on the operating state of the engine.

  16. Control of SO{sub 2} and NOx emissions from fossil fuel-fired power plants: Research and practice of TPRI

    SciTech Connect (OSTI)

    Ming-Chuan Zhang

    1993-12-31

    The generation of electric power in China has been dominated by coal for many years. By the end of 1990, total installed generating capacity reached 135 GW, of which fossil fuel-fired plants accounted for 74 percent. The total electricity generated reached 615 TWh, with fossil fuels accounting for 80.5 percent. About 276 million tons of raw coal are consumed in these fossil fuel-burning units per year, accounting for about 25 percent of the total output of the country. According to the government, by the year 2000, the total installed capacity of Chinese power systems should be at least 240 GW, of which fossil fuels will account for about 77 percent. The coal required for power generation will increase to about 530 million tons per year, accounting for about 38 percent of the total coal output. So, it is obvious that coal consumed in coal-fired power plants occupies a very important place in the national fuel balance. The current environmental protection standards, which are based on ground-level concentrations of pollutants, do not effectively lead to the control of pollution emission concentrations or total SO{sub 2} emissions. Due to the practical limitations of the Chinese economy, there is a limited capability to introduce advanced sulfur emission control technologies. Thus, except for the two 360 MW units imported from Japan for the Luohuang Power Plant in Shichuan province, all the other fossil fuel-fired units have not yet adopted any kind of SO{sub 2} removal measures. The Luohuang units are equipped with Mitsubishi limestone flue gas desulfurization systems. Because of the lack of effective pollution control technologies, large areas of the country have been seriously polluted by SO{sub 2}, and some of them even by acid rain.

  17. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical...

    Office of Scientific and Technical Information (OSTI)

    Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Citation Details In-Document Search Title: Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping ...

  18. Formulating Energy Policies Related to Fossil Fuel Use:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONF-9 O O 255 --I DE90 008741 Formulating Energy Policies Related to Fossil Fuel Use: i Critical Uncertainties in the Global Carbon Cycle. W. M. Post, V. H. Dale, D. L. DeAngelis, L. K. Mann, P. J. Mulholland, R. V. O'Neill, T. -H. Peng, M. P. Farrell Environmental Sciences Division Oak Ridge National Laboratory Post Office Box 2008 Oak Ridge, Tennessee 37831 The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Understanding the global carbon cycle

  19. Chlorine induced corrosion of steels in fossil fuel power plants

    SciTech Connect (OSTI)

    Spiegel, M.; Grabke, H.J.

    1998-12-31

    The corrosion of steels in power plants (coal combustion, waste incineration) is mainly due to condensed chlorides in the ash deposited on the boiler tubes. These chlorides are stabilized by HCl in the combustion gas. In the case of coal as a fuel, chlorine is present as chloride minerals in the raw material which is converted to HCl during the combustion process. Corrosion of steels in chlorine containing environments occurs by the active oxidation mechanism, which is a self-sustaining accelerated oxidation process, catalyzed by chlorine. This study shows that solid chlorides react with the oxide scale of the steels to form chlorine, which initiates active oxidation. In order to prevent chlorine induced corrosion, the deposition of chlorides on the tubes within the coal ash must be avoided. This is possible by the presence of SO{sub 2}, which is present in the combustion gas, converting the chlorides to sulfates in the gas phase. The paper presents an example of a failure case in a coal fired plant in Germany. In this plant, chlorine induced corrosion was observed after effective removal of SO{sub 2} by additions of CaO. From thermodynamic calculations it can be shown that a certain amount of SO{sub 2} is necessary in order to avoid deposition of chlorides and to prevent corrosion.

  20. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  1. Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the

    Office of Scientific and Technical Information (OSTI)

    United States (Journal Article) | SciTech Connect Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States Citation Details In-Document Search Title: Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States Quantification of the spatial distribution of sector-specific fossil fuel CO2 emissions provides strategic information to public and private decision-makers on climate change mitigation options and can provide critical

  2. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Large Scale Variable Renewable Integration Now Available EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration ...

  3. N.R. 20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS...

    Office of Scientific and Technical Information (OSTI)

    20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; 14 SOLAR ENERGY; 15 GEOTHERMAL ENERGY; GEOTHERMAL POWER PLANTS; COMPUTERIZED SIMULATION; HEAT...

  4. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  5. Converting coal to liquid fuels. [US DOE

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    Liquid fuels play a vital role in the US economy. Oil represents about 40 percent of the energy consumed each year in this country. In many cases, it fills needs for which other energy forms cannot substitute efficiently or economically - in transportation, for example. Despite a current world-wide surplus of oil, conventional petroleum is a depletable resource. It inevitably will become harder and more expensive to extract. Already in the US, most of the cheap, easily reached oil has been found and extracted. Even under optimistic projections of new discoveries, domestic oil production, particularly in the lower 48 states, will most likely continue to drop. A future alternative to conventional petroleum could be liquid fuels made from coal. The technique is called coal liquefaction. From 1 to 3 barrels of oil can be made from each ton of coal. The basic technology is known; the major obstacles in the US have been the high costs of the synthetic oil and the risks of building large, multi-billion dollar first-of-a-kind plants. Yet, as natural petroleum becomes less plentiful and more expensive, oil made from abundant coal could someday become an increasingly important energy option. To prepare for that day, the US government is working with private industries and universities to establish a sound base of technical knowledge in coal liquefaction.

  6. Environmental impact of fossil fuel combustion in power generation

    SciTech Connect (OSTI)

    Allen, J.W.; Beal, P.R.

    1996-12-31

    All the recent developments in the combustion systems employed for power generation have been based on environmental considerations. Combustion modifications have been developed and utilised in order to control NO{sub x} emissions and improvements continue to be made as the legislative requirements tighten. Chemical processes and fuel switching are used to control SO{sub x} emissions. After nitrogen, carbon dioxide is the major gas emitted from the combustion process and its potential potency as a greenhouse gas is well documented. Increased efficiency cycles, mainly based on natural gas as the prime fuel, can minimise the amount of CO{sub x} produced per unit of power generated. As the economics of natural gas utilisation become less favourable a return to clean coal technology based power generation processes may be required.

  7. FutureGen: Stepping-Stone to Sustainable Fossil-Fuel Power Generation

    SciTech Connect (OSTI)

    Zitney, S.E.

    2006-11-01

    This presentation will highlight the U.S. Department of Energy's FutureGen Initiative. The nearly $1 billion government-industry project is a stepping-stone toward future coal-fired power plants that will produce hydrogen and electricity with zero-emissions, including carbon dioxide. The 275-megawatt FutureGen plant will initiate operations around 2012 and employ advanced coal gasification technology integrated with combined cycle electricity generation, hydrogen production, and carbon capture and sequestration. The initiative is a response to a presidential directive to develop a hydrogen economy by drawing upon the best scientific research to address the issue of global climate change. The FutureGen plant will be based on cutting-edge power generation technology as well as advanced carbon capture and sequestration systems. The centerpiece of the project will be coal gasification technology that can eliminate common air pollutants such as sulfur dioxide and nitrogen oxides and convert them to useable by-products. Gasification will convert coal into a highly enriched hydrogen gas, which can be burned much more cleanly than directly burning the coal itself. Alternatively, the hydrogen can be used in a fuel cell to produce ultra-clean electricity, or fed to a refinery to help upgrade petroleum products. Carbon sequestration will also be a key feature that will set the Futuregen plant apart from other electric power plant projects. The initial goal will be to capture 90 percent of the plant's carbon dioxide, but capture of nearly 100 percent may be possible with advanced technologies. Once captured, the carbon dioxide will be injected as a compressed fluid deep underground, perhaps into saline reservoirs. It could even be injected into oil or gas reservoirs, or into unmineable coal seams, to enhance petroleum or coalbed methane recovery. The ultimate goal for the FutureGen plant is to show how new technology can eliminate environmental concerns over the future use of coal--the most abundant fossil fuel in the United States with supplies projected to last 250 years. FutureGen's co-production of power and hydrogen will also serve as a stepping-stone to an environmentally sustainable energy future.

  8. Identifying fly ash at a distance from fossil fuel power stations

    SciTech Connect (OSTI)

    Flanders, P.J.

    1999-02-15

    A method has been developed to identify fly ash originating at fossil fuel power stations, even at a distance where the ash level is lower by a factor of 1000 from that close to a source. Until now such detection has been difficult and uncertain. The technique combines collection of particles, measurement of magnetization and coercive field, and microscopy. The analysis depends on the fact that ash from iron sulfide in fossil fuels is in the form of spherical magnetite. These particles have a relatively high coercive field H{sub c}, near 135 Oe, compared with airborne particulates from soil erosion which have an H{sub c} of {approximately}35 Oe. The coercive field of any sample therefore gives an indication for the percentage of fly ash relative to the total amount of magnetic material that is airborne. The concentration of ash from a large, isolated coal burning power station is found to fall off with the distance from the source, approximately as D{sup {minus}1}. As D increases there is a drop in H{sub c}, associated with the reduced amount of fly ash relative to the airborne particulates from soil erosion.

  9. An optical gas temperature probe for high temperature fossil fuel process streams

    SciTech Connect (OSTI)

    Bauman, L.E.; Cook, R.L.; Lineberry, J.T.; Litchford, R.J.

    1995-12-31

    Reported here are the results of a feasibility study of a modular optical gas temperature probe for direct measurement of gas temperature in fossil-fueled combustion streams. A probe based upon the spectroscopic technique of line reversal would be superior to currently available gas temperature technology. The study concluded that a modular form of the line reversal optical temperature probe is feasible and, as such. the probe should be a commercially viable product with potential economic benefits from improved monitoring and control of utility furnaces. Such a probe will have the capability of making direct measurements of gas temperature in hot (>1500 K) process streams of coal combustion systems and large-scale power plant facilities.

  10. Micronized coal-fired retrofit system for SO{sub x} reduction: Krakow Clean Fossil Fuels and Energy Efficiency Program. Technical progress report No. 1, [April--June 1994

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    Objective of the project is to retrofit the Balice Boilerhouse with a TCS Coal Micronization System and Amerex baghouses to achieve higher combustion efficiencies and lower air emissions, including SO{sub 2}, NO{sub x}, CO and particulate matter. The Balice Boilerhouse is located adjacent to the Krakow Airport and provides heating steam for the Polish Military Unit No. 1616, which is based in the vicinity of the Krakow airport. Progress is described.

  11. Coal-fueled diesel technology development: Nozzle development for coal-fueled diesel engines

    SciTech Connect (OSTI)

    Johnson, R.N.; Lee, M.; White, R.A.

    1994-01-01

    Direct injection of a micronized coal water mixture fuel into the combustion chambers of a diesel engine requires atomizing an abrasive slurry fuel with accurately sized orifices. Five injector orifice materials were evaluated: diamond compacts, chemical vapor deposited diamond tubes, thermally stabilized diamond, tungsten carbide with cobalt binder, and tungsten carbide with nickel binder with brazed and mechanically mounted orifice inserts. Nozzle bodies were fabricated of Armco 17-4 precipitation hardening stainless steel and Stellite 6B in order to withstand cyclic injection pressures and elevated temperatures. Based on a total of approximately 200 cylinder hours of engine operation with coal water mixture fuel diamond compacts were chosen for the orifice material.

  12. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  13. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  14. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled ``Clean Uses of Fossil Fuels.`` was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  15. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  16. Better batteries to break dependence on fossil fuels > EMC2 News...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Better batteries to break dependence on fossil fuels April 28th, 2015 By Linda B. ... said Abrua, which means better and more affordable designs for fuel cells and batteries. ...

  17. The Council of Industrial Boiler Owners special project on non-utility fossil fuel ash classification

    SciTech Connect (OSTI)

    Svendsen, R.L.

    1996-12-31

    Information is outlined on the Council of Industrial Boiler Owners (CIBO) special project on non-utility fossil fuel ash classification. Data are presented on; current (1996) regulatory status of fossil-fuel combustion wastes; FBC technology identified for further study; CIBO special project methods; Bevill amendment study factors; data collection; and CIBO special project status.

  18. Combustion and fuel characterization of coal-water fuels

    SciTech Connect (OSTI)

    Chow, O.K.; Gralton, G.W.; Lachowicz, Y.V.; Laflesh, R.C.; Levasseur, A.A.; Liljedahl, G.N.

    1989-02-01

    This five-year research project was established to provide sufficient data on coal-water fuel (CWF) chemical, physical, and combustion properties to assess the potential for commercial firing in furnaces designed for gas or oil firing. Extensive laboratory testing was performed at bench-scale, pilot-scale (4 {times} 10{sup 6}Btu/hr) and commercial-scale (25 {times} 10{sup 6} to 50 {times} 10{sup 6}Btu/hr) on a cross-section of CWFs. Fuel performance characteristics were assessed with respect to coal properties, level of coal beneficiation, and slurry formulation. The performance of four generic burner designs was also assessed. Boiler performance design models were applied to analyze the impacts associated with conversion of seven different generic unit designs to CWF firing. Equipment modifications, operating limitations, and retrofit costs were determined for each design when utilizing several CWFs. Unit performance analyses showed significantly better load capacity for utility and industrial boilers as the CWF feed coal ash content is reduced to 5% or 2.6%. In general, utility units had more attractive capacity limits and retrofit costs than the industrial boilers and process heaters studied. Economic analyses indicated that conversion to CWF firing generally becomes feasible when differential fuel costs are above $1.00/10{sup 6}Btu. 60 figs., 24 tabs.

  19. Low-emission vortex combustion of biomass and fossil fuel

    SciTech Connect (OSTI)

    Finker, F.Z.; Kubischkin, I.B.; Akhmedov, D.B.

    1995-11-01

    The article introduces the results of development and industrial experience of low-emission vortex combustion technology (LEVC) of biomass and fossil fuel in industrial and utility boilers in Russian timber and paper industries and Polish power plants. The LEVC technology is based on aerodynamics method of multiple circulation of gases and fuel in the furnaces. LEVC technology accumulates the advantages of conventional and fluidized bed combustion technology. Existing boilers could be easily retrofitted for the application of LEVC technology without requiring major investment. The repowering of boiler with LEVC was the result the reduction NOx emission to the level 170g/GJ without installation additional flue gas cleaning equipment and it gave the opportunity for an injection of sulfur sorbent in the furnace. The authors discussed Russian-Polish experiment on utility boiler retrofitted with the application of LEVC. As the result the efficiency of the boiler increased in 2%. The reduction of the emission is: NOx-40%, SO2-17%.

  20. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 85 citations and includes a subject term index and title list.)

  1. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 84 citations and includes a subject term index and title list.)

  2. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 119 citations and includes a subject term index and title list.)

  4. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  5. Coal Technology '80. Volume 5. Synthetic fuels from coal. Volume 6. Industrial/utility applications for coal

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The 3rd international coal utilization exhibition and conference Coal Technology '80 was held at the Astrohall, Houston, Texas, November 18-20, 1980. Volume 5 deals with coal gasification and coal liquefaction. Volume 6 deals with fluidized-bed combustion of coal, cogeneration and combined-cycle power plants, coal-fuel oil mixtures (COM), chemical feedstocks via coal gasification and Fischer-Tropsch synthesis. Thirty-six papers have been entered individually into EDB and seven also into ERA; three had been entered previously from other sources. (LTN)

  6. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  7. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However, the strength of the secondary flow is found nearly the same behind the first and the second vortex generator pair as well as far from the second vortex generator pair in the case of Duct2. Both ducts are able to create a counter-rotating and a second set of twin foci. Duct2 is able to create the second set of twin foci in an earlier streamwise location than Duct1, as these foci are well-known to their heat transfer augmentation. A larger vortex formation area and a greater induced vorticity field between vortex pairs are observed for Duct2 compared with Duct1. As the induced flow field between the vortex pairs increases the heat transfer, and as the flow field between the vortex cores is found larger in the case of Duct2, therefore, it is expected to obtain better heat transfer characteristics for Duct2 compared with Duct1. (author)

  8. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Map Appendix State/area maps Figure A1. Fossil fuel production on federal and Indian lands, FY 2014 Source: U.S. Energy Information Administration based on U.S. Department of the Interior, Office of Natural Resources Revenue. "ONNR Statistical Information Site" (http://statistics.onrr.gov). July 2015 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2014 24 Figure A2. Changes in fossil fuels production (trillion

  9. Further experience for environmental improvement in fossil fuel combustion

    SciTech Connect (OSTI)

    Lazzeri, L.; Santis, R. de

    1998-12-31

    Reburning is a technology which has proven, by plant demonstration, capable of providing compliance with very stringent regulatory emissions requests (less than 90 ppm NO{sub x} firing oil and gas and less than 160--170 ppm firing coal). Designing a Reburn System requires a contemporary control of many parameters like flow rates, local stoichiometries residence times, etc.; it also requires the availability and capability of using complex and sophisticated numerical modeling. Although the system can be adapted to any already installed hardware it should be noted that the availability of reliable LNB`s and of specifically designed OFA`s and Reburn fuel injectors can greatly enhance the system performance. Design of OFA system is a subcase of a Reburn System design, as it implies same concepts of mixing and residence times which are the basis of Reburn System. As shown in the cases previously presented Reburning always provides additional margins to OFA operation specifically when very low emission limits are pursued. Finally it should be noted that the use of Reburning may create problems of unburned specifically when very low local stoichiometries and when very low sulfur oils are used which are often characterized by asphaltene instability especially when STZ oil is the result of blending high and low sulfur oils. A specific know-how has been jointly developed by Ansaldo and ENEL to solve these problems acting on both atomizer type selection and operation.

  10. Process for producing fluid fuel from coal

    DOE Patents [OSTI]

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  11. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  12. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  13. Novel injector techniques for coal-fueled diesel engines

    SciTech Connect (OSTI)

    Badgley, P.R.

    1992-09-01

    This report, entitled Novel Injector Techniques for Coal-Fueled Diesel Engines,'' describes the progress and findings of a research program aimed at development of a dry coal powder fuel injector in conjunction with the Thermal Ignition Combustion System (TICS) concept to achieve autoignition of dry powdered coal in a single-cylinder high speed diesel engine. The basic program consisted of concept selection, analysis and design, bench testing and single cylinder engine testing. The coal injector concept which was selected was a one moving part dry-coal-powder injector utilizing air blast injection. Adiabatics has had previous experience running high speed diesel engines on both direct injected directed coal-water-slurry (CWS) fuel and also with dry coal powder aspirated into the intake air. The Thermal Ignition Combustion System successfully ignited these fuels at all speeds and loads without requiring auxiliary ignition energy such as pilot diesel fuel, heated intake air or glow or spark plugs. Based upon this prior experience, it was shown that the highest efficiency and fastest combustion was with the dry coal, but that the use of aspiration of coal resulted in excessive coal migration into the engine lubrication system. Based upon a desire of DOE to utilize a more modern test engine, the previous naturally-aspirated Caterpillar model 1Y73 single cylinder engine was replaced with a turbocharged (by use of shop air compressor and back pressure control valve) single cylinder version of the Cummins model 855 engine.

  14. September 2013 Most Viewed Documents for Fossil Fuels | OSTI...

    Office of Scientific and Technical Information (OSTI)

    Roe-Hoam Yoon; Ramazan Asmatulu; Ismail Yildirim; William Jansen; Jinmig Zhang; Brad Atkinson; Jeff Havens (2004) 26 > VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL ...

  15. Plants Martin, Christopher; Pavlish, John 20 FOSSIL-FUELED POWER...

    Office of Scientific and Technical Information (OSTI)

    was provided by the Wyoming State Legislature under an award made through the Wyoming Clean Coal Technologies Research Program. University Of North Dakota USDOE United States...

  16. EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels by Fluid Identification

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2011-01-21

    Berkeley Lab researchers Greg Newman and Michael Commer have developed advanced software for discovering and mapping offshore fossil fuel deposits. When combined with established seismic methods, this software makes possible direct imaging of reservoir fluids....

  17. Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    Liquid-fluidized-bed heat exchanger flow distribution models Cole, L.T.; Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS; FLUIDIZED BED HEAT EXCHANGERS; DESIGN;...

  18. Impacts of Renewable Generation on Fossil Fuel Unit Cycling: Costs and Emissions (Presentation)

    SciTech Connect (OSTI)

    Brinkman, G.; Lew, D.; Denholm, P.

    2012-09-01

    Prepared for the Clean Energy Regulatory Forum III, this presentation looks at the Western Wind and Solar Integration Study and reexamines the cost and emissions impacts of fossil fuel unit cycling.

  19. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Office of Energy Efficiency and Renewable Energy (EERE)

    This paper was prepared in response to recent requests that the U.S. Energy Information Administration (EIA) provide updated summary information regarding fossil fuel production on federal and...

  20. fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED...

    Office of Scientific and Technical Information (OSTI)

    draft fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 42 ENGINEERING NOT INCLUDED IN OTHER...

  1. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect (OSTI)

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  2. Fossil-energy program. Progress report for June 1981

    SciTech Connect (OSTI)

    Not Available

    1981-08-01

    This report - the eighty-third of series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, flue gas desulfurization, coal preparation waste utilization, atmospheric fluidized bed coal combustor for cogeneration, TVA FBC demonstration plant program technical support, PFBC systems analysis, fossil fuel applications assessments, performance assurance system support for fossil energy projects, international energy technology assessment, generalized equilibrium models for liquid and gaseous fuel supplies, analyses of coal production goals, and fossil energy information center.

  3. Coal fueled diesel system for stationary power applications-technology development

    SciTech Connect (OSTI)

    1995-08-01

    The use of coal as a fuel for diesel engines dates back to the early days of the development of the engine. Dr. Diesel envisioned his concept as a multi-fuel engine, with coal a prime candidate due to the fact that it was Germany`s primary domestic energy resource. It is interesting that the focus on coal burning diesel engines appears to peak about every twenty years as shortages of other energy resources increase the economic attractiveness of using coal. This periodic interest in coal started in Germany with the work of Diesel in the timeframe 1898-1906. Pawlikowski carried on the work from 1916 to 1928. Two German companies commercialized the technology prior to and during World War II. The next flurry of activity occurred in the United States in the period from 1957-69, with work done at Southwest Research Institute, Virginia Polytechnical University, and Howard University. The current period of activity started in 1978 with work sponsored by the Conservation and Renewable Energy Branch of the US Department of Energy. This work was done at Southwest Research Institute and by ThermoElectron at Sulzer Engine in Switzerland. In 1982, the Fossil Energy Branch of the US Department of Energy, through the Morgantown Energy Technology Center (METC) initiated a concentrated effort to develop coal burning diesel and gas turbine engines. The diesel engine work in the METC sponsored program was performed at Arthur D. Little (Cooper-Bessemer as subcontractor), Bartlesville Energy Technology Center (now NIPER), Caterpillar, Detroit Diesel Corporation, General Motor Corporation (Electromotive Division), General Electric, Southwest Research Institute, and various universities and other research and development organizations. This DOE-METC coal engine RD & D initiative which spanned the 1982-1993 timeframe is the topic of this review document. The combustion of a coal-water fuel slurry in a diesel engine is described. The engine modifications necessary are discussed.

  4. 2004 Office of Fossil Energy Fuel Cell Program Annual Report

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Annual report of fuel cell projects sponsored by Department of Energy, National Energy Technology Laboratory.

  5. Table 3.2 Value of Fossil Fuel Production, 1949-2011 (Billion Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    Value of Fossil Fuel Production, 1949-2011 (Billion Dollars) Year Coal 1 Natural Gas 2 Crude Oil 3,4 Total Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 1949 2.52 17.37 [R] 0.33 2.24 4.68 32.27 [R] 7.52 51.88 [R] 1950 2.91 19.84 [R] .44 3.00 4.95 33.80 [R] 8.30 56.64 [R] 1951 3.05 19.40 [R] .52 3.32 [R] 5.69 36.19 [R] 9.26 58.92 [R] 1952 2.67 16.73 [R] .64 4.01 5.79 36.25 [R] 9.11 56.99 [R] 1953 2.55 15.79 [R] .76 4.67 [R] 6.32 39.06 [R] 9.63 59.52 [R] 1954 2.02 12.40 [R]

  6. Clean Coal Research

    Broader source: Energy.gov [DOE]

    DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled...

  7. Coal markets squeeze producers

    SciTech Connect (OSTI)

    Ryan, M.

    2005-12-01

    Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

  8. Standard for the qualification of high capacity fossil fuel fired plant operators

    SciTech Connect (OSTI)

    Axtman, W.

    1996-12-31

    The American Society of Mechanical Engineers, at the request of the U.S. Environmental Protection Agency (EPA) and, in recognition of the needs and benefits associated with standard qualifications of operators of high capacity fossil fuel fired plants, established the Qualifications of High Capacity Fossil Fuel Fired Operator (QFO) Committee in 1994. The purpose of the QFO Committee is to develop and maintain such a standard for operators. This standard includes qualifications, duties, responsibilities and the certification requirements for operators as appropriate to The Clean Air Act as amended in 1990 for fossil fuel fired plants with inputs equal to or greater than 10,000 Btu/hr. This Standard does not cover the certification or validation of fossil plant operating procedures, operating practices, facility performance, nor compliance with any particular permit requirement. This standard recognizes the titles or positions to which any particular fossil plant operator may apply, will vary within a facility. Therefore, this standard does not attempt to identify the individual who is required to obtain certification in any class designation. The fossil plant owner is urged to contact the local jurisdiction in which the fossil plant is located in this regard. This standard does not in itself require certification but rather it serves as a means for complying with federal, state, and local regulations which require operators of fossil fuel fired boilers with inputs equal to or greater than 10,000,000 But/hr to be certified. Safety codes and standards are intended to enhance public health and safety. Revisions to this Standard result from committee considerations of factors such as technological advances, new data, and changing environmental and industry needs. Revisions do not imply that previous editions of this standard were inadequate.

  9. Gas turbine fuel from low-rank coal

    SciTech Connect (OSTI)

    Maas, D.J.; Smith, F.J.

    1986-06-01

    Five low-rank coals from the western United States were cleaned in a bench-scale heavy media separation procedures followed by acid leaching and hydrothermal processing. The objective of these cleaning steps was to determine the amenability of preparing gas turbine quality fuel from low-rank coal. The best candidate for scale-up was determined to be a Wyoming subbituminous coal from the eagle Butte mine. Two hundred thirty kilograms of cleaned and micronized coal/water fuel were prepared in pilot-scale equipment to determine process parameters and fuel characteristics. After establishing operating conditions, two thousand kilograms of cleaned and micronized coal/water and powdered coal fuel were produced for testing in a pilot-scale gas turbine combustor. An economic analysis was completed for a commercial-scale plant designed to produce clean gas turbine fuel from low-rank coal using the most promising process steps identified form the bench- and pilot-scale studies. 21 refs., 12 figs., 20 tabs.

  10. Supersonic coal water slurry fuel atomizer

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

    1991-01-01

    A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

  11. Fossil energy program. Progress report, July 1980

    SciTech Connect (OSTI)

    McNeese, L. E.

    1980-10-01

    This report - the seventy-second of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process and program analysis, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, fossil energy applications assessments, performance assurance system support for fossil energy projects, international assessment of atmospheric fluidized bed combustion technology, and PFBC systems analysis.

  12. Cracow clean fossil fuels and energy efficiency program. Progress report

    SciTech Connect (OSTI)

    1998-10-01

    Since 1990 the US Department of Energy has been involved in a program aimed at reducing air pollution caused by small, coal-fired sources in Poland. The program focuses on the city of Cracow and is designed so that results will be applicable and extendable to the entire region. This report serves both as a review of the progress which has been made to date in achieving the program objectives and a summary of work still in progress.

  13. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014 July 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2014 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data,

  14. Combustion system for hybrid solar fossil fuel receiver

    DOE Patents [OSTI]

    Mehos, Mark S.; Anselmo, Kenneth M.; Moreno, James B.; Andraka, Charles E.; Rawlinson, K. Scott; Corey, John; Bohn, Mark S.

    2004-05-25

    A combustion system for a hybrid solar receiver comprises a pre-mixer which combines air and fuel to form an air-fuel mixture. The mixture is introduced tangentially into a cooling jacket. A burner plenum is fluidically connected to the cooling jacket such that the burner plenum and the cooling jacket are arranged in thermal contact with one another. The air-fuel mixture flows through the cooling jacket cooling the burner plenum to reduce pre-ignition of the air-fuel mixture in the burner plenum. A combustion chamber is operatively associated with and open to the burner plenum to receive the air-fuel mixture from the burner plenum. An igniter is operatively positioned in the combustion chamber to combust the air-fuel mixture, releasing heat. A recuperator is operatively associated with the burner plenum and the combustion chamber and pre-heats the air-fuel mixture in the burner plenum with heat from the combustion chamber. A heat-exchanger is operatively associated and in thermal contact with the combustion chamber. The heat-exchanger provides heat for the hybrid solar receiver.

  15. FE Clean Coal News | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    near Panama City. Solid oxide fuel cell technology being developed by the Office of Fossil Energy for coal-fueled central power generation is being adapted to power UUVs....

  16. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Information Administration (EIA) Analysis & Projections ‹ See all Coal Reports U.S. Coal Supply and Demand: 2010 Year in Review Release Date: June 1, 2011 | Next Release Date: Periodically | full report Exports and Imports Exports Total U.S. coal exports for 2010 increased by 38.3 percent to 81.7 million short tons (Figure 8). Figure Data This increase was largely due to two factors. First, heavy rains and flooding in Australia, Indonesia, and Colombia reduced world coal supply and

  17. The Mesaba Energy Project: Clean Coal Power Initiative, Round...

    Office of Scientific and Technical Information (OSTI)

    Mesaba Energy Project: Clean Coal Power Initiative, Round 2 Stone, Richard; Gray, Gordon; Evans, Robert 01 COAL, LIGNITE, AND PEAT; 20 FOSSIL-FUELED POWER PLANTS The Mesaba Energy...

  18. Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems

    SciTech Connect (OSTI)

    Anbo Wang; Gary Pickrell

    2011-12-31

    This report summarizes technical progress on the program ??Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems? funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed jointly by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering and the Department of Materials Science and Engineering at Virginia Tech. This three-year project started on October 1, 2008. In the project, a fiber optical sensing system based on intrinsic Fabry-Perot Interferometer (IFPI) was developed for strain and temperature measurements for Ultra Supercritical boiler condition assessment. Investigations were focused on sensor design, fabrication, attachment techniques and novel materials for high temperature and strain measurements. At the start of the project, the technical requirements for the sensing technology were determined together with our industrial partner Alstom Power. As is demonstrated in Chapter 4, all the technical requirements are successfully met. The success of the technology extended beyond laboratory test; its capability was further validated through the field test at DOE NETL, in which the sensors yielded distributed temperature mapping of a testing coupon installed in the turbine test rig. The measurement results agreed well with prior results generated with thermocouples. In this project, significant improvements were made to the IFPI sensor technology by splicing condition optimization, transmission loss reduction, sensor signal demodulation and sensor system design.

  19. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  20. Coal-fueled diesels for modular power generation

    SciTech Connect (OSTI)

    Wilson, R.P.; Rao, A.K.; Smith, W.C.

    1993-11-01

    Interest in coal-fueled heat engines revived after the sharp increase in the prices of natural gas and petroleum in the 1970`s. Based on the success of micronized coal water slurry combustion tests in an engine in the 1980`s, Morgantown Energy Technology Center (METC) of the US Department of Energy. initiated several programs for the development of advanced coal-fueled diesel and gas turbine engines for use in cogeneration, small utilities, industrial applications and transportation. Cooper-Bessemer and Arthur D. Little have been developing technology since 1985, under the sponsor of METC, to enable coal water slurry (CWS) to be utilized in large bore, medium-speed diesel engines. Modular power generation applications in the 10--100 MW size (each plant typically using from two to eight engines) are the target applications for the late 1990`s and beyond when, according to the US DOE and other projections, oil and natural gas prices are expected to escalate much more rapidly compared to the price of coal. As part of this program over 7.50 hours of prototype engine operation has been achieved on coal water slurry (CWS), including over 100 hours operation of a six-cylinder full scale engine with Integrated Emissions Control System in 1993. In this paper, the authors described the project cost of the CWS fuel used, the heat rate of the engine operating on CWS, the projected maintenance cost for various engine components, and the demonstrated low emissions characteristics of the coal diesel system.

  1. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect (OSTI)

    Geiling, D.W.

    1993-08-01

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  2. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B.

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  3. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    SciTech Connect (OSTI)

    Lew, D.; Brinkman, G.; Kumar, N.; Besuner, P.; Agan, D.; Lefton, S.

    2012-08-01

    High penetrations of wind and solar power will impact the operations of the remaining generators on the power system. Regional integration studies have shown that wind and solar may cause fossil-fueled generators to cycle on and off and ramp down to part load more frequently and potentially more rapidly. Increased cycling, deeper load following, and rapid ramping may result in wear-and-tear impacts on fossil-fueled generators that lead to increased capital and maintenance costs, increased equivalent forced outage rates, and degraded performance over time. Heat rates and emissions from fossil-fueled generators may be higher during cycling and ramping than during steady-state operation. Many wind and solar integration studies have not taken these increased cost and emissions impacts into account because data have not been available. This analysis considers the cost and emissions impacts of cycling and ramping of fossil-fueled generation to refine assessments of wind and solar impacts on the power system.

  4. Liquid Tin Anode Direct Coal Fuel Cell Final Program Report

    SciTech Connect (OSTI)

    Tao, Thomas

    2012-01-26

    This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

  5. Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Carl R. Evenson; Shane E. Roark

    2006-03-31

    The objective of this project was to develop an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. A family of hydrogen separation membranes was developed including single phase mixed conducting ceramics, ceramic/ceramic composites, cermet membranes, cermet membranes containing a hydrogen permeable metal, and intermediate temperature composite layered membranes. Each membrane type had different operating parameters, advantages, and disadvantages that were documented over the course of the project. Research on these membranes progressed from ceramics to cermets to intermediate temperature composite layered membranes. During this progression performance was increased from 0.01 mL x min{sup -1} x cm{sup -2} up to 423 mL x min{sup -1} x cm{sup -2}. Eltron and team membranes not only developed each membrane type, but also membrane surface catalysis and impurity tolerance, creation of thin film membranes, alternative applications such as membrane promoted alkane dehydrogenation, demonstration of scale-up testing, and complete engineering documentation including process and mechanical considerations necessary for inclusion of Eltron membranes in a full scale integrated gasification combined cycle power plant. The results of this project directly led to a new $15 million program funded by the Department of Energy. This new project will focus exclusively on scale-up of this technology as part of the FutureGen initiative.

  6. Hydrogen milestone could help lower fossil fuel refining costs

    ScienceCinema (OSTI)

    McGraw, Jennifer

    2013-05-28

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, laboratory fellow and technical director of the INL High Temperature Electrolysis team, today announced that the latest fuel cell modification has set a new mark in endurance. The group's Integrated Laboratory Scale experiment has now operated continuously for 2,583 hours at higher efficiencies than previously attained. Learn more about INL research at http://www.facebook.com/idahonationallaboratory.

  7. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  8. Commercialization strategies for coal-derived transportation fuels

    SciTech Connect (OSTI)

    Tomlinson, G.; Gray, D.

    1992-12-31

    The objective of this paper is to analyze a program that can stimulate the development of a synthetic liquid transportation fuels from coal industry, by requiring that the products be bought at their true cost of production. These coal-derived liquids will then be assimulated into the nation`s fuel supply system. The cost of this program will be borne by increased cost of all fuels in the marketplace. The justification of the program is the assumption that, because of increasing demand, the world oil price (WOP) will increase to a level that will make coal-derived fuels economical in the relatively near future. However, as noted in the International Energy Outlook of 1990: ``Given current costs and Technologies, it is estimated the cost of crude oil would have to exceed $35 per barrel in 1989 dollars for at least four consecutive years for commercial production, in the range of 100,000 barrels per day, of synthetic liquids to occur. This delayed response of production to price increases reflects the planning and construction time required to complete a coal liquefaction plant``. This program is designed to reduce this time lag so that coal-derived fuels will be available when they are needed. This timely production capability of coal liquids may be able to limit future world oil prices to the actual cost of synthetic alternatives. In addition, the program is structured so that it will provide synthetic fuel producers with a cushion in the event that the WOP continues to remain low.

  9. Enzymantic Conversion of Coal to Liquid Fuels

    SciTech Connect (OSTI)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

  10. Timing is everything : along the fossil fuel transition pathway.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Walker, La Tonya Nicole; Malczynski, Leonard A.

    2013-10-01

    People save for retirement throughout their career because it is virtually impossible to save all you'll need in retirement the year before you retire. Similarly, without installing incremental amounts of clean fossil, renewable or transformative energy technologies throughout the coming decades, a radical and immediate change will be near impossible the year before a policy goal is set to be in place. Therefore, our research question is,To meet our desired technical and policy goals, what are the factors that affect the rate we must install technology to achieve these goals in the coming decades?' Existing models do not include full regulatory constraints due to their often complex, and inflexible approaches to solve foroptimal' engineering instead ofrobust' and multidisciplinary solutions. This project outlines the theory and then develops an applied software tool to model the laboratory-to-market transition using the traditional technology readiness level (TRL) framework, but develops subsequent and a novel regulatory readiness level (RRL) and market readiness level (MRL). This tool uses the ideally-suited system dynamics framework to incorporate feedbacks and time delays. Future energy-economic-environment models, regardless of their programming platform, may adapt this software model component framework ormodule' to further vet the likelihood of new or innovative technology moving through the laboratory, regulatory and market space. The prototype analytical framework and tool, called the Technology, Regulatory and Market Readiness Level simulation model (TRMsim) illustrates the interaction between technology research, application, policy and market dynamics as they relate to a new or innovative technology moving from the theoretical stage to full market deployment. The initial results that illustrate the model's capabilities indicate for a hypothetical technology, that increasing the key driver behind each of the TRL, RRL and MRL components individually decreases the time required for the technology to progress through each component by 63, 68 and 64%, respectively. Therefore, under the current working assumptions, to decrease the time it may take for a technology to move from the conceptual stage to full scale market adoption one might consider expending additional effort to secure regulatory approval and reducing the uncertainty of the technology's demand in the marketplace.

  11. Boiler and steam generator corrosion: Fossil-fuel power plants. March 1977-December 1989 (A Bibliography from the NTIS data base). Report for March 1977-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. Hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 88 citations fully indexed and including a title list.)

  12. EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY Documents Available for ...

  13. Biomass and Coal into Liquid Fuel with CO2 Capture - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Biomass and Coal into Liquid Fuel with CO2 Capture New Single-step hydrolysis process co-converts coal and any biomass to liquid fuel Savannah ...

  14. Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2008-10-15

    Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

  15. Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned Undersea Vehicles

    Broader source: Energy.gov [DOE]

    Solid oxide fuel cell (SOFC) technology being developed by the U.S. Department of Energy (DOE) for coal-based central power generation is being adapted by the U.S. Office of Naval Research for use in advanced unmanned undersea vehicles (UUVs).

  16. Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor

    SciTech Connect (OSTI)

    Wagland, S.T.; Kilgallon, P.; Coveney, R.; Garg, A.; Smith, R.; Longhurst, P.J.; Pollard, S.J.T.; Simms, N.

    2011-06-15

    An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal + 10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal + 10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

  17. Assessment of a multi-stage underwater vehicle concept using a fossil-fuel Stirling engine

    SciTech Connect (OSTI)

    Reader, G.T.; Potter, I.J.

    1995-12-31

    The Stirling Engine because of its inherent closed-cycle operation can be readily modified to work in an airless environment even if the primary source of energy is a fossil fuel. Thus, Stirling engines are well suited for use in the underwater environment and have been operated successfully in manned military submarines since the early 1980s. In recent years fossil fueled Stirling systems have been also proposed for use in small unmanned underwater vehicles (UUVs). However, in this case the need to carry an onboard oxygen supply in a very confined space has presented a number of design difficulties. These are identified in the paper. However, if the oxidant supply to the engine is provided by the membrane extraction of dissolved oxygen from seawater and/or disposable fuel/oxidant pods are used then the UUV Stirling system becomes more attractive. If this latter concept is extended to include multi-stage vehicles then it can be shown that fossil fueled Stirlings could also be put to effective use in long range-long endurance underwater vehicular operations.

  18. Fossil fuel-fired peak heating for geothermal greenhouses

    SciTech Connect (OSTI)

    Rafferty, K.

    1997-01-01

    Greenhouses are a major application of low-temperature geothermal resources. In virtually all operating systems, the geothermal fluid is used in a hot water heating system to meet 100% of both the peak and annual heating requirements of the structure. This strategy is a result of the relatively low costs associated with the development of most US geothermal direct-use resources and past tax credit programs which penalized systems using any conventional fuel sources. Increasingly, greenhouse operations will encounter limitations in available geothermal resource flow due either to production or disposal considerations. As a result, it will be necessary to operate additions at reduced water temperatures reflective of the effluent from the existing operations. Water temperature has a strong influence on heating system design. Greenhouse operators tend to have unequivocal preferences regarding heating system equipment. Many growers, particularly cut flower and bedding plant operators, prefer the {open_quotes}bare tube{close_quotes} type heating system. This system places small diameter plastic tubes under the benches or adjacent to the plants. Hot water is circulated through the tubes providing heat to the plants and the air in the greenhouse. Advantages include the ability to provide the heat directly to the plants, low cost, simple installation and the lack of a requirement for fans to circulate air. The major disadvantage of the system is poor performance at low (<140{degrees}F) water temperatures, particularly in cold climates. Under these conditions, the quantity of tubing required to meet the peak heating load is substantial. In fact, under some conditions, it is simply impractical to install sufficient tubing in the greenhouse to meet the peak heating load.

  19. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect (OSTI)

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  20. SUBTASK 3.11 – PRODUCTION OF CBTL-BASED JET FUELS FROM BIOMASS-BASED FEEDSTOCKS AND MONTANA COAL

    SciTech Connect (OSTI)

    Sharma, Ramesh

    2014-06-01

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used interchangeably without any special requirements and thus provides a pathway to energy security to the U.S. military and the entire nation. This subtask was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26- 08NT43291. Nonfederal funding was provided by Accelergy Corporation.

  1. Characterization and supply of coal based fuels

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    This report discusses a number of special fuel slurries with a short description of the preparation method and numerous data sheets.

  2. NREL: Technology Deployment - Fossil Fuel Dependency Falls from 100% to 56%

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Alcatraz Island Fossil Fuel Dependency Falls from 100% to 56% on Alcatraz Island News Solar Cells Light Up Prison Cells on 'The Rock' Sponsors U.S. National Park Service American Recovery and Reinvestment Act Key Partners National Park Service Golden Gate National Recreation Area National Park Service Denver Services Center Princeton Power Inc. University of Washington Lawrence Berkeley National Laboratory U.S. DOE Federal Energy Management Program Related Stories U.S. Virgin Islands

  3. March 2016 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy, Office of Scientific and Technical Information Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 310 Bamboo: An Overlooked Biomass Resource? Scurlock, J.M.O. (2000) 197 Solubility of methane in water under natural conditions: a laboratory study. Final report, April 1, 1978-June 30, 1982 Blount, C.W.; Price, L.C. (1982) 186 ADVANCED TECHNIQUES FOR RESERVOIR SIMULATION AND MODELING OF

  4. EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels by Fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Identification - Energy Innovation Portal Energy Analysis Energy Analysis Find More Like This Return to Search EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels by Fluid Identification Lawrence Berkeley National Laboratory Contact LBL About This Technology Plots of electrical conductivity over the Troll Field in the North Sea produced by analyzing 3D electromagnetic field data. Plots of electrical conductivity over the Troll Field in the North Sea produced by analyzing 3D

  5. High capacity fossil fuel fired plant operator training program. Student handbook. Final report

    SciTech Connect (OSTI)

    Pearson, S.; Gardner, M.; Nguyen, Q.

    1994-09-30

    The operator of fossil fuel-fired boilers has a significant responsibility in assuring that the unit is continuously operated in a manner which complies with the various state and federal regulations. The course will emphasize the operating principles for all types of boilers and for all types of control equipment used for controlling air emissions from boilers. The course will emphasize the significant operating parameters that directly influence air emissions.

  6. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1997-05-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  7. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1996-01-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  8. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Bergman, H.L.

    1980-01-04

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  9. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration Now Available

    Broader source: Energy.gov [DOE]

    A new report “Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration” from the Electric Power Research Institute (EPRI) and jointly funded by the Offices of...

  10. EA-1778: Proposed Rule, 10 CFR 433 and 435, Energy Conservation and Fossil Fuel-Generated Energy

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of DOE's Proposed Rule, 10 CFR Part 433, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Commercial and Multi-Family High-Rise Residential Buildings and 10 CFR Part 435, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Low-Rise Residential Buildings.

  11. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    SciTech Connect (OSTI)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  12. Long-term tradeoffs between nuclear- and fossil-fuel burning

    SciTech Connect (OSTI)

    Krakowski, R.A.

    1996-12-31

    A global energy/economics/environmental (E{sup 3}) model has been adapted with a nuclear energy/materials model to understand better {open_quotes}top-level{close_quotes}, long-term trade offs between civilian nuclear power, nuclear-weapons proliferation, fossil-fuel burning, and global economic welfare. Using a {open_quotes}business-as-usual{close_quotes} (BAU) point-of-departure case, economic, resource, proliferation-risk implications of plutonium recycle in LAIRs, greenhouse-gas-mitigating carbon taxes, and a range of nuclear energy costs (capital and fuel) considerations have been examined. After describing the essential elements of the analysis approach being developed to support the Los Alamos Nuclear Vision Project, preliminary examples of parametric variations about the BAU base-case scenario are presented. The results described herein represent a sampling from more extensive results collected in a separate report. The primary motivation here is: (a) to compare the BAU basecase with results from other studies; (b) to model on a regionally resolved global basis long-term (to year {approximately}2100) evolution of plutonium accumulation in a variety of forms under a limited range of fuel-cycle scenarios; and (c) to illustrate a preliminary connectivity between risks associated with nuclear proliferation and fossil-fuel burning (e.g., greenhouse-gas accumulations).

  13. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  14. Fossil Energy Program semiannual progress report for April 1991 through September 1991

    SciTech Connect (OSTI)

    Judkins, R.R.

    1992-10-01

    This report covers progress made during the period April 1, 1991, through September 30, 1991, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Fossil Energy Office of Petroleum Reserves, and the US Agency for International Development (USAID). The Fossil Energy Program organization chart is shown in the appendix. Project discussed are: materials research and development; environmental analysis support; coal conversion development; coal combustion research; fossil fuel supplies modeling and research; evaluations and assessments; and coal structure and chemistry.

  15. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  16. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  17. Coal based synthetic fuel technology assessment guides

    SciTech Connect (OSTI)

    Not Available

    1981-09-01

    Seventeen synthetic fuel processes are described in detail and compared on a uniform basis. This work was supported by the Energy Information Administration for the purpose of technology assessment of the processes, their efficiency, the capitalized and operating cost of plants of similar size, possible constraints, possible siting problems, regional effects, pollution control, etc. (LTN)

  18. Proceedings of the second US Department of Energy environmental control symposium. Volume 1. Fossil energy

    SciTech Connect (OSTI)

    1980-06-01

    These proceedings document the presentations given at the Second Environmental Control Symposium. Symposium presentations highlighted environmental control activities which span the entire DOE. Volume I contains papers relating to coal preparation, oil shales, coal combustion, advanced coal utilization (fluidized bed combustion, MHD generators, OCGT, fuel cells), coal gasification, coal liquefaction, and fossil resource extraction (enhanced recovery). Separate abstracts for individual papers are prepared for inclusion in the Energy Data Base. (DMC)

  19. Producing liquid fuels from coal: prospects and policy issues

    SciTech Connect (OSTI)

    James T. Bartis; Frank Camm; David S. Ortiz

    2008-07-01

    The increase in world oil prices since 2003 has prompted renewed interest in producing and using liquid fuels from unconventional resources, such as biomass, oil shale, and coal. This book focuses on issues and options associated with establishing a commercial coal-to-liquids (CTL) industry within the United States. It describes the technical status, costs, and performance of methods that are available for producing liquids from coal; the key energy and environmental policy issues associated with CTL development; the impediments to early commercial experience; and the efficacy of alternative federal incentives in promoting early commercial experience. Because coal is not the only near-term option for meeting liquid-fuel needs, this book also briefly reviews the benefits and limitations of other approaches, including the development of oil shale resources, the further development of biomass resources, and increasing dependence on imported petroleum. A companion document provides a detailed description of incentive packages that the federal government could offer to encourage private-sector investors to pursue early CTL production experience while reducing the probability of bad outcomes and limiting the costs that might be required to motivate those investors. (See Rand Technical Report TR586, Camm, Bartis, and Bushman, 2008.) 114 refs., 2 figs., 16 tabs., 3 apps.

  20. Integrating catalytic coal gasifiers with solid oxide fuel cells

    SciTech Connect (OSTI)

    Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

    2010-01-01

    A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

  1. Fossil Energy Program semiannual progress report for October 1991--March 1992

    SciTech Connect (OSTI)

    Judkins, R.R.

    1992-11-01

    This report covers progress made during the period October 1, 1991, through March 31, 1992, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Office of Basic Energy Sciences, the DOE Fossil Energy Office of Petroleum Reserves, the DOE Fossil Energy Naval Petroleum and Oil Shale Reserves, and the US Agency for International Development. The Fossil Energy Program organization chart is shown in the appendix. Topics discussed are under the following projects: materials research and developments; environmental analysis support; coal conversion development; coal combustion research; and fossil fuels supplies modeling and research.

  2. Can industry`s `fourth` fossil fuel establish presence in US?

    SciTech Connect (OSTI)

    Armor, A.F.; Dene, C.E.

    1996-09-01

    After five years of commercial experience burning Orimulsion overseas, US utilities are now evaluating the new fuel as a serious alternative to oil. In their relentless drive to remain competitive, electric utilities with oil-fired generating units are searching for lower cost fuel alternatives. Because of high fuel prices, oil-fired units have low capacity factors. Only 23 out of 142 oil-capable units in the US had capacity factors greater than 50% in 1993; the average was a mere 24%. Utility consumption of fuel oil slid from over 600,000 barrels (bbl)/day in 1989 to less than 200,000 bbl/day last year. Orimulsion now fuels nearly 3,000 MW/yr worldwide. The UK`s PowerGen Ltd, currently the world`s largest consumer of Orimulsion, fires some 10-million bbl/yr at two 500-MW units at its Ince plant and three 120-MW units at its Richborough plant. Both plants formerly burned fuel oil, and have been using Orimulsion since 1991. Canada`s New Brunswick Power Corp has fired Orimulsion in two units at its Dalhousie plant since 1994 (Power, April 1995, p 27); one 105-MW unit was originally designed for fuel oil, the other 212-MW unit was designed for coal. Last year, Denmark`s SK Power converted its coal-fired, 700-MW Asnaes Unit 5 to Orimulsion firing. And in the US, Florida Power and Light Co. (FP and L) has signed a 20-yr fuel supply contract with Bitor America Corp (Boca Raton, Fla.), for two 800-MW units at the oil-fired Manatee plant, contingent on securing necessary permits. The Manatee installation (Power, September 1994, p 57) would be the first in the US to burn the fuel. Today, five years after Orimulsion begun to be used commercially, many of the lingering questions involving the new fuel`s handling, transportation, combustion, emissions control, spill control, and waste utilization have been settled. Several US utilities have expressed serious interest in the fuel as an alternative to oil.

  3. Publications of the Oak Ridge National Laboratory Fossil Energy Program, October 1, 1991--March 31, 1993

    SciTech Connect (OSTI)

    Carlson, P.T.

    1993-06-01

    The Oak Ridge National Laboratory (ORNL) Fossil Energy Program, organized in FY 1974 as the Coal Technology Program, involves research and development activities for the Department of Energy (DOE) Assistant Secretary for Fossil Energy that cover a wide range of fossil energy technologies. The principal focus of the Laboratory`s fossil energy activities relates to coal, with current emphasis on materials research and development; environmental, health, and safety research; and the bioprocessing of coal to produce liquid or gaseous fuels. This bibliography covers the period of October 1, 1991, through March 31, 1993.

  4. Development of alternative fuels from coal-derived syngas

    SciTech Connect (OSTI)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  5. Characterization and supply of coal based fuels. Volume 1, Final report and appendix A (Topical report)

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  6. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  7. Liquid fossil-fuel technology. Quarterly technical progress report, January-March 1983

    SciTech Connect (OSTI)

    Linville, B.

    1983-07-01

    Accomplishments for the quarter ending March 1983 are presented under the following headings: liquid fossil fuel cycle, processing, utilization, and project integration and technology transfer. Feature articles for this quarter are: (1) abandoned oil field reports issued; (2) oilfield water data bank report published; (3) microbial enhanced recovery report issued; (4) polymer-augmented project could be economic today; (5) carbon dioxide EOR estimates given; (6) BETC passes 65th milestone; and (7) fifty achievements for fifty years (1918-1968). BETC publications are also listed. (ATT)

  8. Comparison of emissions from landfills, municipal waste combustors, and fossil fuel-fired utilities

    SciTech Connect (OSTI)

    1996-11-01

    Landfilling is the most popular disposal method for managing municipal solid waste (MSW). However, air emissions from MSW landfills have generally been unregulated until recently. Instead, EPA has focused on emissions from municipal waste combustors (MWCs), even though they only manage 15% of MSW generated in the United States. In the past, little data have been available comparing landfill and MWC air emissions. Such information is provided by this paper. It also compares emissions from waste-to-energy MWCs and fossil fuel-fired utilities with equivalent electrical generation capacity. 1 refs., 6 tabs.

  9. USVI Makes Headway Toward Goal to Reduce Fossil Fuel 60% by 2025

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil prices spike to over $145/ barrel and price of electricity exceeds $0.50/kWh in U.S. Virgin Islands (USVI) USVI announces goal to reduce fossil fuel use 60% by 2025 In 3rd most active hurricane season on record, Earl hits USVI Virgin Islands Energy O ce (VIEO) launches Sun Power Loan Program WAPA installs waste heat recovery plant, adding 19 MW of power without burning a single drop of additional oil VIEO awards nearly $1 million to USVI nonpro ts for energy e ciency and renewable energy

  10. International Experts on Clean Coal, Carbon Capture Technologies to Meet at Pittsburgh Coal Conference

    Broader source: Energy.gov [DOE]

    The role of fossil fuels in the global energy portfolio, reducing the environmental impacts of coal-based energy systems, and recent advances in clean coal technology are just some of the subjects that will be discussed at the 2012 International Pittsburgh Coal Conference to be held October 15-18 at the David L. Lawrence Convention Center in Pittsburgh, Pa.

  11. Fossil | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    by Daniel Wood, Energy Department. Fossil energy sources, including oil, coal and natural gas, are non-renewable resources that formed when prehistoric plants and animals died...

  12. Development of a 5 kW Prototype Coal-Based Fuel Cell

    SciTech Connect (OSTI)

    Chuang, Steven S.C.; Mirzababaei, Jelvehnaz; Rismanchian, Azadeh

    2014-01-20

    The University of Akron Fuel Cell Laboratory pioneered the development of a laboratory scale coal-based fuel cell, which allows the direct use of high sulfur content coal as fuel. The initial research and coal fuel cell technology development (“Coal-based Fuel Cell,” S. S. C. Chuang, PCT Int. Appl. 2006, i.e., European Patent Application, 35 pp. CODEN: PIXXD2 WO 2006028502 A2 20060316) have demonstrated that it is feasible to electrochemically oxidize carbon to CO2, producing electricity. The key innovative concept of this coal-based fuel cell technology is that carbon in coal can be converted through an electrochemical oxidation reaction into manageable carbon dioxide, efficiently generating electricity without involving coal gasification, reforming, and water-gas shift reaction. This study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reaction. A carbon injection system was developed to inject the solid fuel without bringing air into the anode chamber; a fuel cell stack was developed and tested to demonstrate the feasibility of the fuel cell stack. Further improvement of anode catalyst activity and durability is needed to bring this novel coal fuel cell to a highly efficient, super clean, multi-use electric generation technology, which promises to provide low cost electricity by expanding the utilization of U.S. coal supplies and relieving our dependence on foreign oil.

  13. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO{sub 2} was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO{sub 2}. In contrast, mixed char reactivity to H{sub 2}O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H{sub 2}O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times and off-gas compositions in gasification conditions established in a variety of commercial gasifiers. The model has the potential to provide insight on certain implications of co-firing coal and biomass in gasification and combustion application when kinetic parameters for the mixed chars are employed.

  14. NEW SOLID FUELS FROM COAL AND BIOMASS WASTE

    SciTech Connect (OSTI)

    Hamid Farzan

    2001-09-24

    Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable fuel. These fuels will be converted to energy while reducing CO{sub 2} emissions from power generating boilers and mitigating global warming concerns. This report describes the sludge analysis, solid fuel preparation and production, combustion performance, environmental emissions and required equipment.

  15. A brief overview of Chinese Design Code on Fossil-Fueled Power Plants

    SciTech Connect (OSTI)

    Xu Zhongqing; He Yehong

    1996-10-01

    The Chinese Design Code on Fossil Fueled Power Plants (DL 5000-94) was issued in April 1994 by the Ministry of Electric Power Industry, P.R. China, and the English version has been drafted and will be formally published in the near future. Based on the 1984 version and the nation`s current policies, the 1994 version was formed to meet the challenges of the nation`s speedy development of electric power construction. In general, the code is primarily a directive document guiding the planning and engineering of China`s large- and medium-sized fossil-fueled power plants. The preparation of the 1984 version and the revision of it to the 1994 version were all carried out by the East China Electric Power Design Institute under the direction of Electric Power Planning and Engineering Institute. For small-sized power plants with unit rating of 25 MW and below, there is another national design code titled Code for Design of Small Sized Power Plants (GB 50049-94) issued in November 1994 jointly by the China`s National Technology Supervision Administration and the Ministry of Construction.

  16. Fuel injection of coal slurry using vortex nozzles and valves

    DOE Patents [OSTI]

    Holmes, Allen B.

    1989-01-01

    Injection of atomized coal slurry fuel into an engine combustion chamber is achieved at relatively low pressures by means of a vortex swirl nozzle. The outlet opening of the vortex nozzle is considerably larger than conventional nozzle outlets, thereby eliminating major sources of failure due to clogging by contaminants in the fuel. Control fluid, such as air, may be used to impart vorticity to the slurry and/or purge the nozzle of contaminants during the times between measured slurry charges. The measured slurry charges may be produced by a diaphragm pump or by vortex valves controlled by a separate control fluid. Fluidic circuitry, employing vortex valves to alternatively block and pass cool slurry fuel flow, is disclosed.

  17. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  19. Fossil Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy Fossil Energy Below are resources for Tribes on fossil energy. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011 This paper...

  20. Status of fossil energy resources: A global perspective

    SciTech Connect (OSTI)

    Balat, M.

    2007-07-01

    This article deals with recently status of global fossil energy sources. Fossil energy sources have been split into three categories: oil,coal, and natural gas. Fossil fuels are highly efficient and cheap. Currently oil is the fastest primary energy source in the world (39% of world energy consumption). Coal will be a major source of energy for the world for the foreseeable future (24% of world energy consumption). In 2030, coal covers 45% of world energy needs. Natural gas is expected to be the fastest growing component of world energy consumption (23% of world energy consumption). Fossil fuel extraction and conversion to usable energy has several environmental impacts. They could be a major contributor to global warming and greenhouse gases and a cause of acid rain; therefore, expensive air pollution controls are required.

  1. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H; Parish, Esther S; Kline, Keith L

    2015-01-01

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  2. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dale, Virginia H; Parish, Esther S; Kline, Keith L

    2015-01-01

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most ofmore » which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.« less

  3. SECA Coal-Based Systems - FuelCell Energy, Inc.

    SciTech Connect (OSTI)

    Ayagh, Hossein

    2014-01-31

    The overall goal of this U.S. Department of Energy (DOE) sponsored project is the development of solid oxide fuel cell (SOFC) cell and stack technology suitable for use in highly-efficient, economically-competitive central generation power plant facilities fueled by coal synthesis gas (syngas). This program incorporates the following supporting objectives: • Reduce SOFC-based electrical power generation system cost to $700 or less (2007 dollars) for a greater than 100 MW Integrated Gasification Fuel Cell (IGFC) power plant, exclusive of coal gasification and CO2 separation subsystem costs. • Achieve an overall IGFC power plant efficiency of at least 50%, from coal (higher heating value or HHV) to AC power (exclusive of CO2 compression power requirement). • Reduce the release of CO2 to the environment in an IGFC power plant to no more than 10% of the carbon in the syngas. • Increase SOFC stack reliability to achieve a design life of greater than 40,000 hours. At the inception of the project, the efforts were focused on research, design and testing of prototype planar SOFC power generators for stationary applications. FuelCell Energy, Inc. successfully completed the initial stage of the project by meeting the program metrics, culminating in delivery and testing of a 3 kW system at National Energy Technology Laboratory (NETL). Subsequently, the project was re-aligned into a three phase effort with the main goal to develop SOFC technology for application in coal-fueled power plants with >90% carbon capture. Phase I of the Coal-based efforts focused on cell and stack size scale-up with concurrent enhancement of performance, life, cost, and manufacturing characteristics. Also in Phase I, design and analysis of the baseline (greater than 100 MW) power plant system—including concept identification, system definition, and cost analysis—was conducted. Phase II efforts focused on development of a ≥25 kW SOFC stack tower incorporating multiple stack building blocks of scaled-up cells, suitable for integration into a large-scale fuel cell power module. Activities in Phase II also included the development of the baseline system, factory cost estimate for the baseline plant’s power block, and conceptual design of a natural gas fueled sub-MW system to be used for testing and verification of the fuel cell stacks in a system environment. The specific objective for Phase III was the validation of the performance and robustness of stacks and scaled stack arrays suitable for use in large-scale power generation systems such as an IGFC with reliable, fail-safe operation being of paramount importance. The work culminated in the verification tests of a 60 kW SOFC stack module in a power plant facility. This final technical report summarizes the progress made during the project period. Significant progress was made in the areas of cell and stack technology development, stack module design, sub-scale module tests, Baseline Power Plant system development and Proof-of- Concept Module unit design. The development of this technology will significantly advance the nation’s energy security and independence interests while simultaneously addressing environmental concerns, including greenhouse gas emissions and water usage.

  4. Coal/D-RDF (densified refuse-derived fuel) co-firing project, Milwaukee County, Wisconsin

    SciTech Connect (OSTI)

    Hecklinger, R.S.; Rehm, F.R.

    1985-11-01

    A Research and Development Project was carried out to mix a densified refuse-derived fuel with coal at the fuel-receiving point and to co-fire the mixture in a spreader-stoker fired boiler. Two basic series of test runs were conducted. For the first series, coal was fired to establish a base line condition. For the second series, a mixture of coal and densified refuse-derived fuel was fired. The report describes the equipment used to densify refuse derived fuel, procedures used to prepare and handle the coal and densified refuse derived fuel mixture and the test results. The results include the effect of the coal and densified refuse derived fuel mixture on plant operations, boiler efficiency, stack emissions and EP toxicity.

  5. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined less by the needs of the plant than by the availability in the soil solution; in addition to occurring naturally, Cl is present in excess as the anion complement in K fertilizer applications. An analysis was performed on existing data for switchgrass samples from ten different farms in the south-central portion of Iowa, with the goal of determining correlations between switchgrass elemental composition and geographical and seasonal changes so as to identify factors that influence the elemental composition of biomass. The most important factors in determining levels of various chemical compounds were found to be seasonal and geographical differences related to soil conditions. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions as well as fly ash. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures using cluster analysis were developed to characterize the inorganic material in these samples. Each of the biomass types exhibited different inorganic associations in the fuel as well as in the deposits and fly ash. Morphological analyses of the wheat straw show elongated 10-30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the organic structure of the biomass materials. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Although growing rapidly, the fouling deposits of the biomass and coal-biomass blends were significantly weaker than those of the coals. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similarity from the fuel to the ash analyzed. A high percentage of particles from both fuel and ash samples contained both Si and K. While Cl was a significant component in the fuel, very little was detected in the ash sample.

  6. Wear mechanism and wear prevention in coal-fueled diesel engines. Task 7, Extended wear testing

    SciTech Connect (OSTI)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  7. Wear mechanism and wear prevention in coal-fueled diesel engines

    SciTech Connect (OSTI)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  8. Fireside corrosion in oxy-fuel combustion of coal

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Holcomb, Gordon R.; Tylczak, Joseph; Meier, Gerald H.; Jung, Kee Young; Mu, Nan; Yanar, Nazik M.; Pettit, Frederick S.

    2011-08-01

    Oxy-fuel combustion is based on burning fossil fuels in a mixture of recirculated flue gas and oxygen, rather than in air. An optimized oxy-combustion power plant will have ultra-low emissions since the flue gas that results from oxy-fuel combustion consists almost entirely of CO2 and water vapor. Once the water vapor is condensed, it is relatively easy to sequester the CO2 so that it does not escape into the atmosphere. A variety of laboratory tests comparing air-firing to oxy-firing conditions, and tests examining specific simpler combinations of oxidants, were conducted at 650-700 C. Alloys studied included model Fe-Cr and Ni-Crmore » alloys, commercial ferritic steels, austenitic steels, and nickel base superalloys. Furthermore, the observed corrosion behavior shows accelerated corrosion even with sulfate additions that remain solid at the tested temperatures, encapsulation of ash components in outer iron oxide scales, and a differentiation between oxy-fuel combustion flue gas recirculation choices.« less

  9. Fireside Corrosion in Oxy-Fuel Combustion of Coal

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Tylczak, Joseph; Meier, G.H.; Jung. K.; Mu, N.; Yanar, N.M.; Pettit, F.S.

    2012-08-01

    Oxy-fuel combustion is based on burning fossil fuels in a mixture of recirculated flue gas and oxygen, rather than in air. An optimized oxy-combustion power plant will have ultra-low emissions since the flue gas that results from oxy-fuel combustion consists almost entirely of CO2 and water vapor. Once the water vapor is condensed, it is relatively easy to sequester the CO2 so that it does not escape into the atmosphere. A variety of laboratory tests comparing air-firing to oxy-firing conditions, and tests examining specific simpler combinations of oxidants, were conducted at 650-700 C. Alloys studied included model Fe-Cr and Ni-Cr alloys, commercial ferritic steels, austenitic steels, and nickel base superalloys. The observed corrosion behavior shows accelerated corrosion even with sulfate additions that remain solid at the tested temperatures, encapsulation of ash components in outer iron oxide scales, and a differentiation between oxy-fuel combustion flue gas recirculation choices.

  10. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect (OSTI)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025. Other potential benefits of the demonstration include developing a passive technology for water treatment for trace metal and nutrient release reductions, using power plant by-products to improve coal mine land reclamation and carbon sequestration, developing wildlife habitat and green-space around production facilities, generating Total Maximum Daily Load (TMDL) credits for the use of process water, and producing wood products for use by the lumber and pulp and paper industry. Project activities conducted during the five year project period include: Assessing tree cultivation and other techniques used to sequester carbon; Project site assessment; Greenhouse studies to determine optimum plant species and by-product application; Designing, constructing, operating, monitoring, and evaluating the CCWESTRS system; and Reporting (ongoing). The ability of the system to sequester carbon will be the primary measure of effectiveness, measured by accessing survival and growth response of plants within the CCWESTRS. In addition, costs associated with design, construction, and monitoring will be evaluated and compared to projected benefits of other carbon sequestration technologies. The test plan involves the application of three levels each of two types of power plant by-products--three levels of FGD gypsum mulch, and three levels of ash pond irrigation water. This design produces nine treatment levels which are being tested with two species of hardwood trees (sweet gum and sycamore). The project is examining the effectiveness of applications of 0, 8-cm, and 15-cm thick gypsum mulch layers and 0, 13 cm, and 25 cm of coal fly ash water for irrigation. Each treatment combination is being replicated three times, resulting in a total of 54 treatment plots (3 FGD gypsum levels X 3 irrigation water levels x 2 tree species x 3 replicates). Survival and growth response of plant species in terms of sequestering carbon in plant material and soil will be the primary measure of effectiveness of each treatment. Additionally, the ability of the site soils and unsaturated zone subsurface m

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  12. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    SciTech Connect (OSTI)

    Michael Petrik; Robert Ruhl

    2012-03-31

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled “Small Scale SOFC Demonstration using Bio-based and Fossil Fuels.” Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  13. Results of studies on application of CCMHD to advanced fossil fuel power plant cycles

    SciTech Connect (OSTI)

    Foote, J.P.; Wu, Y.C.L.S.; Lineberry, J.T.

    1998-07-01

    A study was conducted to assess the potential for application of a Closed Cycle MHD disk generator (CCMHD) in advanced fossil fuel power generation systems. Cycle analyses were conducted for a variety of candidate power cycles, including simple cycle CCMHD (MHD); a cycle combining CCMHD and gas turbines (MHD/GT); and a triple combined cycle including CCMHD, gas turbines, and steam turbines (MHD/GT/ST). The above cycles were previously considered in cycle studies reported by Japanese researchers. Also considered was a CCMHD cycle incorporating thermochemical heat recovery through reforming of the fuel stream (MHD/REF), which is the first consideration of this approach. A gas turbine/steam turbine combined cycle (GT/ST) was also analyzed for baseline comparison. The only fuel considered in the study was CH4. Component heat and pressure losses were neglected, and the potential for NOx emission due to high combustion temperatures was not considered. Likewise, engineering limitations for cycle components, particularly the high temperature argon heater, were not considered. This approach was adopted to simplify the analysis for preliminary screening of candidate cycles. Cycle calculations were performed using in-house code. Ideal gas thermodynamic properties were calculated using the NASA SP- 273 data base, and thermodynamic properties for steam were calculated using the computerized ASME Steam Tables. High temperature equilibrium compositions for combustion gas were calculated using tabulated values of the equilibrium constants for the important reactions.

  14. Estimating Externalities of Coal Fuel Cycles, Report 3

    SciTech Connect (OSTI)

    Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

    1994-09-01

    The agreement between the US DOE and the EC established the specific objectives of the study: (a) to develop a methodological framework that uses existing data and models to quantify the external costs and benefits of energy; (b) to demonstrate the application of the framework to estimate the externalities of the coal, biomass, oil, natural gas, hydro, nuclear, photovoltaic, and wind fuel cycles (by agreement with the EC, the US addressed the first six of these); and (c) to identify major gaps in the availability of information to quantify impacts, damages, benefits, and externalities of fuel cycles; and to suggest priorities for future research. The main consideration in defining these objectives was a desire to have more information about externalities, and a better method for estimating them.

  15. Coal and Biomass to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids » Coal and Biomass to Liquids Coal and Biomass to Liquids Over the last several decades, the Office of Fossil Energy performed RD&D activities that made significant advancements in the areas of coal conversion to liquid fuels and chemicals. Technology improvements and cost reductions that were achieved led to the construction of demonstration-scale facilities. The program is now supporting work to reduce the carbon footprint of coal derived liquids by incorporating the

  16. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Table 7. Sales of fossil fuel production from federal and Indian lands by state/area, FY 2003-14 trillion Btu State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 Alabama 75 57 51 47 40 42 60 88 86 71 46 29 Alaska 61 66 68 52 32 28 27 23 21 19 18 21 Arizona 258 273 280 193 180 162 157 154 164 163 167 158 Arkansas 7 8 10 10 10 11 15 18 14 13 11 11 California 141 125 124 139 146 129 116 115 121 125 121 119 Colorado 785 842 960 906 905 931 846 868 917 952 875 877 Florida 0 - - - - -

  17. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; Summers, Cathy A.; Gerdemann, Steve; Oryshchyn, Danylo B.; Turner, Paul; Patrick, Brian R.

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  18. A creep damage estimation method for in-service fossil fuel boiler superheater tubes

    SciTech Connect (OSTI)

    Nogata, F. . Dept. of Mechanical Engineering); Takahashi, H. . Research Inst. of Fracture Technology)

    1995-02-01

    Because mechanical properties of structural materials for high-temperature use, such as boiler tubing, degrade during long-term service, it is essential to detect toughness degradation by means of a nondestructive and simple field test technique. A grain boundary etching technique is developed to detect material degradation, and assess creep strength and notch toughness. An etching test using a picric acid solution with a wetting agent or using 20 percent HNO[sub 3] with alcoholic solution was found to have great potential for the nondestructive estimation of grain boundary embrittlement caused by carbide and sigma precipitation in SUS stainless steel. The feasibility of this estimation procedure was determined showing the relationships between Charpy impact energy (CVN) and grooving width (W[sub GS]), and creep damage ratio ([Phi]) and W[sub GS]. Superheater tubes of fossil fuel boiler were tested on site to demonstrate the validity of this technique.

  19. Device for separating CO2 from fossil-fueled power plant emissions

    DOE Patents [OSTI]

    Burchell, Timothy D.; Judkins, Roddie R.; Wilson, Kirk A.

    2002-04-23

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  20. Techno-Economic Analysis of Scalable Coal-Based Fuel Cells

    SciTech Connect (OSTI)

    Chuang, Steven S. C.

    2014-08-31

    Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels and stack revealed that the planner fuel cell stack is not suitable for operation with carbon and coal fuels due to lack of mechanical strength and difficulty in sealing. We have developed scalable processes for manufacturing of process for planner and tubular cells. Our studies suggested that tubular cell stack could be the only option for scaling up the coal-based fuel cell. Although the direct feeding of coal into fuel cell can significantly simplify the fuel cell system, the durability of the fuel cell needs to be further improved before scaling up. We are developing a tubular fuel cell stack with a coal injection and a CO2 recycling unit.

  1. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect (OSTI)

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  2. Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis

    SciTech Connect (OSTI)

    Kakwani, R. M.; Wilson, Jr., R. P.; Winsor, R. E.

    1991-12-01

    Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

  3. Novel injector techniques for coal-fueled diesel engines. Final report

    SciTech Connect (OSTI)

    Badgley, P.R.

    1992-09-01

    This report, entitled ``Novel Injector Techniques for Coal-Fueled Diesel Engines,`` describes the progress and findings of a research program aimed at development of a dry coal powder fuel injector in conjunction with the Thermal Ignition Combustion System (TICS) concept to achieve autoignition of dry powdered coal in a single-cylinder high speed diesel engine. The basic program consisted of concept selection, analysis and design, bench testing and single cylinder engine testing. The coal injector concept which was selected was a one moving part dry-coal-powder injector utilizing air blast injection. Adiabatics has had previous experience running high speed diesel engines on both direct injected directed coal-water-slurry (CWS) fuel and also with dry coal powder aspirated into the intake air. The Thermal Ignition Combustion System successfully ignited these fuels at all speeds and loads without requiring auxiliary ignition energy such as pilot diesel fuel, heated intake air or glow or spark plugs. Based upon this prior experience, it was shown that the highest efficiency and fastest combustion was with the dry coal, but that the use of aspiration of coal resulted in excessive coal migration into the engine lubrication system. Based upon a desire of DOE to utilize a more modern test engine, the previous naturally-aspirated Caterpillar model 1Y73 single cylinder engine was replaced with a turbocharged (by use of shop air compressor and back pressure control valve) single cylinder version of the Cummins model 855 engine.

  4. Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University

    SciTech Connect (OSTI)

    Trembly, J. P.

    2007-06-01

    Coal is the United States’ most widely used fossil fuel for the production of electric power. Coal’s availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.

  5. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/03

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions.

  6. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/02

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions. (DMC)

  7. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  8. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    Energy Science and Technology Software Center (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The softwaremore » can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.« less

  9. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    SciTech Connect (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The software can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.

  10. An overview of alternative fossil fuel price and carbon regulation scenarios

    SciTech Connect (OSTI)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices, (3) externally generated oil price forecasts, and (4) the historical difficulty in accurately forecasting oil prices. Overall, a spread between the FE-EERE High Oil Price and Reference scenarios of well over $8/bbl is supported by the literature. We conclude that a wide range of carbon regulation scenarios are possible, especially within the time frame considered by EERE and FE (through 2050). The Working Group's Carbon Cap-and-Trade Scenario is found to be less aggressive than many Kyoto-style targets that have been analyzed, and similar in magnitude to the proposed Climate Stewardship Act. The proposed scenario is more aggressive than some other scenarios found in the literature, however, and ignores carbon banking and offsets and does not allow nuclear power to expand. We are therefore somewhat concerned that the stringency of the proposed carbon regulation scenario in the 2010 to 2025 period will lead to a particularly high estimated cost of carbon reduction. As described in more detail later, we encourage some flexibility in the Working Group's ultimate implementation of the Carbon Cap-and-Trade Scenario. We conclude by identifying additional scenarios that might be considered in future analyses, describing a concern with the proposed specification of the High Fuel Price Scenario, and highlighting the possible difficulty of implementing extreme scenarios with current energy modeling tools.

  11. Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report

    SciTech Connect (OSTI)

    Roberts, William L

    2012-10-31

    The primary objectives of this work can be summed into two major categories. Firstly, the fundamentals of the combustion of glycerol (in both a refined and unrefined form) were to be investigated, with emphasis of the development of a system capable of reliably and repeatedly combusting glycerol as well as an analysis of the emissions produced during glycerol combustion. Focus was placed on quantifying common emissions in comparison to more traditional fuels and this work showed that the burner developed was able to completely combust glycerol within a relatively wide range of operating conditions. Additionally, focus was placed on examining specific emissions in more detail, namely interesting NOx emissions observed in initial trials, acrolein and other volatile organic emissions, and particulate and ash emissions. This work showed that the combustion of crude glycerol could result in significantly reduced NOx emissions as a function of the high fuel bound oxygen content within the glycerol fuel. It also showed that when burned properly, the combustion of crude glycerol did not result in excessive emissions of acrolein or any other VOC compared to the combustion from more traditional fuels. Lastly however, this work has shown that in any practical application in which glycerol is being burned, it will be necessary to explore ash mitigation techniques due to the very high particulate matter concentrations produced during glycerol combustion. These emissions are comparable to unfiltered coal combustion and are directly tied to the biodiesel production method. The second focus of this work was directed to developing a commercialization strategy for the use of glycerol as a fuel replacement. This strategy has identified a 30 month plan for the scaling up of the laboratory scale burner into a pre-pilot scale system. Additionally, financing options were explored and an assessment was made of the economics of replacing a traditional fuel (namely natural gas) with crude glycerol from biodiesel production. This analysis showed that the cost of replacing natural gas with crude glycerol requires a strong function of the market price per unit of energy for the traditional fuel. However, the economics can be improved through the inclusion of a federal tax credit for the use of a renewable fuel. The conclusion of this analysis also shows that the ideal customer for energy replacement via crude glycerol is biodiesel producers who are located in remote regions, where the cost of energy is higher and the cost of crude glycerol is lowest. Lastly, the commercialization strategy analyzed competing technologies, namely traditional natural gas and electric heaters, as well as competing glycerol burners, and concludes with a discussion of the requirements for a pilot demonstration.

  12. Fossil Energy Program. Progress report for April 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-06-01

    This report - the sixty-ninth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, coal cogeneration/district heating plant assessment, performance assurance system support, and international energy technology assessment.

  13. Fossil energy program. Progress report for May 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-08-01

    This report - the seventieth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, technical support to the TVA fluidized bed combustion demonstration plant program, coal cogeneration/district heating plant assessment, atmospheric fluidized bed coal combustor for cogeneration, performance assurance system support and international energy technology assessment.

  14. Fossil energy program. Progress report for June 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-08-01

    This report - the seventy-first of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluation, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, TVA fluidized combustion demonstration plant program technical support, coal cogeneration/district heating plant assessment, performance assurance system support, and international energy technology assessment.

  15. Hawaii energy strategy project 2: Fossil energy review. Task 1: World and regional fossil energy dynamics

    SciTech Connect (OSTI)

    Breazeale, K.; Isaak, D.T.; Yamaguchi, N.; Fridley, D.; Johnson, C.; Long, S.

    1993-12-01

    This report in the Hawaii Energy Strategy Project examines world and regional fossil energy dynamics. The topics of the report include fossil energy characteristics, the world oil industry including reserves, production, consumption, exporters, importers, refining, products and their uses, history and trends in the global oil market and the Asia-Pacific market; world gas industry including reserves, production, consumption, exporters, importers, processing, gas-based products, international gas market and the emerging Asia-Pacific gas market; the world coal industry including reserves, classification and quality, utilization, transportation, pricing, world coal market, Asia-Pacific coal outlook, trends in Europe and the Americas; and environmental trends affecting fossil fuels. 132 figs., 46 tabs.

  16. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  17. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  18. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Citation Details In-Document Search Title: Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked

  19. Coal-Based Oxy-Fuel System Evaluation and Combustor Development; Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications

    SciTech Connect (OSTI)

    Hollis, Rebecca

    2013-03-31

    Clean Energy Systems, Inc. (CES) partnered with the U.S. Department of Energy’s National Energy Technology Laboratory in 2005 to study and develop a competing technology for use in future fossil-fueled power generation facilities that could operate with near zero emissions. CES’s background in oxy-fuel (O-F) rocket technology lead to the award of Cooperative Agreement DE-FC26-05NT42645, “Coal-Based Oxy-Fuel System Evaluation and Combustor Development,” where CES was to first evaluate the potential of these O-F power cycles, then develop the detailed design of a commercial-scale O-F combustor for use in these clean burning fossil-fueled plants. Throughout the studies, CES found that in order to operate at competitive cycle efficiencies a high-temperature intermediate pressure turbine was required. This led to an extension of the Agreement for, “Oxy-Fuel Turbomachinery Development for Energy Intensive Industrial Applications” where CES was to also develop an intermediate-pressure O-F turbine (OFT) that could be deployed in O-F industrial plants that capture and sequester >99% of produced CO2, at competitive cycle efficiencies using diverse fuels. The following report details CES’ activities from October 2005 through March 2013, to evaluate O-F power cycles, develop and validate detailed designs of O-F combustors (main and reheat), and to design, manufacture, and test a commercial-scale OFT, under the three-phase Cooperative Agreement.

  20. Vibration mills in the manufacturing technology of slurry fuel from unbeneficiated coal sludge

    SciTech Connect (OSTI)

    E.G. Gorlov; A.I. Seregin; G.S. Khodakov [Institute for Fossil Fuels, Moscow (Russia)

    2008-08-15

    Coal-water slurry fuel (CWSF) is economically viable provided that its ash content does not exceed 30% and the amount water in the fuel is at most 45%. Two impoundments were revealed that have considerable reserves of waste coal useful for commercial manufacture of CWSF without the beneficiation step. One of the CWSF manufacture steps is the comminution of coal sludge to have a particle size required by the combustion conditions. Vibration mills, which are more compact and energy-intensive that drum mills, can be used in the CWSG manufacture process. The rheological characteristics of CWSF obtained from unbeneficiated waste coal were determined.

  1. Liquid fuels from co-processing coal with bitumen or heavy oil: A review

    SciTech Connect (OSTI)

    Moschopedis, S.E.; Hepler, L.G.

    1987-01-01

    Coal, bitumen and heavy oil (and various pitches, resids, etc.) are similar in that they require more substantial treatment than does conventional light oil to yield useful liquid fuels. The authors provide a brief and selective review of technologies for liquefying coal, followed by consideration of co-processing coal with bitumen/heavy oil. Such co-processing may be considered as use of bitumen/heavy oil as a solvent and/or hydrogen donor in liquefaction of coal, or as the use of coal to aid upgrading bitumen/heavy oil.

  2. Fossil Energy Program annual progress report for April 1997 through March 1998

    SciTech Connect (OSTI)

    Judkins, R.R.

    1998-07-01

    This report covers progress made on research and development projects that contribute to the advancement of fossil energy technologies, covering the areas of coal, clean coal technology, gas, petroleum, and support to the Strategic Petroleum Reserve (SPR). Papers are arranged under the following topical sections: materials research and development; environmental analysis support; bioprocessing research; fossil fuels supplies modeling and research; and oil and gas production.

  3. The coprocessing of fossil fuels and biomass for CO{sub 2} emission reduction in the transportation sector

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Yuanji; Borgwardt, R.H.

    1993-10-01

    Research is underway to evaluate the Hydrocarb process for conversion of carbonaceous raw material to clean carbon and methanol products. These products are valuable in the market either as fuel or as chemical commodities. As fuel, methanol and carbon can be used economically, either independently or in slurry form, in efficient heat energies (turbines and internal combustion engines) for both mobile and stationary single and combined cycle power plants. When considering CO{sub 2} emission control in the utilization of fossil fuels, the copressing of those fossil fuels with biomass (which may include, wood, municipal solid waste and sewage sludge) is a viable mitigation approach. By coprocessing both types of feedstock to produce methanol and carbon while sequestering all or part of the carbon, a significant net CO{sub 2} reduction is achieved if the methanol is substituted for petroleum fuels in the transportation sector. The Hydrocarb process has the potential, if the R&D objectives are achieved, to produce alternative transportation fuel from indigenous resources at lower cost than any other biomass conversion process. These comparisons suggest the resulting fuel can significantly displace gasoline at a competitive price while mitigating CO{sub 2} emissions and reducing ozone and other toxics in urban atmospheres.

  4. EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon

    Energy Savers [EERE]

    County, WY | Department of Energy 2: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY Documents Available for Download November 27, 2009 EIS-0432: Notice of Intent to Prepare an Environmental Impact Statement Federal Loan Guarantee to Support the Construction and Startup of the Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, Wyoming December 16, 2009

  5. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    SciTech Connect (OSTI)

    David Petti; J. Stephen Herring

    2010-03-01

    As described in the Department of Energy Office of Nuclear Energy’s Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled “Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors”, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: • Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, • Produce hydrogen for industrial processes and transportation fuels, and • Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nation’s energy security through more effective utilization of our country’s resources while simultaneously providing economic stability and growth (through predictable energy prices and high value jobs), in an environmentally sustainable and secure manner (through lower land and water use, and decreased byproduct emissions). The reduction in imported oil will also increase the retention of wealth within the U.S. economy while still supporting economic growth. Nuclear energy is the only non-fossil fuel that has been demonstrated to reliably supply energy for a growing industrial economy.

  6. The impact of environmental regulation on productivity in the US fossil-fueled power plants

    SciTech Connect (OSTI)

    Whang, J.

    1993-12-31

    The purpose of this dissertation is to examine the impact of environmental regulation on productivity in the U.S. fossil fueled electric generating industry. With the oil shocks, environmental regulation has been considered as one of the main culprits for the apparent productivity slowdown during the 1970`s. Even though new pieces of legislation are continuously enacted to regulate hazardous pollutants emitted, it is difficult to find thorough and meaningful analyses on the effects of regulation. Without exact measurement of regulation effects, it is not easy to design socially efficient environmental policies to reconcile several conflicting goals. Using plant-level production and environmental data for the last two decades, the effects of differentiated environmental regulation are carefully examined. Since unbalanced panel data set is used, fixed-effects and random-effects models are also examined. The estimated impact of environmental regulation explains 6 to 10 percent of the variation of total factor productivity growth rates. This appears to be a relatively mild effect compared with several previous studies.

  7. Determining NO{sub x} emissions from fossil fuel-fired sources

    SciTech Connect (OSTI)

    McNeel, A.

    1996-11-01

    To determine nitrogen oxides (NO{sub x}) emissions, the concentration of NO{sub x} within the stack gas must be determined. USEPA Reference Methods 7, 7A, 7C, 7D and/or 7E are the procedures to be used for NO{sub x} measurement as referenced in 40 CFR 60 subparts D, Da, Db and Dc - {open_quotes}Standards of performance for fossil fuel-fired steam generators...{open_quotes}. Depending upon the reason for determining NO{sub x} emissions, information in addition to NO{sub x} concentrations may be needed. Generally, USEPA Reference Methods 1 - 4 will be used to gather the additional data needed to satisfy the specific need for determining NO{sub x} emissions. The following text outlines the individual NO{sub x} sampling methodology, the relative costs of the reference method (RM) sampling, and the use of the resulting reference method data to calculate emissions in units of applicable standards.

  8. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  9. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Lippert, Thomas E.

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  10. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  11. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  12. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two different co-processed fuel oils were tested: one that had been partially hydrotreated, and the other a product of fractionation before hydrotreating. Task 5 focused on examining refining methods that would utilize coal and produce thermally stable jet fuel, included delayed coking and solvent extraction. Delayed coking was done on blends of decant oil and coal, with the goal to produce a premium carbon product and liquid fuels. Coking was done on bench scale and large laboratory scale cokers. Two coals were examined for co-coking, using Pittsburgh seam coal and Marfork coal product. Reactions in the large, laboratory scaled coker were reproducible in yields of products and in quality of products. While the co-coke produced from both coals was of sponge coke quality, minerals left in the coke made it unacceptable for use as anode or graphite grade filler.

  13. Coal in a changing climate

    SciTech Connect (OSTI)

    Lashof, D.A.; Delano, D.; Devine, J.

    2007-02-15

    The NRDC analysis examines the changing climate for coal production and use in the United States and China, the world's two largest producers and consumers of coal. The authors say that the current coal fuel cycle is among the most destructive activities on earth, placing an unacceptable burden on public health and the environment. There is no such thing as 'clean coal.' Our highest priorities must be to avoid increased reliance on coal and to accelerate the transition to an energy future based on efficient use of renewable resources. Energy efficiency and renewable energy resources are technically capable of meeting the demands for energy services in countries that rely on coal. However, more than 500 conventional coal-fired power plants are expected in China in the next eight years alone, and more than 100 are under development in the United States. Because it is very likely that significant coal use will continue during the transition to renewables, it is important that we also take the necessary steps to minimize the destructive effects of coal use. That requires the U.S. and China to take steps now to end destructive mining practices and to apply state of the art pollution controls, including CO{sub 2} control systems, to sources that use coal. Contents of the report are: Introduction; Background (Coal Production; Coal Use); The Toll from Coal (Environmental Effects of Coal Production; Environmental Effects of Coal Transportation); Environmental Effects of Coal Use (Air Pollutants; Other Pollutants; Environmental Effects of Coal Use in China); What Is the Future for Coal? (Reducing Fossil Fuel Dependence; Reducing the Impacts of Coal Production; Reducing Damage From Coal Use; Global Warming and Coal); and Conclusion. 2 tabs.

  14. Power-Gen `95. Book III: Generation trends. Volume 1 - current fossil fuel technologies. Volume 2 - advanced fossil fuel technologies. Volume 3 - gas turbine technologies I

    SciTech Connect (OSTI)

    1995-12-31

    This document is Book III of Power-Gen 1995 for the Americas. I contains papers on the following subjects: (1) Coal technologies, (2) atmospheric fluidized bed combustion, (3) repowering, (4) pressurized fluidized bed combustion, (5) combined cycle facilities, and (6) aeroderivitive and small gas turbines.

  15. An Internet-based interactive module for air emissions from fossil fuel based power generation

    SciTech Connect (OSTI)

    Karman, D.; O`Leary, K.; O`Reilly, S.

    1997-12-31

    The proliferation of the Internet, Web pages and associated software tools available for developing multimedia material provides significant opportunities in training, education and information transfer. This paper will describe the development, testing and evaluation of an interactive teaching module aimed at college and university students that have previous education in thermodynamics and basic chemistry. The module is currently in development at the Department of Civil and Environmental Engineering at Carleton University with support from Environment Canada. Preliminary testing of this module is expected to begin late January. The module contains options to look at CO, CO{sub 2}, SO{sub 2} and NO{sub x} emissions associated with electric power generation in thermal stations that use coal, natural gas, crude and distillate oil. Factors governing the thermal efficiency of typical boiler systems and the thermodynamic limitations for converting heat into work are discussed. Supporting background information such as emission trends and emission factors used in calculations are also included as part of this module. A simple Rankine cycle without reheat or regeneration is considered to compare the emissions per unit energy delivered from each of the fuels considered. For natural gas and distillate oil, combined cycle operation is considered with a gas turbine-heat recovery steam generator combination replacing the boiler in the simple Rankine cycle. For all fuels, the cogeneration option is investigated by expanding the steam to an intermediate pressure in the turbine and utilizing the remaining heat by condensing the steam in a heat recovery application. Emission factors and basic information on CO, SO{sub 2} and NO{sub x} control technologies are utilized to calculate and report the emissions per unit energy delivered under the various scenarios investigated.

  16. Process for the production and recovery of fuel values from coal

    DOE Patents [OSTI]

    Sass, Allan; McCarthy, Harry E.; Kaufman, Paul R.; Finney, Clement S.

    1982-01-01

    A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

  17. Fossil Energy Crossword Puzzle | Department of Energy

    Energy Savers [EERE]

    Crossword Puzzle Fossil Energy Crossword Puzzle PDF icon Fossil Energy Crossword Puzzle (including answer key) More Documents & Publications Fossil Energy Word Find Intermediate Energy Infobook and Intermediate Infobook Activities (29 Activities) Coal Study Guide for Elementary School

  18. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  19. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  20. Coal-fueled diesel technology development. Final report, March 3, 1988--January 31, 1994

    SciTech Connect (OSTI)

    1994-01-31

    Since 1979, the US Department of Energy has been sponsoring Research and Development programs to use coal as a fuel for diesel engines. In 1984, under the partial sponsorship of the Burlington Northern and Norfolk Southern Railroads, GE completed a 30-month study on the economic viability of a coal-fueled locomotive. In response to a GE proposal to continue researching the economic and technical feasibility of a coal-fueled diesel engine for locomotives, DOE awarded a contract to GE Corporate Research and Development for a three-year program that began in March 1985 and was completed in 1988. That program was divided into two parts: an Economic Assessment Study and a Technical Feasibility Study. The Economic Assessment Study evaluated the benefits to be derived from development of a coal-fueled diesel engine. Seven areas and their economic impact on the use of coal-fueled diesels were examined; impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The Technical Feasibility Study used laboratory- and bench-scale experiments to investigate the combustion of coal. The major accomplishments of this study were the development of injection hardware for coal water slurry (CWS) fuel, successful testing of CWS fuel in a full-size, single-cylinder, medium-speed diesel engine, evaluation of full-scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions. Full combustion of CWS fuel was accomplished at full and part load with reasonable manifold conditions.

  1. Automated remote control of fuel supply section for the coal fired power plant

    SciTech Connect (OSTI)

    Chudin, O.V.; Maidan, B.V.; Tsymbal, A.A.

    1996-05-01

    Approximately 6,000 miles east of Moscow, lays the city of Khabarovsk. This city`s coal-fired Power Plant 3 supplies electricity, heat and hot water to approximately 250,000 customers. Plant 3 has three units with a combined turbine capacity of 540 MW, (3 {times} 180) electrical and 780 (3 {times} 260) Gkal an hour thermal capacity with steam productivity of 2010 (3 {times} 670) tons per hour at 540 C. Coal fired thermal electric power plants rely on the equipment of the fuel supply section. The mechanism of the fuel supply section includes: conveyor belts, hammer crushers, guiding devices, dumping devices, systems for dust neutralizing, iron separators, metal detectors and other devices. As a rule, the fuel path in the power plant has three main directions: from the railroad car unloading terminal to the coal warehouse; from the coal warehouse to the acceptance bunkers of the power units, and the railroad car unloading terminal to the acceptance bunkers of power units. The fuel supply section always has a reserve and is capable of uninterruptible fuel supply during routine maintenance and/or repair work. This flexibility requires a large number of fuel traffic routes, some of which operate simultaneously with the feeding of coal from the warehouse to the acceptance bunkers of the power units, or in cases when rapid filling of the bunkers is needed, two fuel supply routes operate at the same time. The remote control of the fuel handling system at Power Plant 3 is described.

  2. Clean Coal Research | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Coal Research Clean Coal Research DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled power plants by increasing overall system efficiencies and reducing capital costs. In the near-term, advanced technologies that increase the power generation efficiency for new plants and technologies to capture carbon dioxide (CO2) from new and existing

  3. Comparison of AB2588 multipathway risk factors for California fossil-fuel power stations

    SciTech Connect (OSTI)

    Gratt, L.B.; Levin, L.

    1997-12-31

    Substances released from power plants may travel through various exposure pathways resulting in human health and environmental risks. The stack air emission`s primary pathway is inhalation from the ambient air. Multipathway factors (adjustment factors to the inhalation risk) are used to evaluate the importance of non-inhalation pathways (such as ingestion and dermal contact). The multipathway factor for a specific substance is the health risk by all pathways divided by the inhalation health risk for that substance. These factors are compared for fossil fuel power stations that submitted regulatory risk assessments in compliance with California Toxic Hot Spots Act (AB2588). Substances representing the largest contributions to the cancer risk are of primary concern: arsenic, beryllium, cadmium, chromium (+6), formaldehyde, nickel, lead, selenium, and PAHs. Comparisons of the chemical-specific multipathway factors show the impacts of regulatory policy decisions on the estimated health risk for trace substances. As an example, point estimates of the soil mixing depth, varying from 1 cm to 15 cm, relate to the relative importance of the pathway. For the deeper mixing depths, the root-zone uptake by homegrown tomato plants (for assumed consumption rate of 15% for San Diego) may result in high multipathway factors for several trace metals. For shallower mixing depths, soil ingestion may become the dominant non-inhalation pathway. These differences may lead to significantly different risk estimates for similar facilities located at different California locations such as to be under local regulatory authorities. The overall multipathway factor for the total cancer risk is about 2, much smaller than some of the chemical-specific factors. Science-based multipathway analysis should reduce much of the concern that may be due to policy-based decisions on pathway selection and high-value point-estimates of the parameters.

  4. Renewable wood fuel: Fuel feed system for a pulverized coal boiler. Final report

    SciTech Connect (OSTI)

    1996-01-01

    This report evaluates a pilot test program conducted by New York State Gas & Electric Corporation to evaluate the feasibility of co-firing a pulverized coal plant with renewable wood fuels. The goal was to establish that such a co-firing system can reduce air emissions while maintaining good operational procedures and cost controls. The test fuel feed system employed at Greenidge Station`s Boiler 6 was shown to be effective in feeding wood products. Emission results were promising and an economic analysis indicates that it will be beneficial to pursue further refinements to the equipment and systems. The report recommends further evaluation of the generation and emission impacts using woods of varied moisture contents and at varied Btu input rates to determine if a drying system would be a cost-effective option.

  5. Table 11.6 Installed Nameplate Capacity of Fossil-Fuel Steam...

    U.S. Energy Information Administration (EIA) Indexed Site

    With Environmental Equipment," " 1985-2010 (Megawatts)" "Year","Coal",,,,"Petrol...ers)",,"Collectors","Towers","(Scrubbers)" 1985,302056,120591,56955,304706,36054,28895,65,...

  6. EIS-0357- Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA

    Broader source: Energy.gov [DOE]

    This Environmental Impact Statement (EIS) assesses the potential environmental impacts that would result from a proposed Department of Energy (DOE) action to provide cost-shared funding for construction and operation of facilities near Gilberton, Pennsylvania, which have been proposed by WMPI PTY, LLC, for producing electricity, steam, and liquid fuels from anthracite coal waste (culm). The project was selected by DOE under the Clean Coal Power Initiative (CCPI) to demonstrate the integration of coal waste gasification and Fischer-Tropsch (F-T) synthesis of liquid hydrocarbon fuels at commercial scale.

  7. Transportation costs for new fuel forms produced from low rank US coals

    SciTech Connect (OSTI)

    Newcombe, R.J.; McKelvey, D.G. ); Ruether, J.A. )

    1990-09-01

    Transportation costs are examined for four types of new fuel forms (solid, syncrude, methanol, and slurry) produced from low rank coals found in the lower 48 states of the USA. Nine low rank coal deposits are considered as possible feedstocks for mine mouth processing plants. Transportation modes analyzed include ship/barge, pipelines, rail, and truck. The largest potential market for the new fuel forms is coal-fired utility boilers without emission controls. Lowest cost routes from each of the nine source regions to supply this market are determined. 12 figs.

  8. Coal liquefaction process wherein jet fuel, diesel fuel and/or ASTM No. 2 fuel oil is recovered

    DOE Patents [OSTI]

    Bauman, Richard F.; Ryan, Daniel F.

    1982-01-01

    An improved process for the liquefaction of coal and similar solid carbonaceous materials wherein a hydrogen donor solvent or diluent derived from the solid carbonaceous material is used to form a slurry of the solid carbonaceous material and wherein the naphthenic components from the solvent or diluent fraction are separated and used as jet fuel components. The extraction increases the relative concentration of hydroaromatic (hydrogen donor) components and as a result reduces the gas yield during liquefaction and decreases hydrogen consumption during said liquefaction. The hydrogenation severity can be controlled to increase the yield of naphthenic components and hence the yield of jet fuel and in a preferred embodiment jet fuel yield is maximized while at the same time maintaining solvent balance.

  9. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  10. Krakow clean fossil fuels and energy efficiency program. Phase 1 report

    SciTech Connect (OSTI)

    Butcher, T.; Pierce, B.

    1995-06-01

    Krakow is one of the largest and oldest cities in Poland. It is situated in the south of the country on the banks of the Vistula River. From the 11th until the 17th centuries, it was the capital of Poland. Today, Krakow is a city of 750,000 residents, one of the largest centers of higher education, an important industrial center, and is of particular importance because of the number and kinds of historic buildings and sites. For this reason, Krakow was included by the UNESCO in the list of the world`s cultural heritages. For about three decades, significant air pollution has been one of Krakow`s most serious problems. Because the city is situated in the Vistula River valley, it is poorly ventilated and experiences a high concentration of air pollutants. The quality of air in Krakow is affected mainly by industry (Sendzimir Steelworks, energy industry, chemical plants), influx from the Silesian industrial region (power plants, metallurgy), transboundary pollution (Ostrava - Czech Republic), and local sources of low pollution, i.e. more than 1,000 boiler houses using solid fuels and more than 100,000 coal-fired home stoves. These local sources, with low stacks and almost no pollution-control equipment, are responsible for about 35-40% of the air pollution. This report presents phase I results of a program to reduce pollution in krakow. Phase I was to gather information on emissions and costs, and to verify assumptions on existing heating methods and alternatives.

  11. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  12. Additive development for ultra-clean coal slurry fuel: Final report

    SciTech Connect (OSTI)

    Berggren, M.H.; Swanson, W.W.

    1988-05-24

    AMAX performed research to develop improved quality, cost-effective dispersing additives for coal-water slurry fuels intended for high-intensity combustion systems. Dispersants were identified on the basis of coal surface characteristics and coal-dispersant interactions. Micronized samples of physically and chemically cleaned coal feedstocks from the Eastern and Midwestern regions of the United States were examined using bulk and surface analysis techniques. Utilization of coal surface and dispersant functionality was optimized through multicomponent application of additives, pH control, and control of surface oxidation. A low-cost, low-alkali, sulfur-free dextrin compound was found to be effective in enhancing dispersion when applied to the coal surfaces as a pretreatment or with conventional dispersants as a co-additive. The cleaning method and ash content had minimal direct impact on coal surface functionality. Parameters such as internal moisture, particle size, surface area, surface oxidation, and soluble ions were the primary considerations which influenced slurry loading and additive consumption. The dispersing additive packages functioned over the range of coal types and cleaning levels investigated. The preferred additives were compatible with each other, allowing for blending to optimize performance, cost, and alkali contamination. Each additive was found to be suitable for use in applications which utilize elevated-temperature fuel delivery systems. 17 refs., 8 figs., 27 tabs.

  13. A review of METC`S continuous process monitoring devices for application to high temperature and pressure fossil fuel process streams

    SciTech Connect (OSTI)

    Chisholm, W.P.

    1994-12-31

    The Morgantown Energy Technology Center of the United States Department of Energy, in support of advanced fossil fuel technologies, is developing and applying a number of innovative continuous process monitors. These include an inductively coupled plasma spectrometer, an alkali monitor, a particle counter and sizer, and a water vapor monitor. The alkali monitor is a flame emission spectrometer currently undergoing field trials. Alkali emission from gasifiers and combustors is of interest because it causes corrosion and deposition on downstream components, such as particle filters, sulfur compound sorbents, turbine blades, etc. This device can measure alkali concentrations at the part-per-billion level. The particle monitoring devices use laser light scattering to count and size particles. By measuring particle concentration around a particulate removal device, capture efficiency can be measured in real time with a resolution of one minute. Particles between .45 and 80 microns can be counted at rates as high as one million per second in 5 bar, 350 degree celsius environments. The optical water vapor monitor uses near-infrared light absorption to monitor and control steam injection in an advanced heat exchanger. It is targeted for a 300 degrees celsius and 5 bar environment. The inductively coupled plasma system uses a helium and argon plasma discharge within a torch assembly capable of accepting a high temperature and pressure sample stream. An artificial neural network is being developed to interpret its data. Real-time data from a bench-scale coal gasifier will be presented and discussed.

  14. General circulation model calculations of the direct radiative forcing by anthropogenic sulfate and fossil-fuel soot aerosol

    SciTech Connect (OSTI)

    Haywood, J.M.; Roberts, D.L.; Slingo, A.

    1997-07-01

    A new radiation code within a general circulation model is used to assess the direct solar and thermal radiative forcing by sulfate aerosol of anthropogenic origin and soot aerosol from fossil-fuel burning. The radiative effects of different aerosol profiles, relative humidity parameterizations, chemical compositions, and internal and external mixtures of the two aerosol types are investigated. The contribution to the radiative forcing from cloudy sky regions is found to be negligible for sulfate aerosol; this is in contrast to recent studies where the cloudy sky contribution was estimated using a method in which the spatial correlation between cloud amount and sulfate burden was ignored. However, the radiative forcing due to fossil-fuel soot aerosol is enhanced in cloudy regions if soot aerosol exists within or above the cloud. The global solar radiative forcing due to sulfate aerosol is estimated to be -0.38 W m{sup -2} and the global thermal radiative forcing is estimated to be +0.01 W m{sup -2}. The hemispheric mean radiative forcings vary by only about 10% for reasonable assumptions about the chemical form of the sulfate aerosol and the relative humidity dependence; the uncertainties in the aerosol loading are far more significant. If a soot/sulfate mass ratio of 0.075 is assumed, then the global solar radiative forcing weakens to -0.18 W m{sup -2} for an external mixture and weakens further for an internal mixture. Additionally, the spatial distribution of the radiative forcing shows strong negative/positive forcing contrasts that may influence the dynamical response of the atmosphere. Although these results are extremely sensitive to the adopted soot/sulfate ratio and the assumed vertical profile, they indicate that fossil-fuel soot aerosol may exert a nonnegligible radiative forcing and emphasize the need to consider each anthropogenic aerosol species. 58 refs., 8 figs., 1 tab.

  15. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known signal-to-noise problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  16. Estimates of health risks associated with radionuclide emissions from fossil-fueled steam-electric generating plants. Final report

    SciTech Connect (OSTI)

    Nelson, C.

    1995-08-01

    Under the Title III, Section 112 of the 1990 Clean Air Act Amendment, Congress directed the U.S. Environmental Protection Agency (EPA) to perform a study of the hazards to public resulting from pollutants emitted by electric utility system generating units. Radionuclides are among the groups of pollutants listed in the amendment. This report updates previously published data and estimates with more recently available information regarding the radionuclide contents of fossil fuels, associated emissions by steam-electric power plants, and potential health effects to exposed population groups.

  17. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that the extent of steam and current load accelerate the degradation caused by PH3. A unique filtering technique has been proposed to reduce the effect of PH3. In addition, various cell materials have been proposed to reduce the rate of degradation caused by H2S. Furthermore, a three-dimensional, transient multi-physics model has been formulated to describe primary transport processes and electro-chemical reactions occurring within the cell. This model has been validated using data gathered from accelerated tests. The validated model then has been used to study the degradation rates under a range of operating conditions and impurity levels. This has resulted in a procedure that uses both experiments and simulations to predict the life-time of a cell operating with syngas with known concentration of trace impurities. Finally all the experience and knowledge gained has been disseminated via 39 journal papers and 43 presentations/posters/conference papers.

  18. DOE Transfers Coal to Fuel Paducah Area Economic Development

    Broader source: Energy.gov [DOE]

    PADUCAH, Ky. – The U.S. Department of Energy (DOE) recently completed transferring ownership of nearly 15,000 tons of excess coal to the Paducah Area Community Reuse Organization (PACRO), which...

  19. Development of high energy density fuels from mild gasification of coal

    SciTech Connect (OSTI)

    Greene, Marvin

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily skimmed'' from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  20. Development of high energy density fuels from mild gasification of coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  1. Krakow clean fossil fuels and energy efficiency program. Final report: Initial site investigation

    SciTech Connect (OSTI)

    1995-11-15

    Original objective of this project was to retrofit the Balice Boilerhouse with a TCS Coal Micronization system and Amerex baghouses to achieve higher combustion efficiencies and lower air emission, including SO{sub 2}, NO{sub x}, CO and particulate matter. The Balice Boilerhouse is located adjacent to the Krakow Airport and provides heating steam for the Polish Military Unit No. 1616. In May 1995 the Polish Military announced it had decided to convert its boiler house to gas; thus cancelling the TCS Project. The balance of 1995 was spent considering alternative Project sites in Krakow for the application of the TCS coal Micronization technology.

  2. Energy Department's Fossil Energy Chief to Tour Western Michigan...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy Chief to Tour Western Michigan University's Clean Coal Research Facilities, ... Capture and Sequestration (CCS) technology help industry make fossil energy use ...

  3. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.'' This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft[sup 2] cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  4. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, ``Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.`` This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft{sup 2} cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  5. Workshop on the utilization of coal as an alternative to petroleum fuels in the Andean region. Volume 2. Contributed papers

    SciTech Connect (OSTI)

    Not Available

    1985-06-28

    Since the advent of the petroleum crisis in the mid-seventies, with its escalating fuel-oil prices, coal production has shown a substantial increase. Worldwide coal reserves are large, and the technology exists to exploit these reserves. Andean countries, especially Peru, are known to have significant underutilized coal reserves, which could prove socially and economically attractive for energy policy and planning and for long-term self-sufficiency. At present, many industrial operations and electric-generating facilities in Bolivia, Ecuador, and Peru are dependent on fuel-oil from diminishing domestic reserves or from imports. With current prices of coal generally about half those for residual petroleum fuels (based on energy content), the potential exists for exploitation of Andean coal as an alternative to petroleum fuels. Greater use of coal resources would help meet the demand for increased energy needed to improve living standards and for increased industrialization in the area.

  6. Abrasive wear by coal-fueled diesel engine and related particles

    SciTech Connect (OSTI)

    Ives, L.K. )

    1992-09-01

    The development of commercially viable diesel engines that operate directly on pulverized coal-fuels will require solution to the problem of severe abrasive wear. The purpose of the work described in this report was to investigate the nature of the abrasive wear problem. Analytical studies were carried out to determine the characteristics of the coal-fuel and associated combustion particles responsible for abrasion. Laboratory pinon-disk wear tests were conducted on oil-particle mixtures to determine the relationship between wear rate and a number of different particle characteristics, contact parameters, specimen materials properties, and other relevant variables.

  7. Cost-Benefit Analysis of Flexibility Retrofits for Coal and Gas-Fueled Power Plants: August 2012 - December 2013

    SciTech Connect (OSTI)

    Venkataraman, S.; Jordan, G.; O'Connor, M.; Kumar, N.; Lefton, S.; Lew, D.; Brinkman, G.; Palchak, D.; Cochran, J.

    2013-12-01

    High penetrations of wind and solar power plants can induce on/off cycling and ramping of fossil-fueled generators. This can lead to wear-and-tear costs and changes in emissions for fossil-fueled generators. Phase 2 of the Western Wind and Solar Integration Study (WWSIS-2) determined these costs and emissions and simulated grid operations to investigate the full impact of wind and solar on the fossil-fueled fleet. This report studies the costs and benefits of retrofitting existing units for improved operational flexibility (i.e., capability to turndown lower, start and stop faster, and ramp faster between load set-points).

  8. ROSE-based compact simulator for fossil fuel-fired power plant

    SciTech Connect (OSTI)

    Dana, H.; Burelle, R.

    1996-11-01

    Nuclear simulators specifications typically ask for {open_quotes}high fidelity full scope replica simulator{close_quotes}. This request is not only the norm but also mandatory due to the strict regulations and safety concerns in that industry. It is an unquestionable fact that these types of simulators do provide the most realistic and effective environment to train control room operators in normal, abnormal operations, and especially in emergency conditions which would be difficult to rehearse otherwise. Utilities in the fossil industry who could afford the price that these top of the line simulators demand would not hesitate long to acquire one. Fortunately for the others, this industry has the luxury to be more flexible in its simulator`s needs which permits utilities to select a simulator within their specific budget. They may chose from a wide range of different types of simulators, including full scope or partial scope, high fidelity or generic, hardware control rooms replicas or CRT-based graphical emulations. In all cases, a simulator must be economically beneficial to plant operations to justify its cost. Taking into account the distinctive requirements of the fossil industry, including their budget constraints, CAE used its vast experience in nuclear simulators to produce a user-friendly, CRT-based compact fossil simulator, using ROSE (Real-time Object-oriented Software Environment). This paper describes the specifics and characteristics of the ROSE-base compact simulator.

  9. COAL & POWER SYSTEMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    COAL & POWER SYSTEMS STRATEGIC & MULTI-YEAR PROGRAM PLANS U.S. DEPARTMENT OF ENERGY * OFFICE OF FOSSIL ENERGY GREENER, SOONER... THROUGH TECHNOLOGY INTRODUCTION .......... i-1 STRATEGIC PLAN ........ 1-1 PROGRAM PLANS Vision 21 .......................... 2-1 Central Power Systems ...... 3-1 Distributed Generation ..... 4-1 Fuels ................................ 5-1 Carbon Sequestration ....... 6-1 Advanced Research ........... 7-1 TABLE OF CONTENTS STRATEGIC & MULTI-YEAR PROGRAM

  10. EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration

    Broader source: Energy.gov [DOE]

    The Energy Department released a report on fossil fleet transition with renewable integration, describing operational and engineering challenges to the fossil generation fleet.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  12. Los Alamos Lab: Fossil Energy & Environment, Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Fossil Energy, as well as projects supported by the Department of Interior ... to the entire fossil fuel cycle, from exploration and production to capture and storage ...

  13. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    SciTech Connect (OSTI)

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  14. Clean coal technologies: Research, development, and demonstration program plan

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The US Department of Energy, Office of Fossil Energy, has structured an integrated program for research, development, and demonstration of clean coal technologies that will enable the nation to use its plentiful domestic coal resources while meeting environmental quality requirements. The program provides the basis for making coal a low-cost, environmentally sound energy choice for electric power generation and fuels production. These programs are briefly described.

  15. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  16. CRACOW CLEAN FOSSIL FUELS AND ENERGY EFFICIENCY PROGRAM. PROGRESS REPORT, OCTOBER 1998

    SciTech Connect (OSTI)

    PIERCE,B.

    1998-10-01

    Since 1990 the US Department of Energy has been involved in a program aimed at reducing air pollution caused by small, coal-fired sources in Poland. The program focuses on the city of Cracow and is designed so that results will be applicable and extendable to the entire region. This report serves both as a review of the progress which has been made to date in achieving the program objectives and a summary of work still in progress.

  17. Method for providing improved solid fuels from agglomerated subbituminous coal

    DOE Patents [OSTI]

    Janiak, Jerzy S.; Turak, Ali A.; Pawlak, Wanda; Ignasiak, Boleslaw L.

    1989-01-01

    A method is provided for separating agglomerated subbituminous coal and the heavy bridging liquid used to form the agglomerates. The separation is performed by contacting the agglomerates with inert gas or steam at a temperature in the range of 250.degree. to 350.degree. C. at substantially atmospheric pressure.

  18. Coal-water slurry fuel internal combustion engine and method for operating same

    DOE Patents [OSTI]

    McMillian, Michael H.

    1992-01-01

    An internal combustion engine fueled with a coal-water slurry is described. About 90 percent of the coal-water slurry charge utilized in the power cycle of the engine is directly injected into the main combustion chamber where it is ignited by a hot stream of combustion gases discharged from a pilot combustion chamber of a size less than about 10 percent of the total clearance volume of main combustion chamber with the piston at top dead center. The stream of hot combustion gases is provided by injecting less than about 10 percent of the total coal-water slurry charge into the pilot combustion chamber and using a portion of the air from the main combustion chamber that has been heated by the walls defining the pilot combustion chamber as the ignition source for the coal-water slurry injected into the pilot combustion chamber.

  19. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    SciTech Connect (OSTI)

    Xiao, Hai; Dong, Junhang; Lin, Jerry; Romero, Van

    2012-03-01

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases. This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  20. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  1. Characterization of coal-water slurry fuel sprays from diesel engine injectors

    SciTech Connect (OSTI)

    Caton, J.A.; Kihm, K.D.

    1993-06-01

    Experiments were conducted to characterize coal-water slurry fuel sprays from diesel engine injectors. Since the combustion event is a strong function of the fuel spray, full characterization of the spray is a necessity for successful engine design and for modeling of the combustion process. Two experimental facilities were used at TAMU to study the injection of coal slurry fuels. The first experimental facility incorporates General Electric locomotive engine components (injection pump, fuel line, and nozzle) and a specially designed diaphragm to separate the abrasive coal slurry fuel from the moving parts of the pump. The second experimental facility is based on an accumulator injector from General Electric. Instrumentation includes instantaneous needle lift and fuel line pressure. A pressurized visualization chamber was used to provide a spray environment which simulated the engine gas density and permitted the use of spray diagnostic techniques. The study was divided into two phases: (1) overall characterization of the spray, and (2) detailed droplet size and size distribution characterization. In addition to this overall characterization of the spray, the second phase of this study characterized the details of the atomization quality.

  2. EA-1870: Utah Coal and Biomass Fueled Pilot Plant, Kanab, Kane County, Utah

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared an Environmental Assessment to evaluate the potential impacts of providing financial assistance to Viresco Energy, LLC, for its construction and operation of a Coal and Biomass Fueled Pilot Plant, which would be located in Kanab, Utah.

  3. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  4. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  5. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  6. Through its Clean Coal Research Program, FE

    Energy Savers [EERE]

    its inception as part of DOE in 1977, FE's R&D mission has continued to evolve to reflect the nation's key energy supply, security and environmental needs. Coal represents 93 percent of total U.S. fossil fuel reserves and is the largest single source (45 percent) of electricity generation, both currently and projected for the foreseeable future. It also is among the most carbon- intensive energy resources. Continuing the legacy of previous successes in the Clean Coal Technology Development

  7. Task 27 -- Alaskan low-rank coal-water fuel demonstration project

    SciTech Connect (OSTI)

    1995-10-01

    Development of coal-water-fuel (CWF) technology has to-date been predicated on the use of high-rank bituminous coal only, and until now the high inherent moisture content of low-rank coal has precluded its use for CWF production. The unique feature of the Alaskan project is the integration of hot-water-drying (HWD) into CWF technology as a beneficiation process. Hot-water-drying is an EERC developed technology unavailable to the competition that allows the range of CWF feedstock to be extended to low-rank coals. The primary objective of the Alaskan Project, is to promote interest in the CWF marketplace by demonstrating the commercial viability of low-rank coal-water-fuel (LRCWF). While commercialization plans cannot be finalized until the implementation and results of the Alaskan LRCWF Project are known and evaluated, this report has been prepared to specifically address issues concerning business objectives for the project, and outline a market development plan for meeting those objectives.

  8. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  9. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  10. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  11. Research Without Borders: NETL Pens MOU with Brazilian Coal Association

    Broader source: Energy.gov [DOE]

    The Department of Energy’s National Energy Technology Laboratory and the Brazilian Coal Association signed a Memorandum of Understanding on carbon capture and storage (CCS) in Florianópolis, Brazil. By signing the MOU, both parties agreed to work together over the next 5 years to assess the potential of CCS in fossil fuel–based systems, as well as the development of clean coal technologies applicable to Brazilian coals. The memorandum also covers the development of other technologies to reduce the environmental impact of fossil fuel production and use.

  12. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Table 11. Sales of coal production from federal and Indian lands by state/area, FY 2003-14 million short tons State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 Alabama 0 0 0 0 0 0 1 3 3 2 1 0 Alaska 0 0 0 0 0 0 0 0 0 0 0 0 Arizona 13 13 14 9 9 8 8 8 8 8 8 8 Arkansas 0 0 0 0 0 0 0 0 0 0 0 0 California 0 0 0 0 0 0 0 0 0 0 0 0 Colorado 22 22 25 22 22 23 18 19 19 19 17 17 Florida 0 0 0 0 0 0 0 0 0 0 0 0 Illinois 0 0 0 0 0 0 0 0 0 0 0 0 Indiana 0 0 0 0 0 0 0 0 0 0 0 0 Kansas 0 0 0 0

  13. A review of trace element emissions from the combustion of refuse-derived fuel with coal

    SciTech Connect (OSTI)

    Norton, G.A. )

    1992-05-01

    The effects of cocombusting refuse-derived fuel (RDF) with coal on stack emissions of trace elements in the ash stream were reviewed. The large number of variables and uncertainties involved precluded drawing definitive conclusions regarding many of the trace elements. However, it is evident that cocombustion resulted in increased emissions of Cd, Cu, Hg, Pb, and Zn. Emissions of As and Ni tended to decrease when RDF was fired with coal. Modeling studies indicated that ambient levels of trace elements during cocombustion should be within acceptable limits. However, periodic monitoring of Cd, Hg, and Pb may be warranted in some instances.

  14. Fossil fuel power plants: Computer systems for power plant control, maintenance, and operation. (Latest citations from the Compendex database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    The bibliography contains citations concerning fossil fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 250 citations and includes a subject term index and title list.)

  15. Assessment of Long-Term Research Needs for Coal-Liquefaction Technologies

    SciTech Connect (OSTI)

    Penner, S.S.

    1980-03-01

    The Fossil Energy Research Working Group (FERWG), at the request of J.M. Deutch (Under Secretary of DOE), E. Frieman (Director, Office of Energy Research) and G. Fumich, Jr. (Assistant Secretary for Fossil Fuels), has studied and reviewed currently funded coal-liquefaction technologies. These studies were performed in order to provide an independent assessment of critical research areas that affect the long-term development of coal-liquefaction technologies. This report summarizes the findings and research recommendations of FERWG.

  16. Advanced Fossil Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Advanced-Fossil-Fact-Sheet-FINAL.pdf More Documents & Publications CO2 Conference Presentation POWER-GEN Conference Presentation National Coal Council Presentation...

  17. Fossil | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Fossil For the first time since 1995, U.S. oil production has surpassed imports. Explore the trend with our <a href="node/770751">interactive chart</a>. | Graphic by Daniel Wood, Energy Department. For the first time since 1995, U.S. oil production has surpassed imports. Explore the trend with our interactive chart. | Graphic by Daniel Wood, Energy Department. Fossil energy sources, including oil, coal and natural gas, are non-renewable resources that formed when

  18. A formalized approach to cycle chemistry improvement in fossil fuel power plants

    SciTech Connect (OSTI)

    Dimmer, J.P.; Dooley, R.B.

    1995-01-01

    The overall cost impact of cycle chemistry problems in fossil plants is typically hidden within the statistics of component forced outages, efficiency losses and premature end of useful component life. Corrosion of components in US utility steam generating plants is responsible for an estimated 50% of forced outages and over three billion dollars a year in additional operating and maintenance costs. These problems are usually the direct result of repeat incidents of impurity ingress, corrosion, and/or corrosion product generation transport, and deposition on heat transfer and power generation process equipment surfaces. The only way to prevent repeat incidents of cycle chemistry corrosion and/or deposition-influenced equipment problems is to implement a formalized cycle chemistry improvement program that addresses the root-causes of these problems. This paper describes such a program being implemented at twelve (12) utilities under EPRI research project RP2712-11, {open_quotes}Cycle Chemistry Improvement Program.{close_quotes} Interim utility results, after almost three years of project participation, have demonstrated substantial reductions in availability/performance losses and water treatment costs due to applications of state-of-the-art cycle chemistry, monitoring equipment and/or process control systems.

  19. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  20. Wear mechanism and wear prevention in coal-fueled diesel engines

    SciTech Connect (OSTI)

    Schwalb, J.A.; Ryan, T.W.

    1991-10-01

    Coal fueled diesel engines present unique wear problems in the piston ring/cylinder liner area because of their tendency to contaminate the lube-oil with high concentrations of highly abrasive particles. This program involved a series of bench-scale wear tests and engine tests designed to investigate various aspects of the ring/liner wear problem and to make specific recommendations to engine manufacturers as to how to alleviate these problems. The program was organized into tasks, designed to accomplish the following objectives: (1) define the predominant wear mechanisms causing accelerated wear in the ring/liner area; (2) investigate the effectiveness of traditional approaches to wear prevention to prevent wear in coal-fueled engines; (3) further refine information on the most promising approaches to wear prevention; (4) present detailed information and recommendations to engine manufacturers on the most promising approach to wear prevention; (5) present a final report covering the entire program; (6)complete engine tests with a coal-derived liquid fuel, and investigate the effects of the fuel on engine wear and emissions.

  1. Carbon dioxide storage potential in coalbeds: A near-term consideration for the fossil energy industry

    SciTech Connect (OSTI)

    Byrer, C.W.; Guthrie, H.D.

    1998-07-01

    The concept of using gassy unminable coalbeds for carbon dioxide (CO2) storage while concurrently initiating and enhancing coalbed methane production may be a viable near-term system for industry consideration. Coal is the most abundant and cheapest fossil fuel resource, and it has played a vital role in the stability and growth of the US economy. With the burning of coal in power plants, the energy source is also one of the fuel causing large CO2 emissions. In the near future, coal may also have a role in solving environmental greenhouse gas concerns with increasing CO2 emissions throughout the world. Coal resources may be an acceptable and significant geological sink for storing CO2 emissions in amenable unminable coalbeds while at the same time producing natural gas from gassy coalbeds. Industry proprietary research has shown that the recovery of coalbed methane can be enhanced by the injection of CO2 via well bores into coal deposits. Gassy coals generally have shown a 2:1 coal-absorption selectivity for CO2 over methane which could allow for the potential of targeting unminable coals near fossil fueled power plants to be utilized for storing stack gas CO2. Preliminary technical and economic assessments of this concept appear to merit further research leading to pilot demonstrations in selected regions of the US.

  2. Carbon dioxide storage potential in coalbeds: A near-term consideration for the fossil energy industry

    SciTech Connect (OSTI)

    Byrer, C.W.; Guthrie, H.D.

    1998-04-01

    The concept of using gassy unminable coalbeds for carbon dioxide (CO2) storage while concurrently initiating and enhancing coalbed methane production may be a viable near-term system for industry consideration. Coal is our most abundant and cheapest fossil fuel resource, and it has played a vital role in the stability and growth of the US economy. With the burning of coal in power plants, the energy source is also one of the fuels causing large CO2 emissions. In the near future, coal may also have a role in solving environmental greenhouse gas concerns with increasing CO2 emissions throughout the world. Coal resources may be an acceptable and significant {open_quotes}geological sink{close_quotes} for storing CO2 emissions in amenable unminable coalbeds while at the same time producing natural gas from gassy coalbeds. Industry proprietary research has shown that the recovery of coalbed methane can be enhanced by the injection of CO2 via well bores into coal deposits. Gassy coals generally have shown a 2:1 coal-absorption selectivity for CO2 over methane which could allow for the potential of targeting unminable coals near fossil fueled power plants to be utilized for storing stack gas CO2. Preliminary technical and economic assessments of this concept appear to merit further research leading to pilot demonstrations in selected re ions of the US.

  3. Impacts from a fossil fuel power plant on ozone levels in Memphis, Tennessee

    SciTech Connect (OSTI)

    Mueller, S.F.; Bailey, E.M.

    1998-12-31

    The Tennessee Valley Authority (TVA) Allen power plant is located on the Mississippi River in the southwest corner of Memphis, Tennessee. Allen has three coal-fired cyclone boilers with a rated capacity of 272 MW each. It is a Phase 2 plant under Title IV of the Clean Air Act and is the largest single source of NO{sub x} in the Memphis area. TVA plans to reduce Allen NOx emissions through a combination of burning low-sulfur coal (which has the benefit of reducing NO{sub x} emissions while also reducing SO{sub 2} emissions) and installing gas re-burn technology. A modeling study using the SAI, Inc., UAM-V photochemical model was conducted to examine the potential impacts of NO{sub x} reductions on ozone levels in the Memphis area. A series of four model simulations were made in which different Allen emissions scenarios were examined. The focus period of the photochemical modeling was 11--14 July 1995 when measurements in and near Memphis indicated peak hourly ozone levels of 135--140 ppb. This analysis primarily examined computed impacts within 50 km of Memphis. Allen was computed to contribute as much as 20--30 ppb to ground ozone levels 20-50 km downwind using its NO{sub x} emission rate before Title IV compliance. After compliance it was computed to contribute only about 10--20 ppb. At the same time, maximum daily ozone reductions due to Allen NO{sub x} titration of ozone were between 30 and 60 ppb. These benefits will be reduced by 30--50% after Title IV compliance, and are expected to occur within 30 km of the plant. More model grid cells indicated dis-benefits (net ground-level ozone increases) than benefits on three of the four episode days using the Title IV compliance emission rate. Significant ozone dis-benefits were expected because of the well-documented NO titration of ozone within plumes having a high ratio of NO to volatile organic compounds.

  4. Fireside Corrosion in Oxy-fuel Combustion of Coal

    SciTech Connect (OSTI)

    G. R. Holcomb; J. Tylczak; G. H. Meier; B. Lutz; K. Jung; N. Mu; N. M. Yanar; F. S. Pettit; J. Zhu; A. Wise; D. Laughlin; S. Sridhar

    2012-05-20

    Oxy-fuel combustion is burning a fuel in oxygen rather than air. The low nitrogen flue gas that results is relatively easy to capture CO{sub 2} from for reuse or sequestration. Corrosion issues associated with the environment change (replacement of much of the N{sub 2} with CO{sub 2} and higher sulfur levels) from air- to oxy-firing were examined. Alloys studied included model Fe-Cr alloys and commercial ferritic steels, austenitic steels, and nickel base superalloys. The corrosion behavior is described in terms of corrosion rates, scale morphologies, and scale/ash interactions for the different environmental conditions.

  5. Method of producing a colloidal fuel from coal and a heavy petroleum fraction

    DOE Patents [OSTI]

    Longanbach, James R.

    1983-08-09

    A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300.degree.-550.degree. C. The slurry is heated to a temperature of 400.degree.-500.degree. C. for a limited time of only about 1-5 minutes before cooling to a temperature of less than 300.degree. C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

  6. A novel configuration for coproducing transportation fuels and power from coal and natural gas

    SciTech Connect (OSTI)

    Gray, D.; Tomlinson, G.

    1998-07-01

    The US Department of Energy and Mitretek Systems have evolved and evaluated a concept that combines the use of gas and coal for the highly efficient production of electric power and high quality transportation fuels. In its simplest form, this coproduction cofeed (CoCo) concept consists of diverting coal-derived synthesis gas from the combined cycle power block of an Integrated Coal Gasification Combined Cycle (IGCC) unit to a slurry-phase Fischer-Tropsch (F-T) synthesis reactor. The unreacted synthesis gas from the F-T reactor, and imported natural gas are then combusted in the downstream combined cycle power generation unit. Combining processes in this manner accomplishes the equivalent of natural gas to liquid synthesis while eliminating the conversion losses associated with the production of synthesis gas from natural gas. The paper discusses the benefits of coproduction.

  7. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  8. Coal-water slurry sprays from an electronically controlled accumulator fuel injection system: Break-up distances and times

    SciTech Connect (OSTI)

    Caton, J.A.; Payne, S.E.; Terracina, D.P.; Kihm, K.D.

    1993-12-31

    Experiments have been completed to characterize coal-water slurry sprays from an electronically-controlled accumulator fuel injection system of a diesel engine. The sprays were injected into a pressurized chamber equipped with windows. High speed movies, fuel pressures and needle lifts were obtained as a function of time, orifice diameter, coal loading, gas density in the chamber, and accumulator fuel pressure. For the base conditions (50% (by man) coal loading, 0.4 mm diameter nozzle hole, coal-water slurry pressure of 82 MPa (12,000 psi), and a chamber density of 25 kg/m{sup 3}), the break-up time was 0.30 ms. An empirical correlation for spray tip penetration, break-up time and initial jet velocity was developed. For the conditions of this study, the spray tip penetration and initial jet velocity were 15% greater for coal-water slurry than for diesel fuel or water. Results of this study and the correlation are specific to the tested coal-water slurry and are not general for other coal-water slurry fuels.

  9. Fossil fleet transition with fuel changes and large scale variable renewable integration

    SciTech Connect (OSTI)

    James, Revis; Hesler, Stephen; Bistline, John

    2015-03-31

    Variability in demand as seen by grid-connected dispatchable generators can increase due to factors such as greater production from variable generation assets (for example, wind and solar), increased reliance on demand response or customer-driven automation, and aggregation of loads. This variability results a need for these generators to operate in a range of different modes, collectively referred to as “flexible operations.” This study is designed to inform power companies, researchers, and policymakers of the scope and trends in increasing levels of flexible operations as well as reliability challenges and impacts for dispatchable assets. Background Because there is rarely a direct monetization of the value of operational flexibility, the decision to provide such flexibility is typically dependent on unit- and region-specific decisions made by asset owners. It is very likely that much greater and more widespread flexible operations capabilities will be needed due to increased variability in demand seen by grid-connected generators, uncertainty regarding investment in new units to provide adequate operational flexibility, and the retirement of older, uncontrolled sub-critical pulverized coal units. Objective To enhance understanding of the technical challenges and operational impacts associated with dispatchable assets needed to increase operational flexibility and support variable demand. Approach The study approach consists of three elements: a literature review of relevant prior studies, analysis of detailed scenarios for evolution of the future fleet over the next 35 years, and engineering assessment of the degree and scope of technical challenges associated with transformation to the future fleet. The study approach integrated two key elements rarely brought together in a single analysis—1) long-term capacity planning, which enables modeling of unit retirements and new asset investments, and 2) unit commitment analysis, which permits examination of hourly unit dispatch while considering operational limitations relevant to flexible operations capabilities.

  10. Coal-water fuel supply and boiler-conversion study. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-10-01

    This report presents the results of a study on the feasibility of converting an oil-fired boiler at Occidental Chemical Company's Niagara Falls, New York facility to coal/water slurry (CWS) fuel. The study evaluates technical and economic issues concerning a decision to convert the boiler. Conversion costs are weighted against CWS fuel-cost savings compared to oil and an acceptable market price for the CWS fuel is developed that provides a specified rate of return for the conversion. The report uses the target CWS fuel price in developing a design for a CWS fuel-production plant that could manufacture CWS at that price. In order to achieve the target price the CWS fuel-product plant must be sized to achieve economies of scale and plant output would be far in excess of the converted-boiler's demand. As a result of CWS fuel marketing study was undertaken to define additional boiler-conversion candidates in the western New York area. Without this additional CWS fuel demand, CWS cannot be produced at the target fuel price.

  11. Fireside Corrosion in Oxy-fuel Combustion of Coal

    SciTech Connect (OSTI)

    Holcomb, Gordon R; Tylczak, Joseph; Meier, Gerald H; Lutz, Bradley; Jung, Keeyoung; Mu, Nan; Yanar, Nazik M; Pettit, Frederick S; Zhu, Jingxi; Wise, Adam; Laughlin, David E.; Sridhar, Seetharaman

    2013-11-25

    Oxy-fuel combustion is burning a fuel in oxygen rather than air for ease of capture of CO2 from for reuse or sequestration. Corrosion issues associated with the environment change (replacement of much of the N2 with CO2 and higher sulfur levels) from air- to oxy-firing were examined. Alloys studied included model FeCr alloys and commercial ferritic steels, austenitic steels, and nickel base superalloys. The corrosion behavior is described in terms of corrosion rates, scale morphologies, and scale/ash interactions for the different environmental conditions. Evidence was found for a hreshold for severe attack between 10-4 and 10-3 atm of SO3 at 700C.

  12. Systems simulation of cotton gin waste as a supplemental fuel in a coal powered generating plant

    SciTech Connect (OSTI)

    Parnell, C.B.; Grubaugh, E.K.; Johnston, M.T.; Ladd, K.L.

    1981-01-01

    A systems simulation model of gin trash use at a Lamb County, Texas, power plant was developed. The model is being used to study gin trash supply, both quantity and transportation, fixed and variable cost, and economic benefit/costs of gin trash utilization. Preliminary results indicate the positive feasibility of using gin trash as a supplemental fuel in a coal fired power plant. (MHR)

  13. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation�s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  14. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  15. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    1995-12-31

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  16. Methodology for comparing the health effects of electricity generation from uranium and coal fuels

    SciTech Connect (OSTI)

    Rhyne, W.R.; El-Bassioni, A.A.

    1981-12-08

    A methodology was developed for comparing the health risks of electricity generation from uranium and coal fuels. The health effects attributable to the construction, operation, and decommissioning of each facility in the two fuel cycle were considered. The methodology is based on defining (1) requirement variables for the materials, energy, etc., (2) effluent variables associated with the requirement variables as well as with the fuel cycle facility operation, and (3) health impact variables for effluents and accidents. The materials, energy, etc., required for construction, operation, and decommissioning of each fuel cycle facility are defined as primary variables. The materials, energy, etc., needed to produce the primary variable are defined as secondary requirement variables. Each requirement variable (primary, secondary, etc.) has associated effluent variables and health impact variables. A diverging chain or tree is formed for each primary variable. Fortunately, most elements reoccur frequently to reduce the level of analysis complexity. 6 references, 11 figures, 6 tables.

  17. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G.; Sandstrom, William A.; Tarman, Paul B.

    1982-01-01

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  18. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    SciTech Connect (OSTI)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  19. Coal-fueled diesel technology development Emissions Control

    SciTech Connect (OSTI)

    Van Kleunen, W.; Kaldor, S.; Gal, E.; Mengel, M.; Arnold, M.

    1994-01-01

    GEESI Emissions Control program activity ranged from control concept testing of 10 CFM slipstream from a CWS fuel single cylinder research diesel engine to the design, installation, and operation of a full-size Emissions Control system for a full-size CWS fuel diesel engine designed for locomotive operation.Early 10 CFM slipstream testing program activity was performed to determine Emissions Characteristics and to evaluate Emissions Control concepts such a Barrier filtration, Granular bed filtration, and Cyclone particulate collection for reduction of particulate and gaseous emissions. Use of sorbent injection into the engine exhaust gas upstream of the barrier filter or use of sorbent media in the granular bed filter were found to provide reduction of exhaust gas SO{sub 2} and NO{sub x} in addition to collection of ash particulate. Emergence of the use of barrier filtration as a most practical Emissions Control concept disclosed a need to improve cleanability of the filter media in order to avoid reduction of turbocharger performance by excessive barrier filter pressure drop. The next progression of program activity, after the slipstream feasibility state, was 500 CFM cold flow testing of control system concepts. The successful completion of 500 CFM cold flow testing of the Envelope Filter led to a subsequent progression to a similar configuration Envelope Filter designed to operate at 500 CFM hot gas flow from the CWS fuel research diesel engine in the GETS engine test laboratory. This Envelope Filter included the design aspect proven by cold flow testing as well as optimization of the selection of the installed filter media.

  20. Fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Topical report February 1994--February 1995

    SciTech Connect (OSTI)

    1995-02-01

    Experiments were made on use of H and CH plasmas for converting waste materials and heavy oils to H-rich transportation fuels. Batch and continuous experiments were conducted with an industrial microwave generator and a commercial microwave oven. A continuously circulating reactor was constructed for conducting experiments on flowing oils. Experiments on decomposition of scrap tires showed that microwave plasmas can be used to decompose scrap tires into potentially useful liquid products. In a batch experiment using a commercial microwave oven, about 20% of the tire was converted to liquid products in about 9 minutes. Methane was decomposed in a microwave plasma to yield a liquid products composed of various compound types; GC/MS analyses identified unsaturated compounds including benzene, toluene, ethyl benzene, methyl and ethyl naphthalene, small amounts of larger aromatic rings, and olefinic compounds. Experiments on a crude oil in a continuously flowing reactor showed that distillate materials are produced using H and CH plasmas. Also, the recycle oils had an overall carbon aromaticity lower than that of starting feed material, indicating that some hydrogenation and methanation had taken place in the recycle oils.

  1. ABB`s investigations into air toxic emissions from fossil fuel and MSW combustion

    SciTech Connect (OSTI)

    Wesnor, J.D.

    1994-12-31

    Since passage of the Clean Air Act, Asea Brown Boveri (ABB) has been actively developing a knowledge base on the Title 3 hazardous air pollutants, more commonly called air toxics. As ABB is a multinational company, US operating companies are able to call upon work performed by European counterparts, who have faced similar legislation several years ago. In addition to the design experience and database acquired in Europe, ABB Inc. has been pursuing several other avenues to expand its air toxics knowledge. ABB Combustion Engineering (ABB CE) is presently studying the formation of organic pollutants within the combustion furnace and partitioning of trace metals among the furnace outlet streams. ABB Environmental Systems (ABBES) has reviewed available and near-term control technologies and methods. Also, both ABB CE and ABBES have conducted source sampling and analysis at commercial installations for hazardous air pollutants to determine the emission rates and removal performance of various types of equipment. Several different plants hosted these activities, allowing for variation in fuel type and composition, boiler configuration, and air pollution control equipment. This paper discusses the results of these investigations.

  2. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect (OSTI)

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  3. High efficiency, quasi-instantaneous steam expansion device utilizing fossil or nuclear fuel as the heat source

    SciTech Connect (OSTI)

    Claudio Filippone, Ph.D.

    1999-06-01

    Thermal-hydraulic analysis of a specially designed steam expansion device (heat cavity) was performed to prove the feasibility of steam expansions at elevated rates for power generation with higher efficiency. The steam expansion process inside the heat cavity greatly depends on the gap within which the steam expands and accelerates. This system can be seen as a miniaturized boiler integrated inside the expander where steam (or the proper fluid) is generated almost instantaneously prior to its expansion in the work-producing unit. Relatively cold water is pulsed inside the heat cavity, where the heat transferred causes the water to flash to steam, thereby increasing its specific volume by a large factor. The gap inside the heat cavity forms a special nozzle-shaped system in which the fluid expands rapidly, accelerating toward the system outlet. The expansion phenomenon is the cause of ever-increasing fluid speed inside the cavity system, eliminating the need for moving parts (pumps, valves, etc.). In fact, the subsequent velocity induced by the sudden fluid expansion causes turbulent conditions, forcing accelerating Reynolds and Nusselt numbers which, in turn, increase the convective heat transfer coefficient. When the combustion of fossil fuels constitutes the heat source, the heat cavity concept can be applied directly inside the stator of conventional turbines, thereby greatly increasing the overall system efficiency.

  4. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  5. Coal within a revised energy perspective

    SciTech Connect (OSTI)

    Darmstadter, J.

    2006-07-15

    The author considers the use of coal within a revised energy perspective, focusing on the factors that will drive which fuels are used to generate electricity going forward. He looks at the world markets for fossil fuels and the difficulties of predicting oil and natural gas supply and prices, as demonstrated by the variability in projections from one year to another in the EIA's Annual Energy Outlook. 4 refs., 1 tab.

  6. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal and Coal-Biomass to Liquids FAQs faq-header-big.jpg BASICS Q: How are gasoline and diesel fuel made from coal? A: Gasoline and diesel fuels can be produced from coal in two ...

  7. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  8. ESCOE fossil energy program, November 15, 1976-August 15, 1980. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-08-15

    The Engineering Societies Commission on Energy, Inc. has carried out engineering tasks for DOE as follows: recruited and developed a professional staff for engineering studies; evaluated some 17 processes for converting coal to gaseous or liquid fuels (in the process identifying and perfecting basic cost estimate data and methods for consistency and in conformance to cost guidelines); developed a simple, yet effective, ESCOE/DOE information system; evaluated applicable non-fossil research studies; assessed the adequacy of available materials for coal conversion processes; compared five coal liquefaction processes; examined problems in retrofitting oil- and gas-burning plants to burn coal; prepared a R and D plan and development schedule for fuel cells; supported the ASPEN computerized design work; developed consistent cost estimating methods; reviewed coal mining research programs; assisted in planning basic engineering research programs; examined oil recovery by mining; and reviewed alternative technologies. (LTN)

  9. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  10. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    SciTech Connect (OSTI)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was found that the ground pellets could be used as an effective NOx control agent for pulverized-coal-fired systems. NOx emissions reductions up to 63% were recorded, when using AFP as a NOx control agent. In addition to performance benefits, economic analyses showed the good economic benefits of AFP fuel. Using equipment manufacturer inputs, and reasonable values for biomass, biosolids and coal fines costs, it was determined that an AFP plant would have good profitability. For cases where biosolids contents were in the range of 50%, the after tax Internal Rates of Return were in the range of 40% to 50%. These are very attractive returns. Besides the baseline analysis for the various AFP formulations tested at pilot scale, sensitivity analysis showed the impact of important parameters on return. From results, it was clear that returns are excellent for a range of parameters that could be expected in practice. Importantly, these good returns are achieved even without incentives related to the emissions control benefits of biomass.

  11. Fossil Energy Word Find | Department of Energy

    Energy Savers [EERE]

    Word Find Fossil Energy Word Find Word Find (inlcuidng answer key) PDF icon Fossil Energy Word Search More Documents & Publications Fossil Energy Crossword Puzzle Coal Study Guide for Elementary School Guide to Low-Emission Boiler and Combustion Equipment Selection

  12. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  13. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  14. Coal to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in

  15. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

    2005-04-29

    The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

  16. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  17. DOE's Coal Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July 25, 2013 - 10:32am Addthis Statement of Christopher Smith, Acting Assistant Secretary for Fossil Energy before the House Committee on Science, Space and Technology Subcommittee on Energy Thank you Chairman Lummis, Ranking Member Swalwell, and members of the Subcommittee. I appreciate the opportunity to discuss the Department of Energy's (DOE) coal research and development (R&D) activities. Coal fuels approximately 40 percent of our domestic electricity production. As the Energy

  18. Repowering with clean coal technologies

    SciTech Connect (OSTI)

    Freier, M.D.; Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N.

    1996-02-01

    Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

  19. Combustion characterization of coal/refuse derived fuels using thermogravimetric-fourier transform infrared-mass spectrometry

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Lu, Huagang; Hyatt, J.

    1995-12-31

    The fundamental thermal behavior of five materials (Illinois coal No. 6, Kentucky coal No. 9, polyvinyl chloride, cellulose, newspaper) has been investigated using the TGA/FTIR/MS system under the condition of combustion. The system was used to identify molecular chlorine, along with HCI, CO, CO{sub 2}, H{sub 2}O and various hydrocarbons in the gaseous products of the combustion of PVC resin in air. This is a significant finding that will lead us to examine this combustion step further to look for the formation of chlorinated organic compounds during co-firing of coal with refuse derived fuels.

  20. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  1. Hawaii energy strategy project 2: Fossil energy review. Task 2: Fossil energy in Hawaii

    SciTech Connect (OSTI)

    Breazeale, K.; Yamaguchi, N.D.; Keeville, H.

    1993-12-01

    In Task 2, the authors establish a baseline for evaluating energy use in Hawaii, and examine key energy and economic indicators. They provide a detailed look at fossil energy imports by type, current and possible sources of oil, gas and coal, quality considerations, and processing/transformation. They present time series data on petroleum product consumption by end-use sector, though they caution the reader that the data is imperfect. They discuss fuel substitutability to identify those end-use categories that are most easily switched to other fuels. They then define and analyze sequential scenarios of fuel substitution in Hawaii and their impacts on patterns of demand. They also discuss energy security--what it means to Hawaii, what it means to neighboring economies, whether it is possible to achieve energy security. 95 figs., 48 tabs.

  2. Fossil resource and energy security dynamics in conventional and carbon-constrained worlds

    SciTech Connect (OSTI)

    McCollum, David; Bauer, Nico; Calvin, Katherine V.; Kitous, Alban; Riahi, Keywan

    2014-04-01

    Fossil resource endowments and the future development of fossil fuel prices are important factors that will critically influence the nature and direction of the global energy system. In this paper we analyze a multi-model ensemble of long-term energy and emissions scenarios that were developed within the framework of the EMF27 integrated assessment model inter-comparison exercise. The diverse nature of these models highlights large uncertainties in the likely development of fossil resource (coal, oil, and natural gas) consumption, trade, and prices over the course of the twenty-first century and under different climate policy frameworks. We explore and explain some of the differences across scenarios and models and compare the scenario results with fossil resource estimates from the literature. A robust finding across the suite of IAMs is that the cumulative fossil fuel consumption foreseen by the models is well within the bounds of estimated recoverable reserves and resources. Hence, fossil resource constraints are, in and of themselves, unlikely to limit future GHG emissions. Our analysis also shows that climate mitigation policies could lead to a major reallocation of financial flows between regions, in terms of expenditures on fossil fuels and carbon, and can help to alleviate near-term energy security concerns via the reductions in oil imports and increases in energy system diversity they will help to motivate.

  3. Coal-fueled high-speed diesel engine development. Final report, September 28, 1990--November 30, 1993

    SciTech Connect (OSTI)

    Kakwani, R.M.; Winsor, R.E.; Ryan, T.W. III; Schwalb, J.A.; Wahiduzzaman, S.; Wilson, R.P. Jr.

    1993-09-01

    The goal of this program was to study the feasibility of operating a Detroit Diesel Series 149 engine at high speeds using a Coal-Water-Slurry (CWS) fuel. The CWS-fueled 149 engine is proposed for the mine-haul off-highway truck and work boat marine markets. Economic analysis studies indicate that, for these markets, the use of CWS fuel could have sufficient operating cost savings, depending upon the future diesel fuel price, emission control system capital and operating costs, and maintenance and overhaul costs. A major portion of the maintenance costs is expected to be due to lower life and higher cost of the CWS injectors. Injection and combustion systems were specially designed for CWS, and were installed in one cylinder of a Detroit Diesel 8V-149TI engine for testing. The objective was to achieve engine operation for sustained periods at speeds up to 1,900 rpm with reasonable fuel economy and coal burnout rate. A computer simulation predicted autoignition of coal fuel at 1,900 rpm would require an average droplet size of 18 microns and 19:1 compression ratio, so the injection system, and pistons were designed accordingly. The injection system was capable of supplying the required volume of CWS/injection with a duration of approximately 25 crank angle degrees and peak pressures on the order of 100 mpa. In addition to the high compression ratio, the combustion system also utilized hot residual gases in the cylinder, warm inlet air admission and ceramic insulated engine components to enhance combustion. Autoignition of CWS fuel was achieved at 1900 rpm, at loads ranging from 20--80 percent of the rated load of diesel-fuel powered cylinders. Limited emissions data indicates coal burnout rates in excess of 99 percent. NO{sub x} levels were significantly lower, while unburned hydrocarbon levels were higher for the CWS fueled cylinder than for corresponding diesel-fuel powered cylinders.

  4. Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

    SciTech Connect (OSTI)

    Beverly L. Smith; Thomas J. Bruno

    2007-09-15

    We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of each distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.

  5. Method of producing a colloidal fuel from coal and a heavy petroleum fraction. [partial liquefaction of coal in slurry, filtration and gasification of residue

    DOE Patents [OSTI]

    Longanbach, J.R.

    1981-11-13

    A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300 to 550/sup 0/C. The slurry is heated to a temperature of 400 to 500/sup 0/C for a limited time of only about 1 to 5 minutes before cooling to a temperature of less than 300/sup 0/C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

  6. Investments in fossil energy technology: How the government's fossil energy R&D program has made a difference

    SciTech Connect (OSTI)

    None, None

    1997-03-01

    America has the technological capacity to change its energy future. There is no reason, for example, why our nation must continue following a path of rising oil imports when billions of barrels of crude oil remain in domestic oil fields. There is no reason why we cannot continue to use our abundant supplies of high-value, low-cost coal when we have the scientific know-how to remove virtually all of its pollutants and reduce greenhouse gas emissions. There is no reason why we cannot turn increasingly to clean-burning natural gas and tap the huge supplies we know exist within our borders. We remain a nation rich in the fuels that have powered economic growth. Today 85 percent of the energy we use to heat our homes and businesses, generate our electricity, and fuel our vehicles comes from coal, petroleum and natural gas. As we move toward a new century, the contributions of these fuels will grow. By 2015, the United States is likely to require nearly 20 percent more energy than it uses today, and fossil fuels are projected to supply almost 88 percent of the energy Americans will consume. We have the scientific know-how to continue using our fossil fuel wealth without fear of environmental damage or skyrocketing costs. The key is technology - developing cutting edge concepts that are beyond the private sector's current capabilities. Some of the most important innovations in America's energy industry are the results of investments in the Federal government's fossil energy research and development programs. Today, our air and water are cleaner, our economy is stronger, and our industries are more competitive in the global market because these programs have produced results. This booklet summarizes many of these achievements. It is not a comprehensive list by any means. Still, it provides solid evidence that the taxpayers' investment in government fossil energy research has paid real and measurable dividends.

  7. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  8. Coal-fueled diesel system for stationary power applications -- Technology development. Final report, March 1988--June 1994

    SciTech Connect (OSTI)

    1995-10-01

    Morgantown Energy Technology Center, Cooper-Bessemer and Arthur D. Little have developed the technology to enable coal-water slurry to be utilized in large-bore, medium-speed diesel engines. The target application is modular power generation in the 10 to 100 MW size, with each plant using between two and eight engines. Such systems are expected to be economically attractive in the non-utility generation market after 2000, when oil and natural gas prices are expected to escalate rapidly compared to the price of coal. During this development program, over 1,000 hours of prototype engine operation have been achieved on coal-water slurry (CWS), including over 100 hours operation of a six-cylinder, 1.8 MW engine with an integrated emissions control system. Arthur D. Little, Inc., managed the coal-fueled diesel development, with Cooper-Bessemer as the principal subcontractor responsible for the engine design and testing. Several key technical advances which enable the viability of the coal-fueled diesel engine were made under this program. Principal among them are the development and demonstration of (1) durable injection nozzles; (2) an integrated emissions control system; ad (3) low-cost clean coal slurry formulations optimized for the engine. Significant advances in all subsystem designs were made to develop the full-scale Cooper-Bessemer coal engine components in preparation for a 100-hour proof-of-concept test of an integrated system, including emissions controls. The Clean Coal Diesel power plant of the future will provide a cost-competitive, low-emissions, modular, coal-based power generation option to the non-utility generation, small utility, independent power producer, and cogeneration markets. Combined cycle efficiencies will be approximately 48% (lower heating value basis) and installed cost will be approximately $1,300/kW (1992 dollars).

  9. Exergy & Economic Analysis of Catalytic Coal Gasifiers Coupled with Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Siefert, Nicholas; Litster, Shawn

    2012-01-01

    The National Energy Technology Laboratory (NETL) has undertaken a review of coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide. One way to achieve an overall system efficiency of greater than 60% is in a power plant in which a catalytic coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis and this is sent to a SOFC, with CO{sub 2} capture occurring either before or after the SOFC. Integration of a catalytic gasifier with a SOFC, as opposed to a conventional entrained flow gasifier, is improved due to (a) decreased exergy destruction inside a catalytic, steam-coal gasifier producing a high-methane content syngas, and (b) decreased exergy destruction in the SOFC due to the ability to operate at lower air stoichiometric flow ratios. For example, thermal management of the SOFC is greatly improved due to the steam-methane reforming in the anode of the fuel cell. This paper has two main goals. First, we converted the levelized cost of electricity (LCOE) estimates of various research groups into an average internal rate of return on investment (IRR) in order to make comparisons between their results, and to underscore the increased rate of return on investment for advanced integrated gasification fuel cell systems with carbon capture & sequestration (IGFC-CCS) compared with conventional integrated gasification combined cycle (IGCC-CCS) systems and pulverized coal combustion (PCC-CCS) systems. Using capital, labor, and fuel costs from previous researchers and using an average price of baseload electricity generation of $61.50 / MW-hr, we calculated inflation-adjusted IRR values of up to 13%/yr for catalytic gasification with pressurized fuel cell and carbon dioxide capture and storage (CCS), whereas we calculate an IRR of ∼4%/yr and ∼2%/yr for new, conventional IGCC-CCS and PCC-CCS, respectively. If the carbon dioxide is used for enhanced oil recovery rather than for saline aquifer storage, then the IRR values improve to 16%/yr, 10%/yr, and 8%/yr, respectively. For comparison, the IRR of a new conventional IGCC or PCC power plant without CO{sub 2} capture are estimated to be 11%/yr and 15.0%/yr, respectively. Second, we conducted an exergy analysis of two different configurations in which syngas from a catalytic gasifier fuels a SOFC. In the first case, the CO{sub 2} is captured before the SOFC, and the anode tail gas is sent back to the catalytic gasifier. In the second case, the anode tail gas is oxy-combusted using oxygen ion ceramic membranes and then CO{sub 2} is captured for sequestration. In both cases, we find that the system efficiency is greater than 60%. These values compare well with previous system analysis. In future work, we plan to calculate the IRR of these two cases and compare with previous economic analyses conducted at NETL.

  10. Fossil Energy RSS Feeds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy RSS Feeds Fossil Energy RSS Feeds RSS, sometimes known as Really Simple Syndication, is a popular means of sharing content (such as news headlines) without requiring readers to constantly visit a Web site to see what's new. RSS feeds contain headlines and hyperlinks to longer articles or Web pages. RSS feeds from the Office of Fossil Energy provide updates of specific interest to the fossil fuel community. Fossil Energy RSS feeds are free of charge. RSS content can be read using

  11. Publications of the Oak Ridge National Laboratory Fossil Energy Program and the AR and TD Materials Program, April 1, 1995--March 31, 1997

    SciTech Connect (OSTI)

    Carlson, P.T.

    1997-07-01

    The Oak Ridge National Laboratory (ORNL) Fossil Energy Program, organized in FY 1974 as the Coal Technology Program, involves research and development activities that cover a wide range of fossil energy technologies. The principal focus of the Laboratory`s fossil energy activities relates to coal, with current emphasis on materials research and development; environmental, health, and safety research; and the bioprocessing of coal to produce liquid or gaseous fuels. This bibliography covers the period of April 1, 1995, through March 31, 1997, and is a supplement to the earlier bibliographies in this series. The publications listed in this document have been limited to topical reports, open literature publications, full-length papers in published proceedings of conferences, and books and book articles. A major activity of the Fossil Energy Program is the Advanced Research and Technology Development (AR and TD) Materials Program. The objective of the AR and TD Materials Program is to conduct research and development on materials for fossil energy applications, with a focus on the longer-term needs for materials with general applicability to the various fossil fuel technologies. Beginning with this report, publications of the AR and TD Materials Program, previously compiled in separate reports, and publications from non-materials activities of the Fossil Energy Program will be combined in a single report.

  12. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 6, January--March 1996

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1996-02-29

    The objectives for this quarter of study on the co-firing of high sulfur coals with refuse derived fuels were two-fold. First, the effects of different experimental parameters such as temperature, flow rates and reaction times on the formation of chlorinated organic compounds were studied using the tubular furnace as a reactor followed by GC/MS analysis. Secondly, the effect of fuel/air ratio on the flue gas composition and combustion efficiency were studied with the AFBC system.

  13. Fossil Energy Today - First Quarter, 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NETL's High Speed Imaging System Welcome to Fossil Energy Today Carbon Sequestration Atlas Coal-Fired Project of the Year National Risk Assessment Program Storage Retention Goals ...

  14. Utilization of fuel cells to beneficially use coal mine methane. Final report

    SciTech Connect (OSTI)

    Brown, J.T.; O`Brien, D.G.; Miller, A.R.; Atkins, R.; Sanders, M.

    1996-03-01

    DOE has been given the responsibility to encourage industry to recover and use methane that is currently being released to the atmosphere. At this time the only method being employed at the Left Fork Mine to remove methane is the mine ventilation system. The methane content was measured at one one-hundredth of a percent. To prevent this methane from being vented to the atmosphere, degasification wells are proposed. To use the coal mine methane, it is proposed to use phosphoric-acid fuel cells to convert methane to electric power. These fuel cells contain (1) a steam reformer to convert the methane to hydrogen (and carbon dioxide), (2) the fuel cell stack, and (3) a power conditioner that provides 200 kW of 60 Hz alternating current output. The environmental impacts and benefits of using this technology ware summarized in the report. The study indicates the methane emission reduction that could be achieved on a national and Global level. The important point being that this technology is economically viable as is demonstrated in the report.

  15. Energy Department’s Fossil Energy Chief to Tour Western Michigan University’s Clean Coal Research Facilities, Host Business Roundtable

    Broader source: Energy.gov [DOE]

    WASHINGTON  – Tomorrow, Wednesday, June 27, 2012, Assistant Energy Secretary for Fossil Energy Charles McConnell will join Western Michigan University President John M. Dunn and Core Energy CEO Bob...

  16. Keystone coal industry manual

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The 1994 Keystone Coal Industry Manual is presented. Keystone has served as the one industry reference authority for the many diverse organizations concerned with the supply and utilization of coal in the USA and Canada. Through the continuing efforts of coal producers, buyers, users, sellers, and equipment designers and manufacturers, the coal industry supplies an abundant and economical fuel that is indispensable in meeting the expanding energy needs of North America. The manual is divided into the following sections: coal sales companies, coal export, transportation of coal, consumer directories, coal associations and groups, consulting and financial firms, buyers guide, industry statistics and ownership, coal preparation, coal mine directory, and coal seams.

  17. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  18. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  19. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  20. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  1. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C.; Paulson, Leland E.

    1995-01-01

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  2. Fossil-energy program. Quarterly progress report for June 30, 1983

    SciTech Connect (OSTI)

    McNeese, L.E.

    1983-08-01

    This quarterly report covers the progress made during the period March 31 through June 30 for the Oak Ridge National Laboratory research and development projects that are carried out in support of the increased utilization of coal and other fossil fuels as sources of clean energy. These projects are supported by various parts of DOE including Fossil Energy, Basic Energy Sciences, Office of Health and Environmental Research, Office of Environmental Compliance and Overview, the Electric Power Research Institute, and by the Tennessee Valley Authority and the EPA Office of Research and Development through inter-agency agreement with DOE.

  3. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nations CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

  4. Hawaii Energy Strategy Project 2: Fossil Energy Review. Task IV. Scenario development and analysis

    SciTech Connect (OSTI)

    Yamaguchi, N.D.; Breazeale, K.

    1993-12-01

    The Hawaii Energy Strategy (HES) Program is a seven-project effort led by the State of Hawaii Department of Business, Economic Development & Tourism (DBEDT) to investigate a wide spectrum of Hawaii energy issues. The East-West Center`s Program on Resources: Energy and Minerals, has been assigned HES Project 2, Fossil Energy Review, which focuses on fossil energy use in Hawaii and the greater regional and global markets. HES Project 2 has four parts: Task I (World and Regional Fossil Energy Dynamics) covers petroleum, natural gas, and coal in global and regional contexts, along with a discussion of energy and the environment. Task II (Fossil Energy in Hawaii) focuses more closely on fossil energy use in Hawaii: current utilization and trends, the structure of imports, possible future sources of supply, fuel substitutability, and energy security. Task III`s emphasis is Greenfield Options; that is, fossil energy sources not yet used in Hawaii. This task is divided into two sections: first, an in-depth {open_quotes}Assessment of Coal Technology Options and Implications for the State of Hawaii,{close_quotes} along with a spreadsheet analysis model, which was subcontracted to the Environmental Assessment and Information Sciences Division of Argonne National Laboratory; and second, a chapter on liquefied natural gas (LNG) in the Asia-Pacific market and the issues surrounding possible introduction of LNG into the Hawaii market.

  5. Production of a pellet fuel from Illinois coal mines. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.; Ho, Ken

    1995-12-31

    The goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, we will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach.

  6. Addressing the Need for Alternative Transportation Fuels: The Joint

    Office of Scientific and Technical Information (OSTI)

    BioEnergy Institute (Journal Article) | SciTech Connect Addressing the Need for Alternative Transportation Fuels: The Joint BioEnergy Institute Citation Details In-Document Search Title: Addressing the Need for Alternative Transportation Fuels: The Joint BioEnergy Institute Today, carbon-rich fossil fuels, primarily oil, coal, and natural gas, provide 85% of the energy consumed in the U.S. As world demand increases, oil reserves may become rapidly depleted. Fossil fuel use increases CO{sub

  7. On-Site Coal Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Research Advanced Energy Systems Advanced Energy Systems research conceives, analyzes, and develops energy technologies that can minimize the environmental impact of fossil ...

  8. Fossil Energy Today - Second Quarter, 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Fossil Energy Today - Second Quarter, 2011 Topics In This Issue... Office Reorganization McConnell Joins FE Staff Coal Cleaning Commercial Success Sonar Survey Program Heating Oil Reserve Converts Stock Marcellus Shale Water Management FE Spotlight Upcoming Events PDF icon Fossil Energy Today - Issue No. 2, Second Quarter, 2011 More Documents & Publications Fossil Energy Today - First Quarter, 2013 Fossil Energy Today - Third Quarter, 2011 Fossil Energy Today - Second Quarter, 2012

  9. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  10. Coal Study Guide - High School | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    High School More Documents & Publications Coal Study Guide - Middle School Coal Study Guide for Elementary School Fossil Energy Today - First Quarter, 2011

  11. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  12. Co-firing High Sulfur Coal with Refuse Derived Fuels. Technical Progress Report {number_sign}11

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, John T.; Lloyd, William G.

    1997-05-31

    The objective of this quarter of study was to prepare fuel pellets containing PVC, newspaper and plastics to be co-fired with coal in the AFBC combustor. The Western Kentucky University atmospheric fluidized bed combustion system requires the fuel to fall from a bunker into a lock-hopper, and from there into a mixing box where the fuel is auger-fed under pressure into the bottom of the fluidized bed. The fuel must flow freely out of the bunker and through the lock- hopper for proper feeding into the combustor. In order for the fuel to continuously fall through these units and into the mixing box during combustion, the density of the fuel and the size of the particles must meet certain requirements. The particles must be no larger than 3/8 inches in diameter and must have a density approaching that of coal. Loose materials such as sawdust, shredded paper products and most shredded plastics do not feed properly in the WKU AFBC system. Bridging and blockage of feed chutes result, even with constant vibration of parts of the feed mechanism. It is not possible to run the AFBC system powered solely by these loose materials.

  13. Production of a pellet fuel from Illinois coal fines. Technical report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.

    1995-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. For this effort, we will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. Previously it has been decided that corn starch would be used as binder and a roller-and-die mill would be used for pellet manufacture. A quality starch binder has been identified and tested. To potentially lower binder costs, a starch that costs about 50% of the high quality starch was tested. Results indicate that the lower cost starch will not lower binder cost because more is required to produce a comparable quality pellet. Also, a petroleum in water emulsion was evaluated as a potential binder. The compound seemed to have adhesive properties but was found to be a poor binder. Arrangements have been made to collect a waste slurry from the mine previously described.

  14. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Coal-Biomass to Liquids Turning coal into liquid fuels like gasoline, diesel and jet fuel, with biomass to reduce carbon dioxide emissions, is the main goal of the Coal and Coal-Biomass to Liquids program. The program also aims to reduce the cost of these low-emission fuels, and will take advantage of carbon capture and sequestration technologies to further reduce greenhouse gas emissions. Other Coal and Coal-Biomass to Liquids (C&CBTL) Program Activities: The C&CBTL Program

  15. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  16. Determination of the Average Aromatic Cluster Size of Fossil Fuels by Solid-State NMR at High Magnetic Field

    SciTech Connect (OSTI)

    Mao, Kanmi; Kennedy, Gordon J.; Althaus, Stacey M.; Pruski, Marek

    2013-01-07

    We show that the average aromatic cluster size in complex carbonaceous materials can be accurately determined using fast magic-angle spinning (MAS) NMR at a high magnetic field. To accurately quantify the nonprotonated aromatic carbon, we edited the 13C spectra using the recently reported MAS-synchronized spinecho, which alleviated the problem of rotational recoupling of 1H-13C dipolar interactions associated with traditional dipolar dephasing experiments. The dependability of this approach was demonstrated on selected Argonne Premium coal standards, for which full sets of basic structural parameters were determined with high accuracy.

  17. Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  18. Fossil-fuel power plants: Computer systems for power plant control, maintenance, and operation. October 1976-December 1989 (A Bibliography from the COMPENDEX data base). Report for October 1976-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-02-01

    This bibliography contains citations concerning fossil-fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 240 citations fully indexed and including a title list.)

  19. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  20. Process for clean-burning fuel from low-rank coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Sethi, Vijay (Laramie, WY); Brecher, Lee E. (Laramie, WY)

    1994-01-01

    A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

  1. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  2. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  3. Blackout: coal, climate and the last energy crisis

    SciTech Connect (OSTI)

    Heinberg, R. [Post Carbon Institute in California, CA (United States)

    2009-07-15

    Coal fuels more than 30 per cent of UK electricity production, and about 50 per cent in the US, providing a significant portion of total energy output. China and India's recent ferocious economic growth has been based almost entirely on coal-generated electricity. Coal currently looks like a solution to many of our fast-growing energy problems. However, while coal advocates are urging us full steam ahead, the increasing reliance on this dirtiest of all fossil fuels has crucial implications for energy policy, pollution levels, the global climate, world economy and geopolitics. Drawbacks to a coal-based energy strategy include: Scarcity - new studies suggest that the peak of world coal production may actually be less than two decades away; Cost - the quality of produced coal is declining, while the expense of transportation is rising, leading to spiralling costs and increasing shortages; and, Climate impacts - our ability to deal with the historic challenge of climate change may hinge on reducing coal consumption in future years.

  4. "An Economic Process for Coal Liquefaction to Liquid Fuels" SBIR Phase II -- Final Scientific/Technical Report

    SciTech Connect (OSTI)

    Ganguli, Partha Sarathi

    2009-02-19

    The current commercial processes for direct coal liquefaction utilize expensive backmix-flow reactor system and conventional catalysts resulting in incomplete and retrogressive reactions that produce low distillate liquid yield and high gas yield, with high hydrogen consumption. The new process we have developed, which uses a less expensive reactor system and highly active special catalysts, resulted in high distillate liquid yield, low gas yield and low hydrogen consumption. The new reactor system using the special catalyst can be operated smoothly for direct catalytic coal liquefaction. Due to high hydrogenation and hydrocracking activities of the special catalysts, moderate temperatures and high residence time in each stage of the reactor system resulted in high distillate yield in the C{sub 4}-650{degrees}F range with no 650{degrees}F{sup +} product formed except for the remaining unconverted coal residue. The C{sub 4}-650{degrees}F distillate is more valuable than the light petroleum crude. Since there is no 650{degrees}F{sup +} liquid product, simple reforming and hydrotreating of the C{sub 4}-650{degrees}F product will produce the commercial grade light liquid fuels. There is no need for further refinement using catalytic cracking process that is currently used in petroleum refining. The special catalysts prepared and used in the experimental runs had surface area between 40-155 m{sup 2}/gm. The liquid distillate yield in the new process is >20 w% higher than that in the current commercial process. Coal conversion in the experimental runs was moderate, in the range of 88 - 94 w% maf-coal. Though coal conversion can be increased by adjustment in operating conditions, the purpose of limiting coal conversion to moderate amounts in the process was to use the remaining unconverted coal for hydrogen production by steam reforming. Hydrogen consumption was in the range of 4.0 - 6.0 w% maf-coal. A preliminary economic analysis of the new coal liquefaction process was carried out by comparing the design and costs of the current commercial plant of the Shenhua Corporation in Erdos, Inner Mongolia. The cost of producing synthetic crude oil from coal in the current commercial process was estimated to be $50.5 per barrel compared to the estimated cost of $41.7 per barrel in the new process. As mentioned earlier, the light distillate product in the new process is of higher quality and value than the C{sub 4}-975{degrees}F product in the current commercial process adopted by the Shenhua Corporation. In sum, the new coal liquefaction process is superior and less capital intensive to current commercial process, and has a high potential for commercialization.

  5. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas Fletcher; Alan Sayre

    2003-01-01

    The goal of this project is to carry out the necessary experiments and analyses to extend leading submodels of coal transformations to the new conditions anticipated in next-generation energy technologies. During the first project quarter, a technical kick-off meeting was held on the Brown campus involving PIs from Brown (Hurt, Calo), BYU (Fletcher), and B&W (Sayre, Burge). Following this first meeting the current version of CBK (Version 8) was transferred to B&W McDermott and the HP-CBK code developed by BYU was transferred to Brown to help guide the code development in this project. Also during the first project year, progress was reviewed at an all-hands meeting was held at Brigham Young University in August, 2001. The meeting was attended by PIs Fletcher, Hurt, Calo, and Sayre, and also by affiliated investigators Steven Burge from McDermott and Prof. William Hecker from BYU. During the first project year, significant progress was made on several fronts, as described in detail in the previous annual report. In the current second annual report, we report on progress made on two important project tasks. At Brown University: (1) Char combustion reactivities at 500 C in air were determined for a diverse set of solid fuels and organic model compound chars. These varied over 4 orders of magnitude for the chars prepared at 700 C, and over 3 orders of magnitude for the chars prepared at 1000 C. The resultant reactivities correlate poorly with organic elemental composition and with char surface area. (2) Specially-acquired model materials with minute amounts of inorganic matter exhibit low reactivities that fall in a narrow band as a function of wt-% carbon. Reactivities in this sample subset correlate reasonably well with total char surface area. (3) A hybrid chemical/statistical model was developed which explains most of the observed reactivity variation based on four variables: the amounts of nano-dispersed K, nanodispersed (Ca+Mg), elemental carbon (wt-% daf), and nano-dispersed vanadium, listed in decreasing order of importance. Catalytic effects play a very significant role in the oxidation of most practical solid fuel chars. Some degree of reactivity estimation is possible using only elemental analyses of parent fuels, but only if correlative techniques make use of the existing body of knowledge on the origin, form and dispersion of inorganic matter in various fuel classes. During the past year at BYU, work focused primarily on renovation of the BYU high pressure drop tube reactor (HPDT). This work has included design and testing of a flat-flame burner that can be operated at high pressure. A high-temperature, high-pressure gas profile has been achieved within this high-pressure flat-flame burner (HP-FFB). Detailed descriptions of the design and testing of the HP-FFB are given in this report. In addition, continued char reactivity experiments in the high pressure thermogravimetric analyzer (HP-TGA) have been performed on chars produced at different pressures in the HPDT. Results of the HP-TGA reactivity studies on a high-volatile A bituminous (Pittsburgh No.8) char are that intrinsic char activation energy increases with pyrolysis pressure, and that the oxygen order is roughly 0.9. These results are different than previous research on chars produced at atmospheric pressure. These new data show that the rate constant decreases with increasing pyrolysis pressure. However, the hydrogen content of the new chars produced at elevated pressures was fairly high ({approx}2 wt. %, daf), and char samples produced at higher temperatures are desired. During the next project year, experimental work on oxygen reactivity at high pressure will continue at BYU, and on CO{sub 2} reactivity at high pressure at Brown University. Selected chars produced at BYU under high pressure conditions will also be used at Brown for reactivity studies.

  6. Producing usable fuel from municipal solid waste

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1995-03-01

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  7. CO{sub 2}-mitigation measures through reduction of fossil fuel burning in power utilities. Which road to go?

    SciTech Connect (OSTI)

    Kaupp, A.

    1996-12-31

    Five conditions, at minimum, should be examined in the comparative analysis of CO{sub 2}-mitigation options for the power sector. Under the continuing constraint of scarce financial resources for any private or public investment in the power sector, the following combination of requirements characterise a successful CO{sub 2}-mitigation project: (1) Financial attractiveness for private or public investors. (2) Low, or even negative, long range marginal costs per ton of `CO{sub 2} saved`. (3) High impact on CO{sub 2}-mitigation, which indicates a large market potential for the measure. (4) The number of individual investments required to achieve the impact is relatively small. In other words, logistical difficulties in project implementation are minimised. (5) The projects are `socially fair` and have minimal negative impact on any segment of the society. This paper deals with options to reduce carbonaceous fuel burning in the power sector. Part I explains how projects should be selected and classified. Part II describes the technical options. Since reduction of carbonaceous fuel burning may be achieved through Demand Side Management (DSM) and Supply Side Management (SSM) both are treated. Within the context of this paper SSM does not mean to expand power supply as demand grows. It means to economically generate and distribute power as efficiently as possible. In too many instances DSM has degenerated into efficient lighting programs and utility managed incentives and rebate programs. To what extent this is a desirable situation for utilities in Developing Countries that face totally different problems as their counterparts in highly industrialised countries remains to be seen. Which road to go is the topic of this paper.

  8. Fossil Energy Program Annual Progress Report for April 1, 2002, Through March 31, 2003

    SciTech Connect (OSTI)

    Judkins, RR

    2003-06-19

    The mission of the Fossil Energy Program is to conduct research and development that contribute to the advancement of fossil energy technologies. The Oak Ridge National Laboratory Fossil Energy Program research and development activities, performed for the Department of Energy Assistant Secretary for Fossil Energy, cover the areas of coal, clean coal technology, gas, petroleum, and support to the Strategic Petroleum Reserve. Projects on the ORNL Fossil Energy Program are supported by the U.S. Department of Energy Office of Fossil Energy, the DOE National Energy Technology Laboratory, the DOE Fossil Energy Clean Coal Technology Program, the DOE National Petroleum Technology Office, and the DOE Fossil Energy Office of Strategic Petroleum Reserve. The ORNL Fossil Energy Program shares with DOE Oak Ridge Operations technical management responsibility for all activities on the DOE Fossil Energy Advanced Research Materials Program. The Advanced Research Materials Program includes research at other DOE and government laboratories, at universities, and at industrial organizations.

  9. Meeting today's challenges to supply tomorrow's energy. Clean fossil energy technical and policy seminar

    SciTech Connect (OSTI)

    2005-07-01

    Papers discussed the coal policy of China, Russia, Indonesia and Vietnam; clean coal technology (small-scale coal power plants, carbon capture and sequestration, new coking process SCOPE21, coal gasification (HyPr-RING), CO{sub 2} reduction technology, Supercritical coal-fired units and CFB boilers, EAGLE project, coal liquefaction), the coal consumer's view of clean fossil energy policy, and natural gas policy and technology. Some of the papers only consist of the presentation overheads/viewgraphs.

  10. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect (OSTI)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  11. Cost and quality of fuels for electric utility plants: Energy data report. 1980 annual

    SciTech Connect (OSTI)

    Not Available

    1981-06-25

    In 1980 US electric utilities reported purchasng 594 million tons of coal, 408.5 million barrels of oil and 3568.7 billion ft/sup 3/ of gas. As compared with 1979 purchases, coal rose 6.7%, oil decreased 20.9%, and gas increased for the fourth year in a row. This volume presents tabulated and graphic data on the cost and quality of fossil fuel receipts to US electric utilities plants with a combined capacity of 25 MW or greater. Information is included on fuel origin and destination, fuel types, and sulfur content, plant types, capacity, and flue gas desulfurization method used, and fuel costs. (LCL)

  12. Process for clean-burning fuel from low-rank coal

    DOE Patents [OSTI]

    Merriam, N.W.; Sethi, V.; Brecher, L.E.

    1994-06-21

    A process is described for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage. 1 fig.

  13. Evaluation of vost and semivost methods for halogenated compounds in the Clean Air Act amendments title III. Validation study at fossil fuel plant

    SciTech Connect (OSTI)

    Jackson, M.D.; Knoll, J.E.; Midgett, M.R.; McGaughey, J.F.; Bursey, J.T.

    1993-01-01

    The Clean Air Act Amendments of 1990 (CAAA), Title III, present a need for stationary source sampling and analytical methods for the list of 189 toxic air pollutants. The US Environmental Protection Agency (EPA) has used VOST and SemiVOST sampling and analytical methods for a wide variety of volatile and semivolatile organic compounds in the past, but these methodologies have been completely validated for only a few of the organic compounds. The applicability of VOST and SemiVOST techniques to the halogenated organic compounds listed in Title III of the Clean Air Act Amendments of 1990 has been evaluated under laboratory conditions for chromatographic separation, mass spectrometric response, sorbent recovery and analytical method detection limit. Dynamic spiking techniques for the sampling trains (both gaseous and liquid dynamic spiking) were also evaluated in the laboratory. In the study, the VOST and SemiVOST methods were evaluated in the field at a fossil fuel power plant. The source was selected to provide actual stationary source emissions with the compounds of interest present in trace amounts or not present. The paper presents the results of the field validation of the VOST and SemiVOST sampling and analytical methods.

  14. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    SciTech Connect (OSTI)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D.

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  15. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

  16. Fossil-fuel processing technical/professional services: comparison of Fischer-Tropsch reactor systems. Phase I, final report

    SciTech Connect (OSTI)

    Thompson, G.J.; Riekena, M.L.; Vickers, A.G.

    1981-09-01

    The Fischer-Tropsch reaction was commercialized in Germany and used to produce military fuels in fixed bed reactors. It was recognized from the start that this reactor system had severe operating and yield limitations and alternative reactor systems were sought. In 1955 the Sasol I complex, using an entrained bed (Synthol) reactor system, was started up in South Africa. Although this reactor was a definite improvement and is still operating, the literature is filled with proponents of other reactor systems, each claiming its own advantages. This report provides a summary of the results of a study to compare the development potential of three of these reactor systems with the commercially operating Synthol-entrained bed reactor system. The commercial Synthol reactor is used as a benchmark against which the development potential of the other three reactors can be compared. Most of the information on which this study is based was supplied by the M.W. Kellogg Co. No information beyond that in the literature on the operation of the Synthol reactor system was available for consideration in preparing this study, nor were any details of the changes made to the original Synthol system to overcome the operating problems reported in the literature. Because of conflicting claims and results found in the literature, it was decided to concentrate a large part of this study on a kinetic analysis of the reactor systems, in order to provide a theoretical analysis of intrinsic strengths and weaknesses of the reactors unclouded by different catalysts, operating conditions and feed compositions. The remainder of the study considers the physical attributes of the four reactor systems and compares their respective investment costs, yields, catalyst requirements and thermal efficiencies from simplified conceptual designs.

  17. DESIGNING AND OPPORTUNITY FUEL WITH BIOMASS AND TIRE-DERIVED FUEL FOR COFIRING AT WILLOW ISLAND GENERATING STATION AND COFIRING SAWDUST WITH COAL AT ALBRIGHT GENERATING STATION

    SciTech Connect (OSTI)

    K. Payette; D. Tillman

    2004-06-01

    During the period July 1, 2000-March 31, 2004, Allegheny Energy Supply Co., LLC (Allegheny) conducted an extensive demonstration of woody biomass cofiring at its Willow Island and Albright Generating Stations. This demonstration, cofunded by USDOE and Allegheny, and supported by the Biomass Interest Group (BIG) of EPRI, evaluated the impacts of sawdust cofiring in both cyclone boilers and tangentially-fired pulverized coal boilers. The cofiring in the cyclone boiler--Willow Island Generating Station Unit No.2--evaluated the impacts of sawdust alone, and sawdust blended with tire-derived fuel. The biomass was blended with the coal on its way to the combustion system. The cofiring in the pulverized coal boiler--Albright Generating Station--evaluated the impact of cofiring on emissions of oxides of nitrogen (NO{sub x}) when the sawdust was injected separately into the furnace. The demonstration of woody biomass cofiring involved design, construction, and testing at each site. The results addressed impacts associated with operational issues--capacity, efficiency, and operability--as well as formation and control of airborne emissions such as NO{sub x}, sulfur dioxide (SO{sub 2}2), opacity, and mercury. The results of this extensive program are detailed in this report.

  18. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  19. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established “reburning” chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  20. Study of organic compounds evolved during the co-firing of coal and refuse derived fuel using TG/MS

    SciTech Connect (OSTI)

    Puroshothama, Shobha; Lu, R.; Yang, Xiaodong

    1996-10-01

    The evolution of organic compounds during the combustion of carbonaceous fuel coupled with solid waste disposal and limited landfill space has been a cause for concern. Co-firing high sulfur coal with refuse derived fuel seems an attractive alternative technique to tackle the dual problem of controlling SO{sub x} emissions as well as those of the chlorinated organic toxins. The TG serves to emulate the conditions of the fluidized bed combustor and the MS serves as the detector for evolved gases. This versatile combination is used to study the decomposition pathway as well as predict the conditions at which various compounds are formed and may serve as a means of reducing the formation of these chlorinated organic compounds.

  1. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX{reg_sign}) molten carbonate fuel cell. Volumes 1--6, Final report

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  2. Publications of the Fossil Energy Advanced Research and Technology Development Materials Program, April 1, 1991--March 31, 1993

    SciTech Connect (OSTI)

    Carlson, P.T.

    1993-05-01

    Objective of DOE`s Fossil Energy Advanced Research and Technology Development Materials Program is to conduct research and development on materials for fossil energy applications, with focus on longer-term needs. The Program includes research aimed at a better understanding of materials behavior in fossil energy environments and on the development of new materials capable of substantial improvement in plant operations and reliability. Scope of the program addresses materials requirements for all fossil energy systems, including materials for coal preparation, coal liquefaction, coal gasification, heat engines and heat recovery, combustion systems, and fuel cells. Work on the Program is conducted at national and government laboratories, universities, and industrial research facilities. Research conducted on the Program is divided among the following areas: (1) ceramics, (2) new alloys, (3) corrosion research, and (4) program development and technology transfer. This bibliography covers the period of April 1, 1992, through March 31, 1993, and is a supplement to previous bibliographies in this series. The publications listed are limited to topical reports, open literature publications in refereed journals, full-length papers in published proceedings of conferences, full-length papers in unrefereed journals, and books and book articles.

  3. Publications of the Fossil Energy Advanced Research and Technology Development Materials Program, April 1, 1991--March 31, 1993

    SciTech Connect (OSTI)

    Carlson, P.T.

    1993-01-01

    Objective of DOE's Fossil Energy Advanced Research and Technology Development Materials Program is to conduct research and development on materials for fossil energy applications, with focus on longer-term needs. The Program includes research aimed at a better understanding of materials behavior in fossil energy environments and on the development of new materials capable of substantial improvement in plant operations and reliability. Scope of the program addresses materials requirements for all fossil energy systems, including materials for coal preparation, coal liquefaction, coal gasification, heat engines and heat recovery, combustion systems, and fuel cells. Work on the Program is conducted at national and government laboratories, universities, and industrial research facilities. Research conducted on the Program is divided among the following areas: (1) ceramics, (2) new alloys, (3) corrosion research, and (4) program development and technology transfer. This bibliography covers the period of April 1, 1992, through March 31, 1993, and is a supplement to previous bibliographies in this series. The publications listed are limited to topical reports, open literature publications in refereed journals, full-length papers in published proceedings of conferences, full-length papers in unrefereed journals, and books and book articles.

  4. Coal Combustion Products | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Combustion Products Coal Combustion Products Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge. PDF icon Fossil Energy Research Benefits - Coal Combustion Products More Documents & Publications EIS-0146: Final Programmatic Environmental Impact Statement Guide to

  5. Hydrogen Production: Coal Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Gasification Hydrogen Production: Coal Gasification The U.S. Department of Energy (DOE) Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically through the process of coal gasification with carbon capture, utilization, and storage. DOE anticipates that coal gasification for hydrogen production with carbon capture, utilization, and storage could be deployed in the mid-term time frame. How Does It Work? Chemically, coal is a complex and highly

  6. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  7. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. Specific conclusions are as follows: (1) To implement CO{sub 2} capture and sequestration on a national scale will decrease power plant net efficiencies and significantly increase the cost of electricity. To make responsible societal decisions, accurate and consistent economic and environmental analysis of all alternatives for atmospheric CO{sub 2} mitigation are required. (2) Commercial CO{sub 2} capture technology, though expensive and energy intensive, exists today. (3) The most promising approach to more economical CO{sub 2} capture is to develop power plant systems that facilitate efficient CO{sub 2} capture. (4) While CO{sub 2} disposal in depleted oil and gas reservoirs is feasible today, the ability to dispose of large quantities Of CO{sub 2} is highly uncertain because of both technical and institutional issues. Disposal into the deep ocean or confined aquifers offers the potential for large quantity disposal, but there are technical, safety, liability, and environmental issues to resolve. Therefore, the highest priority research should focus on establishing the feasibility of large scale disposal options.

  8. Coal Distribution Database, 2006

    U.S. Energy Information Administration (EIA) Indexed Site

    TF RailroadVesselShip Fuel It is also noted that Destination State code of "X Export" indicates movements to foreign destinations. 1 68 Domestic Coal Distribution...

  9. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    economical, reliable, and safe batteries. To substantially improve battery ... degradation, suboptimal reliability, and potential safety concerns in batteries. ...

  10. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    depends on developing batteries that are increasingly economical, reliable, and safe. A ... active in batteries, particularly those that degrade a battery's service lifetime. ...

  11. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  12. Launching the Next Wave of Clean Fossil Energy Innovation | Department...

    Broader source: Energy.gov (indexed) [DOE]

    an advanced power plant that cuts carbon pollution, or building an efficient microgrid network that better utilizes fossil fuels, loan guarantees under this solicitation...

  13. UNITED STATES OF AMERICA DEPARTMENT OF ENERGY OFFICE OF FOSSIL...

    Broader source: Energy.gov (indexed) [DOE]

    ... meet domestic demand, many LNG import facilities were proposed, but few were constructed. ... renewable energy supplies, which will compound this country's dependency on fossil fuels. ...

  14. System studies guiding fossil energy RD & D

    SciTech Connect (OSTI)

    2007-12-31

    The article describes the following recently completed studies, all of which may be accessed on NETL's website: http://netl.doe.gov/energy-analyses/ref-shelf.html: Cost and performance baseline for fossil energy power plants - volume 1: bituminous coal and natural gas to electricity (May 2007); Increasing security and reducing carbon emissions of the US transportation sector: a transformational role for coal with biomass (August 2007); Industrial size gasification for syngas, substitute natural gas, and power production (April 2007); and Carbon dioxide capture from existing coal-fired power plants (December 2006). 2 figs.

  15. Characterization and supply of coal based fuels. Volume 2, Appendicies B through M, Final report

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    This report discusses a number of special fuel slurries with a short description of the preparation method and numerous data sheets.

  16. Methodology and a preliminary data base for examining the health risks of electricity generation from uranium and coal fuels

    SciTech Connect (OSTI)

    El-Bassioni, A.A.

    1980-08-01

    An analytical model was developed to assess and examine the health effects associated with the production of electricity from uranium and coal fuels. The model is based on a systematic methodology that is both simple and easy to check, and provides details about the various components of health risk. A preliminary set of data that is needed to calculate the health risks was gathered, normalized to the model facilities, and presented in a concise manner. Additional data will become available as a result of other evaluations of both fuel cycles, and they should be included in the data base. An iterative approach involving only a few steps is recommended for validating the model. After each validation step, the model is improved in the areas where new information or increased interest justifies such upgrading. Sensitivity analysis is proposed as the best method of using the model to its full potential. Detailed quantification of the risks associated with the two fuel cycles is not presented in this report. The evaluation of risks from producing electricity by these two methods can be completed only after several steps that address difficult social and technical questions. Preliminary quantitative assessment showed that several factors not considered in detail in previous studies are potentially important. 255 refs., 21 figs., 179 tabs.

  17. The effect of oxygen-to-fuel stoichiometry on coal ash fine-fragmentation mode formation mechanisms.

    SciTech Connect (OSTI)

    Fix, G.; Seames, W. S.; Mann, M. D.; Benson, S. A.; Miller, D. J.

    2011-04-01

    Ash particles smaller than 2.5 {micro}m in diameter generated during pulverized coal combustion are difficult to capture and may pose greater harm to the environment and human health than the discharge of larger particles. Recent research efforts on coal ash formation have revealed a middle fine-fragment mode centered around 2 {micro}m. Formation of this middle or fine-fragment mode (FFM) is less well understood compared to larger coarse and smaller ultrafine ash. This study is part of an overall effort aimed at determining the key factors that impact the formation of FFM. This work examined the effects of oxygen-to-fuel stoichiometry (OFS). Pulverized Illinois No.6 bituminous coal was combusted and the ash generated was size segregated in a Dekati low pressure inertial impactor. The mass of each fraction was measured and the ash was analyzed using scanning electron microscopy (SEM) and X-ray microanalysis. The FFM ash types were classified based on the SEM images to evaluate the significant fine-fragment ash formation mechanisms and determine any possible link between stoichiometry and formation mechanism. From the particle size distributions (PSDs), the coarse mode appears unaffected by the change in OFS, however, the OFS 1.05 lowered the fraction of ultrafine ash in relation to the higher OFS settings, and appears to increase the portion of the FFM. An intermediate minimum was found in the FFM at 1.3 {micro}m for the 1.20 and 1.35 OFS tests but was not observed in the 1.05 OFS. SEM analysis also suggests that OFS may contribute to changing formation mechanisms.

  18. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  19. Fossil Energy Announces Addition of Two Key Staff Members

    Broader source: Energy.gov [DOE]

    The Department of Energy’s Office of Fossil Energy today announced the recent appointment of two key senior staff members to the Office of Fossil Energy – Julio Friedmann, Deputy Assistant Secretary for Clean Coal, and Paula Gant, Deputy Assistant Secretary for Oil and Natural Gas.

  20. Fossil Energy Program Annual Progress Report for the Period April 1, 2000 through March 31, 2001

    SciTech Connect (OSTI)

    Judkins, RR

    2001-06-14

    This report covers progress made at Oak Ridge National Laboratory (ORNL) on research and development projects that contribute to the advancement of fossil energy technologies. Projects on the ORNL Fossil Energy Program are supported by the U.S. Department of Energy (DOE) Office of Fossil Energy, the DOE National Energy Technology Laboratory (NETL), the DOE Fossil Energy Clean Coal Technology (CCT) Program, the DOE National Petroleum Technology Office, and the DOE Fossil Energy Office of Strategic Petroleum Reserve (SPR). The ORNL Fossil Energy Program research and development activities cover the areas of coal, clean coal technology, gas, petroleum, and support to the SPR. An important part of the Fossil Energy Program is technical management of all activities on the DOE Fossil Energy Advanced Research (AR) Materials Program. The AR Materials Program involves research at other DOE and government laboratories, at universities, and at industrial organizations.

  1. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 8, July 1996--August 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1996-08-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GC/MS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  2. Fossil Energy Today - Fourth Quarter, 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Fossil Energy Today - Fourth Quarter, 2012 Topics In This Issue.... National Sequestration Education Center Opens in Illinois Environment, Security, Safety & Health in the Office of Fossil Energy AVESTAR Center Deploys 3-D Virtual Training System FE Teams Earn Secretary of Energy Achievement Awards NETL Organizes Coal and Power Training Course for State Department Risk Profiles Help Predict CO2 Storage Site Obstacles PDF icon Fossil Energy Today, Issue No. 8, Fourth Quarter, 2012 More

  3. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  4. Fossil energy waste management. Technology status report

    SciTech Connect (OSTI)

    Bossart, S.J.; Newman, D.A.

    1995-02-01

    This report describes the current status and recent accomplishments of the Fossil Energy Waste Management (FE WM) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Waste Management Program is to identify and develop optimal strategies to manage solid by-products from advanced coal technologies for the purpose of ensuring the competitiveness of advanced coal technologies as a future energy source. The projects in the Fossil Energy Waste Management Program are divided into three types of activities: Waste Characterization, Disposal Technologies, and Utilization Technologies. This technology status report includes a discussion on barriers to increased use of coal by-products. Also, the major technical and nontechnical challenges currently being addressed by the FE WM program are discussed. A bibliography of 96 citations and a list of project contacts is included if the reader is interested in obtaining additional information about the FE WM program.

  5. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  6. Effects of the furnace temperature on the CO, CO{sub 2}, NO{sub x} and unburned hydrocarbon emissions from the combustion of coal and alternative fuels

    SciTech Connect (OSTI)

    Levendis, Y.A.; Atal, A.; Courtemanche, B.

    1999-07-01

    Results are presented on the emissions of carbon monoxide (CO), carbon dioxide (CO{sub 2}), unburned aromatic hydrocarbons, as well as oxides of nitrogen (NO{sub x}) from the combustion of pulverized bituminous coal, tire-derived fuel and, for a limited number of runs, waste plastics-derived fuel. The particle size cuts of pulverized coal, tire and plastics were 63--75 {micro}m and 180--300 {micro}m, respectively. Combustion experiments were conducted in a laboratory-scale drop-tube furnace at gas temperatures, in the range of 1,300--1,600 K, and several fuel mass loadings in the furnace, expressed in terms of global equivalence ratios in the range of 0.4--2.4. The CO, CO{sub 2} and NO{sub x} emissions were monitored continuously with infrared absorption and chemiluminescent instruments. Up to sixty 2-7 ring polynuclear aromatic hydrocarbons (PAH) were detected by capillary gas chromatography - mass spectrometry (GC-MS) techniques. Results showed that the PAH emission yields (mg/g fuel introduced) increased drastically with increasing bulk equivalence ratio (in the aforementioned range), at fixed furnace temperatures. This was also true for the CO yields, while the CO{sub 2} yields increased with increasing {o}, reached a maximum around stoichiometry and then decreased mildly. NO{sub x} yields decreased precipitously with increasing equivalence ratio. The CO and, especially, the PAH yields from tire-derived and plastics-derived fuels were much higher than those from coal, but the relative amounts of individual PAH components were remarkably similar in the combustion effluent of all fuels. The CO{sub 2} emissions and, especially, the NO{sub x} emissions from tire crumb were lower than those from coal. The CO{sub 2} emissions from plastics were comparable to those from coal, but their NO {sub x} emissions were much lower than those from tire. At fixed bulk equivalence ratios, however, as the furnace gas temperature increased the PAH yields from coal, tire crumb, and plastics decreased drastically, while the CO emission yields increased. At the highest temperature tested herein, 1,600 K ({approx}1,300 C), the effluent of the combustion of the fuels appeared to be devoid of PAHs. No{sub x} yields increased mildly with temperature. The influence of temperature, in this range, on the CO{sub 2} emissions was not significant. 65 refs., 2 figs., 1 tab.

  7. DKRW Advanced Fuels LLC | Open Energy Information

    Open Energy Info (EERE)

    Fuels LLC Place: Houston, Texas Zip: 77056 Product: Focues on projects that utilise coal gasification technology, including coal-to-liquids, methanation, and integrated coal...

  8. Initial operating results of coal-fired steam generators converted to 100% refuse-derived fuel

    SciTech Connect (OSTI)

    Barsin, J.A. ); Graika, P.K. ); Gonyeau, J.A. ); Bloomer, T.M. )

    1988-01-01

    The conversion of Northern States Power Company's (NSP) Red Wing and Wilmarth steam generators to fire refuse-derived fuel (RDF) is discussed. The use of the existing plant with the necessary modifications to the boilers has allowed NSP to effectively incinerate the fuel as required by Washington and Ramsey Counties. This paper covers the six-month start-up of Red Wing No. 1, commencing in May 1987, and the operating results since the plant went commercial in July 1987.

  9. Materials issues in solid oxide fuel cell systems

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  10. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, n

    U.S. Energy Information Administration (EIA) Indexed Site

    Carolina" "Item", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Coal (dollars per million Btu)",3.64,3.76,3.98,3.85,3.71,3.66,2.89,2.34,2.33,2.17,1.91,1.62,1.59,1.57,1.39,1.42,1.45,1.45,1.47,1.51,1.56,1.57,1.53,1.63,1.72 "Average heat value (Btu per

  11. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, n

    U.S. Energy Information Administration (EIA) Indexed Site

    Dakota" "Item", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Coal (dollars per million Btu)",2.09,2,2.19,2.09,1.95,1.76,1.74,1.56,1.51,1.42,1.39,1.34,1.3,1.03,0.99,0.94,0.93,0.92,0.94,1.03,1.08,1.1,1.13,1.13,1.15 "Average heat value (Btu per

  12. NETL: Coal Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification Systems Coal Gasification is a process that can turn coal into clean power, chemicals, hydrogen and transportation fuels, and can be used to capture the carbon from the coal for storage or for enhanced oil recovery. To better understand the basic concepts behind Gasification, watch this short video: What is Gasification? The Gasification Systems Program is developing advanced technologies to reduce the cost and increase the efficiency of producing coal syngas. Click on the Graphic

  13. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1995-11-30

    Studies involving the tubular furnace are in the process of identifying the ideal experimental coal-to-refuse derived fuel(RDF) ratio for use in the AFBC system. A series of experiments with this furnace has been performed to determine the possible chemical pathway for formation of chlorinated organic compounds during the combustion of various RDF sources. Phenol and chlorine appear to be likely reactants necessary for the formation of these compounds. The main goal of these experiment is to determine the exact experimental conditions for the formation of chlorinated organic compounds, as well as methods to inhibit their development. Work on the fluidized bed combustor has involved five combustion runs, in which a combustion efficiency of greater than 96% and with a consistent CO{sub 2} concentration of approximately 13% was obtained. Modifications responsible for these improvements include the addition of the underbed fuel feed system and revision of the flue gas sampling system. New methods of determining combustion efficiency and percentage of SO{sub 2} capture using TG techniques to analyze combustion products are being developed. The current outlook using this TGA/FTIR method is very promising, since previously obscured reactions are being studied. the analysis of combustion products is revealing a more complete picture of the combustion process within the AFBC system.

  14. Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)

    SciTech Connect (OSTI)

    Quimby, J.M.

    1992-02-01

    The objective of this contract is to investigate the removal of So{sub x} and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for So{sub x} removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% So{sub x} removal efficiency. This research project is now in the second of a 3 phase (Phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell's, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: Design, procurement, and installation; Shakedown and startup; Reporting. Attempts to validate the concept of electrostatic agglomeration were not possible in the shakedown program before budget constraints halted the program. What was learned was that electrostatic precipitation is feasible in the temperature range of 1600--1800{degrees}F and at pressures above 10 atmospheres.

  15. Development of high energy density fuels from mild gasification of coal

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    The overall objective of the program is the determination of the minimal processing requirements to produce High Energy Density Fuels (HEDF), meeting a minimal energy density of 130,000 Btu/gal (conventional jet fuels have energy densities in the vicinity of 115,000--120,000 Btu/gal) and having acceptable advanced fuel specifications in accordance with the three defined categories of HEDF. The program encompasses assessing current technology capability; selecting acceptable processing and refining schemes; and generating samples of advanced test fuels. A task breakdown structure was developed containing eight key tasks. This report summarizes the work that Amoco Oil Company (AOC), as key subcontractor, performed in the execution of Task 4, Proposed Upgrading Schemes for Advanced Fuel. The intent of the Task 4 study was to represent all the candidate processing options, that were either studied in the experimental efforts of Task 3 or were available from the prior art in the open literature, in a linear program (LP) model. The LP model would allow scaling of the bench-scale Task 3 results to commercial scale and would perform economic evaluations on any combination of the processes which might be used to make HEDF. Section 2.0 of this report summarizes the process and economic bases used. Sections 3.0 and 4.0 details the economics and processing sensitivities for HEDF production. 1 ref., 15 figs., 9 tabs.

  16. Workshop on the utilization of coal as an alternative to petroleum fuels in the Andean Region. Volume 1. Summary report. Held in Lima, Peru on June 24-28, 1985

    SciTech Connect (OSTI)

    1985-12-31

    The Workshop on the Utilization of Coal as an Alternative to Petroleum Fuels in the Andean Region was one regional effort to examine issues involved in developing coal as a major energy source. Held in Lima, Peru, June 24-28, 1985, and funded by the Government of Peru and the U.S. Agency for International Development (AID), the workshop examined technological measures and economic policy initiatives needed to promote coal development, particularly in Peru, Bolivia, and Ecuador.

  17. Cooperative Research Program in coal liquefaction. Technical report, May 1, 1994--October 31, 1994

    SciTech Connect (OSTI)

    1994-12-31

    Progress reports are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts.

  18. Fossil Energy Program semiannual progress report for October 1992 through March 1993

    SciTech Connect (OSTI)

    Judkins, R.R.

    1993-07-01

    This report covers progress made during the period October 1, 1992, through March 31, 1993, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Fossil Energy Office of Petroleum Reserves, and the US Agency for International Development. In particular, projects related to materials and coal combustion, environmental analysis, and bioconversion are described.

  19. Driving it home: choosing the right path for fueling North America's transportation future

    SciTech Connect (OSTI)

    Ann Bordetsky; Susan Casey-Lefkowitz; Deron Lovaas; Elizabeth Martin-Perera; Melanie Nakagawa; Bob Randall; Dan Woynillowicz

    2007-06-15

    North America faces an energy crossroads. With the world fast approaching the end of cheap, plentiful conventional oil, we must choose between developing ever-dirtier sources of fossil fuels -- at great cost to our health and environment -- or setting a course for a more sustainable energy future of clean, renewable fuels. This report explores the full scale of the damage done by attempts to extract oil from liquid coal, oil shale, and tar sands; examines the risks for investors of gambling on these dirty fuel sources; and lays out solutions for guiding us toward a cleaner fuel future. Table of contents: Executive Summary; Chapter 1: Transportation Fuel at a Crossroads; Chapter 2: Canadian Tar Sands: Scraping the Bottom of the Barrel in Endangered Forests; Chapter 3: Oil Shale Extraction: Drilling Through the American West; Chapter 4: Liquid Coal: A 'Clean Fuel' Mirage; Chapter 5: The Investment Landscape: Dirty Fuels Are Risky Business; Chapter 6: The Clean Path for Transportation and Conclusion.

  20. Novel Intergrated Process to Process to Produce Fuels from Coal and Other Carbonaceous Feedstocks

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-03-25

    BioConversion Technology, LLC has developed a novel gasifier design that produces a clean, medium to high BTU synthesis gas that can be utilized for a variety of applications. The staged, indirectly heated design produces high quality synthesis gas without the need for costly pure oxygen. This design also allows for extreme flexibility with respect to feedstocks (including those with high moisture contents) in addition to high throughputs in a small gasifier footprint. A pilot scale testing project was proposed to assist BCT with commercializing the process. A prototype gasifier constructed by BCT was transported to WRI for installation and testing. After troubleshooting, the gasifier was successfully operated with both coal and biomass feedstocks. Instrument upgrades are recommended for further testing.

  1. DOE - Fossil Energy:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NEWSALERT - Keep Up to date with e-mail alerts from the Office of Fossil Energy Fossil Energy NEWSALERT is a free, e-mail notification service of the U.S. Department of Energy's ...

  2. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  3. Life-cycle analysis of alternative aviation fuels in GREET

    SciTech Connect (OSTI)

    Elgowainy, A.; Han, J.; Wang, M.; Carter, N.; Stratton, R.; Hileman, J.; Malwitz, A.; Balasubramanian, S.

    2012-07-23

    The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, developed at Argonne National Laboratory, has been expanded to include well-to-wake (WTWa) analysis of aviation fuels and aircraft. This report documents the key WTWa stages and assumptions for fuels that represent alternatives to petroleum jet fuel. The aviation module in GREET consists of three spreadsheets that present detailed characterizations of well-to-pump and pump-to-wake parameters and WTWa results. By using the expanded GREET version (GREET1{_}2011), we estimate WTWa results for energy use (total, fossil, and petroleum energy) and greenhouse gas (GHG) emissions (carbon dioxide, methane, and nitrous oxide) for (1) each unit of energy (lower heating value) consumed by the aircraft or (2) each unit of distance traveled/ payload carried by the aircraft. The fuel pathways considered in this analysis include petroleum-based jet fuel from conventional and unconventional sources (i.e., oil sands); Fisher-Tropsch (FT) jet fuel from natural gas, coal, and biomass; bio-jet fuel from fast pyrolysis of cellulosic biomass; and bio-jet fuel from vegetable and algal oils, which falls under the American Society for Testing and Materials category of hydroprocessed esters and fatty acids. For aircraft operation, we considered six passenger aircraft classes and four freight aircraft classes in this analysis. Our analysis revealed that, depending on the feedstock source, the fuel conversion technology, and the allocation or displacement credit methodology applied to co-products, alternative bio-jet fuel pathways have the potential to reduce life-cycle GHG emissions by 55-85 percent compared with conventional (petroleum-based) jet fuel. Although producing FT jet fuel from fossil feedstock sources - such as natural gas and coal - could greatly reduce dependence on crude oil, production from such sources (especially coal) produces greater WTWa GHG emissions compared with petroleum jet fuel production unless carbon management practices, such as carbon capture and storage, are used.

  4. Secretary of Energy and Rep. Chabot Highlight Clean Coal and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Rep. Chabot Highlight Clean Coal and Hydrogen Research and Tout America's Economic ... the importance of science and technology in reducing our dependence on fossil ...

  5. Fossil generation restructuring in the Ukraine

    SciTech Connect (OSTI)

    Galambas, J.W.

    1996-12-31

    This paper describes the Ukrainian electrical system as it was in 1991, defines the need for restructuring, outlines the restructuring process, identifies a number of major obstacles that are hindering the implementation of the fossil generation, restructuring process, and points out major problems in the coal procurement system. It describes the visits to several Ukrainian power plants, defines restructuring success to date, makes suggestions for improved restructuring progress, highlights lessons learned, and enlightens the audience on the opportunities of investing in the Ukrainian power generation industry. The primary focus is on the Fossil Generator Advisor task, which was carried out under the direction of Hagler Bailly Consulting, Inc. (Hagler Bailly).

  6. Fossil energy biotechnology: A research needs assessment. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The Office of Program Analysis of the US Department of Energy commissioned this study to evaluate and prioritize research needs in fossil energy biotechnology. The objectives were to identify research initiatives in biotechnology that offer timely and strategic options for the more efficient and effective uses of the Nation`s fossil resource base, particularly the early identification of new and novel applications of biotechnology for the use or conversion of domestic fossil fuels. Fossil energy biotechnology consists of a number of diverse and distinct technologies, all related by the common denominator -- biocatalysis. The expert panel organized 14 technical subjects into three interrelated biotechnology programs: (1) upgrading the fuel value of fossil fuels; (2) bioconversion of fossil feedstocks and refined products to added value chemicals; and, (3) the development of environmental management strategies to minimize and mitigate the release of toxic and hazardous petrochemical wastes.

  7. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,..."Natural Gas ... " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,..."Natu...

  8. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  9. Integrated two-stage coal liquefaction process

    DOE Patents [OSTI]

    Bronfenbrenner, James C.; Skinner, Ronald W.; Znaimer, Samuel

    1985-01-01

    This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

  10. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30

    The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  11. Clean Coal Technology Demonstration Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Coal Technology Demonstration Program Clean Coal Technology Demonstration Program The Office of Fossil Energy's Clean Coal Technology Demonstration Program (1986-1993) laid the foundation for effective technologies now in use that have helped significantly lower emissions of sulfur dioxide (SO2), nitrogen oxides (NOx) and airborne particulates (PM10). PDF icon Clean Coal Technology Demonstration Program More Documents & Publications Return on Investment Sustainable Coal Use Clean Coal

  12. H. R. 2762: a Bill to amend the Internal Revenue Code of 1954 to increase the energy investment tax credit for conversions to coal-fueled facilities, and for other purposes. Introduced in the House of Representatives, Ninety-Ninth Congress, First Session, June 13, 1985

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    H.R.2762 amends the Internal Revenue Code of 1954 by inserting incentives for investing in coal conversions and the purchase of coal mining equipment. The Bill proposes a 10% investment tax credit for the former and a 5% tax credit for the latter, with an expiration date for both of December 31, 1993. The Text of the Bill defines conversions to coal fuel and coal mining equipment, specifies the procedures for amortizing equipment, offers tax incentives to conduct coal research activities, and specifies the requirements for conversion to coal under the Powerplant and Industrial Fuel Use Act.

  13. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 13, October--December, 1995

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-01-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit. During Quarter 13 (October--December 1995), testing of the GranuFlow dewatering process indicated a 3--4% reduction in cake moisture for screen-bowl and solid-bowl centrifuge products. The Orimulsion additions were also found to reduce the potential dustiness of the fine coal, as well as improve solids recovery in the screen-bowl centrifuge. Based on these results, Lady Dunn management now plans to use a screen bowl centrifuge to dewater their Microcel{trademark} column froth product. Subtask 3.3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter. Continuing Subtask 6.4 work, investigating coal-water-slurry formulation, indicated that selective agglomeration products can be formulated into slurries with lower viscosities than advanced flotation products. Subtask 6.5 agglomeration bench-scale testing results indicate that a very fine grind is required to meet the 2 lb ash/MBtu product specification for the Winifrede coal, while the Hiawatha coal requires a grind in the 100- to 150-mesh topsize range. Detailed design work remaining involves the preparation and issuing of the final task report. Utilizing this detailed design, a construction bid package was prepared and submitted to three Colorado based contractors for quotes as part of Task 9.

  14. The Office of Fossil Energy's (FE) Clean

    Energy Savers [EERE]

    Office of Fossil Energy's (FE) Clean Coal Technology Demonstration Program (1986-1993) laid the foundation for effective technologies now in use that have helped significantly lower emissions of sulfur dioxide (SO 2 ), nitrogen oxides (NO x ) and airborne particulates (PM 10 ). The program forged cost-sharing partnerships between the U.S. Department of Energy, industry, universities and technology suppliers and users. The U.S. General Accounting Office said the program demonstrated "how the

  15. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  16. Chemicals, fuels and electricity from coal. A proposed tri-generation concept for utilization of CO{sub 2} from power plants

    SciTech Connect (OSTI)

    Song, C.

    1999-07-01

    A tri-generation concept is proposed for the 21st century for making liquid fuels and chemicals along with electricity using CO{sub 2} from flue gases of coal-based electric power plants. The CO{sub 2} from flue gas in the power plant can be converted with CH{sub 4} (natural gas) to form synthesis gas (CO and H{sub 2} mixture) using the waste heat in the power plant. The H{sub 2}O and O{sub 2} in the flue gas will be used as co-reactants and need not be separated from the flue gas. The hot synthesis gas can be used as feedstock for fuel cells for electricity generation (such as MCFC and SOFC). The hot synthesis gas can also be used for gas turbines to generate electricity. The synthesis gas at moderate temperature can be converted into chemicals and fuels, e.g., methanol and mixed alcohols for chemical and fuel uses, dimethylether (DME) and mixed ethers for diesel fuel, dimethyl carbonate and acetic acid for chemicals. The fuels thus produced may be used either for conventional IC engines or in fuel cell-driven vehicles. This concept could also be applied, in principle, for natural gas-based power plants and IGCC power plants.

  17. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of alkali chlorides and sulfates gives increased sintering. At the same time, increased amounts calcium salts in the ash appear to reduce sintering tendency. Thus, the results suggest that a calcium based sorbent for SO{sub 2} and HCl capture might reduce problems related to ash sintering. An extensive literature exists, however, that states otherwise.

  18. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    SciTech Connect (OSTI)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO{sub 2} underground represents negative CO{sub 2} emissions if the biomass is grown sustainably (i.e., if one ton of new biomass growth replaces each ton consumed), and this offsets positive CO{sub 2} emissions associated with the coal used in these systems. Different coal:biomass input ratios will produce different net lifecycle greenhouse gas (GHG) emissions for these systems, which is the reason that attention in our analysis was given to the impact of the biomass input fraction. In the case of systems that produce only products with no carbon content, namely electricity, ammonia and hydrogen, only coal was considered as a feedstock because it is possible in theory to essentially fully decarbonize such products by capturing all of the coal-derived CO{sub 2} during the production process.

  19. Best option for CO{sub 2} reduction in fossil-fired power stations

    SciTech Connect (OSTI)

    Pruschek, R.; Goettlicher, G.; Oeljeklaus, G.; Haupt, G.; Zimmermann, G.

    1998-07-01

    If CO{sub 2} emissions have to be reduced by 60 or even 80% by the middle of next century and energy supply still has to rely on coal, CO{sub 2} removal has to be considered as an option. Conceivable methods to remove CO{sub 2} from fossil fired power plants are removal from flue gas, combustion in O{sub 2}/CO{sub 2} or removal from a fuel gas after CO shift. If coal is to be used, the IGCC (Integrated Coal Gasification Combined Cycle) power plant with CO shift conversion and physical washing and the IGCC with O{sub 2}/CO{sub 2} firing were found to be the most appropriate options with respect to energy efficiency and economy. However, only the IGCC with CO shift and CO{sub 2} wash could be constructed on the basis of today's technology. Based on a Siemens Model V94.3A gas turbine-generator and proven process engineering components, the overall efficiency only decreases by acceptable 6% points with the need of an approximately 20% higher investment. In this case, the CO{sub 2} stream is of highest purity and therefore suited for both disposal or reuse in chemical processes. The largest potential for reuse of CO{sub 2} for chemical products is the production of methanol as a substitute of oil-based transport fuels. The projected integration of such a methanol synthesis in an IGCC is also briefly addressed.

  20. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alternative fuels are defined as methanol, ethanol, natural gas, liquefied petroleum gas (propane), coal-derived liquid fuels, hydrogen, electricity, biodiesel, renewable diesel,...