National Library of Energy BETA

Sample records for fossil fuel combustion

  1. Low-emission vortex combustion of biomass and fossil fuel

    SciTech Connect (OSTI)

    Finker, F.Z.; Kubischkin, I.B.; Akhmedov, D.B.

    1995-11-01

    The article introduces the results of development and industrial experience of low-emission vortex combustion technology (LEVC) of biomass and fossil fuel in industrial and utility boilers in Russian timber and paper industries and Polish power plants. The LEVC technology is based on aerodynamics method of multiple circulation of gases and fuel in the furnaces. LEVC technology accumulates the advantages of conventional and fluidized bed combustion technology. Existing boilers could be easily retrofitted for the application of LEVC technology without requiring major investment. The repowering of boiler with LEVC was the result the reduction NOx emission to the level 170g/GJ without installation additional flue gas cleaning equipment and it gave the opportunity for an injection of sulfur sorbent in the furnace. The authors discussed Russian-Polish experiment on utility boiler retrofitted with the application of LEVC. As the result the efficiency of the boiler increased in 2%. The reduction of the emission is: NOx-40%, SO2-17%.

  2. Combustion system for hybrid solar fossil fuel receiver

    DOE Patents [OSTI]

    Mehos, Mark S.; Anselmo, Kenneth M.; Moreno, James B.; Andraka, Charles E.; Rawlinson, K. Scott; Corey, John; Bohn, Mark S.

    2004-05-25

    A combustion system for a hybrid solar receiver comprises a pre-mixer which combines air and fuel to form an air-fuel mixture. The mixture is introduced tangentially into a cooling jacket. A burner plenum is fluidically connected to the cooling jacket such that the burner plenum and the cooling jacket are arranged in thermal contact with one another. The air-fuel mixture flows through the cooling jacket cooling the burner plenum to reduce pre-ignition of the air-fuel mixture in the burner plenum. A combustion chamber is operatively associated with and open to the burner plenum to receive the air-fuel mixture from the burner plenum. An igniter is operatively positioned in the combustion chamber to combust the air-fuel mixture, releasing heat. A recuperator is operatively associated with the burner plenum and the combustion chamber and pre-heats the air-fuel mixture in the burner plenum with heat from the combustion chamber. A heat-exchanger is operatively associated and in thermal contact with the combustion chamber. The heat-exchanger provides heat for the hybrid solar receiver.

  3. Environmental impact of fossil fuel combustion in power generation

    SciTech Connect (OSTI)

    Allen, J.W.; Beal, P.R.

    1996-12-31

    All the recent developments in the combustion systems employed for power generation have been based on environmental considerations. Combustion modifications have been developed and utilised in order to control NO{sub x} emissions and improvements continue to be made as the legislative requirements tighten. Chemical processes and fuel switching are used to control SO{sub x} emissions. After nitrogen, carbon dioxide is the major gas emitted from the combustion process and its potential potency as a greenhouse gas is well documented. Increased efficiency cycles, mainly based on natural gas as the prime fuel, can minimise the amount of CO{sub x} produced per unit of power generated. As the economics of natural gas utilisation become less favourable a return to clean coal technology based power generation processes may be required.

  4. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect (OSTI)

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  5. Municipal waste combustion assessment: Fossil fuel co-firing. Final report, October 1988-July 1989

    SciTech Connect (OSTI)

    Landrum, V.J.; Barton, R.G.

    1989-07-01

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; and describes the population of coal fired boilers that currently co-fire RDF, have previously co-fired RDF but have ceased to do so, and have been used in RDF co-firing demonstrations. (Fossil fuel co-firing, defined as the combustion of RDF with another fuel (usually coal) in a device designed primarily to burn the other fuel, is generally confined to commercial and utility boilers.) Model plants are developed and good combustion practices are recommended.

  6. Further experience for environmental improvement in fossil fuel combustion

    SciTech Connect (OSTI)

    Lazzeri, L.; Santis, R. de

    1998-12-31

    Reburning is a technology which has proven, by plant demonstration, capable of providing compliance with very stringent regulatory emissions requests (less than 90 ppm NO{sub x} firing oil and gas and less than 160--170 ppm firing coal). Designing a Reburn System requires a contemporary control of many parameters like flow rates, local stoichiometries residence times, etc.; it also requires the availability and capability of using complex and sophisticated numerical modeling. Although the system can be adapted to any already installed hardware it should be noted that the availability of reliable LNB`s and of specifically designed OFA`s and Reburn fuel injectors can greatly enhance the system performance. Design of OFA system is a subcase of a Reburn System design, as it implies same concepts of mixing and residence times which are the basis of Reburn System. As shown in the cases previously presented Reburning always provides additional margins to OFA operation specifically when very low emission limits are pursued. Finally it should be noted that the use of Reburning may create problems of unburned specifically when very low local stoichiometries and when very low sulfur oils are used which are often characterized by asphaltene instability especially when STZ oil is the result of blending high and low sulfur oils. A specific know-how has been jointly developed by Ansaldo and ENEL to solve these problems acting on both atomizer type selection and operation.

  7. Table 1.15 Non-Combustion Use of Fossil Fuels, 1980-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Non-Combustion Use of Fossil Fuels, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5<//td> 1980 145 230 58 253 14 [R] 37 58 795 [R] 639 2.4 [ – –] [ – –] 1981 125 229 56 216 15 [R] 27 54 722 [R] 518 [R] 2.1 [ – –] [ – –] 1982 125 256 51 157 15 [R] 25 48 678 [R] 448 [R] 1.4 [ – –] [

  8. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  9. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  11. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  12. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect (OSTI)

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  13. ABB`s investigations into air toxic emissions from fossil fuel and MSW combustion

    SciTech Connect (OSTI)

    Wesnor, J.D.

    1994-12-31

    Since passage of the Clean Air Act, Asea Brown Boveri (ABB) has been actively developing a knowledge base on the Title 3 hazardous air pollutants, more commonly called air toxics. As ABB is a multinational company, US operating companies are able to call upon work performed by European counterparts, who have faced similar legislation several years ago. In addition to the design experience and database acquired in Europe, ABB Inc. has been pursuing several other avenues to expand its air toxics knowledge. ABB Combustion Engineering (ABB CE) is presently studying the formation of organic pollutants within the combustion furnace and partitioning of trace metals among the furnace outlet streams. ABB Environmental Systems (ABBES) has reviewed available and near-term control technologies and methods. Also, both ABB CE and ABBES have conducted source sampling and analysis at commercial installations for hazardous air pollutants to determine the emission rates and removal performance of various types of equipment. Several different plants hosted these activities, allowing for variation in fuel type and composition, boiler configuration, and air pollution control equipment. This paper discusses the results of these investigations.

  14. Advanced fossil fuel combustor

    SciTech Connect (OSTI)

    Rogers, B.

    1995-05-01

    Charged with enhancing the use of US fossil energy resources, the Morgantown Energy Technology Center (METC) is a federal Department of Energy research center that performs its own research and also manages the work of contractors. One interesting recent METC project is the effort to develop a ``multiannular swirl burner`` (MSB) for use in an advanced fossil fuel combustion system. The design is being developed by an outside contractor with funding and technical assistance from METC. Recently, EG and G Technical Services of West Virginia was asked to provide analytical support to the contractor developing the MSB. Design projects like this usually require building and testing a series of very expensive prototypes. Recent success with computational fluid dynamic (CFD) design techniques, however, have generated a great deal of excitement because of its ability to reduce research and development costs. Using FLUENT, a CFD package from Fluent Inc., EG and G was able to predict, with a high degree of accuracy, the performance of one of the MSB combustor prototypes. Furthermore, the model provided researchers with a more detailed understanding of the proposed design`s performance characteristics.

  15. replace fossil fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    replace fossil fuels - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  16. No Fossil Fuel - Kingston | Open Energy Information

    Open Energy Info (EERE)

    Fossil Fuel - Kingston Jump to: navigation, search Name No Fossil Fuel - Kingston Facility No Fossil Fuel - Kingston Sector Wind energy Facility Type Commercial Scale Wind Facility...

  17. DOE - Fossil Energy: How Fossil Fuels Were Formed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Fuel Formation Fossil Energy Study Guides How Fossil Fuels were Formed Contrary to what many people believe, fossil fuels are not the remains of dead dinosaurs. In fact, most of the fossil fuels we find today were formed millions of years before the first dinosaurs. Formation of Coal - Primordial Swamp - Ancient Seas - Coal Seam - - Fossil fuels were formed from plants and animals that lived 300 million years ago in primordial swamps and oceans (top). Over time the plants and animals died

  18. Fossil fuel furnace reactor

    DOE Patents [OSTI]

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  19. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  20. No Fossils in This Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plan for Environmental Teaching GM Environmental Science Club No Fossils in This Fuel Your PlanET Sixth through Eighth Grades (Can be easily adapted to any elementary/middle school level) Ingredients: Yeast, sugar ... what are you making? Sweet rolls? Not in Science Class! You're blending these ingredients to make an innovative form of fuel! That's right ... when these two simple ingredients are mixed, the yeast  a simple, living organism  breaks the sugar down into ethyl alcohol, or

  1. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  2. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues » submit Greening up fossil fuels with carbon sequestration Researchers make progress fighting climate change by capturing carbon dioxide from power plants and storing it deep underground in geological reservoirs March 25, 2013 Greening up fossil fuels with carbon sequestration Most of the world's existing energy supply is stored underground in

  3. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  4. The Council of Industrial Boiler Owners special project on non-utility fossil fuel ash classification

    SciTech Connect (OSTI)

    Svendsen, R.L.

    1996-12-31

    Information is outlined on the Council of Industrial Boiler Owners (CIBO) special project on non-utility fossil fuel ash classification. Data are presented on; current (1996) regulatory status of fossil-fuel combustion wastes; FBC technology identified for further study; CIBO special project methods; Bevill amendment study factors; data collection; and CIBO special project status.

  5. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy...

  6. fossil fuels | OpenEI Community

    Open Energy Info (EERE)

    energy becomes more competitive with fossil fuels in OECD countries, reports of this nature can go a long way to supporting more and more development. The four new reports in...

  7. An oxy-hydrocarbon model of fossil fuels

    SciTech Connect (OSTI)

    Fred D. Lang; Tom Canning

    2007-09-15

    This paper asserts a new method of analyzing fossil fuels, useful for sorting coals into well-defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multivariant approach for describing the lower ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high-energy ranks. In addition, for a few special cases, multiple low and high ranks are also well described by the multivariant approach. As useful as these techniques are for analyzing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems' Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time.

  8. Fuel Formulation Effects on Diesel Fuel Injection, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission ...

  9. Replace Fossil Fuels, Final Technical Report Roberts, William...

    Office of Scientific and Technical Information (OSTI)

    Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Roberts, William L 09 BIOMASS FUELS biofuels, glycerin, glycerol,...

  10. Norwegian carbon taxes and their implication for fossil fuels

    SciTech Connect (OSTI)

    Kaarstad, O.

    1995-12-31

    The Scandinavian countries, and in particular Norway and Sweden, have since 1990/91 taxed CO{sub 2}-emissions with carbon tax of about US $150 per ton of CO{sub 2}. One may therefore say that these countries have placed themselves in a role as {open_quotes}carbon tax laboratories{close_quotes}. These very high CO{sub 2}-taxes have been in place for about four years and the first lessons from this experience are reported. In general it would seem as if the taxation mechanism is less efficient than economists have expected. The CO{sub 2}-emissions are increasing in both Norway and Sweden and the stabilization goal to the year 2000 will not be achieved in spite of the high taxation. The fossil fuel industry will have to learn to live with the climate change question which is inherently hostile to fossil fuels. It is argued that a more informed and active participation by the fossil fuel industry is needed in the climate change discussion. In addition the image of fossil fuels will benefit from showing real and potential improvement in the area of greenhouse gas emissions in the whole energy chain from production to combustion. The R&D effort being done into CO{sub 2}-capture and -disposal is creating such an option for the future. It is argued that the image of the entire fossil fuel industry will benefit from the creation of a {open_quotes}CO{sub 2}-free{close_quote} option or vision for oil, gas and coal. A number of examples are shown where today (or in the near future) actual CO{sub 2}-disposal in underground formations are taking place.

  11. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  12. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines 2012 DOE Hydrogen and Fuel Cells ...

  13. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    Open Energy Info (EERE)

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  14. Advanced Combustion and Fuels

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  15. Fossil fuel is king with energy producers

    SciTech Connect (OSTI)

    Hansen, T.

    1996-11-01

    Worldwide energy consumption is expected to double today`s levels by 2020, according to the World Energy Council. As diverse energy needs develop, fossil fuels are expected to continue to be the major source for power generation throughout the world. In the United States, utility deregulation is making low-cost fuel and power plant efficiency more important than ever. Electricity generators see both natural gas and coal as the fuels that will allow them to best meet the nation`s future energy needs. Coal will see less increase in its share of electricity generation than natural gas due to the costs associated with meeting the Clean Air Act Amendments` (CAAA) requirements. According to Organizations for Economic Cooperation Development, coal in both the United States and Europe will experience a 12 percent growth by 2010. Even with this somewhat slow growth, coal will remain the nation`s number one fuel for electricity generation well into the next century.

  16. Internal combustion engine fuel feed

    SciTech Connect (OSTI)

    Cochard, P.; Guicherd, C.

    1980-02-19

    In a method and apparatus for controlling the fuel feed to a stratified-charge internal combustion engine, from idle up to the position corresponding with the maximum flow of air, the overall richness (Rg) of the combustible mixture is reduced by acting simultaneously upon the flow of fuel feeding the main chamber and upon the flow of fuel injected into the auxiliary chamber. For higher loads the maximum flow of air is kept constant and rg is increased by continuing to act upon both fuel flows. By keeping the richness of the mixture in the auxiliary chamber substantially constant, it is possible to obtain the best compromise between the performance of the engine and the emission of pollutant gases.

  17. Fuel Effects on Mixing-Controlled Combustion Strategies for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion ...

  18. NREL: Transportation Research - Fuel Combustion Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Laboratory NREL's Fuel Combustion Laboratory focuses on characterizing fuels at the molecular level. This information can then be used to understand and predict a fuel's effect on engine performance and emissions. By understanding the effects of fuel chemistry on ignition, as well as the potential emissions impacts, we can develop fuels that enable more efficient engine designs, using both today's technology and future advanced combustion concepts. This lab supports the Renewable

  19. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, Bertrand D.; Confer, Gregory L.; Shen, Zujing; Hapeman, Martin J.; Flynn, Paul L.

    1993-12-21

    Apparatus and a method of introducing a primary fuel, which may be a coal water slutty, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure.

  20. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, B.D.; Confer, G.L.; Zujing Shen; Hapeman, M.J.; Flynn, P.L.

    1993-12-21

    Apparatus and a method of introducing a primary fuel, which may be a coal water slurry, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure. 19 figures.

  1. Fossil fuel conversion--measurement and modeling

    SciTech Connect (OSTI)

    Solomon, P.R.; Smoot, L.D.; Serio, M.A.; Hamblen, D.G.; Brewster, B.S.; Radulovic, P.T.

    1994-10-01

    The main objective of this program is to understand the chemical and physical mechanisms in coal conversion processes and incorporate this knowledge in computer-aided reactor engineering technology for the purposes of development, evaluation, design, scale-up, simulation, control and feedstock evaluation in advanced coal conversion devices. To accomplish this objective, this program will: (1) provide critical data on the physical and chemical processes in fossil fuel gasifiers and combustors; (2) further develop a set of comprehensive codes; and (3) apply these codes to model various types of combustors and gasifiers (fixed-bed, transport reactor, and fluidized-bed for coal and gas turbines for natural gas).

  2. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1997-05-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1996-01-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  4. Combustor nozzle for a fuel-flexible combustion system

    DOE Patents [OSTI]

    Haynes, Joel Meier (Niskayuna, NY); Mosbacher, David Matthew (Cohoes, NY); Janssen, Jonathan Sebastian (Troy, NY); Iyer, Venkatraman Ananthakrishnan (Mason, OH)

    2011-03-22

    A combustor nozzle is provided. The combustor nozzle includes a first fuel system configured to introduce a syngas fuel into a combustion chamber to enable lean premixed combustion within the combustion chamber and a second fuel system configured to introduce the syngas fuel, or a hydrocarbon fuel, or diluents, or combinations thereof into the combustion chamber to enable diffusion combustion within the combustion chamber.

  5. Fossil Fuels Study Guide - High School | Department of Energy

    Office of Environmental Management (EM)

    Fuels Study Guide - High School Fossil Fuels Study Guide - High School PDF icon Fossil Fuels Study Guide - High School More Documents & Publications Coal Study Guide for Elementary School Coal Study Guide - Middle School Secondary Energy Infobook and Secondary Infobook Activities (19 Activities)

  6. Fossil Fuel-Generated Energy Consumption Reduction for New Federal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings and Major Renovations of Federal Buildings | Department of Energy Buildings Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in a Supplemental Notice of Proposed Rulemaking. File fossilfuel.docx More Documents & Publications Fossil Fuel-Generated Energy Consumption

  7. Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems | Department of Energy Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered Energy Systems Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered Energy Systems May 1, 2014 - 9:33am Addthis The Agricultural Renewable Energy Conversion Incentive Program, funded in part by DOE's State Energy Program (SEP), assists farmers and ranchers to convert fossil-fueled agricultural production systems to renewable energy power. The program will install solar panels to replace

  8. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings OIRA Comparison Document Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document...

  9. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships (Redirected from Brazil-NETL Cooperation) Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation...

  10. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation AgencyCompany Organization National Energy...

  11. Pre-Combustion Carbon Capture Research | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification...

  12. renewable sources of power. Demand for fossil fuels surely will overrun supply s

    Broader source: Energy.gov (indexed) [DOE]

    renewable sources of power. Demand for fossil fuels surely will overrun supply sooner or later, as indeed it already has in the casc of United States domestic oil drilling. Recognition also is growing that our air and land can no longer absorb unlimited quantities of waste from fossil fuel extraction and combustion. As that day draws nearer, policymakers will have no realistic alternative but to turn to sources of power that today make up a viable but small part of America's energy picture. And

  13. NREL: Transportation Research - Fuel Combustion and Engine Performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Test & Evaluation Fuels Performance Combustion & Engines Fuel Chemistry Emissions & Fuel Economy Power Electronics & Electric Machines Sustainable Mobility Systems Analysis &...

  14. A Comparison of Combustion and Emissions of Diesel Fuels and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    was used to study how selected oxygenated fuels affect combustion and emissions in a modern diesel engine during conventional combustion and low-temperature combustion (LTC). ...

  15. Combustion, Efficiency, and Fuel Effects in a Spark-Assisted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine 2004 Diesel...

  16. State Grid Biomass Fuel and Combustion Technology Laboratory...

    Open Energy Info (EERE)

    Biomass Fuel and Combustion Technology Laboratory Jump to: navigation, search Name: State Grid Biomass Fuel and Combustion Technology Laboratory Place: Beijing Municipality, China...

  17. Factors Affecting HCCI Combustion Phasing for Fuels with Single...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004 ...

  18. Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Emission Control | Department of Energy Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control 2003 DEER Conference Presentation: The Pennsylvania State University PDF icon 2003_deer_boehman.pdf More Documents & Publications Fuel Impacts on Soot Nanostructure and Reactivity Effect of Alternative Fuels on Soot Properties and Regeneration of Diesel Particulate

  19. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels

    Office of Environmental Management (EM)

    in Gas Turbines - Fact Sheet, May 2014 | Department of Energy Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines - Fact Sheet, May 2014 Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines - Fact Sheet, May 2014 GE Global Research developed and tested new fuel-flexible gas turbine nozzle technology concepts that will enable end users to efficiently generate power and heat from industrial off-gases and gasified industrial,

  20. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  1. Fuel injector nozzle for internal combustion engine

    SciTech Connect (OSTI)

    Klomp, E.D.; Peters, B.D.

    1990-06-12

    This patent describes a fuel injection nozzle for a combustion chamber of an internal combustion engine. It comprises: a nozzle body with at least one fuel flow opening therethrough for feed fuel to the chamber, a resilient diaphragm normally sealing the opening and having orifice means therein for further atomizing and directing the pulses into the chamber, fastening means for fixing the diaphragm to the body so that diaphragm can deflect by a predetermined amount under low engine load operating conditions so that a wide angle cone of atomized fuel is injected into and generally at one end of the combustion chamber for the stratified charge thereof and deflect by an amount greater than the first amount of deflection under high engine load operating conditions. A narrow spray cone of atomized fuel is injected in a deeper pattern into and throughout the combustion chamber for optimizing the charge thereof and fuel burns under the low and high load engine operating conditions.

  2. Accurate Predictions of Fuel Effects on Combustion and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    With Detailed Fuel Chemistry Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry Accurate fuel models ...

  3. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2012 ii This report...

  4. Optimization of fossil fuel sources: An exergy approach

    SciTech Connect (OSTI)

    Camdali, U.

    2007-02-15

    We performed linear programming for optimization of fossil fuel supply in 2000 in Turkey. For this, an exergy analysis is made because the second law of thermodynamics takes into account the quality of energy as well as quantity of energy. Our analyses showed that the interfuel substitution between different fossil fuels will lead to a best energy mix of the country. The total retail price of fossil fuels can be lowered to 11.349 billion US$ from 13.012 billion US$ by increasing the domestic production of oil, lignite, and hard coal and by decreasing imports. The remaining demand can be met by natural gas imports. In conclusion, our analysis showed that a reduction of 1.663 billion US$ in fossil fuel cost can be made possible by giving more emphasis on domestic production, particularly of oil, lignite and hard coal.

  5. Disclosure of Permitted Communication Concerning Fossil Fuel Energy

    Energy Savers [EERE]

    Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No. EERE-2010-BT-STD-0031; RIN 1904-AB96 | Department of Energy Fossil Fuel Energy Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No. EERE-2010-BT-STD-0031; RIN 1904-AB96 Disclosure of Permitted Communication Concerning Fossil Fuel Energy Consumption Reduction for New Construction and Major Renovations of Federal Buildings -- Docket No.

  6. Fossil Fuel-Generated Energy Consumption Reduction for New Federal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings and Major Renovations of Federal Buildings OIRA Comparison Document | Department of Energy Buildings OIRA Comparison Document Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document Document details the Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in an OIRA Comparison Document. File fossilfuel_compare2014.docx More

  7. Advanced Combustion Technologies | Department of Energy

    Energy Savers [EERE]

    Air Separation Oxycombustion cannot be simply substituted for air combustion in existing fossil-fueled power plants due to differences in combustion characteristics. For...

  8. Evaluation of innovative fossil fuel power plants with CO{sub 2} removal

    SciTech Connect (OSTI)

    2000-07-15

    This interim report presents initial results of an ongoing study of the potential cost of electricity produced in both conventional and innovative fossil fueled power plants that incorporate carbon dioxide (CO{sub 2}) removal for subsequent sequestration or use. The baseline cases are natural gas combined cycle (NGCC) and ultra-supercritical pulverized coal (PC) plants, with and without post combustion CO{sub 2} removal, and integrated gasification combined cycle (IGCC) plants, with and without pre-combustion CO{sub 2} removal.

  9. Fireside Corrosion in Oxy-Fuel Combustion of Coal

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Tylczak, Joseph; Meier, G.H.; Jung. K.; Mu, N.; Yanar, N.M.; Pettit, F.S.

    2012-08-01

    Oxy-fuel combustion is based on burning fossil fuels in a mixture of recirculated flue gas and oxygen, rather than in air. An optimized oxy-combustion power plant will have ultra-low emissions since the flue gas that results from oxy-fuel combustion consists almost entirely of CO2 and water vapor. Once the water vapor is condensed, it is relatively easy to sequester the CO2 so that it does not escape into the atmosphere. A variety of laboratory tests comparing air-firing to oxy-firing conditions, and tests examining specific simpler combinations of oxidants, were conducted at 650-700 C. Alloys studied included model Fe-Cr and Ni-Cr alloys, commercial ferritic steels, austenitic steels, and nickel base superalloys. The observed corrosion behavior shows accelerated corrosion even with sulfate additions that remain solid at the tested temperatures, encapsulation of ash components in outer iron oxide scales, and a differentiation between oxy-fuel combustion flue gas recirculation choices.

  10. Fuel Interchangeability Considerations for Gas Turbine Combustion

    SciTech Connect (OSTI)

    Ferguson, D.H.

    2007-10-01

    In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

  11. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M.; Splitter, Derek A.; Kokjohn, Sage L.

    2015-07-14

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  12. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2013-12-31

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  13. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft004_mueller_2012_o.pdf More Documents & Publications Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Vehicle Technologies Office

  14. Experience in preparing fuel for combustion

    SciTech Connect (OSTI)

    Rude, J.

    1995-09-01

    The key phase seems to be that wood is the ORIGINAL FUEL. Certainly as man discovered fire, it was the most obvious as well as abundantly available fuel and it burned very well because man was smart enough to select the dry wood once he understood the basics of combustion. As the needs started to go beyond the most elementary, designs for burning ideal fuels were pretty well perfected, however, the burning of less ideal fuels still remain a challenge. To provide plant steam requirements by burning waste that must be disposed of anyway can reduce operating cost considerably. For most of us involved in producing steam, the experience we have with fuels such as bark, wood waste, sludge, and miscellaneous forms of solid combustible waste material, are a result of burning these fuels in an existing boiler supposedly designed for wood waste or possibly a combination of wood and other fuels such as coal, oil, or gas. For a supplier of fuel preparation systems, the typical application involves the sizing, cleaning, and drying of wood waste, and sludge from a pulp and/or paper mill. Other forms of combustible waste are dealt with occasionally and after proper preparation fired in the combustion system for the purpose of generating hot gas and/or steam for the plant process.

  15. Environmental review for the conversion of Bellefonte Nuclear Plant to fossil fuel

    SciTech Connect (OSTI)

    Carter, R.; Rucker, H.; Summers, R.

    1998-07-01

    The Tennessee Valley Authority recently issued for public review a Draft Environmental Impact Statement for the conversion of the unfinished Bellefonte Nuclear Plant to fossil fuel. The DEIS was structured to support three tiers of decision making. Tier 1 is to decide between the No-Action Alternative, which is to leave Bellefonte as a partially completed nuclear plant into the indefinite future, and the Proposed Action Alternative, which is to proceed with converting Bellefonte to fossil fuel. Tier 2 is to select one of five conversion options. In the DEIS, TVA indicated no preference among the five competing fossil conversion options. The five conversion pathways would fully repower the plant consistent with fossil fuel availability, would use commercially ready systems and technologies and be designed to fully utilize the capacity of transmission lines serving Bellefonte. Conversion options addressed were pulverized coal (PC), natural gas combined cycle (NGCC), integrated gasification combined cycle (IGCC), IGCC with joint production of electricity and chemicals, and an option, which combines elements of NGCC and IGCC with coproduction. Tier 3 involves decisions about eight sub-option choices, basically types of processes, equipment, and modes of operation, which is part of two or more conversion options. An example of a sub-option choice would be the type of gasifier that would be used in conversion options involving coal or petroleum coke gasification. Other sub-option choices addressed in the DEIS were natural gas pipeline corridors; fuels, feedstocks, and by-products transportation modes; types of combustion turbines; solid fuels; types of boilers for conventional coal-fired options; chemical production mixes; and modes of onsite solid fuel conveyance. The impact of constructing and operating each proposed fossil conversion option at Bellefonte were evaluated for 18 environmental resource and economic categories.

  16. Combustion Science for Cleaner Fuels

    SciTech Connect (OSTI)

    Ahmed, Musahid

    2014-10-17

    Musahid Ahmed discusses how he and his team use the Advanced Light Source (ALS) to study combustion chemistry at our '8 Big Ideas' Science at the Theater event on October 8th, 2014, in Oakland, California.

  17. Plasma enhancement of combustion of solid fuels

    SciTech Connect (OSTI)

    Askarova, A.S.; Karpenko, E.I.; Messerle, V.E.; Ustimenko, A.B.

    2006-03-15

    Plasma fuel systems that increase the coal burning efficiency are discussed. The systems were tested for fuel oil-free startup of boilers and stabilizating a pulverized-coal flame in power-generating boilers equipped with different types of burner and burning all types of power-generating coal. Plasma ignition, thermochemical treatment of an air-fuel mixture prior to combustion, and its burning in a power-generating boiler were numerically simulated. Environmental friendliness of the plasma technology was demonstrated.

  18. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  19. Fuels for Advanced Combustion Engines

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  20. Fuels for Advanced Combustion Engines

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  1. Fossil fuel combined cycle power system

    DOE Patents [OSTI]

    Labinov, Solomon Davidovich; Armstrong, Timothy Robert; Judkins, Roddie Reagan

    2006-10-10

    A system for converting fuel energy to electricity includes a reformer for converting a higher molecular weight gas into at least one lower molecular weight gas, at least one turbine to produce electricity from expansion of at least one of the lower molecular weight gases, and at least one fuel cell. The system can further include at least one separation device for substantially dividing the lower molecular weight gases into at least two gas streams prior to the electrochemical oxidization step. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  2. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect (OSTI)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  3. Fossil fuel combined cycle power generation method

    DOE Patents [OSTI]

    Labinov, Solomon D [Knoxville, TN; Armstrong, Timothy R [Clinton, TN; Judkins, Roddie R [Knoxville, TN

    2008-10-21

    A method for converting fuel energy to electricity includes the steps of converting a higher molecular weight gas into at least one mixed gas stream of lower average molecular weight including at least a first lower molecular weight gas and a second gas, the first and second gases being different gases, wherein the first lower molecular weight gas comprises H.sub.2 and the second gas comprises CO. The mixed gas is supplied to at least one turbine to produce electricity. The mixed gas stream is divided after the turbine into a first gas stream mainly comprising H.sub.2 and a second gas stream mainly comprising CO. The first and second gas streams are then electrochemically oxidized in separate fuel cells to produce electricity. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  4. Combustion and Emissions Performance of Dual-Fuel Gasoline and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Combustion and Emissions Performance of Dual-Fuel Gasoline...

  5. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  6. Vehicle Technologies Office Merit Review 2014: Advanced Combustion and Fuels

    Broader source: Energy.gov [DOE]

    Presentation given by NREL at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced combustion and fuels.

  7. Fuels Performance: Navigating the Intersection of Fuels and Combustion (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2014-12-01

    Researchers at the National Renewable Energy Laboratory (NREL), the only national laboratory dedicated 100% to renewable energy and energy efficiency, recognize that engine and infrastructure compatibility can make or break the impact of even the most promising fuel. NREL and its industry partners navigate the intersection of fuel chemistry, ignition kinetics, combustion, and emissions, with innovative approaches to engines and fuels that meet drivers' expectations, while minimizing petroleum use and GHGs.

  8. Fossil fuels in a sustainable energy future

    SciTech Connect (OSTI)

    Bechtel, T.F.

    1995-12-01

    The coal industry in the United States has become a world leader in safety, productivity, and environmental protection in the mining of coal. The {open_quotes}pick-and-shovel{close_quotes} miner with mangled limbs and black lung disease has been replaced by the highly skilled technicians that lead the world in tons per man-hour. The gob piles, polluted streams, and scared land are a thing of the past. The complementary efforts of the DOE and EPRI-funded programs in coal utilization R&D and the Clean Coal Technology Program commercial demonstrations, have positioned the power generation industry to utilize coal in a way that doesn`t pollute the air or water, keeps electrical power costs low, and avoids the mountains of waste material. This paper reviews the potential for advanced coal utilization technologies in new power generation applications as well as the repowering of existing plants to increase their output, raise their efficiency, and reduce pollution. It demonstrates the potential for these advanced coal-fueled plants to play a complementary role in future planning with the natural gas and oil fired units currently favored in the market place. The status of the US program to demonstrate these technologies at commercial scale is reviewed in some detail.

  9. US fossil fuel technologies for Thailand

    SciTech Connect (OSTI)

    Buehring, W.A.; Dials, G.E.; Gillette, J.L.; Szpunar, C.B.; Traczyk, P.A.

    1990-10-01

    The US Department of Energy has been encouraging other countries to consider US coal and coal technologies in meeting their future energy needs. Thailand is one of three developing countries determined to be a potentially favorable market for such exports. This report briefly profiles Thailand with respect to population, employment, energy infrastructure and policies, as well as financial, economic, and trade issues. Thailand is shifting from a traditionally agrarian economy to one based more strongly on light manufacturing and will therefore require increased energy resources that are reliable and flexible in responding to anticipated growth. Thailand has extensive lignite deposits that could fuel a variety of coal-based technologies. Atmospheric fluidized-bed combustors could utilize this resource and still permit Thailand to meet emission standards for sulfur dioxide. This option also lends itself to small-scale applications suitable for private-sector power generation. Slagging combustors and coal-water mixtures also appear to have potential. Both new construction and refurbishment of existing plants are planned. 18 refs., 3 figs., 7 tabs.

  10. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-04-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming process, mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  11. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-07-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRB and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  12. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-09-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  13. U.S. DOE fossil energy fuel cell program

    SciTech Connect (OSTI)

    Wayne Surdoval

    2007-07-01

    The U.S. Department of Energy's Office of Fossil Energy's National Energy Technology Laboratory, in partnership with private industry, educational institutions, and national laboratories, is leading the research, development, and demonstration of high efficiency, fuel flexible solid oxide fuel cells (SOFCs) and coal based SOFC power generation systems for stationary markets. This Fuel Cell Program has three parts: Solid State Energy Conversion Alliance (SECA) cost reduction, SECA fuel cell coal based systems, and advanced SECA systems. The SECA cost reduction goal is to have SOFCs capable of being mass manufactured at $400 per kilowatt by 2010. Concurrently, the scale-up, aggregation, and integration of the technology will progress in parallel leading to prototype validation of megawatt class products by 2012 with potential testing at FutureGen. The SECA coal-based and advanced systems goals are the development of megawatt-class fuel cell power systems that will enable affordable, reliable, efficient, and environmentally-friendly electrical power from coal.

  14. An optical gas temperature probe for high temperature fossil fuel process streams

    SciTech Connect (OSTI)

    Bauman, L.E.; Cook, R.L.; Lineberry, J.T.; Litchford, R.J.

    1995-12-31

    Reported here are the results of a feasibility study of a modular optical gas temperature probe for direct measurement of gas temperature in fossil-fueled combustion streams. A probe based upon the spectroscopic technique of line reversal would be superior to currently available gas temperature technology. The study concluded that a modular form of the line reversal optical temperature probe is feasible and, as such. the probe should be a commercially viable product with potential economic benefits from improved monitoring and control of utility furnaces. Such a probe will have the capability of making direct measurements of gas temperature in hot (>1500 K) process streams of coal combustion systems and large-scale power plant facilities.

  15. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Statistical Overview of 5 Years of HCCI Fuel and Engine Data from ORNL Response of Oil Sands Derived Fuels in Diesel HCCI Operation Combustion, Efficiency, and Fuel Effects in a ...

  16. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions | Department of Energy Coal-Derived Liquids to Enable HCCI Technology Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels Derived from Heavy Crude Sources

  17. Complete Fuel Combustion for Diesel Engines Resulting in Greatly Reduced

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions and Improved Fuel Efficiency | Department of Energy Complete Fuel Combustion for Diesel Engines Resulting in Greatly Reduced Emissions and Improved Fuel Efficiency Complete Fuel Combustion for Diesel Engines Resulting in Greatly Reduced Emissions and Improved Fuel Efficiency An advanced engine design that is 15 percent more efficient than diesel, pollution free, and uses any fuel. PDF icon deer08_zajac.pdf More Documents & Publications Impact of Biodiesel Metals on the

  18. Vehicle Technologies Office: Fuel Effects on Advanced Combustion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Efficiency & Emissions » Vehicle Technologies Office: Fuel Effects on Advanced Combustion Vehicle Technologies Office: Fuel Effects on Advanced Combustion More than 90 percent of transportation relies on petroleum-based fuels: gasoline and diesel. While alternative fuels and plug-in electric vehicles offer great promise to reduce America's petroleum consumption, petroleum-based fuels are likely to play a substantial role for years to come. However, the sources

  19. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  20. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  1. Chlorine induced corrosion of steels in fossil fuel power plants

    SciTech Connect (OSTI)

    Spiegel, M.; Grabke, H.J.

    1998-12-31

    The corrosion of steels in power plants (coal combustion, waste incineration) is mainly due to condensed chlorides in the ash deposited on the boiler tubes. These chlorides are stabilized by HCl in the combustion gas. In the case of coal as a fuel, chlorine is present as chloride minerals in the raw material which is converted to HCl during the combustion process. Corrosion of steels in chlorine containing environments occurs by the active oxidation mechanism, which is a self-sustaining accelerated oxidation process, catalyzed by chlorine. This study shows that solid chlorides react with the oxide scale of the steels to form chlorine, which initiates active oxidation. In order to prevent chlorine induced corrosion, the deposition of chlorides on the tubes within the coal ash must be avoided. This is possible by the presence of SO{sub 2}, which is present in the combustion gas, converting the chlorides to sulfates in the gas phase. The paper presents an example of a failure case in a coal fired plant in Germany. In this plant, chlorine induced corrosion was observed after effective removal of SO{sub 2} by additions of CaO. From thermodynamic calculations it can be shown that a certain amount of SO{sub 2} is necessary in order to avoid deposition of chlorides and to prevent corrosion.

  2. High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Fuel Reactivity Controlled Compression Ignition Combustion High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion An optimized dual-fuel PCCI concept, RCCI, is proposed. PDF icon deer10_reitz.pdf More Documents & Publications Effect of Compression Ratio and Piston Geometry on RCCI load limit Optimization of Advanced Diesel Engine Combustion Strategies Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI)

  3. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  4. Hydrogen-fueled internal combustion engines.

    SciTech Connect (OSTI)

    Verhelst, S.; Wallner, T.; Energy Systems; Ghent Univ.

    2009-12-01

    The threat posed by climate change and the striving for security of energy supply are issues high on the political agenda these days. Governments are putting strategic plans in motion to decrease primary energy use, take carbon out of fuels and facilitate modal shifts. Taking a prominent place in these strategic plans is hydrogen as a future energy carrier. A number of manufacturers are now leasing demonstration vehicles to consumers using hydrogen-fueled internal combustion engines (H{sub 2}ICEs) as well as fuel cell vehicles. Developing countries in particular are pushing for H{sub 2}ICEs (powering two- and three-wheelers as well as passenger cars and buses) to decrease local pollution at an affordable cost. This article offers a comprehensive overview of H{sub 2}ICEs. Topics that are discussed include fundamentals of the combustion of hydrogen, details on the different mixture formation strategies and their emissions characteristics, measures to convert existing vehicles, dedicated hydrogen engine features, a state of the art on increasing power output and efficiency while controlling emissions and modeling.

  5. Results of studies on application of CCMHD to advanced fossil fuel power plant cycles

    SciTech Connect (OSTI)

    Foote, J.P.; Wu, Y.C.L.S.; Lineberry, J.T.

    1998-07-01

    A study was conducted to assess the potential for application of a Closed Cycle MHD disk generator (CCMHD) in advanced fossil fuel power generation systems. Cycle analyses were conducted for a variety of candidate power cycles, including simple cycle CCMHD (MHD); a cycle combining CCMHD and gas turbines (MHD/GT); and a triple combined cycle including CCMHD, gas turbines, and steam turbines (MHD/GT/ST). The above cycles were previously considered in cycle studies reported by Japanese researchers. Also considered was a CCMHD cycle incorporating thermochemical heat recovery through reforming of the fuel stream (MHD/REF), which is the first consideration of this approach. A gas turbine/steam turbine combined cycle (GT/ST) was also analyzed for baseline comparison. The only fuel considered in the study was CH4. Component heat and pressure losses were neglected, and the potential for NOx emission due to high combustion temperatures was not considered. Likewise, engineering limitations for cycle components, particularly the high temperature argon heater, were not considered. This approach was adopted to simplify the analysis for preliminary screening of candidate cycles. Cycle calculations were performed using in-house code. Ideal gas thermodynamic properties were calculated using the NASA SP- 273 data base, and thermodynamic properties for steam were calculated using the computerized ASME Steam Tables. High temperature equilibrium compositions for combustion gas were calculated using tabulated values of the equilibrium constants for the important reactions.

  6. Synthetic fuel aromaticity and staged combustion

    SciTech Connect (OSTI)

    Longanbach, J. R.; Chan, L. K.; Levy, A.

    1982-11-15

    Samples of middle and heavy SRC-II distillates were distilled into 50 C boiling point range fractions. These were characterized by measurements of their molecular weight, elemental analysis and basic nitrogen content and calculation of average molecular structures. The structures typically consisted of 1 to 3 aromatic rings fused to alicyclic rings with short, 1 to 3 carbon aliphatic side chains. The lower boiling fractions contained significant amounts (1 atom/molecule) of oxygen while the heavier fractions contained so few heteroatoms that they were essentially hydrocarbons. Laboratory scale oxidative-pyrolysis experiments were carried out at pyrolysis temperatures of 500 to 1100 C and oxygen concentrations from 0 to 100 percent of stoichiometry. Analysis of liquid products, collected in condensers cooled with liquid nitrogen showed that aromatization is a major reaction in the absence of oxygen. The oxygen-containing materials (phenolics) seem to be more resistant to thermal pyrolysis than unsubstituted aromatics. Nitrogen converts from basic to nonbasic forms at about 500 C. The nonbasic nitrogen is more stable and survives up to 700 C after which it is slowly removed. A recently constructed 50,000 Btu/hr staged combustor was used to study the chemistry of the nitrogen and aromatics. SRC II combustion was studied under fuel-rich, first-stage conditions at air/fuel ratios from 0.6 to 1.0 times stoichiometric. The chemistry of the fuel during combustion calls for further investigation in order to examine the mechanism by which HCN is evolved as a common intermediate for the formation of the nitrogen-containing gaseous combustion products. 25 references, 45 figures, 25 tables.

  7. CO2 Emissions from Fuel Combustion | Open Energy Information

    Open Energy Info (EERE)

    from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References "CO2 Emissions from Fuel Combustion" Retrieved from "http:...

  8. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal-Derived Liquids to Enable HCCI Technology Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing ...

  9. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  10. Fossil fuel-fired peak heating for geothermal greenhouses

    SciTech Connect (OSTI)

    Rafferty, K.

    1996-12-01

    This report examines the capital and operating costs for fossil fuel-fired peak heating systems in geothermally (direct use) heated greenhouses. Issues covered include equipment capital costs, fuel requirements, maintenance and operating costs, system control and integration into conventional hot water greenhouse heating systems. Annual costs per square foot of greenhouse floor area are developed for three climates: Helena, MT; Klamath Falls, OR and San Bernardino, CA, for both boiler and individual unit heater peaking systems. In most applications, peaking systems sized for 60% of the peak load are able to satisfy over 95% of the annual heating requirements and cost less than $0.15 per square foot per year to operate. The propane-fired boiler system has the least cost of operation in all but Helena, MT climate.

  11. Carbonaceous fuel combustion with improved desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Shen, Ming-shing (Rocky Point, NY)

    1980-01-01

    Lime utilization for sulfurous oxides adsorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. The iron oxide present in the spent limestone is found to catalyze the regeneration rate of the spent limestone in a reducing environment. Thus both the calcium and iron components may be recycled.

  12. Mitigating environmental pollution and impacts from fossil fuels: The role of alternative fuels

    SciTech Connect (OSTI)

    Liu, L.; Cheng, S.Y.; Li, J.B.; Huang, Y.F.

    2007-07-01

    In order to meet the rising global demand for energy, rapid development of conventional fossil fuels (i.e., coal, oil, and natural gas) have been experienced by many nations, bringing dramatic economic benefit and prosperity to fossil-fuel industries as well as well being of human society. However, various fossil-fuel related activities emit huge quantities of gaseous, liquid, and solid waste materials, posing a variety of impacts, risks, and liabilities to the environment. Therefore, on the one hand, control measures are desired for effectively managing pollution issues; on the other hand, it becomes extremely critical to invest efforts in finding promising alternative energy sources as solutions to the possible energy shortage crisis in future. This article focuses on both aspects through: (1) a discussion of waste materials generated from fossil-fuel industries and waste management measures; and (2) an exploration of some well-recognized alternative fuels in terms of their nature, availability, production, handling, environmental performances, and current and future applications. The conclusion restates the urgency of finding replaceable long-term alternatives to the conventional fuels.

  13. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and

    Energy Savers [EERE]

    Large Scale Variable Renewable Integration Now Available | Department of Energy EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration Now Available EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration Now Available October 15, 2015 - 3:31pm Addthis A new report "Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration" from the

  14. Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the

    Office of Scientific and Technical Information (OSTI)

    United States (Journal Article) | SciTech Connect Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States Citation Details In-Document Search Title: Spatial Relationships of Sector-Specific Fossil-fuel CO2 Emissions in the United States Quantification of the spatial distribution of sector-specific fossil fuel CO2 emissions provides strategic information to public and private decision-makers on climate change mitigation options and can provide critical

  15. EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes

    Office of Environmental Management (EM)

    and Large Scale Variable Renewable Integration | Department of Energy EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration October 15, 2015 - 8:58am Addthis A new report, "Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration" from the Electric Power Research

  16. Oxy-Combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxy-combustion-is a promising technology for capturing carbon dioxide (CO2) from fossil fuel power plants, and reducing greenhouse gas emissions. However, the cost, energy...

  17. oxy-combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rates are increased ...increases efficiency. Equipment size is reduced ...decreases capital cost. No air in-leakage ...increases CO2 purity. The combustion of fossil fuels in...

  18. N.R. 20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS...

    Office of Scientific and Technical Information (OSTI)

    20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; 14 SOLAR ENERGY; 15 GEOTHERMAL ENERGY; GEOTHERMAL POWER PLANTS; COMPUTERIZED SIMULATION; HEAT...

  19. Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    ACI Committee 229 Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; FLY ASH; WASTE PRODUCT UTILIZATION; BACKFILLING; THERMAL...

  20. Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION...

    Office of Scientific and Technical Information (OSTI)

    carbon capture, utilisation, and storage Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION; POWER GENERATION; CARBON DIOXIDE; CAPTURE; STORAGE; USA; ENHANCED...

  1. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Large Scale Variable Renewable Integration Now Available EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration ...

  2. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  3. Nitrogen/oxygen separations in metal-organic frameworks for clean fossil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fuel combustion | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Nitrogen/oxygen separations in metal-organic frameworks for clean fossil fuel combustion

  4. Factors Affecting HCCI Combustion Phasing for Fuels with Single- and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dual-Stage Chemistry | Department of Energy Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sandia National Laboratories PDF icon 2004_deer_dec.pdf More Documents & Publications Microsoft PowerPoint - DEER03-P.ppt HCCI and Stratified-Charge CI Engine Combustion Research Improving Efficiency and

  5. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  6. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  7. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled ``Clean Uses of Fossil Fuels.`` was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  8. Pilot fuel ignited stratified charge rotary combustion engine and fuel injector therefor

    SciTech Connect (OSTI)

    Loyd, R. W.

    1980-02-12

    For a pilot fuel ignited stratified charge rotary, internal combustion engine, the fuel injection system and a fuel injector therefor comprises a fuel injector having plural discharge ports with at least one of the discharge ports located to emit a ''pilot'' fuel charge (relatively rich fuel-air mixture) into a passage in the engine housing, which passage communicates with the engine combustion chambers. An ignition element is located in the passage to ignite the ''pilot'' fuel (a relatively rich fuel-air mixture) flowing through the passage. At least one other discharge port of the fuel injector is in substantially direct communication with the combustion chambers of the engine to emit a main fuel charge into the latter. The ignited ''pilot'' fuelair mixture, when ignited, flashes into the combustion chambers to ignite the main, relatively lean, fuel-air mixture which is in the combustion chambers.

  9. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  10. Fuel properties to enable lifted-flame combustion

    SciTech Connect (OSTI)

    Kurtz, Eric

    2015-03-15

    The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enable LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental understanding of flame lift-off, generate model validation data, and demonstrate LLFC concurrent with FMC efforts. Additionally, LLNL was added to the project during the second year to develop a detailed kinetic mechanism for a key oxygenate to support CFD modeling. Successful completion of this project allowed the team to enhance fundamental understanding of LLFC, improve the state of current combustion models and increase understanding of desired fuel properties. This knowledge also improves our knowledge of how cost effective and environmentally friendly renewable fuels can assist in helping meet future emission and greenhouse gas regulations.

  11. Advanced Combustion and Fuels; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Zigler, Brad

    2015-06-08

    Presented at the U.S. Department of Energy Vehicle Technologies Office 2015 Annual Merit Review and Peer Evaluation Meeting, held June 8-12, 2015, in Arlington, Virginia. It addresses technical barriers of inadequate data and predictive tools for fuel and lubricant effects on advanced combustion engines, with the strategy being through collaboration, develop techniques, tools, and data to quantify critical fuel physico-chemical effects to enable development of advanced combustion engines that use alternative fuels.

  12. Fuels For Advanced Combustion Engines (FACE) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For Advanced Combustion Engines (FACE) Fuels For Advanced Combustion Engines (FACE) 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_02_sluder.pdf More Documents & Publications Statistical Overview of 5 Years of HCCI Fuel and Engine Data from ORNL Efficient Emissions Control for Multi-Mode Lean DI Engines Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies

  13. Refractory failure in IGCC fossil fuel power systems

    SciTech Connect (OSTI)

    Dogan, Cynthia P.; Kwong, Kyei-Sing; Bennett, James P.; Chinn, Richard E.

    2001-01-01

    Current generation refractory materials used in slagging gasifiers employed in Integrated Gasification Combined Cycle (IGCC) fossil fuel power systems have unacceptably short service lives, limiting the reliability and cost effectiveness of gasification as a means to generate power. The short service life of the refractory lining results from exposure to the extreme environment inside the operating gasifier, where the materials challenges include temperatures to 1650 C, thermal cycling, alternating reducing and oxidizing conditions, and the presence of corrosive slags and gases. Compounding these challenges is the current push within the industry for fuel flexibility, which results in slag chemistries and operating conditions that can vary widely as the feedstock for the gasifier is supplemented with alternative sources of carbon, such as petroleum coke and biomass. As a step toward our goal of developing improved refractory materials for this application, we have characterized refractory-slag interactions, under a variety of simulated gasifier conditions, utilizing laboratory exposure tests such as the static cup test and a gravimetric test. Combining this information with that gained from the post-mortem analyses of spent refractories removed from working gasifiers, we have developed a better understanding of refractory failure in gasifier environments. In this paper, we discuss refractory failures in slagging gasifiers and possible strategies to reduce them. Emphasis focuses on the refractories employed in gasifier systems which utilize coal as the primary feedstock.

  14. Chapter 4. Fuel Economy, Consumption and Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    national concerns about dependence on foreign oil and the deleterious effect on the environment of fossil fuel combustion, residential vehicle fleet fuel consumption was...

  15. A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels in a Modern DI Diesel Engine | Department of Energy A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A single-cylinder engine was used to study how selected oxygenated fuels affect combustion and emissions in a modern diesel engine during conventional combustion and low-temperature combustion (LTC). PDF icon

  16. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions | Department of Energy Statistical Overview of 5 Years of HCCI Fuel and Engine Data from ORNL Response of Oil Sands Derived Fuels in Diesel HCCI Operation Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine

  17. Engine combustion control at low loads via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2014-10-07

    A compression ignition (diesel) engine uses two or more fuel charges during a combustion cycle, with the fuel charges having two or more reactivities (e.g., different cetane numbers), in order to control the timing and duration of combustion. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot). At low load and no load (idling) conditions, the aforementioned results are attained by restricting airflow to the combustion chamber during the intake stroke (as by throttling the incoming air at or prior to the combustion chamber's intake port) so that the cylinder air pressure is below ambient pressure at the start of the compression stroke.

  18. Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Unmanned Undersea Vehicles | Department of Energy Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned Undersea Vehicles Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned Undersea Vehicles January 31, 2013 - 12:00pm Addthis An unmanned undersea vehicle (UUV) being deployed during a U.S. Office of Naval Research demonstration near Panama City. Solid oxide fuel cell technology being developed by the Office of Fossil

  19. Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean-Combustion Engines | Department of Energy Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft004_mueller_2013_o.pdf More Documents & Publications Fuels and Combustion Strategies for High-Efficiency Clean-Combustion

  20. Hydrogen-or-Fossil-Combustion Nuclear Combined-Cycle Systems for Base- and Peak-Load Electricity Production

    SciTech Connect (OSTI)

    Forsberg, Charles W; Conklin, Jim

    2007-09-01

    A combined-cycle power plant is described that uses (1) heat from a high-temperature nuclear reactor to meet base-load electrical demands and (2) heat from the same high-temperature reactor and burning natural gas, jet fuel, or hydrogen to meet peak-load electrical demands. For base-load electricity production, fresh air is compressed; then flows through a heat exchanger, where it is heated to between 700 and 900 C by heat provided by a high-temperature nuclear reactor via an intermediate heat-transport loop; and finally exits through a high-temperature gas turbine to produce electricity. The hot exhaust from the Brayton-cycle gas turbine is then fed to a heat recovery steam generator that provides steam to a steam turbine for added electrical power production. To meet peak electricity demand, the air is first compressed and then heated with the heat from a high-temperature reactor. Natural gas, jet fuel, or hydrogen is then injected into the hot air in a combustion chamber, combusts, and heats the air to 1300 C-the operating conditions for a standard natural-gas-fired combined-cycle plant. The hot gas then flows through a gas turbine and a heat recovery steam generator before being sent to the exhaust stack. The higher temperatures increase the plant efficiency and power output. If hydrogen is used, it can be produced at night using energy from the nuclear reactor and stored until needed. With hydrogen serving as the auxiliary fuel for peak power production, the electricity output to the electric grid can vary from zero (i.e., when hydrogen is being produced) to the maximum peak power while the nuclear reactor operates at constant load. Because nuclear heat raises air temperatures above the auto-ignition temperatures of the various fuels and powers the air compressor, the power output can be varied rapidly (compared with the capabilities of fossil-fired turbines) to meet spinning reserve requirements and stabilize the electric grid. This combined cycle uses the unique characteristics of high-temperature reactors (T>700 C) to produce electricity for premium electric markets whose demands can not be met by other types of nuclear reactors. It may also make the use of nuclear reactors economically feasible in smaller electrical grids, such as those found in many developing countries. The ability to rapidly vary power output can be used to stabilize electric grid performance-a particularly important need in small electrical grids.

  1. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  2. Investigation of Fuel Quality Impact on the Combustion and Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of a Turbo-Charged SI Engine Operated on Low BTU Gases Investigation of Fuel Quality Impact on the Combustion and Exhaust Emissions of a Turbo-Charged SI Engine Operated on Low ...

  3. High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation

    SciTech Connect (OSTI)

    Steinberg, M; Cooper, J F; Cherepy, N

    2002-01-02

    Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power generation cycles are: (1) increased efficiency by a factor of up to 2 over many conventional fossil fuel steam plants, (2) reduced power generation cost, especially for increasing fossil fuel cost, (3) reduced CO2 emission per kWh, and (4) direct sequestration or reuse (e.g., in enhanced oil or NG recovery) of the CO{sub 2} product.

  4. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 13159553.pdf (405 KB) Technology Marketing Summary This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen

  5. Catalyst for Improving the Combustion Efficiency of Petroleum Fuels in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines Catalyst for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_hirs.pdf More Documents & Publications Greenpower Trap Mufflerl System BILIWG: Consistent "Figures of Merit" (Presentation) GNEP Element:Demonstrate More Proliferation-Resistant

  6. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However, the strength of the secondary flow is found nearly the same behind the first and the second vortex generator pair as well as far from the second vortex generator pair in the case of Duct2. Both ducts are able to create a counter-rotating and a second set of twin foci. Duct2 is able to create the second set of twin foci in an earlier streamwise location than Duct1, as these foci are well-known to their heat transfer augmentation. A larger vortex formation area and a greater induced vorticity field between vortex pairs are observed for Duct2 compared with Duct1. As the induced flow field between the vortex pairs increases the heat transfer, and as the flow field between the vortex cores is found larger in the case of Duct2, therefore, it is expected to obtain better heat transfer characteristics for Duct2 compared with Duct1. (author)

  7. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Map Appendix State/area maps Figure A1. Fossil fuel production on federal and Indian lands, FY 2014 Source: U.S. Energy Information Administration based on U.S. Department of the Interior, Office of Natural Resources Revenue. "ONNR Statistical Information Site" (http://statistics.onrr.gov). July 2015 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2014 24 Figure A2. Changes in fossil fuels production (trillion

  8. Effect of air distribution on solid fuel bed combustion

    SciTech Connect (OSTI)

    Kuo, J.T.; Hsu, W.S.; Yo, T.C.

    1996-09-01

    One important aspect of refuse mass-burn combination control is the manipulation of combustion air. Proper air manipulation is key to the achievement of good combustion efficiency and reduction of pollutant emissions. Experiments, using a small fix-grate laboratory furnace with cylindrical combustion chamber, were performed to investigate the influence of undergrate/sidewall air distribution on the combustion of beds of wood cubes. Wood cubes were used as a convenient laboratory surrogate of solid refuse. Specifically, for different bed configurations (e.g. bed height, bed voidage and bed fuel size, etc.), burning rates and combustion temperatures at different bed locations were measured under various air supply and distribution conditions. One of the significant results of the experimental investigation is that combustion, with air injected from side walls and no undergrate air, provide the most efficient combustion. On the other hand, combustion with undergrate air achieves higher combustion rates but with higher CO emissions. A simple one-dimensional model was constructed to derive correlations of combustion rate as functions of flue gas temperature and oxygen concentration. Despite the fact that the model is one dimensional and many detailed chemical and physical processes of combustion are not considered, comparisons of the model predictions and the experimental results indicate that the model is appropriate for quantitative evaluation of bed burning rates.

  9. Investigation of Fuel Quality Impact on the Combustion and Exhaust

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions of a Turbo-Charged SI Engine Operated on Low BTU Gases | Department of Energy Fuel Quality Impact on the Combustion and Exhaust Emissions of a Turbo-Charged SI Engine Operated on Low BTU Gases Investigation of Fuel Quality Impact on the Combustion and Exhaust Emissions of a Turbo-Charged SI Engine Operated on Low BTU Gases Research results validate an engine simulation model and provide guidelines for the improved control of combustion stability of SI engines operated on low-BTU

  10. Solid fuel combustion system for gas turbine engine

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN)

    1993-01-01

    A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

  11. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  12. OXIDATION OF FUELS IN THE COOL FLAME REGIME FOR COMBUSTION AND REFORMING FOR FUEL CELLS.

    SciTech Connect (OSTI)

    NAIDJA,A.; KRISHNA,C.R.; BUTCHER,T.; MAHAJAN,D.

    2002-08-01

    THE REVIEW INTEGRATES RECENT INVESTIGATIONS ON AUTO OXIDATION OF FUEL OILS AND THEIR REFORMING INTO HYDROGEN RICH GAS THAT COULD SERVE AS A FEED FOR FUEL CELLS AND COMBUSTION SYSTEMS.

  13. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M.

    2008-07-01

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  14. Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    Liquid-fluidized-bed heat exchanger flow distribution models Cole, L.T.; Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS; FLUIDIZED BED HEAT EXCHANGERS; DESIGN;...

  15. fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED...

    Office of Scientific and Technical Information (OSTI)

    draft fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 42 ENGINEERING NOT INCLUDED IN OTHER...

  16. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Broader source: Energy.gov [DOE]

    This paper was prepared in response to recent requests that the U.S. Energy Information Administration (EIA) provide updated summary information regarding fossil fuel production on federal and...

  17. Impacts of Renewable Generation on Fossil Fuel Unit Cycling: Costs and Emissions (Presentation)

    SciTech Connect (OSTI)

    Brinkman, G.; Lew, D.; Denholm, P.

    2012-09-01

    Prepared for the Clean Energy Regulatory Forum III, this presentation looks at the Western Wind and Solar Integration Study and reexamines the cost and emissions impacts of fossil fuel unit cycling.

  18. Stratified charge combustion system and method for gaseous fuel internal combustion engines

    SciTech Connect (OSTI)

    Rhoades, W.A. Jr.

    1986-03-11

    This patent describes a stratified charge combustion system for use in a gaseous fuel internal combustion engine. This system consists of: (a) a combustion chamber; (b) an ignition; (c) a gaseous fuel injection valve assembly in communication with the combustion chamber and in spaced relationship from the ignition source with a portion of the inside surfaces extending between the fuel injection valve assembly and the ignition source. The fuel valve assembly defines an entry port for the entrance of gaseous fuel, the entry port is recessed outside of a fixed inside surface. (d) means for pressuring the gaseous fuel prior to injection; and (e) a curved transitional surface extending from the entry port toward the portion of the inside surfaces extending between the fuel injection valve assembly and the ignition source. The curved transitional surface curves away from the direction of the entry port. The curved transitional surface has a curvature for the particular direction and configuration of the entry port. The particular configuration of the portion of the inside surfaces extends between the injection valve assembly and the ignition source. The particular arrangment of the fuel injection valve assembly in the combustion chamber, and for the particular pressure of the gaseous fuel is to produce the Coanda Effect in the injected gaseous fuel flow after it passes through the entry port and follows the curved transitional surface under the Coanda Effect. As the curved transitional surface curves away from the direction of the entry port, a flow is produced of the gaseous fuel that clings to and follows the particular configuration of the inside surfaces to the ignition source.

  19. FUEL INTERCHANGEABILITY FOR LEAN PREMIXED COMBUSTION IN GAS TURBINE ENGINES

    SciTech Connect (OSTI)

    Don Ferguson; Geo. A. Richard; Doug Straub

    2008-06-13

    In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for todays engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.

  20. Superheated fuel injection for combustion of liquid-solid slurries

    DOE Patents [OSTI]

    Robben, F.A.

    1984-10-19

    A method and device are claimed for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal. 2 figs., 2 tabs.

  1. Superheated fuel injection for combustion of liquid-solid slurries

    DOE Patents [OSTI]

    Robben, Franklin A. (Berkeley, CA)

    1985-01-01

    A method and device for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal.

  2. A combustion model for IC engine combustion simulations with multi-component fuels

    SciTech Connect (OSTI)

    Ra, Youngchul; Reitz, Rolf D.

    2011-01-15

    Reduced chemical kinetic mechanisms for the oxidation of representative surrogate components of a typical multi-component automotive fuel have been developed and applied to model internal combustion engines. Starting from an existing reduced mechanism for primary reference fuel (PRF) oxidation, further improvement was made by including additional reactions and by optimizing reaction rate constants of selected reactions. Using a similar approach to that used to develop the reduced PRF mechanism, reduced mechanisms for the oxidation of n-tetradecane, toluene, cyclohexane, dimethyl ether (DME), ethanol, and methyl butanoate (MB) were built and combined with the PRF mechanism to form a multi-surrogate fuel chemistry (MultiChem) mechanism. The final version of the MultiChem mechanism consists of 113 species and 487 reactions. Validation of the present MultiChem mechanism was performed with ignition delay time measurements from shock tube tests and predictions by comprehensive mechanisms available in the literature. A combustion model was developed to simulate engine combustion with multi-component fuels using the present MultiChem mechanism, and the model was applied to simulate HCCI and DI engine combustion. The results show that the present multi-component combustion model gives reliable performance for combustion predictions, as well as computational efficiency improvements through the use of reduced mechanism for multi-dimensional CFD simulations. (author)

  3. Compounded turbocharged rotary internal combustion engine fueled with natural gas

    SciTech Connect (OSTI)

    Jenkins, P.E.

    1992-10-15

    This patent describes a compounded engine. It comprises: a first Wankel engine having a housing with a trochoidal inner surface containing a generally triangular shaped rotor, the engine containing a fuel supply system suitable for operating the engine with natural gas as a fuel; a turbocharge compressing air for combustion by the engine, the turbocharger being driven by the exhaust gases which exit from the engine; a combustion chamber in fluid communication with the exhaust from the engine after that exhaust has passed through the turbocharger, the chamber having an ignition device suitable for igniting hydrocarbons in the engine exhaust, whereby the engine timing, and the air and fuel mixture of the engine are controlled so that when the engine exhaust reaches the combustion chamber the exhaust contains a sufficient amount of oxygen and hydrocarbons to enable ignition and combustion of the engine exhaust in the combustion chamber without the addition of fuel or air, and whereby the engine operating conditions are controlled to vary the performance of the secondary combustor; and a controllable ignition device to ignite the exhaust gases in the combustion chamber at predetermined times.

  4. Accelerating the Computation of Detailed Chemical Reaction Kinetics for Simulating Combustion of Complex Fuels

    SciTech Connect (OSTI)

    Grout, Ray W

    2012-01-01

    Combustion of hydrocarbon fuels has been a very challenging scientific and engineering problem due to the complexity of turbulent flows and hydrocarbon reaction kinetics. There is an urgent need to develop an efficient modeling capability to accurately predict the combustion of complex fuels. Detailed chemical kinetic models for the surrogates of fuels such as gasoline, diesel and JP-8 consist of thousands of chemical species and Arrhenius reaction steps. Oxygenated fuels such as bio-fuels and heavier hydrocarbons, such as from newer fossil fuel sources, are expected to have a much more complex chemistry requiring increasingly larger chemical kinetic models. Such models are beyond current computational capability, except for homogeneous or partially stirred reactor type calculations. The advent of highly parallel multi-core processors and graphical processing units (GPUs) promises a steep increase in computational performance in the coming years. This paper will present a software framework that translates the detailed chemical kinetic models to high- performance code targeted for GPU accelerators.

  5. Apparatus and method for combusting low quality fuel

    DOE Patents [OSTI]

    Brushwood, John Samuel; Pillsbury, Paul; Foote, John; Heilos, Andreas

    2003-11-04

    A gas turbine (12) capable of combusting a low quality gaseous fuel having a ratio of flammability limits less than 2, or a heat value below 100 BTU/SCF. A high quality fuel is burned simultaneously with the low quality fuel to eliminate instability in the combustion flame. A sensor (46) is used to monitor at least one parameter of the flame indicative of instability. A controller (50) having the sensor signal (48) as input is programmed to control the relative flow rates of the low quality and high quality fuels. When instability is detected, the flow rate of high quality fuel is automatically increased in relation to the flow rate of low quality fuel to restore stability.

  6. Oxy-fuel combustion with integrated pollution control

    DOE Patents [OSTI]

    Patrick, Brian R. (Chicago, IL); Ochs, Thomas Lilburn (Albany, OR); Summers, Cathy Ann (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul Chandler (Independence, OR)

    2012-01-03

    An oxygen fueled integrated pollutant removal and combustion system includes a combustion system and an integrated pollutant removal system. The combustion system includes a furnace having at least one burner that is configured to substantially prevent the introduction of air. An oxygen supply supplies oxygen at a predetermine purity greater than 21 percent and a carbon based fuel supply supplies a carbon based fuel. Oxygen and fuel are fed into the furnace in controlled proportion to each other and combustion is controlled to produce a flame temperature in excess of 3000 degrees F. and a flue gas stream containing CO2 and other gases. The flue gas stream is substantially void of non-fuel borne nitrogen containing combustion produced gaseous compounds. The integrated pollutant removal system includes at least one direct contact heat exchanger for bringing the flue gas into intimated contact with a cooling liquid to produce a pollutant-laden liquid stream and a stripped flue gas stream and at least one compressor for receiving and compressing the stripped flue gas stream.

  7. Surrogate Model Development for Fuels for Advanced Combustion Engines

    SciTech Connect (OSTI)

    Anand, Krishnasamy; Ra, youngchul; Reitz, Rolf; Bunting, Bruce G

    2011-01-01

    The fuels used in internal-combustion engines are complex mixtures of a multitude of different types of hydrocarbon species. Attempting numerical simulations of combustion of real fuels with all of the hydrocarbon species included is highly unrealistic. Thus, a surrogate model approach is generally adopted, which involves choosing a few representative hydrocarbon species whose overall behavior mimics the characteristics of the target fuel. The present study proposes surrogate models for the nine fuels for advanced combustion engines (FACE) that have been developed for studying low-emission, high-efficiency advanced diesel engine concepts. The surrogate compositions for the fuels are arrived at by simulating their distillation profiles to within a maximum absolute error of 4% using a discrete multi-component (DMC) fuel model that has been incorporated in the multi-dimensional computational fluid dynamics (CFD) code, KIVA-ERC-CHEMKIN. The simulated surrogate compositions cover the range and measured concentrations of the various hydrocarbon classes present in the fuels. The fidelity of the surrogate fuel models is judged on the basis of matching their specific gravity, lower heating value, hydrogen/carbon (H/C) ratio, cetane number, and cetane index with the measured data for all nine FACE fuels.

  8. 2004 Office of Fossil Energy Fuel Cell Program Annual Report

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Annual report of fuel cell projects sponsored by Department of Energy, National Energy Technology Laboratory.

  9. Pulsating catalytic combustion of gaseous fuels

    SciTech Connect (OSTI)

    Gal-Ed, R.

    1988-01-01

    This study investigated the feasibility of operating catalytic combustors under pulsating conditions and the circumstances under which acoustic pulsations increase the combustion efficiencies and output of catalytic combustors. An experimental catalytic combustor was developed, and a theoretical model of acoustic motions in non-isothermal, low match number, duct flow was used to predict the acoustic behavior of the combustor. The effects of pulsations were determined by comparing temperature and species concentration data measured during operation with pulsations at different frequencies and pressure amplitudes to similar data measured during non-pulsating combustion. Experiments conducted with lean mixtures of methane or propane with air revealed that acoustic pulsations affected the temperature distribution along the combustor at flow Reynolds numbers less than 17,500. Excitation of pulsations during methane combustion caused shifts in the location of the combustion, and sometimes the onset of extinction of gas phase reactions. This occurred when several catalyst segments were located in the combustion section between an upstream pressure node and a downstream velocity node, defined here as an in phase location. Propane mixtures were used to investigate possible improvements in combustor's performance. Burning propane mixtures on a single catalyst segment at an in phase location showed that the excitation of acoustic pulsations increased the combustion efficiency by 10 to 50%. The changes in the operation of catalytic combustors caused by acoustic waves are explained by acoustic streaming. When the catalyst surfaces are at an in phase location, rotational flows caused by acoustic streaming enhance the reactants and products diffusion rate to and from the catalyst surfaces, respectively, improving combustion efficiency.

  10. Fuel Modification t Facilitate Future Combustion Regimes? | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Modification t Facilitate Future Combustion Regimes? Fuel Modification t Facilitate Future Combustion Regimes? 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_foster.pdf More Documents & Publications Are There Practical Approaches for Achieving the Theoretical Maximum Engine Efficiency? HCCI - A Technical Review and Progress Report 2006 Vehicle Technologies Office Merit Review 2015: RCM Studies to Enable Gasoline-Relevant Low

  11. Intelligent emissions controller for substance injection in the post-primary combustion zone of fossil-fired boilers

    DOE Patents [OSTI]

    Reifman, Jaques (Western Springs, IL); Feldman, Earl E. (Willowbrook, IL); Wei, Thomas Y. C. (Downers Grove, IL); Glickert, Roger W. (Pittsburgh, PA)

    2003-01-01

    The control of emissions from fossil-fired boilers wherein an injection of substances above the primary combustion zone employs multi-layer feedforward artificial neural networks for modeling static nonlinear relationships between the distribution of injected substances into the upper region of the furnace and the emissions exiting the furnace. Multivariable nonlinear constrained optimization algorithms use the mathematical expressions from the artificial neural networks to provide the optimal substance distribution that minimizes emission levels for a given total substance injection rate. Based upon the optimal operating conditions from the optimization algorithms, the incremental substance cost per unit of emissions reduction, and the open-market price per unit of emissions reduction, the intelligent emissions controller allows for the determination of whether it is more cost-effective to achieve additional increments in emission reduction through the injection of additional substance or through the purchase of emission credits on the open market. This is of particular interest to fossil-fired electrical power plant operators. The intelligent emission controller is particularly adapted for determining the economical control of such pollutants as oxides of nitrogen (NO.sub.x) and carbon monoxide (CO) emitted by fossil-fired boilers by the selective introduction of multiple inputs of substances (such as natural gas, ammonia, oil, water-oil emulsion, coal-water slurry and/or urea, and combinations of these substances) above the primary combustion zone of fossil-fired boilers.

  12. Advanced Combustion Engine R&D and Fuels Technology Merit Review |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Advanced Combustion Engine R&D and Fuels Technology Merit Review Advanced Combustion Engine R&D and Fuels Technology Merit Review Merit review of DOE FCVT combustion, emission control, health impacts, and fuels research. PDF icon Annual Progress Report More Documents & Publications Heavy Vehicle Systems Optimization Peer Review 2008 Annual Merit Review Results Summary - 7. Combustion Research 2012 Annual Merit Review Results Report - Advanced Combustion

  13. Method and system for low-NO.sub.x dual-fuel combustion of liquid and/or gaseous fuels

    DOE Patents [OSTI]

    Gard, Vincent; Chojnacki, Dennis A; Rabovitser, Ioseph K

    2014-12-02

    A method and apparatus for combustion in which a pressurized preheated liquid fuel is atomized and a portion thereof flash vaporized, creating a mixture of fuel vapor and liquid droplets. The mixture is mixed with primary combustion oxidant, producing a fuel/primary oxidant mixture which is then injected into a primary combustion chamber in which the fuel/primary oxidant mixture is partially combusted, producing a secondary gaseous fuel containing hydrogen and carbon oxides. The secondary gaseous fuel is mixed with a secondary combustion oxidant and injected into the second combustion chamber wherein complete combustion of the secondary gaseous fuel is carried out. The resulting second stage flue gas containing very low amounts of NO.sub.x is then vented from the second combustion chamber.

  14. Alcohol Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Fuels Alcohol Fuels Goals Advance a multiscale approach to collaborative reaction kinetic model development and validation, by focusing team efforts on particular alcohol fuels. The team's initial focus has been on n-butanol. This has recently broadened to include detailed kinetic modeling of other isomeric butanols, plus some comparisons with smaller alcohols and the corresponding ketones, aldehydes, and enols. In the future we expect to use what we have learned from the butanol study

  15. Plasmatron Fuel Reformer Development and Internal Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasmatron Generation of Hydrogen rich Gas for Diesel Aftertreatment and Other Applications A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration and Desulfation

  16. Standard for the qualification of high capacity fossil fuel fired plant operators

    SciTech Connect (OSTI)

    Axtman, W.

    1996-12-31

    The American Society of Mechanical Engineers, at the request of the U.S. Environmental Protection Agency (EPA) and, in recognition of the needs and benefits associated with standard qualifications of operators of high capacity fossil fuel fired plants, established the Qualifications of High Capacity Fossil Fuel Fired Operator (QFO) Committee in 1994. The purpose of the QFO Committee is to develop and maintain such a standard for operators. This standard includes qualifications, duties, responsibilities and the certification requirements for operators as appropriate to The Clean Air Act as amended in 1990 for fossil fuel fired plants with inputs equal to or greater than 10,000 Btu/hr. This Standard does not cover the certification or validation of fossil plant operating procedures, operating practices, facility performance, nor compliance with any particular permit requirement. This standard recognizes the titles or positions to which any particular fossil plant operator may apply, will vary within a facility. Therefore, this standard does not attempt to identify the individual who is required to obtain certification in any class designation. The fossil plant owner is urged to contact the local jurisdiction in which the fossil plant is located in this regard. This standard does not in itself require certification but rather it serves as a means for complying with federal, state, and local regulations which require operators of fossil fuel fired boilers with inputs equal to or greater than 10,000,000 But/hr to be certified. Safety codes and standards are intended to enhance public health and safety. Revisions to this Standard result from committee considerations of factors such as technological advances, new data, and changing environmental and industry needs. Revisions do not imply that previous editions of this standard were inadequate.

  17. Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion in a Light-Duty Diesel Engine Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel Engine Six different fuels were investigated to study the ...

  18. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion

    Office of Scientific and Technical Information (OSTI)

    Engines (Technical Report) | SciTech Connect Technical Report: DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Citation Details In-Document Search Title: DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Research in 2011 was focused on diesel range fuels and diesel combustion and fuels evaluated in 2011 included a series of oxygenated biofuels fuels from University of Maine, oxygenated fuel compounds representing materials which could

  19. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engines (Technical Report) | SciTech Connect DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Citation Details In-Document Search Title: DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Research in 2011 was focused on diesel range fuels and diesel combustion and fuels evaluated in 2011 included a series of oxygenated biofuels fuels from University of Maine, oxygenated fuel compounds representing materials which could be made from

  20. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  1. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters- Fact Sheet 2014

    Broader source: Energy.gov [DOE]

    Fact sheet summarizing a project to develop and demonstrate a full-scale fuel handling and combustion system

  2. Foundation Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foundation Fuels Foundation Fuels Goals Advance a multiscale approach to collaborative reaction kinetic model development with emphasis on the kinetic foundation mechanism of H2/CO/C1-C4 hydrocarbons and oxygenates. Deliverables A suite of theoretical tools and approaches ranging from electronic structure calculations (ab initio, density functional, and partly empirical), reaction rate theory calculations (including variational effects, anharmonicity, and quantum effects), kinetic modeling,

  3. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011 March 2012 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2011 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data,

  4. Apparatus and method for solid fuel chemical looping combustion

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Weber, Justin M

    2015-04-14

    The disclosure provides an apparatus and method utilizing fuel reactor comprised of a fuel section, an oxygen carrier section, and a porous divider separating the fuel section and the oxygen carrier section. The porous divider allows fluid communication between the fuel section and the oxygen carrier section while preventing the migration of solids of a particular size. Maintaining particle segregation between the oxygen carrier section and the fuel section during solid fuel gasification and combustion processes allows gases generated in either section to participate in necessary reactions while greatly mitigating issues associated with mixture of the oxygen carrier with char or ash products. The apparatus and method may be utilized with an oxygen uncoupling oxygen carrier such as CuO, Mn.sub.3O.sub.4, or Co.sub.3O.sub.4, or utilized with a CO/H.sub.2 reducing oxygen carrier such as Fe.sub.2O.sub.3.

  5. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  6. Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    Venkatesan, Krishna

    2011-11-30

    The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to provide experimental combustion data of our target fuels at gas turbine conditions. Based on an initial assessment of premixer design requirements and challenges, the most promising sub-scale premixer concepts were evaluated both experimentally and computationally. After comprehensive screening tests, two best performing concepts were scaled up for further development. High pressure single nozzle tests were performed with the scaled premixer concepts at target gas turbine conditions with opportunity fuels. Single-digit NOx emissions were demonstrated for syngas fuels. Plasma-assisted pilot technology was demonstrated to enhance ignition capability and provide additional flame stability margin to a standard premixing fuel nozzle. However, the impact of plasma on NOx emissions was observed to be unacceptable given the goals of this program and difficult to avoid.

  7. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    SciTech Connect (OSTI)

    Confer, Keith

    2014-09-30

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  8. Municipal solid waste combustion: Fuel testing and characterization

    SciTech Connect (OSTI)

    Bushnell, D.J.; Canova, J.H.; Dadkhah-Nikoo, A.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  9. Combustion characteristics of alternative gaseous fuels

    SciTech Connect (OSTI)

    Park, O.; Veloo, Peter S.; Liu, N.; Egolfopoulos, Fokion N.

    2011-01-01

    Fundamental flame properties of mixtures of air with hydrogen, carbon monoxide, and C{sub 1}C{sub 4} saturated hydrocarbons were studied both experimentally and numerically. The fuel mixtures were chosen in order to simulate alternative gaseous fuels and to gain insight into potential kinetic couplings during the oxidation of fuel mixtures. The studies included the use of the counterflow configuration for the determination of laminar flame speeds, as well as extinction and ignition limits of premixed flames. The experiments were modeled using the USC Mech II kinetic model. It was determined that when hydrocarbons are added to hydrogen flames as additives, flame ignition, propagation, and extinction are affected in a counterintuitive manner. More specifically, it was found that by substituting methane by propane or n-butane in hydrogen flames, the reactivity of the mixture is reduced both under pre-ignition and vigorous burning conditions. This behavior stems from the fact that propane and n-butane produce higher amounts of methyl radicals that can readily recombine with atomic hydrogen and reduce thus the rate of the H + O{sub 2} ? O + OH branching reaction. The kinetic model predicts closely the experimental data for flame propagation and extinction for various fuel mixtures and pressures, and for various amounts of carbon dioxide in the fuel blend. On the other hand, it underpredicts, in general, the ignition temperatures.

  10. CO2 emissions mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine V.; Wada, Kenichi; Van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher and decrease with mitigation. A first deviation from the optimal transition pathway relaxes global emission targets until 2030, in accordance with the Copenhagen pledges and regionally-specific low-carbon technology targets. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger - twice and more - than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear cut across models, as we find carbon leakage effects ranging from positive to negative because leakage and substitution patterns of coal, oil, and gas differ. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  11. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine; Wada, Kenichi; van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  12. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  13. Fuel injector nozzle for an internal combustion engine

    DOE Patents [OSTI]

    Cavanagh, Mark S. (Bloomington, IL); Urven, Jr., Roger L. (Colona, IL); Lawrence, Keith E. (Peoria, IL)

    2007-11-06

    A direct injection fuel injector includes a nozzle tip having a plurality of passages allowing fluid communication between an inner nozzle tip surface portion and an outer nozzle tip surface portion and directly into a combustion chamber of an internal combustion engine. A first group of the passages have inner surface apertures located substantially in a first common plane. A second group of the passages have inner surface apertures located substantially in at least a second common plane substantially parallel to the first common plane. The second group has more passages than the first group.

  14. Fuel Injector Nozzle For An Internal Combustion Engine

    DOE Patents [OSTI]

    Cavanagh, Mark S. (Bloomington, IL); Urven, Jr.; Roger L. (Colona, IL); Lawrence, Keith E. (Peoria, IL)

    2006-04-25

    A direct injection fuel injector includes a nozzle tip having a plurality of passages allowing fluid communication between an inner nozzle tip surface portion and an outer nozzle tip surface portion and directly into a combustion chamber of an internal combustion engine. A first group of the passages have inner surface apertures located substantially in a first common plane. A second group of the passages have inner surface apertures located substantially in at least a second common plane substantially parallel to the first common plane. The second group has more passages than the first group.

  15. Fuel injector nozzle for an internal combustion engine

    DOE Patents [OSTI]

    Cavanagh, Mark S. (Bloomington, IL); Urven, Jr., Roger L. (Colona, IL); Lawrence, Keith E. (Peoria, IL)

    2011-03-22

    A direct injection fuel injector includes a nozzle tip having a plurality of passages allowing fluid communication between an inner nozzle tip surface portion and an outer nozzle tip surface portion and directly into a combustion chamber of an internal combustion engine. A first group of the passages have inner surface apertures located substantially in a first common plane. A second group of the passages have inner surface apertures located substantially in at least a second common plane substantially parallel to the first common plane. The second group has more passages than the first group.

  16. Fuel injector nozzle for an internal combustion engine

    DOE Patents [OSTI]

    Cavanagh, Mark S. (Bloomington, IL); Urven, Jr., Roger L. (Colona, IL); Lawrence, Keith E. (Peoria, IL)

    2008-11-04

    A direct injection fuel injector includes a nozzle tip having a plurality of passages allowing fluid communication between an inner nozzle tip surface portion and an outer nozzle tip surface portion and directly into a combustion chamber of an internal combustion engine. A first group of the passages have inner surface apertures located substantially in a first common plane. A second group of the passages have inner surface apertures located substantially in at least a second common plane substantially parallel to the first common plane. The second group has more passages than the first group.

  17. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  18. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  19. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B.

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  20. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    SciTech Connect (OSTI)

    Lew, D.; Brinkman, G.; Kumar, N.; Besuner, P.; Agan, D.; Lefton, S.

    2012-08-01

    High penetrations of wind and solar power will impact the operations of the remaining generators on the power system. Regional integration studies have shown that wind and solar may cause fossil-fueled generators to cycle on and off and ramp down to part load more frequently and potentially more rapidly. Increased cycling, deeper load following, and rapid ramping may result in wear-and-tear impacts on fossil-fueled generators that lead to increased capital and maintenance costs, increased equivalent forced outage rates, and degraded performance over time. Heat rates and emissions from fossil-fueled generators may be higher during cycling and ramping than during steady-state operation. Many wind and solar integration studies have not taken these increased cost and emissions impacts into account because data have not been available. This analysis considers the cost and emissions impacts of cycling and ramping of fossil-fueled generation to refine assessments of wind and solar impacts on the power system.

  1. Pilot scale production and combustion of liquid fuels from refuse derived fuel (RDF): Part 2

    SciTech Connect (OSTI)

    Klosky, M.K.

    1996-09-01

    EnerTech is developing a process for producing pumpable slurry fuels, comparable to Coal-Water-Fuels (CWF), from solid Refuse Derived Fuels (RDF). Previous reports have described the characteristics of the enhanced carbonized RDF slurry fuels. This paper summarizes those fuel characteristics and reports on the latest combustion tests performed with the final product fuel. The objective of this research was to determine the boiler and emission performance from the carbonized RDF slurry fuel using statistical screening experiments. Eight combustion tests were performed with a pilot scale pulverized coal/oil boiler simulator, with CO, SO{sub 2}, and NO{sub x} emissions determined on-line. The combustion tests produced simultaneous CO and NO{sub x} emissions well below and SO{sub 2} emissions comparable to the promulgated New Source Performance Standards (NSPS). This research will form the basis for later combustion experiments to be performed with the carbonized RDF slurry fuel, in which dioxin/furan and trace metal emissions will be determined.

  2. Plasma-Enhanced Combustion of Hydrocarbon Fuels and Fuel Blends Using Nanosecond Pulsed Discharges

    SciTech Connect (OSTI)

    Cappelli, Mark; Mungal, M Godfrey

    2014-10-28

    This project had as its goals the study of fundamental physical and chemical processes relevant to the sustained premixed and non-premixed jet ignition/combustion of low grade fuels or fuels under adverse flow conditions using non-equilibrium pulsed nanosecond discharges.

  3. Combustion instabilities in sudden expansion oxy-fuel flames

    SciTech Connect (OSTI)

    Ditaranto, Mario; Hals, Joergen

    2006-08-15

    An experimental study on combustion instability is presented with focus on oxy-fuel type combustion. Oxidants composed of CO{sub 2}/O{sub 2} and methane are the reactants flowing through a premixer-combustor system. The reaction starts downstream a symmetric sudden expansion and is at the origin of different instability patterns depending on oxygen concentration and Reynolds number. The analysis has been conducted through measurement of pressure, CH* chemiluminescence, and velocity. As far as stability is concerned, oxy-fuel combustion with oxygen concentration similar to that found in air combustion cannot be sustained, but requires at least 30% oxygen to perform in a comparable manner. Under these conditions and for the sudden expansion configuration used in this study, the instability is at low frequency and low amplitude, controlled by the flame length inside the combustion chamber. Above a threshold concentration in oxygen dependent on equivalence ratio, the flame becomes organized and concentrated in the near field. Strong thermoacoustic instability is then triggered at characteristic acoustic modes of the system. Different modes can be triggered depending on the ratio of flame speed to inlet velocity, but for all types of instability encountered, the heat release and pressure fluctuations are linked by a variation in mass-flow rate. An acoustic model of the system coupled with a time-lag-based flame model made it possible to elucidate the acoustic mode selection in the system as a function of laminar flame speed and Reynolds number. The overall work brings elements of reflection concerning the potential risk of strong pressure oscillations in future gas turbine combustors for oxy-fuel gas cycles. (author)

  4. Orimulsion conversion boosts prospects of `fourth` fossil fuel

    SciTech Connect (OSTI)

    1995-04-01

    This article describes how, by retrofitting a 100-MW oil-fired and a 215-MW coal-fired unit, one utility turned a plant destined for peaking service into a base-load asset with a predictable fuel bill and manageable emissions-even in environmentally sensitive Atlantic Canada. Six years ago, New Brunswick Power Corp (NB Power) found itself on the horns of a dilemma. For years, the utility had been searching for a powerplant fuel with a more stable price than oil, which at the time was fueling one-third of its generating capacity. Buying and burning more domestic coal-even at twice the price of offshore supplies-was the preferred option, because that would also help keep New Brunswick`s coal mines open. But by 1989, federal and provincial legislation had begun to plan for stringent limits on SO{sub 2} emissions that would take the local-coal card out of NB Power`s hand. Containing up to 8% sulfur, New Brunswick coal would be too dirty to burn by itself; emissions from a 200-MW unit would alone use up nearly half of the utility`s system-wide annual quota for SO{sub 2} emissions schedules for imposition in 1994. Enter Bitor America Corp, the Boca Raton (Fla) marketing subsidiary of the world`s third-largest oil company, Petroleos de Venezuela SA (PdVSA). Looking to further the fortunes of Orimulsion, a liquid emulsion of bitumen and water from the Orinoco region of Venezuela, Bitor funded and provided technical support for the first large-scale test burn of the fuel in the 100-MW Unit 1 of NB Power`s Dalhousie station in northern New Brunswick. After making the required modifications, NB Power burned Orimulsion in Unit 1 for two years. By 1991, the utility had cleanly converted more than a million barrels of the fuel to nearly half a million megawatt-hours of electricity-in the process finding few reasons not to commit to permanently converting Dalhousie`s Unit 1, as well as coal fired 215-MW Unit 2, to burn Orimulsion.

  5. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  6. Fireside Corrosion in Oxy-fuel Combustion of Coal

    SciTech Connect (OSTI)

    G. R. Holcomb; J. Tylczak; G. H. Meier; B. Lutz; K. Jung; N. Mu; N. M. Yanar; F. S. Pettit; J. Zhu; A. Wise; D. Laughlin; S. Sridhar

    2012-05-20

    Oxy-fuel combustion is burning a fuel in oxygen rather than air. The low nitrogen flue gas that results is relatively easy to capture CO{sub 2} from for reuse or sequestration. Corrosion issues associated with the environment change (replacement of much of the N{sub 2} with CO{sub 2} and higher sulfur levels) from air- to oxy-firing were examined. Alloys studied included model Fe-Cr alloys and commercial ferritic steels, austenitic steels, and nickel base superalloys. The corrosion behavior is described in terms of corrosion rates, scale morphologies, and scale/ash interactions for the different environmental conditions.

  7. Hydrogen milestone could help lower fossil fuel refining costs

    ScienceCinema (OSTI)

    McGraw, Jennifer

    2013-05-28

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, laboratory fellow and technical director of the INL High Temperature Electrolysis team, today announced that the latest fuel cell modification has set a new mark in endurance. The group's Integrated Laboratory Scale experiment has now operated continuously for 2,583 hours at higher efficiencies than previously attained. Learn more about INL research at http://www.facebook.com/idahonationallaboratory.

  8. Technical considerations in repowering a nuclear plant for fossil fueled operation

    SciTech Connect (OSTI)

    Patti, F.J.

    1996-03-01

    Repowering involves replacement of the reactor by a fossil fuel source of steam. This source can be a conventional fossil fueled boiler or the heat recovery steam generator (HRSG) on a gas turbine exhaust. The existing steam turbine plant is used to the extent possible. Alternative fuels for repowering a nuclear plant are coal, natural gas and oil. In today`s world oil is not usually an alternative. Selection of coal or natural gas is largely a matter of availability of the fuel near the location of the plant. Both the fossil boiler and the HRSG produce steam at higher pressures and temperatures than the throttle conditions for a saturated steam nuclear turbine. It is necessary to match the steam conditions from the new source to the existing turbine as closely as possible. Technical approaches to achieve a match range from using a topping turbine at the front end of the cycle to attemperation of the throttle steam with feedwater. The electrical output from the repowered plant is usually greater than that of the original nuclear fueled design. This requires consideration of the ability to use the excess electricity. Interfacing of the new facility with the existing turbine plant requires consideration of facility layout and design. Site factors must also be considered, especially for a coal fired boiler, since rail and coal handling facilities must be added to a site for which these were not considered. Additional site factors that require consideration are ash handling and disposal.

  9. Timing is everything : along the fossil fuel transition pathway.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Walker, La Tonya Nicole; Malczynski, Leonard A.

    2013-10-01

    People save for retirement throughout their career because it is virtually impossible to save all you'll need in retirement the year before you retire. Similarly, without installing incremental amounts of clean fossil, renewable or transformative energy technologies throughout the coming decades, a radical and immediate change will be near impossible the year before a policy goal is set to be in place. Therefore, our research question is,To meet our desired technical and policy goals, what are the factors that affect the rate we must install technology to achieve these goals in the coming decades?' Existing models do not include full regulatory constraints due to their often complex, and inflexible approaches to solve foroptimal' engineering instead ofrobust' and multidisciplinary solutions. This project outlines the theory and then develops an applied software tool to model the laboratory-to-market transition using the traditional technology readiness level (TRL) framework, but develops subsequent and a novel regulatory readiness level (RRL) and market readiness level (MRL). This tool uses the ideally-suited system dynamics framework to incorporate feedbacks and time delays. Future energy-economic-environment models, regardless of their programming platform, may adapt this software model component framework ormodule' to further vet the likelihood of new or innovative technology moving through the laboratory, regulatory and market space. The prototype analytical framework and tool, called the Technology, Regulatory and Market Readiness Level simulation model (TRMsim) illustrates the interaction between technology research, application, policy and market dynamics as they relate to a new or innovative technology moving from the theoretical stage to full market deployment. The initial results that illustrate the model's capabilities indicate for a hypothetical technology, that increasing the key driver behind each of the TRL, RRL and MRL components individually decreases the time required for the technology to progress through each component by 63, 68 and 64%, respectively. Therefore, under the current working assumptions, to decrease the time it may take for a technology to move from the conceptual stage to full scale market adoption one might consider expending additional effort to secure regulatory approval and reducing the uncertainty of the technology's demand in the marketplace.

  10. Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using CFD Simulations With Detailed Fuel Chemistry | Department of Energy Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry Accurate fuel models with hundreds of species in advanced CFD with reasonable simulation times. Reaction workbench used for surrogate blend formulation and model

  11. Fuels for Advanced Combustion Engines Research Diesel Fuels: Analysis of Physical and Chemical Properties

    SciTech Connect (OSTI)

    Gallant, Tom; Franz, Jim; Alnajjar, Mikhail; Storey, John Morse; Lewis Sr, Samuel Arthur; Sluder, Scott; Cannella, William C; Fairbridge, Craig; Hager, Darcy; Dettman, Heather; Luecke, Jon; Ratcliff, Matthew A.; Zigler, Brad

    2009-01-01

    The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and /u1H//u1/u3C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT/sT) apparatus.

  12. Fuel, lubricant and additive effects in combustion chamber deposit formation

    SciTech Connect (OSTI)

    Kelemen, S.R.; Homan, H.S.

    1996-10-01

    CCD causes octane requirement increase (ORI) and can potentially contributes to exhaust emissions and combustion chamber deposit interference (CCDI). Experiments were conducted to identify the separate fuel, lubricant and additive contributions to the amount and composition of CCD. CCD originates from multiple sources. Gasoline hydrocarbon components, gasoline additives, engine lubricant, and atmospheric nitrogen contribute to CCD in different ways. With some fuels the engine lubricant is the main contributor to CCD and this is shown by the high ash level in the CCD. For other fuels CCD is predominantly organic. Significant amounts of nitrogen were found in the CCD even when the fuel and lubricant were nitrogen free. The pyrolysis reactivity of different CCDs was studied to gain an understanding about the transformations that potentially happen over longer times and lower temperatures on the combustion chamber walls. In all cases during mild pyrolysis (375{degrees}C) there was a substantial increase in the level of aromatic carbon and a decrease in the level of organic oxygen. The largest increases in the amount of aromatic carbon occurred for CCDs that were the least aromatic.

  13. Assessment of a multi-stage underwater vehicle concept using a fossil-fuel Stirling engine

    SciTech Connect (OSTI)

    Reader, G.T.; Potter, I.J.

    1995-12-31

    The Stirling Engine because of its inherent closed-cycle operation can be readily modified to work in an airless environment even if the primary source of energy is a fossil fuel. Thus, Stirling engines are well suited for use in the underwater environment and have been operated successfully in manned military submarines since the early 1980s. In recent years fossil fueled Stirling systems have been also proposed for use in small unmanned underwater vehicles (UUVs). However, in this case the need to carry an onboard oxygen supply in a very confined space has presented a number of design difficulties. These are identified in the paper. However, if the oxidant supply to the engine is provided by the membrane extraction of dissolved oxygen from seawater and/or disposable fuel/oxidant pods are used then the UUV Stirling system becomes more attractive. If this latter concept is extended to include multi-stage vehicles then it can be shown that fossil fueled Stirlings could also be put to effective use in long range-long endurance underwater vehicular operations.

  14. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; et al

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increasesmore » strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.« less

  15. Fuel-Flexible Combustion System for Co-production Plant Applications

    SciTech Connect (OSTI)

    Joel Haynes; Justin Brumberg; Venkatraman Iyer; Jonathan Janssen; Ben Lacy; Matt Mosbacher; Craig Russell; Ertan Yilmaz; Williams York; Willy Ziminsky; Tim Lieuwen; Suresh Menon; Jerry Seitzman; Ashok Anand; Patrick May

    2008-12-31

    Future high-efficiency, low-emission generation plants that produce electric power, transportation fuels, and/or chemicals from fossil fuel feed stocks require a new class of fuel-flexible combustors. In this program, a validated combustor approach was developed which enables single-digit NO{sub x} operation for a future generation plants with low-Btu off gas and allows the flexibility of process-independent backup with natural gas. This combustion technology overcomes the limitations of current syngas gas turbine combustion systems, which are designed on a site-by-site basis, and enable improved future co-generation plant designs. In this capacity, the fuel-flexible combustor enhances the efficiency and productivity of future co-production plants. In task 2, a summary of market requested fuel gas compositions was created and the syngas fuel space was characterized. Additionally, a technology matrix and chemical kinetic models were used to evaluate various combustion technologies and to select two combustor concepts. In task 4 systems analysis of a co-production plant in conjunction with chemical kinetic analysis was performed to determine the desired combustor operating conditions for the burner concepts. Task 5 discusses the experimental evaluation of three syngas capable combustor designs. The hybrid combustor, Prototype-1 utilized a diffusion flame approach for syngas fuels with a lean premixed swirl concept for natural gas fuels for both syngas and natural gas fuels at FA+e gas turbine conditions. The hybrid nozzle was sized to accommodate syngas fuels ranging from {approx}100 to 280 btu/scf and with a diffusion tip geometry optimized for Early Entry Co-generation Plant (EECP) fuel compositions. The swozzle concept utilized existing GE DLN design methodologies to eliminate flow separation and enhance fuel-air mixing. With changing business priorities, a fully premixed natural gas & syngas nozzle, Protoytpe-1N, was also developed later in the program. It did not have the diluent requirements of Prototype-1 and was demonstrated at targeted gas turbine conditions. The TVC combustor, Prototype-2, premixes the syngas with air for low emission performance. The combustor was designed for operation with syngas and no additional diluents. The combustor was successfully operated at targeted gas turbine conditions. Another goal of the program was to advance the status of development tools for syngas systems. In Task 3 a syngas flame evaluation facility was developed. Fundamental data on syngas flame speeds and flame strain were obtained at pressure for a wide range of syngas fuels with preheated air. Several promising reduced order kinetic mechanisms were compared with the results from the evaluation facility. The mechanism with the best agreement was selected for application to syngas combustor modeling studies in Task 6. Prototype-1 was modeled using an advanced LES combustion code. The tools and combustor technology development culminate in a full-scale demonstration of the most promising technology in Task 8. The combustor was operated at engine conditions and evaluated against the various engine performance requirements.

  16. Fossil fuel-fired peak heating for geothermal greenhouses

    SciTech Connect (OSTI)

    Rafferty, K.

    1997-01-01

    Greenhouses are a major application of low-temperature geothermal resources. In virtually all operating systems, the geothermal fluid is used in a hot water heating system to meet 100% of both the peak and annual heating requirements of the structure. This strategy is a result of the relatively low costs associated with the development of most US geothermal direct-use resources and past tax credit programs which penalized systems using any conventional fuel sources. Increasingly, greenhouse operations will encounter limitations in available geothermal resource flow due either to production or disposal considerations. As a result, it will be necessary to operate additions at reduced water temperatures reflective of the effluent from the existing operations. Water temperature has a strong influence on heating system design. Greenhouse operators tend to have unequivocal preferences regarding heating system equipment. Many growers, particularly cut flower and bedding plant operators, prefer the {open_quotes}bare tube{close_quotes} type heating system. This system places small diameter plastic tubes under the benches or adjacent to the plants. Hot water is circulated through the tubes providing heat to the plants and the air in the greenhouse. Advantages include the ability to provide the heat directly to the plants, low cost, simple installation and the lack of a requirement for fans to circulate air. The major disadvantage of the system is poor performance at low (<140{degrees}F) water temperatures, particularly in cold climates. Under these conditions, the quantity of tubing required to meet the peak heating load is substantial. In fact, under some conditions, it is simply impractical to install sufficient tubing in the greenhouse to meet the peak heating load.

  17. Table 3.1 Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu) Year Coal 1 Natural Gas 2 Crude Oil 3 Fossil Fuel Composite 4 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Percent Change 7 1949 0.21 1.45 0.05 0.37 0.44 3.02 0.26 1.81 – – 1950 .21 1.41 .06 .43 .43 2.95 [R] .26 1.74 -3.6 1951 .21 1.35 .06 .40 .44 2.78 .26 1.65 -5.4 1952 .21 1.31 [R] .07 .45 .44 2.73 .26 1.63 -1.0 1953 .21 1.29 .08 .50 .46 2.86 .27 1.69 3.3 1954 .19 1.18 .09 .55 .48 2.94 .28 1.70 .7 1955

  18. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1. Fossil fuel sales of production from federal lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 679 3,939 33.0% 93 347 14.7% 6,798 6,981 35.7% 436 8,960 40.6%

  19. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Table 2. Fossil fuel sales of production from Indian lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 10 59 0.5% 2 6 0.3% 283 291 1.5% 30 616 2.8% 972 1.7% 2004 10 58

  20. Formulating Energy Policies Related to Fossil Fuel Use: Critical Uncertainties in the Global Carbon Cycle

    DOE R&D Accomplishments [OSTI]

    Post, W. M.; Dale, V. H.; DeAngelis, D. L.; Mann, L. K.; Mulholland, P. J.; O`Neill, R. V.; Peng, T. -H.; Farrell, M. P.

    1990-02-01

    The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Four reservoirs can be identified, including the atmosphere, terrestrial biosphere, oceans, and sediments. Atmospheric CO{sub 2} concentration is determined by characteristics of carbon fluxes among major reservoirs of the global carbon cycle. The objective of this paper is to document the knowns, and unknowns and uncertainties associated with key questions that if answered will increase the understanding of the portion of past, present, and future atmospheric CO{sub 2} attributable to fossil fuel burning. Documented atmospheric increases in CO{sub 2} levels are thought to result primarily from fossil fuel use and, perhaps, deforestation. However, the observed atmospheric CO{sub 2} increase is less than expected from current understanding of the global carbon cycle because of poorly understood interactions among the major carbon reservoirs.

  1. FUEL FORMULATION EFFECTS ON DIESEL FUEL INJECTION, COMBUSTION, EMISSIONS AND EMISSION CONTROL

    SciTech Connect (OSTI)

    Boehman, A; Alam, M; Song, J; Acharya, R; Szybist, J; Zello, V; Miller, K

    2003-08-24

    This paper describes work under a U.S. DOE sponsored Ultra Clean Fuels project entitled ''Ultra Clean Fuels from Natural Gas,'' Cooperative Agreement No. DE-FC26-01NT41098. In this study we have examined the incremental benefits of moving from low sulfur diesel fuel and ultra low sulfur diesel fuel to an ultra clean fuel, Fischer-Tropsch diesel fuel produced from natural gas. Blending with biodiesel, B100, was also considered. The impact of fuel formulation on fuel injection timing, bulk modulus of compressibility, in-cylinder combustion processes, gaseous and particulate emissions, DPF regeneration temperature and urea-SCR NOx control has been examined. The primary test engine is a 5.9L Cummins ISB, which has been instrumented for in-cylinder combustion analysis and in-cylinder visualization with an engine videoscope. A single-cylinder engine has also been used to examine in detail the impacts of fuel formulation on injection timing in a pump-line-nozzle fueling system, to assist in the interpretation of results from the ISB engine.

  2. NREL: Technology Deployment - Fossil Fuel Dependency Falls from 100% to 56%

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Alcatraz Island Fossil Fuel Dependency Falls from 100% to 56% on Alcatraz Island News Solar Cells Light Up Prison Cells on 'The Rock' Sponsors U.S. National Park Service American Recovery and Reinvestment Act Key Partners National Park Service Golden Gate National Recreation Area National Park Service Denver Services Center Princeton Power Inc. University of Washington Lawrence Berkeley National Laboratory U.S. DOE Federal Energy Management Program Related Stories U.S. Virgin Islands

  3. High capacity fossil fuel fired plant operator training program. Student handbook. Final report

    SciTech Connect (OSTI)

    Pearson, S.; Gardner, M.; Nguyen, Q.

    1994-09-30

    The operator of fossil fuel-fired boilers has a significant responsibility in assuring that the unit is continuously operated in a manner which complies with the various state and federal regulations. The course will emphasize the operating principles for all types of boilers and for all types of control equipment used for controlling air emissions from boilers. The course will emphasize the significant operating parameters that directly influence air emissions.

  4. September 2013 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy, Office of Scientific and Technical Information September 2013 Most Viewed Documents for Fossil Fuels Science Subject Feed EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 42 /> Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. (1996) 36 /> Fluid Dynamics in Sucker Rod Pumps Cutler, R.P.; Mansure, A.J. (1999) 35 />

  5. September 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy, Office of Scientific and Technical Information September 2015 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 141 Decomposition of calcium sulfate: a review of the literature. [62 refs] Swift, W M; Panek, A F; Smith, G W; Vogel, G J; Jonke, A A (1976) 122 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs.,

  6. December 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 213 Bamboo: An Overlooked Biomass Resource? Scurlock, J.M.O. (2000) 159 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)]; Barker, K.M. [Petrolite Corp. (United States)] (1994) 134 ADVANCED TECHNIQUES FOR RESERVOIR

  7. EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels by Fluid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Identification - Energy Innovation Portal Energy Analysis Energy Analysis Find More Like This Return to Search EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels by Fluid Identification Lawrence Berkeley National Laboratory Contact LBL About This Technology Plots of electrical conductivity over the Troll Field in the North Sea produced by analyzing 3D electromagnetic field data. Plots of electrical conductivity over the Troll Field in the North Sea produced by analyzing 3D

  8. July 2013 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Scientific and Technical Information July 2013 Most Viewed Documents for Fossil Fuels Science Subject Feed EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 82 /> Controlled low strength materials (CLSM), reported by ACI Committee 229 Rajendran, N. (1997) 65 /> Systems and economic analysis of microalgae ponds for conversion of CO{sub 2} to biomass. Final report Benemann, J.R.; Oswald, W.J.

  9. June 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Scientific and Technical Information June 2015 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 134 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)]; Barker, K.M. [Petrolite Corp. (United States)] (1994) 94 Fluid Dynamics in Sucker Rod Pumps Cutler, R.P.; Mansure, A.J. (1999) 92

  10. Most Viewed Documents for Fossil Fuels: December 2014 | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information Most Viewed Documents for Fossil Fuels: December 2014 Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 107 EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 60 DENSE MEDIUM CYCLONE OPTIMIZATON Gerald H. Luttrell; Chris J. Barbee; Peter J. Bethell; Chris J. Wood

  11. Most Viewed Documents for Fossil Fuels: September 2014 | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information Most Viewed Documents for Fossil Fuels: September 2014 Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 138 Autothermal Reforming of Natural Gas to Synthesis Gas Steven F. Rice; David P. Mann (2007) 51 Avian Collisions with Wind Turbines: A Summary of Existing Studies and Comparisons to Other Sources of Avian Collision Mortality in the United

  12. Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Low Temperature Combustion in a Light-Duty Diesel Engine Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel Engine Six different fuels were investigated to study the influence of fuel properties on engine out emissions and performance of low temperature premixed compression ignition combustion light-duty HSDI engines PDF icon deer10_tatur.pdf More Documents & Publications An Experimental Investigation of Low Octane Gasoline in Diesel Engines Use of Low

  13. Determination of combustion products from alternative fuels - part 1. LPG and CNG combustion products

    SciTech Connect (OSTI)

    Whitney, K.A.; Bailey, B.K.

    1994-10-01

    This paper describes efforts underway to identify volatile organic exhaust species generated by a light-duty vehicle operating over the Federal Test Procedure (FTP) on CNG and LPG, and to compare them to exhaust constituents generated from the same vehicle operating on a fuel blended to meet California Phase 2 specifications. The exhaust species from this vehicle were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without the vehicle`s catalytic converter in place to determine the influence of the vehicle`s catalyst on species formation. Speciation data showed greater than 87 percent of all LPG and greater than 95 percent of all CNG hydrocarbon exhaust constituents to be composed of C{sub 1} to C{sub 3} compounds. In addition, toxic emissions from the combustion of CNG and LPG were as low as 10 percent of those generated by combustion of gasoline. A comparison of ozone forming potential of the three fuels was made based on the Maximum Incremental Reactivity scale used by the California Air Resources Board. Post-catalyst results from stoichiometric operation indicated that LPG and CNG produced 63 percent and 88 percent less potential ozone than reformulated gasoline, respectively. On average over all equivalence ratios, CNG and LPG exhaust constituents were approximately 65 percent less reactive than those from reformulated gasoline. 4 refs., 3 figs., 14 tabs.

  14. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion

    Office of Scientific and Technical Information (OSTI)

    Combustion Engines Bunting, Bruce G ORNL; Bunce, Michael ORNL 02 PETROLEUM; 04 OIL SHALES AND TAR SANDS; 10 SYNTHETIC FUELS; 33 ADVANCED PROPULSION SYSTEMS; BIOFUELS;...

  15. Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft004_mueller_2010_o.pdf More Documents & Publications Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research Optical-Engine and Surrogate-Fuels Research for an Improved Understanding of Fuel Effects on Advanced-Combustion Strateg

  16. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    DOE Patents [OSTI]

    Shen, Ming-Shing (Rocky Point, NY); Yang, Ralph T. (Middle Island, NY)

    1980-01-01

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  17. Advanced technologies for co-processing fossil and biomass resources for transportation fuels and power generation

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Y.

    2004-07-01

    Over the past few decades, a number of processes have been proposed or are under development for coprocessing fossil fuel and biomass for transportation fuels and power generation. The paper gives a brief description of the following processes: the Hydrocarb system for converting biomass and other carbonaceous fuels to elemental carbon and hydrogen, methane or methanol; the Hynol process where the second step of the Hydrocarb process is replaced with a methane steam reformer to convert methane to CO and H{sub 2}S without deposition of carbon; the Carnol process where CO{sub 2} from coal and the biomass power plants is reacted with hydrogen to produce methanol; and advanced biomass high efficiency power generator cycle where a continuous plasma methane decomposition reactor (PDR) is used with direct carbon fuel cell to produce power and carbon and hydrogen. 13 refs., 5 figs., 2 tabs.

  18. Fireside Corrosion in Oxy-fuel Combustion of Coal

    SciTech Connect (OSTI)

    Holcomb, Gordon R; Tylczak, Joseph; Meier, Gerald H; Lutz, Bradley; Jung, Keeyoung; Mu, Nan; Yanar, Nazik M; Pettit, Frederick S; Zhu, Jingxi; Wise, Adam; Laughlin, David E.; Sridhar, Seetharaman

    2013-11-25

    Oxy-fuel combustion is burning a fuel in oxygen rather than air for ease of capture of CO2 from for reuse or sequestration. Corrosion issues associated with the environment change (replacement of much of the N2 with CO2 and higher sulfur levels) from air- to oxy-firing were examined. Alloys studied included model FeCr alloys and commercial ferritic steels, austenitic steels, and nickel base superalloys. The corrosion behavior is described in terms of corrosion rates, scale morphologies, and scale/ash interactions for the different environmental conditions. Evidence was found for a hreshold for severe attack between 10-4 and 10-3 atm of SO3 at 700C.

  19. EA-1778: Proposed Rule, 10 CFR 433 and 435, Energy Conservation and Fossil Fuel-Generated Energy

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of DOE's Proposed Rule, 10 CFR Part 433, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Commercial and Multi-Family High-Rise Residential Buildings and 10 CFR Part 435, Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Low-Rise Residential Buildings.

  20. Coal-water slurry fuel internal combustion engine and method for operating same

    DOE Patents [OSTI]

    McMillian, Michael H.

    1992-01-01

    An internal combustion engine fueled with a coal-water slurry is described. About 90 percent of the coal-water slurry charge utilized in the power cycle of the engine is directly injected into the main combustion chamber where it is ignited by a hot stream of combustion gases discharged from a pilot combustion chamber of a size less than about 10 percent of the total clearance volume of main combustion chamber with the piston at top dead center. The stream of hot combustion gases is provided by injecting less than about 10 percent of the total coal-water slurry charge into the pilot combustion chamber and using a portion of the air from the main combustion chamber that has been heated by the walls defining the pilot combustion chamber as the ignition source for the coal-water slurry injected into the pilot combustion chamber.

  1. Long-term tradeoffs between nuclear- and fossil-fuel burning

    SciTech Connect (OSTI)

    Krakowski, R.A.

    1996-12-31

    A global energy/economics/environmental (E{sup 3}) model has been adapted with a nuclear energy/materials model to understand better {open_quotes}top-level{close_quotes}, long-term trade offs between civilian nuclear power, nuclear-weapons proliferation, fossil-fuel burning, and global economic welfare. Using a {open_quotes}business-as-usual{close_quotes} (BAU) point-of-departure case, economic, resource, proliferation-risk implications of plutonium recycle in LAIRs, greenhouse-gas-mitigating carbon taxes, and a range of nuclear energy costs (capital and fuel) considerations have been examined. After describing the essential elements of the analysis approach being developed to support the Los Alamos Nuclear Vision Project, preliminary examples of parametric variations about the BAU base-case scenario are presented. The results described herein represent a sampling from more extensive results collected in a separate report. The primary motivation here is: (a) to compare the BAU basecase with results from other studies; (b) to model on a regionally resolved global basis long-term (to year {approximately}2100) evolution of plutonium accumulation in a variety of forms under a limited range of fuel-cycle scenarios; and (c) to illustrate a preliminary connectivity between risks associated with nuclear proliferation and fossil-fuel burning (e.g., greenhouse-gas accumulations).

  2. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    SciTech Connect (OSTI)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  3. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Citation Details In-Document Search Title: DOE Project 18546, AOP Task 1.1, Fuel ...

  4. Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

    DOE Patents [OSTI]

    Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

    2014-03-04

    The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

  5. Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment

    SciTech Connect (OSTI)

    Sayer, J.H.

    1995-06-01

    The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

  6. Fuel injection for internal combustion engines. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-08-01

    The bibliography contains citations concerning research and development of fuel injection systems applied to internal combustion engines and turbines. Gasoline, diesel, synthetic fuels, and liquid gas systems are discussed relative to systems` variations and performances. Fuel injection atomization and combustion are considered in theory, and fuel injection relative to emission control is included.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  7. Fuel injection for internal combustion engines. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations concerning research and development of fuel injection systems applied to internal combustion engines and turbines. Gasoline, diesel, synthetic fuels, and liquid gas systems are discussed relative to systems' variations and performances. Fuel injection atomization and combustion are considered in theory, and fuel injection relative to emission control is included. (Contains a minimum of 223 citations and includes a subject term index and title list.)

  8. Fuel NOx production during the combustion of low caloric value fuel

    SciTech Connect (OSTI)

    Colaluca, M.A.; Caraway, J.P.

    1997-07-01

    The objective of this investigation is to identify and qualify physical mechanisms and parameters that affect the combustion of low caloric value gases (LCVG) and the formation of NOx pollutants produced form fuel bound nitrogen. Average physical properties of a low caloric value gas were determined from the products of several industrial coal gasifiers. A computer model was developed, utilizing the PHOENICS computational fluid dynamics software to model the combustion of LCVG. The model incorporates a 3-dimensional physical design and is based on typical industrial combustors. Feed stock to the gasifier can be wood, feed stock manure, cotton gin trash, coal, lignite and numerous forms of organic industrial wastes.

  9. Fuel combustion exhibiting low NO{sub x} and CO levels

    DOE Patents [OSTI]

    Keller, J.O.; Bramlette, T.T.; Barr, P.K.

    1996-07-30

    Method and apparatus are disclosed for safely combusting a fuel in such a manner that very low levels of NO{sub x} and CO are produced. The apparatus comprises an inlet line containing a fuel and an inlet line containing an oxidant. Coupled to the fuel line and to the oxidant line is a mixing means for thoroughly mixing the fuel and the oxidant without combusting them. Coupled to the mixing means is a means for injecting the mixed fuel and oxidant, in the form of a large-scale fluid dynamic structure, into a combustion region. Coupled to the combustion region is a means for producing a periodic flow field within the combustion region to mix the fuel and the oxidant with ambient gases in order to lower the temperature of combustion. The means for producing a periodic flow field can be a pulse combustor, a rotating band, or a rotating cylinder within an acoustic chamber positioned upstream or downstream of the region of combustion. The mixing means can be a one-way flapper valve; a rotating cylinder; a rotating band having slots that expose open ends of said fuel inlet line and said oxidant inlet line simultaneously; or a set of coaxial fuel annuli and oxidizer annuli. The means for producing a periodic flow field may or may not be in communication with an acoustic resonance. When employed, the acoustic resonance may be upstream or downstream of the region of combustion. 14 figs.

  10. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heaters - Fact Sheet 2014 | Department of Energy Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 The goal of this research effort was to develop and demonstrate a combustion system capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery

  11. High efficiency, quasi-instantaneous steam expansion device utilizing fossil or nuclear fuel as the heat source

    SciTech Connect (OSTI)

    Claudio Filippone, Ph.D.

    1999-06-01

    Thermal-hydraulic analysis of a specially designed steam expansion device (heat cavity) was performed to prove the feasibility of steam expansions at elevated rates for power generation with higher efficiency. The steam expansion process inside the heat cavity greatly depends on the gap within which the steam expands and accelerates. This system can be seen as a miniaturized boiler integrated inside the expander where steam (or the proper fluid) is generated almost instantaneously prior to its expansion in the work-producing unit. Relatively cold water is pulsed inside the heat cavity, where the heat transferred causes the water to flash to steam, thereby increasing its specific volume by a large factor. The gap inside the heat cavity forms a special nozzle-shaped system in which the fluid expands rapidly, accelerating toward the system outlet. The expansion phenomenon is the cause of ever-increasing fluid speed inside the cavity system, eliminating the need for moving parts (pumps, valves, etc.). In fact, the subsequent velocity induced by the sudden fluid expansion causes turbulent conditions, forcing accelerating Reynolds and Nusselt numbers which, in turn, increase the convective heat transfer coefficient. When the combustion of fossil fuels constitutes the heat source, the heat cavity concept can be applied directly inside the stator of conventional turbines, thereby greatly increasing the overall system efficiency.

  12. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect (OSTI)

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  13. Comparison of emissions from landfills, municipal waste combustors, and fossil fuel-fired utilities

    SciTech Connect (OSTI)

    1996-11-01

    Landfilling is the most popular disposal method for managing municipal solid waste (MSW). However, air emissions from MSW landfills have generally been unregulated until recently. Instead, EPA has focused on emissions from municipal waste combustors (MWCs), even though they only manage 15% of MSW generated in the United States. In the past, little data have been available comparing landfill and MWC air emissions. Such information is provided by this paper. It also compares emissions from waste-to-energy MWCs and fossil fuel-fired utilities with equivalent electrical generation capacity. 1 refs., 6 tabs.

  14. USVI Makes Headway Toward Goal to Reduce Fossil Fuel 60% by 2025

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil prices spike to over $145/ barrel and price of electricity exceeds $0.50/kWh in U.S. Virgin Islands (USVI) USVI announces goal to reduce fossil fuel use 60% by 2025 In 3rd most active hurricane season on record, Earl hits USVI Virgin Islands Energy O ce (VIEO) launches Sun Power Loan Program WAPA installs waste heat recovery plant, adding 19 MW of power without burning a single drop of additional oil VIEO awards nearly $1 million to USVI nonpro ts for energy e ciency and renewable energy

  15. Better batteries to break dependence on fossil fuels > EMC2 News > The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Materials Center at Cornell Better batteries to break dependence on fossil fuels April 28th, 2015 › By Linda B. Glaser By 2050 world population is projected to reach 10 billion people, and energy needs will double from what we require today. "We are nowhere near ready," said Héctor D. Abruña at a Charter Day Weekend lecture, "Cornell and the Energy Landscape in the Age of Sustainability" April 26. Fortunately, the work being done by Abruña and others at

  16. Browse by Discipline -- E-print Network Subject Pathways: Fossil Fuels --

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, science, and technology for the research community -- hosted by the Office of Scientific and Technical Information, U.S. Department of Energy Fossil Fuels Go to Research Groups Preprints Provided by Individual Scientists: A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Abu-Khamsin, Sidqi (Sidqi Abu-Khamsin) - Department of Petroleum Engineering, King Fahd University of Petroleum and Minerals Al-Khattaf, Sulaiman (Sulaiman Al-Khattaf) - Department of Chemical Engineering, King

  17. June 2014 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Scientific and Technical Information June 2014 Most Viewed Documents for Fossil Fuels Science Subject Feed Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 95 /> Evaluation of 2004 Toyota Prius Hybrid Electric Drive System Staunton, R.H.; Ayers, C.W.; Chiasson, J.N. (U Tennessee-Knoxville); Burress, B.A. (ORISE); Marlino, L.D. (2006) 63 /> Systems and economic analysis of microalgae

  18. March 2014 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information 4 Most Viewed Documents for Fossil Fuels Science Subject Feed Systems and economic analysis of microalgae ponds for conversion of CO{sub 2} to biomass. Final report Benemann, J.R.; Oswald, W.J. (1996) 65 /> Avian Collisions with Wind Turbines: A Summary of Existing Studies and Comparisons to Other Sources of Avian Collision Mortality in the United States Wallace P. Erickson, Gregory D. Johnson, M. Dale Strickland, David P. Young, Jr.,

  19. March 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information 5 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 184 A kinetic study of methanol synthesis in a slurry reactor using a CuO/ZnO/Al sub 2 O sub 3 catalyst Al-Adwani, H.A. (1992) 97 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)];

  20. Combustion of refuse derived fuel in a fluidized bed

    SciTech Connect (OSTI)

    Piao, Guilin; Aono, Shigeru; Mori, Shigekatsu; Deguchi, Seiichi; Fujima, Yukihisa; Kondoh, Motohiro; Yamaguchi, Masataka

    1998-12-31

    Power generation from Refuse Derived Fuel (RDF) is an attractive utilization technology of municipal solid waste. To explain the behavior of RDF-fired fluidized bed incinerator, the commercial size RDF was continuously burnt in a 30 x 30 cm bubbling type fluidized-bed combustor. It was found that 12 kg/h of RDF feed rate was too high feed for this test unit and the Co level was higher than 500 ppm. However, 10 kg/h of RDF was a proper feed rate and the Co level was kept under 150 ppm. Secondary air injection and changing air ratio from the pipe grid were effective for the complete combustion of RDE. It was also found that HCl concentration in flue gas was controlled by the calcium component contained in RDF and its level was decreased with decreasing the combustor temperature.

  1. Determination of alternative fuels combustion products: Phase 2 final report

    SciTech Connect (OSTI)

    Whitney, K.A.

    1997-06-01

    This report describes the laboratory efforts to accomplish four independent tasks: (1) speciation of hydrocarbon exhaust emissions from a light-duty vehicle operated over the chassis dynamometer portion of the light-duty FTP after modifications for operation on butane and butane blends; (2) evaluation of NREL`s Variable Conductance Vacuum Insulated Catalytic Converter Test Article 4 for the reduction of cold-start FTP exhaust emissions after extended soak periods for a Ford FFV Taurus operating on E85; (3) support of UDRI in an attempt to define correlations between engine-out combustion products identified by SwRI during chassis dynamometer testing, and those found during flow tube reactor experiments conducted by UDRI; and (4) characterization of small-diameter particulate matter from a Ford Taurus FFV operating in a simulated fuel-rich failure mode on CNG, LPG, M85, E85, and reformulated gasoline. 22 refs., 18 figs., 17 tabs.

  2. Modeling the Effects of Steam-Fuel Reforming Products on Low Temperature Combustion of n-Heptane

    Broader source: Energy.gov [DOE]

    The effects of blends of base fuel (n-heptane) and fuel-reformed products on the low-temperature combustion process were investigated.

  3. Combustion rates of chars from high-volatile fuels for FBC application

    SciTech Connect (OSTI)

    Masi, S.; Salatino, P.; Senneca, O.

    1997-12-31

    The fluidized bed combustion of high volatile fuels is often associated with huge occurrence of comminution phenomena. These result into in-bed generation of substantial amounts of carbon fines which further undergo competitive processes of combustion and elutriation. The small size of carbon fines generated by comminution is such that their further combustion is largely controlled by the intrinsic kinetics of carbon oxidation, alone or in combination with intraparticle diffusion. The competition between fine combustion and elutriation strongly affects the efficiency of fixed carbon conversion and calls for thorough characterization of the combustion kinetics and of residence times of fines in a fluidized bed of coarse solids. In this paper a collection of intrinsic combustion kinetic and porosimetric data for chars from three high-volatile fuels suitable for FBC application is presented. Chars from a Refuse Derived Fuel (RDF), a Tyre Derived Fuel (TDF) and a biomass (Robinia Pseudoacacia) are obtained from devolatilization, in fluidized bed, of fuel samples. Thermogravimetric analysis, mercury porosimetry and helium pycnometry are used to characterize the reactivity and the pore structure of the chars. Combustion rates are characterized over a wide range of temperatures (320--850 C) and oxygen partial pressures, covering the entire range of interest in fluidized bed combustion. Analysis of thermogravimetric and porosimetric data is directed to obtaining the parameters (pre-exponential factors, reaction orders, activation energies, intraparticle diffusivities) of combustion kinetic submodels for application in fluidized bed combustor modeling.

  4. Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine | Department of Energy Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Oak Ridge National Laboratory, Fuel, Engines, and Emissions Research Center PDF icon 2004_deer_bunting2.pdf More Documents & Publications Enabling and Expanding HCCI in PFI Gasoline Engines with High EGR and Spark Assist

  5. A brief overview of Chinese Design Code on Fossil-Fueled Power Plants

    SciTech Connect (OSTI)

    Xu Zhongqing; He Yehong

    1996-10-01

    The Chinese Design Code on Fossil Fueled Power Plants (DL 5000-94) was issued in April 1994 by the Ministry of Electric Power Industry, P.R. China, and the English version has been drafted and will be formally published in the near future. Based on the 1984 version and the nation`s current policies, the 1994 version was formed to meet the challenges of the nation`s speedy development of electric power construction. In general, the code is primarily a directive document guiding the planning and engineering of China`s large- and medium-sized fossil-fueled power plants. The preparation of the 1984 version and the revision of it to the 1994 version were all carried out by the East China Electric Power Design Institute under the direction of Electric Power Planning and Engineering Institute. For small-sized power plants with unit rating of 25 MW and below, there is another national design code titled Code for Design of Small Sized Power Plants (GB 50049-94) issued in November 1994 jointly by the China`s National Technology Supervision Administration and the Ministry of Construction.

  6. Identifying fly ash at a distance from fossil fuel power stations

    SciTech Connect (OSTI)

    Flanders, P.J.

    1999-02-15

    A method has been developed to identify fly ash originating at fossil fuel power stations, even at a distance where the ash level is lower by a factor of 1000 from that close to a source. Until now such detection has been difficult and uncertain. The technique combines collection of particles, measurement of magnetization and coercive field, and microscopy. The analysis depends on the fact that ash from iron sulfide in fossil fuels is in the form of spherical magnetite. These particles have a relatively high coercive field H{sub c}, near 135 Oe, compared with airborne particulates from soil erosion which have an H{sub c} of {approximately}35 Oe. The coercive field of any sample therefore gives an indication for the percentage of fly ash relative to the total amount of magnetic material that is airborne. The concentration of ash from a large, isolated coal burning power station is found to fall off with the distance from the source, approximately as D{sup {minus}1}. As D increases there is a drop in H{sub c}, associated with the reduced amount of fly ash relative to the airborne particulates from soil erosion.

  7. Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies

    SciTech Connect (OSTI)

    Chia-fon F. Lee; Alan C. Hansen

    2010-09-30

    In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

  8. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H; Parish, Esther S; Kline, Keith L

    2015-01-01

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  9. Can industry`s `fourth` fossil fuel establish presence in US?

    SciTech Connect (OSTI)

    Armor, A.F.; Dene, C.E.

    1996-09-01

    After five years of commercial experience burning Orimulsion overseas, US utilities are now evaluating the new fuel as a serious alternative to oil. In their relentless drive to remain competitive, electric utilities with oil-fired generating units are searching for lower cost fuel alternatives. Because of high fuel prices, oil-fired units have low capacity factors. Only 23 out of 142 oil-capable units in the US had capacity factors greater than 50% in 1993; the average was a mere 24%. Utility consumption of fuel oil slid from over 600,000 barrels (bbl)/day in 1989 to less than 200,000 bbl/day last year. Orimulsion now fuels nearly 3,000 MW/yr worldwide. The UK`s PowerGen Ltd, currently the world`s largest consumer of Orimulsion, fires some 10-million bbl/yr at two 500-MW units at its Ince plant and three 120-MW units at its Richborough plant. Both plants formerly burned fuel oil, and have been using Orimulsion since 1991. Canada`s New Brunswick Power Corp has fired Orimulsion in two units at its Dalhousie plant since 1994 (Power, April 1995, p 27); one 105-MW unit was originally designed for fuel oil, the other 212-MW unit was designed for coal. Last year, Denmark`s SK Power converted its coal-fired, 700-MW Asnaes Unit 5 to Orimulsion firing. And in the US, Florida Power and Light Co. (FP and L) has signed a 20-yr fuel supply contract with Bitor America Corp (Boca Raton, Fla.), for two 800-MW units at the oil-fired Manatee plant, contingent on securing necessary permits. The Manatee installation (Power, September 1994, p 57) would be the first in the US to burn the fuel. Today, five years after Orimulsion begun to be used commercially, many of the lingering questions involving the new fuel`s handling, transportation, combustion, emissions control, spill control, and waste utilization have been settled. Several US utilities have expressed serious interest in the fuel as an alternative to oil.

  10. Post-Combustion Carbon Capture Research | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Post-Combustion Carbon Capture Research Post-Combustion Carbon Capture Research Fossil fuel fired electric generating plants are the cornerstone of America's central power system. Currently, the existing fossil fuel fleet accounts for about two-thirds of all electricity generated domestically, over 40% from coal alone. Electricity demand is expected to increase dramatically over the next 30 years, and adding new generating capacity typically requires long lead time. In the meantime, the United

  11. Fossil energy program. Progress report, July 1980

    SciTech Connect (OSTI)

    McNeese, L. E.

    1980-10-01

    This report - the seventy-second of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process and program analysis, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, fossil energy applications assessments, performance assurance system support for fossil energy projects, international assessment of atmospheric fluidized bed combustion technology, and PFBC systems analysis.

  12. Use of Low Cetane Fuel to Enable Low Temperature Combustion

    Broader source: Energy.gov [DOE]

    Document:  ace011_ciatti_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Steve CiattiPresenting Organization: Argonne National Laboratory (ANL...

  13. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  14. Table 1.14 Sales of Fossil Fuels Produced on Federal and American Indian Lands, Fiscal Years 2003-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Sales of Fossil Fuels Produced on Federal and American Indian Lands, Fiscal Years 2003-2011 Fiscal Year 7 Crude Oil and Lease Condensate Natural Gas Plant Liquids 1 Natural Gas 2 Coal 3 Total Fossil Fuels 4 Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Sales 5,6 Sales as Share of Total U.S. Production Million Barrels Trillion Btu Percent

  15. Internal combustion engine cylinder-to-cylinder balancing with balanced air-fuel ratios

    DOE Patents [OSTI]

    Harris, Ralph E.; Bourn, Gary D.; Smalley, Anthony J.

    2006-01-03

    A method of balancing combustion among cylinders of an internal combustion engine. For each cylinder, a normalized peak firing pressure is calculated as the ratio of its peak firing pressure to its combustion pressure. Each cylinder's normalized peak firing pressure is compared to a target value for normalized peak firing pressure. The fuel flow is adjusted to any cylinder whose normalized peak firing pressure is not substantially equal to the target value.

  16. Use of Low Cetane Fuel to Enable Low Temperature Combustion | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace011_ciatti_2011_o.pdf More Documents & Publications An Experimental Investigation of Low Octane Gasoline in Diesel Engines Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies

  17. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    SciTech Connect (OSTI)

    Michael Petrik; Robert Ruhl

    2012-03-31

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled “Small Scale SOFC Demonstration using Bio-based and Fossil Fuels.” Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  18. Evaluation of unthrottled combustion system options for light duty applications with future syncrude derived fuels. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Needham, J. R.; Cooper, B. M.; Norris-Jones, S. R.

    1982-12-01

    An experimental program examining the interaction between several fuel and light duty automotive engine combinations is detailed. Combustion systems addressed covered indirect and direct injection diesel and spark ignited stratified charge. Fuels primarily covered D2, naphtha and intermediate broadcut blends. Low ignition quality diesel fuels were also evaluated. The results indicate the baseline fuel tolerance of each combustion system and enable characteristics of the systems to be compared. Performance, gaseous and particulate emissions aspects were assessed. The data obtained assists in the selection of candidate combustion systems for potential future fuels. Performance and environmental penalties as appropriate are highlighted relative to the individual candidates. Areas of further work for increased understanding are also reviewed.

  19. A creep damage estimation method for in-service fossil fuel boiler superheater tubes

    SciTech Connect (OSTI)

    Nogata, F. . Dept. of Mechanical Engineering); Takahashi, H. . Research Inst. of Fracture Technology)

    1995-02-01

    Because mechanical properties of structural materials for high-temperature use, such as boiler tubing, degrade during long-term service, it is essential to detect toughness degradation by means of a nondestructive and simple field test technique. A grain boundary etching technique is developed to detect material degradation, and assess creep strength and notch toughness. An etching test using a picric acid solution with a wetting agent or using 20 percent HNO[sub 3] with alcoholic solution was found to have great potential for the nondestructive estimation of grain boundary embrittlement caused by carbide and sigma precipitation in SUS stainless steel. The feasibility of this estimation procedure was determined showing the relationships between Charpy impact energy (CVN) and grooving width (W[sub GS]), and creep damage ratio ([Phi]) and W[sub GS]. Superheater tubes of fossil fuel boiler were tested on site to demonstrate the validity of this technique.

  20. Table 3.7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil 1 Petroleum Products 2 Total Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 1949 2,368 16,332 [R] 3,976 27,423 [R] 0 0 304,658 2,101,235 [R] 137,130 945,789 [R] 448,132 3,090,779 [R] 1950 2,624 17,904 [R] 5,297 36,142 [R] 0 0 369,208 2,519,159 [R] 214,629 1,464,445 [R] 591,758 4,037,650 [R] 1951 2,420 15,402 [R] 1,932 12,296 [R] 0 0 374,869

  1. Table 3.8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 297,179 2,049,652 [R] 8,323 57,404 [R] 1,823 12,573 [R] 98,425 678,840 [R] 461,439 3,182,557 [R] 867,189 5,981,026 [R] 1950 269,195 1,836,756 [R] 6,159 42,024 [R] 3,199 21,827 [R] 102,717 700,853 [R] 394,434 2,691,280 [R] 775,704 5,292,740 [R] 1951 586,056

  2. Table 3.9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 -294,811 -2,033,320 [R] -4,347 -29,981 [R] -1,823 -12,573 [R] 206,233 1,422,395 [R] -324,309 -2,236,768 [R] -419,057 -2,890,248 [R] 1950 -266,571 -1,818,852 [R] -862 -5,882 [R] -3,199 -21,827 [R] 266,491 1,818,306 [R] -179,805 -1,226,835 [R] -183,946

  3. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Table 7. Sales of fossil fuel production from federal and Indian lands by state/area, FY 2003-14 trillion Btu State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 Alabama 75 57 51 47 40 42 60 88 86 71 46 29 Alaska 61 66 68 52 32 28 27 23 21 19 18 21 Arizona 258 273 280 193 180 162 157 154 164 163 167 158 Arkansas 7 8 10 10 10 11 15 18 14 13 11 11 California 141 125 124 139 146 129 116 115 121 125 121 119 Colorado 785 842 960 906 905 931 846 868 917 952 875 877 Florida 0 - - - - -

  4. Device for separating CO2 from fossil-fueled power plant emissions

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Judkins, Roddie R. (Knoxville, TN); Wilson, Kirk A. (Knoxville, TN)

    2002-04-23

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  5. Combustion, Control, and Fuel Effects in a Spark Assisted HCCI Engine

    Office of Scientific and Technical Information (OSTI)

    Equipped with Variable Valve Timing (Conference) | SciTech Connect Combustion, Control, and Fuel Effects in a Spark Assisted HCCI Engine Equipped with Variable Valve Timing Citation Details In-Document Search Title: Combustion, Control, and Fuel Effects in a Spark Assisted HCCI Engine Equipped with Variable Valve Timing Widespread implementation of homogeneous charge compression ignition (HCCI) engines is presently hindered by stability, control, and load range issues. Although the operable

  6. Fuel combustion exhibiting low NO.sub.x and CO levels

    DOE Patents [OSTI]

    Keller, Jay O. (3534 Brunell Dr., Oakland, CA 94602); Bramlette, T. Tazwell (2105 Canyon Lakes Dr., San Ramon, CA 94583); Barr, Pamela K. (294 Joyce St., Livermore, CA 94550)

    1996-01-01

    Method and apparatus for safely combusting a fuel in such manner that very low levels of NO.sub.x and CO are produced. The apparatus comprises an inlet line (12) containing a fuel and an inlet line (18) containing an oxidant. Coupled to the fuel line (12) and to the oxidant line (18) is a mixing means (11,29,33,40) for thoroughly mixing the fuel and the oxidant without combusting them. Coupled to the mixing means (11,29,33,40) is a means for injecting the mixed fuel and oxidant, in the form of a large-scale fluid dynamic structure (8), into a combustion region (2). Coupled to the combustion region (2) is a means (1,29,33) for producing a periodic flow field within the combustion region (2) to mix the fuel and the oxidant with ambient gases in order to lower the temperature of combustion. The means for producing a periodic flow field can be a pulse combustor (1), a rotating band (29), or a rotating cylinder (33) within an acoustic chamber (32) positioned upstream or downstream of the region (2) of combustion. The mixing means can be a one-way flapper valve (11); a rotating cylinder (33); a rotating band (29) having slots (31) that expose open ends (20,21) of said fuel inlet line (12) and said oxidant inlet line (18) simultaneously; or a set of coaxial fuel annuli (43) and oxidizer annuli (42,44). The means for producing a periodic flow field (1, 29, 33) may or may not be in communication with an acoustic resonance. When employed, the acoustic resonance may be upstream or downstream of the region of combustion (2).

  7. Use of Low Cetane Fuel to Enable Low Temperature Combustion | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace011_ciatti_2012_o.pdf More Documents & Publications Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel Engine An Experimental Investigation of Low Octane Gasoline in Diesel Engines Development of Advanced Combustion Technologies for Increased Thermal Efficiency

  8. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity...

    Broader source: Energy.gov (indexed) [DOE]

    Publications Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity Fuels - Fact Sheet, 2015...

  9. Power-Gen `95. Book III: Generation trends. Volume 1 - current fossil fuel technologies. Volume 2 - advanced fossil fuel technologies. Volume 3 - gas turbine technologies I

    SciTech Connect (OSTI)

    1995-12-31

    This document is Book III of Power-Gen 1995 for the Americas. I contains papers on the following subjects: (1) Coal technologies, (2) atmospheric fluidized bed combustion, (3) repowering, (4) pressurized fluidized bed combustion, (5) combined cycle facilities, and (6) aeroderivitive and small gas turbines.

  10. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  11. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  12. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-10-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  13. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  14. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  15. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    1993-09-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  16. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  17. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    Energy Science and Technology Software Center (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The softwaremore » can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.« less

  18. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    SciTech Connect (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The software can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.

  19. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/02

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions. (DMC)

  20. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/03

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions.

  1. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  2. Compression ignition engine having fuel system for non-sooting combustion and method

    DOE Patents [OSTI]

    Bazyn, Timothy; Gehrke, Christopher

    2014-10-28

    A direct injection compression ignition internal combustion engine includes a fuel system having a nozzle extending into a cylinder of the engine and a plurality of spray orifices formed in the nozzle. Each of the spray orifices has an inner diameter dimension of about 0.09 mm or less, and define inter-orifice angles between adjacent spray orifice center axes of about 36.degree. or greater such that spray plumes of injected fuel from each of the spray orifices combust within the cylinder according to a non-sooting lifted flame and gas entrainment combustion pattern. Related methodology is also disclosed.

  3. Advancement in Fuel Spray and Combustion Modeling for Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Vehicle Technologies Office Merit Review 2014: Advancement...

  4. Summary of workshop on materials issues associated with low-NO{sub x} combustion conditions in fossil-fired boilers

    SciTech Connect (OSTI)

    1996-08-01

    It was anticipated by some members of the high-temperature corrosion community that the fitting of low-NO{sub x} burners to coal-fired power plants would lead to an increase in furnace wall corrosion, as a result of the relatively substoichiometric conditions created by the staged combustion process. These expectations were not borne out by initial experience. Recently, however, cases of severe furnace wall corrosion have been reported by some U.S. utility boilers retrofitted with modern low-NO{sub x} burners. There is extensive experience of furnace wall corrosion in utility boilers in the U.K., which indicates that excessive fireside corrosion rates (>200 nm/hr; 34 mil/yr) are experienced when tubes are exposed simultaneously to substoichiometric gaseous environments (CO>3.0 percent) and high radiant heat fluxes. Such conditions may be generated when flame impingement occurs. Where such conditions persist, increases in fuel chlorine content will exacerbate the rate of metal loss. In the absence of either circumstances, corrosion rates are much reduced and little influence of coal chlorine content is anticipated. Although the corrosion is essentially sulfidation caused by H{sub 2}S in the flue gas, the contribution of fuel sulfur in the corrosion experience by U.K. boilers is unresolved, partly because of the relatively small range in sulfur content of coals burned in U.K. utility boilers. The intent of this workshop was three-fold: to better define the problem in terms of the form and rate of attack; to examine what is known about its root causes; and to review the potential for using corrosion-resistant materials as part of the solution.

  5. Synthetic fuel aromaticity and staged combustion. First quarterly technical progress report, September 23-December 31, 1980

    SciTech Connect (OSTI)

    Levy, Arthur; Longanbach, James R.; Chan, Lisa K.

    1981-01-28

    Synthetic liquid fuels, otherwise referred to as synfuels or coal-derived liquids, are probably best characterized from a combustion-environmental point of view as low in hydrogen, low in sulfur, high in nitrogen, and high in aromatics. As a consequence two of the more critical problems in synfuel combustion are NO/sub x/ formation and soot formation (and polycyclic organic matter). This program is directed to these two issues. At first hand the solutions to burning synfuels high in aromatics and fuel-bound nitrogen are diametrically opposed, i.e., high temperature and excess air keep soot levels down, low temperatures and vitiated air keep nitrogen oxide levels down. Staged combustion however offers a logical solution to the above. This program separates and analyzes the synfuel combustion problem via its component parts and then puts them together again phenomenologically via the stage combustion process.

  6. Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Parks, II, James E; Prikhodko, Vitaly Y

    2009-01-01

    Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOX and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associated with DPF regeneration. In this study, a SiC DPF was loaded and regenerated on a 1.7-liter 4-cylinder diesel engine operated in conventional and advanced combustion modes at different speed and load conditions. A diesel oxidation catalyst (DOC) and a lean NOX trap (LNT) were also installed in the exhaust stream. Five steady-state speed and load conditions were weighted to estimate Federal Test Procedure (FTP) fuel efficiency. The DPF was loaded using lean-rich cycling with frequencies that resulted in similar levels of NOX emissions downstream of the LNT. The pressure drop across the DPF was measured at a standard point (1500 rpm, 5.0 bar) before and after loading, and a P rise rate was determined for comparison between conventional and advanced combustion modes. Higher PM emissions in conventional combustion resulted in a higher rate of backpressure rise across the DPF at all of the load points leading to more frequent DPF regenerations and higher fuel penalty. The fuel penalty during conventional combustion was 4.2% compared with 3.1% for a mixture of conventional and advanced modes.

  7. Pre-Combustion Carbon Capture Research | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and oxygen/air under high temperature and pressure to form synthesis gas. This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller amounts of other gaseous components, such as methane. The syngas

  8. Biomass Fuel Characterization : Testing and Evaluating the Combustion Characteristics of Selected Biomass Fuels : Final Report May 1, 1988-July, 1989.

    SciTech Connect (OSTI)

    Bushnell, Dwight J.; Haluzok, Charles; Dadkhah-Nikoo, Abbas

    1990-04-01

    Results show that two very important measures of combustion efficiency (gas temperature and carbon dioxide based efficiency) varied by only 5.2 and 5.4 percent respectively. This indicates that all nine different wood fuel pellet types behave very similarly under the prescribed range of operating parameters. The overall mean efficiency for all tests was 82.1 percent and the overall mean temperature was 1420 1{degree}F. Particulate (fly ash) ad combustible (in fly ash) data should the greatest variability. There was evidence of a relationship between maximum values for both particulate and combustible and the percentages of ash and chlorine in the pellet fuel. The greater the percentage of ash and chlorine (salt), the greater was the fly ash problem, also, combustion efficiency was decreased by combustible losses (unburned hydrocarbons) in the fly ash. Carbon monoxide and Oxides of Nitrogen showed the next greatest variability, but neither had data values greater than 215.0 parts per million (215.0 ppm is a very small quantity, i.e. 1 ppm = .001 grams/liter = 6.2E-5 1bm/ft{sup 3}). Visual evidence indicates that pellets fuels produced from salt laden material are corrosive, produce the largest quantities of ash, and form the only slag or clinker formations of all nine fuels. The corrosion is directly attributable to salt content (or more specifically, chloride ions and compounds formed during combustion). 45 refs., 23 figs., 19 tabs.

  9. Cyclic Combustion Variations in Dual Fuel Partially Premixed Pilot-Ignited Natural Gas Engines

    SciTech Connect (OSTI)

    Srinivasan, K. K.; Krishnan, S. R.

    2012-05-09

    Dual fuel pilot ignited natural gas engines are identified as an efficient and viable alternative to conventional diesel engines. This paper examines cyclic combustion fluctuations in conventional dual fuel and in dual fuel partially premixed low temperature combustion (LTC). Conventional dual fueling with 95% (energy basis) natural gas (NG) substitution reduces NOx emissions by almost 90%t relative to straight diesel operation; however, this is accompanied by 98% increase in HC emissions, 10 percentage points reduction in fuel conversion efficiency (FCE) and 12 percentage points increase in COVimep. Dual fuel LTC is achieved by injection of a small amount of diesel fuel (2-3 percent on an energy basis) to ignite a premixed natural gas???????¢????????????????air mixture to attain very low NOx emissions (less than 0.2 g/kWh). Cyclic variations in both combustion modes were analyzed by observing the cyclic fluctuations in start of combustion (SOC), peak cylinder pressures (Pmax), combustion phasing (Ca50), and the separation between the diesel injection event and Ca50 (termed ???????¢????????????????relative combustion phasing???????¢???????????????). For conventional dual fueling, as % NG increases, Pmax decreases, SOC and Ca50 are delayed, and cyclic variations increase. For dual fuel LTC, as diesel injection timing is advanced from 20???????????????° to 60???????????????°BTDC, the relative combustion phasing is identified as an important combustion parameter along with SoC, Pmax, and CaPmax. For both combustion modes, cyclic variations were characterized by alternating slow and fast burn cycles, especially at high %NG and advanced injection timings. Finally, heat release return maps were analyzed to demonstrate thermal management strategies as an effective tool to mitigate cyclic combustion variations, especially in dual fuel LTC.

  10. Fuel-air mixing and combustion in a two-dimensional Wankel engine

    SciTech Connect (OSTI)

    Shih, T.I.P.; Schock, H.J.; Ramos, J.I.

    1987-01-01

    The effects of mixture stratification at the intake port and gaseous fuel injection on the flow field and fuel-air mixing in a two-dimensional rotary engine model have been investigated by means of a two-equation model of turbulence, an algebraic grid generation method and an approximate factorization time-linearized numerical technique. It is shown that the fuel distribution in the combustion chamber is a function of the air-fuel mixture fluctuations at the intake port. The fuel is advected by the flow field induced by the rotor and is concentrated near the leading apex during the intake stroke. During compression, the fuel concentration is highest near the trailing apex and lowest near the rotor. The penetration of gaseous fuel injected into the combustion chamber during the compression stroke increases with the injection velocity.

  11. Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home Home The Combustion Energy Frontier Research Center (CEFRC) was established by the US Department of Energy (DOE) in August 2009 as one of the 46 new centers around the country dedicated to addressing the pressing issues of energy sustainability, energy security, and climate change. The CEFRC, funded at $20 million over 5 years and directed by Professor Chung K. Law of Princeton University, focuses on the combustion of fossil and alternative fuels to produce heat and power. The research team

  12. The origin of organic pollutants from the combustion of alternative fuels: Phase 5/6 report

    SciTech Connect (OSTI)

    Sidhu, S.; Graham, J.; Taylor, P.; Dellinger, B.

    1998-05-01

    As part of the US Department of Energy National Renewable Energy Laboratory program on alternative automotive fuels, the subcontractor has been conducting studies on the origin and fate of organic pollutants from the combustion of alternative fuels. Laboratory experiments were conducted simulating cold start of four alterative fuels (compressed natural gas, liquefied petroleum gas, methanol-gasoline mix, and ethanol-gasoline mix) using a commercial three-way catalyst under fuel-lean conditions. This report summarizes the results of these experiments. It appears that temperature of the catalyst is a more important parameter for fuel conversion and pollutant formation than oxygen concentration or fuel composition.

  13. Fossil Energy | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    fossil energy. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011 This paper provides updated summary information regarding fossil fuel production on federal and Indian lands. It includes the U.S. Energy Information Administration's (EIA) best estimates of fossil fuel sales from production on federal and Indian lands for fiscal years (fy) 2003 through 2011. Source: EIA.

  14. Fuel injection characteristics and combustion behavior of a direct-injection stratified-charge engine

    SciTech Connect (OSTI)

    Balles, E.N.; Ekchian, J.A.; Heywood, J.B.

    1984-01-01

    High levels of hydrocarbon emissions during light load operation keep the direct injection stratified charge engine from commercial application. Previous analytical work has identified several possible hydrocarbon emissions mechanisms which can result from poor in-cylinder fuel distribution. Poor fuel distribution can be caused by erratic fuel injection. Experiments conducted on a single cylinder disc engine show a dramatic increase in the cycle to cycle variation in injection characteristics as engine load decreases. This is accompanied by an increase in cycle to cycle variation in combustion behavior suggesting that degradation in combustion results from the degradation in the quality of the injection event. Examination of combustion and injection characteristics on a cycle by cycle basis shows that, at light load, IMEP and heat release do not correlate with the amount of fuel injected into the cylinder. There are strong indications that individual cycles undergo partial or complete misfire.

  15. Complete Fuel Combustion for Diesel Engines Resulting in Greatly...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resulting in Greatly Reduced Emissions and Improved Fuel Efficiency An advanced engine design that is 15 percent more efficient than diesel, pollution free, and uses any fuel. ...

  16. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  17. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W.; Scott, Paul B.

    2003-09-02

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

  18. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

    2011-11-01

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

  19. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    SciTech Connect (OSTI)

    David Petti; J. Stephen Herring

    2010-03-01

    As described in the Department of Energy Office of Nuclear Energys Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, Produce hydrogen for industrial processes and transportation fuels, and Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nations energy security through more effective utilization of our countrys resources while simultaneously providing economic stability and growth (through predictable energy prices and high value jobs), in an environmentally sustainable and secure manner (through lower land and water use, and decreased byproduct emissions). The reduction in imported oil will also increase the retention of wealth within the U.S. economy while still supporting economic growth. Nuclear energy is the only non-fossil fuel that has been demonstrated to reliably supply energy for a growing industrial economy.

  20. Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Replace Fossil Fuels, Final Technical Report (Technical Report) | SciTech Connect Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Citation Details In-Document Search Title: Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report The primary objectives of this work can be summed into two major categories. Firstly, the fundamentals of the combustion of glycerol (in both a

  1. Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_04_mueller.pdf More Documents & Publications Vehicle Technologies Office: 2010 Fuel Technologies R&D Annual Progress Report Vehicle Technologies Office: 2008-2009 Fuels Technologies R&D Progress Report Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research

  2. The impact of environmental regulation on productivity in the US fossil-fueled power plants

    SciTech Connect (OSTI)

    Whang, J.

    1993-12-31

    The purpose of this dissertation is to examine the impact of environmental regulation on productivity in the U.S. fossil fueled electric generating industry. With the oil shocks, environmental regulation has been considered as one of the main culprits for the apparent productivity slowdown during the 1970`s. Even though new pieces of legislation are continuously enacted to regulate hazardous pollutants emitted, it is difficult to find thorough and meaningful analyses on the effects of regulation. Without exact measurement of regulation effects, it is not easy to design socially efficient environmental policies to reconcile several conflicting goals. Using plant-level production and environmental data for the last two decades, the effects of differentiated environmental regulation are carefully examined. Since unbalanced panel data set is used, fixed-effects and random-effects models are also examined. The estimated impact of environmental regulation explains 6 to 10 percent of the variation of total factor productivity growth rates. This appears to be a relatively mild effect compared with several previous studies.

  3. Determining NO{sub x} emissions from fossil fuel-fired sources

    SciTech Connect (OSTI)

    McNeel, A.

    1996-11-01

    To determine nitrogen oxides (NO{sub x}) emissions, the concentration of NO{sub x} within the stack gas must be determined. USEPA Reference Methods 7, 7A, 7C, 7D and/or 7E are the procedures to be used for NO{sub x} measurement as referenced in 40 CFR 60 subparts D, Da, Db and Dc - {open_quotes}Standards of performance for fossil fuel-fired steam generators...{open_quotes}. Depending upon the reason for determining NO{sub x} emissions, information in addition to NO{sub x} concentrations may be needed. Generally, USEPA Reference Methods 1 - 4 will be used to gather the additional data needed to satisfy the specific need for determining NO{sub x} emissions. The following text outlines the individual NO{sub x} sampling methodology, the relative costs of the reference method (RM) sampling, and the use of the resulting reference method data to calculate emissions in units of applicable standards.

  4. Table 3.2 Value of Fossil Fuel Production, 1949-2011 (Billion Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    Value of Fossil Fuel Production, 1949-2011 (Billion Dollars) Year Coal 1 Natural Gas 2 Crude Oil 3,4 Total Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 1949 2.52 17.37 [R] 0.33 2.24 4.68 32.27 [R] 7.52 51.88 [R] 1950 2.91 19.84 [R] .44 3.00 4.95 33.80 [R] 8.30 56.64 [R] 1951 3.05 19.40 [R] .52 3.32 [R] 5.69 36.19 [R] 9.26 58.92 [R] 1952 2.67 16.73 [R] .64 4.01 5.79 36.25 [R] 9.11 56.99 [R] 1953 2.55 15.79 [R] .76 4.67 [R] 6.32 39.06 [R] 9.63 59.52 [R] 1954 2.02 12.40 [R]

  5. GRH 12-01 Fireside Corrosion in Oxy-fuel Combustion Poster 0108

    SciTech Connect (OSTI)

    G. R. Holcomb; J. Tylczak; G. H. Meier; B. Lutz; K. Jung; N. Mu; N. M. Yanar; F. S. Pettit; J. Zhu; A. Wise; D. Laughlin; S. Sridhar

    2012-05-20

    The goals are to: (1) Achieve 90% CO{sub 2} capture at no more than a 35% increase in levelized cost of electricity of post-combustion capture for new and existing conventional coal-fired power plants; (2) Provide high-temperature corrosion information to aid in materials development and selection for oxy-fuel combustion; and (3) Identify corrosion mechanism and behavior differences between air- and oxy-firing.

  6. Improving combustion stability in a bi-fuel engine

    SciTech Connect (OSTI)

    1995-06-01

    This article describes how a new strategy for ignition timing control can reduce NOx emissions from engines using CNG and gasoline. Until a proper fueling infrastructure is established, a certain fraction of vehicles powered by compressed natural gas (CNG) must have bi-fuel capability. A bi-fuel engine, enjoying the longer range of gasoline and the cleaner emissions of CNG, can overcome the problem of having few CNG fueling stations. However, bi-fuel engines must be optimized to run on both fuels since low CNG volumetric efficiency causes power losses compared to gasoline.

  7. Fuel Effects on Ignition and Their Impact on Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006deertaylor.pdf More Documents & Publications Fuel Requirements for ...

  8. Use of Low Cetane Fuel to Enable Low Temperature Combustion

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. Gasoline-Like Fuel Effects on Advanced Combustion Regimes

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Gasoline-like fuel effects on advanced combustion regimes

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  11. Gasoline-Like Fuel Effects on Advanced Combustion Regimes

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  12. An Analysis of the Impact of Selected Fuel Thermochemical Properties on Internal Combustion Engine Efficiency

    SciTech Connect (OSTI)

    Szybist, James P; Chakravathy, Kalyana; Daw, C Stuart

    2012-01-01

    In this study we model the effects of 23 different fuels on First and Second Law thermodynamic efficiency of an adiabatic internal combustion engine. First Law efficiency is calculated using lower heating value (LHV) while Second Law efficiency is calculated with exergy, which represents the inherent chemical energy available to produce propulsion. We find that First Law efficiency can deviate by as much as nine percentage points between fuels while Second Law efficiency exhibits a much smaller degree of variability. We also find that First and Second Law efficiency can be nearly the same for some fuels (methane and ethane) but differ substantially for other fuels (hydrogen and ethanol). The differences in First and Second Law efficiency are due to differences in LHV and exergy for a given fuel. In order to explain First Law efficiency differences between fuels as well as the differences between LHV and exergy, we introduce a new term: the molar expansion ratio (MER), defined as the ratio of product moles to reactant moles for complete stoichiometric combustion. We find that the MER is a useful expression for providing a physical explanation for fuel-specific efficiency differences as well as differences between First and Second Law efficiency. First and Second Law efficiency are affected by a number of other fuel-specific thermochemical properties, such as the ratio of specific heat and dissociation of combustion products.

  13. Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a Multi-Cylinder Light Duty Diesel Engine | Department of Energy Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-06_curran.pdf More Documents &

  14. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  15. Sandia Energy - Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spray Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Fuels Spray Combustion Spray CombustionAshley Otero2015-10-28T02:17:06+00:00 Fuel...

  16. Combustion characteristics of refuse derived fuels. Final report

    SciTech Connect (OSTI)

    Tsang, W.; Macek, A.; Domalski, E.; Walker, J.A.; Charagundla, S.R.; Colbert, J.C.; Kirklin, D.R.; Ledford, A.E. Jr.; Decker, P.H.; Ryan, R.V.

    1983-01-01

    The purpose of the laboratory studies presented here is to furnish preliminary input to the technologists in the sense of providing relative rankings through comparisons of appropriate coal and MSW combustion related properties. Support for a future program of sub-scale (demonstration or pilot) experiments to expand on the concepts and quantify them for scale-up to industrial sizes should be provided. A complete plan for this second phase study is included as an appendix to this report. With respect to the actual experimental investigations; these consist of three main tasks. Specifically: (a) static measurements (calorimetry, proximates and ultimate analysis; (b) dynamic measurements using the full range of modern thermoanalytical instrumentation; and (c) combustion of particulates in a specially constructed laboratory furnace as well as studies on the entrainment properties of MSW. The first two tasks deal mainly with the chemical properties of municipal solid waste and is of general utility. The latter is more specifically orientated. The scale of laboratory instrumentation set definite to the limits particle size with respect to the intrainment and combustion studies. Thus the most straightforward application is to combustion in stokers, including semi-suspension units.

  17. Comparison of AB2588 multipathway risk factors for California fossil-fuel power stations

    SciTech Connect (OSTI)

    Gratt, L.B.; Levin, L.

    1997-12-31

    Substances released from power plants may travel through various exposure pathways resulting in human health and environmental risks. The stack air emission`s primary pathway is inhalation from the ambient air. Multipathway factors (adjustment factors to the inhalation risk) are used to evaluate the importance of non-inhalation pathways (such as ingestion and dermal contact). The multipathway factor for a specific substance is the health risk by all pathways divided by the inhalation health risk for that substance. These factors are compared for fossil fuel power stations that submitted regulatory risk assessments in compliance with California Toxic Hot Spots Act (AB2588). Substances representing the largest contributions to the cancer risk are of primary concern: arsenic, beryllium, cadmium, chromium (+6), formaldehyde, nickel, lead, selenium, and PAHs. Comparisons of the chemical-specific multipathway factors show the impacts of regulatory policy decisions on the estimated health risk for trace substances. As an example, point estimates of the soil mixing depth, varying from 1 cm to 15 cm, relate to the relative importance of the pathway. For the deeper mixing depths, the root-zone uptake by homegrown tomato plants (for assumed consumption rate of 15% for San Diego) may result in high multipathway factors for several trace metals. For shallower mixing depths, soil ingestion may become the dominant non-inhalation pathway. These differences may lead to significantly different risk estimates for similar facilities located at different California locations such as to be under local regulatory authorities. The overall multipathway factor for the total cancer risk is about 2, much smaller than some of the chemical-specific factors. Science-based multipathway analysis should reduce much of the concern that may be due to policy-based decisions on pathway selection and high-value point-estimates of the parameters.

  18. FutureGen: Stepping-Stone to Sustainable Fossil-Fuel Power Generation

    SciTech Connect (OSTI)

    Zitney, S.E.

    2006-11-01

    This presentation will highlight the U.S. Department of Energy's FutureGen Initiative. The nearly $1 billion government-industry project is a stepping-stone toward future coal-fired power plants that will produce hydrogen and electricity with zero-emissions, including carbon dioxide. The 275-megawatt FutureGen plant will initiate operations around 2012 and employ advanced coal gasification technology integrated with combined cycle electricity generation, hydrogen production, and carbon capture and sequestration. The initiative is a response to a presidential directive to develop a hydrogen economy by drawing upon the best scientific research to address the issue of global climate change. The FutureGen plant will be based on cutting-edge power generation technology as well as advanced carbon capture and sequestration systems. The centerpiece of the project will be coal gasification technology that can eliminate common air pollutants such as sulfur dioxide and nitrogen oxides and convert them to useable by-products. Gasification will convert coal into a highly enriched hydrogen gas, which can be burned much more cleanly than directly burning the coal itself. Alternatively, the hydrogen can be used in a fuel cell to produce ultra-clean electricity, or fed to a refinery to help upgrade petroleum products. Carbon sequestration will also be a key feature that will set the Futuregen plant apart from other electric power plant projects. The initial goal will be to capture 90 percent of the plant's carbon dioxide, but capture of nearly 100 percent may be possible with advanced technologies. Once captured, the carbon dioxide will be injected as a compressed fluid deep underground, perhaps into saline reservoirs. It could even be injected into oil or gas reservoirs, or into unmineable coal seams, to enhance petroleum or coalbed methane recovery. The ultimate goal for the FutureGen plant is to show how new technology can eliminate environmental concerns over the future use of coal--the most abundant fossil fuel in the United States with supplies projected to last 250 years. FutureGen's co-production of power and hydrogen will also serve as a stepping-stone to an environmentally sustainable energy future.

  19. Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels/Spray Combustion - Spray Combustionadmin2015-10-28T02:17:06+00:00

  20. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  1. Dual fuel combustion in a turbocharged diesel engine

    SciTech Connect (OSTI)

    Few, P.C.; Newlyn, H.A.

    1987-01-01

    The modification of a turbocharged diesel engine to a dual-fuel engine using methane as the supplementary fuel has been carried out. The effect of the gaseous fuel in a turbo-charged diesel engine has been investigated by means of a heat release study and a computer program already developed at Leicester Polytechnic. It is used in order to examine the rate of heat released under any operational condition.

  2. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined less by the needs of the plant than by the availability in the soil solution; in addition to occurring naturally, Cl is present in excess as the anion complement in K fertilizer applications. An analysis was performed on existing data for switchgrass samples from ten different farms in the south-central portion of Iowa, with the goal of determining correlations between switchgrass elemental composition and geographical and seasonal changes so as to identify factors that influence the elemental composition of biomass. The most important factors in determining levels of various chemical compounds were found to be seasonal and geographical differences related to soil conditions. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions as well as fly ash. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures using cluster analysis were developed to characterize the inorganic material in these samples. Each of the biomass types exhibited different inorganic associations in the fuel as well as in the deposits and fly ash. Morphological analyses of the wheat straw show elongated 10-30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the organic structure of the biomass materials. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Although growing rapidly, the fouling deposits of the biomass and coal-biomass blends were significantly weaker than those of the coals. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similarity from the fuel to the ash analyzed. A high percentage of particles from both fuel and ash samples contained both Si and K. While Cl was a significant component in the fuel, very little was detected in the ash sample.

  3. Vehicle Technologies Office Merit Review 2015: Advanced Combustion and Fuels

    Broader source: Energy.gov [DOE]

    Presentation given by National Renewable Energy Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about advanced...

  4. Study of trajectories and combustion of fuel-oil droplets in the combustion chamber of a power-plant boiler with the use of a mathematical model

    SciTech Connect (OSTI)

    Enyakin, Yu.P.; Usman, Yu.M.

    1988-03-01

    A mathematical model was developed to permit study of the behavior of fuel-oil droplets in a combustion chamber, and results are presented from a computer calculation performed for the 300-MW model TGMP-314P boiler of a power plant. The program written to perform the calculations was organized so that the first stage would entail calculation of the combustion (vaporization) of a droplet of liquid fuel. The program then provided for a sudden decrease in the mass of the fuel particle, simulating rupture of the coke shell and ejection of some of the liquid. The program then considered the combustion of a hollow coke particle. Physicochemical parameters characteristic of fuel oil M-100 were introduced in the program in the first stage of computations, while parameters characteristic of the coke particle associated with an unburned fuel-oil droplet were included in the second stage.

  5. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

    2005-04-29

    The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

  6. Determination of alternative fuels combustion products: Phase 3 report

    SciTech Connect (OSTI)

    Whitney, K.A.

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  7. Fossil fuel conversion -- Measurement and modeling. Topical report, September 14, 1993--June 30, 1997

    SciTech Connect (OSTI)

    1997-12-31

    Progress is described on the following tasks: Fixed-bed devolatilization processes; Fixed-bed combustion and gasification processes; Physical processes in transport reactors; Chemical processes in transport reactors; Advanced fixed-bed model development and evaluation; Advanced two-dimensional transport reactor model development and evaluation; Modeling of gas phase combustion; Modeling of fluidized bed systems; Advanced fixed-bed code application and implementation; Advanced two-dimensional transport gasification code applications and implementation; Modeling of fluidized-bed system applications and implementation; and Applications of ACERC combustion and gasification codes and AFR diagnostic capabilities to systems of interest to METC.

  8. Chemical Kinetic Simulation of the Combustion of Bio-based Fuels

    SciTech Connect (OSTI)

    Ashen, Ms. Refuyat; Cushman, Ms. Katherine C.

    2007-10-01

    Due to environmental and economic issues, there has been an increased interest in the use of alternative fuels. However, before widespread use of biofuels is feasible, the compatibility of these fuels with specific engines needs to be examined. More accurate models of the chemical combustion of alternative fuels in Homogeneous Charge Compression Ignition (HCCI) engines are necessary, and this project evaluates the performance of emissions models and uses the information gathered to study the chemical kinetics involved. The computer simulations for each alternative fuel were executed using the Chemkin chemical kinetics program, and results from the runs were compared with data gathered from an actual engine that was run under similar conditions. A new heat transfer mechanism was added to the existing model's subroutine, and simulations were then conducted using the heat transfer mechanism. Results from the simulation proved to be accurate when compared with the data taken from the actual engine. The addition of heat transfer produced more realistic temperature and pressure data for biodiesel when biodiesel's combustion was simulated in an HCCI engine. The addition of the heat transfer mechanism essentially lowered the peak pressures and peak temperatures during combustion of all fuels simulated in this project.

  9. Fuel Effects on Ignition and Their Impact on Advanced Combustion Engines (Poster)

    SciTech Connect (OSTI)

    Taylor, J.; Li, H.; Neill, S.

    2006-08-01

    The objective of this report is to develop a pathway to use easily measured ignition properties as metrics for characterizing fuels in advanced combustion engine research--correlate IQT{trademark} measured parameters with engine data. In HCCL engines, ignition timing depends on the reaction rates throughout compression stroke: need to understand sensitivity to T, P, and [O{sub 2}]; need to rank fuels based on more than one set of conditions; and need to understand how fuel composition (molecular species) affect ignition properties.

  10. Determination of combustion products from alternative fuels. Part I. LPG and CNG combustion products

    SciTech Connect (OSTI)

    Whitney, K.A.; Bailey, B.K.

    1994-10-01

    This paper describes efforts underway to identify volatile organic exhaust species generated by a light-duty vehicle operating over the Federal Test Procedure (FTP) on CNG and LPG, and to compare them to exhaust constituents generated from the same vehicle operating on a fuel blended to meet California Phase 2 specifications. The exhaust species from this vehicle were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2 nominally, and were analyzed with and without the vehicle`s catalytic converter in place to determine the influence of the vehicle`s catalyst on species formation. 4 refs., 3 figs., 14 tabs.

  11. General circulation model calculations of the direct radiative forcing by anthropogenic sulfate and fossil-fuel soot aerosol

    SciTech Connect (OSTI)

    Haywood, J.M.; Roberts, D.L.; Slingo, A.

    1997-07-01

    A new radiation code within a general circulation model is used to assess the direct solar and thermal radiative forcing by sulfate aerosol of anthropogenic origin and soot aerosol from fossil-fuel burning. The radiative effects of different aerosol profiles, relative humidity parameterizations, chemical compositions, and internal and external mixtures of the two aerosol types are investigated. The contribution to the radiative forcing from cloudy sky regions is found to be negligible for sulfate aerosol; this is in contrast to recent studies where the cloudy sky contribution was estimated using a method in which the spatial correlation between cloud amount and sulfate burden was ignored. However, the radiative forcing due to fossil-fuel soot aerosol is enhanced in cloudy regions if soot aerosol exists within or above the cloud. The global solar radiative forcing due to sulfate aerosol is estimated to be -0.38 W m{sup -2} and the global thermal radiative forcing is estimated to be +0.01 W m{sup -2}. The hemispheric mean radiative forcings vary by only about 10% for reasonable assumptions about the chemical form of the sulfate aerosol and the relative humidity dependence; the uncertainties in the aerosol loading are far more significant. If a soot/sulfate mass ratio of 0.075 is assumed, then the global solar radiative forcing weakens to -0.18 W m{sup -2} for an external mixture and weakens further for an internal mixture. Additionally, the spatial distribution of the radiative forcing shows strong negative/positive forcing contrasts that may influence the dynamical response of the atmosphere. Although these results are extremely sensitive to the adopted soot/sulfate ratio and the assumed vertical profile, they indicate that fossil-fuel soot aerosol may exert a nonnegligible radiative forcing and emphasize the need to consider each anthropogenic aerosol species. 58 refs., 8 figs., 1 tab.

  12. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known signal-to-noise problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  13. Determination of alternative fuels combustion products: Phase 1 report

    SciTech Connect (OSTI)

    Whitney, K.A.

    1997-09-01

    This report describes the laboratory effort to identify and quantify organic exhaust species generated from alternative-fueled light-duty vehicles operating over the Federal Test Procedure on compressed natural gas, liquefied petroleum gas, methanol, ethanol, and reformulated gasoline. The exhaust species from these vehicles were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without a vehicle catalyst in place to determine the influence of a catalytic converter on species formation.

  14. Estimates of health risks associated with radionuclide emissions from fossil-fueled steam-electric generating plants. Final report

    SciTech Connect (OSTI)

    Nelson, C.

    1995-08-01

    Under the Title III, Section 112 of the 1990 Clean Air Act Amendment, Congress directed the U.S. Environmental Protection Agency (EPA) to perform a study of the hazards to public resulting from pollutants emitted by electric utility system generating units. Radionuclides are among the groups of pollutants listed in the amendment. This report updates previously published data and estimates with more recently available information regarding the radionuclide contents of fossil fuels, associated emissions by steam-electric power plants, and potential health effects to exposed population groups.

  15. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 85 citations and includes a subject term index and title list.)

  16. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 84 citations and includes a subject term index and title list.)

  17. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  18. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 119 citations and includes a subject term index and title list.)

  19. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  20. Method of regulating the amount of underfire air for combustion of wood fuels in spreader-stroke boilers

    DOE Patents [OSTI]

    Tuttle, Kenneth L. (Federal Way, WA)

    1980-01-01

    A method of metering underfire air for increasing efficiency and reducing particulate emissions from wood-fire, spreader-stoker boilers is disclosed. A portion of the combustion air, approximately one pound of air per pound of wood, is fed through the grate into the fuel bed, while the remainder of the combustion air is distributed above the fuel in the furnace, and the fuel bed is maintained at a depth sufficient to consume all oxygen admitted under fire and to insure a continuous layer of fresh fuel thereover to entrap charred particles inside the fuel bed.

  1. Combustion aspects of the reapplication of energetic materials as fuels as a viable demil technology

    SciTech Connect (OSTI)

    Baxter, L.; Davis, K.; Sinquefield, S.; Huey, S.; Lipkin, J.; Shah, D.; Ross, J.; Sclippa, G.

    1996-05-01

    This investigation addresses the combustion-related aspects of the reapplication of energetic materials as fuels in boilers as an economically viable and environmentally acceptable use of excess energetic materials. The economics of this approach indicate that the revenues from power generation and chemical recovery approximately equal the costs of boiler modification and changes in operation. The primary tradeoff is the cost of desensitizing the fuels against the cost of open burn/open detonation (OB/OD) or other disposal techniques. Two principal combustion-related obstacles to the use of energetic-material-derived fuels are NO{sub x} generation and the behavior of metals. NO{sub x} measurements obtained in this investigation indicate that the nitrated components (nitrocellulose, nitroglycerin, etc.) of energetic materials decompose with NO{sub x} as the primary product. This can lead to high uncontrolled NO{sub x} levels (as high as 2,600 ppm on a 3% O{sub 2} basis for a 5% blend of energetic material in the fuel). NO{sub x} levels are sensitive to local stoichiometry and temperature. The observed trends resemble those common during the combustion of other nitrogen-containing fuels. Implications for NO{sub x} control strategies are discussed. The behavior of inorganic components in energetic materials tested in this investigation could lead to boiler maintenance problems such as deposition, grate failure, and bed agglomeration. The root cause of the problem is the potentially extreme temperature generated during metal combustion. Implications for furnace selection and operation are discussed.

  2. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  3. Graphite fuels combustion off-gas treatment options

    SciTech Connect (OSTI)

    Kirkham, R.J.; Lords, R.E.

    1993-03-01

    Scenarios for burning bulk graphite and for burning crushed fuel particles from graphite spent nuclear fuels have been considered. Particulates can be removed with sintered metal filters. Subsequent cooling would then condense semi-volatile fission products into or onto a particulate. These particulates would be trapped by a second sintered metal filter or downstream packed bed. A packed bed scrub column can be used to eliminate most of the iodine-129 and tritium. A molecular sieve bed is proposed to collect the residual {sup 129}I and other tramp radionuclides downstream (Ruthenium, etc.). Krypton-85 can be recovered, if need be, either by cryogenics or by the KALC process (Krypton Adsorption in Liquid Carbon dioxide). Likewise carbon-14 in the form of carbon dioxide could be collected with a caustic or lime scrub solution and incorporated into a grout. Sulfur dioxide present will be well below regulatory concern level of 4.0 tons per year and most of it would be removed by the scrubber. Carbon monoxide emissions will depend on the choice of burner and start-up conditions. Should the system exceed the regulatory concern level, a catalytic converter in the final packed bed will be provided. Radon and its daughters have sufficiently short half-lives (less than two minutes). If necessary, an additional holdup bed can be added before the final HEPA filters or additional volume can be added to the molecular sieve bed to limit radon emissions. The calculated total effective dose equivalent at the Idaho National Engineering Laboratory boundary from a single release of all the {sup 3}, {sup 14}C, {sup 85}Kr, and {sup 129}I in the total fuel mass if 0.43 mrem/year.

  4. Combined catalysts for the combustion of fuel in gas turbines

    DOE Patents [OSTI]

    Anoshkina, Elvira V.; Laster, Walter R.

    2012-11-13

    A catalytic oxidation module for a catalytic combustor of a gas turbine engine is provided. The catalytic oxidation module comprises a plurality of spaced apart catalytic elements for receiving a fuel-air mixture over a surface of the catalytic elements. The plurality of catalytic elements includes at least one primary catalytic element comprising a monometallic catalyst and secondary catalytic elements adjacent the primary catalytic element comprising a multi-component catalyst. Ignition of the monometallic catalyst of the primary catalytic element is effective to rapidly increase a temperature within the catalytic oxidation module to a degree sufficient to ignite the multi-component catalyst.

  5. The origin of organic pollutants from the combustion of alternative fuels: Phase IV report

    SciTech Connect (OSTI)

    Taylor, P.H.; Dellinger, B.; Sidhu, S.K.

    1997-06-01

    As part of the US-DOE`s on-going interest in the use of alternative automotive fuels, the University of Dayton Research Institute has been conducting research on pollutant emissions resulting from the combustion of candidate fuels. This research, under the direction and sponsorship of the NREL, has been concerned primarily with the combustion of compressed natural gas, liquefied petroleum gas (LPG), methanol, and ethanol. In the first 24 months of this program, studies of the oxygen rich, stoichiometric, and fuel-rich thermal degradation of these fuels in the temperature range of 300 to 1100{degrees}C at atmospheric pressure and for reaction times of 1.0 and 2.0 s were completed. Trace organic products were identified and quantified for each fuel as a function of temperature. The results of these studies agreed well with the results of tail-pipe emission studies in that the types and quantity of emissions measured in both the laboratory and engine tests were shown to be very similar under certain operating conditions. However, some chemicals were observed in the laboratory studies that were not observed in the engine studies and vice versa. This result is important in that it has implications concerning the origin of these emissions. Experiments concerning the NO perturbed oxidation of methanol, M85, ethanol, and E85 indicated the presence of complex oxidation chemistry. At mild temperatures, NO addition resulted in enhanced fuel conversion. At elevated temperatures, an inhibitory effect was observed through increased yields of both partial oxidation and pyrolysis-type reaction products. Comparison of flow reactor product distributions with engine test results generally indicated improved comparisons when NO was added to the fuel. Analysis of secondary components of alcohol fuels resulted in some unexpected observations. Several previously unidentified species were observed in these experiments which may impact atmospheric reactivity assessments of these fuels.

  6. Fossil Energy Program semiannual progress report for April 1991 through September 1991

    SciTech Connect (OSTI)

    Judkins, R.R.

    1992-10-01

    This report covers progress made during the period April 1, 1991, through September 30, 1991, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Fossil Energy Office of Petroleum Reserves, and the US Agency for International Development (USAID). The Fossil Energy Program organization chart is shown in the appendix. Project discussed are: materials research and development; environmental analysis support; coal conversion development; coal combustion research; fossil fuel supplies modeling and research; evaluations and assessments; and coal structure and chemistry.

  7. ROSE-based compact simulator for fossil fuel-fired power plant

    SciTech Connect (OSTI)

    Dana, H.; Burelle, R.

    1996-11-01

    Nuclear simulators specifications typically ask for {open_quotes}high fidelity full scope replica simulator{close_quotes}. This request is not only the norm but also mandatory due to the strict regulations and safety concerns in that industry. It is an unquestionable fact that these types of simulators do provide the most realistic and effective environment to train control room operators in normal, abnormal operations, and especially in emergency conditions which would be difficult to rehearse otherwise. Utilities in the fossil industry who could afford the price that these top of the line simulators demand would not hesitate long to acquire one. Fortunately for the others, this industry has the luxury to be more flexible in its simulator`s needs which permits utilities to select a simulator within their specific budget. They may chose from a wide range of different types of simulators, including full scope or partial scope, high fidelity or generic, hardware control rooms replicas or CRT-based graphical emulations. In all cases, a simulator must be economically beneficial to plant operations to justify its cost. Taking into account the distinctive requirements of the fossil industry, including their budget constraints, CAE used its vast experience in nuclear simulators to produce a user-friendly, CRT-based compact fossil simulator, using ROSE (Real-time Object-oriented Software Environment). This paper describes the specifics and characteristics of the ROSE-base compact simulator.

  8. Advanced combustion, emission control, health impacts, and fuels merit review and peer evaluation

    SciTech Connect (OSTI)

    None, None

    2006-10-01

    This report is a summary and analysis of comments from the Advisory Panel at the FY 2006 DOE National Laboratory Advanced Combustion, Emission Control, Health Impacts, and Fuels Merit Review and Peer Evaluation, held May 15-18, 2006 at Argonne National Laboratory. The work evaluated in this document supports the FreedomCAR and Vehicle Technologies Program. The results of this merit review and peer evaluation are major inputs used by DOE in making its funding decisions for the upcoming fiscal year.

  9. Methods and systems to thermally protect fuel nozzles in combustion systems

    DOE Patents [OSTI]

    Helmick, David Andrew; Johnson, Thomas Edward; York, William David; Lacy, Benjamin Paul

    2013-12-17

    A method of assembling a gas turbine engine is provided. The method includes coupling a combustor in flow communication with a compressor such that the combustor receives at least some of the air discharged by the compressor. A fuel nozzle assembly is coupled to the combustor and includes at least one fuel nozzle that includes a plurality of interior surfaces, wherein a thermal barrier coating is applied across at least one of the plurality of interior surfaces to facilitate shielding the interior surfaces from combustion gases.

  10. Basic combustion and pollutant-formation processes for pulverized fuels. Quarterly technical progress report No. 4, 1 July 1981-30 September 1981

    SciTech Connect (OSTI)

    Germane, G.J.; Smoot, L.D.

    1981-10-15

    This contract study of basic combustion and pollutant formation processes for pulverized solid fossil fuels includes coal-water mixtures and chars derived from coal pyrolysis, liquefaction or gasification processes. The factors that affect the physical properties of coal-water mixtures (CWM) have been identified and characterization tests initiated to determine how these variables (e.g., solids loading, particle size, particle size distribution, additives) affect the coal slurries. A bench-scale apparatus consisting of a pressure vessel and an atomizing nozzle was designed and is being fabricated. This apparatus will assist in the development of handling and atomization techniques for the combustion tests. It will also aid in comparing viscosities of slurries of different solids loadings and coal types. Chars were obtained for characterization tests. A series of potential tests to characterize the chars was identified. Grading and sizing of the chars was begun as well as elemental analysis. Samples of the chars were sent to Phillips for CO/sub 2/ reactivity tests to be performed. Coding for incorporation of swirling flows into the two-dimensional coal combustion model (PCGC-2) was completed. Debugging was initiated and sample computations are performed for a gaseous, isothermal system for low swirl numbers. Convergence problems were encountered when attempts were made to complete runs at higher swirl numbers.

  11. Experimental Investigation of Fuel-Reactivity Controlled Compression Ignition (RCCI) Combustion Mode in a Multi-Cylinder, Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Cho, Kukwon; Curran, Scott; Prikhodko, Vitaly Y; Sluder, Scott; Parks, II, James E; Wagner, Robert M

    2011-01-01

    An experimental study was performed to provide the combustion and emission characteristics resulting from fuel-reactivity controlled compression ignition (RCCI) combustion mode utilizing dual-fuel approach in a light-duty, multi-cylinder diesel engine. In-cylinder fuel blending using port fuel injection of gasoline before intake valve opening (IVO) and early-cycle, direct injection of diesel fuel was used as the charge preparation and fuel blending strategy. In order to achieve the desired auto-ignition quality through the stratification of the fuel-air equivalence ratio ( ), blends of commercially available gasoline and diesel fuel were used. Engine experiments were performed at an engine speed of 2300rpm and an engine load of 4.3bar brake mean effective pressure (BMEP). It was found that significant reduction in both nitrogen oxide (NOx) and particulate matter (PM) was realized successfully through the RCCI combustion mode even without applying exhaust gas recirculation (EGR). However, high carbon monoxide (CO) and hydrocarbon (HC) emissions were observed. The low combustion gas temperature during the expansion and exhaust processes seemed to be the dominant source of high CO emissions in the RCCI combustion mode. The high HC emissions during the RCCI combustion mode could be due to the increased combustion quenching layer thickness as well as the -stratification at the periphery of the combustion chamber. The slightly higher brake thermal efficiency (BTE) of the RCCI combustion mode was observed than the other combustion modes, such as the conventional diesel combustion (CDC) mode, and single-fuel, premixed charge compression ignition (PCCI) combustion mode. The parametric study of the RCCI combustion mode revealed that the combustion phasing and/or the peak cylinder pressure rise rate of the RCCI combustion mode could be controlled by several physical parameters premixed ratio (rp), intake swirl intensity, and start of injection (SOI) timing of directly injected fuel unlike other low temperature combustion (LTC) strategies.

  12. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    DOE Patents [OSTI]

    Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

    2012-05-15

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  13. Sandia Energy - DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DISI Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Fuels DISI Combustion DISI CombustionAshley Otero2015-10-28T02:15:13+00:00 In order to...

  14. Enhancing Transportation Energy Security through Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Energy Security through Advanced Combustion and Fuels Technologies Enhancing Transportation Energy Security through Advanced Combustion and Fuels Technologies 2005 ...

  15. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of air pollutant emissions. In Phase 3, the team retrofitted three fuel-flexible burners into a fired heater at a Shell plant and demonstrated the project’s technology over a 6-month period. The project burners performed well during this period. They remain in commercial service at the Shell plant. Through this work, an improved understanding of flame stabilization mechanisms was gained. Also, methods for accommodating a wide range of fuel compositions were developed. This knowledge facilitated the commercialization of a new generation of burners that are suitable for the fuels of the future.

  16. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    SciTech Connect (OSTI)

    Hai Xiao; Junhang Dong; Jerry Lin; Van Romero

    2011-12-31

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project ??DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases.? This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  17. The origin and fate of organic pollutants from the combustion of alternative fuels

    SciTech Connect (OSTI)

    1995-06-01

    The overall objective of this project is to determine the impact of alternative fuels on air quality, particularly ozone formation. The objective will be met through three steps: (1) qualitative identification of alternative fuel combustion products, (2) quantitative measurement of specific emission levels of these products, and (3) determination of the fate of the combustion products in the atmosphere. The alternative fuels of interest are methanol, ethanol, natural gas, and LP gas. The role of the University of Dayton Research Institute (UDRI) in this project is two-fold. First, fused silica flow reactor instrumentation is being used to obtain both qualitative identification and quantitative data on the thermal degradation products from the fuel-lean (oxidative), stoichiometric, and fuel-rich (pyrolytic) decomposition of methanol, ethanol, liquefied petroleum gas, and natural gas. Secondly, a laser photolysis/laser-induced fluorescence (LP/LIF) apparatus is being used to determine the rates and mechanisms of reaction of selected degradation products under atmospheric conditions. This draft final report contains the results of the second year of the study. The authors initially discuss the results of their flow reactor studies. This is followed by a discussion of the initial results from their LP/LIF studies of the reaction of hydroxyl (OH) radicals with methanol and ethanol. In the coming year, they plan to obtain quantitative data on the oxidation of methyl-t-butyl-ether and reformulated gasoline under fuel-lean, stoichiometric, and fuel-rich conditions. They also plan to conduct a mechanistic analysis of the reaction of OH with acetaldehyde and formaldehyde over an extended temperature range.

  18. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Parag Kulkarni; Wei Wei; Arnaldo Frydman; Thomas McNulty; Roger Shisler

    2005-11-01

    It is expected that in the 21st century the Nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It will be necessary to improve both the process efficiency and environmental impact performance of fossil fuel utilization. GE Global Research is developing an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP module offers the potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions including NO{sub x}. GE was awarded a contract from U.S. DOE NETL to develop the UFP technology. Work on the Phase I program started in October 2000, and work on the Phase II effort started in April 2005. In the UFP technology, coal and air are simultaneously converted into separate streams of (1) high-purity hydrogen that can be utilized in fuel cells or turbines, (2) sequestration-ready CO{sub 2}, and (3) high temperature/pressure vitiated air to produce electricity in a gas turbine. The process produces near-zero emissions with an estimated efficiency higher than IGCC with conventional CO2 separation. The Phase I R&D program established the feasibility of the integrated UFP technology through lab-, bench- and pilot-scale testing and investigated operating conditions that maximize separation of CO{sub 2} and pollutants from the vent gas, while simultaneously maximizing coal conversion efficiency and hydrogen production. The Phase I effort integrated experimental testing, modeling and preliminary economic studies to demonstrate the UFP technology. The Phase II effort will focus on three high-risk areas: economics, sorbent attrition and lifetime, and product gas quality for turbines. The economic analysis will include estimating the capital cost as well as the costs of hydrogen and electricity for a full-scale UFP plant. These costs will be benchmarked with IGCC polygen costs for plants of similar size. Sorbent attrition and lifetime will be addressed via bench-scale experiments that monitor sorbent performance over time and by assessing materials interactions at operating conditions. The product gas from the third reactor (high-temperature vitiated air) will be evaluated to assess the concentration of particulates, pollutants and other impurities relative to the specifications required for gas turbine feed streams. This is the eighteenth quarterly technical progress report for the UFP program, which is supported by U.S. DOE NETL (Contract No. DE-FC26-00FT40974) and GE. This report summarizes program accomplishments for the Phase II period starting July 01, 2005 and ending September 30, 2005. The report includes an introduction summarizing the UFP technology, main program tasks, and program objectives; it also provides a summary of program activities and accomplishments covering progress in tasks including process modeling, scale-up and economic analysis.

  19. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  20. Krakow clean fossil fuels and energy efficiency program. Final report: Initial site investigation

    SciTech Connect (OSTI)

    1995-11-15

    Original objective of this project was to retrofit the Balice Boilerhouse with a TCS Coal Micronization system and Amerex baghouses to achieve higher combustion efficiencies and lower air emission, including SO{sub 2}, NO{sub x}, CO and particulate matter. The Balice Boilerhouse is located adjacent to the Krakow Airport and provides heating steam for the Polish Military Unit No. 1616. In May 1995 the Polish Military announced it had decided to convert its boiler house to gas; thus cancelling the TCS Project. The balance of 1995 was spent considering alternative Project sites in Krakow for the application of the TCS coal Micronization technology.

  1. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  2. Proceedings of the second US Department of Energy environmental control symposium. Volume 1. Fossil energy

    SciTech Connect (OSTI)

    1980-06-01

    These proceedings document the presentations given at the Second Environmental Control Symposium. Symposium presentations highlighted environmental control activities which span the entire DOE. Volume I contains papers relating to coal preparation, oil shales, coal combustion, advanced coal utilization (fluidized bed combustion, MHD generators, OCGT, fuel cells), coal gasification, coal liquefaction, and fossil resource extraction (enhanced recovery). Separate abstracts for individual papers are prepared for inclusion in the Energy Data Base. (DMC)

  3. Control of SO{sub 2} and NOx emissions from fossil fuel-fired power plants: Research and practice of TPRI

    SciTech Connect (OSTI)

    Ming-Chuan Zhang

    1993-12-31

    The generation of electric power in China has been dominated by coal for many years. By the end of 1990, total installed generating capacity reached 135 GW, of which fossil fuel-fired plants accounted for 74 percent. The total electricity generated reached 615 TWh, with fossil fuels accounting for 80.5 percent. About 276 million tons of raw coal are consumed in these fossil fuel-burning units per year, accounting for about 25 percent of the total output of the country. According to the government, by the year 2000, the total installed capacity of Chinese power systems should be at least 240 GW, of which fossil fuels will account for about 77 percent. The coal required for power generation will increase to about 530 million tons per year, accounting for about 38 percent of the total coal output. So, it is obvious that coal consumed in coal-fired power plants occupies a very important place in the national fuel balance. The current environmental protection standards, which are based on ground-level concentrations of pollutants, do not effectively lead to the control of pollution emission concentrations or total SO{sub 2} emissions. Due to the practical limitations of the Chinese economy, there is a limited capability to introduce advanced sulfur emission control technologies. Thus, except for the two 360 MW units imported from Japan for the Luohuang Power Plant in Shichuan province, all the other fossil fuel-fired units have not yet adopted any kind of SO{sub 2} removal measures. The Luohuang units are equipped with Mitsubishi limestone flue gas desulfurization systems. Because of the lack of effective pollution control technologies, large areas of the country have been seriously polluted by SO{sub 2}, and some of them even by acid rain.

  4. Fossil fuel power plants: Computer systems for power plant control, maintenance, and operation. (Latest citations from the Compendex database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    The bibliography contains citations concerning fossil fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 250 citations and includes a subject term index and title list.)

  5. A formalized approach to cycle chemistry improvement in fossil fuel power plants

    SciTech Connect (OSTI)

    Dimmer, J.P.; Dooley, R.B.

    1995-01-01

    The overall cost impact of cycle chemistry problems in fossil plants is typically hidden within the statistics of component forced outages, efficiency losses and premature end of useful component life. Corrosion of components in US utility steam generating plants is responsible for an estimated 50% of forced outages and over three billion dollars a year in additional operating and maintenance costs. These problems are usually the direct result of repeat incidents of impurity ingress, corrosion, and/or corrosion product generation transport, and deposition on heat transfer and power generation process equipment surfaces. The only way to prevent repeat incidents of cycle chemistry corrosion and/or deposition-influenced equipment problems is to implement a formalized cycle chemistry improvement program that addresses the root-causes of these problems. This paper describes such a program being implemented at twelve (12) utilities under EPRI research project RP2712-11, {open_quotes}Cycle Chemistry Improvement Program.{close_quotes} Interim utility results, after almost three years of project participation, have demonstrated substantial reductions in availability/performance losses and water treatment costs due to applications of state-of-the-art cycle chemistry, monitoring equipment and/or process control systems.

  6. Fossil Energy

    Office of Environmental Management (EM)

    Fossil Energy Research and Development Fossil Energy Research and Development Table of Contents Page Appropriation Language .................................................................................................................... FE-3 Overview ............................................................................................................................................ FE-4 Coal

  7. DOE - Fossil Energy:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Energy RSS Feeds RSS, sometimes known as Really Simple Syndication, is a popular means of sharing content (such as news headlines) without requiring readers to constantly visit a Web site to see what’s new. RSS feeds contain headlines and hyperlinks to longer articles or Web pages. RSS feeds from the Office of Fossil Energy provide updates of specific interest to the fossil fuel community. Fossil Energy RSS feeds are free of charge. RSS content can be read using software called an RSS

  8. A Combustion Model for the TWA 800 Center-Wing Fuel Tank Explosion

    SciTech Connect (OSTI)

    Baer, M.R.; Gross, R.J.

    1998-10-02

    In support of the National Transportation Safety Board investigation of the TWA Flight 800 accident, a combined experimental/computational effort was conducted that focused on quarter-scale testing and simulation of the fuel-air explosion in the Boeing 747 center wing fuel tank. This report summarizes the modeling approach used at Sandia National Laboratories. In this approach approximations are introduced that capture the essential physics associated with turbulent flame propagation in multiple compartment fuel tanks. This model efficiently defines the pressure loading conditions during a jet-fuel air explosion in a fuel tank confinement. Modeling calculations compare favorably with a variety of experimental quarter-scale tests conducted in rigid confinement. The modeling describes well the overpressure history in several geometry configurations. Upon demonstrating a reasonable comparison to experimental observations, a parametric study of eight possible ignition sources is then discussed. Model calculations demonstrate that different loading conditions arise as the location of the ignition event is varied. By comparing the inferred damage and calculated impulses to that seen in the recovered tank, it maybe possible to reduce the number of likely sources. A possible extension of this work to better define tank damage includes coupling the combustion model as a pressure loading routine for structural failure analysis.

  9. An Integrated Hydrogen Production-CO2 Capture Process from Fossil Fuel

    SciTech Connect (OSTI)

    Zhicheng Wang

    2007-03-15

    The new technology concept integrates two significant complementary hydrogen production and CO{sub 2}-sequestration approaches that have been developed at Oak Ridge National Laboratory (ORNL) and Clark Atlanta University. The process can convert biomass into hydrogen and char. Hydrogen can be efficiently used for stationary power and mobile applications, or it can be synthesized into Ammonia which can be used for CO{sub 2}-sequestration, while char can be used for making time-release fertilizers (NH{sub 4}HCO{sub 3}) by absorption of CO{sub 2} and other acid gases from exhaust flows. Fertilizers are then used for the growth of biomass back to fields. This project includes bench scale experiments and pilot scale tests. The Combustion and Emission Lab at Clark Atlanta University has conducted the bench scale experiments. The facility used for pilot scale tests was built in Athens, GA. The overall yield from this process is 7 wt% hydrogen and 32 wt% charcoal/activated carbon of feedstock (peanut shell). The value of co-product activated carbon is about $1.1/GJ and this coproduct reduced the selling price of hydrogen. And the selling price of hydrogen is estimated to be $6.95/GJ. The green house experimental results show that the samples added carbon-fertilizers have effectively growth increase of three different types of plants and improvement ability of keeping fertilizer in soil to avoid the fertilizer leaching with water.

  10. Webinar: Fuzzy Mud and the Future of Alternative Fuels | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Webinar: Fuzzy Mud and the Future of Alternative Fuels Share Browse By - Any - Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Diesel ---Electric drive technology ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Powertrain research --Building design ---Construction --Manufacturing -Energy sources --Renewable energy ---Bioenergy ---Solar energy --Fossil fuels ---Natural Gas --Nuclear energy ---Nuclear

  11. Combustion characterization of coal/refuse derived fuels using thermogravimetric-fourier transform infrared-mass spectrometry

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Lu, Huagang; Hyatt, J.

    1995-12-31

    The fundamental thermal behavior of five materials (Illinois coal No. 6, Kentucky coal No. 9, polyvinyl chloride, cellulose, newspaper) has been investigated using the TGA/FTIR/MS system under the condition of combustion. The system was used to identify molecular chlorine, along with HCI, CO, CO{sub 2}, H{sub 2}O and various hydrocarbons in the gaseous products of the combustion of PVC resin in air. This is a significant finding that will lead us to examine this combustion step further to look for the formation of chlorinated organic compounds during co-firing of coal with refuse derived fuels.

  12. An Experimental and Chemical Kinetics Study of the Combustion of Syngas and High Hydrogen Content Fuels

    SciTech Connect (OSTI)

    Santoro, Robers; Dryer, Frederick; Ju, Yiguang

    2013-09-30

    An integrated and collaborative effort involving experiments and complementary chemical kinetic modeling investigated the effects of significant concentrations of water and CO2 and minor contaminant species (methane [CH4], ethane [C2H6], NOX, etc.) on the ignition and combustion of HHC fuels. The research effort specifically addressed broadening the experimental data base for ignition delay, burning rate, and oxidation kinetics at high pressures, and further refinement of chemical kinetic models so as to develop compositional specifications related to the above major and minor species. The foundation for the chemical kinetic modeling was the well validated mechanism for hydrogen and carbon monoxide developed over the last 25 years by Professor Frederick Dryer and his co-workers at Princeton University. This research furthered advance the understanding needed to develop practical guidelines for realistic composition limits and operating characteristics for HHC fuels. A suite of experiments was utilized that that involved a high-pressure laminar flow reactor, a pressure-release type high-pressure combustion chamber and a high-pressure turbulent flow reactor.

  13. Optical-Engine Study of a Low-Temperature Combustion Strategy Employing a Dual-Row, Narrow-Included-Angle Nozzle and Early, Direct Injection of Diesel Fuel

    Broader source: Energy.gov [DOE]

    Insight into mechanisms causing observed sharp emissions increase with diesel fuel injection is gained through experiments in an optical engine employing a similar low-temperature combustion strategy of early, direct injection of diesel fuel.

  14. Investigation on Flame Characteristics and Burner Operability Issues of Oxy-Fuel Combustion

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-05-30

    Oxy-fuel combustion has been used previously in a wide range of industrial applications. Oxy- combustion is carried out by burning a hydrocarbon fuel with oxygen instead of air. Flames burning in this configuration achieve higher flame temperatures which present opportunities for significant efficiency improvements and direct capture of CO{sub 2} from the exhaust stream. In an effort to better understand and characterize the fundamental flame characteristics of oxy-fuel combustion this research presents the experimental measurements of flame stability of various oxyfuel flames. Effects of H{sub 2} concentration, fuel composition, exhaust gas recirculation ratio, firing inputs, and burner diameters on the flame stability of these fuels are discussed. Effects of exhaust gas recirculation i.e. CO{sub 2} and H{sub 2}O (steam) acting as diluents on burner operability are also presented. The roles of firing input on flame stability are then analyzed. For this study it was observed that many oxy-flames did not stabilize without exhaust gas recirculation due to their higher burning velocities. In addition, the stability regime of all compositions was observed to decrease as the burner diameter increased. A flashback model is also presented, using the critical velocity gradient g{sub F}) values for CH{sub 4}-O{sub 2}-CO{sub 2} flames. The scaling relation (𝐠{sub F} = 𝐜 𝐒{sub 𝐋}{sup 2}/𝛂) for different burner diameters was obtained for various diameter burners. The report shows that results correlated linearly with a scaling value of c =0.0174. The second part of the study focuses on the experimental measurements of the flow field characteristics of premixed CH{sub 4}/21%O{sub 2}/79%N{sub 2} and CH{sub 4}/38%O{sub 2}/72%CO{sub 2} mixtures at constant firing input of 7.5 kW, constant, equivalence ratio of 0.8, constant swirl number of 0.92 and constant Reynolds Numbers. These measurements were taken in a swirl stabilized combustor at atmospheric pressure. The flow field visualization using Particle Imaging Velocimetry (PIV) technique is implemented to make a better understanding of the turbulence characteristics of CH{sub 4}/air and CH{sub 4}/38%O{sub 2}/72%CO{sub 2} combustion. The velocity fluctuations, turbulence intensities and local propagation velocities along the combustion chamber have been determined. The turbulent intensities increase as we move away from the combustor axis. CH{sub 4}-38%O{sub 2}-72%CO{sub 2} flames have low radial velocity and turbulent intensity distributions at different axial distances when compared with CH{sub 4}-Air flames.

  15. An Internet-based interactive module for air emissions from fossil fuel based power generation

    SciTech Connect (OSTI)

    Karman, D.; O`Leary, K.; O`Reilly, S.

    1997-12-31

    The proliferation of the Internet, Web pages and associated software tools available for developing multimedia material provides significant opportunities in training, education and information transfer. This paper will describe the development, testing and evaluation of an interactive teaching module aimed at college and university students that have previous education in thermodynamics and basic chemistry. The module is currently in development at the Department of Civil and Environmental Engineering at Carleton University with support from Environment Canada. Preliminary testing of this module is expected to begin late January. The module contains options to look at CO, CO{sub 2}, SO{sub 2} and NO{sub x} emissions associated with electric power generation in thermal stations that use coal, natural gas, crude and distillate oil. Factors governing the thermal efficiency of typical boiler systems and the thermodynamic limitations for converting heat into work are discussed. Supporting background information such as emission trends and emission factors used in calculations are also included as part of this module. A simple Rankine cycle without reheat or regeneration is considered to compare the emissions per unit energy delivered from each of the fuels considered. For natural gas and distillate oil, combined cycle operation is considered with a gas turbine-heat recovery steam generator combination replacing the boiler in the simple Rankine cycle. For all fuels, the cogeneration option is investigated by expanding the steam to an intermediate pressure in the turbine and utilizing the remaining heat by condensing the steam in a heat recovery application. Emission factors and basic information on CO, SO{sub 2} and NO{sub x} control technologies are utilized to calculate and report the emissions per unit energy delivered under the various scenarios investigated.

  16. On droplet combustion of biodiesel fuel mixed with diesel/alkanes in microgravity condition

    SciTech Connect (OSTI)

    Pan, Kuo-Long; Li, Je-Wei; Chen, Chien-Pei; Wang, Ching-Hua

    2009-10-15

    The burning characteristics of a biodiesel droplet mixed with diesel or alkanes such as dodecane and hexadecane were experimentally studied in a reduced-gravity environment so as to create a spherically symmetrical flame without the influence of natural convection due to buoyancy. Small droplets on the order of 500 {mu}m in diameter were initially injected via a piezoelectric technique onto the cross point intersected by two thin carbon fibers; these were prepared inside a combustion chamber that was housed in a drag shield, which was freely dropped onto a foam cushion. It was found that, for single component droplets, the tendency to form a rigid soot shell was relatively small for biodiesel fuel as compared to that exhibited by the other tested fuels. The soot created drifted away readily, showing a puffing phenomenon; this could be related to the distinct molecular structure of biodiesel leading to unique soot layers that were more vulnerable to oxidative reactivity as compared to the soot generated by diesel or alkanes. The addition of biodiesel to these more traditional fuels also presented better performance with respect to annihilating the soot shell, particularly for diesel. The burning rate generally follows that of multi-component fuels, by some means in terms of a lever rule, whereas the mixture of biodiesel and dodecane exhibits a somewhat nonlinear relation with the added fraction of dodecane. This might be related to the formation of a soot shell. (author)

  17. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect (OSTI)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025. Other potential benefits of the demonstration include developing a passive technology for water treatment for trace metal and nutrient release reductions, using power plant by-products to improve coal mine land reclamation and carbon sequestration, developing wildlife habitat and green-space around production facilities, generating Total Maximum Daily Load (TMDL) credits for the use of process water, and producing wood products for use by the lumber and pulp and paper industry. Project activities conducted during the five year project period include: Assessing tree cultivation and other techniques used to sequester carbon; Project site assessment; Greenhouse studies to determine optimum plant species and by-product application; Designing, constructing, operating, monitoring, and evaluating the CCWESTRS system; and Reporting (ongoing). The ability of the system to sequester carbon will be the primary measure of effectiveness, measured by accessing survival and growth response of plants within the CCWESTRS. In addition, costs associated with design, construction, and monitoring will be evaluated and compared to projected benefits of other carbon sequestration technologies. The test plan involves the application of three levels each of two types of power plant by-products--three levels of FGD gypsum mulch, and three levels of ash pond irrigation water. This design produces nine treatment levels which are being tested with two species of hardwood trees (sweet gum and sycamore). The project is examining the effectiveness of applications of 0, 8-cm, and 15-cm thick gypsum mulch layers and 0, 13 cm, and 25 cm of coal fly ash water for irrigation. Each treatment combination is being replicated three times, resulting in a total of 54 treatment plots (3 FGD gypsum levels X 3 irrigation water levels x 2 tree species x 3 replicates). Survival and growth response of plant species in terms of sequestering carbon in plant material and soil will be the primary measure of effectiveness of each treatment. Additionally, the ability of the site soils and unsaturated zone subsurface m

  18. Experimental Investigation of the Effects of Fuel Characteristics on High Efficiency Clean Combustion (HECC) in a Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Cho, Kukwon; Han, Manbae; Wagner, Robert M; Sluder, Scott

    2009-01-01

    An experimental study was performed to understand fuel property effects on low temperature combustion (LTC) processes in a light-duty diesel engine. These types of combustion modes are often collectively referred to as high efficiency clean combustion (HECC). A statistically designed set of research fuels, the Fuels for Advanced Combustion Engines (FACE), were used for this study. Engine conditions consistent with low speed cruise (1500 rpm, 2.6 bar BMEP) were chosen for investigating fuel property effects on HECC operation in a GM 1.9-L common rail diesel engine. The FACE fuel matrix includes nine combinations of fuel properties including cetane number (30 to 55), aromatic contents (20 to 45 %), and 90 % distillation temperature (270 to 340 C). HECC operation was achieved with high levels of EGR and adjusting injection parameters, e.g. higher fuel rail pressure and single injection event, which is also known as Premixed Charge Compression Ignition (PCCI) combustion. Engine performance, pollutant emissions, and details of the combustion process are discussed in this paper. Cetane number was found to significantly affect the combustion process with variations in the start of injection (SOI) timing, which revealed that the ranges of SOI timing for HECC operation and the PM emission levels were distinctively different between high cetane number (55) and low cetane number fuels (30). Low cetane number fuels showed comparable levels of regulated gas emissions with high cetane number fuels and had an advantage in PM emissions.

  19. Fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Topical report February 1994--February 1995

    SciTech Connect (OSTI)

    1995-02-01

    Experiments were made on use of H and CH plasmas for converting waste materials and heavy oils to H-rich transportation fuels. Batch and continuous experiments were conducted with an industrial microwave generator and a commercial microwave oven. A continuously circulating reactor was constructed for conducting experiments on flowing oils. Experiments on decomposition of scrap tires showed that microwave plasmas can be used to decompose scrap tires into potentially useful liquid products. In a batch experiment using a commercial microwave oven, about 20% of the tire was converted to liquid products in about 9 minutes. Methane was decomposed in a microwave plasma to yield a liquid products composed of various compound types; GC/MS analyses identified unsaturated compounds including benzene, toluene, ethyl benzene, methyl and ethyl naphthalene, small amounts of larger aromatic rings, and olefinic compounds. Experiments on a crude oil in a continuously flowing reactor showed that distillate materials are produced using H and CH plasmas. Also, the recycle oils had an overall carbon aromaticity lower than that of starting feed material, indicating that some hydrogenation and methanation had taken place in the recycle oils.

  20. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  1. Krakow clean fossil fuels and energy efficiency program. Phase 1 report

    SciTech Connect (OSTI)

    Butcher, T.; Pierce, B.

    1995-06-01

    Krakow is one of the largest and oldest cities in Poland. It is situated in the south of the country on the banks of the Vistula River. From the 11th until the 17th centuries, it was the capital of Poland. Today, Krakow is a city of 750,000 residents, one of the largest centers of higher education, an important industrial center, and is of particular importance because of the number and kinds of historic buildings and sites. For this reason, Krakow was included by the UNESCO in the list of the world`s cultural heritages. For about three decades, significant air pollution has been one of Krakow`s most serious problems. Because the city is situated in the Vistula River valley, it is poorly ventilated and experiences a high concentration of air pollutants. The quality of air in Krakow is affected mainly by industry (Sendzimir Steelworks, energy industry, chemical plants), influx from the Silesian industrial region (power plants, metallurgy), transboundary pollution (Ostrava - Czech Republic), and local sources of low pollution, i.e. more than 1,000 boiler houses using solid fuels and more than 100,000 coal-fired home stoves. These local sources, with low stacks and almost no pollution-control equipment, are responsible for about 35-40% of the air pollution. This report presents phase I results of a program to reduce pollution in krakow. Phase I was to gather information on emissions and costs, and to verify assumptions on existing heating methods and alternatives.

  2. A perspective on the range of gasoline compression ignition combustion strategies for high engine efficiency and low NOx and soot emissions: Effects of in-cylinder fuel stratification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dempsey, Adam B.; Curran, Scott J.; Wagner, Robert M.

    2016-01-14

    Many research studies have shown that low temperature combustion in compression ignition engines has the ability to yield ultra-low NOx and soot emissions while maintaining high thermal efficiency. To achieve low temperature combustion, sufficient mixing time between the fuel and air in a globally dilute environment is required, thereby avoiding fuel-rich regions and reducing peak combustion temperatures, which significantly reduces soot and NOx formation, respectively. It has been demonstrated that achieving low temperature combustion with diesel fuel over a wide range of conditions is difficult because of its properties, namely, low volatility and high chemical reactivity. On the contrary, gasolinemore » has a high volatility and low chemical reactivity, meaning it is easier to achieve the amount of premixing time required prior to autoignition to achieve low temperature combustion. In order to achieve low temperature combustion while meeting other constraints, such as low pressure rise rates and maintaining control over the timing of combustion, in-cylinder fuel stratification has been widely investigated for gasoline low temperature combustion engines. The level of fuel stratification is, in reality, a continuum ranging from fully premixed (i.e. homogeneous charge of fuel and air) to heavily stratified, heterogeneous operation, such as diesel combustion. However, to illustrate the impact of fuel stratification on gasoline compression ignition, the authors have identified three representative operating strategies: partial, moderate, and heavy fuel stratification. Thus, this article provides an overview and perspective of the current research efforts to develop engine operating strategies for achieving gasoline low temperature combustion in a compression ignition engine via fuel stratification. In this paper, computational fluid dynamics modeling of the in-cylinder processes during the closed valve portion of the cycle was used to illustrate the opportunities and challenges associated with the various fuel stratification levels.« less

  3. Fossil Energy Word Find | Department of Energy

    Office of Environmental Management (EM)

    Word Find Fossil Energy Word Find Word Find (inlcuidng answer key) PDF icon Fossil Energy Word Search More Documents & Publications Fossil Energy Crossword Puzzle Coal Study Guide for Elementary School Guide to Low-Emission Boiler and Combustion Equipment Selection

  4. Comminution phenomena during the fluidized bed combustion of a commercial refuse-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A.; Chirone, R.; D`Anna, G.

    1995-12-31

    A commercial densified refuse-derived fuel (RDF), obtained as pellets from municipal solid wastes, was burned in two laboratory scale bubbling fluidized bed combustors, having an internal diameter of 41 mm. The apparatus were both batchwise operated at 850 C by injecting batches of RDF particles into a bed of silica sand (300--400 {micro}m as size range) fluidized at a superficial gas velocity of 0.8 m/s. RDF particles with equivalent mean diameter ranging from 4 to 9 mm were used. Different experimental procedures were set up to separately investigate comminution phenomena of fuel particles. Results were compared with those obtained burning a South African bituminous coal. Results pointed out that RDF particles undergo a strong primary fragmentation phenomenon, with a probability of particle breakage equal to 1 for fuel particles larger than 6 mm. Attrition and char fragmentation phenomena are particularly relevant under both inert and oxidizing conditions, generating a large amount of unburned fines which may affect overall combustion efficiency.

  5. Table 11.6 Installed Nameplate Capacity of Fossil-Fuel Steam-Electric Generators With Environmental Equipment, 1985-2010 (Megawatts)

    U.S. Energy Information Administration (EIA) Indexed Site

    Installed Nameplate Capacity of Fossil-Fuel Steam-Electric Generators With Environmental Equipment," " 1985-2010 (Megawatts)" "Year","Coal",,,,"Petroleum and Natural Gas",,,,"Total 1" ,,,"Flue Gas","Total 2",,,"Flue Gas","Total 2",,,"Flue Gas","Total 2"

  6. Optical investigation of the combustion behaviour inside the engine operating in HCCI mode and using alternative diesel fuel

    SciTech Connect (OSTI)

    Mancaruso, E.; Vaglieco, B.M.

    2010-04-15

    In order to understand the effect of both the new homogeneous charge compression ignition (HCCI) combustion process and the use of biofuel, optical measurements were carried out into a transparent CR diesel engine. Rape seed methyl ester was used and tests with several injection pressures were performed. OH and HCO radical were detected and their evolutions were analyzed during the whole combustion. Moreover, soot concentration was measured by means the two colour pyrometry method. The reduction of particulate emission with biodiesel as compared to the diesel fuel was noted. Moreover, this effect resulted higher increasing the injection pressure. In the case of RME the oxidation of soot depends mainly from O{sub 2} content of fuel and OH is responsible of the NO formation in the chamber as it was observed for NO{sub x} exhaust emission. Moreover, it was investigated the evolution of HCO and CO into the cylinder. HCO was detected at the start of combustion. During the combustion, HCO oxidizes due to the increasing temperature and it produces CO. Both fuels have similar trend, the highest concentrations are detected for low injection pressure. This effect is more evident for the RME fuel. (author)

  7. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  8. Prediction of Combustion Stability and Flashback in Turbines with High-Hydrogen Fuel

    SciTech Connect (OSTI)

    Lieuwen, Tim; Santavicca, Dom; Yang, Vigor

    2012-03-31

    During the duration of this sponsorship, we broadened our understanding of combustion instabilities through both analytical and experimental work. Predictive models were developed for flame response to transverse acoustic instabilities and for quantifying how a turbulent flame responds to velocity and fuel/air ratio forcing. Analysis was performed on the key instability mechanisms controlling heat release response for flames over a wide range of instability frequencies. Importantly, work was done closely with industrial partners to transition existing models into internal instability prediction codes. Experimentally, the forced response of hydrogen-enriched natural gas/air premixed and partially premixed flames were measured. The response of a lean premixed flame was investigated, subjected to velocity, equivalence ratio, and both forcing mechanisms simultaneously. In addition, important physical mechanisms controlling the response of partially premixed flames to inlet velocity and equivalence ratio oscillations were analyzed. This final technical report summarizes our findings and major publications stemming from this program.

  9. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  10. Municipal Solid Waste Combustion : Fuel Testing and Characterization : Task 1 Report, May 30, 1990-October 1, 1990.

    SciTech Connect (OSTI)

    Bushnell, Dwight J.; Canova, Joseph H.; Dadkhah-Nikoo, Abbas.

    1990-10-01

    The objective of this study is to screen and characterize potential biomass fuels from waste streams. This will be accomplished by determining the types of pollutants produced while burning selected municipal waste, i.e., commercial mixed waste paper residential (curbside) mixed waste paper, and refuse derived fuel. These materials will be fired alone and in combination with wood, equal parts by weight. The data from these experiments could be utilized to size pollution control equipment required to meet emission standards. This document provides detailed descriptions of the testing methods and evaluation procedures used in the combustion testing and characterization project. The fuel samples will be examined thoroughly from the raw form to the exhaust emissions produced during the combustion test of a densified sample.

  11. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels Research Team Members Key Contacts Fuels Gasification will likely be the cornerstone of future energy and chemical processes due to its flexibility to accommodate numerous feedstocks such as coal, biomass, and natural gas, and to produce a variety of products, including heat and specialty chemicals. Advanced integrated gasification combined cycle schemes require the production of clean hydrogen to fuel innovative combustion turbines and fuel cells. This research will focus on development

  12. Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Duty/Spray Combustion - Spray Combustionadmin2015-10-28T02:00:56+00:00 Optically accessible high-temperature, high-pressure spray chamber Optically accessible high-temperature, high-pressure spray chamber Fuel spray injection is expected to be one of the key elements for enabling high-efficiency, low-emission engines of the future. Understanding the details of the spray combustion process is therefore now more important than ever. But investigating engine combustion processes is

  13. CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS

    SciTech Connect (OSTI)

    Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

    2009-11-30

    This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

  14. Effects of Combustion-Induced Vortex Breakdown on Flashback Limits of Syngas-Fueled Gas Turbine Combustors

    SciTech Connect (OSTI)

    Ahsan Choudhuri

    2011-03-31

    Turbine combustors of advanced power systems have goals to achieve very low pollutants emissions, fuel variability, and fuel flexibility. Future generation gas turbine combustors should tolerate fuel compositions ranging from natural gas to a broad range of syngas without sacrificing operational advantages and low emission characteristics. Additionally, current designs of advanced turbine combustors use various degrees of swirl and lean premixing for stabilizing flames and controlling high temperature NOx formation zones. However, issues of fuel variability and NOx control through premixing also bring a number of concerns, especially combustor flashback and flame blowout. Flashback is a combustion condition at which the flame propagates upstream against the gas stream into the burner tube. Flashback is a critical issue for premixed combustor designs, because it not only causes serious hardware damages but also increases pollutant emissions. In swirl stabilized lean premixed turbine combustors onset of flashback may occur due to (i) boundary layer flame propagation (critical velocity gradient), (ii) turbulent flame propagation in core flow, (iii) combustion instabilities, and (iv) upstream flame propagation induced by combustion induced vortex breakdown (CIVB). Flashback due to first two foregoing mechanisms is a topic of classical interest and has been studied extensively. Generally, analytical theories and experimental determinations of laminar and turbulent burning velocities model these mechanisms with sufficient precision for design usages. However, the swirling flow complicates the flashback processes in premixed combustions and the first two mechanisms inadequately describe the flashback propensity of most practical combustor designs. The presence of hydrogen in syngas significantly increases the potential for flashback. Due to high laminar burning velocity and low lean flammability limit, hydrogen tends to shift the combustor operating conditions towards flashback regime. Even a small amount of hydrogen in a fuel blend triggers the onset of flashback by altering the kinetics and thermophysical characteristics of the mixture. Additionally, the presence of hydrogen in the fuel mixture modifies the response of the flame to the global effects of stretch and preferential diffusion. Despite its immense importance in fuel flexible combustor design, little is known about the magnitude of fuel effects on CIVB induced flashback mechanism. Hence, this project investigates the effects of syngas compositions on flashback resulting from combustion induced vortex breakdown. The project uses controlled experiments and parametric modeling to understand the velocity field and flame interaction leading to CIVB driven flashback.

  15. Gasoline-like Fuel Effects on High-load, Boosted HCCI Combustion Employing Negative Valve Overlap Strategy

    SciTech Connect (OSTI)

    Kalaskar, Vickey B; Szybist, James P; Splitter, Derek A

    2014-01-01

    In recent years a number of studies have demonstrated that boosted operation combined with external EGR is a path forward for expanding the high load limit of homogeneous charge compression ignition (HCCI) operation with the negative valve overlap (NVO) valve strategy. However, the effects of fuel composition with this strategy have not been fully explored. In this study boosted HCCI combustion is investigated in a single-cylinder research engine equipped with direct injection (DI) fueling, cooled external exhaust gas recirculation (EGR), laboratory pressurized intake air, and a fully-variable hydraulic valve actuation (HVA) valve train. Three fuels with significant compositional differences are investigated: regular grade gasoline (RON = 90.2), 30% ethanol-gasoline blend (E30, RON = 100.3), and 24% iso-butanol-gasoline blend (IB24, RON = 96.6). Results include engine loads from 350 to 800 kPa IMEPg for all fuels at three engine speeds 1600, 2000, and 2500 rpm. All operating conditions achieved thermal efficiency (gross indicated efficiency) between 38 and 47%, low NOX emissions ( 0.1 g/kWh), and high combustion efficiency ( 96.5%). Detailed sweeps of intake manifold pressure (atmospheric to 250 kPaa), EGR (0 25% EGR), and injection timing are conducted to identify fuel-specific effects. The major finding of this study is that while significant fuel compositional differences exist, in boosted HCCI operation only minor changes in operational conditions are required to achieve comparable operation for all fuels. In boosted HCCI operation all fuels were able to achieve matched load-speed operation, whereas in conventional SI operation the fuel-specific knock differences resulted in significant differences in the operable load-speed space. Although all fuels were operable in boosted HCCI, the respective air handling requirements are also discussed, including an analysis of the demanded turbocharger efficiency.

  16. Fossil Energy RSS Feeds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy RSS Feeds Fossil Energy RSS Feeds RSS, sometimes known as Really Simple Syndication, is a popular means of sharing content (such as news headlines) without requiring readers to constantly visit a Web site to see what's new. RSS feeds contain headlines and hyperlinks to longer articles or Web pages. RSS feeds from the Office of Fossil Energy provide updates of specific interest to the fossil fuel community. Fossil Energy RSS feeds are free of charge. RSS content can be read using

  17. Sandia Energy - Pressurized Combustion and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion and Gasification Home Transportation Energy Predictive Simulation of Engines Clean FuelsPower Solid Fuels Conversion Pressurized Combustion and Gasification...

  18. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Bergman, H.L.

    1980-01-04

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  19. Low temperature combustion using nitrogen enrichment to mitigate NOx from large bore natural gas fueled engines.

    SciTech Connect (OSTI)

    Biruduganti, M.; Gupta, S.; Sekar, R.; Energy Systems

    2010-01-01

    Low temperature combustion is identified as one of the pathways to meet the mandatory ultra low NO{sub x} emissions levels set by the regulatory agencies. Exhaust gas recirculation (EGR) is a well known technique to realize low NO{sub x} emissions. However, EGR has many built-in adverse ramifications that negate its advantages in the long term. This paper discusses nitrogen enrichment of intake air using air separation membranes as a better alternative to the mature EGR technique. This investigation was undertaken to determine the maximum acceptable level of nitrogen enrichment of air for a single-cylinder spark-ignited natural gas engine. NO{sub x} reduction as high as 70% was realized with a modest 2% nitrogen enrichment while maintaining power density and simultaneously improving fuel conversion efficiency (FCE). Any enrichment beyond this level degraded engine performance in terms of power density, FCE, and unburned hydrocarbon emissions. The effect of ignition timing was also studied with and without N{sub 2} enrichment. Finally, lean burn versus stoichiometric operation utilizing nitrogen enrichment was compared. Analysis showed that lean burn operation along with nitrogen enrichment is one of the effective pathways for realizing better FCE and lower NO{sub x} emissions.

  20. Supersonic combustion engine and method of combustion initiation and distribution

    SciTech Connect (OSTI)

    Stickler, D.B.; Ballantyne, A.; Kyuman Jeong.

    1993-06-29

    A supersonic combustion ramjet engine having a combustor with a combustion zone intended to channel gas flow at relatively high speed therethrough, the engine comprising: means for substantially continuously supplying fuel into the combustion zone; and means for substantially instantaneously igniting a volume of fuel in the combustion zone for providing a spatially controlled combustion distribution, the igniting means having means for providing a diffuse discharge of energy into the volume, the volume extending across a substantially complete cross-sectional area of the combustion zone, the means for discharging energy being capable of generating free radicals within the volume of reactive fuel in the combustion zone such that fuel in the volume can initiate a controlled relatively rapid combustion of fuel in the combustion zone whereby combustion distribution in relatively high speed gas flows through the combustion zone can be initiated and controlled without dependence upon a flame holder or relatively high local static temperature in the combustion zone.

  1. Boiler and steam generator corrosion: Fossil-fuel power plants. March 1977-December 1989 (A Bibliography from the NTIS data base). Report for March 1977-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. Hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 88 citations fully indexed and including a title list.)

  2. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  3. Response to several FOIA requests - Renewable Energy. Demand for Fossil

    Energy Savers [EERE]

    Fuels | Department of Energy Demand for Fossil Fuels Response to several FOIA requests - Renewable Energy. Demand for Fossil Fuels Response to several FOIA requests - Renewable Energy. nepdg_251_500.pdf. Demand for Fossil Fuels. Renewable sources of power. Demand for fossil fuels surely will overrun supply sooner or later, as indeed it already has in the casc of United States domestic oil drilling. Recognition also is growing that our air and land can no longer absorb unlimited quantities

  4. Sensitivity of natural gas HCCI combustion to fuel and operating parameters using detailed kinetic modeling

    SciTech Connect (OSTI)

    Aceves, S; Dibble, R; Flowers, D; Smith, J R; Westbrook, C K

    1999-07-19

    This paper uses the HCT (Hydrodynamics, Chemistry and Transport) chemical kinetics code to analyze natural gas HCCI combustion in an engine. The HCT code has been modified to better represent the conditions existing inside an engine, including a wall heat transfer correlation. Combustion control and low power output per displacement remain as two of the biggest challenges to obtaining satisfactory performance out of an HCCI engine, and these are addressed in this paper. The paper considers the effect of natural gas composition on HCCI combustion, and then explores three control strategies for HCCI engines: DME (dimethyl ether) addition, intake heating and hot EGR addition. The results show that HCCI combustion is sensitive to natural gas composition, and an active control may be required to compensate for possible changes in composition. The three control strategies being considered have a significant effect in changing the combustion parameters for the engine, and should be able to control HCCI combustion.

  5. Advanced Combustion Engine R&D and Fuels Technology Merit Review...

    Office of Environmental Management (EM)

    PDF icon Annual Progress Report More Documents & Publications Heavy Vehicle Systems Optimization Peer Review 2008 Annual Merit Review Results Summary - 7. Combustion Research 2012...

  6. DOE Science Showcase - Fuel Cells Research | OSTI, US Dept of Energy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Scientific and Technical Information DOE Science Showcase - Fuel Cells Research Clean, Efficient, and Reliable Power for the 21st Century Fuel cells are an important enabling technology for the nation's energy portfolio and have the potential to revolutionize the way we power our nation, offering cleaner, more-efficient alternatives to the combustion of gasoline and other fossil fuels. Courtesy of DOE Fuel Cell Technologies Program Fuel Cells Research Results in DOE Databases DOE

  7. Role of fuel/oxidizer ratio on the synthesis conditions of CuAl{sub 2}O{sub 3} nanocomposite prepared through solution combustion synthesis

    SciTech Connect (OSTI)

    Nasiri, H.; Bahrami Motlagh, E.; Vahdati Khaki, J.; Zebarjad, S.M.

    2012-11-15

    Highlights: ? With increasing the fuel to oxidizer ratio synthesis products changed from CuO to Cu{sub 2}O. ? With increasing the fuel to oxidizer ratio the combustion temperature decreased. ? Maximum ratio that synthesis could occur was achieved. ? The stoichiometric ratio had the maximum combustion temperature. ? Solution with graphite had lower combustion temperature. -- Abstract: The role of fuel/oxidizer ratio in the synthesis conditions of CuAl{sub 2}O{sub 3} nanocomposite, which was prepared through solution combustion synthesis, method was investigated. For this purpose, copper and aluminum nitrates as well as urea were used as oxidizer and fuel, respectively. The fuel/oxidizer (F/O) ratios were selected from the range of 0.91.75. The products were analyzed using X-ray diffraction, SEM and TEM techniques. During the process the temperature was recorded as a function of time. The results showed that by increasing the F/O ratio up to the stoichiometric amount, the combustion temperature increases. Further increment of F/O ratio resulted in a decrease in the combustion temperature. Microscopic evaluations, using SEM and TEM, proved feasibility of the production of CuAl{sub 2}O{sub 3} through this method.

  8. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  9. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas Fletcher; Alan Sayre

    2003-01-01

    The goal of this project is to carry out the necessary experiments and analyses to extend leading submodels of coal transformations to the new conditions anticipated in next-generation energy technologies. During the first project quarter, a technical kick-off meeting was held on the Brown campus involving PIs from Brown (Hurt, Calo), BYU (Fletcher), and B&W (Sayre, Burge). Following this first meeting the current version of CBK (Version 8) was transferred to B&W McDermott and the HP-CBK code developed by BYU was transferred to Brown to help guide the code development in this project. Also during the first project year, progress was reviewed at an all-hands meeting was held at Brigham Young University in August, 2001. The meeting was attended by PIs Fletcher, Hurt, Calo, and Sayre, and also by affiliated investigators Steven Burge from McDermott and Prof. William Hecker from BYU. During the first project year, significant progress was made on several fronts, as described in detail in the previous annual report. In the current second annual report, we report on progress made on two important project tasks. At Brown University: (1) Char combustion reactivities at 500 C in air were determined for a diverse set of solid fuels and organic model compound chars. These varied over 4 orders of magnitude for the chars prepared at 700 C, and over 3 orders of magnitude for the chars prepared at 1000 C. The resultant reactivities correlate poorly with organic elemental composition and with char surface area. (2) Specially-acquired model materials with minute amounts of inorganic matter exhibit low reactivities that fall in a narrow band as a function of wt-% carbon. Reactivities in this sample subset correlate reasonably well with total char surface area. (3) A hybrid chemical/statistical model was developed which explains most of the observed reactivity variation based on four variables: the amounts of nano-dispersed K, nanodispersed (Ca+Mg), elemental carbon (wt-% daf), and nano-dispersed vanadium, listed in decreasing order of importance. Catalytic effects play a very significant role in the oxidation of most practical solid fuel chars. Some degree of reactivity estimation is possible using only elemental analyses of parent fuels, but only if correlative techniques make use of the existing body of knowledge on the origin, form and dispersion of inorganic matter in various fuel classes. During the past year at BYU, work focused primarily on renovation of the BYU high pressure drop tube reactor (HPDT). This work has included design and testing of a flat-flame burner that can be operated at high pressure. A high-temperature, high-pressure gas profile has been achieved within this high-pressure flat-flame burner (HP-FFB). Detailed descriptions of the design and testing of the HP-FFB are given in this report. In addition, continued char reactivity experiments in the high pressure thermogravimetric analyzer (HP-TGA) have been performed on chars produced at different pressures in the HPDT. Results of the HP-TGA reactivity studies on a high-volatile A bituminous (Pittsburgh No.8) char are that intrinsic char activation energy increases with pyrolysis pressure, and that the oxygen order is roughly 0.9. These results are different than previous research on chars produced at atmospheric pressure. These new data show that the rate constant decreases with increasing pyrolysis pressure. However, the hydrogen content of the new chars produced at elevated pressures was fairly high ({approx}2 wt. %, daf), and char samples produced at higher temperatures are desired. During the next project year, experimental work on oxygen reactivity at high pressure will continue at BYU, and on CO{sub 2} reactivity at high pressure at Brown University. Selected chars produced at BYU under high pressure conditions will also be used at Brown for reactivity studies.

  10. Decision-maker's guide to wood fuel for small industrial energy users. Final report. [Includes glossary

    SciTech Connect (OSTI)

    Levi, M. P.; O'Grady, M. J.

    1980-02-01

    The technology and economics of various wood energy systems available to the small industrial and commercial energy user are considered. This book is designed to help a plant manager, engineer, or others in a decision-making role to become more familiar with wood fuel systems and make informed decisions about switching to wood as a fuel. The following subjects are discussed: wood combustion, pelletized wood, fuel storage, fuel handling and preparation, combustion equipment, retrofitting fossil-fueled boilers, cogeneration, pollution abatement, and economic considerations of wood fuel use. (MHR)

  11. Applied combustion

    SciTech Connect (OSTI)

    1993-12-31

    From the title, the reader is led to expect a broad practical treatise on combustion and combustion devices. Remarkably, for a book of modest dimension, the author is able to deliver. The text is organized into 12 Chapters, broadly treating three major areas: combustion fundamentals -- introduction (Ch. 1), thermodynamics (Ch. 2), fluid mechanics (Ch. 7), and kinetics (Ch. 8); fuels -- coal, municipal solid waste, and other solid fuels (Ch. 4), liquid (Ch. 5) and gaseous (Ch. 6) fuels; and combustion devices -- fuel cells (Ch. 3), boilers (Ch. 4), Otto (Ch. 10), diesel (Ch. 11), and Wankel (Ch. 10) engines and gas turbines (Ch. 12). Although each topic could warrant a complete text on its own, the author addresses each of these major themes with reasonable thoroughness. Also, the book is well documented with a bibliography, references, a good index, and many helpful tables and appendices. In short, Applied Combustion does admirably fulfill the author`s goal for a wide engineering science introduction to the general subject of combustion.

  12. Dual-Fuel Combustion Turbine Provides Reliable Power to U.S. Navy Submarine Base New London in Groton, Connecticut

    SciTech Connect (OSTI)

    Halverson, Mark A.)

    2002-01-01

    In keeping with a long-standing tradition of running Base utilities as a business, the U.S. Navy Submarine Base New London installed a dual-fuel combustion turbine with a heat recovery boiler. The 5-megawatt (MW) gas- and oil-fired combustion turbine sits within the Lower Base area, just off the shores of the Thames River. The U.S. Navy owns, operates, and maintains the combined heat and power (CHP) plant, which provides power to the Navy?s nuclear submarines when they are in port and to the Navy?s training facilities at the Submarine Base. Heat recovered from the turbine is used to produce steam for use in Base housing, medical facilities, and laundries. In FY00, the Navy estimates that it will save over $500,000 per year as a result of the combined heat and power unit.

  13. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion...

    Office of Scientific and Technical Information (OSTI)

    Fuels obtained in late 2011, which will be evaluated in 2012, include a series of oil shale derived fuels from PNNL, green diesel fuel (hydrotreated vegetable oil) from UOP, ...

  14. DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels/DISI Combustion - DISI Combustionadmin2015-10-28T02:15:13+00:00 In order to reduce our dependence on petroleum and to reduce CO2emissions, it is important to both supplement traditional gasoline with renewable fuels and to improve the fuel efficiency of automotive engines. Under the Energy Independence and Security Act (EISA) of 2007, the volume of renewable fuel required to be blended into transportation fuel will increase from 9 billion gallons in 2008 to 36 billion gallons by 2022. At

  15. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  16. Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

    SciTech Connect (OSTI)

    Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

    2011-12-22

    The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

  17. Fossil energy program. Progress report for May 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-08-01

    This report - the seventieth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, technical support to the TVA fluidized bed combustion demonstration plant program, coal cogeneration/district heating plant assessment, atmospheric fluidized bed coal combustor for cogeneration, performance assurance system support and international energy technology assessment.

  18. Fossil energy program. Progress report for June 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-08-01

    This report - the seventy-first of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluation, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, TVA fluidized combustion demonstration plant program technical support, coal cogeneration/district heating plant assessment, performance assurance system support, and international energy technology assessment.

  19. Fossil Energy Program. Progress report for April 1980

    SciTech Connect (OSTI)

    McNeese, L.E.

    1980-06-01

    This report - the sixty-ninth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, coal cogeneration/district heating plant assessment, performance assurance system support, and international energy technology assessment.

  20. Office of Fossil Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Energy - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  1. Los Alamos Lab: Fossil Energy & Environment, Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office > Applied Energy Programs > Fossil Energy Science Program Office Applied Energy Civilian Nuclear Office of Science CONTACTS Program Director Melissa Fox 505-665-0896 A New Era for Fossil Fuels The Office of Fossil Energy and Environment (FE) is the focal point for Los Alamos' efforts in fossil energy R&D. As part of the Science Program Office, FE leads the program development related to research on the use of conventional and unconventional fossil fuels, including associated

  2. Is combustion of plastics desirable?

    SciTech Connect (OSTI)

    Piasecki, B.; Rainey, D.; Fletcher, K.

    1998-07-01

    Managing waste will always entail some tradeoffs. All of the three options--recycling, landfilling and combustion--have some disadvantages. Even landfilling, which produces no emissions, fails to take advantage of the energy value inherent in plastic. Waste combustion, on the other hand, recovers the energy in plastic materials and reduces the volume of disposed solid waste by up to 90% of its initial preburn volumes. However, this management option generates emissions and produces an ash residue that must be managed. As demonstrated by recent test burns, improvements in combustion and air-pollution-control technology have dramatically reduced the health risks from emissions and ash. Recent studies have shown that plastics--in quantities even higher than those normally found in municipal solid waste--do not adversely affect levels of emissions or the quality of ash from waste-to-energy facilities. In addition, waste-to-energy facilities may be a relatively economical source of fuel, and may be a more economic solution to waste management than the other available options. A waste-to-energy plant generally produces electricity that is sold to the electric utilities for approximately six cents per kilowatt-hour, a rate that is competitive with those offered by nuclear power plants and power plants that generate energy by burning fossil fuels.

  3. Multicylinder Diesel Engine for Low Temperature Combustion Operation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Low Temperature Combustion Operation Multicylinder Diesel Engine for Low Temperature Combustion Operation Fuel injection strategies to extend low temperature combustion ...

  4. Basic Research Needs for Clean and Efficient Combustion of 21st Century Transportation Fuels

    SciTech Connect (OSTI)

    McIlroy, A.; McRae, G.; Sick, V.; Siebers, D. L.; Westbrook, C. K.; Smith, P. J.; Taatjes, C.; Trouve, A.; Wagner, A. F.; Rohlfing, E.; Manley, D.; Tully, F.; Hilderbrandt, R.; Green, W.; Marceau, D.; O'Neal, J.; Lyday, M.; Cebulski, F.; Garcia, T. R.; Strong, D.

    2006-11-01

    To identify basic research needs and opportunities underlying utilization of evolving transportation fuels, with a focus on new or emerging science challenges that have the potential for significant long-term impact on fuel efficiency and emissions.

  5. Vehicle Technologies Office Merit Review 2014: Fuel Properties to Enable Lifted Flame Combustion

    Broader source: Energy.gov [DOE]

    Presentation given by Ford Motor Company at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fuel properties to enable...

  6. Design, operation, and performance of a modern air pollution control system for a refuse derived fuel combustion facility

    SciTech Connect (OSTI)

    Weaver, E.H.; Azzinnari, C.

    1997-12-01

    The Robbins, Illinois refuse derived fuel combustion facility was recently placed into service. Large and new, the facility is designed to process 1600 tons of waste per day. Twenty-five percent of the waste, or 400 tons per day, is separated out in the fuel preparation process. The remaining 1200 tons per day is burned in two circulating fluidized bed boilers. The system is designed to meet new source performance standards for municipal waste combustion facilities, including total particulate, acid gases (HCl, SO{sub 2}, HF), heavy metals (including mercury), and dioxins. The system utilizes semi-dry scrubbers with lime and activated carbon injected through dual fluid atomizers for control of acid gases. Final polishing of acid gas emissions, particulate control, heavy metals removal, and control of dioxins is accomplished with pulse jet fabric filters. This paper discusses the design of the facility`s air pollution control system, including all auxiliary systems required to make it function properly. Also discussed is the actual operation and emissions performance of the system.

  7. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

    2008-10-21

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  8. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  9. Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  11. DOE - Fossil Energy: Office of Fossil Energy Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clean Coal Technologies - Carbon Capture, Utilization and Storage - Hydrogen & Other Clean Fuels - Oil & Natural Gas Technologies - Natural Gas Regulation - U.S. Petroleum Reserves - STAY CONNECTED Join Us on Facebook Follow Us on Twitter Sign Up for NewsAlerts Subscribe to our RSS Feeds Office of Fossil Energy home page FOSSIL ENERGY NEWS SPOTLIGHT Regional Partnership Documentary Wins "Best of Show" Aurora Award A documentary co-produced by Prairie Public Broadcasting and the

  12. Fossil-fuel power plants: Computer systems for power plant control, maintenance, and operation. October 1976-December 1989 (A Bibliography from the COMPENDEX data base). Report for October 1976-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-02-01

    This bibliography contains citations concerning fossil-fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 240 citations fully indexed and including a title list.)

  13. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis ...

  14. Enabling High Efficiency Clean Combustion with Micro-Variable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel Injector and Adaptive PCCI Enabling High Efficiency Clean Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel ...

  15. Final Report: No{sub x} Emissions from By Product Fuel Combustion in Steel Making, September 15, 1996 - October 15, 1999

    SciTech Connect (OSTI)

    Pershing, David W.; Lighty, JoAnn S.; Eddings, Eric G.; Cacciatore, David A.

    1999-01-28

    Exhaust gases from the primary operations in the steel making process are almost exclusively utilized as supplemental fuels within the steel plant. These by-product fuels include blast furnace gas (BFG) and coke oven gas (COG) which contain mixtures of H{sub 2}, CO, CH{sub 4} and trace amounts of some heavier hydrocarbons and the impurities NH{sub 3} and HCN. These fuels are burned alone or in combination with natural gas to fire the coke ovens, blast furnace stoves utility boilers and metal working furnaces. The utilization of these by-product fuels reduces the waste gas emissions at the steel mill and reduces the requirements for outside fuel sources. However, as with primary fuel sources, the combustion of these by-product fuel blends does produce hazardous pollutants, in particular nitrogen oxides, and because these are atypical fuel blends of varying composition, the pollutant formation is not well understood. The objective of this research was to develop an understanding of the mechanisms controlling NO{sub x} formation from the combustion of by-product fuels from the steel industry and investigate control and design options to minimize emissions. The minimization strategies investigated were constrained by limits on CO and hydrocarbon emissions, both of which increased under fuel-rich combustion scenarios that resulted in reduced NO{sub x} emissions. Also, the minimization strategies were constrained by the need for reasonable heat generation rates in the furnaces that employ these by-product fuels, so that product steel quality is not adversely affected.

  16. Fuel Effects on Combustion and Emissions of a Direct-Inection Diesel Engine Operating at Moderate to High Engine Speed and Load

    SciTech Connect (OSTI)

    Szybist, James P; Szymkowicz, Patrick G.; Northrop, William F

    2012-01-01

    It is advantageous to increase the specific power output of diesel engines and to operate them at higher load for a greater portion of a driving cycle to achieve better thermal efficiency and thus reduce vehicle fuel consumption. Such operation is limited by excessive smoke formation at retarded injection timing and high rates of cylinder pressure rise at more advanced timing. Given this window of operation, it is desired to understand the influence of fuel properties such that optimum combustion performance and emissions can be retained over the range of fuels commonly available in the marketplace. It has been shown in previous studies that varying cetane number (CN) of diesel fuel has little effect on ignition delay at high engine load due to the domination of high cylinder temperature on ignition kinetics. The work here experimentally confirms that finding but also shows that emissions and combustion performance vary according to fuel reactivity. Data are examined from a direct-injection single cylinder research engine for eight common diesel fuels including soy-based biodiesel blends at two high load operating points with no exhaust gas recirculation (EGR) and at a moderate load with four levels of EGR. It is shown in the work that at high engine load where combustion is controlled by mixing processes, CN and other fuel properties have little effect on engine performance, although lower CN fuels produce a small increase in noise, smoke and CO emissions. Biodiesel blends increase NOX emissions and decreases CO and smoke emissions at high load, but otherwise have little effect on performance. At moderate load, higher CN fuels are more tolerant to EGR due to their better chemical reactivity at retarded injection timing, but all fuels produce comparable thermal efficiency at advanced combustion phasing regardless of EGR. In contrast to the high load conditions, there was no increase in NOX emissions for biodiesel at the moderate load condition. It is concluded that although higher CN does not significantly alter ignition delay at moderate to high loads it has a dominant influence on the acceptable injection timing range. Apart from CN effects, fuel oxygen content plays an independent role in reducing some emissions. It is therefore recommended that compensation for fuel ignitability and oxygen content be included in combustion control strategies to optimize emissions and performance of future diesel engines.

  17. Chemical Kinetic Reaction Mechanisms for Combustion of Hydrocarbon and Other Types of Chemical Fuels

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Reaction mechanisms have been tested and validated extensively through comparisons between computed results and measured data from laboratory experiments (e.g., shock tubes, laminar flames, rapid compression machines, flow reactors, stirred reactors) and from practical systems (e.g., diesel engines, spark-ignition engines, homogeneous charge, compression ignition (HCCI) engines). These kinetic models are used to examine a wide range of combustion systems.

  18. Fossil Energy

    Office of Environmental Management (EM)

    of Fossil Energy Natural gas production from "shale" formations (fine-grained sedimentary rocks with relatively low permeability that can be rich sources of petroleum and natural gas) is one of the most rapidly-growing trends in U.S. domestic energy exploration and production. In some cases, this fast expansion has resulted in natural gas drilling and production activity in parts of the country that have seen little or no activity of this type in the recent past. "Natural Gas from

  19. Development of Advanced Combustion Technologies for Increased...

    Office of Environmental Management (EM)

    in Improving Thermal Efficiency Heavy-Duty Low Temperature Combustion Development Activities at Caterpillar Fuel Effects on Low Temperature Combustion in a Light-Duty Diesel Engine...

  20. Producing usable fuel from municipal solid waste

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1995-03-01

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  1. Development of a Raman spectroscopy technique to detect alternate transportation fuel hydrocarbon intermediates in complex combustion environments.

    SciTech Connect (OSTI)

    Ekoto, Isaac W.; Barlow, Robert S.

    2012-12-01

    Spontaneous Raman spectra for important hydrocarbon fuels and combustion intermediates were recorded over a range of low-to-moderate flame temperatures using the multiscalar measurement facility located at Sandia/CA. Recorded spectra were extrapolated to higher flame temperatures and then converted into empirical spectral libraries that can readily be incorporated into existing post-processing analysis models that account for crosstalk from overlapping hydrocarbon channel signal. Performance testing of the developed libraries and reduction methods was conducted through an examination of results from well-characterized laminar reference flames, and was found to provide good agreement. The diagnostic development allows for temporally and spatially resolved flame measurements of speciated hydrocarbon concentrations whose parent is more chemically complex than methane. Such data are needed to validate increasingly complex flame simulations.

  2. CO{sub 2}-mitigation measures through reduction of fossil fuel burning in power utilities. Which road to go?

    SciTech Connect (OSTI)

    Kaupp, A.

    1996-12-31

    Five conditions, at minimum, should be examined in the comparative analysis of CO{sub 2}-mitigation options for the power sector. Under the continuing constraint of scarce financial resources for any private or public investment in the power sector, the following combination of requirements characterise a successful CO{sub 2}-mitigation project: (1) Financial attractiveness for private or public investors. (2) Low, or even negative, long range marginal costs per ton of `CO{sub 2} saved`. (3) High impact on CO{sub 2}-mitigation, which indicates a large market potential for the measure. (4) The number of individual investments required to achieve the impact is relatively small. In other words, logistical difficulties in project implementation are minimised. (5) The projects are `socially fair` and have minimal negative impact on any segment of the society. This paper deals with options to reduce carbonaceous fuel burning in the power sector. Part I explains how projects should be selected and classified. Part II describes the technical options. Since reduction of carbonaceous fuel burning may be achieved through Demand Side Management (DSM) and Supply Side Management (SSM) both are treated. Within the context of this paper SSM does not mean to expand power supply as demand grows. It means to economically generate and distribute power as efficiently as possible. In too many instances DSM has degenerated into efficient lighting programs and utility managed incentives and rebate programs. To what extent this is a desirable situation for utilities in Developing Countries that face totally different problems as their counterparts in highly industrialised countries remains to be seen. Which road to go is the topic of this paper.

  3. Integrated Advanced Reciprocating Internal Combustion Engine System for Increased Utilization of Gaseous Opportunity Fuels

    SciTech Connect (OSTI)

    Pratapas, John; Zelepouga, Serguei; Gnatenko, Vitaliy; Saveliev, Alexei; Jangale, Vilas; Li, Hailin; Getz, Timothy; Mather, Daniel

    2013-08-31

    The project is addressing barriers to or opportunities for increasing distributed generation (DG)/combined heat and power (CHP) use in industrial applications using renewable/opportunity fuels. This project brings together novel gas quality sensor (GQS) technology with engine management for opportunity fuels such as landfill gas, digester gas and coal bed methane. By providing the capability for near real-time monitoring of the composition of these opportunity fuels, the GQS output can be used to improve the performance, increase efficiency, raise system reliability, and provide improved project economics and reduced emissions for engines used in distributed generation and combined heat and power.

  4. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of alkali chlorides and sulfates gives increased sintering. At the same time, increased amounts calcium salts in the ash appear to reduce sintering tendency. Thus, the results suggest that a calcium based sorbent for SO{sub 2} and HCl capture might reduce problems related to ash sintering. An extensive literature exists, however, that states otherwise.

  5. Vehicle Technologies Office Merit Review 2015: Gasoline-Like Fuel Effects on Advanced Combustion Regimes

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about gasoline-like...

  6. Vehicle Technologies Office Merit Review 2014: Use of Low Cetane Fuel to Enable Low Temperature Combustion

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the use of low...

  7. Modeling the Fuel Spray and Combustion Process of the Ignition Quality Tester with KIVA-3V

    SciTech Connect (OSTI)

    Bogin, G. E. Jr.; DeFilippo, A.; Chen, J. Y.; Chin, G.; Luecke, J.; Ratcliff, M. A.; Zigler, B. T.; Dean, A. M.

    2010-05-01

    Discusses the use of KIVA-3V to develop a model that reproduces ignition behavior inside the Ignition Quality Tester, which measures the ignition delay of low-volatility fuels.

  8. Vehicle Technologies Office Merit Review 2014: Gasoline-Like Fuel Effects on Advanced Combustion Regimes

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about gasoline-like...

  9. Fuel Effects on Ignition and Their Impact on Advanced Combustion Engines

    Broader source: Energy.gov [DOE]

    Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

  10. EERE Success Story-Arizona: Solar Panels Replace Inefficient Fossil

    Office of Environmental Management (EM)

    Fuel-Powered Energy Systems | Department of Energy Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered Energy Systems EERE Success Story-Arizona: Solar Panels Replace Inefficient Fossil Fuel-Powered Energy Systems May 1, 2014 - 9:33am Addthis The Agricultural Renewable Energy Conversion Incentive Program, funded in part by DOE's State Energy Program (SEP), assists farmers and ranchers to convert fossil-fueled agricultural production systems to renewable energy power. The program

  11. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect (OSTI)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  12. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    SciTech Connect (OSTI)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D.

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  13. Evaluation of vost and semivost methods for halogenated compounds in the Clean Air Act amendments title III. Validation study at fossil fuel plant

    SciTech Connect (OSTI)

    Jackson, M.D.; Knoll, J.E.; Midgett, M.R.; McGaughey, J.F.; Bursey, J.T.

    1993-01-01

    The Clean Air Act Amendments of 1990 (CAAA), Title III, present a need for stationary source sampling and analytical methods for the list of 189 toxic air pollutants. The US Environmental Protection Agency (EPA) has used VOST and SemiVOST sampling and analytical methods for a wide variety of volatile and semivolatile organic compounds in the past, but these methodologies have been completely validated for only a few of the organic compounds. The applicability of VOST and SemiVOST techniques to the halogenated organic compounds listed in Title III of the Clean Air Act Amendments of 1990 has been evaluated under laboratory conditions for chromatographic separation, mass spectrometric response, sorbent recovery and analytical method detection limit. Dynamic spiking techniques for the sampling trains (both gaseous and liquid dynamic spiking) were also evaluated in the laboratory. In the study, the VOST and SemiVOST methods were evaluated in the field at a fossil fuel power plant. The source was selected to provide actual stationary source emissions with the compounds of interest present in trace amounts or not present. The paper presents the results of the field validation of the VOST and SemiVOST sampling and analytical methods.

  14. A review of METC`S continuous process monitoring devices for application to high temperature and pressure fossil fuel process streams

    SciTech Connect (OSTI)

    Chisholm, W.P.

    1994-12-31

    The Morgantown Energy Technology Center of the United States Department of Energy, in support of advanced fossil fuel technologies, is developing and applying a number of innovative continuous process monitors. These include an inductively coupled plasma spectrometer, an alkali monitor, a particle counter and sizer, and a water vapor monitor. The alkali monitor is a flame emission spectrometer currently undergoing field trials. Alkali emission from gasifiers and combustors is of interest because it causes corrosion and deposition on downstream components, such as particle filters, sulfur compound sorbents, turbine blades, etc. This device can measure alkali concentrations at the part-per-billion level. The particle monitoring devices use laser light scattering to count and size particles. By measuring particle concentration around a particulate removal device, capture efficiency can be measured in real time with a resolution of one minute. Particles between .45 and 80 microns can be counted at rates as high as one million per second in 5 bar, 350 degree celsius environments. The optical water vapor monitor uses near-infrared light absorption to monitor and control steam injection in an advanced heat exchanger. It is targeted for a 300 degrees celsius and 5 bar environment. The inductively coupled plasma system uses a helium and argon plasma discharge within a torch assembly capable of accepting a high temperature and pressure sample stream. An artificial neural network is being developed to interpret its data. Real-time data from a bench-scale coal gasifier will be presented and discussed.

  15. Fossil-fuel processing technical/professional services: comparison of Fischer-Tropsch reactor systems. Phase I, final report

    SciTech Connect (OSTI)

    Thompson, G.J.; Riekena, M.L.; Vickers, A.G.

    1981-09-01

    The Fischer-Tropsch reaction was commercialized in Germany and used to produce military fuels in fixed bed reactors. It was recognized from the start that this reactor system had severe operating and yield limitations and alternative reactor systems were sought. In 1955 the Sasol I complex, using an entrained bed (Synthol) reactor system, was started up in South Africa. Although this reactor was a definite improvement and is still operating, the literature is filled with proponents of other reactor systems, each claiming its own advantages. This report provides a summary of the results of a study to compare the development potential of three of these reactor systems with the commercially operating Synthol-entrained bed reactor system. The commercial Synthol reactor is used as a benchmark against which the development potential of the other three reactors can be compared. Most of the information on which this study is based was supplied by the M.W. Kellogg Co. No information beyond that in the literature on the operation of the Synthol reactor system was available for consideration in preparing this study, nor were any details of the changes made to the original Synthol system to overcome the operating problems reported in the literature. Because of conflicting claims and results found in the literature, it was decided to concentrate a large part of this study on a kinetic analysis of the reactor systems, in order to provide a theoretical analysis of intrinsic strengths and weaknesses of the reactors unclouded by different catalysts, operating conditions and feed compositions. The remainder of the study considers the physical attributes of the four reactor systems and compares their respective investment costs, yields, catalyst requirements and thermal efficiencies from simplified conceptual designs.

  16. Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

    SciTech Connect (OSTI)

    Kirby S. Chapman; Amar Patil

    2007-06-30

    Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.

  17. Table 8.5c Consumption of Combustible Fuels for Electricity Generation: Electric Power Sector by Plant Type, 1989-2011 (Breakout of Table 8.5b)

    U.S. Energy Information Administration (EIA) Indexed Site

    5c Consumption of Combustible Fuels for Electricity Generation: Electric Power Sector by Plant Type, 1989-2011 (Breakout of Table 8.5b) Year Coal 1 Petroleum Natural Gas 6 Other Gases 7 Biomass Other 10 Distillate Fuel Oil 2 Residual Fuel Oil 3 Other Liquids 4 Petroleum Coke 5 Total 5 Wood 8 Waste 9 Short Tons Barrels Short Tons Barrels Thousand Cubic Feet Billion Btu Billion Btu Billion Btu Electricity-Only Plants 11<//td> 1989 767,378,330 25,574,094 241,960,194 3,460 517,385 270,124,673

  18. Air-fuel ratio controller for a turbocharged internal combustion engine

    SciTech Connect (OSTI)

    Serve, J.V.; Eckard, D.W.

    1988-09-13

    This patent describes an air-fuel ratio controller for a gaseous-fueled, turbo-charged engine having an air manifold, a gas manifold, and a turbine inlet. The controller consists of: means for controlling air manifold pressure, comprising means for providing an air manifold pressure set point signal based on gas manifold pressure and engine RPM's and at least one constant input; and means for controlling turbine inlet temperature, the means comprising means for modulating the slope of the set point signal for the air manifold pressure controller.

  19. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  20. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D; Swank, William D.

    2011-08-30

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  1. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  2. Turbulent Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  3. Engine Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engine Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  4. APBF Effects on Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    APBF Effects on Combustion APBF Effects on Combustion 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft001_bunting_2010_o.pdf More Documents & Publications Fuel and Lubricant Effects APBF Effects on Combustion Non-Petroleum Based Fuel Effects on Advanced Combustion

  5. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  6. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  7. DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Automotive/DISI Combustion - DISI Combustionadmin2015-10-28T02:06:42+00:00 DISI engine in all-metal configuration with lower oil-collection cylinder installed. DISI engine in all-metal configuration with lower oil-collection cylinder installed. In order to reduce our dependence on petroleum and to reduce CO2emissions, it is important to both supplement traditional gasoline with renewable fuels and to improve the fuel efficiency of automotive engines. Under the Energy Independence and Security

  8. Vehicle Technologies Office Merit Review 2015: Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about fuel effects on...

  9. Vehicle Technologies Office Merit Review 2014: Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratories at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the fuel effects...

  10. A review of trace element emissions from the combustion of refuse-derived fuel with coal

    SciTech Connect (OSTI)

    Norton, G.A. )

    1992-05-01

    The effects of cocombusting refuse-derived fuel (RDF) with coal on stack emissions of trace elements in the ash stream were reviewed. The large number of variables and uncertainties involved precluded drawing definitive conclusions regarding many of the trace elements. However, it is evident that cocombustion resulted in increased emissions of Cd, Cu, Hg, Pb, and Zn. Emissions of As and Ni tended to decrease when RDF was fired with coal. Modeling studies indicated that ambient levels of trace elements during cocombustion should be within acceptable limits. However, periodic monitoring of Cd, Hg, and Pb may be warranted in some instances.

  11. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    e.g., MIT, . . . Interface and Double Layer Density function theory and reaction energies Lithium Ion Di usion Classical molecular dynamics Cell Kinetics Cell-level simulations...

  12. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    depends on developing batteries that are increasingly economical, reliable, and safe. A vehicle battery is a large investment and carries with it a requirement for a long, reliable...

  13. Launching the Next Wave of Clean Fossil Energy Innovation | Department...

    Broader source: Energy.gov (indexed) [DOE]

    an advanced power plant that cuts carbon pollution, or building an efficient microgrid network that better utilizes fossil fuels, loan guarantees under this solicitation...

  14. Advanced Combustion Technology to Enable High Efficiency Clean Combustion

    Office of Energy Efficiency and Renewable Energy (EERE)

    Summary of advanced combustion research at Cummins to explore strategies for fuel economy improvements (PCCI and HECC) and redced engine-out NOx emissions.

  15. Effects of the furnace temperature on the CO, CO{sub 2}, NO{sub x} and unburned hydrocarbon emissions from the combustion of coal and alternative fuels

    SciTech Connect (OSTI)

    Levendis, Y.A.; Atal, A.; Courtemanche, B.

    1999-07-01

    Results are presented on the emissions of carbon monoxide (CO), carbon dioxide (CO{sub 2}), unburned aromatic hydrocarbons, as well as oxides of nitrogen (NO{sub x}) from the combustion of pulverized bituminous coal, tire-derived fuel and, for a limited number of runs, waste plastics-derived fuel. The particle size cuts of pulverized coal, tire and plastics were 63--75 {micro}m and 180--300 {micro}m, respectively. Combustion experiments were conducted in a laboratory-scale drop-tube furnace at gas temperatures, in the range of 1,300--1,600 K, and several fuel mass loadings in the furnace, expressed in terms of global equivalence ratios in the range of 0.4--2.4. The CO, CO{sub 2} and NO{sub x} emissions were monitored continuously with infrared absorption and chemiluminescent instruments. Up to sixty 2-7 ring polynuclear aromatic hydrocarbons (PAH) were detected by capillary gas chromatography - mass spectrometry (GC-MS) techniques. Results showed that the PAH emission yields (mg/g fuel introduced) increased drastically with increasing bulk equivalence ratio (in the aforementioned range), at fixed furnace temperatures. This was also true for the CO yields, while the CO{sub 2} yields increased with increasing {o}, reached a maximum around stoichiometry and then decreased mildly. NO{sub x} yields decreased precipitously with increasing equivalence ratio. The CO and, especially, the PAH yields from tire-derived and plastics-derived fuels were much higher than those from coal, but the relative amounts of individual PAH components were remarkably similar in the combustion effluent of all fuels. The CO{sub 2} emissions and, especially, the NO{sub x} emissions from tire crumb were lower than those from coal. The CO{sub 2} emissions from plastics were comparable to those from coal, but their NO {sub x} emissions were much lower than those from tire. At fixed bulk equivalence ratios, however, as the furnace gas temperature increased the PAH yields from coal, tire crumb, and plastics decreased drastically, while the CO emission yields increased. At the highest temperature tested herein, 1,600 K ({approx}1,300 C), the effluent of the combustion of the fuels appeared to be devoid of PAHs. No{sub x} yields increased mildly with temperature. The influence of temperature, in this range, on the CO{sub 2} emissions was not significant. 65 refs., 2 figs., 1 tab.

  16. ?Aceite Vegetal Puro Como Combustible Diesel? (Straight Vegetable Oil as a Diesel Fuel? Spanish Version) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01

    Discusses the use of straight vegetable oil as a diesel fuel and the use of biodiesel as a transportation fuel.

  17. Sandia Energy - Combustion Kinetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    knowledge that combustion is governed by chain reactions of radicals. Diesel and Otto didn't need to know any chemistry beyond fuel + air heat However, in the intervening...

  18. Proposed methodology for combustion toxicology testing of combined halon replacement agent/jet fuel interaction. Final report, June-September 1991

    SciTech Connect (OSTI)

    Kibert, C.J.

    1993-04-01

    An international consensus to remove Chlorofluorocarbon (CFC) compounds from production and U.S. national policy to implement the resulting protocols has motivated the U.S. Air Force to embark on a program to find a suitable replacement for Halon 1211, currently used to extinguish flight line fires. This research addressed the feasibility of conducting a combustion toxicology (CT) program to assess the toxic products of the combustion interaction of JP-8 and the Group 1 or so-called Near Term candidate replacement agents for Halon 1211: HCFCs -123, -124, and -142b. A laboratory scale experiment benchmarked on large scale testing of a 150 sq ft pool fire was developed on the basis of Froude scaling of the full scale fire to a 15 x 15 cm pan fire. A prototype apparatus was developed and investigation into the use of animal behavior methods as an indicator of human incapacitation was conducted. The result is a new method which may potentially be utilized for future toxicity studies of the combustion interaction of current and future U.S. Air Force fuels with various fire extinguishants. Extinguishing agents, Halon 1211, Halon replacement, Combustion.

  19. Reducing mode circulating fluid bed combustion

    DOE Patents [OSTI]

    Lin, Yung-Yi (Katy, TX); Sadhukhan, Pasupati (Katy, TX); Fraley, Lowell D. (Sugarland, TX); Hsiao, Keh-Hsien (Houston, TX)

    1986-01-01

    A method for combustion of sulfur-containing fuel in a circulating fluid bed combustion system wherein the fuel is burned in a primary combustion zone under reducing conditions and sulfur captured as alkaline sulfide. The reducing gas formed is oxidized to combustion gas which is then separated from solids containing alkaline sulfide. The separated solids are then oxidized and recycled to the primary combustion zone.

  20. Studies of the combustion of coal/refuse derived fuels using thermogravimetric-Fourier transform infrared-mass spectrometry

    SciTech Connect (OSTI)

    Lu, Huagang; Li, Jigui; Lloyd, W.G.

    1995-11-01

    According to a report of the Environmental Protection Agency (EPA), `Characterization of Municipal Solid Waste (MSW) in the United States`, the total MSW produced in the U.S. increased from 179 million tons in 1988 to 195 million tons in 1990. The EPA predicted that the country would produce about 216 million tons of garbage in the year 2000. The amount of waste generated and the rapidly declining availability of sanitary landfills has forced most municipalities to evaluate alternative waste management technologies for reducing the volume of waste sent to landfills. The fraction of MSW that is processed by such technologies as separation and recycling, composting, and waste-to-energy was forecast to increase from a few percent today to 30-40% by the year 2000. Waste-to-energy conversion of MSW can appear to be attractive because of the energy recovered, the economic value of recycled materials, and the cost savings derived from reduced landfill usage. However, extra care needs to be taken in burning MSW or refuse-derived fuel (RDF) to optimize the operating conditions of a combustor so that the combustion takes place in an environmentally acceptable manner. For instance, polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) have been found in the precipitator fly ash and flue gas of some incinerator facilities in the United States and Europe. The amount of PCDDs and PCDFs occurs only in the parts-per-billion to parts-per-trillion range, but these chlorinated organics exhibit very high toxicity (LD{sub 50} < 10 {mu}g/Kg). The compound 2,3,7,8-tetrachlorodibenzodioxin has been found to be acnegenic, carcinogenic, and teratogenic. This has slowed or even stopped the construction and operation of waste-to-energy plants.