National Library of Energy BETA

Sample records for format uhv-compatible solids

  1. Formation of thin walled ceramic solid oxide fuel cells

    DOE Patents [OSTI]

    Claar, Terry D. (Tisle, IL); Busch, Donald E. (Hinsdale, IL); Picciolo, John J. (Lockport, IL)

    1989-01-01

    To reduce thermal stress and improve bonding in a high temperature monolithic solid oxide fuel cell (SOFC), intermediate layers are provided between the SOFC's electrodes and electrolyte which are of different compositions. The intermediate layers are comprised of a blend of some of the materials used in the electrode and electrolyte compositions. Particle size is controlled to reduce problems involving differential shrinkage rates of the various layers when the entire structure is fired at a single temperature, while pore formers are provided in the electrolyte layers to be removed during firing for the formation of desired pores in the electrode layers. Each layer includes a binder in the form of a thermosetting acrylic which during initial processing is cured to provide a self-supporting structure with the ceramic components in the green state. A self-supporting corrugated structure is thus formed prior to firing, which the organic components of the binder and plasticizer removed during firing to provide a high strength, high temperature resistant ceramic structure of low weight and density.

  2. Maskelynite formation via solid-state transformation: Evidence of infrared and x-ray anisotropy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jaret, Steven J.; Ehm, Lars; Woerner, William R.; Phillips, Brian L.; Nekvasil, Hanna; Wright, Shawn P.; Glotch, Timothy D.

    2015-03-24

    We present optical microscopy, micro-Raman spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, high-energy X-ray total scattering experiments, and micro-Fourier transform infrared (micro-FTIR) spectroscopy on shocked labradorite from the Lonar Crater, India. We show that maskelynite of shock class 2 is structurally more similar to fused glass than to crystalline plagioclase. However, there are slight but significant differences – preservation of original pre-impact igneous zoning, anisotropy at Infrared wavelengths, X-ray anisotropy, and preservation of some intermediate range order – which are all consistent with a solid-state transformation formation of maskelynite.

  3. Remarks on energetic conditions for positronium formation in non-polar solids. Coupled Dipole Method application

    E-Print Network [OSTI]

    Pietrow, Marek

    2015-01-01

    A numerical program calculating an energy of a positron or (and) an electron near the free volume in solid n-alkanes has been build. The theory of interaction of e+ or (and) e- with this non-polar media based on polarizability has been introduced. The energy of the e+ -- e- pair in the bulk was compared to that calculated when the pair forms a positronium (Ps) inside the free volume. The calculations are based on the Coupled Dipole Method and the dipole-dipole interaction energy for induced dipoles is taken into account. Furthermore, a correction of a local permittivity for the e+ -- e- interaction is calculated taking into account the non-isotropic medium between them. The method is a step toward more accurate calculations of energetic conditions during the Ps formation in matter. The possibility of emission of the excess energy of the Ps formation as electromagnetic radiation is discussed. It is argued that if this radiation is observed, it can be used as a new spectroscopic tool providing information about...

  4. Formation of hydrogen peroxide and water from the reaction of cold hydrogen atoms with solid oxygen at 10K

    E-Print Network [OSTI]

    N. Miyauchi; H. Hidaka; T. Chigai; A. Nagaoka; N. Watanabe; A. Kouchi

    2008-05-01

    The reactions of cold H atoms with solid O2 molecules were investigated at 10 K. The formation of H2O2 and H2O has been confirmed by in-situ infrared spectroscopy. We found that the reaction proceeds very efficiently and obtained the effective reaction rates. This is the first clear experimental evidence of the formation of water molecules under conditions mimicking those found in cold interstellar molecular clouds. Based on the experimental results, we discuss the reaction mechanism and astrophysical implications.

  5. An experimental study of Worthington jet formation after impact of solid spheres

    E-Print Network [OSTI]

    McKown, Jenna Marie

    2011-01-01

    The impacts of solid spheres with the free surface have been studied for over one hundred years. In this thesis, the Worthington jets resulting from the impacts of hydrophobic and hydrophilic spheres with the free surface ...

  6. Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters

    SciTech Connect (OSTI)

    Sacci, Robert L; Black, Jennifer M; Wisinger, Nina; Dudney, Nancy J.; More, Karren Leslie; Unocic, Raymond R

    2015-01-01

    The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. To probe the mechanisms of solid electrolyte interphase formation and Li electrodeposition from a standard battery electrolyte, we use in situ electrochemical scanning transmission electron microscopy for controlled potential sweep-hold electrochemical measurements with simultaneous BF and ADF STEM image acquisition. Through a combined quantitative electrochemical measurement and quantitative STEM imaging approach, based upon electron scattering theory, we show that chemically sensitive ADF STEM imaging can be used to estimate the density of evolving SEI constituents and distinguish contrast mechanisms of Li-bearing components in the liquid cell.

  7. ARTIFACT FORMATION IN HIGH VOLUME SAMPLING OF VOC's AND SOLID ORGANIC COMPOUNDS.

    E-Print Network [OSTI]

    Boyer, Edmond

    when sampling polluted air. Purified air containing 180 ppbv ozone seems to destroy PAH according Atmospheriques, Boite 7059, UNIVERSITE PARIS 7, 2, place Jussieu, 75251 PARIS Cedex 05 ABSTRACT Pollutants from well äs solid (SOC's) organic compounds. High volume samplers are commonly used m air quality

  8. J. Phys. Chem. Solids Pergamon Press 1967. Vol. 28, pp. 2061-2065. Printed in Great Britain. RELATION OF VACANCY FORMATION AND MIGRATION

    E-Print Network [OSTI]

    Glyde, Henry R.

    . RELATION OF VACANCY FORMATION AND MIGRATION ENERGIES TO THE DEBYE TEMPERATURE IN SOLIDS H. R. GLYDE School) Abstract-A derivation of the relation between the vacancy formation energy E,, the migration energy E of the potential, to a property E,, which depends on the absolute magnitude or depth of the potential. (q

  9. EXPLORING THE POTENTIAL FORMATION OF ORGANIC SOLIDS IN CHONDRITES AND COMETS THROUGH POLYMERIZATION OF INTERSTELLAR FORMALDEHYDE

    SciTech Connect (OSTI)

    Kebukawa, Yoko; Cody, George D.; David Kilcoyne, A. L. E-mail: yoko@ep.sci.hokudai.ac.jp

    2013-07-01

    Polymerization of interstellar formaldehyde, first through the formose reaction and then through subsequent condensation reactions, provides a plausible explanation for how abundant and highly chemically complex organic solids may have come to exist in primitive solar system objects. In order to gain better insight on the reaction, a systematic study of the relationship of synthesis temperature with resultant molecular structure was performed. In addition, the effect of the presence of ammonia on the reaction rate and molecular structure of the product was studied. The synthesized formaldehyde polymer is directly compared to chondritic insoluble organic matter (IOM) isolated from primitive meteorites using solid-state {sup 13}C nuclear magnetic resonance, Fourier transform infrared, and X-ray absorption near edge structure spectroscopy. The molecular structure of the formaldehyde polymer is shown to exhibit considerable similarity at the functional group level with primitive chondritic IOM. The addition of ammonia to the solution enhances the rate of polymerization reaction at lower temperatures and results in substantial incorporation of nitrogen into the polymer. Morphologically, the formaldehyde polymer exists as submicron to micron-sized spheroidal particles and spheroidal particle aggregates that bare considerable similarity to the organic nanoglobules commonly observed in chondritic IOM. These spectroscopic and morphological data support the hypothesis that IOM in chondrites and refractory organic carbon in comets may have formed through the polymerization of interstellar formaldehyde after planetesimal accretion, in the presence of liquid water, early in the history of the solar system.

  10. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Unocic, Raymond R [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Sacci, Robert L [ORNL] [ORNL; Adamczyk, Leslie A [ORNL] [ORNL; Alsem, Daan Hein [Hummingbird Scientific] [Hummingbird Scientific; Dai, Sheng [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; More, Karren Leslie [ORNL] [ORNL

    2014-01-01

    Complex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

  11. In-Situ Observation of Solid Electrolyte Interphase Formation in Ordered Mesoporous Hard Carbon by Small-Angle Neutron Scattering

    SciTech Connect (OSTI)

    Bridges, Craig A [ORNL; Paranthaman, Mariappan Parans [ORNL; Sun, Xiao-Guang [ORNL; Zhao, Jinkui [ORNL; Dai, Sheng [ORNL

    2012-01-01

    The aim of this work was to better understand the electrochemical processes occurring during the cycling of a lithium-ion half-cell containing ordered mesoporous hard carbon using time-resolved in situ small-angle neutron scattering (SANS). Utilizing electrolytes containing mixtures of deuterated (2H) and non-deuterated (1H) carbonates, we have addressed the challenging task of monitoring the formation and evolution of the solid-electrolyte interphase (SEI) layer. An evolution occurs in the SEI layer during discharge from a composition dominated by a higher scattering length density (SLD) lithium salt, to a lower SLD lithium salt for the ethylene carbonate/dimethyl carbonate (EC/DMC) mixture employed. By comparing half-cells containing different solvent deuteration levels, we show that it is possible to observe both SEI formation and lithium intercalation occurring concurrently at the low voltage region in which lithium intercalates into the hard carbon. These results demonstrate that SANS can be employed to monitor complicated electrochemical processes occurring in rechargeable batteries, in a manner that simultaneously provides information on the composition and microstructure of the electrode.

  12. Phased Array Approach To Retrieve Gases, Liquids, Or Solids From Subsurface And Subaqueous Geologic Or Man-Made Formations

    DOE Patents [OSTI]

    Rynne, Timothy M. (Long Beach, CA); Spadaro, John F. (Huntington Beach, CA); Iovenitti, Joe L. (Pleasant Hill, CA); Dering, John P. (Lakewood, CA); Hill, Donald G. (Walnut Creek, CA)

    1998-10-27

    A method of enhancing the remediation of contaminated soils and ground water, production of oil and gas, and production of any solid, gas, and/or liquid from subsurface geologic and man-made formations including the steps of estimating the geometric boundaries of the region containing the material to be recovered, drilling a recovery well(s) into subsurface in a strategic location to recover the material of interest, establishing multiple sources of acoustical power in an array about and spaced-apart from the surface or at various depths below the surface in a borehole(s) and/or well(s), directing a volume of acoustical excitation from the sources into the region containing the material to be recovered, the excitation in the form of either controllable sinusoidal, square, pulsed, or various combinations of these three waveforms, and controlling the phasing, frequency, power, duration, and direction of these waveforms from the sources to increase and control the intensity of acoustical excitation in the region of the material to be recovered to enhance. the recovery of said material from the recovery well(s). The invention will augment any technology affecting the removal of materials from the subsurface.

  13. O({sup 3}P{sub J}) formation and desorption by 157-nm photoirradiation of amorphous solid water

    SciTech Connect (OSTI)

    DeSimone, Alice J.; Orlando, Thomas M.

    2014-03-07

    Photodissociation of amorphous solid water (ASW) deposited on a thinly oxidized copper substrate at 82 K was studied by measuring O({sup 3}P{sub J=2,1,0}) photoproducts detected with resonance-enhanced multiphoton ionization. For each spin-orbit state, the oxygen atom time-of-flight spectrum was measured as a function of H{sub 2}O exposure, which is related to ice thickness, and 157-nm irradiation time. Four Maxwell-Boltzmann distributions with translational temperatures of 10?000 K, 1800 K, 400 K, and 82 K were found to fit the data. The most likely formation mechanisms are molecular elimination following ionization of water and ion-electron recombination, secondary recombination of hydroxyl radicals, and photodissociation of adsorbed hydroxyl radicals. Evidence for O-atom diffusion through bulk ASW was found for H{sub 2}O exposures of at least 5 Langmuir (1 L = 10{sup ?6} Torr?s). The cross sections for O({sup 3}P{sub 2}) depletion were 1.3 × 10{sup ?19} and 6.5 × 10{sup ?20} cm{sup 2} for 1 and 5 L, respectively.

  14. Formation dry-out from CO2 injection into saline aquifers: Part 1, Effects of solids precipitation and their mitigation

    E-Print Network [OSTI]

    Pruess, Karsten

    2009-01-01

    Formation in Natural Gas Storage Aquifers, Proceedings,documented for aquifer gas storage systems, where halite (

  15. Role of Surface Oxides in the Formation of Solid-Electrolyte Interphases at Silicon Electrodes for Lithium-Ion Batteries

    E-Print Network [OSTI]

    Webb, Lauren J.

    for Lithium-Ion Batteries Kjell W. Schroder,,,§ Anthony G. Dylla,,§ Stephen J. Harris, Lauren J. Webb electrodes in lithium-ion batteries are still poorly understood. This lack of understanding inhibits of the SEI. KEYWORDS: lithium-ion batteries, solid-electrolyte interphase, SEI, TOF-SIMS, XPS, PCA 1

  16. Comparative study of P and S wave amplitudes of acoustic logging through solid formations contribution to the knowledge of in situ stresses and fractures

    E-Print Network [OSTI]

    Rousseau, A

    2005-01-01

    In order to compare the ratios between the amplitudes of P and S acoustic waves drawn from various boreholes, we have defined a specific wave parameter called magnitude : for each shot, we have added the maximum positive amplitude values and the absolute values of the minimum negative amplitudes of a given wave recorded at different depths. In compact formations, the difference between the logarithms of the magnitudes of S and P waves provides a value that appears to be characteristic of the state of stress of the domain where a borehole is drilled. Accidents between those formations, such as fractures or sedimentary joints can be determined, and breakouts well distinguished.

  17. Ab initio Molecular Dynamics Simulations of the Initial Stages of Solid-electrolyte Interphase Formation on Lithium Ion Battery Graphitic Anodes

    E-Print Network [OSTI]

    Leung, Kevin; 10.1039/B925853A

    2010-01-01

    The decomposition of ethylene carbonate (EC) during the initial growth of solid-electrolyte interphase (SEI) films at the solvent-graphitic anode interface is critical to lithium ion battery operations. Ab initio molecular dynamics simulations of explicit liquid EC/graphite interfaces are conducted to study these electrochemical reactions. We show that carbon edge terminations are crucial at this stage, and that achievable experimental conditions can lead to surprisingly fast EC breakdown mechanisms, yielding decomposition products seen in experiments but not previously predicted.

  18. Solid electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA)

    1993-06-15

    This invention pertains to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized (encapsulated) in a solid organic polymer matrix. In particular, this invention relates to solid polymer electrolytes derived by immobilizing complexes (solvates) formed between a Li salt such as LiAsF.sub.6, LiCF.sub.3 SO.sub.3 or LiClO.sub.4 and a mixture of aprotic organic solvents having high dielectric constants such as ethylene carbonate (EC) (dielectric constant=89.6) and propylene carbonate (PC) (dielectric constant=64.4) in a polymer matrix such as polyacrylonitrile, poly(tetraethylene glycol diacrylate), or poly(vinyl pyrrolidinone).

  19. Perovskite solid electrolytes for SOFC

    SciTech Connect (OSTI)

    Sammells, A.F.

    1992-09-01

    Selected perovskite solid electrolytes incorporated into research size fuel cells have shown stability for > 4000 hours at 600{degrees}C. Perovskite lattice requirements which favor low E{sub a} for ionic conduction include (i) that the perovskite lattice possess a moderate enthalpy of formation, (ii) perovskite lattice possess large free volumes, (iii) that the lattice minimally polarizes the mobile ion and (iv) that the crystallographic saddle point r{sub c} for ionic conduction is {approx_equal} 1.

  20. Perovskite solid electrolytes for SOFC

    SciTech Connect (OSTI)

    Sammells, A.F.

    1992-01-01

    Selected perovskite solid electrolytes incorporated into research size fuel cells have shown stability for > 4000 hours at 600{degrees}C. Perovskite lattice requirements which favor low E{sub a} for ionic conduction include (i) that the perovskite lattice possess a moderate enthalpy of formation, (ii) perovskite lattice possess large free volumes, (iii) that the lattice minimally polarizes the mobile ion and (iv) that the crystallographic saddle point r{sub c} for ionic conduction is {approx equal} 1.

  1. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  2. Solids mass flow determination

    DOE Patents [OSTI]

    Macko, Joseph E. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

  3. Nanoengineered Thin Films for Solid Oxide Fuel Cells 

    E-Print Network [OSTI]

    Su, Qing

    2013-11-21

    Solid oxide fuel cells (SOFCs) are very attractive as energy generation devices because of their high energy efficiency, flexible fuel selections and clean energy conversion. To avoid cell cracking and formation of non-conducting compounds...

  4. Artificial Solid Electrolyte Interphase-Protected LixSi Nanoparticles: An Efficient and Stable Prelithiation Reagent for Lithium-Ion

    E-Print Network [OSTI]

    Cui, Yi

    Artificial Solid Electrolyte Interphase-Protected LixSi Nanoparticles: An Efficient and Stable loss in lithium-ion batteries, particularly during the formation of the solid electrolyte interphase surface area significantly increases solid electrolyte interphase (SEI) formation in the first and later

  5. Rotary bulk solids divider

    DOE Patents [OSTI]

    Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

    1992-01-01

    An apparatus for the disbursement of a bulk solid sample comprising, a gravity hopper having a top open end and a bottom discharge end, a feeder positioned beneath the gravity hopper so as to receive a bulk solid sample flowing from the bottom discharge end, and a conveyor receiving the bulk solid sample from the feeder and rotating on an axis that allows the bulk solid sample to disperse the sample to a collection station.

  6. Laser cooling of solids

    SciTech Connect (OSTI)

    Epstein, Richard I; Sheik-bahae, Mansoor

    2008-01-01

    We present an overview of solid-state optical refrigeration also known as laser cooling in solids by fluorescence upconversion. The idea of cooling a solid-state optical material by simply shining a laser beam onto it may sound counter intuitive but is rapidly becoming a promising technology for future cryocooler. We chart the evolution of this science in rare-earth doped solids and semiconductors.

  7. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  8. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  9. Solid State Division

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M.

    1989-08-01

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  10. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  11. Solid Waste Management (Indiana)

    Broader source: Energy.gov [DOE]

    The state supports the implementation of source reduction, recycling, and other alternative solid waste management practices over incineration and land disposal. The Indiana Department of...

  12. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  13. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO); Grohmann, Karel (Littleton, CO); Himmel, Michael E. (Littleton, CO); Richard, Christopher J. (Lakewood, CO)

    1993-01-01

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  14. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E.; Grohmann, Karel; Himmel, Michael E.; Richard, Christopher J.

    1993-03-02

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  15. Managing America's solid waste

    SciTech Connect (OSTI)

    Phillips, J. A.

    1998-09-15

    This report presents an historical overview of the federal role in municipal solid waste management from 1965 to approximately 1995. Attention is focuses on the federal role in safeguarding public health, protecting the environment, and wisely using material and energy resources. It is hoped that this report will provide important background for future municipal solid waste research and development initiatives.

  16. Management of Solid Waste (Oklahoma)

    Broader source: Energy.gov [DOE]

    The Solid Waste Management Division of the Department of Environmental Quality regulates solid waste disposal or any person who generates, collects, transports, processes, and/or disposes of solid...

  17. Solid Waste Management (North Carolina)

    Broader source: Energy.gov [DOE]

    The Solid Waste Program regulates safe management of solid waste through guidance, technical assistance, regulations, permitting, environmental monitoring, compliance evaluation and enforcement....

  18. Solid Waste Management (Kansas)

    Broader source: Energy.gov [DOE]

    This act aims to establish and maintain a cooperative state and local program of planning and technical and financial assistance for comprehensive solid waste management. No person shall construct,...

  19. Solid State Lighting Reliability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid State Lighting Reliability 2015Building Technologies Office Peer Review Lynn Davis, PhD RTI International ldavis@rti.org --- 919-316-3325 Project Summary Timeline: Start...

  20. Solids Accumulation Scouting Studies

    SciTech Connect (OSTI)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.

    2012-09-26

    The objective of Solids Accumulation activities was to perform scaled testing to understand the behavior of remaining solids in a Double Shell Tank (DST), specifically AW-105, at Hanford during multiple fill, mix, and transfer operations. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles containing plutonium could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste staging tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids: Gibbsite, Zirconia, Sand, and Stainless Steel, with stainless steel particles representing the heavier particles, e.g., plutonium, and supernatant were charged to the test tank and rotating liquid jets were used to mix most of the solids while the simulant was pumped out. Subsequently, the volume and shape of the mounds of residual solids and the spatial concentration profiles for the surrogate for heavier particles were measured. Several techniques were developed and equipment designed to accomplish the measurements needed and they included: 1. Magnetic particle separator to remove simulant stainless steel solids. A device was designed and built to capture these solids, which represent the heavier solids during a waste transfer from a staging tank. 2. Photographic equipment to determine the volume of the solids mounds. The mounds were photographed as they were exposed at different tank waste levels to develop a composite of topographical areas. 3. Laser rangefinders to determine the volume of the solids mounds. The mounds were scanned after tank supernatant was removed. 4. Core sampler to determine the stainless steel solids distribution within the solids mounds. This sampler was designed and built to remove small sections of the mounds to evaluate concentrations of the stainless steel solids at different special locations. 5. Computer driven positioner that placed the laser rangefinders and the core sampler in appropriate locations over solids mounds that accumulated on the bottom of a scaled staging tank where mixing is poor. These devices and techniques were effective to estimate the movement, location, and concentrations of the solids representing heavier particles and could perform well at a larger scale The experiment contained two campaigns with each comprised of ten cycles to fill and empty the scaled staging tank. The tank was filled without mixing, but emptied, while mixing, in seven batches; the first six were of equal volumes of 13.1 gallons each to represent the planned fullscale batches of 145,000 gallons, and the last, partial, batch of 6.9 gallons represented a full-scale partial batch of 76,000 gallons that will leave a 72-inch heel in the staging tank for the next cycle. The sole difference between the two campaigns was the energy to mix the scaled staging tank, i.e., the nozzle velocity and jet rotational speed of the two jet pumps. Campaign 1 used 22.9 ft/s, at 1.54 rpm based on past testing and Campaign 2 used 23.9 ft/s at 1.75 rpm, based on visual observation of minimum velocity that allowed fast settling solids, i.e., sand and stainless steel, to accumulate on the scaled tank bottom.

  1. Characteristics and removal of filter cake formed by formate-based drilling mud 

    E-Print Network [OSTI]

    Alotaibi, Mohammed Badri

    2009-05-15

    and this makes the filter cake a strong permeability barrier. Various cleaning fluids were proposed to remove drilling mud filter cake; including: solid-free formate brine and formate brine doped with organic acids (acetic, formic, and citric acids), esters...

  2. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, K.M.; Alamgir, M.; Choe, H.S.

    1995-12-12

    This invention relates to Li ion (Li{sup +}) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF{sub 3}SO{sub 2}){sub 2}, LiAsF{sub 6}, and LiClO{sub 4}. 2 figs.

  3. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA); Choe, Hyoun S. (Waltham, MA)

    1995-01-01

    This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

  4. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, Donald J. (Albuquerque, NM); Armstrong, Pamela S. (Abingdon, MD); Panitz, Janda Kirk G. (Edgewood, NM)

    1998-01-01

    A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

  5. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, D.J.; Armstrong, P.S.; Panitz, J.K.G.

    1998-03-17

    A solid electrolytic capacitor is described having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects. 2 figs.

  6. Thermally Triggered Calcium Phosphate Formation from Calcium-Loaded Liposomes

    E-Print Network [OSTI]

    of utilizing lipid vesicles for the synthesis of inorganic solids of controlled shape and/or size is well the rapid in situ formation of polymer hydrogels, inorganic solids, and other materials for medical. Mixing of a calcium-loaded lipid vesicle suspension with aqueous inorganic phosphate resulted in a stable

  7. Solid state switch

    DOE Patents [OSTI]

    Merritt, B.T.; Dreifuerst, G.R.

    1994-07-19

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1,500 A peak, 1.0 [mu]s pulsewidth, and 4,500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry. 6 figs.

  8. Observations of Solids in Protoplanetary Disks

    E-Print Network [OSTI]

    Andrews, Sean M

    2015-01-01

    This review addresses the state of research that employs astronomical (remote sensing) observations of solids ("dust") in young circumstellar disks to learn about planet formation. The intention is for it to serve as an accessible, introductory, pedagogical resource for junior scientists interested in the subject. After some historical background and a basic observational primer, the focus is shifted to the three fundamental topics that broadly define the field: (1) demographics -- the relationships between disk properties and the characteristics of their environments and hosts; (2) structure -- the spatial distribution of disk material and its associated physical conditions and composition; and (3) evolution -- the signposts of key changes in disk properties, including the growth and migration of solids and the impact of dynamical interactions with young planetary systems. Based on the state of the art results in these areas, suggestions are made for potentially fruitful lines of work in the near future.

  9. Solid State Lighting

    SciTech Connect (OSTI)

    Hastbacka, Mildred; Dieckmann, John; Bouza, Antonio

    2013-03-30

    The article discusses solid state lighting technologies. This topic was covered in two previous ASHRAE Journal columns (2010). This article covers advancements in technologies and the associated efficacies. The life-cycle, energy savings and market potential of these technologies are addressed as well.

  10. Solid polymer electrolyte compositions

    DOE Patents [OSTI]

    Garbe, James E. (Stillwater, MN); Atanasoski, Radoslav (Edina, MN); Hamrock, Steven J. (St. Paul, MN); Le, Dinh Ba (St. Paul, MN)

    2001-01-01

    An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

  11. Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm

    SciTech Connect (OSTI)

    Cooke, Gary A.

    2015-03-09

    The Enclosure to this memo discusses the solid phase characterization of a solid sample that was retrieved from the single-shell Tank 241-C-111 extended reach sluicer #2. This sluicer, removed from riser #3 on September 25, 2014, was found to have approximately 0.4 gallons of solid tank waste adhering to the nozzle area.

  12. Danish Solid Oxide Fuel Cell project: DK-SOFC 1997-1999

    E-Print Network [OSTI]

    Danish Solid Oxide Fuel Cell project: DK-SOFC 1997-1999 Contracts no. ENS 1443/97-0003, ENS 1443 the format of annual- and final reporting from the Danish Solid Oxide Fuel Cell projects. From then on materials and contacting to metallic interconnects in order to make a basis for further improvements

  13. Solid fuel volatilization to produce synthesis gas

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Degenstein, Nick J.; Dreyer, Brandon J.; Colby, Joshua L.

    2014-07-29

    A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.

  14. Interface Engineering of Garnet Solid Electrolytes

    E-Print Network [OSTI]

    Cheng, Lei

    2015-01-01

    A commercial lithium ion battery uses solid electrodes withsolution in the lithium ion battery with a solid electrolytesolid-state lithium ion conductors for solid-state battery

  15. TRANSPORT NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2014-01-01

    NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION Lutgard

  16. TRANSPORT NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2012-01-01

    NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION Lutgard

  17. Heat Recovery From Solid Waste 

    E-Print Network [OSTI]

    Underwood, O. W.

    1981-01-01

    areas of evaluation, including the cost of fuel, cost of solid waste disposal, plant energy requirements, available technology, etc....

  18. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich (Sarov, RU); Vedeneev, Nikolai Ivanovich (Sarov, RU)

    2002-04-30

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  19. Long cycle life solid-state solid polymer electrolyte cells

    SciTech Connect (OSTI)

    Sammells, A.F.

    1988-02-02

    This patent describes a rechargeable solid-state lithium conducting solid polymer electrolyte electrochemical cell comprising: a lithium intercalation compound negative electrode selected from the group consisting of: MoO/sub 2/; RuO/sub 2/; WO; OsO/sub 2/; IrO/sub 2/; and Mo1/2V1/2O/sub 2/; a lithium ion conducting solid polymer electrolyte comprising a lithium ion conducting supporting electrolyte complexed with a solid polymer contacting the negative electrode on one side; and a lithium intercalation compound positive electrode contacting the opposite side of the solid polymer electrolyte.

  20. Solid waste handling

    SciTech Connect (OSTI)

    Parazin, R.J.

    1995-05-31

    This study presents estimates of the solid radioactive waste quantities that will be generated in the Separations, Low-Level Waste Vitrification and High-Level Waste Vitrification facilities, collectively called the Tank Waste Remediation System Treatment Complex, over the life of these facilities. This study then considers previous estimates from other 200 Area generators and compares alternative methods of handling (segregation, packaging, assaying, shipping, etc.).

  1. Solid phase extraction membrane

    DOE Patents [OSTI]

    Carlson, Kurt C [Nashville, TN; Langer, Roger L [Hudson, WI

    2002-11-05

    A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.

  2. Solid State Lighting Reliability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo.Hydrogen4EnergySolid State Lighting Reliability 2014 Building

  3. Solar solids reactor

    DOE Patents [OSTI]

    Yudow, B.D.

    1986-02-24

    A solar powered kiln is provided, that is of relatively simple design and which efficiently uses solar energy. The kiln or solids reactor includes a stationary chamber with a rearward end which receives solid material to be reacted and a forward end through which reacted material is disposed of, and a screw conveyor extending along the bottom of the chamber for slowly advancing the material between the chamber ends. Concentrated solar energy is directed to an aperture at the forward end of the chamber to heat the solid material moving along the bottom of the chamber. The solar energy can be reflected from a mirror facing at an upward incline, through the aperture and against a heat-absorbing material near the top of the chamber, which moves towards the rear of the chamber to distribute heat throughout the chamber. Pumps at the forward and rearward ends of the chamber pump heated sweep gas through the length of the chamber, while minimizing the flow of gas through an open aperture through which concentrated sunlight is received.

  4. Solar solids reactor

    DOE Patents [OSTI]

    Yudow, Bernard D. (Chicago, IL)

    1987-01-01

    A solar powered kiln is provided, that is of relatively simple design and which efficiently uses solar energy. The kiln or solids reactor includes a stationary chamber with a rearward end which receives solid material to be reacted and a forward end through which reacted material is disposed of, and a screw conveyor extending along the bottom of the chamber for slowly advancing the material between the chamber ends. Concentrated solar energy is directed to an aperture at the forward end of the chamber to heat the solid material moving along the bottom of the chamber. The solar energy can be reflected from a mirror facing at an upward incline, through the aperture and against a heat-absorbing material near the top of the chamber, which moves towards the rear of the chamber to distribute heat throughout the chamber. Pumps at the forward and rearward ends of the chamber pump heated sweep gas through the length of the chamber, while minimizing the flow of gas through an open aperture through which concentrated sunlight is received.

  5. Packaging of solid state devices

    DOE Patents [OSTI]

    Glidden, Steven C.; Sanders, Howard D.

    2006-01-03

    A package for one or more solid state devices in a single module that allows for operation at high voltage, high current, or both high voltage and high current. Low thermal resistance between the solid state devices and an exterior of the package and matched coefficient of thermal expansion between the solid state devices and the materials used in packaging enables high power operation. The solid state devices are soldered between two layers of ceramic with metal traces that interconnect the devices and external contacts. This approach provides a simple method for assembling and encapsulating high power solid state devices.

  6. SOLIDS PRECIPITATION EVENT IN MCU CAUSAL ANALYSIS AND RECOMMENDATIONS FROM SOLIDS RECOVERY TEAM

    SciTech Connect (OSTI)

    Garrison, A.; Aponte, C.

    2014-08-15

    A process upset occurred in the Modular Caustic-Side Solvent Extraction Unit (MCU) facility on April 6th, 2014. During recovery efforts, a significant amount of solids were found in the Salt Solution Feed Tank (SSFT), Salt Solution Receipt Tanks (SSRTs), two extraction contactors, and scrub contactors. The solids were identified by Savannah River National Laboratory (SRNL) as primarily sodium oxalate and sodium alumina silicate (NAS) with the presence of some aluminum hydroxide. NAS solids have been present in the SSFT since simulant runs during cold chemical startup of MCU in 2007, and have not hindered operations since that time. During the process upset in April 2014, the oxalate solids partially blocked the aqueous outlet of the extraction contactors, causing salt solution to exit through the contactor organic outlet to the scrub contactors with the organic phase. This salt solution overwhelmed the scrub contactors and passed with the organic phase to the strip section of MCU. The partially reversed flow of salt solution resulted in a Strip Effluent (SE) stream that was high in Isopar™ L, pH and sodium. The primary cause of the excessive solids accumulation in the SSRTs and SSFT at MCU is attributed to an increase in the frequency of oxalic acid cleaning of the 512-S primary filter. Agitation in the SSRTs at MCU in response to cold weather likely provided the primary mechanism to transfer the solids to the contactors. Sources of the sodium oxalate solids are attributed to the oxalic acid cleaning solution used to clean the primary filter at the Actinide Removal Process (ARP) filtration at 512-S, as well as precipitation from the salt batch feed, which is at or near oxalate saturation. The Solids Recovery Team was formed to determine the cause of the solids formation and develop recommendations to prevent or mitigate this event in the future. A total of 53 recommendations were generated. These recommendations were organized into 4 focus areas: • Improve understanding of oxalate equilibrium and kinetics in salt solutions • Reduction/elimination of oxalic acid cleaning in 512-S • Flowsheet optimization • Improving diagnostic capability The recommendations implemented prior to resumption of MCU operations provide a risk mitigation or detection function through additional sampling and observation. The longer term recommendations provide a framework to increase the basic process knowledge of both oxalate chemistry and filtration behavior and then facilitate decisions that improve the salt flowsheet as a system.

  7. Low Energy Electrodynamics in Solids (LEES) 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Energy Electrodynamics in Solids (LEES) 2012 Low Energy Electrodynamics in Solids (LEES) 2012 July 22-27, 2012; Napa...

  8. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  9. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  10. Solid state thermal engine

    SciTech Connect (OSTI)

    Wayman, C.M.

    1981-01-27

    An improved solid state thermal engine utilizes as a drive member a braided belt fabricated from a memory alloy such as nickel-titanium and nickel-titanium ternary alloys, copper-zinc and copper-zinc ternary alloys, and the like. The braided belt is mounted on a set of pulleys to provide passage through a hot zone where the belt contracts and develops tension, and through a cold zone where it relaxes and stretches. Since more energy is delivered by contraction than is required for relaxation, positive work output results with an efficiency of between onefifth and one-third of the carnot cycle.

  11. Solid state heat engine

    SciTech Connect (OSTI)

    Cory, J.S.

    1981-12-15

    A compact solid state turbine heat engine can be devised by pairing the nitinol elements. Each element is characterized by being in thermal contact with at least one hot water and one cold water bath and mechanically coupled to at least one driven pulley and driver pulley. A second nitinol element is similarly configured with a driver pulley, driven pulley, hot and cold water bath. The driver pulley associated with the first nitinol element is mechanically coupled to the driven pulley of the second nitinol element. Similarly, the driver pulley of the second nitinol element is mechanically coupled to the driven pulley of the first nitinol element. The paired nitinol elements form a compound solid state turbine engine wherein each nitinol element lies in a single plane and wherein the engine may be combined with a plurality of such pairs for increased power output. The nitinol elements may also incorporate a snubber to limit the strain on the element and the engine may further incorporate a variable radius pulley to increase the efficiency of mechanical conversion.

  12. Space-time complexity in solid state models

    SciTech Connect (OSTI)

    Bishop, A.R.

    1985-01-01

    In this Workshop on symmetry-breaking it is appropriate to include the evolving fields of nonlinear-nonequilibrium systems in which transitions to and between various degrees of ''complexity'' (including ''chaos'') occur in time or space or both. These notions naturally bring together phenomena of pattern formation and chaos and therefore have ramifications for a huge array of natural sciences - astrophysics, plasmas and lasers, hydrodynamics, field theory, materials and solid state theory, optics and electronics, biology, pattern recognition and evolution, etc. Our particular concerns here are with examples from solid state and condensed matter.

  13. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  14. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

    1993-01-01

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  15. Solid Waste Management Act (Pennsylvania)

    Broader source: Energy.gov [DOE]

    This Act provides for the planning and regulation of solid waste storage, collection, transportation, processing, treatment, and disposal. It requires that municipalities submit plans for municipal...

  16. Solid Waste Management (South Dakota)

    Broader source: Energy.gov [DOE]

    This statute contains provisions for solid waste management systems, groundwater monitoring, liability for pollution, permitting, inspections, and provisions for waste reduction and recycling...

  17. Solid state rapid thermocycling

    DOE Patents [OSTI]

    Beer, Neil Reginald; Spadaccini, Christopher

    2014-05-13

    The rapid thermal cycling of a material is targeted. A solid state heat exchanger with a first well and second well is coupled to a power module. A thermoelectric element is coupled to the first well, the second well, and the power module, is configured to transfer thermal energy from the first well to the second well when current from the power module flows through the thermoelectric element in a first direction, and is configured to transfer thermal energy from the second well to the first well when current from the power module flows through the thermoelectric element in a second direction. A controller may be coupled to the thermoelectric elements, and may switch the direction of current flowing through the thermoelectric element in response to a determination by sensors coupled to the wells that the amount of thermal energy in the wells falls below or exceeds a pre-determined threshold.

  18. SOLID MECHANICS James R. Rice

    E-Print Network [OSTI]

    1 SOLID MECHANICS James R. Rice School of Engineering and Applied Sciences, and Department of Earth: February 2010 Downloadable at: http://esag.harvard.edu/rice/e0_Solid_Mechanics_94_10.pdf TABLE OF CONTENTS provided on last three pages, pp. 87-89 INTRODUCTION The application of the principles of mechanics to bulk

  19. Valve for controlling solids flow

    DOE Patents [OSTI]

    Staiger, M.D.

    1982-09-29

    A valve for controlling the flow of solids comprises a vessel having an overflow point, an inlet line for discharging solids into the vessel positioned within the vessel such that the inlet line's discharge point is lower than the vessel's overflow point, and means for introducing a fluidizing fluid into the vessel. The fluidizing fluid fluidizes the solids within the vessel so that they overflow at the vessel's overflow point. For the removal of nuclear waste product the vessel may be placed within a sealed container having a bottom connected transport line for transporting the solids to storage or other sites. The rate of solids flow is controlled by the flow rate of the fluidizing fluid and by V-notch weirs of different sizes spaced about the top of the vessel.

  20. A comparison of observables for solid-solid phase transitions

    SciTech Connect (OSTI)

    Smilowitz, Laura B [Los Alamos National Laboratory; Henson, Bryan F [Los Alamos National Laboratory; Romero, Jerry J [Los Alamos National Laboratory

    2009-01-01

    The study of solid-solid phase transformations is hindered by the difficulty of finding a volumetric probe to use as a progress variable. Solids are typically optically opaque and heterogeneous. Over the past several years, second harmonic generation (SHG) has been used as a kinetic probe for a solid-solid phase transition in which the initial and final phases have different symmetries. Bulk generation of SHG is allowed by symmetry only in noncentrosymmetric crystallographic space groups. For the organic energetic nitramine octahydro-1,3 ,5,7 -tetranitro-1,3 ,5,7 -tatrazocine (HMX), the beta phase is centro symmetric (space group P2{sub 1}/c) and the delta phase iS noncentrosymmetric (space group P6{sub 1}22) making SHG an extremely sensitive, essentially zero background probe of the phase change progress. We have used SHG as a tool to follow the progress of the transformation from beta to delta phase during the solid-solid transformation. However, kinetic models of the transformation derived using different observables from several other groups have differed, showing later onset for the phase change and faster progression to completion. In this work, we have intercompared several techniques to understand these differences. The three techniques discussed are second harmonic generation, Raman spectroscopy, and differential scanning calorimetry (DSC). The progress of the beta to delta phase transition in HMX observed with each of these different probes will be discussed and advantages and disadvantages of each technique described. This paper compares several different observables for use in measuring the kinetics of solid-solid phase transitions. Relative advantages and disadvantages for each technique are described and a direct comparison of results is made for the beta to delta polymorphic phase transition of the energetic nitramine, octahydro-1,3,5,7-tetranitro-1,3,5,7-tatrazocine.

  1. Solid Xenon Project

    SciTech Connect (OSTI)

    Balakishiyeva, Durdana N.; Saab, Tarek [University of Florida (United States); Mahapatra, Rupak [Texas A and M University (United States); Yoo, Jonghee [FNAL (United States)

    2010-08-30

    Crystals like Germanium and Silicon need to be grown in specialized facilities which is time and money costly. It takes many runs to test the detector once it's manufactured and mishaps are very probable. It is of a great challenge to grow big germanium crystals and that's why stacking them up in a tower is the only way at the moment to increase testing mass. Liquid Noble gas experiments experiencing contamination problems, their predicted energy resolution at 10 keV and lower energy range is not as good as predicted. Every experiment is targeting one specific purpose, looking for one thing. Why not to design an experiment that is diverse and build a detector that can search for Dark Matter, Solar Axions, Neutrinoless Double Beta decay, etc. Solid Xenon detector is such detector. We designed a simple Xenon crystal growing chamber that was put together at Fermi National Accelerator Laboratory. The first phase of this experiment was to demonstrate that a good, crack free Xenon crystal can be grown (regardless of many failed attempts by various groups) and our first goal, 1 kg crystal, was successful.

  2. High power density solid oxide fuel cells

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2004-10-12

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O (LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  3. Stiffening solids with liquid inclusions

    E-Print Network [OSTI]

    Robert W. Style; Rostislav Boltyanskiy; Benjamin Allen; Katharine E. Jensen; Henry P. Foote; John S. Wettlaufer; Eric R. Dufresne

    2014-07-24

    From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and engineering materials. Eshelby's inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite's bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby's theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet's deformation is strongly size-dependent with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straight-forward extension of Eshelby's theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive effect of liquid-stiffening of solids is expected whenever droplet radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young's modulus of the solid matrix.

  4. Tribological Characterization of Carbon Based Solid Lubricants 

    E-Print Network [OSTI]

    Sanchez, Carlos Joel

    2012-10-19

    High performance machines such as gas turbine engines demand efficient solid lubricants at high temperature and in vacuum. The current conventional solid lubricants need to be further improved. This research evaluates carbon based solid lubricants...

  5. The formation of the Kuiper belt by the outward transport of

    E-Print Network [OSTI]

    Morbidelli, Alessandro

    .............................................................. The formation of the Kuiper belt ............................................................................................................................................................................. The `dynamically cold Kuiper belt' consists of objects on low- inclination orbits between ,40 and ,50 AU from size unless the cold Kuiper belt originally contained tens of Earth masses of solids. Although several

  6. THE INSTITUTE FOR SOLID STATE PHYSICS 2006 THE INSTITUTE FOR SOLID STATE PHYSICS 2006

    E-Print Network [OSTI]

    Katsumoto, Shingo

    #12;#12;#12;2 THE INSTITUTE FOR SOLID STATE PHYSICS 2006 #12;3 THE INSTITUTE FOR SOLID STATE PHYSICS 2006 #12;4 THE INSTITUTE FOR SOLID STATE PHYSICS 2006 #12;5 THE INSTITUTE FOR SOLID STATE PHYSICS 2006 #12;6 THE INSTITUTE FOR SOLID STATE PHYSICS 2006 #12;7 THE INSTITUTE FOR SOLID STATE PHYSICS 2006

  7. Solid flexible electrochemical supercapacitor using Tobacco mosaic...

    Office of Scientific and Technical Information (OSTI)

    Solid flexible electrochemical supercapacitor using Tobacco mosaic virus nanostructures and ALD ruthenium oxide Citation Details In-Document Search Title: Solid flexible...

  8. Solid Waste Management Act (West Virginia)

    Broader source: Energy.gov [DOE]

    In addition to establishing a comprehensive program of controlling all phases of solid waste management and assigning responsibilities for solid waste management to the Secretary of Department of...

  9. Solid Solution Lithium Alloy Cermet Anodes

    E-Print Network [OSTI]

    Richardson, Thomas J.; Chen, Guoying

    2006-01-01

    Solid Solution Lithium Alloy Cermet Anodes Thomas J.94720 USA Abstract Lithium-magnesium solid solution alloysHeating mixtures of lithium nitride and magnesium provides a

  10. Solid electrolyte material manufacturable by polymer processing...

    Office of Scientific and Technical Information (OSTI)

    Patent: Solid electrolyte material manufacturable by polymer processing methods Citation Details In-Document Search Title: Solid electrolyte material manufacturable by polymer...

  11. Evidence for Epoxide Formation from the Electrochemical Reduction of Ethylene Carbonate

    E-Print Network [OSTI]

    in the formation of an effective solid electrolyte interface layer on the carbon anode in lithium-ion cells this reduction form a solid electrolyte interface SEI on the electrode surface, and pre- vent further reduction after EC/tetrahydrofuran electrolyte reduction that is unlike any other we have seen in the literature

  12. Composite solid polymer electrolyte membranes

    DOE Patents [OSTI]

    Formato, Richard M. (Shrewsbury, MA); Kovar, Robert F. (Wrentham, MA); Osenar, Paul (Watertown, MA); Landrau, Nelson (Marlborough, MA); Rubin, Leslie S. (Newton, MA)

    2001-06-19

    The present invention relates to composite solid polymer electrolyte membranes (SPEMs) which include a porous polymer substrate interpenetrated with an ion-conducting material. SPEMs of the present invention are useful in electrochemical applications, including fuel cells and electrodialysis.

  13. Composite solid polymer electrolyte membranes

    DOE Patents [OSTI]

    Formato, Richard M.; Kovar, Robert F.; Osenar, Paul; Landrau, Nelson; Rubin, Leslie S.

    2006-05-30

    The present invention relates to composite solid polymer electrolyte membranes (SPEMs) which include a porous polymer substrate interpenetrated with an ion-conducting material. SPEMs of the present invention are useful in electrochemical applications, including fuel cells and electrodialysis.

  14. Cogeneration/Cogeneration - Solid Waste 

    E-Print Network [OSTI]

    Pyle, F. B.

    1980-01-01

    This paper reviews the rationale for cogeneration and basic turbine types available. Special considerations for cogeneration in conjunction with solid waste firing are outlined. Optimum throttle conditions for cogeneration are significantly...

  15. Solid State Photovoltaic Research Branch

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This report summarizes the progress of the Solid State Photovoltaic Research Branch of the Solar Energy Research Institute (SERI) from October 1, 1988, through September 30,l 1989. Six technical sections of the report cover these main areas of SERIs in-house research: Semiconductor Crystal Growth, Amorphous Silicon Research, Polycrystalline Thin Films, III-V High-Efficiency Photovoltaic Cells, Solid-State Theory, and Laser Raman and Luminescence Spectroscopy. Sections have been indexed separately for inclusion on the data base.

  16. Water Formatics Engineered formation of nanobubbles networks

    E-Print Network [OSTI]

    Jacob, Eshel Ben

    Water Formatics Engineered formation of nanobubbles networks in water and aqueous solutions We present the idea that the anomalous effects of rf-treatments of water and aqueous solution resulted from-bubble exchange interactions. These exchange interactions are mediated by the ordering of the water molecules

  17. Pulsed Power for Solid-State Lasers

    SciTech Connect (OSTI)

    Gagnon, W; Albrecht, G; Trenholme, J; Newton, M

    2007-04-19

    Beginning in the early 1970s, a number of research and development efforts were undertaken at U.S. National Laboratories with a goal of developing high power lasers whose characteristics were suitable for investigating the feasibility of laser-driven fusion. A number of different laser systems were developed and tested at ever larger scale in pursuit of the optimum driver for laser fusion experiments. Each of these systems had associated with it a unique pulsed power option. A considerable amount of original and innovative engineering was carried out in support of these options. Ultimately, the Solid-state Laser approach was selected as the optimum driver for the application. Following this, the Laser Program at the Lawrence Livermore National Laboratory and the University of Rochester undertook aggressive efforts directed at developing the technology. In particular, at Lawrence Livermore National Laboratory, a series of laser systems beginning with the Cyclops laser and culminating in the present with the National Ignition Facility were developed and tested. As a result, a large amount of design information for solid-state laser pulsed power systems has been documented. Some of it is in the form of published papers, but most of it is buried in internal memoranda, engineering reports and LLNL annual reports. One of the goals of this book is to gather this information into a single useable format, such that it is easily accessed and understood by other engineers and physicists for use with future designs. It can also serve as a primer, which when seriously studied, makes the subsequent reading of original work and follow-up references considerably easier. While this book deals only with the solid-state laser pulsed power systems, in the bibliography we have included a representative cross section of papers and references from much of the very fine work carried out at other institutions in support of different laser approaches. Finally, in recent years, there has been a renewed interest in high-average-power solid-state glass lasers. Much of the prime power technology developed in support of this has definite applications in the long term for fusion power plant scenarios.

  18. A Strong Bond Model for Stress Relaxation of Soft Solid Interfaces

    E-Print Network [OSTI]

    Arun K. Singh; Vinay A. Juvekar

    2014-11-29

    In this article, we propose a mathematical model which explains the formation of strong bonds during the relaxation process of a soft solid on a hard surface. As a result, the soft solid relaxes to a non zero residual stress level. The model assumes that formation of strong bonds occurs owing to transition from weak to strong bonds at a critical time. Parametric studies are carried out to understand the effect of different friction parameters related with the model on the relaxation process. The relaxation model is, in turn, validated with experiments and corresponding numerical values are justified.

  19. Municipal Solid Waste in The United States

    E-Print Network [OSTI]

    Laughlin, Robert B.

    ...................................................................................................................... 17 The Solid Waste Management Hierarchy2007 Facts and Figures Municipal Solid Waste in The United States #12;United States Environmental Protection Agency Office of Solid Waste (5306P) EPA530-R-08-010 November 2008 www.epa.gov #12;MUNICIPAL SOLID

  20. Municipal Solid Waste in The United States

    E-Print Network [OSTI]

    Barlaz, Morton A.

    ...................................................................................................................18 The Solid Waste Management Hierarchy2011 Facts and Figures Municipal Solid Waste in The United States #12;United States Environmental Protection Agency Office of Solid Waste (5306P) EPA530-R-13-001 May 2013 www.epa.gov #12;MUNICIPAL SOLID

  1. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  2. ARTICLE IN PRESS Solid State Communications ( )

    E-Print Network [OSTI]

    Raychaudhuri, Pratap

    400005, India b Solid State Laser Division, Raja Ramanna Centre for Advanced Technology, Indore 425013

  3. Commissioning and first results of scanning type EXAFS beamline (BL-09) at INDUS-2 synchrotron source

    SciTech Connect (OSTI)

    Poswal, A. K. Agrawal, A. Yadav, A. K. Nayak, C. Basu, S. Bhattachryya, D.; Jha, S. N.; Sahoo, N. K.; Kane, S. R.; Garg, C. K.

    2014-04-24

    An Energy Scanning X-ray Absorption Fine Structure spectroscopy beamline has recently been installed and commissioned at BL-09 bending magnet port of INDUS-2 synchrotron source, Indore. The beamline uses an UHV compatible fixed exit double crystal monochromator (DCM) with two Si (111) crystals. Two grazing incidence cylindrical mirrors are also used in this beamline; the pre-mirror is used as a collimating mirror while the post mirror is used for vertical focusing and higher harmonic rejection. In this beamline it is possible to carry out EXAFS measurements both in transmission and fluorescence mode on various types of samples, using Ionization chamber detectors and solid state drift detector respectively. In this paper, results from first experiments of the Energy Scanning EXAFS beamline are presented.

  4. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P.; Stechel, Ellen Beth; Moyer, Connor J.; Ambrosini, Andrea; Key, Robert J.

    2010-09-01

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  5. Formation of bands and ridges on Europa by cyclic deformation: Insights from analogue wax experiments

    E-Print Network [OSTI]

    Manga, Michael

    Formation of bands and ridges on Europa by cyclic deformation: Insights from analogue wax perform a set of analogue wax experiments aimed at understanding the processes and conditions that lead to lineament formation on Europa. We heat a layer of wax from below and cool it from above so that a solid

  6. Application of laser simulation method for the analysis of crater formation experiment on PALS laser

    E-Print Network [OSTI]

    Limpouch, Jiri

    Application of laser simulation method for the analysis of crater formation experiment on PALS laser S. Borodziuk, A. Kasperczuk, T. Pisarczyk Institute of Plasma Physics and Laser Microfusion, 23; final version 17 June 2003 The crater formation process is studied in the "laser ­ Al solid target

  7. Early formation of evolved asteroidal crust James M. D. Day1

    E-Print Network [OSTI]

    Mcdonough, William F.

    granoblastic textures, 120u triple junctions between coexist- ing silicates, polysynthetic twinning-rich, with andesite bulk compositions. Their age of 4.52 6 0.06 Gyr demonstrates formation early in Solar System unrecognized diversity of early-formed materials in the Solar System. Formation of crust, the outermost solid

  8. Solid-state lithium battery

    DOE Patents [OSTI]

    Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

    2014-11-04

    The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

  9. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J. (Urbana, IL); Foster, Christopher A. (Champaign, IL); Hendricks, Charles D. (Livermore, CA)

    1982-01-01

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  10. Solid-Liquid Interfacial Premelting

    E-Print Network [OSTI]

    Yang, Yang; Asta, Mark; Laird, Brian Bostian

    2013-02-28

    liquid-liquid miscibility gap, negligible solubility of Pb in the Al solid phase, and a large melting point separa- tion (600 K for Pb and 933 K for Al). We have previously reported results from MD simulations on this system at 625 K, a temperature just... undergoes a roughening transition about 100 K below the melting point of Al. Simulation details.—In our simulations of the Al-Pb solid-liquid interface, we employ a classical many-body potential developed by Landa et al. [42] to model the inter- atomic...

  11. TRANSITION PATH SAMPLING STUDIES OF SOLID-SOLID TRANSFORMATIONS

    E-Print Network [OSTI]

    Gruenwald, Michael

    isomerizations, or transport processes in solids, are characterized by widely disparate timescales. While. Many processes occurring in nature and technology such as the folding of a protein or the transport the freezing point, can remain in this supercooled state for hours or even days. Thus, the time scale

  12. Solid-state radioluminescent compositions

    DOE Patents [OSTI]

    Clough, Roger L. (Albuquerque, NM); Gill, John T. (Miamisburg, OH); Hawkins, Daniel B. (Fairbanks, AK); Renschler, Clifford L. (Tijeras, NM); Shepodd, Timothy J. (Livermore, CA); Smith, Henry M. (Overland Park, KS)

    1991-01-01

    A solid state radioluminescent composition for light source comprises an optically clear polymer organic matrix containing tritiated organic materials and dyes capable of "red" shifting primary scintillation emissions from the polymer matrix. The tritiated organic materials are made by reducing, with tritium, an unsaturated organic compound that prior to reduction contains olefinic or alkynylic bonds.

  13. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, J.G.; Benson, D.K.; Tracy, C.E.

    1998-02-10

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O--CeO{sub 2}--SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

  14. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  15. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  16. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, Ji-Guang (Golden, CO); Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

    1998-01-01

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

  17. Quality Services: Solid Wastes, Part 360: Solid Waste Management Facilities (New York)

    Broader source: Energy.gov [DOE]

    These regulations apply to all solid wastes with the exception of hazardous or radioactive waste. Proposed solid waste processing facilities are required to obtain permits prior to construction,...

  18. Planet formation and migration

    E-Print Network [OSTI]

    John C B Papaloizou; Caroline Terquem

    2005-11-28

    We review the observations of extrasolar planets, ongoing developments in theories of planet formation, orbital migration, and the evolution of multiplanet systems.

  19. SYNERGIA Forum Integrated Municipal Solid Waste Management

    E-Print Network [OSTI]

    Columbia University

    2nd SYNERGIA Forum «Integrated Municipal Solid Waste Management: Recycling and Energy Change and Solid Waste Management" Anthony Mavropoulos President, Scientific Technical Committee, Chairman, SYNERGIA "Where Greece stands on the Ladder of Sustainable Waste Management " *Nikolaos

  20. Gaines County Solid Waste Management Act (Texas)

    Broader source: Energy.gov [DOE]

    This Act establishes the Gaines County Solid Waste Management District, a governmental body to develop and carry out a regional water quality protection program through solid waste management and...

  1. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  2. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and Technology of Ceramic Fuel Cells, p. 209, Elsevier, NewI. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal

  3. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal and J.create connected nanostructured SOFC electrodes is reviewed.of Solid Oxide Fuel Cells (SOFC) to directly and efficiently

  4. Sandia Energy - (Lighting and) Solid-State Lighting: Science...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Lighting and) Solid-State Lighting: Science, Technology, Economic Perspectives Home Energy Research EFRCs Solid-State Lighting Science EFRC (Lighting and) Solid-State Lighting:...

  5. Sandia Energy - Brief History of Solid-State Lighting Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brief History of Solid-State Lighting Technology Home Energy Research EFRCs Solid-State Lighting Science EFRC Overview Brief History of Solid-State Lighting Technology Brief...

  6. Something for Nothing: Solid-Oxide Fuel Cells

    E-Print Network [OSTI]

    Gururangan, Karthik

    2015-01-01

    would be using other solid electrolytes. (Steele, This valueanode, cathode, and electrolyte are solid and the rate ofBy choosing a solid oxide electrolyte, the much larger

  7. 2014 Solid-State Lighting Project Portfolio

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    White LED Light Engines ... A-23 Phosphor Systems for Illumination Quality Solid State Lighting Products ... A-24...

  8. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect (OSTI)

    Sholklapper, Tal Zvi

    2007-12-15

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  9. Solid Waste Diversion Plan Fallen Star, 2012

    E-Print Network [OSTI]

    Aluwihare, Lihini

    2012 Prepared by: Facilities Management #12;UC San Diego Solid Waste Diversion Plan Table of Contents Overview Location and Areas Covered Recycling and Solid Waste Management Contact Campus/Medical Center Campus Recycling and Solid Waste Management Contact The Facilities Management department is responsible

  10. Suspended Solids Profiler Shop Test Report

    SciTech Connect (OSTI)

    STAEHR, T.W.

    2000-01-19

    The Suspended Solids Profiler (SSP) Instrument is planned to be installed in the AZ-101 tank to measure suspended solids concentrations during mixer pump testing. The SSP sensor uses a reflectance measurement principle to determine the suspended solids concentrations. The purpose of this test is to provide a documented means of verifying that the functional components of the SSP operate properly.

  11. Physics 480 Introduction to Solid State Physics

    E-Print Network [OSTI]

    Kioussis, Nicholas

    Physics 480 Introduction to Solid State Physics Spring 2012 Logistics Lecture Room: 1100 (Live Oak://www.csun.edu/~nkioussi Prerequisites Quantum Mechanics or Modern Physics at 375 level Textbook Introduction to Solid State Physics, Charles Kittel, Wiley, 8th Edition Reference: Neil W. Ashcroft and N. David Mermin, Solid State Physics

  12. Energy and solid/hazardous waste

    SciTech Connect (OSTI)

    1981-12-01

    This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included. (PSB)

  13. Rechargeable solid polymer electrolyte battery cell

    DOE Patents [OSTI]

    Skotheim, Terji (East Patchoque, NY)

    1985-01-01

    A rechargeable battery cell comprising first and second electrodes sandwiching a solid polymer electrolyte comprising a layer of a polymer blend of a highly conductive polymer and a solid polymer electrolyte adjacent said polymer blend and a layer of dry solid polymer electrolyte adjacent said layer of polymer blend and said second electrode.

  14. Solid Waste Management Plan. Revision 4

    SciTech Connect (OSTI)

    1995-04-26

    The waste types discussed in this Solid Waste Management Plan are Municipal Solid Waste, Hazardous Waste, Low-Level Mixed Waste, Low-Level Radioactive Waste, and Transuranic Waste. The plan describes for each type of solid waste, the existing waste management facilities, the issues, and the assumptions used to develop the current management plan.

  15. Perovskite solid electrolytes for SOFC

    SciTech Connect (OSTI)

    Sammells, A.F.

    1993-11-01

    We have synthesized a new series of brownmillerite solid electrolyte phases Ba{sub 2}GdIn{sub 1-x}Ga{sub x}O{sub 5} (x = 0,0.2,0.4) with the x = 0.2 phase exhibiting an unusually low E. relative to both the observed ionic conductivity in this phase and to E{sub a}s observed in similar compounds. We attribute measured ionic conductivities to a lack of available charge carriers in Ba{sub 2}GdIn{sub 0.8}Ga{sub 0.2}O{sub 5}. However, the low E{sub a} supports the premise that brownmillerite solid electrolyte structures are suitable for supporting high ionic conductivity. Current work is focusing on enhancing the amount of charge carriers in these materials by systematically introducing disorder into the brownmillerite lattice.

  16. Solid-state membrane module

    DOE Patents [OSTI]

    Gordon, John Howard (Salt Lake City, UT); Taylor, Dale M. (Murray, UT)

    2011-06-07

    Solid-state membrane modules comprising at least one membrane unit, where the membrane unit has a dense mixed conducting oxide layer, and at least one conduit or manifold wherein the conduit or manifold comprises a dense layer and at least one of a porous layer and a slotted layer contiguous with the dense layer. The solid-state membrane modules may be used to carry out a variety of processes including the separating of any ionizable component from a feedstream wherein such ionizable component is capable of being transported through a dense mixed conducting oxide layer of the membrane units making up the membrane modules. For ease of construction, the membrane units may be planar.

  17. Solid friction between soft filaments

    E-Print Network [OSTI]

    Andrew Ward; Feodor Hilitski; Walter Schwenger; David Welch; A. W. C. Lau; Vincenzo Vitelli; L. Mahadevan; Zvonimir Dogic

    2015-03-04

    Any macroscopic deformation of a filamentous bundle is necessarily accompanied by local sliding and/or stretching of the constituent filaments. Yet the nature of the sliding friction between two aligned filaments interacting through multiple contacts remains largely unexplored. Here, by directly measuring the sliding forces between two bundled F-actin filaments, we show that these frictional forces are unexpectedly large, scale logarithmically with sliding velocity as in solid-like friction, and exhibit complex dependence on the filaments' overlap length. We also show that a reduction of the frictional force by orders of magnitude, associated with a transition from solid-like friction to Stokes' drag, can be induced by coating F-actin with polymeric brushes. Furthermore, we observe similar transitions in filamentous microtubules and bacterial flagella. Our findings demonstrate how altering a filament's elasticity, structure and interactions can be used to engineer interfilament friction and thus tune the properties of fibrous composite materials.

  18. Supercritical/Solid Catalyst (SSC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

  19. MSME in Solid Mechanics Research is conducted in analytical, computational and experimental solid mechanics

    E-Print Network [OSTI]

    Feeny, Brian

    MSME in Solid Mechanics Research is conducted in analytical, computational and experimental solid mechanics including theory of elasticity, fastening and joining, experimental mechanics and optical strain measurement, impact and crashworthiness. MS Track for Solid Mechanics The MSME degree program for solid

  20. Solid state division progress report, period ending February 29, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-09-01

    Research is reported concerning theoretical solid state physics; surface and near-surface properties of solids; defects in solids; transport properties of solids; neutron scattering; crystal growth and characterization; and isotope research materials.

  1. Solid-water detoxifying reagents for chemical and biological agents

    DOE Patents [OSTI]

    Hoffman, Dennis M. (Livermore, CA); Chiu, Ing Lap (Castro Valley, CA)

    2006-04-18

    Formation of solid-water detoxifying reagents for chemical and biological agents. Solutions of detoxifying reagent for chemical and biological agents are coated using small quantities of hydrophobic nanoparticles by vigorous agitation or by aerosolization of the solution in the presence of the hydrophobic nanoparticles to form a solid powder. For example, when hydrophobic fumed silica particles are shaken in the presence of IN oxone solution in approximately a 95:5-weight ratio, a dry powder results. The hydrophobic silica forms a porous coating of insoluble fine particles around the solution. Since the chemical or biological agent tends to be hydrophobic on contact with the weakly encapsulated detoxifying solution, the porous coating breaks down and the detoxifying reagent is delivered directly to the chemical or biological agent for maximum concentration at the point of need. The solid-water (coated) detoxifying solutions can be blown into contaminated ventilation ducting or other difficult to reach sites for detoxification of pools of chemical or biological agent. Once the agent has been detoxified, it can be removed by flushing the area with air or other techniques.

  2. Notes on Star Formation

    E-Print Network [OSTI]

    Krumholz, Mark R

    2015-01-01

    This book provides an introduction to the field of star formation at a level suitable for graduate students or advanced undergraduates in astronomy or physics. The structure of the book is as follows. The first two chapters begin with a discussion of observational techniques, and the basic phenomenology they reveal. The goal is to familiarize students with the basic techniques that will be used throughout, and to provide a common vocabulary for the rest of the book. The next five chapters provide a similar review of the basic physical processes that are important for star formation. Again, the goal is to provide a basis for what follows. The remaining chapters discuss star formation over a variety of scales, starting with the galactic scale and working down to the scales of individual stars and their disks. The book concludes with a brief discussion of the clearing of disks and the transition to planet formation. The book includes five problem sets, complete with solutions.

  3. Word formation in Thadou

    E-Print Network [OSTI]

    Haokip, Pauthang

    2014-01-01

    As stated above, compound words of Thadou are mostlyNote that the resulting new words are always nouns. a. b. c.bad’ (negative) Haokip: Word formation in Thadou a. â-sâa ?

  4. Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    An, Zhinan; Jia, Haoling; Wu, Yueying; Rack, Philip D.; Patchen, Allan D.; Liu, Yuzi; Ren, Yang; Li, Nan; Liaw, Peter K.

    2015-05-04

    The concept of high configurational entropy requires that the high-entropy alloys (HEAs) yield single-phase solid solutions. However, phase separations are quite common in bulk HEAs. A five-element alloy, CrCoCuFeNi, was deposited via radio frequency magnetron sputtering and confirmed to be a single-phase solid solution through the high-energy synchrotron X-ray diffraction, energy-dispersive spectroscopy, wavelength-dispersive spectroscopy, and transmission electron microscopy. The formation of the solid-solution phase is presumed to be due to the high cooling rate of the sputter-deposition process.

  5. Solid phase microextraction field kit

    DOE Patents [OSTI]

    Nunes, Peter J.; Andresen, Brian D.

    2005-08-16

    A field kit for the collection, isolation and concentration of trace amounts of high explosives (HE), biological weapons (BW) and chemical weapons (CW) residues in air, soil, vegetation, swipe, and liquid samples. The field kit includes a number of Solid Phase Microextraction (SPME) fiber and syringe assemblies in a hermetically sealed transportation container or tubes which includes a sampling port, a number of extra SPME fiber and syringe assemblies, the fiber and syringe assemblies including a protective cap for the fiber, and an extractor for the protective cap, along with other items including spare parts, protective glove, and an instruction manual, all located in an airtight container.

  6. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  7. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  8. Solid state electrochromic light modulator

    DOE Patents [OSTI]

    Cogan, S.F.; Rauh, R.D.

    1990-07-03

    An all solid-state variable transmission electrochromic device has a source of charge compensating ions. An inorganic oxide counter electrode film which on reduction with the accompanying insertion of the charge compensating ions increases its transmission of light of predetermined wavelength is separated from a primary electrochromic film which on reduction with the accompanying insertion of the charge compensating ions decreases its transmission of light of predetermined wavelength by an insulating electrolyte film that transports the charge compensating ions. First and second electrodes are contiguous with the inorganic oxide counter electrode film and the primary electrochromic film, respectively, and separated by the three films. 4 figs.

  9. Sandia Energy - Solid Fuels Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)GeothermalFuel Magnetization and Laser(TSPEARSolar ResourceSolid Fuels

  10. Nanoscale Mixing of Soft Solids

    SciTech Connect (OSTI)

    Choi, Soo-Hyung; Lee, Sangwoo; Soto, Haidy E.; Lodge, Timothy P.; Bates, Frank S. (UMM); (Texas)

    2013-03-07

    Assessing the state of mixing on the molecular scale in soft solids is challenging. Concentrated solutions of micelles formed by self-assembly of polystyrene-block-poly(ethylene-alt-propylene) (PS-PEP) diblock copolymers in squalane (C{sub 30}H{sub 62}) adopt a body-centered cubic (bcc) lattice, with glassy PS cores. Utilizing small-angle neutron scattering (SANS) and isotopic labeling ({sup 1}H and {sup 2}H (D) polystyrene blocks) in a contrast-matching solvent (a mixture of squalane and perdeuterated squalane), we demonstrate quantitatively the remarkable fact that a commercial mixer can create completely random mixtures of micelles with either normal, PS(H), or deuterium-labeled, PS(D), cores on a well-defined bcc lattice. The resulting SANS intensity is quantitatively modeled by the form factor of a single spherical core. These results demonstrate both the possibility of achieving complete nanoscale mixing in a soft solid and the use of SANS to quantify the randomness.

  11. Solid Holography and Massive Gravity

    E-Print Network [OSTI]

    Alberte, Lasma; Khmelnitsky, Andrei; Pujolas, Oriol

    2015-01-01

    Momentum dissipation is an important ingredient in condensed matter physics that requires a translation breaking sector. In the bottom-up gauge/gravity duality, this implies that the gravity dual is massive. We start here a systematic analysis of holographic massive gravity (HMG) theories, which admit field theory dual interpretations and which, therefore, might store interesting condensed matter applications. We show that there are many phases of HMG that are fully consistent effective field theories and which have been left overlooked in the literature. The most important distinction between the different HMG phases is that they can be clearly separated into solids and fluids. This can be done both at the level of the unbroken spacetime symmetries as well as concerning the elastic properties of the dual materials. We extract the modulus of rigidity of the solid HMG black brane solutions and show how it relates to the graviton mass term. We also consider the implications of the different HMGs on the electric...

  12. Contamination and solid state welds.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-05-01

    Since sensitivity to contamination is one of the verities of solid state joining, there is a need for assessing contamination of the part(s) to be joined, preferably nondestructively while it can be remedied. As the surfaces that are joined in pinch welds are inaccessible and thus provide a greater challenge, most of the discussion is of the search for the origin and effect of contamination on pinch welding and ways to detect and mitigate it. An example of contamination and the investigation and remediation of such a system is presented. Suggestions are made for techniques for nondestructive evaluation of contamination of surfaces for other solid state welds as well as for pinch welds. Surfaces that have good visual access are amenable to inspection by diffuse reflection infrared Fourier transform (DRIFT) spectroscopy. Although other techniques are useful for specific classes of contaminants (such as hydrocarbons), DRIFT can be used most classes of contaminants. Surfaces such as the interior of open tubes or stems that are to be pinch welded can be inspected using infrared reflection spectroscopy. It must be demonstrated whether or not this tool can detect graphite based contamination, which has been seen in stems. For tubes with one closed end, the technique that should be investigated is emission infrared spectroscopy.

  13. OVERCOMING THE METER BARRIER AND THE FORMATION OF SYSTEMS WITH TIGHTLY PACKED INNER PLANETS (STIPs)

    SciTech Connect (OSTI)

    Boley, A. C.; Morris, M. A.; Ford, E. B.

    2014-09-10

    We present a solution to the long outstanding meter barrier problem in planet formation theory. As solids spiral inward due to aerodynamic drag, they will enter disk regions that are characterized by high temperatures, densities, and pressures. High partial pressures of rock vapor can suppress solid evaporation, and promote collisions between partially molten solids, allowing rapid growth. This process should be ubiquitous in planet-forming disks, which may be evidenced by the abundant class of Systems with Tightly packed Inner Planets discovered by the NASA Kepler Mission.

  14. Solid-oxide fuel cell electrolyte

    DOE Patents [OSTI]

    Bloom, Ira D. (Bolingbrook, IL); Hash, Mark C. (Joliet, IL); Krumpelt, Michael (Naperville, IL)

    1993-01-01

    A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

  15. Design of Nanocrystal Solids for Photoelectrochemical Synthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design of Nanocrystal Solids for Photoelectrochemical Synthesis of Liquid Fuels The proposed research project seeks to exploit the unique size-, composition-, and surface-tunable...

  16. MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE...

    Office of Scientific and Technical Information (OSTI)

    Open problems in condensed matter physics, 1987 Falicov, L.M. 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE PHYSICS; RESEARCH PROGRAMS;...

  17. Solid-State Lighting Technical Reports

    SciTech Connect (OSTI)

    None

    2011-12-16

    A page that contains links to technical reports of studies estimating the energy savings potential of solid-state lighting in numerous applications.

  18. Solid State Lighting Program (Falcon)

    SciTech Connect (OSTI)

    Meeks, Steven

    2012-06-30

    Over the past two years, KLA-Tencor and partners successfully developed and deployed software and hardware tools that increase product yield for High Brightness LED (HBLED) manufacturing and reduce product development and factory ramp times. This report summarizes our development effort and details of how the results of the Solid State Light Program (Falcon) have started to help HBLED manufacturers optimize process control by enabling them to flag and correct identified killer defect conditions at any point of origin in the process manufacturing flow. This constitutes a quantum leap in yield management over current practice. Current practice consists of die dispositioning which is just rejection of bad die at end of process based upon probe tests, loosely assisted by optical in-line monitoring for gross process deficiencies. For the first time, and as a result of our Solid State Lighting Program, our LED manufacturing partners have obtained the software and hardware tools that optimize individual process steps to control killer defects at the point in the processes where they originate. Products developed during our two year program enable optimized inspection strategies for many product lines to minimize cost and maximize yield. The Solid State Lighting Program was structured in three phases: i) the development of advanced imaging modes that achieve clear separation between LED defect types, improves signal to noise and scan rates, and minimizes nuisance defects for both front end and back end inspection tools, ii) the creation of defect source analysis (DSA) software that connect the defect maps from back-end and front-end HBLED manufacturing tools to permit the automatic overlay and traceability of defects between tools and process steps, suppress nuisance defects, and identify the origin of killer defects with process step and conditions, and iii) working with partners (Philips Lumileds) on product wafers, obtain a detailed statistical correlation of automated defect and DSA map overlay to failed die identified using end product probe test results. Results from our two year effort have led to “automated end-to-end defect detection” with full defect traceability and the ability to unambiguously correlate device killer defects to optically detected features and their point of origin within the process. Success of the program can be measured by yield improvements at our partner’s facilities and new product orders.

  19. Mathematical Models and Numerical Solutions of Liquid-Solid and Solid-Liquid Phase Change

    E-Print Network [OSTI]

    Surana, Karan S.; Joy, Aaron; Quiros, Luis; Reddy, JN

    2015-04-01

    This paper presents numerical simulations of liquid-solid and solid-liquid phase change processes using mathematical models in Lagrangian and Eulerian descriptions. The mathematical models are derived by assuming a smooth ...

  20. Methods for Increasing Sensitivity and Throughput of Solid-State NMR Spectroscopy of Pharmaceutical Solids

    E-Print Network [OSTI]

    Schieber, Loren

    2010-01-22

    Solid-state nuclear magnetic resonance (SSNMR) spectroscopy has been demonstrated to be a powerful technique for investigating solid dosage formulations. SSNMR has the ability to determine physical form, molecular structure, ...

  1. Solid phase sequencing of biopolymers

    DOE Patents [OSTI]

    Cantor, Charles (Del Mar, CA); Koster, Hubert (La Jolla, CA)

    2010-09-28

    This invention relates to methods for detecting and sequencing target nucleic acid sequences, to mass modified nucleic acid probes and arrays of probes useful in these methods, and to kits and systems which contain these probes. Useful methods involve hybridizing the nucleic acids or nucleic acids which represent complementary or homologous sequences of the target to an array of nucleic acid probes. These probes comprise a single-stranded portion, an optional double-stranded portion and a variable sequence within the single-stranded portion. The molecular weights of the hybridized nucleic acids of the set can be determined by mass spectroscopy, and the sequence of the target determined from the molecular weights of the fragments. Nucleic acids whose sequences can be determined include DNA or RNA in biological samples such as patient biopsies and environmental samples. Probes may be fixed to a solid support such as a hybridization chip to facilitate automated molecular weight analysis and identification of the target sequence.

  2. Fibrillar dimer formation of islet amyloid polypeptides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chiu, Chi -cheng; de Pablo, Juan J.

    2015-05-08

    Amyloid deposits of human islet amyloid polypeptide (hIAPP), a 37-residue hormone co-produced with insulin, have been implicated in the development of type 2 diabetes. Residues 20 – 29 of hIAPP have been proposed to constitute the amyloidogenic core for the aggregation process, yet the segment is mostly unstructured in the mature fibril, according to solid-state NMR data. Here we use molecular simulations combined with bias-exchange metadynamics to characterize the conformational free energies of hIAPP fibrillar dimer and its derivative, pramlintide. We show that residues 20 – 29 are involved in an intermediate that exhibits transient ?-sheets, consistent with recent experimentalmore »and simulation results. By comparing the aggregation of hIAPP and pramlintide, we illustrate the effects of proline residues on inhibition of the dimerization of IAPP. The mechanistic insights presented here could be useful for development of therapeutic inhibitors of hIAPP amyloid formation.« less

  3. NEWS & VIEWS PATTERN FORMATION

    E-Print Network [OSTI]

    Loss, Daniel

    no apologies for investing energy into problems of specific application to a particular process in nature, and having the curiosity to want to find out how they work. The general public, and especially children flow/surface growth system in a rarely explored region of parameter space for such pattern formation

  4. Isolating Triggered Star Formation

    E-Print Network [OSTI]

    Elizabeth J. Barton; Jacob A. Arnold; Andrew R. Zentner; James S. Bullock; Risa H. Wechsler

    2007-08-21

    Galaxy pairs provide a potentially powerful means of studying triggered star formation from galaxy interactions. We use a large cosmological N-body simulation coupled with a well-tested semi-analytic substructure model to demonstrate that the majority of galaxies in close pairs reside within cluster or group-size halos and therefore represent a biased population, poorly suited for direct comparison to ``field'' galaxies. Thus, the frequent observation that some types of galaxies in pairs have redder colors than ``field'' galaxies is primarily a selection effect. We select galaxy pairs that are isolated in their dark matter halos with respect to other massive subhalos (N=2 halos) and a control sample of isolated galaxies (N=1 halos) for comparison. We then apply these selection criteria to a volume-limited subset of the 2dF Galaxy Redshift Survey with M_Bj ~ 5 above their average past value, while only 10% of isolated galaxies in the control sample show this level of enhancement. Thus, 14% (20 %) of the galaxies in these close pairs show clear triggered star formation. The isolation criteria we develop provide a means to constrain star formation and feedback prescriptions in hydrodynamic simulations and a very general method of understanding the importance of triggered star formation in a cosmological context. (Abridged.)

  5. Biochemical transformation of solid carbonaceous material

    DOE Patents [OSTI]

    Lin, Mow S. (Rocky Point, NY); Premuzic, Eugene T. (East Moriches, NY)

    2001-09-25

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed.

  6. Managing America`s solid waste

    SciTech Connect (OSTI)

    Not Available

    1998-03-02

    This report presents an historical overview of the federal role in municipal solid waste management from 1965 to approximately 1995. Attention is focuses on the federal role in safeguarding public health, protecting the environment, and wisely using material and energy resources. It is hoped that this report will provide important background for future municipal solid waste research and development initiatives.

  7. Modeling Solid-Electrolyte-Electrode Interfaces

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Modeling Solid-Electrolyte- Electrode Interfaces N. D. Lepley and N. A. W. Holzwarth Wake Forest University Supported by NSF grant DMR-1105485 #12;Motivation · Solid electrolyte/electrode interfaces more chemically stable · Enable Li anodes, S cathodes · Interested in characterizing interface ­ What interface

  8. Solid waste burial grounds interim safety analysis

    SciTech Connect (OSTI)

    Saito, G.H.

    1994-10-01

    This Interim Safety Analysis document supports the authorization basis for the interim operation and restrictions on interim operations for the near-surface land disposal of solid waste in the Solid Waste Burial Grounds. The Solid Waste Burial Grounds Interim Safety Basis supports the upgrade progress for the safety analysis report and the technical safety requirements for the operations in the Solid Waste Burial Grounds. Accident safety analysis scenarios have been analyzed based on the significant events identified in the preliminary hazards analysis. The interim safety analysis provides an evaluation of the operations in the Solid Waste Burial Grounds to determine if the radiological and hazardous material exposures will be acceptable from an overall health and safety standpoint to the worker, the onsite personnel, the public, and the environment.

  9. Surfactant process for promoting gas hydrate formation and application of the same

    DOE Patents [OSTI]

    Rogers, Rudy E. (Starkville, MS); Zhong, Yu (Brandon, MS)

    2002-01-01

    This invention relates to a method of storing gas using gas hydrates comprising forming gas hydrates in the presence of a water-surfactant solution that comprises water and surfactant. The addition of minor amounts of surfactant increases the gas hydrate formation rate, increases packing density of the solid hydrate mass and simplifies the formation-storage-decomposition process of gas hydrates. The minor amounts of surfactant also enhance the potential of gas hydrates for industrial storage applications.

  10. In situ transmission electron microscopy analysis of conductive filament during solid electrolyte resistance switching

    SciTech Connect (OSTI)

    Fujii, Takashi; Arita, Masashi; Takahashi, Yasuo; Fujiwara, Ichiro

    2011-05-23

    An in situ transmission electron microscopy (TEM) analysis of a solid electrolyte, Cu-GeS, during resistance switching is reported. Real-time observations of the filament formation and disappearance process were performed in the TEM instrument and the conductive-filament-formation model was confirmed experimentally. Narrow conductive filaments were formed corresponding to resistance switching from high- to low-resistance states. When the resistance changed to high-resistance state, the filament disappeared. It was also confirmed by use of selected area diffractometry and energy-dispersive x-ray spectroscopy that the conductive filament was made of nanocrystals composed mainly of Cu.

  11. The Formation of a Bubble from a Submerged Orifice

    E-Print Network [OSTI]

    Simmons, Jonathan A; Shikhmurzaev, Yulii D

    2015-01-01

    The formation of a single bubble from an orifice in a solid surface, submerged in an in- compressible, viscous Newtonian liquid, is simulated. The finite element method is used to capture the multiscale physics associated with the problem and to track the evolution of the free surface explicitly. The results are compared to a recent experimental analysis and then used to obtain the global characteristics of the process, the formation time and volume of the bubble, for a range of orifice radii; Ohnesorge numbers, which combine the material parameters of the liquid; and volumetric gas flow rates. These benchmark calculations, for the parameter space of interest, are then utilised to validate a selection of scaling laws found in the literature for two regimes of bubble formation, the regimes of low and high gas flow rates.

  12. Tetraphosphine Linker Scaffolds with a Tetraphenyltin Core for Superior Immobilized Catalysts: A Solid-State NMR Study 

    E-Print Network [OSTI]

    Perera, Melanie Ingrid

    2012-10-19

    the mechanism of the phosphonium formation in more detail by utilizing solid-state NMR spectroscopy. It has also been a point of interest to study the linkers and catalysts under realistic conditions, in the presence of solvents. Therefore, HRMAS (high...

  13. PHYSICAL REVIEW E 86, 031603 (2012) Solidification fronts in supercooled liquids: How rapid fronts can lead to disordered glassy solids

    E-Print Network [OSTI]

    Knobloch, Edgar

    2012-01-01

    theory capable of describing equilibrium aspects of melting, freezing, and also the interfaces between equilibrium DFT, these theories have been shown to be able to describe the dynamics of crystal formation [13) of the particles in the system. These theories essentially treat the solid phase as an inhomogeneous liquid

  14. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  15. SAMPLE RESULTS FROM MCU SOLIDS OUTAGE

    SciTech Connect (OSTI)

    Peters, T.; Washington, A.; Oji, L.; Coleman, C.; Poirier, M.

    2014-09-22

    Savannah River National Laboratory (SRNL) has received several solid and liquid samples from MCU in an effort to understand and recover from the system outage starting on April 6, 2014. SRNL concludes that the presence of solids in the Salt Solution Feed Tank (SSFT) is the likely root cause for the outage, based upon the following discoveries ? A solids sample from the extraction contactor #1 proved to be mostly sodium oxalate ? A solids sample from the scrub contactor#1 proved to be mostly sodium oxalate ? A solids sample from the Salt Solution Feed Tank (SSFT) proved to be mostly sodium oxalate ? An archived sample from Tank 49H taken last year was shown to contain a fine precipitate of sodium oxalate ? A solids sample from the extraction contactor #1 drain pipe from extraction contactor#1 proved to be mostly sodium aluminosilicate ? A liquid sample from the SSFT was shown to have elevated levels of oxalate anion compared to the expected concentration in the feed Visual inspection of the SSFT indicated the presence of precipitated or transferred solids, which were likely also in the Salt Solution Receipt Tank (SSRT). The presence of the solids coupled with agitation performed to maintain feed temperature resulted in oxalate solids migration through the MCU system and caused hydraulic issues that resulted in unplanned phase carryover from the extraction into the scrub, and ultimately the strip contactors. Not only did this carryover result in the Strip Effluent (SE) being pushed out of waste acceptance specification, but it resulted in the deposition of solids into several of the contactors. At the same time, extensive deposits of aluminosilicates were found in the drain tube in the extraction contactor #1. However it is not known at this time how the aluminosilicate solids are related to the oxalate solids. The solids were successfully cleaned out of the MCU system. However, future consideration must be given to the exclusion of oxalate solids into the MCU system. There were 53 recommendations for improving operations recently identified. Some additional considerations or additional details are provided below as recommendations. ? From this point on, IC-Anions analyses of the DSSHT should be part of the monthly routine analysis in order to spot negative trends in the oxalate leaving the MCU system. Care must be taken to monitor the oxalate content to watch for sudden precipitation of oxalate salts in the system. ? Conduct a study to optimize the cleaning strategy at ARP-MCU through decreasing the concentration or entirely eliminating the oxalic acid. ? The contents of the SSFT should remain unagitated. Routine visual observation should be maintained to ensure there is not a large buildup of solids. As water with agitation provided sufficient removal of the solids in the feed tank, it should be considered as a good means for dissolving oxalate solids if they are found in the future. ? Conduct a study to improve prediction of oxalate solubility in salt batch feed materials. As titanium and mercury have been found in various solids in this report, evaluate if either element plays a role in oxalate solubility during processing. ? Salt batch characterization focuses primarily on characterization and testing of unaltered Tank 21H material; however, non-typical feeds are developed through cleaning, washing, and/or sump transfers. As these solutions are processed through MCU, they may precipitate solids or reduce performance. Salt batch characterization and testing should be expanded to encompass a broader range of feeds that may be processed through ARPMCU.

  16. Solid state radiative heat pump

    DOE Patents [OSTI]

    Berdahl, Paul H. (Oakland, CA)

    1986-01-01

    A solid state radiative heat pump (10, 50, 70) operable at room temperature (300.degree. K.) utilizes a semiconductor having a gap energy in the range of 0.03-0.25 eV and operated reversibly to produce an excess or deficit of charge carriers as compared to thermal equilibrium. In one form of the invention (10, 70) an infrared semiconductor photodiode (21, 71) is used, with forward or reverse bias, to emit an excess or deficit of infrared radiation. In another form of the invention (50), a homogeneous semiconductor (51) is subjected to orthogonal magnetic and electric fields to emit an excess or deficit of infrared radiation. Three methods of enhancing transmission of radiation through the active surface of the semiconductor are disclosed. In one method, an anti-reflection layer (19) is coated into the active surface (13) of the semiconductor (11), the anti-reflection layer (19) having an index of refraction equal to the square root of that of the semiconductor (11). In the second method, a passive layer (75) is spaced from the active surface (73) of the semiconductor (71) by a submicron vacuum gap, the passive layer having an index of refractive equal to that of the semiconductor. In the third method, a coupler (91) with a paraboloid reflecting surface (92) is in contact with the active surface (13, 53) of the semiconductor (11, 51), the coupler having an index of refraction about the same as that of the semiconductor.

  17. Solid state radiative heat pump

    DOE Patents [OSTI]

    Berdahl, P.H.

    1984-09-28

    A solid state radiative heat pump operable at room temperature (300 K) utilizes a semiconductor having a gap energy in the range of 0.03-0.25 eV and operated reversibly to produce an excess or deficit of change carriers as compared equilibrium. In one form of the invention an infrared semiconductor photodiode is used, with forward or reverse bias, to emit an excess or deficit of infrared radiation. In another form of the invention, a homogenous semiconductor is subjected to orthogonal magnetic and electric fields to emit an excess or deficit of infrared radiation. Three methods of enhancing transmission of radiation the active surface of the semiconductor are disclosed. In one method, an anti-refection layer is coated into the active surface of the semiconductor, the anti-reflection layer having an index of refraction equal to the square root of that of the semiconductor. In the second method, a passive layer is speaced trom the active surface of the semiconductor by a submicron vacuum gap, the passive layer having an index of refractive equal to that of the semiconductor. In the third method, a coupler with a paraboloid reflecting surface surface is in contact with the active surface of the semiconductor, the coupler having an index of refraction about the same as that of the semiconductor.

  18. The genealogy of convex solids

    E-Print Network [OSTI]

    Domokos, Gabor; Szabó, Timea

    2012-01-01

    The shape of homogeneous, smooth convex bodies as described by the Euclidean distance from the center of gravity represents a rather restricted class M_C of Morse-Smale functions on S^2. Here we show that even M_C exhibits the complexity known for general Morse-Smale functions on S^2 by exhausting all combinatorial possibilities: every 2-colored quadrangulation of the sphere is isomorphic to a suitably represented Morse-Smale complex associated with a function in M_C (and vice versa). We prove our claim by an inductive algorithm, starting from the path graph P_2 and generating convex bodies corresponding to quadrangulations with increasing number of vertices by performing each combinatorially possible vertex splitting by a convexity- preserving local manipulation of the surface. Since convex bodies carrying Morse-Smale complexes isomorphic to P_2 exist, this algorithm not only proves our claim but also defines a hierarchical order among convex solids and general- izes the known classification scheme in [35], ...

  19. Solid state safety jumper cables

    DOE Patents [OSTI]

    Kronberg, James W. (353 Church Rd., Beech Island, SC 29841)

    1993-01-01

    Solid state jumper cables for connecting two batteries in parallel, having two bridge rectifiers for developing a reference voltage, a four-input decoder for determining which terminals are to be connected based on a comparison of the voltage at each of the four terminals to the reference voltage, and a pair of relays for effecting the correct connection depending on the determination of the decoder. No connection will be made unless only one terminal of each battery has a higher voltage than the reference voltage, indicating "positive" terminals, and one has a lower voltage than the reference voltage, indicating "negative" terminals, and that, therefore, the two high voltage terminals may be connected and the two lower voltage terminals may be connected. Current flows once the appropriate relay device is closed. The relay device is preferably a MOSFET (metal oxide semiconductor field effect transistor) combined with a series array of photodiodes that develop MOSFET gate-closing potential when the decoder output causes an LED to light.

  20. Highly efficient solid state catalysis by reconstructed (001) Ceria surface

    SciTech Connect (OSTI)

    Solovyov, VF; Ozaki, T; Atrei, A; Wu, LJ; Al-Mahboob, A; Sadowski, JT; Tong, X; Nykypanchuk, D; Li, Q

    2014-04-10

    Substrate engineering is a key factor in the synthesis of new complex materials. The substrate surface has to be conditioned in order to minimize the energy threshold for the formation of the desired phase or to enhance the catalytic activity of the substrate. The mechanism of the substrate activity, especially of technologically relevant oxide surfaces, is poorly understood. Here we design and synthesize several distinct and stable CeO2 (001) surface reconstructions which are used to grow epitaxial films of the high-temperature superconductor YBa2Cu3O7. The film grown on the substrate having the longest, fourfold period, reconstruction exhibits a twofold increase in performance over surfaces with shorter period reconstructions. This is explained by the crossover between the nucleation site dimensions and the period of the surface reconstruction. This result opens a new avenue for catalysis mediated solid state synthesis.

  1. Emptiness Formation Probability

    E-Print Network [OSTI]

    Nicholas Crawford; Stephen Ng; Shannon Starr

    2014-12-30

    We present rigorous upper and lower bounds on the emptiness formation probability for the ground state of a spin-$1/2$ Heisenberg XXZ quantum spin system. For a $d$-dimensional system we find a rate of decay of the order $\\exp(-c L^{d+1})$ where $L$ is the sidelength of the box in which we ask for the emptiness formation event to occur. In the $d=1$ case this confirms previous predictions made in the integrable systems community, though our bounds do not achieve the precision predicted by Bethe ansatz calculations. On the other hand, our bounds in the case $d \\geq 2$ are new. The main tools we use are reflection positivity and a rigorous path integral expansion which is a variation on those previously introduced by Toth, Aizenman-Nachtergaele and Ueltschi.

  2. Formate-assisted pyrolysis

    DOE Patents [OSTI]

    DeSisto, William Joseph; Wheeler, Marshall Clayton; van Heiningen, Adriaan R. P.

    2015-03-17

    The present invention provides, among other thing, methods for creating significantly deoxygenated bio-oils form biomass including the steps of providing a feedstock, associating the feedstock with an alkali formate to form a treated feedstock, dewatering the treated feedstock, heating the dewatered treated feedstock to form a vapor product, and condensing the vapor product to form a pyrolysis oil, wherein the pyrolysis oil contains less than 30% oxygen by weight.

  3. Washing of the AW-101 entrained solids

    SciTech Connect (OSTI)

    GJ Lumetta

    2000-03-31

    BNFL Inc. (BNFL) is under contract with the US Department of Energy, River Protection Project (DOE-RPP) to design, construct, and operate facilities for treating wastes stored in the single-shell and double-shell tanks at the Hanford Site, Richland, Washington. The DOE-BNFL RPP contract identifies two feeds to the waste treatment plant: (1) primarily liquid low-activity waste (LAW) consisting of less than 2 wt% entrained solids and (2) high-level waste (HLW) consisting of 10 to 200 g/L solids slurry. This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing on the composition of the entrained solids in the diluted AW-101 low-activity waste (LAW) sample. The objective of this work was to gather data on the solubility of the AW-101 entrained solids in 0.01 M NaOH, so that BNFL can evaluate whether these solids require caustic leaching. The work was conducted according to test plan BNFL-TP-29953-9, Rev. 0, LAW Entrained Solids Water Wash and Caustic Leach Testing. The test went according to plan, with no deviations from the test plan. Based on the results of the 0.01 M NaOH washing, a decision was made by BNFL to not proceed with the caustic leaching test. The composition of the washed solids was such that caustic leaching would not result in significant reduction in the immobilized HLW volume.

  4. Solid electrolytes for battery applications a theoretical perspective a

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Solid electrolytes for battery applications ­ a theoretical perspective a Natalie Holzwarth, USA · Introduction and motivation for solid electrolytes · What can computation do for this project? · Specific examples ­ LiPON, thio phosphates, other solid electrolytes · Suggestions for collaboration

  5. THERMODYNAMICS OF SOLID AND LIQUID GROUP III-V ALLOYS

    E-Print Network [OSTI]

    Anderson, T.J.

    2011-01-01

    cell design using a CaF2 solid electrolyte cell.for the CaF2 solid electrolyte cell. Helium purificationzirconia as the solid electrolyte and a (CO + C0 2 ) gaseous

  6. Theoretical and computer models of detonation in solid explosives

    SciTech Connect (OSTI)

    Tarver, C.M.; Urtiew, P.A.

    1997-10-01

    Recent experimental and theoretical advances in understanding energy transfer and chemical kinetics have led to improved models of detonation waves in solid explosives. The Nonequilibrium Zeldovich - von Neumann - Doring (NEZND) model is supported by picosecond laser experiments and molecular dynamics simulations of the multiphonon up-pumping and internal vibrational energy redistribution (IVR) processes by which the unreacted explosive molecules are excited to the transition state(s) preceding reaction behind the leading shock front(s). High temperature, high density transition state theory calculates the induction times measured by laser interferometric techniques. Exothermic chain reactions form product gases in highly excited vibrational states, which have been demonstrated to rapidly equilibrate via supercollisions. Embedded gauge and Fabry-Perot techniques measure the rates of reaction product expansion as thermal and chemical equilibrium is approached. Detonation reaction zone lengths in carbon-rich condensed phase explosives depend on the relatively slow formation of solid graphite or diamond. The Ignition and Growth reactive flow model based on pressure dependent reaction rates and Jones-Wilkins-Lee (JWL) equations of state has reproduced this nanosecond time resolved experimental data and thus has yielded accurate average reaction zone descriptions in one-, two- and three- dimensional hydrodynamic code calculations. The next generation reactive flow model requires improved equations of state and temperature dependent chemical kinetics. Such a model is being developed for the ALE3D hydrodynamic code, in which heat transfer and Arrhenius kinetics are intimately linked to the hydrodynamics.

  7. Irradiation-induced composition patterns in binary solid solutions

    SciTech Connect (OSTI)

    Dubey, Santosh; El-Azab, Anter [School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906 (United States)] [School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906 (United States)

    2013-09-28

    A theoretical/computational model for the irradiation-driven compositional instabilities in binary solid solutions has been developed. The model is suitable for investigating the behavior of structural alloys and metallic nuclear fuels in a reactor environment as well as the response of alloy thin films to ion beam irradiation. The model is based on a set of reaction-diffusion equations for the dynamics of vacancies, interstitials, and lattice atoms under irradiation. The dynamics of these species includes the stochastic generation of defects by collision cascades as well as the defect reactions and diffusion. The atomic fluxes in this model are derived based on the transitions of lattice defects. The set of reaction-diffusion equations are stiff, hence a stiffly stable method, also known as the Gear method, has been used to numerically approximate the equations. For the Cu-Au alloy in the solid solution regime, the model results demonstrate the formation of compositional patterns under high-temperature particle irradiation, with Fourier space properties (Fourier spectrum, average wavelength, and wavevector) depending on the cascade damage characteristics, average composition, and irradiation temperature.

  8. 1993 Solid Waste Reference Forecast Summary

    SciTech Connect (OSTI)

    Valero, O.J.; Blackburn, C.L. [Westinghouse Hanford Co., Richland, WA (United States); Kaae, P.S.; Armacost, L.L.; Garrett, S.M.K. [Pacific Northwest Lab., Richland, WA (United States)

    1993-08-01

    This report, which updates WHC-EP-0567, 1992 Solid Waste Reference Forecast Summary, (WHC 1992) forecasts the volumes of solid wastes to be generated or received at the US Department of Energy Hanford Site during the 30-year period from FY 1993 through FY 2022. The data used in this document were collected from Westinghouse Hanford Company forecasts as well as from surveys of waste generators at other US Department of Energy sites who are now shipping or plan to ship solid wastes to the Hanford Site for disposal. These wastes include low-level and low-level mixed waste, transuranic and transuranic mixed waste, and nonradioactive hazardous waste.

  9. Passivation-free solid state battery

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Peramunage, Dharmasena (Norwood, MA)

    1998-01-01

    This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

  10. Solid State Energy Conversion Alliance Delphi SOFC

    SciTech Connect (OSTI)

    Steven Shaffer; Gary Blake; Sean Kelly; Subhasish Mukerjee; Karl Haltiner; Larry Chick; David Schumann; Jeff Weissman; Gail Geiger; Ralphi Dellarocco

    2006-12-31

    The following report details the results under the DOE SECA program for the period July 2006 through December 2006. Developments pertain to the development of a 3 to 5 kW Solid Oxide Fuel Cell power system for a range of fuels and applications. This report details technical results of the work performed under the following tasks for the SOFC Power System: Task 1 SOFC System Development; Task 2 Solid Oxide Fuel Cell Stack Developments; Task 3 Reformer Developments; Task 4 Development of Balance of Plant Components; Task 5 Project Management; and Task 6 System Modeling & Cell Evaluation for High Efficiency Coal-Based Solid Oxide Fuel Cell Gas Turbine Hybrid System.

  11. MODELING AND SIMULATION OF FINGERING PATTERN FORMATION IN A COMBUSTION MODEL

    E-Print Network [OSTI]

    Shen, Jie

    MODELING AND SIMULATION OF FINGERING PATTERN FORMATION IN A COMBUSTION MODEL LINA HU, CLAUDE-MICHEL BRAUNER, JIE SHEN, AND GREGORY I. SIVASHINSKY Abstract. We consider a model of gas-solid combustion background. Combustion is basically a process of fast oxidation accompanied by substantial heat release

  12. Energy Secretary Bodman Statement on Hanford Solid Waste Settlement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Statement on Hanford Solid Waste Settlement Agreement Energy Secretary Bodman Statement on Hanford Solid Waste Settlement Agreement January 9, 2006 - 9:43am Addthis Richland, WA -...

  13. Measurement of diesel solid nanoparticle emissions using a catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic...

  14. Nevada Industrial Solid Waste Disposal Site Permit Application...

    Open Energy Info (EERE)

    Nevada Industrial Solid Waste Disposal Site Permit Application Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Nevada Industrial Solid Waste Disposal Site...

  15. Georgia Comprehensive Solid Waste Management Act of 1990 (Georgia)

    Broader source: Energy.gov [DOE]

    The Georgia Comprehensive Solid Waste Management Act (SWMA) of 1990 was implemented in order to improve solid waste management procedures, permitting processes and management throughout the state. ...

  16. The Kanatzidis - Chang Cell: dye sensitized all solid state solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Kanatzidis - Chang Cell: dye sensitized all solid state solar cell Home > Research > ANSER Research Highlights > The Kanatzidis - Chang Cell: dye sensitized all solid state...

  17. FEMP Outdoor Solid-State Lighting Intiative: Resources for Outdoor...

    Office of Environmental Management (EM)

    Outdoor Solid-State Lighting Intiative: Resources for Outdoor SSL Applications FEMP Outdoor Solid-State Lighting Intiative: Resources for Outdoor SSL Applications Fact sheet...

  18. Energy Department Announces $4 Million Solicitation for Solid...

    Energy Savers [EERE]

    Energy Department Announces 4 Million Solicitation for Solid-State Lighting Research Energy Department Announces 4 Million Solicitation for Solid-State Lighting Research August...

  19. Federal Technology Deployment Pilot: Exterior Solid State Lighting...

    Energy Savers [EERE]

    Federal Technology Deployment Pilot: Exterior Solid State Lighting Federal Technology Deployment Pilot: Exterior Solid State Lighting Presentation-given at the Fall 2011 Federal...

  20. Solid-State Lighting Commercial Product Development Resulting...

    Energy Savers [EERE]

    Solid-State Lighting Commercial Product Development Resulting from DOE-Funded Projects Solid-State Lighting Commercial Product Development Resulting from DOE-Funded Projects...

  1. DOE Solid-State Lighting Program: Modest Investments, Extraordinary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modest Investments, Extraordinary Impacts DOE Solid-State Lighting Program Shaping the Future of Solid-State Lighting Today, LED (light-emitting diode) technologies illuminate...

  2. System Reliability Model for Solid-State Lighting Luminaires...

    Energy Savers [EERE]

    System Reliability Model for Solid-State Lighting Luminaires System Reliability Model for Solid-State Lighting Luminaires Lead Performer: RTI International - Research Triangle...

  3. Technology assessment and market analysis of solid state ultracapacitors

    E-Print Network [OSTI]

    Jiang, Zibo

    2007-01-01

    This report provides quantitative analysis of Solid State Ultracapacitors (SSUs) from technological and financial perspectives. SSUs are Ultracapacitors with solid electrolytes predicted to have huge application potential ...

  4. Electrical Generation for More-Electric Aircraft using Solid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells This study, completed by...

  5. Geothermal Power Plants — Minimizing Solid Waste and Recovering Minerals

    Broader source: Energy.gov [DOE]

    Although many geothermal power plants generate no appreciable solid waste, the unique characteristics of some geothermal fluids require special attention to handle entrained solid byproducts.

  6. Energetic Materials for EGS Well Stimulation (solids, liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well...

  7. 2014 DOE SOLID-STATE LIGHTING MARKET DEVELOPMENT WORKSHOP | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE SOLID-STATE LIGHTING MARKET DEVELOPMENT WORKSHOP 2014 DOE SOLID-STATE LIGHTING MARKET DEVELOPMENT WORKSHOP DOE SSL Market Development Workshop Agenda.pdf More Documents &...

  8. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  9. National Energy Technology Laboratory Publishes Solid Oxide Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Publishes Solid Oxide Fuel Cell Studies What does this project do? For more information on DOE's efforts to make solid oxide fuel cells an efficient and economically compelling...

  10. Something for Nothing: Solid-Oxide Fuel Cells

    E-Print Network [OSTI]

    Gururangan, Karthik

    2015-01-01

    A. (2001). Materials for fuel cell technologies. Nature,Temperature Solid Oxide Fuel Cell in Hydrocarbon-Airin solid-oxide fuel cell. Letters to Nature,404. Retrieved

  11. Petroleum Engineering 321 Formation Evaluation

    E-Print Network [OSTI]

    measurements to estimate hydrocarbon reserves and petrophysical properties of the formation such as porosity Description: Introduction to well-log interpretation for formation evaluation of hydrocarbon, net pay thickness, water/hydrocarbon saturation, permeability, and saturation-dependent capillary

  12. Solid-State Lighting Manufacturing Workshop

    Broader source: Energy.gov [DOE]

    Nearly 200 lighting industry leaders, chip makers, fixture and component manufacturers, and others gathered in Fairfax, Virginia, on April 21 and 22, 2009, for the first-ever DOE Solid-State...

  13. Layered solid sorbents for carbon dioxide capture

    DOE Patents [OSTI]

    Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

    2014-11-18

    A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

  14. Montana Solid Waste Management Act (Montana)

    Broader source: Energy.gov [DOE]

    It is the public policy of the state to control solid waste management systems to protect the public health and safety and to conserve natural resources whenever possible. The Department of...

  15. Solid Waste as an Energy Source 

    E-Print Network [OSTI]

    Erlandsson, K. I.

    1979-01-01

    The cost history of conventional fuels over the past several years has forced a hard search for alternate energy sources. One alternate energy source that has gained more and more acceptance is solid waste. This is the case particularly...

  16. AW-101 entrained solids - Solubility versus temperature

    SciTech Connect (OSTI)

    GJ Lumetta; RC Lettau; GF Piepel

    2000-03-31

    This report describes the results of a test conducted by Battelle to assess the solubility of the solids entrained in the diluted AW-101 low-activity waste (LAW) sample. BNFL requested Battelle to dilute the AW-1-1 sample using de-ionized water to mimic expected plant operating conditions. BNFL further requested Battelle to assess the solubility of the solids present in the diluted AW-101 sample versus temperature conditions of 30, 40, and 50 C. BNFL requested these tests to assess the composition of the LAW supernatant and solids versus expected plant-operating conditions. The work was conducted according to test plan BNFL-TP-29953-7, Rev. 0, Determination of the Solubility of LAW Entrained Solids. The test went according to plan, with no deviations from the test plan.

  17. Novel phosphors for solid state lighting

    E-Print Network [OSTI]

    Furman, Joshua D

    2010-11-16

    Solid state white light emitting diode lighting devices outperform conventional light sources in terms of lifetime, durability, and lumens per watt. However, the capital contribution is still to high to encourage widespread adoption. Furthermore...

  18. Experimental analysis of municipal solid waste samples 

    E-Print Network [OSTI]

    Mendoza Sanchez, Itza

    2002-01-01

    In the analysis of municipal solid waste consolidation, large-scale devices are usually used to measure the compression and hydraulic conductivity parameters. The use of those devices is justified due to difficulties in probing undisturbed samples...

  19. Geothermal Direct-Use — Minimizing Solid Waste

    Broader source: Energy.gov [DOE]

    Aquaculture and horticulture businesses, and other industries that use geothermal direct-use systems typically don't generate any more solid waste than those that use other energy resources.

  20. Solid State AC Motor Drives - Conservation Perspectives 

    E-Print Network [OSTI]

    Mohan, N.; Ferraro, R. J.

    1982-01-01

    Variable Frequency Solid-State Inverters: can control the speed of ac motors by producing adjustable frequency ac voltage, with an enormous potential for energy conservation in pumps and air handling systems. 3. Other Variable Frequency Drives: include...

  1. Modeling of solid oxide fuel cells

    E-Print Network [OSTI]

    Lee, Won Yong, S.M. Massachusetts Institute of Technology

    2006-01-01

    A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

  2. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  3. Experimental equilibrium structures of solids and gases 

    E-Print Network [OSTI]

    Reilly, Anthony M.

    In the past sixty years, X-ray, neutron and electron dffraction have emerged as the structural techniques of choice in the solid state. However, despite many advances in theory and instrumentation, these diffraction ...

  4. Solid-state diffusion in amorphous zirconolite

    SciTech Connect (OSTI)

    Yang, C.; Dove, M. T.; Trachenko, K.; Zarkadoula, E.; Todorov, I. T.; Geisler, T.; Brazhkin, V. V.

    2014-11-14

    We discuss how structural disorder and amorphization affect solid-state diffusion, and consider zirconolite as a currently important case study. By performing extensive molecular dynamics simulations, we disentangle the effects of amorphization and density, and show that a profound increase of solid-state diffusion takes place as a result of amorphization. Importantly, this can take place at the same density as in the crystal, representing an interesting general insight regarding solid-state diffusion. We find that decreasing the density in the amorphous system increases pre-factors of diffusion constants, but does not change the activation energy in the density range considered. We also find that atomic species in zirconolite are affected differently by amorphization and density change. Our microscopic insights are relevant for understanding how solid-state diffusion changes due to disorder and for building predictive models of operation of materials to be used to encapsulate nuclear waste.

  5. Structural and dielectric properties of erbium doped BiFeO{sub 3}?PbTiO{sub 3} solid solutions

    SciTech Connect (OSTI)

    Vandana,, E-mail: anupinders@gmail.com; Singh, Anupinder, E-mail: anupinders@gmail.com; Singh, Lakhwant, E-mail: anupinders@gmail.com; Kaur, Anumeet, E-mail: anupinders@gmail.com [Multifunctional Materials Laboratory, Department of Physics, Guru Nanak Dev University, Amritsar-143005 (India); Dahyia, Sajjan [Department of Physics, Maharshi Dayanand University, Rohtak-124001 (India); Chatterjee, Ratnamala [Indian Institute of Technology Delhi, Hauz Khas, New Delhi-110016 (India)

    2014-04-24

    Single phase Er substituted at A-site BiFeO{sub 3}?PbTiO{sub 3} solid solutions were synthesized using solid state reaction route. The calcinations at different temperature reveals that the single and pure tetragonal phase formation has been accomplished at 1000°C. The SEM micrographs did not show any distinguishable change in grain size. The dielectric studies established that the dielectric constant decreases and ferroelectric T{sub c} increases with increase in Er.

  6. Solid waste management: a public policy study 

    E-Print Network [OSTI]

    Jayawant, Mandar Prabhatkumar

    1993-01-01

    . Floodplains, surface water, and groundwater: Facilities in floodplains must not restrict the flow of base floods, reduce the temporary water storage capacity of the floodplain, or result in washout of solid waste; dredge and fill material may...SOLID WASTE MANAGEMENT: A PUBLIC POLICY STUDY A Thesis MANDAR PRABHATKUMAR JAYAWANT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1993...

  7. Grating enhanced solid-state laser amplifiers

    DOE Patents [OSTI]

    Erlandson, Alvin C. (Livermore, CA); Britten, Jerald A. (Clayton, CA)

    2010-11-09

    A novel method and apparatus for suppressing ASE and parasitic oscillation modes in a high average power laser is introduced. Such an invention, as disclosed herein, uses diffraction gratings to increase gain, stored energy density, and pumping efficiency of solid-state laser gain media, such as, but not limited to rods, disks and slabs. By coupling predetermined gratings to solid-state gain media, such as crystal or ceramic laser gain media, ASE and parasitic oscillation modes can be effectively suppressed.

  8. Secondary calcium solid electrolyte high temperature battery

    SciTech Connect (OSTI)

    Sammells, A.F.; Schumacher, B.

    1986-01-01

    The authors report on recent work directed towards determining the viability of polycrystalline Ca/sup 2 +/ conducting ..beta..''-alumina solid electrolytes as the basis for a new type of high temperature battery. In this battery system the negative electrode consisted of a calcium-silicon alloy whose redox electro-chemistry was mediated to the calcium conducting solid electrolyte via the use of the molten salt eutectic CaCl/sub 2/ (51.4/sup M//0), CaI/sub 2/ (mp 550/sup 0/C). Both the molten salt and the calcium-alloy negative active material were separated from the positive active material via the Ca/sup 2 +/ conducting polycrystalline solid electrolyte. The positive electrode consisted of a solid-state matrix having a somewhat related crystallographic structure to Ca/sup 2 +/ ..beta..''-alumina, but where a significant fraction of the A1/sup 3 +/ sites located within this solid electrolyte's spinel block were replaced by immobile transition metal species. These species were available for participating in solid-state redox electrochemistry upon electrochemical cell cycling.

  9. A quasimechanism of melt acceleration in the thermal decomposition of crystalline organic solids

    SciTech Connect (OSTI)

    Henson, Bryan F

    2009-01-01

    It has been know for half a century that many crystalline organic solids undergo an acceleration in the rate of thermal decomposition as the melting temperature is approached. This acceleration terminates at the melting point, exhibiting an Arrhenius-like temperature dependence in the faster decomposition rate from the liquid phase. This observation has been modeled previously using various premelting behaviors based on e.g. freezing point depression induced by decomposition products or solvent impurities. These models do not, however, indicate a mechanism for liquid formation and acceleration which is an inherent function of the bulk thermodynamics of the molecule. Here we show that such an inherent thermodynamic mechanism for liquid formation exists in the form of the so-called quasi-liquid layer at the solid surface. We explore a kinetic mechanism which describes the acceleration of rate and is a function of the free energies of sublimation and vaporization. We construct a differential rate law from these thermodynamic free energies and a normalized progress variable. We further construct a reduced variable formulation of the model which is a simple function of the metastable liquid activity below the melting point, and show that it is applicable to the observed melt acceleration in several common organic crystalline solids. A component of the differential rate law, zero order in the progress variable, is shown to be proportional to the thickness of the quasiliquid layer predicted by a recent thermodynamic theory for this phenomenon. This work therefore serves not only to provide new insight into thermal decomposition in a broad class or organic crystalline solids, but also further validates the underlying thermodynamic nature of the phenomenon of liquid formation on the molecular surface at temperatures below the melting point.

  10. Local formation of HArF in solid argon: Low-temperature limit and thermal activation

    E-Print Network [OSTI]

    Lignell, H.; Khriachtchev, L.; Lignell, A.; Räsänen, M.

    2010-01-01

    Räsänen, IR light. The thermal activation of the process wasand R. ?ArHAr? and thermal activation of these processes aretemperature limit and thermal activation H. Lignell, a? L.

  11. Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: In uence of Electrochemical Preparation and

    E-Print Network [OSTI]

    Webb, Lauren J.

    as an anode material for lithium- ion batteries due to its large volumetric and gravimetric energy density (9 electrolyte interphase (SEI) under applied potential, which hampers silicon's performance as a lithium-ion the cell and hindering lithium-ion transfer kinetics. Identi cation of the chemical composition

  12. Molecular Dynamics Simulation of Damage Cascade Formation in Ion Bombarded Solids 

    E-Print Network [OSTI]

    Chen, Di

    2012-10-19

    includes the types of boiling water reactor and pressure water reactor, uranium oxide is used as nuclear fuels, which are surrounded by fuel cladding materials made of Zircaloy. Under normal operation conditions, the fuel center can reach a temperature....46exp[ ( / ) /1.02]M M? ? ? ? (4.2) Where 1M and 2M are mass of the incident and target atom, respectively. 4.3 Results and Discussion Fig. 8 plots the damage creation per Ag atom ( /dV n ) as a function of Ag cluster size n...

  13. Planet Formation with Migration

    E-Print Network [OSTI]

    J. E. Chambers

    2006-10-30

    In the core-accretion model, gas-giant planets form solid cores which then accrete gaseous envelopes. Tidal interactions with disk gas cause a core to undergo inward type-I migration in 10^4 to 10^5 years. Cores must form faster than this to survive. Giant planets clear a gap in the disk and undergo inward type-II migration in migration times exceed typical disk lifetimes if viscous accretion occurs mainly in the surface layers of disks. Low turbulent viscosities near the midplane may allow planetesimals to form by coagulation of dust grains. The radius r of such planetesimals is unknown. If rmigration timescale and cores will survive. Migration is substantial in most cases, leading to a wide range of planetary orbits, consistent with the observed variety of extrasolar systems. When r is of order 100m and midplane alpha is of order 3 times 10^-5, giant planets similar to those in the Solar System can form.

  14. Solid electrolyte-electrode system for an electrochemical cell

    DOE Patents [OSTI]

    Tuller, Harry L. (Wellesley, MA); Kramer, Steve A. (Somerville, MA); Spears, Marlene A. (Woburn, MA)

    1995-01-01

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is also provided.

  15. Harmonic Volumetric Mapping for Solid Modeling Applications Xiaohu Guo

    E-Print Network [OSTI]

    Li, Xin "Shane"

    Harmonic Volumetric Mapping for Solid Modeling Applications Xin Li SBU Xiaohu Guo UT Dallas Hongyu volumetric mapping from a solid polycube model(a) to the solid Buddha model(b). (c) is the color with corresponding cross-sections in (f) and (h), respectively. Abstract Harmonic volumetric mapping for two solid

  16. Solid electrolyte-electrode system for an electrochemical cell

    DOE Patents [OSTI]

    Tuller, H.L.; Kramer, S.A.; Spears, M.A.

    1995-04-04

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is also provided. 17 figures.

  17. DUST FORMATION IN MACRONOVAE

    SciTech Connect (OSTI)

    Takami, Hajime; Ioka, Kunihito [Institute of Particle and Nuclear Studies, KEK, 1-1, Oho, Tsukuba 305-0801 (Japan); Nozawa, Takaya, E-mail: takami@post.kek.jp, E-mail: kunihito.ioka@kek.jp, E-mail: takaya.nozawa@nao.ac.jp [National Astronomical Observatory of Japan, 2-21-1, Osawa, Mitaka, Tokyo 181-8588 (Japan)

    2014-07-01

    We examine dust formation in macronovae (as known as kilonovae), which are the bright ejecta of neutron star binary mergers and one of the leading sites of r-process nucleosynthesis. In light of information about the first macronova candidate associated with GRB 130603B, we find that dust grains of r-process elements have difficulty forming because of the low number density of the r-process atoms, while carbon or elements lighter than iron can condense into dust if they are abundant. Dust grains absorb emission from ejecta with an opacity even greater than that of the r-process elements, and re-emit photons at infrared wavelengths. Such dust emission can potentially account for macronovae without r-process nucleosynthesis as an alternative model. This dust scenario predicts a spectrum with fewer features than the r-process model and day-scale optical-to-ultraviolet emission.

  18. Pulse Jet Mixing Tests With Noncohesive Solids

    SciTech Connect (OSTI)

    Meyer, Perry A.; Bamberger, Judith A.; Enderlin, Carl W.; Fort, James A.; Wells, Beric E.; Sundaram, S. K.; Scott, Paul A.; Minette, Michael J.; Smith, Gary L.; Burns, Carolyn A.; Greenwood, Margaret S.; Morgen, Gerald P.; Baer, Ellen BK; Snyder, Sandra F.; White, Michael; Piepel, Gregory F.; Amidan, Brett G.; Heredia-Langner, Alejandro; Bailey, Sharon A.; Bower, John C.; Denslow, Kayte M.; Eakin, David E.; Elmore, Monte R.; Gauglitz, Phillip A.; Guzman, Anthony D.; Hatchell, Brian K.; Hopkins, Derek F.; Hurley, David E.; Johnson, Michael D.; Kirihara, Leslie J.; Lawler, Bruce D.; Loveland, Jesse S.; Mullen, O Dennis; Pekour, Mikhail S.; Peters, Timothy J.; Robinson, Peter J.; Russcher, Michael S.; Sande, Susan; Santoso, Christian; Shoemaker, Steven V.; Silva, Steve M.; Smith, Devin E.; Su, Yin-Fong; Toth, James J.; Wiberg, John D.; Yu, Xiao-Ying; Zuljevic, Nino

    2009-05-11

    This report summarizes results from pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid conducted during FY 2007 and 2008 to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant (WTP). Tests were conducted at three geometric scales using noncohesive simulants. The test data were used to independently develop mixing models that can be used to predict full-scale WTP vessel performance and to rate current WTP mixing system designs against two specific performance requirements. One requirement is to ensure that all solids have been disturbed during the mixing action, which is important to release gas from the solids. The second requirement is to maintain a suspended solids concentration below 20 weight percent at the pump inlet. The models predict the height to which solids will be lifted by the PJM action, and the minimum velocity needed to ensure all solids have been lifted from the floor. From the cloud height estimate we can calculate the concentration of solids at the pump inlet. The velocity needed to lift the solids is slightly more demanding than "disturbing" the solids, and is used as a surrogate for this metric. We applied the models to assess WTP mixing vessel performance with respect to the two perform¬ance requirements. Each mixing vessel was evaluated against these two criteria for two defined waste conditions. One of the wastes was defined by design limits and one was derived from Hanford waste characterization reports. The assessment predicts that three vessel types will satisfy the design criteria for all conditions evaluated. Seven vessel types will not satisfy the performance criteria used for any of the conditions evaluated. The remaining three vessel types provide varying assessments when the different particle characteristics are evaluated. The assessment predicts that three vessel types will satisfy the design criteria for all conditions evaluated. Seven vessel types will not satisfy the performance criteria used for any of the conditions evaluated. The remaining three vessel types provide varying assessments when the different particle characteristics are evaluated. The HLP-022 vessel was also evaluated using 12 m/s pulse jet velocity with 6-in. nozzles, and this design also did not satisfy the criteria for all of the conditions evaluated.

  19. Municipal Solid WasteMunicipal Solid Waste Landfills In CitiesLandfills In Cities

    E-Print Network [OSTI]

    Columbia University

    -Section of Closure #12;Schedule III ­ Gazette 19 & 21 Specifications for Landfill Cover Daily cover of 10cm of soil;Post Closure Care-Requirements The Post-closure care of landfill site shall be conducted for at leastMunicipal Solid WasteMunicipal Solid Waste Landfills In CitiesLandfills In Cities Arun

  20. Efficient and Color-Tunable Oxyfluoride Solid Solution Phosphors for Solid-State White Lighting

    SciTech Connect (OSTI)

    Im, Won Bin; George, Nathan; Kurzman, Joshua; Brinkley, Stuart; Mikhailovsky, Alexander; Hu, Jerry; Chmelka, Bradley F.; DenBaars, Steven P.; Seshadri, Ram (UCSB)

    2012-09-06

    A solid solution strategy helps increase the efficiency of Ce{sup 3+} oxyfluoride phosphors for solid-state white lighting. The use of a phosphor-capping architecture provides additional light extraction. The accompanying image displays electroluminescence spectra from a 434-nm InGaN LED phosphor that has been capped with the oxyfluoride phosphor.

  1. Solid-State Microcellular Acrylonitrile-Butadiene-Styrene Foams Solid-StateMicrocellular

    E-Print Network [OSTI]

    Hochberg, Michael

    Solid-State Microcellular Acrylonitrile-Butadiene-Styrene Foams Solid-StateMicrocellular Acrylonitrile-Butadiene-Styrene Foams Ross E. Murray, John E. Weller and Vipin Kumar* Department of Mechanical. INTRODUCTION ABS (Acrylonitrile-butadiene-styrene)has grown to become one of the most widely used thermoplastic

  2. Coordinated garbage collection for raid array of solid state disks

    DOE Patents [OSTI]

    Dillow, David A; Ki, Youngjae; Oral, Hakki S; Shipman, Galen M; Wang, Feiyi

    2014-04-29

    An optimized redundant array of solid state devices may include an array of one or more optimized solid-state devices and a controller coupled to the solid-state devices for managing the solid-state devices. The controller may be configured to globally coordinate the garbage collection activities of each of said optimized solid-state devices, for instance, to minimize the degraded performance time and increase the optimal performance time of the entire array of devices.

  3. Solid materials for removing arsenic and method thereof

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2008-07-01

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  4. Solid materials for removing arsenic and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2010-09-28

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  5. The effect of water on tritium release behavior from solid breeder candidates

    SciTech Connect (OSTI)

    Suematsu, K.; Nishikawa, M.; Fukada, S.; Kinjyo, T.; Koyama, T.; Yamashita, N. [Graduate School of Engineering Science, Kyushu Univ., Fukuoka, 812-8581 (Japan)

    2008-07-15

    The authors have made a tritium release model to represent the release behavior of bred tritium from solid breeder materials using a series of studies. It has been observed that a large amount of adsorbed water and water produced by water formation reaction are released to the purge gas even though dry purge gas with hydrogen is introduced to solid breeder materials. According to our tritium release model, the presence of water in the purge gas and surface water on the material has a large effect on the tritium release behavior. In this study, the authors quantified the amount of adsorbed water and the capacity of the water formation reaction for various solid breeder materials (Li{sub 2}TiO{sub 3}, Li{sub 4}SiO{sub 4}, Li{sub 2}ZrO{sub 3}, LiAlO{sub 2}). The effect of surface water on the chemical form of tritium released from the LiAlO{sub 2} blanket is also discussed in this study. (authors)

  6. Crystal Structure Representations for Machine Learning Models of Formation Energies

    E-Print Network [OSTI]

    Faber, Felix; von Lilienfeld, O Anatole; Armiento, Rickard

    2015-01-01

    We introduce and evaluate a set of feature vector representations of crystal structures for machine learning (ML) models of formation energies of solids. ML models of atomization energies of organic molecules have been successful using a Coulomb matrix representation of the molecule. We consider three ways to generalize such representations to periodic systems: (i) a matrix where each element is related to the Ewald sum of the electrostatic interaction between two different atoms in the unit cell repeated over the lattice; (ii) an extended Coulomb-like matrix that takes into account a number of neighboring unit cells; and (iii) an Ansatz that mimics the periodicity and the basic features of the elements in the Ewald sum matrix by using a sine function of the crystal coordinates of the atoms. The representations are compared for a Laplacian kernel with Manhattan norm, trained to reproduce formation energies using a data set of 3938 crystal structures obtained from the Materials Project. For training sets consi...

  7. REMOVAL OF SOLIDS FROM HIGHLY ENRICHED URANIUM SOLUTIONS USING THE H-CANYON CENTRIFUGE

    SciTech Connect (OSTI)

    Rudisill, T; Fernando Fondeur, F

    2009-01-15

    Prior to the dissolution of Pu-containing materials in HB-Line, highly enriched uranium (HEU) solutions stored in Tanks 11.1 and 12.2 of H-Canyon must be transferred to provide storage space. The proposed plan is to centrifuge the solutions to remove solids which may present downstream criticality concerns or cause operational problems with the 1st Cycle solvent extraction due to the formation of stable emulsions. An evaluation of the efficiency of the H-Canyon centrifuge concluded that a sufficient amount (> 90%) of the solids in the Tank 11.1 and 12.2 solutions will be removed to prevent any problems. We based this conclusion on the particle size distribution of the solids isolated from samples of the solutions and the calculation of particle settling times in the centrifuge. The particle size distributions were calculated from images generated by scanning electron microscopy (SEM). The mean particle diameters for the distributions were 1-3 {micro}m. A significant fraction (30-50%) of the particles had diameters which were < 1 {micro}m; however, the mass of these solids is insignificant (< 1% of the total solids mass) when compared to particles with larger diameters. It is also probable that the number of submicron particles was overestimated by the software used to generate the particle distribution due to the morphology of the filter paper used to isolate the solids. The settling times calculated for the H-Canyon centrifuge showed that particles with diameters less than 1 to 0.5 {micro}m will not have sufficient time to settle. For this reason, we recommend the use of a gelatin strike to coagulate the submicron particles and facilitate their removal from the solution; although we have no experimental basis to estimate the level of improvement. Incomplete removal of particles with diameters < 1 {micro}m should not cause problems during purification of the HEU in the 1st Cycle solvent extraction. Particles with diameters > 1 {micro}m account for > 99% of the solid mass and will be efficiently removed by the centrifuge; therefore, the formation of emulsions during solvent extraction operations is not an issue. Under the current processing plan, the solutions from Tanks 11.1 and 12.2 will be transferred to the enriched uranium storage (EUS) tank following centrifugation. The solution from Tanks 11.1 and 12.2 may remain in the EUS tank for an extended time prior to purification. The effects of extended storage on the solution were not evaluated as part of this study.

  8. Method for silicon nitride precursor solids recovery

    DOE Patents [OSTI]

    Crosbie, Gary M. (Dearborn, MI); Predmesky, Ronald L. (Livonia, MI); Nicholson, John M. (Wayne, MI)

    1992-12-15

    Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

  9. Apparatus for silicon nitride precursor solids recovery

    DOE Patents [OSTI]

    Crosbie, Gary M. (Dearborn, MI); Predmesky, Ronald L. (Livonia, MI); Nicholson, John M. (Wayne, MI)

    1995-04-04

    Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

  10. Solid Waste Assurance Program Implementation Plan

    SciTech Connect (OSTI)

    Irons, L.G.

    1995-06-19

    On June 6, 1995, a waiver to Hanford Site Solid Waste Acceptance Criteria, was approved by the US Department of Energy Richland Operations Office (RL) to replace the low-level, mixed, and transuranic (TRU) generator assessment programs with the Solid Waste Assurance Program (SWAP). This is associated with a waiver that was approved on March 16, 1995 to replace the Storage/Disposal Approval Record (SDAR) requirements with the Waste Specification System (WSS). This implementation plan and the SWAP applies to Solid Waste Disposal (SWD) functions, facilities, and personnel who perform waste acceptance, verification, receipt, and management functions of dangerous, radioactive, and mixed waste from on- and off-site generators who ship to or within the Hanford Site for treatment, storage, and/or disposal (TSD) at SWD TSD facilities.

  11. Solid waste 30-year volume summary

    SciTech Connect (OSTI)

    Valero, O.J.; Armacost, L.L.; DeForest, T.J.; Templeton, K.J.; Williams, N.C.

    1994-06-01

    A 30-year forecast of the solid waste volumes to be generated or received at the US Department of Energy Hanford Site is described in this report. The volumes described are low-level mixed waste (LLMW) and transuranic/transuranic mixed (TRU/TRUM) waste that will require treatment, storage, and disposal at Hanford`s Solid Waste Operations Complex (SWOC) during the 30-year period from FY 1994 through FY 2023. The data used to complete this document were collected from onsite and offsite waste generators who currently, or are planning to, ship solid wastes to the Hanford Site. An analysis of the data suggests that over 300,000 m{sup 3} of LLMW and TRU/TRUM waste will be managed at Hanford`s SWOC over the next 30 years. An extensive effort was made this year to collect this information. The 1993 solid waste forecast was used as a starting point, which identified approximately 100,000 m{sup 3} of LLMW and TRU/TRUM waste to be sent to the SWOC. After analyzing the forecast waste volume, it was determined that additional waste was expected from the tank waste remediation system (TWRS), onsite decontamination and decommissioning (D&D) activities, and onsite remedial action (RA) activities. Data presented in this report establish a starting point for solid waste management planning. It is recognized that forecast estimates will vary (typically increasing) as facility planning and missions continue to change and become better defined, but the information presented still provides useful insight into Hanford`s future solid waste management requirements.

  12. Pulse Jet Mixing Tests With Noncohesive Solids

    SciTech Connect (OSTI)

    Meyer, Perry A.; Bamberger, Judith A.; Enderlin, Carl W.; Fort, James A.; Wells, Beric E.; Sundaram, S. K.; Scott, Paul A.; Minette, Michael J.; Smith, Gary L.; Burns, Carolyn A.; Greenwood, Margaret S.; Morgen, Gerald P.; Baer, Ellen BK; Snyder, Sandra F.; White, Michael K.; Piepel, Gregory F.; Amidan, Brett G.; Heredia-Langner, Alejandro

    2012-02-17

    This report summarizes results from pulse jet mixing (PJM) tests with noncohesive solids in Newtonian liquid. The tests were conducted during FY 2007 and 2008 to support the design of mixing systems for the Hanford Waste Treatment and Immobilization Plant (WTP). Tests were conducted at three geometric scales using noncohesive simulants, and the test data were used to develop models predicting two measures of mixing performance for full-scale WTP vessels. The models predict the cloud height (the height to which solids will be lifted by the PJM action) and the critical suspension velocity (the minimum velocity needed to ensure all solids are suspended off the floor, though not fully mixed). From the cloud height, the concentration of solids at the pump inlet can be estimated. The predicted critical suspension velocity for lifting all solids is not precisely the same as the mixing requirement for 'disturbing' a sufficient volume of solids, but the values will be similar and closely related. These predictive models were successfully benchmarked against larger scale tests and compared well with results from computational fluid dynamics simulations. The application of the models to assess mixing in WTP vessels is illustrated in examples for 13 distinct designs and selected operational conditions. The values selected for these examples are not final; thus, the estimates of performance should not be interpreted as final conclusions of design adequacy or inadequacy. However, this work does reveal that several vessels may require adjustments to design, operating features, or waste feed properties to ensure confidence in operation. The models described in this report will prove to be valuable engineering tools to evaluate options as designs are finalized for the WTP. Revision 1 refines data sets used for model development and summarizes models developed since the completion of Revision 0.

  13. Hanford Site Solid Waste Acceptance Criteria

    SciTech Connect (OSTI)

    Not Available

    1993-11-17

    This manual defines the Hanford Site radioactive, hazardous, and sanitary solid waste acceptance criteria. Criteria in the manual represent a guide for meeting state and federal regulations; DOE Orders; Hanford Site requirements; and other rules, regulations, guidelines, and standards as they apply to acceptance of radioactive and hazardous solid waste at the Hanford Site. It is not the intent of this manual to be all inclusive of the regulations; rather, it is intended that the manual provide the waste generator with only the requirements that waste must meet in order to be accepted at Hanford Site TSD facilities.

  14. Tubular solid oxide fuel cell demonstration activities

    SciTech Connect (OSTI)

    Ray, E.R.; Veyo, S.E.

    1995-12-31

    This reports on a solid oxide fuel cell demonstration program in which utilities are provided fully integrated, automatically controlled, packaged solid oxide fuel cell power generation systems. These field units serve to demonstrate to customers first hand the beneficial attributes of the SOFC, to expose deficiencies through experience in order to guide continued development, and to garner real world feedback and data concerning not only cell and stack parameters, but also transportation, installation, permitting and licensing, start-up and shutdown, system alarming, fault detection, fault response, and operator interaction.

  15. Solid-State Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo.Hydrogen4EnergySolid State LightingDepartment ofSolid-State

  16. A Molecular Dynamics Study of Chemical Reactions of Solid Pentaerythritol Tetranitrate at Extreme Conditions

    SciTech Connect (OSTI)

    Wu, C J; Manaa, M R; Fried, L E

    2006-05-30

    We have carried out density functional based tight binding (DFTB) molecular dynamics (MD) simulation to study energetic reactions of solid Pentaerythritol Tetranitrate (PETN) at conditions approximating the Chapman-Jouguet (CJ) detonation state. We found that the initial decomposition of PETN molecular solid is characterized by uni-molecular dissociation of the NO{sub 2}groups. Interestingly, energy release from this powerful high explosive was found to proceed in several stages. The large portion of early stage energy release was found to be associated with the formation of H{sub 2}O molecules within a few picoseconds of reaction. It took nearly four times as long for majority of CO{sub 2} products to form, accompanied by a slow oscillatory conversion between CO and CO{sub 2}. The production of N{sub 2} starts after NO{sub 2} loses its oxygen atoms to hydrogen or carbon atoms to form H{sub 2}O or CO. We identified many intermediate species that emerge and contribute to reaction kinetics, and compared our simulation with a thermo-chemical equilibrium calculation. In addition, a detailed chemical kinetics of formation of H{sub 2}O, CO, and CO{sub 2} were developed. Rate constants of formations of H{sub 2}O, CO{sub 2} and N{sub 2} were reported.

  17. Energy aspects of solid waste management: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The Eighteenth Annual Illinois Energy Conference entitled Energy Aspects of Solid Waste Management'' was held in Chicago, Illinois on October 29--30, 1990. The conference program was developed by a planning committee that drew upon Illinois energy and environmental specialists from the major sectors including energy industries, environmental organizations, research universities, utility companies, federal, state and local government agencies, and public interest groups. Within this framework, the committee identified a number of key topic areas surrounding solid waste management in Illinois which were the focus of the conference. These issues included: review of the main components of the solid waste cycle in the Midwest and what the relative impact of waste reduction, recycling, incineration and land disposal might be on Illinois' and the Midwest's solid waste management program. Investigation of special programs in the Midwest dealing with sewage sludge, combustion residuals and medical/infectious wastes. Review of the status of existing landfills in Illinois and the Midwest and an examination of the current plans for siting of new land disposal systems. Review of the status of incinerators and waste-to-energy systems in Illinois and the Midwest, as well as an update on activities to maximize methane production from landfills in the Midwest.

  18. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  19. Solid composite electrolytes for lithium batteries

    DOE Patents [OSTI]

    Kumar, Binod (Dayton, OH); Scanlon, Jr., Lawrence G. (Fairborn, OH)

    2000-01-01

    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a ceramic-ceramic composite electrolyte is provided containing lithium nitride and lithium phosphate. The ceramic-ceramic composite is also preferably annealed and exhibits an activation energy of about 0.1 eV.

  20. Energy aspects of solid waste management: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    The Eighteenth Annual Illinois Energy Conference entitled ``Energy Aspects of Solid Waste Management`` was held in Chicago, Illinois on October 29--30, 1990. The conference program was developed by a planning committee that drew upon Illinois energy and environmental specialists from the major sectors including energy industries, environmental organizations, research universities, utility companies, federal, state and local government agencies, and public interest groups. Within this framework, the committee identified a number of key topic areas surrounding solid waste management in Illinois which were the focus of the conference. These issues included: review of the main components of the solid waste cycle in the Midwest and what the relative impact of waste reduction, recycling, incineration and land disposal might be on Illinois` and the Midwest`s solid waste management program. Investigation of special programs in the Midwest dealing with sewage sludge, combustion residuals and medical/infectious wastes. Review of the status of existing landfills in Illinois and the Midwest and an examination of the current plans for siting of new land disposal systems. Review of the status of incinerators and waste-to-energy systems in Illinois and the Midwest, as well as an update on activities to maximize methane production from landfills in the Midwest.

  1. Thermodynamic modelling of solid solutions JIBAMITRA GANGULY

    E-Print Network [OSTI]

    Ganguly, Jibamitra

    with the phase equilibrium constraints. The latter are calculated from the internally consistent thermochemical will summarise the general concepts of thermodynamic solution theory and a number of macroscopic models that have were originally developed for polymer and liquid solutions, but are also applicable to oxide and solid

  2. Solid polymer MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Pleasant Hill, CA)

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  3. Solid oxide MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  4. Iron-stabilized nanocrystalline ZrO{sub 2} solid solutions: Synthesis by combustion and thermal stability

    SciTech Connect (OSTI)

    Legorreta Garcia, Felipe; Resende, Valdirene Gonzaga de; De Grave, Eddy; Peigney, Alain; Barnabe, Antoine; Laurent, Christophe

    2009-06-03

    The synthesis of Fe{sup 3+}-stabilized zirconia by the nitrate/urea combustion route was investigated. Using several characterization techniques, including X-ray diffraction, field-emission-gun scanning electron microscopy and notably Moessbauer spectroscopy, it was possible to determine the appropriate amount of urea that allows to obtain a totally stabilized Zr{sub 0.9}Fe{sub 0.1}O{sub 1.95} solid solution. The nanocrystalline zirconia solid solution is mostly tetragonal, but the presence of the cubic phase could not be ruled out. An in-depth study of the thermal stability in air showed that the Fe{sup 3+} solubility in the stabilized solid solution starts to decrease at about 875 deg. C which results in the formation of hematite (possibly containing some Zr{sup 4+}) at the surface of the zirconia grains and further provokes the progressive transformation into the monoclinic zirconia phase.

  5. Charge transfer kinetics at the solid–solid interface in porous electrodes

    E-Print Network [OSTI]

    Bai, Peng

    Interfacial charge transfer is widely assumed to obey the Butler–Volmer kinetics. For certain liquid–solid interfaces, the Marcus–Hush–Chidsey theory is more accurate and predictive, but it has not been applied to porous ...

  6. Electrophoretic Deposition of Highly Efficient Phosphors for White Solid State Lighting using near UV-Emitting LEDs /

    E-Print Network [OSTI]

    Choi, Jae Ik

    2014-01-01

    for near-UV LED solid state lighting,” Solid State Sci.for near-UV LED solid state lighting,” ECS J. Solid Statefor Near-UV LED Solid State Lighting” ECS Journal of Solid

  7. Lochon Catalyzed D-D Fusion in Deuterated Palladium in the Solid State

    E-Print Network [OSTI]

    K. P. Sinha; A. Meulenberg

    2007-05-04

    Lochons (local charged bosons or local electron pairs) can form on D+ to give D- (bosonic ions) in Palladium Deuteride in the solid state. Such entities will occur at special sites or in linear channel owing to strong electron-phonon interaction or due to potential inversion on metallic electrodes. These lochons can catalyze D- - D+ fusion as a consequence of internal conversion leading to the formation of He-4 plus production of energy (Q=23.8 MeV) which is carried by the alpha particle and the ejected electron-pair. The reaction rate for this fusion process is calculated.

  8. Examining solid waste management issues in the City of Bryan 

    E-Print Network [OSTI]

    Arekere, Dhananjaya Marigowda

    2006-04-12

    Economic aspects of household recycling behavior and attitudes in City of Bryan are examined to improve solid waste management policies in the city. Using survey data collected by mail and personal interviews, residentsÂ? attitudes towards solid...

  9. Country report Municipal solid waste composition determination supporting

    E-Print Network [OSTI]

    Columbia University

    Country report Municipal solid waste composition determination supporting the integrated solid waste management system in the island of Crete E. Gidarakos *, G. Havas, P. Ntzamilis Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University

  10. Quantitative analysis of perivascular antibody distribution in solid tumors

    E-Print Network [OSTI]

    Rhoden, John J. (John Joseph)

    2013-01-01

    Monoclonal antibodies and proteins derived from them are an emerging class of anticancer therapeutics that have shown efficacy in a range of blood and solid tumors. Antibodies targeting solid tumors face considerable ...

  11. Heat Pump Water Heater using Solid-State Energy Converters |...

    Energy Savers [EERE]

    Heat Pump Water Heater using Solid-State Energy Converters Heat Pump Water Heater using Solid-State Energy Converters Sheetak will work on developing a full scale prototype of its...

  12. Louisiana Solid Waste Management and Resource Recovery Law (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Environmental Quality manages solid waste for the state of Louisiana under the authority of the Solid Waste Management and Resource Recover Law. The Department makes...

  13. Systems and methods for monitoring a solid-liquid interface

    DOE Patents [OSTI]

    Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

    2013-06-11

    Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

  14. Lithium-ion batteries having conformal solid electrolyte layers

    DOE Patents [OSTI]

    Kim, Gi-Heon; Jung, Yoon Seok

    2014-05-27

    Hybrid solid-liquid electrolyte lithium-ion battery devices are disclosed. Certain devices comprise anodes and cathodes conformally coated with an electron insulating and lithium ion conductive solid electrolyte layer.

  15. Solid State Lighting: GATEWAY and CALiPER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Laboratory Marc.Ledbetter@pnnl.gov 503.417.7557 April 3, 2013 Solid State Lighting: GATEWAY & CALiPER Solid State Lighting: GATEWAY & CALiPER 2 | Building Technologies...

  16. DOE Releases Latest Report on Energy Savings Forecast of Solid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Latest Report on Energy Savings Forecast of Solid-State Lighting DOE Releases Latest Report on Energy Savings Forecast of Solid-State Lighting September 12, 2014 - 2:06pm Addthis...

  17. Aluminum Reactions and Problems in Municipal Solid Waste Landfills

    E-Print Network [OSTI]

    problematic for landfill operations by generating undesirable heat, liquid leachate, and gases reactions. Another source of water in a MSW landfill is leachate recirculation, which is not recommended: Solid wastes; Aluminum; Chemicals; Waste disposal; Landfills. Author keywords: Solid waste; Leachate

  18. An overview of the sustainability of solid waste management at military installations

    E-Print Network [OSTI]

    Borglin, S.

    2010-01-01

    Developing Integrated Solid Waste Management Plans at ArmyFact Sheet on Solid Waste Management practices. Department2002). Handbook of Solid Waste Management. New York, McGraw

  19. Review and Status of Solid Waste Management Practices in Multan, Pakistan

    E-Print Network [OSTI]

    Shoaib, Muhammad; Mirza, Umar Karim; Sarwar, Muhammad Avais

    2006-01-01

    Center. (2004). Solid waste management study, Multan.and Status of Solid Waste Management Practices in Multan,problems related to solid waste management in Multan City.

  20. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    James, "Study of solid electrolyte polarization by a complexThe NO 2 response of solid electrolyte sensors made usingTechnologies using Solid Electrolytes in Measuring Gas

  1. Solid lithium ion conducting electrolytes and methods of preparation

    DOE Patents [OSTI]

    Narula, Chaitanya K; Daniel, Claus

    2013-05-28

    A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

  2. Solid-State Lighting (SSL) Manufacturing Workshops Report

    SciTech Connect (OSTI)

    none,

    2009-10-01

    The final report from the U.S. Department of Energy 2009 Solid-State Lighting Manufacturing Workshops.

  3. Treating tar sands formations with karsted zones

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX)

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  4. Management of municipal solid wastes in Italy by Grazia Leonzioa

    E-Print Network [OSTI]

    Columbia University

    1 Management of municipal solid wastes in Italy by Grazia Leonzioa and N.J. Themelisb regions in the management of municipal solid wastes the view is rather heterogeneous. Only three regions contributes little to the management of municipal solid waste, in comparison to the regions of group 1

  5. Municipal solid waste characteristics and management in Allahabad, India

    E-Print Network [OSTI]

    Columbia University

    Municipal solid waste characteristics and management in Allahabad, India Mufeed Sharholy a , Kafeel parameters of the municipal solid waste management (MSWM) problem such as the generation rate of MSW and rise in community living standard accelerates the generation rate of muni- cipal solid waste (MSW

  6. Sustainable Decentralized Model for Solid Waste Management in Urban India

    E-Print Network [OSTI]

    Columbia University

    Sustainable Decentralized Model for Solid Waste Management in Urban India Hita Unnikrishnan, Brunda the sustenance of a decentralized solid waste management system in urban India. Towards this end, two a national legislation ­ the Municipal Solid Waste (Management and Handling) rules, 2000 (Ministry

  7. 2014 Course Description Solid Waste Engineering -CE 477

    E-Print Network [OSTI]

    Barlaz, Morton A.

    on course web site http://people.engr.ncsu.edu/barlaz/ Solid Waste Technology & Management by Christensen et al (eBook available through NCSU libraries) Solid waste management must be addressed by virtually aspects of municipal solid waste (MSW) management including refuse generation, source reduction

  8. MARKET-BASED APPROACHES TO SOLID WASTE MANAGEMENT

    E-Print Network [OSTI]

    Bateman, Ian J.

    MARKET-BASED APPROACHES TO SOLID WASTE MANAGEMENT by DAVID PEARCE and R. KERRY TURNER CSERGE Working Paper WM 92-02 #12;MARKET-BASED APPROACHES TO SOLID WASTE MANAGEMENT by DAVID PEARCE and R. KERRY permits. #12;1 1. INTRODUCTION: WASTE MANAGEMENT FAILURES Rational decision making about solid waste

  9. Blue Solid-State Photoluminescence and Electroluminescence from Novel

    E-Print Network [OSTI]

    Myrick, Michael Lenn

    Blue Solid-State Photoluminescence and Electroluminescence from Novel Poly copolymers give rise to efficient ( ) 0.16-0.76) blue solid-state emission (max ) 422-443 nm) which can-PPE (max 500-520 nm). The effective and blue-shifted solid-state emission is a result of disrupting

  10. Solid low-level radioactive waste radiation stability studies 

    E-Print Network [OSTI]

    Williams, Arnold Andre?

    1989-01-01

    MANAGEMENT . . . Historical background Characteristics of radioactive wastes Classification of radioactive wastes Disposal methodology and criteria Handling and storage of radioactive wastes SOLID RADIOACTIVE WASTES Historical background... Characteristics of the solidified wastes Storage and handling of solid radioactive wastes Shipment of solid radioactive wastes Solidification of waste solutions MATERIALS AND METHODS Ion-exchange methods. High integrity containers (HIC). . tv tx 15 15...

  11. Ris National Laboratory Fuel Cells and Solid State Chemistry Department

    E-Print Network [OSTI]

    Risø National Laboratory Postprint Fuel Cells and Solid State Chemistry Department Year 2007 Paper Højgaard Jensen1, Jørgen B. Bilde-Sørensen3, Mogens Mogensen1 1Fuel Cells and Solid State Chemistry-Sørensen3 , Mogens Mogensen1 1 Fuel Cells and Solid State Chemistry Department, Risø National Laboratory

  12. COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS

    E-Print Network [OSTI]

    COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS Ugur Pasaogullari and Chao-dimensional model has been developed to simulate solid oxide fuel cells (SOFC). The model fully couples current density operation. INTRODUCTION Solid oxide fuel cells (SOFC) are among possible candidates

  13. Review article Components manufacturing for solid oxide fuel cells

    E-Print Network [OSTI]

    Gleixner, Stacy

    of solid oxide fuel cell (SOFC) components is given and the fabrication techniques of ceramic components Elsevier Science B.V. All rights reserved. Keywords: Solid oxide fuel cell (SOFC); Components manufacturingReview article Components manufacturing for solid oxide fuel cells F. Tietz *, H.-P. Buchkremer, D

  14. A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts

    E-Print Network [OSTI]

    RESEARCH HIGHLIGHTS A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts From fuels to renewable energy sources. Solid oxide fuel cells (SOFCs) have enormous potential in this area A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts Rob Usiskin In partnership

  15. Solid Oxide Fuel Cell: Perspective of Dynamic Modeling and Control

    E-Print Network [OSTI]

    Huang, Biao

    Solid Oxide Fuel Cell: Perspective of Dynamic Modeling and Control Biao Huang Yutong Qi Monjur: This paper presents a review of state-of-the-art solid oxide fuel cells (SOFC), from perspective of dynamic. Keywords: Solid Oxide Fuel Cell, Control Relevant Model, Model Predictive Control 1. INTRODUCTION Today

  16. Molybdenum Dioxide As A Solid Oxide Fuel Cell Anodic Catalyst

    E-Print Network [OSTI]

    Collins, Gary S.

    Molybdenum Dioxide As A Solid Oxide Fuel Cell Anodic Catalyst Jay Thunstrom, Su Ha, Oscar Flores are being developed. One of the most auspicious and the topic presented here is the solid oxide fuel cell hydrocarbons and have great resistance to poisoning. Solid Oxide Fuel Cell Operation Three stages exist

  17. Composite Solid Polymer Electrolytes Based on Pluronics: Does Ordering Matter?

    E-Print Network [OSTI]

    Khan, Saad A.

    Composite Solid Polymer Electrolytes Based on Pluronics: Does Ordering Matter? Lyudmila MVised Manuscript ReceiVed October 5, 2007 Composite solids polymer electrolytes (SPEs) based on Pluronic block One of the modern trends in development of solid polymer electrolytes (SPEs) based on "salt

  18. Use-driven concept formation

    E-Print Network [OSTI]

    Roberts, Jennifer M. (Jennifer Marie)

    2010-01-01

    When faced with a complex task, humans often identify domain-specific concepts that make the task more tractable. In this thesis, I investigate the formation of domain-specific concepts of this sort. I propose a set of ...

  19. Brown dwarf formation Gilles Chabrier

    E-Print Network [OSTI]

    Joergens, Viki

    : not observed ! Constraints on BD formation/ejection by disk instability: magnetic field No B (pure hydro accretion - Collapse of a cloud -> starts forming small N-body clusters of small (~10-3 Msol

  20. Cross Domain Mathematical Concept Formation 

    E-Print Network [OSTI]

    Steel, Graham; Colton, Simon; Bundy, Alan; Walsh, Toby

    2000-01-01

    Many interesting concepts in mathematics are essentially "cross-domain" in nature, relating objects from more than one area of mathematics, e.g. prime order groups. These concepts are often vital to the formation of a ...

  1. Radiation Damage in Polarized Ammonia Solids

    E-Print Network [OSTI]

    K. Slifer

    2007-11-28

    Solid NH3 and ND3 provide a highly polarizable, radiation resistant source of polarized protons and deuterons and have been used extensively in high luminosity experiments investigating the spin structure of the nucleon. Over the past twenty years, the UVA polarized target group has been instrumental in producing and polarizing much of the material used in these studies, and many practical considerations have been learned in this time. In this discussion, we analyze the polarization performance of the solid ammonia targets used during the recent JLab Eg4 run. Topics include the rate of polarization decay with accumulated charge, the annealing procedure for radiation damaged targets to recover polarization, and the radiation induced change in optimum microwave frequency used to polarize the sample. We also discuss the success we have had in implementing frequency modulation of the polarizing microwave frequency.

  2. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

    1999-01-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  3. Generator configuration for solid oxide fuel cells

    DOE Patents [OSTI]

    Reichner, Philip (Plum Boro, PA)

    1989-01-01

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  4. Basic properties of coals and other solids

    SciTech Connect (OSTI)

    Arnett, E.M.

    1991-01-01

    Results are reported here for the heats of immersion of samples of polyvinylpyridine and the following coals: Exxon Rawhide, Argonne Wyodak, Illinois {number sign}6, Pittsburgh {number sign}8 in solutions of twelve sulfonic and carboxylic acids and boron trichloride. Heats of immersion in the different types of acids vary considerably from one solid system to another and the simple solid base polyvinylpyridine is a poor model for the more complex coals. The coals show varying degrees of correlation with each other. An important feature of the second half of the year has been an extensive comparison of titrametric heats of reaction of the different acids with several coal liquids and the coals from which they were derived. 16 figs., 1 tab.

  5. Enhanced electrodes for solid state gas sensors

    DOE Patents [OSTI]

    Garzon, Fernando H. (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM)

    2001-01-01

    A solid state gas sensor generates an electrical potential between an equilibrium electrode and a second electrode indicative of a gas to be sensed. A solid electrolyte substrate has the second electrode mounted on a first portion of the electrolyte substrate and a composite equilibrium electrode including conterminous transition metal oxide and Pt components mounted on a second portion of the electrolyte substrate. The composite equilibrium electrode and the second electrode are electrically connected to generate an electrical potential indicative of the gas that is being sensed. In a particular embodiment of the present invention, the second electrode is a reference electrode that is exposed to a reference oxygen gas mixture so that the electrical potential is indicative of the oxygen in a gas stream.

  6. UCN transport simulation in solid deuterium crystals

    E-Print Network [OSTI]

    Yu. N. Pokotilovski

    2012-03-04

    The extraction efficiency of ultracold neutrons from cryogenic moderators depends critically on the neutron transparency of the moderator material. The Monte Carlo simulation of the probability of the UCN going out from non-ideal (disordered) solid deuterium crystals has been performed. It was based on the use of the correlation function describing the density fluctuations in a disordered material, the latter being inferred from the measured very low neutron energy total cross sections for this material.

  7. Test Plan - Solids Accumulation Scouting Studies

    SciTech Connect (OSTI)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.; Fowley, M. D.

    2012-05-10

    This plan documents the highlights of the Solids Accumulations Scouting Studies test; a project, from Washington River Protection Solutions (WRPS), that began on February 1, 2012. During the last 12 weeks considerable progress has been made to design and plan methods that will be used to estimate the concentration and distribution of heavy fissile solids in accumulated solids in the Hanford double-shell tank (DST) 241-AW-105 (AW-105), which is the primary goal of this task. This DST will be one of the several waste feed delivery staging tanks designated to feed the Pretreatment Facility (PTF) of the Waste Treatment and Immobilization Plant (WTP). Note that over the length of the waste feed delivery mission AW-105 is currently identified as having the most fill empty cycles of any DST feed tanks, which is the reason for modeling this particular tank. At SRNL an existing test facility, the Mixing Demonstration Tank, which will be modified for the present work, will use stainless steel particles in a simulant that represents Hanford waste to perform mock staging tanks transfers that will allow solids to accumulate in the tank heel. The concentration and location of the mock fissile particles will be measured in these scoping studies to produce information that will be used to better plan larger scaled tests. Included in these studies is a secondary goal of developing measurement methods to accomplish the primary goal. These methods will be evaluated for use in the larger scale experiments. Included in this plan are the several pretest activities that will validate the measurement techniques that are currently in various phases of construction. Aspects of each technique, e.g., particle separations, volume determinations, topographical mapping, and core sampling, have been tested in bench-top trials, as discussed herein, but the actual equipment to be employed during the full test will need evaluation after fabrication and integration into the test facility.

  8. Solid tags for identifying failed reactor components

    DOE Patents [OSTI]

    Bunch, Wilbur L. (Richland, WA); Schenter, Robert E. (Richland, WA)

    1987-01-01

    A solid tag material which generates stable detectable, identifiable, and measurable isotopic gases on exposure to a neutron flux to be placed in a nuclear reactor component, particularly a fuel element, in order to identify the reactor component in event of its failure. Several tag materials consisting of salts which generate a multiplicity of gaseous isotopes in predetermined ratios are used to identify different reactor components.

  9. Solid state synthesis of poly(dichlorophosphazene)

    DOE Patents [OSTI]

    Allen, Christopher W. (Essex Junction, VT); Hneihen, Azzam S. (Burlington, VT); Peterson, Eric S. (Idaho Falls, ID)

    2001-01-01

    A method for making poly(dichlorophosphazene) using solid state reactants is disclosed and described. The present invention improves upon previous methods by removing the need for chlorinated hydrocarbon solvents, eliminating complicated equipment and simplifying the overall process by providing a "single pot" two step reaction sequence. This may be accomplished by the condensation reaction of raw materials in the melt phase of the reactants and in the absence of an environmentally damaging solvent.

  10. COMPILATION OF DISPOSABLE SOLID WASTE CASK EVALUATIONS

    SciTech Connect (OSTI)

    THIELGES, J.R.; CHASTAIN, S.A.

    2007-06-21

    The Disposable Solid Waste Cask (DSWC) is a shielded cask capable of transporting, storing, and disposing of six non-fuel core components or approximately 27 cubic feet of radioactive solid waste. Five existing DSWCs are candidates for use in storing and disposing of non-fuel core components and radioactive solid waste from the Interim Examination and Maintenance Cell, ultimately shipping them to the 200 West Area disposal site for burial. A series of inspections, studies, analyses, and modifications were performed to ensure that these casks can be used to safely ship solid waste. These inspections, studies, analyses, and modifications are summarized and attached in this report. Visual inspection of the casks interiors provided information with respect to condition of the casks inner liners. Because water was allowed to enter the casks for varying lengths of time, condition of the cask liner pipe to bottom plate weld was of concern. Based on the visual inspection and a corrosion study, it was concluded that four of the five casks can be used from a corrosion standpoint. Only DSWC S/N-004 would need additional inspection and analysis to determine its usefulness. The five remaining DSWCs underwent some modification to prepare them for use. The existing cask lifting inserts were found to be corroded and deemed unusable. New lifting anchor bolts were installed to replace the existing anchors. Alternate lift lugs were fabricated for use with the new lifting anchor bolts. The cask tiedown frame was modified to facilitate adjustment of the cask tiedowns. As a result of the above mentioned inspections, studies, analysis, and modifications, four of the five existing casks can be used to store and transport waste from the Interim Examination and Maintenance Cell to the disposal site for burial. The fifth cask, DSWC S/N-004, would require further inspections before it could be used.

  11. SOLID ELECTROLYTE BATTERIES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 -Rob Robertseere.energy.gov TimothySOLID ELECTROLYTE BATTERIES

  12. Reduction Mechanism of Fluoroethylene Carbonate for Stable Solid–Electrolyte Interphase Film on Silicon Anode

    SciTech Connect (OSTI)

    Chen, Xilin; Li, Xiaolin; Mei, Donghai; Feng, Ju; Hu, Mary Y.; Hu, Jian Z.; Engelhard, Mark H.; Zheng, Jianming; Xu, Wu; Xiao, Jie; Liu, Jun; Zhang, Jiguang

    2014-02-01

    Fluoroethylene Carbonate (FEC) is an effective electrolyte additive which can significantly improve the cyclability of Si and other anode materials. However, the fundamental mechanism on this improvement is still not well understood. Based on the results obtained from 6Li Nuclear Magnetic Resonance and X-ray Photoelectron Scanning study, we propose a molecular level mechanism on how FEC affects the formation of solid electrolyte interphase (SEI) film: 1) FEC is reduced through the opening of the five member ring leading to the formation of lithium poly (vinyl carbonate), LiF and some dimmers; 2) The high tensile strength of the FEC-derived lithium poly (vinyl carbonate) enhances the stability of the SEI film. This mechanism has been verified by the results of electrochemical tests.

  13. Municipal solid-waste management in Istanbul

    SciTech Connect (OSTI)

    Kanat, Gurdal

    2010-08-15

    Istanbul, with a population of around 13 million people, is located between Europe and Asia and is the biggest city in Turkey. Metropolitan Istanbul produces about 14,000 tons of solid waste per day. The aim of this study was to assess the situation of municipal solid-waste (MSW) management in Istanbul. This was achieved by reviewing the quantity and composition of waste produced in Istanbul. Current requirements and challenges in relation to the optimization of Istanbul's MSW collection and management system are also discussed, and several suggestions for solving the problems identified are presented. The recovery of solid waste from the landfills, as well as the amounts of landfill-generated biogas and electricity, were evaluated. In recent years, MSW management in Istanbul has improved because of strong governance and institutional involvement. However, efforts directed toward applied research are still required to enable better waste management. These efforts will greatly support decision making on the part of municipal authorities. There remains a great need to reduce the volume of MSW in Istanbul.

  14. EFFICIENT THEORETICAL SCREENING OF SOLID SORBENTS FOR CO2 CAPTURE APPLICATIONS

    SciTech Connect (OSTI)

    Duan, Yuhua; Sorescu, Dan C; Luebke, David

    2011-01-01

    Carbon dioxide is a major combustion product of coal, which once released into the air can contribute to global climate change. Current CO2 capture technologies for power generation processes including amine solvents and CaO-based sorbent materials require very energy intensive regeneration steps which result in significantly decreased efficiency. Hence, there is a critical need for new materials that can capture and release CO2 reversibly with acceptable energy costs if CO2 is to be captured and sequestered economically. Inorganic sorbents are one such class of materials which typically capture CO2 through the reversible formation of carbonates. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates from the vast array of possible solid materials has been proposed and validated. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO2 capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. For a given solid, the first step is to attempt to extract thermodynamic properties from thermodynamic databases and available literatures. If the thermodynamic properties of the compound of interest are unknown, an ab initio thermodynamic approach is used to calculate them. These properties expressed conveniently as chemical potentials and heat of reactions, either from databases or from calculations, are further used for computing the thermodynamic reaction equilibrium properties of the CO2 absorption/desorption cycle based on the chemical potential and heat of reaction. Only those solid materials for which lower capture energy costs are predicted at the desired process conditions are selected as CO2 sorbent candidates and further considered for experimental validations. Solid sorbents containing alkali and alkaline earth metals have been reported in several previous studies to be good candidates for CO2 sorbent applications due to their high CO2 absorption capacity at moderate working temperatures. In addition to introducing our selection process in this presentation, we will present our results for solid systems of alkali and alkaline metal oxides, hydroxides and carbonates/bicarbonates to validate our methodology. Additionally, applications of our computational method to mixed solid systems of Li2O and SiO2 with different mixing ratios, we showed that increasing the Li2O/SiO2 ratio in lithium silicates increases their corresponding turnover temperatures for CO2 capture reactions. These theoretical predictions are in good agreement with available experimental findings.

  15. SW New Mexico Oil Well Formation Tops

    SciTech Connect (OSTI)

    Shari Kelley

    2015-10-21

    Rock formation top picks from oil wells from southwestern New Mexico from scout cards and other sources. There are differing formation tops interpretations for some wells, so for those wells duplicate formation top data are presented in this file.

  16. Use of Alternative Fuels in Solid Oxide Fuel Cells Fuel Cells and Solid State Chemistry Department, Ris National Laboratory, Technical

    E-Print Network [OSTI]

    Use of Alternative Fuels in Solid Oxide Fuel Cells Anke Hagen Fuel Cells and Solid State Chemistry on a variety of environmentally benign energy production technologies. Fuel cells can be a key element in this scenario. One of the fuel cells types ­ the solid oxide fuel cell (SOFC) ­ has a number of advantages

  17. May 19-21, 2003 Ris International Energy Conference No 1 Solid Oxide Fuel CellsSolid Oxide Fuel Cells

    E-Print Network [OSTI]

    May 19-21, 2003 Risø International Energy Conference No 1 Solid Oxide Fuel CellsSolid Oxide Fuel #12;May 19-21, 2003 Risø International Energy Conference No 3 IntroductionIntroduction · "Fuel cells few moving parts" · "Solid oxide technology may prove to be the most reliable of fuel cell power

  18. Organic Tandem Solar Cells: Design and Formation

    E-Print Network [OSTI]

    Chen, Chun-Chao

    2015-01-01

    Angeles Organic Tandem Solar Cells: Design and Formation AOrganic Tandem Solar Cells: Design and Formation by Chun-multi-junction tandem solar-cell design. Given this design,

  19. REGULATORY COOPERATION COUNCIL - WORK PLANNING FORMAT: Natural...

    Energy Savers [EERE]

    FORMAT: Natural Gas Use in Transportation REGULATORY COOPERATION COUNCIL - WORK PLANNING FORMAT: Natural Gas Use in Transportation RCC Workplan NGV.PDF More Documents &...

  20. Solid State Division Progress Report for period ending March 31, 1986

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M.

    1986-08-01

    This report is divided into: theoretical solid-state physics, surface and near-surface properties of solids, defects in solids, transport properties of solids, neutron scattering, and synthesis and properties of novel materials. (DLC)

  1. FORMATION OF CIRCUMBINARY PLANETS IN A DEAD ZONE

    SciTech Connect (OSTI)

    Martin, Rebecca G.; Armitage, Philip J. [JILA, University of Colorado and NIST, UCB 440, Boulder, CO 80309 (United States); Alexander, Richard D. [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom)

    2013-08-10

    Circumbinary planets have been observed at orbital radii where binary perturbations may have significant effects on the gas disk structure, on planetesimal velocity dispersion, and on the coupling between turbulence and planetesimals. Here, we note that the impact of all of these effects on planet formation is qualitatively altered if the circumbinary disk structure is layered, with a non-turbulent midplane layer (dead zone) and strongly turbulent surface layers. For close binaries, we find that the dead zone typically extends from a radius close to the inner disk edge up to a radius of around 10-20 AU from the center of mass of the binary. The peak in the surface density occurs within the dead zone, far from the inner disk edge, close to the snow line, and may act as a trap for aerodynamically coupled solids. We suggest that circumbinary planet formation may be easier near this preferential location than for disks around single stars. However, dead zones around wide binaries are less likely, and hence planet formation may be more difficult there.

  2. Solid solution lithium alloy cermet anodes

    DOE Patents [OSTI]

    Richardson, Thomas J.

    2013-07-09

    A metal-ceramic composite ("cermet") has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.

  3. Supplementary content for Evaluating Air Blown Gasification for Energy Recovery from Wastewater Solids: Impact

    E-Print Network [OSTI]

    , drying the solids to 10% (wt) water content. Dried solids are briquetted and fed to the gasifier where

  4. Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode

    E-Print Network [OSTI]

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-01-01

    Infiltrated Solid Oxide Fuel Cell Electrode Tal Z.SOFC (Solid Oxide Fuel Cell) electrodes can significantly

  5. Interface control document between PUREX Plant Transition and Solid Waste Disposal Division

    SciTech Connect (OSTI)

    Carlson, A.B.

    1995-09-01

    The interfacing responsibilities regarding solid waste management are described for the Solid Waste Disposal Division and the PUREX Transition Organization.

  6. Covalently bonded three-dimensional carbon nanotube solids via boron induced nanojunctions

    SciTech Connect (OSTI)

    Sumpter, Bobby G; Meunier, Vincent; Terrones Maldonado, Humberto; Terrones Maldonado, Mauricio; Ajayan, Pullikel M; Hashim, Daniel; Romo Herrera, Jose M; Cullen, David; Munoz-Sandoval, Emilio; Smith, David J; Vajtai, Robert; Roy, Ajit K; Ganguli, Sabyasachi; Kelkhoff, Doug; Suttle, Joesph; Lezzi, Peter; Hahm, Gwan; Narayanan, Narayanan

    2012-01-01

    The establishment of covalent junctions between carbon nanotubes (CNTs) and the modification of their straight tubular morphology are two strategies needed to successfully synthesize nanotube-based three-dimensional (3D) frameworks exhibiting superior material properties. Engineering such 3D structures in scalable synthetic processes still remains a challenge. This work pioneers the bulk synthesis of 3D macroscale nanotube elastic solids directly via a boron-doping strategy during chemical vapor deposition, which influences the formation of atomic-scale elbow junctions and nanotube covalent interconnections. Detailed elemental analysis revealed that the elbow junctions are preferred sites for excess boron atoms, indicating the role of boron and curvature in the junction formation mechanism, in agreement with our first principle theoretical calculations. Exploiting this material s ultra-light weight, super-hydrophobicity, high porosity, thermal stability, and mechanical flexibility, the strongly oleophilic sponge-like solids are demonstrated as unique reusable sorbent scaffolds able to efficiently remove oil from contaminated seawater even after repeated use.

  7. Formation of porous gas hydrates

    E-Print Network [OSTI]

    Salamatin, Andrey N

    2015-01-01

    Gas hydrates grown at gas-ice interfaces are examined by electron microscopy and found to have a submicron porous texture. Permeability of the intervening hydrate layers provides the connection between the two counterparts (gas and water molecules) of the clathration reaction and makes further hydrate formation possible. The study is focused on phenomenological description of principal stages and rate-limiting processes that control the kinetics of the porous gas hydrate crystal growth from ice powders. Although the detailed physical mechanisms involved in the porous hydrate formation still are not fully understood, the initial stage of hydrate film spreading over the ice surface should be distinguished from the subsequent stage which is presumably limited by the clathration reaction at the ice-hydrate interface and develops after the ice grain coating is finished. The model reveals a time dependence of the reaction degree essentially different from that when the rate-limiting step of the hydrate formation at...

  8. The expected anisotropy in solid inflation

    E-Print Network [OSTI]

    Nicola Bartolo; Marco Peloso; Angelo Ricciardone; Caner Unal

    2014-07-30

    Solid inflation is an effective field theory of inflation in which isotropy and homogeneity are accomplished via a specific combination of anisotropic sources (three scalar fields that individually break isotropy). This results in specific observational signatures that are not found in standard models of inflation: a non-trivial angular dependence for the squeezed bispectrum, and a possibly long period of anisotropic inflation (to drive inflation, the "solid" must be very insensitive to any deformation, and thus background anisotropies are very slowly erased). In this paper we compute the expected level of statistical anisotropy in the power spectrum of the curvature perturbations of this model. To do so, we account for the classical background values of the three scalar fields that are generated on large (superhorizon) scales during inflation via a random walk sum, as the perturbation modes leave the horizon. Such an anisotropy is unavoidably generated, even starting from perfectly isotropic classical initial conditions. The expected level of anisotropy is related to the duration of inflation and to the amplitude of the squeezed bispectrum. If this amplitude is close to its current observational limit (so that one of the most interesting predictions of the model can be observed in the near future), we find that a level of statistical anisotropy $\\gtrsim 3\\%$ in the power spectrum is to be expected, if inflation lasted $\\gtrsim 20-30$ e-folds more than the final $50-60$ efolds required to generare the CMB modes. We also comment and point out various similarities between solid inflation and models of inflation where a suitable coupling of the inflaton to a vector kinetic term $F^{2}$ gives frozen and scale invariant vector perturbations on superhorizon scales.

  9. Integrated solid waste management of Scottsdale, Arizona

    SciTech Connect (OSTI)

    1995-11-01

    The subject document reports the results of an in-depth investigation of the fiscal year 1992 cost of the city of Scottsdale, Arizona, integrated municipal solid waste management (IMSWM) system, the energy consumed to operate the system, and the environmental performance requirements for each of the system`s waste-processing and disposal facilities. The document reports actual data from records kept by participants. Every effort was made to minimize the use of assumptions, and no attempt is made to interpret the data reported. Analytical approaches are documented so that interested analysts may per-form manipulation or further analysis of the data. As such, the report is a reference document for municipal solid waste (MSW) management professionals who are interested in the actual costs and energy consumption, for a 1-year period, of an operating IMSWM system. The report is organized into two main parts. The first part is the executive summary and case study portion of the report. The executive summary provides a basic description of the study area and selected economic and energy information. Within the case study are detailed descriptions of each component operating during the study period; the quantities of solid waste collected, processed, and marketed within the study boundaries; the cost of MSW in Scottsdale; an energy usage analysis; a review of federal, state, and local environmental requirement compliance; a reference section; and a glossary of terms. The second part of the report focuses on a more detailed discourse on the above topics. In addition, the methodology used to determine the economic costs and energy consumption of the system components is found in the second portion of this report. The methodology created for this project will be helpful for those professionals who wish to break out the costs of their own integrated systems.

  10. 1994 Solid waste forecast container volume summary

    SciTech Connect (OSTI)

    Templeton, K.J.; Clary, J.L.

    1994-09-01

    This report describes a 30-year forecast of the solid waste volumes by container type. The volumes described are low-level mixed waste (LLMW) and transuranic/transuranic mixed (TRU/TRUM) waste. These volumes and their associated container types will be generated or received at the US Department of Energy Hanford Site for storage, treatment, and disposal at Westinghouse Hanford Company`s Solid Waste Operations Complex (SWOC) during a 30-year period from FY 1994 through FY 2023. The forecast data for the 30-year period indicates that approximately 307,150 m{sup 3} of LLMW and TRU/TRUM waste will be managed by the SWOC. The main container type for this waste is 55-gallon drums, which will be used to ship 36% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of 55-gallon drums is Past Practice Remediation. This waste will be generated by the Environmental Restoration Program during remediation of Hanford`s past practice sites. Although Past Practice Remediation is the primary generator of 55-gallon drums, most waste generators are planning to ship some percentage of their waste in 55-gallon drums. Long-length equipment containers (LECs) are forecasted to contain 32% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of LECs is the Long-Length Equipment waste generator, which is responsible for retrieving contaminated long-length equipment from the tank farms. Boxes are forecasted to contain 21% of the waste. These containers are primarily forecasted for use by the Environmental Restoration Operations--D&D of Surplus Facilities waste generator. This waste generator is responsible for the solid waste generated during decontamination and decommissioning (D&D) of the facilities currently on the Surplus Facilities Program Plan. The remaining LLMW and TRU/TRUM waste volume is planned to be shipped in casks and other miscellaneous containers.

  11. Ultrasonic characterization of solid liquid suspensions

    DOE Patents [OSTI]

    Panetta, Paul D.

    2010-06-22

    Using an ultrasonic field, properties of a solid liquid suspension such as through-transmission attenuation, backscattering, and diffuse field are measured. These properties are converted to quantities indicating the strength of different loss mechanisms (such as absorption, single scattering and multiple scattering) among particles in the suspension. Such separation of the loss mechanisms can allow for direct comparison of the attenuating effects of the mechanisms. These comparisons can also indicate a model most likely to accurately characterize the suspension and can aid in determination of properties such as particle size, concentration, and density of the suspension.

  12. Nanoengineering for solid-state lighting.

    SciTech Connect (OSTI)

    Schubert, E. Fred; Koleske, Daniel David; Wetzel, Christian; Lee, Stephen Roger; Missert, Nancy A.; Lin, Shawn-Yu; Crawford, Mary Hagerott; Fischer, Arthur Joseph

    2009-09-01

    This report summarizes results from a 3-year Laboratory Directed Research and Development project performed in collaboration with researchers at Rensselaer Polytechnic Institute. Our collaborative effort was supported by Sandia's National Institute for Nanoengineering and focused on the study and application of nanoscience and nanoengineering concepts to improve the efficiency of semiconductor light-emitting diodes for solid-state lighting applications. The project explored LED efficiency advances with two primary thrusts: (1) the study of nanoscale InGaN materials properties, particularly nanoscale crystalline defects, and their impact on internal quantum efficiency, and (2) nanoscale engineering of dielectric and metal materials and integration with LED heterostructures for enhanced light extraction efficiency.

  13. Phase 2, Solid waste retrieval strategy

    SciTech Connect (OSTI)

    Johnson, D.M.

    1994-09-29

    Solid TRU retrieval, Phase 1 is scheduled to commence operation in 1998 at 218W-4C-T01 and complete recovery of the waste containers in 2001. Phase 2 Retrieval will recover the remaining buried TRU waste to be retrieved and provide the preliminary characterization by non-destructive means to allow interim storage until processing for disposal. This document reports on researching the characterization documents to determine the types of wastes to be retrieved and where located, waste configurations, conditions, and required methods for retrieval. Also included are discussions of wastes encompassed by Phase 2 for which there are valid reasons to not retrieve.

  14. Solids mass flow indication with radiation

    DOE Patents [OSTI]

    Macko, Joseph E. (Irwin, PA); Estriplet, Isnard (Irwin, PA)

    1985-06-04

    Method and apparatus for indicating mass flow of a solid particulate material through a rotary feeder. A radiation source and detector are positioned in a manner whereby radiation flux is directed through, and attenuated by, particulate material contained in rotating pockets. A Cesium-137 gamma source can be mounted within the shaft of the feeder, and one or more detectors can be mounted outside of the feeder housing. The detected signal is indicative of the mass of particulate material contained within a given pocket rotating within the feeder.

  15. Plastic flow in solids with interfaces

    E-Print Network [OSTI]

    Anurag Gupta; David Steigmann

    2011-11-25

    A non-equilibrium theory of isothermal and diffusionless evolution of incoherent interfaces within a plastically deforming solid is developed. The irreversible dynamics of the interface are driven by its normal motion, incoherency (slip and misorientation), and an intrinsic plastic flow; and purely by plastic deformation in the bulk away from the interface. Using the continuum theory for defect distribution (in bulk and over the interface) we formulate a general kinematical framework, derive relevant balance laws and jump conditions, and prescribe a thermodynamically consistent constitutive/kinetic structure for interface evolution.

  16. Solid composite electrolytes for lithium batteries

    DOE Patents [OSTI]

    Kumar, Binod (Dayton, OH); Scanlon, Jr., Lawrence G. (Fairborn, OH)

    2001-01-01

    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a polymer-ceramic composite electrolyte containing poly(ethylene oxide), lithium tetrafluoroborate and titanium dioxide is provided in the form of an annealed film having a room temperature conductivity of from 10.sup.-5 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1 and an activation energy of about 0.5 eV.

  17. Solid Freeform Fabrication of Aesthetic Objects

    ScienceCinema (OSTI)

    Hart, George [SUNY Stony Brook, Stony Brook, New York, United States

    2009-09-01

    Solid Freeform Fabrication (aka. Rapid Prototyping) equipment can produce beautiful three-dimensional objects of exquisite intricacy. To use this technology to its full potential requires spatial visualization in the designer and new geometric algorithms as tools. As both a sculptor and a research professor in the Computer Science department at Stony Brook University, George Hart is exploring algorithms for the design of elaborate aesthetic objects. In this talk, he will describe this work, show many images, and bring many physical models to display.

  18. Solid State Marx Modulators for Emerging Applications

    SciTech Connect (OSTI)

    Kemp, M.A.; /SLAC

    2012-09-14

    Emerging linear accelerator applications increasingly push the boundaries of RF system performance and economics. The power modulator is an integral part of RF systems whose characteristics play a key role in the determining parameters such as efficiency, footprint, cost, stability, and availability. Particularly within the past decade, solid-state switch based modulators have become the standard in high-performance, high power modulators. One topology, the Marx modulator, has characteristics which make it particularly attractive for several emerging applications. This paper is an overview of the Marx topology, some recent developments, and a case study of how this architecture can be applied to a few proposed linear accelerators.

  19. Piezonuclear neutrons from fracturing of inert solids

    E-Print Network [OSTI]

    F. Cardone; A. Carpinteri; G. Lacidogna

    2009-03-18

    Neutron emission measurements by means of helium-3 neutron detectors were performed on solid test specimens during crushing failure. The materials used were marble and granite, selected in that they present a different behaviour in compression failure (i.e., a different brittleness index) and a different iron content. All the test specimens were of the same size and shape. Neutron emissions from the granite test specimens were found to be of about one order of magnitude higher than the natural background level at the time of failure.

  20. Tubular solid oxide fuel cell current collector

    DOE Patents [OSTI]

    Bischoff, Brian L. (Knoxville, TN); Sutton, Theodore G. (Kingston, TN); Armstrong, Timothy R. (Clinton, TN)

    2010-07-20

    An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

  1. Tubular solid oxide fuel cell development program

    SciTech Connect (OSTI)

    Ray, E.R.; Cracraft, C.

    1995-12-31

    This paper presents an overview of the Westinghouse Solid Oxide Fuel Cell (SOFC) development activities and current program status. The Westinghouse goal is to develop a cost effective cell that can operate for 50,000 to 100,000 hours. Progress toward this goal will be discussed and test results presented for multiple single cell tests which have now successfully exceeded 56,000 hours of continuous power operation at temperature. Results of development efforts to reduce cost and increase power output of tubular SOFCs are described.

  2. Plastic flow in solids with interfaces

    E-Print Network [OSTI]

    Gupta, Anurag

    2011-01-01

    A non-equilibrium theory of isothermal and diffusionless evolution of incoherent interfaces within a plastically deforming solid is developed. The irreversible dynamics of the interface are driven by its normal motion, incoherency (slip and misorientation), and an intrinsic plastic flow; and purely by plastic deformation in the bulk away from the interface. Using the continuum theory for defect distribution (in bulk and over the interface) we formulate a general kinematical framework, derive relevant balance laws and jump conditions, and prescribe a thermodynamically consistent constitutive/kinetic structure for interface evolution.

  3. Solid state transport-based thermoelectric converter

    DOE Patents [OSTI]

    Hu, Zhiyu

    2010-04-13

    A solid state thermoelectric converter includes a thermally insulating separator layer, a semiconducting collector and an electron emitter. The electron emitter comprises a metal nanoparticle layer or plurality of metal nanocatalyst particles disposed on one side of said separator layer. A first electrically conductive lead is electrically coupled to the electron emitter. The collector layer is disposed on the other side of the separator layer, wherein the thickness of the separator layer is less than 1 .mu.m. A second conductive lead is electrically coupled to the collector layer.

  4. Idaho Solid Waste Webpage | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources JumpNewTexas:HydrothermallyIFB Agro|How toProofForm 204)319Solid

  5. Wastes Hazardous or Solid | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThinWarsaw, Poland: EnergyPage Edit HistoryWastes Hazardous or Solid

  6. solid state lighting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnal VariationsSolid-State Lighting

  7. solid-sorbent | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnal VariationsSolid-State

  8. Solid-State NMR | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|Sensitive Species3performedValley |SolarSole UseSolid-State NMR

  9. SolidEnergy Systems | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|Sensitive Species3performedValley |SolarSole UseSolid-State

  10. Sandia Energy - Solid-State Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)GeothermalFuel Magnetization and Laser(TSPEARSolar ResourceSolid

  11. Possible global environmental impacts of solid waste practices

    SciTech Connect (OSTI)

    Davis, M.M.; Holter, G.M.; DeForest, T.J.; Stapp, D.C.; Dibari, J.C.

    1994-09-01

    Pollutants resulting from the management of solid waste have been shown to affect the air, land, oceans, and waterways. In addition, solid wastes have other, more indirect impacts such as reduction in feedstocks of natural resources, because useful materials are disposed of rather than recycled. The objective of this study is to evaluate solid waste management practices that have negative implications on the global environment and develop recommendations for reducing such impacts. Recommendations identifying needed changes are identified that will reduce global impacts of solid waste practices in the future. The scope of this study includes the range of non-hazardous solid wastes produced within our society, including municipal solid waste (MSW) and industrial solid waste (ISW), as well as industry-specific wastes from activities such as construction, demolition, and landclearing. Most solid waste management decisions continue to be made and implemented at very local levels, predominantly with a short-term focus to respond to relatively immediate pressures of landfill shortages, funding problems, political considerations, and the like. In this rush to address immediate local problems, little consideration is being given to potential impacts, either short- or long-term, at the national or global level resulting from solid waste management practices. More and more, the cumulative impacts from local decisions concerning solid waste management are beginning to manifest themselves in broader, longer-term impacts than are being addressed by the decision-makers or, at the very least, are presenting a greater and greater potential for such impacts.

  12. FED, the Font "EDitor" and Font Formats

    E-Print Network [OSTI]

    Cohen, Joseph D.

    This memo describes FED, a program used for compiling and inspecting fonts: AST font format, a text format which can be used to create and edit fonts: and KST font format, the binary format used by SCRIMP, TJ6, and PUB.

  13. Method of fracturing a geological formation

    DOE Patents [OSTI]

    Johnson, James O. (2679-B Walnut, Los Alamos, NM 87544)

    1990-01-01

    An improved method of fracturing a geological formation surrounding a well bore is disclosed. A relatively small explosive charge is emplaced in a well bore and the bore is subsequently hydraulically pressurized to a pressure less than the formation breakdown pressure and preferably greater than the fracture propagation pressure of the formation. The charge is denoted while the bore is so pressurized, resulting in the formation of multiple fractures in the surrounding formation with little or no accompanying formation damage. Subsequent hydraulic pressurization can be used to propagate and extend the fractures in a conventional manner. The method is useful for stimulating production of oil, gas and possibly water from suitable geologic formations.

  14. Solids flow rate measurement in dense slurries

    SciTech Connect (OSTI)

    Porges, K.G.; Doss, E.D.

    1993-09-01

    Accurate and rapid flow rate measurement of solids in dense slurries remains an unsolved technical problem, with important industrial applications in chemical processing plants and long-distance solids conveyance. In a hostile two-phase medium, such a measurement calls for two independent parameter determinations, both by non-intrusive means. Typically, dense slurries tend to flow in laminar, non-Newtonian mode, eliminating most conventional means that usually rely on calibration (which becomes more difficult and costly for high pressure and temperature media). These issues are reviewed, and specific solutions are recommended in this report. Detailed calculations that lead to improved measuring device designs are presented for both bulk density and average velocity measurements. Cross-correlation, chosen here for the latter task, has long been too inaccurate for practical applications. The cause and the cure of this deficiency are discussed using theory-supported modeling. Fluid Mechanics are used to develop the velocity profiles of laminar non-Newtonian flow in a rectangular duct. This geometry uniquely allows the design of highly accurate `capacitive` devices and also lends itself to gamma transmission densitometry on an absolute basis. An absolute readout, though of less accuracy, is also available from a capacitive densitometer and a pair of capacitive sensors yields signals suitable for cross-correlation velocity measurement.

  15. The expected anisotropy in solid inflation

    SciTech Connect (OSTI)

    Bartolo, Nicola; Ricciardone, Angelo; Peloso, Marco; Unal, Caner E-mail: peloso@physics.umn.edu E-mail: unal@physics.umn.edu

    2014-11-01

    Solid inflation is an effective field theory of inflation in which isotropy and homogeneity are accomplished via a specific combination of anisotropic sources (three scalar fields that individually break isotropy). This results in specific observational signatures that are not found in standard models of inflation: a non-trivial angular dependence for the squeezed bispectrum, and a possibly long period of anisotropic inflation (to drive inflation, the ''solid'' must be very insensitive to any deformation, and thus background anisotropies are very slowly erased). In this paper we compute the expected level of statistical anisotropy in the power spectrum of the curvature perturbations of this model. To do so, we account for the classical background values of the three scalar fields that are generated on large (superhorizon) scales during inflation via a random walk sum, as the perturbation modes leave the horizon. Such an anisotropy is unavoidably generated, even starting from perfectly isotropic classical initial conditions. The expected level of anisotropy is related to the duration of inflation and to the amplitude of the squeezed bispectrum. If this amplitude is close to its current observational limit (so that one of the most interesting predictions of the model can be observed in the near future), we find that a level of statistical anisotropy F{sup 2} gives frozen and scale invariant vector perturbations on superhorizon scales.

  16. Solid-state power conversion handbook

    SciTech Connect (OSTI)

    Tarter, R.E.

    1993-01-01

    This new handbook is the first to be devoted to the field of solid-state power conversion. The material in this book is to be used in engineering practice and is oriented toward application rather than theory. The purpose of the book is to assemble in a single volume all the pertinent and comprehensive information necessary to meet the growing demands placed upon solid-state power conversion equipment. These demands include increased efficiency, improved reliability, higher packaging density, improved performance, and meeting safety and electromagnetic compatibility (EMC) requirements. The material presented includes a thorough analysis of fundamental electrical and magnetic aspects of power conversion plus thermal, protection, and reliability considerations. Attention is focused on semi-conductor and magnetic components and on analysis of various topologies. The handbook is organized into four sections. (1) Chapters 1-3 present the relations of various waveforms, transient components with emphasis on power semiconductors and magnetic components. (2) Chapters 4-12 deal with single-level conversion of rectifier circuits, filters, inverters and converters, feedback and stability analysis, and modulators and pulse-forming networks. (3) Chapters 13-16 discuss ancillary topics related to safety, EMC, thermal management, and reliability. (4) Chapters 17-19 cover design and operation of power supplies and systems from a detailed building block standpoint.

  17. 1995 Solid Waste 30-year volume summary

    SciTech Connect (OSTI)

    Valero, O.J. [Westinghouse Hanford Co., Richland, WA (United States); DeForest, T.J.; Templeton, K.J. [Pacific Northwest Lab., Richland, WA (United States)

    1995-06-01

    This document, prepared by Pacific Northwest Laboratory (PNL) under the direction of Westinghouse Hanford Company (WHC), provides a description of the annual low-level mixed waste (LLMW) and transuranic/transuranic mixed solid waste (TRU-TRUM) volumes expected to be managed by Hanford`s Solid Waste Central Waste Complex (CWC) over the next 30 years. The waste generation sources and waste categories are also described. This document is intended to be used as a reference for short- and long-term planning of the Hanford treatment, storage, and disposal (TSD) activities over the next several decades. By estimating the waste volumes that will be generated in the future, facility planners can determine the timing of key waste management activities, evaluate alternative treatment strategies, and plan storage and disposal capacities. In addition, this document can be used by other waste sites and the general public to gain a better understanding of the types and volumes of waste that will be managed at Hanford.

  18. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Warner, K.A.

    1999-06-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

  19. The Epoch of Galaxy Formation

    E-Print Network [OSTI]

    Raul Jimenez

    2001-10-09

    I present a biased review of when the epoch of formation of galaxies (both disks and ellipticals) maybe took place. I base my arguments in simple (mostly) analytic models that have been recently developed to reproduce most of the observed photometric, chemical and dynamical properties of galaxies both at low and high redshift.

  20. Earth and Terrestrial Planet Formation

    E-Print Network [OSTI]

    Jacobson, Seth A

    2015-01-01

    The growth and composition of Earth is a direct consequence of planet formation throughout the Solar System. We discuss the known history of the Solar System, the proposed stages of growth and how the early stages of planet formation may be dominated by pebble growth processes. Pebbles are small bodies whose strong interactions with the nebula gas lead to remarkable new accretion mechanisms for the formation of planetesimals and the growth of planetary embryos. Many of the popular models for the later stages of planet formation are presented. The classical models with the giant planets on fixed orbits are not consistent with the known history of the Solar System, fail to create a high Earth/Mars mass ratio, and, in many cases, are also internally inconsistent. The successful Grand Tack model creates a small Mars, a wet Earth, a realistic asteroid belt and the mass-orbit structure of the terrestrial planets. In the Grand Tack scenario, growth curves for Earth most closely match a Weibull model. The feeding zon...

  1. Cloud Formation, Evolution and Destruction

    E-Print Network [OSTI]

    Estalella, Robert

    Chapter 4 Cloud Formation, Evolution and Destruction We now begin to trace the journey towards a star. How long does this take? The answer is surprisingly short: a good many clouds already contain new stars and these stars tend to be young. The typical cloud cannot spend long, if any time at all

  2. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  3. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1996-02-13

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  4. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1995-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  5. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1996-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  6. Solid State Division progress report, September 30, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-04-01

    Progress made during the 19 months from March 1, 1980, through September 30, 1981, is reported in the following areas: theoretical solid state physics (surfaces, electronic and magnetic properties, particle-solid interactions, and laser annealing); surface and near-surface properties of solids (plasma materials interactions, ion-solid interactions, pulsed laser annealing, and semiconductor physics and photovoltaic conversion); defects in solids (radiation effects, fracture, and defects and impurities in insulating crystals); transport properties of solids (fast-ion conductors, superconductivity, and physical properties of insulating materials); neutron scattering (small-angle scattering, lattice dynamics, and magnetic properties); crystal growth and characterization (nuclear waste forms, ferroelectric mateirals, high-temperature materials, and special materials); and isotope research materials. Publications and papers are listed. (WHK)

  7. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1995-10-03

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  8. Electrophoretic Deposition of Highly Efficient Phosphors for White Solid State Lighting using near UV-Emitting LEDs /

    E-Print Network [OSTI]

    Choi, Jae Ik

    2014-01-01

    for Near-UV LED Solid State Lighting” ECS Journal of Solidfor Near-UV LED Solid State Lighting”, ECS J. Solid Statefor near-UV LED solid state lighting,” ECS J. Solid State

  9. Structural Integrity Program for INTEC Calcined Solids Storage Facilities

    SciTech Connect (OSTI)

    Jeffrey Bryant

    2008-08-30

    This report documents the activities of the structural integrity program at the Idaho Nuclear Technology and Engineering Center relevant to the high-level waste Calcined Solids Storage Facilities and associated equipment, as required by DOE M 435.1-1, 'Radioactive Waste Management Manual'. Based on the evaluation documented in this report, the Calcined Solids Storage Facilities are not leaking and are structurally sound for continued service. Recommendations are provided for continued monitoring of the Calcined Solids Storage Facilities.

  10. Constraints on the Formation Age of Cometary Material from the NASA Stardust Mission

    SciTech Connect (OSTI)

    Matzel, J; Ishii, H; Joswiak, D; Hutcheon, I; Bradley, J; Brownlee, D; Weber, P K; Teslich, N; Matrajt, G; McKeegan, K; MacPherson, G

    2009-11-13

    We measured the {sup 26}Al-{sup 26}Mg isotope systematics of a {approx} 5-micrometer refractory particle, Coki, returned from comet 81P/Wild 2 in order to relate the time scales of formation of cometary inclusions to their meteoritic counterparts. The data show no evidence of radiogenic {sup 26}Mg and define an upper limit to the abundance of {sup 26}Al at the time of particle formation: {sup 26}Al/{sup 27}Al < 1 x 10-5. The absence of {sup 26}Al indicates that Coki formed >1.7 million years after the oldest solids in the solar system, calcium- and aluminum-rich inclusions (CAIs). The data suggest that high-temperature inner solar system material formed, was subsequently transferred to the Kuiper Belt, and was incorporated into comets several million years after CAI formation.

  11. EIS-0286: Hanford Solid (Radioactive and Hazardous) Waste Program

    Broader source: Energy.gov [DOE]

    The Hanford Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement (HSW EIS) analyzes the proposed waste management practices at the Hanford Site.

  12. Evaluation of wall boundary condition parameters for gas-solids...

    Office of Scientific and Technical Information (OSTI)

    predictions of various gas-solids fluidized beds. Several models for the granular flow wall boundary condition are available in the open literature for numerical modeling of...

  13. 8.231 Physics of Solids I, Fall 2002

    E-Print Network [OSTI]

    Greytak, Thomas John, 1940-

    Introduction to the basic concepts of the quantum theory of solids. Topics: periodic structure and symmetry of crystals; diffraction; reciprocal lattice; chemical bonding; lattice dynamics, phonons, thermal properties; ...

  14. A two-photoelectrode solid-state photoelectrochemical cell

    SciTech Connect (OSTI)

    Sammells, A.F.; Schmidt, S.K.

    1985-02-01

    This article describes a two photoelectrode solid-state photoelectrochemical cell which is able to produce photopotentials in excess of one voltage and possesses some inherent storage capacity. The storage capacity is presently limited by the low concentration and thin solid polymer electrolyte (SPE) redox layers used between the photoelectrode and the SPE membrane. The use of solid-electrolyte based photoelectrochemical cells provides a unique approach for the photoelectrochemical conversion and storage of selected redox species incorporated within the proximity of the semiconductor/solid electrolyte interface. It is expected that the described cell will be of potential value as not only a specialized storage device, but for specific detector applications.

  15. South Carolina Solid Waste Policy and Management Act (South Carolina)

    Broader source: Energy.gov [DOE]

    The state of South Carolina supports a regional approach to solid waste management and encourages the development and implementation of alternative waste management practices and resource recovery....

  16. Curved mesh generation and mesh refinement using Lagrangian solid mechanics

    E-Print Network [OSTI]

    Persson, P.-O.

    2009-01-01

    Nonlinear continuum mechanics for ?nite element analysis,nement using Lagrangian Solid Mechanics Per-Olof Persson ?methods for computational mechanics has been emphasized in

  17. 2013 Solid-State Lighting Market Introduction Workshop Presentations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Market Introduction Workshop Presentations and Materials 2013 Solid-State Lighting Market Introduction Workshop Presentations and Materials This page provides links to the...

  18. 2012 Solid-State Lighting Market Introduction Workshop Presentations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Market Introduction Workshop Presentations and Materials 2012 Solid-State Lighting Market Introduction Workshop Presentations and Materials This page provides links to the...

  19. Method of synthesizing polymers from a solid electrolyte

    DOE Patents [OSTI]

    Skotheim, T.A.

    1984-10-19

    A method of synthesizing electrically conductive polymers from a solvent-free solid polymer electrolyte is disclosed. An assembly of a substrate having an electrode thereon, a thin coating of solid electrolyte including a solution of PEO complexed with an alkali salt, and a thin transparent noble metal electrode are disposed in an evacuated chamber into which a selected monomer vapor is introduced while an electric potential is applied across the solid electrolyte to hold the thin transparent electrode at a positive potential relative to the electrode on the substrate, whereby a highly conductive polymer film is grown on the transparent electrode between it and the solid electrolyte.

  20. Process for minimizing solids contamination of liquids from coal pyrolysis

    DOE Patents [OSTI]

    Wickstrom, Gary H. (Yorba Linda, CA); Knell, Everett W. (Los Alamitos, CA); Shaw, Benjamin W. (Costa Mesa, CA); Wang, Yue G. (West Covina, CA)

    1981-04-21

    In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

  1. Hanford Site Solid (Radioactive and Hazardous) Waste Program...

    Office of Environmental Management (EM)

    Office 2 3 TITLE: 4 Revised Draft Hanford Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact 5 Statement, Richland, Benton County, Washington (DOE...

  2. Revised Draft Hanford Site Solid (Radioactive and Hazardous)...

    Office of Environmental Management (EM)

    Operations Office TITLE: Revised Draft Hanford Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement, Richland, Benton County, Washington (DOE...

  3. Final Hanford Site Solid (Radioactive and Hazardous) Waste Program...

    Office of Environmental Management (EM)

    Richland Operations Office TITLE: Final Hanford Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement, Richland, Benton County, Washington (DOE...

  4. Method and apparatus for semi-solid material processing

    DOE Patents [OSTI]

    Han, Qingyou (Knoxville, TN) [Knoxville, TN; Jian, Xiaogang (Knoxville, TN) [Knoxville, TN; Xu, Hanbing (Knoxville, TN) [Knoxville, TN; Meek, Thomas T. (Knoxville, TN) [Knoxville, TN

    2009-11-24

    A method of forming a material includes the steps of: vibrating a molten material at an ultrasonic frequency while cooling the material to a semi-solid state to form non-dendritic grains therein; forming the semi-solid material into a desired shape; and cooling the material to a solid state. The method makes semi-solid castings directly from molten materials (usually a metal), produces grain size usually in the range of smaller than 50 .mu.m, and can be easily retrofitted into existing conventional forming maching.

  5. Solid-Liquid Separation of Animal Manure and Wastewater 

    E-Print Network [OSTI]

    Mukhtar, Saqib; Sweeten, John M.; Auvermann, Brent W.

    1999-10-19

    Solid-liquid separation is an alternative treatment for animal manure and process-generated wastewater. This publication explains the techniques, equipment, performance and economics of separators....

  6. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume...

    Office of Environmental Management (EM)

    exempt, small quantity hazardous waste, and industrial solid waste. It includes food waste, residential rubbish, commercial and industrial wastes, and construction and...

  7. fll INTRODUCTION Solid mechanics is a fundamental discipline which, in

    E-Print Network [OSTI]

    , solid mechanics is a central discipline for hydrocarbon resource extraction by drilling, hydraulic aggregates, whether in the form of artificially struc- tured composites or conventional engineering materials

  8. Solid-State Lighting Program Strategy Overview - 2014 BTO Peer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Strategy Overview - 2014 BTO Peer Review Solid-State Lighting Program Strategy Overview - 2014 BTO Peer Review Presenter: James Broderick, U.S. Department of Energy This...

  9. Nanocrystalline cerium oxide materials for solid fuel cell systems

    SciTech Connect (OSTI)

    Brinkman, Kyle S

    2015-05-05

    Disclosed are solid fuel cells, including solid oxide fuel cells and PEM fuel cells that include nanocrystalline cerium oxide materials as a component of the fuel cells. A solid oxide fuel cell can include nanocrystalline cerium oxide as a cathode component and microcrystalline cerium oxide as an electrolyte component, which can prevent mechanical failure and interdiffusion common in other fuel cells. A solid oxide fuel cell can also include nanocrystalline cerium oxide in the anode. A PEM fuel cell can include cerium oxide as a catalyst support in the cathode and optionally also in the anode.

  10. Solid State Processing of New Low Cost Titanium Powders Enabling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing of New Low Cost Titanium Powders Enabling Affordable Automotive Components Solid State Processing of New Low Cost Titanium Powders Enabling Affordable Automotive...

  11. Production of Ultra-Cold-Neutrons in Solid ?-Oxygen

    E-Print Network [OSTI]

    E. Gutsmiedl; A. Frei; F. Boehle; A. Maier; S. Paul; H. Schober; A. Orecchini

    2010-07-30

    Our recent neutron scattering measurements of phonons and magnons in solid \\alpha-oxygen have led us to a new understanding of the production mechanismen of ultra-cold-neutrons (UCN) in this super-thermal converter. The UCN production in solid \\alpha-oxygen is dominated by the excitation of phonons. The contribution of magnons to UCN production becomes only slightly important above E >10 meV and at E >4 meV. Solid \\alpha-oxygen is in comparison to solid deuterium less effcient in the down-scattering of thermal or cold neutrons into the UCN energy regime.

  12. Energy Department Announces $4 Million Solicitation for Solid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    diodes (LEDs), organic light-emitting diodes (OLEDs) and light-emitting polymers. "Solid-state lighting advances have the potential to greatly reduce energy...

  13. Mimicking anhydrobiosis on solid supported lipid bilayers 

    E-Print Network [OSTI]

    Chapa, Vanessa Alyss

    2007-09-17

    may be involved. 54 In the last ten years, an alternative mechanism of anhydrobiosis, the formation of sugar glasses, or vitrification, has been proposed to work in conjunction with water replacement to stabilize dry bilayers. 57 Glasses... when dehydrated and although the specifics remain unclear, it has been proposed that vitrification inhibits the increase in T m . 60 Previous Studies of Liposomes Whereas the use of supported lipid bilayers in anhydrobiotic studies is novel...

  14. Ordered rate constitutive theories in Lagrangian description for thermoelastic solids and thermoviscoelastic solids with and without memory using Helmholtz free energy density

    E-Print Network [OSTI]

    Moody, Tristan

    2013-05-31

    The research work presented here considers development of constitutive theories in Lagrangian description for homogeneous, isotropic, compressible and incompressible thermoelastic solids, thermoviscoelastic solids without ...

  15. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L. (Lincoln, MA); He, Bo X. (Newton, MA)

    1990-01-01

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  16. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  17. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA); Tran, Tri D. (Livermore, CA); Feikert, John H. (Livermore, CA); Mayer, Steven T. (San Leandro, CA)

    1997-01-01

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  18. Solid waste recycling programs at Rocky Flats

    SciTech Connect (OSTI)

    Millette, R.L.; Blackman, T.E.; Shepard, M.D.

    1994-12-31

    The Rocky Flats (RFP) recycling programs for solid waste materials have been in place for over ten years. Within the last three years, the programs were centralized under the direction of the Rocky Flats Waste Minimization department, with the assistance of various plant organizations (e.g., Trucking, Building Services, Regulated Waste Operations, property Utilization and Disposal and Security). Waste Minimization designs collection and transportation systems for recyclable materials and evaluates recycling markets for opportunities to add new commodities to the existing programs. The Waste Minimization department also promotes employee participation in the Rocky Flats Recycling Programs, and collects all recycling data for publication. A description of the program status as of January 1994 is given.

  19. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  20. Solid oxide fuel cell matrix and modules

    DOE Patents [OSTI]

    Riley, B.

    1988-04-22

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs. 11 figs.

  1. Producing usable fuel from municipal solid waste

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1995-03-01

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  2. Solid polymeric electrolytes for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles A.; Xu, Wu; Sun, Xiaoguang

    2006-03-14

    Novel conductive polyanionic polymers and methods for their preparion are provided. The polyanionic polymers comprise repeating units of weakly-coordinating anionic groups chemically linked to polymer chains. The polymer chains in turn comprise repeating spacer groups. Spacer groups can be chosen to be of length and structure to impart desired electrochemical and physical properties to the polymers. Preferred embodiments are prepared from precursor polymers comprising the Lewis acid borate tri-coordinated to a selected ligand and repeating spacer groups to form repeating polymer chain units. These precursor polymers are reacted with a chosen Lewis base to form a polyanionic polymer comprising weakly coordinating anionic groups spaced at chosen intervals along the polymer chain. The polyanionic polymers exhibit high conductivity and physical properties which make them suitable as solid polymeric electrolytes in lithium batteries, especially secondary lithium batteries.

  3. Solid phase microextraction device using aerogel

    DOE Patents [OSTI]

    Miller, Fred S.; Andresen, Brian D.

    2005-06-14

    A sample collection substrate of aerogel and/or xerogel materials bound to a support structure is used as a solid phase microextraction (SPME) device. The xerogels and aerogels may be organic or inorganic and doped with metals or other compounds to target specific chemical analytes. The support structure is typically formed of a glass fiber or a metal wire (stainless steel or kovar). The devices are made by applying gel solution to the support structures and drying the solution to form aerogel or xerogel. Aerogel particles may be attached to the wet layer before drying to increase sample collection surface area. These devices are robust, stable in fields of high radiation, and highly effective at collecting gas and liquid samples while maintaining superior mechanical and thermal stability during routine use. Aerogel SPME devices are advantageous for use in GC/MS analyses due to their lack of interfering background and tolerance of GC thermal cycling.

  4. Solid oxide fuel cell power system development

    SciTech Connect (OSTI)

    Kerr, Rick; Wall, Mark; Sullivan, Neal

    2015-06-26

    This report summarizes the progress made during this contractual period in achieving the goal of developing the solid oxide fuel cell (SOFC) cell and stack technology to be suitable for use in highly-efficient, economically-competitive, commercially deployed electrical power systems. Progress was made in further understanding cell and stack degradation mechanisms in order to increase stack reliability toward achieving a 4+ year lifetime, in cost reduction developments to meet the SECA stack cost target of $175/kW (in 2007 dollars), and in operating the SOFC technology in a multi-stack system in a real-world environment to understand the requirements for reliably designing and operating a large, stationary power system.

  5. Interconnection of bundled solid oxide fuel cells

    DOE Patents [OSTI]

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  6. Solid oxide fuel cell process and apparatus

    DOE Patents [OSTI]

    Cooper, Matthew Ellis (Morgantown, WV); Bayless, David J. (Athens, OH); Trembly, Jason P. (Durham, NC)

    2011-11-15

    Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H.sub.2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H.sub.2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.

  7. Tubular solid oxide fuel cell developments

    SciTech Connect (OSTI)

    Bratton, R.J.; Singh, P.

    1995-08-01

    An overview of the tubular solid oxide fuel cell (SOFC) development at Westinghouse is presented in this paper. The basic operating principles of SOFCs, evolution in tubular cell design and performance improvement, selection criteria for cell component materials, and cell processing techniques are discussed. The commercial goal is to develop a cell that can operate for 5 to 10 years. Results of cell test operated for more than 50,000 hours are presented. Since 1986, significant progress has been made in the evolution of cells with higher power, lower cost and improved thermal cyclic capability. Also in this period, successively larger multi-kilowatt electrical generators systems have been built and successfully operated for more than 7000 hours.

  8. Integrated solid waste management of Sevierville, Tennessee

    SciTech Connect (OSTI)

    1995-11-01

    The subject document reports the results of an in-depth investigation of the fiscal year 1992 cost of the City of Sevierville, Tennessee integrated municipal solid waste management (IMSWM) system, the energy consumed to operate the system, and the environmental performance requirements for each of the system`s waste-processing and disposal facilities. Actual data from records kept by participants is reported in this document. Every effort was made to minimize the use of assumptions, and no attempt is made to interpret the data reported. Analytical approaches are documented so that interested analysts may perform manipulation or further analysis of the data. As such, the report is a reference document for MSW management professionals who are interested in the actual costs and energy consumption for a one-year period, of an operating IMSWM systems.

  9. Singles correlation energy contributions in solids

    E-Print Network [OSTI]

    Klimeš, Ji?í; Maggio, Emanuele; Kresse, Georg

    2015-01-01

    The random phase approximation to the correlation energy often yields highly accurate results for condensed matter systems. However, ways how to improve its accuracy are being sought and here we explore the relevance of singles contributions for prototypical solid state systems. We set out with a derivation of the random phase approximation using the adiabatic connection and fluctuation dissipation theorem, but contrary to the most commonly used derivation, the density is allowed to vary along the coupling constant integral. This yields results closely paralleling standard perturbation theory. We re-derive the standard singles of G\\"orling-Levy perturbation theory [G\\"orling and Levy, Phys. Rev. A {\\bf 50}, 196 (1994)], highlight the analogy of our expression to the renormalized singles introduced by Ren and coworkers [Ren, Tkatchenko, Rinke, and Scheffler, Phys. Rev. Lett. {\\bf 106}, 153003 (2011)], and introduce a new approximation for the singles using the density matrix in the random phase approximation. ...

  10. Solid-state lighting technology perspective.

    SciTech Connect (OSTI)

    Tsao, Jeffrey Yeenien; Coltrin, Michael Elliott

    2006-08-01

    Solid-State Lighting (SSL) uses inorganic light-emitting diodes (LEDs) and organic light-emitting diodes (OLEDs) to convert electricity into light for illumination. SSL has the potential for enormous energy savings and accompanying environmental benefits if its promise of 50% (or greater) energy efficiencies can be achieved. This report provides a broad summary of the technologies that underlie SSL. The applications for SSL and potential impact on U.S. and world-wide energy consumption, and impact on the human visual experience are discussed. The properties of visible light and different technical metrics to characterize its properties are summarized. The many factors contributing to the capital and operating costs for SSL and traditional lighting sources (incandescent, fluorescent, and high-intensity discharge lamps) are discussed, with extrapolations for future SSL goals. The technologies underlying LEDs and OLEDs are also described, including current and possible alternative future technologies and some of the present limitations.

  11. Athermal jamming of soft frictionless Platonic solids

    E-Print Network [OSTI]

    Kyle C. Smith; Meheboob Alam; Timothy S. Fisher

    2010-11-18

    A mechanically-based structural optimization method is utilized to explore the phenomena of jamming for assemblies of frictionless Platonic solids. Systems of these regular convex polyhedra exhibit mechanically stable phases with density substantially less than optimal for a given shape, revealing that thermal motion is necessary to access high density phases. We confirm that the large system jamming threshold of $0.623 \\pm 0.003$ for tetrahedra is consistent with experiments on tetrahedral dice. Also, the extremely short-ranged translational correlations of packed tetrahedra observed in experiments are confirmed here, in contrast with those of thermally simulated glasses. Though highly ordered phases are observed to form for small numbers of cubes and dodecahedra, the short correlation length scale suppresses ordering in large systems, resulting in packings that are mechanically consistent with `orientationally disordered' contacts (point-face and edge-edge contacts). Mild nematic ordering is observed for large systems of cubes, whereas angular correlations for the remaining shapes are ultra short-ranged. Power-law scaling exponents for energy with respect to distance from the jamming threshold exhibit a clear dependence on the `highest order' percolating contact topology. These nominal exponents are 6, 4, and 2 for configurations having percolating point-face (or edge-edge), edge-face, and face-face contacts, respectively. These Platonic solids exhibit hypostatic behavior, with average jamming contact number between the isostatic value for spheres and that of asymmetric particles. These shapes violate the isostatic conjecture, displaying contact number that decreases monotonically with sphericity. The common symmetry of dual polyhedra results in local translational structural similarity. (Note abstract abridged due to length constraint)

  12. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  13. Controlled Irradiative Formation of Penitentes

    E-Print Network [OSTI]

    V. Bergeron; C. Berger; M. D. Betterton

    2006-01-24

    Spike-shaped structures are produced by light-driven ablation in very different contexts. Penitentes 1-4 m high are common on Andean glaciers, where their formation changes glacier dynamics and hydrology. Laser ablation can produce cones 10-100 microns high with a variety of proposed applications in materials science. We report the first laboratory generation of centimeter-scale snow and ice penitentes. Systematically varying conditions allows identification of the essential parameters controlling the formation of ablation structures. We demonstrate that penitente initiation and coarsening requires cold temperatures, so that ablation leads to sublimation rather than melting. Once penitentes have formed, further growth of height can occur by melting. The penitentes intially appear as small structures (3 mm high) and grow by coarsening to 1-5 cm high. Our results are an important step towards understanding and controlling ablation morphologies.

  14. Laser beam pulse formatting method

    DOE Patents [OSTI]

    Daly, T.P.; Moses, E.I.; Patterson, R.W.; Sawicki, R.H.

    1994-08-09

    A method for formatting a laser beam pulse using one or more delay loops is disclosed. The delay loops have a partially reflective beam splitter and a plurality of highly reflective mirrors arranged such that the laser beam pulse enters into the delay loop through the beam splitter and circulates therein along a delay loop length defined by the mirrors. As the laser beam pulse circulates within the delay loop a portion thereof is emitted upon each completed circuit when the laser beam pulse strikes the beam splitter. The laser beam pulse is thereby formatted into a plurality of sub-pulses. The delay loops are used in combination to produce complex waveforms by combining the sub-pulses using additive waveform synthesis. 8 figs.

  15. Shock Formation in Lovelock Theories

    E-Print Network [OSTI]

    Harvey S. Reall; Norihiro Tanahashi; Benson Way

    2014-09-12

    We argue that Lovelock theories of gravity suffer from shock formation, unlike General Relativity. We consider the propagation of (i) a discontinuity in curvature, and (ii) weak, high frequency, gravitational waves. Such disturbances propagate along characteristic hypersurfaces of a "background" spacetime and their amplitude is governed by a transport equation. In GR the transport equation is linear. In Lovelock theories, it is nonlinear and its solutions can blow up, corresponding to the formation of a shock. We show that this effect is absent in some simple cases e.g. a flat background spacetime, and demonstrate its presence for a plane wave background. We comment on weak cosmic censorship, the evolution of shocks, and the nonlinear stability of Minkowski spacetime, in Lovelock theories.

  16. Size Dependence of a Temperature-Induced Solid-Solid Phase Transition in Copper(I) Sulfide

    E-Print Network [OSTI]

    Rivest, Jessy B

    2012-01-01

    of CZTS-based thin film solar cells. Thin Solid Films 2009,comprised the original thin film solar cell in 1954. 33,44

  17. Membrane adhesion and domain formation

    E-Print Network [OSTI]

    Thomas R. Weikl; Reinhard Lipowsky

    2007-09-23

    We review theoretical results for the adhesion-induced phase behavior of biomembranes. The focus is on models in which the membranes are represented as discretized elastic sheets with embedded adhesion molecules. We present several mechanism that lead to the formation of domains during adhesion, and discuss the time-dependent evolution of domain patterns obtained in Monte-Carlo simulations. The simulated pattern dynamics has striking similarities to the pattern evolution observed during T cell adhesion.

  18. Absorption and elimination of formate following oral administration of calcium formate in female human subjects

    E-Print Network [OSTI]

    Hanzlik, Robert P.; Fowler, Stephen C.; Eells, Janis T.

    2005-02-01

    Published abstract: Calcium formate is a water-soluble salt of an essential mineral nutrient with potential for use as a dietary calcium supplement. Formate ion is a product of endogenous and xenobiotic metabolism, but sustained high plasma formate...

  19. Synthesis and characterization of the LDH hydrotalcite-pyroaurite solid-solution series

    SciTech Connect (OSTI)

    Rozov, K.; Berner, U.; Taviot-Gueho, C.; Leroux, F.; Renaudin, G.; Kulik, D.; Diamond, L.W.

    2010-08-15

    A layered double hydroxide (LDH) hydrotalcite-pyroaurite solid-solution series Mg{sub 3}(Al{sub x}Fe{sub 1-x})(CO{sub 3}){sub 0.5}(OH){sub 8} with 1 - x = 0.0, 0.1...1.0 was prepared by co-precipitation at 23 {+-} 2 {sup o}C and pH = 11.40 {+-} 0.03. The compositions of the solids and the reaction solutions were determined using ICP-OES (Mg, Al, Fe, and Na) and TGA techniques (CO{sub 3}{sup 2-}, OH{sup -}, and H{sub 2}O). Powder X-ray diffraction was employed for phase identification and determination of the unit cell parameters a{sub o} and c{sub o} from peak profile analysis. The parameter a{sub o} = b{sub o} was found to be a linear function of the composition. This dependency confirms Vegard's law and indicates the presence of a continuous solid-solution series in the hydrotalcite-pyroaurite system. TGA data show that the temperatures at which interlayer H{sub 2}O molecules and CO{sub 3}{sup 2-} anions are lost, and at which dehydroxylation of the layers occurs, all decrease with increasing mole fraction of iron within the hydroxide layers. Features of the Raman spectra also depend on the iron content. The absence of Raman bands for Fe-rich members (x{sub Fe} > 0.5) is attributed to possible fluorescence phenomena. Based on chemical analysis of both the solids and the reaction solutions after synthesis, preliminary Gibbs free energies of formation have been estimated. Values of {Delta}G{sup o}{sub f}(hydrotalcite) = - 3773.3 {+-} 51.4 kJ/mol and {Delta}G{sup o}{sub f}(pyroaurite) = - 3294.5 {+-} 95.8 kJ/mol were found at 296.15 K. The formal uncertainties of these formations constants are very high. Derivation of more precise values would require carefully designed solubility experiments and improved analytical techniques.

  20. Solid Phase Characterization of Tank 241-C-108 Residual Waste Solids Samples

    SciTech Connect (OSTI)

    Cooke, Gary A.; Pestovich, John A.; Huber, Heinz J.

    2013-05-29

    This report presents the results for solid phase characterization (SPC) of solid samples removed from tank 241-C-108 (C-108) on August 12-13,2012, using the off-riser sampler. Samples were received at the 222-S Laboratory on August 13 and were described and photographed. The SPC analyses that were performed include scanning electron microscopy (SEM) using the ASPEX(R)l scanning electron microscope, X-ray diffraction (XRD) using the Rigaku(R) 2 MiniFlex X-ray diffractometer, and polarized light microscopy (PLM) using the Nikon(R) 3 Eclipse Pol optical microscope. The SEM is equipped with an energy dispersive X-ray spectrometer (EDS) to provide chemical information. Gary A. Cooke conducted the SEM analysis, John A. Pestovich performed the XRD analysis, and Dr. Heinz J. Huber performed the PLM examination. The results of these analyses are presented here.

  1. Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program

    SciTech Connect (OSTI)

    Nguyen Minh

    2006-07-31

    This report summarizes the work performed for Phase I (October 2001 - August 2006) under Cooperative Agreement DE-FC26-01NT41245 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled 'Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program'. The program focuses on the development of a low-cost, high-performance 3-to-10-kW solid oxide fuel cell (SOFC) system suitable for a broad spectrum of power-generation applications. During Phase I of the program significant progress has been made in the area of SOFC technology. A high-efficiency low-cost system was designed and supporting technology developed such as fuel processing, controls, thermal management, and power electronics. Phase I culminated in the successful demonstration of a prototype system that achieved a peak efficiency of 41%, a high-volume cost of $724/kW, a peak power of 5.4 kW, and a degradation rate of 1.8% per 500 hours. . An improved prototype system was designed, assembled, and delivered to DOE/NETL at the end of the program. This prototype achieved an extraordinary peak efficiency of 49.6%.

  2. Porous Solids DOI: 10.1002/anie.200503950

    E-Print Network [OSTI]

    Osterloh, Frank

    solids have found technological applications as [*] N. N. Akl, X. Qi, J. Y. Kim, Prof. F. E. Osterloh in electrically conducting compo- sites,[14­17] as electrode materials for Li-battery applications,[18 mobile ions into porous structures.[8,9] We describe herein a novel approach to metallic porous solids

  3. UNCORRECTED 2 Multiscale boundary conditions in crystalline solids

    E-Print Network [OSTI]

    Qian, Dong

    UNCORRECTED PROOF 1 2 Multiscale boundary conditions in crystalline solids: 3 Theory scale simulations of crystalline solids. Based on Fourier analysis of regular lattices structures with a crystalline gold substrate. Complete atomistic resolution on the coarse grain is alternatively 19 employed

  4. TRD -Your Partner for Technical R&D Crystalline Solids

    E-Print Network [OSTI]

    Capecchi, Mario R.

    TRD - Your Partner for Technical R&D Crystalline Solids Wei-Qin (Tony) Tong, Ph.D. Novartis-States Organic Molecular Solid Amorphous Crystalline Polymorphs Solvates/Hydrates Monotropic Enantiotropic is between amorphous and crystalline materials · Solubility ratios of polymorphs are typically independent

  5. Plastic flow in two-dimensional solids Akira Onuki

    E-Print Network [OSTI]

    Plastic flow in two-dimensional solids Akira Onuki Department of Physics, Kyoto University, Kyoto-Landau model of plastic deformation in two-dimensional solids is presented. The fundamental dynamic variables in uniaxial stretching. High-density dislocations produced in plastic flow do not disappear even if the flow

  6. Nikolaos Bonanos Fuel Cells & Solid State Chemistry Dept.

    E-Print Network [OSTI]

    Nikolaos Bonanos Fuel Cells & Solid State Chemistry Dept. Risø, Technical University of Denmark, P Oxide Fuel Cells, Genova, Italy, 22-24 October 2007 nikolaos.bonanos@risoe.dk Materials for SPFCs conductors I: Danish-French workshop on solid state materials for low to medium temperature fuel cells

  7. Absorption spectroscopy in solid hydrogen: challenges to experimentalists and theorists

    E-Print Network [OSTI]

    -rotational spectra. However, when they interact in the gas, liquid, or solid, there are induced dipoles that can interact with radiation. In the solid because of the large lattice constant, these dipoles arise primarily is a quantum crystal, in which the individual molecules undergo almost free rotation and vibration in the hcp

  8. Fast Solid State Gas Sensor Characterization Ruby N. Ghosh1

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Fast Solid State Gas Sensor Characterization Technique Ruby N. Ghosh1 , Peter Tobias1# , Hui Hu2@egr.msu.edu Abstract---- We describe a new technique for character- izing fast solid state planar gas sensors. Using can capture the fast com- ponent of the sensor response as well as the steady state value in a single

  9. Modulated optical solid-state spectrometer applications in plasma diagnostics

    E-Print Network [OSTI]

    Howard, John

    Modulated optical solid-state spectrometer applications in plasma diagnostics John Howard Plasma A new electro-optically modulated optical solid-state MOSS interferometer has been constructed for the measurement of the low order spectral moments of line emission from optically thin radiant media

  10. Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro-

    E-Print Network [OSTI]

    Lin, Xi

    for the commercialization of solid oxide fuel cells (SOFCs) are its high manufacturing and material costs expressed in termsUday Pal Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro- chemical of the SOFC system cost per unit power ($/kW). In this work, anode-supported planar SOFCs were fabricated

  11. Process and material that encapsulates solid hazardous waste

    DOE Patents [OSTI]

    O'Brien, Michael H. (Idaho Falls, ID); Erickson, Arnold W. (Idaho Falls, ID)

    1999-01-01

    A method of encapsulating mixed waste in which a thermoplastic polymer having a melting temperature less than about 150.degree. C. and sulfur and mixed waste are mixed at an elevated temperature not greater than about 200.degree. C. and mixed for a time sufficient to intimately mix the constituents, and then cooled to a solid. The resulting solid is also disclosed.

  12. Fast sampling calorimetry with solid argon ionization chambers

    SciTech Connect (OSTI)

    Clark, E.; Linn, S.; Piekarz, H.; Wahl, H.; Womersley, J.; Hansen, S.; Hurh, P.; Rivetta, C.; Sanders, R.; Schmitt, R.; Stanek, R.; Stefanik, A.

    1992-12-31

    A proposal for the fast sampling calorimetry with solid argon as active medium and the preliminary results from the solid argon test cell are presented. The proposed test calorimeter module structure, the signal routing and the mechanical and cryogenic arrangements are also discussed.

  13. An Unstable Elliptic Free Boundary Problem arising in Solid Combustion

    E-Print Network [OSTI]

    Monneau, Régis

    An Unstable Elliptic Free Boundary Problem arising in Solid Combustion R. Monneau Ecole Nationale in solid combustion. The maximal solution and every local minimizer of the energy are regular, that is, {u combustion, singularity, unstable problem, Aleksandrov reflection, unique blow-up limit, second variation

  14. Enzyme Activity and Biomolecule Templating at Liquid and Solid Interfaces

    SciTech Connect (OSTI)

    Harvey W. Blanch

    2004-12-01

    There are two main components of this research program. The first involves studies of the adsorption and catalytic activity of proteins at fluid-fluid and fluid-solid interfaces; the second employs biological macromolecules as templates at the solid-liquid interface for controlled crystallization of inorganic materials, to provide materials with specific functionality.

  15. Integrating Multiple Solid Oxide Fuel Cell Modules* Burak Ozpineci1

    E-Print Network [OSTI]

    Tolbert, Leon M.

    is growing faster with time. Coal, oil, and other energy sources have been used to generate electricity for more than a century. Today, as conventional fossil energy supplies, such as oil, coal and natural gas of Energy's Solid-State Energy Conversion Alliance (SECA) program [3] is targeting solid oxide fuel cell

  16. Pre-1970 transuranic solid waste at the Hanford Site

    SciTech Connect (OSTI)

    Greenhalgh, W.O.

    1995-05-23

    The document is based on a search of pre-1970 Hanford Solid Waste Records. The available data indicates seven out of thirty-one solid waste burial sites used for pre-1970 waste appear to be Transuranic (TRU). A burial site defined to be TRU contains >100 nCi/gm Transuranic nuclides.

  17. Solid Oxide Fuel Cells Victoria A. Liem and Jeongmin Ahn

    E-Print Network [OSTI]

    Collins, Gary S.

    Solid Oxide Fuel Cells Victoria A. Liem and Jeongmin Ahn Introduction to Multiscale Engineering With the continually increasing demand of fuel in modern times and the long-term goal of sustainability, fuel cell technology has become important and vital to further advancement in energy production. Solid oxide fuel cells

  18. Solid-State NMR Investigation of Block Copolymer Electrolyte Dynamics

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Solid-State NMR Investigation of Block Copolymer Electrolyte Dynamics D. J. Harris,*, T. J in solid polymer electrolytes. The electrolytic properties of lithium salt-doped poly(ethyl- ene oxide- vored candidates for polymer electrolytes.1,2 Some of the primary applications for polymer electrolyte

  19. Tantalum Solid Electrolytic Capacitors/TE TESeries: Type : T

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    Tantalum Solid Electrolytic Capacitors/TE TESeries: Type : T -55 to +125°C 4 to 35 V .DC 0.1 to 330.3 1.3 EIA code 3216 3528 6032 5846 7343 W.V. code W.V. (V) code #12;Tantalum Solid Electrolytic

  20. MultiLayer solid electrolyte for lithium thin film batteries

    DOE Patents [OSTI]

    Lee, Se -Hee; Tracy, C. Edwin; Pitts, John Roland; Liu, Ping

    2015-07-28

    A lithium metal thin-film battery composite structure is provided that includes a combination of a thin, stable, solid electrolyte layer [18] such as Lipon, designed in use to be in contact with a lithium metal anode layer; and a rapid-deposit solid electrolyte layer [16] such as LiAlF.sub.4 in contact with the thin, stable, solid electrolyte layer [18]. Batteries made up of or containing these structures are more efficient to produce than other lithium metal batteries that use only a single solid electrolyte. They are also more resistant to stress and strain than batteries made using layers of only the stable, solid electrolyte materials. Furthermore, lithium anode batteries as disclosed herein are useful as rechargeable batteries.

  1. Degradation in Solid Oxide Cells During High Temperature Electrolysis

    SciTech Connect (OSTI)

    Manohar Sohal

    2009-05-01

    Idaho National Laboratory has an ongoing project to generate hydrogen from steam using solid oxide electrolysis cells. One goal of that project is to address the technical and degradation issues associated with solid oxide electrolysis cells. This report covers a variety of these degradation issues, which were discussed during a workshop on “Degradation in Solid Oxide Electrolysis Cells and Strategies for its Mitigation,” held in Phoenix, AZ on October 27, 2008. Three major degradation issues related to solid oxide electrolysis cells discussed at the workshop are: • Delamination of O2-electrode and bond layer on steam/O2-electrode side • Contaminants (Ni, Cr, Si, etc.) on reaction sites (triple-phase boundary) • Loss of electrical/ionic conductivity of electrolyte. This list is not all inclusive, but the workshop summary can be useful in providing a direction for future research related to the degradation of solid oxide electrolysis cells.

  2. Solid polymer electrolyte composite membrane comprising laser micromachined porous support

    DOE Patents [OSTI]

    Liu, Han (Waltham, MA); LaConti, Anthony B. (Lynnfield, MA); Mittelsteadt, Cortney K. (Natick, MA); McCallum, Thomas J. (Ashland, MA)

    2011-01-11

    A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a rigid, non-electrically-conducting support, the support preferably being a sheet of polyimide having a thickness of about 7.5 to 15 microns. The support has a plurality of cylindrical pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores, which preferably have a diameter of about 5 microns, are made by laser micromachining and preferably are arranged in a defined pattern, for example, with fewer pores located in areas of high membrane stress and more pores located in areas of low membrane stress. The pores are filled with a first solid polymer electrolyte, such as a perfluorosulfonic acid (PFSA) polymer. A second solid polymer electrolyte, which may be the same as or different than the first solid polymer electrolyte, may be deposited over the top and/or bottom of the first solid polymer electrolyte.

  3. Structure formation: Models, Dynamics and Status

    E-Print Network [OSTI]

    T. Padmanabhan

    1995-08-25

    The constraints on the models for the structure formation arising from various cosmological observations at different length scales are reviewed. The status of different models for structure formation is examined critically in the light of these observations.

  4. XML Format for SESAME and LEOS

    SciTech Connect (OSTI)

    Durrenberger, J K; Neely, J R; Sterne, P A

    2009-04-29

    The objective of this document is to describe the XML format used by LLNL and LANL to represent the equation-of-state and related material information in the LEOS and SESAME data libraries. The primary purpose of this document is to describe a specific XML format for representing EOS data that is tailored to the nature of the underlying data and is amenable to conversion to both legacy SESAME and LEOS binary formats. The secondary purpose is to describe an XML format that lends itself to a 'natural' representation in a binary file format of the SESAME, pdb or hdf5 form so that this format and related tools can be used for the rapid and efficient development and implementation of prototype data structures. This document describes the XML format only. A working knowledge of LEOS and SESAME formats is assumed.

  5. Dynamics and control of electromagnetic satellite formations

    E-Print Network [OSTI]

    Ahsun, Umair, 1972-

    2007-01-01

    Satellite formation flying is an enabling technology for many space missions, especially for space-based telescopes. Usually there is a tight formation-keeping requirement that may need constant expenditure of fuel or at ...

  6. Formation damage in underbalanced drilling operations 

    E-Print Network [OSTI]

    Reyes Serpa, Carlos Alberto

    2003-01-01

    Formation damage has long been recognized as a potential source of reduced productivity and injectivity in both horizontal and vertical wells. From the moment that the pay zone is being drilled until the well is put on production, a formation...

  7. La cl informatique Formation Word XP

    E-Print Network [OSTI]

    Vellend, Mark

    La clé informatique Formation Word XP Aide-mémoire Hiver 2004 #12;#12;Formation Word XP Hiver 2004 1. PRÉSENTATION DE L'INTERFACE DE MICROSOFT WORD XP................ 1 1.1. L'interface générale

  8. Proportional structural effects of formative indicators

    E-Print Network [OSTI]

    Franke, George R.; Preacher, Kristopher J.; Rigdon, Ed E.

    2009-03-15

    that are proportional to their effects on the formative construct itself. This constraint has important implications for developing and testing formative models. This study demonstrates the existence of the constraint, shows that researchers must consider...

  9. 13. Sustainability in Practice: Exploring Innovations in Domestic Solid Waste Management in India

    E-Print Network [OSTI]

    Columbia University

    13. Sustainability in Practice: Exploring Innovations in Domestic Solid Waste Management in India environmental conditions, particularly through solid waste management. Solid waste is defined as the organic management system is the framework within which all activities regarding solid waste take place. Solid waste

  10. Treating nahcolite containing formations and saline zones

    DOE Patents [OSTI]

    Vinegar, Harold J

    2013-06-11

    A method for treating a nahcolite containing subsurface formation includes removing water from a saline zone in or near the formation. The removed water is heated using a steam and electricity cogeneration facility. The heated water is provided to the nahcolite containing formation. A fluid is produced from the nahcolite containing formation. The fluid includes at least some dissolved nahcolite. At least some of the fluid is provided to the saline zone.

  11. Solid State Electronics (ECE 103) ECE MS Comp Exam, Fall 2013 (a) Draw the energy band diagram of a piece of Si at room temperature (label the diagram) and

    E-Print Network [OSTI]

    California at San Diego, University of

    Solid State Electronics (ECE 103) ­ ECE MS Comp Exam, Fall 2013 (a) Draw the energy band diagram of a piece of Si at room temperature (label the diagram) and use the band diagram to illustrate the doping (r.t.). (b) Use band diagrams to illustrate the formation of p/n junction. (c) For a p/n+ diode, p-Si

  12. PHYSICAL REVIEW B 88, 144307 (2013) Direct observation of the phonon dispersion of a three-dimensional solid/solid

    E-Print Network [OSTI]

    Deymier, Pierre

    2013-01-01

    Department of Geology, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA 4 Inorganic and ultrasonic phononic crystals.4,7­9 With the recent advances in material fabrication and characterization for solid/solid systems, very few attempts have been made to experimentally characterize dispersion

  13. PHYSICAL REVIEW B 85, 035438 (2012) Enhancing and tuning phonon transport at vibrationally mismatched solid-solid interfaces

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    2012-01-01

    mismatched solid-solid interfaces Timothy S. English,* John C. Duda, Justin L. Smoyer, Donald A. Jordan received 11 December 2011; published 23 January 2012) The thermal conductance of interfaces plays a major interfacial phonon transport as well as the ability to predict thermal interface conductance. However, despite

  14. Electromagnetic Formation Flight of Satellite Arrays

    E-Print Network [OSTI]

    Electromagnetic Formation Flight of Satellite Arrays Daniel W. Kwon and David W. Miller February 2005 SSL # 2-05 #12;#12;Electromagnetic Formation Flight of Satellite Arrays By DANIEL W. KWON S;#12;Electromagnetic Formation Flight of Satellite Arrays by DANIEL W. KWON Submitted to the Department of Aeronautics

  15. SOLID EARTH OPTION FOR EARTH SCIENCE (GYA/GYS) MAJORS The main goals of the Solid Earth option are to give you an understanding of how our lively

    E-Print Network [OSTI]

    Liu, Paul

    SOLID EARTH OPTION FOR EARTH SCIENCE (GYA/GYS) MAJORS The main goals of the Solid Earth option tools we use to unravel its complex history. Solid Earth science is the study of the materials, architecture, and processes of the dynamic solid Earth. It deals with rock-forming minerals and processes

  16. Electrochemical formation of field emitters

    SciTech Connect (OSTI)

    Bernhardt, Anthony F. (Berkeley, CA)

    1999-01-01

    Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area.

  17. Petrophysical evaluation of subterranean formations

    DOE Patents [OSTI]

    Klein, James D; Schoderbek, David A; Mailloux, Jason M

    2013-05-28

    Methods and systems are provided for evaluating petrophysical properties of subterranean formations and comprehensively evaluating hydrate presence through a combination of computer-implemented log modeling and analysis. Certain embodiments include the steps of running a number of logging tools in a wellbore to obtain a variety of wellbore data and logs, and evaluating and modeling the log data to ascertain various petrophysical properties. Examples of suitable logging techniques that may be used in combination with the present invention include, but are not limited to, sonic logs, electrical resistivity logs, gamma ray logs, neutron porosity logs, density logs, NRM logs, or any combination or subset thereof.

  18. Formation Flying and Deformable Instruments

    SciTech Connect (OSTI)

    Rio, Yvon

    2009-05-11

    Astronomers have always attempted to build very stable instruments. They fight all that can cause mechanical deformation or image motion. This has led to well established technologies (autoguide, active optics, thermal control, tip/tilt correction), as well as observing methods based on the use of controlled motion (scanning, micro scanning, shift and add, chopping and nodding). Formation flying disturbs this practice. It is neither possible to reduce the relative motion to very small amplitudes, nor to control it at will. Some impacts on Simbol-X instrument design, and operation are presented.

  19. EXPERIMENTAL METHODS TO ESTIMATE ACCUMULATED SOLIDS IN NUCLEAR WASTE TANKS

    SciTech Connect (OSTI)

    Duignan, M.; Steeper, T.; Steimke, J.

    2012-12-10

    The Department of Energy has a large number of nuclear waste tanks. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles, e.g., plutonium containing, could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids and supernatant were charged to the test tank and rotating liquid jets were used to remove most of the solids. Then the volume and shape of the residual solids and the spatial concentration profiles for the surrogate for plutonium were measured. This paper discusses the overall test results, which indicated heavy solids only accumulate during the first few transfer cycles, along with the techniques and equipment designed and employed in the test. Those techniques include: Magnetic particle separator to remove stainless steel solids, the plutonium surrogate from a flowing stream; Magnetic wand used to manually remove stainless steel solids from samples and the tank heel; Photographs were used to determine the volume and shape of the solids mounds by developing a composite of topographical areas; Laser rangefinders to determine the volume and shape of the solids mounds; Core sampler to determine the stainless steel solids distribution within the solids mounds; Computer driven positioner that placed the laser rangefinders and the core sampler over solids mounds that accumulated on the bottom of a scaled staging tank in locations where jet velocities were low. These devices and techniques were very effective to estimate the movement, location, and concentrations of the solids representing plutonium and are expected to perform well at a larger scale. The operation of the techniques and their measurement accuracies will be discussed as well as the overall results of the accumulated solids test.

  20. Structure of spontaneously formed solid-electrolyte interphase on lithiated graphite determined using small-angle neutron scattering

    SciTech Connect (OSTI)

    Sacci, Robert L [ORNL; Banuelos, Jose Leo [ORNL; Veith, Gabriel M [ORNL; Littrell, Ken [ORNL; Cheng, Yongqiang [ORNL; Wildgruber, Christoph U [ORNL; Jones, Lacy L [ORNL; Ramirez-Cuesta, Anibal J [ORNL; Rother, Gernot [ORNL; Dudney, Nancy J [ORNL

    2015-01-01

    We report the first small-angle neutron scattering of a chemically formed solid-electrolyte interphase from LixC6 reacting with ethylene carbonate/dimethyl carbon solvent. This provides a different and perhaps simpler view of SEI formation than the usual electrochemically-driven reaction. We show that an organic layer coats the graphite particles filling in micro-pores and is polymeric in nature being 1-3 nm thick. We used inelastic neutron scattering to probe the chemistry, and we found that the SEI showed similar inelastic scattering to polyethylene oxide.

  1. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  2. Solid State Replacement of Rotating Mirror Cameras

    SciTech Connect (OSTI)

    Frank, A M; Bartolick, J M

    2006-08-25

    Rotating mirror cameras have been the mainstay of mega-frame per second imaging for decades. There is still no electronic camera that can match a film based rotary mirror camera for the combination of frame count, speed, resolution and dynamic range. The rotary mirror cameras are predominantly used in the range of 0.1 to 100 micro-seconds per frame, for 25 to more than a hundred frames. Electron tube gated cameras dominate the sub microsecond regime but are frame count limited. Video cameras are pushing into the microsecond regime but are resolution limited by the high data rates. An all solid state architecture, dubbed ''In-situ Storage Image Sensor'' or ''ISIS'', by Prof. Goji Etoh, has made its first appearance into the market and its evaluation is discussed. Recent work at Lawrence Livermore National Laboratory has concentrated both on evaluation of the presently available technologies and exploring the capabilities of the ISIS architecture. It is clear though there is presently no single chip camera that can simultaneously match the rotary mirror cameras, the ISIS architecture has the potential to approach their performance.

  3. Photon-counting solid-state photomultiplier

    SciTech Connect (OSTI)

    Petroff, M.D.; Stapelbroek, M.G.

    1989-02-01

    The Solid-State Photomultiplier is a silicon device capable of continuous detection of individual photons in the wave length range from 0.4 to 28 ..mu..m. Operated with an applied bias near 7 volts the device responds to the absorption of an incident photon with a submicrosecond-rise-time current pulse with a narrow amplitude distribution well above the electronic readout noise level. Optimal photon-counting performance occurs between 6 and 10 K and for count rates less than 10/sup 10/ counts/s per cm/sup 2/ of detector area. A 60% counting quantum efficiency has been demonstrated at 20 ..mu..m, and near 60% was observed in the visible light region. The underlying mechanism involves extremely fast internal charge amplification by impact ionization of impurity-band electrons and results in a pulse for each photoelectrically or thermally induced free carrier. The thermally induced dark pulse rate at 7 K is sufficiently low that background limited detector performance is obtained at a background of less than 10/sup 6/ photons/cm/sup 2/s.

  4. Passive tomography for elastic waves in solids

    E-Print Network [OSTI]

    Mikael Carmona; Olivier Michel; Jean-Louis Lacoume; Nathalie Sprynski; Barbara Nicolas

    2011-03-24

    In this paper we derive relations between the cross-correlation of ambient noises recorded at two different points and the Green's function of the elastic waves in a medium with viscous damping. The Green's function allows to estimate physical parameters such as speeds or distances. Furthermore, this work is extended by introducing the Green's correlation function proposed by J-L. Lacoume in [Lacoume07]. Some recent works proved the possible reconstruction of the Green's function for scalar waves from the cross-correlation function of ambient noise. In this work, we consider vector waves propagating in a three dimensional solid medium. Two approaches are developed. Firstly, we extend theoretical derivations proposed by Y. Colin de Verdi`ere in [ColinDeVerdiere09], relating cross-correlation of scalar waves to 1D Green's function using linear operator theory. The second approach recasts the three dimensional problem in the framework of Fourier theory. This allows to improve physical understanding of the underlying physical processes as outlined in [Lacoume07].

  5. Solid oxide fuel cell having monolithic core

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Young, John E. (Woodridge, IL)

    1984-01-01

    A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween, and each interconnect wall consists of thin layers of the cathode and anode materials sandwiching a thin layer of interconnect material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick.

  6. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

    1988-01-01

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  7. Solid oxide fuel cell having monolithic core

    DOE Patents [OSTI]

    Ackerman, J.P.; Young, J.E.

    1983-10-12

    A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

  8. Compact solid source of hydrogen gas

    DOE Patents [OSTI]

    Kravitz, Stanley H.; Hecht, Andrew M.; Sylwester, Alan P.; Bell, Nelson S.

    2004-06-08

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  9. Durability Evaluation of Reversible Solid Oxide Cells

    SciTech Connect (OSTI)

    Xiaoyu Zhang; James E. O'Brien; Robert C. O'Brien; Gregory K. Housley

    2013-11-01

    An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. A new test apparatus for single cell and small stack tests has been developed for this purpose. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

  10. Modeling Degradation in Solid Oxide Electrolysis Cells

    SciTech Connect (OSTI)

    Manohar S. Sohal; Anil V. Virkar; Sergey N. Rashkeev; Michael V. Glazoff

    2010-09-01

    Idaho National Laboratory has an ongoing project to generate hydrogen from steam using solid oxide electrolysis cells (SOECs). To accomplish this, technical and degradation issues associated with the SOECs will need to be addressed. This report covers various approaches being pursued to model degradation issues in SOECs. An electrochemical model for degradation of SOECs is presented. The model is based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic no equilibrium. It is shown that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, , within the electrolyte. The within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just near the oxygen electrode/electrolyte interface, leading to oxygen electrode delamination. These predictions are in accordance with the reported literature on the subject. Development of high pressures may be avoided by introducing some electronic conduction in the electrolyte. By combining equilibrium thermodynamics, no equilibrium (diffusion) modeling, and first-principles, atomic scale calculations were performed to understand the degradation mechanisms and provide practical recommendations on how to inhibit and/or completely mitigate them.

  11. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

  12. Solid Oxide Fuel Cell Systems PVL Line

    SciTech Connect (OSTI)

    Susan Shearer - Stark State College; Gregory Rush - Rolls-Royce Fuel Cell Systems

    2012-05-01

    In July 2010, Stark State College (SSC), received Grant DE-EE0003229 from the U.S. Department of Energy (DOE), Golden Field Office, for the development of the electrical and control systems, and mechanical commissioning of a unique 20kW scale high-pressure, high temperature, natural gas fueled Stack Block Test System (SBTS). SSC worked closely with subcontractor, Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) over a 13 month period to successfully complete the project activities. This system will be utilized by RRFCS for pre-commercial technology development and training of SSC student interns. In the longer term, when RRFCS is producing commercial products, SSC will utilize the equipment for workforce training. In addition to DOE Hydrogen, Fuel Cells, and Infrastructure Technologies program funding, RRFCS internal funds, funds from the state of Ohio, and funding from the DOE Solid State Energy Conversion Alliance (SECA) program have been utilized to design, develop and commission this equipment. Construction of the SBTS (mechanical components) was performed under a Grant from the State of Ohio through Ohio's Third Frontier program (Grant TECH 08-053). This Ohio program supported development of a system that uses natural gas as a fuel. Funding was provided under the Department of Energy (DOE) Solid-state Energy Conversion Alliance (SECA) program for modifications required to test on coal synthesis gas. The subject DOE program provided funding for the electrical build, control system development and mechanical commissioning. Performance testing, which includes electrical commissioning, was subsequently performed under the DOE SECA program. Rolls-Royce Fuel Cell Systems is developing a megawatt-scale solid oxide fuel cell (SOFC) stationary power generation system. This system, based on RRFCS proprietary technology, is fueled with natural gas, and operates at elevated pressure. A critical success factor for development of the full scale system is the capability to test fuel cell components at a scale and under conditions that can be accurately extrapolated to full system performance. This requires specially designed equipment that replicates the pressure (up to 6.5 bara), temperature (about 910 C), anode and cathode gas compositions, flows and power generation density of the full scale design. The SBTS fuel cell anode gas is produced through the reaction of pipeline natural gas with a mixture of steam, CO2, and O2 in a catalytic partial oxidation (CPOX) reactor. Production of the fuel cell anode gas in this manner provides the capability to test a fuel cell with varying anode gas compositions ranging from traditional reformed natural gas to a coal-syngas surrogate fuel. Stark State College and RRFCS have a history of collaboration. This is based upon SSCAs commitment to provide students with skills for advanced energy industries, and RRFCS need for a workforce that is skilled in high temperature fuel cell development and testing. A key to this approach is the access of students to unique SOFC test and evaluation equipment. This equipment is designed and developed by RRFCS, with the participation of SSC interns. In the near-term, the equipment will be used by RRFCS for technology development. When this stage is completed, and RRFCS has moved to commercial products, SSC will utilize this equipment for workforce training. The RRFCS fuel cell design is based upon a unique ceramic substrate architecture in which a porous, flat substrate (tube) provides the support structure for a network of solid oxide fuel cells that are electrically connected in series. These tubes are grouped into a {approx}350-tube repeat configuration, called a stack/block. Stack/block testing, performed at system conditions, provides data that can be confidently scaled to full scale performance. This is the basis for the specially designed and developed test equipment that is required for advancing and accelerating the RRFCS SOFC power system development program. All contract DE-EE0003229 objectives were achieved and deliverables completed during the peri

  13. Solid oxide fuel cell matrix and modules

    DOE Patents [OSTI]

    Riley, Brian (Willimantic, CT)

    1990-01-01

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

  14. Formation and processing of rheocast microstructures

    E-Print Network [OSTI]

    Martínez-Ayers, Raúl Andrés, 1977-

    2004-01-01

    (cont.) given slurry was proposed. The fluidity of rheocast A357 alloy slurries was contrasted with the fluidity of superheated liquid. Rheocast slurries with 37% solid particles,were found to flow about half as far as ...

  15. Electrophoretic Deposition of Highly Efficient Phosphors for White Solid State Lighting using near UV-Emitting LEDs /

    E-Print Network [OSTI]

    Choi, Jae Ik

    2014-01-01

    films for tubular solid oxide fuel cells by electrophoreticfilms for tubular solid oxide fuel cells by electrophoreticdeposition of solid oxide fuel cell material powders,” In:

  16. Mn solid solutions in self-assembled Ge/Si (001) quantum dot heterostructures

    SciTech Connect (OSTI)

    Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

    2012-12-10

    Heteroepitaxial Ge{sub 0.98}Mn{sub 0.02} quantum dots (QDs) on Si (001) were grown by molecular beam epitaxy. The standard Ge wetting layer-hut-dome-superdome sequence was observed, with no indicators of second phase formation in the surface morphology. We show that Mn forms a dilute solid solution in the Ge quantum dot layer, and a significant fraction of the Mn partitions into a sparse array of buried, Mn-enriched silicide precipitates directly underneath a fraction of the Ge superdomes. The magnetic response from the ultra-thin film indicates the absence of robust room temperature ferromagnetism, perhaps due to anomalous intermixing of Si into the Ge quantum dots.

  17. Using XFELs for Probing of Complex Interaction Dynamics of Ultra-Intense Lasers with Solid Matter

    E-Print Network [OSTI]

    Kluge, Thomas; Huang, Lingen; Metzkes, Josefine; Schramm, Ulrich; Bussmann, Michael; Cowan, Thomas E

    2013-01-01

    We demonstrate the potential of X-ray free-electron lasers (XFEL) to advancethe understanding of complex plasma dynamics by allowing for the first time nanometer and femtosecond resolution at the same time in plasma diagnostics. Plasma phenomena on such short timescales are of high relevance for many fields of physics, in particular in the ultra-intense ultra-short laser interaction with matter. Highly relevant yet only partially understood phenomena may become directly accessible in experiment. These include relativistic laser absorption at solid targets, creation of energetic electrons and electron transport in warm dense matter, including the seeding and development of surface and beam instabilities, ambipolar expansion, shock formation, and dynamics at the surfaces or at buried layers. We demonstrate the potentials of XFEL plasma probing for high power laser matter interactions using exemplary the small angle X-ray scattering technique, focusing on general considerations for XFEL probing.

  18. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

    1981-02-19

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  19. Semiconductor nanocrystals covalently bound to solid inorganic surfaces using self-assembled monolayers

    DOE Patents [OSTI]

    Alivisatos, A.P.; Colvin, V.L.

    1998-05-12

    Methods are described for attaching semiconductor nanocrystals to solid inorganic surfaces, using self-assembled bifunctional organic monolayers as bridge compounds. Two different techniques are presented. One relies on the formation of self-assembled monolayers on these surfaces. When exposed to solutions of nanocrystals, these bridge compounds bind the crystals and anchor them to the surface. The second technique attaches nanocrystals already coated with bridge compounds to the surfaces. Analyses indicate the presence of quantum confined clusters on the surfaces at the nanolayer level. These materials allow electron spectroscopies to be completed on condensed phase clusters, and represent a first step towards synthesis of an organized assembly of clusters. These new products are also disclosed. 10 figs.

  20. Semiconductor nanocrystals covalently bound to solid inorganic surfaces using self-assembled monolayers

    DOE Patents [OSTI]

    Alivisatos, A. Paul (Berkeley, CA); Colvin, Vicki L. (Berkeley, CA)

    1998-01-01

    Methods are described for attaching semiconductor nanocrystals to solid inorganic surfaces, using self-assembled bifunctional organic monolayers as bridge compounds. Two different techniques are presented. One relies on the formation of self-assembled monolayers on these surfaces. When exposed to solutions of nanocrystals, these bridge compounds bind the crystals and anchor them to the surface. The second technique attaches nanocrystals already coated with bridge compounds to the surfaces. Analyses indicate the presence of quantum confined clusters on the surfaces at the nanolayer level. These materials allow electron spectroscopies to be completed on condensed phase clusters, and represent a first step towards synthesis of an organized assembly of clusters. These new products are also disclosed.

  1. Recovery of the actinides by electrochemical methods in molten chlorides using solid aluminium cathode

    SciTech Connect (OSTI)

    Malmbeck, R.; Mendes, E.; Serp, J.; Soucek, P.; Glatz, J.P. [European Commission, JRC, Institute for Transuranium Elements, Postfach 2340, 76125 Karlsruhe (Germany); Cassayre, L. [Laboratoire de Genie Chimique - LGC, Universite Paul Sabatier, UMR 5503, 118 route de Narbonne, 31062 Toulouse Cedex 04 (France)

    2007-07-01

    An electrorefining process in molten chloride salts is being developed at ITU to reprocess the spent nuclear fuel. According to the thermochemical properties of the system, aluminium is the most promising electrode material for the separation of actinides (An) from lanthanides (Ln). The actinides are selectively reduced from the fission products and stabilized by the formation of solid and compact actinide-aluminium alloys with the reactive cathode material. In this work, the maximum loading of aluminium with actinides was investigated by potentiostatic and galvano-static electrorefining of U-Pu- Zr alloys. A very high aluminium capacity was achieved, as the average loading was 1.6 g of U and Pu into 1 g of aluminium and the maximum achieved loading was 2.3 g. For recovery of the actinides from aluminium, a process based on chlorination and a subsequent sublimation of AlCl{sub 3} is proposed. (authors)

  2. Method of Fabrication of High Power Density Solid Oxide Fuel Cells

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

    2008-09-09

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O(LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  3. Heating tar sands formations while controlling pressure

    DOE Patents [OSTI]

    Stegemeier, George Leo (Houston, TX) [Houston, TX; Beer, Gary Lee (Houston, TX) [Houston, TX; Zhang, Etuan (Houston, TX) [Houston, TX

    2010-01-12

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. A pressure in the majority of the section may be maintained below a fracture pressure of the formation. The pressure in the majority of the section may be reduced to a selected pressure after the average temperature reaches a temperature that is above 240.degree. C. and is at or below pyrolysis temperatures of hydrocarbons in the section. At least some hydrocarbon fluids may be produced from the formation.

  4. Coring in deep hardrock formations

    SciTech Connect (OSTI)

    Drumheller, D.S.

    1988-08-01

    The United States Department of Energy is involved in a variety of scientific and engineering feasibility studies requiring extensive drilling in hard crystalline rock. In many cases well depths extend from 6000 to 20,000 feet in high-temperature, granitic formations. Examples of such projects are the Hot Dry Rock well system at Fenton Hill, New Mexico and the planned exploratory magma well near Mammoth Lakes, California. In addition to these programs, there is also continuing interest in supporting programs to reduce drilling costs associated with the production of geothermal energy from underground sources such as the Geysers area near San Francisco, California. The overall progression in these efforts is to drill deeper holes in higher temperature, harder formations. In conjunction with this trend is a desire to improve the capability to recover geological information. Spot coring and continuous coring are important elements in this effort. It is the purpose of this report to examine the current methods used to obtain core from deep wells and to suggest projects which will improve existing capabilities. 28 refs., 8 figs., 2 tabs.

  5. Coke formation in visbreaking process

    SciTech Connect (OSTI)

    Yan, T.Y. )

    1987-04-01

    Visbreaking is a mild cracking process primarily used to reduce residual oil viscosity and thus decrease the amount of cutter stock required for blending to heavy fuels specification. It can also be used to produce incremental quantities of gasoline, middle distillates and catalytic cracker feeds. This process was widely used in the 1930s and 1940s and became obsolete until a few years ago. When the need for increased conversion of residues to light products became desirable, visbreaking offered economic advantages to many refining schemes - especially in Western Europe. Between 1978-1981, Exxon brought on stream seven visbreakers ranging from 1900 to 9100 tons/SD capacity. In January 1983, the world-wide visbreaking capacity was over 2 MM B/SD. The visbreaking process and its application in refinery operations have been well described. In general, the process economics improve as the process severity is increased but it is limited by coke formation in the process. For this reason, they have studied the kinetics of coke formation in the visbreaking process.

  6. Capillary adhesion between elastic solids with randomly rough surfaces

    E-Print Network [OSTI]

    B. N. J. Persson

    2008-05-06

    I study how the contact area and the work of adhesion, between two elastic solids with randomly rough surfaces, depend on the relative humidity. The surfaces are assumed to be hydrophilic, and capillary bridges form at the interface between the solids. For elastically hard solids with relative smooth surfaces, the area of real contact and therefore also the sliding friction, are maximal when there is just enough liquid to fill out the interfacial space between the solids, which typically occurs for $d_{\\rm K} \\approx 3 h_{\\rm rms}$, where $d_{\\rm K}$ is the height of the capillary bridge and $h_{\\rm rms}$ the root-mean-square roughness of the (combined) surface roughness profile. For elastically soft solids, the area of real contact is maximal for very low humidity (i.e., small $d_{\\rm K}$), where the capillary bridges are able to pull the solids into nearly complete contact. In both case, the work of adhesion is maximal (and equal to $2\\gamma {\\rm cos}\\theta$, where $\\gamma$ is the liquid surface tension and $\\theta$ the liquid-solid contact angle) when $d_{\\rm K} >> h_{\\rm rms}$, corresponding to high relative humidity.

  7. Solid Waste Management in Vietnam An Industrial Ecology Study by Thao Nguyen

    E-Print Network [OSTI]

    Columbia University

    Solid Waste Management in Vietnam An Industrial Ecology Study by Thao Nguyen School greatly magnified the problems with Vietnam's solid waste management system, pushing waste management ..................................................................................................................................3 3. Solid Waste Management in Vietnam 3.1 Generation and Components

  8. Development of a Segregated Municipal Solid Waste Gasification System for Electrical Power Generation 

    E-Print Network [OSTI]

    Maglinao, Amado Latayan

    2013-04-11

    Gasification technologies are expected to play a key role in the future of solid waste management since the conversion of municipal and industrial solid wastes to a gaseous fuel significantly increases its value. Municipal solid waste (MSW...

  9. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    Films for Solid Oxide Fuel Cell Applications by Jason Dalefor Solid Oxide Fuel Cell Applications Copyright 2007 byFilms for Solid Oxide Fuel Cell Applications by Jason Dale

  10. Solid-State Lighting Patents Resulting from DOE-Funded Projects...

    Energy Savers [EERE]

    Solid-State Lighting Patents Resulting from DOE-Funded Projects Solid-State Lighting Patents Resulting from DOE-Funded Projects 2013 DOE Solid-State Lighting Program Fact Sheet...

  11. Transport properties of the solid polymer electrolyte system P(EO)nLiTFSI

    E-Print Network [OSTI]

    Edman, L.

    2011-01-01

    Properties of the Solid Polymer Electrolyte System P(EO)Properties of the Solid Polymer Electrolyte System P(EO)~Properties of the Solid Polymer Electrolyte System P(EO)~

  12. DIRECT SOLID-STATE PRECIPITATION PROCESSED A-15 (Nb3Al) SUPERCONDUCTING MATERIAL

    E-Print Network [OSTI]

    Hong, M.

    2010-01-01

    Letters DIRECT SOLID-STATE PRECIPITATION PROCESSED A-15 (Nb48 DIRECT SOLID-STATE PRECIPITATION PROCESSED A-IS (Nb Al)ABSTRACT A "solid~state precipitation" process was used to

  13. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.Tubular Solid Oxide Fuel Cell Technology, U.S. Department ofOxide Films for Solid Oxide Fuel Cell Applications by Jason

  14. Isothermal Solid-State Transformation Kinetics Applied to Pd/Cu Alloy Membrane Fabrication

    SciTech Connect (OSTI)

    Pomerantz, Natalie L; Payzant, E Andrew; Ma, Yi Hua

    2010-01-01

    In this work, time-resolved, in situ high-temperature X-ray diffraction (HT-XRD) was used to study the solid-state transformation kinetics of the formation of the fcc Pd/Cu alloy from Pd/Cu bi-layers for the purpose of fabricating sulfur tolerant Pd/Cu membranes for H2 separation. Thin layers of Pd and Cu (total ~15 wt% Cu) were deposited on porous stainless steel (PSS) with the electroless deposition method and annealed in H2 at 500, 550 and 600 C. The kinetics of the annealing process were successfully described by the Avrami nucleation and growth model showing that the annealing process was diffusion controlled and one dimensional. The activation energy for the solid-state transformation was 175 kJ/mol, which was similar to the activation energy of Pd-Cu bulk interdiffusion. Furthermore, the Avrami model was able to successfully describe the changes in permeance and activation energy observed in Pd/Cu alloy membranes during characterization as they were annealed at high temperatures.

  15. Method for solid state crystal growth

    DOE Patents [OSTI]

    Nolas, George S.; Beekman, Matthew K.

    2013-04-09

    A novel method for high quality crystal growth of intermetallic clathrates is presented. The synthesis of high quality pure phase crystals has been complicated by the simultaneous formation of both clathrate type-I and clathrate type-II structures. It was found that selective, phase pure, single-crystal growth of type-I and type-II clathrates can be achieved by maintaining sufficient partial pressure of a chemical constituent during slow, controlled deprivation of the chemical constituent from the primary reactant. The chemical constituent is slowly removed from the primary reactant by the reaction of the chemical constituent vapor with a secondary reactant, spatially separated from the primary reactant, in a closed volume under uniaxial pressure and heat to form the single phase pure crystals.

  16. Meeting Department of Defense non-hazardous solid waste goals

    SciTech Connect (OSTI)

    Eakes, W.S.; Comstock, J.

    1999-07-01

    This paper will discuss the previous and present Department of Defense (DOD) non-hazardous solid waste goals and how Navy and Marine Corps installation collect solid waste data and measure the goals. The installation and central data collection systems used, data collection problems and solutions, data quality, and the yearly measure. The paper will also discuss the original solid waste reduction and diversion goal and how the Navy and Marine Corps performed. The new DOD landfill and incineration diversion goal will be discussed and some techniques the Navy will use to meet the new goals.

  17. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus; Crumlin, Ethan J.; Mao, Baohua; Rani, Sana; Chang, Rui; Karlsson, Patrik G.; Edwards, Mårten O. M.; Lundqvist, Måns; Moberg, Robert; Ross, Phil; et al

    2015-05-07

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquidmore »and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.« less

  18. Using “Tender” x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Crumlin, Ethan J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Mao, Baohua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Rani, Sana [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chang, Rui [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Karlsson, Patrik G. [VG Scienta,Uppsala (Sweden); Edwards, Mårten O. M. [VG Scienta,Uppsala (Sweden); Lundqvist, Måns [VG Scienta,Uppsala (Sweden); Moberg, Robert [VG Scienta,Uppsala (Sweden); Ross, Phil [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hussain, Zahid [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Liu, Zhi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)

    2015-05-07

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a “dip & pull” method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, “dip & pull” approach, with a “tender” X-ray synchrotron source (2 keV–7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt²? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of “tender” AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.

  19. Solid polymer electrolyte from phosphorylated chitosan

    SciTech Connect (OSTI)

    Fauzi, Iqbal Arcana, I Made

    2014-03-24

    Recently, the need of secondary battery application continues to increase. The secondary battery which using a liquid electrolyte was indicated had some weakness. A solid polymer electrolyte is an alternative electrolytes membrane which developed in order to replace the liquid electrolyte type. In the present study, the effect of phosphorylation on to polymer electrolyte membrane which synthesized from chitosan and lithium perchlorate salts was investigated. The effect of the component’s composition respectively on the properties of polymer electrolyte, was carried out by analyzed of it’s characterization such as functional groups, ion conductivity, and thermal properties. The mechanical properties i.e tensile resistance and the morphology structure of membrane surface were determined. The phosphorylation processing of polymer electrolyte membrane of chitosan and lithium perchlorate was conducted by immersing with phosphoric acid for 2 hours, and then irradiated on a microwave for 60 seconds. The degree of deacetylation of chitosan derived from shrimp shells was obtained around 75.4%. Relative molecular mass of chitosan was obtained by viscometry method is 796,792 g/mol. The ionic conductivity of chitosan membrane was increase from 6.33 × 10{sup ?6} S/cm up to 6.01 × 10{sup ?4} S/cm after adding by 15 % solution of lithium perchlorate. After phosphorylation, the ionic conductivity of phosphorylated lithium chitosan membrane was observed 1.37 × 10{sup ?3} S/cm, while the tensile resistance of 40.2 MPa with a better thermal resistance. On the strength of electrolyte membrane properties, this polymer electrolyte membrane was suggested had one potential used for polymer electrolyte in field of lithium battery applications.

  20. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich`s solution and analysis.