National Library of Energy BETA

Sample records for forecast 4 3

  1. 3TIER Environmental Forecast Group Inc 3TIER | Open Energy Information

    Open Energy Info (EERE)

    TIER Environmental Forecast Group Inc 3TIER Jump to: navigation, search Name: 3TIER Environmental Forecast Group Inc (3TIER) Place: Seattle, Washington Zip: 98121 Sector: Renewable...

  2. Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4

    U.S. Energy Information Administration (EIA) Indexed Site

    Current Forecast: March 8, 2016; Previous Forecast: February 9, 2016 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 2014 2015 2016 2017 2014-2015 2015-2016 2016-2017 U.S. Energy Supply U.S. ...

  3. RACORO Forecasting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hartsock CIMMS, University of Oklahoma  ARM AAF Wiki page  Weather Briefings  Observed Weather  Cloud forecasting models  BUFKIT forecast soundings + guidance from Norman NWS enhanced pages and discussions NAM-WRF updated twice/day (12Z and 00Z) Forecast out to 84-hours RUC (updated every 3 hours) Operational RUC forecast only goes out 12 hours (developmental out 24 hours)

  4. Gasoline price forecast to stay below 3 dollar a gallon in 2015

    Gasoline and Diesel Fuel Update (EIA)

    Gasoline price forecast to stay below $3 a gallon in 2015 The national average pump price of gasoline is expected to stay below $3 per gallon during 2015. In its new monthly forecast, the U.S. Energy Information Administration said the retail price for regular gasoline should average $2.33 per gallon this year. The price of gasoline increased in early February after falling for 17 weeks in a row. But gasoline prices will continue to remain low in 2015 when compared with pump prices in recent

  5. BEAMLINE 4-3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4-3 CURRENT STATUS: Open SUPPORTED TECHNIQUES: X-ray Absorption Spectroscopy MAIN SCIENTIFIC DISCIPLINES: Environmental Materials Biology % TIME GENERAL USE: 100% SCHEDULING:...

  6. Preparation of 3,3'-diamino-4,4'-azofurazan

    DOE Patents [OSTI]

    Hiskey, Michael A. (Los Alamos, NM); Chavez, David E. (Ranchos de Taos, NM); Bishop, Robert L. (Santa Fe, NM); Kramer, John F. (Santa Fe, NM); Kinkead, Scott A. (Los Alamos, NM)

    2003-04-22

    A method of preparing 3,3'-diamino-4,4'-azofurazan is provided together with a composition of matter including a mixture of 3,3'-diamino-4,4'-azofurazan and 1,3,5-triamino-2,4,6-trinitrobenzene.

  7. Why Models Don%3CU%2B2019%3Et Forecast.

    SciTech Connect (OSTI)

    McNamara, Laura A.

    2010-08-01

    The title of this paper, Why Models Don't Forecast, has a deceptively simple answer: models don't forecast because people forecast. Yet this statement has significant implications for computational social modeling and simulation in national security decision making. Specifically, it points to the need for robust approaches to the problem of how people and organizations develop, deploy, and use computational modeling and simulation technologies. In the next twenty or so pages, I argue that the challenge of evaluating computational social modeling and simulation technologies extends far beyond verification and validation, and should include the relationship between a simulation technology and the people and organizations using it. This challenge of evaluation is not just one of usability and usefulness for technologies, but extends to the assessment of how new modeling and simulation technologies shape human and organizational judgment. The robust and systematic evaluation of organizational decision making processes, and the role of computational modeling and simulation technologies therein, is a critical problem for the organizations who promote, fund, develop, and seek to use computational social science tools, methods, and techniques in high-consequence decision making.

  8. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Beamline 1.4.3 Print Tuesday, 20 October 2009 08:08 FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science,...

  9. 3D cloud detection and tracking system for solar forecast using multiple sky imagers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Zhenzhou; Yu, Dantong; Huang, Dong; Heiser, John; Yoo, Shinjae; Kalb, Paul

    2015-06-23

    We propose a system for forecasting short-term solar irradiance based on multiple total sky imagers (TSIs). The system utilizes a novel method of identifying and tracking clouds in three-dimensional space and an innovative pipeline for forecasting surface solar irradiance based on the image features of clouds. First, we develop a supervised classifier to detect clouds at the pixel level and output cloud mask. In the next step, we design intelligent algorithms to estimate the block-wise base height and motion of each cloud layer based on images from multiple TSIs. Thus, this information is then applied to stitch images together intomore » larger views, which are then used for solar forecasting. We examine the system’s ability to track clouds under various cloud conditions and investigate different irradiance forecast models at various sites. We confirm that this system can 1) robustly detect clouds and track layers, and 2) extract the significant global and local features for obtaining stable irradiance forecasts with short forecast horizons from the obtained images. Finally, we vet our forecasting system at the 32-megawatt Long Island Solar Farm (LISF). Compared with the persistent model, our system achieves at least a 26% improvement for all irradiance forecasts between one and fifteen minutes.« less

  10. 3D cloud detection and tracking system for solar forecast using multiple sky imagers

    SciTech Connect (OSTI)

    Peng, Zhenzhou; Yu, Dantong; Huang, Dong; Heiser, John; Yoo, Shinjae; Kalb, Paul

    2015-06-23

    We propose a system for forecasting short-term solar irradiance based on multiple total sky imagers (TSIs). The system utilizes a novel method of identifying and tracking clouds in three-dimensional space and an innovative pipeline for forecasting surface solar irradiance based on the image features of clouds. First, we develop a supervised classifier to detect clouds at the pixel level and output cloud mask. In the next step, we design intelligent algorithms to estimate the block-wise base height and motion of each cloud layer based on images from multiple TSIs. Thus, this information is then applied to stitch images together into larger views, which are then used for solar forecasting. We examine the system’s ability to track clouds under various cloud conditions and investigate different irradiance forecast models at various sites. We confirm that this system can 1) robustly detect clouds and track layers, and 2) extract the significant global and local features for obtaining stable irradiance forecasts with short forecast horizons from the obtained images. Finally, we vet our forecasting system at the 32-megawatt Long Island Solar Farm (LISF). Compared with the persistent model, our system achieves at least a 26% improvement for all irradiance forecasts between one and fifteen minutes.

  11. Forecasting Flu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forecasting Flu March 6, 2016 Forecasting Flu What if we could forecast infectious diseases the same way we forecast the weather, and predict how diseases like Dengue, Typhus or Zika were going to spread? Using real-time data from Wikipedia and social media, Sara del Valle and her team from Los Alamos National Laboratory have developed a global disease-forecasting system that will improve the way we respond to epidemics. Using this model, individuals and public health officials can monitor

  12. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials...

  13. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL...

  14. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 4.0.3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA)

  15. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 4.0.3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA)

  16. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 4.0.3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA)

  17. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  18. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  19. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  20. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  1. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  2. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  3. Beamline 4.0.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High-resolution spectroscopy of complex materials (MERLIN) Endstations: 4.0.3.1: High-resolution inelastic scattering (MERIXS) 4.0.3.2: Angle-resolved photoemission spectroscopy (ARPES) GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics 9.0-cm-period quasiperiodic elliptical polarization undulator (EPU9) Energy range 9eV-120eV with current gratings Monochromator Variable-included-angle spherical grating monochromator (SGM) Calculated flux (1.9 GeV, 400 mA) 1012

  4. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution,

  5. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution,

  6. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution,

  7. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution,

  8. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 1.4.3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution,

  9. Simulations of Clouds and Sensitivity Study by Weather Research and Forecast Model for Atmospheric Radiation Measurement Case 4

    SciTech Connect (OSTI)

    Wu, J.; Zhang, M.

    2005-03-18

    One of the large errors in general circulation models (GCMs) cloud simulations is from the mid-latitude, synoptic-scale frontal cloud systems. Now, with the availability of the cloud observations from Atmospheric Radiation Measurement (ARM) 2000 cloud Intensive Operational Period (IOP) and other observational datasets, the community is able to document the model biases in comparison with the observations and make progress in development of better cloud schemes in models. Xie et al. (2004) documented the errors in midlatitude frontal cloud simulations for ARM Case 4 by single-column models (SCMs) and cloud resolving models (CRMs). According to them, the errors in the model simulated cloud field might be caused by following reasons: (1) lacking of sub-grid scale variability; (2) lacking of organized mesoscale cyclonic advection of hydrometeors behind a moving cyclone which may play important role to generate the clouds there. Mesoscale model, however, can be used to better under stand these controls on the subgrid variability of clouds. Few studies have focused on applying mesoscale models to the forecasting of cloud properties. Weaver et al. (2004) used a mesoscale model RAMS to study the frontal clouds for ARM Case 4 and documented the dynamical controls on the sub-GCM-grid-scale cloud variability.

  10. 4-fluoroalkyl-3-halophenyl nortropanes

    DOE Patents [OSTI]

    Goodman, Mark M. (Atlanta, GA); Chen, Ping (Indianapolis, IN)

    2002-06-04

    A series of compounds in the 4-fluoroalkyl-3-halophenyl nortropanes family are described as diagnostic and therapeutic agents for diseases associated with serotonin transporter dysfunction. These compounds bind to serotonin transporter protein with high affinity and selectivity. The invention provides methods of synthesis which incorporate radioisotopic halogens at a last step which permit high radiochemical yield and maximum usable product life. The radiolabeled compounds of the invention are useful as imaging agents for visualizing the location and density of serotonin transporter by PET and SPECT imaging.

  11. Use of 3,3'-diamino-4,4'-azoxyfurazan and 3,3'-diamino-4,4'-azofurazan as insensitive high explosive materials

    DOE Patents [OSTI]

    Hiskey, Michael A. (Los Alamos, NM); Chavez, David E. (Ranchos de Taos, NM); Bishop, Robert L. (Santa Fe, NM); Kramer, John F. (Santa Fe, NM); Kinkead, Scott A. (Los Alamos, NM)

    2002-01-01

    A method of preparing 3,3'-diamino-4,4'-azofurazan is provided together with a composition of matter including a mixture of 3,3'-diamino-4,4'-azofurazan and 1,3,5-triamino-2,4,6-trinitrobenzene.

  12. Acquisition Forecast

    Broader source: Energy.gov [DOE]

    It is the policy of the Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) to provide timely information to the public regarding DOE/NNSA’s forecast of future prime contracting opportunities and subcontracting opportunities which are available via the Department’s major site and facilities management contractors.

  13. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 4.2-730 K Scientific disciplines Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials Scientific applications Biological...

  14. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE...

  15. Picture of the Week: Forecasting Flu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Forecasting Flu What if we could forecast infectious diseases the same way we forecast the weather, and predict how diseases like Dengue, Typhus or Zika were going to spread? March 6, 2016 flu epidemics modellled using social media Watch the video on YouTube. Forecasting Flu What if we could forecast infectious diseases the same way we forecast the weather, and predict how diseases like Dengue, Typhus or Zika were going to spread? Using real-time data from Wikipedia and social media, Sara del

  16. tablehc4.3.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Income Relative to Poverty Line Below 100 Percent......0.3 1.0 1.6 Q 1. Below 150 percent of poverty line or 60 percent of median State ...

  17. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range...

  18. chap4_3.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E* REFERENCES pbar + A Berlin ncp Ball: PLB 423, 21 (1998); p, p,3He + A ISiS: PRL 77, ... of K CP A 30 MeV and that employed by ISiS, K 30 MeV for protons and K CP 9Z + 30 ...

  19. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution, reflection,

  20. Beamline 1.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print FTIR spectromicroscopy Scientific disciplines: Biology, correlated electron systems, environmental science, geology, chemistry, polymers, soft materials GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 0.05-1.2 eV Frequency range 650 - 10,000 cm-1 Interferometer resolution Up to 0.125 cm-1 Endstations Nicolet Magna 760 FTIR, Nic-Plan IR Microscope (N2 purged) Characteristics Motorized sample stage, 0.1-micron resolution, reflection,

  1. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range 20-10,000 cm-1 Interferometer resolution 0.00096 cm-1 Endstations Bruker IFS 125HR with 9 scanner chambers Characteristics High resolution Far-IR to Mid-IR spectroscopy primarily for gas phase and cluster samples. Spatial resolution ~1 mm Detectors Wide-range MCT-A (mercury cadmium telluride), Si Bolometer, DLATGS, hot

  2. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range 20-10,000 cm-1 Interferometer resolution 0.00096 cm-1 Endstations Bruker IFS 125HR with 9 scanner chambers Characteristics High resolution Far-IR to Mid-IR spectroscopy primarily for gas phase and cluster samples. Spatial resolution ~1 mm Detectors Wide-range MCT-A (mercury cadmium telluride), Si Bolometer, DLATGS, hot

  3. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range 20-10,000 cm-1 Interferometer resolution 0.00096 cm-1 Endstations Bruker IFS 125HR with 9 scanner chambers Characteristics High resolution Far-IR to Mid-IR spectroscopy primarily for gas phase and cluster samples. Spatial resolution ~1 mm Detectors Wide-range MCT-A (mercury cadmium telluride), Si Bolometer, DLATGS, hot

  4. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range 20-10,000 cm-1 Interferometer resolution 0.00096 cm-1 Endstations Bruker IFS 125HR with 9 scanner chambers Characteristics High resolution Far-IR to Mid-IR spectroscopy primarily for gas phase and cluster samples. Spatial resolution ~1 mm Detectors Wide-range MCT-A (mercury cadmium telluride), Si Bolometer, DLATGS, hot

  5. Beamline 5.4.3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Print High resolution far-IR to mid-IR spectroscopy GENERAL BEAMLINE INFORMATION Operational 2011 Source characteristics Bend magnet Energy range 0.002-1.0 eV Frequency range 20-10,000 cm-1 Interferometer resolution 0.00096 cm-1 Endstations Bruker IFS 125HR with 9 scanner chambers Characteristics High resolution Far-IR to Mid-IR spectroscopy primarily for gas phase and cluster samples. Spatial resolution ~1 mm Detectors Wide-range MCT-A (mercury cadmium telluride), Si Bolometer, DLATGS, hot

  6. Wind Forecasting Improvement Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forecasting Improvement Project Wind Forecasting Improvement Project October 3, 2011 - 12:12pm Addthis This is an excerpt from the Third Quarter 2011 edition of the Wind Program R&D Newsletter. In July, the Department of Energy launched a $6 million project with the National Oceanic and Atmospheric Administration (NOAA) and private partners to improve wind forecasting. Wind power forecasting allows system operators to anticipate the electrical output of wind plants and adjust the electrical

  7. Development and testing of improved statistical wind power forecasting methods.

    SciTech Connect (OSTI)

    Mendes, J.; Bessa, R.J.; Keko, H.; Sumaili, J.; Miranda, V.; Ferreira, C.; Gama, J.; Botterud, A.; Zhou, Z.; Wang, J.

    2011-12-06

    Wind power forecasting (WPF) provides important inputs to power system operators and electricity market participants. It is therefore not surprising that WPF has attracted increasing interest within the electric power industry. In this report, we document our research on improving statistical WPF algorithms for point, uncertainty, and ramp forecasting. Below, we provide a brief introduction to the research presented in the following chapters. For a detailed overview of the state-of-the-art in wind power forecasting, we refer to [1]. Our related work on the application of WPF in operational decisions is documented in [2]. Point forecasts of wind power are highly dependent on the training criteria used in the statistical algorithms that are used to convert weather forecasts and observational data to a power forecast. In Chapter 2, we explore the application of information theoretic learning (ITL) as opposed to the classical minimum square error (MSE) criterion for point forecasting. In contrast to the MSE criterion, ITL criteria do not assume a Gaussian distribution of the forecasting errors. We investigate to what extent ITL criteria yield better results. In addition, we analyze time-adaptive training algorithms and how they enable WPF algorithms to cope with non-stationary data and, thus, to adapt to new situations without requiring additional offline training of the model. We test the new point forecasting algorithms on two wind farms located in the U.S. Midwest. Although there have been advancements in deterministic WPF, a single-valued forecast cannot provide information on the dispersion of observations around the predicted value. We argue that it is essential to generate, together with (or as an alternative to) point forecasts, a representation of the wind power uncertainty. Wind power uncertainty representation can take the form of probabilistic forecasts (e.g., probability density function, quantiles), risk indices (e.g., prediction risk index) or scenarios (with spatial and/or temporal dependence). Statistical approaches to uncertainty forecasting basically consist of estimating the uncertainty based on observed forecasting errors. Quantile regression (QR) is currently a commonly used approach in uncertainty forecasting. In Chapter 3, we propose new statistical approaches to the uncertainty estimation problem by employing kernel density forecast (KDF) methods. We use two estimators in both offline and time-adaptive modes, namely, the Nadaraya-Watson (NW) and Quantilecopula (QC) estimators. We conduct detailed tests of the new approaches using QR as a benchmark. One of the major issues in wind power generation are sudden and large changes of wind power output over a short period of time, namely ramping events. In Chapter 4, we perform a comparative study of existing definitions and methodologies for ramp forecasting. We also introduce a new probabilistic method for ramp event detection. The method starts with a stochastic algorithm that generates wind power scenarios, which are passed through a high-pass filter for ramp detection and estimation of the likelihood of ramp events to happen. The report is organized as follows: Chapter 2 presents the results of the application of ITL training criteria to deterministic WPF; Chapter 3 reports the study on probabilistic WPF, including new contributions to wind power uncertainty forecasting; Chapter 4 presents a new method to predict and visualize ramp events, comparing it with state-of-the-art methodologies; Chapter 5 briefly summarizes the main findings and contributions of this report.

  8. UPF Forecast | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UPF Forecast UPF Forecast UPF Procurement provides the following forecast of subcontracting opportunities. Keep in mind that these requirements may be revised or cancelled, depending on program budget funding or departmental needs. If you have questions or would like to express an interest in any of the opportunities listed below, contact UPF Procurement. Descriptiona Methodb NAICS Est. Dollar Range RFP release/ Award datec Buyer/ Phone Commodities Equipment Rental FOC 238910 TBD 3Q FY15/ 3Q

  9. The Wind Forecast Improvement Project (WFIP): A Public/Private Partnership for Improving Short Term Wind Energy Forecasts and Quantifying the Benefits of Utility Operations. The Southern Study Area, Final Report

    SciTech Connect (OSTI)

    Freedman, Jeffrey M.; Manobianco, John; Schroeder, John; Ancell, Brian; Brewster, Keith; Basu, Sukanta; Banunarayanan, Venkat; Hodge, Bri-Mathias; Flores, Isabel

    2014-04-30

    This Final Report presents a comprehensive description, findings, and conclusions for the Wind Forecast Improvement Project (WFIP) -- Southern Study Area (SSA) work led by AWS Truepower (AWST). This multi-year effort, sponsored by the Department of Energy (DOE) and National Oceanographic and Atmospheric Administration (NOAA), focused on improving short-term (15-minute - 6 hour) wind power production forecasts through the deployment of an enhanced observation network of surface and remote sensing instrumentation and the use of a state-of-the-art forecast modeling system. Key findings from the SSA modeling and forecast effort include: 1. The AWST WFIP modeling system produced an overall 10 - 20% improvement in wind power production forecasts over the existing Baseline system, especially during the first three forecast hours; 2. Improvements in ramp forecast skill, particularly for larger up and down ramps; 3. The AWST WFIP data denial experiments showed mixed results in the forecasts incorporating the experimental network instrumentation; however, ramp forecasts showed significant benefit from the additional observations, indicating that the enhanced observations were key to the model systems’ ability to capture phenomena responsible for producing large short-term excursions in power production; 4. The OU CAPS ARPS simulations showed that the additional WFIP instrument data had a small impact on their 3-km forecasts that lasted for the first 5-6 hours, and increasing the vertical model resolution in the boundary layer had a greater impact, also in the first 5 hours; and 5. The TTU simulations were inconclusive as to which assimilation scheme (3DVAR versus EnKF) provided better forecasts, and the additional observations resulted in some improvement to the forecasts in the first 1 - 3 hours.

  10. ARM - CARES - Tracer Forecast for CARES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CampaignsCarbonaceous Aerosols and Radiative Effects Study (CARES)Tracer Forecast for CARES Related Links CARES Home AAF Home ARM Data Discovery Browse Data Post-Campaign Data Sets Field Updates CARES Wiki Campaign Images Experiment Planning Proposal Abstract and Related Campaigns Science Plan Operations Plan Measurements Forecasts News News & Press Backgrounder (PDF, 1.45MB) G-1 Aircraft Fact Sheet (PDF, 1.3MB) Contacts Rahul Zaveri, Lead Scientist Tracer Forecasts for CARES This webpage

  11. SSQ V3 N3_Final_4oct13.indd

    National Nuclear Security Administration (NNSA)

    3 * October 2013 Message from the Acting Assistant Deputy Administrator for Research, Development, Test Capabilities, and Evaluation, Roger A. Lewis Defense Programs Stockpile Stewardship in Action Volume 3, Number 3 Inside this Issue 2 The Z Astrophysical Plasma Properties Collaboration 4 Science Using Guns at a Million Times Atmospheric Pressure: Megabar Science 5 Outstanding Poster Awards 6 Spotlight on the Offi ce of Test Capabilities and Evaluation 8 Five Students Selected for the

  12. Thermoelectric properties of polycrystalline In4Se3 and In4Te3

    SciTech Connect (OSTI)

    Shi, Xun; Cho, Jung Y; Salvador, James R.; Yang, Jihui; Wang, Hsin

    2010-01-01

    High thermoelectric performance of a single crystal layered compound In{sub 4}Se{sub 3} was reported recently. We present here an electrical and thermal transport property study over a wide temperature range for polycrystalline samples of In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3}. Our data demonstrate that these materials are lightly doped semiconductors, leading to large thermopower and resistivity. Very low thermal conductivity, below 1 W/m K, is observed. The power factors for In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3} are much smaller when compared with state-of-the-art thermoelectric materials. This combined with the very low thermal conductivity results in the maximum ZT value of less than 0.6 at 700 K for In{sub 4}Se{sub 3}.

  13. ALT-3 Target & CMU Version 4

    SciTech Connect (OSTI)

    Griego, Jeffrey R; Atchison, Walter L.; Holtkamp, David; Oro, David M.; Reinovsky, Robert E.; Rousculp, Christopher L.; Tabaka, Leonard J.

    2012-06-11

    The third Advance Liner Technology (ALT-3) experiment is the next in a long tradition of collaborations between LANL and RFNC/VNIIEF in high-explosive pulsed-power. Here a VNIIEF provided Disk Explosive Magnetic Generator (DEMG) will drive a LANL provided experimental load and diagnostic package. The objective of the experiment is to explore the use of a cylindrical liner-ontarget in tera-Pascal equation of state measurement. This presentation will discuss version 4 of the experimental target and central measuring unit (CMU) along with R & D already performed in fabrication of the target.

  14. table4.3_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Offsite-Produced Fuel Consumption, 2002; Level: National and Regional Data; Row: Values of Shipments and Employment Sizes; Column: Energy Sources; Unit: Trillion Btu. RSE Economic Residual Distillate Natural LPG and Coke and Row Characteristic(a) Total Electricity(b) Fuel Oil Fuel Oil(c) Gas(d) NGL(e) Coal Breeze Other(f) Factors Total United States RSE Column Factors: 0.6 0.6 1.3 2.2 0.7 1.4 1.5 0.6 1 Value of Shipments and Receipts (million dollars) Under 20 1,276 437 15 50 598 W 47 W 97 14.5

  15. DOE Taking Wind Forecasting to New Heights | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Taking Wind Forecasting to New Heights DOE Taking Wind Forecasting to New Heights May 18, 2015 - 3:24pm Addthis A 2013 study conducted for the U.S. Department of Energy (DOE) by the National Oceanic and Atmospheric Administration (NOAA), AWS Truepower, and WindLogics in the Great Plains and Western Texas, demonstrated that wind power forecasts can be improved substantially using data collected from tall towers, remote sensors, and other devices, and incorporated into improved forecasting models

  16. ANL Software Improves Wind Power Forecasting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ANL Software Improves Wind Power Forecasting ANL Software Improves Wind Power Forecasting May 1, 2012 - 3:19pm Addthis This is an excerpt from the Second Quarter 2012 edition of the Wind Program R&D Newsletter. Since 2008, Argonne National Laboratory and INESC TEC (formerly INESC Porto) have conducted a research project to improve wind power forecasting and better use of forecasting in electricity markets. One of the main results from the project is ARGUS PRIMA (PRediction Intelligent

  17. EIA lowers forecast for summer gasoline prices

    Gasoline and Diesel Fuel Update (EIA)

    EIA lowers forecast for summer gasoline prices U.S. gasoline prices are expected to be lower this summer than previously thought. The price for regular gasoline this summer is now expected to average $3.53 a gallon, according to the new monthly forecast from the U.S. Energy Information Administration. That's down 10 cents from last month's forecast and 16 cents cheaper than last summer. After reaching a weekly peak of $3.78 a gallon in late February, pump prices fell nine weeks in a row to $3.52

  18. Wind Power Forecasting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data Presentations BPA Super Forecast Methodology Related Links Near Real-time Wind Animation Meteorological Data Customer Supplied Generation Imbalance Dynamic Transfer Limits...

  19. Wind Power Forecasting Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Operations Call 2012 Retrospective Reports 2012 Retrospective Reports 2011 Smart Grid Wind Integration Wind Integration Initiatives Wind Power Forecasting Wind Projects Email...

  20. NREL: Transmission Grid Integration - Forecasting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    generation output by using forecasts that incorporate meteorological data to predict production. Such systems typically provide forecasts at a number of timescales, ranging from...

  1. Funding Opportunity Announcement for Wind Forecasting Improvement Project

    Office of Environmental Management (EM)

    in Complex Terrain | Department of Energy Funding Opportunity Announcement for Wind Forecasting Improvement Project in Complex Terrain Funding Opportunity Announcement for Wind Forecasting Improvement Project in Complex Terrain April 4, 2014 - 9:47am Addthis On April 4, 2014 the U.S. Department of Energy announced a $2.5 million funding opportunity entitled "Wind Forecasting Improvement Project in Complex Terrain." By researching the physical processes that take place in complex

  2. SEP Request for Approval Form 5 - Model Does Not Satisfy 3.4.1-3.4.10

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements | Department of Energy 5 - Model Does Not Satisfy 3.4.1-3.4.10 Requirements SEP Request for Approval Form 5 - Model Does Not Satisfy 3.4.1-3.4.10 Requirements File SEP-Request-for-Approval-Form-5_Model-Does-Not-Satisfy-3.4.1-3.4.10-Requirements.docx More Documents & Publications SEP Request for Approval Form 3 - Other Complex Regression Model Rationale SEP Request for Approval Form 7 - Other Situations for Consumption Adjustment

  3. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    1 Carbon Dioxide Emissions for U.S. Commercial Buildings, by Year (Million Metric Tons) (1) Commercial U.S. Site Growth Rate Growth Rate Com.% Com.% Fossil Electricity Total 2010-Year Total 2010-Year of Total U.S. of Total Global 1980 245 409 653 4,723 14% 3.5% 1981 226 427 653 4,601 14% 3.6% 1982 226 426 653 4,357 15% 3.6% 1983 226 434 659 4,332 15% 3.6% 1984 236 455 691 4,561 15% 3.6% 1985 217 477 695 4,559 15% 3.6% 1986 216 481 698 4,564 15% 3.5% 1987 220 503 723 4,714 15% 3.5% 1988 230 531

  4. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    2 2010 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 211.9 211.9 20.4% Space Heating 87.4 10.2 6.7 0.3 17.3 5.6 50.5 160.7 15.5% Space Cooling 2.3 149.1 151.3 14.6% Ventilation 95.2 95.2 9.2% Refrigeration 69.1 69.1 6.7% Electronics 46.4 46.4 4.5% Water Heating 23.2 2.0 2.0 16.2 41.4 4.0% Computers 37.7 37.7 3.6% Cooking 9.5 4.1 13.6 1.3%

  5. LED Lighting Forecast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Market Studies LED Lighting Forecast LED Lighting Forecast The DOE report Energy Savings Forecast of Solid-State Lighting in General Illumination Applications ...

  6. JAS3D v. 2.4

    Energy Science and Technology Software Center (OSTI)

    2009-06-29

    JAS3D is a three-dimensional finite element program originally designed to solve Lagrangian quasistatic non-linear mechanics problems, and subsequently extended to include both implicit and explicit dynamics. A set of continuum equations describes the nonlinear mechanics involving large rotation and strain. Innovative multilevel nonlinear iterative methods are used to solve the equations. A wide variety of material constitutive models are available, and contact interface logic is implemented. Two Lagrangian uniform-strain elements are available: an eighth-node hexahedronmore » for solids and a four-node quadrilateral for shells. Both use hourglass stiffness to control zero-energy modes. In addition, a version of the hexahedron is available with uniform pressure and a deviatoric response scalable from the mean response of the original element up to a fully-integrated response. Bodies under analysis may be loaded by surface pressures and concentrated forces, specified displacements, or body forces from gravity, steady-state transport, or thermal expansion.« less

  7. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    4 2025 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 171.2 171.2 16.1% Space Heating 89.4 7.7 6.3 0.4 14.3 5.5 25.7 135.0 12.7% Ventilation 94.4 94.4 8.9% Space Cooling 1.8 81.5 83.3 7.8% Electronics 63.8 63.8 6.0% Refrigeration 53.7 53.7 5.1% Computers 31.2 31.2 2.9% Water Heating 27.5 2.3 2.3 14.0 43.7 4.1% Cooking 11.0 3.5 14.5 1.4%

  8. The forecast calls for flu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory found a way to forecast the flu season and even next week's sickness trends. ... Laboratory found a way to forecast the flu season and even next week's sickness trends. ...

  9. Solar Forecasting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems Integration » Solar Forecasting Solar Forecasting On December 7, 2012, DOE announced $8 million to fund two solar projects that are helping utilities and grid operators better forecast when, where, and how much solar power will be produced at U.S. solar energy plants. Part of the SunShot Systems Integration efforts, the Solar Forecasting projects will allow power system operators to integrate more solar energy into the electricity grid, and ensure the economic and reliable delivery of

  10. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    5 2035 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 179.6 179.6 15.5% Space Heating 87.3 6.7 6.6 0.4 13.7 5.5 25.5 132.0 11.4% Ventilation 100.7 100.7 8.7% Space Cooling 1.7 84.1 85.8 7.4% Electronics 72.3 72.3 6.2% Refrigeration 55.6 55.6 4.8% Water Heating 28.8 2.5 2.5 13.3 44.7 3.9% Computers 33.6 33.6 2.9% Cooking 11.9 3.4 15.2 1.3%

  11. 1994 Solid waste forecast container volume summary

    SciTech Connect (OSTI)

    Templeton, K.J.; Clary, J.L.

    1994-09-01

    This report describes a 30-year forecast of the solid waste volumes by container type. The volumes described are low-level mixed waste (LLMW) and transuranic/transuranic mixed (TRU/TRUM) waste. These volumes and their associated container types will be generated or received at the US Department of Energy Hanford Site for storage, treatment, and disposal at Westinghouse Hanford Company`s Solid Waste Operations Complex (SWOC) during a 30-year period from FY 1994 through FY 2023. The forecast data for the 30-year period indicates that approximately 307,150 m{sup 3} of LLMW and TRU/TRUM waste will be managed by the SWOC. The main container type for this waste is 55-gallon drums, which will be used to ship 36% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of 55-gallon drums is Past Practice Remediation. This waste will be generated by the Environmental Restoration Program during remediation of Hanford`s past practice sites. Although Past Practice Remediation is the primary generator of 55-gallon drums, most waste generators are planning to ship some percentage of their waste in 55-gallon drums. Long-length equipment containers (LECs) are forecasted to contain 32% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of LECs is the Long-Length Equipment waste generator, which is responsible for retrieving contaminated long-length equipment from the tank farms. Boxes are forecasted to contain 21% of the waste. These containers are primarily forecasted for use by the Environmental Restoration Operations--D&D of Surplus Facilities waste generator. This waste generator is responsible for the solid waste generated during decontamination and decommissioning (D&D) of the facilities currently on the Surplus Facilities Program Plan. The remaining LLMW and TRU/TRUM waste volume is planned to be shipped in casks and other miscellaneous containers.

  12. California Public Resources Code Division 3, Chapter 4 - Geothermal...

    Open Energy Info (EERE)

    Public Resources Code Division 3, Chapter 4 - Geothermal Resources Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: California...

  13. RELAP5-3D V. 4.X.X

    Energy Science and Technology Software Center (OSTI)

    000191MLTPL01 NON-NRC FUNDED RELAP5-3D VERSION 4.x.x SOFTWARE REACTOR EXCURSION AND LEAK ANALYSIS PACKAGE - THREE DIMENSIONAL

  14. Meeting Materials: November 3-4, 2003 | Department of Energy

    Office of Environmental Management (EM)

    3-4, 2003 Meeting Materials: November 3-4, 2003 PDF icon Meeting Minutes PDF icon Presentation: Overview of World and U.S. Energy Data Projections by Howard Gruenspecht More Documents & Publications Meeting Materials: May 18-19, 2004 Meeting Materials: Sept. 30 - Oct. 1, 2002 Meeting Materials: November 5-6, 2001

  15. probabilistic energy production forecasts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    probabilistic energy production forecasts - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  16. Categorical Exclusion Determinations: B3.4 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Categorical Exclusion Determinations: B3.4 Existing Regulations B3.4: Transport packaging tests for radioactive or hazardous material Drop, puncture, water-immersion, thermal, and fire tests of transport packaging for radioactive or hazardous materials to certify that designs meet the applicable requirements (such as 49 CFR 173.411 and 173.412 and 10 CFR 71.73). Previous Regulations Categorical Exclusion Determinations dated before November 14th, 2011 were issued under previous DOE NEPA

  17. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    3 2015 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 160.0 160.0 16.6% Space Heating 89.9 9.0 6.2 0.3 15.5 5.5 26.4 137.3 14.2% Space Cooling 1.9 80.0 81.9 8.5% Ventilation 85.0 85.0 8.8% Refrigeration 55.8 55.8 5.8% Electronics 49.9 49.9 5.2% Water Heating 25.5 2.0 2.0 14.3 41.8 4.3% Computers 30.0 30.0 3.1% Cooking 10.2 3.6 13.8 1.4%

  18. Categorical Exclusion Determinations: B4.3 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Categorical Exclusion Determinations: B4.3 Existing Regulations B4.3: Electric power marketing rate changes Rate changes for electric power, power transmission, and other products or services provided by a Power Marketing Administration that are based on a change in revenue requirements if the operations of generation projects would remain within normal operating limits. DOCUMENTS AVAILABLE FOR DOWNLOAD July 30, 2012 CX-009087: Categorical Exclusion Determination Hydroelectric Power Rate

  19. October 2012 Energy Assurance Planning Bulletin Volume 3 No 4

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OCTOBER 1, 2012 THE AMERICAN RECOVERY AND REINVESTMENT ACT VOLUME 3, NUMBER 4 Need to Know ... Need to Know The EAP Initiative began in August 2009 providing funds to 47 States, DC, 2 ...

  20. Using Wikipedia to forecast diseases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using Wikipedia to forecast diseases Using Wikipedia to forecast diseases Scientists can now monitor and forecast diseases around the globe more effectively by analyzing views of Wikipedia articles. November 13, 2014 Del Valle and her team observe findings from their research on disease patterns from analyzing Wikipedia articles. Del Valle and her team observe findings from their research on disease patterns from analyzing Wikipedia articles. Contact Nancy Ambrosiano Communications Office (505)

  1. Forecast Energy | Open Energy Information

    Open Energy Info (EERE)

    Zip: 94965 Region: Bay Area Sector: Services Product: Intelligent Monitoring and Forecasting Services Year Founded: 2010 Website: www.forecastenergy.net Coordinates:...

  2. UWIG Forecasting Workshop -- Albany (Presentation)

    SciTech Connect (OSTI)

    Lew, D.

    2011-04-01

    This presentation describes the importance of good forecasting for variable generation, the different approaches used by industry, and the importance of validated high-quality data.

  3. Using Wikipedia to forecast diseases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    based on today's forecast." Del Valle and her team were able to successfully monitor influenza in the United States, Poland, Japan and Thailand, dengue fever in Brazil and...

  4. Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole

    DOE Patents [OSTI]

    Lee, K.Y.

    1985-03-05

    A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated. 1 fig., 1 tab.

  5. Synthesis of 3-amino-4-hydroxylaminothiazolidine-2-thiones and 2,3-dimethyl-4. cap alpha. ,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazines

    SciTech Connect (OSTI)

    Epshtein, S.P.; Orlova, T.I.; Rukasov, A.F.; Tashchi, V.P.; Putsykin, Yu. G.

    1987-10-01

    The reaction of dimeric nitroso chlorides of olefins with potassium dithiocarbazate was used to synthesize 3-amino-4-hydroxylaminothiazolidine-2-thiones, which undergo rearrangement to 2-mercapto-1,3,4-thiadiazines on heating and react with butane-2,3-dione to give 2,3-dimethyl-4..cap alpha..,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazine 4-oxides. The latter are reduced by sodium borohydride to the corresponding 3,4,4..cap alpha..,5-tetrahydro-7-thioxo derivatives. The IR spectra of KBr pellets of the compounds were recorded with a Perkin-Elmer spectrometer. The UV spectra of solutions in ethanol were obtained with a Specord UV spectrophotometer. The PMR spectra of solutions of the compounds in d/sub 6/-DMSO were obtained with a Varian FT-80A spectrometer with tetramethylsilane (TMS) as the internal standard.

  6. EIS-0476: Vogtle Electric Generating Plant, Units 3 and 4

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of construction and startup of the proposed Units 3 and 4 at the Vogtle Electric Generating Plant in Burke County, Georgia. DOE adopted two Nuclear Regulatory Commission EISs associated with this project (i.e., NUREG-1872, issued 8/2008, and NUREG-1947, issued 3/2011).

  7. Method for preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline from 1,2,3,4-tetrahydroquinoline

    DOE Patents [OSTI]

    Field, George; Hammond, Peter R.

    1994-01-01

    Methods for the efficient preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline include a first method in which the acylation of m-aminophenol obtains a lactam which is reduced to give the desired quinoline and a second method in which tetrahydroquinoline is nitrated and hydrogenated and then hydrolyzed to obtain the desire quinoline. 7-hydroxy-1,2,3,4-tetrahydroquinoline is used in the efficient synthesis of four lasing dyes of the rhodamine class.

  8. Method for preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline from 1,2,3,4-tetrahydroquinoline

    DOE Patents [OSTI]

    Field, G.; Hammond, P.R.

    1994-02-01

    Methods for the efficient preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline include a first method in which the acylation of m-aminophenol obtains a lactam which is reduced to give the desired quinoline and a second method in which tetrahydroquinoline is nitrated and hydrogenated and then hydrolyzed to obtain the desire quinoline. 7-hydroxy-1,2,3,4-tetrahydroquinoline is used in the efficient synthesis of four lasing dyes of the rhodamine class.

  9. CMS 3.4 Temporary Changes, 4/10/95 | Department of Energy

    Office of Environmental Management (EM)

    Microsoft Office document icon CMS3-04.doc More Documents & Publications QAS 2.5 Design Control 31595 OSS 19.9 Industrial Hygiene 41095 NSS 18.4 Unreviewed Safety Questions...

  10. DOE Announces Webinars on Solar Forecasting Metrics, the DOE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Energy Department will present a live webinar titled "Solar Forecasting Metrics" on Thursday, February 13, from 3:00 p.m. to 5:00 p.m. Eastern Standard Time. During this ...

  11. Intermediate future forecasting system

    SciTech Connect (OSTI)

    Gass, S.I.; Murphy, F.H.; Shaw, S.H.

    1983-12-01

    The purposes of the Symposium on the Department of Energy's Intermediate Future Forecasting System (IFFS) were: (1) to present to the energy community details of DOE's new energy market model IFFS; and (2) to have an open forum in which IFFS and its major elements could be reviewed and critiqued by external experts. DOE speakers discussed the total system, its software design, and the modeling aspects of oil and gas supply, refineries, electric utilities, coal, and the energy economy. Invited experts critiqued each of these topics and offered suggestions for modifications and improvement. This volume documents the proceedings (papers and discussion) of the Symposium. Separate abstracts have been prepared for each presentation for inclusion in the Energy Data Base.

  12. Solar Energy Market Forecast | Open Energy Information

    Open Energy Info (EERE)

    Market Forecast Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Solar Energy Market Forecast AgencyCompany Organization: United States Department of Energy Sector:...

  13. Funding Opportunity Announcement for Wind Forecasting Improvement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Funding Opportunity Announcement for Wind Forecasting Improvement Project in Complex Terrain Funding Opportunity Announcement for Wind Forecasting Improvement Project in Complex...

  14. Upcoming Funding Opportunity for Wind Forecasting Improvement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Wind Forecasting Improvement Project in Complex Terrain Upcoming Funding Opportunity for Wind Forecasting Improvement Project in Complex Terrain February 12, 2014 - 10:47am...

  15. Astrophysical S factors of radiative {sup 3}He{sup 4}He, {sup 3}H{sup 4}He, and {sup 2}H{sup 4}He capture

    SciTech Connect (OSTI)

    Dubovichenko, S. B.

    2010-09-15

    The possibility of describing the astrophysical S factors for radiative {sup 3}He{sup 4}He capture at energies of up to 15 keV and radiative {sup 3}H{sup 4}He and {sup 2}H{sup 4}He capture at energies of up 5 keV is considered on the basis of the potential cluster model involving forbidden states.

  16. FIGS-3&4.CHP:Corel VENTURA

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    S3. Crude Oil Supply and Disposition, Figure S4. Crude Oil Ending Stocks, 1 0 2,500 5,000 7,500 10,000 12,500 15,000 17,500 0 2,500 5,000 7,500 10,000 12,500 15,000 17,500 Jul Aug...

  17. Electric-dipole allowed and intercombination transitions among the 3d{sup 5}, 3d{sup 4}4s and 3d{sup 4}4p levels of Fe IV

    SciTech Connect (OSTI)

    Deb, Narayan C.; Hibbert, Alan

    2010-07-15

    Oscillator strengths and transition rates for the electric-dipole (E1) allowed and intercombination transitions among 3d{sup 5}, 3d{sup 4}4s and 3d{sup 4}4p levels of Fe IV are calculated using the CIV3 code of Hibbert and coworkers. Using the Hartree-Fock functions up to 3d orbitals we have also optimized 4s, 4p, 4d, 4f, 5s, 5p and 5d orbitals of which 4s and 4p are taken to be spectroscopic and the remaining orbitals represent corrections to the spectroscopic orbitals or the correlation effects. The J-dependent levels of 108 LS states are included in the calculation and the relativistic effects are accounted for via the Breit-Pauli operator. Configurations are chosen in two steps: (a) two promotions were allowed from the 3p, 3d, 4s and 4p subshells, using all the orbitals; and (b) selective promotions from the 3s subshell are included, but only to the 3s and 4s orbitals. The ab initio fine-structure levels are then fine tuned to reproduce observed energy levels as closely as possible, and the resulting wavefunctions are used to calculate oscillator strengths and transition rates for all possible E1 transitions. For many of these transitions, the present results show good agreement between the length and velocity forms while for some transitions, some large disagreements are found with other available results. The complete list of weighted oscillator strengths, transition rates, and line strengths for transitions among the fine structure levels of the three lowest configurations are presented in ascending order of wavelength.

  18. Science on Tap - Forecasting illness

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science on Tap - Forecasting illness Science on Tap - Forecasting illness WHEN: Mar 17, 2016 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los Alamos, New Mexico 87544 USA CONTACT: Linda Anderman (505) 665-9196 CATEGORY: Bradbury INTERNAL: Calendar Login Event Description Mark your calendars for this event held every third Thursday from 5:30 to 7 p.m. A short presentation is followed by a lively discussion on a different subject each month. Forecasting the flu (and other

  19. RELAP5-3D Developmental Assessment. Comparison of Version 4.3.4i on Linux and Windows

    SciTech Connect (OSTI)

    Bayless, Paul David

    2015-10-01

    Figures have been generated comparing the parameters used in the developmental assessment of the RELAP5-3D code, version 4.3i, compiled on Linux and Windows platforms. The figures, which are the same as those used in Volume III of the RELAP5-3D code manual, compare calculations using the semi-implicit solution scheme with available experiment data. These figures provide a quick, visual indication of how the code predictions differ between the Linux and Windows versions.

  20. Value of Wind Power Forecasting

    SciTech Connect (OSTI)

    Lew, D.; Milligan, M.; Jordan, G.; Piwko, R.

    2011-04-01

    This study, building on the extensive models developed for the Western Wind and Solar Integration Study (WWSIS), uses these WECC models to evaluate the operating cost impacts of improved day-ahead wind forecasts.

  1. NOVEL CONCEPTS FOR ISOTOPIC SEPARATION OF 3HE/4HE

    SciTech Connect (OSTI)

    Roy, L.; Nigg, H.; Watson, H.

    2012-09-04

    The research outlined below established theoretical proof-of-concept using ab initio calculations that {sup 3}He can be separated from {sup 4}He by taking advantage of weak van der Waals interactions with other higher molecular weight rare gases such as xenon. To the best of our knowledge, this is the only suggested method that exploits the physical differences of the isotopes using a chemical interaction.

  2. October 2012 Energy Assurance Planning Bulletin Volume 3 No 4

    Energy Savers [EERE]

    OCTOBER 1, 2012 THE AMERICAN RECOVERY AND REINVESTMENT ACT VOLUME 3, NUMBER 4 Need to Know Program Recap Action Items Quarterly and Project Close- Out Reports Due Energy Assurance Success Stories Portland, Oregon's Community-Wide Approach to Local Government Energy Assurance Planning News from the States North Carolina reaps benefits from SLEAP Upcoming Events GridWeek 2012 DOE Winter Fuels Outlook Conference ASERTTI Fall Meeting NMU "The Basics" Courses World Energy Engineering

  3. Microsoft Word - Showerhead Guidance _3-4__final_ _2_.docx

    Office of Environmental Management (EM)

    Showerhead Enforcement Guidance Issued: March 4, 2011 On February 3, 2011, the Department of Energy withdrew from OMB review, as unwarranted, the draft interpretative rule setting out the Department's views on the definition of a "showerhead" under the Energy Policy Conservation Act (EPCA) - and we formally withdraw that draft interpretive rule from consideration today. Nevertheless, to provide certainty to all stakeholders, the Department has decided to issue this brief enforcement

  4. 4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -4 -3 -2 -1 0 1 2 3 4 -4 -3 -2 -1 0 1 2 3 4 px x -0.006 -0.004 -0.002 0 0.002 0.004 0.006 -0.02 -0.015 -0.01 -0.005 0 0.005 0.01 0.015 0.02 px x(m) 50 100 50 100 0 10000 20000 30000 50 100

  5. Acceptance test report for core sample trucks 3 and 4

    SciTech Connect (OSTI)

    Corbett, J.E.

    1996-04-10

    The purpose of this Acceptance Test Report is to provide documentation for the acceptance testing of the rotary mode core sample trucks 3 and 4, designated as HO-68K-4600 and HO-68K-4647, respectively. This report conforms to the guidelines established in WHC-IP-1026, ``Engineering Practice Guidelines,`` Appendix M, ``Acceptance Test Procedures and Reports.`` Rotary mode core sample trucks 3 and 4 were based upon the design of the second core sample truck (HO-68K-4345) which was constructed to implement rotary mode sampling of the waste tanks at Hanford. Successful completion of acceptance testing on June 30, 1995 verified that all design requirements were met. This report is divided into four sections, beginning with general information. Acceptance testing was performed on trucks 3 and 4 during the months of March through June, 1995. All testing was performed at the ``Rock Slinger`` test site in the 200 West area. The sequence of testing was determined by equipment availability, and the initial revision of the Acceptance Test Procedure (ATP) was used for both trucks. Testing was directed by ICF-KH, with the support of WHC Characterization Equipment Engineering and Characterization Project Operations. Testing was completed per the ATP without discrepancies or deviations, except as noted.

  6. Diagnosis of the Marine Low Cloud Simulation in the NCAR Community Earth System Model (CESM) and the NCEP Global Forecast System (GFS)-Modular Ocean Model v4 (MOM4) coupled model

    SciTech Connect (OSTI)

    Xiao, Heng; Mechoso, C. R.; Sun, Rui; Han, J.; Pan, H. L.; Park, S.; Hannay, Cecile; Bretherton, Christopher S.; Teixeira, J.

    2014-07-25

    We present a diagnostic analysis of the marine low cloud climatology simulated by two state-of-the-art coupled atmosphere-ocean models: the NCAR Community Earth System Model (CESM) and the NCEP Global Forecasting System (GFS). In both models, the shallow convection and boundary layer turbulence parameterizations have been recently updated: both models now use a mass-flux scheme for the parameterization of shallow convection, and a turbulence parameterization capable of handling Stratocumulus (Sc)-topped Planetary Boundary Layers (PBLs). For shallow convection, both models employ a convective trigger function based on the concept of convective inhibition and both include explicit convective overshooting/penetrative entrainment formulation. For Sc-topped PBL, both models treat explicitly turbulence mixing and cloud-top entrainment driven by cloud-top radiative cooling. Our focus is on the climatological transition from Sc to shallow Cumulus (Cu)-topped PBL in the subtropical eastern oceans. We show that in the CESM the coastal Sc-topped PBLs in the subtropical Eastern Pacific are well-simulated but the climatological transition from Sc to shallow Cu is too abrupt and happens too close to the coast. By contrast, in the GFS coupled simulation the coastal Sc amount and PBL depth are severely underestimated while the transition from Sc to shallow Cu is delayed and offshore Sc cover is too extensive in the subtropical Eastern Pacific. We discuss the possible connections between such differences in the simulations and differences in the parameterizations of shallow convection and boundary layer turbulence in the two models.

  7. Solar Forecast Improvement Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Forecast Improvement Project Solar Forecast Improvement Project NOAA.png For the Solar Forecast Improvement Project (SFIP), the Earth System Research Laboratory (ESRL) is partnering with the National Center for Atmospheric Research (NCAR) and IBM to develop more accurate methods for solar forecasts using their state-of-the-art weather models. APPROACH NOAA solar.png SFIP has three main goals: 1) to develop solar forecasting metrics tailored to the utility sector; 2) to improve solar

  8. Propellant Containing 3, 6bis(1h-1,2,3,4-Tetrazol-5-Ylamino)-1,2,4,5- Tetrazine Or Salt Thereof

    DOE Patents [OSTI]

    Hiskey, Michael A. (Los Alamos, NM); Chavez, David E. (Ranchos de Taos, NM); Naud, Darren (Los Alamos, NM)

    2003-12-02

    The compound 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine and its salts are provided together with a propellant composition including an oxidizer, a binder and 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine or its salts.

  9. Material Property Correlations: Comparisons between FRAPCON-3.4, FRAPTRAN 1.4, and MATPRO

    SciTech Connect (OSTI)

    Luscher, Walter G.; Geelhood, Kenneth J.

    2010-08-01

    The U.S. Nuclear Regulatory Commission (NRC) uses the computer codes FRAPCON-3 and FRAPTRAN to model steady state and transient fuel behavior, respectively, in regulatory analysis. In order to effectively model fuel behavior, material property correlations must be used for a wide range of operating conditions (e.g. temperature and burnup). In this sense, a 'material property' is a physical characteristic of the material whose quantitative value is necessary in the analysis process. Further, the property may be used to compare the benefits of one material versus another. Generally speaking, the material properties of interest in regulatory analysis of nuclear fuel behavior are mechanical or thermodynamic in nature. The issue of what is and is not a 'material property' will never be universally resolved. In this report, properties such as thermal conductivity are included. Other characteristics of the material (e.g. fission gas release) are considered 'models' rather than properties, and are discussed elsewhere. Still others (e.g., neutron absorption cross-section) are simply not required in this specific analysis. The material property correlations for the FRAPCON-3 and FRAPTRAN computer codes were documented in NUREG/CR-6534 and NUREG/CR-6739, respectively. Some of these have been modified or updated since the original code documentation was published. The primary purpose of this report is to consolidate the current material property correlations used in FRAPCON-3 and FRAPTRAN into a single document. Material property correlations for oxide fuels, including uranium dioxide (UO2) and mixed oxide (MOX) fuels, are described in Section 2. Throughout this document, the term MOX will be used to describe fuels that are blends of uranium and plutonium oxides, (U,Pu)O2. The properties for uranium dioxide with other additives (e.g., gadolinia) are also discussed. Material property correlations for cladding materials and gases are described in Sections 3 and 4, respectively. In addition to describing the material property correlations used in the subroutines of FRAPCON-3 and FRAPTRAN, this report also provides a variety of comparisons between material property correlations and data. Although they are frequently identical, comparisons are made between the material property correlations used in the FRAPCON-3 and FRAPTRAN codes. Comparisons are also made between the material property correlations used in MATPRO, a compilation of fuel and cladding material property correlations with an extensive history of used with various fuel performance and severe accident codes. For a number of reasons, consistency between the material property correlations in FRAPCON-3, FRAPTRAN, and MATPRO has never been complete. However, the current versions of FRAPCON-3 and FRAPTRAN use a relatively consistent set of correlations for the properties that are used by both codes. The material property correlations in the most recent version of MATPRO are documented in Volume 4 of NUREG/CR-6150. In addition to comparison of the various correlations, correlation-to-data comparisons are also made with FRAPCON-3, FRAPTRAN, and MATPRO. All comparisons made in this report are based on the material property correlations used in the most recent version of the FRAPCON-3 and FRAPTRAN codes, FRAPCON-3.4 and FRAPTRAN 1.4. The source code for each material property correlation discussed will be provided for FRAPCON-3.4 and FRAPTRAN 1.4 (see appendix) as well as a range of applicability and an estimate of uncertainty where possible.

  10. Preparation of 3,3'-azobis(6-amino-1,2,4,5-tetrazine)

    DOE Patents [OSTI]

    Hiskey, Michael A.; Chavez, David E.; Naud, Darren

    2002-01-01

    The compound of the structure ##STR1## where a, b, c, d and e are 0 or 1 and a+b+c+d+e is from 0 to 5 is disclosed together with the species 3,3'-azobis(6-amino-1,2,4,5-tetrazine) and a process of preparing such compounds.

  11. Methods of using (1S,3S)-3-amino-4-difluoromethylenyl-1-cyclopentanoic acid

    DOE Patents [OSTI]

    Silverman, Richard B; Dewey, Stephen L; Miller, Steven

    2015-03-03

    (1S,3S)-3-amino-4-difluoromethylenyl-1-cyclopentanoic acid also known as CPP-115 or its pharmaceutically acceptable salts can be used to treat addiction and neurological disorders such as epilepsy without side effects such as visual field defects caused by vigabatrin (Sabril).

  12. Magnetic Ordering in Sr3YCo4O10+x

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kishida, Takayoshi; Kapetanakis, Myron D.; Yan, Jiaqiang; Sales, Brian C.; Pantelides, Sokrates T.; Pennycook, Stephen J.; Chisholm, Matthew F.

    2016-01-28

    Transition-metal oxides often exhibit complex magnetic behavior due to the strong interplay between atomic-structure, electronic and magnetic degrees of freedom. Cobaltates, especially, exhibit complex behavior because of cobalt’s ability to adopt various valence and spin state configurations. The case of the oxygen-deficient perovskite Sr3YCo4O10+x (SYCO) has gained considerable attention because of persisting uncertainties about its structure and the origin of the observed room temperature ferromagnetism. Here we report a combined investigation of SYCO using aberration-corrected scanning transmission electron microscopy and density functional theory calculations.

  13. trans-K3[TcO2(CN)4

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Edwards, Matthew K.; Twamley, Brendan; Krause, Jeanette A.; Bryan, Samuel A.

    2010-07-14

    The dioxotetracyanotechnetate anion, [TcO2(CN)4]3-, of the title complex has octahedral symmetry. The technetium is located on a center of inversion and is bound by two oxygen atoms and four cyano ligands. The Tc?O bond distance of 1.7721 (12) is consistent with double bond character. The potassium cations [located on special (1/2,0,1) and general positions] reside in octahedral or tetrahedral environments; interionic KO and KN interactions occur in the 2.7877 (19)-2.8598 (15) range.

  14. AGR 3/4 Irradiation Test Final As Run Report

    SciTech Connect (OSTI)

    Collin, Blaise P.

    2015-06-01

    Several fuel and material irradiation experiments have been planned for the Idaho National Laboratory Advanced Reactor Technologies Technology Development Office Advanced Gas Reactor Fuel Development and Qualification Program (referred to as the INL ART TDO/AGR fuel program hereafter), which supports the development and qualification of tristructural-isotropic (TRISO) coated particle fuel for use in HTGRs. The goals of these experiments are to provide irradiation performance data to support fuel process development, qualify fuel for normal operating conditions, support development and validation of fuel performance and fission product transport models and codes, and provide irradiated fuel and materials for post irradiation examination and safety testing (INL 05/2015). AGR-3/4 combined the third and fourth in this series of planned experiments to test TRISO coated low enriched uranium (LEU) oxycarbide fuel. This combined experiment was intended to support the refinement of fission product transport models and to assess the effects of sweep gas impurities on fuel performance and fission product transport by irradiating designed-to-fail fuel particles and by measuring subsequent fission metal transport in fuel-compact matrix material and fuel-element graphite. The AGR 3/4 fuel test was successful in irradiating the fuel compacts to the burnup and fast fluence target ranges, considering the experiment was terminated short of its initial 400 EFPD target (Collin 2015). Out of the 48 AGR-3/4 compacts, 42 achieved the specified burnup of at least 6% fissions per initial heavy-metal atom (FIMA). Three capsules had a maximum fuel compact average burnup < 10% FIMA, one more than originally specified, and the maximum fuel compact average burnup was <19% FIMA for the remaining capsules, as specified. Fast neutron fluence fell in the expected range of 1.0 to 5.51025 n/m2 (E >0.18 MeV) for all compacts. In addition, the AGR-3/4 experiment was globally successful in keeping the temperature in the twelve capsules relatively flat in a range of temperatures suitable for the measurement of fission product diffusion in compact matrix and structural graphite materials.

  15. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    6 2009 Methane Emissions for U.S. Commercial Buildings Energy Production, by Fuel Type (1) Fuel Type Petroleum 0.5 Natural Gas 26.8 Coal 0.3 Wood 0.4 Electricity (2) 50.5 Total 78.5 Note(s): Source(s): MMT CO2 Equivalent 1) Sources of emissions include oil and gas production, processing, and distribution; coal mining; and utility and site combustion. Carbon Dioxide equivalent units are calculated by converting methane emissions to carbon dioxide emissions (methane's global warming potential is

  16. EVMS Training Snippet: 4.3 Management Reserve Versus Contingency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Target Baseline (OTB) and The Over Target Schedule (OTS) Implementations EVMS Training Snippet: 4.4 Undistributed Budget (UB) EVMS Training Snippet: 4.6 Baseline Control Methods...

  17. RELAP5-3D Developmental Assessment: Comparison of Versions 4.3.4i and 4.2.1i

    SciTech Connect (OSTI)

    Bayless, Paul David

    2015-10-01

    Figures have been generated comparing the parameters used in the developmental assessment of the RELAP5-3D code using versions 4.3.4i and 4.2.1i. The figures, which are the same as those used in Volume III of the RELAP5-3D code manual, compare calculations using the semi-implicit solution scheme with available experiment data. These figures provide a quick, visual indication of how the code predictions changed between these two code versions and can be used to identify cases in which the assessment judgment may need to be changed in Volume III of the code manual. Changes to the assessment judgments made after reviewing all of the assessment cases are also provided.

  18. Synthesis of g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction with enhanced photocatalytic performance

    SciTech Connect (OSTI)

    He, Peizhi; Song, Limin; Zhang, Shujuan; Wu, Xiaoqing; Wei, Qingwu

    2014-03-01

    Graphical abstract: g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction photocatalyst with visible-light response was prepared by a facile coprecipitation method. The results show that g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} possesses a much higher activity for the decomposition of RhB than that of the pure Ag{sub 3}PO{sub 4} particles. The most mechanism is that g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction photocatalyst can efficiently separate the photogenerated electronhole pairs, enhancing the photocatalytic activity of g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} composites. - Highlights: g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction showed much higher activity than that of Ag{sub 3}PO{sub 4}. The high activity could be attributed to g-C{sub 3}N{sub 4} for modifying Ag{sub 3}PO{sub 4}. More OH radicals may be significant reason to improve Ag{sub 3}PO{sub 4} activity. - Abstract: g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction photocatalyst with visible-light response was prepared by a facile coprecipitation method. The photocatalysts were characterized by X-ray powder diffraction, transmission electron microscopy, UVvis absorption spectroscopy and Fourier transform infrared spectroscopy. The photocatalytic activities of the obtained samples were tested by using Rhodamine B (RhB) as the degradation target under visible light irradiation. g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} decomposed RhB more effectively than the pure Ag{sub 3}PO{sub 4} particles did, and 2 wt.% g-C{sub 3}N{sub 4} had the highest activity. Furthermore, 2 wt.% g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} degraded high-concentration RhB more potently than unmodified Ag{sub 3}PO{sub 4} did, probably because g-C{sub 3}N{sub 4}/Ag{sub 3}PO{sub 4} heterojunction photocatalyst enhanced the photocatalytic activity by efficiently separating the photogenerated electronhole pairs.

  19. ARM - PI Product - CCPP-ARM Parameterization Testbed Model Forecast Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsCCPP-ARM Parameterization Testbed Model Forecast Data ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : CCPP-ARM Parameterization Testbed Model Forecast Data Dataset contains the NCAR CAM3 (Collins et al., 2004) and GFDL AM2 (GFDL GAMDT, 2004) forecast data at locations close to the ARM research sites. These data are generated from a series of multi-day forecasts in which both CAM3 and AM2 are

  20. DOE-HDBK-1011/3-92; DOE Fundamentals Handbook Electrical Science Volume 3 of 4

    Office of Environmental Management (EM)

    3-92 JUNE 1992 DOE FUNDAMENTALS HANDBOOK ELECTRICAL SCIENCE Volume 3 of 4 U.S. Department of Energy FSC-6910 Washington, D.C. 20585 Distribution Statement A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information. P. O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576- 8401. Available to the public from the National

  1. Reactions of Deuterated Methanol (CD3OD) on Fe3O4(111)

    SciTech Connect (OSTI)

    Li, Zhisheng; Potapenko, Denis V.; Rim, Kwang T.; Flytzani-Stephanopoulos, Maria; Flynn, George; Osgood, Richard; Wen, Xiaodong; Batista, Enrique R.

    2015-01-15

    We report an experimental and theoretical investigation of the decomposition (partial oxidation) of deuterated methanol (CD3OD) on a single-crystal Fe3O4(111) surface. The crystal surface contains majority areas of a Fe-terminated Fe3O4(111) surface as well as smaller regions of O-terminated FeO(111) or biphase surface reconstruction. Our investigation uses a combination of scanning tunneling microscopy, temperature-programmed desorption, and density functional theory calculations to examine the surface reactions and adsorbates as a function of coverage. Our studies show that the reaction of methanol on this ironoxide surface is highly sensitive to atomic-level surface reconstructions

  2. Forecasting Water Quality & Biodiversity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forecasting Water Quality & Biodiversity March 25, 2015 Cross-cutting Sustainability Platform Review Principle Investigator: Dr. Henriette I. Jager Organization: Oak Ridge National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information 2015 DOE Bioenergy Technologies Office (BETO) Project Peer Review Goal Statement Addresses the following MYPP BETO goals:  Advance scientific methods and models for measuring and understanding

  3. The Vapor Pressure of 1-(2,2,3,3-Tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-prop anol

    SciTech Connect (OSTI)

    Steele, W.V.

    2002-01-29

    The vapor pressure of the compound 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol was measured over the temperature range 62 to 92 C using a Knudsen effusion technique. This compound, known as Cs-7SB, is the modifier component in the caustic-side solvent extraction process solvent. The vapor pressure is related to temperature by the equation ln(p/Pa) = (32.202 {+-} 0.265) - (12154 {+-} 93)/T, where p is the pressure, expressed in pascals; Pa is the reference pressure of 1 pascal; and T is the temperature, expressed in degrees kelvin. The derived heat of vaporization is 101.1 {+-} 0.8{sup kJ{center_dot}mol{sup 1} at 351 K. Because the vapor pressures over the temperature range of 15 to 50 C were lower than the design capabilities of the Knudsen effusion apparatus, the vapor pressures at these temperature limits were obtained by extrapolation. The estimated values are 4.6 {+-} 0.3E-05 (3.5 {+-} 0.2E-07 mm Hg) and 4.5 {+-} 0.1E-03 Pa (3.4 {+-} 0.1E-05 mm Hg) for 15 C and 50 C, respectively.

  4. Microstructural Contol of the Porous Si3N4 Ceramics Consisted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contol of the Porous Si3N4 Ceramics Consisted of 3-Dimensionally Intermingled Rod-like Grains Microstructural Contol of the Porous Si3N4 Ceramics Consisted of 3-Dimensionally...

  5. CCPP-ARM Parameterization Testbed Model Forecast Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Klein, Stephen

    2008-01-15

    Dataset contains the NCAR CAM3 (Collins et al., 2004) and GFDL AM2 (GFDL GAMDT, 2004) forecast data at locations close to the ARM research sites. These data are generated from a series of multi-day forecasts in which both CAM3 and AM2 are initialized at 00Z every day with the ECMWF reanalysis data (ERA-40), for the year 1997 and 2000 and initialized with both the NASA DAO Reanalyses and the NCEP GDAS data for the year 2004. The DOE CCPP-ARM Parameterization Testbed (CAPT) project assesses climate models using numerical weather prediction techniques in conjunction with high quality field measurements (e.g. ARM data).

  6. CCPP-ARM Parameterization Testbed Model Forecast Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Klein, Stephen

    Dataset contains the NCAR CAM3 (Collins et al., 2004) and GFDL AM2 (GFDL GAMDT, 2004) forecast data at locations close to the ARM research sites. These data are generated from a series of multi-day forecasts in which both CAM3 and AM2 are initialized at 00Z every day with the ECMWF reanalysis data (ERA-40), for the year 1997 and 2000 and initialized with both the NASA DAO Reanalyses and the NCEP GDAS data for the year 2004. The DOE CCPP-ARM Parameterization Testbed (CAPT) project assesses climate models using numerical weather prediction techniques in conjunction with high quality field measurements (e.g. ARM data).

  7. Pressure-enhanced superconductivity in Eu3Bi2S4F4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Yongkang; Zhai, Hui -Fei; Zhang, Pan; Xu, Zhu -An; Cao, Guang -Han; Thompson, J. D.

    2014-12-17

    The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of 1.5 K at ambient pressure, is investigated by transport and magnetic measurements. Accompanied with the enhancement of metallicity under pressures, the onset superconducting transition temperature increases abruptly around 1.0 GPa, reaching ~10.0 K at 2.26 GPa. Alternating current magnetic susceptibility measurements indicate that a new superconducting phase with a higher Tc emerges and dominates at high pressures. In the broad pressure window of 0.68GPa≤p≤2.00 GPa, the high-Tc phase coexists with the low-Tc phase. Hall effect measurements reveal a significant difference in electronic structures between themore » two superconducting phases. As a result, our work devotes the effort to establish the commonality of pressure effect on the BiS2-based superconductors, and also uncovers the importance of electron carrier density in the high-Tc phase.« less

  8. Synthesis, characterization and optical properties of NH{sub 4}Dy(PO{sub 3}){sub 4}

    SciTech Connect (OSTI)

    Chemingui, S.; Ferhi, M. Horchani-Naifer, K.; Férid, M.

    2014-09-15

    Polycrystalline powders of NH{sub 4}Dy(PO{sub 3}){sub 4} polyphosphate have been grown by the flux method. This compound was found to be isotopic with NH{sub 4}Ce(PO{sub 3}){sub 4} and RbHo(PO{sub 3}){sub 4}. It crystallizes in the monoclinic space group P2{sub 1/n} with unit cell parameters a=10.474(6) Å, b=9.011(4) Å, c=10.947(7) Å and β=106.64(3)°. The title compound has been transformed to triphosphate Dy(PO{sub 3}){sub 3} after calcination at 800 °C. Powder X-ray diffraction, infrared and Raman spectroscopies and the differential thermal analysis have been used to identify these materials. The spectroscopic properties have been investigated through absorption, excitation, emission spectra and decay curves of Dy{sup 3+} ion in both compounds at room temperature. The emission spectra show the characteristic emission bands of Dy{sup 3+} in the two compounds, before and after calcination. The integrated emission intensity ratios of the yellow to blue (I{sub Y}/I{sub B}) transitions and the chromaticity properties have been determined from emission spectra. The decay curves are found to be double-exponential. The non-exponential behavior of the decay rates was related to the resonant energy transfer as well as cross-relaxation between the donor and acceptor Dy{sup 3+} ions. The determined properties have been discussed as function of crystal structure of both compounds. They reveal that NH{sub 4}Dy(PO{sub 3}){sub 4} is promising for white light generation but Dy(PO{sub 3}){sub 3} is potential candidates in field emission display (FED) and plasma display panel (PDP) devices. - Graphical abstract: The CIE color coordinate diagrams showing the chromatic coordinates of Dy{sup 3+} luminescence in NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3}. - Highlights: • The polycrystalline powders of NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3} are synthesized. • The obtained powders are characterized. • The spectroscopic properties of Dy{sup 3+} ion are investigated. • Results are discussed as function of crystal structure and chemical composition. • The usefulness of NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3} in optical devices is revealed.

  9. A Highly Porous and Robust (3,3,4)-Connected Metal-Organic Framework

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembled with a 90° Bridging-Angle Embedded Octacarboxylate Ligand | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Highly Porous and Robust (3,3,4)-Connected Metal-Organic Framework Assembled with a 90° Bridging-Angle Embedded Octacarboxylate Ligand Previous Next List Weigang Lu, Daqiang Yuan, Trevor A. Makal, Jian-Rong Li, Dr. Hong-Cai Zhou, Angew. Chem. Int. Ed., 51: 1580-1584 (2012) DOI: 10.1002/anie.201106615 Thumbnail image of graphical abstract

  10. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane

    SciTech Connect (OSTI)

    Ocola, Esther J.; Medders, Cross; Laane, Jaan; Meinander, Niklas

    2014-04-28

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2 and a tilt angle of 9.4 between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x{sub 1}{sup 4} + x{sub 2}{sup 4}) b(x{sub 1}{sup 2} + x{sub 2}{sup 2}) + cx{sub 1}{sup 2}x{sub 2}{sup 2}, where x{sub 1} and x{sub 2} are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  11. Subtask 3.4 - Fischer - Tropsch Fuels Development

    SciTech Connect (OSTI)

    Joshua Strege; Anthony Snyder; Jason Laumb; Joshua Stanislowski; Michael Swanson

    2012-05-01

    Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing Fischer??Tropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through the EERC??U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding for BP1 was provided by the North Dakota Industrial Commission??s (NDIC) Renewable Energy Council.

  12. Methodology for Developing the REScheckTM Software through Version 4.4.3

    SciTech Connect (OSTI)

    Bartlett, Rosemarie; Connell, Linda M.; Gowri, Krishnan; Lucas, Robert G.; Schultz, Robert W.; Taylor, Zachary T.; Wiberg, John D.

    2012-09-01

    The Energy Policy Act of 1992 (EPAct, Public Law 102-486) establishes the 1992 Model Energy Code (MEC), published by the Council of American Building Officials (CABO), as the target for several energy-related requirements for residential buildings (CABO 1992). The U.S. Department of Housing and Urban Development (HUD) and the U.S. Department of Agriculture (via Rural Economic and Community Development [RECD] [formerly Farmers Home Administration]) are required to establish standards for government-assisted housing that meet or exceed the requirements of the Council of American Building Officials Model Energy Code, 1992. CABO issued 1992, 1993, and 1995 editions of the MEC (CABO 1992, 1993, and 1995). Effective December 4, 1995, CABO assigned all rights and responsibilities for the MEC to the International Code Council (ICC). The first edition of the ICCs International Energy Conservation Code (ICC 1998) issued in 1998 therefore replaced the 1995 edition of the MEC. The 1998 IECC incorporates the provisions of the 1995 MEC and includes the technical content of the MEC as modified by approved changes from the 1995, 1996, and 1997 code development cycles. The ICC subsequently issued the 2000 edition of the IECC (ICC 1999). Many states and local jurisdictions have adopted one edition of the MEC or IECC as the basis for their energy code. In a Federal Register notice issued January 10, 2001 (FR Vol. 99, No. 7, page 1964), the U.S. Department of Energy (DOE) concluded that the 1998 and 2000 editions of the IECC improve energy efficiency over the 1995 MEC. DOE has previously issued notices that the 1993 and 1995 MEC also improved energy efficiency compared to the preceding editions. To help builders comply with the MEC and IECC requirements, and to help HUD, RECD, and state and local code officials enforce these code requirements, DOE tasked Pacific Northwest National Laboratory (PNNL) with developing the MECcheck compliance materials. In November 2002, MECcheck was renamed REScheck to better identify it as a residential code compliance tool. The MEC in MECcheck was outdated because it was taken from the Model Energy Code, which has been succeeded by the IECC. The RES in REScheck is also a better fit with the companion commercial product, COMcheck. The easy-to-use REScheck compliance materials include a compliance and enforcement manual for all the MEC and IECC requirements and three compliance approaches for meeting the codes thermal envelope requirements?prescriptive packages, software, and a trade-off worksheet (included in the compliance manual). The compliance materials can be used for single-family and low-rise multifamily dwellings. The materials allow building energy efficiency measures (such as insulation levels) to be traded off against each other, allowing a wide variety of building designs to comply with the code. This report explains the methodology used to develop Version 4.4.3 of the REScheck software developed for the 1992, 1993, and 1995 editions of the MEC, and the 1998, 2000, 2003, 2006, 2007, 2009, and 2012 editions of the IECC, and the 2006 edition of the International Residential Code (IRC). Although some requirements contained in these codes have changed, the methodology used to develop the REScheck software for these editions is similar. Beginning with REScheck Version 4.4.0, support for 1992, 1993, and 1995 MEC and the 1998 IECC is no longer included, but those sections remain in this document for reference purposes. REScheck assists builders in meeting the most complicated part of the code?the building envelope Uo-, U-, and R-value requirements in Section 502 of the code. This document details the calculations and assumptions underlying the treatment of the code requirements in REScheck, with a major emphasis on the building envelope requirements.

  13. Supply Forecast and Analysis (SFA)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Matthew Langholtz Science Team Leader Oak Ridge National Laboratory DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Supply Forecast and Analysis (SFA) 2 | Bioenergy Technologies Office Goal Statement * Provide timely and credible estimates of feedstock supplies and prices to support - the development of a bioeconomy; feedstock demand analysis of EISA, RFS2, and RPS mandates - the data and analysis of other projects in Analysis and Sustainability, Feedstock Supply and Logistics,

  14. NERSC Users Group Meeting October 3-4, 2005 Presentations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Highlight III: Feeding the Pipeline: The SNfactory Search for Nearby Supernovae October 4, 2005 | Author(s): Richard Scalzo | Download File: scalzo.pdf | pdf | 1.1...

  15. NERSC Users Group Meeting October 3-4, 2005 Presentations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview: a high-level description of system, processors, interconnect, file systems, compilers, benchmarking, etc October 3, 2005 | Author(s): Richard Gerber | Download File:...

  16. Proposed Southline Transmission Line Project - Volume 3 of 4...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Right-of-Way ... G-1 11 12 13 VOLUME SUMMARY 14 15 Volume 1 - Executive Summary, Chapters 1, 2, and 3 16 Volume 2 -...

  17. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloroanisole

    DOE Patents [OSTI]

    Ott, D.G.; Benziger, T.M.

    1991-03-05

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole is described. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB. 8 figures.

  18. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloroanisole

    DOE Patents [OSTI]

    Ott, Donald G. (Los Alamos, NM); Benziger, Theodore M. (Santa Fe, NM)

    1991-01-01

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.

  19. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloranisole

    DOE Patents [OSTI]

    Ott, Donald G. (Los Alamos, NM); Benziger, Theodore M. (Santa Fe, NM)

    1990-01-01

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.

  20. Project Profile: Forecasting and Influencing Technological Progress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Influencing Technological Progress in Solar Energy Project Profile: Forecasting and ... energy technologies based on estimates of future rates of progress and adoption. ...

  1. NREL: Resource Assessment and Forecasting Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are used to plan and develop renewable energy technologies and support climate change research. Learn more about NREL's resource assessment and forecasting research:...

  2. Forecast and Funding Arrangements - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Waste Forecast and Funding Arrangements About Us Hanford Site Solid Waste Acceptance Program What's New Acceptance Criteria Acceptance Process Becoming a new Hanford...

  3. Microsoft Word - T4_VEIC_TO2_ Sub3_Residential Retrofit Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Retrofit Program Design Guide Play BookTEAM 4 FINAL.docx Microsoft Word - T4VEICTO2 Sub3Residential Retrofit Program Design Guide Play BookTEAM 4 FINAL.docx PDF icon ...

  4. Operating Experience Level 3: Radcalc V4.1 Software Defect | Department of

    Energy Savers [EERE]

    Energy Level 3: Radcalc V4.1 Software Defect Operating Experience Level 3: Radcalc V4.1 Software Defect September 6, 2011 OE-3 2011-01: Radcalc V4.1 Software Defect PDF icon OE-3 2011-01: Radcalc V4.1 Software Defect More Documents & Publications RADCALC DOE-HDBK-1129-2007 DOE-STD-3013-2012

  5. Table 4.3 Offsite-Produced Fuel Consumption, 2002

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Offsite-Produced Fuel Consumption, 2002;" " Level: National and Regional Data; " " Row: Values of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," "," "," "," " " "," ",," "," ",," "," ",," ","RSE"

  6. Table 4.3 Offsite-Produced Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Offsite-Produced Fuel Consumption, 2010; Level: National and Regional Data; Row: Values of Shipments and Employment Sizes; Column: Energy Sources; Unit: Trillion Btu. Economic Residual Distillate Natural LPG and Coke and Characteristic(a) Total Electricity(b) Fuel Oil Fuel Oil(c) Gas(d) NGL(e) Coal Breeze Other(f) Total United States Value of Shipments and Receipts (million dollars) Under 20 1,038 314 6 53 445 14 25 Q 181 20-49 918 296 11 19 381 10 97 5 97 50-99 1,018 308 7 13 440 5 130 6 110

  7. 4-cyano-3-hydroxybutanoyl hydrazines, derivatives and process for the preparation thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I.; Wang, Guijun

    2000-01-01

    Novel 4-cyano-3-hydroxybutanoyl hydrazides (10), particularly R-chiral intermediates are described. The intermediates are useful in preparing (R)-3-hydroxy-4-trimethylaminobutyric acid (L-carnitine) and R-4-amino-3-hydroxybutyric acid (GABOB) and chiral chemical intermediates which are medically useful.

  8. IDIQ BS Ex A (Rev. 3.1, 4/9/13) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 31 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) ......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ....... 3 GC-3 INDEPENDENT CONTRACTOR (Jun 2009) ............................................................................ 4 GC-4 SUBCONTRACT INTERPRETATION (Jun

  9. IDIQ BS Ex A (Rev. 3.4, 12/15/14) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 12/15/14) Exhibit A General Conditions Page 1 of 20 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) ......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ....... 3 GC-3 INDEPENDENT CONTRACTOR (Jun 2009) ............................................................................ 4 GC-4 SUBCONTRACT INTERPRETATION (Jun

  10. Natural Gas Prices Forecast Comparison--AEO vs. Natural Gas Markets

    SciTech Connect (OSTI)

    Wong-Parodi, Gabrielle; Lekov, Alex; Dale, Larry

    2005-02-09

    This paper evaluates the accuracy of two methods to forecast natural gas prices: using the Energy Information Administration's ''Annual Energy Outlook'' forecasted price (AEO) and the ''Henry Hub'' compared to U.S. Wellhead futures price. A statistical analysis is performed to determine the relative accuracy of the two measures in the recent past. A statistical analysis suggests that the Henry Hub futures price provides a more accurate average forecast of natural gas prices than the AEO. For example, the Henry Hub futures price underestimated the natural gas price by 35 cents per thousand cubic feet (11.5 percent) between 1996 and 2003 and the AEO underestimated by 71 cents per thousand cubic feet (23.4 percent). Upon closer inspection, a liner regression analysis reveals that two distinct time periods exist, the period between 1996 to 1999 and the period between 2000 to 2003. For the time period between 1996 to 1999, AEO showed a weak negative correlation (R-square = 0.19) between forecast price by actual U.S. Wellhead natural gas price versus the Henry Hub with a weak positive correlation (R-square = 0.20) between forecasted price and U.S. Wellhead natural gas price. During the time period between 2000 to 2003, AEO shows a moderate positive correlation (R-square = 0.37) between forecasted natural gas price and U.S. Wellhead natural gas price versus the Henry Hub that show a moderate positive correlation (R-square = 0.36) between forecast price and U.S. Wellhead natural gas price. These results suggest that agencies forecasting natural gas prices should consider incorporating the Henry Hub natural gas futures price into their forecasting models along with the AEO forecast. Our analysis is very preliminary and is based on a very small data set. Naturally the results of the analysis may change, as more data is made available.

  11. Structure and optical properties of a noncentrosymmetric borate RbSr{sub 4}(BO{sub 3}){sub 3}

    SciTech Connect (OSTI)

    Xia, M.J.; Li, R.K.

    2013-01-15

    A new noncentrosymmetric borate, RbSr{sub 4}(BO{sub 3}){sub 3} (abbreviated as RSBO), has been grown from Rb{sub 2}O--B{sub 2}O{sub 3}--RbF flux and its crystal structure was determined by single crystal x-ray diffraction. It crystallizes in space group Ama2 with cell parameters of a=11.128(10) A, b=12.155(15) A, c=6.952(7) A, Z=4. The basic structural units are isolated planar BO{sub 3} groups. Second harmonic generation (SHG) test of the title compound by the Kurtz-Perry method shows that RSBO can be phase matchable with an effective SHG coefficient about two-thirds as large as that of KH{sub 2}PO{sub 4} (KDP). Finally, based on the anionic group approximation, the optical properties of the title compound are compared with those of the structure-related apatite-like compounds with the formula 'A{sub 5}(TO{sub n}){sub 3}X'. - Graphical abstract: RbSr{sub 4}(BO{sub 3}){sub 3} and some other borate NLO compounds, namely Ca{sub 5}(BO{sub 3}){sub 3}F RCa{sub 4}(BO{sub 3}){sub 3}O (R=Y or Gd) and Na{sub 3}La{sub 2}(BO{sub 3}){sub 3} can be viewed as the derivatives of apatite. They have similar formula composed of five cations and three anion groups (we call them 5/3 structures). The detailed SHG coefficients and optical properties of the apatite-like NLO crystals were compared and summarized. Highlights: Black-Right-Pointing-Pointer A new noncentrosymmetric borate RbSr{sub 4}(BO{sub 3}){sub 3} was grown from flux. Black-Right-Pointing-Pointer The RbSr{sub 4}(BO{sub 3}){sub 3} can be viewed as a derivative of the apatite-like structure. Black-Right-Pointing-Pointer The structure and its relationship to the optical properties of RbSr{sub 4}(BO{sub 3}){sub 3} are compared with other NLO crystals with apatite-like structures. Black-Right-Pointing-Pointer The basic structural units are the planar BO{sub 3} groups in the structure. Black-Right-Pointing-Pointer Second harmonic generation (SHG) test shows that RbSr{sub 4}(BO{sub 3}){sub 3} can be phase matchable with an effective SHG coefficient about two-thirds as large as that of KH{sub 2}PO{sub 4}.

  12. R&D Ex A (Rev. 3.4, 3/6/15) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 3/6/15) Exhibit A General Conditions Page 1 of 21 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  13. HONEYWELL - KANSAS CITY PLANT FISCAL YEARS 2009 THRU 2015 SMALL BUSINESS PROGRAM RESULTS & FORECAST

    National Nuclear Security Administration (NNSA)

    HONEYWELL - KANSAS CITY PLANT FISCAL YEARS 2009 THRU 2015 SMALL BUSINESS PROGRAM RESULTS & FORECAST CATEGORY Total Procurement Total SB Small Disad. Bus Woman-Owned SB Hub-Zone SB Veteran-Owned SB Service Disabled Vet. SB FY 2009 Dollars Goal (projected) $183,949,920 $82,690,000 $4,550,000 $8,829,596 $3,370,000 $5,025,000 $460,000 FY 2009 Dollars Accomplished $143,846,731 $68,174,398 $9,247,214 $11,333,905 $4,979,858 $6,713,791 $1,612,136 FY 2009 % Goal 45.0% 2.5% 4.8% 1.8% 2.7% 0.25% FY

  14. The addition of hydrogen atoms to diacetylene and the heats of formation of i-C4H3 and n-C4H3.

    SciTech Connect (OSTI)

    Klippenstein, Stephen J.; Miller, James A.

    2005-01-01

    In this article, we discuss in detail the addition of hydrogen atoms to diacetylene and the reverse dissociation reactions, H + C{sub 4}H{sub 2} {leftrightarrow} i-C{sub 4}H{sub 3} (R1) and H + C{sub 4}H{sub 2} n-C{sub 4}H{sub 3} (R2). The theory utilizes high-level electronic structure methodology to characterize the potential energy surface, Rice-Ramsperger-Kassel-Marcus (RRKM) theory to calculate microcanonical/J-resolved rate coefficients, and a two-dimensional master-equation approach to extract phenomenological (thermal) rate coefficients. Comparison is made with experimental results where they are available. The rate coefficients k{sub 1}(T, p) and k{sub 2}(T, p) are cast in forms that can be used in chemical kinetic modeling. In addition, we predict values of the heats of formation of i-C{sub 4}H{sub 3} and n-C{sub 4}H{sub 3} and discuss their importance in flame chemistry. Our basis-set extrapolated, quadratic-configuration-interaction with single and double excitations (and triple excitations added perturbatively), QCISD(T), predictions of these heats of formation at 298 K are 130.8 kcal/mol for n-C{sub 4}H{sub 3} and 119.3 kcal/mol for the i-isomer; multireference CI calculations with a nine-electron, nine-orbital, complete-active-space (CAS) reference wavefunction give just slightly larger values for these parameters. Our results are in good agreement with the recent focal-point analysis of Wheeler et al. (J. Chem. Phys. 2004, 121, 8800-8813), but they differ substantially for {Delta} H{sub f 298}{sup 0}(n-C{sub 4}H{sub 3}) with the earlier diffusion Monte Carlo predictions of Krokidis et al.

  15. Process For The Preparation Of 3,4-Dihyd Roxybutanoic Acid And Salts Thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I. (Haslett, MI)

    1994-06-07

    A process for the preparation of 3,4-dihydroxybutanoic acid (1) and salts thereof from a glucose source containing 1,4-linked glucose as a substituent is described. The process uses an alkali metal hdyroxide and hydrogen peroxide to convert the glucose source to (1). The compound (1) is useful as a chemical intermediate to naturally occurring fatty acids and is used to prepare 3,4-dihydroxybutanoic acid-gamma-lactone (2) and furanone (3), particularly stereoisomers of these compounds.

  16. Process for the preparation of 3,4-dihydroxybutanoic acid and salts thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I. (Haslett, MI)

    1994-01-01

    A process for the preparation of 3,4-dihydroxybutanoic acid (1) and salts thereof from a glucose source containing 1,4-linked glucose as a substituent is described. The process uses an alkali metal hdyroxide and hydrogen peroxide to convert the glucose source to (1). The compound (1) is useful as a chemical intermediate to naturally occurring fatty acids and is used to prepare 3,4-dihydroxybutanoic acid-gamma-lactone (2) and furanone (3), particularly stereoisomers of these compounds.

  17. Growth and characterization of 4-chloro-3-nitrobenzophenone single crystals using vertical Bridgman technique

    SciTech Connect (OSTI)

    Aravinth, K. Babu, G. Anandha Ramasamy, P.

    2014-04-24

    4-chloro-3-nitrobenzophenone (4C3N) has been grown by using vertical Bridgman technique. The grown crystal was confirmed by Powder X-ray diffraction analysis. The crystalline perfection of the grown crystal was examined by high-resolution X-ray diffraction study. The fluorescence spectra of grown 4C3N single crystals exhibit emission peak at 575 nm. The micro hardness measurements were used to analyze the mechanical property of the grown crystal.

  18. DOE Labor Relations Training and Information Session, November 3-4, 2015

    Office of Environmental Management (EM)

    Training Materials | Department of Energy Labor Relations Training and Information Session, November 3-4, 2015 Training Materials DOE Labor Relations Training and Information Session, November 3-4, 2015 Training Materials The Department of Energy held the First Annual DOE Labor Relations Training and Information Session on November 3-4, 2015. The training was held in Washington, DC and was designed for DOE site Human Resources personnel, representatives of DOE's contractor labor unions and

  19. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore » diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  20. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  1. Colorado Code of Regulations 4 CCR 723-3, Rules Regulating Electric...

    Open Energy Info (EERE)

    Colorado Code of Regulations 4 CCR 723-3, Rules Regulating Electric Utilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document-...

  2. Code of Colorado Regulations 4 CCR 723-3, Rules Regulating Electric...

    Open Energy Info (EERE)

    Code of Colorado Regulations 4 CCR 723-3, Rules Regulating Electric Utilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document-...

  3. Bifunctional Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+}nanocomposites obtained by the homogeneous precipitation method

    SciTech Connect (OSTI)

    Peng, Hongxia; Cui, Bin; Wang, Yingsai

    2013-05-15

    Graphical abstract: The TEM images reveal clearly the coreshell structures because of the obvious difference in contrast between the central part and the fringe, which indicates the Gd{sub 2}O{sub 3}:Eu{sup 3+} layer had successfully deposited on the magnetite Fe{sub 3}O{sub 4} cores. And Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles keep the spherical morphology, non-aggregation and rough surface. The images reveal that the average diameters of the Fe{sub 3}O{sub 4} and Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles are ?200 nm and ?250 nm, respectively. The thickness of Gd{sub 2}O{sub 3}:Eu{sup 3+} layer is ?25 nm. Highlights: ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites were synthesized by homogeneous precipitation method. ? Formation of coreshell nanostructure revealed by transmission electron microscopy. ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites showed magnetic behavior and fluorescence properties. ? Possible applications including bioseparation, drug delivery system, bio-labels, etc. - Abstract: An easy homogeneous precipitation method was developed for the synthesis of bifunctional magnetic-fluorescent nanocomposites with Fe{sub 3}O{sub 4} nanoparticles as the core and europium-doped gadolinium oxide (Gd{sub 2}O{sub 3}:Eu{sup 3+}) as the shell. The nanocomposites showed both strong magnetic behavior and unique Eu-related fluorescence properties with a high emission intensity, which may lead to development of nanocomposites with great potential for applications in drug targeting, biosensors, and diagnostic analysis.

  4. Morphology control of open-framework zinc phosphate Zn{sub 4}(H{sub 3}O)(NH{sub 4}){sub 3}(PO{sub 4}){sub 4} via microwave-assisted technique

    SciTech Connect (OSTI)

    Ding, Ling; Song, Yu; Yang, Wei; Xue, Run-Miao; Zhai, Shang-Ru; An, Qing-Da

    2013-08-15

    Open-framework zinc phosphates were synthesized by microwave-assisted technique, and it was shown that the morphology of as-prepared materials could be easily tailored by changing synthesis temperature, reaction time and pH value. During the synthesis, when the reaction temperature increases from 130 C to 220 C, the products transformed from hexagonal prisms to polyhedron along with the disappearance of the hexagonal prisms vertical plane. Simultaneously, both the reaction time and pH value could promote the nucleation and growth of crystal particles. More interestingly, the target products with different morphologies could be obtained by varying the usage of NaOH or NH{sub 3}H{sub 2}O at 130 C during the microwave synthesis process. - Graphical abstract: Zinc phosphates with variable morphologies can be obtained by simply tuning the microwave-heating temperatures. Display Omitted - Highlights: Synthesis of open-framework Zn{sub 4} (H{sub 3}O) (NH{sub 4}){sub 3}(PO{sub 4}){sub 4} compounds employing microwave technique. Dependence of morphology on the reaction conditions. Morphology transformation from hexagonal prisms to polyhedron was observed.

  5. Combining multi-objective optimization and bayesian model averaging to calibrate forecast ensembles of soil hydraulic models

    SciTech Connect (OSTI)

    Vrugt, Jasper A; Wohling, Thomas

    2008-01-01

    Most studies in vadose zone hydrology use a single conceptual model for predictive inference and analysis. Focusing on the outcome of a single model is prone to statistical bias and underestimation of uncertainty. In this study, we combine multi-objective optimization and Bayesian Model Averaging (BMA) to generate forecast ensembles of soil hydraulic models. To illustrate our method, we use observed tensiometric pressure head data at three different depths in a layered vadose zone of volcanic origin in New Zealand. A set of seven different soil hydraulic models is calibrated using a multi-objective formulation with three different objective functions that each measure the mismatch between observed and predicted soil water pressure head at one specific depth. The Pareto solution space corresponding to these three objectives is estimated with AMALGAM, and used to generate four different model ensembles. These ensembles are post-processed with BMA and used for predictive analysis and uncertainty estimation. Our most important conclusions for the vadose zone under consideration are: (1) the mean BMA forecast exhibits similar predictive capabilities as the best individual performing soil hydraulic model, (2) the size of the BMA uncertainty ranges increase with increasing depth and dryness in the soil profile, (3) the best performing ensemble corresponds to the compromise (or balanced) solution of the three-objective Pareto surface, and (4) the combined multi-objective optimization and BMA framework proposed in this paper is very useful to generate forecast ensembles of soil hydraulic models.

  6. Thermoacoustic engine simulations with lattice Boltzmann CFD. Tasks 3, 4 and 5 progress report

    SciTech Connect (OSTI)

    1995-02-06

    Advanced Projects Research Incorporated has completed tasks number 3, 4 and 5 of the specified tasks in the LANL subcontract. Task 3 required measurement of the acoustic attenuation for various thermoacoustic conditions and Task 4 involved the analysis of the energy transfer mechanisms for the geometries of Task 3. Finally, Task 5 specified that simulations of thermoacoustic engine configurations used at LANL were to be performed. Discussion of all 3 task results is presented.

  7. 2013 3rd Qtr Package

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Agency * The 3 rd Quarter forecast for the end-of-year (EOY) Agency adjusted net revenue is 75 million. o This is 54 million higher than the 2 nd Quarter Review forecast,...

  8. Text-Alternative Version LED Lighting Forecast

    Broader source: Energy.gov [DOE]

    The DOE report Energy Savings Forecast of Solid-State Lighting in General Illumination Applications estimates the energy savings of LED white-light sources over the analysis period of 2013 to 2030....

  9. energy data + forecasting | OpenEI Community

    Open Energy Info (EERE)

    energy data + forecasting Home FRED Description: Free Energy Database Tool on OpenEI This is an open source platform for assisting energy decision makers and policy makers in...

  10. Offshore Lubricants Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Forecast Home There are currently no posts in this category. Syndicate...

  11. Coal Fired Power Generation Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    Coal Fired Power Generation Market Forecast Home There are currently no posts in this category. Syndicate...

  12. Distribution of Wind Power Forecasting Errors from Operational Systems (Presentation)

    SciTech Connect (OSTI)

    Hodge, B. M.; Ela, E.; Milligan, M.

    2011-10-01

    This presentation offers new data and statistical analysis of wind power forecasting errors in operational systems.

  13. Metrics for Evaluating the Accuracy of Solar Power Forecasting (Presentation)

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B.; Florita, A.; Lu, S.; Hamann, H.; Banunarayanan, V.

    2013-10-01

    This presentation proposes a suite of metrics for evaluating the performance of solar power forecasting.

  14. RSE Table N6.3 and N6.4. Relative Standard Errors for Tables N6.3 and N6.4

    U.S. Energy Information Administration (EIA) Indexed Site

    3 and N6.4. Relative Standard Errors for Tables N6.3 and N6.4;" " Unit: Percents." " "," ",," ","Distillate"," "," " " "," ",,,"Fuel Oil",,,"Coal" "NAICS"," ","Net Demand","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","for Electricity(b)","Fuel

  15. Nambe Pueblo Water Budget and Forecasting model.

    SciTech Connect (OSTI)

    Brainard, James Robert

    2009-10-01

    This report documents The Nambe Pueblo Water Budget and Water Forecasting model. The model has been constructed using Powersim Studio (PS), a software package designed to investigate complex systems where flows and accumulations are central to the system. Here PS has been used as a platform for modeling various aspects of Nambe Pueblo's current and future water use. The model contains three major components, the Water Forecast Component, Irrigation Scheduling Component, and the Reservoir Model Component. In each of the components, the user can change variables to investigate the impacts of water management scenarios on future water use. The Water Forecast Component includes forecasting for industrial, commercial, and livestock use. Domestic demand is also forecasted based on user specified current population, population growth rates, and per capita water consumption. Irrigation efficiencies are quantified in the Irrigated Agriculture component using critical information concerning diversion rates, acreages, ditch dimensions and seepage rates. Results from this section are used in the Water Demand Forecast, Irrigation Scheduling, and the Reservoir Model components. The Reservoir Component contains two sections, (1) Storage and Inflow Accumulations by Categories and (2) Release, Diversion and Shortages. Results from both sections are derived from the calibrated Nambe Reservoir model where historic, pre-dam or above dam USGS stream flow data is fed into the model and releases are calculated.

  16. Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Docket No....

  17. The role of MAP4K3 in lifespan regulation of Caenorhabditiselegans

    SciTech Connect (OSTI)

    Khan, Maruf H.; Hart, Matthew J.; Rea, Shane L.

    2012-08-24

    Highlights: Black-Right-Pointing-Pointer Inhibition of MAP4K3 by RNAi leads to increased mean lifespan in Caenorhabditis elegans. Black-Right-Pointing-Pointer Mutation in the citron homology domain of MAP4K3 leads to increased mean lifespan. Black-Right-Pointing-Pointer Mutation in the kinase domain of MAP4K3 has no significant effect on mean lifespan. -- Abstract: The TOR pathway is a kinase signaling pathway that regulates cellular growth and proliferation in response to nutrients and growth factors. TOR signaling is also important in lifespan regulation - when this pathway is inhibited, either naturally, by genetic mutation, or by pharmacological means, lifespan is extended. MAP4K3 is a Ser/Thr kinase that has recently been found to be involved in TOR activation. Unexpectedly, the effect of this protein is not mediated via Rheb, the more widely known TOR activation pathway. Given the role of TOR in growth and lifespan control, we looked at how inhibiting MAP4K3 in Caenorhabditiselegans affects lifespan. We used both feeding RNAi and genetic mutants to look at the effect of MAP4K3 deficiency. Our results show a small but significant increase in mean lifespan in MAP4K3 deficient worms. MAP4K3 thus represents a new target in the TOR pathway that can be targeted for pharmacological intervention to control lifespan.

  18. On the peculiar properties of triangular-chain EuCr{sub 3}(BO{sub 3}){sub 4} antiferromagnet

    SciTech Connect (OSTI)

    Gondek, ?.; Szytu?a, A.; Przewo?nik, J.; ?ukrowski, J.; Prokhorov, A.; Chernush, L.; Zubov, E.; Dyakonov, V.; Tyvanchuk, Yu.

    2014-02-15

    In this paper we report studies on EuCr{sub 3}(BO{sub 3}){sub 4} compound, that is a member of newly discovered family of huntite-related specimens for non-linear optics. For the first time, the uncommon temperature dependence of the EuCr{sub 3}(BO{sub 3}){sub 4} lattice parameters is reported. Additionally, the magnetism of this compound is extremely interesting. Namely, a possible interplay in between potentially magnetic rare-earth ions and 3d metal stacked within quasi-1D chain that can lead to a great variety of magnetic behaviour. Indeed, in our studies we have found 3D-long range ordering with metamagnetic behaviour, while at higher temperature the magnetic chains become uncoupled. - Graphical abstract: Torsion-like vibrations are the key to understand negative thermal expansion along the a-axis. Display Omitted - Highlights: EuCr{sub 3}(BO{sub 3}){sub 4} is a peculiar triangular-chain antiferromagnet. Rare earth sublattice is non-magnetic with Eu{sup 3+} configuration. Cr{sup 3+} magnetic moments show 1-D behaviour along with spin fluctuations. Torsion vibrations of Cr triangular tubes lead to anomalous expansion of unit cell.

  19. Microsoft Word - T4_VEIC_TO2_ Sub3_Residential Retrofit Program Design

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide Play Book_TEAM 4 FINAL.docx | Department of Energy Microsoft Word - T4_VEIC_TO2_ Sub3_Residential Retrofit Program Design Guide Play Book_TEAM 4 FINAL.docx Microsoft Word - T4_VEIC_TO2_ Sub3_Residential Retrofit Program Design Guide Play Book_TEAM 4 FINAL.docx PDF icon residential_retrofit_program_design_guide.pdf More Documents & Publications Microsoft Word - Horizon Wind Energy Comments.docx Reporting Pre-guidance Announcement 06-02-2011 Letter to SEP Recipients on Changes to

  20. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Citation Details In-Document Search Title: HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Crystal and interfacial structures of oxide nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y{sub 2}O{sub 3} ODS ferritic steel have been examined using high-resolution transmission electron microscopy (HRTEM) techniques. Oxide nanoparticles with a complex-oxide core and an amorphous

  1. Molecular and crystal structures of 4'-hydroxy derivative of (3R,6R)-3-methyl-6-isopropyl-2-(4-phenylbenzylidene)cyclohexanone

    SciTech Connect (OSTI)

    Kutulya, L. A.; Kulishov, V. I.; Shishkina, S. V.; Tolochko, A. S.; Roshal', A. D.; Shishkin, O. V.

    2008-05-15

    The molecular and crystal structures of the 4-hydroxy derivative of (3R,6R)-3-methyl-6-isopropyl-2-(4-phenylbenzylidene)cyclohexanone are determined by X-ray diffraction analysis. Single crystals are orthorhombic, a = 9.147(2) A, b = 12.959(2) A, c = 15.695(5) A, V = 1860.4(7) A{sup 3}, Z = 4, and space group P2{sub 1}2{sub 1}2{sub 1}. The cyclohexanone ring in the crystal structure has an asymmetric chair conformation. The puckering parameters are as follows: the puckering amplitude S is 0.91, and the puckering angles {theta} and {psi} are equal to 20.2{sup o} and 10.4{sup o}, respectively. It is established that the enone fragment and the cyclohexanone ring in molecules are flattened considerably. In the crystal structure, the molecules are linked by the hydrogen bonds (bond length, 1.85 A). The structural features and the strength of the hydrogen bonds for the compound under investigation and its analogue with one benzene ring are compared using the X-ray diffraction and IR spectroscopic data.

  2. DOE Provides $4.3 Million to Improve Reliability of the U.S. Electric Grid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Provides $4.3 Million to Improve Reliability of the U.S. Electric Grid DOE Provides $4.3 Million to Improve Reliability of the U.S. Electric Grid August 21, 2009 - 3:47pm Addthis Innovative Synchrophasor Research Will Provide Better Real-Time Information WASHINGTON, DC - The Department of Energy's Office of Electricity and Energy Reliability today announced that it will provide $4.3 million for four projects that will use innovative synchrophasor research to improve

  3. RELAP5-3D Developmental Assessment: Comparison of Versions 4.2.1i and 4.1.3i

    SciTech Connect (OSTI)

    Paul D. Bayless

    2014-06-01

    Figures have been generated comparing the parameters used in the developmental assessment of the RELAP5-3D code using versions 4.2.1i and 4.1.3i. The figures, which are the same as those used in Volume III of the RELAP5-3D code manual, compare calculations using the semi-implicit solution scheme with available experiment data. These figures provide a quick, visual indication of how the code predictions changed between these two code versions and can be used to identify cases in which the assessment judgment may need to be changed in Volume III of the code manual. Changes to the assessment judgments made after reviewing all of the assessment cases are also provided.

  4. RELAP5-3D Developmental Assessment: Comparison of Versions 4.0.3is and 2.4.2is

    SciTech Connect (OSTI)

    Paul D. Bayless

    2012-09-01

    Figures have been generated comparing the parameters used in the developmental assessment of the RELAP5-3D code using versions 4.0.3is and 2.4.2is. The figures, which are the same as those used in Volume III of the RELAP5-3D code manual, compare calculations using the semi-implicit solution scheme with available experiment data. These figures provide a quick, visual indication of how the code predictions changed between these two code versions and can be used to identify cases in which the assessment judgment may need to be changed in Volume III of the code manual. Changes to the assessment judgments made after reviewing all of the assessment cases are also provided.

  5. Structural and electronic response of U{sub 3}Fe{sub 4}Ge{sub 4} to high pressure

    SciTech Connect (OSTI)

    Henriques, M. S.; Prchal, J.; Havela, L.; Raison, P.; Heathman, S.; Griveau, J.-C.; Colineau, E.; Gonalves, A. P.

    2015-03-21

    Structural, magnetic, and electrical properties have been studied on a U{sub 3}Fe{sub 4}Ge{sub 4} single crystal under hydrostatic pressure. The orthorhombic crystal structure is found to be stable up to 30 GPa, the highest applied pressure, but the compressibility is strongly anisotropic. Contrary to typical uranium intermetallics for which the softest lattice direction is along the shortest inter-uranium links, in U{sub 3}Fe{sub 4}Ge{sub 4} the lattice is compressed most in a perpendicular direction for the high pressure range. The elastic properties are modified considerably in the vicinity of 1?GPa when the b axis is transformed from least compressible to most compressible. The bulk modulus is found to be about 150?GPa. The anomalies in the elastic properties are reflected in the electronic properties that consistently indicate a change of the magnetic ground state from ferromagnetic to antiferromagnetic. Both types of order exhibit a gap in the magnon spectrum; however, it is twice as high for the ferromagnetic state. The magnetoresistance reveals field-induced transitions of different origins in the antiferromagnetic state along the easy and hard magnetization directions.

  6. 4-(3-Methoxyphenyl)-2,6-dimethylcyclohex-3-enecarboxylic acid

    SciTech Connect (OSTI)

    Xie, Songwen; Nusbaum, Dannette A.; Stein, Holly J.; Pink, Maren

    2012-03-15

    The racemic title compound, C{sub 16}H{sub 20}O{sub 3}, was synthesized to study the hydrogen-bonding interaction of the two enantiomers in the solid state. In the crystal structure, R and S pairs of the racemate are linked by pairs of intermolecular O-H...O hydrogen bonds, producing centrosymmetric R{sub 2}{sup 2}(8) rings.

  7. Vicarious nucleophilic substitution using 4-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxylamine to prepare 1,3-diamino-2,4,6-trinitrobenzene or 1,3,5-triamino-2,4,6-trinitrobenzene

    DOE Patents [OSTI]

    Mitchell, Alexander R. (Livermore, CA); Pagoria, Philip F. (Livermore, CA); Schmidt, Robert D. (Livermore, CA)

    1997-01-01

    The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,-trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0.degree. and 50.degree. C. for between about 0.1 and 24 hr, a trinitroaromatic compound of structure V: ##STR1## wherein X, Y, and Z are each independently selected from the group consisting of --H and --NH.sub.2, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen; with an effective amount of 1-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxamine to produce DATB or TATB; in the presence of a strong base selected from sodium butoxide, potassium butoxide, potassium propoxide, sodium propoxide, sodium ethoxide, potassium ethoxide, sodium methoxide, potassium methoxide, and combinations thereof; in a solvent selected from the group consisting of methanol, ethanol, propanol, butanol, dimethylsulphoxide, N-methylpyrrolidone, hexamethylphosphoramide, dimethylformide, dimethylacetamide and mixtures thereof, provided that when alcohols are present or when hydroxylamine or its O-alkyl derivatives replace ATA primarily DATB is formed; and (b) isolating the DATB or TATB produced. DATB and TATB are important and useful specialty explosives and intermediates for other materials.

  8. Vicarious nucleophilic substitution using 4-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxylamine to prepare 1,3-diamino-2,4,6-trinitrobenzene or 1,3,5-triamino-2,4,6-trinitrobenzene

    DOE Patents [OSTI]

    Mitchell, A.R.; Pagoria, P.F.; Schmidt, R.D.

    1997-05-27

    The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0 and 50 C for between about 0.1 and 24 hr, a trinitroaromatic compound of the structure shown where X, Y, and Z are each independently selected from the group consisting of -H and -NH{sub 2}, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen; with an effective amount of 1-amino-1,2,4-triazole, hydroxylamine or O-alkylhydroxamine to produce DATB or TATB; in the presence of a strong base selected from sodium butoxide, potassium butoxide, potassium propoxide, sodium propoxide, sodium ethoxide, potassium ethoxide, sodium methoxide, potassium methoxide, and combinations thereof; in a solvent selected from the group consisting of methanol, ethanol, propanol, butanol, dimethylsulphoxide, N-methylpyrrolidone, hexamethylphosphoramide, dimethylformide, dimethylacetamide and mixtures thereof, provided that when alcohols are present or when hydroxylamine or its O-alkyl derivatives replace ATA primarily DATB is formed; and (b) isolating the DATB or TATB produced. DATB and TATB are important and useful specialty explosives and intermediates for other materials.

  9. Microstructural Contol of the Porous Si3N4 Ceramics Consisted of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3-Dimensionally Intermingled Rod-like Grains | Department of Energy Contol of the Porous Si3N4 Ceramics Consisted of 3-Dimensionally Intermingled Rod-like Grains Microstructural Contol of the Porous Si3N4 Ceramics Consisted of 3-Dimensionally Intermingled Rod-like Grains Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and

  10. Ramp Forecasting Performance from Improved Short-Term Wind Power Forecasting: Preprint

    SciTech Connect (OSTI)

    Zhang, J.; Florita, A.; Hodge, B. M.; Freedman, J.

    2014-05-01

    The variable and uncertain nature of wind generation presents a new concern to power system operators. One of the biggest concerns associated with integrating a large amount of wind power into the grid is the ability to handle large ramps in wind power output. Large ramps can significantly influence system economics and reliability, on which power system operators place primary emphasis. The Wind Forecasting Improvement Project (WFIP) was performed to improve wind power forecasts and determine the value of these improvements to grid operators. This paper evaluates the performance of improved short-term wind power ramp forecasting. The study is performed for the Electric Reliability Council of Texas (ERCOT) by comparing the experimental WFIP forecast to the current short-term wind power forecast (STWPF). Four types of significant wind power ramps are employed in the study; these are based on the power change magnitude, direction, and duration. The swinging door algorithm is adopted to extract ramp events from actual and forecasted wind power time series. The results show that the experimental short-term wind power forecasts improve the accuracy of the wind power ramp forecasting, especially during the summer.

  11. Process for the preparation of 3,4-dihydroxybutanoic acid and salts thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I. (Haslett, MI)

    1994-01-01

    A process for the preparation of 3,4-dihydroxybutanoic acid (1) and salts thereof from a glucose source containing 1,4-1inked glucose as a substituent is described. The process uses an alkali metal hdyroxide and hydrogen peroxide to convert the glucose source to (1). The compound (1) is useful as a chemical intermediate to naturally occurring fatty acids and is used to prepare 3,4-dihydroxybutanoic acid-gamma-lactone (2) and furanone (3), particularly stereoisomers of these compounds.

  12. 3-nitro-1,2,4-triazol-5-one, a less sensitive explosive

    DOE Patents [OSTI]

    Lee, Kien-Yin (Los Alamos, NM); Coburn, Michael D. (Los Alamos, NM)

    1988-01-01

    A less sensitive explosive, 3-nitro-1,2,4-triazol-5-one. The compound 3-nitro-1,2,4-triazol-5-one (NTO) has a crystal density of 1.93 g/cm.sup.3 and calculated detonation velocity and pressure equivalent to those of RDX. It can be prepared in high yield from inexpensive starting materials in a safe synthesis. Results from initial small-scale sensitivity tests indicate that NTO is less sensitive than RDX and HMX in all respects. A 4.13 cm diameter, unconfined plate-dent test at 92% of crystal density gave the detonation pressure predicted for NTO by the BKW calculation.

  13. DOE - Office of Legacy Management -- Dayton Project Units 3 and 4 - OH 07

    Office of Legacy Management (LM)

    Units 3 and 4 - OH 07 FUSRAP Considered Sites Site: Dayton Project Units 3 & 4 (OH.07 ) U.S. Army Corps of Engineers (FUSRAP) - No Further Action Designated Name: Not Designated Alternate Name: Monsanto Units III and IV Unit III - Board of Education Maintenance Facility Unit IV - Runnymede Playhouse OH.07-1 OH.07-2 OH.07-3 Location: Unit III - 1601 W. First Street Unit IV - Runnymede Road and Dixon Avenue , Dayton , Ohio OH.07-4 OH.07-5 Evaluation Year: 1987 Site Operations: October 1943 to

  14. A reduced graphene oxide/Co{sub 3}O{sub 4} composite for supercapacitor electrode

    SciTech Connect (OSTI)

    Xiang, Chengcheng; Li, Ming; Zhi, Mingjia; Manivannan, Ayyakkannu; Wu, Nianqiang

    2013-03-15

    20 nm sized Co{sub 3}O{sub 4} nanoparticles are in-situ grown on the chemically reduced graphene oxide (rGO) sheets to form a rGO-Co{sub 3}O{sub 4} composite during hydrothermal processing. The rGO-Co{sub 3}O{sub 4} composite is employed as the pseudocapacitor electrode in the 2 M KOH aqueous electrolyte solution. The rGOCo{sub 3}O{sub 4} composite electrode exhibits a specific capacitance of 472 F/g at a scan rate of 2 mV/s in a two-electrode cell. 82.6% of capacitance is retained when the scan rate increases to 100 mV/s. The rGOCo{sub 3}O{sub 4} composite electrode shows high rate capability and excellent long-term stability. It also exhibits high energy density at relatively high power density. The energy density reaches 39.0 Wh/kg at a power density of 8.3 kW/kg. The super performance of the composite electrode is attributed to the synergistic effects of small size and good redox activity of the Co{sub 3}O{sub 4} particles combined with high electronic conductivity of the rGO sheets.

  15. Ultrathin Li3VO4 Nanoribbon/Graphene Sandwich-Like Nanostructures...

    Office of Scientific and Technical Information (OSTI)

    Title: Ultrathin Li3VO4 NanoribbonGraphene Sandwich-Like Nanostructures with Ultrahigh Lithium ion Storage Properties Two-dimensional (2D) "graphene-like" inorganic materials, ...

  16. Increases in 3He/4He in Fumarolic Gas Associated with the 1989...

    Open Energy Info (EERE)

    Beneath Mammoth Mountain, California Citation Michael L. Sorey,B. Mack Kennedy,William C. Evans,Christopher D. Farrar. 1990. Increases in 3He4He in Fumarolic Gas Associated with...

  17. 4 Code of Colorado Regulations (CCR) 723-3 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 4 Code of Colorado Regulations (CCR) 723-3Legal Abstract Colorado Public Utilities...

  18. Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and Weight...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and WeightLegal Abstract Statute outlining...

  19. Colorado - 4 C.C.R. 723-3-3703 - Applications | Open Energy Informatio...

    Open Energy Info (EERE)

    OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: Colorado - 4 C.C.R. 723-3-3703 - ApplicationsLegal Abstract This section governs the application...

  20. 4 C.C.R. 723-3-3206 - Construction or Extension of Transmission...

    Open Energy Info (EERE)

    C.C.R. 723-3-3206 - Construction or Extension of Transmission Facilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 4...

  1. Colorado - 4 C.C.R. 723-3-3705 - Prehearing Conference, Parties...

    Open Energy Info (EERE)

    OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: Colorado - 4 C.C.R. 723-3-3705 - Prehearing Conference, Parties and Public NoticeLegal Abstract This...

  2. Colorado - 4 C.C.R. 723-3 | Open Energy Information

    Open Energy Info (EERE)

    OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: Colorado - 4 C.C.R. 723-3Legal Abstract These rules describe the electric service to be provided by...

  3. Tax Deduction Qualified Software- Green Building Studio Web Service version 3.4

    Broader source: Energy.gov [DOE]

    Information about the Green Building Studio Web Service version 3.4 qualified computer software, which calculates energy and power cost savings that meet federal tax incentive requirements for commercial buildings.

  4. ARPA-E awards IIT-Argonne team $3.4 million for breakthrough battery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technology | Argonne National Laboratory The Illinois Insitutue of Technology will share $3.4 million to develop a prototype of their "nanoelectrofuel" flow battery. Funding for the prototype project comes from the U.S. Department of Energy's Advanced Research Projects Agency-Energy. Click to enlarge. The Illinois Insitutue of Technology will share $3.4 million to develop a prototype of their "nanoelectrofuel" flow battery. Funding for the prototype project comes from the

  5. Policy Flash 2014-01 Acquisition Guide 15.4-3 Negotiation Documentation:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-negotiation Plan & the Price Negotiation Memorandum | Department of Energy 1 Acquisition Guide 15.4-3 Negotiation Documentation: Pre-negotiation Plan & the Price Negotiation Memorandum Policy Flash 2014-01 Acquisition Guide 15.4-3 Negotiation Documentation: Pre-negotiation Plan & the Price Negotiation Memorandum Questions concerning this policy flash should be directed to Sandy Shin of the Field Assistance and Oversight Division, Office Acquisition and Project Management at

  6. Ultrathin Li3VO4 Nanoribbon/Graphene Sandwich-Like Nanostructures with

    Office of Scientific and Technical Information (OSTI)

    Ultrahigh Lithium ion Storage Properties (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Ultrathin Li3VO4 Nanoribbon/Graphene Sandwich-Like Nanostructures with Ultrahigh Lithium ion Storage Properties Citation Details In-Document Search Title: Ultrathin Li3VO4 Nanoribbon/Graphene Sandwich-Like Nanostructures with Ultrahigh Lithium ion Storage Properties Two-dimensional (2D) "graphene-like" inorganic materials, because of the short lithium ion

  7. Type Ia supernovae yielding distances with 3-4% precision (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Type Ia supernovae yielding distances with 3-4% precision Citation Details In-Document Search Title: Type Ia supernovae yielding distances with 3-4% precision The luminosities of Type Ia supernovae (SN), the thermonuclear explosions of white dwarf stars, vary systematically with their intrinsic color and light-curve decline rate. These relationships have been used to calibrate their luminosities to within ~0.14-0.20 mag from broadband optical light curves, yielding

  8. Mesoporous Fe{sub 3}O{sub 4}/hydroxyapatite composite for targeted drug delivery

    SciTech Connect (OSTI)

    Gu, Lina; He, Xiaomei; Wu, Zhenyu

    2014-11-15

    Highlights: Mesoporous Fe{sub 3}O{sub 4}/hydroxyapatite composite was synthesized by a simple, efficient and environmental friendly method. The prepared material had a large surface area, high pore volume, and good magnetic separability. DOX-loaded Fe{sub 3}O{sub 4}/hydroxyapatite composite exhibited surprising slow drug release behavior and pH-dependent behavior. - Abstract: In this contribution, we introduced a simple, efficient, and green method of preparing a mesoporous Fe{sub 3}O{sub 4}/hydroxyapatite (HA) composite. The as-prepared material had a large surface area, high pore volume, and good magnetic separability, which made it suitable for targeted drug delivery systems. The chemotherapeutic agent doxorubicin (DOX) was used to investigate the drug release behavior of Fe{sub 3}O{sub 4}/HA composite. The drug release profiles displayed a little burst effect and pH-dependent behavior. The release rate of DOX at pH 5.8 was larger than that at pH 7.4, which could be attributed to DOX protonation in acid medium. In addition, the released DOX concentrations remained at 0.83 and 1.39 ?g/ml at pH 7.4 and 5.8, respectively, which indicated slow, steady, and safe release rates. Therefore, the as-prepared Fe{sub 3}O{sub 4}/hydroxyapatite composite could be an efficient platform for targeted anticancer drug delivery.

  9. Synthesis, crystal structure and DFT studies of N-(4-acetyl-5,5-dimethyl-4,5-dihydro-1,3,4-thiadiazol-2-yl)acetamide

    SciTech Connect (OSTI)

    Gautam, P.; Gautam, D.; Chaudhary, R. P.

    2013-12-15

    The title compound N-(4-acetyl-5,5-dimethyl-4,5-dihydro-1,3,4-thiadiazol-2-yl)acetamide (III) was obtained from the reaction of 2-(propan-2-ylidene)hydrazinecarbothioamide (II) with acetic anhydride instead of formation of the desired thiosemcarbazide derivative of Meldrum acid. The structures of II and III were established by elemental analysis, IR, NMR, Mass and X-ray crystallographic studies. II crystallizes in triclinic system, sp. gr. P-bar1 Z = 2; III crystallizes in the monoclinic system, sp. gr. P2{sub 1}/c, Z = 8. Density functional theory (DFT) calculations have been carried out for III. {sup 1}H and {sup 13}C NMR of III has been calculated and correlated with experimental results.

  10. L3:THM.ITM.P4.02 Igor Bolotnov NCSU

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P4.02 Igor Bolotnov NCSU Completed: 1/31/12 CASL-U-2012-0012-000 CASL-U-2012-0012-000 ITM Simulations of Subcooled Flow Nucleate Boiling Experiment at TAMU L3:THM.ITM.P4.02 milestone report Igor A. Bolotnov, North Carolina State University Carlos E. Estrada-Perez, Texas A&M University Yassin A. Hassan, Texas A&M University 31 January 2012 (Ver. 1.0) L3:THM.ITM.P4.02 report 2 Abstract: A set of challenge simulations are formulated by CASL-THM members based on anticipated experimental data

  11. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P. (Livermore, CA); Moody, Gordon L. (Tracy, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-01-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  12. Preparation of 1,3,5-triamo-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P. (Livermore, CA); Moody, Gordon L. (Tracy, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-05-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  13. Table HC3.4 Space Heating Characteristics by Owner-Occupied Housing Unit, 2005

    Gasoline and Diesel Fuel Update (EIA)

    .4 Space Heating Characteristics by Owner-Occupied Housing Unit, 2005 Million U.S. Housing Units Total................................................................ 111.1 78.1 64.1 4.2 1.8 2.3 5.7 Do Not Have Space Heating Equipment....... 1.2 0.6 0.3 N Q Q Q Have Main Space Heating Equipment.......... 109.8 77.5 63.7 4.2 1.8 2.2 5.6 Use Main Space Heating Equipment............ 109.1 77.2 63.6 4.2 1.8 2.1 5.6 Have Equipment But Do Not Use It.............. 0.8 0.3 Q N Q Q Q Main Heating Fuel

  14. A two-fold interpenetrating 3D metal-organic framework material constructed from helical chains linked via 4,4'-H{sub 2}bpz fragments

    SciTech Connect (OSTI)

    Xie Yiming; Zhao Zhenguo; Wu Xiaoyuan; Zhang Qisheng; Chen Lijuan; Wang Fei; Chen Shanci; Lu Canzhong

    2008-12-15

    A 3-connected dia-f-type metal-organic framework compound {l_brace}[Ag(L){sub 3/2}H{sub 2}PO{sub 4}]{r_brace}{sub n} (1) has been synthesized by self-assembly of 4,4'-H{sub 2}bpz (L=4,4'-H{sub 2}bpz=3,3',5,5'-tetramethyl-4,4'-bipyrazole) and Ag{sub 4}P{sub 2}O{sub 7} under hydrothermal conditions. It crystallizes in the tetragonal space group I4{sub 1}/acd with a=21.406(4) A, b=21.406(4) A, c=36.298(8) A, Z=32. X-ray single-crystal diffraction reveals that 1 has a three-dimensional framework with an unprecedented alternate left- and right-handed helices structure, featuring a non-uniform two-fold interpenetrated (4.14{sup 2}) net. Photoluminescent investigation reveals that the title compound displays interesting emissions in a wide region, which shows that the title compound may be a good potential candidate as a photoelectric material. - Graphical abstract: A 3-connected dia-f-type metal-organic framework compound [Ag(4,4'-bpz){sub 3/2}H{sub 2}PO{sub 4}] shows unprecedented alternating left- and right-handed helices structure, featuring a non-uniform two-fold interpenetrated (4.14{sup 2}) net.

  15. L3:AMA.RX.P4.01 Hongbin Zhang INL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AMA.RX.P4.01 Hongbin Zhang INL Completed: 1/31/12 CASL-U-2012-0011-000 Consortium for Advanced Simulation of LWRs CASL-U-2012-0011-000 Power Uprate Limitation Assessment Milestone Deliverable - AMA.RX.P4.01 1 Introduction This is a follow-on task of an AMA Level 3 milestone (AMA.RX.P3.01) delivered during POR- 3 to further assess the LWR power uprate limitations and align CASL work to facilitate additional power uprates. A power uprate workshop was held at ORNL in September 2011. A comprehensive

  16. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | DOE PAGES Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Authors: Dhar, S. K. [1] ; Provino, A. [2] ; Manfrinetti, P. [2] ; Kulkarni, R. [1] ; Goyal, Neeraj [1] ; Paudyal, D. [3] + Show Author Affiliations Department of Condensed Matter Physics & Materials Science, T.I.F.R., Homi Bhabha Road, Colaba, Mumbai, 400005, India Department of Chemistry, University of Genova, Via Dodecaneso 31, 16146

  17. EIA revises up forecast for U.S. 2013 crude oil production by 70,000 barrels per day

    Gasoline and Diesel Fuel Update (EIA)

    EIA revises up forecast for U.S. 2013 crude oil production by 70,000 barrels per day The forecast for U.S. crude oil production keeps going higher. The U.S. Energy Information Administration revised upward its projection for crude oil output in 2013 by 70,000 barrels per day and for next year by 190,000 barrels per day. U.S. oil production is now on track to average 7.5 million barrels per day this year and rise to 8.4 million barrels per day in 2014, according to EIA's latest monthly forecast.

  18. 3-nitro-1,2,4-triazol-5-one: A less sensitive explosive

    DOE Patents [OSTI]

    Lee, Kien-Yin; Coburn, M.D.

    1987-01-30

    A less sensitive explosive, 3-nitro-1,2,4-triazol-5-one. The compound 3-nitro--1,2,4-triazol-5-one (NTO) has a crystal density of 1.93 g/cm/sup 3/ and calculated detonation velocity and pressure equivalent to those of RDX. It can be prepared in high yield from inexpensive starting materials in a safe synthesis. Results from initial small-scale sensitivity tests indicate that NTO is less sensitive than RDX and HMX in all respects. A 4.13 cm diameter, unconfined plate-dent test at 92% of crystal density gave the detonation pressure predicted for NTO by the BKW calculation. 3 tabs.

  19. Solar Forecasting Gets a Boost from Watson, Accuracy Improved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Forecasting Gets a Boost from Watson, Accuracy Improved by 30% Solar Forecasting Gets a Boost from Watson, Accuracy Improved by 30% October 27, 2015 - 11:48am Addthis IBM ...

  20. A Review of Variable Generation Forecasting in the West: July...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rely on an array of VG forecasts suited to different purposes. Some of the most common types of VG forecasts are defined below: 2 This report is available at no cost from the...

  1. PBL FY 2003 Second Quarter Review Forecast of Generation Accumulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the rate period (i.e., FY 2002-2006), a forecast of that end-of-year Accumulated Net Revenue (ANR) will be completed. If the ANR at the end of the forecast year falls below the...

  2. Issues in midterm analysis and forecasting, 1996

    SciTech Connect (OSTI)

    1996-08-01

    This document consists of papers which cover topics in analysis and modeling that underlie the Annual Energy Outlook 1996. Topics include: The Potential Impact of Technological Progress on U.S. Energy Markets; The Outlook for U.S. Import Dependence; Fuel Economy, Vehicle Choice, and Changing Demographics, and Annual Energy Outlook Forecast Evaluation.

  3. NREL: Resource Assessment and Forecasting - Capabilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capabilities Best Practices Handbook Helps Industry Collect and Interpret Solar Resource Data Read about this new comprehensive resource for the solar industry. NREL's resource assessment and forecasting research staff provides expertise in renewable energy measurement and instrumentation. Major capabilities include solar resource measurement, instrument calibration, instrument characterization, solar monitoring training, and standards development and information dissemination. Solar Resource

  4. Issues in midterm analysis and forecasting 1998

    SciTech Connect (OSTI)

    1998-07-01

    Issues in Midterm Analysis and Forecasting 1998 (Issues) presents a series of nine papers covering topics in analysis and modeling that underlie the Annual Energy Outlook 1998 (AEO98), as well as other significant issues in midterm energy markets. AEO98, DOE/EIA-0383(98), published in December 1997, presents national forecasts of energy production, demand, imports, and prices through the year 2020 for five cases -- a reference case and four additional cases that assume higher and lower economic growth and higher and lower world oil prices than in the reference case. The forecasts were prepared by the Energy Information Administration (EIA), using EIA`s National Energy Modeling System (NEMS). The papers included in Issues describe underlying analyses for the projections in AEO98 and the forthcoming Annual Energy Outlook 1999 and for other products of EIA`s Office of Integrated Analysis and Forecasting. Their purpose is to provide public access to analytical work done in preparation for the midterm projections and other unpublished analyses. Specific topics were chosen for their relevance to current energy issues or to highlight modeling activities in NEMS. 59 figs., 44 tabs.

  5. Wind Power Forecasting Error Distributions over Multiple Timescales (Presentation)

    SciTech Connect (OSTI)

    Hodge, B. M.; Milligan, M.

    2011-07-01

    This presentation presents some statistical analysis of wind power forecast errors and error distributions, with examples using ERCOT data.

  6. Wind power forecasting in U.S. electricity markets.

    SciTech Connect (OSTI)

    Botterud, A.; Wang, J.; Miranda, V.; Bessa, R. J.; Decision and Information Sciences; INESC Porto

    2010-04-01

    Wind power forecasting is becoming an important tool in electricity markets, but the use of these forecasts in market operations and among market participants is still at an early stage. The authors discuss the current use of wind power forecasting in U.S. ISO/RTO markets, and offer recommendations for how to make efficient use of the information in state-of-the-art forecasts.

  7. Wind power forecasting in U.S. Electricity markets

    SciTech Connect (OSTI)

    Botterud, Audun; Wang, Jianhui; Miranda, Vladimiro; Bessa, Ricardo J.

    2010-04-15

    Wind power forecasting is becoming an important tool in electricity markets, but the use of these forecasts in market operations and among market participants is still at an early stage. The authors discuss the current use of wind power forecasting in U.S. ISO/RTO markets, and offer recommendations for how to make efficient use of the information in state-of-the-art forecasts. (author)

  8. Combined Heat And Power Installation Market Forecast | OpenEI...

    Open Energy Info (EERE)

    Combined Heat And Power Installation Market Forecast Home There are currently no posts in this category. Syndicate...

  9. Uncertainty Reduction in Power Generation Forecast Using Coupled

    Office of Scientific and Technical Information (OSTI)

    Wavelet-ARIMA (Conference) | SciTech Connect Conference: Uncertainty Reduction in Power Generation Forecast Using Coupled Wavelet-ARIMA Citation Details In-Document Search Title: Uncertainty Reduction in Power Generation Forecast Using Coupled Wavelet-ARIMA In this paper, we introduce a new approach without implying normal distributions and stationarity of power generation forecast errors. In addition, it is desired to more accurately quantify the forecast uncertainty by reducing prediction

  10. Today's Forecast: Improved Wind Predictions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Today's Forecast: Improved Wind Predictions Today's Forecast: Improved Wind Predictions July 20, 2011 - 6:30pm Addthis Stan Calvert Wind Systems Integration Team Lead, Wind & Water Power Program What does this project do? It will increase the accuracy of weather forecast models for predicting substantial changes in winds at heights important for wind energy up to six hours in advance, allowing grid operators to predict expected wind power production. Accurate weather forecasts are critical

  11. Vicarious nucleophilic substitution to prepare 1,3-diamino-2,4,6-trinitrobenzene or 1,3,5-triamino-2,4,6-trinitrobenzene

    DOE Patents [OSTI]

    Mitchell, Alexander R. (Livermore, CA); Pagoria, Philip F. (Livermore, CA); Schmidt, Robert D. (Livermore, CA)

    1996-01-01

    The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,-trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0.degree. and 50.degree. C. for between about 0.1 and 24 hr, a trinitroaromatic compound of structure V: ##STR1## wherein X, Y, and Z are each independently selected from --H, or --NH.sub.2, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen, with an amount effective to produce DATB or TATB of 1,1,1-trialkylhydrazinium halide wherein alkyl is selected from methyl, ethyl, propyl or butyl and halide is selected from chloride, bromide or iodide. in the presence of a strong base selected from sodium butoxide, potassium butoxide, potassium propoxide, sodium propoxide, sodium ethoxide, potassium ethoxide, sodium methoxide, potassium methoxide, and combinations thereof; in a solvent selected from the group consisting of methanol, ethanol, propanol, butanol, dimethylsulphoxide, N-methylpyrrolidone, hexamethylphosphoramide, dimethylformide, dimethylacetamide and mixtures thereof, provided that when alcohols are present primarily DATB and picramide is formed; and (b) isolating the DATB or TATB produced. DATB and TATB are useful specialty explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  12. Vicarious nucleophilic substitution to prepare 1,3-diamino-2,4,6-trinitrobenzene or 1,3,5-triamino-2,4,6-trinitrobenzene

    DOE Patents [OSTI]

    Mitchell, A.R.; Pagoria, P.F.; Schmidt, R.D.

    1996-10-29

    The present invention relates to a process to produce 1,3-diamino-2,4,6-trinitrobenzene (DATB) or 1,3,5-triamino-2,4,6,trinitrobenzene (TATB) by: (a) reacting at ambient pressure and a temperature of between about 0 and 50 C for between about 0.1 and 24 hr, a trinitroaromatic compound of the structure shown within where X, Y, and Z are each independently selected from --H, or --NH{sub 2}, with the proviso that at least 1 or 2 of X, Y, and Z are hydrogen, with an amount effective to produce DATB or TATB, or 1,1,1-trialkylhydrazinium halide wherein alkyl is selected from methyl, ethyl, propyl or butyl and halide is selected from chloride, bromide or iodide, in the presence of a strong base selected from sodium butoxide, potassium butoxide, potassium propoxide, sodium propoxide, sodium ethoxide, potassium ethoxide, sodium methoxide, potassium methoxide, and combinations thereof; in a solvent selected from the group consisting of methanol, ethanol, propanol, butanol, dimethylsulfoxide, N-methylpyrrolidone, hexamethylphosphoramide, dimethylformide, dimethylacetamide and mixtures thereof, provided that when alcohols are present primarily DATB and picramide is formed; and (b) isolating the DATB or TATB produced. DATB and TATB are useful specialty explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  13. The Wind Forecast Improvement Project (WFIP): A Public-Private Partnership Addressing Wind Energy Forecast Needs

    SciTech Connect (OSTI)

    Wilczak, J. M.; Finley, Cathy; Freedman, Jeff; Cline, Joel; Bianco, L.; Olson, J.; Djalaova, I.; Sheridan, L.; Ahlstrom, M.; Manobianco, J.; Zack, J.; Carley, J.; Benjamin, S.; Coulter, R. L.; Berg, Larry K.; Mirocha, Jeff D.; Clawson, K.; Natenberg, E.; Marquis, M.

    2015-10-11

    The Wind Forecast Improvement Project (WFIP) is a public-private research program, the goals of which are to improve the accuracy of short-term (0-6 hr) wind power forecasts for the wind energy industry and then to quantify the economic savings that accrue from more efficient integration of wind energy into the electrical grid. WFIP was sponsored by the U.S. Department of Energy (DOE), with partners that include the National Oceanic and Atmospheric Administration (NOAA), private forecasting companies (WindLogics and AWS Truepower), DOE national laboratories, grid operators, and universities. WFIP employed two avenues for improving wind power forecasts: first, through the collection of special observations to be assimilated into forecast models to improve model initial conditions; and second, by upgrading NWP forecast models and ensembles. The new observations were collected during concurrent year-long field campaigns in two high wind energy resource areas of the U.S. (the upper Great Plains, and Texas), and included 12 wind profiling radars, 12 sodars, 184 instrumented tall towers and over 400 nacelle anemometers (provided by private industry), lidar, and several surface flux stations. Results demonstrate that a substantial improvement of up to 14% relative reduction in power root mean square error (RMSE) was achieved from the combination of improved NOAA numerical weather prediction (NWP) models and assimilation of the new observations. Data denial experiments run over select periods of time demonstrate that up to a 6% relative improvement came from the new observations. The use of ensemble forecasts produced even larger forecast improvements. Based on the success of WFIP, DOE is planning follow-on field programs.

  14. BUILDOUT AND UPGRADE OF CENTRAL EMERGENCY GENERATOR SYSTEM, GENERATOR 3 AND 4 ELECTRICAL INSTALLATION

    SciTech Connect (OSTI)

    Gary D. Seifert; G. Shawn West; Kurt S. Myers; Jim Moncur

    2006-07-01

    SECTION 01000SUMMARY OF WORK PART 1GENERAL 1.1 SUMMARY The work to be performed under this project consists of providing the labor, equipment, and materials to perform "Buildout and Upgrade of Central Emergency Generator System, Generator 3 and 4 Electrical Installation" for the National Aeronautics and Space Administration at the Dryden Flight Research Center (NASA/DFRC), Edwards, California 93523. All modifications to existing substations and electrical distribution systems are the responsibility of the contractor. It is the contractors responsibility to supply a complete and functionally operational system. The work shall be performed in accordance with these specifications and the related drawings. The work of this project is defined by the plans and specifications contained and referenced herein. This work specifically includes but is not limited to the following: Scope of Work - Installation 1. Install all electrical wiring and controls for new generators 3 and 4 to match existing electrical installation for generators 1 and 2 and in accordance with drawings. Contractor shall provide as-built details for electrical installation. 2. Install battery charger systems for new generators 3 and 4 to match existing battery charging equipment and installation for generators 1 and 2. This may require exchange of some battery charger parts already on-hand. Supply power to new battery chargers from panel and breakers as shown on drawings. Utilize existing conduits already routed to generators 3 and 4 to field route the new wiring in the most reasonable way possible. 3. Install electrical wiring for fuel/lube systems for new generators 3 and 4 to match existing installation for generators 1 and 2. Supply power to lube oil heaters and fuel system (day tanks) from panel and breakers as shown on drawings. Utilize existing conduits already routed to generators 3 and 4 to field route the new wiring in the most reasonable way possible. Add any conduits necessary to complete wiring to fuel systems. 4. Install power to new dampers/louvers from panel and breakers as shown on drawings. Wiring shall be similar to installation to existing dampers/louvers. Utilize existing conduits already routed to louver areas to field route the new wiring in the most reasonable way possible. Add any conduits necessary to complete wiring to new dampers/louvers. 5. Install power to jacket water heaters for new generators 3 and 4 from panel and breakers as shown on drawings. Utilize existing conduits already routed to generators 3 and 4 to field route the new wiring in the most reasonable way possible. 6. Install new neutral grounding resistor and associated parts and wiring for new generators 3 and 4 to match existing installation for generators 1 and 2. Grounding resistors will be Government Furnished Equipment (GFE). 7. Install two new switchgear sections, one for generator #3 and one for generator #4, to match existing generator #1 cubicle design and installation and in accordance with drawings and existing parts lists. This switchgear will be provided as GFE. 8. Ground all new switchgear, generators 3 and 4, and any other new equipment to match existing grounding connections for generators 1 and 2, switchgear and other equipment. See drawings for additional details. Grounding grid is already existing. Ensure that all grounding meets National Electrical Code requirements. 9. Cummins DMC control for the generator and switchgear syste

  15. A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

    SciTech Connect (OSTI)

    Jian, ZL; Sun, Y; Ji, XL

    2015-01-01

    A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

  16. Operational forecasting based on a modified Weather Research and Forecasting model

    SciTech Connect (OSTI)

    Lundquist, J; Glascoe, L; Obrecht, J

    2010-03-18

    Accurate short-term forecasts of wind resources are required for efficient wind farm operation and ultimately for the integration of large amounts of wind-generated power into electrical grids. Siemens Energy Inc. and Lawrence Livermore National Laboratory, with the University of Colorado at Boulder, are collaborating on the design of an operational forecasting system for large wind farms. The basis of the system is the numerical weather prediction tool, the Weather Research and Forecasting (WRF) model; large-eddy simulations and data assimilation approaches are used to refine and tailor the forecasting system. Representation of the atmospheric boundary layer is modified, based on high-resolution large-eddy simulations of the atmospheric boundary. These large-eddy simulations incorporate wake effects from upwind turbines on downwind turbines as well as represent complex atmospheric variability due to complex terrain and surface features as well as atmospheric stability. Real-time hub-height wind speed and other meteorological data streams from existing wind farms are incorporated into the modeling system to enable uncertainty quantification through probabilistic forecasts. A companion investigation has identified optimal boundary-layer physics options for low-level forecasts in complex terrain, toward employing decadal WRF simulations to anticipate large-scale changes in wind resource availability due to global climate change.

  17. Synthesis and crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate

    SciTech Connect (OSTI)

    Belhouchet, M. Mhiri, T.

    2013-01-15

    The crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate C{sub 6}H{sub 3}(NH{sub 3})(OH)SO{sub 3} {center_dot} 0.5H{sub 2}O is determined by single-crystal X-ray diffraction. The unit cell parameters are as follows: a = 11.2395(3), b = 10.3814(3), c = 13.7509(4) A, {beta} = 100.326(1) Degree-Sign , V = 1578.49(8) A{sup 3}, space group P2{sub 1}/n, Z = 4. The crystal structure can be described us a succession of infinite corrugated layers parallel to ab plane. These layers consist of rings formed by four sulfonate molecules located around a center of symmetry. The rings are connected to each other and to water molecules via O-H...O hydrogen bonds. The structure is further stabilized by {pi}-{pi} interactions between phenyl rings of organic entities of successive layers.

  18. President Obama Announces $3.4 Billion Investment to Spur Transition to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Smart Energy Grid | Department of Energy 3.4 Billion Investment to Spur Transition to Smart Energy Grid President Obama Announces $3.4 Billion Investment to Spur Transition to Smart Energy Grid October 27, 2009 - 12:00am Addthis ARCADIA, FLORIDA - Speaking at Florida Power and Light's (FPL) DeSoto Next Generation Solar Energy Center, President Barack Obama today announced the largest single energy grid modernization investment in U.S. history, funding a broad range of technologies that will

  19. In operando X-ray studies of the conversion reaction in Mn3O4 lithium

    Office of Scientific and Technical Information (OSTI)

    battery anodes (Journal Article) | SciTech Connect operando X-ray studies of the conversion reaction in Mn3O4 lithium battery anodes Citation Details In-Document Search Title: In operando X-ray studies of the conversion reaction in Mn3O4 lithium battery anodes Authors: Lowe, Michael A. ; Gao, Jie ; Abruña, Héctor D. Publication Date: 2013-01-01 OSTI Identifier: 1080663 DOE Contract Number: SC0001086 Resource Type: Journal Article Resource Relation: Journal Name: J. Mater. Chem. A; Journal

  20. Type Ia supernovae yielding distances with 3-4% precision (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Type Ia supernovae yielding distances with 3-4% precision Citation Details In-Document Search Title: Type Ia supernovae yielding distances with 3-4% precision × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this

  1. L3:RTM.PTR.P4.03 Demonstrate Initial Deterministic Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PTR.P4.03 Demonstrate Initial Deterministic Transport Capability through VERA-CS Greg Davidson Oak Ridge National Laboratory March 31, 2012 CASL-8-2012-0245-000 CASL-U-2012-0245-000 B i l l M a r t i n P a g e | 2 6/4/2014 CASL-U-2012-0245-000 B i l l M a r t i n P a g e | 3 6/4/2014 CASL-U-2012-0245-000 B i l l M a r t i n P a g e | 4 6/4/2014 CASL-U-2012-0245-000

  2. Crystal structure of 4-[benzylideneamino]-3-thiophen-2-yl-methyl-4,5-dihydro-1H-[1,2,4] triazole-5-one

    SciTech Connect (OSTI)

    Tanak, H.

    2013-12-15

    The crystal structure of the title compound C{sub 14}H{sub 12}N{sub 4}OS was determined by the X-ray diffraction method. The compound crystallizes in the triclinic space group P-bar1 with Z = 2. The molecule is not planar: the dihedral angle between the triazole and thiophene rings is 73.98(2)°, and that between the triazole and benzene rings is 4.05(2)°. The thiophene ring is disordered over two positions, which are approximately parallel and oppositely oriented. The major component refined to a site-occupancy factor of 0.573(3). An intramolecular C-H...O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked together by two pairs of N-H...O interactions (to the same O atom as acceptor), forming inversion dimers. The crystal packing is also stabilized by π-π interactions [centroid-centroid distance is 3.978 Å].

  3. Resveratrol analogue 3,4,4?,5-tetramethoxystilbene inhibits growth, arrests cell cycle and induces apoptosis in ovarian SKOV?3 and A-2780 cancer cells

    SciTech Connect (OSTI)

    Piotrowska, Hanna; Myszkowski, Krzysztof; Zi?kowska, Alicja; Kulcenty, Katarzyna; Wierzchowski, Marcin; Kaczmarek, Mariusz; Murias, Marek; Kwiatkowska-Borowczyk, Eliza; Department of Cancer Diagnostics and Immunology, Greater Poland Cancer Centre, Poznan ; Jodynis-Liebert, Jadwiga

    2012-08-15

    In the screening studies, cytotoxicity of 12 methylated resveratrol analogues on 11 human cancer cell lines was examined. The most active compound 3,4,4?5-tetramethoxystilbene (DMU-212) and two ovarian cancer cell lines A-2780 (IC{sub 50} = 0.71 ?M) and SKOV-3 (IC{sub 50} = 11.51 ?M) were selected for further investigation. To determine the mechanism of DMU-212 cytotoxicity, its ability to induce apoptosis was examined. DMU-212 arrested cell cycle in the G2/M or G0/G1 phase which resulted in apoptosis of both cell lines. The expression level of 84 apoptosis-related genes was investigated. In SKOV-3 cells DMU-212 caused up-regulation of pro-apoptotic Bax, Apaf-1 and p53 genes, specific to intrinsic pathway of apoptosis, and a decrease in Bcl-2 and Bcl 2110 mRNA expressions. Conversely, in A-2780 cells an increased expression of pro-apoptotic genes Fas, FasL, TNF, TNFRSF10A, TNFRSF21, TNFRSF16 specific to extracellular mechanism of apoptosis was observed. There are no data published so far regarding the receptor mediated apoptosis induced by DMU-212. The activation of caspase-3/7 was correlated with decreased TRAF-1 and BIRC-2 expression level in A-2780 cells exposed to DMU-212. DMU-212 caused a decrease in CYP1A1 and CYP1B1 mRNA levels in A-2780 by 50% and 75%, and in SKOV-3 cells by 15% and 45%, respectively. The protein expression was also reduced in both cell lines. It is noteworthy that the expression of CYP1B1 protein was entirely inhibited in A-2780 cells treated with DMU-212. It can be suggested that different CYP1B1 expression patterns in either ovarian cell line may affect their sensitivity to cytotoxic activity of DMU-212. -- Highlights: ? DMU-212 was the most cytotoxic among 12 O-methylated resveratrol analogues. ? DMU-212 arrested cell cycle at G2/M and G0/G1phase ? DMU-212 triggered mitochondria- and receptor?mediated apoptosis. ? DMU-212 entirely inhibited CYP1B1 protein expression in A-2780 cells.

  4. Elasticity and magnetocaloric effect in MnFe4Si3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herlitschke, Marcus; Klobes, B.; Sergueev, I.; Hering, Paul; Persson, Joerg; Hermann, Raphael P.

    2016-03-16

    The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the infuence of the magnetic transition and the magnetocaloric effect on the lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low energy, ~5 neV, phonon modes. A significant infuence of the magnetic transition on the lattice dynamics is observed only in the low energy region. Here, MnFe4Si3 and other compoundsmore » in the Mn5-xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements and Moessbauer spectroscopy in order to study the magnetic transitions and to complement the obtained results on the lattice dynamics.« less

  5. EVMS Training Snippet: 4.3 Management Reserve Versus Contingency and Budget

    Office of Environmental Management (EM)

    Versus Funds | Department of Energy 3 Management Reserve Versus Contingency and Budget Versus Funds EVMS Training Snippet: 4.3 Management Reserve Versus Contingency and Budget Versus Funds This EVMS Training Snippet, sponsored by the Office of Project Management (PM) discusses the differences between Management Reserve and Contingency as well as the difference between Budget versus Funds as applied in DOE. The purpose is to provide a common understanding within DOE and among DOE contractors,

  6. Thermally stable compositions including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt

    DOE Patents [OSTI]

    Hiskey, Michael A. (Los Alamos, NM); Huynh, My Hang (Los Alamos, NM)

    2010-01-26

    An explosive formulation including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt and a high temperature binder is disclosed together with a process of preparing 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt.

  7. Forecastability as a Design Criterion in Wind Resource Assessment: Preprint

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B. M.

    2014-04-01

    This paper proposes a methodology to include the wind power forecasting ability, or 'forecastability,' of a site as a design criterion in wind resource assessment and wind power plant design stages. The Unrestricted Wind Farm Layout Optimization (UWFLO) methodology is adopted to maximize the capacity factor of a wind power plant. The 1-hour-ahead persistence wind power forecasting method is used to characterize the forecastability of a potential wind power plant, thereby partially quantifying the integration cost. A trade-off between the maximum capacity factor and the forecastability is investigated.

  8. Superstrings on AdS{sub 4}xCP{sup 3} from supergravity

    SciTech Connect (OSTI)

    D'Auria, Riccardo; Trigiante, Mario; Fre, Pietro; Grassi, Pietro Antonio

    2009-04-15

    We derive from a general formulation of pure spinor string theory on type IIA backgrounds the specific form of the action for the AdS{sub 4}xCP{sup 3} background. We provide a complete geometrical characterization of the structure of the superfields involved in the action.

  9. Facilely preparation and microwave absorption properties of Fe{sub 3}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Wang, Guiqin, E-mail: wanggq@dlut.edu.cn [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085 (China); Chang, Yongfeng; Wang, Lifang; Liu, Lidong; Liu, Chao [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085 (China)

    2013-03-15

    Highlights: ? A bran-new method is firstly used to fabricate Fe{sub 3}O{sub 4} nanoparticles. ? The detailed analysis of formation mechanism is discussed. ? The electromagnetic absorption properties are defined. ? The effect of nanometer-sized is considered for the excellent microwave absorption. - Abstract: The Fe{sub 3}O{sub 4} nanoparticles were prepared by a novel wet-chemical method which shows its highly synthesizing efficiency and controllability. A possible formation mechanism was also proposed to explain the synthesizing process. X-ray diffraction (XRD) and transmission electron microscope (TEM) were employed and yielded an examination of an average diameter of 77 nm of the as-synthesized Fe{sub 3}O{sub 4} nanoparticles with face-centered cubic structure. Vibrating sample magnetometer (VSM) and vector network analyzer were employed to measure the magnetic property and electromagnetic parameters of the nanoparticles, then reflection losses (RL (dB)) were calculated in the frequency range of 218 GHz. A large saturation magnetization (72.36 emu/g) and high coercivity (95 Oe) were determined and indicated that the Fe{sub 3}O{sub 4} nanoparticles own strong magnetic performance. Following simulation results showed that the lowest reflection loss of the sample was ?21.2 dB at 5.6 GHz with layer thickness of 6 mm. Effect of nanometer-sized further provided an explanation for the excellent microwave absorption behavior shown by the Fe{sub 3}O{sub 4} nanoparticles.

  10. High pressures and the Kondo gap in Ce{sub 3}Bi{sub 4}Pt{sub 3}

    SciTech Connect (OSTI)

    Cooley, J.C.; Aronson, M.C.; Canfield, P.C.

    1997-03-01

    We have measured the electrical resistivity {rho}(T) of single crystals of Ce{sub 3}Bi{sub 4}Pt{sub 3} for temperatures from 1.2 to 300 K, and pressures from 1 bar to 145 kbar. The transport is dominated at high temperatures by excitations across a small activation gap {Delta}, which increases rapidly with pressure. The low-temperature transport involves variable range hopping among extrinsic states in the gap. The spatial extent of the in-gap states reflects coupling to conduction-electron states, and is strongly modified as pressure enhances {Delta}. Despite the strong pressure dependence of {Delta}, a direct correspondence between single-ion energetics and the measured gap is maintained, and the role of valence fluctuations is minimal even at the highest pressures. {copyright} {ital 1997} {ital The American Physical Society}

  11. Synthesis and crystal structure of the palladium oxides NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Panin, Rodion V. Khasanova, Nellie R.; Abakumov, Artem M.; Antipov, Evgeny V.; Tendeloo, Gustaaf van; Schnelle, Walter

    2007-05-15

    NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4} have been prepared by solid-state reaction of Na{sub 2}O{sub 2} or KO{sub 2} and PdO in sealed silica tubes. Crystal structures of the synthesized phases were refined by the Rietveld method from X-ray powder diffraction data. NaPd{sub 3}O{sub 4} (space group Pm3-barn, a=5.64979(6) A, Z=2) is isostructural to NaPt{sub 3}O{sub 4}. It consists of NaO{sub 8} cubes and PdO{sub 4} squares, corner linked into a three-dimensional framework where the planes of neighboring PdO{sub 4} squares are perpendicular to each other. Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2){sup o}, Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations alternate with Na{sub 3} layers along the c-axis. Na{sub 2}PdO{sub 3} exhibits a stacking disorder, detected by electron diffraction and Rietveld refinement. K{sub 3}Pd{sub 2}O{sub 4}, prepared for the first time, crystallizes in the orthorhombic space group Cmcm (a=6.1751(6) A, b=9.1772(12) A, c=11.3402(12) A, Z=4). Its structure is composed of planar PdO{sub 4} units connected via common edges to form parallel staggered PdO{sub 2} strips, where potassium atoms are located between them. Magnetic susceptibility measurements of K{sub 3}Pd{sub 2}O{sub 4} reveal a Curie-Weiss behavior in the temperature range above 80 K. - Graphical abstract: Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2), Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations (NaPd{sub 2}O{sub 6} slabs) alternate with Na{sub 3} layers along the c-axis.

  12. Sprague-Dawley rats display sex-linked differences in the pharmacokinetics of 3,4-methylenedioxymethamphetamine (MDMA) and its metabolite 3,4-methylenedioxyamphetamine (MDA)

    SciTech Connect (OSTI)

    Fonsart, Julien, E-mail: julien.fonsart@lrb.aphp.f [Universite Paris Descartes, Faculte de Pharmacie, Paris F-75006 (France); CNRS, UMR 7157, Paris F-75006 (France); INSERM, U705, Paris F-75006 (France); Assistance Publique-Hopitaux de Paris, Laboratoire de Toxicologie Biologique, Hopital Lariboisiere, Paris F-75010 (France); Menet, Marie-Claude [Universite Paris Descartes, Faculte de Pharmacie, Paris F-75006 (France); Universite Paris Descartes, Faculte de Pharmacie, Plateau Spectrometrie de Masse (IFR 71), Service de Chimie Analytique, Paris F-75006 (France); Debray, Marcel; Hirt, Deborah; Noble, Florence; Scherrmann, Jean-Michel; Decleves, Xavier [Universite Paris Descartes, Faculte de Pharmacie, Paris F-75006 (France); CNRS, UMR 7157, Paris F-75006 (France); INSERM, U705, Paris F-75006 (France)

    2009-12-15

    The use of 3,4-methylenedioxymethamphetamine (MDMA, ecstasy) has increased in recent years; it can lead to life-threatening hyperthermia and serotonin syndrome. Human and rodent males appear to be more sensitive to acute toxicity than are females. MDMA is metabolized to five main metabolites by the enzymes CYP1A2, CYP2D and COMT. Little is presently known about sex-dependent differences in the pharmacokinetics of MDMA and its metabolites. We therefore analyzed MDMA disposition in male and female rats by measuring the plasma and urine concentrations of MDMA and its metabolites using a validated LC-MS method. MDA AUC{sub last} and C{sub max} were 1.6- to 1.7-fold higher in males than in females given MDMA (5 mg/kg sc), while HMMA C{sub max} and AUC{sub last} were 3.2- and 3.5-fold higher, respectively. MDMA renal clearance was 1.26-fold higher in males, and that of MDA was 2.2-fold higher. MDMA AUC{sub last} and t{sub 1/2} were 50% higher in females given MDMA (1 mg/kg iv). MDA C{sub max} and AUC{sub last} were 75-82% higher in males, with a 2.8-fold higher metabolic index. Finally, the AUC{sub last} of MDA was 0.73-fold lower in males given 1 mg/kg iv MDA. The volumes of distribution of MDMA and MDA at steady-state were similar in the two sexes. These data strongly suggest that differences in the N-demethylation of MDMA to MDA are major influences on the MDMA and MDA pharmacokinetics in male and female rats. Hence, males are exposed to significantly more toxic MDA, which could explain previously reported sexual dysmorphism in the acute effects and toxicity of MDMA in rats.

  13. Forecasting hotspots using predictive visual analytics approach

    DOE Patents [OSTI]

    Maciejewski, Ross; Hafen, Ryan; Rudolph, Stephen; Cleveland, William; Ebert, David

    2014-12-30

    A method for forecasting hotspots is provided. The method may include the steps of receiving input data at an input of the computational device, generating a temporal prediction based on the input data, generating a geospatial prediction based on the input data, and generating output data based on the time series and geospatial predictions. The output data may be configured to display at least one user interface at an output of the computational device.

  14. Inhibition of aminoacylase 3 protects rat brain cortex neuronal cells from the toxicity of 4-hydroxy-2-nonenal mercapturate and 4-hydroxy-2-nonenal

    SciTech Connect (OSTI)

    Tsirulnikov, Kirill; Abuladze, Natalia; Bragin, Anatol; Brain Research Institute, University of California at Los Angeles, CA 90095 ; Faull, Kym; Department of Psychiatry and Biobehavioral Sciences, University of California at Los Angeles, CA 90095; Pasarow Mass Spectrometry Laboratory, University of California at Los Angeles, CA 90095 ; Cascio, Duilio; Damoiseaux, Robert; Schibler, Matthew J.; Pushkin, Alexander

    2012-09-15

    4-Hydroxy-2-nonenal (4HNE) and acrolein (ACR) are highly reactive neurotoxic products of lipid peroxidation that are implicated in the pathogenesis and progression of Alzheimer's and Parkinson's diseases. Conjugation with glutathione (GSH) initiates the 4HNE and ACR detoxification pathway, which generates the mercapturates of 4HNE and ACR that can be excreted. Prior work has shown that the efficiency of the GSH-dependent renal detoxification of haloalkene derived mercapturates is significantly decreased upon their deacetylation because of rapid transformation of the deacetylated products into toxic compounds mediated by ?-lyase. The enzymes of the GSH-conjugation pathway and ?-lyases are expressed in the brain, and we hypothesized that a similar toxicity mechanism may be initiated in the brain by the deacetylation of 4HNE- and ACR-mercapturate. The present study was performed to identify an enzyme(s) involved in 4HNE- and ACR-mercapturate deacetylation, characterize the brain expression of this enzyme and determine whether its inhibition decreases 4HNE and 4HNE-mercapturate neurotoxicity. We demonstrated that of two candidate deacetylases, aminoacylases 1 (AA1) and 3 (AA3), only AA3 efficiently deacetylates both 4HNE- and ACR-mercapturate. AA3 was further localized to neurons and blood vessels. Using a small molecule screen we generated high-affinity AA3 inhibitors. Two of them completely protected rat brain cortex neurons expressing AA3 from the toxicity of 4HNE-mercapturate. 4HNE-cysteine (4HNE-Cys) was also neurotoxic and its toxicity was mostly prevented by a ?-lyase inhibitor, aminooxyacetate. The results suggest that the AA3 mediated deacetylation of 4HNE-mercapturate may be involved in the neurotoxicity of 4HNE.

  15. Global disease monitoring and forecasting with Wikipedia

    SciTech Connect (OSTI)

    Generous, Nicholas; Fairchild, Geoffrey; Deshpande, Alina; Del Valle, Sara Y.; Priedhorsky, Reid; Salathé, Marcel

    2014-11-13

    Infectious disease is a leading threat to public health, economic stability, and other key social structures. Efforts to mitigate these impacts depend on accurate and timely monitoring to measure the risk and progress of disease. Traditional, biologically-focused monitoring techniques are accurate but costly and slow; in response, new techniques based on social internet data, such as social media and search queries, are emerging. These efforts are promising, but important challenges in the areas of scientific peer review, breadth of diseases and countries, and forecasting hamper their operational usefulness. We examine a freely available, open data source for this use: access logs from the online encyclopedia Wikipedia. Using linear models, language as a proxy for location, and a systematic yet simple article selection procedure, we tested 14 location-disease combinations and demonstrate that these data feasibly support an approach that overcomes these challenges. Specifically, our proof-of-concept yields models with up to 0.92, forecasting value up to the 28 days tested, and several pairs of models similar enough to suggest that transferring models from one location to another without re-training is feasible. Based on these preliminary results, we close with a research agenda designed to overcome these challenges and produce a disease monitoring and forecasting system that is significantly more effective, robust, and globally comprehensive than the current state of the art.

  16. A survey on wind power ramp forecasting.

    SciTech Connect (OSTI)

    Ferreira, C.; Gama, J.; Matias, L.; Botterud, A.; Wang, J.

    2011-02-23

    The increasing use of wind power as a source of electricity poses new challenges with regard to both power production and load balance in the electricity grid. This new source of energy is volatile and highly variable. The only way to integrate such power into the grid is to develop reliable and accurate wind power forecasting systems. Electricity generated from wind power can be highly variable at several different timescales: sub-hourly, hourly, daily, and seasonally. Wind energy, like other electricity sources, must be scheduled. Although wind power forecasting methods are used, the ability to predict wind plant output remains relatively low for short-term operation. Because instantaneous electrical generation and consumption must remain in balance to maintain grid stability, wind power's variability can present substantial challenges when large amounts of wind power are incorporated into a grid system. A critical issue is ramp events, which are sudden and large changes (increases or decreases) in wind power. This report presents an overview of current ramp definitions and state-of-the-art approaches in ramp event forecasting.

  17. Global disease monitoring and forecasting with Wikipedia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Generous, Nicholas; Fairchild, Geoffrey; Deshpande, Alina; Del Valle, Sara Y.; Priedhorsky, Reid; Salathé, Marcel

    2014-11-13

    Infectious disease is a leading threat to public health, economic stability, and other key social structures. Efforts to mitigate these impacts depend on accurate and timely monitoring to measure the risk and progress of disease. Traditional, biologically-focused monitoring techniques are accurate but costly and slow; in response, new techniques based on social internet data, such as social media and search queries, are emerging. These efforts are promising, but important challenges in the areas of scientific peer review, breadth of diseases and countries, and forecasting hamper their operational usefulness. We examine a freely available, open data source for this use: accessmore » logs from the online encyclopedia Wikipedia. Using linear models, language as a proxy for location, and a systematic yet simple article selection procedure, we tested 14 location-disease combinations and demonstrate that these data feasibly support an approach that overcomes these challenges. Specifically, our proof-of-concept yields models with up to 0.92, forecasting value up to the 28 days tested, and several pairs of models similar enough to suggest that transferring models from one location to another without re-training is feasible. Based on these preliminary results, we close with a research agenda designed to overcome these challenges and produce a disease monitoring and forecasting system that is significantly more effective, robust, and globally comprehensive than the current state of the art.« less

  18. Baseline and Target Values for PV Forecasts: Toward Improved Solar Power Forecasting: Preprint

    SciTech Connect (OSTI)

    Zhang, Jie; Hodge, Bri-Mathias; Lu, Siyuan; Hamann, Hendrik F.; Lehman, Brad; Simmons, Joseph; Campos, Edwin; Banunarayanan, Venkat

    2015-08-05

    Accurate solar power forecasting allows utilities to get the most out of the solar resources on their systems. To truly measure the improvements that any new solar forecasting methods can provide, it is important to first develop (or determine) baseline and target solar forecasting at different spatial and temporal scales. This paper aims to develop baseline and target values for solar forecasting metrics. These were informed by close collaboration with utility and independent system operator partners. The baseline values are established based on state-of-the-art numerical weather prediction models and persistence models. The target values are determined based on the reduction in the amount of reserves that must be held to accommodate the uncertainty of solar power output. forecasting metrics. These were informed by close collaboration with utility and independent system operator partners. The baseline values are established based on state-of-the-art numerical weather prediction models and persistence models. The target values are determined based on the reduction in the amount of reserves that must be held to accommodate the uncertainty of solar power output.

  19. Chemically induced Parkinson's disease: intermediates in the oxidation of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine to the 1-methyl-4-phenyl-pyridinium ion

    SciTech Connect (OSTI)

    Chacon, J.N.; Chedekel, M.R.; Land, E.J.; Truscott, T.G.

    1987-04-29

    Various unstable intermediate oxidation states have been postulated in the metabolic activation of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine to the 1-methyl-4-phenyl pyridinium ion. We now report the first direct observation of these free radical intermediates by pulse radiolysis and flash photolysis. Studies are described of various reactions of such species, in particular with dopamine whose autoxidation to dopamine quinone is reported to be potentiated by 1-methyl-4-phenyl-1,2,3, 6-tetrahydropyridine.

  20. Phenotype-genotype variability in the human CYP3A locus as assessed by the probe drug quinine and analyses of variant CYP3A4 alleles

    SciTech Connect (OSTI)

    Rodriguez-Antona, Cristina . E-mail: cristina.rodriguez-antona@cnio.es; Sayi, Jane G.; Gustafsson, Lars L.; Bertilsson, Leif; Ingelman-Sundberg, Magnus

    2005-12-09

    The human cytochrome P450 3A (CYP3A) enzymes, which metabolize 50% of currently used therapeutic drugs, exhibit great interindividual differences in activity that have a major impact on drug treatment outcome, but hitherto no genetic background importantly contributing to this variation has been identified. In this study we show that CYP3A4 mRNA and hnRNA contents with a few exceptions vary in parallel in human liver, suggesting that mechanisms affecting CYP3A4 transcription, such as promoter polymorphisms, are relevant for interindividual differences in CYP3A4 expression. Tanzanian (n = 143) healthy volunteers were phenotyped using quinine as a CYP3A probe and the results were used for association studies with CYP3A4 genotypes. Carriers of CYP3A4*1B had a significantly lower activity than those with CYP3A4*1 whereas no differences were seen for five other SNPs investigated. Nuclear proteins from the B16A2 hepatoma cells were found to bind with less affinity to the CYP3A4*1B element around -392 bp as compared to CYP3A4*1. The data indicate the existence of a genetic CYP3A4 polymorphism with functional importance for interindividual differences in enzyme expression.

  1. Study of structural and electronic properties of Mn{sub 3}O{sub 4}

    SciTech Connect (OSTI)

    Kaur, Ramandeep Maitra, Tulika Nautiyal, Tashi

    2014-04-24

    Using density functional theory calculations we have examined the structural and electronic properties of magnetic spinel Mn{sub 3}O{sub 4}. We have optimized the structure (both volume and c/a ratio) within GGA. Then Coulomb correlations are included in the calculations to study the electronic properties. We observe that both the band gap and magnetic moment increase with the increase in Coulomb correlation due to the increased Jahn-Teller splitting and localization of the single e{sub g} electron of Mn{sup 3+}.

  2. Spot test for 1,3,5-triamino-2,4,6-trinitrobenzene, TATB

    DOE Patents [OSTI]

    Harris, B.W.

    1984-11-29

    A simple, sensitive and specific spot test for 1,3,5-triamino-2,4,6-trinitrobenzene, TATB, is described. Upon the application of the composition of matter of the subject invention to samples containing in excess of 0.1 mg of this explosive, a bright orange color results. Interfering species such as TNT and Tetryl can be removed by first treating the sample with a solvent which does not dissolve the TATB, but readily dissolves these interfering explosives.

  3. Spot test for 1,3,5-triamino-2,4,6-trinitrobenzene, TATB

    DOE Patents [OSTI]

    Harris, Betty W.

    1986-01-01

    A simple, sensitive and specific spot test for 1,3,5-triamino-2,4,6-trinitrobenzene, TATB, is described. Upon the application of the composition of matter of the present invention to samples containing in excess of 0.1 mg of this explosive, a bright orange color results. Interfering species such as TNT and Tetryl can be removed by first treating the sample with a solvent which does not dissolve much of the TATB, but readily dissolves these explosives.

  4. PPPL launches a $4.3 million project to expand research on magnetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reconnection | Princeton Plasma Physics Lab PPPL launches a $4.3 million project to expand research on magnetic reconnection By John Greenwald February 28, 2014 Tweet Widget Google Plus One Share on Facebook Nearly two-dozen institutions will participate in experiments on FLARE. Nearly two-dozen institutions will participate in experiments on FLARE. PPPL is developing a new and more powerful version of its world-leading Magnetic Reconnection Experiment (MRX), which recreates one of the most

  5. PPPL launches a $4.3 million project to expand research on magnetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reconnection | Princeton Plasma Physics Lab PPPL launches a $4.3 million project to expand research on magnetic reconnection By John Greenwald February 28, 2014 Tweet Widget Google Plus One Share on Facebook Nearly two-dozen institutions will participate in experiments on FLARE. Nearly two-dozen institutions will participate in experiments on FLARE. PPPL is developing a new and more powerful version of its world-leading Magnetic Reconnection Experiment (MRX), which recreates one of the most

  6. PPPL receives $4.3 million to increase understanding of the role that

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plasma plays in synthesizing nanoparticles | Princeton Plasma Physics Lab PPPL receives $4.3 million to increase understanding of the role that plasma plays in synthesizing nanoparticles By John Greenwald June 9, 2014 Tweet Widget Google Plus One Share on Facebook Physicist Yevgeny Raitses, the principal investigator for research into the role of plasma in synthesizing nanoparticles, in PPPL's nanotechnology laboratory. (Photo by Elle Starkman/PPPL Office of Communications) Physicist Yevgeny

  7. HELIOSPHERIC ENERGETIC NEUTRAL HYDROGEN MEASURED WITH ASPERA-3 AND ASPERA-4

    SciTech Connect (OSTI)

    Galli, A.; Wurz, P.; Kollmann, P.; Brandt, P. C.; Bzowski, M.; Sok?, J. M.; Kubiak, M. A.; Grigoriev, A.; Barabash, S.

    2013-09-20

    We re-analyze the signal of non-planetary energetic neutral atoms (ENAs) in the 0.4-5.0 keV range measured with the Neutral Particle Detector (NPD) of the ASPERA-3 and ASPERA-4 experiments on board the Mars and Venus Express satellites. Due to improved knowledge of sensor characteristics and exclusion of data sets affected by instrument effects, the typical intensity of the ENA signal obtained by ASPERA-3 is an order of magnitude lower than in earlier reports. The ENA intensities measured with ASPERA-3 and ASPERA-4 now agree with each other. In the present analysis, we also correct the ENA signal for Compton-Getting and for ionization loss processes under the assumption of a heliospheric origin. We find spectral shapes and intensities consistent with those measured by the Interstellar Boundary Explorer (IBEX). The principal advantage of ASPERA with respect to the IBEX sensors is the two times better spectral resolution. In this study, we discuss the physical significance of the spectral shapes and their potential variation across the sky. At present, these observations are the only independent test of the heliospheric ENA signal measured with IBEX in this energy range. The ASPERA measurements also allow us to check for a temporal variation of the heliospheric signal as they were obtained between 2003 and 2007, whereas IBEX has been operational since the end of 2008.

  8. 3D and 4D magnetic susceptibility tomography based on complex MR images

    DOE Patents [OSTI]

    Chen, Zikuan; Calhoun, Vince D

    2014-11-11

    Magnetic susceptibility is the physical property for T2*-weighted magnetic resonance imaging (T2*MRI). The invention relates to methods for reconstructing an internal distribution (3D map) of magnetic susceptibility values, .chi. (x,y,z), of an object, from 3D T2*MRI phase images, by using Computed Inverse Magnetic Resonance Imaging (CIMRI) tomography. The CIMRI technique solves the inverse problem of the 3D convolution by executing a 3D Total Variation (TV) regularized iterative convolution scheme, using a split Bregman iteration algorithm. The reconstruction of .chi. (x,y,z) can be designed for low-pass, band-pass, and high-pass features by using a convolution kernel that is modified from the standard dipole kernel. Multiple reconstructions can be implemented in parallel, and averaging the reconstructions can suppress noise. 4D dynamic magnetic susceptibility tomography can be implemented by reconstructing a 3D susceptibility volume from a 3D phase volume by performing 3D CIMRI magnetic susceptibility tomography at each snapshot time.

  9. 3TIER | Open Energy Information

    Open Energy Info (EERE)

    Northwest Area Sector: Services Product: Assessment and forecasting products for wind, solar, and hydro Number of Employees: 51-200 Website: www.3tier.com Coordinates:...

  10. SOLID WASTE INTEGRATED FORECAST TECHNICAL (SWIFT) REPORT FY2005 THRU FY2035 2005.0 VOLUME 2

    SciTech Connect (OSTI)

    BARCOT, R.A.

    2005-08-17

    This report provides up-to-date life cycle information about the radioactive solid waste expected to be managed by Hanford's Waste Management (WM) Project from onsite and offsite generators. It includes: (1) an overview of Hanford-wide solid waste to be managed by the WM Project; (2) multi-level and waste class-specific estimates; (3) background information on waste sources; and (4) comparisons to previous forecasts and other national data sources. The focus of this report is low-level waste (LLW), mixed low-level waste (MLLW), and transuranic waste, both non-mixed and mixed (TRU(M)). Some details on hazardous waste are also provided, however, this information is not considered comprehensive. This report includes data requested in December, 2004 with updates through March 31,2005. The data represent a life cycle forecast covering all reported activities from FY2005 through the end of each program's life cycle and are an update of the previous FY2004.1 data version.

  11. Simple and low-temperature preparation of Co{sub 3}O{sub 4} sphere-like nanoparticles via solid-state thermolysis of the [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3} complex

    SciTech Connect (OSTI)

    Farhadi, Saeid; Pourzare, Kolsoum

    2012-06-15

    Highlights: ? [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3} precursor was used for synthesizing pure Co{sub 3}O{sub 4} nanocrystals. ? Co{sub 3}O{sub 4} nanocrystals were synthesized at low temperature of 200 C. ? Co{sub 3}O{sub 4} nanocrystals show a weak ferromagnetic behavior at room temperature. ? This simple method is low-cost and suitable for high-scale production of Co{sub 3}O{sub 4}. -- Abstract: In this work, spinel-type Co{sub 3}O{sub 4} spherical nanoparticles were easily prepared via decomposition of the hexamminecobalt(III) nitrate complex, [Co(NH{sub 3}){sub 6}](NO{sub 3}){sub 3}, at low temperature (200 C). The product was characterized by thermal analysis (TGA/DTA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, UVvis spectroscopy, transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), BrunauerEmmettTeller (BET) specific surface area measurement and magnetic measurements. The results confirmed that pure single-phase Co{sub 3}O{sub 4} nanoparticles with weak ferromagnetic behavior were obtained by this method. TEM images showed that the Co{sub 3}O{sub 4} nanoparticles are sphere-like with an average diameter size of around 15 nm. The optical spectrum indicated two direct band gaps at 2.15 and 3.56 eV which are blue-shifted relative to reported values for the bulk sample. Using this fast and simple method, Co{sub 3}O{sub 4} nanoparticles can be produced without expensive and toxic solvents or complicated equipment.

  12. Multiband Te p Based Superconductivity of Ta4Pd3Te16

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, David J.

    2014-10-06

    We recently discovered that Ta4Pd3Te16 is a superconductor that has been suggested to be an unconventional superconductor near magnetism. Here, we report electronic structure calculations showing that despite the layered crystal structure the material is an anisotropic three-dimensional (3D) metal. The Fermi surface contains prominent one-dimensional (1D) and two-dimensional (2D) features, including nested 1D sheets, a 2D cylindrical section, and a 3D sheet. Moreover, the electronic states that make up the Fermi surface are mostly derived from Te p states with small Ta d and Pd d contributions. This places the compound far from magnetic instabilities. The results are discussedmore » in terms of multiband superconductivity.« less

  13. Enhanced piezoelectric performance of (0.98-x)Bi(Sc{sub 3/4}In{sub 1/4})O{sub 3}-xPbTiO{sub 3}-0.02Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3} ternary high temperature piezoelectric ceramics

    SciTech Connect (OSTI)

    Chen Jianguo; Zhao Tianlong; Cheng Jinrong; Dong Shuxiang

    2013-04-14

    (0.98-x)Bi(Sc{sub 3/4}In{sub 1/4})O{sub 3}-xPbTiO{sub 3}-0.02Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3} (BSI-PT-PZN) high temperature piezoelectric ceramics were prepared by traditional solid-state reaction method. Combining X-ray diffraction results with piezoelectric data, it was found that the morphotropic phase boundary (MPB) occurred at x = 0.575. The piezoelectric constant d{sub 33}, curie temperature T{sub c}, and electromechanical coupling factor k{sub p} of BIS-PT-PZN ceramics with MPB composition were 427 pC/N, 412 Degree-Sign C, and 0.51, respectively. Furthermore, the strain of BIS-PT-PZN ceramics reached up to 0.25% under the electric field of 40 kV/cm. Temperature-dependent electromechanical coupling coefficient for MPB composition was stable from room temperature up to 350 Degree-Sign C. The piezoelectric properties of BIS-PT-PZN ceramics were comparable to that of 0.36BiScO{sub 3}-0.64PbTiO{sub 3} (BS-PT) ceramics, and the piezoelectric constant d{sub 33} of BIS-PT-PZN ceramics was about twice that of our previous reported 0.4Bi(Sc{sub 3/4}In{sub 1/4})O{sub 3}-0.6PbTiO{sub 3} (BSI-PT) ceramics. The reduction in the expensive Sc{sub 2}O{sub 3} content and comparable piezoelectric properties with BS-PT ceramics indicated that BIS-PT-PZN ceramics were promising for commercial applications as high temperature actuators and sensors.

  14. Twelve-month, 12 km resolution North American WRF-Chem v3.4 air quality simulation: performance evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tessum, C. W.; Hill, J. D.; Marshall, J. D.

    2015-04-07

    We present results from and evaluate the performance of a 12-month, 12 km horizontal resolution year 2005 air pollution simulation for the contiguous United States using the WRF-Chem (Weather Research and Forecasting with Chemistry) meteorology and chemical transport model (CTM). We employ the 2005 US National Emissions Inventory, the Regional Atmospheric Chemistry Mechanism (RACM), and the Modal Aerosol Dynamics Model for Europe (MADE) with a volatility basis set (VBS) secondary aerosol module. Overall, model performance is comparable to contemporary modeling efforts used for regulatory and health-effects analysis, with an annual average daytime ozone (O3) mean fractional bias (MFB) of 12%more » and an annual average fine particulate matter (PM2.5) MFB of −1%. WRF-Chem, as configured here, tends to overpredict total PM2.5 at some high concentration locations and generally overpredicts average 24 h O3 concentrations. Performance is better at predicting daytime-average and daily peak O3 concentrations, which are more relevant for regulatory and health effects analyses relative to annual average values. Predictive performance for PM2.5 subspecies is mixed: the model overpredicts particulate sulfate (MFB = 36%), underpredicts particulate nitrate (MFB = −110%) and organic carbon (MFB = −29%), and relatively accurately predicts particulate ammonium (MFB = 3%) and elemental carbon (MFB = 3%), so that the accuracy in total PM2.5 predictions is to some extent a function of offsetting over- and underpredictions of PM2.5 subspecies. Model predictive performance for PM2.5 and its subspecies is in general worse in winter and in the western US than in other seasons and regions, suggesting spatial and temporal opportunities for future WRF-Chem model development and evaluation.« less

  15. Twelve-month, 12 km resolution North American WRF-Chem v3.4 air quality simulation: performance evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tessum, C. W.; Hill, J. D.; Marshall, J. D.

    2014-12-02

    We present results from and evaluate the performance of a 12 month, 12 km horizontal resolution air pollution simulation for the contiguous United States using the WRF-Chem (Weather Research and Forecasting with Chemistry) meteorology and chemical transport model (CTM). We employ the 2005 US National Emissions Inventory, the Regional Atmospheric Chemistry Mechanism (RACM), and the Modal Aerosol Dynamics Model for Europe (MADE) with a Volatility Basis Set (VBS) secondary aerosol module. Overall, model performance is comparable to contemporary models used for regulatory and health-effects analysis, with an annual average daytime ozone (O3) mean fractional bias (MFB) of 12% and anmore » annual average fine particulate matter (PM2.5) MFB of −1%. WRF-Chem, as configured here, tends to overpredict total PM2.5 at some high concentration locations, and generally overpredicts average 24 h O3 concentrations, with better performance at predicting average daytime and daily peak O3 concentrations. Predictive performance for PM2.5 subspecies is mixed: the model overpredicts particulate sulfate (MFB = 65%), underpredicts particulate nitrate (MFB = −110%) and organic carbon (MFB = −65%), and relatively accurately predicts particulate ammonium (MFB = 3%) and elemental carbon (MFB = 3%), so that the accuracy in total PM2.5 predictions is to some extent a function of offsetting over- and underpredictions of PM2.5 subspecies. Model predictive performance for PM2.5 and its subspecies is in general worse in winter and in the western US than in other seasons and regions, suggesting spatial and temporal opportunities for future WRF-Chem model development and evaluation.« less

  16. Metrics for Evaluating the Accuracy of Solar Power Forecasting: Preprint

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B. M.; Florita, A.; Lu, S.; Hamann, H. F.; Banunarayanan, V.

    2013-10-01

    Forecasting solar energy generation is a challenging task due to the variety of solar power systems and weather regimes encountered. Forecast inaccuracies can result in substantial economic losses and power system reliability issues. This paper presents a suite of generally applicable and value-based metrics for solar forecasting for a comprehensive set of scenarios (i.e., different time horizons, geographic locations, applications, etc.). In addition, a comprehensive framework is developed to analyze the sensitivity of the proposed metrics to three types of solar forecasting improvements using a design of experiments methodology, in conjunction with response surface and sensitivity analysis methods. The results show that the developed metrics can efficiently evaluate the quality of solar forecasts, and assess the economic and reliability impact of improved solar forecasting.

  17. The hyperthermia mediated by 3,4-methylenedioxymethamphetamine (MDMA, Ecstasy) is sensitive to sex differences

    SciTech Connect (OSTI)

    Wyeth, Richard P. [Division of Pharmacology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Division of Physiology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Mills, Edward M. [Division of Pharmacology and Toxicology, College of Pharmacy, University of Texas at Austin, Austin, TX 78712 (United States); Ullman, Alison [Division of Pharmacology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Division of Physiology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Kenaston, M. Alexander; Burwell, Johanna [Division of Pharmacology and Toxicology, College of Pharmacy, University of Texas at Austin, Austin, TX 78712 (United States); Sprague, Jon E. [Division of Pharmacology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Division of Physiology, Virginia College of Osteopathic Medicine, Blacksburg, VA 24060 (United States); Raabe College of Pharmacy, Ohio Northern University, Ada, OH 45810 (United States)], E-mail: j-sprague@onu.edu

    2009-02-15

    Female subjects have been reported to be less sensitive to the hyperthermic effects of 3,4-methylenedioxymethamine (MDMA) than males. Studies were designed to examine the cellular mechanisms involved in these sex sensitive differences. Gonadectomized female and male rats were treated with a 200 {mu}g 100 {mu}L{sup -1} of estrogen or 100 {mu}g 100 {mu}L{sup -1} of testosterone respectively every 5 days for a total of three doses. Rats were then challenged with either saline or MDMA (20 mg kg{sup -1}, sc). Rats were then euthanized and aortas were constricted, in vitro, by serial phenylephrine (Phe) addition with or without the inhibitor of nitric oxide (NO) synthase, g-nitro-L-Arginine-Methyl Ester (L-NAME). Skeletal muscle uncoupling protein-3 (UCP3) expression was measured as well as plasma norepinephrine (NE) levels. All males but no females developed hyperthermia following MDMA treatment. The EC{sub 50} for Phe dose response curves increased only in the females treated with MDMA and T{sub max} for Phe increased following L-NAME only in the females. Both males and females demonstrated an increase in plasma NE following MDMA treatment; however, males displayed a significantly greater NE concentration. Skeletal muscle UCP3 expression was 80% less in females than in males. These results suggest that the inability of MDMA to induce a thermogenic response in the female subjects may be due to four sex-specific mechanisms: 1) Female subjects have reduced sympathetic activation following MDMA challenge; 2) Female vasculature is less sensitive to {alpha}{sub 1}-AR stimulation following MDMA challenge; 3) Female vasculature has an increased sensitivity to NO; 4) UCP3 expression in skeletal muscle is less in females.

  18. Data:547177e4-4225-4cc3-8d4b-95cddfe449b8 | Open Energy Information

    Open Energy Info (EERE)

    under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information...

  19. Interpretation of 3D void measurements with Tripoli4.6/JEFF3.1.1 Monte Carlo code

    SciTech Connect (OSTI)

    Blaise, P.; Colomba, A.

    2012-07-01

    The present work details the first analysis of the 3D void phase conducted during the EPICURE/UM17x17/7% mixed UOX/MOX configuration. This configuration is composed of a homogeneous central 17x17 MOX-7% assembly, surrounded by portions of 17x17 1102 assemblies with guide-tubes. The void bubble is modelled by a small waterproof 5x5 fuel pin parallelepiped box of 11 cm height, placed in the centre of the MOX assembly. This bubble, initially placed at the core mid-plane, is then moved in different axial positions to study the evolution in the core of the axial perturbation. Then, to simulate the growing of this bubble in order to understand the effects of increased void fraction along the fuel pin, 3 and 5 bubbles have been stacked axially, from the core mid-plane. The C/E comparison obtained with the Monte Carlo code Tripoli4 for both radial and axial fission rate distributions, and in particular the reproduction of the very important flux gradients at the void/water interfaces, changing as the bubble is displaced along the z-axis are very satisfactory. It demonstrates both the capability of the code and its library to reproduce this kind of situation, as the very good quality of the experimental results, confirming the UM-17x17 as an excellent experimental benchmark for 3D code validation. This work has been performed within the frame of the V and V program for the future APOLL03 deterministic code of CEA starting in 2012, and its V and V benchmarking database. (authors)

  20. Upcoming Funding Opportunity for Wind Forecasting Improvement Project in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Complex Terrain | Department of Energy Wind Forecasting Improvement Project in Complex Terrain Upcoming Funding Opportunity for Wind Forecasting Improvement Project in Complex Terrain February 12, 2014 - 10:47am Addthis On February 11, 2014 the Wind Program announced a Notice of Intent to issue a funding opportunity entitled "Wind Forecasting Improvement Project in Complex Terrain." By researching the physical processes that take place in complex terrain, this funding would improve

  1. Module 6 - Metrics, Performance Measurements and Forecasting | Department

    Energy Savers [EERE]

    of Energy 6 - Metrics, Performance Measurements and Forecasting Module 6 - Metrics, Performance Measurements and Forecasting This module focuses on the metrics and performance measurement tools used in Earned Value. This module reviews metrics such as cost and schedule variance along with cost and schedule performance indices. In addition, this module will outline forecasting tools such as estimate to complete (ETC) and estimate at completion (EAC)

  2. DOE Benefits Forecasts: Report of the External Peer Review Panel |

    Office of Environmental Management (EM)

    Department of Energy Benefits Forecasts: Report of the External Peer Review Panel DOE Benefits Forecasts: Report of the External Peer Review Panel A report for the FY 2007 GPRA methodology review, highlighting the views of an external expert peer review panel on DOE benefits forecasts. PDF icon Report of the External Peer Review Panel More Documents & Publications Industrial Technologies Funding Profile by Subprogram Survey of Emissions Models for Distributed Combined Heat and Power

  3. NREL: Resource Assessment and Forecasting - Webmaster

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Webmaster Use this form to send us your comments and questions, report problems with the site, or ask for help finding information on the site. Please enter your name and email address in the boxes provided, then type your message below. When you are finished, click "Send Message." NOTE: If you enter your e-mail address incorrectly, we will be unable to reply. Your name: Your email address: Your message: Send Message Printable Version Resource Assessment & Forecasting Home

  4. Ensemble Solar Forecasting Statistical Quantification and Sensitivity Analysis: Preprint

    SciTech Connect (OSTI)

    Cheung, WanYin; Zhang, Jie; Florita, Anthony; Hodge, Bri-Mathias; Lu, Siyuan; Hamann, Hendrik F.; Sun, Qian; Lehman, Brad

    2015-12-08

    Uncertainties associated with solar forecasts present challenges to maintain grid reliability, especially at high solar penetrations. This study aims to quantify the errors associated with the day-ahead solar forecast parameters and the theoretical solar power output for a 51-kW solar power plant in a utility area in the state of Vermont, U.S. Forecasts were generated by three numerical weather prediction (NWP) models, including the Rapid Refresh, the High Resolution Rapid Refresh, and the North American Model, and a machine-learning ensemble model. A photovoltaic (PV) performance model was adopted to calculate theoretical solar power generation using the forecast parameters (e.g., irradiance, cell temperature, and wind speed). Errors of the power outputs were quantified using statistical moments and a suite of metrics, such as the normalized root mean squared error (NRMSE). In addition, the PV model's sensitivity to different forecast parameters was quantified and analyzed. Results showed that the ensemble model yielded forecasts in all parameters with the smallest NRMSE. The NRMSE of solar irradiance forecasts of the ensemble NWP model was reduced by 28.10% compared to the best of the three NWP models. Further, the sensitivity analysis indicated that the errors of the forecasted cell temperature attributed only approximately 0.12% to the NRMSE of the power output as opposed to 7.44% from the forecasted solar irradiance.

  5. Wind Power Forecasting Error Distributions: An International Comparison; Preprint

    SciTech Connect (OSTI)

    Hodge, B. M.; Lew, D.; Milligan, M.; Holttinen, H.; Sillanpaa, S.; Gomez-Lazaro, E.; Scharff, R.; Soder, L.; Larsen, X. G.; Giebel, G.; Flynn, D.; Dobschinski, J.

    2012-09-01

    Wind power forecasting is expected to be an important enabler for greater penetration of wind power into electricity systems. Because no wind forecasting system is perfect, a thorough understanding of the errors that do occur can be critical to system operation functions, such as the setting of operating reserve levels. This paper provides an international comparison of the distribution of wind power forecasting errors from operational systems, based on real forecast data. The paper concludes with an assessment of similarities and differences between the errors observed in different locations.

  6. The Wind Forecast Improvement Project (WFIP): A Public/Private...

    Broader source: Energy.gov (indexed) [DOE]

    research project whose overarching goals are to improve the accuracy of short-term wind energy forecasts, and to demonstrate the economic value of these improvements. WFIP Round...

  7. Improving the Accuracy of Solar Forecasting Funding Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunity, DOE is funding solar projects that are helping utilities, grid operators, solar power plant owners, and other stakeholders better forecast when, where, and how much...

  8. FY 2004 Second Quarter Review Forecast of Generation Accumulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonneville Power Administration Power Business Line Generation (PBL) Accumulated Net Revenue Forecast for Financial-Based Cost Recovery Adjustment Clause (FB CRAC) and Safety-Net...

  9. PBL FY 2003 Third Quarter Review Forecast of Generation Accumulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2003 Bonneville Power Administration Power Business Line Generation Accumulated Net Revenue Forecast for Financial-Based Cost Recovery Adjustment Clause (FB CRAC) and Safety-Net...

  10. Roel Neggers European Centre for Medium-range Weather Forecasts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transition from shallow to deep convection using a dual mass flux boundary layer scheme Roel Neggers European Centre for Medium-range Weather Forecasts Introduction " " % % &...

  11. (2R)-4-Oxo-4[3-(Trifluoromethyl)-5,6-diihydro:1,2,4}triazolo[4,3-a}pyrazin-7(8H)-y1]-1-(2,4,5-trifluorophenyl)butan-2-amine: A Potent, Orally Active Dipeptidyl Peptidase IV Inhibitor for the Treatment of Type 2 Diabetes

    SciTech Connect (OSTI)

    Kim, D.; Wang, L.; Beconi, M.; Eiermann, G.; Fisher, M.; He, H.; Hickey, G.; Kowalchick, Jennifer; Leiting, Barbara; Lyons, K.; Marsilio, F.; McCann, F.; Patel, R.; Petrov, A.; Scapin, G.; Patel, S.; Roy, R.; Wu, J.; Wyvratt, M.; Zhang, B.; Zhu, L.; Thornberry, N.; Weber, A.

    2010-11-10

    A novel series of {beta}-amino amides incorporating fused heterocycles, i.e., triazolopiperazines, were synthesized and evaluated as inhibitors of dipeptidyl peptidase IV (DPP-IV) for the treatment of type 2 diabetes. (2R)-4-Oxo-4-[3-(trifluoromethyl)-5,6-dihydro[1,2,4]triazolo[4,3-a]pyrazin-7(8H)-yl]-1-(2,4,5-trifluorophenyl)butan-2-amine (1) is a potent, orally active DPP-IV inhibitor (IC{sub 50} = 18 nM) with excellent selectivity over other proline-selective peptidases, oral bioavailability in preclinical species, and in vivo efficacy in animal models. MK-0431, the phosphate salt of compound 1, was selected for development as a potential new treatment for type 2 diabetes.

  12. Combustion synthesized nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode for lithium-ion batteries

    SciTech Connect (OSTI)

    Nathiya, K.; Bhuvaneswari, D.; Gangulibabu; Kalaiselvi, N.

    2012-12-15

    Graphical abstract: Nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C compound has been synthesized using a novel corn assisted combustion (CAC) method, wherein the composite prepared at 850 C is found to exhibit superior physical and electrochemical properties than the one synthesized at 800 C (Fig. 1). Despite the charge disproportionation of V{sup 4+} and a possible solid solution behavior of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3} cathode upon insertion and de-insertion of Li{sup +} ions, the structural stability of the same is appreciable, even with the extraction of third lithium at 4.6 V (Fig. 2). An appreciable specific capacity of 174 mAh g{sup ?1} with an excellent columbic efficiency (99%) and better capacity retention upon high rate applications have been exhibited by Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode, thus demonstrating the feasibility of CAC method in preparing the title compound to best suit with the needs of lithium battery applications. Display Omitted Highlights: ? Novel corn assisted combustion method has been used to synthesize Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C. ? Corn is a cheap and eco benign combustible fuel to facilitate CAC synthesis. ? Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C exhibits an appreciable specific capacity of 174 mAh g{sup ?1} (C/10 rate). ? Currently observed columbic efficiency of 99% is better than the reported behavior. ? Suitability of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode up to 10C rate is demonstrated. -- Abstract: Nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C composite synthesized using a novel corn assisted combustion method at 850 C exhibits superior physical and electrochemical properties than the one synthesized at 800 C. Despite the charge disproportionation of V{sup 4+} and a possible solid solution behavior of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3} cathode upon insertion and extraction of Li{sup +} ions, the structural stability of the same is appreciable, even with the extraction of third lithium at 4.6 V. An appreciable specific capacity of 174 mAh g{sup ?1} and better capacity retention upon high rate applications have been exhibited by Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode, thus demonstrating the suitability of the same for lithium-ion battery applications.

  13. Oxidase uncoupling in heme monooxygenases: Human cytochrome P450 CYP3A4 in Nanodiscs

    SciTech Connect (OSTI)

    Grinkova, Yelena V.; Denisov, Ilia G.; McLean, Mark A.; Sligar, Stephen G.

    2013-01-25

    Highlights: ? Substantial reducing equivalents are lost in human P450 CYP3A4 via an oxidase channel. ? Substrate binding has a pronounced effect on uncoupling in cytochrome P450. ? Anionic phospholipids improve the overall coupling in CYP3A4 Nanodiscs. -- Abstract: The normal reaction mechanism of cytochrome P450 operates by utilizing two reducing equivalents to reduce atmospheric dioxygen, producing one molecule of water and an oxygenated product in an overall stoichiometry of 2 electrons:1 dioxygen:1 product. However, three alternate unproductive pathways exist where the intermediate ironoxygen states in the catalytic cycle can yield reduced oxygen products without substrate metabolism. The first involves release of superoxide from the oxygenated intermediate while the second occurs after input of the second reducing equivalent. Superoxide rapidly dismutates and hence both processes produce hydrogen peroxide that can be cytotoxic to the organism. In both cases, the formation of hydrogen peroxide involves the same overall stoichiometry as oxygenases catalysis. The key step in the catalytic cycle of cytochrome P450 involves scission of the oxygenoxygen bond of atmospheric dioxygen to produce a higher valent iron-oxo state termed Compound I. This intermediate initiates a radical reaction in the oxygenase pathway but also can uptake two additional reducing equivalents from reduced pyridine nucleotide (NADPH) and the flavoprotein reductase to produce a second molecule of water. This non-productive decay of Compound I thus yields an overall oxygen to NADPH ratio of 1:2 and does not produce hydrocarbon oxidation. This water uncoupling reaction provides one of a limited means to study the reactivity of the critical Compound I intermediate in P450 catalysis. We measured simultaneously the rates of NADPH and oxygen consumption as a function of substrate concentration during the steady-state hydroxylation of testosterone catalyzed by human P450 CYP3A4 reconstituted in Nanodiscs. We discovered that the oxidase uncoupling pathway is also operating in the substrate free form of the enzyme with rate of this pathway substantially increasing with the first substrate binding event. Surprisingly, a large fraction of the reducing equivalents used by the P450 system is wasted in this oxidase pathway. In addition, the overall coupling with testosterone and bromocryptine as substrates is significantly higher in the presence of anionic lipids, which is attributed to the changes in the redox potential of CYP3A4 and reductase.

  14. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect (OSTI)

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  15. LPG--a direct source of C/sub 3/-C/sub 4/ olefins

    SciTech Connect (OSTI)

    Pujado, P.R.; Berg, R.C.; Vora, B.V.

    1983-03-28

    This article describes the selective production of olefins by the catalytic dehydrogenation of the corresponding paraffins by means of UOP's Oleflex process. In this process, propylene can be obtained at about 85 mol % selectivity by the catalytic dehydrogenation of propane. Isobutylene can be obtained at selectivities in excess of 90 mol % from isobutane, and n-butenes (1-butene plus 2-butene) at about 80 mol % from n-butane. The availability of this technology, coupled with an abundant supply of LPG (C/sub 3/ and C/sub 4/ paraffins), opens new avenues for the selective production of propylene and butylenes.

  16. Results of the Gallium-Clad Phase 3 and Phase 4 tasks (canceled prior to completion)

    SciTech Connect (OSTI)

    Morris, R.N.

    1998-08-01

    This report summarizes the results of the Gallium-Clad interactions Phase 3 and 4 tasks. Both tasks were to involve examining the out-of-pile stability of residual gallium in short fuel rods with an imposed thermal gradient. The thermal environment was to be created by an electrical heater in the center of the fuel rod and coolant flow on the rod outer cladding. Both tasks were canceled due to difficulties with fuel pellet fabrication, delays in the preparation of the test apparatus, and changes in the Fissile Materials Disposition program budget.

  17. Buildings Energy Data Book: 4.3 Federal Buildings and Facilities Expenditures

    Buildings Energy Data Book [EERE]

    3 Direct Appropriations on Federal Buildings Energy Conservation Retrofits and Capital Equipment ($2010 Million) FY 1985 FY 1986 FY 1987 FY 1988 FY 1989 FY 1990 Source(s): DOE/FEMP, Annual Report to Congress on FEMP FY 2007, Jan. 2010, Table 11-B, p. 31; DOE/FEMP, Annual Report to Congress on FEMP, Nov. 2007, Table 9-B, p. 26 for 1985, 1990, 1995, 2000-2006; DOE/FEMP, Annual Report to Congress on FEMP, Sep. 2004, Table 4-B, p. 38 for 1986-1989, 1991-1994, 1996-1999; EIA, Annual Energy Review

  18. Enhanced Short-Term Wind Power Forecasting and Value to Grid Operations: Preprint

    SciTech Connect (OSTI)

    Orwig, K.; Clark, C.; Cline, J.; Benjamin, S.; Wilczak, J.; Marquis, M.; Finley, C.; Stern, A.; Freedman, J.

    2012-09-01

    The current state of the art of wind power forecasting in the 0- to 6-hour time frame has levels of uncertainty that are adding increased costs and risk on the U.S. electrical grid. It is widely recognized within the electrical grid community that improvements to these forecasts could greatly reduce the costs and risks associated with integrating higher penetrations of wind energy. The U.S. Department of Energy has sponsored a research campaign in partnership with the National Oceanic and Atmospheric Administration (NOAA) and private industry to foster improvements in wind power forecasting. The research campaign involves a three-pronged approach: 1) a 1-year field measurement campaign within two regions; 2) enhancement of NOAA's experimental 3-km High-Resolution Rapid Refresh (HRRR) model by assimilating the data from the field campaign; and 3) evaluation of the economic and reliability benefits of improved forecasts to grid operators. This paper and presentation provides an overview of the regions selected, instrumentation deployed, data quality and control, assimilation of data into HRRR, and preliminary results of HRRR performance analysis.

  19. Data:873baff3-174f-491f-a4c4-7c1d016cc484 | Open Energy Information

    Open Energy Info (EERE)

    baff3-174f-491f-a4c4-7c1d016cc484 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1....

  20. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel

    SciTech Connect (OSTI)

    Hsiung, L; Fluss, M; Wall, M; Kimura, A

    2009-11-18

    Crystal and interfacial structures of oxide nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y{sub 2}O{sub 3} ODS ferritic steel have been examined using high-resolution transmission electron microscopy (HRTEM) techniques. Oxide nanoparticles with a complex-oxide core and an amorphous shell were frequently observed. The crystal structure of complex-oxide core is identified to be mainly monoclinic Y{sub 4}Al{sub 2}O{sub 9} (YAM) oxide compound. Orientation relationships between the oxide and matrix are found to be dependent on the particle size. Large particles (> 20 nm) tend to be incoherent and have a spherical shape, whereas small particles (< 10 nm) tend to be coherent or semi-coherent and have a faceted interface. The observations of partially amorphous nanoparticles lead us to propose three-stage mechanisms to rationalize the formation of oxide nanoparticles containing core/shell structures in as-fabricated ODS steels.

  1. update4_supplemental_lists_1c_2c_2c3b_041411updated_051711.xls | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy icon update4_supplemental_lists_1c_2c_2c3b_041411updated_051711.xls More Documents & Publications updated_supplemental_lists_1h-2h-3g- 11-4-2011.xlsx updated_supplemental_lists_1j-2j-3i_12-22-2011.xlsx list2_eligible_multifamily_buildings_10-cfr-440-22b4ii.xls

  2. Voluntary Green Power Market Forecast through 2015

    SciTech Connect (OSTI)

    Bird, L.; Holt, E.; Sumner, J.; Kreycik, C.

    2010-05-01

    Various factors influence the development of the voluntary 'green' power market--the market in which consumers purchase or produce power from non-polluting, renewable energy sources. These factors include climate policies, renewable portfolio standards (RPS), renewable energy prices, consumers' interest in purchasing green power, and utilities' interest in promoting existing programs and in offering new green options. This report presents estimates of voluntary market demand for green power through 2015 that were made using historical data and three scenarios: low-growth, high-growth, and negative-policy impacts. The resulting forecast projects the total voluntary demand for renewable energy in 2015 to range from 63 million MWh annually in the low case scenario to 157 million MWh annually in the high case scenario, representing an approximately 2.5-fold difference. The negative-policy impacts scenario reflects a market size of 24 million MWh. Several key uncertainties affect the results of this forecast, including uncertainties related to growth assumptions, the impacts that policy may have on the market, the price and competitiveness of renewable generation, and the level of interest that utilities have in offering and promoting green power products.

  3. Exclusion of an Exotic Top Quark with -4/3 Electric Charge Using Soft Lepton Tagging

    SciTech Connect (OSTI)

    Aaltonen, T.; Adelman, J.; Alvarez Gonzalez, B.; Amerio, S.; Amidei, D.; Anastassov, A.; Annovi, A.; Antos, J.; Apollinari, G.; Appel, J.; Apresyan, A.; /Purdue U. /Waseda U.

    2010-06-01

    We present a measurement of the electric charge of the top quark using p{bar p} collisions corresponding to an integrated luminosity of 2.7 fb{sup -1} at the CDF II detector. We reconstruct t{bar t} events in the lepton+jets final state and use kinematic information to determine which b-jet is associated with the leptonically- or hadronically-decaying t-quark. Soft lepton taggers are used to determine the b-jet flavor. Along with the charge of the W boson decay lepton, this information permits the reconstruction of the top quark's electric charge. Out of 45 reconstructed events with 2.4 {+-} 0.8 expected background events, 29 are reconstructed as tt with the standard model +2/3 charge, whereas 16 are reconstructed as t{bar t} with an exotic -4/3 charge. This is consistent with the standard model and excludes the exotic scenario at 95% confidence level. This is the strongest exclusion of the exotic charge scenario and the first to use soft leptons for this purpose.

  4. Solvent extraction of Li+, H3O+ and NH4+ into nitrobenzene by using sodium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)

    SciTech Connect (OSTI)

    Makrlik, Emanuel; Selucky, P.; Vanura, Petr; Moyer, Bruce A

    2013-01-01

    From extraction experiments and c-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + NaL+ (nb) , ML+ (nb) + Na+ (aq) taking place in the two-phase water nitrobenzene system (M+ = Li+, H3O+, NH+4; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: zH3O+ < Li+ < NH+4.

  5. Two lead(II) 2,4-dioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate complexes exhibiting different topologies and fluorescent properties

    SciTech Connect (OSTI)

    Chen Zilu; Yan Jiehua; Xing Huihui; Zhang Zhong; Liang Fupei

    2011-05-15

    The reactions of PbCl{sub 2} with 2,4-dioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid (H{sub 3}iso) gave two complexes [Pb(H{sub 2}iso){sub 2}(H{sub 2}O)]{sub n} (1) and [Pb(Hiso)(H{sub 2}O)]{sub n} (2), which were characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and single crystal X-ray diffraction analysis. The two complexes display different topologies. 1 shows a three-dimensional framework with the Schlaefli symbol (4.8{sup 5})(4.8{sup 2}) no matter if the weak Pb-O bonds are included or not. However, 2 presents a 3,3-connected two-dimensional sheet with the Schlaefli symbol (4.8{sup 2})(4.8{sup 2}) based on the calculation of only the normal Pb-O bonds and a 5,5-connected 3D network with the Schlaefli symbol (4{sup 15}.6{sup 4})(4{sup 4}.6{sup 8}.8{sup 2}) when the weak Pb-O bonds are also included. The fluorescent studies reveal an emission attributed to intraligand emission for 1 and an emission assigned to LMCT for 2. -- Graphical abstract: The reactions of PbCl{sub 2} with 2,4-dioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic acid (H{sub 3}iso) gave two complexes [Pb(H{sub 2}iso){sub 2}(H{sub 2}O)]{sub n} (1) and [Pb(Hiso)(H{sub 2}O)]{sub n} (2), which display different topologies and fluorescent properties. Display Omitted Highlights: {yields} Two Pb(II) complexes were prepared from the reactions of PbCl{sub 2} with the same ligand. {yields} The two title complexes display different topologies. {yields} Both normal and weak Pb-O bonds are discussed in the manuscript.{yields} The title two complexes show different fluorescent properties.

  6. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect (OSTI)

    West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory; He, Jian; Hitchcock, Dale; Yan, Yonggao; Hwu, Shiou-Jyh

    2013-10-15

    Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-JahnTeller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagom fashion. Enhanced ferromagnetic ordering attributed to doping non-JahnTeller Mn{sup 4+}.

  7. Study of difference in interfacial reaction at Fe{sub 3}O{sub 4}/ZnO and ZnO/Fe{sub 3}O{sub 4} heterostructure using synchrotron radiation

    SciTech Connect (OSTI)

    Wadikar, A. D. Master, Ridhi Choudhary, R. J. Phase, D. M.

    2014-04-24

    We have prepared Fe{sub 3}O{sub 4}/ZnO and ZnO/Fe{sub 3}O{sub 4} bilayer structure on p-Si substrate using pulsed laser deposition technique (PLD). X-ray diffraction study revealed (0001) oriented growth of ZnO and (111) oriented growth of Fe{sub 3}O{sub 4} in both the bilayer structure. We observed a change in the density of states near the Fermi level in valence band spectra in case of Fe{sub 3}O{sub 4}/ZnO bilayer when compared to that of ZnO/Fe{sub 3}O{sub 4}. Nonlinear current–voltage (I-V) characteristics were observed in both the samples confirmed that these bilayer structures can be used for spintronic application.

  8. Spin-lozenge thermodynamics and magnetic excitations in Na3RuO4

    SciTech Connect (OSTI)

    Haraldsen, Jason T; Stone, Matthew B; Lumsden, Mark D; Barnes, Ted {F E }; Jin, Rongying; Taylor, J. W.; Fernandez-Alonso, F

    2009-01-01

    We report inelastic and elastic neutron scattering, magnetic susceptibility, and heat capacity measurements of polycrystalline sodium ruthenate (Na3RuO4). Previous work suggests this material consists of isolated tetramers of S = 3/2 Ru5+ ions in a so-called lozenge configuration. Using a Heisenberg antiferromagnet Hamiltonian, we analytically determine the energy eigenstates for general spin S. From this model, the neutron scattering cross-sections for excitations associated with spin-3/2 tetramer configurations is determined. Comparison of magnetic susceptibility and inelastic neutron scattering results shows that the proposed lozenge model is not distinctly supported, but provides evidence that the system may be better described as a pair of non-interacting inequivalent dimers, i.e double dimers. However, the existence of long-range magnetic order below Tc ≈ 28 K immediately questions such a description. Although no evidence of the lozenge model is observed, future studies on single crystals may further clarify the appropriate magnetic Hamiltonian.

  9. updated_supplemental_lists_1h-2h-3g- 11-4-2011.xlsx | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    h-2h-3g- 11-4-2011.xlsx More Documents & Publications updated_supplemental_lists_1n-2n-3m_07-06-2012.xlsx updated_supplemental_lists_1p_2p_3o_04302013.xlsx updated_supplemental_lists_1j-2j-3i_12-22

  10. Conversion of 4-Hydroxybutyrate to Acetyl Coenzyme A and Its Anapleurosis in the Metallosphaera sedula 3-Hydroxypropionate/4-Hydroxybutyrate Carbon Fixation Pathway

    SciTech Connect (OSTI)

    Hawkins, AB; Adams, MWW; Kelly, RM

    2014-03-25

    The extremely thermoacidophilic archaeon Metallosphaera sedula (optimum growth temperature, 73 degrees C, pH 2.0) grows chemolithoautotrophically on metal sulfides or molecular hydrogen by employing the 3-hydroxypropionate/4-hydroxybutyrate (3HP/4HB) carbon fixation cycle. This cycle adds two CO2 molecules to acetyl coenzyme A (acetyl-CoA) to generate 4HB, which is then rearranged and cleaved to form two acetyl-CoA molecules. Previous metabolic flux analysis showed that two-thirds of central carbon precursor molecules are derived from succinyl-CoA, which is oxidized to malate and oxaloacetate. The remaining one-third is apparently derived from acetyl-CoA. As such, the steps beyond succinyl-CoA are essential for completing the carbon fixation cycle and for anapleurosis of acetyl-CoA. Here, the final four enzymes of the 3HP/4HB cycle, 4-hydroxybutyrate-CoA ligase (AMP forming) (Msed_0406), 4-hydroxybutyryl-CoA dehydratase (Msed_1321), crotonyl-CoA hydratase/(S)-3-hydroxybutyryl-CoA dehydrogenase (Msed_0399), and acetoacetyl-CoA beta-ketothiolase (Msed_0656), were produced recombinantly in Escherichia coli, combined in vitro, and shown to convert 4HB to acetyl-CoA. Metabolic pathways connecting CO2 fixation and central metabolism were examined using a gas-intensive bioreactor system in which M. sedula was grown under autotrophic (CO2-limited) and heterotrophic conditions. Transcriptomic analysis revealed the importance of the 3HP/4HB pathway in supplying acetyl-CoA to anabolic pathways generating intermediates in M. sedula metabolism. The results indicated that flux between the succinate and acetyl-CoA branches in the 3HP/4HB pathway is governed by 4-hydroxybutyrate-CoA ligase, possibly regulated posttranslationally by the protein acetyltransferase (Pat)/Sir2-dependent system. Taken together, this work confirms the final four steps of the 3HP/4HB pathway, thereby providing the framework for examining connections between CO2 fixation and central metabolism in M. sedula.

  11. Comparison of Wind Power and Load Forecasting Error Distributions: Preprint

    SciTech Connect (OSTI)

    Hodge, B. M.; Florita, A.; Orwig, K.; Lew, D.; Milligan, M.

    2012-07-01

    The introduction of large amounts of variable and uncertain power sources, such as wind power, into the electricity grid presents a number of challenges for system operations. One issue involves the uncertainty associated with scheduling power that wind will supply in future timeframes. However, this is not an entirely new challenge; load is also variable and uncertain, and is strongly influenced by weather patterns. In this work we make a comparison between the day-ahead forecasting errors encountered in wind power forecasting and load forecasting. The study examines the distribution of errors from operational forecasting systems in two different Independent System Operator (ISO) regions for both wind power and load forecasts at the day-ahead timeframe. The day-ahead timescale is critical in power system operations because it serves the unit commitment function for slow-starting conventional generators.

  12. The Wind Forecast Improvement Project (WFIP): A Public/Private Partnership

    Energy Savers [EERE]

    for Improving Short Term Wind Energy Forecasts and Quantifying the Benefits of Utility Operations | Department of Energy The Wind Forecast Improvement Project (WFIP): A Public/Private Partnership for Improving Short Term Wind Energy Forecasts and Quantifying the Benefits of Utility Operations The Wind Forecast Improvement Project (WFIP): A Public/Private Partnership for Improving Short Term Wind Energy Forecasts and Quantifying the Benefits of Utility Operations The Wind Forecast Improvement

  13. Stress analysis of single port (ISB) jumper connectors for 2-, 3-, and 4-in. sizes

    SciTech Connect (OSTI)

    Islam, M.A.; Julyk, J.L.; Weiner, E.O. [ICF Kaiser Hanford Co., Richland, WA (United States)

    1995-05-26

    Jumper connectors are used in the Hanford site for remotely connecting jumper pipe lines in the radioactive zones. The jumper pipes are used for transporting radioactive fluids and hazardous chemicals. This report evaluates the adequacy and the integrity of the 2-, 3-, and 4-in. single-port integral seal block (ISB) jumper connector assemblies, as well as the three-way 2-in. configuration. The evaluation considers limiting forces from the piping to the nozzle. A stress evaluation of the jumper components (hook, hook pin, operating screw, nozzle and nozzle flange, and block) under operational (pressure, thermal, dead weight, and axial torquing of the jumper) and seismic loading is addressed in the report.

  14. Fundamental Kinetics Database Utilizing Shock Tube Measurements (Volumes 1, 2, 3, 4, and Volume 6)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Davidson, D. F.; Hanson, R. K

    The data from shock tube experiments generally takes three forms: ignition delay times, species concentration time-histories and reaction rate measurements. Volume 1 focuses on ignition delay time data measured and published by the Shock Tube Group in the Mechanical Engineering Department of Stanford University. The cut-off date for inclusion into this volume was January 2005. Volume 2 focuses on species concentration time-histories and was cut off December 2005. The two volumes are in PDF format and are accompanied by a zipped file of supporting data. Volume 3 was issued in 2009. Volume 4, Ignition delay times measurements came out in May, 2014, along with Reaction Rates Measurements, Vol 6. Volume 5 is not available at this time.

  15. Buildings Energy Data Book: 4.3 Federal Buildings and Facilities Expenditures

    Buildings Energy Data Book [EERE]

    1 FY 2007 Federal Buildings Energy Prices and Expenditures, by Fuel Type ($2010) Fuel Type Electricity 23.68 (1) 4,009 Natural Gas 9.37 1,138 Fuel Oil 15.25 419 Coal 3.62 63 Purchased Steam 24.30 318 LPG/Propane 17.06 44 Other 16.19 37 Average 17.05 Total 6,029 Note(s): Source(s): Average Fuel Prices Total Expenditures ($/million BTU) ($ million) (2) Prices and expenditures are for Goal-Subject buildings. 1) $0.0776/kWh. 2) Energy used in Goal-Subject buildings in FY 2007 accounted for 33.8% of

  16. Volume_VIII_App_P_Summary_Ch 3_ References_Ch 4

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -Comment Summaries and Responses Plains & Eastern Final Environmental Impact Statement October 2015 i Contents 3. COMMENT SUMMARIES AND RESPONSES .............................................................................. 3-1 3.1 Introduction ................................................................................................................................ 3-1 3.2 How DOE Considered Public Comments

  17. Short-Term Energy Outlook Model Documentation: Macro Bridge Procedure to Update Regional Macroeconomic Forecasts with National Macroeconomic Forecasts

    Reports and Publications (EIA)

    2010-01-01

    The Regional Short-Term Energy Model (RSTEM) uses macroeconomic variables such as income, employment, industrial production and consumer prices at both the national and regional1 levels as explanatory variables in the generation of the Short-Term Energy Outlook (STEO). This documentation explains how national macroeconomic forecasts are used to update regional macroeconomic forecasts through the RSTEM Macro Bridge procedure.

  18. Energy Savings Forecast of Solid-State Lighting in General Illuminatio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forecast of Solid-State Lighting in General Illumination Applications Energy Savings Forecast of Solid-State Lighting in General Illumination Applications PDF icon...

  19. Geek-Up[3.4.2011]: 3,000+ MW and 2,500 Year-Old Greek Pottery | Department

    Office of Environmental Management (EM)

    of Energy 4.2011]: 3,000+ MW and 2,500 Year-Old Greek Pottery Geek-Up[3.4.2011]: 3,000+ MW and 2,500 Year-Old Greek Pottery March 4, 2011 - 5:03pm Addthis An Attic black-figured amphora, currently in the British Museum, of the type that will be studied at SLAC. | Photo by Marie-Lan Nguyen, Courtesy of SLAC National Accelerator Laboratory An Attic black-figured amphora, currently in the British Museum, of the type that will be studied at SLAC. | Photo by Marie-Lan Nguyen, Courtesy of SLAC

  20. Quantum reactive scattering of O({sup 3}P)+H{sub 2} at collision energies up to 4.4 eV

    SciTech Connect (OSTI)

    Gacesa, Marko; Kharchenko, Vasili

    2014-10-28

    We report the results of quantum scattering calculations for the O({sup 3}P)+H{sub 2} reaction for a range of collision energies from 0.4 to 4.4 eV, important for astrophysical and atmospheric processes. The total and state-to-state reactive cross sections are calculated using a fully quantum time-independent coupled-channel approach on recent potential energy surfaces of {sup 3}A{sup ?} and {sup 3}A{sup ?} symmetry. A larger basis set than in the previous studies was used to ensure single-surface convergence at higher energies. Our results agree well with the published data at lower energies and indicate the breakdown of reduced dimensionality approach at collision energies higher than 1.5 eV. Differential cross sections and momentum transfer cross sections are also reported.

  1. NaLaF{sub 4}:Pr{sup 3+},Yb{sup 3+}, an efficient blue to near infra-red quantum cutter

    SciTech Connect (OSTI)

    Guille, A.; Pereira, A.; Moine, B.

    2013-12-01

    In order to reduce the thermalization losses in solar cells, down-conversion of blue photons into near infra-red photons is a promising solution. In the present paper, we analyse the energy transfer processes between Pr{sup 3+} and Yb{sup 3+} in NaLaF{sub 4} and we show that an efficient quantum-cutting process occurs. Nevertheless, we also show that a back transfer from Yb{sup 3+} toward the {sup 1}G{sub 4} level of Pr{sup 3+} ion leading to emission beyond 1??m reduces the potentiality of this material as a quantum cutter for Si solar cells.

  2. Volume_VIII_App_P_Summary_Ch 3_ References_Ch 4

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ......... 3-245 16 Environmental Justice ......Journal of Dairy Science 81(3):722-7.

  3. Enhanced photocatalytic performance of g-C{sub 3}N{sub 4} with BiOCl quantum dots modification

    SciTech Connect (OSTI)

    Zheng, Chun-zhi Zhang, Chun-yong Zhang, Guo-hua Zhao, De-jian Wang, Ya-zhen

    2014-07-01

    Highlights: Novel BiOCl quantum dots modified g-C{sub 3}N{sub 4} photocatalyst was synthesized. BiOCl-g-C{sub 3}N{sub 4} showed much higher photocatalytic activity than pure g-C{sub 3}N{sub 4} and BiOCl. High separation efficiency of photoinduced carriers results in the enhanced performance. - Abstract: Novel BiOCl quantum dots modified g-C{sub 3}N{sub 4} photocatalyst was synthesized by a one-step chemical bath method at low temperature. The photocatalyst was characterized using X-ray diffraction, high-resolution transmission microscopy UVvisible light diffusion reflectance spectrometry, and photoluminescence spectroscopy. The results indicated that BiOCl quantum dots were dispersed on g-C{sub 3}N{sub 4} to form heterojunction structures with high specific surface area. BiOCl-g-C{sub 3}N{sub 4} showed much higher photocatalytic activity than pure g-C{sub 3}N{sub 4} and BiOCl for rhodamine B degradation. The enhanced performance was induced by the high separation efficiency of photoinduced carriers.

  4. R&D Ex A (Rev. 3.1, 4/9/13) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 31 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  5. U.S. Regional Demand Forecasts Using NEMS and GIS

    SciTech Connect (OSTI)

    Cohen, Jesse A.; Edwards, Jennifer L.; Marnay, Chris

    2005-07-01

    The National Energy Modeling System (NEMS) is a multi-sector, integrated model of the U.S. energy system put out by the Department of Energy's Energy Information Administration. NEMS is used to produce the annual 20-year forecast of U.S. energy use aggregated to the nine-region census division level. The research objective was to disaggregate this regional energy forecast to the county level for select forecast years, for use in a more detailed and accurate regional analysis of energy usage across the U.S. The process of disaggregation using a geographic information system (GIS) was researched and a model was created utilizing available population forecasts and climate zone data. The model's primary purpose was to generate an energy demand forecast with greater spatial resolution than what is currently produced by NEMS, and to produce a flexible model that can be used repeatedly as an add-on to NEMS in which detailed analysis can be executed exogenously with results fed back into the NEMS data flow. The methods developed were then applied to the study data to obtain residential and commercial electricity demand forecasts. The model was subjected to comparative and statistical testing to assess predictive accuracy. Forecasts using this model were robust and accurate in slow-growing, temperate regions such as the Midwest and Mountain regions. Interestingly, however, the model performed with less accuracy in the Pacific and Northwest regions of the country where population growth was more active. In the future more refined methods will be necessary to improve the accuracy of these forecasts. The disaggregation method was written into a flexible tool within the ArcGIS environment which enables the user to output the results in five year intervals over the period 2000-2025. In addition, the outputs of this tool were used to develop a time-series simulation showing the temporal changes in electricity forecasts in terms of absolute, per capita, and density of demand.

  6. Determination of Reportable Radionuclides for DWPF Sludge Batch 3 (Macrobatch 4)

    SciTech Connect (OSTI)

    Bannochie, C

    2005-05-01

    The Waste Acceptance Product Specifications (WAPS) 1.2 require that ''The Producer shall report the inventory of radionuclides (in Curies) that have half-lives longer than 10 years and that are, or will be, present in concentrations greater than 0.05 percent of the total inventory for each waste type indexed to the years 2015 and 3115''. As part of the strategy to meet WAPS 1.2, the Defense Waste Processing Facility (DWPF) will report for each waste type, all radionuclides (with half-lives greater than 10 years) that have concentrations greater than 0.01 percent of the total inventory from time of production through the 1100 year period from 2015 through 3115. The initial listing of radionuclides to be included is based on the design-basis glass as identified in the Waste Form Compliance Plan (WCP) and Waste Form Qualification Report (WQR). However, it is required that this list be expanded if other radionuclides with half-lives greater than 10 years are identified that meet the greater than 0.01% criterion for Curie content. Specification 1.6 of the WAPS, IAEA Safeguards Reporting for HLW, requires that the ratio by weights of the following uranium and plutonium isotopes be reported: U-233, U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, and Pu-242. Therefore, the complete set of reportable radionuclides must also include this set of U and Pu isotopes. The Defense Waste Processing Facility (DWPF) is receiving radioactive sludge slurry from High Level Waste Tank 40. The radioactive sludge slurry in Tank 40 is a blend of the previous contents of Tank 40 (Sludge Batch 2) and the sludge that was transferred to Tank 40 from Tank 51. The blend of sludge from Tank 51 and Tank 40 defines Macrobatch 4 (also referred to as Sludge Batch 3). This report develops the list of reportable radionuclides and associated activities and determines the radionuclide activities as a function of time. The DWPF will use this list and the activities as one of the inputs for the development of the Production Records that relate to radionuclide inventory. This work was initiated through Task Technical Request HLW/DWPF/TTR-03-0005, Revision 1 entitled Sludge Batch 3 SRTC Shielded Cells Testing. Specifically, this report details results from performing, in part, Subtask 3 of the TTR and, in part, meets Deliverable 6 of the TTR. The work was performed following the Technical Task and Quality Assurance Plan (TTQAP), WSRC-RP-2003-00249, Rev. 1 and Analytical Study Plan (ASP), WSRC-RP-2004-00262. In order to determine the reportable radionuclides for Sludge Batch 3 (Macro Batch 4), a list of radioisotopes that may meet the criteria as specified by the Department of Energy's (DOE) WAPS was developed. All radioactive U-235 fission products and all radioactive activation products that could be in the SRS HLW were considered. In addition, all U and Pu isotopes identified in WAPS 1.6 were included in the list. This list was then evaluated and some isotopes excluded from the projection calculations.

  7. X-ray magnetic circular dichroism for Co{sub x}Fe{sub 4?x}N (x?=?0, 3, 4) films grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Ito, Keita; Sanai, Tatsunori; Yasutomi, Yoko; Toko, Kaoru; Suemasu, Takashi; Zhu, Siyuan; Kimura, Akio; Takeda, Yukiharu; Saitoh, Yuji

    2014-05-07

    We evaluated orbital (m{sub orb}) and spin magnetic moments (m{sub spin}) of Co{sub x}Fe{sub 4?x}N (x?=?0, 3, 4) epitaxial thin films grown by molecular beam epitaxy using x-ray magnetic circular dichroism, and discussed the dependence of these values on x. Site-averaged m{sub spin} value of Fe atoms was deduced to be 1.91??{sub B} per atom, and that of Co atoms to be 1.47??{sub B} per atom in Co{sub 3}FeN at 300?K. These values are close to 1.87??{sub B} per Fe atom in Fe{sub 4}N and 1.43??{sub B} per Co atom in Co{sub 4}N, respectively. This result implies that the Fe and Co atoms in the Co{sub 3}FeN films were located both at corner and face-centered sites in the anti-perovskite lattice. Spin magnetic moments per unit cell were decreased linearly with increasing x in Co{sub x}Fe{sub 4?x}N. This tendency is in good agreement with theory predicted by the first-principle calculation.

  8. Thermal Reactions of Uranium Metal, UO2, U3O8, UF4, and UO2F2 with NF3 to Produce UF6

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Kozelisky, Anne E.; Edwards, Matthew K.

    2009-11-01

    he objective of this paper is to demonstrate that NF3 fluorinates uranium metal, UO2, UF4, UO3, U3O8, and UO2F22H2O to produce the volatile UF6 at temperatures between 100 and 500?C. Thermogravimetric reaction profiles are described that reflect changes in the uranium oxidation state and discrete chemical speciation. Differences in the onset temperatures for each system indicate that NF3-substrate interactions are important for the temperature at which NF3 reacts: U metal > UO3 > UO2 > UO2F2 > UF4 and in fact may indicate different fluorination mechanisms for these various substrates. These studies demonstrate that NF3 is a potential replacement fluorinating agent in the existing nuclear fuel cycle and in oft-proposed actinide volatility reprocessing.

  9. Fe3-xTixO4 Nanoparticles as Tunable Probes of Microbial Metal Oxidation

    SciTech Connect (OSTI)

    Liu, Juan; Pearce, Carolyn I.; Liu, Chongxuan; Wang, Zheming; Shi, Liang; Arenholz, Elke; Rosso, Kevin M.

    2013-05-14

    Present and emerging biotechnological applications for iron (oxyhydr)oxide nanomaterials depend on their interaction with microorganisms, as do their toxicity, transport, and fate in biological and environmental systems. However, mass or electron transfer along key molecular pathways at microbe-nanomaterial interfaces is extremely difficult to quantify because of system complexity. Inspired by Fe(II)-oxidizing microbes widespread in nature, we isolate and characterize one such pathway by examining the oxidation of Fe3-xTixO4 (magnetite-titanomagnetite) nanoparticles by the bacterial electron transfer enzyme MtoA, a decaheme c-type cytochrome. Oxidation by MtoA was studied as a function of the thermodynamic driving force for electron transfer by controlling the Ti(IV) doping content (x), which tunes the solid-state Fe(II)/Fe(III) ratio built into the nanoparticles. A higher Fe(II)/Fe(III) ratio appears to proportionally increase the electron transfer kinetics to the cytochrome. In situ x-ray diffraction indicated that during oxidation the spinel ferrite lattice remains intact while structural Fe(II) is progressively depleted. Surface and atomic site specific Fe L2,3-edge x-ray magnetic circular dichroism indicated that MtoA directly accesses magnetically-ordered B-sublattice Fe(II) at the interface. This study provides first quantitative insights into an isolated molecular pathway for biotransformation of iron (oxyhydr)oxide nanomaterials. And, more generally, it also illustrates new techniques for probing these pathways in detail, featuring use of tailored nanoparticles, purified metalloenzyme, and synchrotron x-ray absorption spectroscopies.

  10. Demand forecasting and revenue requirements, with implications for consideration in British Columbia

    SciTech Connect (OSTI)

    Acton, J.P.

    1983-05-01

    This paper was filed as an exhibit on behalf of The Consumers' Association of Canada (B.C. Branch), The Federated Anti-Poverty Groups of B.C., The Sierra Club of Western Canada, and the B.C. Old Age Pensioners' Organization. It was subjected to cross-examination on October 29, 1982, during Phase I of the hearings. The Utilities Commission had designated Phase I for consideration of (1) demand, (2) assets in service, (3) revenue requirements excluding return, and (4) financing and capital requirements. This paper presents a general discussion of the elements of a rate structure and their relationship to the demand for electricity, a systematic review of some 50 empirical studies of the demand for electricity as a function of price and other factors by the three principal classes of customers, and a discussion of the notion of revenue requirements. The paper should be of interest to utility regulators, rate specialists, and forecasters for its review of demand models and to academics concerned with the study of energy demand.

  11. High momentum transfer R{sub T,L} response functions for {sup 3,4}He.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: High momentum transfer R{sub T,L} response functions for {sup 3,4}He. Citation Details In-Document Search Title: High momentum transfer R{sub T,L} response functions for {sup 3,4}He. The tantalizing problem of the 'quenching' of the Coulomb sum rule observed in medium weight nuclei is investigated in light nuclei at high momentum transfer. Inclusive electron scattering cross sections for {sup 3,4}He have been measured in the quasielastic region at

  12. Science and Engineering of an Operational Tsunami Forecasting System

    ScienceCinema (OSTI)

    Gonzalez, Frank

    2010-01-08

    After a review of tsunami statistics and the destruction caused by tsunamis, a means of forecasting tsunamis is discussed as part of an overall program of reducing fatalities through hazard assessment, education, training, mitigation, and a tsunami warning system. The forecast is accomplished via a concept called Deep Ocean Assessment and Reporting of Tsunamis (DART). Small changes of pressure at the sea floor are measured and relayed to warning centers. Under development is an international modeling network to transfer, maintain, and improve tsunami forecast models.

  13. Li{sub 2}B{sub 3}O{sub 4}F{sub 3}, a new lithium-rich fluorooxoborate

    SciTech Connect (OSTI)

    Pilz, Thomas; Nuss, Hanne; Jansen, Martin

    2012-02-15

    The new lithium fluorooxoborate, Li{sub 2}B{sub 3}O{sub 4}F{sub 3}, is obtained by a solid state reaction from LiBO{sub 2} and LiBF{sub 4} at 553 K and crystallizes in the acentric orthorhombic space group P2{sub 1}2{sub 1}2{sub 1} (no. 19) with the cell parameters a=4.8915(9), b=8.734(2), and c=12.301(2) A. Chains of fluorinated boroxine rings along the b axis consists of BO{sub 3} triangles and BO{sub 2}F{sub 2} as well as BO{sub 3}F tetrahedra. Mobile lithium ions are compensating the negative charge of the anionic chain, in which the fourfold coordinated boron atoms bear a negative formal charge. Annealing Li{sub 2}B{sub 3}O{sub 4}F{sub 3} at temperatures above 573 K leads to conversion into Li{sub 2}B{sub 6}O{sub 9}F{sub 2}. The title compound is an ionic conductor with the highest ion conductivity among the hitherto know lithium fluorooxoborates, with conductivities of 1.6 Multiplication-Sign 10{sup -9} and 1.8 Multiplication-Sign 10{sup -8} S cm{sup -1} at 473 and 523 K, respectively. - Graphical abstract: Repetition unit of Li{sub 2}B{sub 3}O{sub 4}F{sub 3}. Highlights: Black-Right-Pointing-Pointer Li{sub 2}B{sub 3}O{sub 4}F{sub 3} is the third member within the family of lithium fluorooxoborates. Black-Right-Pointing-Pointer It shows the highest lithium ion conductivity among them. Black-Right-Pointing-Pointer Chains of interconnected fluorinated boroxine rings run along the b axis. Black-Right-Pointing-Pointer Acentric space group meets the requirement for second harmonic generation.

  14. Helium-3 and Helium-4 acceleration by high power laser pulses for hadron therapy

    SciTech Connect (OSTI)

    Bulanov, S. S.; Esarey, E.; Schroeder, C. B.; Leemans, W. P.; Bulanov, S. V.; Margarone, D.; Korn, G.; Haberer, T.

    2015-06-24

    The laser driven acceleration of ions is considered a promising candidate for an ion source for hadron therapy of oncological diseases. Though proton and carbon ion sources are conventionally used for therapy, other light ions can also be utilized. Whereas carbon ions require 400 MeV per nucleon to reach the same penetration depth as 250 MeV protons, helium ions require only 250 MeV per nucleon, which is the lowest energy per nucleon among the light ions. This fact along with the larger biological damage to cancer cells achieved by helium ions, than that by protons, makes this species an interesting candidate for the laser driven ion source. Two mechanisms (Magnetic Vortex Acceleration and hole-boring Radiation Pressure Acceleration) of PW-class laser driven ion acceleration from liquid and gaseous helium targets are studied with the goal of producing 250 MeV per nucleon helium ion beams that meet the hadron therapy requirements. We show that He3 ions, having almost the same penetration depth as He4 with the same energy per nucleon, require less laser power to be accelerated to the required energy for the hadron therapy.

  15. Volvo Penta 4.3 GL E15 Emissions and Durability Test

    SciTech Connect (OSTI)

    Zoubul, G.; Cahoon, M.; Kolb, R.

    2011-10-01

    A new Volvo Penta carbureted 4.3 GL engine underwent emissions and dynamometer durability testing from break-in to expected end of life using an accelerated ICOMIA marine emissions cycle and E15 fuel. Only ethanol content was controlled. All aging used splash-blended E15 fuel. Exhaust emissions, exhaust gas temperature, torque, power, barometric pressure, air temperature, and fuel flow were measured at five intervals using site-blended E15 aging fuel and certification fuel (E0). The durability test cycle showed no noticeable impact on mechanical durability or engine power. Emissions performance degraded beyond the certification limit for this engine family, mostly occurring by 28% of expected life. Such degradation is inconsistent with prior experience. Comparisons showed that E15 resulted in lower CO and HC, but increased NOX, as expected for non-feedback-controlled carbureted engines with increased oxygen in the fuel. Fuel consumption also increased with E15 compared with E0. Throughout testing, poor starting characteristics were exhibited on E15 fuel for hot re-start and cold-start. Cranking time to start and smooth idle was roughly doubled compared with typical E0 operation. The carburetor was factory-set for lean operation to ensure emissions compliance. Test protocols did not include carburetor adjustment to account for increased oxygen in the E15 fuel.

  16. Superconducting and magnetic properties of Sr3Ir4Sn13

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Amato, A.; Khasanov, R.; Luetkens, H.; Wang, Kefeng; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    In this research, magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr₃Ir₄Sn₁₃. From magnetization measurements the lower and upper critical fields of Sr₃Ir₄Sn₁₃ are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr₃Ir₄Sn₁₃. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth λ. The dependence of λ⁻² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr₃Ir₄Sn₁₃ withmore » a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature λ(0) is 291(3) nm. The ratio Δ(0)/kBTc = 2.1(1) indicates that Sr₃Ir₄Sn₁₃ should be considered as a strong-coupling superconductor.« less

  17. EIS No. 20100312 EIS Comanche Peak Nuclear Power Plant Units 3 and 4

    SciTech Connect (OSTI)

    Bjornstad, David J

    2010-08-01

    In accordance with Section 309(a) of the Clean Air Act, EPA is required to make its comments on EISs issued by other Federal agencies public. Historically, EPA has met this mandate by publishing weekly notices of availability of EPA comments, which includes a brief summary of EPA's comment letters, in the Federal Register. Since February 2008, EPA has been including its comment letters on EISs on its Web site at: http://www.epa.gov/compliance/nepa/eisdata.html. Including the entire EIS comment letters on the Web site satisfies the Section 309(a) requirement to make EPA's comments on EISs available to the public. Accordingly, on March 31, 2010, EPA discontinued the publication of the notice of availability of EPA comments in the Federal Register. EIS No. 20100312, Draft EIS, NRC, TX, Comanche Peak Nuclear Power Plant Units 3 and 4, Application for Combined Licenses (COLs) for Construction Permits and Operating Licenses, (NUREG-1943), Hood and Somervell Counties, TX, Comment Period Ends: 10/26/2010.

  18. Test documentation for converting TWRS baseline data from RDD-100 V3.0.2.2 to V4.0.3. Revision 1

    SciTech Connect (OSTI)

    Gneiting, B.C.; Johnston, M.E.

    1996-05-03

    This document describes the test documentation required for converting between two versions of the RDD-100 software application, specifically version 3.0.2.2 and version 4.0.3. The area of focus in the successful conversion of the master data set between two versions of the database tool and their corresponding data structures.

  19. An in-situ phosphorus source for the synthesis of Cu3P and the subsequent conversion to Cu3PS4 nanoparticle clusters

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sheets, Erik J.; Stach, Eric A.; Yang, Wei -Chang; Balow, Robert B.; Wang, Yunjie; Walker, Bryce C.; Agrawal, Rakesh

    2015-09-20

    The search for alternative earth abundant semiconducting nanocrystals for sustainable energy applications has brought forth the need for nanoscale syntheses beyond bulk synthesis routes. Of particular interest are metal phosphides and derivative I-V-VI chalcogenides including copper phosphide (Cu3P) and copper thiophosphate (Cu3PS4). Herein, we report a one-pot, solution-based synthesis of Cu3P nanocrystals utilizing an in-situ phosphorus source: phosphorus pentasulfide (P2S5) in trioctylphosphine (TOP). By injecting this phosphorus source into a copper solution in oleylamine (OLA), uniform and size controlled Cu3P nanocrystals with a phosphorous-rich surface are synthesized. The subsequent reaction of the Cu3P nanocrystals with decomposing thiourea forms nanoscale Cu3PS4more » particles having p-type conductivity and an effective optical band gap of 2.36 eV.« less

  20. Fuel Cell Technologies Office Multi-Year Research, Development, and Demonstration Plan - 3.4 Fuel Cells

    Energy Savers [EERE]

    2 Technical Plan - Fuel Cells Multi-Year Research, Development and Demonstration Plan Page 3.4 - 1 3.4 Fuel Cells Fuel cells offer a highly efficient way to use diverse energy sources and, as a result, have demonstrated lower energy use and emissions when compared with conventional technologies. They also can be powered by emissions-free fuels that are produced from clean, domestic resources, helping to reduce the nation's dependence on imported petroleum. The largest markets for fuel cells

  1. Energy Forecasting Framework and Emissions Consensus Tool (EFFECT...

    Open Energy Info (EERE)

    Tool (EFFECT) EFFECT is an open, Excel-based modeling tool used to forecast greenhouse gas emissions from a range of development scenarios at the regional and national levels....

  2. Network Bandwidth Utilization Forecast Model on High Bandwidth Network

    SciTech Connect (OSTI)

    Yoo, Wucherl; Sim, Alex

    2014-07-07

    With the increasing number of geographically distributed scientific collaborations and the scale of the data size growth, it has become more challenging for users to achieve the best possible network performance on a shared network. We have developed a forecast model to predict expected bandwidth utilization for high-bandwidth wide area network. The forecast model can improve the efficiency of resource utilization and scheduling data movements on high-bandwidth network to accommodate ever increasing data volume for large-scale scientific data applications. Univariate model is developed with STL and ARIMA on SNMP path utilization data. Compared with traditional approach such as Box-Jenkins methodology, our forecast model reduces computation time by 83.2percent. It also shows resilience against abrupt network usage change. The accuracy of the forecast model is within the standard deviation of the monitored measurements.

  3. Solar Trackers Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    Solar Trackers Market Forecast Home John55364's picture Submitted by John55364(100) Contributor 12 May, 2015 - 03:54 Solar Trackers Market - Global Industry Analysis, Size, Share,...

  4. Forecasting Crude Oil Spot Price Using OECD Petroleum Inventory Levels

    Reports and Publications (EIA)

    2003-01-01

    This paper presents a short-term monthly forecasting model of West Texas Intermediate crude oil spot price using Organization for Economic Cooperation and Development (OECD) petroleum inventory levels.

  5. Value of Improved Short-Term Wind Power Forecasting

    SciTech Connect (OSTI)

    Hodge, B. M.; Florita, A.; Sharp, J.; Margulis, M.; Mcreavy, D.

    2015-02-01

    This report summarizes an assessment of improved short-term wind power forecasting in the California Independent System Operator (CAISO) market and provides a quantification of its potential value.

  6. Improving the Accuracy of Solar Forecasting Funding Opportunity

    Broader source: Energy.gov [DOE]

    Through the Improving the Accuracy ofSolar Forecasting Funding Opportunity,DOE is funding solar projects that are helping utilities, grid operators, solar power plant owners, and other...

  7. PBL FY 2002 Second Quarter Review Forecast of Generation Accumulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Slice true-ups, and actual expense levels. Any variation of these can change the net revenue situation. FY 2002 Forecasted Second Quarter Results 170 (418) FY 2002 Unaudited...

  8. World oil inventories forecast to grow significantly in 2016...

    U.S. Energy Information Administration (EIA) Indexed Site

    World oil inventories forecast to grow significantly in 2016 and 2017 Global oil inventories are expected to continue strong growth over the next two years which should keep oil ...

  9. Table 4.3 Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves, 1949-2010

    U.S. Energy Information Administration (EIA) Indexed Site

    Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves, 1949-2010 Year Crude Oil 1 Natural Gas (Dry) Natural Gas Liquids 1 Total Thousand Barrels Million Cubic Feet 2 Thousand Barrels COE 3 Thousand Barrels Thousand Barrels COE 3 Thousand Barrels COE 3 American Petroleum Institute and American Gas Association Data<//td> 1949 24,649,489 179,401,693 32,013,150 3,729,012 3,069,146 59,731,785 1950 25,268,398 184,584,745 32,938,034 4,267,663 3,495,219 61,701,652 1951 27,468,031

  10. Development and Demonstration of Advanced Forecasting, Power and Environmental Planning and Management Tools and Best Practices

    Broader source: Energy.gov [DOE]

    Development and Demonstration of Advanced Forecasting, Power and Environmental Planning and Management Tools and Best Practices

  11. D-B CONST Exhibit A General Conditions (Rev. 4.3, 9-27-13)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 9/27/13) Exhibit A General Conditions Page 1 of 29 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2 AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Apr 2013) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  12. Synthesis of polycrystalline Co{sub 3}O{sub 4} nanowires with excellent ammonium perchlorate catalytic decomposition property

    SciTech Connect (OSTI)

    Zhou, Hai; Lv, Baoliang; Wu, Dong; Xu, Yao

    2014-12-15

    Graphical abstract: Co{sub 3}O{sub 4} nanowires with excellent ammonium perchlorate catalytic decomposition property were synthesized via a methanamide-assisted hydrolysis and subsequent dissolution–recrystallization process in the presence of methanamide. - Abstract: Co{sub 3}O{sub 4} nanowires, with the length of tens of micrometers and the width of several hundred nanometers, were produced by a hydrothermal treatment and a post-anneal process. X-ray diffraction (XRD) result showed that the Co{sub 3}O{sub 4} nanowires belong to cubic crystal system. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analysis indicated that the Co{sub 3}O{sub 4} nanowires, composed by single crystalline nanoparticles, were of polycrystalline nature. On the basis of time-dependent experiments, methanamide-assisted hydrolysis and subsequent dissolution–recrystallization process were used to explain the precursors' formation process of the polycrystalline Co{sub 3}O{sub 4} nanowires. The TGA experiments showed that the as-obtained Co{sub 3}O{sub 4} nanowires can catalyze the thermal decomposition of ammonium perchlorate (AP) effectively.

  13. Alternative current conduction mechanisms of organic-inorganic compound [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4}

    SciTech Connect (OSTI)

    Ben Bechir, M. Karoui, K.; Guidara, K.; Ben Rhaiem, A.; Tabellout, M.

    2014-04-21

    [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} has been studied by X-ray powder diffraction patterns, differential scanning calorimetry (DSC), and impedance spectroscopy. The [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} hybrid compound is crystallized at room temperature (T ? 300?K) in the orthorhombic system with Pnma space group. Five phase transitions (T{sub 1}?=?255?K, T{sub 2}?=?282?K, T{sub 3}?=?302?K, T{sub 4}?=?320?K, and T{sub 5}?=?346?K) have been proved by DSC measurements. The electrical technique was measured in the 10{sup ?1}-10{sup 7}?Hz frequency range and 233363?K temperature interval. The frequency dependence of alternative current (AC) conductivity is interpreted in terms of Jonscher's law. The AC electrical conduction in [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} is analyzed by different processes, which can be attributed to several models: the correlated barrier hopping model in phase I, the overlapping large polaron tunneling model in phase II, the quantum mechanical tunneling model in phase IV, and the non-overlapping small polaron tunneling model in phases III, V, and VI. The conduction mechanism is studied with the help of Elliot's theory, and the Elliot's parameters are determined.

  14. 4-D stratigraphic architecture and 3-D reservoir zonation of the Mirado Formation, Cusiana Field, Colombia

    SciTech Connect (OSTI)

    Fajardo, A.A. ); Cross, T.A. )

    1996-01-01

    A high-resolution sequence stratigraphic study using 2300 feet of core calibrated with geophysical logs from 14 wells and 1800 measurements of porosity and permeability established the 4-D stratigraphy and 3-D reservoir zonation of the Mirador. Virtually all reservoir-quality facies are through cross-stratified sandstones which occur in channel facies successions in the lower Mirador, but in bay-head delta and estuarine channel facies successions in the upper Mirador. Petrophysical properties and the geometry, continuity and volume of reservoir-quality sandstones change regularly as function of their stratigraphic position. These vertical facies successions reflect increasing accommodation-to-sediment supply (A/S) ratio through each intermediate-term cycle. The upper long-term cycle comprises four intermediate-term, landward-stepping, symmetrical base-level cycles. These cycles consist of estuarine channel, bay-head to bay-fill facies successions. The transition from channel to bay-head to bay-fill facies successions represents an increase in A/S ratio, and the reverse transition indicates a decrease in A/S ratio. Sixteen reservoir zones were defined within the Cusiana field. Reservoirs within the upper and lower long-term cycles are separated by a continuous middle Mirador mudstone which creates two large reservoir divisions. At the second level of zonation, the reservoir compartments and fluid-flow retardants coincide with the intermediate-term stratigraphic cycles. A third level of reservoir compartmentalization follows the distribution of facies successions within the intermediate-term cycles. A strong stratigraphic control on reservoir properties occurs at the three scales of stratigraphic cyclicity. In all cases as A/S ratio increases, porosity and permeability decrease.

  15. 4-D stratigraphic architecture and 3-D reservoir zonation of the Mirado Formation, Cusiana Field, Colombia

    SciTech Connect (OSTI)

    Fajardo, A.A.; Cross, T.A.

    1996-12-31

    A high-resolution sequence stratigraphic study using 2300 feet of core calibrated with geophysical logs from 14 wells and 1800 measurements of porosity and permeability established the 4-D stratigraphy and 3-D reservoir zonation of the Mirador. Virtually all reservoir-quality facies are through cross-stratified sandstones which occur in channel facies successions in the lower Mirador, but in bay-head delta and estuarine channel facies successions in the upper Mirador. Petrophysical properties and the geometry, continuity and volume of reservoir-quality sandstones change regularly as function of their stratigraphic position. These vertical facies successions reflect increasing accommodation-to-sediment supply (A/S) ratio through each intermediate-term cycle. The upper long-term cycle comprises four intermediate-term, landward-stepping, symmetrical base-level cycles. These cycles consist of estuarine channel, bay-head to bay-fill facies successions. The transition from channel to bay-head to bay-fill facies successions represents an increase in A/S ratio, and the reverse transition indicates a decrease in A/S ratio. Sixteen reservoir zones were defined within the Cusiana field. Reservoirs within the upper and lower long-term cycles are separated by a continuous middle Mirador mudstone which creates two large reservoir divisions. At the second level of zonation, the reservoir compartments and fluid-flow retardants coincide with the intermediate-term stratigraphic cycles. A third level of reservoir compartmentalization follows the distribution of facies successions within the intermediate-term cycles. A strong stratigraphic control on reservoir properties occurs at the three scales of stratigraphic cyclicity. In all cases as A/S ratio increases, porosity and permeability decrease.

  16. Crude oil and alternate energy production forecasts for the twenty-first century: The end of the hydrocarbon era

    SciTech Connect (OSTI)

    Edwards, J.D.

    1997-08-01

    Predictions of production rates and ultimate recovery of crude oil are needed for intelligent planning and timely action to ensure the continuous flow of energy required by the world`s increasing population and expanding economies. Crude oil will be able to supply increasing demand until peak world production is reached. The energy gap caused by declining conventional oil production must then be filled by expanding production of coal, heavy oil and oil shales, nuclear and hydroelectric power, and renewable energy sources (solar, wind, and geothermal). Declining oil production forecasts are based on current estimated ultimate recoverable conventional crude oil resources of 329 billion barrels for the United States and close to 3 trillion barrels for the world. Peak world crude oil production is forecast to occur in 2020 at 90 million barrels per day. Conventional crude oil production in the United States is forecast to terminate by about 2090, and world production will be close to exhaustion by 2100.

  17. Study forecasts disappearance of conifers due to climate change

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study forecasts disappearance of conifers due to climate change Study forecasts disappearance of conifers due to climate change New results, reported in a paper released today in the journal Nature Climate Change, suggest that global models may underestimate predictions of forest death. December 21, 2015 Los Alamos scientist Nate McDowell discusses how climate change is killing trees with PBS NewsHour reporter Miles O'Brien. Los Alamos scientist Nate McDowell discusses how climate change is

  18. Forecasting neutrino masses from combining KATRIN and the CMB observations:

    Office of Scientific and Technical Information (OSTI)

    Frequentist and Bayesian analyses (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Forecasting neutrino masses from combining KATRIN and the CMB observations: Frequentist and Bayesian analyses Citation Details In-Document Search Title: Forecasting neutrino masses from combining KATRIN and the CMB observations: Frequentist and Bayesian analyses We present a showcase for deriving bounds on the neutrino masses from laboratory experiments and cosmological

  19. Energy Department Forecasts Geothermal Achievements in 2015 | Department of

    Office of Environmental Management (EM)

    Energy Forecasts Geothermal Achievements in 2015 Energy Department Forecasts Geothermal Achievements in 2015 The 40th annual Stanford Geothermal Workshop in January featured speakers in the geothermal sector, including Jay Nathwani, Acting Director of the Energy Department's Geothermal Technologies Office. Nathwani shared achievements and challenges in the program's technical portfolio. The 40th annual Stanford Geothermal Workshop in January featured speakers in the geothermal sector,

  20. Expert Panel: Forecast Future Demand for Medical Isotopes | Department of

    Office of Environmental Management (EM)

    Energy Expert Panel: Forecast Future Demand for Medical Isotopes Expert Panel: Forecast Future Demand for Medical Isotopes The Expert Panel has concluded that the Department of Energy and National Institutes of Health must develop the capability to produce a diverse supply of radioisotopes for medical use in quantities sufficient to support research and clinical activities. Such a capability would prevent shortages of isotopes, reduce American dependence on foreign radionuclide sources and

  1. Synthesis and luminescent properties of spindle-like CaWO{sub 4}:Sm{sup 3+} phosphors

    SciTech Connect (OSTI)

    Tian, Yue [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China) [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Liu, Yu [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, Liaoning 116024 (China)] [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian, Liaoning 116024 (China); Hua, Ruinian, E-mail: rnhua@dlnu.edu.cn [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China)] [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Na, Liyan [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China)] [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Chen, Baojiu, E-mail: chenmbj@sohu.com [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)] [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)

    2012-01-15

    Graphical abstract: In this paper, spindle-like CaWO{sub 4}:Sm{sup 3+} phosphors were prepared via a polyvinylpyrrolidone (PVP)-assisted sonochemical process. Dependence of emission intensity on Sm{sup 3+} ions concentration in the CaWO{sub 4}:Sm{sup 3+} phosphor were also calculated via a nonlinear fitting by using the formula y = ax/(1 + bx{sup c}). Highlights: Black-Right-Pointing-Pointer The samples were prepared via a PVP assisted sonochemical process. Black-Right-Pointing-Pointer The color coordinates for 1 mol% Sm{sup 3+} doped CaWO{sub 4} phosphor were calculated. Black-Right-Pointing-Pointer The D-D interaction is responsible for concentration quenching between Sm{sup 3+} ions. Black-Right-Pointing-Pointer The critical energy transfer distances (R{sub c}) were obtained. -- Abstract: Spindle-like CaWO{sub 4}:Sm{sup 3+} phosphors were prepared via a Polyvinylpyrrolidone (PVP)-assisted sonochemical process, and characterized by using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and photoluminescence spectroscopy (PL). The XRD results suggested that the prepared samples are single-phase. The FE-SEM images indicated that the prepared CaWO{sub 4}:Sm{sup 3+} phosphors are composed of many spindles with maximum average diameter of 150 nm and maximum average length of 500 nm. Under 404 nm excitation, the characteristic emissions corresponding to {sup 4}G{sub 5/2} {yields} {sup 6}H{sub J} (J = 5/2, 7/2, 9/2 and 11/2) transitions of Sm{sup 3+} in CaWO{sub 4} phosphors were observed. The color coordinates for 1 mol% Sm{sup 3+} doped CaWO{sub 4} phosphor were calculated to be (0.595, 0.404). The fluorescent concentration quenching of Sm{sup 3+} doped spindle-like phosphors was studied based on the Van Uitert's model, and it was found that the electric dipole-dipole (D-D) interaction is the dominant energy transfer mechanism between Sm{sup 3+} ions in the CaWO{sub 4}:Sm{sup 3+} phosphors. The critical energy transfer distance was estimated.

  2. Wind Energy Forecasting: A Collaboration of the National Center for Atmospheric Research (NCAR) and Xcel Energy

    SciTech Connect (OSTI)

    Parks, K.; Wan, Y. H.; Wiener, G.; Liu, Y.

    2011-10-01

    The focus of this report is the wind forecasting system developed during this contract period with results of performance through the end of 2010. The report is intentionally high-level, with technical details disseminated at various conferences and academic papers. At the end of 2010, Xcel Energy managed the output of 3372 megawatts of installed wind energy. The wind plants span three operating companies1, serving customers in eight states2, and three market structures3. The great majority of the wind energy is contracted through power purchase agreements (PPAs). The remainder is utility owned, Qualifying Facilities (QF), distributed resources (i.e., 'behind the meter'), or merchant entities within Xcel Energy's Balancing Authority footprints. Regardless of the contractual or ownership arrangements, the output of the wind energy is balanced by Xcel Energy's generation resources that include fossil, nuclear, and hydro based facilities that are owned or contracted via PPAs. These facilities are committed and dispatched or bid into day-ahead and real-time markets by Xcel Energy's Commercial Operations department. Wind energy complicates the short and long-term planning goals of least-cost, reliable operations. Due to the uncertainty of wind energy production, inherent suboptimal commitment and dispatch associated with imperfect wind forecasts drives up costs. For example, a gas combined cycle unit may be turned on, or committed, in anticipation of low winds. The reality is winds stayed high, forcing this unit and others to run, or be dispatched, to sub-optimal loading positions. In addition, commitment decisions are frequently irreversible due to minimum up and down time constraints. That is, a dispatcher lives with inefficient decisions made in prior periods. In general, uncertainty contributes to conservative operations - committing more units and keeping them on longer than may have been necessary for purposes of maintaining reliability. The downside is costs are higher. In organized electricity markets, units that are committed for reliability reasons are paid their offer price even when prevailing market prices are lower. Often, these uplift charges are allocated to market participants that caused the inefficient dispatch in the first place. Thus, wind energy facilities are burdened with their share of costs proportional to their forecast errors. For Xcel Energy, wind energy uncertainty costs manifest depending on specific market structures. In the Public Service of Colorado (PSCo), inefficient commitment and dispatch caused by wind uncertainty increases fuel costs. Wind resources participating in the Midwest Independent System Operator (MISO) footprint make substantial payments in the real-time markets to true-up their day-ahead positions and are additionally burdened with deviation charges called a Revenue Sufficiency Guarantee (RSG) to cover out of market costs associated with operations. Southwest Public Service (SPS) wind plants cause both commitment inefficiencies and are charged Southwest Power Pool (SPP) imbalance payments due to wind uncertainty and variability. Wind energy forecasting helps mitigate these costs. Wind integration studies for the PSCo and Northern States Power (NSP) operating companies have projected increasing costs as more wind is installed on the system due to forecast error. It follows that reducing forecast error would reduce these costs. This is echoed by large scale studies in neighboring regions and states that have recommended adoption of state-of-the-art wind forecasting tools in day-ahead and real-time planning and operations. Further, Xcel Energy concluded reduction of the normalized mean absolute error by one percent would have reduced costs in 2008 by over $1 million annually in PSCo alone. The value of reducing forecast error prompted Xcel Energy to make substantial investments in wind energy forecasting research and development.

  3. Synthesis and crystal structure of a new open-framework iron phosphate (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}]: Novel linear trimer of corner-sharing Fe(III) octahedra

    SciTech Connect (OSTI)

    Mi, Jin-Xiao; Wang, Cheng-Xin; Chen, Ning; Li, Rong; Pan, Yuanming

    2010-12-15

    A new iron phosphate (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}] has been synthesized hydrothermally at HF concentrations from 0.5 to 1.2 mL. Single-crystal X-ray diffraction analysis reveals its three-dimensional open-framework structure (monoclinic, space group P2{sub 1}/n (No. 14), a=6.2614(13) A, b=9.844(2) A, c=14.271(3) A, {beta}=92.11(1){sup o}, V=879.0(3) A{sup 3}). This structure is built from isolated linear trimers of corner-sharing Fe(III) octahedra, which are linked by (PO{sub 4}) groups to form ten-membered-ring channels along [1 0 0]. This isolated, linear trimer of corner-sharing Fe(III) octahedra, [(FeO{sub 4}){sub 3}(OH){sub 2}F{sub 2}], is new and adds to the diverse linkages of Fe polyhedra as secondary building units in iron phosphates. The trivalent iron at octahedral sites for the title compound has been confirmed by synchrotron Fe K-edge XANES spectra and magnetic measurements. Magnetic measurements also show that this compound exhibit a strong antiferromagnetic exchange below T{sub N}=17 K, consistent with superexchange interactions expected for the linear trimer of ferric octahedra with the Fe-F-Fe angle of 132.5{sup o}. -- Graphical abstract: The three-dimensional open-framework structure of (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}] is built from a novel isolated, linear (FeO{sub 4}){sub 3}(OH){sub 2}F{sub 2} trimer of corner-sharing Fe(III) octahedra linked by PO{sub 4} tetrahedra. Display Omitted

  4. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect (OSTI)

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  5. Increasing biogas yield of rural biogas digester by addition of NH/sub 4/HCO/sub 3/

    SciTech Connect (OSTI)

    Sun, G.C.; Chen, G.Q.; Chen, M.; Liu, K.X.; Zhou, S.Y.

    1983-12-01

    By addition of 0.3% NH/sub 4/HCO/sub 3/ instead of animal manure into rural biogas digester in which the rotted rice straw was the major feedstock, the biogas yield doubled in comparison with the check digester (0.1 m/sup 3//m/sup 3//d) and the fertility of NH/sub 4/HCO/sub 3/ did not decrease because of biogas fermentation. Many digesters have been built in China. But, owing to the problems of improper management, unsuitable influent mixing, etc., neither digesters nor feedstock were fully utilized. In order to solve these problems, adding NH/sub 4/HCO/sub 3/ into digester instead of animal manure was tried. Its results showed that the suitable C/N ratio of influent mixing was obtained, the fertility of effluent went up, and biogas producing rate increased. The concentration of NH/sub 4/HCO/sub 3/ is 0.2-0.6%, but the optimal is 0.3%.

  6. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Hui; Yu, Xiqian; Bai, Ying; Wu, Feng; Wu, Chuan; Liu, Liang-Yu; Yang, Xiao-Qing

    2015-01-01

    Na3V2-xMgx(PO4)3/C composites with different Mg2+ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg2+ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na3V2-xMgx(PO4)3/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na3V1.95Mg0.05(PO4)3/C. For example, when the current density increased from 1 C to 30 C, the specific capacitymore » only decreased from 112.5 mAh g-1 to 94.2 mAh g-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh g-1 to 86.2 mAh g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.« less

  7. Spin orientations of the spin-half Ir4+ ions in Sr3NiIrO6, Sr2IrO4 and Na2IrO3: Density functional, perturbation theory and Madelung potential analyses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gordon, Elijah E.; Xiang, Hongjun; Koehler, Jurgen; Whangbo, Myung -Hwan

    2016-03-01

    The spins of the low-spin Ir4+ (S = 1/2, d5) ions at the octahedral sites of the oxides Sr3NiIrO6, Sr2IrO4 and Na2IrO3 exhibit preferred orientations with respect to their IrO6 octahedra. We evaluated the magnetic anisotropies of these S = 1/2 ions on the basis of DFT calculations including spin-orbit coupling (SOC), and probed their origin by performing perturbation theory analyses with SOC as perturbation within the LS coupling scheme. The observed spin orientations of Sr3NiIrO6 and Sr2IrO4 are correctly predicted by DFT calculations, and are accounted for by the perturbation theory analysis. As for the spin orientation of Na2IrO3,more » both experimental studies and DFT calculations have not been unequivocal. Our analysis reveals that the Ir4+ spin orientation of Na2IrO3 should have nonzero components along the c- and a-axes directions. The spin orientations determined by DFT calculations are sensitive to the accuracy of the crystal structures employed, which is explained by perturbation theory analyses when interactions between adjacent Ir4+ ions are taken into consideration. There are indications implying that the 5d electrons of Na2IrO3 are less strongly localized compared with those of Sr3NiIrO6 and Sr2IrO4. This implication was confirmed by showing that the Madelung potentials of the Ir4+ ions are less negative in Na2IrO3 than in Sr3NiIrO6, Sr2IrO4. Most transition-metal S = 1/2 ions do have magnetic anisotropies because the SOC induces interactions among their crystal-field split d-states, and the associated mixing of the states modifies only the orbital parts of the states. This finding cannot be mimicked by a spin Hamiltonian because this model Hamiltonian lacks the orbital degree of freedom, thereby leading to the spin-half syndrome. As a result, the spin-orbital entanglement for the 5d spin-half ions Ir4+ is not as strong as has been assumed lately.« less

  8. Exchange bias effect in Au-Fe3O4 dumbbell nanoparticles induced by the charge transfer from gold

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feygenson, Mikhail; Bauer, John C; Gai, Zheng; Marques, Carlos; Aronson, Meigan C.; Teng, Xiaowei; Su, Dong; Stanic, Vesna; Urban, Volker S; Kevin, Beyer; et al

    2015-08-10

    We have studied the origin of the exchange bias effect in the Au-Fe3O4 dumbbell nanoparticles in two samples with different sizes of the Au seed nanoparticles (4.1 and 2.7 nm) and same size of Fe3O4 nanoparticles (9.8 nm). The magnetization, small-angle neutron scattering, synchrotron x-ray diffraction and scanning transmission electron microscope measurements determined the antiferromagnetic FeO wüstite phase within Fe3O4 nanoparticles, originating at the interface with the Au nanoparticles. The interface between antiferromagnetic FeO and ferrimagnetic Fe3O4 is giving rise to the exchange bias effect. The strength of the exchange bias fields depends on the interfacial area and lattice mismatchmore » between both phases. We propose that the charge transfer from the Au nanoparticles is responsible for a partial reduction of the Fe3O4 into FeO phase at the interface with Au nanoparticles. The Au-O bonds are formed across the interface to accommodate an excess of oxygen released during the reduction of magnetite.« less

  9. " East North Central",21.3,"NA",26,27.6,29,32.4

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Vehicles, Selected Survey Years (Millions)" ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",129.3,137.3,147.5,151.2,156.8,191 "Household Characteristics" "Census...

  10. National Oceanic and Atmospheric Administration Provides Forecasting Support for CLASIC and CHAPS 2007

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NOAA Provides Forecasting Support for CLASIC and CHAPS 2007 Forecasting Challenge While weather experiments in the heart of Tornado Alley typically focus on severe weather, the CLASIC and CHAPS programs will have different emphases. Forecasters from the National Oceanic and Atmospheric Administration in Norman, Okla. will provide weather forecasting support to these two Department of Energy experiments based in the state. Forecasting support for meteorological research field programs usually

  11. Process for manufacturing bis(2-methoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracene

    SciTech Connect (OSTI)

    Rasmussen, Paul George; Lawton, Richard Graham

    2014-06-03

    A process to manufacture substituted tetracyano-hexaazatricyclics with the substitutions occurring at the 9 and 10 hydrogens. The process begins with 2,3-dichloro-5,6-dicyanopyrazine, which is reacted to form the desired tetracyano-hexaazatricyclic. Different process embodiments enable different reaction paths to the desired tetracyano-hexaazatricyclic. Different tetracyano-hexaazatricyclic embodiments include bis(2-methoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracene and bis(2-methoxyethoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracen- e.

  12. Being WISE. I. Validating stellar population models and M {sub *}/L ratios at 3.4 and 4.6 ?m

    SciTech Connect (OSTI)

    Norris, Mark A.; Meidt, Sharon; Van de Ven, Glenn; Schinnerer, Eva; Groves, Brent; Querejeta, Miguel

    2014-12-10

    Using data from the Wide-field Infrared Survey Explorer mission, we have measured near infra-red (NIR) photometry of a diverse sample of dust-free stellar systems (globular clusters, dwarf and giant early-type galaxies) which have metallicities that span the range -2.2 < [Fe/H] (dex) < 0.3. This dramatically increases the sample size and broadens the metallicity regime over which the 3.4 (W1) and 4.6 ?m (W2) photometry of stellar populations have been examined. We find that the W1 W2 colors of intermediate and old (>2 Gyr) stellar populations are insensitive to the age of the stellar population, but that the W1 W2 colors become bluer with increasing metallicity, a trend not well reproduced by most stellar population synthesis (SPS) models. In common with previous studies, we attribute this behavior to the increasing strength of the CO absorption feature located in the 4.6 ?m bandpass with metallicity. Having used our sample to validate the efficacy of some of the SPS models, we use these models to derive stellar mass-to-light ratios in the W1 and W2 bands. Utilizing observational data from the SAURON and ATLAS3D surveys, we demonstrate that these bands provide extremely simple, yet robust stellar mass tracers for dust free older stellar populations that are freed from many of the uncertainties common among optical estimators.

  13. AGR-2 AND AGR-3/4 RELEASE-TO-BIRTH RATIO DATA ANALYSIS

    SciTech Connect (OSTI)

    Pham, Binh T; Einerson, Jeffrey J; Scates, Dawn M; Maki, John T; Petti, David A

    2014-09-01

    A series of Advanced Gas Reactor (AGR) irradiation tests is being conducted in the Advanced Test Reactor at Idaho National Laboratory in support of development and qualification of tristructural isotropic (TRISO) low enriched fuel used in the High Temperature Gas-cooled Reactor (HTGR). Each AGR test consists of multiple independently controlled and monitored capsules containing fuel compacts placed in a graphite cylinder shrouded by a steel shell. These capsules are instrumented with thermocouples embedded in the graphite enabling temperature control. AGR configuration and irradiation conditions are based on prismatic HTGR technology distinguished primarily by the use of helium coolant, a low-power-density ceramic core capable of withstanding very high temperatures, and TRISO coated particle fuel. Thus, these tests provide valuable irradiation performance data to support fuel process development, qualify fuel for normal operating conditions, and support development and validation of fuel performance and fission product transport models and codes. The release-rate-to-birth-rate ratio (R/B) for each of fission product isotopes (i.e., krypton and xenon) is calculated from release rates in the sweep gas flow measured by the germanium detectors used in the AGR Fission Product Monitoring (FPM) System installed downstream from each irradiated capsule. Birth rates are calculated based on the fission power in the experiment and fission product generation models. Thus, this R/B is a measure of the ability of fuel kernel, particle coating layers, and compact matrix to retain fission gas atoms preventing their release into the sweep gas flow, especially in the event of particle coating failures that occurred during AGR-2 and AGR-3/4 irradiations. The major factors that govern gaseous radioactive decay, diffusion, and release processes are found to be material diffusion coefficient, temperature, and isotopic decay constant. For each of all AGR capsules, ABAQUS-based three-dimensional finite-element thermal models are created to predict daily averages of fuel compact temperatures for the entire irradiation period, which are used in establishing the R/B correlation with temperature and decay constant. This correlation can be used by reactor designers to estimate fission gas release from postulated failed fuel particles in HTGR cores, which is the key safety factor for fuel performance assessment.

  14. User Guide for VISION 3.4.7 (Verifiable Fuel Cycle Simulation) Model

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Robert F. Jeffers; Gretchen E. Matthern; Steven J. Piet; Wendell D. Hintze

    2011-07-01

    The purpose of this document is to provide a guide for using the current version of the Verifiable Fuel Cycle Simulation (VISION) model. This is a complex model with many parameters and options; the user is strongly encouraged to read this user guide before attempting to run the model. This model is an R&D work in progress and may contain errors and omissions. It is based upon numerous assumptions. This model is intended to assist in evaluating 'what if' scenarios and in comparing fuel, reactor, and fuel processing alternatives at a systems level. The model is not intended as a tool for process flow and design modeling of specific facilities nor for tracking individual units of fuel or other material through the system. The model is intended to examine the interactions among the components of a fuel system as a function of time varying system parameters; this model represents a dynamic rather than steady-state approximation of the nuclear fuel system. VISION models the nuclear cycle at the system level, not individual facilities, e.g., 'reactor types' not individual reactors and 'separation types' not individual separation plants. Natural uranium can be enriched, which produces enriched uranium, which goes into fuel fabrication, and depleted uranium (DU), which goes into storage. Fuel is transformed (transmuted) in reactors and then goes into a storage buffer. Used fuel can be pulled from storage into either separation or disposal. If sent to separations, fuel is transformed (partitioned) into fuel products, recovered uranium, and various categories of waste. Recycled material is stored until used by its assigned reactor type. VISION is comprised of several Microsoft Excel input files, a Powersim Studio core, and several Microsoft Excel output files. All must be co-located in the same folder on a PC to function. You must use Powersim Studio 8 or better. We have tested VISION with the Studio 8 Expert, Executive, and Education versions. The Expert and Education versions work with the number of reactor types of 3 or less. For more reactor types, the Executive version is currently required. The input files are Excel2003 format (xls). The output files are macro-enabled Excel2007 format (xlsm). VISION 3.4 was designed with more flexibility than previous versions, which were structured for only three reactor types - LWRs that can use only uranium oxide (UOX) fuel, LWRs that can use multiple fuel types (LWR MF), and fast reactors. One could not have, for example, two types of fast reactors concurrently. The new version allows 10 reactor types and any user-defined uranium-plutonium fuel is allowed. (Thorium-based fuels can be input but several features of the model would not work.) The user identifies (by year) the primary fuel to be used for each reactor type. The user can identify for each primary fuel a contingent fuel to use if the primary fuel is not available, e.g., a reactor designated as using mixed oxide fuel (MOX) would have UOX as the contingent fuel. Another example is that a fast reactor using recycled transuranic (TRU) material can be designated as either having or not having appropriately enriched uranium oxide as a contingent fuel. Because of the need to study evolution in recycling and separation strategies, the user can now select the recycling strategy and separation technology, by year.

  15. Alternative current conduction mechanisms of organic-inorganic compound [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4}

    SciTech Connect (OSTI)

    Ben Bechir, M. Karoui, K.; Guidara, K.; Ben Rhaiem, A.; Tabellout, M.

    2014-05-28

    The [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} single crystal has been analyzed by X-ray powder diffraction patterns, differential scanning calorimetry (DSC), and electrical impedance spectroscopy. [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} crystallizes at room temperature in the monoclinic system with P2{sub 1}/{sub C} space group. Three phase transitions at T{sub 1}?=?226?K, T{sub 2}?=?264?K, and T{sub 3}?=?297?K have been evidenced by DSC measurements. The electrical technique was measured in the 10{sup ?1}10{sup 7}?Hz frequency range and 203313?K temperature intervals. The frequency dependence of alternative current (AC) conductivity is interpreted in terms of Jonscher's law (developed). The AC electrical conduction in [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} compound is studied by two processes which can be attributed to a hopping transport mechanism: the correlated barrier hopping model in phases I, II, and III, the non-overlapping small polaron tunneling model in phase IV. The conduction mechanism is interpreted with the help of Elliot's theory, and the Elliot's parameters are found.

  16. AVLIS: a technical and economic forecast

    SciTech Connect (OSTI)

    Davis, J.I.; Spaeth, M.L.

    1986-01-01

    The AVLIS process has intrinsically large isotopic selectivity and hence high separative capacity per module. The critical components essential to achieving the high production rates represent a small fraction (approx.10%) of the total capital cost of a production facility, and the reference production designs are based on frequent replacement of these components. The specifications for replacement frequencies in a plant are conservative with respect to our expectations; it is reasonable to expect that, as the plant is operated, the specifications will be exceeded and production costs will continue to fall. Major improvements in separator production rates and laser system efficiencies (approx.power) are expected to occur as a natural evolution in component improvements. With respect to the reference design, such improvements have only marginal economic value, but given the exigencies of moving from engineering demonstration to production operations, we continue to pursue these improvements in order to offset any unforeseen cost increases. Thus, our technical and economic forecasts for the AVLIS process remain very positive. The near-term challenge is to obtain stable funding and a commitment to bring the process to full production conditions within the next five years. If the funding and commitment are not maintained, the team will disperse and the know-how will be lost before it can be translated into production operations. The motivation to preserve the option for low-cost AVLIS SWU production is integrally tied to the motivation to maintain a competitive nuclear option. The US industry can certainly survive without AVLIS, but our tradition as technology leader in the industry will certainly be lost.

  17. Communication: Imaging the effects of the antisymmetric-stretching excitation in the O({sup 3}P) + CH{sub 4}(v{sub 3} = 1) reaction

    SciTech Connect (OSTI)

    Pan, Huilin [Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan (China) [Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan (China); State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Liu, Kopin, E-mail: kliu@po.iams.sinica.edu.tw [Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan (China)] [Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P. O. Box 23-166, Taipei 10617, Taiwan (China)

    2014-05-21

    Effects of one-quantum excitation of the antisymmetric-stretching mode of CH{sub 4}(v{sub 3} = 1) on the O({sup 3}P) + CH{sub 4} reaction were studied in a crossed-beam, ion-imaging experiment. In the post-threshold region, we found that (1) the product state distributions are dominated by the CH{sub 3}(0{sub 0}) + OH(v{sup ?} = 1) pair, (2) the product angular distributions extend toward sideways from the backward dominance of the ground-state reaction, and (3) vibrational excitation exerts a positive effect on reactivity, but translational energy is more efficient in promoting the rate of this central-barrier reaction. All major findings agree reasonably well with recent theoretical results. Some remaining questions are pointed out.

  18. Crystal structure of 1-methyl-3-([2,2-dimethyl-4,6-dioxo-1,3-dioxane-5-ylidene]methyl)urea

    SciTech Connect (OSTI)

    Habibi, A. Ghorbani, H. S.; Bruno, G.; Rudbari, H. A.; Valizadeh, Y.

    2013-12-15

    The crystal structure of 1-Methyl-3-([2,2-dimethyl-4,6-dioxo-1,3-dioxane-5-ylidene]methyl)urea (C{sub 9}H{sub 12}N{sub 2}O{sub 5}) has been determined by single crystal X-ray diffraction analysis. The crystals are monoclinic, a = 5.3179(2), b = 18.6394(6), c =10.8124(3) , ? = 100.015(2), Z = 4, sp. gr. P2{sub 1}/c, R = 0.0381 for 2537 reflections with I > 2?(I). Except for C(CH{sub 3}){sub 2} group, the molecule is planar. The structure is stabilized by inter- and intramolecular N-H...O hydrogen bonds and weak C-H...O interactions.

  19. SU-E-J-01: 3D Fluoroscopic Image Estimation From Patient-Specific 4DCBCT-Based Motion Models

    SciTech Connect (OSTI)

    Dhou, S; Hurwitz, M; Lewis, J; Mishra, P

    2014-06-01

    Purpose: 3D motion modeling derived from 4DCT images, taken days or weeks before treatment, cannot reliably represent patient anatomy on the day of treatment. We develop a method to generate motion models based on 4DCBCT acquired at the time of treatment, and apply the model to estimate 3D time-varying images (referred to as 3D fluoroscopic images). Methods: Motion models are derived through deformable registration between each 4DCBCT phase, and principal component analysis (PCA) on the resulting displacement vector fields. 3D fluoroscopic images are estimated based on cone-beam projections simulating kV treatment imaging. PCA coefficients are optimized iteratively through comparison of these cone-beam projections and projections estimated based on the motion model. Digital phantoms reproducing ten patient motion trajectories, and a physical phantom with regular and irregular motion derived from measured patient trajectories, are used to evaluate the method in terms of tumor localization, and the global voxel intensity difference compared to ground truth. Results: Experiments included: 1) assuming no anatomic or positioning changes between 4DCT and treatment time; and 2) simulating positioning and tumor baseline shifts at the time of treatment compared to 4DCT acquisition. 4DCBCT were reconstructed from the anatomy as seen at treatment time. In case 1) the tumor localization error and the intensity differences in ten patient were smaller using 4DCT-based motion model, possible due to superior image quality. In case 2) the tumor localization error and intensity differences were 2.85 and 0.15 respectively, using 4DCT-based motion models, and 1.17 and 0.10 using 4DCBCT-based models. 4DCBCT performed better due to its ability to reproduce daily anatomical changes. Conclusion: The study showed an advantage of 4DCBCT-based motion models in the context of 3D fluoroscopic images estimation. Positioning and tumor baseline shift uncertainties were mitigated by the 4DCBCT-based motion models, while they caused errors when using 4DCT-based motion models. Partially funded by Varian research grant.

  20. Down-regulation of p-coumaroyl quinate/shikimate 3'-hydroxylase (C3'H) and cinnamate 4-hydroxylase (C4H) genes in the lignin biosynthetic pathway of Eucalyptus urophylla x E. grandis leads to improved sugar release

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sykes, Robert W.; Gjersing, Erica L.; Foutz, Kirk; Rottmann, William H.; Kuhn, Sean A.; Foster, Cliff E.; Ziebell, Angela; Turner, Geoffrey B.; Decker, Stephen R.; Hinchee, Maud A. W.; et al

    2015-08-27

    In this study, lignocellulosic materials provide an attractive replacement for food-based crops used to produce ethanol. Understanding the interactions within the cell wall is vital to overcome the highly recalcitrant nature of biomass. One factor imparting plant cell wall recalcitrance is lignin, which can be manipulated by making changes in the lignin biosynthetic pathway. In this study, eucalyptus down-regulated in expression of cinnamate 4-hydroxylase (C4H, EC 1.14.13.11) or p-coumaroyl quinate/shikimate 3'-hydroxylase (C3'H, EC 1.14.13.36) were evaluated for cell wall composition and reduced recalcitrance.

  1. Comparison of AEO 2006 Natural Gas Price Forecast to NYMEX FuturesPrices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan

    2005-12-19

    On December 12, 2005, the reference case projections from ''Annual Energy Outlook 2006'' (AEO 2006) were posted on the Energy Information Administration's (EIA) web site. We at LBNL have in the past compared the EIA's reference case long-term natural gas price forecasts from the AEO series to contemporaneous natural gas prices that can be locked in through the forward market, with the goal of better understanding fuel price risk and the role that renewables play in mitigating such risk (see, for example, http://eetd.lbl.gov/ea/EMS/reports/53587.pdf or http://eetd.lbl.gov/ea/ems/reports/54751.pdf). As such, we were curious to see how the latest AEO gas price forecast compares to the NYMEX natural gas futures strip. This brief memo presents our findings. As a refresher, our past work in this area has found that over the past five years, forward natural gas contracts (with prices that can be locked in--e.g., gas futures, swaps, and physical supply) have traded at a premium relative to contemporaneous long-term reference case gas price forecasts from the EIA. As such, we have concluded that, over the past five years at least, levelized cost comparisons of fixed-price renewable generation with variable price gas-fired generation that have been based on AEO natural gas price forecasts (rather than forward prices) have yielded results that are ''biased'' in favor of gas-fired generation, presuming that long-term price stability is valued. In this memo we simply update our past analysis to include the latest long-term gas price forecast from the EIA, as contained in AEO 2006. For the sake of brevity, we do not rehash information (on methodology, potential explanations for the premiums, etc.) contained in our earlier reports on this topic; readers interested in such information are encouraged to download that work from http://eetd.lbl.gov/ea/EMS/reports/53587.pdf or http://eetd.lbl.gov/ea/ems/reports/54751.pdf. As was the case in the past five AEO releases (AEO 2001-AEO 2005), we once again find that the AEO 2006 reference case gas price forecast falls well below where NYMEX natural gas futures contracts were trading at the time the EIA finalized its gas price forecast. In fact, the NYMEX-AEO 2006 reference case comparison yields by far the largest premium--$2.3/MMBtu levelized over five years--that we have seen over the last six years. In other words, on average, one would have had to pay $2.3/MMBtu more than the AEO 2006 reference case natural gas price forecast in order to lock in natural gas prices over the coming five years and thereby replicate the price stability provided intrinsically by fixed-price renewable generation (or other forms of generation whose costs are not tied to the price of natural gas). Fixed-price generation (like certain forms of renewable generation) obviously need not bear this added cost, and moreover can provide price stability for terms well in excess of five years.

  2. Forecasting the 2013–2014 influenza season using Wikipedia

    SciTech Connect (OSTI)

    Hickmann, Kyle S.; Fairchild, Geoffrey; Priedhorsky, Reid; Generous, Nicholas; Hyman, James M.; Deshpande, Alina; Del Valle, Sara Y.; Salathé, Marcel

    2015-05-14

    Infectious diseases are one of the leading causes of morbidity and mortality around the world; thus, forecasting their impact is crucial for planning an effective response strategy. According to the Centers for Disease Control and Prevention (CDC), seasonal influenza affects 5% to 20% of the U.S. population and causes major economic impacts resulting from hospitalization and absenteeism. Understanding influenza dynamics and forecasting its impact is fundamental for developing prevention and mitigation strategies. We combine modern data assimilation methods with Wikipedia access logs and CDC influenza-like illness (ILI) reports to create a weekly forecast for seasonal influenza. The methods are applied to the 2013-2014 influenza season but are sufficiently general to forecast any disease outbreak, given incidence or case count data. We adjust the initialization and parametrization of a disease model and show that this allows us to determine systematic model bias. In addition, we provide a way to determine where the model diverges from observation and evaluate forecast accuracy. Wikipedia article access logs are shown to be highly correlated with historical ILI records and allow for accurate prediction of ILI data several weeks before it becomes available. The results show that prior to the peak of the flu season, our forecasting method produced 50% and 95% credible intervals for the 2013-2014 ILI observations that contained the actual observations for most weeks in the forecast. However, since our model does not account for re-infection or multiple strains of influenza, the tail of the epidemic is not predicted well after the peak of flu season has passed.

  3. Forecasting the 2013–2014 influenza season using Wikipedia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hickmann, Kyle S.; Fairchild, Geoffrey; Priedhorsky, Reid; Generous, Nicholas; Hyman, James M.; Deshpande, Alina; Del Valle, Sara Y.; Salathé, Marcel

    2015-05-14

    Infectious diseases are one of the leading causes of morbidity and mortality around the world; thus, forecasting their impact is crucial for planning an effective response strategy. According to the Centers for Disease Control and Prevention (CDC), seasonal influenza affects 5% to 20% of the U.S. population and causes major economic impacts resulting from hospitalization and absenteeism. Understanding influenza dynamics and forecasting its impact is fundamental for developing prevention and mitigation strategies. We combine modern data assimilation methods with Wikipedia access logs and CDC influenza-like illness (ILI) reports to create a weekly forecast for seasonal influenza. The methods are appliedmore » to the 2013-2014 influenza season but are sufficiently general to forecast any disease outbreak, given incidence or case count data. We adjust the initialization and parametrization of a disease model and show that this allows us to determine systematic model bias. In addition, we provide a way to determine where the model diverges from observation and evaluate forecast accuracy. Wikipedia article access logs are shown to be highly correlated with historical ILI records and allow for accurate prediction of ILI data several weeks before it becomes available. The results show that prior to the peak of the flu season, our forecasting method produced 50% and 95% credible intervals for the 2013-2014 ILI observations that contained the actual observations for most weeks in the forecast. However, since our model does not account for re-infection or multiple strains of influenza, the tail of the epidemic is not predicted well after the peak of flu season has passed.« less

  4. Forecasting the Magnitude of Sustainable Biofeedstock Supplies: the Challenges and the Rewards

    SciTech Connect (OSTI)

    Graham, Robin Lambert

    2007-01-01

    Forecasting the magnitude of sustainable biofeedstock supplies is challenging because of 1) the myriad of potential feedstock types and their management 2) the need to account for the spatial variation of both the supplies and their environmental and economic consequences, and 3) the inherent challenges of optimizing across economic and environmental considerations. Over the last two decades U.S. biomass forecasts have become increasingly complex and sensitive to environmental and economic considerations. More model development and research is needed however, to capture the landscape and regional tradeoffs of differing biofeedstock supplies especially with regards water quality concerns and wildlife/biodiversity. Forecasts need to be done in the context of the direction of change and what the probable land use and attendant environmental and economic outcomes would be if biofeedstocks were not being produced. To evaluate sustainability, process-oriented models need to be coupled or used to inform sector models and more work needs to be done on developing environmental metrics that are useful for evaluating economic and environmental tradeoffs. These challenges are exciting and worthwhile as they will enable the bioenergy industry to capture environmental and social benefits of biofeedstock production and reduce risks.

  5. Evaluation of Forecasted Southeast Pacific Stratocumulus in the NCAR, GFDL and ECMWF Models

    SciTech Connect (OSTI)

    Hannay, C; Williamson, D L; Hack, J J; Kiehl, J T; Olson, J G; Klein, S A; Bretherton, C S; K?hler, M

    2008-01-24

    We examine forecasts of Southeast Pacific stratocumulus at 20S and 85W during the East Pacific Investigation of Climate (EPIC) cruise of October 2001 with the ECMWF model, the Atmospheric Model (AM) from GFDL, the Community Atmosphere Model (CAM) from NCAR, and the CAM with a revised atmospheric boundary layer formulation from the University of Washington (CAM-UW). The forecasts are initialized from ECMWF analyses and each model is run for 3 days to determine the differences with the EPIC field data. Observations during the EPIC cruise show a stable and well-mixed boundary layer under a sharp inversion. The inversion height and the cloud layer have a strong and regular diurnal cycle. A key problem common to the four models is that the forecasted planetary boundary layer (PBL) height is too low when compared to EPIC observations. All the models produce a strong diurnal cycle in the Liquid Water Path (LWP) but there are large differences in the amplitude and the phase compared to the EPIC observations. This, in turn, affects the radiative fluxes at the surface. There is a large spread in the surface energy budget terms amongst the models and large discrepancies with observational estimates. Single Column Model (SCM) experiments with the CAM show that the vertical pressure velocity has a large impact on the PBL height and LWP. Both the amplitude of the vertical pressure velocity field and its vertical structure play a significant role in the collapse or the maintenance of the PBL.

  6. SINGLE-STEP CONVERSION OF UO$sub 3$ TO UF$sub 4$

    DOE Patents [OSTI]

    Moore, J.E.

    1960-07-12

    A description is given of the preparation of uranium tetrafluoride by reacting a hexavalent uranium compound with a pclysaccharide and gaseous hydrogen fluoride at an elevated temperature. Uranium trioxide and starch are combined with water to form a doughy mixture. which is extruded into pellets and dried. The pellets are then contacted with HF at a temperature from 500 to 700 deg C in a moving bed reactor to prcduce UF/sub 4/. Reduction of the hexavalent uranium to UO/sub 2/ and conversion of the UO/sub 2/ to UF/sub 4/ are accomplished simultaneously in this process.

  7. Magnetic anisotropies in epitaxial Fe{sub 3}O{sub 4}/GaAs(100) patterned structures

    SciTech Connect (OSTI)

    Zhang, W. Zhang, D.; Yuan, S. J.; Huang, Z. C.; Zhai, Y.; Wong, P. K. J.; Wu, J.; Xu, Y. B.

    2014-10-15

    Previous studies on epitaxial Fe{sub 3}O{sub 4} rings in the context of spin-transfer torque effect have revealed complicated and undesirable domain structures, attributed to the intrinsic fourfold magnetocrystalline anisotropy in the ferrite. In this Letter, we report a viable solution to this problem, utilizing a 6-nm-thick epitaxial Fe{sub 3}O{sub 4} thin film on GaAs(100), where the fourfold magnetocrystalline anisotropy is negligible. We demonstrate that in the Fe{sub 3}O{sub 4} planar wires patterned from our thin film, such a unique magnetic anisotropy system has been preserved, and relatively simple magnetic domain configurations compared to those previous reports can be obtained.

  8. AGR-3/4 Final Data Qualification Report for ATR Cycles 151A through 155B-1

    SciTech Connect (OSTI)

    Pham, Binh T.

    2015-03-01

    This report provides the qualification status of experimental data for the entire Advanced Gas Reactor 3/4 (AGR 3/4) fuel irradiation. AGR-3/4 is the third in a series of planned irradiation experiments conducted in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for the AGR Fuel Development and Qualification Program, which supports development of the advanced reactor technology under the INL ART Technology Development Office (TDO). The main objective of AGR-3/4 irradiation is to provide a known source of fission products for subsequent transport through compact matrix and structural graphite materials due to the presence of designed-to-fail fuel particles. Full power irradiation of the AGR 3/4 test began on December 14, 2011 (ATR Cycle 151A), and was completed on April 12, 2014 (end of ATR Cycle 155B) after 369.1 effective full power days of irradiation. The AGR-3/4 test was in the reactor core for eight of the ten ATR cycles between 151A and 155B. During the unplanned outage cycle, 153A, the experiment was removed from the ATR northeast flux trap (NEFT) location and stored in the ATR canal. This was to prevent overheating of fuel compacts due to higher than normal ATR power during the subsequent Powered Axial Locator Mechanism cycle, 153B. The AGR 3/4 test was inserted back into the ATR NEFT location during the outage of ATR Cycle 154A on April 26, 2013. Therefore, the AGR-3/4 irradiation data received during these 2 cycles (153A and 153B) are irrelevant and their qualification status isnot included in this report. Additionally, during ATR Cycle 152A the ATR core ran at low power for a short enough duration that the irradiation data are not used for physics and thermal calculations. However, the qualification status of irradiation data for this cycle is still covered in this report. As a result, this report includes data from 8 ATR Cycles: 151A, 151B, 152A, 152B, 154A, 154B, 155A, and 155B, as recorded in the Nuclear Data Management and Analysis System (NDMAS). The AGR 3/4 data streams addressed in this report include thermocouple (TC) temperatures, sweep gas data (flow rates, pressure, and moisture content), and Fission Product Monitoring System (FPMS) data (release rates, release to birth rate ratios [R/Bs], and particle failure counts) for each of the twelve capsules in the AGR 3/4 experiment. During Outage Cycle 155A, fourteen flow meters were installed downstream from fourteen FPMS monitors to measure flows from the monitors; qualification status of these data are also included in the report. The final data qualification status for these data streams is determined by a Data Review Committee (DRC) composed of AGR technical leads, Sitewide Quality Assurance (QA), and NDMAS analysts. For ATR Cycles 151A through 154B, the DRC convened on February 12, 2014, reviewed the data acquisition process, and considered whether the data met the requirements for data collection as specified in QA approved INL ART TDO data collection plans. The DRC also examined the results of NDMAS data testing and statistical analyses, and confirmed the qualification status of the data as given in this report. The qualification status of AGR-3/4 irradiation data during the first six cycles were previously reported in INL/EXT-14-31186 document. This report presents data qualification status for the entire AGR-3/4 irradiation.

  9. 300 Area D4 Project 3rd Quarter Fiscal Year 2006 Building Completion Report

    SciTech Connect (OSTI)

    D. S. Smith

    2006-09-25

    This report documents the deactivation, decontamination, decommissioning, and demolition of five buildings in the 300 Area of the Hanford Site. The D4 of these facilities included characterization, engineering, removal of hazardous and radiologically contaminated materials, equipment removal, utility disconnection, deactivation, decontamination, demolition of the structure, and stabilization or removal of the remaining slab and foundation as appropriate.

  10. Strain-Specific V3 and CD4 Binding Site Autologous HIV-1 Neutralizing Antibodies Select Neutralization-Resistant Viruses

    SciTech Connect (OSTI)

    Moody, M. Anthony; Gao, Feng; Gurley, Thaddeus C.; Amos, Joshua D.; Kumar, Amit; Hora, Bhavna; Marshall, Dawn J.; Whitesides, John F.; Xia, Shi-Mao; Parks, Robert; Lloyd, Krissey E.; Hwang, Kwan-Ki; Lu, Xiaozhi; Bonsignori, Mattia; Finzi, Andrs; Vandergrift, Nathan A.; Alam, S. Munir; Ferrari, Guido; Shen, Xiaoying; Tomaras, Georgia D.; Kamanga, Gift; Cohen, Myron S.; Sam, Noel E.; Kapiga, Saidi; Gray, Elin S.; Tumba, Nancy L.; Morris, Lynn; Zolla-Pazner, Susan; Gorny, Miroslaw K.; Mascola, John R.; Hahn, Beatrice H.; Shaw, George M.; Sodroski, Joseph G.; Liao, Hua-Xin; Montefiori, DavidC.; Hraber, PeterT.; Korber, BetteT.; Haynes, BartonF.

    2015-09-09

    The third variable (V3) loop and the CD4 binding site (CD4bs) of the viral envelope are frequently targeted by neutralizing antibodies (nAbs) in HIV-1-infected individuals. In chronic infection, virus escape mutants repopulate the plasma and V3 and CD4bs nAbs emerge that can neutralize heterologous tier 1 easy-to-neutralize, but not tier 2 difficult-to-neutralize HIV-1 isolates. However, neutralization sensitivity of autologous plasma viruses to this type of nAb response has not been studied. We describe the development and evolution in vivo of antibodies distinguished by their target specificity for V3and CD4bs epitopes on autologous tier 2 viruses but not on heterologous tier 2 viruses. A surprisingly high fraction of autologous circulating viruses was sensitive to these antibodies. These findings demonstrate a role for V3 and CD4bs antibodies in constraining the native envelope trimer in vivo to a neutralization-resistant phenotype, explaining why HIV-1 transmission generally occurs by tier 2 neutralization-resistant viruses.

  11. Strain-Specific V3 and CD4 Binding Site Autologous HIV-1 Neutralizing Antibodies Select Neutralization-Resistant Viruses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moody, M.  Anthony; Gao, Feng; Gurley, Thaddeus  C.; Amos, Joshua  D.; Kumar, Amit; Hora, Bhavna; Marshall, Dawn  J.; Whitesides, John  F.; Xia, Shi-Mao; Parks, Robert; et al

    2015-09-09

    The third variable (V3) loop and the CD4 binding site (CD4bs) of the viral envelope are frequently targeted by neutralizing antibodies (nAbs) in HIV-1-infected individuals. In chronic infection, virus escape mutants repopulate the plasma and V3 and CD4bs nAbs emerge that can neutralize heterologous tier 1 easy-to-neutralize, but not tier 2 difficult-to-neutralize HIV-1 isolates. However, neutralization sensitivity of autologous plasma viruses to this type of nAb response has not been studied. We describe the development and evolution in vivo of antibodies distinguished by their target specificity for V3and CD4bs epitopes on autologous tier 2 viruses but not on heterologous tiermore » 2 viruses. A surprisingly high fraction of autologous circulating viruses was sensitive to these antibodies. These findings demonstrate a role for V3 and CD4bs antibodies in constraining the native envelope trimer in vivo to a neutralization-resistant phenotype, explaining why HIV-1 transmission generally occurs by tier 2 neutralization-resistant viruses.« less

  12. Materials Data on Na3H5(CO2)4 (SG:2) by Materials Project (Dataset) | Data

    Office of Scientific and Technical Information (OSTI)

    Explorer Na3H5(CO2)4 (SG:2) by Materials Project Title: Materials Data on Na3H5(CO2)4 (SG:2) by Materials Project Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations Authors: Kristin Persson Publication Date: 2014-11-02 OSTI Identifier: 1183905 Report Number(s): mp-555083 DOE

  13. Production of the ammonium salt of 3,5-dinitro-1,2,4-triazole by solvent extraction

    DOE Patents [OSTI]

    Lee, Kien Y. (Los Alamos, NM); Ott, Donald G. (Los Alamos, NM)

    1980-01-01

    The ammonium salt of 3,5-dinitro-1,2,4-triazole has utility as a chemical explosive. In accordance with the present invention, it may readily be produced by solvent extraction using high-molecular weight, water-insoluble amines followed by amination with anhydrous ammonia gas. The aqueous reaction mixture produced in the synthesis of the parent compound, 3,5-dinitro-1,2,4-triazole, is quite suitable--and indeed is preferred--for use as the feed material in the process of the invention.

  14. IDIQ BS Ex A (Rev. 3.1, 4/9/13) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on claims shall be paid at the rate established by the Secretary of the Treasury of the United States pursuant to Public Law 92-41 (85 Stat. 97). IDIQ BS Ex A (Rev. 3.1, 4913)...

  15. Colorado - 4 C.C.R. 723-3 | Open Energy Information

    Open Energy Info (EERE)

    (Redirected from Colorado - C.C.R. 723-3 - Rules Regulating Electric Utilities) Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document-...

  16. Scanning Tunneling Microscopy and Theoretical Study of Water Adsorption on Fe3O4: Implications for Catalysis

    SciTech Connect (OSTI)

    Rim, Kwang T.; Eom, Daejin; Chan, Siu-Wai; Flytzani-Stephanopoulos, Maria; Flynn, George; Wen, Xiaodong; Batista, Enrique R.

    2012-10-23

    The reduced surface of a natural Hematite single crystal a-Fe2O3(0001) sample has multiple surface domains with di!erent terminations, Fe2O3(0001), FeO(111), and Fe3O4(111). The adsorption of water on this surface was investigated via Scanning Tunneling Microscopy (STM) and first-principle theoretical simulations. Water species are observed only on the Fe-terminated Fe3O4(111) surface at temperatures up to 235 K. Between 235 and 245 K we observed a change in the surface species from intact water molecules and hydroxyl groups bound to the surface to only hydroxyl groups atop the surface terminating FeIII cations. This indicates a low energy barrier for water dissociation on the surface of Fe3O4 that is supported by our theoretical computations. Our first principles simulations con"rm the identity of the surface species proposed from the STM images, finding that the most stable state of a water molecule is the dissociated one (OH + H), with OH atop surface terminating FeIII sites and H atop under-coordinated oxygen sites. Attempts to simulate reaction of the surface OH with coadsorbed CO fail because the only binding sites for CO are the surface FeIII atoms, which are blocked by the much more strongly bound OH. In order to promote this reaction we simulated a surface decorated with gold atoms. The Au adatoms are found to cap the under-coordinated oxygen sites and dosed CO is found to bind to the Au adatom. This newly created binding site for CO not only allows for coexistence of CO and OH on the surface of Fe3O4 but also provides colocation between the two species. These two factors are likely promoters of catalytic activity on Au/Fe3O4(111) surfaces.

  17. Evidence of Eu{sup 2+} 4f electrons in the valence band spectra of EuTiO{sub 3} and EuZrO{sub 3}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T.; Valant, M.; Williams, J. R.; Bugnet, M.; Botton, G. A.; Ohashi, N.; Sakka, Y.

    2012-10-15

    We report on optical band gap and valence electronic structure of two Eu{sup 2+}-based perovskites, EuTiO{sub 3} and EuZrO{sub 3} as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f{sup 7} electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO{sub 3} perovskites except that it is shifted to higher binding energies. Appearance of the Eu{sup 2+} 4f{sup 7} band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  18. 3-4-10_Final_Testimony_28SWPA29_28Worthingon29.pdf

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    JON C. WORTHINGTON ADMINISTRATOR SOUTHWESTERN POWER ADMINISTRATION U.S. DEPARTMENT OF ENERGY BEFORE THE SUBCOMMITTEE ON WATER AND POWER COMMITTEE ON NATURAL RESOURCES U.S. HOUSE OF REPRESENTATIVES MARCH 4, 2010 2 Madame Chairwoman and Members of the Subcommittee, I am Jon Worthington, Administrator of Southwestern Power Administration (Southwestern). I appreciate this opportunity to share with you today how Southwestern continues to promote our Nation's energy security by effectively marketing

  19. Survey of Variable Generation Forecasting in the West: August 2011 - June 2012

    SciTech Connect (OSTI)

    Porter, K.; Rogers, J.

    2012-04-01

    This report surveyed Western Interconnection Balancing Authorities regarding their implementation of variable generation forecasting, the lessons learned to date, and recommendations they would offer to other Balancing Authorities who are considering variable generation forecasting. Our survey found that variable generation forecasting is at an early implementation stage in the West. Eight of the eleven Balancing Authorities interviewed began forecasting in 2008 or later. It also appears that less than one-half of the Balancing Authorities in the West are currently utilizing variable generation forecasting, suggesting that more Balancing Authorities in the West will engage in variable generation forecasting should more variable generation capacity be added.

  20. (4-Methoxyphenyl)(3,4,5-trimethoxyphenyl)methanone inhibits tubulin polymerization, induces G{sub 2}/M arrest, and triggers apoptosis in human leukemia HL-60 cells

    SciTech Connect (OSTI)

    Magalhes, Hemerson I.F.; Wilke, Diego V.; Bezerra, Daniel P.; Cavalcanti, Bruno C.; Rotta, Rodrigo; Lima, Dnis P. de; Beatriz, Adilson; Moraes, Manoel O.; Diniz-Filho, Jairo; Pessoa, Claudia

    2013-10-01

    (4-Methoxyphenyl)(3,4,5-trimethoxyphenyl)methanone (PHT) is a known cytotoxic compound belonging to the phenstatin family. However, the exact mechanism of action of PHT-induced cell death remains to be determined. The aim of this study was to investigate the mechanisms underlying PHT-induced cytotoxicity. We found that PHT displayed potent cytotoxicity in different tumor cell lines, showing IC{sub 50} values in the nanomolar range. Cell cycle arrest in G{sub 2}/M phase along with the augmented metaphase cells was found. Cells treated with PHT also showed typical hallmarks of apoptosis such as cell shrinkage, chromatin condensation, phosphatidylserine exposure, increase of the caspase 3/7 and 8 activation, loss of mitochondrial membrane potential, and internucleosomal DNA fragmentation without affecting membrane integrity. Studies conducted with isolated tubulin and docking models confirmed that PHT binds to the colchicine site and interferes in the polymerization of microtubules. These results demonstrated that PHT inhibits tubulin polymerization, arrests cancer cells in G{sub 2}/M phase of the cell cycle, and induces their apoptosis, exhibiting promising anticancer therapeutic potential. - Highlights: PHT inhibits tubulin polymerization. PHT arrests cancer cells in G{sub 2}/M phase of the cell cycle. PHT induces caspase-dependent apoptosis.

  1. Angular distribution and recoil effect for 1 MeV Au+ ions through a Si3N4 thin foil

    SciTech Connect (OSTI)

    Jin, Ke; Zhu, Zihua; Manandhar, Sandeep; Liu, Jia; Chen, Chien-Hung; Shutthanandan, Vaithiyalingam; Thevuthasan, Suntharampillai; Weber, William J; Zhang, Yanwen

    2014-01-01

    The Stopping and Range of Ions in Matter (SRIM) code has been widely used to predict nuclear stopping power and angular distribution of ion-solid collisions. However, experimental validation of the predictions is insufficient for slow heavy ions in nonmetallic compounds. In this work, time-of-flight secondary ion mass spectrometry (ToF-SIMS) is applied to determine the angular distribution of 1 MeV Au ions after penetrating a Si3N4 foil with a thickness of ~100 nm. The exiting Au ions are collected by a Si wafer located ~14 mm behind the Si3N4 foil, and the resulting 2-dimensional distribution of Au ions on the Si wafer is measured by ToF-SIMS. The SRIM-predicted angular distribution of Au ions through the Si3N4 thin foil is compared with the measured results, indicating that SRIM slightly overestimates the nuclear stopping power by up to 10%. In addition, thickness reduction of the suspended Si3N4 foils induced by 1 MeV Au ion irradiation is observed with an average loss rate of ~107 atom/ion.

  2. Heterojunction metal-oxide-metal Au-Fe{sub 3}O{sub 4}-Au single nanowire device for spintronics

    SciTech Connect (OSTI)

    Reddy, K. M. Punnoose, Alex; Hanna, Charles; Padture, Nitin P.

    2015-05-07

    In this report, we present the synthesis of heterojunction magnetite nanowires in alumina template and describe magnetic and electrical properties from a single nanowire device for spintronics applications. Heterojunction Au-Fe-Au nanowire arrays were electrodeposited in porous aluminum oxide templates, and an extensive and controlled heat treatment process converted Fe segment to nanocrystalline cubic magnetite phase with well-defined Au-Fe{sub 3}O{sub 4} interfaces as confirmed by the transmission electron microscopy. Magnetic measurements revealed Verwey transition shoulder around 120 K and a room temperature coercive field of 90 Oe. Current–voltage (I-V) characteristics of a single Au-Fe{sub 3}O{sub 4}-Au nanowire have exhibited Ohmic behavior. Anomalous positive magnetoresistance of about 0.5% is observed on a single nanowire, which is attributed to the high spin polarization in nanowire device with pure Fe{sub 3}O{sub 4} phase and nanocontact barrier. This work demonstrates the ability to preserve the pristine Fe{sub 3}O{sub 4} and well defined electrode contact metal (Au)–magnetite interface, which helps in attaining high spin polarized current.

  3. Distinguishing tautomerism in the crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide using DFT-D calculations and {sup 13}C solid-state NMR

    SciTech Connect (OSTI)

    Li, Xiaozhou; Bond, Andrew D.; Johansson, Kristoffer E.; Van de Streek, Jacco

    2014-08-01

    The crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide contains an imine tautomer, rather than the previously reported amine tautomer. The tautomers can be distinguished using dispersion-corrected density functional theory calculations and by comparison of calculated and measured {sup 13}C solid-state NMR spectra. The crystal structure of the title compound, C{sub 11}H{sub 13}N{sub 3}O{sub 2}S{sub 2}, has been determined previously on the basis of refinement against laboratory powder X-ray diffraction (PXRD) data, supported by comparison of measured and calculated {sup 13}C solid-state NMR spectra [Hangan et al. (2010 ▶). Acta Cryst. B66, 615–621]. The mol@@ecule is tautomeric, and was reported as an amine tautomer [systematic name: N-(5-ethyl-1,3,4-thia@@diazol-2-yl)-p-toluene@@sulfonamide], rather than the correct imine tautomer. The protonation site on the mol@@ecule’s 1,3,4-thia@@diazole ring is indicated by the inter@@molecular contacts in the crystal structure: N—H⋯O hydrogen bonds are established at the correct site, while the alternative protonation site does not establish any notable inter molecular inter@@actions. The two tautomers provide essentially identical Rietveld fits to laboratory PXRD data, and therefore they cannot be directly distinguished in this way. However, the correct tautomer can be distinguished from the incorrect one by previously reported qu@@anti@@tative criteria based on the extent of structural distortion on optimization of the crystal structure using dispersion-corrected density functional theory (DFT-D) calculations. Calculation of the {sup 13}C SS-NMR spectrum based on the correct imine tautomer also provides considerably better agreement with the measured {sup 13}C SS-NMR spectrum.

  4. Fuel performance improvement program: description and characterization of HBWR Series H-2, H-3, and H-4 test rods

    SciTech Connect (OSTI)

    Guenther, R.J.; Barner, J.O.; Welty, R.K.

    1980-03-01

    The fabrication process and as-built characteristics of the HBWR Series H-2 and H-3 test rods, as well as the three packed-particle (sphere-pac) rods in HBWR Series H-4 are described. The HBWR Series H-2, H-3, and H-4 tests are part of the irradiation test program of the Fuel Performance Improvement Program. Fifteen rods were fabricated for the three test series. Rod designs include: (1) a reference dished pellet design incorporating chamfered edges, (2) a chamfered, annular pellet design combined with graphite-coated cladding, and (3) a sphere-pac design. Both the annular-coated and sphere-pac designs include internal pressurization using helium.

  5. EXPLORING THE z = 3-4 MASSIVE GALAXY POPULATION WITH ZFOURGE: THE PREVALENCE OF DUSTY AND QUIESCENT GALAXIES

    SciTech Connect (OSTI)

    Spitler, Lee R.; Rees, Glen; Straatman, Caroline M. S.; Labb, Ivo; Glazebrook, Karl; Kacprzak, Glenn G.; Nanayakkara, Themiya; Tran, Kim-Vy H.; Papovich, Casey; Kawinwanichakij, Lalitwadee; Mehrtens, Nicola; Tilvi, Vithal; Tomczak, Adam R.; Quadri, Ryan F.; Persson, S. Eric; Kelson, Daniel D.; McCarthy, Patrick J.; Monson, Andrew J.; Van Dokkum, Pieter; Allen, Rebecca

    2014-06-01

    Our understanding of the redshift z > 3 galaxy population relies largely on samples selected using the popular ''dropout'' technique, typically consisting of UV-bright galaxies with blue colors and prominent Lyman breaks. As it is currently unknown if these galaxies are representative of the massive galaxy population, we here use the FOURSTAR Galaxy Evolution (ZFOURGE) survey to create a stellar mass-limited sample at z = 3-4. Uniquely, ZFOURGE uses deep near-infrared medium-bandwidth filters to derive accurate photometric redshifts and stellar population properties. The mass-complete sample consists of 57 galaxies with log M>10.6, reaching below M {sup *} at z = 3-4. On average, the massive z = 3-4 galaxies are extremely faint in the observed optical with median R{sub tot}{sup AB}=27.480.41 (rest-frame M {sub 1700} = 18.05 0.37). They lie far below the UV luminosity-stellar mass relation for Lyman break galaxies and are about ?100 fainter at the same mass. The massive galaxies are red (R K {sub s} {sub AB} = 3.9 0.2; rest-frame UV-slope ? = 0.2 0.3) likely from dust or old stellar ages. We classify the galaxy spectral energy distributions by their rest-frame UV and VJ colors and find a diverse population: 46{sub ?6?17}{sup +6+10}% of the massive galaxies are quiescent, 40{sub ?6?5}{sup +6+7}% are dusty star-forming galaxies, and only 14{sub ?3?4}{sup +3+10}% resemble luminous blue star-forming Lyman break galaxies. This study clearly demonstrates an inherent diversity among massive galaxies at higher redshift than previously known. Furthermore, we uncover a reservoir of dusty star-forming galaxies with 4 lower specific star-formation rates compared to submillimeter-selected starbursts at z > 3. With 5 higher numbers, the dusty galaxies may represent a more typical mode of star formation compared to submillimeter-bright starbursts.

  6. Pumping-route-dependent concentration quenching and temperature effect of green up- and down-conversion luminescence in Er{sup 3+}/Yb{sup 3+} co-doped Gd{sub 2}(WO{sub 4}){sub 3} phosphors

    SciTech Connect (OSTI)

    Li, Jingjing; Sun, Jiashi [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Liu, Jutao [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Li, Xiangping; Zhang, Jinsu [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Tian, Yue [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Fu, Shaobo; Cheng, Lihong; Zhong, Haiyang [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Xia, Haiping [Key laboratory of Photo-electronic Materials, Ningbo University, Ningbo, Zhejiang 315211 (China); Chen, Baojiu, E-mail: chenmbj@sohu.com [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)

    2013-06-01

    Graphical abstract: A comparative study on the concentration quenching behaviors of green down- and up-conversion emissions was carried out for the first time, and the different concentration quenching mechanisms were analyzed. Secondly, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power and Er{sup 3+} doping concentration. Highlights: ? Gd{sub 2}(WO{sub 4}){sub 3}:Er/Yb phosphors were prepared via a co-precipitation reaction. ? Morphology and structure of the phosphors were characterized by XRD and SEM. ? Concentration quenching mechanisms for down and up emissions were studied. ? Thermal effect induced by laser irradiation was studied via temperature sensing tech. - Abstract: Gd{sub 2}(WO{sub 4}){sub 3} phosphors with various Er{sup 3+} concentrations and fixed Yb{sup 3+} concentration were synthesized via a co-precipitation method, and their crystal structure and morphology were characterized by using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The concentration quenching behaviors of green up- and down-conversion emissions of Er{sup 3+} were analyzed, and it was confirmed that the difference between quenching concentration for up- and down-conversion emissions resulted from the different population routes. The temperature sensing properties of the Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors were studied, and it was found that the Er{sup 3+} doping concentration slightly affected the sensitivity, and Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors could be used in a broad temperature region for detecting temperature. Finally, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power and Er{sup 3+} doping concentration.

  7. THE GREAT OBSERVATORIES ORIGINS DEEP SURVEY: CONSTRAINTS ON THE LYMAN CONTINUUM ESCAPE FRACTION DISTRIBUTION OF LYMAN-BREAK GALAXIES AT 3.4 < z < 4.5

    SciTech Connect (OSTI)

    Vanzella, E.; Nonino, M.; Fontanot, F.; Cristiani, S.; Tozzi, P.; Giavalisco, M.; Inoue, A. K.; Grazian, A.; Giallongo, E.; Boutsia, K.; Fontana, A.; Pentericci, L.; Dickinson, M.; Stern, D.; Ferguson, H.; Spinrad, H.; Rosati, P.

    2010-12-10

    We use ultra-deep ultraviolet VLT/VIMOS intermediate-band and VLT/FORS1 narrowband imaging in the GOODS Southern field to derive limits on the distribution of the escape fraction (f{sub esc}) of ionizing radiation for L {>=} L*{sub z=3} Lyman-break galaxies (LBGs) at redshift 3.4-4.5. Only one LBG, at redshift z = 3.795, is detected in its Lyman continuum (LyC; S/N {approx_equal} 5.5), the highest redshift galaxy currently known with a direct detection. Its ultraviolet morphology is quite compact (R{sub eff} = 0.8 kpc physical). Three out of seven active galactic nuclei are also detected in their LyC, including one at redshift z = 3.951 and z{sub 850} = 26.1. From stacked data (LBGs), we set an upper limit to the average f{sub esc} in the range 5%-20%, depending on how the data are selected (e.g., by magnitude and/or redshift). We undertake extensive Monte Carlo simulations that take into account intergalactic attenuation, stellar population synthesis models, dust extinction, and photometric noise in order to explore the moments of the distribution of the escaping radiation. Various distributions (exponential, log-normal, and Gaussian) are explored. We find that the median f{sub esc} is lower than {approx_equal}6% with an 84% percentile limit not larger than 20%. If this result remains valid for fainter LBGs down to current observational limits, then the LBG population might be not sufficient to account for the entire photoionization budget at the redshifts considered here, with the exact details dependent upon the assumed ionizing background and QSO contribution thereto. It is possible that f{sub esc} depends on the UV luminosity of the galaxies, with fainter galaxies having higher f{sub esc}, and estimates of f{sub esc} from a sample of faint LBGs from HUDF (i{sub 775} {<=}28.5) are in broad quantitative agreement with such a scenario.

  8. Annual Performance Evaluation of a Pair of Energy Efficient Houses (WC3 and WC4) in Oak Ridge, TN

    SciTech Connect (OSTI)

    Biswas, Kaushik; Christian, Jeffrey E; Gehl, Anthony C; Jackson, Roderick K; Boudreaux, Philip R

    2012-04-01

    Beginning in 2008, two pairs of energy-saver houses were built at Wolf Creek in Oak Ridge, TN. These houses were designed to maximize energy efficiency using new ultra-high-efficiency components emerging from ORNL s Cooperative Research and Development Agreement (CRADA) partners and others. The first two houses contained 3713 square feet of conditioned area and were designated as WC1 and WC2; the second pair consisted of 2721 square feet conditioned area with crawlspace foundation and they re called WC3 and WC4. This report is focused on the annual energy performance of WC3 and WC4, and how they compare against a previously benchmarked maximum energy efficient house of a similar footprint. WC3 and WC4 are both about 55-60% more efficient than traditional new construction. Each house showcases a different envelope system: WC3 is built with advanced framing featured cellulose insulation partially mixed with phase change materials (PCM); and WC4 house has cladding composed of an exterior insulation and finish system (EIFS). The previously benchmarked house was one of three built at the Campbell Creek subdivision in Knoxville, TN. This house (CC3) was designed as a transformation of a builder house (CC1) with the most advanced energy-efficiency features, including solar electricity and hot water, which market conditions are likely to permit within the 2012 2015 period. The builder house itself was representative of a standard, IECC 2006 code-certified, all-electric house built by the builder to sell around 2005 2008.

  9. Impacts of Improved Day-Ahead Wind Forecasts on Power Grid Operations: September 2011

    SciTech Connect (OSTI)

    Piwko, R.; Jordan, G.

    2011-11-01

    This study analyzed the potential benefits of improving the accuracy (reducing the error) of day-ahead wind forecasts on power system operations, assuming that wind forecasts were used for day ahead security constrained unit commitment.

  10. DOE Releases Latest Report on Energy Savings Forecast of Solid-State Lighting

    Broader source: Energy.gov [DOE]

    DOE has published a new report forecasting the energy savings of LED white-light sources compared with conventional white-light sources. The sixth iteration of the Energy Savings Forecast of Solid...

  11. Status of Centralized Wind Power Forecasting in North America: May 2009-May 2010

    SciTech Connect (OSTI)

    Porter, K.; Rogers, J.

    2010-04-01

    Report surveys grid wind power forecasts for all wind generators, which are administered by utilities or regional transmission organizations (RTOs), typically with the assistance of one or more wind power forecasting companies.

  12. EERE Success Story-Solar Forecasting Gets a Boost from Watson...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forecasting Gets a Boost from Watson, Accuracy Improved by 30% EERE Success Story-Solar Forecasting Gets a Boost from Watson, Accuracy Improved by 30% October 27, 2015 - 11:48am ...

  13. RELAP5/MOD3 code manual. Volume 4, Models and correlations

    SciTech Connect (OSTI)

    1995-08-01

    The RELAP5 code has been developed for best-estimate transient simulation of light water reactor coolant systems during postulated accidents. The code models the coupled behavior of the reactor coolant system and the core for loss-of-coolant accidents and operational transients such as anticipated transient without scram, loss of offsite power, loss of feedwater, and loss of flow. A generic modeling approach is used that permits simulating a variety of thermal hydraulic systems. Control system and secondary system components are included to permit modeling of plant controls, turbines, condensers, and secondary feedwater systems. RELAP5/MOD3 code documentation is divided into seven volumes: Volume I presents modeling theory and associated numerical schemes; Volume II details instructions for code application and input data preparation; Volume III presents the results of developmental assessment cases that demonstrate and verify the models used in the code; Volume IV discusses in detail RELAP5 models and correlations; Volume V presents guidelines that have evolved over the past several years through the use of the RELAP5 code; Volume VI discusses the numerical scheme used in RELAP5; and Volume VII presents a collection of independent assessment calculations.

  14. Experimental investigations of material models for Ti-6A1-4V and 2024-T3

    SciTech Connect (OSTI)

    Leseur, D

    1999-05-03

    This report describes studies of the deformation and failure behavior of Ti-6Al-4V and 2024-T3 aluminum. Data was obtained at high strain rates and large strains using the split Hopkinson pressure bar technique. This information, plus additional data from the literature, was used to critically evaluate the ability of the Johnson Cook material model to represent the deformation and failure response of Ti-6AMV and 2024-T3 under conditions relevant to simulations of engine containment and the influence of uncontained engine debris on aircraft structures. This model is being used in the DYNA3D finite element code, which is being developed/validated for evaluating aircraft/engine designs relative to the federal airworthiness standards and for improving mitigation/containment technology. The results of the experimental work reported here were used to define a new set of material constants for the strength component of the Johnson Cook model for Ti-6Al-4V and 2024-T3. The capabilities and limitations of the model are reviewed. The model can accurately represent the stress-strain response of the materials. The major concern with the Johnson Cook material model is its ability to accurately represent the stress - strain rate response at strain rates greater than 10{sup 3}-10{sup 4} s{sup {minus}1}. Additional work is also needed to adequately account for failure via shear localization, which was the dominant failure mode at high strain rates in both materials. Failure modeling in both Ti-6Al-N and 2024-T3 will be considered further in future reports.

  15. Weather forecast-based optimization of integrated energy systems.

    SciTech Connect (OSTI)

    Zavala, V. M.; Constantinescu, E. M.; Krause, T.; Anitescu, M.

    2009-03-01

    In this work, we establish an on-line optimization framework to exploit detailed weather forecast information in the operation of integrated energy systems, such as buildings and photovoltaic/wind hybrid systems. We first discuss how the use of traditional reactive operation strategies that neglect the future evolution of the ambient conditions can translate in high operating costs. To overcome this problem, we propose the use of a supervisory dynamic optimization strategy that can lead to more proactive and cost-effective operations. The strategy is based on the solution of a receding-horizon stochastic dynamic optimization problem. This permits the direct incorporation of economic objectives, statistical forecast information, and operational constraints. To obtain the weather forecast information, we employ a state-of-the-art forecasting model initialized with real meteorological data. The statistical ambient information is obtained from a set of realizations generated by the weather model executed in an operational setting. We present proof-of-concept simulation studies to demonstrate that the proposed framework can lead to significant savings (more than 18% reduction) in operating costs.

  16. Weather Research and Forecasting Model with the Immersed Boundary Method

    Energy Science and Technology Software Center (OSTI)

    2012-05-01

    The Weather Research and Forecasting (WRF) Model with the immersed boundary method is an extension of the open-source WRF Model available for wwww.wrf-model.org. The new code modifies the gridding procedure and boundary conditions in the WRF model to improve WRF's ability to simutate the atmosphere in environments with steep terrain and additionally at high-resolutions.

  17. Review of Wind Energy Forecasting Methods for Modeling Ramping Events

    SciTech Connect (OSTI)

    Wharton, S; Lundquist, J K; Marjanovic, N; Williams, J L; Rhodes, M; Chow, T K; Maxwell, R

    2011-03-28

    Tall onshore wind turbines, with hub heights between 80 m and 100 m, can extract large amounts of energy from the atmosphere since they generally encounter higher wind speeds, but they face challenges given the complexity of boundary layer flows. This complexity of the lowest layers of the atmosphere, where wind turbines reside, has made conventional modeling efforts less than ideal. To meet the nation's goal of increasing wind power into the U.S. electrical grid, the accuracy of wind power forecasts must be improved. In this report, the Lawrence Livermore National Laboratory, in collaboration with the University of Colorado at Boulder, University of California at Berkeley, and Colorado School of Mines, evaluates innovative approaches to forecasting sudden changes in wind speed or 'ramping events' at an onshore, multimegawatt wind farm. The forecast simulations are compared to observations of wind speed and direction from tall meteorological towers and a remote-sensing Sound Detection and Ranging (SODAR) instrument. Ramping events, i.e., sudden increases or decreases in wind speed and hence, power generated by a turbine, are especially problematic for wind farm operators. Sudden changes in wind speed or direction can lead to large power generation differences across a wind farm and are very difficult to predict with current forecasting tools. Here, we quantify the ability of three models, mesoscale WRF, WRF-LES, and PF.WRF, which vary in sophistication and required user expertise, to predict three ramping events at a North American wind farm.

  18. Wind Forecast Improvement Project Southern Study Area Final Report |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy PDF icon Wind Forecast Improvement Project Southern Study Area Final Report.pdf More Documents & Publications QER - Comment of Edison Electric Institute (EEI) 1 QER - Comment of Canadian Hydropower Association QER - Comment of Edison Electric Institute (EEI) 2

  19. Central Wind Power Forecasting Programs in North America by Regional Transmission Organizations and Electric Utilities

    SciTech Connect (OSTI)

    Porter, K.; Rogers, J.

    2009-12-01

    The report addresses the implementation of central wind power forecasting by electric utilities and regional transmission organizations in North America.

  20. A Public-Private-Academic Partnership to Advance Solar Power Forecasting |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Public-Private-Academic Partnership to Advance Solar Power Forecasting A Public-Private-Academic Partnership to Advance Solar Power Forecasting UCAR logo2.jpg The University Corporation for Atmospheric Research (UCAR) will develop a solar power forecasting system that advances the state of the science through cutting-edge research. APPROACH UCAR value chain.png The team will develop a solar power forecasting system that advances the state of the science through

  1. Electron-irradiation induced phase transformation in La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3}: La{sup 3+} displacement in a preserved NASICON framework

    SciTech Connect (OSTI)

    Crosnier-Lopez, M.P. . E-mail: marie-pierre.crosnier-lopez@univ-lemans.fr; Barre, M.; Le Berre, F.; Fourquet, J.L.

    2006-08-15

    The La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} NASICON-type compound (S.G. P3-bar - neutron and X-ray diffraction experiments) is investigated by transmission electron microscopy (TEM) technique, selected area electron diffraction (SAED) and high-resolution electron microscopy (HREM), in order to study locally the lanthanum distribution. An irreversible structural transformation (P-bar -bar -bar ->P-bar c-bar ->R-bar -bar -bar ) is observed, without modification of the atomic content and cell size, as soon as the phase is illuminated by the electron beam. The progressive disappearance of the spots which do not check the R conditions on the SAED patterns is clearly shown along two zone axis, [001] and [100]. This transformation implies the displacement of the two La{sup 3+} cations in a preserved classical [Zr{sub 2}(PO{sub 4}){sub 3}]{sup -} network. This interesting behavior is in good agreement with the La{sup 3+} ionic conductivity observed in La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} (4.09x10{sup -7}Scm{sup -1} at 700 deg. C). To our knowledge, this is the first time that a complete TEM study is done on a NASICON-type phase.

  2. Interface composition between Fe{sub 3}O{sub 4} nanoparticles and GaAs for spintronic applications

    SciTech Connect (OSTI)

    Hihath, Sahar; Kiehl, Richard A.; Benthem, Klaus van

    2014-08-28

    Recent interest in spintronic applications has necessitated the study of magnetic materials in contact with semiconductor substrates; importantly, the structure and composition of these interfaces can influence both device functionality and the magnetic properties. Nanoscale ferromagnet/semiconductor structures are of particular interest. In this study, the interface structure between a monolayer of ferromagnetic magnetite (Fe{sub 3}O{sub 4}) nanoparticles and a GaAs substrate was studied using cross-sectional transmission electron microscopy techniques. It was found that a continuous amorphous oxide interface layer separates the nanoparticles from the GaAs substrate, and that iron diffused into the interface layer forming a compositional gradient. Electron energy-loss near-edge fine structures of the O K absorption edge revealed that the amorphous oxide is composed of γ-Fe{sub 2}O{sub 3} directly underneath the Fe{sub 3}O{sub 4} nanoparticles, followed by a solid solution of Ga{sub 2}O{sub 3} and FeO and mostly Ga{sub 2}O{sub 3} when approaching the buckled oxide/substrate interface. Real-space density functional theory calculations of the dynamical form factor confirmed the experimental observations. The implication of the findings on the optimization of these structures for spin injection is discussed.

  3. RELAP5-3D Developmental Assessment: Comparison of Version 4.2.1i on Linux and Windows

    SciTech Connect (OSTI)

    Paul D. Bayless

    2014-06-01

    Figures have been generated comparing the parameters used in the developmental assessment of the RELAP5-3D code, version 4.2i, compiled on Linux and Windows platforms. The figures, which are the same as those used in Volume III of the RELAP5-3D code manual, compare calculations using the semi-implicit solution scheme with available experiment data. These figures provide a quick, visual indication of how the code predictions differ between the Linux and Windows versions.

  4. (2,2-Bipyridyl)bis(eta5-1,2,3,4,5-pentamethylcyclopentadienyl)Strontium(II)

    SciTech Connect (OSTI)

    Kazhdan, Daniel; Kazhdan, Daniel; Hu, Yung-Jin; Kokai, Akos; Levi, Zerubba; Rozenel, Sergio

    2008-07-03

    In the title compound, the Sr-N distances are 2.624 (3) and 2.676 (3) Angstroms. The Sr-centroid distances are 2.571 and 2.561 Angstroms. The N-C-C-N torsion angle in the bipyridine ligand is 2.2 (4){sup o}. Interestingly, the bipyridine ligand is tilted. The angle between the plane defined by Sr1, N1 and N2 and the plane defined by the 12 atoms of the bipyridine ligand is 10.7{sup o}.

  5. A reaction mechanism for titanium nitride CVD from TiCl{sub 4} and NH{sub 3}

    SciTech Connect (OSTI)

    Larson, R.S.; Allendorf, M.D.

    1995-12-01

    A gas-phase and surface reaction mechanism for the CVD of TiN from TiCl{sub 4} and NH{sub 3} is proposed. The only gas-phase process is complex formation, which can compete with deposition. The surface mechanism postulates the stepwise elimination of Cl and H atoms from TiCl{sub 4} and NH{sub 3}, respectively, to form solid TiN and gaseous HCl. The mechanism also accounts for the change in oxidation state of Ti by allowing for liberation of N{sub 2}. Provided that the surface composition is at steady state, the stoichiometry of the overall reaction is reproduced exactly. In addition, the global kinetic law predicted by the mechanism is successfully fit to new deposition data from a rotating disk reactor and is shown to be consistent with literature results.

  6. Experiment analysis and summary report for LOFT ATWS experiments L9-3 and L9-4

    SciTech Connect (OSTI)

    Adams, J.P.

    1983-09-01

    Experiments L9-3 and L9-4 were conducted on April 7, 1983, and September 24, 1983, respectively, in the Loss-of-Fluid Test facility. These experiments simulated a complete loss-of-feedwater (Experiment L9-3) and a station-blackout (Experiment L9-4) anticipated transient without scram. This report presents the experimental results and compares the data on postexperiment calculations made using the RELAP5/MOD1 computer code. Conclusions are drawn regarding the inherent ability of the plant to shut down the reactor without operator intervention, the effectiveness of a recovery procedure, and the ability of RELAP5/MOD1 to calculate the dominant phenomena.

  7. Use of wind power forecasting in operational decisions.

    SciTech Connect (OSTI)

    Botterud, A.; Zhi, Z.; Wang, J.; Bessa, R.J.; Keko, H.; Mendes, J.; Sumaili, J.; Miranda, V.

    2011-11-29

    The rapid expansion of wind power gives rise to a number of challenges for power system operators and electricity market participants. The key operational challenge is to efficiently handle the uncertainty and variability of wind power when balancing supply and demand in ths system. In this report, we analyze how wind power forecasting can serve as an efficient tool toward this end. We discuss the current status of wind power forecasting in U.S. electricity markets and develop several methodologies and modeling tools for the use of wind power forecasting in operational decisions, from the perspectives of the system operator as well as the wind power producer. In particular, we focus on the use of probabilistic forecasts in operational decisions. Driven by increasing prices for fossil fuels and concerns about greenhouse gas (GHG) emissions, wind power, as a renewable and clean source of energy, is rapidly being introduced into the existing electricity supply portfolio in many parts of the world. The U.S. Department of Energy (DOE) has analyzed a scenario in which wind power meets 20% of the U.S. electricity demand by 2030, which means that the U.S. wind power capacity would have to reach more than 300 gigawatts (GW). The European Union is pursuing a target of 20/20/20, which aims to reduce greenhouse gas (GHG) emissions by 20%, increase the amount of renewable energy to 20% of the energy supply, and improve energy efficiency by 20% by 2020 as compared to 1990. Meanwhile, China is the leading country in terms of installed wind capacity, and had 45 GW of installed wind power capacity out of about 200 GW on a global level at the end of 2010. The rapid increase in the penetration of wind power into power systems introduces more variability and uncertainty in the electricity generation portfolio, and these factors are the key challenges when it comes to integrating wind power into the electric power grid. Wind power forecasting (WPF) is an important tool to help efficiently address this challenge, and significant efforts have been invested in developing more accurate wind power forecasts. In this report, we document our work on the use of wind power forecasting in operational decisions.

  8. Gaussian approximation of lambdaphi/sup 4/ theory in (3+1)-dimensional spatially flat Robertson-Walker space

    SciTech Connect (OSTI)

    Pohle, H.

    1989-03-15

    We investigate lambdaphi/sup 4/ theory within the Gaussian approximation in spatially flat Robertson-Walker space in 3+1 dimensions. After having performed an adiabatic expansion for one of the ansatz functions, we find that the renormalization of the energy-momentum tensor provides two additional constraints which have to be satisfied by the bare couplings. These conditions force the theory to be trivial after renormalization.

  9. The structure of mixed {sup 3}He-{sup 4}He droplets doped with OCS: A density functional approach

    SciTech Connect (OSTI)

    Leal, Antonio; Mateo, David; Pi, Mart; Barranco, Manuel [Departament ECM, Facultat de Fsica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain)] [Departament ECM, Facultat de Fsica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona (Spain); Navarro, Jess [IFIC (CSIC-Universidad de Valencia), P.O. Box 22085, E-46071 Valencia (Spain)] [IFIC (CSIC-Universidad de Valencia), P.O. Box 22085, E-46071 Valencia (Spain)

    2013-11-07

    We have investigated the structure and energetics of mixed {sup 3}He-{sup 4}He droplets doped with a carbonyl sulfide molecule within a density functional approach considering a small but finite temperature of 0.1 K. The molecule is treated as an external field to which the helium droplet is attached. The energetics and appearance of these droplets are discussed for selected numbers of helium atoms, identifying the first magic numbers of the fermionic component.

  10. Properties of some ionic liquids based on1-methyl-3-octylimidazolium and 4-methyl-N-butylpyridinium cations.

    SciTech Connect (OSTI)

    Papaiconomou, Nicolas; Yakelis, Neal; Salminen, Justin; Bergman,Robert; Prausnitz, John M.

    2005-09-29

    Syntheses are reported for ionic liquids containing 1-methyl-3octylimidazolium and 4-methyl-N-butylpyridinium cations, and trifluoromethansulfonate, dicyanamide, bis(trifluoromethylsulfonyl)imide, and nonafluorobutanesulfonate anions. Densities, melting points and glass transition points, solubility in water as well as polarities have been measured. Ionic liquids based on pyridinium cations exhibit higher melting points, lower solubility in water, and higher polarity than those based on imidazolium cations.

  11. Microsoft PowerPoint - 4b-Mound Reindustrilaization Workshop Parts 1-3-Hanford-Adrian_comp

    Office of Legacy Management (LM)

    Reindustrialization Workshop Tri-Cities (Hanford) Case Study Tuesday, May 20, 2014 Tri-City Development Council (TRIDEC) * Formed in 1963 * Private Not-for-Profit * 335 Members * Contracts with 4 Cities, 2 Counties, 3 Port Districts * 42 Member Board of Directors TRIDEC Major Programs * Business Recruitment * Business Retention & Expansion (BRE) * Mid-Columbia Energy Initiative (MCEI) * Federal Programs Long History of Land Transfers Long History of Land Transfers * 1958 City of Richland

  12. Strong enhancement of s -wave superconductivity near a quantum critical point of Ca3Ir4Sn13

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Guguchia, Z.; Khasanov, R.; Chinotti, M.; Li, L.; Wang, Kefeng; Petrovic, C.; Morenzoni, E.

    2015-11-11

    We repormore » t microscopic studies by muon spin rotation/relaxation as a function of pressure of the Ca3Ir4Sn13 and Sr3Ir4Sn13 system displaying superconductivity and a structural phase transition associated with the formation of a charge density wave (CDW). Our findings show a strong enhancement of the superfluid density and a dramatic increase of the pairing strength above a pressure of ≈ 1.6 GPa giving direct evidence of the presence of a quantum critical point separating a superconducting phase coexisting with CDW from a pure superconducting phase. The superconducting order parameter in both phases has the same s-wave symmetry. In spite of the conventional phonon-mediated BCS character of the weakly correlated (Ca1-xSrx)3Ir4Sn13 system the dependence of the effective superfluid density on the critical temperature puts this compound in the “Uemura” plot close to unconventional superconductors. This system exemplifies that conventional BCS superconductors in the presence of competing orders or multi-band structure can also display characteristics of unconventional superconductors.« less

  13. Analysis of Variability and Uncertainty in Wind Power Forecasting: An International Comparison: Preprint

    SciTech Connect (OSTI)

    Zhang, J.; Hodge, B. M.; Gomez-Lazaro, E.; Lovholm, A. L.; Berge, E.; Miettinen, J.; Holttinen, H.; Cutululis, N.; Litong-Palima, M.; Sorensen, P.; Dobschinski, J.

    2013-10-01

    One of the critical challenges of wind power integration is the variable and uncertain nature of the resource. This paper investigates the variability and uncertainty in wind forecasting for multiple power systems in six countries. An extensive comparison of wind forecasting is performed among the six power systems by analyzing the following scenarios: (i) wind forecast errors throughout a year; (ii) forecast errors at a specific time of day throughout a year; (iii) forecast errors at peak and off-peak hours of a day; (iv) forecast errors in different seasons; (v) extreme forecasts with large overforecast or underforecast errors; and (vi) forecast errors when wind power generation is at different percentages of the total wind capacity. The kernel density estimation method is adopted to characterize the distribution of forecast errors. The results show that the level of uncertainty and the forecast error distribution vary among different power systems and scenarios. In addition, for most power systems, (i) there is a tendency to underforecast in winter; and (ii) the forecasts in winter generally have more uncertainty than the forecasts in summer.

  14. 4Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vs relative E(3He, n), E(3He, p); deduced . 4Li deduced levels, . 1996ED02: 4He(p, nX), E 100, 200 MeV; measured inclusive (, En). 4Li deduced evidence for narrow...

  15. Tailoring the coercivity in ferromagnetic ZnO thin films by 3d and 4f elements codoping

    SciTech Connect (OSTI)

    Lee, J. J.; Xing, G. Z. Yi, J. B.; Li, S.; Chen, T.; Ionescu, M.

    2014-01-06

    Cluster free, Co (3d) and Eu (4f) doped ZnO thin films were prepared using ion implantation technique accompanied by post annealing treatments. Compared with the mono-doped ZnO thin films, the samples codoped with Co and Eu exhibit a stronger magnetization with a giant coercivity of 1200 Oe at ambient temperature. This was further verified through x-ray magnetic circular dichroism analysis, revealing the exchange interaction between the Co 3d electrons and the localized carriers induced by Eu{sup 3+} ions codoping. The insight gained with modulating coercivity in magnetic oxides opens up an avenue for applications requiring non-volatility in spintronic devices.

  16. Crystal and molecular structures of the 4-(1H)-pyridone (=L) lanthanide complexes [l brace][GdL(NO[sub 3])[sub 3](H[sub 2]O)][center dot]CH[sub 3]OH[r brace][sub 2] and [DyL[sub 4](NO[sub 3])[sub 2

    SciTech Connect (OSTI)

    Goodgame, D.M.L.; Lalia-Kantouri, M.; Williams, D.J. )

    1993-05-01

    The crystal structures of the title compounds have been determined by single crystal diffraction methods. Crystals of the dysprosium compound are monoclinic, space group P2[sub 1]/c with a = 14.133(4), b = 13.438(5), c = 14.401(4) [Angstrom], [beta] = 103.98(2)[degrees], V = 2654(1) [Angstrom][sup 3], Z = 4, D[sub c] = 1.82 g cm[sup [minus]3], final R = 0.035. The Dy atom is eight-coordinate with a distorted dodecahedral coordination geometry involving two bidentate nitrate groups and four pyridone oxygen atoms. An erbium complex with analogous stoichiometry was also prepared but not structurally characterized. Crystals of the Gd compound are monoclinic, space group P2[sub 1]/n, with a = 11.226(2), b = 9.075(2), c = 16.737(3) [Angstrom], [beta] = 93.88(3)[degrees], V = 1701(1) [Angstrom][sup 3], Z = 2, D[sub c] = 1.91 g cm[sup [minus]3], final R = 0.042. Each Gd atom is bonded to one pyridone oxygen atom, a water molecule and three bidentate nitrate groups. An oxygen atom of one of the bidentate nitrates additionally serves to bridge pairs of Gd atoms so as to form a dinuclear complex in which each Gd atom is nine-coordinate with a tricapped trigonal prismatic geometry. Crystals of L[sub 2]HNO[sub 3] are monoclinic, space group I2/a with a = 12.479(4), b = 6.535(2), c = 14.297(6) [Angstrom], [beta] = 96.07(3)[degrees], V = 1159(1) [Angstrom][sup 3], Z = 4, D[sub c] = 1.45 g cm[sup [minus]3], final R = 0.057. The pyridones are linked in pairs by very short (2.44 [Angstrom]) symmetrical O[center dot][center dot][center dot]H[center dot][center dot][center dot]O hydrogen bonds. Each pair is further linked via a nitrate ion by means of N-H[center dot][center dot][center dot]O(nitrate)[center dot][center dot][center dot]H-N hydrogen bonds, so as to form an extended chevron-like pyridone-pyridone-nitrate-pyridone-pyridone array. Adjacent chains are linked via weak C-H[center dot][center dot][center dot]O(NO[sub 3]) interactions. 5 refs., 7 figs., 7 tabs.

  17. Poly[{mu}{sub 4}-sulfido-tris(thiocyanato-{kappa}N)-tris({mu}{sub 3}-1,2,4-triazolato-{kappa}{sup 3}N{sup 1}:N{sup 2}:N{sup 4})-tetrazinc(II)] : a three-dimensional zinc sulfide coordination polymer.

    SciTech Connect (OSTI)

    Park, H.; Geiser, U.; Halder, G. J.; Schlueter, J. A.; Materials Science Division

    2008-01-01

    The title compound, [Zn{sub 4}(C{sub 2}H{sub 2}N{sub 3}){sub 3}(NCS){sub 3}S]{sub n}, is a three-dimensional coordination polymer consisting of tetrahedral SZn{sub 4} clusters bridged by triazole ligands. In the tetrahedral unit, three Zn atoms are connected to six bridging triazolate ligands, whereas the fourth Zn atom (site symmetry 3m) is bonded to three terminal thiocyanate anions that protrude into the void space created by the Zn-triazolate network. The network prototype is simple cubic, but a strong distortion along a body diagonal and the imposition of a polar direction by the arrangement of the molecular constituents lead to the trigonal space group R3m. This study demonstrates the use of the 3-mercapto-1,2,4-triazole ligand as an effective source for sulfide ions in the synthesis of sulfide-based coordination polymers.

  18. Structural instability of the CoO4 tetrahedral chain in SrCoO3-δ thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Glamazda, A.; Choi, Kwang-yong; Lemmens, P.; Choi, Woo Seok; Jeen, Hyoungjeen; Meyer, Tricia L.; Lee, Ho Nyung

    2015-08-31

    Raman scattering experiments together with detailed lattice dynamic calculations are performed to elucidate crystallographic and electronic peculiarities of SrCoO3-δ films. We observe that the 85 cm-1 phonon mode involving the rotation of a CoO4 tetrahedron undergoes a hardening by 21 cm-1 when the temperature is decreased. In addition, new phonon modes appear at 651.5 and 697.6 cm-1 . The latter modes are attributed to the Jahn-Teller activated modes. Upon cooling from room temperature, all phonons exhibit an exponential-like increase of intensity with a characteristic energy of about 103–107 K. We attribute this phenomenon to an instability of the CoO4 tetrahedralmore » chain structure, which constitutes a key ingredient to understand the electronic and structural properties of the brownmillerite SrCoO2.5.« less

  19. Validation of a 20-year forecast of US childhood lead poisoning: Updated prospects for 2010

    SciTech Connect (OSTI)

    Jacobs, David E. . E-mail: dejacobs@starpower.net; Nevin, Rick

    2006-11-15

    We forecast childhood lead poisoning and residential lead paint hazard prevalence for 1990-2010, based on a previously unvalidated model that combines national blood lead data with three different housing data sets. The housing data sets, which describe trends in housing demolition, rehabilitation, window replacement, and lead paint, are the American Housing Survey, the Residential Energy Consumption Survey, and the National Lead Paint Survey. Blood lead data are principally from the National Health and Nutrition Examination Survey. New data now make it possible to validate the midpoint of the forecast time period. For the year 2000, the model predicted 23.3 million pre-1960 housing units with lead paint hazards, compared to an empirical HUD estimate of 20.6 million units. Further, the model predicted 498,000 children with elevated blood lead levels (EBL) in 2000, compared to a CDC empirical estimate of 434,000. The model predictions were well within 95% confidence intervals of empirical estimates for both residential lead paint hazard and blood lead outcome measures. The model shows that window replacement explains a large part of the dramatic reduction in lead poisoning that occurred from 1990 to 2000. Here, the construction of the model is described and updated through 2010 using new data. Further declines in childhood lead poisoning are achievable, but the goal of eliminating children's blood lead levels {>=}10 {mu}g/dL by 2010 is unlikely to be achieved without additional action. A window replacement policy will yield multiple benefits of lead poisoning prevention, increased home energy efficiency, decreased power plant emissions, improved housing affordability, and other previously unrecognized benefits. Finally, combining housing and health data could be applied to forecasting other housing-related diseases and injuries.

  20. Synthesis, characterization and magnetic property of a new 3D iron phosphite: |C{sub 4}N{sub 3}H{sub 14}|[Fe{sub 3}(HPO{sub 3}){sub 4}F{sub 2}(H{sub 2}O){sub 2}] with intersecting channels

    SciTech Connect (OSTI)

    Qiao Jian; Zhang Lirong; Yu Yang; Li Guanghua; Jiang Tianchan; Huo Qisheng; Liu Yunling

    2009-07-15

    A new open-framework iron (III) phosphite |C{sub 4}N{sub 3}H{sub 14}|[Fe{sub 3}(HPO{sub 3}){sub 4}F{sub 2}(H{sub 2}O){sub 2}] has been solvothermally synthesized by using diethylenetriamine (DETA) as the structure-directing agent. Single-crystal X-ray diffraction analysis reveals that the compound crystallizes in the monoclinic space group C2/c having unit cell parameters a=12.877(3) A, b=12.170(2) A, c=12.159(2) A, beta=93.99(3){sup o}, V=1900.9(7) A{sup 3}, and Z=4 with R{sub 1}=0.0447, wR{sub 2}=0.0958. The complex structure consists of HPO{sub 3} pseudo-tetrahedra and {l_brace}Fe{sub 3}O{sub 14}F{sub 2}{r_brace} trimer building units. The assembly of these building units generates 3D inorganic framework with intersecting 6-, 8-, and 10-ring channels. The DETA cations are located in the 10-ring channels linked by hydrogen bonds. The Moessbauer spectrum shows that there exhibit two crystallographically independent iron (III) atoms. And the magnetic investigation shows the presence of antiferromagnetic interactions. Further characterization of the title compound was performed using X-ray powder diffraction (XRD), infrared (IR) spectra, thermal gravimetric analyses (TGA), inductively coupled plasma (ICP) and elemental analyses. - Graphical abstract: A new three-dimensional iron phosphite with intersecting 6-, 8-, 10-ring channels has been solvothermally synthesized by using diethylenetriamine (DETA) as the structure-directing agent.

  1. Data:Ed681d16-9c5b-4ae3-a097-4da62829c05b | Open Energy Information

    Open Energy Info (EERE)

    under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information...

  2. Heavy fermion Ce{sub 3}Co{sub 4}Sn{sub 13} compound under pressure

    SciTech Connect (OSTI)

    Collave, J. R.; Borges, H. A.; Ramos, S. M.; Hering, E. N.; Mendona-Ferreira, L.; Pagliuso, P. G.

    2015-05-07

    The non-magnetic heavy fermion compound Ce{sub 3}Co{sub 4}Sn{sub 13} was studied under pressure. We report single crystalline measurements of electrical resistivity as a function of temperature ?(T) under pressure. Some characteristic features related to a structural transition (T{sub S}), crystalline field effects (T{sub CEF}), and a low temperature maximum (T{sub max}), possibly connected simultaneously to the onset of Kondo lattice coherence and short range magnetic correlations, were identified in the ?(T) data. A pressure-temperature phase diagram with T{sub S} and T{sub max} was constructed by mapping these features. Like for most Ce-based heavy fermion compounds, T{sub max} moves to higher temperatures with pressure, indicating that it is related to the Kondo energy scale, due to the increase of hybridization induced by pressure. On the other hand, T{sub S}, associated to a superlattice distortion and probably combined with a charge density wave transition, decreases as a function of pressure. However, differently from the Sr{sub 3?x}Ca{sub x}Ir{sub 4}Sn{sub 13} system, where a superlattice quantum phase transition is observed [L. E. Klintberg et al., Phys. Rev. Lett. 109, 237?008 (2012)], in Ce{sub 3}Co{sub 4}Sn{sub 13} T{sub S}???154?K, at ambient pressure (P?=?0), seems to stabilize at around 143?K for P???19 kilobars. We also investigated ?(T) in external magnetic fields, at P?=?0. Negative magnetoresistance and increase of T{sub max} are observed, suggesting suppression of low temperature short range magnetic correlations.

  3. Linkage mapping of the aldo-2, Pax-5, Ambp, and D4H9S3E loci on mouse chromosome 4 in the region of homology with human chromosome 9

    SciTech Connect (OSTI)

    Pilz, A.; Abbott, C. ); Fountain, J. ); Peters, J. )

    1993-12-01

    The genes for aldolase-B (ALDOB), the [alpha]-microglobulin/bikunin precursor (AMBP), the paired box gene PAX5, and the anonymous DNA marker D9S3 map to human chromosome 9 (HSA9). The authors have set out to map the mouse homologues of each of these genes. The mouse genes for Pax-5 and Ambp previously been shown to map to MMU4. They have used an interspecific backcross to confirm these localizations and to map the mouse homologues of ALDOB (Aldo-2) and D9S3 (D4H9S3E) to the same chromosome. These genes were mapped with respect to the four anchor loci for MMU4. In addition, the panel of backcross DNAs had previously been typed for [delta]-amino levulinate dehydratase (Lv), orosomucoid-1 (Orm-1), and hexabranchion (Hxb), the human homologues of which map to HSA9q. The recombination distances [+-] the standard error between each pair of loci are D4Nds4-1.6[+-]1.1-D4H9S3E-4.0[+-]1.7 (Galt) 0.8[+-]0.8-Pax-5-4.8[+-]1.9-Aldo-2-6.3[+-]2.2-(Lv, Orm-1, Ambp)-1.6[+-]1.1-Hxb-4.0[+-]1.7-Tyrp-1-4.8[+-]1.9-Ifa. The data from this study have extended the known region of conserved synteny between human chromosome 9 and mouse chromosome 4. 17 refs., 2 figs.

  4. Operational results of shaft repair by installing stave type cooler at Kimitsu Nos. 3 and 4 blast furnaces

    SciTech Connect (OSTI)

    Oda, Hiroshi; Amano, Shigeru; Sakamoto, Aiichiro; Anzai, Osamu; Nakagome, Michiru; Kuze, Toshisuke; Imuta, Akira

    1997-12-31

    Nos. 3 and 4 blast furnaces in Nippon Steel Corporation Kimitsu Works were both initially fitted with cooling plate systems. With the aging of each furnace, the damage to their respective inner-shaft profiles had become serious. Thus, in order to prevent operational change and prolong the furnace life, the inner-shaft profile of each furnace was repaired by replacing the former cooling plate system with the stave type cooler during the two-week-shutdowns. With this repair, stability of burden descent and gas flow near the wall part of the furnace have been achieved. Thus the prolongation of the furnace life is naturally expected.

  5. 119Sn-NMR investigations on superconducting Ca3Ir4Sn13: Evidence for multigap superconductivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarkar, R.; Petrovic, C.; Bruckner, F.; Gunther, M.; Wang, Kefeng; Biswas, P. K.; Luetkens, H.; Morenzoni, E.; Amato, A.; Klauss, H. -H.

    2015-09-25

    In this study, we report bulk superconductivity (SC) in Ca3Ir4Sn13 by means of 119Sn nuclear magnetic resonance (NMR) experiments. Two classical signatures of BCS superconductivity in spin-lattice relaxation rate (1/T1), namely the Hebel–Slichter coherence peak just below the Tc, and the exponential decay in the superconducting phase, are evident. The noticeable decrease of 119Sn Knight shift below Tc indicates spin-singlet superconductivity. The temperature dependence of the spin-lattice relaxation rate 119(1/T1) is convincingly described by the multigap isotropic superconducting gap. NMR experiments do not witness any sign of enhanced spin fluctuations.

  6. Deliverable 3.1.4 -- Final reservoir report and field-scale models Bluebell Field, Utah, Class 1

    SciTech Connect (OSTI)

    Deo, Milind D.

    2000-07-12

    The objective of this project were to: (1) Simulate parts of the reservoir using the conventional dual-porosity, dual-permeability approach, generate progressively complex reservoir models and use the production history match results to quantify formation damage; (2) Examine the effect of the numerical aspects such as grid sizes and fracture properties on the simulations results; (3) Evaluate the effect of fluid thermodynamic properties on production; and (4) Study effect of inclusion of fractures on variability in production from stochastically generated reservoir models.

  7. Synthesis and characterization of d{sup 10} metal complexes with mixed 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate ligands

    SciTech Connect (OSTI)

    Chen, Zhi-Hao; Zhao, Yue; Chen, Shui-Sheng; Wang, Peng; Sun, Wei-Yin

    2013-06-15

    Seven new coordination polymers [Zn(H{sub 2}L)(mbdc)] (1), [Zn(H{sub 3}L)(btc)] (2), [Zn(H{sub 2}L)(Hbtc)] (3), [Zn(H{sub 2}L)(Hbtc)]H{sub 2}O (4), [Zn{sub 2}(H{sub 2}L)(btc)(?{sub 2}-OH)] (5), [Cd(H{sub 2}L)(mbdc)] (6) and [Cd{sub 3}(H{sub 2}L){sub 2}(btc){sub 2}(H{sub 2}O)]5H{sub 2}O (7) were synthesized by reactions of the corresponding metal salt with rigid ligand 1,3-di(1H-imidazol-4-yl)benzene (H{sub 2}L) and different carboxylic acids of 1,3-benzenedicarboxylic acid (H{sub 2}mbdc) and benzene-1,3,5-tricarboxylic acid (H{sub 3}btc), respectively. The results of X-ray crystallographic analysis indicate that complex 1 is 1D chain while 2 is a (3,3)-connected 2D network with Point (Schlfli) symbol of (4,8{sup 2}). Complexes 3 and 6 are 2D networks, 4 is a 3-fold interpenetrating 3D framework with Point (Schlfli) symbol of (6{sup 5},8) and 5 is a (3,8)-connected 2D network with Point (Schlfli) symbol of (3,4{sup 2}){sub 2}(3{sup 4},4{sup 6},5{sup 6},6{sup 8},7{sup 3},8), while 7 is a (3,10)-connected 3D net with Schlfli symbol of (3,4,5){sub 2}(3{sup 4},4{sup 8},5{sup 18},6{sup 12},7{sup 2},8). The thermal stability and photoluminescence of the complexes were investigated. Furthermore, DFT calculations were performed for 24 to discuss the temperature controlled self-assembly of the complexes. - Graphical abstract: Seven new coordination polymers with multicarboxylate and rigid ditopic 4-imidazole containing ligands have been obtained and found to show different structures and topologies. - Highlights: Metal complexes with diverse structures of 1D chain, 2D network and 3D framework. Mixed ligands of 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate. Photoluminescence property.

  8. US TG 4 Activities of QA Forum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications On the Occurrence of Thermal Runaway in Diode in the J-Box US & Japan TG 4 Activities of QA Forum Wind Forecast Improvement Project Southern Study Area...

  9. X-ray diffraction, spectroscopic and DFT studies of 1-(4-bromophenyl)-3,5-diphenylformazan

    SciTech Connect (OSTI)

    Tezcan, H.; Tokay, N.; Alpaslan, G.; Erdnmez, A.

    2013-12-15

    The crystal structure of 1-(4-bromophenyl)-3,5-diphenylformazan was determined by X-ray single crystal diffraction technique. The crystals are orthorhombic, a = 23.0788(9), b = 7.9606(3), c = 18.6340(12) , Z = 8, sp. gr. Pbca, R{sub 1} = 0.074. The structure was also examined using the density-functional theory. Its structure stability, and frontier molecular orbital components were discussed and the results were compared with X-ray and spectral results. The maximum absorbtion peaks of the UV-vis spectrum of the compound have been calculated using the time-dependent density-functional theory. It was found a good agreement between the calculated and experimental maximum absorption wavelength.

  10. Effect Of EDTA On Luminescence Property Of Eu{sup +3} Doped YPO{sub 4} Nanoparticles

    SciTech Connect (OSTI)

    Parchur, A. K.; Okram, G. S.; Singh, R. A.; Tewari, R.; Pradhan, Lina; Vatsa, R. K.; Ningthoujam, R. S.

    2010-12-01

    Nanoparticles of Eu{sup 3+} doped YPO{sub 4} have been prepared using ethylene glycol (EG). Ethylene diamine tetra acetic acid (EDTA) is used as a complexing agent. X-ray diffraction results show that the nanoparticles are crystalline in tetragonal structure. Based on William-Hall relation, the effective crystallite size and strain developed in lattice are found to be 28 nm and 0.002, respectively. With the addition of EDTA, there is a slight shift towards the lower wavelength in emission peaks. Asymmetric ratio of electric to magnetic dipole transition intensities are found to decrease with addition of EDTA. Emission intensity decreases with EDTA because of decrease of particle size as well as decrease of number of Eu{sup 3+} activators per unit volume. These materials are dispersible in water, which may have potential biological applications.

  11. Table 4

    U.S. Energy Information Administration (EIA) Indexed Site

    Night... 16.6 3.4 5.1 3.1 2.9 1.3 0.8 7.89 Automatic Control... 18.2 3.1 6.9 3.4 3.2 1.1 0.5 7.89 High...

  12. Recovery of oscillatory magneto-resistance in phase separated La{sub 0.3}Pr{sub 0.4}Ca{sub 0.3}MnO{sub 3} epitaxial thin films

    SciTech Connect (OSTI)

    Alagoz, H. S., E-mail: alagoz@ualberta.ca; Jeon, J.; Mahmud, S. T.; Saber, M. M.; Chow, K. H., E-mail: khchow@ualberta.ca; Jung, J., E-mail: jjung@ualberta.ca [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2E1 (Canada); Prasad, B. [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom)] [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom); Egilmez, M. [Department of Physics, American University of Sharjah, Sharjah (United Arab Emirates)] [Department of Physics, American University of Sharjah, Sharjah (United Arab Emirates)

    2013-12-02

    In-plane angular dependent magneto-resistance has been studied in La{sub 0.3}Pr{sub 0.4}Ca{sub 0.3}MnO{sub 3} (LPCMO) manganite thin films deposited on the (100) oriented NdGaO{sub 3}, and (001) oriented SrTiO{sub 3} and LaAlO{sub 3} substrates. At temperatures where the electronic phase separation is the strongest, a metastable irreversible state exists in the films whose resistivity ? attains a large time dependent value. The ? decreases sharply with an increasing angle ? between the magnetic field and the current, and does not display an expected oscillatory cos{sup 2}?/sin{sup 2}? dependence for all films. The regular oscillations are recovered during repetitive sweeping of ? between 0 and 180. We discuss possible factors that could produce these unusual changes in the resistivity.

  13. Forecast of transportation energy demand through the year 2010

    SciTech Connect (OSTI)

    Mintz, M.M.; Vyas, A.D.

    1991-04-01

    Since 1979, the Center for Transportation Research (CTR) at Argonne National Laboratory (ANL) has produced baseline projections of US transportation activity and energy demand. These projections and the methodologies used to compute them are documented in a series of reports and research papers. As the lastest in this series of projections, this report documents the assumptions, methodologies, and results of the most recent projection -- termed ANL-90N -- and compares those results with other forecasts from the current literature, as well as with the selection of earlier Argonne forecasts. This current forecast may be used as a baseline against which to analyze trends and evaluate existing and proposed energy conservation programs and as an illustration of how the Transportation Energy and Emission Modeling System (TEEMS) works. (TEEMS links disaggregate models to produce an aggregate forecast of transportation activity, energy use, and emissions). This report and the projections it contains were developed for the US Department of Energy's Office of Transportation Technologies (OTT). The projections are not completely comprehensive. Time and modeling effort have been focused on the major energy consumers -- automobiles, trucks, commercial aircraft, rail and waterborne freight carriers, and pipelines. Because buses, rail passengers services, and general aviation consume relatively little energy, they are projected in the aggregate, as other'' modes, and used primarily as scaling factors. These projections are also limited to direct energy consumption. Projections of indirect energy consumption, such as energy consumed in vehicle and equipment manufacturing, infrastructure, fuel refining, etc., were judged outside the scope of this effort. The document is organized into two complementary sections -- one discussing passenger transportation modes, and the other discussing freight transportation modes. 99 refs., 10 figs., 43 tabs.

  14. NREL: Energy Analysis - Energy Forecasting and Modeling Staff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Forecasting and Modeling The following includes summary bios of staff expertise and interests in analysis relating to energy economics, energy system planning, risk and uncertainty modeling, and energy infrastructure planning. Team Lead: Nate Blair Administrative Support: Elizabeth Torres Clayton Barrows Dave Bielen Aaron Bloom Greg Brinkman Brian W Bush Stuart Cohen Wesley Cole Paul Denholm Victor Diakov Nicholas DiOrio Aron Dobos Kelly Eurek Janine Freeman Bethany Frew Pieter Gagnon

  15. NREL: Resource Assessment and Forecasting - Data and Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data and Resources National Solar Radiation Database NREL resource assessment and forecasting research information is available from the following sources. Renewable Resource Data Center (RReDC) Provides information about biomass, geothermal, solar, and wind energy resources. Measurement and Instrumentation Data Center Provides irradiance and meteorological data from stations throughout the United States. Baseline Measurement System (BMS) Provides live solar radiation data from approximately 70

  16. Pressure dependence of the exchange interaction in the dimeric single-molecule magnet [Mn{sub 4}O{sub 3}Cl{sub 4}(O{sub 2}CEt){sub 3}(py){sub 3}]{sub 2} from inelastic neutron scattering

    SciTech Connect (OSTI)

    Sieber, A.; Waldmann, O.; Ochsenbein, S. T.; Carver, G.; Guedel, H. U.; Foguet-Albiol, D.; Christou, G.; Mutka, H.; Fernandez-Alonso, F.; Mezouar, M.; Weber, H. P.

    2006-07-01

    The low-lying magnetic excitations in the dimers of single-molecule magnets [Mn{sub 4}O{sub 3}Cl{sub 4}(O{sub 2}CEt){sub 3}(py){sub 3}]{sub 2}, or (Mn{sub 4}){sub 2}, are studied by inelastic neutron scattering as a function of hydrostatic pressure. The anisotropy parameters D and B{sub 0}{sup 4}, which describe each Mn{sub 4} subunit, are essentially pressure independent, while the antiferromagnetic exchange coupling J between the two Mn{sub 4} subunits strongly depends on pressure, with an increase of 42% at 17 kbar. Additional pressure-dependent powder x-ray measurements allow a structural interpretation of the findings.

  17. Analysis of a typical BWR/4 MSIV closure ATWS using RAMONA-3B and TRAC-BD1 codes

    SciTech Connect (OSTI)

    Hsu, C.J.; Neymotin, L.; Saha, P.

    1984-01-01

    Analysis of a typical BWR/4 Anticipated Transient Without Scram (ATWS) has been performed using two advanced, best-estimate computer codes, namely, RAMONA-3B and TRAC-BD1. The transient was initiated by an inadvertant closure of all Main Steam Isolation Valves (MSIVs) with subsequent failure to scram the reactor. However, all other safety features namely, the safety and relief valves, recirculation pump trip, high pressure coolant injection and the standby liquid (boron) control system were assumed to work as designed. No other operator action was assumed. It has been found that both RAMONA-3B (with three-dimensional neutron kinetics) and TRAC-BD1 (with point kinetics) yielded similar results for the global parameters such as reactor power, system pressure and the suppression pool temperature. Both calculations showed that the reactor can be brought to hot shutdown in approximately twenty to twenty-five minutes with borated water mass flow rate of 2.78 kg/s (43 gpm) with 23800 ppM of boron. The suppression pool water temperature (assuming no pool cooling) at this time could be in the range of 170 to 205/sup 0/F. An additional TRAC-BD1 calculation with RAMONA-3B reactor power indicates that the thermal-hydraulic models in RAMONA-3B, although simpler than those in TRAC-BD1, can adequately represent the system behavior during the ATWS-type transient.

  18. A hybrid procedure for MSW generation forecasting at multiple time scales in Xiamen City, China

    SciTech Connect (OSTI)

    Xu, Lilai; Gao, Peiqing; Cui, Shenghui; Liu, Chun

    2013-06-15

    Highlights: ? We propose a hybrid model that combines seasonal SARIMA model and grey system theory. ? The model is robust at multiple time scales with the anticipated accuracy. ? At month-scale, the SARIMA model shows good representation for monthly MSW generation. ? At medium-term time scale, grey relational analysis could yield the MSW generation. ? At long-term time scale, GM (1, 1) provides a basic scenario of MSW generation. - Abstract: Accurate forecasting of municipal solid waste (MSW) generation is crucial and fundamental for the planning, operation and optimization of any MSW management system. Comprehensive information on waste generation for month-scale, medium-term and long-term time scales is especially needed, considering the necessity of MSW management upgrade facing many developing countries. Several existing models are available but of little use in forecasting MSW generation at multiple time scales. The goal of this study is to propose a hybrid model that combines the seasonal autoregressive integrated moving average (SARIMA) model and grey system theory to forecast MSW generation at multiple time scales without needing to consider other variables such as demographics and socioeconomic factors. To demonstrate its applicability, a case study of Xiamen City, China was performed. Results show that the model is robust enough to fit and forecast seasonal and annual dynamics of MSW generation at month-scale, medium- and long-term time scales with the desired accuracy. In the month-scale, MSW generation in Xiamen City will peak at 132.2 thousand tonnes in July 2015 1.5 times the volume in July 2010. In the medium term, annual MSW generation will increase to 1518.1 thousand tonnes by 2015 at an average growth rate of 10%. In the long term, a large volume of MSW will be output annually and will increase to 2486.3 thousand tonnes by 2020 2.5 times the value for 2010. The hybrid model proposed in this paper can enable decision makers to develop integrated policies and measures for waste management over the long term.

  19. Towards a Science of Tumor Forecast for Clinical Oncology

    SciTech Connect (OSTI)

    Yankeelov, Tom; Quaranta, Vito; Evans, Katherine J; Rericha, Erin

    2015-01-01

    We propose that the quantitative cancer biology community make a concerted effort to apply the methods of weather forecasting to develop an analogous theory for predicting tumor growth and treatment response. Currently, the time course of response is not predicted, but rather assessed post hoc by physical exam or imaging methods. This fundamental limitation of clinical oncology makes it extraordinarily difficult to select an optimal treatment regimen for a particular tumor of an individual patient, as well as to determine in real time whether the choice was in fact appropriate. This is especially frustrating at a time when a panoply of molecularly targeted therapies is available, and precision genetic or proteomic analyses of tumors are an established reality. By learning from the methods of weather and climate modeling, we submit that the forecasting power of biophysical and biomathematical modeling can be harnessed to hasten the arrival of a field of predictive oncology. With a successful theory of tumor forecasting, it should be possible to integrate large tumor specific datasets of varied types, and effectively defeat cancer one patient at a time.

  20. Assessment of the possibility of forecasting future natural gas curtailments

    SciTech Connect (OSTI)

    Lemont, S.

    1980-01-01

    This study provides a preliminary assessment of the potential for determining probabilities of future natural-gas-supply interruptions by combining long-range weather forecasts and natural-gas supply/demand projections. An illustrative example which measures the probability of occurrence of heating-season natural-gas curtailments for industrial users in the southeastern US is analyzed. Based on the information on existing long-range weather forecasting techniques and natural gas supply/demand projections enumerated above, especially the high uncertainties involved in weather forecasting and the unavailability of adequate, reliable natural-gas projections that take account of seasonal weather variations and uncertainties in the nation's energy-economic system, it must be concluded that there is little possibility, at the present time, of combining the two to yield useful, believable probabilities of heating-season gas curtailments in a form useful for corporate and government decision makers and planners. Possible remedial actions are suggested that might render such data more useful for the desired purpose in the future. The task may simply require the adequate incorporation of uncertainty and seasonal weather trends into modeling systems and the courage to report projected data, so that realistic natural gas supply/demand scenarios and the probabilities of their occurrence will be available to decision makers during a time when such information is greatly needed.

  1. Buildings Energy Data Book: 5.3 Heating, Cooling, and Ventilation Equipment

    Buildings Energy Data Book [EERE]

    4 Residential Air Conditioner and Heat Pump Cooling Efficiencies 2005 2007 2007 Stock Equipment Type Air Conditioners SEER 10.2 13.0 21.0 Heat Pump - Cooling Air-Source SEER 10.0 13.0 17.0 Ground-Source EER 13.8 16.0 30.0 Heat Pump - Heating Air-Source HSPF 6.8 7.7 10.6 Ground-Source COP 3.4 3.4 5.0 Source(s): EIA/Navigant Consulting, EIA - Technology Forecast Updates - Residential and Commercial Buildings Technologies Reference Case, Second Edition (Revised), Sept. 2007, p. 26-31. Efficiency

  2. First Dark Matter Search Results from a 4-kg CF$_3$I Bubble Chamber Operated in a Deep Underground Site

    SciTech Connect (OSTI)

    Behnke, E.; Behnke, J.; Brice, S.J.; Broemmelsiek, D.; Collar, J.I.; Conner, A.; Cooper, P.S.; Crisler, M.; Dahl, C.E.; Fustin, D.; Grace, E.; /Indiana U., South Bend /Fermilab

    2012-04-01

    New data are reported from the operation of a 4.0 kg CF{sub 3}I bubble chamber in the 6800 foot deep SNOLAB underground laboratory. The effectiveness of ultrasound analysis in discriminating alpha decay background events from single nuclear recoils has been confirmed, with a lower bound of >99.3% rejection of alpha decay events. Twenty single nuclear recoil event candidates and three multiple bubble events were observed during a total exposure of 553 kg-days distributed over three different bubble nucleation thresholds. The effective exposure for single bubble recoil-like events was 437.4 kg-days. A neutron background internal to the apparatus, of known origin, is estimated to account for five single nuclear recoil events and is consistent with the observed rate of multiple bubble events. This observation provides world best direct detection constraints on WIMP-proton spin-dependent scattering for WIMP masses >20 GeV/c{sup 2} and demonstrates significant sensitivity for spin-independent interactions.

  3. Multifunctional Properties of Cyanate Ester Composites with SiO2 Coated Fe3O4 Fillers

    SciTech Connect (OSTI)

    Sun, Weixing; Sun, Wuzhu; Kessler, Michael R.; Bowler, Nicola; Dennis, Kevin W.; McCallum, R. William; Li, Qi; Tan, Xiaoli

    2013-02-22

    SiO2 coated Fe3O4 submicrometer spherical particles (a conducting core/insulating shell configuration) are fabricated using a hydrothermal method and are loaded at 10 and 20 vol % into a bisphenol E cyanate ester matrix for synthesis of multifunctional composites. The dielectric constant of the resulting composites is found to be enhanced over a wide frequency and temperature range while the low dielectric loss tangent of the neat cyanate ester polymer is largely preserved up to 160 ?C due to the insulating SiO2 coating on individual conductive Fe3O4 submicrometer spheres. These composites also demonstrate high dielectric breakdown strengths at room temperature. Dynamic mechanical analysis indicates that the storage modulus of the composite with a 20 vol % filler loading is twice as high as that of neat resin, but the glass transition temperature considerably decreases with increasing filler content. Magnetic measurements reveal a large saturation magnetization and negligibly low coercivity and remanent magnetization in these composites.

  4. A High-Conduction Ge Substituted Li3AsS4 Solid Electrolyte with Exceptional Low Activation Energy

    SciTech Connect (OSTI)

    Sahu, Gayatri [ORNL; Rangasamy, Ezhiylmurugan [ORNL; Li, Juchuan [ORNL; Chen, Yan [ORNL; An, Ke [ORNL; Dudney, Nancy J [ORNL; Liang, Chengdu [ORNL

    2014-01-01

    Lithium-ion conducting solid electrolytes show potential to enable high-energy-density secondary batteries and offer distinctive safety features as an advantage over traditional liquid electrolytes. Achieving the combination of high ionic conductivity, low activation energy, and outstanding electrochemical stability in crystalline solid electrolytes is a challenge for the synthesis of novel solid electrolytes. Herein we report an exceptionally low activation energy (Ea) and high room temperature superionic conductivity via facile aliovalent substitution of Li3AsS4 by Ge, which increased the conductivity by two orders of magnitude as compared to the parent compound. The composition Li3.334Ge0.334As0.666S4 has a high ionic conductivity of 1.12 mScm-1 at 27oC. Local Li+ hopping in this material is accompanied by distinctive low activation energy Ea of 0.17 eV being the lowest of Li+ solid conductors. Furthermore, this study demonstrates the efficacy of surface passivation of solid electrolyte to achieve compatibility with metallic lithium electrodes.

  5. Ultrathin Li3VO4 Nanoribbon/Graphene Sandwich-Like Nanostructures with Ultrahigh Lithium ion Storage Properties

    SciTech Connect (OSTI)

    Lu, Pei-Jun; Liu, Jun N.; Liang, Shuquan; Liu, Jun; Wang, W. J.; Lei, Ming; Tang, Shasha; Yang, Qian

    2015-03-01

    Two-dimensional (2D) "graphene-like" inorganic materials, because of the short lithium ion diffusion path and unique 2D carrier pathways, become a new research focus of the lithium storages. Some "graphene-like" binary compounds, such as, MnO2, MoS2 and VO2 ultrathin nanosheets, have been synthesized by a peeling method, which also exhibit enhanced lithium storage performances. However, it still remains a great challenge to synthesize widely-used lithium-containing ternary oxides with "graphene-like" nanostructures, because the lithium-containing ternary oxides, unlike ternary layered double hydroxides (LDH), are very hard to be directly peeled. Herein, we successfully synthesized ultrathin Li3VO4 nanoribbons with a thickness of about 3 nm by transformation from ultrathin V2O5xH2O nanoribbons, moreover, we achieved the preparation of ultrathin Li3VO4 nanoribbon@graphene sandwich-like nanostructures (LVO/G) through a layer-by-layer assembly method. The unique sandwich-like nanostructures shows not only a high specific reversible capacitance (up to 452.5 mA hg-1 after 200 cycles) but also an excellent cycling performance (with more than 299.2 mA hg-1 of the capacity at 10 C after 1000 cycles) as well as very high rate capability. Such template strategy, using "graphene-like" binary inorganic nanosheets as templates to synthesize lithium-containing ternary oxide nanosheets, may be extended to prepare other ternary oxides with "graphene-like" nanostructures

  6. Spectroscopic studies and structure of 3-methoxy-2 -[(2,4,4,6,6-pentachloro-1,3,5,2{lambda}{sup 5},4{lambda}{sup 5},6{lambda}{sup 5}-triazatriphosphin-2-yl)oxy] benzaldehyde

    SciTech Connect (OSTI)

    Oezay, H.; Yildiz, M.; Uenver, H.; Durlu, T. N.

    2013-01-15

    The compound called 3-methoxy-2- [(2,4,4,6,6-pentachloro-1,3,5,2{lambda}{sup 5},4{lambda}{sup 5},6{lambda}{sup 5}-triazatriphosphin-2-yl)oxy] benzaldehyde has been synthesized from the reaction of 2-hydroxy-3-methoxybenzaldehyde with hexachlorocyclotriphosphazene. It has been characterized by elemental analysis, MS, IR, {sup 1}H NMR, {sup 13}C NMR, {sup 31}P NMR and UV-visible spectroscopic techniques. The structure of the title compound has been determind by X-ray analysis. Crystals are orthorhombic, space group P2{sub 1}2{sub 1}2{sub 1}, Z = 4, a = 7.705(1), b = 12.624(1), c = 17.825(2) A, R{sub 1} = 0.0390 and wR{sub 2} = 0.1074 [I > 2{sigma}(I)], respectively.

  7. Structure tracking aided design and synthesis of Li3V2(PO4)3 nanocrystals as high-power cathodes for lithium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Liping; Bai, Jianming; Gao, Peng; Wang, Xiaoya; Looney, J. Patrick; Wang, Feng

    2015-07-30

    In this study, preparing new electrode materials with synthetic control of phases and electrochemical properties is desirable for battery applications but hardly achievable without knowing how the synthesis reaction proceeds. Herein, we report on structure tracking-aided design and synthesis of single-crystalline Li3V2(PO4)3 (LVP) nanoparticles with extremely high rate capability. A comprehensive investigation was made to the local structural orderings of the involved phases and their evolution toward forming LVP phase using in situ/ex situ synchrotron X-ray and electron-beam diffraction, spectroscopy, and imaging techniques. The results shed light on the thermodynamics and kinetics of synthesis reactions and enabled the design ofmore » a cost-efficient synthesis protocol to make nanocrystalline LVP, wherein solvothermal treatment is a crucial step leading to an amorphous intermediate with local structural ordering resembling that of LVP, which, upon calcination at moderate temperatures, rapidly transforms into the desired LVP phase. The obtained LVP particles are about 50 nm, coated with a thin layer of amorphous carbon and featured with excellent cycling stability and rate capability – 95% capacity retention after 200 cycles and 66% theoretical capacity even at a current rate of 10 C. The structure tracking based method we developed in this work offers a new way of designing battery electrodes with synthetic control of material phases and properties.« less

  8. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  9. 3d-4f spin interaction and field-induced metamagnetism in RCrO{sub 4} (R?=?Ho, Gd, Lu) compounds

    SciTech Connect (OSTI)

    Midya, A.; Khan, N.; Bhoi, D.; Mandal, P.

    2014-05-07

    We observe that the zircon-type RCrO{sub 4} (R?=?Ho, Gd, Lu) compounds exhibit complicated magnetic properties and large magnetic entropy change due to the strong competition between ferromagnetic and antiferromagnetic interactions. For a field change of 7?T, the maximum values of entropy change and refrigerant capacity reach 28?J?kg{sup ?1}?K{sup ?1} and 740?J?kg{sup ?1}, respectively, for GdCrO{sub 4} whereas the corresponding values for HoCrO{sub 4} are 29?J?kg{sup ?1}?K{sup ?1} and 550?J?kg{sup ?1}. For GdCrO{sub 4} compound, the magnetic entropy change is quite large even at low temperatures well below the ferromagnetic transition.

  10. Acoustic emission during the ferroelectric transition Pm3{sup }m to P4mm in BaTiO{sub 3} and the ferroelastic transition R3{sup }m-C2/c in Pb{sub 3}(PO{sub 4}){sub 2}

    SciTech Connect (OSTI)

    Salje, E. K. H.; Dul'kin, E.; Roth, M.

    2015-04-13

    Acoustic emission (AE) spectroscopy without frequency filtering (?broadband AE) and moderate time integration is shown to be sensitive enough to allow the investigation of subtle nano-structural changes in ferroelectric BaTiO{sub 3} and ferroelastic Pb{sub 3}(PO{sub 4}){sub 2}. AE signals during weak phase transitions are compatible with avalanche statistics as observed previously in large-strain systems. While the data are too sparse to determine avalanche exponents, they are well suited to determine other thermodynamic parameters such as transition temperatures and critical stresses.

  11. Part 4

    Office of Environmental Management (EM)

    as set forth below: 4.3.1.1. Standard 55-gallon (208-liter) Drum Standard 55-gallon drums are configured as a 7-pack or as an individual unit. 4.3.1.2. Standard Waste Box (SWB)...

  12. Morphology and chemical termination of HF-etched Si{sub 3}N{sub 4} surfaces

    SciTech Connect (OSTI)

    Liu, Li-Hong; Debenedetti, William J. I.; Peixoto, Tatiana; Gokalp, Sumeyra; Shafiq, Natis; Veyan, Jean-François; Chabal, Yves J.; Michalak, David J.; Hourani, Rami

    2014-12-29

    Several reports on the chemical termination of silicon nitride films after HF etching, an important process in the microelectronics industry, are inconsistent claiming N-H{sub x}, Si-H, or fluorine termination. An investigation combining infrared and x-ray photoelectron spectroscopies with atomic force and scanning electron microscopy imaging reveals that under some processing conditions, salt microcrystals are formed and stabilized on the surface, resulting from products of Si{sub 3}N{sub 4} etching. Rinsing in deionized water immediately after HF etching for at least 30 s avoids such deposition and yields a smooth surface without evidence of Si-H termination. Instead, fluorine and oxygen are found to terminate a sizeable fraction of the surface in the form of Si-F and possibly Si-OH bonds. The relatively unique fluorine termination is remarkably stable in both air and water and could lead to further chemical functionalization pathways.

  13. Nonsymmetric bent-core liquid crystals based on a 1,3,4-thiadiazole core unit and their nematic mesomorphism

    SciTech Connect (OSTI)

    Seltmann, Jens; Marini, Alberto; Mennucci, Benedetta; Dey, Sonal; Kumar, Satyendra; Lehmann, Matthias

    2012-09-06

    The synthesis and thermotropic properties of novel V-shaped molecules having a central 1,3,4-thiadiazole core with a bend-angle of 160 degrees are reported. The compounds consist of a shape-persistent oligo(phenylene ethynylene) scaffold with lateral alkyloxy substituents. One of the terminal aromatic units possesses an alkoxy chain capped by an ethyl ester group while the second terminus is a pyridyl group. They exhibit enantiotropic nematic phases and are characterized by polarized optical microscopy, differential scanning calorimetry, and X-ray diffraction. Results from conoscopy indicate a biaxial nature of the nematic phase near room temperature. DFT calculations of dipole moments and molecular polarizabilities are used to substantiate the experimental findings.

  14. Synthesis and crystal structure studies of ethyl 5-methyl-1, 3-diphenyl-1H-pyrazole-4-carboxylate

    SciTech Connect (OSTI)

    Chandra,; Babu, E. A. Jithesh; Mahendra, M.; Srikantamurthy, N.; Umesha, K. B.

    2014-04-24

    The title compound, C{sub 19}H{sub 18}N{sub 2}O{sub 2}, was investigated by single crystal X-ray diffraction method. It crystallizes in monoclinic class under the space group P2{sub 1}/c with cell parameters a= 8.4593(4) Å, b=15.6284(6) Å, c=12.4579(5) Å, α=90°, β=98.241(3)°, γ=90° and Z=2. The ethoxycarbonyl group is slightly twisted from the pyrazole ring, and adopts syn-periplanar conformation. The crystal structure is stabilized by intermolecular C-H….O hydrogen bonds, which help in stabilizing the crystal structure.

  15. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 4 AND 5 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-30

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 4 and 5 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  16. Structure and optical homogeneity of LiNbO{sub 3}:Zn (0.034.5 mol.%) crystals

    SciTech Connect (OSTI)

    Sidorov, Nikolay E-mail: tepl-na@chemy.kolasc.net.ru E-mail: Jovial1985@yandex.ru Tepljakova, Natalja E-mail: tepl-na@chemy.kolasc.net.ru E-mail: Jovial1985@yandex.ru Gabain, Aleksei E-mail: tepl-na@chemy.kolasc.net.ru E-mail: Jovial1985@yandex.ru Yanichev, Aleksander E-mail: tepl-na@chemy.kolasc.net.ru E-mail: Jovial1985@yandex.ru Palatnikov, Mikhail E-mail: tepl-na@chemy.kolasc.net.ru E-mail: Jovial1985@yandex.ru

    2014-11-14

    Structure and optical homogeneity of LiNbO{sub 3}:Zn (0.034.5 mol.%) crystals were searched by photoinduced light scattering and by Raman spectroscopy. The photorefractive effect depends on Zn{sup 2+} concentration nonmonotonically. Decrease of photorefractive effect is explained by decrease of structure defects with localized electrons. The Zn{sup 2+} cations replace structure defects Nb{sub Li} and Li{sub Nb}, trapping levels appear near the bottom of the conduction band and photo electrons recombine with emission under laser radiation. By the Raman spectra the area of the high structure order is found. In this area the own alternation, the alternation of impurity cations and the vacancies along the polar axis is almost perfect.

  17. Electronic structure and magnetism in g-C{sub 4}N{sub 3} controlled by strain engineering

    SciTech Connect (OSTI)

    Liu, L. Z.; Liu, X. X.; Wu, X. L. E-mail: paul.chu@cityu.edu.hk; Chu, Paul K. E-mail: paul.chu@cityu.edu.hk

    2015-03-30

    Regulation of magnetism and half-metallicity has attracted much attention because of its potential in spintronics. The magnetic properties and electronic structure of graphitic carbon nitride (g-C{sub 4}N{sub 3}) with external strain are determined theoretically based on the density function theory and many-body perturbation theory (G{sub 0}W{sub 0}). Asymmetric deformation induced by uniaxial strain not only regulates the magnetic characteristics but also leads to a transformation from half-metallicity to metallicity. However, this transition cannot occur in the structure with symmetric deformation induced by biaxial strain. Our results suggest the use of strain engineering in metal-free spintronics applications.

  18. Ag/AgBr/g-C{sub 3}N{sub 4}: A highly efficient and stable composite photocatalyst for degradation of organic contaminants under visible light

    SciTech Connect (OSTI)

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Graphical abstract: Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed excellent photocatalytic activities on the degradation of methyl orange (MO) under visible light. The improved photocatalytic performance and stability of Ag/AgBr/g-C{sub 3}N{sub 4} originated from the synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. O{sub 2}?, one of the reactive species, was responsible for the photodegradation of MO compared to H+ and OH. - Highlights: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalyst was reported. Ag/AgBr/g-C{sub 3}N{sub 4} had novel energy band combination between AgBr and g-C{sub 3}N{sub 4}. Synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. Electron trapping role of metallic Ag dominated the stability of Ag/AgBr/g-C{sub 3}N{sub 4}. - Abstract: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts were constructed via depositionprecipitation method and extensively characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UVvis diffuse reflectance spectroscopy (DRS). Under visible light (? > 420 nm), Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed much higher photocatalytic activities than those of Ag/AgBr and g-C{sub 3}N{sub 4} for degradation of methyl orange (MO). 50% Ag/AgBr/g-C{sub 3}N{sub 4} presented the best photocatalytic performance, which was mainly attributed to the synergistic effects of AgBr/g-C{sub 3}N{sub 4} interface and the in situ metallic Ag nanoparticles for efficiently separating electronhole pairs. Furthermore, Ag/AgBr/g-C{sub 3}N{sub 4} remained good photocatalytic activity through 5 times of cycle experiments. Additionally, the radical scavengers experiment indicated that O{sub 2}{sup ?} was the main reactive species for the MO degradation under visible light.

  19. Synthesis of one-dimensional porous Co{sub 3}O{sub 4} nanobelts and their ethanol gas sensing properties

    SciTech Connect (OSTI)

    Che, Hongwei; Liu, Aifeng; Hou, Junxian; Zhang, Xiaoliang; Bai, Yongmei; Mu, Jingbo; Wang, Renliang

    2014-11-15

    Graphical abstract: 1D porous porous Co{sub 3}O{sub 4} nanobelts were synthesized via a facile route without use of any surfactants or organic solvent, exhibiting ethanol gas sensing properties superior to the commercial Co{sub 3}O{sub 4} powders. - Highlights: One-dimensional porous Co{sub 3}O{sub 4} nanobelts were synthesized. The belt-like morphology can be finely controlled via adjusting the reaction parameters. The evolution process of porous Co{sub 3}O{sub 4} nanobelts was investigated. Porous Co{sub 3}O{sub 4} nanobelts exhibit superior ethanol gas sensing properties. - Abstract: In this paper, one-dimensional porous Co{sub 3}O{sub 4} nanobelts were synthesized via a facile template-free hydrothermal method and subsequent the thermal decomposition. Their microstructures and morphologies were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and N{sub 2} adsorptiondesorption techniques. The results indicate that the reaction parameters such as the molar ratio of Co(NO{sub 3}){sub 2}6H{sub 2}O to C{sub 2}H{sub 4}N{sub 4}, the amount of Co(NO{sub 3}){sub 2}6H{sub 2}O, the hydrothermal temperature and time play crucial rules in controlling the microstructures and morphologies of the as-prepared cobalt precursors. A possible formation mechanism was proposed. Moreover, the obtained porous Co{sub 3}O{sub 4} nanobelts exhibit ethanol gas sensing properties superior to the commercial Co{sub 3}O{sub 4} powders at a working temperature of 200 C, suggesting their potential applications as nanosensors.

  20. Facile deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets for highly efficient photocatalysis

    SciTech Connect (OSTI)

    Wang, Peifu; Shi, Penghui; Hong, Yuanchen; Zhou, Xuejun; Yao, Weifeng

    2015-02-15

    Graphical abstract: The photocatalytic performance of Ag{sub 3}PO{sub 4} was highly improved by the in situ deposition of Ag{sub 3}PO{sub 4} particles on graphene-like MoS{sub 2} nanosheets. - Highlights: A novel composite photocatalyst was synthesized by depositing Ag{sub 3}PO{sub 4} on the graphene-like MoS{sub 2} nanosheets. Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a high photocatalytic activity for RhB degradation. Graphene-like MoS{sub 2} nanosheets. MoS{sub 2} nanosheets play an important role in photocatalytic activity by serving as an effective acceptor of the photogenerated carriers. - Abstract: A facile method for the in situ deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets was developed to improve the photocatalytic performance of Ag{sub 3}PO{sub 4} catalysts. The heterostructure of Ag{sub 3}PO{sub 4}/MoS{sub 2} composites was characterized by using X-ray diffraction spectra (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The prepared Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a much higher photocatalytic activity than that of Ag{sub 3}PO{sub 4} for the degradation of Rhodamine B (RhB) under visible light irradiation (>400 nm). The improved photocatalytic activity of Ag{sub 3}PO{sub 4}/MoS{sub 2} is attributed to the efficient separation of photogenerated electronhole pairs in the composite. This result provides a new perspective on the design of high-performance photocatalysts which is promising for energy applications.

  1. Economic Evaluation of Short-Term Wind Power Forecasts in ERCOT: Preliminary Results; Preprint

    SciTech Connect (OSTI)

    Orwig, K.; Hodge, B. M.; Brinkman, G.; Ela, E.; Milligan, M.; Banunarayanan, V.; Nasir, S.; Freedman, J.

    2012-09-01

    Historically, a number of wind energy integration studies have investigated the value of using day-ahead wind power forecasts for grid operational decisions. These studies have shown that there could be large cost savings gained by grid operators implementing the forecasts in their system operations. To date, none of these studies have investigated the value of shorter-term (0 to 6-hour-ahead) wind power forecasts. In 2010, the Department of Energy and National Oceanic and Atmospheric Administration partnered to fund improvements in short-term wind forecasts and to determine the economic value of these improvements to grid operators, hereafter referred to as the Wind Forecasting Improvement Project (WFIP). In this work, we discuss the preliminary results of the economic benefit analysis portion of the WFIP for the Electric Reliability Council of Texas. The improvements seen in the wind forecasts are examined, then the economic results of a production cost model simulation are analyzed.

  2. Typical BWR/4 MSIV closure ATWS analysis using RAMONA-3B code with space-time neutron kinetics

    SciTech Connect (OSTI)

    Neymotin, L.; Saha, P.

    1984-01-01

    A best-estimate analysis of a typical BWR/4 MSIV closure ATWS has been performed using the RAMONA-3B code with three-dimensional neutron kinetics. All safety features, namely, the safety and relief valves, recirculation pump trip, high pressure safety injections and the standby liquid control system (boron injection), were assumed to work as designed. No other operator action was assumed. The results show a strong spatial dependence of reactor power during the transient. After the initial peak of pressure and reactor power, the reactor vessel pressure oscillated between the relief valve set points, and the reactor power oscillated between 20 to 50% of the steady state power until the hot shutdown condition was reached at approximately 1400 seconds. The suppression pool bulk water temperature at this time was predicted to be approx. 96/sup 0/C (205/sup 0/F). In view of code performance and reasonable computer running time, the RAMONA-3B code is recommended for further best-estimate analyses of ATWS-type events in BWRs.

  3. SCALE: A modular code system for performing standardized computer analyses for licensing evaluation. Miscellaneous -- Volume 3, Revision 4

    SciTech Connect (OSTI)

    Petrie, L.M.; Jordon, W.C.; Edwards, A.L. |

    1995-04-01

    SCALE--a modular code system for Standardized Computer Analyses Licensing Evaluation--has been developed by Oak Ridge National Laboratory at the request of the US Nuclear Regulatory Commission. The SCALE system utilizes well-established computer codes and methods within standard analysis sequences that (1) allow an input format designed for the occasional user and/or novice; (2) automate the data processing and coupling between modules, and (3) provide accurate and reliable results. System developments has been directed at problem-dependent cross-section processing and analysis of criticality safety, shielding, heat transfer, and depletion/decay problems. Since the initial release of SCALE in 1980, the code system has been heavily used for evaluation of nuclear fuel facility and package designs. This revision documents Version 4.2 of the system. This manual is divided into three volumes: Volume 1--for the control module documentation, Volume 2--for the functional module documentation, and Volume 3--for the data libraries and subroutine libraries.

  4. Electrosprayed heterojunction WO{sub 3}/BiVO{sub 4} films with nanotextured pillar structure for enhanced photoelectrochemical water splitting

    SciTech Connect (OSTI)

    Mali, Mukund G.; Yoon, Hyun; Yoon, Sam S.; Kim, Min-woo; Swihart, Mark T.; Al-Deyab, Salem S.

    2015-04-13

    We demonstrate that the addition of a tungsten oxide (WO{sub 3}) layer beneath a bismuth vanadate (BiVO{sub 4}) photocatalyst layer with a nanotextured pillar morphology significantly increases the photocurrent density in photoelectrochemical water splitting. The WO{sub 3}-BiVO{sub 4} bilayer films produced a photocurrent of up to 3.3?mA/cm{sup 2} under illumination at 100 mW/cm{sup 2} (AM1.5 spectrum). The bilayer film was characterized by scanning electron microscopy, X-ray diffraction, and photoelectrochemical methods, which confirmed the superiority of the bilayer film in terms of its morphology and charge separation and transport ability. Both WO{sub 3} and BiVO{sub 4} were deposited by electrostatic spraying under open-air conditions, which resulted in nanotextured pillars of BiVO{sub 4} atop a smooth WO{sub 3} film. The optimal coating conditions are also reported.

  5. SU-E-QI-17: Dependence of 3D/4D PET Quantitative Image Features On Noise

    SciTech Connect (OSTI)

    Oliver, J; Budzevich, M; Zhang, G; Latifi, K; Dilling, T; Balagurunathan, Y; Gu, Y; Grove, O; Feygelman, V; Gillies, R; Moros, E; Lee, H.

    2014-06-15

    Purpose: Quantitative imaging is a fast evolving discipline where a large number of features are extracted from images; i.e., radiomics. Some features have been shown to have diagnostic, prognostic and predictive value. However, they are sensitive to acquisition and processing factors; e.g., noise. In this study noise was added to positron emission tomography (PET) images to determine how features were affected by noise. Methods: Three levels of Gaussian noise were added to 8 lung cancer patients PET images acquired in 3D mode (static) and using respiratory tracking (4D); for the latter images from one of 10 phases were used. A total of 62 features: 14 shape, 19 intensity (1stO), 18 GLCM textures (2ndO; from grey level co-occurrence matrices) and 11 RLM textures (2ndO; from run-length matrices) features were extracted from segmented tumors. Dimensions of GLCM were 256256, calculated using 3D images with a step size of 1 voxel in 13 directions. Grey levels were binned into 256 levels for RLM and features were calculated in all 13 directions. Results: Feature variation generally increased with noise. Shape features were the most stable while RLM were the most unstable. Intensity and GLCM features performed well; the latter being more robust. The most stable 1stO features were compactness, maximum and minimum length, standard deviation, root-mean-squared, I30, V10-V90, and entropy. The most stable 2ndO features were entropy, sum-average, sum-entropy, difference-average, difference-variance, difference-entropy, information-correlation-2, short-run-emphasis, long-run-emphasis, and run-percentage. In general, features computed from images from one of the phases of 4D scans were more stable than from 3D scans. Conclusion: This study shows the need to characterize image features carefully before they are used in research and medical applications. It also shows that the performance of features, and thereby feature selection, may be assessed in part by noise analysis.

  6. Summary Report on the Transportation Combustion Engine Efficiency Colloquium Held at USCAR, March 3 and 4, 2010

    SciTech Connect (OSTI)

    Daw, C Stuart; Graves, Ronald L; Caton, Jerald A; Wagner, Robert M

    2010-11-01

    This report summarizes results from an invited two-day colloquium of twenty-nine combustion engine experts from academia, industry, and national labs that was convened March 3rd and 4th, 2010, at the headquarters of the United States Council for Automotive Research (USCAR) in Southfield, Michigan. The colloquium was held at the request of The Department of Energy (DOE) Office of Freedom Car and Vehicle Technologies (OFCVT) to review and assess the current state of transportation combustion engine technology from theoretical and practical perspectives. In the ensuing discussions, the experts were able to reach a broad consensus on some important questions regarding current fuel efficiency limits. They also identified technology barriers and recommended specific near and longer-term R&D priorities for DOE's consideration. Internal combustion engines currently play a dominant role in U.S. transportation and are expected to continue to do so well beyond 2020 [1]. Because of this, the Department of Energy (DOE) has placed high priority on promoting technologies that maximize combustion engine fuel efficiency while minimizing greenhouse gas emissions. Identification of the most promising paths to achieve these goals has recently become more complicated as non-traditional transportation fuels and hybrid electric vehicles become widely available. To reassess the state of combustion engine science and identify new opportunities for technology breakthroughs, an invited colloquium of combustion engine experts was convened on March 3rd and 4th, 2010, at the headquarters of the United States Council for Automotive Research (USCAR) in Southfield, Michigan. The colloquium objectives were: (1) Review and assess the current state of transportation combustion engine technology from both theoretical and practical perspectives; (2) Arrive at a consensus on the theoretical and practical fuel efficiencies that can be achieved; and (3) Recommend near and longer-term R&D priorities for DOE to consider in developing their strategic planning for reaching efficiency goals. This report summarizes the main discussion points and recommendations that emerged from the meeting. Included are areas where there is widespread consensus and areas where there are still important technical uncertainties and wide ranging opinions.

  7. Residential sector end-use forecasting with EPRI-Reeps 2.1: Summary input assumptions and results

    SciTech Connect (OSTI)

    Koomey, J.G.; Brown, R.E.; Richey, R.

    1995-12-01

    This paper describes current and projected future energy use by end-use and fuel for the U.S. residential sector, and assesses which end-uses are growing most rapidly over time. The inputs to this forecast are based on a multi-year data compilation effort funded by the U.S. Department of Energy. We use the Electric Power Research Institute`s (EPRI`s) REEPS model, as reconfigured to reflect the latest end-use technology data. Residential primary energy use is expected to grow 0.3% per year between 1995 and 2010, while electricity demand is projected to grow at about 0.7% per year over this period. The number of households is expected to grow at about 0.8% per year, which implies that the overall primary energy intensity per household of the residential sector is declining, and the electricity intensity per household is remaining roughly constant over the forecast period. These relatively low growth rates are dependent on the assumed growth rate for miscellaneous electricity, which is the single largest contributor to demand growth in many recent forecasts.

  8. Watt-Sun: A Multi-Scale, Multi-Model, Machine-Learning Solar Forecasting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology | Department of Energy Watt-Sun: A Multi-Scale, Multi-Model, Machine-Learning Solar Forecasting Technology Watt-Sun: A Multi-Scale, Multi-Model, Machine-Learning Solar Forecasting Technology IBM logo.png As part of this project, new solar forecasting technology will be developed that leverages big data processing, deep machine learning, and cloud modeling integrated in a universal platform with an open architecture. Similar to the Watson computer system, this proposed technology

  9. Central Wind Forecasting Programs in North America by Regional Transmission Organizations and Electric Utilities: Revised Edition

    SciTech Connect (OSTI)

    Rogers, J.; Porter, K.

    2011-03-01

    The report and accompanying table addresses the implementation of central wind power forecasting by electric utilities and regional transmission organizations in North America. The first part of the table focuses on electric utilities and regional transmission organizations that have central wind power forecasting in place; the second part focuses on electric utilities and regional transmission organizations that plan to adopt central wind power forecasting in 2010. This is an update of the December 2009 report, NREL/SR-550-46763.

  10. Integration of Behind-the-Meter PV Fleet Forecasts into Utility Grid System

    Office of Environmental Management (EM)

    Operations | Department of Energy Integration of Behind-the-Meter PV Fleet Forecasts into Utility Grid System Operations Integration of Behind-the-Meter PV Fleet Forecasts into Utility Grid System Operations Clean Power Research logo.jpg This project will address the need for a more accurate approach to forecasting net utility load by taking into consideration the contribution of customer-sited PV energy generation. Tasks within the project are designed to integrate novel PV power

  11. The Value of Improved Short-Term Wind Power Forecasting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Value of Improved Short- Term Wind Power Forecasting B.-M. Hodge and A. Florita National Renewable Energy Laboratory J. Sharp Sharply Focused, LLC M. Margulis and D. Mcreavy Lockheed Martin Technical Report NREL/TP-5D00-63175 February 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory (NREL)

  12. Value of Improved Wind Power Forecasting in the Western Interconnection (Poster)

    SciTech Connect (OSTI)

    Hodge, B.

    2013-12-01

    Wind power forecasting is a necessary and important technology for incorporating wind power into the unit commitment and dispatch process. It is expected to become increasingly important with higher renewable energy penetration rates and progress toward the smart grid. There is consensus that wind power forecasting can help utility operations with increasing wind power penetration; however, there is far from a consensus about the economic value of improved forecasts. This work explores the value of improved wind power forecasting in the Western Interconnection of the United States.

  13. Report of the external expert peer review panel: DOE benefits forecasts

    SciTech Connect (OSTI)

    None, None

    2006-12-20

    A report for the FY 2007 GPRA methodology review, highlighting the views of an external expert peer review panel on DOE benefits forecasts.

  14. Fe{sub 3}O{sub 4}/Zeolite nanocomposites synthesized by microwave assisted coprecipitation and its performance in reducing viscosity of heavy oil

    SciTech Connect (OSTI)

    Iskandar, Ferry; Fitriani, Pipit; Merissa, Shanty; Khairurrijal,; Abdullah, Mikrajuddin; Mukti, Rino R.

    2014-02-24

    Fe{sub 3}O{sub 4}/Zeolite nanocomposites have been synthesized via microwave assisted coprecipitation method and show to be efficient in reducing viscosity of heavy oil compared to other Fe{sub 3}O{sub 4}/Zeolite nanocomposites prepared by conventional method. The following precursors such as FeCl{sub 3}?6H{sub 2}O, FeSO{sub 4}?7H{sub 2}O, NH{sub 4}OH, and natural zeolite of heulandite type were used in the sample preparation. In this study, the effect of Fe{sub 3}O{sub 4} composition in the composite and microwave time heating were investigated. Fe{sub 3}O{sub 4}/Zeolite nanocomposites were then characterized to study the influence on crystal structures, morphology and physicochemical properties. The characterization techniques include X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen physisorption. The results show that by increasing the microwave heating time, the degree of nanocomposite intergrowth can be enhanced. The nanocomposite was tested in catalytic aquathermolysis of heavy oil at 200C for 6 h and the Fe{sub 3}O{sub 4}/zeolite of 1 to 4 ratios performed the highest viscosity reduction of heavy oil reaching 92%.

  15. Ag{sub 3}PO{sub 4}/ZnO: An efficient visible-light-sensitized composite with its application in photocatalytic degradation of Rhodamine B

    SciTech Connect (OSTI)

    Liu, Wei; School of Chemistry and Material Science, Huaibei Normal University, Huaibei 235000 ; Wang, Mingliang; Xu, Chunxiang; Chen, Shifu; Fu, Xianliang

    2013-01-15

    Graphical abstract: The free OH radicals generated in the VB of ZnO play the primary role in the visible-light photocatalytic degradation of RhB in Ag{sub 3}PO{sub 4}/ZnO system. The accumulated electrons in the CB of Ag{sub 3}PO{sub 4} can be transferred to O{sub 2} adsorbed on the surface of the composite semiconductors and H{sub 2}O{sub 2} yields. H{sub 2}O{sub 2} reacts with electrons in succession to produce active OH to some extent. Display Omitted Highlights: ? Efficient visible-light-sensitized Ag{sub 3}PO{sub 4}/ZnO composites were successfully prepared. ? Effect of Ag{sub 3}PO{sub 4} content on the catalytic activity of Ag{sub 3}PO{sub 4}/ZnO is studied in detail. ? Rate constant of RhB degradation over Ag{sub 3}PO{sub 4}(3.0 wt.%)/ZnO is 3 times that of Ag{sub 3}PO{sub 4}. ? The active species in RhB degradation are examined by adding a series of scavengers. ? Visible light degradation mechanism of RhB over Ag{sub 3}PO{sub 4}/ZnO is systematically studied. -- Abstract: The efficient visible-light-sensitized Ag{sub 3}PO{sub 4}/ZnO composites with various weight percents of Ag{sub 3}PO{sub 4} were prepared by a facile ball milling method. The photocatalysts were characterized by XRD, DRS, SEM, EDS, XPS, and BET specific area. The OH radicals produced during the photocatalytic reaction was detected by the TAPL technique. The photocatalytic property of Ag{sub 3}PO{sub 4}/ZnO was evaluated by photocatalytic degradation of Rhodamine B under visible light irradiation. Significantly, the results revealed that the photocatalytic activity of the composites was much higher than that of pure Ag{sub 3}PO{sub 4} and ZnO. The rate constant of RhB degradation over Ag{sub 3}PO{sub 4}(3.0 wt.%)/ZnO is 3 times that of single-phase Ag{sub 3}PO{sub 4}. The optimal percentage of Ag{sub 3}PO{sub 4} in the composite is 3.0 wt.%. It is proposed that the OH radicals produced in the valence band of ZnO play the leading role in the photocatalytic degradation of Rhodamine B by Ag{sub 3}PO{sub 4}/ZnO systems under visible light irradiation.

  16. g-C{sub 3}N{sub 4}/NaTaO{sub 3} organicinorganic hybrid nanocomposite: High-performance and recyclable visible light driven photocatalyst

    SciTech Connect (OSTI)

    Kumar, Santosh; Kumar, Bharat; Surendar, T.; Shanker, Vishnu

    2014-01-01

    Graphical abstract: High-performance and recyclable visible-light driven g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposite photocatalysts have been prepared by a facile ultrasonic dispersion method. The hybrid nanocomposite photocatalyst can be promising photocatalytic material for practical application in water splitting and environmental remediation. - Highlights: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites as a high performance and recyclable photocatalysts. These catalysts exhibited significantly enhanced photocatalytic activity under UVvisible light irradiation. More attractively, dramatic activity is generated under visible light irradiation due to the g-C{sub 3}N{sub 4} loaded. Interestingly, the as-prepared hybrid nanocomposites possess high reusability. - Abstract: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposites have been prepared by a facile ultrasonic dispersion method. Our results clearly show the formation of interface between NaTaO{sub 3} and g-C{sub 3}N{sub 4} and further loading of g-C{sub 3}N{sub 4} did not affect the crystal structure and morphology of NaTaO{sub 3}. The g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites exhibited enhanced photocatalytic performance for the degradation of Rhodamine B under UVvisible and visible light irradiation compared to pure NaTaO{sub 3} and Degussa P25. Interestingly, the visible light photocatalytic activity is generated due to the loading of g-C{sub 3}N{sub 4}. A mechanism is proposed to discuss the enhanced photocatalytic activity based on trapping experiments of photoinduced radicals and holes. Under visible light irradiation, electron excited from the valance band (VB) to conduction band (CB) of g-C{sub 3}N{sub 4} could directly inject into the CB of NaTaO{sub 3}, making g-C{sub 3}N{sub 4}/NaTaO{sub 3} visible light driven photocatalyst. Since the as-prepared hybrid nanocomposites possess high reusability therefore it can be promising photocatalyst for environmental applications.

  17. Net-structured Co{sub 3}O{sub 4}/C nanosheet array with enhanced electrochemical performance toward lithium storage

    SciTech Connect (OSTI)

    Yu, Y.X.; Liu, X.Y.; Xia, X.H.; Xiong, Q.Q.; Wang, X.L.; Gu, C.D.; Tu, J.P.

    2014-03-01

    Graphical abstract: - Highlights: Co{sub 3}O{sub 4}/C nanosheet array on nickel foam was synthesized by hydrothermal method, followed by magnetron sputtering of a carbon layer. The Co{sub 3}O{sub 4}/C nanosheet array electrode delivers an initial discharge capacity of 1340.4 mAh g{sup ?1} at 0.1 C. After 100 cycles, the capacity retention of the Co{sub 3}O{sub 4}/C is 88.8% of its initial discharge capacity. The enhanced electrochemical performances are attributed to the porous nanosheet array and the thin carbon layer coated on Co{sub 3}O{sub 4} nanosheets. - Abstract: Freestanding Co{sub 3}O{sub 4}/C nanosheet array growing directly on nickel foam substrate was synthesized using a hydrothermal approach, followed by a direct current magnetron sputtering of a thin carbon layer. The Co{sub 3}O{sub 4} nanosheets with thicknesses of 1020 nm are interconnected with each other, forming a highly open net-structure. The Co{sub 3}O{sub 4}/C nanosheet array electrode delivers an initial discharge capacity of 1340.4 mAh g{sup ?1} at 0.1 C, and maintains a high specific capacity of 912.1 mAh g{sup ?1} at room temperature and can still remain 88.8% of its initial discharge capacity at 55 C at 1 C after 100 cycles. The enhanced electrochemical performances are attributed to the porous nanosheet array and the thin carbon layer coated on Co{sub 3}O{sub 4} nanosheets, which cannot only facilitate Li{sup +} and electron transportation in the electrode, but also improve its structure stability during cycling.

  18. Enhanced visible light photocatalytic hydrogen evolution of sulfur-doped polymeric g-C{sub 3}N{sub 4} photocatalysts

    SciTech Connect (OSTI)

    Ge, Lei; Han, Changcun; Xiao, Xinlai; Guo, Lele; Li, Yujing

    2013-10-15

    Graphical abstract: - Highlights: Sulfur-doped g-C{sub 3}N{sub 4} was prepared using thiourea as sulfur source. The sulfur-doped g-C{sub 3}N{sub 4} shows significantly enhanced H{sub 2} evolution activity. The doped sulfur species plays key roles in the improvement of H{sub 2} production. Photocatalytic mechanism is proposed based on the experimental results. The mechanism is confirmed by PL spectra and transient photocurrent curves. - Abstract: Visible light-activated sulfur-doped g-C{sub 3}N{sub 4} photocatalysts were successfully synthesized using thiourea as sulfur source. The obtained photocatalysts were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microcopy, ultravioletvisible diffuse reflection spectroscopy, X-ray photoelectron spectroscopy, photoluminescence spectroscopy and transient photocurrent response. The sulfur-doped g-C{sub 3}N{sub 4} photocatalysts show beneficial effects on visible light absorption, electronhole pair generation and separation. The sulfur species doped in the samples was identified as S{sup 2?} to replace N atoms in the g-C{sub 3}N{sub 4} framework. The photocatalytic activities of the sulfur-doped g-C{sub 3}N{sub 4} under visible light were evaluated by hydrogen evolution from water splitting in aqueous solution containing methanol. The sulfur-doped g-C{sub 3}N{sub 4} photocatalyst showed the highest photocatalytic performance with H{sub 2} evolution rate of 12.16 ?mol h{sup ?1}, about 6 times higher than un-doped g-C{sub 3}N{sub 4}. It can be concluded that the sulfur species play a vital role and act as active sites in the photocatalytic reaction. This novel sulfur-doped g-C{sub 3}N{sub 4} can be potentially used in energy and environmental applications.

  19. Experimental results of direct containment heating by high-pressure melt ejection into the Surtsey vessel: The DCH-3 and DCH-4 tests

    SciTech Connect (OSTI)

    Allen, M.D.; Pilch, M.; Brockmann, J.E.; Tarbell, W.W. ); Nichols, R.T. ); Sweet, D.W. )

    1991-08-01

    Two experiments, DCH-3 and DCH-4, were performed at the Surtsey test facility to investigate phenomena associated with a high-pressure melt ejection (HPME) reactor accident sequence resulting in direct containment heating (DCH). These experiments were performed using the same experimental apparatus with identical initial conditions, except that the Surtsey test vessel contained air in DCH-3 and argon in DCH-4. Inerting the vessel with argon eliminated chemical reactions between metallic debris and oxygen. Thus, a comparison of the pressure response in DCH-3 and DCH-4 gave an indication of the DCH contribution due to metal/oxygen reactions. 44 refs., 110 figs., 43 tabs.

  20. Environmental management technology demonstration and commercialization: Tasks 2, 3, 4, and 8. Semiannual report, October 1994--March 1995

    SciTech Connect (OSTI)

    Hawthorne, S.B.; Ness, R.O. Jr.; Nowok, J.W.; Pflughoeft-Hassett, D.; Hurley, J.P.; Steadman, E.N.

    1995-05-01

    The objective of the Environmental Management program at the Energy and Environmental Research Center (EERC) is to develop, demonstrate, and commercialize technologies that address the environmental management needs of contaminated sites, including characterization, sensors, and monitoring; low-level mixed waste processing; material disposition technology; improved waste forms; in situ containment and remediation; and efficient separation technologies for radioactive wastes. Task 2 is the extraction and analysis of pollutant organics from contaminated solids using off-line supercritical fluid extraction (SFE) and on-line SFE-infrared spectroscopy. Task 3, pyrolysis of plastics, has as its objectives to develop a commercial process to significantly reduce the volume of mixed-plastics-paper-resin waste contaminated with low-level radioactive material; concentrate contaminants in a collectible form; and determine the distribution and form of contaminants after pyrolysis of the mixed waste. Task 4, stabilization of vitrified wastes, has as its objectives to (1) demonstrate a waste vitrification procedure for enhanced stabilization of waste materials and (2) develop a testing protocol to understand the long-term leaching behavior of the stabilized waste form. The primary objective of Task 8, Management and reporting, is coordination of this project with other programs and opportunities. In addition, management oversight will be maintained to ensure that tasks are completed and coordinated as planned and that deliverables are submitted in a timely manner. Accomplishments to date is each task are described. 62 refs.