National Library of Energy BETA

Sample records for fluoride hf produced

  1. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  2. Method of making porous ceramic fluoride

    DOE Patents [OSTI]

    Reiner, Robert H. (Knoxville, TN); Holcombe, Cressie E. (Farragut, TN)

    1990-01-01

    A process for making a porous ceramic composite where fumed silica particles are coated with a nitrate, preferably aluminum nitrate. Next the nitrate is converted to an oxide and formed into a desired configuration. This configuration is heated to convert the oxide to an oxide silicate which is then react with HF, resulting in the fluoride ceramic, preferably aluminum fluoride.

  3. Hydrolysis of ZrCl4 and HfCl4: The Initial Steps in the High-Temperature Oxidation of Metal Chlorides to Produce ZrO2 and HfO2

    SciTech Connect (OSTI)

    Fang, Zongtang; Dixon, David A.

    2013-03-08

    The gas-phase hydrolysis of MCl4 (M = Zr, Hf) to produce the initial particles on the way to zirconia and hafnia nanoparticles has been studied with electronic structure theory. The potential energy surfaces, the themochemistry of the reaction species, and the reaction paths for the initial steps of MCl4 reacting with H2O have been calculated. The hydrolysis of MCl4 at higher temperatures begins with the formation of oxychlorohydroxides followed by the elimination of HCl instead of the direct production of MOCl2 and HCl or MO2 and HCl due to the substantial endothermicities associated with the formation of gas-phase MO2. The structural properties and heats of formation of the reactants and products are consistent with the available experimental results. A number of metal oxychlorides (oxychlorohydroxides) intermediate clusters have been studied to assess their role in the production of MO2 nanoparticles. The calculated clustering reaction energies of those intermediates are highly exothermic, so they could be readily formed in the hydrolysis process. These intermediate clusters can be formed exothermically from metal oxychlorohydroxides by the elimination of one HCl or H2O molecule. Our calculations show that the mechanisms leading to the formation of MO2 nanoparticles are complicated and are accompanied by the potential production of a wide range of intermediates, as found for the production of TiO2 particles from the high-temperature oxidation of TiCl4.

  4. Divalent fluoride doped cerium fluoride scintillator

    DOE Patents [OSTI]

    Anderson, David F. (630 Sylvan Pl., Batavia, IL 60510); Sparrow, Robert W. (28 Woodlawn Dr., Sturbridge, MA 01566)

    1991-01-01

    The use of divalent fluoride dopants in scintillator materials comprising cerium fluoride is disclosed. The preferred divalent fluoride dopants are calcium fluoride, strontium fluoride, and barium fluoride. The preferred amount of divalent fluoride dopant is less than about two percent by weight of the total scintillator. Cerium fluoride scintillator crystals grown with the addition of a divalent fluoride have exhibited better transmissions and higher light outputs than crystals grown without the addition of such dopants. These scintillators are useful in radiation detection and monitoring applications, and are particularly well suited for high-rate applications such as positron emission tomography (PET).

  5. Improved Growth of High-Temperature Superconductors with HF Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control - Energy Innovation Portal Electricity Transmission Electricity Transmission Find More Like This Return to Search Improved Growth of High-Temperature Superconductors with HF Pressure Control Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication A new method of HF control for synthesizing YBCO using the BaF2 ex situ process (83 KB) Graphical representation of the removal of hydrogen fluoride gas by the absorber during growth of

  6. Magnesium fluoride recovery method

    DOE Patents [OSTI]

    Gay, Richard L.; McKenzie, Donald E.

    1989-01-01

    A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

  7. Fluorohydrogenate Cluster Ions in the Gas Phase: Electrospray Ionization Mass Spectrometry of the [1-Ethyl-3-methylimidazolium+][F(HF)2.3] Ionic Liquid

    SciTech Connect (OSTI)

    Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

    2013-12-01

    Electrospray ionization of the fluorohydrogenate ionic liquid [1-ethyl-3-methylimidazolium][F(HF)2.3] ionic liquid was conducted to understand the nature of the anionic species as they exist in the gas phase. Abundant fluorohydrogenate clusters were produced; however, the dominant anion in the clusters was [FHF-], and not the fluoride-bound HF dimers or trimers that are seen in solution. Density functional theory (DFT) calculations suggest that HF molecules are bound to the clusters by about 30 kcal/mol. The DFT-calculated structures of the [FHF-]-bearing clusters show that the favored interactions of the anions are with the methynic and acetylenic hydrogen atoms on the imidazolium cation, forming planar structures similar to those observed in the solid state. A second series of abundant negative ions was also formed that contained [SiF5-] together with the imidazolium cation and the fluorohydrogenate anions that originate from reaction of the spray solution with silicate surfaces.

  8. Methods of controlling hydrogen fluoride pressure during chemical fabrication processes

    DOE Patents [OSTI]

    Solovyov, Vyacheslav (Rocky Point, NY); Wiesmann, Harold (Stony Brook, NY)

    2009-11-24

    The present invention is a method for producing a crystalline end-product. The method comprising exposing a fluoride-containing precursor to a hydrogen fluoride absorber under conditions suitable for the conversion of the precursor into the crystalline end-product.

  9. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM

    Office of Scientific and Technical Information (OSTI)

    FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS (Technical Report) | SciTech Connect Technical Report: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Citation Details In-Document Search Title: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Authors: Sense, Karl A. ; Stone, Richard W. ; Filbert, Jr., Robert B. Publication Date: 1957-07-27 OSTI Identifier: 12484781 Report Number(s):

  10. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM

    Office of Scientific and Technical Information (OSTI)

    FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS (Technical Report) | SciTech Connect Technical Report: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS Citation Details In-Document Search Title: VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND LITHIUM FLUORIDE-ZIRCONIUM FLUORIDE SYSTEMS × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and

  11. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  12. Fluorination of amorphous thin-film materials with xenon fluoride

    DOE Patents [OSTI]

    Weil, R.B.

    1987-05-01

    A method is disclosed for producing fluorine-containing amorphous semiconductor material, preferably comprising amorphous silicon. The method includes depositing amorphous thin-film material onto a substrate while introducing xenon fluoride during the film deposition process.

  13. Fluorination of amorphous thin-film materials with xenon fluoride

    DOE Patents [OSTI]

    Weil, Raoul B. (Haifa, IL)

    1988-01-01

    A method is disclosed for producing fluorine-containing amorphous semiconductor material, preferably comprising amorphous silicon. The method includes depositing amorphous thin-film material onto a substrate while introducing xenon fluoride during the film deposition process.

  14. Hf-irJ

    Office of Legacy Management (LM)

    Hf-irJ jnj,4 States Governmen Department of Energy Inemorandum DOTE: DAY o 1S5a . 7 EPY TO F . O 0 NE-24 SUJEC': Authorization for Remedial Action of Residential Vicinity Properties at * ~ Lodi, New Jersey TO: Joe LaGrone, Manager Oak Ridge Operations Office ~* The data in the attached draft Radiological Survey Reports conducted by Bechtel National, Inc. (BNI) indicates that the soil concentration on these vicinity properties exceed the Department of Energy remedial action guidelines. Based on

  15. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

    DOE Patents [OSTI]

    Bartlett, Neil (Orinda, CA); Whalen, J. Marc (Corning, NY); Chacon, Lisa (Corning, NY)

    2000-12-12

    A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

  16. Corrosion of high Ni-Cr alloys and Type 304L stainless steel in HNO/sub 3/-HF

    SciTech Connect (OSTI)

    Ondrejcin, R.S.; McLaughlin, B.D.

    1980-04-01

    Nineteen alloys were evaluated as possible materials of construction for steam heating coils, the dissolver vessel, and the off-gas system of proposed facilities to process thorium and uranium fuels. Commercially available alloys were found that are satisfactory for all applications. With thorium fuel, which requires HNO/sub 3/-HF for dissolution, the best alloy for service at 130/sup 0/C when complexing agents for fluoride are used is Inconel 690; with no complexing agents at 130/sup 0/C, Inconel 671 is best. At 95/sup 0/C, six other alloys tested would be adequate: Haynes 25, Ferralium, Inconel 625, Type 304L stainless steel, Incoloy 825, and Haynes 20 (in order of decreasing preference); based on composition, six untested alloys would also be adequate. The ions most effective in reducing fluoride corrosion were the complexing agents Zr/sup 4 +/ and Th/sup 4 +/; Al/sup 3 +/ was less effective. With uranium fuel, modestly priced Type 304L stainless steel is adequate. Corrosion will be most severe in HNO/sub 3/-HF used occasionally for flushing and in solutions of HNO/sub 3/ and corrosion products (ferric and dichromate ions). HF corrosion can be minimized by complexing the fluoride ion and by passivation of the steel with strong nitric acid. Corrosion caused by corrosion products can be minimized by operating at lower temperatures.

  17. Evolution of magnetic properties and microstructure of Hf{sub 2}Co{sub 11}B

    Office of Scientific and Technical Information (OSTI)

    alloys (Journal Article) | SciTech Connect Journal Article: Evolution of magnetic properties and microstructure of Hf{sub 2}Co{sub 11}B alloys Citation Details In-Document Search Title: Evolution of magnetic properties and microstructure of Hf{sub 2}Co{sub 11}B alloys Amorphous Hf{sub 2}Co{sub 11}B alloys produced by melt-spinning have been crystallized by annealing at 500-800 °C, and the products have been investigated using magnetization measurements, x-ray diffraction, and scanning

  18. Separation of High Order Harmonics with Fluoride Windows

    SciTech Connect (OSTI)

    Allison, Tom; van Tilborg, Jeroen; Wright, Travis; Hertlein, Marcus; Falcone, Roger; Belkacem, Ali

    2010-08-02

    The lower orders produced in high order harmonic generation can be effciently temporally separated into monochromatic pulses by propagation in a Fluoride window while still preserving their femtosecond pulse duration. We present calculations for MgF2, CaF2, and LiF windows for the third, fifth, and seventh harmonics of 800 nm. We demonstrate the use of this simple and inexpensive technique in a femtosecond pump/probe experiment using the fifth harmonic.

  19. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the ...

  20. Method for fluorination of actinide fluorides and oxyfluorides using O/sub 2/F/sub 2/

    DOE Patents [OSTI]

    Eller, P.G.; Malm, J.G.; Penneman, R.A.

    1984-08-01

    The present invention relates generally to methods of fluorination and more particularly to the use of O/sub 2/F/sub 2/ for the preparation of actinide hexafluorides, and for the extraction of deposited actinides and fluorides and oxyfluorides thereof from reaction vessels. The experiments set forth hereinabove demonstrate that the room temperature or below use of O/sub 2/F/sub 2/ will be highly beneficial for the preparation of pure actinide hexafluorides from their respective tetrafluorides without traces of HF being present as occurs using other fluorinating agents: and decontamination of equipment previously exposed to actinides: e.g., walls, feed lines, etc.

  1. Ternary ceramic alloys of Zr-Ce-Hf oxides

    DOE Patents [OSTI]

    Becher, P.F.; Funkenbusch, E.F.

    1990-11-20

    A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

  2. Ternary ceramic alloys of ZR-CE-HF oxides

    DOE Patents [OSTI]

    Becher, Paul F. (Oak Ridge, TN); Funkenbusch, Eric F. (White Bear Lake, MN)

    1990-01-01

    A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

  3. Rare earth/iron fluoride and methods for making and using same

    DOE Patents [OSTI]

    Schmidt, Frederick A. (Ames, IA); Wheelock, John T. (Neveda, IA); Peterson, David T. (Ames, IA)

    1991-12-17

    A particulate mixture of Fe.sub.2 O.sub.3 and RE.sub.2 O.sub.3, where RE is a rare earth element, is reacted with an excess of HF acid to form an insoluble fluoride compound (salt) comprising REF.sub.3 and FeF.sub.3 present in solid solution in the REF.sub.3 crystal lattice. The REF.sub.3 /FeF.sub.3 compound is dried to render it usable as a reactant in the thermite reduction process as well as other processes which require an REF.sub.3 /FeF.sub.3 mixture. The dried REF.sub.3 /FeF.sub.3 compound comprises about 5 weight % to about 40 weight % of FeF.sub.3 and the balance REF.sub.3 to this end.

  4. Infrared study on room-temperature atomic layer deposition of HfO{sub 2} using tetrakis(ethylmethylamino)hafnium and remote plasma-excited oxidizing agents

    SciTech Connect (OSTI)

    Kanomata, Kensaku [Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Japan and Japan Society for the Promotion of Science, 5-3-1 Kojimachi, Chiyoda-ku, Tokyo 102-0083 (Japan); Ohba, Hisashi; Pungboon Pansila, P.; Ahmmad, Bashir; Kubota, Shigeru; Hirahara, Kazuhiro; Hirose, Fumihiko, E-mail: fhirose@yz.yamagata-u.ac.jp [Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510 (Japan)

    2015-01-01

    Room-temperature atomic layer deposition (ALD) of HfO{sub 2} was examined using tetrakis (ethylmethylamino)hafnium (TEMAH) and remote plasma-excited water and oxygen. A growth rate of 0.26?nm/cycle at room temperature was achieved, and the TEMAH adsorption and its oxidization on HfO{sub 2} were investigated by multiple internal reflection infrared absorption spectroscopy. It was observed that saturated adsorption of TEMAH occurs at exposures of ?1??10{sup 5}?L (1 L?=?1??10{sup ?6} Torr s) at room temperature, and the use of remote plasma-excited water and oxygen vapor is effective in oxidizing the TEMAH molecules on the HfO{sub 2} surface, to produce OH sites. The infrared study suggested that HfOH plays a role as an adsorption site for TEMAH. The reaction mechanism of room temperature HfO{sub 2} ALD is discussed in this paper.

  5. Quantum mechanical force field for hydrogen fluoride with explicit electronic polarization

    SciTech Connect (OSTI)

    Mazack, Michael J. M.; Gao, Jiali

    2014-05-28

    The explicit polarization (X-Pol) theory is a fragment-based quantum chemical method that explicitly models the internal electronic polarization and intermolecular interactions of a chemical system. X-Pol theory provides a framework to construct a quantum mechanical force field, which we have extended to liquid hydrogen fluoride (HF) in this work. The parameterization, called XPHF, is built upon the same formalism introduced for the XP3P model of liquid water, which is based on the polarized molecular orbital (PMO) semiempirical quantum chemistry method and the dipole-preserving polarization consistent point charge model. We introduce a fluorine parameter set for PMO, and find good agreement for various gas-phase results of small HF clusters compared to experiments and ab initio calculations at the M06-2X/MG3S level of theory. In addition, the XPHF model shows reasonable agreement with experiments for a variety of structural and thermodynamic properties in the liquid state, including radial distribution functions, interaction energies, diffusion coefficients, and densities at various state points.

  6. Method for decontamination of nickel-fluoride-coated nickel containing actinide-metal fluorides

    DOE Patents [OSTI]

    Windt, Norman F. (Paducah, KY); Williams, Joe L. (Paducah, KY)

    1983-01-01

    The invention is a process for decontaminating particulate nickel contaminated with actinide-metal fluorides. In one aspect, the invention comprises contacting nickel-fluoride-coated nickel with gaseous ammonia at a temperature effecting nickel-catalyzed dissociation thereof and effecting hydrogen-reduction of the nickel fluoride. The resulting nickel is heated to form a melt and a slag and to effect transfer of actinide metals from the melt into the slag. The melt and slag are then separated. In another aspect, nickel containing nickel oxide and actinide metals is contacted with ammonia at a temperature effecting nickel-catalyzed dissociation to effect conversion of the nickel oxide to the metal. The resulting nickel is then melted and separated as described. In another aspect nickel-fluoride-coated nickel containing actinide-metal fluorides is contacted with both steam and ammonia. The resulting nickel then is melted and separated as described. The invention is characterized by higher nickel recovery, efficient use of ammonia, a substantial decrease in slag formation and fuming, and a valuable increase in the service life of the furnace liners used for melting.

  7. Dispersion of UO{sub 2}F{sub 2} aerosol and HF vapor in the operating floor during winter ventilation at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W.; Carter, J.C.

    1996-12-30

    The gaseous diffusion process is currently employed at two plants in the US: the Paducah Gaseous Diffusion Plant and the Portsmouth Gaseous Diffusion Plant. As part of a facility-wide safety evaluation, a postulated design basis accident involving large line-rupture induced releases of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant (GDP) is evaluated. When UF{sub 6} is released into the atmosphere, it undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form vaporized hydrogen fluoride (HF) and aerosolized uranyl fluoride (UO{sub 2}F{sub 2}). These reactants disperse in the process building and transport through the building ventilation system. The ventilation system draws outside air into the process building, distributes it evenly throughout the building, and discharges it to the atmosphere at an elevated temperature. Since air is recirculated from the cell floor area to the operating floor, issues concerning in-building worker safety and evacuation need to be addressed. Therefore, the objective of this study is to evaluate the transport of HF vapor and UO{sub 2}F{sub 2} aerosols throughout the operating floor area following B-line break accident in the cell floor area.

  8. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the presentation slides from Arkema at the July 17, 2012, Fuel Cell Technologies Program webinar, "Fuel Cells for Portable Power." PDF icon Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides More Documents & Publications

  9. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  10. MicroPlanet Technology Corp formerly HF Capital Corp | Open Energy...

    Open Energy Info (EERE)

    Technology Corp formerly HF Capital Corp Jump to: navigation, search Name: MicroPlanet Technology Corp (formerly HF Capital Corp) Place: Seattle, Washington Zip: 98104 Sector:...

  11. Rotationally resolved spectroscopy of a librational fundamental band of hydrogen fluoride tetramer

    SciTech Connect (OSTI)

    Blake, Thomas A.; Sharpe, Steven W.; Xantheas, Sotiris S.

    2000-07-08

    The rotationally resolved spectrum of a fundamental band of hydrogen fluoride tetramer has been recorded using a pulsed slit-jet, diode laser spectrometer. The band has a parallel rotational structure and is assigned as the H-F out-of-plane libration fundamental with A{sub u} symmetry. Ninety-five ground state combination differences were fit to a symmetric top Hamiltonian to give the following ground state rotational constants: B{sup ''}=0.132 081(7) cm{sup -1}, D{sub J}{sup ''}=7.1(7)x10{sup -7} cm{sup -1}, D{sub JK}{sup ''}=-9(2)x10{sup -7} cm{sup -1}, H{sub JJJ}{sup ''}=6(2)x10{sup -10} cm{sup -1}, H{sub JJK}{sup ''}=9(7)x10{sup -10} cm{sup -1}, H{sub JKK}{sup ''}=-1.3(8)x10{sup -10} cm{sup -1}. A total of 190 transitions were fit to determine the upper state spectroscopic constants: v{sub 4}=714.7849(1) cm{sup -1}, B{sup '}=0.129 634(5) cm{sup -1}, {delta}(C-B)=0.001 344 cm{sup -1}, D{sub J}{sup '}=6.4(5)x10{sup -7} cm{sup -1}, D{sub JK}{sup '}=-4.5(6)x10{sup -7} cm{sup -1}, {delta}D{sub K}=2.92(8)x10{sup -6} cm{sup -1}, H{sub JJJ}{sup '}=3(1)x10{sup -10} cm{sup -1}, H{sub JKK}{sup '}=-1.55(6)x10{sup -8} cm{sup -1}; {delta}H{sub KKK}=-4.65(6)x10{sup -8} cm{sup -1}. Furthermore, a perpendicular band centered at 752.7 cm{sup -1} was observed. The band has a rotational line spacing that gives an approximate B{sup ''} value of 0.132 cm{sup -1}; it has been assigned as the E{sub u} symmetry, H-F in-plane libration fundamental of the HF tetramer. Finally, a parallel band was observed at 741.0 cm{sup -1} with B{sup ''}=0.076 cm{sup -1} and has been assigned as the A{sup ''} symmetry, H-F out-of-plane libration fundamental of the HF pentamer. Structural parameters and harmonic vibrational frequencies are estimated from first-principles, correlated MP2 and CCSD(T) calculations. These are the largest calculations performed to date for this system with respect to both orbital basis set and level of electron correlation. The CCSD(T) harmonic frequencies are, in particular, the first reported for the tetramer at this level of theory. Based on our results, we suggest ''best estimates'' of R{sub FF}=2.51 Aa, r{sub HF}=0.947 Aa, and {theta}{sub HFF}=9.7 degree sign for the structural parameters and a range for D{sub e} of 27.4 to 28.1 kcal/mol (D{sub 0}=19.7 to 20.4 kcal/mol) for the parameters and for the energy of the tetramer dissociating into four monomers. (c) 2000 American Institute of Physics.

  12. Effects of fluoride emissions on enzyme activity in metabolism of agricultural plants

    SciTech Connect (OSTI)

    Moeri, P.B.

    1980-01-01

    The effects of fluoride on the activity of malatedehydrogenase (MDH) in rape seed and rye grass have been investigated. Fluoride, which has been absorbed from the air, seems to act differently from fluoride added to the soil. The action of airborne fluoride compounds resorbed by the plant on the activity of MDH significantly correlated with the distance from an aluminum plant, crop yield, and fluoride content. 5 references, 5 figures, 2 tables.

  13. Formation of lithium fluoride/metal nanocomposites for energy storage through solid state reduction of metal fluorides

    SciTech Connect (OSTI)

    Amatucci, GG; Pereira, N; Badway, F; Sina, M; Cosandey, F; Ruotolo, M; Cao, C

    2011-12-01

    In order to utilize high energy metal fluoride electrode materials as direct replacement electrode materials for lithium ion batteries in the future, a methodology to prelithiate the cathode or anode must be developed. Herein, we introduce the use of a solid state Li(3)N route to achieve the lithiation and mechanoreduction of metal fluoride based nanocomposites. The resulting prelithiation was found to be effective with the formation of xLiF:Me structures of very fine nanodimensions analogous to what is found by electrochemical lithiation. Physical and electrochemical properties of these nanocomposites for the bismuth and iron lithium fluoride systems are reported. (C) 2011 Elsevier B.V. All rights reserved.

  14. An Overview of Liquid Fluoride Salt Heat Transport Technology

    SciTech Connect (OSTI)

    Cetiner, Mustafa Sacit; Holcomb, David Eugene

    2010-01-01

    Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

  15. Continuous production of granular or powder Ti, Zr and Hf or their alloy products

    DOE Patents [OSTI]

    White, Jack C.; Oden, Laurance L.

    1993-01-01

    A continuous process for producing a granular metal selected from the group consisting of Ti, Zr or Hf under conditions that provide orderly growth of the metal free of halide inclusions comprising: a) dissolving a reducing metal selected from the group consisting of Na, Mg, Li or K in their respective halide salts to produce a reducing molten salt stream; b) preparing a second molten salt stream containing the halide salt of Ti, Zr or Hf; c) mixing and reacting the two molten streams of steps a) and b) in a continuous stirred tank reactor; d) wherein steps a) through c) are conducted at a temperature range of from about 800.degree. C. to about 1100.degree. C. so that a weight percent of equilibrium solubility of the reducing metal in its respective halide salt varies from about 1.6 weight percent at about 900.degree. C. to about 14.4 weight percent at about 1062.degree. C.; and wherein a range of concentration of the halide salt of Ti, Zn or Hf in molten halides of Na, Mg, Li or K is from about 1 to about 5 times the concentration of Na, Mg, Li or K; e) placing the reacted molten stream from step c) in a solid-liquid separator to recover an impure granular metal product by decantation, centrifugation, or filtration; and f) removing residual halide salt impurity by vacuum evaporator or inert gas sweep at temperatures from about 850.degree. C. to 1000.degree. C. or cooling the impure granular metal product to ambient temperature and water leaching off the residual metal halide salt.

  16. High Temperature Fluoride Salt Test Loop

    SciTech Connect (OSTI)

    Aaron, Adam M.; Cunningham, Richard Burns; Fugate, David L.; Holcomb, David Eugene; Kisner, Roger A.; Peretz, Fred J.; Robb, Kevin R.; Wilson, Dane F.; Yoder, Jr, Graydon L.

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels with 3 cm diameter graphite-based fuel pebbles slowly circulating up through the core. Molten salt coolant (FLiBe) at 700°C flows concurrently (at significantly higher velocity) with the pebbles and is used to remove heat generated in the reactor core (approximately 1280 W/pebble), and supply it to a power conversion system. Refueling equipment continuously sorts spent fuel pebbles and replaces spent or damaged pebbles with fresh fuel. By combining greater or fewer numbers of pebble channel assemblies, multiple reactor designs with varying power levels can be offered. The PB-AHTR design is discussed in detail in Reference [1] and is shown schematically in Fig. 1. Fig. 1. PB-AHTR concept (drawing taken from Peterson et al., Design and Development of the Modular PB-AHTR Proceedings of ICApp 08). Pebble behavior within the core is a key issue in proving the viability of this concept. This includes understanding the behavior of the pebbles thermally, hydraulically, and mechanically (quantifying pebble wear characteristics, flow channel wear, etc). The experiment being developed is an initial step in characterizing the pebble behavior under realistic PB-AHTR operating conditions. It focuses on thermal and hydraulic behavior of a static pebble bed using a convective salt loop to provide prototypic fluid conditions to the bed, and a unique inductive heating technique to provide prototypic heating in the pebbles. The facility design is sufficiently versatile to allow a variety of other experimentation to be performed in the future. The facility can accommodate testing of scaled reactor components or sub-components such as flow diodes, salt-to-salt heat exchangers, and improved pump designs as well as testing of refueling equipment, high temperature instrumentation, and other reactor core designs.

  17. Hydrogen desorption from hydrogen fluoride and remote hydrogen plasma cleaned silicon carbide (0001) surfaces

    SciTech Connect (OSTI)

    King, Sean W. Tanaka, Satoru; Davis, Robert F.; Nemanich, Robert J.

    2015-09-15

    Due to the extreme chemical inertness of silicon carbide (SiC), in-situ thermal desorption is commonly utilized as a means to remove surface contamination prior to initiating critical semiconductor processing steps such as epitaxy, gate dielectric formation, and contact metallization. In-situ thermal desorption and silicon sublimation has also recently become a popular method for epitaxial growth of mono and few layer graphene. Accordingly, numerous thermal desorption experiments of various processed silicon carbide surfaces have been performed, but have ignored the presence of hydrogen, which is ubiquitous throughout semiconductor processing. In this regard, the authors have performed a combined temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS) investigation of the desorption of molecular hydrogen (H{sub 2}) and various other oxygen, carbon, and fluorine related species from ex-situ aqueous hydrogen fluoride (HF) and in-situ remote hydrogen plasma cleaned 6H-SiC (0001) surfaces. Using XPS, the authors observed that temperatures on the order of 7001000?C are needed to fully desorb C-H, C-O and Si-O species from these surfaces. However, using TPD, the authors observed H{sub 2} desorption at both lower temperatures (200550?C) as well as higher temperatures (>700?C). The low temperature H{sub 2} desorption was deconvoluted into multiple desorption states that, based on similarities to H{sub 2} desorption from Si (111), were attributed to silicon mono, di, and trihydride surface species as well as hydrogen trapped by subsurface defects, steps, or dopants. The higher temperature H{sub 2} desorption was similarly attributed to H{sub 2} evolved from surface O-H groups at ?750?C as well as the liberation of H{sub 2} during Si-O desorption at temperatures >800?C. These results indicate that while ex-situ aqueous HF processed 6H-SiC (0001) surfaces annealed at <700?C remain terminated by some surface CO and SiO bonding, they may still exhibit significant chemical reactivity due to the creation of surface dangling bonds resulting from H{sub 2} desorption from previously undetected silicon hydride and surface hydroxide species.

  18. Sol-gel process of fluoride and fluorobromide materials

    SciTech Connect (OSTI)

    Poncelet, O.; Guilment, J.; Paz-Pujalt, G.

    1996-12-31

    The alkoxides M(OR{sub x}){sub n} wherein M is an alkaline-earth or rare-earth and OR{sub X} is a fluoroalkoxo or bromoalkoxo group exhibit the properties to form pure fluoride materials by hydrolysis at room temperature. Using this property, the authors synthesized pure barium and europium fluoride and pure alkaline-earth bromide. The hydrolysis of a heteroleptic species, Ba(OCH{sub 2}CH{sub 2}Br)[OCH(CF{sub 3}){sub 2}] allowed pure and crystalline BaFBr materials to be obtained at room temperature.

  19. METHOD OF PRODUCING PLUTONIUM TETRAFLUORIDE

    DOE Patents [OSTI]

    Tolley, W.B.; Smith, R.C.

    1959-12-15

    A process is presented for preparing plutonium tetrafluoride from plutonium(IV) oxalate. The oxalate is dried and decomposed at about 300 deg C to the dioxide, mixed with ammonium bifluoride, and the mixture is heated to between 50 and 150 deg C whereby ammonium plutonium fluoride is formed. The ammonium plutonium fluoride is then heated to about 300 deg C for volatilization of ammonium fluoride. Both heating steps are preferably carried out in an inert atmosphere.

  20. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A.; Hughes, Robert W.; Smith, Ronald I.; Gregory, Duncan H.

    2012-01-15

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  1. EIS-0359: Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky Site

    Broader source: Energy.gov [DOE]

    This site-specific EIS considers the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three locations within the Paducah site; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion co-product; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold.

  2. Evolution of magnetic properties and microstructure of Hf2Co11B...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Evolution of magnetic properties and microstructure of Hf2Co11B alloys Citation Details In-Document Search Title: Evolution of magnetic properties and ...

  3. Metal oxide and metal fluoride nanostructures and methods of making same

    DOE Patents [OSTI]

    Wong, Stanislaus S. (Stony Brook, NY); Mao, Yuanbing (Los Angeles, CA)

    2009-08-18

    The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.

  4. Photochemical oxygenation of a technetium fluoride using F{sub 2} and O{sub 2}

    SciTech Connect (OSTI)

    Beitz, J.V.; Williams, C.W.

    1996-10-01

    Photochemical conversion of technetium fluorides and oxyfluorides is largely uninvestigated. Because technetium was introduced into U.S. uranium enrichment plants, decommissioning and decontamination of these plants will involve technetium fluorides and oxyfluorides. Photochemical conversion of such compounds may facilitate waste minimization and cost avoidance goals during plant clean-up. Photochemical fluorination using ultraviolet photolysis of a mixture of fluorine and oxygen gases is an effective means of converting solid, nonvolatile fluorides of fight actinides, such as U, Np, and Pu, into volatile hexafluorides thereby removing surface radioactive contamination. Our studies involved the interaction of ultraviolet light, oxygen, and fluorine with technetium fluoride.

  5. Grout formulation for disposal of low-level and hazardous waste streams containing fluoride

    DOE Patents [OSTI]

    McDaniel, E.W.; Sams, T.L.; Tallent, O.K.

    1987-06-02

    A composition and related process for disposal of hazardous waste streams containing fluoride in cement-based materials is disclosed. the presence of fluoride in cement-based materials is disclosed. The presence of fluoride in waste materials acts as a set retarder and as a result, prevents cement-based grouts from setting. This problem is overcome by the present invention wherein calcium hydroxide is incorporated into the dry-solid portion of the grout mix. The calcium hydroxide renders the fluoride insoluble, allowing the grout to set up and immobilize all hazardous constituents of concern. 4 tabs.

  6. Measurement and analysis of muonic x rays of 176,177,178,179,180Hf

    SciTech Connect (OSTI)

    Tanaka, Y.; Steffen, R.M.; Shera, E.B.; Reuter, W.; Hoehn, M.V.; Zumbro, J.D.

    1984-07-01

    Monopole and quadrupole charge distributions of /sup 176/Hf, /sup 177/Hf, /sup 178/Hf, /sup 179/Hf, and /sup 180/Hf were investigated by muonic atom K and L x-ray measurements. The model-independent Barrett charge radii R/sub k/ and the isotope shifts ..delta..R/sub k/ were measured, and values of and ..delta.. were deduced. A weak odd-even staggering of the nuclear charge radii was observed for the series /sup 176 -178/Hf and /sup 178 -180/Hf. A large negative isomer shift was observed in the 2/sup +/ state of the /sup 176/Hf nucleus, a fact that existing theories do not explain. The quadrupole moments of the first excited states of the hafnium nuclei were determined to be Q/sup 176/(2/sup +/) = -2.10(2) e b, Q/sup 177/((9/2)/sup -/) = 1.30(2) e b, Q/sup 178/(2/sup +/) = -2.02(2) e b, Q/sup 179/((11/2)/sup +/) = 1.88(3) e b, and Q/sup 180/(2/sup +/) = -2.00(2) e b. These quadrupole moments and the simultaneously determined B(E2) values for the respective nuclei are in satisfactory agreement with the predictions of the axially symmetric rotor model.

  7. Multifunctional gold coated rare-earth hydroxide fluoride nanotubes for simultaneous wastewater purification and quantitative pollutant determination

    SciTech Connect (OSTI)

    Zhang, Da-Quan; Sun, Tian-Ying; Yu, Xue-Feng; Jia, Yue; Chen, Ming; Wang, Jia-Hong; Huang, Hao; Chu, Paul K.

    2014-04-01

    Highlights: The morphology and properties of Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) were investigated. YHF:Ce NTs were conjugated with Au nanoparticles to produce Au-YHF:Ce nanocomposites. Au-YHF:Ce NTs showed excellent capability and efficiency in removing Congo red from solutions. Au-YHF:Ce NTs were utilized to determine the concentration of Congo red based on SERS. - Abstract: Ce-doped yttrium hydroxide fluoride nanotubes (YHF:Ce NTs) with large surface area are synthesized and conjugated with Au nanoparticles (NPs) to produce Au-YHF:Ce nanocomposites. The Au-YHF:Ce NTs have a hollow structure, rough surface, polymer coating, and good surface-enhanced Raman spectroscopy (SERS) properties. They are applied to wastewater treatment to remove Congo red as a typical pollutant. The materials not only remove pollutants rapidly from the wastewater, but also detect trace amounts of the pollutants quantitatively. The multifunctional Au-YHF:Ce NTs have commercial potential as nano-absorbents and nano-detectors in water treatment and environmental monitoring.

  8. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Wensheng He, David Mountz, Tao Zhang, Chris Roger July 17, 2012 2 Outline Background on Arkema's polyvinylidene fluoride (PVDF) blend membrane technology Overview of membrane properties and performance Summary 3 Membrane Technology Polymer Blend * Kynar ® PVDF * Chemical and electrochemical stability * Mechanical strength * Excellent barrier against methanol * Polyelectrolyte * H + conduction and water uptake

  9. Ferroelectric fluoride compositions and methods of making and using same

    DOE Patents [OSTI]

    Halasyamani, P Shiv; Chang, Hong-Young

    2015-04-07

    A method for synthesis of a ferroelectric material characterized by the general formula A.sub.xB.sub.yF.sub.z where A is an alkaline earth metal, B is transition metal or a main group metal, x and y each range from about 1 to about 5, and z ranges from about 1 to about 20 comprising contacting an alkaline earth metal fluoride, a difluorometal compound and a fluoroorganic acid in a medium to form a reaction mixture; and subjecting the reaction mixture to conditions suitable for hydrothermal crystal growth.

  10. Time-dependent water dynamics in hydrated uranyl fluoride

    SciTech Connect (OSTI)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved thermodynamic hydrates with 02.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translational diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre pockets formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.

  11. Time-dependent water dynamics in hydrated uranyl fluoride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved ‘thermodynamic’ hydrates with 0–2.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translationalmore » diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2–300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre ‘pockets’ formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.« less

  12. Microstructure–property relationships in a high-strength 51Ni–29Ti–20Hf shape memory alloy

    SciTech Connect (OSTI)

    Coughlin, D. R.; Casalena, L.; Yang, F.; Noebe, R. D.; Mills, M. J.

    2015-09-18

    NiTiHf alloys exhibit remarkable shape memory and pseudoelastic properties that are of fundamental interest to a growing number of industries. In this study, differential scanning calorimetry and isothermal compression tests have revealed that the 51Ni–29Ti–20Hf alloy has useful shape memory properties that include a wide range of transformation temperatures as well as highly stable pseudoelastic behavior. These properties are governed by short-term aging conditions, which may be tailored to control transformation temperatures while giving rise to exceptionally high austenite yield strengths which aid transformation stability. The yield strength of the austenite phase can reach 2.1 GPa by aging for 3hrs at 500°C, while aging for 3hrs at 700°C produced an alloy with an austenite finish temperature (A f ) of 146°C. High-resolution scanning transmission electron microscopy has revealed a new precipitate phase, H-phase, under the homogenized and extruded condition and the aged 3 hrs at 500°C condition, but only the previously identified H-phase precipitate was observed after aging at temperatures of 600°C and 700°C for 3 hrs. Finally, dislocation analysis indicated that plastic deformation of the austenite phase occurred by <100> type slip, similar to that observed in binary NiTi.

  13. Interplay between gadolinium dopants and oxygen vacancies in HfO{sub 2}: A

    Office of Scientific and Technical Information (OSTI)

    density functional theory plus Hubbard U investigation (Journal Article) | SciTech Connect Interplay between gadolinium dopants and oxygen vacancies in HfO{sub 2}: A density functional theory plus Hubbard U investigation Citation Details In-Document Search Title: Interplay between gadolinium dopants and oxygen vacancies in HfO{sub 2}: A density functional theory plus Hubbard U investigation The influence of gadolinium (Gd) doping on the oxygen vacancy (V{sub O}) in monoclinic HfO{sub 2} have

  14. Radiative cooling test facility and performance evaluation of 4-MIL aluminized polyvinyl fluoride and white-paint surfaces

    SciTech Connect (OSTI)

    Kruskopf, M.S.; Berdahl, P.; Martin, M.; Sakkal, F.; Sobolewski, M.

    1980-11-01

    A test facility designed to measure the amount of radiative cooling a specific material or assembly of materials will produce when exposed to the sky is described. Emphasis is placed upon assemblies which are specifically designed to produce radiative cooling and which therefore offer promise for the reduction of temperatures and/or humidities in occupied spaces. The hardware and software used to operate the facility are documented and the results of the first comprehensive experiments are presented. A microcomputer-based control/data acquisition system was employed to study the performance of two prototype radiator surfaces: 4-mil aluminized polyvinyl fluoride (PVF) and white painted surfaces set below polyethylene windscreens. The cooling rates for materials tested were determined and can be approximated by an equation (given). A computer model developed to simulate the cooling process is presented. (MCW)

  15. Proximal renal tubular injury in rats sub-chronically exposed to low fluoride concentrations

    SciTech Connect (OSTI)

    Crdenas-Gonzlez, Mariana C.; Del Razo, Luz M.; Barrera-Chimal, Jonatan; Jacobo-Estrada, Tania; Lpez-Bayghen, Esther; and others

    2013-11-01

    Fluoride is usually found in groundwater at a very wide range of concentration between 0.5 and 25 ppm. At present, few studies have assessed the renal effects of fluoride at environmentally relevant concentrations. Furthermore, most of these studies have used insensitive and nonspecific biomarkers of kidney injury. The aim of this study was to use early and sensitive biomarkers to evaluate kidney injury after fluoride exposure to environmentally relevant concentrations. Recently weaned male Wistar rats were exposed to low (15 ppm) and high (50 ppm) fluoride concentrations in drinking water for a period of 40 days. At the end of the exposure period, kidney injury biomarkers were measured in urine and renal mRNA expression levels were assessed by real time RT-PCR. Our results showed that the urinary kidney injury molecule (Kim-1), clusterin (Clu), osteopontin (OPN) and heat shock protein 72 excretion rate significantly increased in the group exposed to the high fluoride concentration. Accordingly, fluoride exposure increased renal Kim-1, Clu and OPN mRNA expression levels. Moreover, there was a significant dose-dependent increase in urinary ?-2-microglobulin and cystatin-C excretion rate. Additionally, a tendency towards a dose dependent increase of tubular damage in the histopathological light microscopy findings confirmed the preferential impact of fluoride on the tubular structure. All of these changes occurred at early stages in which, the renal function was not altered. In conclusion using early and sensitive biomarkers of kidney injury, we were able to found proximal tubular alterations in rats sub-chronically exposed to fluoride. - Highlights: Exposure to low concentrations of fluoride induced proximal tubular injury Increase in urinary Kim-1, Clu, OPN and Hsp72 in 50 ppm fluoride-exposed group Increase in urinary B2M and CysC in 15 and 50 ppm fluoride-exposed groups Fluoride exposure increased renal Kim, Clu and OPN mRNA expression levels. Fluoride increased kidney injury biomarkers at stages where eGFR was unaltered.

  16. Evolution of magnetic properties and microstructure of Hf2Co11B alloys

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Evolution of magnetic properties and microstructure of Hf2Co11B alloys Citation Details In-Document Search Title: Evolution of magnetic properties and microstructure of Hf2Co11B alloys Authors: McGuire, Michael A. [1] ; Rios, Orlando [1] + Show Author Affiliations Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA Publication Date: 2015-02-07 OSTI Identifier: 1228520 Type: Publisher's Accepted Manuscript Journal Name: Journal

  17. Removal of fluoride impurities from UF/sub 6/ gas

    DOE Patents [OSTI]

    Beitz, J.V.

    1984-01-06

    A method of purifying a UF/sub 6/ gas stream containing one or more metal fluoride impurities composed of a transuranic metal, transition metal or mixtures thereof, is carried out by contacting the gas stream with a bed of UF/sub 5/ in a reaction vessel under conditions where at least one impurity reacts with the UF/sub 5/ to form a nongaseous product and a treated gas stream, and removing the treated gas stream from contact with the bed. The nongaseous products are subsequently removed in a reaction with an active fluorine affording agent to form a gaseous impurity which is removed from the reaction vessel. The bed of UF/sub 5/ is formed by the reduction of UF/sub 6/ in the presence of uv light. One embodiment of the reaction vessel includes a plurality of uv light sources as tubes on which UF/sub 5/ is formed. 2 figures.

  18. Ytterbium-doped borate fluoride laser crystals and lasers

    DOE Patents [OSTI]

    Schaffers, Kathleen I.; DeLoach, Laura D.; Payne, Stephen A.; Keszler, Douglas A.

    1997-01-01

    A new class of solid state laser crystals and lasers are formed from Yb-doped borate fluoride host crystals. The general formula for the host crystals is MM'(BO.sub.3)F, where M, M' are monovalent, divalent aria trivalent metal cations. A particular embodiment of the invention is Yb-doped BaCaBO.sub.3 F (Yb:BCBF). BCBF and some of the related derivative crystals are capable of nonlinear frequency conversion, whereby the fundamental of the laser is converted to a longer or shorter wavelength. In this way, these new crystals can simultaneously serve as self-frequency doubling crystals and laser materials within the laser resonator.

  19. Ytterbium-doped borate fluoride laser crystals and lasers

    DOE Patents [OSTI]

    Schaffers, K.I.; DeLoach, L.D.; Payne, S.A.; Keszler, D.A.

    1997-10-14

    A new class of solid state laser crystals and lasers are formed from Yb-doped borate fluoride host crystals. The general formula for the host crystals is MM{prime}(BO{sub 3})F, where M, M{prime} are monovalent, divalent aria trivalent metal cations. A particular embodiment of the invention is Yb-doped BaCaBO{sub 3}F (Yb:BCBF). BCBF and some of the related derivative crystals are capable of nonlinear frequency conversion, whereby the fundamental of the laser is converted to a longer or shorter wavelength. In this way, these new crystals can simultaneously serve as self-frequency doubling crystals and laser materials within the laser resonator. 6 figs.

  20. Advantages of liquid fluoride thorium reactor in comparison with light water reactor

    SciTech Connect (OSTI)

    Bahri, Che Nor Aniza Che Zainul Majid, Amran Ab.; Al-Areqi, Wadeeah M.

    2015-04-29

    Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium dissolved in salt mixture of lithium fluoride and beryllium fluoride. Therefore, LFTR technology is fundamentally different from the solid fuel technology currently in use. Although the traditional nuclear reactor technology has been proven, it has perceptual problems with safety and nuclear waste products. The aim of this paper is to discuss the potential advantages of LFTR in three aspects such as safety, fuel efficiency and nuclear waste as an alternative energy generator in the future. Comparisons between LFTR and Light Water Reactor (LWR), on general principles of fuel cycle, resource availability, radiotoxicity and nuclear weapon proliferation shall be elaborated.

  1. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  2. Method for converting UF5 to UF4 in a molten fluoride salt

    DOE Patents [OSTI]

    Bennett, Melvin R.; Bamberger, Carlos E.; Kelmers, A. Donald

    1977-01-01

    The reduction of UF.sub.5 to UF.sub.4 in a molten fluoride salt by sparging with hydrogen is catalyzed by metallic platinum. The reaction is also catalyzed by platinum alloyed with gold reaction equipment.

  3. Uranium hexafluoride liquid thermal expansion, elusive eutectic with hydrogen fluoride, and very first production using chlorine trifluoride

    SciTech Connect (OSTI)

    Rutledge, G.P.

    1991-12-31

    Three unusual incidents and case histories involving uranium hexafluoride in the enrichment facilities of the USA in the late 1940`s and early 1950`s are presented. The history of the measurements of the thermal expansion of liquids containing fluorine atoms within the molecule is reviewed with special emphasis upon uranium hexafluoride. A comparison is made between fluorinated esters, fluorocarbons, and uranium hexafluoride. The quantitative relationship between the thermal expansion coefficient, a, of liquids and the critical temperature, T{sub c} is presented. Uranium hexafluoride has an a that is very high in a temperature range that is used by laboratory and production workers - much higher than any other liquid measured. This physical property of UF{sub 6} has resulted in accidents involving filling the UF{sub 6} containers too full and then heating with a resulting rupture of the container. Such an incident at a uranium gaseous diffusion plant is presented. Production workers seldom {open_quotes}see{close_quotes} uranium hexafluoride. The movement of UF{sub 6} from one container to another is usually trailed by weight, not sight. Even laboratory scientists seldom {open_quotes}see{close_quotes} solid or liquid UF{sub 6} and this can be a problem at times. This inability to {open_quotes}see{close_quotes} the UF{sub 6}-HF mixtures in the 61.2{degrees}C to 101{degrees}C temperature range caused a delay in the understanding of the phase diagram of UF{sub 6}-HF which has a liquid - liquid immiscible region that made the eutectic composition somewhat elusive. Transparent fluorothene tubes solved the problem both for the UF{sub 6}-HF phase diagram as well as the UF{sub 6}-HF-CIF{sub 3} phase diagram with a miscibility gap starting at 53{degrees}C. The historical background leading to the first use of CIF{sub 3} to produce UF{sub 6} in both the laboratory and plant at K-25 is presented.

  4. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, J.R.; Dunn, J.G.; Avens, L.R.

    1987-02-13

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF/sub 4/ is not further oxidized to AmF/sub 6/ by the application of O/sub 2/F at room temperature thereto, while plutonium compounds present in the americium sample are fluorinated to volatile PuF/sub 6/, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride thereof.

  5. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, John R. (Los Alamos, NM); Dunn, Jerry G. (Los Alamos, NM); Avens, Larry R. (Los Alamos, NM)

    1987-01-01

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF.sub.4 is not further oxidized to AmF.sub.6 by the application of O.sub.2 F at room temperature, while plutonium compounds present in the americium sample are fluorinated to volatile PuF.sub.6, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride.

  6. Development of fluoride reprocessing technologies devoted to molten-salt reactor systems

    SciTech Connect (OSTI)

    Uhlir, Jan; Marecek, Martin; Tulackova, Radka; Chuchvalcova Bimova, Karolina

    2007-07-01

    Main fuel processing and reprocessing technologies proposed for Molten Salt Reactor fuel cycle are pyrochemical or pyrometallurgical, majority of them are fluoride technologies. It is based on the fact that Molten Salt Reactor fuel is in the chemical form of molten fluorides and the reprocessing technology is needed to be an 'on-line' process. The corresponding pyrochemical separation processes proposed for MSR fuel processing and reprocessing are mainly fluoride volatilization processes, molten salt / liquid metal extraction processes, electrochemical separation processes from the molten salt media and gas extraction from the molten salt medium. Techniques based on fluoride volatilization and on electrochemical separation from fluoride molten salt media are under development in the Czech Republic. Whereas the Fluoride Volatility Method is proposed to be the main 'Front-end' technology of the MSR used as the actinide burner (transmuter), the electro-separation methods should be dedicated to the 'on-line' reprocessing of the circulating MSR fuel and should be used as for MSR incinerating transuranium fuel as for MSR working within the {sup 232}Th - {sup 233}U fuel cycle. (authors)

  7. Thermally-driven H interaction with HfO{sub 2} films deposited on Ge(100) and Si(100)

    SciTech Connect (OSTI)

    Soares, G. V. Feij, T. O.; Baumvol, I. J. R.; Aguzzoli, C.; Krug, C.; Radtke, C.

    2014-01-27

    In the present work, we investigated the thermally-driven H incorporation in HfO{sub 2} films deposited on Si and Ge substrates. Two regimes for deuterium (D) uptake were identified, attributed to D bonded near the HfO{sub 2}/substrate interface region (at 300?C) and through the whole HfO{sub 2} layer (400600?C). Films deposited on Si presented higher D amounts for all investigated temperatures, as well as, a higher resistance for D desorption. Moreover, HfO{sub 2} films underwent structural changes during annealings, influencing D incorporation. The semiconductor substrate plays a key role in this process.

  8. Excitation functions of the natTa(p,x)178m2Hf and natW(p,x)178m2Hf reactions at energies up to 2600 MeV

    SciTech Connect (OSTI)

    Titarenko, Yu. E.; Batyaev, V. F.; Pavlov, K. V.; Titarenko, A. Yu.; Zhivun, V. M.; Chauzova, M. V.; Ignatyuk, A. V.; Mashnik, Stepan Georgievich; Leray, S.; Boudard, A.; David, J. -C.; Mancusi, D.; Cugnon, J.; Yariv, Y.; Nishihara, K.; Matsuda, N.; Kumawat, H.; Stankovskiy, A. Yu.

    2015-04-29

    Due to potential level of energy intensity 178m2Hf is an extremely interesting isomer. One possible way to produce this isomer is irradiation of natTa or natW samples with high energy protons. Irradiation of natTa or natW samples performed for other purposes provides an opportunity to study the corresponding reactions. This paper presents the 178m2Hf independent production cross sections for both targets measured by the gamma-ray spectrometry method. The reaction excitation functions have been obtained for the proton energies from 40 up to 2600 MeV. The experimental results were compared with calculations by various versions of the intranuclear cascade model in the well-known codes: ISABEL, Bertini, INCL4.5+ABLA07, PHITS, CASCADE07 and CEM03.02. The isomer ratio for the natTa(p,x) 178m2Hf reaction is evaluated on the basis of the available data.

  9. On stability of self-sustained volume discharge in working mixtures of non-chain electrochemical HF laser

    SciTech Connect (OSTI)

    Belevtsev, A A; Kazantsev, S Yu; Konov, I G; Lebedev, A A; Podlesnykh, S V; Firsov, K N

    2011-08-31

    Burning voltage of a self-sustained volume discharge (SSVD) is studied as a function of the specific energy deposition in SF{sub 5} with C{sub 2}-H{sub 6} and H{sub 2} mixtures, which are working media of a non-chain electrochemical HF laser. It is established that the voltage rises linearly with increasing the specific energy deposition, the relative voltage rise in the SF{sub 6}-C{sub 2}H{sub 6} mixtures being noticeably higher than in pure SF{sub 6} and SF{sub 6}-H{sub 2} mixtures. An assumption is suggested and substantiated on determining the role of molecule dissociation by the electron impact leading to the observed voltage rise. From experimental data we have found approximate energy expenditures of producing dissociation fragments including atomic fluorine in a discharge in pure SF{sub 6}: E-tilde {sub d}(F)= 5{+-}1 eV. The values of E{sub d} well agree with literature data obtained by other experimental methods. A conclusion is drawn that the dissociation process is the main mechanism limiting the current density, which implies SSVD realisation without preliminary gas ionisation in working mixtures of a non-chain HF laser and determines a higher stability of the volume discharge in mixtures of SF{sub 6} with hydrocarbons (deuterocarbons) as compared to mixtures with hydrogen (deuterium). A method is suggested and substantiated for numerical estimation of the limitation effect of the current density and its influence on the SSVD stability. (control of radiation parameters)

  10. Lifetime measurements of yrast states in {sup 162}Yb and {sup 166}Hf

    SciTech Connect (OSTI)

    McCutchan, E.A.; Casten, R.F.; Ai, H.; Amro, H.; Heinz, A.; Meyer, D.A.; Plettner, C.; Qian, J.; Ressler, J.J.; Werner, V.; Williams, E.; Winkler, R.; Zamfir, N.V.; Babilon, M.; Brenner, D.S.; Guerdal, G.; Hughes, R.O.; Thomas, N.J.

    2006-03-15

    Lifetime measurements of yrast levels in {sup 162}Yb and {sup 166}Hf were performed using the recoil distance Doppler-shift method in coincidence mode. Excited states in {sup 162}Yb and {sup 166}Hf were populated via the reactions {sup 116}Cd({sup 50}Ti, 4n) and {sup 122}Sn({sup 48}Ti, 4n), respectively. The resulting B(E2) values are compared with the X(5) critical point model predictions and interacting boson approximation (IBA) model calculations. The X(5) model provides a reasonable description of the yrast B(E2) values in {sup 166}Hf, whereas the IBA fails to reproduce the transition strengths from the higher spin levels. In {sup 162}Yb, some transitions agree with the X(5) predictions while others are more consistent with the predictions of the IBA or a deformed symmetric rotor.

  11. Evolution of magnetic properties and microstructure of Hf2Co11B alloys

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Evolution of magnetic properties and microstructure of Hf2Co11B alloys Citation Details In-Document Search Title: Evolution of magnetic properties and microstructure of Hf2Co11B alloys Authors: McGuire, Michael A [1] ; Rios, Orlando [1] + Show Author Affiliations ORNL Publication Date: 2015-01-01 OSTI Identifier: 1185598 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Journal Article Resource Relation: Journal Name: Journal of

  12. Triaxial strongly deformed bands in {sup 164}Hf and the effect of elevated yrast line

    SciTech Connect (OSTI)

    Ma Wenchao

    2012-10-20

    Two exotic rotational bands have been identified in {sup 164}Hf and linked to known states. They are interpreted as being associated with the calculated triaxial strongly deformed (TSD) potential energy minimum. The bands are substantially stronger and are located at much lower spins than the previously discovered TSD bands in {sup 168}Hf. In addition to the proton and neutron shell gaps at large trixiality, it was proposed that the relative excitation energy of TSD bands above the yrast line plays an important role in the population of TSD bands.

  13. Fluoride-elicited developmental testicular toxicity in rats: Roles of endoplasmic reticulum stress and inflammatory response

    SciTech Connect (OSTI)

    Zhang, Shun; Jiang, Chunyang; Liu, Hongliang; Guan, Zhizhong; Zeng, Qiang; Zhang, Cheng; Lei, Rongrong; Xia, Tao; Gao, Hui; Yang, Lu; Chen, Yihu; Wu, Xue; Zhang, Xiaofei; Cui, Yushan; Yu, Linyu; Wang, Zhenglun; Wang, Aiguo

    2013-09-01

    Long-term excessive fluoride intake is known to be toxic and can damage a variety of organs and tissues in the human body. However, the molecular mechanisms underlying fluoride-induced male reproductive toxicity are not well understood. In this study, we used a rat model to simulate the situations of human exposure and aimed to evaluate the roles of endoplasmic reticulum (ER) stress and inflammatory response in fluoride-induced testicular injury. SpragueDawley rats were administered with sodium fluoride (NaF) at 25, 50 and 100 mg/L via drinking water from pre-pregnancy to gestation, birth and finally to post-puberty. And then the testes of male offspring were studied at 8 weeks of age. Our results demonstrated that fluoride treatment increased MDA accumulation, decreased SOD activity, and enhanced germ cell apoptosis. In addition, fluoride elevated mRNA and protein levels of glucose-regulated protein 78 (GRP78), inositol requiring ER-to-nucleus signal kinase 1 (IRE1), and C/EBP homologous protein (CHOP), indicating activation of ER stress signaling. Furthermore, fluoride also induced testicular inflammation, as manifested by gene up-regulation of tumor necrosis factor-? (TNF-?), interleukin-1? (IL-1?), inducible nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2), in a nuclear factor-?B (NF-?B)-dependent manner. These were associated with marked histopathological lesions including injury of spermatogonia, decrease of spermatocytes and absence of elongated spermatids, as well as severe ultrastructural abnormalities in testes. Taken together, our results provide compelling evidence that ER stress and inflammation would be novel and significant mechanisms responsible for fluoride-induced disturbance of spermatogenesis and germ cell loss in addition to oxidative stress. - Highlights: We used a rat model to simulate the situations of human fluoride (F) exposure. Developmental F exposure induces testicular damage related with oxidative stress. Endoplasmic reticulum stress is involved in testis disorder and germ cell apoptosis. Inflammatory response is implicated in impaired spermatogenesis and germ cell loss.

  14. On the possibility of simultaneous emission of an autonomous cw HF-DF chemical laser in two spectral ranges

    SciTech Connect (OSTI)

    Bashkin, A S; Gurov, L V; Katorgin, B I; Petrova, S N; Polinovsky, D V

    2008-05-31

    The efficiencies of different fuel compositions used in the combustion chamber of an autonomous cw chemical HF-DF laser for obtaining high specific energy parameters during simultaneous lasing in HF and DF molecules in two spectral ranges are theoretically analysed. It is shown that mirrors with the reflectance above 99% in these spectral ranges can be manufactured in principle. (lasers)

  15. Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)

    SciTech Connect (OSTI)

    Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D.

    2012-07-01

    The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

  16. Effect of temperature on the complexation of Uranium(VI) with fluoride in aqueous solutions

    SciTech Connect (OSTI)

    Tian, Guoxin; Rao, Linfeng

    2009-05-18

    Complexation of U(VI) with fluoride at elevated temperatures in aqueous solutions was studied by spectrophotometry. Four successive complexes, UO{sub 2}F{sup +}, UO{sub 2}F{sub 2}(aq), UO{sub 2}F{sub 3}{sup -}, and UO{sub 2}F{sub 4}{sup 2-}, were identified, and the stability constants at 25, 40, 55, and 70 C were calculated. The stability of the complexes increased as the temperature was elevated. The enthalpies of complexation at 25 C were determined by microcalorimetry. Thermodynamic parameters indicate that the complexation of U(VI) with fluoride in aqueous solutions at 25 to 70 C is slightly endothermic and entropy-driven. The Specific Ion Interaction (SIT) approach was used to obtain the thermodynamic parameters of complexation at infinite dilution. Structural information on the U(VI)/fluoride complexes was obtained by extended X-ray absorption fine structure spectroscopy.

  17. Radiolytic Effects on Fluoride Impurities in a U{sub 3}O{sub 8} Matrix

    SciTech Connect (OSTI)

    Icenhour, A.S.

    2000-05-01

    The safe handling and storage of radioactive materials require an understanding of the effects of radiolysis on those materials. Radiolysis may result in the production of gases (e.g., corrosives) or pressures that are deleterious to storage containers. A study has been performed to address these concerns as they relate to the radiolysis of residual fluoride compounds in uranium oxides.

  18. Nuclear quantum effects in water exchange around lithium and fluoride ions

    SciTech Connect (OSTI)

    Wilkins, David M.; Manolopoulos, David; Dang, Liem X.

    2015-02-14

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the water exchange reactions are unaffected by quantization, so a classical description of these reactions gives qualitatively correct and quantitatively reasonable results. We also find that the quantum effects in solutions of lithium are larger than in solutions of fluoride. This is partly due to the stronger interaction of lithium with water molecules, partly due to the lighter mass of lithium, and partly due to competing quantum effects in the hydration of fluoride, which are absent in the hydration of lithium. LXD was supported by US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  19. Nuclear quantum effects in water exchange around lithium and fluoride ions

    SciTech Connect (OSTI)

    Wilkins, David M.; Manolopoulos, David E.; Dang, Liem X.

    2015-02-14

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reactions gives qualitatively correct and quantitatively reasonable results. We also find that the quantum effects in solutions of lithium are larger than in solutions of fluoride. This is partly due to the stronger interaction of lithium with water molecules, partly due to the lighter mass of lithium and partly due to competing quantum effects in the hydration of fluoride, which are absent in the hydration of lithium.

  20. Dissolution of HTGR TRISO beads by the alkali fluoride fusion method

    SciTech Connect (OSTI)

    Byster, S.E.

    1980-07-01

    The alkali fluoride fusion method for the dissolution of HTGR TRISO fuel beads offers significant time advantage over other commonly used fusion procedures when applied to samples weighing less than three grams. The method is straightforward, utilizes standard analytical laboratory equipment, and yields solutions which may be utilized by customary procedures.

  1. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  2. g factor of the 2{sub 1}{sup +} state of {sup 172}Hf

    SciTech Connect (OSTI)

    Berant, Z.; Wolf, A.; Oster, E.; Casperson, R. J.; Werner, V.; Heinz, A.; Casten, R. F.; Terry, J. R.; Winkler, R.; Williams, E.; Qian, J.; Schmidt, A.; Smith, M. K.; Ahn, T.; Gurdal, G.; McCutchan, E. A.; Brenner, D. S.; Beausang, C. W.; Regan, P. H.; Ross, T.

    2009-11-15

    The g factor of the 2{sub 1}{sup +} state of {sup 172}Hf was measured using the perturbed angular correlation technique in a static external magnetic field. The result, g(2{sub 1}{sup +})=0.25(5), is discussed in relation to the systematics of the previously reported g factors in the Hf isotopes and compared with the predictions of several models. An interesting outcome of the analysis presented in this paper is the agreement between the calculated g factors within the interacting boson approximation (IBA) and the results of a large-scale shell model calculation. This agreement supports the emphasis in the IBA on the valence space. The undershooting of the empirical g factors near midshell in both models suggests that they underestimate the role of the saturation of collectivity, which is explicitly incorporated into a phenomenological model that agrees better with the data.

  3. g-factor of the 2{sup+}{sub{1} state of {sup179}Hf.

    SciTech Connect (OSTI)

    Berant, Z.; Oster, E.; Wolf, A.; Casperson, R. J.; Werner, V.; McCutchan, E. A.

    2009-01-01

    The g factor of the 2{sub 1}{sup +} state of {sup 172}Hf was measured using the perturbed angular correlation technique in a static external magnetic field. The result, g(2{sub 1}{sup +}) = 0.25(5), is discussed in relation to the systematics of the previously reported g factors in the Hf isotopes and compared with the predictions of several models. An interesting outcome of the analysis presented in this paper is the agreement between the calculated g factors within the interacting boson approximation (IBA) and the results of a large-scale shell model calculation. This agreement supports the emphasis in the IBA on the valence space. The undershooting of the empirical g factors near midshell in both models suggests that they underestimate the role of the saturation of collectivity, which is explicitly incorporated into a phenomenological model that agrees better with the data.

  4. An Experimental Test Facility to Support Development of the Fluoride Salt Cooled High Temperature Reactor

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Aaron, Adam M; Cunningham, Richard Burns; Fugate, David L; Holcomb, David Eugene; Kisner, Roger A; Peretz, Fred J; Robb, Kevin R; Wilgen, John B; Wilson, Dane F

    2014-01-01

    The need for high-temperature (greater than 600 C) energy exchange and delivery systems is significantly increasing as the world strives to improve energy efficiency and develop alternatives to petroleum-based fuels. Liquid fluoride salts are one of the few energy transport fluids that have the capability of operating at high temperatures in combination with low system pressures. The Fluoride Salt-Cooled High-Temperature Reactor design uses fluoride salt to remove core heat and interface with a power conversion system. Although a significant amount of experimentation has been performed with these salts, specific aspects of this reactor concept will require experimental confirmation during the development process. The experimental facility described here has been constructed to support the development of the Fluoride Salt Cooled High Temperature Reactor concept. The facility is capable of operating at up to 700 C and incorporates a centrifugal pump to circulate FLiNaK salt through a removable test section. A unique inductive heating technique is used to apply heat to the test section, allowing heat transfer testing to be performed. An air-cooled heat exchanger removes added heat. Supporting loop infrastructure includes a pressure control system; trace heating system; and a complement of instrumentation to measure salt flow, temperatures, and pressures around the loop. The initial experiment is aimed at measuring fluoride salt heat transfer inside a heated pebble bed similar to that used for the core of the pebble bed advanced high-temperature reactor. This document describes the details of the loop design, auxiliary systems used to support the facility, the inductive heating system, and facility capabilities.

  5. Method of producing hydrogen

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Wilding, Bruce M.; Zollinger, William T.

    2006-12-26

    A method of producing hydrogen is disclosed and which includes providing a first composition; providing a second composition; reacting the first and second compositions together to produce a chemical hydride; providing a liquid and reacting the chemical hydride with the liquid in a manner to produce a high pressure hydrogen gas and a byproduct which includes the first composition; and reusing the first composition formed as a byproduct in a subsequent chemical reaction to form additional chemical hydride.

  6. Mode specificity in the HF + OH → F + H{sub 2}O reaction

    SciTech Connect (OSTI)

    Song, Hongwei; Li, Jun; Guo, Hua

    2014-10-28

    Full-dimensional quantum dynamics and quasi-classical trajectory calculations are reported for the title reaction on a recently constructed ab initio based global potential energy surface. Strong mode specificity was found, consistent with the prediction of the sudden vector projection model. Specifically, the HF vibration strongly promotes the reaction while the OH vibration has little effect. Rotational excitations of both reactants slightly enhance the reaction.

  7. Method for producing nanostructured metal-oxides

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Simpson, Randall L.; Hrubesh, Lawrence W.; Gash, Alexander

    2006-01-17

    A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe.sup.3+, Cr.sup.3+, Al.sup.3+, Ga.sup.3+, In.sup.3+, Hf.sup.4+, Sn.sup.4+, Zr.sup.4+, Nb.sup.5+, W.sup.6+, Pr.sup.3+, Er.sup.3+, Nd.sup.3+, Ce.sup.3+, U.sup.3+ and Y.sup.3+. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of Fe.sub.xO.sub.y gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.

  8. Electronic properties of InP (001)/HfO{sub 2} (001) interface: Band offsets and oxygen dependence

    SciTech Connect (OSTI)

    KC, Santosh; Dong, Hong; Longo, Roberto C.; Xiong, Ka; Wang, Weichao; Wallace, Robert M.; Cho, Kyeongjae

    2014-01-14

    Using ab-initio methods, atomic structures and electronic properties of InP (001)/HfO{sub 2} (001) interface are studied within the framework of density functional theory. We examine the InP/HfO{sub 2} model interface electronic structures under varying oxidation conditions. The effects of indium and phosphorous concentrations on interfacial bonding, defect states, band offsets, and the thermodynamic stability at the interface are also investigated. The origin of interfacial gap states in InP (001)/HfO{sub 2} (001) interface are proposed, mainly from the P-rich oxides, which is validated by our experimental work. This highlights the importance of surface passivation prior to high-κ deposition based on the in situ spectroscopic results of atomic layer deposition of HfO{sub 2} on InP.

  9. In situ study of e-beam Al and Hf metal deposition on native oxide InP (100)

    SciTech Connect (OSTI)

    Dong, H.; KC, Santosh; Azcatl, A.; Cabrera, W.; Qin, X.; Brennan, B.; Cho, K.; Wallace, R. M.; Zhernokletov, D.

    2013-11-28

    The interfacial chemistry of thin Al (∼3 nm) and Hf (∼2 nm) metal films deposited by electron beam (e-beam) evaporation on native oxide InP (100) samples at room temperature and after annealing has been studied by in situ angle resolved X-ray photoelectron spectroscopy and low energy ion scattering spectroscopy. The In-oxides are completely scavenged forming In-In/In-(Al/Hf) bonding after Al and Hf metal deposition. The P-oxide concentration is significantly decreased, and the P-oxide chemical states have been changed to more P-rich oxides upon metal deposition. Indium diffusion through these metals before and after annealing at 250 °C has also been characterized. First principles calculation shows that In has lower surface formation energy compared with Al and Hf metals, which is consistent with the observed indium diffusion behavior.

  10. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  11. Coal markets squeeze producers

    SciTech Connect (OSTI)

    Ryan, M.

    2005-12-01

    Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

  12. Variable dimensionality in the uranium fluoride/2-methyl-piperazine system: Synthesis and structures of UFO-5, -6, and -7; Zero-, one-, and two-dimensional materials with unprecedented topologies

    SciTech Connect (OSTI)

    Francis, R.J.; Halasyamani, P.S.; Bee, J.S.; O'Hare, D.

    1999-02-24

    Recently, low temperature (T < 300 C) hydrothermal reactions of inorganic precursors in the presence of organic cations have proven highly productive for the synthesis of novel solid-state materials. Interest in these materials is driven by the astonishingly diverse range of structures produced, as well as by their many potential materials chemistry applications. This report describes the high yield, phase pure hydrothermal syntheses of three new uranium fluoride phases with unprecedented structure types. Through the systematic control of the synthesis conditions the authors have successfully controlled the architecture and dimensionality of the phase formed and selectively synthesized novel zero-, one-, and two-dimensional materials.

  13. pH effect on the separation of uranium fluoride effluents by the reverse osmosis process

    SciTech Connect (OSTI)

    Yun Chen ); Min-Lin Chu; Mu-Chang Shieh , Lung-tan, )

    1992-04-01

    Ammonium fluoride solutions and uranium fluoride effluents (UFE) with solute concentrations from 0.101 to 7,920 kg/m{sup 3}, at pH 2.80 to 9.60, have been treated with a continuous feedback reverse osmosis (RO) process. The solute rejections of NH{sub 4}{sup +}, F{sup {minus}}, and U{sup 6+} depend heavily on the feed pH value. For ammonium fluoride solutions, the rejection ratio of NH{sub 4}{sup +} decreases sharply from ca. 90 to 44.2% with the feed pH increased from 3.30 to 9.60, while that of F{sup {minus}} increases abruptly from 44.8 to 99.9% at the same pH change. For UFE solutions, the rejection ratio of U{sup 6+} remains greater than 90% at pH 2.80-7.13, while that of F{sup {minus}} decreases steadily from 96.4 to 18.8% with decreasing feed pH. Accordingly, the fluoride ions can be separated from UFE solutions under acidic conditions. The changes of solute rejection with feed pH can be explained by the different solubilities of the solutes in the membrane at different pH values. The UFE solutions with {alpha} and {beta} activities at 20.4-53.7 and 8.99-21.3 ({times} 10{sup 5} Baq/m{sup 3}) can be reduced to a level lower than 2.41 and 3.37 ({times}10{sup 5} Baq/m{sup 3}), respectively, by the current RO process.

  14. Performance enhancement of GaN metalsemiconductormetal ultraviolet photodetectors by insertion of ultrathin interfacial HfO{sub 2} layer

    SciTech Connect (OSTI)

    Kumar, Manoj E-mail: aokyay@ee.bilkent.edu.tr; Tekcan, Burak; Okyay, Ali Kemal E-mail: aokyay@ee.bilkent.edu.tr

    2015-03-15

    The authors demonstrate improved device performance of GaN metalsemiconductormetal ultraviolet (UV) photodetectors (PDs) by ultrathin HfO{sub 2} (UT-HfO{sub 2}) layer on GaN. The UT-HfO{sub 2} interfacial layer is grown by atomic layer deposition. The dark current of the PDs with UT-HfO{sub 2} is significantly reduced by more than two orders of magnitude compared to those without HfO{sub 2} insertion. The photoresponsivity at 360?nm is as high as 1.42 A/W biased at 5 V. An excellent improvement in the performance of the devices is ascribed to allowed electron injection through UT-HfO{sub 2} on GaN interface under UV illumination, resulting in the photocurrent gain with fast response time.

  15. Considerations of Alloy N for Fluoride Salt-Cooled High-Temperature Reactor Applications

    SciTech Connect (OSTI)

    Ren, Weiju; Muralidharan, Govindarajan; Wilson, Dane F; Holcomb, David Eugene

    2011-01-01

    Fluoride Salt-Cooled High-Temperature Reactors (FHRs) are a promising new class of thermal-spectrum nuclear reactors. The reactor structural materials must possess high-temperature strength and chemical compatibility with the liquid fluoride salt as well as with a power cycle fluid such as supercritical water while remaining resistant to residual air within the containment. Alloy N was developed for use with liquid fluoride salts and it possesses adequate strength and chemical compatibility up to about 700 C. A distinctive property of FHRs is that their maximum allowable coolant temperature is restricted by their structural alloy maximum service temperature. As the reactor thermal efficiency directly increases with the maximum coolant temperature, higher temperature resistant alloys are strongly desired. This paper reviews the current status of Alloy N and its relevance to FHRs including its design principles, development history, high temperature strength, environmental resistance, metallurgical stability, component manufacturability, ASME codification status, and reactor service requirements. The review will identify issues and provide guidance for improving the alloy properties or implementing engineering solutions.

  16. HF-based etching processes for improving laser damage resistance of fused silica optical surfaces

    SciTech Connect (OSTI)

    Suratwala, T I; Miller, P E; Bude, J D; Steele, R A; Shen, N; Monticelli, M V; Feit, M D; Laurence, T A; Norton, M A; Carr, C W; Wong, L L

    2010-02-23

    The effect of various HF-based etching processes on the laser damage resistance of scratched fused silica surfaces has been investigated. Conventionally polished and subsequently scratched fused silica plates were treated by submerging in various HF-based etchants (HF or NH{sub 4}F:HF at various ratios and concentrations) under different process conditions (e.g., agitation frequencies, etch times, rinse conditions, and environmental cleanliness). Subsequently, the laser damage resistance (at 351 or 355 nm) of the treated surface was measured. The laser damage resistance was found to be strongly process dependent and scaled inversely with scratch width. The etching process was optimized to remove or prevent the presence of identified precursors (chemical impurities, fracture surfaces, and silica-based redeposit) known to lead to laser damage initiation. The redeposit precursor was reduced (and hence the damage threshold was increased) by: (1) increasing the SiF{sub 6}{sup 2-} solubility through reduction in the NH4F concentration and impurity cation impurities, and (2) improving the mass transport of reaction product (SiF{sub 6}{sup 2-}) (using high frequency ultrasonic agitation and excessive spray rinsing) away from the etched surface. A 2D finite element crack-etching and rinsing mass transport model (incorporating diffusion and advection) was used to predict reaction product concentration. The predictions are consistent with the experimentally observed process trends. The laser damage thresholds also increased with etched amount (up to {approx}30 {micro}m), which has been attributed to: (1) etching through lateral cracks where there is poor acid penetration, and (2) increasing the crack opening resulting in increased mass transport rates. With the optimized etch process, laser damage resistance increased dramatically; the average threshold fluence for damage initiation for 30 {micro}m wide scratches increased from 7 to 41 J/cm{sup 2}, and the statistical probability of damage initiation at 12 J/cm{sup 2} of an ensemble of scratches decreased from {approx}100 mm{sup -1} of scratch length to {approx}0.001 mm{sup -1}.

  17. Metal-Organic Frameworks Based on Previously Unknown Zr8/Hf Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clusters | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Metal-Organic Frameworks Based on Previously Unknown Zr8/Hf Cubic Clusters Previous Next List Dawei Feng, Hai-Long Jiang, Ying-Pin Chen, Zhi-Yuan Gu, Zhangwen Wei, and Hong-Cai Zhou, Inorg. Chem. 52, 12661-12667 (2013) DOI: 10.1021/ic4018536 Abstract Image Abstract: The ongoing study of zirconium- and hafnium-porphyrinic metal-organic frameworks (MOFs) led to the discovery of isostructural MOFs based

  18. Current-induced spin-orbit torque switching of perpendicularly magnetized Hf|CoFeB|MgO and Hf|CoFeB|TaO{sub x} structures

    SciTech Connect (OSTI)

    Akyol, Mustafa; Yu, Guoqiang; Alzate, Juan G.; Upadhyaya, Pramey; Li, Xiang; Wong, Kin L.; Khalili Amiri, Pedram; Wang, Kang L.; Ekicibil, Ahmet

    2015-04-20

    We study the effect of the oxide layer on current-induced perpendicular magnetization switching properties in Hf|CoFeB|MgO and Hf|CoFeB|TaO{sub x} tri-layers. The studied structures exhibit broken in-plane inversion symmetry due to a wedged CoFeB layer, resulting in a field-like spin-orbit torque (SOT), which can be quantified by a perpendicular (out-of-plane) effective magnetic field. A clear difference in the magnitude of this effective magnetic field (H{sub z}{sup FL}) was observed between these two structures. In particular, while the current-driven deterministic perpendicular magnetic switching was observed at zero magnetic bias field in Hf|CoFeB|MgO, an external magnetic field is necessary to switch the CoFeB layer deterministically in Hf|CoFeB|TaO{sub x}. Based on the experimental results, the SOT magnitude (H{sub z}{sup FL} per current density) in Hf|CoFeB|MgO (?14.12?Oe/10{sup 7} A cm{sup ?2}) was found to be almost 13 larger than that in Hf|CoFeB|TaO{sub x} (?1.05?Oe/10{sup 7} A cm{sup ?2}). The CoFeB thickness dependence of the magnetic switching behavior, and the resulting ?H{sub z}{sup FL} generated by in-plane currents are also investigated in this work.

  19. Process for producing silicon

    DOE Patents [OSTI]

    Olson, Jerry M. (Lakewood, CO); Carleton, Karen L. (Boulder, CO)

    1984-01-01

    A process for producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  20. Method of producing imines

    DOE Patents [OSTI]

    Sithambaram, Shanthakumar (Storrs, CT); Son, Young-Chan (Storrs, CT); Suib, Steven L. (Storrs, CT)

    2008-04-08

    A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.

  1. Process for producing silicon

    DOE Patents [OSTI]

    Olson, J.M.; Carleton, K.L.

    1982-06-10

    A process of producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  2. polymers produced by nature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polymers produced by nature - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  3. Local elastic modulus of RF sputtered HfO{sub 2} thin film by atomic force acoustic microscopy

    SciTech Connect (OSTI)

    Jena, S. Tokas, R. B. Sarkar, P. Thakur, S.; Sahoo, N. K.; Misal, J. S.; Rao, K. D.

    2014-04-24

    Atomic force acoustic microscopy (AFAM) is a useful nondestructive technique for measurement of local elastic modulus of materials at nano-scale spatial resolution by measuring the contact resonance spectra for higher order modes of the AFM cantilever. The elastic modulus of RF sputtered HfO{sub 2} thin film has been measured quantitatively, using reference approach in which measurements are performed on the test and reference samples. Using AFAM, the measured elastic modulus of the HfO{sub 2} thin film is 22327 GPa, which is in agreement with the literature value of 22040 GPa for atomic layer deposited HfO{sub 2} thin film using nanoindentation technique.

  4. Accident prevention and Clean Air Act Amendments of 1990 with particular reference to anhydrous hydrogen fluoride

    SciTech Connect (OSTI)

    Kaiser, G.D. (Science Applications International Corp., McLean, VA (United States))

    1993-07-01

    The sections of the Clean Air Act Amendments (CAAA) of 1990 that refer to accident prevention are to be found in Title III. Two significant requirements of the CAAA in this respect relate to the responsibilities of the Occupational Safety and Health Administration (OSHA), which has promulgated a new Process Safety Management (PSM) standard and the Environmental Protection Agency (EPA), which at the time of writing, is developing Risk Management Program (RMP) regulations. The focus of this paper is on how the requirements of the CAAA may affect the reasons for performing a Quantitative Risk Assessment (QRA) or may affect the results of QRA. In order to limit the discussion, this paper focuses on HF. First, the CAAA requires that the EPA assess the hazards associated with HF; the EPA's current draft report is discussed. Second, a generic assessment of the risks associated with the use of HF is given, with emphasis on alkylation units in refineries. The principal contributors to risk are listed. Finally, an assessment of OSHA's PSM standard 29 CFR 1910.119, the related requirements of state laws such as California's Risk Management and Prevention Program and the potential requirement of EPA's Risk Management Program are given, including an assessment of how these requirements may influence quantitative estimates of risk. 13 refs., 1 fig.

  5. Reactions of aluminum with uranium fluorides and oxyfluorides

    SciTech Connect (OSTI)

    Leitnaker, J.M.; Nichols, R.W.; Lankford, B.S.

    1991-12-31

    Every 30 to 40 million operating hours a destructive reaction is observed in one of the {approximately}4000 large compressors that move UF{sub 6} through the gaseous diffusion plants. Despite its infrequency, such a reaction can be costly in terms of equipment and time. Laboratory experiments reveal that the presence of moderate pressures of UF{sub 6} actually cools heated aluminum, although thermodynamic calculations indicate the potential for a 3000-4000{degrees}C temperature rise. Within a narrow and rather low (<100 torr; 1 torr = 133.322 Pa) pressure range, however, the aluminum is seen to react with sufficient heat release to soften an alumina boat. Three things must occur in order for aluminum to react vigorously with either UF{sub 6} or UO{sub 2}F{sub 2}. 1. An initiating source of heat must be provided. In the compressors, this source can be friction, permitted by disruption of the balance of the large rotating part or by creep of the aluminum during a high-temperature treatment. In the absence of this heat source, compressors have operated for 40 years in UF{sub 6} without significant reaction. 2. The film protecting the aluminum must be breached. Melting (of UF{sub 5} at 620 K or aluminum at 930 K) can cause such a breach in laboratory experiments. In contrast, holding Al samples in UF{sub 6} at 870 K for several hours produces only moderate reaction. Rubbing in the cascade can undoubtedly breach the protective film. 3. Reaction products must not build up and smother the reaction. While uranium products tend to dissolve or dissipate in molten aluminum, AIF{sub 3} shows a remarkable tendency to surround and hence protect even molten aluminum. Hence the initial temperature rise must be rapid and sufficient to move reactants into a temperature region in which products are removed from the reaction site.

  6. Fluoride adsorption on goethite in relation to different types of surface sites

    SciTech Connect (OSTI)

    Hiemstra, T.; Van Riemsdijk, W.H.

    2000-05-01

    Metal (hydr)oxides have different types of surface groups. Fluoride ions have been used as a probe to assess the number of surface sites. The authors have studied the F{sup {minus}} adsorption on goethite by measuring the F{sup {minus}} and H{sup +} interaction and F{sup {minus}} adsorption isotherms. Fluoride ions exchange against singly coordinated surface hydroxyls at low F{sup {minus}} concentrations. At higher concentrations also the doubly coordinated OH groups are involved. The replacement of a surface OH{sup {minus}} by F{sup {minus}} suggests that all F charge ({minus}1) is located at the surface in contrast to oxyanions which have a charge distribution in the interface due to the binding structure in which the anion only partially coordinates with the surface. Analysis of their F{sup {minus}} data with the CD-MUSIC approach shows that the formation of the fluoride surface complex is accompanied by a redistribution of charge. This is supposed to be due to a net switch in the H bonding as a result of the change of the type of surface complex from donating (FeOH, FeOH{sub 2}) to proton accepting (FeF). The modeled redistribution of charge is approximately equivalent with the change of a donating H bond into an accepting H bond. At high F{sup {minus}} concentrations precipitation of F{sup {minus}}, as for instance FeF{sub 3}(s), may occur. The rate of formation is catalyzed by the presence of high electrolyte concentrations.

  7. Produce diesel from gas

    SciTech Connect (OSTI)

    Singleton, A.H.; Regier, S.

    1983-05-01

    The Gulf Badger process converts natural gas directly to hydrocarbon liquids by a catalytic chemical route. Fischer-Tropsch process--which is a carbon monoxide polymerization/ hydrogenation process--is used. Because the process is exothermal, heat removal by either tubular fixed bed, fluidized bed, or slurry are considered. A wax build up of high molecular weight material is removed by hydro-stripping two-bed system. The demonstration plant flow diagram shows the process to be: natural gas is compressed, recycled with CO/sub 2/, sulfur is removed in a zinc oxide drum, CO is removed in amine scrubbers, H/sub 2//CO ratio is adjusted to produce a hydrogen rich stream, and stabilization and distribution follow. A monitoring system using computers is part of the demonstration unit.

  8. Coal-Producing Region

    Gasoline and Diesel Fuel Update (EIA)

    . Coal Production by State (thousand short tons) Year to Date Coal-Producing Region and State July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change Alabama 3,192 3,504 4,331 10,718 12,345 -13.2 Alaska 255 345 372 866 1,178 -26.5 Arizona 1,762 1,912 2,165 5,429 5,979 -9.2 Arkansas 26 27 18 74 58 27.4 Colorado 5,123 5,078 6,574 15,464 18,367 -15.8 Illinois 13,967 13,360 14,816 44,105 42,575 3.6 Indiana 9,124 8,577 9,805 27,164 29,328 -7.4 Kansas 42 49 5 144 16 NM

  9. Methods of using ionic liquids having a fluoride anion as solvents

    DOE Patents [OSTI]

    Pagoria, Philip (Livermore, CA); Maiti, Amitesh (San Ramon, CA); Gash, Alexander (Brentwood, CA); Han, Thomas Yong (Pleasanton, CA); Orme, Christine (Oakland, CA); Fried, Laurence (Livermore, CA)

    2011-12-06

    A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90.degree. C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90.degree. C. during the contacting.

  10. Anodic activation of niobium and tantalum in phosphate-fluoride solutions

    SciTech Connect (OSTI)

    Bairachnyi, B.I.; Stepanova, I.I.

    1988-01-10

    An analysis of the polarization curves for the anodic dissolution of niobium and tantalum in the coordinates showed they are described by Fafel's equation with a slop of the linear sections of -0.125 for niobium and -0.123 for tantalum. In solutions that contained hydrofluoric acid the anodic-anionic polarization of niobium and tantalum was accompanied by the destruction of the oxide film by the fluoride ions and dissolution of the metal phase. Effects of polishing and glossing of the surface of the investigated metals were observed at certain conditions.

  11. Numerical prediction of the thermodynamic properties of ternary Al-Ni-Hf alloys

    SciTech Connect (OSTI)

    Romanowska, Jolanta; Kotowski, S?awomir; Zagula-Yavorska, Maryana

    2014-10-06

    Thermodynamic properties of ternary Al-Hf-Ni system, such as {sup ex}G, ?{sub Al}, ?{sub Ni} and ?{sub Zr} at 1373K were predicted on the basis of thermodynamic properties of binary systems included in the investigated ternary system. The idea of predicting {sup ex}G values was regarded as the calculation of excess Gibbs energy values inside a certain area (a Gibbs triangle) unless all boundary conditions, that is values of {sup ex}G on all legs of the triangle are known. {sup ex}G and L{sub ijk} ternary interaction parameters in the Muggianu extension of the Redlich-Kister formalism are calculated numerically using Wolfram Mathematica 9 software.

  12. System for treating produced water

    DOE Patents [OSTI]

    Sullivan, Enid J. (Los Alamos, NM); Katz, Lynn (Austin, TX); Kinney, Kerry (Austin, TX); Bowman, Robert S. (Lemitar, NM); Kwon, Soondong (Kyungbuk, KR)

    2010-08-03

    A system and method were used to treat produced water. Field-testing demonstrated the removal of contaminants from produced water from oil and gas wells.

  13. Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility

    SciTech Connect (OSTI)

    Herting, Daniel L.

    2014-01-29

    Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

  14. Methods for producing complex films, and films produced thereby

    DOE Patents [OSTI]

    Duty, Chad E.; Bennett, Charlee J. C.; Moon, Ji -Won; Phelps, Tommy J.; Blue, Craig A.; Dai, Quanqin; Hu, Michael Z.; Ivanov, Ilia N.; Jellison, Jr., Gerald E.; Love, Lonnie J.; Ott, Ronald D.; Parish, Chad M.; Walker, Steven

    2015-11-24

    A method for producing a film, the method comprising melting a layer of precursor particles on a substrate until at least a portion of the melted particles are planarized and merged to produce the film. The invention is also directed to a method for producing a photovoltaic film, the method comprising depositing particles having a photovoltaic or other property onto a substrate, and affixing the particles to the substrate, wherein the particles may or may not be subsequently melted. Also described herein are films produced by these methods, methods for producing a patterned film on a substrate, and methods for producing a multilayer structure.

  15. Total ionizing dose effect of ?-ray radiation on the switching characteristics and filament stability of HfOx resistive random access memory

    SciTech Connect (OSTI)

    Fang, Runchen; Yu, Shimeng; Gonzalez Velo, Yago; Chen, Wenhao; Holbert, Keith E.; Kozicki, Michael N.; Barnaby, Hugh

    2014-05-05

    The total ionizing dose (TID) effect of gamma-ray (?-ray) irradiation on HfOx based resistive random access memory was investigated by electrical and material characterizations. The memory states can sustain TID level ?5.2 Mrad (HfO{sub 2}) without significant change in the functionality or the switching characteristics under pulse cycling. However, the stability of the filament is weakened after irradiation as memory states are more vulnerable to flipping under the electrical stress. X-ray photoelectron spectroscopy was performed to ascertain the physical mechanism of the stability degradation, which is attributed to the Hf-O bond breaking by the high-energy ?-ray exposure.

  16. AN EXPERIMENT TO STUDY PEBBLE BED LIQUID-FLUORIDE-SALT HEAT TRANSFER

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Aaron, Adam M; Heatherly, Dennis Wayne; Holcomb, David Eugene; Kisner, Roger A; McCarthy, Mike; Peretz, Fred J; Wilgen, John B; Wilson, Dane F

    2011-01-01

    A forced-convection liquid-fluoride-salt loop is being constructed at Oak Ridge National Laboratory (ORNL). This loop was designed as a versatile experimental facility capable of supporting general thermal/fluid/corrosion testing of liquid fluoride salts. The initial test configuration is designed to support the Pebble Bed Advanced High-Temperature Reactor and incorporates a test section designed to examine the heat transfer behavior of FLiNaK salt in a heated pebble bed. The loop is constructed of Inconel 600 and is capable of operating at up to 700oC. It contains a total of 72 kg of FLiNaK salt and uses an overhung impeller centrifugal sump pump that can provide FLiNaK flow at 4.5 kg/s with a head of 0.125 MPa. The test section is made of silicon carbide (SiC) and contains approximately 600 graphite spheres, 3 cm in diameter. The pebble bed is heated using a unique inductive technique. A forced induction air cooler removes the heat added to the pebble bed. The salt level within the loop is maintained by controlling an argon cover gas pressure. Salt purification is performed in batch mode by transferring the salt from the loop into a specially made nickel crucible system designed to remove oxygen, moisture and other salt impurities. Materials selection for the loop and test section material was informed by 3 months of Inconel 600 and SiC corrosion testing as well as tests examining subcomponent performance in the salt. Several SiC-to-Inconel 600 mechanical joint designs were considered before final salt and gas seals were chosen. Structural calculations of the SiC test section were performed to arrive at a satisfactory test section configuration. Several pump vendors provided potential loop pump designs; however, because of cost, the pump was designed and fabricated in-house. The pump includes a commercial rotating dry gas shaft seal to maintain loop cover gas inventory. The primary instrumentation on the loop includes temperature, pressure, and loop flow rate measurement. Although techniques for all these measurements have improved, no commercial instrumentation was available for flow and pressure measurement that had been tested under these conditions. Instrumentation was tested and modified to meet both corrosion and temperature requirements. This paper discusses the issues encountered during the design and construction of the ORNL Liquid Salt Loop and should prove useful to those contemplating construction of similar high-temperature liquid-fluoride-salt facilities.

  17. Effect of the oxide layer on current-induced spin-orbit torques in Hf|CoFeB|MgO and Hf|CoFeB|TaO{sub x} structures

    SciTech Connect (OSTI)

    Akyol, Mustafa; Alzate, Juan G.; Yu, Guoqiang; Upadhyaya, Pramey; Wong, Kin L.; Khalili Amiri, Pedram; Wang, Kang L.; Ekicibil, Ahmet

    2015-01-19

    We study the effect of the oxide layer on the current-induced spin-orbit torques (SOTs) in perpendicularly magnetized Hf|CoFeB|MgO (MgO-capped) or Hf|CoFeB|TaO{sub x} (TaO{sub x}-capped) structures. The effective fields corresponding to both the field-like and damping-like current-induced SOTs are characterized using electric transport measurements. Both torques are found to be significantly stronger in MgO-capped structures than those in TaO{sub x}-capped structures. The difference in field-like and damping-like SOTs in the different structures may be attributed to the different Rashba-like Hamiltonian, arising from the difference in the electric potential profiles across the oxide|ferromagnet interfaces in the two cases, as well as possible structural and oxidation differences in the underlying CoFeB and Hf layers. Our results show that the oxide layer in heavy-metal|ferromagnet|oxide trilayer structures has a very significant effect on the generated SOTs for manipulation of ferromagnetic layers. These findings could potentially be used to engineer SOT devices with enhanced current-induced switching efficiency.

  18. Morphology and chemical termination of HF-etched Si{sub 3}N{sub 4} surfaces

    SciTech Connect (OSTI)

    Liu, Li-Hong; Debenedetti, William J. I.; Peixoto, Tatiana; Gokalp, Sumeyra; Shafiq, Natis; Veyan, Jean-François; Chabal, Yves J.; Michalak, David J.; Hourani, Rami

    2014-12-29

    Several reports on the chemical termination of silicon nitride films after HF etching, an important process in the microelectronics industry, are inconsistent claiming N-H{sub x}, Si-H, or fluorine termination. An investigation combining infrared and x-ray photoelectron spectroscopies with atomic force and scanning electron microscopy imaging reveals that under some processing conditions, salt microcrystals are formed and stabilized on the surface, resulting from products of Si{sub 3}N{sub 4} etching. Rinsing in deionized water immediately after HF etching for at least 30 s avoids such deposition and yields a smooth surface without evidence of Si-H termination. Instead, fluorine and oxygen are found to terminate a sizeable fraction of the surface in the form of Si-F and possibly Si-OH bonds. The relatively unique fluorine termination is remarkably stable in both air and water and could lead to further chemical functionalization pathways.

  19. Experiments and theory on parametric instabilities excited in HF heating experiments at HAARP

    SciTech Connect (OSTI)

    Kuo, Spencer; Snyder, Arnold; Lee, M. C.

    2014-06-15

    Parametric instabilities excited by O-mode HF heater and the induced ionospheric modification were explored via HAARP digisonde operated in a fast mode. The impact of excited Langmuir waves and upper hybrid waves on the ionosphere are manifested by bumps in the virtual spread, which expand the ionogram echoes upward as much as 140?km and the downward range spread of the sounding echoes, which exceeds 50?km over a significant frequency range. The theory of parametric instabilities is presented. The theory identifies the ionogram bump located between the 3.2?MHz heater frequency and the upper hybrid resonance frequency and the bump below the upper hybrid resonance frequency to be associated with the Langmuir and upper hybrid instabilities, respectively. The Langmuir bump is located close to the upper hybrid resonance frequency, rather than to the heater frequency, consistent with the theory. Each bump in the virtual height spread of the ionogram is similar to the cusp occurring in daytime ionograms at the E-F2 layer transition, indicating that there is a small ledge in the density profile similar to E-F2 layer transitions. The experimental results also show that the strong impact of the upper hybrid instability on the ionosphere can suppress the Langmuir instability.

  20. Fluoride Salt-Cooled High-Temperature Reactor Technology Development and Demonstration Roadmap

    SciTech Connect (OSTI)

    Holcomb, David Eugene; Flanagan, George F; Mays, Gary T; Pointer, William David; Robb, Kevin R; Yoder Jr, Graydon L

    2013-11-01

    Fluoride salt-cooled High-temperature Reactors (FHRs) are an emerging reactor class with potentially advantageous performance characteristics, and fully passive safety. This roadmap describes the principal remaining FHR technology challenges and the development path needed to address the challenges. This roadmap also provides an integrated overview of the current status of the broad set of technologies necessary to design, evaluate, license, construct, operate, and maintain FHRs. First-generation FHRs will not require any technology breakthroughs, but do require significant concept development, system integration, and technology maturation. FHRs are currently entering early phase engineering development. As such, this roadmap is not as technically detailed or specific as would be the case for a more mature reactor class. The higher cost of fuel and coolant, the lack of an approved licensing framework, the lack of qualified, salt-compatible structural materials, and the potential for tritium release into the environment are the most obvious issues that remain to be resolved.

  1. Temperature requirements and corrosion rates in combustion driven hydrogen fluoride supersonic diffusion lasers

    SciTech Connect (OSTI)

    Nordine, P.C.

    1983-08-01

    A maximum F-atom yield from F2 occurs in a combustion driven hydrogen fluoride supersonic diffusion laser (HFSDL) because the amount of fluorine reacted with hydrogen (or deuterium) continues to increase with temperature after most of the unreacted fluorine has been thermally dissociated. A small decease from the maximum combustor F-atom yield allows a significant decease in the required temperature and in the corrosion rates that uncooled laser nozzles would display. The temperatures that give F-atom yields equal to 95 percent of the maximum values were calculated for typical HFSDL combustor pressures and F-atom mole fractions and the corrosion rates of uncooled nozzles were evaluated at these temperatures. The corrosion rates of materials resistant to fluorine attack at the highest temperatures would allow HFSDL applications or test experiments up to several hours duration.

  2. Detailed optical characterization of a near diffraction limited xenon fluoride laser

    SciTech Connect (OSTI)

    Londono, C. ); Smith, M.J.; Trainor, D.W.; Itzkan, I. ); Berggren, R. ); Fulghum, S.F. )

    1988-12-01

    A 1 m gain length, electron beam pumped xenon fluoride laser (lambda = 353, 351 nm) utilizing two laser mixtures of lean and rich NF/sub 3/, with Xe and balance Ne, was operated with a confocal unstable resonator with magnification of 2.24. The resultant beam quality was diagnosed with both shearing interferometry to measure near-field phase and far-field focal spot evaluation techniques. These measurements resulted in a beam quality of <1.15 times the diffraction limit with no evidence of the wide angle energy loss. This laser device was fully characterized with regard to electron beam deposition uniformity, transient refractive index effects, and optical quality of the resonator and diagnostic components.

  3. Features of the band structure and conduction mechanisms in the n-HfNiSn semiconductor heavily doped with Ru

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Romaka, V. V.; Stadnyk, Yu. V.; Korzh, R. O.; Krayovskyy, V. Ya.; Horyn, A. M.

    2014-12-15

    The crystal and electronic structure and energy and kinetic properties of the n-HfNiSn semiconductor heavily doped with a Ru acceptor impurity are investigated in the temperature and Ru concentration ranges T = 80400 K and N{sub A}{sup Ru} ? 9.5 10{sup 19}?5.7 10{sup 20} cm{sup ?3} (x = 00.03), respectively. The mechanism of structural-defect generation is established, which changes the band gap and degree of compensation of the semiconductor and consists in the simultaneous concentration reduction and elimination of donor structural defects by means of the displacement of ?1% of Ni atoms from the Hf (4a) positions, the generation of acceptor structural defects upon the substitution of Ru atoms for Ni atoms in the 4c positions, and the generation of donor defects in the form of vacancies in the Sn (4b) positions. The calculated electronic structure of HfNi{sub 1?x}Ru{sub x}Sn is consistent with the experiment. The results obtained are discussed within the Shklovsky-Efros model for a heavily doped and compensated semiconductor.

  4. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  5. Method of producing submicron size particles and product produced thereby

    DOE Patents [OSTI]

    Bourne, R.S.; Eichman, C.C.; Welbon, W.W.

    1988-05-11

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in ''metallic inks.'' 4 figs.

  6. The integration of Human Factors (HF) in the SAR process training course text

    SciTech Connect (OSTI)

    Ryan, T.G.

    1995-03-01

    This text provides the technical basis for a two-day course on human factors (HF), as applied to the Safety Analysis Report (SAR) process. The overall objective of this text and course is to: provide the participant with a working knowledge of human factors-related requirements, suggestions for doing a human safety analysis applying a graded approach, and an ability to demonstrate using the results of the human safety analysis, that human factors elements as defined by DOE (human factors engineering, procedures, training, oversight, staffing, qualifications), can support wherever necessary, nuclear safety commitments in the SAR. More specifically, the objectives of the text and course are: (1) To provide the SAR preparer with general guidelines for doing HE within the context of a graded approach for the SAR; (2) To sensitize DOE facility managers and staff, safety analysts and SAR preparers, independent reviewers, and DOE reviewers and regulators, to DOE Order 5480.23 requirements for HE in the SAR; (3) To provide managers, analysts, reviewers and regulators with a working knowledge of HE concepts and techniques within the context of a graded approach for the SAR, and (4) To provide SAR managers and DOE reviewers and regulators with general guidelines for monitoring and coordinating the work of preparers of HE inputs throughout the SAR process, and for making decisions regarding the safety relevance of HE inputs to the SAR. As a ready reference for implementing the human factors requirements of DOE Order 5480.22 and DOE Standard 3009-94, this course text and accompanying two-day course are intended for all persons who are involved in the SAR.

  7. Carbide Coatings for Nickel Alloys, Graphite and Carbon/Carbon Composites to be used in Fluoride Salt Valves

    SciTech Connect (OSTI)

    Nagle, Denis; Zhang, Dajie

    2015-10-22

    The focus of this research was concerned with developing materials technology that supports the evolution of Generation IV Advanced High Temperature Reactor (AHTR) concepts. Specifically, we investigate refractory carbide coatings for 1) nickel alloys, and 2) commercial carbon-carbon composites (CCCs). Numerous compelling reasons have driven us to focus on carbon and carbide materials. First, unlike metals, the strength and modulus of CCCs increase with rising temperature. Secondly, graphite and carbon composites have been proven effective for resisting highly corrosive fluoride melts such as molten cryolite [Na?AlF?] at ~1000C in aluminum reduction cells. Thirdly, graphite and carbide materials exhibit extraordinary radiation damage tolerance and stability up to 2000C. Finally, carbides are thermodynamically more stable in liquid fluoride salt than the corresponding metals (i.e. Cr and Zr) found in nickel based alloys.

  8. Method of producing molybdenum-99

    DOE Patents [OSTI]

    Pitcher, Eric John

    2013-05-28

    Method of producing molybdenum-99, comprising accelerating ions by means of an accelerator; directing the ions onto a metal target so as to generate neutrons having an energy of greater than 10 MeV; directing the neutrons through a converter material comprising techentium-99 to produce a mixture comprising molybdenum-99; and, chemically extracting the molybdenum-99 from the mixture.

  9. Method for producing a borohydride

    DOE Patents [OSTI]

    Kong, Peter C.

    2010-06-22

    A method for producing a borohydride is described that includes the steps of providing a source of borate; providing a material that chemically reduces the source of the borate to produce a borohydride; and reacting the source of the borate and the material by supplying heat at a temperature that substantially effects the production of the borohydride.

  10. Method for producing a borohydride

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID)

    2008-09-02

    A method for producing a borohydride is described and which includes the steps of providing a source of borate; providing a material which chemically reduces the source of the borate to produce a borohydride; and reacting the source of borate and the material by supplying heat at a temperature which substantially effects the production of the borohydride.

  11. Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes

    SciTech Connect (OSTI)

    Wang, Feng; Robert, Rosa; Chernova, Natasha A.; Pereira, Nathalie; Omenya, Fredrick; Badway, Fadwa; Hua, Xiao; Ruotolo, Michael; Zhang, Ruigang; Wu, Lijun; Volkov, Vyacheslav; Su, Dong; Key, Baris; Whittingham, M. Stanley; Grey, Clare P.; Amatucci, Glenn G.; Zhu, Yimei; Graetz, Jason

    2015-10-15

    Materials that undergo a conversion reaction with lithium (e.g., metal fluorides MF{sub 2}: M = Fe, Cu, ...) often accommodate more than one Li atom per transition-metal cation, and are promising candidates for high-capacity cathodes for lithium ion batteries. However, little is known about the mechanisms involved in the conversion process, the origins of the large polarization during electrochemical cycling, and why some materials are reversible (e.g., FeF{sub 2}) while others are not (e.g., CuF{sub 2}). In this study, we investigated the conversion reaction of binary metal fluorides, FeF{sub 2} and CuF{sub 2}, using a series of local and bulk probes to better understand the mechanisms underlying their contrasting electrochemical behavior. X-ray pair-distribution-function and magnetization measurements were used to determine changes in short-range ordering, particle size and microstructure, while high-resolution transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS) were used to measure the atomic-level structure of individual particles and map the phase distribution in the initial and fully lithiated electrodes. Both FeF{sub 2} and CuF{sub 2} react with lithium via a direct conversion process with no intercalation step, but there are differences in the conversion process and final phase distribution. During the reaction of Li{sup +} with FeF{sub 2}, small metallic iron nanoparticles (<5 nm in diameter) nucleate in close proximity to the converted LiF phase, as a result of the low diffusivity of iron. The iron nanoparticles are interconnected and form a bicontinuous network, which provides a pathway for local electron transport through the insulating LiF phase. In addition, the massive interface formed between nanoscale solid phases provides a pathway for ionic transport during the conversion process. These results offer the first experimental evidence explaining the origins of the high lithium reversibility in FeF{sub 2}. In contrast to FeF{sub 2}, no continuous Cu network was observed in the lithiated CuF{sub 2}; rather, the converted Cu segregates to large particles (5-12 nm in diameter) during the first discharge, which may be partially responsible for the lack of reversibility in the CuF{sub 2} electrode.

  12. Cellulase producing microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H.C.

    1997-12-30

    Bacteria which produce large amounts of cellulase--containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualifies for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques. 5 figs.

  13. Cellulase producing microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H. Craig (Lenoir City, TN)

    1997-01-01

    Bacteria which produce large amounts of cellulase--containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualifies for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques.

  14. Microorganisms for producing organic acids

    DOE Patents [OSTI]

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-09-30

    Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

  15. Methods of producing cesium-131

    DOE Patents [OSTI]

    Meikrantz, David H; Snyder, John R

    2012-09-18

    Methods of producing cesium-131. The method comprises dissolving at least one non-irradiated barium source in water or a nitric acid solution to produce a barium target solution. The barium target solution is irradiated with neutron radiation to produce cesium-131, which is removed from the barium target solution. The cesium-131 is complexed with a calixarene compound to separate the cesium-131 from the barium target solution. A liquid:liquid extraction device or extraction column is used to separate the cesium-131 from the barium target solution.

  16. Thickness independent reduced forming voltage in oxygen engineered HfO{sub 2} based resistive switching memories

    SciTech Connect (OSTI)

    Sharath, S. U. Kurian, J.; Komissinskiy, P.; Hildebrandt, E.; Alff, L.; Bertaud, T.; Walczyk, C.; Calka, P.; Schroeder, T.

    2014-08-18

    The conducting filament forming voltage of stoichiometric hafnium oxide based resistive switching layers increases linearly with layer thickness. Using strongly reduced oxygen deficient hafnium oxide thin films grown on polycrystalline TiN/Si(001) substrates, the thickness dependence of the forming voltage is strongly suppressed. Instead, an almost constant forming voltage of about 3?V is observed up to 200?nm layer thickness. This effect suggests that filament formation and switching occurs for all samples in an oxidized HfO{sub 2} surface layer of a few nanometer thickness while the highly oxygen deficient thin film itself merely serves as a oxygen vacancy reservoir.

  17. Room temperature strain rate sensitivity in precursor derived HfO{sub 2}/Si-C-N(O) ceramic nanocomposites

    SciTech Connect (OSTI)

    Sujith, Ravindran; Kumar, Ravi

    2014-01-15

    Investigation on the room temperature strain rate sensitivity using depth sensing nanoindentation is carried out on precursor derived HfO{sub 2}/Si-C-N(O) ceramic nanocomposite sintered using pulsed electric current sintering. Using constant load method the strain rate sensitivity values are estimated. Lower strain rate sensitivity of ? 3.7 10{sup ?3} is observed and the limited strain rate sensitivity of these ceramic nanocomposites is explained in terms of cluster model. It is concluded that presence of amorphous Si-C-N(O) clusters are responsible for the limited flowability in these ceramics.

  18. Methods of producing transportation fuel

    DOE Patents [OSTI]

    Nair, Vijay; Roes, Augustinus Wilhelmus Maria; Cherrillo, Ralph Anthony; Bauldreay, Joanna M.

    2011-12-27

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

  19. Energy-Efficient, High-Color-Rendering LED Lamps Using Oxyfluoride and Fluoride Phosphors

    SciTech Connect (OSTI)

    Setlur, A.; Radkov, E; Henderson, C; Her, J; Srivastava, A; Karkada, N; Kishore, M; Kumar, N; Aesram, D; et al.

    2010-01-01

    LED lamps using phosphor downconversion can be designed to replace incandescent or halogen sources with a 'warm-white' correlated color temperature (CCT) of 2700-3200 K and a color rendering index (CRI) greater than 90. However, these lamps have efficacies of {approx}70% of standard 'cool-white' LED packages (CCT = 4500-6000 K; CRI = 75-80). In this report, we describe structural and luminescence properties of fluoride and oxyfluoride phosphors, specifically a (Sr,Ca){sub 3}(Al,Si)O{sub 4}(F,O):Ce{sup 3+} yellow-green phosphor and a K{sub 2}TiF{sub 6}:Mn{sup 4+} red phosphor, that can reduce this gap and therefore meet the spectral and efficiency requirements for high-efficacy LED lighting. LED lamps with a warm-white color temperature (3088 K), high CRI (90), and an efficacy of {approx}82 lm/W are demonstrated using these phosphors. This efficacy is {approx}85% of comparable cool-white lamps using typical Y{sub 3}Al{sub 5}O{sub 12}:Ce{sup 3+}-based phosphors, significantly reducing the efficacy gap between warm-white and cool-white LED lamps that use phosphor downconversion.

  20. Preliminary Demonstration Reactor Point Design for the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Qualls, A. L.; Betzler, Benjamin R.; Brown, Nicholas R.; Carbajo, Juan; Greenwood, Michael Scott; Hale, Richard Edward; Harrison, Thomas J.; Powers, Jeffrey J.; Robb, Kevin R.; Terrell, Jerry W.

    2015-12-01

    Development of the Fluoride Salt-Cooled High-Temperature Reactor (FHR) Demonstration Reactor (DR) is a necessary intermediate step to enable commercial FHR deployment through disruptive and rapid technology development and demonstration. The FHR DR will utilize known, mature technology to close remaining gaps to commercial viability. Lower risk technologies are included in the initial FHR DR design to ensure that the reactor can be built, licensed, and operated within an acceptable budget and schedule. These technologies include tristructural-isotropic (TRISO) particle fuel, replaceable core structural material, the use of that same material for the primary and intermediate loops, and tube-and-shell heat exchangers. This report provides an update on the development of the FHR DR. At this writing, the core neutronics and thermal hydraulics have been developed and analyzed. The mechanical design details are still under development and are described to their current level of fidelity. It is anticipated that the FHR DR can be operational within 10 years because of the use of low-risk, near-term technology options.

  1. Understanding Polymorphism Formation in Electrospun Fibers of Immiscible Poly(vinylidene fluoride) Blends

    SciTech Connect (OSTI)

    G Zhong; L Zhang; R Su; K Wang; H Fong; L Zhu

    2011-12-31

    Effects of electric poling, mechanical stretching, and dipolar interaction on the formation of ferroelectric ({beta} and/or {gamma}) phases in poly(vinylidene fluoride) (PVDF) have been studied in electrospun fibers of PVDF/polyacrylonitrile (PAN) and PVDF/polysulfone (PSF) blends with PVDF as the minor component, using wide-angle X-ray diffraction and Fourier transform infrared techniques. Experimental results of as-electrospun neat PVDF fibers (beaded vs. bead-free) showed that mechanical stretching during electrospinning, rather than electric poling, was effective to induce ferroelectric phases. For as-electrospun PVDF blend fibers with the non-polar PSF matrix, mechanical stretching during electrospinning again was capable of inducing some ferroelectric phases in addition to the major paraelectric ({alpha}) phase. However, after removing the mechanical stretching in a confined melt-recrystallization process, only the paraelectric phase was obtained. For as-electrospun PVDF blend fibers with the polar (or ferroelectric) PAN matrix, strong intermolecular interactions between polar PAN and PVDF played an important role in the ferroelectric phase formation in addition to the mechanical stretching effect during electrospinning. Even after the removal of mechanical stretching through the confined melt-recrystallization process, a significant amount of ferroelectric phases persisted. Comparing the ferroelectric phase formation between PVDF/PSF and PVDF/PAN blend fibers, we concluded that the local electric field-dipole interactions were the determining factor for the nucleation and growth of polar PVDF phases.

  2. Characterizing HfXZr1-XO2 by EXAFS: Relationship Between Bulk and Surface Composition, and Impact on Catalytic Selectivity for Alcohol Conversion

    SciTech Connect (OSTI)

    Jacobs, G.; Milling, M; Ji, Y; Patterson, P; Sparks, D; Davis, B

    2009-01-01

    A series of mixed Hf{sub X}Zr{sub 1-X}O{sub 2} oxide catalysts was prepared according to a recipe that yields the monoclinic structure. The samples were examined by EXAFS spectroscopy at the Zr K and Hf L{sub III} edges. A fitting model was used that simultaneously fits data from both edges, and makes use of an interdependent mixing parameter X mix to take into account substitution of the complementary atom in the nearest metal-metal shell. For XPS analysis, Scofield factors were applied to estimate the relative atomic surface concentrations of Zr and Hf. EXAFS results suggested that a solid bulk solution was formed over a wide range of X for Hf{sub X}Zr{sub 1-X}O{sub 2} binary oxides, and that the relative ratio was retained in the surface shell (i.e., including some subsurface layers by XPS) and the surface (e.g., by ISS). The increase in selectivity for the 1-alkene from dehydration of alcohols at high Zr content does not correlate smoothly with the tuned relative atomic concentration of Hf to Zr. The step change at high Zr content appears to be due to other indirect factors (e.g., surface defects, oxygen vacancies).

  3. Photo-induced tunneling currents in MOS structures with various HfO{sub 2}/SiO{sub 2} stacking dielectrics

    SciTech Connect (OSTI)

    Pang, Chin-Sheng; Hwu, Jenn-Gwo

    2014-04-15

    In this study, the current conduction mechanisms of structures with tandem high-k dielectric in illumination are discussed. Samples of Al/SiO{sub 2}/Si (S), Al/HfO{sub 2}/SiO{sub 2}/Si (H), and Al/3HfO{sub 2}/SiO{sub 2}/Si (3H) were examined. The significant observation of electron traps of sample H compares to sample S is found under the double bias capacitance-voltage (C-V) measurements in illumination. Moreover, the photo absorption sensitivity of sample H is higher than S due to the formation of HfO{sub 2} dielectric layer, which leads to larger numbers of carriers crowded through the sweep of V{sub G} before the domination of tunneling current. Additionally, the HfO{sub 2} dielectric layer would block the electrons passing through oxide from valance band, which would result in less electron-hole (e{sup ?}-h{sup +}) pairs recombination effect. Also, it was found that both of the samples S and H show perimeter dependency of positive bias currents due to strong fringing field effect in dark and illumination; while sample 3H shows area dependency of positive bias currents in strong illumination. The non-uniform tunneling current through thin dielectric and through HfO{sub 2} stacking layers are importance to MOS(p) tunneling photo diodes.

  4. Features of conduction mechanisms in n-HfNiSn semiconductor heavily doped with a Rh acceptor impurity

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Stadnyk, Yu. V.; Romaka, V. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-09-15

    The crystal structure and electron-density distribution, as well as the energy, kinetic, and magnetic characteristics of n-HfNiSn intermetallic semiconductor heavily doped with a Rh acceptor impurity in the temperature range T = 80-400 K, in the acceptor-concentration range N{sub A}{sup Rh} Almost-Equal-To 9.5 Multiplication-Sign 10{sup 19}-1.9 Multiplication-Sign 10{sup 21} cm{sup -3} (x = 0.005-0.10), and in magnetic fields H {<=} 10 kG are investigated. It is established that doping is accompanied by a simultaneous decrease in concentration, the elimination of donor-type structural defects (to x Almost-Equal-To 0.02), and an increase in the concentration of acceptor-type structural defects (0 < x {<=} 0.10). The dependence of the degree of semiconductor compensation on temperature is revealed. A model of the spatial arrangement of atoms in HfNi{sub 1-x}Rh{sub x}Sn is proposed, and the results of calculating the electron structure based on this model agree with the results of investigations of the kinetic and magnetic characteristics of the semiconductor. The results are discussed within the context of the Shklovskii-Efros model for a heavily doped and compensated semiconductor.

  5. Unintentional F doping of SrTiO3(001) etched in HF acid-structure and electronic properties

    SciTech Connect (OSTI)

    Chambers, Scott A.; Droubay, Timothy C.; Capan, Cigdem; Sun, Guangyuan

    2012-02-01

    We show that the HF acid etch commonly used to prepare SrTiO3(001) for heteroepitaxial growth of complex oxides results in a non-negligible level of F doping within the terminal surface layer of TiO2. Using a combination of x-ray photoelectron spectroscopy and scanned angle x-ray photoelectron diffraction, we determine that on average ~ 13% of the O anions in the surface layer are replaced by F, but that F does not occupy O sites in deeper layers. Despite this perturbation to the surface, the Fermi level remains unpinned, and the surface-state density, which determines the amount of band bending, is driven by factors other than F doping. The presence of F at the STO surface is expected to result in lower electron mobilities at complex oxide heterojunctions involving STO substrates because of impurity scattering. Unintentional F doping can be substantially reduced by replacing the HF-etch step with a boil in deionized water, which in conjunction with an oxygen tube furnace anneal, leaves the surface flat and TiO2 terminated.

  6. Electron-stimulated desorption from polished and vacuum fired 316LN stainless steel coated with Ti-Zr-Hf-V

    SciTech Connect (OSTI)

    Malyshev, Oleg B. Valizadeh, Reza; Hogan, Benjamin T.; Hannah, Adrian N.

    2014-11-01

    In this study, two identical 316LN stainless steel tubular samples, which had previously been polished and vacuum-fired and then used for the electron-stimulated desorption (ESD) experiments, were coated with Ti-Zr-Hf-V with different morphologies: columnar and dense. ESD measurement results after nonevaporable getter (NEG) activation to 150, 180, 250, and 350?C indicated that the values for the ESD yields are significantly (220 times) lower than the data from our previous study with similar coatings on nonvacuum-fired samples. Based on these results, the lowest pressure and best long-term performance in particle accelerators will be achieved with a vacuum-fired vacuum chamber coated with dense Ti-Zr-Hf-V coating activated at 180?C. This is likely due to the following facts: after NEG activation, the hydrogen concentration inside the NEG was lower than in the bulk stainless steel substrate; the NEG coating created a barrier for gas diffusion from the sample bulk to vacuum; the dense NEG coating performed better as a barrier than the columnar NEG coating.

  7. Process for producing chalcogenide semiconductors

    DOE Patents [OSTI]

    Noufi, Rommel (Westminster, CO); Chen, Yih-Wen (Omaha, NE)

    1987-01-01

    A process for producing chalcogenide semiconductor material is disclosed. The process includes forming a base metal layer and then contacting this layer with a solution having a low pH and containing ions from at least one chalcogen to chalcogenize the layer and form the chalcogenide semiconductor material.

  8. Process for producing chalcogenide semiconductors

    DOE Patents [OSTI]

    Noufi, R.; Chen, Y.W.

    1985-04-30

    A process for producing chalcogenide semiconductor material is disclosed. The process includes forming a base metal layer and then contacting this layer with a solution having a low pH and containing ions from at least one chalcogen to chalcogenize the layer and form the chalcogenide semiconductor material.

  9. Preliminary requirements for a Fluoride Salt-Cooled High-Temperature Test Reactor (FHTR)

    SciTech Connect (OSTI)

    Massie, M.; Forsberg, C.; Forget, B.; Hu, L. W.

    2012-07-01

    A Fluoride Salt-Cooled High-Temperature Test Reactor (FHTR) design is being developed at MIT to provide the first demonstration and test of a salt-cooled reactor using high-temperature fuel. The first step is to define the requirements. The top level requirements are (1) provide the confidence that a larger demonstration reactor is warranted and (2) develop the necessary data for a larger-scale reactor. Because requirements will drive the design of the FHTR, a significant effort is being undertaken to define requirements and understand the tradeoffs that will be required for a practical design. The preliminary requirements include specifications for design parameters and necessary tests of major reactor systems. Testing requirements include demonstration of components, systems, and procedures for refueling, instrumentation, salt temperature control to avoid coolant freezing, salt chemistry and volume control, tritium monitoring and control, and in-service inspection. Safety tests include thermal hydraulics, neutronics - including intrinsic core shutdown mechanisms such as Doppler feedback - and decay heat removal systems. Materials and coolant testing includes fuels (including mechanical wear and fatigue) and system corrosion behavior. Preliminary analysis indicates a thermal power output below 30 MW, an initial core using pebble-bed or prismatic-block fuel, peak outlet temperatures of at least 700 deg. C, and use of FLi{sup 7}Be ({sup 7}LiF-BeF{sub 2}) coolant. The option to change-out the reactor core, fuel type, and major components is being investigated. While the FHTR will be used for materials testing, its primary mission is as a reactor system performance test to enable the design and licensing of a FHR demonstration power reactor. (authors)

  10. Midwest Biodiesel Producers LLC | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel Producers LLC Jump to: navigation, search Name: Midwest Biodiesel Producers LLC Place: Alexandria, South Dakota Zip: 57311 Product: South Dakota-based biodiesel producer....

  11. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

    1995-03-28

    A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

  12. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, Thomas F. (Chino Hills, CA); Robin, Allen M. (Anaheim, CA); Wolfenbarger, James K. (Torrance, CA); Suggitt, Robert M. (Wappingers Falls, NY)

    1995-01-01

    A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

  13. Method for fluorination of actinide fluorides and oxyfluorides thereof using O.sub.2 F.sub.2

    DOE Patents [OSTI]

    Eller, Phillip G. (Los Alamos, NM); Malm, John G. (Naperville, IL); Penneman, Robert A. (Albuquerque, NM)

    1988-01-01

    Method for fluorination of actinides and fluorides and oxyfluorides thereof using O.sub.2 F.sub.2 which generates actinide hexafluorides, and for removal of actinides and compounds thereof from surfaces upon which they appear as unwanted deposits. The fluorinating agent, O.sub.2 F.sub.2, has been observed to readily perform the above-described tasks at sufficiently low temperatures that there is virtually no damage to the containment vessels. Moreover, the resulting actinide hexafluorides are thereby not destroyed by high temperature reactions with the walls of the reaction vessel. Dioxygen difluoride is easily prepared, stored and transferred to the desired place of reaction.

  14. Method for fluorination of actinide fluorides and oxyfluorides thereof using O[sub 2]F[sub 2

    DOE Patents [OSTI]

    Eller, P.G.; Malm, J.G.; Penneman, R.A.

    1988-11-08

    Method is described for fluorination of actinides and fluorides and oxyfluorides thereof using O[sub 2]F[sub 2] which generates actinide hexafluorides, and for removal of actinides and compounds thereof from surfaces upon which they appear as unwanted deposits. The fluorinating agent, O[sub 2]F[sub 2], has been observed to readily perform the above-described tasks at sufficiently low temperatures that there is virtually no damage to the containment vessels. Moreover, the resulting actinide hexafluorides are thereby not destroyed by high temperature reactions with the walls of the reaction vessel. Dioxygen difluoride is easily prepared, stored and transferred to the desired place of reaction.

  15. No-carrier-added (NCA) aryl (18E) fluorides via the nucleophilic aromatic substitution of electron rich aromatic rings

    DOE Patents [OSTI]

    Ding, Yu-Shin (Central Islip, NY); Fowler, Joanna S. (Bellport, NY); Wolf, Alfred P. (Setauket, NY)

    1993-01-01

    A method for synthesizing no-carrier-added (NCA) aryl [.sup.18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described. The method of the present invention includes the step of reacting aromatic nitro aldehydes having a suitably protected hydroxyl substitutent on an electron rich ring. The reaction is The U.S. Government has rights in this invention pursuant to Contract Number DE-AC02-76CH00016, between the U.S. Department of Energy and Associated Universities Inc.

  16. No-carrier-added (NCA) aryl ([sup 18]F) fluorides via the nucleophilic aromatic substitution of electron rich aromatic rings

    DOE Patents [OSTI]

    Yushin Ding; Fowler, J.S.; Wolf, A.P.

    1993-10-19

    A method for synthesizing no-carrier-added (NCA) aryl [.sup.18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described. The method of the present invention includes the step of reacting aromatic nitro aldehydes having a suitably protected hydroxyl substitutent on an electron rich ring. The reaction is The U.S. Government has rights in this invention pursuant to Contract Number DE-AC02-76CH00016, between the U.S. Department of Energy and Associated Universities Inc.

  17. Process for producing advanced ceramics

    DOE Patents [OSTI]

    Kwong, Kyei-Sing (Tuscaloosa, AL)

    1996-01-01

    A process for the synthesis of homogeneous advanced ceramics such as SiC+AlN, SiAlON, SiC+Al.sub.2 O.sub.3, and Si.sub.3 N.sub.4 +AlN from natural clays such as kaolin, halloysite and montmorillonite by an intercalation and heat treatment method. Included are the steps of refining clays, intercalating organic compounds into the layered structure of clays, drying the intercalated mixture, firing the treated atmospheres and grinding the loosely agglomerated structure. Advanced ceramics produced by this procedure have the advantages of homogeneity, cost effectiveness, simplicity of manufacture, ease of grind and a short process time. Advanced ceramics produced by this process can be used for refractory, wear part and structure ceramics.

  18. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Chen, Chun-Ku

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  19. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site

    Broader source: Energy.gov [DOE]

    This site-specific EIS analyzes the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Paducah site; transportation of all cylinders (DUF6, enriched, and empty) currently stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Portsmouth; construction of a new cylinder storage yard at Portsmouth (if required) for ETTP cylinders; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion coproduct; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold.

  20. Method of producing cyclohexasilane compounds

    DOE Patents [OSTI]

    Elangovan, Arumugasamy; Anderson, Kenneth; Boudjouk, Philip R; Schulz, Douglas L

    2015-03-10

    A method of preparing a cyclohexasilane compound from trichlorosilane is provided. The method includes contacting trichlorosilane with a reagent composition to produce a compound containing a tetradecahalocyclohexasilane dianion, such as a tetradecachlorocyclohexasilane dianion. The reagent composition typically includes (a) tertiary polyamine ligand; and (b) a deprotonating reagent, such as a tertiary amine having a pKa of at least about 10.5. Methods of converting the tetradecahalocyclohexasilane dianion-containing compound to cyclohexasilane or a dodecaorganocyclohexasilane are also provided.

  1. Method for producing hydrophobic aerogels

    DOE Patents [OSTI]

    Hrubesh, Lawrence W. (Pleasanton, CA); Poco, John F. (Livermore, CA); Coronado, Paul R. (Livermore, CA)

    1999-01-01

    A method for treating a dried monolithic aerogel containing non-dispersed particles, with an organometallic surface modifying agent to produce hydrophobic aerogels. The dried, porous hydrophobic aerogels contain a protective layer of alkyl groups, such as methyl groups, on the modified surfaces of the pores of the aerogel. The alkyl groups at the aerogel surface typically contain at least one carbon-metal bond per group.

  2. hydrogen is produced by electrolysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrogen is produced by electrolysis - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  3. Method for producing hydrophobic aerogels

    SciTech Connect (OSTI)

    Hrubesh, L.W.; Poco, J.F.; Coronado, P.R.

    1999-12-21

    A method is described for treating a dried monolithic aerogel containing non-dispersed particles, with an organometallic surface modifying agent to produce hydrophobic aerogels. The dried, porous hydrophobic aerogels contain a protective layer of alkyl groups, such as methyl groups, on the modified surfaces of the pores of the aerogel. The alkyl groups at the aerogel surface typically contain at least one carbon-metal bond per group.

  4. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  5. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  6. Fish Producers Aquaculture Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Aquaculture Low Temperature Geothermal Facility Jump to: navigation, search Name Fish Producers Aquaculture Low Temperature Geothermal Facility Facility Fish Producers...

  7. In situ study of HfO{sub 2} atomic layer deposition on InP(100)

    SciTech Connect (OSTI)

    Dong, H.; Brennan, B.; Kim, J.; Hinkle, C. L.; Wallace, R. M.; Zhernokletov, D.

    2013-04-29

    The interfacial chemistry of the native oxide and chemically treated InP samples during atomic layer deposition (ALD) HfO{sub 2} growth at 250 Degree-Sign C has been studied by in situ X-ray photoelectron spectroscopy. The In-oxide concentration is seen to gradually decrease on the native oxide and acid etched samples. No significant changes of the P-oxide concentrations are detected, while the P-oxides chemical states are seen to change gradually during the initial cycles of ALD on the native oxide and the chemically treated samples. (NH{sub 4}){sub 2}S treatment strongly decreases In-oxide and P-oxide concentrations prior to ALD and maintains low concentrations during the ALD process.

  8. Structure Analysis of a Precipitate Phase in an Ni-Rich High Temperature NiTiHf Shape Memory Alloy

    SciTech Connect (OSTI)

    Yang, Fan; Coughlin, D. R.; Phillips, Patrick J.; Yang, L.; Devaraj, Arun; Kovarik, Libor; Noebe, Ronald D.; Mills, M. J.

    2013-03-22

    Thermal aging of the high temperature shape memory alloy 50.3Ni-29.7Ti-20Hf (at.%) introduces a novel precipitate phase, which plays an important role in improving shape memory properties. The precipitate phase was investigated by conventional electron diffraction, high resolution scanning transmission electron microscopy (STEM) and three dimensional atom probe tomography. An unrelaxed orthorhombic atomic structural model is proposed based on these observations. This model was subsequently relaxed by ab initio calculations. As a result of the relaxation, atom shuffle displacements occur, which in turn yields improved agreement with the STEM images. The relaxed structure, which is termed the H-phase, has also been verified to be thermodymanically stable at 0 K.

  9. Set statistics in conductive bridge random access memory device with Cu/HfO{sub 2}/Pt structure

    SciTech Connect (OSTI)

    Zhang, Meiyun; Long, Shibing Wang, Guoming; Xu, Xiaoxin; Li, Yang; Liu, Qi; Lv, Hangbing; Liu, Ming; Lian, Xiaojuan; Miranda, Enrique; Su, Jordi

    2014-11-10

    The switching parameter variation of resistive switching memory is one of the most important challenges in its application. In this letter, we have studied the set statistics of conductive bridge random access memory with a Cu/HfO{sub 2}/Pt structure. The experimental distributions of the set parameters in several off resistance ranges are shown to nicely fit a Weibull model. The Weibull slopes of the set voltage and current increase and decrease logarithmically with off resistance, respectively. This experimental behavior is perfectly captured by a Monte Carlo simulator based on the cell-based set voltage statistics model and the Quantum Point Contact electron transport model. Our work provides indications for the improvement of the switching uniformity.

  10. Hole Trapping at Surfaces of m?ZrO2 and m?HfO2 Nanocrystals

    SciTech Connect (OSTI)

    Wolf, Matthew J.; Mckenna, Keith P.; Shlyuger, Alexander L.

    2012-12-03

    We investigate hole trapping at the most prevalent facets of monoclinic zirconia (m-ZrO2) and hafnia (m-HfO2) nanocrystals using first-principles methods. The localization of holes at surface oxygen ions is more favorable than in the bulk crystal by up to ?1 eV. This is caused mainly by the reduction of the absolute value of the electrostatic potential at the surface ions with respect to the bulk and by the significant surface distortion caused by the hole localization. The mobility of holes at surfaces is much lower than that found in the bulk and is fairly isotropic. Unlike in cubic oxides, such as MgO and CaO, we do not find a significant driving force for preferential trapping of holes at steps on the m-ZrO2 surface. These fundamental results are relevant to mechanisms of water oxidation, photocatalysis, contact charging, and photodesorption.

  11. Manipulation of electronic and magnetic properties of M{sub 2}C (M = Hf, Nb, Sc, Ta, Ti, V, Zr) monolayer by applying mechanical strains

    SciTech Connect (OSTI)

    Zhao, Shijun; Kang, Wei; Xue, Jianming

    2014-03-31

    Tuning the electronic and magnetic properties of a material through strain engineering is an effective strategy to enhance the performance of electronic and spintronic devices. In this paper, first-principles calculations based on density functional theory are carried out to investigate the electronic and magnetic properties of M{sub 2}C(M = Hf, Nb, Sc, Ta, Ti, V, Zr, known as MXenes) subjected to biaxial symmetric mechanical strains. At the strain-free state, all these MXenes exhibit no spontaneous magnetism except for Ti{sub 2}C and Zr{sub 2}C which show a magnetic moment of 1.92 and 1.25 μ{sub B}/unit, respectively. As the tensile strain increases, the magnetic moments of MXenes are greatly enhanced and a transition from nonmagnetism to ferromagnetism is observed for those nonmagnetic MXenes at zero strains. The most distinct transition is found in Hf{sub 2}C, in which the magnetic moment is elevated to 1.5 μ{sub B}/unit at a strain of 1.80%. We further show that the magnetic properties of Hf{sub 2}C are attributed to the band shift mainly composed of Hf(5d) states.

  12. Fatty acid-producing hosts

    DOE Patents [OSTI]

    Pfleger, Brian F; Lennen, Rebecca M

    2013-12-31

    Described are hosts for overproducing a fatty acid product such as a fatty acid. The hosts include an exogenous nucleic acid encoding a thioesterase and, optionally, an exogenous nucleic acid encoding an acetyl-CoA carboxylase, wherein an acyl-CoA synthetase in the hosts are functionally delected. The hosts prefereably include the nucleic acid encoding the thioesterase at an intermediate copy number. The hosts are preferably recominantly stable and growth-competent at 37.degree. C. Methods of producing a fatty acid product comprising culturing such hosts at 37.degree. C. are also described.

  13. Method for producing a tube

    DOE Patents [OSTI]

    Peterson, Kenneth A. (Albuquerque, NM); Rohde, Steven B. (Corrales, NM); Pfeifer, Kent B. (Los Lunas, NM); Turner, Timothy S. (Rio Rancho, NM)

    2007-01-02

    A method is described for producing tubular substrates having parallel spaced concentric rings of electrical conductors that can be used as the drift tube of an Ion Mobility Spectrometer (IMS). The invention comprises providing electrodes on the inside of a tube that are electrically connected to the outside of the tube through conductors that extend between adjacent plies of substrate that are combined to form the tube. Tubular substrates are formed from flexible polymeric printed wiring board materials, ceramic materials and material compositions of glass and ceramic, commonly known as Low Temperature Co-Fired Ceramic (LTCC). The adjacent plies are sealed together around the electrode.

  14. Producing biofuels using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-04-16

    The present invention provides for a non-naturally occurring polyketide synthase (PKS) capable of synthesizing a carboxylic acid or a lactone, and a composition such that a carboxylic acid or lactone is included. The carboxylic acid or lactone, or derivative thereof, is useful as a biofuel. The present invention also provides for a recombinant nucleic acid or vector that encodes such a PKS, and host cells which also have such a recombinant nucleic acid or vector. The present invention also provides for a method of producing such carboxylic acids or lactones using such a PKS.

  15. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  16. Development of strong-sense validation benchmarks for the fluoride salt-cooled high-temperature reactor

    SciTech Connect (OSTI)

    Blandford, E. D.

    2012-07-01

    The Fluoride salt-cooled High-temperature Reactor (FHR) is a class of reactor concepts currently under development for the U. S. Dept. of Energy. The FHR is defined as a Generation IV reactor that features low-pressure liquid fluoride salt cooling, coated-particle fuel, a high-temperature power cycle, and fully passive decay heat rejection. Recent experimental work using simulant fluids have been performed to demonstrate key 'proof of principle' FHR concepts and have helped inform the reactor design process. An important element of developing FHR technology is to sufficiently validate the predictive accuracy of the computer codes used to model system response. This paper presents a set of thermal-hydraulics experiments, defined as Strong-Sense Benchmarks (SSB's), which will help establish the FHR validation domain for simulant fluid suitability. These SSB's are more specifically designed to investigate single-phase natural circulation which is the dominant mode of FHR decay heat removal during off-normal conditions. SSB s should be viewed as engineering reference standards and differ from traditional confirmatory experiments in the sense that they are more focused on fundamental physics as opposed to reproducing high levels of physical similarity with the prototypical design. (authors)

  17. Vortex Diode Analysis and Testing for Fluoride Salt-Cooled High-Temperature Reactors

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Elkassabgi, Yousri M.; De Leon, Gerardo I.; Fetterly, Caitlin N.; Ramos, Jorge A.; Cunningham, Richard Burns

    2012-02-01

    Fluidic diodes are presently being considered for use in several fluoride salt-cooled high-temperature reactor designs. A fluidic diode is a passive device that acts as a leaky check valve. These devices are installed in emergency heat removal systems that are designed to passively remove reactor decay heat using natural circulation. The direct reactor auxiliary cooling system (DRACS) uses DRACS salt-to-salt heat exchangers (DHXs) that operate in a path parallel to the core flow. Because of this geometry, under normal operating conditions some flow bypasses the core and flows through the DHX. A flow diode, operating in reverse direction, is-used to minimize this flow when the primary coolant pumps are in operation, while allowing forward flow through the DHX under natural circulation conditions. The DRACSs reject the core decay heat to the environment under loss-of-flow accident conditions and as such are a reactor safety feature. Fluidic diodes have not previously been used in an operating reactor system, and therefore their characteristics must be quantified to ensure successful operation. This report parametrically examines multiple design parameters of a vortex-type fluidic diode to determine the size of diode needed to reject a particular amount of decay heat. Additional calculations were performed to size a scaled diode that could be tested in the Oak Ridge National Laboratory Liquid Salt Flow Loop. These parametric studies have shown that a 152.4 mm diode could be used as a test article in that facility. A design for this diode is developed, and changes to the loop that will be necessary to test the diode are discussed. Initial testing of a scaled flow diode has been carried out in a water loop. The 150 mm diode design discussed above was modified to improve performance, and the final design tested was a 171.45 mm diameter vortex diode. The results of this testing indicate that diodicities of about 20 can be obtained for diodes of this size. Experimental results show similar trends as the computational fluid dynamics (CFD) results presented in this report; however, some differences exist that will need to be assessed in future studies. The results of this testing will be used to improve the diode design to be tested in the liquid salt loop system.

  18. Method of producing metallic materials

    DOE Patents [OSTI]

    Branagan, Daniel J.

    2004-02-10

    The invention includes a method of producing a hard metallic material by forming a mixture containing at least 55% iron and at least one of B, C, Si and P. The mixture is formed into an alloy and cooled to form a metallic material having a hardness greater than about 9.2 GPa. The invention includes a method of forming a wire by combining a metal strip and a powder. The strip and the powder are rolled to form a wire containing at least 55% iron and from 2-7 additional elements including at least one of C, Si and B. The invention also includes a method of forming a hardened surface on a substrate by processing a solid mass to form a powder, applying the powder to a surface to form a layer containing metallic glass, and converting the glass to a crystalline material having a nanocrystalline grain size.

  19. Methods for producing secreted polypeptides

    DOE Patents [OSTI]

    Maiyuran, Suchindra; Fidantsef, Ana; Brody, Howard

    2008-07-01

    The present invention relates to methods for producing a polypeptide, comprising: (a) cultivating a fungal host cell in a medium conducive for the production of the polypeptide, wherein the fungal host cell comprises a nucleic acid construct comprising a first nucleotide sequence encoding a signal peptide operably linked to a second nucleotide sequence encoding the polypeptide, wherein the first nucleotide sequence is foreign to the second nucleotide sequence and the 3' end of the first nucleotide sequence is immediately upstream of the initiator codon of the second nucleotide sequence. The present invention also relates to the isolated signal peptide sequences and to constructs, vectors, and fungal host cells comprising the signal peptide sequences operably linked to nucleotide sequences encoding polypeptides.

  20. Number of Producing Gas Wells

    U.S. Energy Information Administration (EIA) Indexed Site

    Producing Gas Wells Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Area 2009 2010 2011 2012 2013 2014 View History U.S. 493,100 487,627 514,637 482,822 484,994 514,786 1989-2014 Alabama 6,913 7,026 7,063 6,327 6,165 6,118 1989-2014 Alaska 261 269 277 185 159 170 1989-2014 Arizona 6 5 5 5 5 5 1989-2014 Arkansas 6,314 7,397 8,388 8,538 9,843 10,150 1989-2014 California 1,643 1,580 1,308 1,423 1,335 1,118 1989-2014

  1. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (GdLu)

    SciTech Connect (OSTI)

    Mioduski, Tomasz; Gumi?ski, Cezary; Zeng, Dewen

    2015-06-15

    This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  2. Does fluoride disrupt hydrogen bond network in cationic lipid bilayer? Time-dependent fluorescence shift of Laurdan and molecular dynamics simulations

    SciTech Connect (OSTI)

    Pokorna, Sarka; Jurkiewicz, Piotr; Hof, Martin; Vazdar, Mario; Cwiklik, Lukasz; Jungwirth, Pavel

    2014-12-14

    Time-dependent fluorescence shift (TDFS) of Laurdan embedded in phospholipid bilayers reports on hydration and mobility of the phospholipid acylgroups. Exchange of H{sub 2}O with D{sub 2}O prolongs the lifetime of lipid-water and lipid-water-lipid interactions, which is reflected in a significantly slower TDFS kinetics. Combining TDFS measurements in H{sub 2}O and D{sub 2}O hydrated bilayers with atomistic molecular dynamics (MD) simulations provides a unique tool for characterization of the hydrogen bonding at the acylgroup level of lipid bilayers. In this work, we use this approach to study the influence of fluoride anions on the properties of cationic bilayers composed of trimethylammonium-propane (DOTAP). The results obtained for DOTAP are confronted with those for neutral phosphatidylcholine (DOPC) bilayers. Both in DOTAP and DOPC H{sub 2}O/D{sub 2}O exchange prolongs hydrogen-bonding lifetime and does not disturb bilayer structure. These results are confirmed by MD simulations. TDFS experiments show, however, that for DOTAP this effect is cancelled in the presence of fluoride ions. We interpret these results as evidence that strongly hydrated fluoride is able to steal water molecules that bridge lipid carbonyls. Consequently, when attracted to DOTAP bilayer, fluoride disrupts the local hydrogen-bonding network, and the differences in TDFS kinetics between H{sub 2}O and D{sub 2}O hydrated bilayers are no longer observed. A distinct behavior of fluoride is also evidenced by MD simulations, which show different lipid-ion binding for Cl{sup ?} and F{sup ?}.

  3. Engineering microbes to produce biofuels

    SciTech Connect (OSTI)

    Wackett, LP

    2011-06-01

    The current biofuels landscape is chaotic. It is controlled by the rules imposed by economic forces and driven by the necessity of finding new sources of energy, particularly motor fuels. The need is bringing forth great creativity in uncovering new candidate fuel molecules that can be made via metabolic engineering. These next generation fuels include long-chain alcohols, terpenoid hydrocarbons, and diesel-length alkanes. Renewable fuels contain carbon derived from carbon dioxide. The carbon dioxide is derived directly by a photosynthetic fuel-producing organism(s) or via intermediary biomass polymers that were previously derived from carbon dioxide. To use the latter economically, biomass depolymerization processes must improve and this is a very active area of research. There are competitive approaches with some groups using enzyme based methods and others using chemical catalysts. With the former, feedstock and end-product toxicity loom as major problems. Advances chiefly rest on the ability to manipulate biological systems. Computational and modular construction approaches are key. For example, novel metabolic networks have been constructed to make long-chain alcohols and hydrocarbons that have superior fuel properties over ethanol. A particularly exciting approach is to implement a direct utilization of solar energy to make a usable fuel. A number of approaches use the components of current biological systems, but re-engineer them for more direct, efficient production of fuels.

  4. DRY FLUORINE SEPARATION METHOD

    DOE Patents [OSTI]

    Seaborg, G.T.; Gofman, J.W.; Stoughton, R.W.

    1959-05-19

    Preparation and separation of U/sup 233/ by irradiation of ThF/sub 4/ is described. During the neutron irradiation to produce Pa/sup 233/ a fluorinating agent such as HF, F/sub 2/, or HF + F/sub 2/ is passed through the ThF/sub 4/ powder to produce PaF/sub 5/. The PaF/sub 5/, being more volatile, is removed as a gas and allowed to decay radioactively to U/sup 233/ fluoride. A batch procedure in which ThO/sub 2/ or Th metal is irradiated and fluorinated is suggested. Some Pa and U fluoride volatilizes away. Then the remainder is fluorinated with F/sub 2/ to produce very volatile UF/sub 6/ which is recovered. (T.R.H.)

  5. Optical properties of chromium and neodymium in zirconium-barium-lanthanum-aluminum fluoride glass. Final report, October 1987-September 1988

    SciTech Connect (OSTI)

    Hanson, F.E.; Caspers, H.H.

    1993-08-01

    The optical properties are reported of chromium and neodymium doped in zirconium-barium-lanthanum-aluminum fluoride glass (ZBLA). The fluorescence of Cr(3+) and of co-doped Cr(3+), Nd(3+) glasses is investigated. Fluorescence decay rates of Cr(3+) and Nd(3+) are measured at various temperatures, and the excitation transfer efficiency between Cr(3+) and Nd(3+) is determined. The absorption spectrum of Nd(3+):ZBLA is characterized in terms of the Judd-Ofelt model of crystal field-induced electric-dipole transitions. The three phenomenological intensity parameters for Nd(3+) in ZBLA glass Omega sub 2,4,6, are compared to those obtained for Nd(3+) in Y3Al5Ol2, Gd3S2Al3Ol2, and LHG-8 glass.

  6. Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride

    SciTech Connect (OSTI)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01

    The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

  7. Effect of Si substrate on interfacial SiO{sub 2} scavenging in HfO{sub 2}/SiO{sub 2}/Si stacks

    SciTech Connect (OSTI)

    Li, Xiuyan, E-mail: xiuyan@adam.t.u-tokyo.ac.jp; Yajima, Takeaki; Nishimura, Tomonori; Nagashio, Kosuke; Toriumi, Akira [Department of Materials Engineering, The University of Tokyo, 7-3-1 Hongo, Tokyo 113-8656 (Japan)

    2014-11-03

    The scavenging kinetics of an ultra-thin SiO{sub 2} interface layer (SiO{sub 2}-IL) in an HfO{sub 2}/SiO{sub 2}/Si stack is discussed by focusing on the substrate effect in addition to oxygen diffusion. {sup 18}O tracing experiments demonstrate that the O-atom moves from the SiO{sub 2}-IL to the HfO{sub 2} layer during scavenging. SiO{sub 2}-IL scavenging with various substrates (Si, SiC, and sapphire) has been found to be significantly different, which suggests that the Si in the substrate is also necessary to continuously cause the scavenging. Based on these findings and thermodynamic considerations, a kinetic model where oxygen vacancy (V{sub O}) transferred from the HfO{sub 2} reacts with the SiO{sub 2}, which is in contact with the Si-substrate, is proposed for the SiO{sub 2}-IL scavenging.

  8. Small cell experiments for electrolytic reduction of uranium oxides to uranium metal using fluoride salts

    SciTech Connect (OSTI)

    Haas, P.A.; Adcock, P.W.; Coroneos, A.C.; Hendrix, D.E. )

    1994-08-01

    Electrolytic reduction of uranium oxide was proposed for the preparation of uranium metal feed for the atomic vapor laser isotope separation (AVLIS) process. A laboratory cell of 25-cm ID was operated to obtain additional information in areas important to design and operation of a pilot plant cell. Reproducible test results and useful operating and control procedures were demonstrated. About 20 kg of uranium metal of acceptable purity were prepared. A good supply of dissolved UO[sub 2] feed at the anode is the most important controlling requirement for efficient cell operation. A large fraction of the cell current is nonproductive in that it does not produce a metal product nor consume carbon anodes. All useful test conditions gave some reduction of UF[sub 4] to produce CF[sub 4] in addition to the reduction of UO[sub 2], but the fraction of metal from the reduction of UF[sub 4] can be decreased by increasing the concentration of dissolved UO[sub 2]. Operation of large continuous cells would probably be limited to current efficiencies of less than 60 pct, and more than 20 pct of the metal would result from the reduction of UF[sub 4].

  9. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  10. California: Agricultural Residues Produce Renewable Fuel | Department...

    Broader source: Energy.gov (indexed) [DOE]

    technology is expected to produce biofuel that reduces greenhouse gas emissions by 80% compared to fossil fuel and help make California a leader in advanced biofuel production. ...

  11. Fracture characteristics and their relationships to producing...

    Open Energy Info (EERE)

    characteristics and their relationships to producing zones in deep wells, Raft River geothermal area Jump to: navigation, search OpenEI Reference LibraryAdd to library Book:...

  12. Looking for footprint of bulk metallic glass in electronic and phonon heat capacities of Cu{sub 55}Hf{sub 45?x}Ti{sub x} alloys

    SciTech Connect (OSTI)

    Remenyi, G.; Biljakovi?, K.; Stareini?, D.; Dominko, D.; Risti?, R.; Babi?, E.; Figueroa, I. A.; Davies, H. A.

    2014-04-28

    We report on the heat capacity investigation of Cu{sub 55}Hf{sub 45?x}Ti{sub x} metallic glasses. The most appropriate procedure to estimate low temperature electronic and phonon contributions has been determined. Both contributions exhibit monotonous Ti concentration dependence, demonstrating that there is no relation of either the electron density of states at the Fermi level or the Debye temperature to the increased glass forming ability in the Ti concentration range x?=?1530. The thermodynamic parameters (e.g., reduced glass temperature) remain better indicators in assessing the best composition for bulk metallic glass formation.

  13. Stable, fertile, high polyhydroxyalkanoate producing plants and methods of producing them

    DOE Patents [OSTI]

    Bohmert-Tatarev, Karen; McAvoy, Susan; Peoples, Oliver P.; Snell, Kristi D.

    2015-08-04

    Transgenic plants that produce high levels of polyhydroxybutyrate and methods of producing them are provided. In a preferred embodiment the transgenic plants are produced using plastid transformation technologies and utilize genes which are codon optimized. Stably transformed plants able to produce greater than 10% dwt PHS in tissues are also provided.

  14. In situ study of the role of substrate temperature during atomic layer deposition of HfO{sub 2} on InP

    SciTech Connect (OSTI)

    Dong, H.; Santosh, K.C.; Qin, X.; Brennan, B.; McDonnell, S.; Kim, J.; Zhernokletov, D.; Hinkle, C. L.; Cho, K.; Wallace, R. M.; Department of Physics, University of Texas at Dallas, Richardson, Texas 75080

    2013-10-21

    The dependence of the “self cleaning” effect of the substrate oxides on substrate temperature during atomic layer deposition (ALD) of HfO{sub 2} on various chemically treated and native oxide InP (100) substrates is investigated using in situ X-ray photoelectron spectroscopy. The removal of In-oxide is found to be more efficient at higher ALD temperatures. The P oxidation states on native oxide and acid etched samples are seen to change, with the total P-oxide concentration remaining constant, after 10 cycles of ALD HfO{sub 2} at different temperatures. An (NH{sub 4}){sub 2} S treatment is seen to effectively remove native oxides and passivate the InP surfaces independent of substrate temperature studied (200 °C, 250 °C and 300 °C) before and after the ALD process. Density functional theory modeling provides insight into the mechanism of the changes in the P-oxide chemical states.

  15. High quality HfO{sub 2}/p-GaSb(001) metal-oxide-semiconductor capacitors with 0.8?nm equivalent oxide thickness

    SciTech Connect (OSTI)

    Barth, Michael; Datta, Suman; Bruce Rayner, G.; McDonnell, Stephen; Wallace, Robert M.; Bennett, Brian R.; Engel-Herbert, Roman

    2014-12-01

    We investigate in-situ cleaning of GaSb surfaces and its effect on the electrical performance of p-type GaSb metal-oxide-semiconductor capacitor (MOSCAP) using a remote hydrogen plasma. Ultrathin HfO{sub 2} films grown by atomic layer deposition were used as a high permittivity gate dielectric. Compared to conventional ex-situ chemical cleaning methods, the in-situ GaSb surface treatment resulted in a drastic improvement in the impedance characteristics of the MOSCAPs, directly evidencing a much lower interface trap density and enhanced Fermi level movement efficiency. We demonstrate that by using a combination of ex-situ and in-situ surface cleaning steps, aggressively scaled HfO{sub 2}/p-GaSb MOSCAP structures with a low equivalent oxide thickness of 0.8?nm and efficient gate modulation of the surface potential are achieved, allowing to push the Fermi level far away from the valence band edge high up into the band gap of GaSb.

  16. X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy investigation of Al-related dipole at the HfO{sub 2}/Si interface

    SciTech Connect (OSTI)

    Zhu, L. Q.; Barrett, N.; Jegou, P.

    2009-01-15

    The presence of an ultrathin oxide layer at the high-k/SiO{sub 2} interface may result in an interfacial dipole related to the specific high-k dielectric used for the gate stacks. 1 nm HfO{sub 2}/x nmAl{sub 2}O{sub 3}/SiO{sub 2}/Si stacks with different x values (x=0, 0.4, 0.8, 1.2) have been prepared by atomic layer deposition. Using photoelectron spectroscopy, an Al-related interfacial dipole in the HfO{sub 2}/Al{sub 2}O{sub 3}/SiO{sub 2} gate stack has been identified. X-ray photoelectron spectroscopy analysis shows that the dipole is correlated with the formation of an interfacial Al-silicate. The dipole is located at the Al-silicate interface between Al{sub 2}O{sub 3} and SiO{sub 2}, and its strength increases with the increase in Al{sub 2}O{sub 3} thickness because of Al silicate growth. Such Al-related interfacial dipole should have potential applications in future positive metal-oxide-semiconductor devices.

  17. Producing X-rays at the APS

    ScienceCinema (OSTI)

    None

    2013-04-19

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest X-ray beams in the Western Hemisphere, and the research carried out by scientists using those X-rays.

  18. Ex Parte Communications- Uranium Producers of America

    Broader source: Energy.gov [DOE]

    On Thursday, February 12, 2015, representatives from the Uranium  Producers  of America (UPA) met with the Department of Energy (DOE) officials to discuss the management of the federal excess...

  19. Methods and systems for producing syngas

    DOE Patents [OSTI]

    Hawkes, Grant L; O'Brien, James E; Stoots, Carl M; Herring, J. Stephen; McKellar, Michael G; Wood, Richard A; Carrington, Robert A; Boardman, Richard D

    2013-02-05

    Methods and systems are provided for producing syngas utilizing heat from thermochemical conversion of a carbonaceous fuel to support decomposition of at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells. Simultaneous decomposition of carbon dioxide and water or steam by one or more solid-oxide electrolysis cells may be employed to produce hydrogen and carbon monoxide. A portion of oxygen produced from at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells is fed at a controlled flow rate in a gasifier or combustor to oxidize the carbonaceous fuel to control the carbon dioxide to carbon monoxide ratio produced.

  20. Methods of producing compounds from plant material

    DOE Patents [OSTI]

    Werpy, Todd A.; Schmidt, Andrew J.; Frye, Jr., John G.; Zacher, Alan H.; Franz, James A.; Alnajjar, Mikhail S.; Neuenschwander, Gary G.; Alderson, Eric V.; Orth, Rick J.; Abbas, Charles A.; Beery, Kyle E.; Rammelsberg, Anne M.; Kim, Catherine J.

    2006-01-03

    The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.

  1. Methods of producing compounds from plant materials

    DOE Patents [OSTI]

    Werpy, Todd A. (West Richland, WA); Schmidt, Andrew J. (Richland, WA); Frye, Jr., John G. (Richland, WA); Zacher, Alan H. (Kennewick, WA), Franz; James A. (Kennewick, WA), Alnajjar; Mikhail S. (Richland, WA), Neuenschwander; Gary G. (Burbank, WA), Alderson; Eric V. (Kennewick, WA), Orth; Rick J. (Kennewick, WA), Abbas; Charles A. (Champaign, IL), Beery; Kyle E. (Decatur, IL), Rammelsberg; Anne M. (Decatur, IL), Kim; Catherine J. (Decatur, IL)

    2010-01-26

    The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.

  2. Produced Water Management and Beneficial Use

    SciTech Connect (OSTI)

    Terry Brown; Carol Frost; Thomas Hayes; Leo Heath; Drew Johnson; David Lopez; Demian Saffer; Michael Urynowicz; John Wheaton; Mark Zoback

    2007-10-31

    Large quantities of water are associated with the production of coalbed methane (CBM) in the Powder River Basin (PRB) of Wyoming. The chemistry of co-produced water often makes it unsuitable for subsequent uses such as irrigated agriculture. However, co-produced waters have substantial potential for a variety of beneficial uses. Achieving this potential requires the development of appropriate water management strategies. There are several unique characteristics of co-produced water that make development of such management strategies a challenge. The production of CBM water follows an inverse pattern compared to traditional wells. CBM wells need to maintain low reservoir pressures to promote gas production. This need renders the reinjection of co-produced waters counterproductive. The unique water chemistry of co-produced water can reduce soil permeability, making surface disposal difficult. Unlike traditional petroleum operations where co-produced water is an undesirable by-product, co-produced water in the PRB often is potable, making it a highly valued resource in arid western states. This research project developed and evaluated a number of water management options potentially available to CBM operators. These options, which focus on cost-effective and environmentally-sound practices, fall into five topic areas: Minimization of Produced Water, Surface Disposal, Beneficial Use, Disposal by Injection and Water Treatment. The research project was managed by the Colorado Energy Research Institute (CERI) at the Colorado School of Mines (CSM) and involved personnel located at CERI, CSM, Stanford University, Pennsylvania State University, the University of Wyoming, the Argonne National Laboratory, the Gas Technology Institute, the Montana Bureau of Mining and Geology and PVES Inc., a private firm.

  3. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    SciTech Connect (OSTI)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the reactor. Batch tests were conducted to examine naphthenic acid biodegradability under several conditions. The conditions used were seed from the anaerobic reactor, wetland sediments under aerobic and anaerobic conditions, and a sterile control. The naphthenic acid was from a commercial source isolated from Gulf Coast petroleum as was dosed at 2 mg/mL. The incubations were for 30 days at 30 C. The results showed that the naphthenic acids were not biodegraded under anaerobic conditions, but were degraded under aerobic conditions. Despite poor performance of the anaerobic reactor, it remains likely that anaerobic treatment of acetate, toluene, and, potentially, other produced-water components is feasible.

  4. Collapse of ferromagnetism in itinerant-electron system: A magnetic, transport properties, and high pressure study of (Hf,Ta)Fe{sub 2} compounds

    SciTech Connect (OSTI)

    Diop, L. V. B. Isnard, O.; Kastil, J.; Arnold, Z.; Kamarad, J.

    2014-10-28

    The magnetism and transport properties were studied for Laves (Hf,Ta)Fe{sub 2} itinerant-electron compounds, which exhibit a temperature-induced first-order transition from the ferromagnetic (FM) to the antiferromagnetic (AFM) state upon heating. At finite temperatures, the field-induced metamagnetic phase transition between the AFM and FM has considerable effects on the transport properties of these model metamagnetic compounds. A large negative magnetoresistance of about 14% is observed in accordance with the metamagnetic transition. The magnetic phase diagram is determined for the Laves Hf{sub 1?x}Ta{sub x}Fe{sub 2} series and its Ta concentration dependence discussed. An unusual behavior is revealed in the paramagnetic state of intermediate compositions, it gives rise to the rapid increase and saturation of the local spin fluctuations of the 3d electrons. This new result is analysed in the frame of the theory of Moriya. For a chosen composition Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2}, exhibiting such remarkable features, a detailed investigation is carried out under hydrostatic pressure up to 1?GPa in order to investigate the volume effect on the magnetic properties. With increasing pressure, the magnetic transition temperature T{sub FM-AFM} from ferromagnetic to antiferromagnetic order decreases strongly non-linearly and disappears at a critical pressure of 0.75?GPa. In the pressure-induced AFM state, the field-induced first-order AFM-FM transition appears and the complex temperature dependence of the AFM-FM transition field is explained by the contribution from both the magnetic and elastic energies caused by the significant temperature variation of the amplitude of the local Fe magnetic moment. The application of an external pressure leads also to the progressive decrease of the Nel temperature T{sub N}. In addition, a large pressure effect on the spontaneous magnetization M{sub S} for pressures below 0.45?GPa, dln(M{sub s})/dP?=??6.3??10{sup ?2?}GPa{sup ?1} was discovered. The presented results are consistent with Moriya's theoretical predictions and can significantly help to better understand the underlying physics of itinerant electron magnetic systems nowadays widely investigated for both fundamental and applications purposes.

  5. Characterization of Soluble Organics in Produced Water

    SciTech Connect (OSTI)

    Bostick, D.T.

    2002-01-16

    Soluble organics in produced water and refinery effluents represent treatment problems for the petroleum industry. Neither the chemistry involved in the production of soluble organics nor the impact of these chemicals on total effluent toxicity is well understood. The U.S. Department of Energy provides funding for Oak Ridge National Laboratory (ORNL) to support a collaborative project with Shell, Chevron, Phillips, and Statoil entitled ''Petroleum and Environmental Research Forum project (PERF 9844: Manage Water-Soluble Organics in Produced Water''). The goal of this project, which involves characterization and evaluation of these water-soluble compounds, is aimed at reducing the future production of such contaminants. To determine the effect that various drilling conditions might have on water-soluble organics (WSO) content in produced water, a simulated brine water containing the principal inorganic components normally found in Gulf of Mexico (GOM) brine sources was prepared. The GOM simulant was then contacted with as-received crude oil from a deep well site to study the effects of water cut, produced-water pH, salinity, pressure, temperature, and crude oil sources on the type and content of the WSO in produced water. The identities of individual semivolatile organic compounds (SVOCs) were determined in all as-received crude and actual produced water samples using standard USEPA Method (8270C) protocol. These analyses were supplemented with the more general measurements of total petroleum hydrocarbon (TPH) content in the gas (C{sub 6}-C{sub 10}), diesel (C{sub 10}-C{sub 20}), and oil (C{sub 20}-C{sub 28}) carbon ranges as determined by both gas chromatographic (GC) and infrared (IR) analyses. An open liquid chromatographic procedure was also used to differentiate the saturated hydrocarbon, aromatic hydrocarbon, and polar components within the extractable TPH. Inorganic constituents in the produced water were analyzed by ion-selective electrodes and inductively coupled plasma (ICP)-atomic emission spectrometry (AES). The WSO found in produced water samples was primarily polar in nature and distributed between the low and midrange carbon ranges. Typical levels of total extractable material (TEM) was about 20 mg/L; that associated with the aromatic fraction was present at 0.2 mg/L and that in the saturated hydrocarbon fraction was present at less than 0.02 mg/L. Formic, acetic, and propionic acids were also found in the produced water, occurring at a total concentration of 30 mg/L. It was estimated that the presence of 30 mg/L organic acids would artificially overstate TEM content by 2 mg/L. Of the five tested parameters, the factor that most controlled the total WSO in produced water was that of aqueous phase pH. Beyond a value of pH7 significant quantities of C{sub 10}-C{sub 20} range material become markedly soluble as they deprotonate in a basic aqueous phase. Both the absolute and relative volumes of GOM brine and crude additionally affected total WSO. Produced water appeared to reach a saturation level of WSO at a.50% water/oil ratio. Pressure slightly enhanced WSO by increasing the relative quantity of C{sub 6}-C{sub 10} range material. Temperature primarily altered the relative ratio of carbon ranges within the WSO without significantly elevating the total WSO in the GOM brine. Salinity had the least affect on the chemical character or the carbon size of WSO in produced water.

  6. Methods for producing reinforced carbon nanotubes

    DOE Patents [OSTI]

    Ren, Zhifen (Newton, MA); Wen, Jian Guo (Newton, MA); Lao, Jing Y. (Chestnut Hill, MA); Li, Wenzhi (Brookline, MA)

    2008-10-28

    Methods for producing reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials are disclosed. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  7. Method of producing a high pressure gas

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Zollinger, William T.

    2006-07-18

    A method of producing a high pressure gas is disclosed and which includes providing a container; supplying the container with a liquid such as water; increasing the pressure of the liquid within the container; supplying a reactant composition such as a chemical hydride to the liquid under pressure in the container and which chemically reacts with the liquid to produce a resulting high pressure gas such as hydrogen at a pressure of greater than about 100 pounds per square inch of pressure; and drawing the resulting high pressure gas from the container.

  8. Solid fuel volatilization to produce synthesis gas

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Degenstein, Nick J.; Dreyer, Brandon J.; Colby, Joshua L.

    2014-07-29

    A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.

  9. Method for producing small hollow spheres

    DOE Patents [OSTI]

    Hendricks, C.D.

    1979-01-09

    Method is disclosed for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T [approx gt] 600 C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10[sup 3] [mu]m) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants. 1 fig.

  10. Method for producing small hollow spheres

    DOE Patents [OSTI]

    Hendricks, Charles D. [Livermore, CA

    1979-01-09

    Method for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T .gtorsim. 600.degree. C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10.sup.3 .mu.m) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants.

  11. Surface and interfacial reaction study of half cycle atomic layer deposited HfO{sub 2} on chemically treated GaSb surfaces

    SciTech Connect (OSTI)

    Zhernokletov, D. M.; Dong, H.; Brennan, B.; Kim, J.; Yakimov, M.; Tokranov, V.; Oktyabrsky, S.; Wallace, R. M.; Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080

    2013-04-01

    An in situ half-cycle atomic layer deposition/X-ray photoelectron spectroscopy (XPS) study was conducted in order to investigate the evolution of the HfO{sub 2} dielectric interface with GaSb(100) surfaces after sulfur passivation and HCl etching, designed to remove the native oxides. With the first pulses of tetrakis(dimethylamido)hafnium(IV) and water, a decrease in the concentration of antimony oxide states present on the HCl-etched surface is observed, while antimony sulfur states diminished below the XPS detection limit on sulfur passivated surface. An increase in the amount of gallium oxide/sulfide is seen, suggesting oxygen or sulfur transfers from antimony to gallium during antimony oxides/sulfides decomposition.

  12. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L.; Keasling, Jay D.

    2015-05-26

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  13. Performance Profiles of Major Energy Producers

    Reports and Publications (EIA)

    2011-01-01

    The information and analyses in Performance Profiles of Major Energy Producers is intended to provide a critical review, and promote an understanding, of the possible motivations and apparent consequences of investment decisions made by some of the largest corporations in the energy industry.

  14. Adaptive control system for gas producing wells

    SciTech Connect (OSTI)

    Fedor, Pashchenko; Sergey, Gulyaev; Alexander, Pashchenko

    2015-03-10

    Optimal adaptive automatic control system for gas producing wells cluster is proposed intended for solving the problem of stabilization of the output gas pressure in the cluster at conditions of changing gas flow rate and changing parameters of the wells themselves, providing the maximum high resource of hardware elements of automation.

  15. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-10-29

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  16. Method of producing a chemical hydride

    DOE Patents [OSTI]

    Klingler, Kerry M.; Zollinger, William T.; Wilding, Bruce M.; Bingham, Dennis N.; Wendt, Kraig M.

    2007-11-13

    A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

  17. Methods of producing continuous boron carbide fibers

    DOE Patents [OSTI]

    Garnier, John E.; Griffith, George W.

    2015-12-01

    Methods of producing continuous boron carbide fibers. The method comprises reacting a continuous carbon fiber material and a boron oxide gas within a temperature range of from approximately 1400.degree. C. to approximately 2200.degree. C. Continuous boron carbide fibers, continuous fibers comprising boron carbide, and articles including at least a boron carbide coating are also disclosed.

  18. Comparison of the vacuum-ultraviolet radiation response of HfO{sub 2}/SiO{sub 2}/Si dielectric stacks with SiO{sub 2}/Si

    SciTech Connect (OSTI)

    Upadhyaya, G. S.; Shohet, J. L.

    2007-02-12

    Vacuum ultraviolet (vuv) emitted during plasma processing degrades dielectrics by generating electron-hole pairs. VUV-induced charging of SiO{sub 2}/p-Si and HfO{sub 2}/SiO{sub 2}/p-Si dielectric stacks are compared. For SiO{sub 2}/p-Si, charging is observed for photon energies >15 eV by ionization of dielectric atoms from photoinjected electrons. In HfO{sub 2}/SiO{sub 2}/p-Si, charging is observed for photon >10 eV and is due to ionization by photoinjected electrons and by H{sup +} trapping in the HfO{sub 2}/SiO{sub 2} bulk. Hydrogen appears during annealing at the Si-SiO{sub 2} interface forming Si-H, which, during irradiation, is depassivated by photoinjected electrons. The authors conclude that dielectric charging in thin oxides (<10 nm) occurs more easily in HfO{sub 2}/SiO{sub 2} than in SiO{sub 2}.

  19. In-operando hard X-ray photoelectron spectroscopy study on the impact of current compliance and switching cycles on oxygen and carbon defects in resistive switching Ti/HfO{sub 2}/TiN cells

    SciTech Connect (OSTI)

    Sowinska, Malgorzata Bertaud, Thomas; Walczyk, Damian; Calka, Pauline; Walczyk, Christian; Thiess, Sebastian; Alff, Lambert; Schroeder, Thomas

    2014-05-28

    In this study, direct experimental materials science evidence of the important theoretical prediction for resistive random access memory (RRAM) technologies that a critical amount of oxygen vacancies is needed to establish stable resistive switching in metal-oxide-metal samples is presented. In detail, a novel in-operando hard X-ray photoelectron spectroscopy technique is applied to non-destructively investigates the influence of the current compliance and direct current voltage sweep cycles on the Ti/HfO{sub 2} interface chemistry and physics of resistive switching Ti/HfO{sub 2}/TiN cells. These studies indeed confirm that current compliance is a critical parameter to control the amount of oxygen vacancies in the conducting filaments in the oxide layer during the RRAM cell operation to achieve stable switching. Furthermore, clear carbon segregation towards the Ti/HfO{sub 2} interface under electrical stress is visible. Since carbon impurities impact the oxygen vacancy defect population under resistive switching, this dynamic carbon segregation to the Ti/HfO{sub 2} interface is suspected to negatively influence RRAM device endurance. Therefore, these results indicate that the RRAM materials engineering needs to include all impurities in the dielectric layer in order to achieve reliable device performance.

  20. Beneficial Reuse of San Ardo Produced Water

    SciTech Connect (OSTI)

    Robert A. Liske

    2006-07-31

    This DOE funded study was performed to evaluate the potential for treatment and beneficial reuse of produced water from the San Ardo oilfield in Monterey County, CA. The potential benefits of a successful full-scale implementation of this project include improvements in oil production efficiency and additional recoverable oil reserves as well as the addition of a new reclaimed water resource. The overall project was conducted in two Phases. Phase I identified and evaluated potential end uses for the treated produced water, established treated water quality objectives, reviewed regulations related to treatment, transport, storage and use of the treated produced water, and investigated various water treatment technology options. Phase II involved the construction and operation of a small-scale water treatment pilot facility to evaluate the process's performance on produced water from the San Ardo oilfield. Cost estimates for a potential full-scale facility were also developed. Potential end uses identified for the treated water include (1) agricultural use near the oilfield, (2) use by Monterey County Water Resources Agency (MCWRA) for the Salinas Valley Water Project or Castroville Seawater Intrusion Project, (3) industrial or power plant use in King City, and (4) use for wetlands creation in the Salinas Basin. All of these uses were found to have major obstacles that prevent full-scale implementation. An additional option for potential reuse of the treated produced water was subsequently identified. That option involves using the treated produced water to recharge groundwater in the vicinity of the oil field. The recharge option may avoid the limitations that the other reuse options face. The water treatment pilot process utilized: (1) warm precipitation softening to remove hardness and silica, (2) evaporative cooling to meet downstream temperature limitations and facilitate removal of ammonia, and (3) reverse osmosis (RO) for removal of dissolved salts, boron, and organics. Pilot study results indicate that produced water from the San Ardo oilfield can be treated to meet project water quality goals. Approximately 600 mg/l of caustic and 100 mg/l magnesium dosing were required to meet the hardness and silica goals in the warm softening unit. Approximately 30% of the ammonia was removed in the cooling tower; additional ammonia could be removed by ion exchange or other methods if necessary. A brackish water reverse osmosis membrane was effective in removing total dissolved solids and organics at all pH levels evaluated; however, the boron treatment objective was only achieved at a pH of 10.5 and above.

  1. United Wisconsin Grain Producers UWGP | Open Energy Information

    Open Energy Info (EERE)

    Name: United Wisconsin Grain Producers (UWGP) Place: Friesland, Wisconsin Product: Bioethanol producer using corn as feedstock References: United Wisconsin Grain Producers...

  2. Effects of Introduced Materials in the Drift Scale Test

    SciTech Connect (OSTI)

    DeLoach, L; Jones, RL

    2002-01-11

    Water samples previously acquired from superheated (>140 C) zones within hydrological test boreholes of the Drift Scale Test (DST) show relatively high fluoride concentrations (5-66 ppm) and low pH (3.1-3.5) values. In these high temperature regions of the rock, water is present superheated vapor only--liquid water for sampling purposes is obtained during the sampling process by cooling. Based on data collected to date, it is evident that the source of the fluoride and low pH is from introduced man-made materials (Teflon{trademark} and/or Viton{trademark} fluoroelastomer) used in the test. The test materials may contribute fluoride either by degassing hydrogen fluoride (HF) directly to produce trace concentrations of HF gas ({approx}0.1 ppm) in the high temperature steam, or by leaching fluoride in the sampling tubes after condensation of the superheated steam. HF gas is known to be released from Viton{trademark} at high temperatures (Dupont Dow Elastomers L.L.C., Elkton, MD, personal communication) and the sample water compositions indicate near stoichiometric balance of hydrogen ion and fluoride ion, indicating dissolution of HF gas into the aqueous phase. These conclusions are based on a series of water samples collected to determine if the source of the fluoride is from the degradation of materials originally installed to facilitate measurements. Analyses of these water samples show that the source of the fluoride is the introduced materials, that is the Viton{trademark} packers used to isolate test zones and/or Teflon{trademark} tubing used to draw water and steam from the test zones. In particular, water samples collected from borehole (BH) 72 high temperatures ({approx} 170 C) prior to introduction of any Viton{trademark} or Teflon{trademark} show pH Values (4.8 to 5.5) and fluoride concentrations well below 1 ppm over a period of six months. These characteristics are typical of condensing DST steam that contains only some dissolved carbon dioxide generated by water-mineral-gas reactions in the rock. With the introduction of the Viton{trademark} packer materials and Teflon{trademark} sampling tube in BH72, the water samples show pH values drop to 3.8, while fluoride rises to 2.4 ppm within three days. After nine days, the pH values reach as low as 3.4 and fluoride concentrations rise as high as 7.5 ppm in the collected samples. The background information describing the fluoride issue and a summary of the water collection activities along with the analytical results are provided below. The results of the field test confirm the hypothesis that the source of the fluoride in specific samples from the DST is the introduced test materials (i.e. Viton{trademark} and/or Teflon{trademark}). This is positive from the perspective of repository performance, particularly waste package and drip shield degradation behavior, as deleterious introduced materials would be avoided in an operating repository. Ongoing laboratory testing to be Completed in January 2002, and additional testing in BH72 and BH55 will address further details, such as the specific material introducing the fluorine and the material breakdown process.

  3. Method for producing highly reflective metal surfaces

    DOE Patents [OSTI]

    Arnold, J.B.; Steger, P.J.; Wright, R.R.

    1982-03-04

    The invention is a novel method for producing mirror surfaces which are extremely smooth and which have high optical reflectivity. The method includes depositing, by electrolysis, an amorphous layer of nickel on an article and then diamond-machining the resulting nickel surface to increase its smoothness and reflectivity. The machined nickel surface then is passivated with respect to the formation of bonds with electrodeposited nickel. Nickel then is electrodeposited on the passivated surface to form a layer of electroplated nickel whose inside surface is a replica of the passivated surface. The mandrel then may be-re-passivated and provided with a layer of electrodeposited nickel, which is then recovered from the mandrel providing a second replica. The mandrel can be so re-used to provide many such replicas. As compared with producing each mirror-finished article by plating and diamond-machining, the new method is faster and less expensive.

  4. Method for producing catalysts from coal

    DOE Patents [OSTI]

    Farcasiu, M.; Derbyshire, F.; Kaufman, P.B.; Jagtoyen, M.

    1998-02-24

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere. 1 fig.

  5. Method for producing catalysis from coal

    DOE Patents [OSTI]

    Farcasiu, Malvina (Pittsburgh, PA); Derbyshire, Frank (Lexington, KY); Kaufman, Phillip B. (Library, PA); Jagtoyen, Marit (Lexington, KY)

    1998-01-01

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.

  6. PROCESS FOR PRODUCING ALKYL ORTHOPHOSPHORIC ACID EXTRACTANTS

    DOE Patents [OSTI]

    Grinstead, R.R.

    1962-01-23

    A process is given for producing superior alkyl orthophosphoric acid extractants for use in solvent extraction methods to recover and purify various metals such as uranium and vanadium. The process comprises slurrying P/sub 2/O/ sub 5/ in a solvent diluent such as kerosene, benzene, isopropyl ether, and the like. An alipbatic alcohol having from nine to seventeen carbon atoms, and w- hcrein ihc OH group is situated inward of the terminal carbon atoms, is added to the slurry while the reaction temperature is mainiained below 60 deg C. The alcohol is added in the mole ratio of about 2 to l, alcohol to P/sub 2/O/sub 5/. A pyrophosphate reaotion product is formed in the slurry-alcohol mixture. Subsequently, the pyrophosphate reaction product is hydrolyzed with dilute mineral acid to produce the desired alkyl orthophosphoric aeid extractant. The extraetant may then be separated and utilized in metal-recovery, solvent- extraction processes. (AEC)

  7. Method of producing .sup.67 Cu

    DOE Patents [OSTI]

    O'Brien, Jr., Harold A. (Los Alamos, NM); Barnes, John W. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM); Thomas, Kenneth E. (Los Alamos, NM); Bentley, Glenn E. (Los Alamos, NM)

    1984-01-01

    A method of producing carrier-free .sup.67 Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including .sup.67 Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  8. Method of producing silicon carbide articles

    DOE Patents [OSTI]

    Milewski, John V. (Los Alamos, NM)

    1985-01-01

    A method of producing articles comprising reaction-bonded silicon carbide (SiC) and graphite (and/or carbon) is given. The process converts the graphite (and/or carbon) in situ to SiC, thus providing the capability of economically obtaining articles made up wholly or partially of SiC having any size and shape in which graphite (and/or carbon) can be found or made. When the produced articles are made of an inner graphite (and/or carbon) substrate to which SiC is reaction bonded, these articles distinguish SiC-coated graphite articles found in the prior art by the feature of a strong bond having a gradual (as opposed to a sharply defined) interface which extends over a distance of mils. A method for forming SiC whisker-reinforced ceramic matrices is also given. The whisker-reinforced articles comprise SiC whiskers which substantially retain their structural integrity.

  9. Process for producing furan from furfural aldehyde

    DOE Patents [OSTI]

    Diebold, J.P.; Evans, R.J.

    1987-04-06

    A process of producing furan and derivatives thereof as disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.

  10. Method and apparatus for producing cryogenic targets

    DOE Patents [OSTI]

    Murphy, James T. (Los Alamos, NM); Miller, John R. (Penfield, NY)

    1984-01-01

    An improved method and apparatus are given for producing cryogenic inertially driven fusion targets in the fast isothermal freezing (FIF) method. Improved coupling efficiency and greater availability of volume near the target for diagnostic purposes and for fusion driver beam propagation result. Other embodiments include a new electrical switch and a new explosive detonator, all embodiments making use of a purposeful heating by means of optical fibers.

  11. Process for producing furan from furfural aldehyde

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Evans, Robert J. (Lakewood, CO)

    1988-01-01

    A process of producing furan and derivatives thereof is disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.

  12. Method and apparatus for producing cryogenic targets

    SciTech Connect (OSTI)

    Murphy, J.T.; Miller, J.R.

    1981-08-28

    An improved method and apparatus are given for producing cryogenic inertially driven fusion targets in the fast isothermal freezing (FIF) method. Improved coupling efficiency and greater availability of volume near the target for diagnostic purposes and for fusion driver beam propagation result. Other embodiments include a new electrical switch and a new explosive detonator, all embodiments making use of a purposeful heating by means of optical fibers.

  13. Scientists produce transparent, light-harvesting material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent, light-harvesting material Scientists produce transparent, light-harvesting material The material could be used in development of transparent solar panels. November 3, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a

  14. Method of producing microchannel and nanochannel articles

    DOE Patents [OSTI]

    D'Urso, Brian R.

    2010-05-04

    A method of making an article having channels therethrough includes the steps of: providing a ductile structure defining at least one macro-channel, the macro-channel containing a salt; drawing the ductile structure in the axial direction of the at least one macro-channel to reduce diameter of the macro-channel; and contacting the salt with a solvent to dissolve the salt to produce an article having at least one microchannel.

  15. Hydrogenase mimic produces hydrogen under the light

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Objective The Science Center Publications Graduate Research opportunities Undergraduate research opportunities EFRC-501 graduate class Seminar schedules Center News Research Highlights Center Research News Media about Center Center Video Library Bisfuel Picture Gallery Hydrogenase mimic produces hydrogen under the light 24 Jan 2013 Researchers from the laboratory of Giovanna Ghirlanda working on Subtask 3 (Fuel Production Complex) have achieved the synthesis of a peptide-based hydrogenase mimic

  16. Experiments with Wind to Produce Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nat EXPERIMENTS WITH WIND TO PRODUCE ENERGY Curriculum: Wind Power (simple machines, weather/climatology, aerodynamics, leverage, mechanics, atmospheric pressure, and energy resources/transformations) Grade Level: K-5 Small groups (3 to 4) Time: Constructing equipment needed in these activities varies based on student ability levels. Activities can be done in 1 or 2 class periods. Summary: There are five activities. The first activity demonstrates wind as energy, and that energy causes

  17. Method and apparatus for producing cryogenic targets

    DOE Patents [OSTI]

    Murphy, J.T.; Miller, J.R.

    1984-08-07

    An improved method and apparatus are given for producing cryogenic inertially driven fusion targets in the fast isothermal freezing (FIF) method. Improved coupling efficiency and greater availability of volume near the target for diagnostic purposes and for fusion driver beam propagation result. Other embodiments include a new electrical switch and a new explosive detonator, all embodiments making use of a purposeful heating by means of optical fibers. 6 figs.

  18. Beneficial Reuse of San Ardo Produced Water

    SciTech Connect (OSTI)

    Robert A. Liske

    2003-09-26

    This report summarizes the work performed from 1 April 2003 to 30 September 2003 and recommends the tasks to be performed during Phase II (Pilot Evaluation). During this period discussions were held with various water agencies regarding use of the treated produced water either directly or indirectly through a water trading arrangement. In particular, several discussions were held with Monterey County Water Resources Agency, that has been charged with the long-term management and preservation of water resources in Monterey County. The Agency is very supportive of the program. However, they would like to see water quality/cost estimate data for the treated produced water from the pilot study prior to evaluating water use/water trade options. The agency sent a letter encouraging the project team to perform the pilot study to evaluate feasibility of the project. In addition, the regulations related to use of the treated water for various applications were updated during this period. Finally, the work plan, health and safety plan and sample analyses plan for performing pilot study to treat the oilfield produced water were developed during this period.

  19. Method for producing metal oxide nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Mendoza, Daniel (Santa Fe, NM); Chen, Chun-Ku (Albuquerque, NM)

    2008-04-15

    Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.

  20. Performance profiles of major energy producers 1989

    SciTech Connect (OSTI)

    Not Available

    1991-01-23

    Performance Profiles of Major Energy Producers 1989 is the thirteenth annual report of the Energy Information Administration's (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 23 major energy companies (the FRS companies'') required to report annually on Form EIA-28. Financial information is reported by major lines of business including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report. It also traces key developments affecting the financial performance of major energy companies in 1989, as well as review of important trends.

  1. Process for producing phenolic compounds from lignins

    DOE Patents [OSTI]

    Agblevor, Foster A. (Lakewood, CO)

    1998-01-01

    A process for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400.degree. C. to about 600.degree. C. at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1-3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof.

  2. Process for producing phenolic compounds from lignins

    DOE Patents [OSTI]

    Agblevor, F.A.

    1998-09-15

    A process is described for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400 C to about 600 C at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1--3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof. 16 figs.

  3. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, Lars G.; Carriera, Laura H.

    1983-01-01

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  4. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, L.G.; Carriera, L.H.

    1983-05-24

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  5. Apparatus for producing voltage and current pulses

    DOE Patents [OSTI]

    Kirbie, Hugh (Los Alamos, NM); Dale, Gregory E. (Los Alamos, NM)

    2010-12-21

    An apparatus having one or more modular stages for producing voltage and current pulses. Each module includes a diode charging means to charge a capacitive means that stores energy. One or more charging impedance means are connected to the diode charging means to provide a return current pathway. A solid-state switch discharge means, with current interruption capability, is connected to the capacitive means to discharge stored energy. Finally, a control means is provided to command the switching action of the solid-state switch discharge means.

  6. Method for producing titanium aluminide weld rod

    DOE Patents [OSTI]

    Hansen, Jeffrey S. (Corvallis, OR); Turner, Paul C. (Albany, OR); Argetsinger, Edward R. (Albany, OR)

    1995-01-01

    A process for producing titanium aluminide weld rod comprising: attaching one end of a metal tube to a vacuum line; placing a means between said vacuum line and a junction of the metal tube to prevent powder from entering the vacuum line; inducing a vacuum within the tube; placing a mixture of titanium and aluminum powder in the tube and employing means to impact the powder in the tube to a filled tube; heating the tube in the vacuum at a temperature sufficient to initiate a high-temperature synthesis (SHS) reaction between the titanium and aluminum; and lowering the temperature to ambient temperature to obtain a intermetallic titanium aluminide alloy weld rod.

  7. Tensor mesons produced in tau lepton decays

    SciTech Connect (OSTI)

    Lopez Castro, G.; Munoz, J. H.

    2011-05-01

    Light tensor mesons (T=a{sub 2}, f{sub 2} and K{sub 2}*) can be produced in decays of {tau} leptons. In this paper we compute the branching ratios of {tau}{yields}T{pi}{nu} decays by assuming the dominance of intermediate virtual states to model the form factors involved in the relevant hadronic matrix elements. The exclusive f{sub 2}(1270){pi}{sup -} decay mode turns out to have the largest branching ratio, of O(10{sup -4}). Our results indicate that the contribution of tensor meson intermediate states to the three-pseudoscalar channels of {tau} decays are rather small.

  8. Method of producing .beta.-spodumene bodies

    DOE Patents [OSTI]

    Chyung, Kenneth (Painted Post, NY); Day, J. Paul (Big Flats, NY); Holleran, Louis M. (Big Flats, NY); Olszewski, Anthony R. (Bath, NY)

    1999-01-01

    Beta-spodumene bodies and method of preparing the bodies that involves providing a uniform plastic batch of inorganic raw materials, organic binder, and vehicle, wherein the inorganic raw materials are composed of, in percent by weight, about 75% to 95% minerals, and about 5% to 25% glass. The batch is formed into a green body that is fired to produce a body composed substantially of beta-spodumene, and having a thermal expansion coefficient of <10.times.10.sup.-7 /.degree.C.(0-800.degree. C.), and a strength of .gtoreq.4 Ksi.

  9. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  10. Performance profiles of major energy producers 1994

    SciTech Connect (OSTI)

    1996-02-01

    Performance Profiles of Major Energy Producers 1994 is the eighteenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments in energy markets, with particular reference to the 24 major U.S. energy companies required to report annually on Form EIA-28. Financial information is reported by major lines of business, including oil and gas production, petroleum refining and marketing, other energy operations, and nonenergy businesses. Financial and operating results are presented in the context of energy market developments with a view toward identifying changing corporate strategies and measuring the performance of ongoing operations both in the United States and abroad.

  11. Method of producing a cellulase-containing cell-free fermentate produced from microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H.C.

    1998-05-26

    Bacteria which produce large amounts of cellulose-containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualities for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques. 5 figs.

  12. Method of producing a cellulase-containing cell-free fermentate produced from microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H. Craig (Lenoir City, TN)

    1998-01-01

    Bacteria which produce large amounts of cellulose-containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualities for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques.

  13. Method for producing small hollow spheres

    DOE Patents [OSTI]

    Rosencwaig, Allen (Danville, CA); Koo, Jackson C. (San Ramon, CA); Dressler, John L. (Spring Valley, OH)

    1981-01-01

    A method for producing small hollow spheres of glass having an outer diameter ranging from about 100.mu. to about 500.mu. with a substantially uniform wall thickness in the range of about 0.5-20.mu.. The method involves introducing aqueous droplets of a glass-forming solution into a long vertical drop oven or furnace having varying temperature regions. In one embodiment, one of the temperature regions is lower than both the preceeding region and the subsequent region. One region utilizes a temperature of at least 200.degree. C. higher than the melting point of the glass-forming material in the solution and, for example, may be at least 3 times higher than the temperature of the preceeding region. In addition, there is a sharp temperature gradient between these regions. As each droplet of solution passes through a first region it forms into a gel membrane having a spherical shape and encapsulates the rest of the drop retained in the elastic outer surface and the water entrapped within diffuses rapidly through the thin gel membrane which causes more of the glass-forming material to go out of solution and is incorporated into the gel membrane causing it to grow in size and become hollow. thus produced hollow glass sphere has a sphericity, concentricity, and wall uniformity of better than 5%. The sphere is capable of retaining material of up to at least 100 atmospheres therein over long periods of time. In one embodiment.

  14. Trip Report-Produced-Water Field Testing

    SciTech Connect (OSTI)

    Sullivan, Enid J.

    2012-05-25

    Los Alamos National Laboratory (LANL) conducted field testing of a produced-water pretreatment apparatus with assistance from faculty at the Texas A&M University (TAMU) protein separation sciences laboratory located on the TAMU main campus. The following report details all of the logistics surrounding the testing. The purpose of the test was to use a new, commercially-available filter media housing containing modified zeolite (surfactant-modified zeolite or SMZ) porous medium for use in pretreatment of oil and gas produced water (PW) and frac-flowback waters. The SMZ was tested previously in October, 2010 in a lab-constructed configuration ('old multicolumn system'), and performed well for removal of benzene, toluene, ethylbenzene, and xylenes (BTEX) from PW. However, a less-expensive, modular configuration is needed for field use. A modular system will allow the field operator to add or subtract SMZ filters as needed to accommodate site specific conditions, and to swap out used filters easily in a multi-unit system. This test demonstrated the use of a commercial filter housing with a simple flow modification and packed with SMZ for removing BTEX from a PW source in College Station, Texas. The system will be tested in June 2012 at a field site in Pennsylvania for treating frac-flowback waters. The goals of this test are: (1) to determine sorption efficiency of BTEX in the new configuration; and (2) to observe the range of flow rates, backpressures, and total volume treated at a given flow rate.

  15. Method for producing and treating coal gases

    DOE Patents [OSTI]

    Calderon, Albert (P.O. Box 126, Bowling Green, OH 43402)

    1990-01-01

    A method of generating a de-sulphurized volatile matter and a relatively low Btu gas includes the initial step of pyrolyzing coal to produce volatile matter and a char. The volatile matter is fed to a first de-sulphurizer containing a de-sulphurizing agent to remove sulphur therefrom. At the same time, the char is gasified to produce a relatively low Btu gas. The low Btu gas is fed to a second de-sulphurizer containing the de-sulphurizing agent to remove sulphur therefrom. A regenerator is provided for removing sulphur from the de-sulphurizing agent. Portions of the de-sulphurizing agent are moved among the first de-sulphurizer, the second de-sulphurizer, and the regenerator such that the regenerator regenerates the de-sulphurizing agent. Preferably, the portions of the de-sulphurizing agent are moved from the second de-sulphurizer to the first de-sulphurizer, from the first de-sulphurizer to the regenerator, and from the regenerator to the second de-sulphurizer.

  16. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  17. Method of producing particulate-reinforced composites and composties produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intenisty acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaciton products comprise a solide particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particles-reinforced composite materials produced by such a process.

  18. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2015-12-29

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  19. Producing usable fuel from municipal solid waste

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1995-03-01

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  20. System and method for producing metallic iron

    DOE Patents [OSTI]

    Bleifuss, Rodney L; Englund, David J; Iwasaki, Iwao; Fosnacht, Donald R; Brandon, Mark M; True, Bradford G

    2013-09-17

    A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.

  1. System and method for producing metallic iron

    DOE Patents [OSTI]

    Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Fosnacht, Donald R. (Hermantown, MN); Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

    2012-01-17

    A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

  2. Performance profiles of major energy producers 1992

    SciTech Connect (OSTI)

    Not Available

    1994-01-13

    Performance Profiles of Major Energy Producers 1992 is the sixteenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 25 major energy companies (the FRS companies) required to report annually on Form EIA-28. Financial information is reported by major lines of business, including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report. The data are presented in the context of key energy market developments with a view toward identifying changing strategies of corporate development and measuring the apparent success of current ongoing operations.

  3. Performance profiles of major energy producers 1996

    SciTech Connect (OSTI)

    1998-01-01

    This publication examines developments in the operations of the major US e energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area. In 1996, 24 companies filed Form EIA-28. The analysis and data presented in this report represents the operations of the Financial Reporting System companies in the context of their worldwide operations and in the context of the major energy markets which they serve. Both energy and nonenergy developments of these companies are analyzed. Although the focus is on developments in 1996, important trends prior to that time are also featured. Sections address energy markets in 1996; key financial developments; oil and gas exploration, development, and production; downstream petroleum in 1996; coal and alternative energy; and foreign direct investment in US energy. 30 figs., 104 tabs.

  4. Rocky Mountain Basins Produced Water Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Historical records for produced water data were collected from multiple sources, including Amoco, British Petroleum, Anadarko Petroleum Corporation, United States Geological Survey (USGS), Wyoming Oil and Gas Commission (WOGC), Denver Earth Resources Library (DERL), Bill Barrett Corporation, Stone Energy, and other operators. In addition, 86 new samples were collected during the summers of 2003 and 2004 from the following areas: Waltman-Cave Gulch, Pinedale, Tablerock and Wild Rose. Samples were tested for standard seven component "Stiff analyses", and strontium and oxygen isotopes. 16,035 analyses were winnowed to 8028 unique records for 3276 wells after a data screening process was completed. [Copied from the Readme document in the zipped file available at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the Zipped file to your PC. When opened, it will contain four versions of the database: ACCESS, EXCEL, DBF, and CSV formats. The information consists of detailed water analyses from basins in the Rocky Mountain region.

  5. Process for producing dispersed particulate composite materials

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Richland, WA); Hirth, John P. (Viola, ID)

    1995-01-01

    This invention is directed to a process for forming noninterwoven dispersed particulate composite products. In one case a composite multi-layer film product comprises a substantially noninterwoven multi-layer film having a plurality of discrete layers. This noninterwoven film comprises at least one discrete layer of a first material and at least one discrete layer of a second material. In another case the first and second materials are blended together with each other. In either case, the first material comprises a metalloid and the second material a metal compound. At least one component of a first material in one discrete layer undergoes a solid state displacement reaction with at least one component of a second material thereby producing the requisite noninterwoven composite film product. Preferably, the first material comprises silicon, the second material comprises Mo.sub.2 C, the third material comprises SiC and the fourth material comprises MoSi.sub.2.

  6. Performance profiles of major energy producers 1993

    SciTech Connect (OSTI)

    1995-01-01

    Performance Profiles of Major Energy Producers 1993 is the seventeenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments in energy markets, with particular reference to the 25 major US energy companies required to report annually on Form EIA-28. Financial information is reported by major liens of business, including oil and gas production, petroleum refining and marketing, other energy operations, and nonenergy businesses. Financial and operating results are presented in the context of energy market developments with a view toward identifying changing corporate strategies and measuring the performance of ongoing operations both in the US and abroad. This year`s report analyzes financial and operating developments for 1993 (Part 1: Developments in 1993) and also reviews key developments during the 20 years following the Arab Oil Embargo of 1973--1974 (Part 2: Major Energy Company Strategies Since the Arab Oil Embargo). 49 figs., 104 tabs.

  7. Automated apparatus for producing gradient gels

    DOE Patents [OSTI]

    Anderson, N.L.

    1983-11-10

    Apparatus for producing a gradient gel which serves as a standard medium for a two-dimensional analysis of proteins, the gel having a density gradient along its height formed by a variation in gel composition, with the apparatus including first and second pumping means each including a plurality of pumps on a common shaft and driven by a stepping motor capable of providing small incremental changes in pump outputs for the gel ingredients, the motors being controlled, by digital signals from a digital computer, a hollow form or cassette for receiving the gel composition, means for transferring the gel composition including a filler tube extending near the bottom of the cassette, adjustable horizontal and vertical arms for automatically removing and relocating the filler tube in the next cassette, and a digital computer programmed to automatically control the stepping motors, arm movements, and associated sensing operations involving the filling operation.

  8. Automated apparatus for producing gradient gels

    DOE Patents [OSTI]

    Anderson, Norman L. (Clarendon Hills, IL)

    1986-01-01

    Apparatus for producing a gradient gel which serves as a standard medium for a two-dimensional analysis of proteins, the gel having a density gradient along its height formed by a variation in gel composition, with the apparatus including first and second pumping means each including a plurality of pumps on a common shaft and driven by a stepping motor capable of providing small incremental changes in pump outputs for the gel ingredients, the motors being controlled, by digital signals from a digital computer, a hollow form or cassette for receiving the gel composition, means for transferring the gel composition including a filler tube extending near the bottom of the cassette, adjustable horizontal and vertical arms for automatically removing and relocating the filler tube in the next cassette, and a digital computer programmed to automatically control the stepping motors, arm movements, and associated sensing operations involving the filling operation.

  9. Decarbonization process for carbothermically produced aluminum

    DOE Patents [OSTI]

    Bruno, Marshall J.; Carkin, Gerald E.; DeYoung, David H.; Dunlap, Sr., Ronald M.

    2015-06-30

    A method of recovering aluminum is provided. An alloy melt having Al.sub.4C.sub.3 and aluminum is provided. This mixture is cooled and then a sufficient amount of a finely dispersed gas is added to the alloy melt at a temperature of about 700.degree. C. to about 900.degree. C. The aluminum recovered is a decarbonized carbothermically produced aluminum where the step of adding a sufficient amount of the finely dispersed gas effects separation of the aluminum from the Al.sub.4C.sub.3 precipitates by flotation, resulting in two phases with the Al.sub.4C.sub.3 precipitates being the upper layer and the decarbonized aluminum being the lower layer. The aluminum is then recovered from the Al.sub.4C.sub.3 precipitates through decanting.

  10. Plasma treatment for producing electron emitters

    DOE Patents [OSTI]

    Coates, Don Mayo (Santa Fe, NM); Walter, Kevin Carl (Los Alamos, NM)

    2001-01-01

    Plasma treatment for producing carbonaceous field emission electron emitters is disclosed. A plasma of ions is generated in a closed chamber and used to surround the exposed surface of a carbonaceous material. A voltage is applied to an electrode that is in contact with the carbonaceous material. This voltage has a negative potential relative to a second electrode in the chamber and serves to accelerate the ions toward the carbonaceous material and provide an ion energy sufficient to etch the exposed surface of the carbonaceous material but not sufficient to result in the implantation of the ions within the carbonaceous material. Preferably, the ions used are those of an inert gas or an inert gas with a small amount of added nitrogen.

  11. Crystal structure and antiferromagnetic ordering of quasi-2D [Cu(HF{sub 2})(pyz){sub 2}]TaF{sub 6} (pyz = pyrazine).

    SciTech Connect (OSTI)

    Manson, J. L.; Schlueter, J. A.; McDonald, R. D.; Singleton, J.; Materials Science Division; Eastern Washington Univ.; LANL

    2010-04-01

    The crystal structure of the title compound was determined by X-ray diffraction at 90 and 295 K. Copper(II) ions are coordinated to four bridging pyz ligands to form square layers in the ab-plane. Bridging HF{sub 2}{sup -} ligands join the layers together along the c-axis to afford a tetragonal, three-dimensional (3D) framework that contains Taf{sub 6}{sup -} anions in every cavity. At 295 K, the pyz rings lie exactly perpendicular to the layers and cooling to 90 K induces a canting of those rings. Magnetically, the compound exhibits 2D antiferromagnetic correlations within the 2D layers with an exchange interaction of -13.1(1) K. Weak interlayer interactions, as mediated by Cu-F-H-F-Cu, leads to long-range magnetic order below 4.2 K. Pulsed-field magnetization data at 0.5 K show a concave curvature with increasing B and reveal a saturation magnetization at 35.4 T.

  12. Methods for producing nanoparticles using palladium salt and uses thereof

    DOE Patents [OSTI]

    Chan, Siu-Wai; Liang, Hongying

    2015-12-01

    The disclosed subject matter is directed to a method for producing nanoparticles, as well as the nanoparticles produced by this method. In one embodiment, the nanoparticles produced by the disclosed method have a high defect density.

  13. How is shale gas produced? | Department of Energy

    Energy Savers [EERE]

    How is shale gas produced? How is shale gas produced? PDF icon How is shale gas produced? More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary Shale Gas Development Challenges: Fracture Fluids

  14. Co-Produced Geothermal Systems | Open Energy Information

    Open Energy Info (EERE)

    Geothermal System: Co-Produced water is the water that is produced as a by-product during oil and gas production. If there is enough water produced at a high enough temperature...

  15. How Much Energy Does Each State Produce? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Does Each State Produce? How Much Energy Does Each State Produce? Energy Production in Trillion Btu: 2012 Click on each state to learn more about how much energy it produces Source: EIA State Energy Data Systems

  16. ASEM Green Independent Power Producers Network | Open Energy...

    Open Energy Info (EERE)

    ASEM Green Independent Power Producers Network Jump to: navigation, search Name: ASEM Green Independent Power Producers Network Place: Germany Sector: Renewable Energy Product: A...

  17. USA Biomass Power Producers Alliance | Open Energy Information

    Open Energy Info (EERE)

    Biomass Power Producers Alliance Jump to: navigation, search Name: USA Biomass Power Producers Alliance Place: Sacramento, California Sector: Biomass Product: National trade...

  18. Methods for producing and using densified biomass products containing...

    Office of Scientific and Technical Information (OSTI)

    producing and using densified biomass products containing pretreated biomass fibers Citation Details In-Document Search Title: Methods for producing and using densified biomass...

  19. Energy Department Announces $12 Million for Technologies to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Announces 12 Million for Technologies to Produce Renewable Carbon Fiber from Biomass Energy Department Announces 12 Million for Technologies to Produce Renewable Carbon Fiber ...

  20. Spotlight on Austin, Texas: Best Offer Ever Produces Upgrades...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Upgrades in Record Time Spotlight on Austin, Texas: Best Offer Ever Produces Upgrades in Record Time Spotlight on Austin, Texas: Best Offer Ever Produces Upgrades in Record Time,...

  1. DOE Seeks Industry Proposals for Feasibility Study to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proposals for Feasibility Study to Produce Greenhouse Gas-Free Hydrogen at Existing Nuclear Power Plants DOE Seeks Industry Proposals for Feasibility Study to Produce Greenhouse ...

  2. Midwest Ethanol Producers Inc MEPI | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Producers Inc MEPI Jump to: navigation, search Name: Midwest Ethanol Producers Inc (MEPI) Place: O'Neill, Nebraska Zip: 68763 Product: Focused on ethanol production....

  3. Association of Renewable Energy Producers Spain | Open Energy...

    Open Energy Info (EERE)

    Renewable Energy Producers Spain Jump to: navigation, search Name: Association of Renewable Energy Producers (Spain) Place: Barcelona, Spain Zip: 8008 Sector: Renewable Energy...

  4. Methods for Post Irradiation Examination of Tritium Producing...

    Office of Environmental Management (EM)

    Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods...

  5. Thamna Bio power and Organic Producers Company TBPOPC | Open...

    Open Energy Info (EERE)

    Thamna Bio power and Organic Producers Company TBPOPC Jump to: navigation, search Name: Thamna Bio-power and Organic Producers Company (TBPOPC) Place: Thamna, Gujarat, India...

  6. Employee-Focused Structure Helps Produce Upgrades for Contractor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Employee-Focused Structure Helps Produce Upgrades for Contractor Employee-Focused Structure Helps Produce Upgrades for Contractor Photo of a young man sitting on a couch, looking ...

  7. Clean Hydrogen Producers Ltd CHP | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Producers Ltd CHP Jump to: navigation, search Name: Clean Hydrogen Producers Ltd (CHP) Place: Geneva, Switzerland Zip: 1209 Sector: Hydro, Hydrogen, Solar Product: Swiss...

  8. Produced water volumes and management practices in the United...

    Office of Scientific and Technical Information (OSTI)

    Produced water volumes and management practices in the United States. Citation Details In-Document Search Title: Produced water volumes and management practices in the United ...

  9. Current Challenges in Commercially Producing Biofuels from Lignocellul...

    Office of Scientific and Technical Information (OSTI)

    Biofuels that are produced from biobased materials are a good alternative to petroleum based fuels. They offer several benefits to society and the environment. Producing second ...

  10. Energy Department Announces $10 Million for Technologies to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies to Produce Advanced Biofuel Products from Biomass Energy Department Announces 10 Million for Technologies to Produce Advanced Biofuel Products from Biomass April 15, ...

  11. AGA Producing Regions Natural Gas Underground Storage Net Withdrawals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AGA Producing Regions Natural Gas Underground Storage Net Withdrawals (Million Cubic Feet) AGA Producing Regions Natural Gas Underground Storage Net Withdrawals (Million Cubic...

  12. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major...

  13. Effect of current compliance and voltage sweep rate on the resistive switching of HfO{sub 2}/ITO/Invar structure as measured by conductive atomic force microscopy

    SciTech Connect (OSTI)

    Wu, You-Lin Liao, Chun-Wei; Ling, Jing-Jenn

    2014-06-16

    The electrical characterization of HfO{sub 2}/ITO/Invar resistive switching memory structure was studied using conductive atomic force microscopy (AFM) with a semiconductor parameter analyzer, Agilent 4156C. The metal alloy Invar was used as the metal substrate to ensure good ohmic contact with the substrate holder of the AFM. A conductive Pt/Ir AFM tip was placed in direct contact with the HfO{sub 2} surface, such that it acted as the top electrode. Nanoscale current-voltage (I-V) characteristics of the HfO{sub 2}/ITO/Invar structure were measured by applying a ramp voltage through the conductive AFM tip at various current compliances and ramp voltage sweep rates. It was found that the resistance of the low resistance state (RLRS) decreased with increasing current compliance value, but resistance of high resistance state (RHRS) barely changed. However, both the RHRS and RLRS decreased as the voltage sweep rate increased. The reasons for this dependency on current compliance and voltage sweep rate are discussed.

  14. Performance profiles of major energy producers, 1997

    SciTech Connect (OSTI)

    1999-01-01

    The energy industry generally and petroleum and natural gas operations in particular are frequently reacting to a variety of unsettling forces. Falling oil prices, economic upswings, currency devaluations, increasingly rigorous environmental quality standards, deregulation of electricity markets, and continued advances in exploration and production technology were among the challenges and opportunities to the industry in 1997. To analyze the extent to which these and other developments have affected energy industry financial and operating performance, strategies, and industry structure, the Energy Information Administration (EIA) maintains the Financial Reporting Systems (FRS). Through Form EIA-28, major US energy companies annually report to the FRS. Financial and operating information is reported by major lines of business, including oil and gas production (upstream), petroleum refining and marketing (downstream), other energy operations, and nonenergy business. Performance Profiles of Major Producers 1997 examines the interplays of energy markets, companies` strategies, and government policies (in 1997 and in historical context) that gave rise to the results given here. The report also analyzes other key aspects of energy company financial performance as seen through the multifaceted lens provided by the FRS data and complementary data for industry overall. 41 figs., 77 tabs.

  15. Process for producing large grain cadmium telluride

    DOE Patents [OSTI]

    Hasoon, Falah S. (Arvada, CO); Nelson, Art J. (Longmont, CO)

    1996-01-01

    A process for producing a cadmium telluride polycrystalline film having grain sizes greater than about 20 .mu.m. The process comprises providing a substrate upon which cadmium telluride can be deposited and placing that substrate within a vacuum chamber containing a cadmium telluride effusion cell. A polycrystalline film is then deposited on the substrate through the steps of evacuating the vacuum chamber to a pressure of at least 10.sup.-6 torr.; heating the effusion cell to a temperature whereat the cell releases stoichiometric amounts of cadmium telluride usable as a molecular beam source for growth of grains on the substrate; heating the substrate to a temperature whereat a stoichiometric film of cadmium telluride can be deposited; and releasing cadmium telluride from the effusion cell for deposition as a film on the substrate. The substrate then is placed in a furnace having an inert gas atmosphere and heated for a sufficient period of time at an annealing temperature whereat cadmium telluride grains on the substrate grow to sizes greater than about 20 .mu.m.

  16. Method for producing ceramic particles and agglomerates

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Gleiman, Seth S. (Santa Fe, NM); Chen, Chun-Ku (Albuquerque, NM)

    2001-01-01

    A method for generating spherical and irregularly shaped dense particles of ceramic oxides having a controlled particle size and particle size distribution. An aerosol containing precursor particles of oxide ceramics is directed into a plasma. As the particles flow through the hot zone of the plasma, they melt, collide, and join to form larger particles. If these larger particles remain in the hot zone, they continue melting and acquire a spherical shape that is retained after they exit the hot zone, cool down, and solidify. If they exit the hot zone before melting completely, their irregular shape persists and agglomerates are produced. The size and size distribution of the dense product particles can be controlled by adjusting several parameters, the most important in the case of powder precursors appears to be the density of powder in the aerosol stream that enters the plasma hot zone. This suggests that particle collision rate is responsible for determining ultimate size of the resulting sphere or agglomerate. Other parameters, particularly the gas flow rates and the microwave power, are also adjusted to control the particle size distribution.

  17. Process for producing large grain cadmium telluride

    DOE Patents [OSTI]

    Hasoon, F.S.; Nelson, A.J.

    1996-01-16

    A process is described for producing a cadmium telluride polycrystalline film having grain sizes greater than about 20 {micro}m. The process comprises providing a substrate upon which cadmium telluride can be deposited and placing that substrate within a vacuum chamber containing a cadmium telluride effusion cell. A polycrystalline film is then deposited on the substrate through the steps of evacuating the vacuum chamber to a pressure of at least 10{sup {minus}6} torr.; heating the effusion cell to a temperature whereat the cell releases stoichiometric amounts of cadmium telluride usable as a molecular beam source for growth of grains on the substrate; heating the substrate to a temperature whereat a stoichiometric film of cadmium telluride can be deposited; and releasing cadmium telluride from the effusion cell for deposition as a film on the substrate. The substrate then is placed in a furnace having an inert gas atmosphere and heated for a sufficient period of time at an annealing temperature whereat cadmium telluride grains on the substrate grow to sizes greater than about 20 {micro}m.

  18. Alloy and method of producing the same

    DOE Patents [OSTI]

    Hufnagel, Todd C.; Ott, Ryan T.; Fan, Cang; Kecskes, Laszlo

    2005-07-19

    In accordance with a preferred embodiment of the invention, an alloy or other composite material is provided formed of a bulk metallic glass matrix with a microstructure of crystalline metal particles. The alloy preferably has a composition of (X.sub.a Ni.sub.b Cu.sub.c).sub.100-d-c Y.sub.d Al.sub.c, wherein the sum of a, b and c equals 100, wherein 40.ltoreq.a.ltoreq.80, 0.ltoreq.b.ltoreq.35, 0.ltoreq.c.ltoreq.40, 4.ltoreq.d.ltoreq.30, and 0.ltoreq.e.ltoreq.20, and wherein preferably X is composed of an early transition metal and preferably Y is composed of a refractory body-centered cubic early transition metal. A preferred embodiment of the invention also provides a method of producing an alloy composed of two or more phases at ambient temperature. The method includes the steps of providing a metastable crystalline phase composed of at least two elements, heating the metastable crystalline phase together with at least one additional element to form a liquid, casting the liquid, and cooling the liquid to form the alloy. In accordance with a preferred embodiment of the invention, the composition and cooling rate of the liquid can be controlled to determine the volume fraction of the crystalline phase and determine the size of the crystalline particles, respectively.

  19. MODIL cryocooler producibility demonstration project results

    SciTech Connect (OSTI)

    Cruz, G.E.; Franks, R.M.

    1993-04-07

    The production of large quantities of spacecraft needed by SDIO will require a cultural change in design and production practices. Low rates production and the need for exceedingly high reliability has driven the industry to custom designed, hand crafted, and exhaustively tested satellites. These factors have mitigated against employing design and manufacturing cost reduction methods commonly used in tactical missile production. Additional challenges to achieving production efficiencies are presented by the SDI spacecraft mission requirement. IR sensor systems, for example, are comprised of subassemblies and components that require the design, manufacture, and maintenance of ultra precision tolerances over challenging operational lifetimes. These IR sensors demand the use of reliable, closed loop, cryogenic refrigerators or active cryocoolers to meet stringent system acquisition and pointing requirements. The authors summarize some spacecraft cryocooler requirements and discuss observations regarding Industry`s current production capabilities of cryocoolers. The results of the Lawrence Livermore National Laboratory (LLNL) Spacecraft Fabrication and Test (SF and T) MODIL`s Phase I producibility demonstration project is presented.

  20. MODIL cryocooler producibility demonstration project results

    SciTech Connect (OSTI)

    Cruz, G.E.; Franks, R.M.

    1993-06-24

    The production of large quantities of spacecraft needed by SDIO will require a cultural change in design and production practices. Low rates production and the need for exceedingly high reliability has driven the industry to custom designed, hand crafted, and exhaustingly tested satellites. These factors have mitigated against employing design and manufacturing cost reduction methods commonly used in tactical missile production. Additional challenges to achieving production efficiencies are presented by the SDI spacecraft mission requirement. IR sensor systems, for example, are comprised of subassemblies and components that require the design, manufacture, and maintenance of ultra precision tolerances over challenging operational lifetimes. These IR sensors demand the use of reliable, closed loop, cryogenic refrigerators or active cryocoolers to meet stringent system acquisition and pointing requirements. The authors summarize some spacecraft cryocooler requirements and discuss their observations regarding Industry`s current production capabilities of cryocoolers. The results of the Lawrence Livermore National Laboratory (LLNL) Spacecraft Fabrication and Test (SF and T) MODIL`s Phase I producibility demonstration project are presented. The current project that involves LLNL and industrial participants is discussed.

  1. FLUORINE IN THE SOLAR NEIGHBORHOOD: IS IT ALL PRODUCED IN ASYMPTOTIC GIANT BRANCH STARS?

    SciTech Connect (OSTI)

    Jnsson, H.; Ryde, N. [Lund Observatory, Department of Astronomy and Theoretical Physics, Lund University, Box 43, SE-221 00 Lund (Sweden); Harper, G. M. [School of Physics, Trinity College, Dublin 2 (Ireland); Richter, M. J. [Physics Department, University of California, Davis, CA 95616 (United States); Hinkle, K. H., E-mail: henrikj@astro.lu.se [National Optical Astronomy Observatory, P.O. Box 26732, Tucson, AZ 85726 (United States)

    2014-07-10

    The origin of ''cosmic'' fluorine is uncertain, but there are three proposed production sites/mechanisms for the origin: asymptotic giant branch (AGB) stars, ? nucleosynthesis in Type II supernovae, and/or the winds of Wolf-Rayet stars. The relative importance of these production sites has not been established even for the solar neighborhood, leading to uncertainties in stellar evolution models of these stars as well as uncertainties in the chemical evolution models of stellar populations. We determine the fluorine and oxygen abundances in seven bright, nearby giants with well determined stellar parameters. We use the 2.3 ?m vibrational-rotational HF line and explore a pure rotational HF line at 12.2 ?m. The latter has never been used before for an abundance analysis. To be able to do this, we have calculated a line list for pure rotational HF lines. We find that the abundances derived from the two diagnostics agree. Our derived abundances are well reproduced by chemical evolution models including only fluorine production in AGB stars and, therefore, we draw the conclusion that this might be the main production site of fluorine in the solar neighborhood. Furthermore, we highlight the advantages of using the 12 ?m HF lines to determine the possible contribution of the ? process to the fluorine budget at low metallicities where the difference between models including and excluding this process is dramatic.

  2. Current Challenges in Commercially Producing Biofuels from Lignocellulosic

    Office of Scientific and Technical Information (OSTI)

    Biomass (Journal Article) | SciTech Connect Current Challenges in Commercially Producing Biofuels from Lignocellulosic Biomass Citation Details In-Document Search Title: Current Challenges in Commercially Producing Biofuels from Lignocellulosic Biomass Biofuels that are produced from biobased materials are a good alternative to petroleum based fuels. They offer several benefits to society and the environment. Producing second generation biofuels is even more challenging than producing first

  3. Methods for producing partially digested restriction DNA fragments and for producing a partially modified PCR product

    DOE Patents [OSTI]

    Wong, Kwong-Kwok (Richland, WA)

    2000-01-01

    The present invention is an improved method of making a partially modified PCR product from a DNA fragment with a polymerase chain reaction (PCR). In a standard PCR process, the DNA fragment is combined with starting deoxynucleoside triphosphates, a primer, a buffer and a DNA polymerase in a PCR mixture. The PCR mixture is then reacted in the PCR producing copies of the DNA fragment. The improvement of the present invention is adding an amount of a modifier at any step prior to completion of the PCR process thereby randomly and partially modifying the copies of the DNA fragment as a partially modified PCR product. The partially modified PCR product may then be digested with an enzyme that cuts the partially modified PCR product at unmodified sites thereby producing an array of DNA restriction fragments.

  4. Method for Producing Flame Retardant Porous Products and Products Produced Thereby

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame.

  5. Method for producing flame retardant porous products and products produced thereby

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame.

  6. Method for producing flame retardant porous products and products produced thereby

    DOE Patents [OSTI]

    Salyer, I.O.

    1998-08-04

    A method for fire retarding porous products used for thermal energy storage and products produced thereby is provided. The method includes treating the surface of the phase change material-containing porous products with a urea fire-retarding agent. Upon exposure to a flame, the urea forms an adduct with the phase change material which will not sustain combustion (is self-extinguishing) in air. No halogens or metal oxides are contained in the fire retardant, so no potentially noxious halide smoke or fumes are emitted if the product is continuously exposed to a flame. 1 fig.

  7. Lift producing device exhibiting low drag and reduced ventilation potential and method for producing the same

    DOE Patents [OSTI]

    Caldwell, Richard A. (115 Wimico Dr., Indian Harbour Beach, FL 32937)

    1991-01-01

    A lift producing device is disclosed which is adapted to be connected to a vehicle to provide lift to the vehicle when the vehicle is moved relative to a first fluid medium having a first density and viscosity and being in contact with a second fluid medium adjacent the vehicle. The second fluid medium has a second fluid density which is different from the first fluid density. The lift producing device comprises opposed first and second major surfaces joined at a longitudinally extending leading edge and at a longitudinally extending trailing edge, with at least a portion of the longitudinally extending leading edge being spaced from the longitudinally extending trailing edge by a predetermined mean chord length. When the vehicle is moved relative to the first fluid medium at a velocity within a range of predetermined velocities, with each of the velocities having a direction inclined from a plane extending through the leading edge and the trailing edge within a predetermined angular range, a region of high pressure is generated in the first fluid medium adjacent the first major surface and a region of low pressure is generated in the first fluid medium adjacent the second major surface. The lift producing device has a cross-sectional shape which will generate a pressure distribution around the device when the vehicle is moved relative to the first fluid medium at a velocity within the range of predetermined velocities such that the first fluid medium exhibits attached laminar flow along the device for a portion of the predetermined mean chord length from the leading edge to the trailing edge and will neither form a laminar separation bubble adjacent the second major surface of the device, nor exhibit turbulent separation adjacent the second major surface for substantially all of the predetermined mean chord length from the leading edge to the trailing edge. The portion along which attached laminar flow is maintained is the longest portion which will still fulfill the flow separation requirements. A method for producing the foil is also disclosed.

  8. SABIC's Carbon Fiber-Reinforced Material used to Produce the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SABIC's Carbon Fiber-Reinforced Material used to Produce the World's First 3D-Printed Vehicle at IMTS 2014 SABIC's Carbon Fiber-Reinforced Material used to Produce the World's ...

  9. Nebraska shows potential to produce biofuel crops | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    shows potential to produce biofuel crops Nebraska shows potential to produce biofuel crops December 9, 2009 - 11:12am Addthis Joshua DeLung What are the key facts? Utilizing sites ...

  10. NREL Updates Survey of Advanced Biofuel Producers in the United...

    Energy Savers [EERE]

    Updates Survey of Advanced Biofuel Producers in the United States NREL Updates Survey of Advanced Biofuel Producers in the United States March 16, 2016 - 2:23pm Addthis The ...

  11. Method for producing aldehyde from CO.sub.2

    DOE Patents [OSTI]

    Liao, James C.; Atsumi, Shota

    2015-09-29

    The invention provides recombinant microorganisms capable of producing isobutyraldehyde using CO.sub.2 as a carbon source. The invention further provides methods of preparing and using such microorganisms to produce isobutyraldehyde.

  12. Biofuel-Producing Lactobacillus Strain - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuel-Producing Lactobacillus Strain Great Lakes Bioenergy Research Center Contact GLBRC ... microorganisms typically considered for biofuel production, like Saccharomyces ...

  13. Thermochemical method for producing hydrogen from hydrogen sulfide

    SciTech Connect (OSTI)

    Herrington, D.R.

    1984-02-21

    Hydrogen is produced from hydrogen sulfide by a 3-step, thermochemical process comprising: (a) contacting hydrogen sulfide with carbon dioxide to form carbonyl sulfide and water, (b) contacting the carbonyl sulfide produced in (a) with oxygen to form carbon monoxide and sulfur dioxide, and (c) contacting the carbon monoxide produced in (b) with water to form carbon dioxide and hydrogen.

  14. Poster — Thur Eve — 64: Preliminary investigation of arc configurations for optimal sparing of normal tissue in hypofractionated stereotactic radiotherapy (HF-SRT) of multiple brain metastases using a 5mm interdigitating micro-multileaf collimator

    SciTech Connect (OSTI)

    Leavens, C; Wronski, M; Lee, YK; Ruschin, M; Soliman, H; Sahgal, A

    2014-08-15

    Purpose: To evaluate normal tissue sparing in intra-cranial HF-SRT, comparing various arc configurations with the Synergy Beam Modulator (SynBM) and Agility linacs, the latter incorporating leaf interdigitation and backup jaws. Methods: Five patients with multiple brain metastases (BMs), (5 BMs (n=2), 3 BMs (n=3)) treated with HF-SRT using 25 Gy (n=2) or 30 Gy (n=3) in 5 fractions, were investigated. Clinical treatment plans used the SynBM. Each patient was retrospectively re-planned on Agility, employing three planning strategies: (A) one isocenter and dedicated arc for each BM; (B) a single isocenter, centrally placed with respect to BMs; (C) the isocenter and arc configuration used in the SynBM plan, where closely spaced (<5cm) BMs used a dedicated isocenter and arcs. Agility plans were normalized for PTV coverage and heterogeneity. Results and Conclusion: Strategy A obtained the greatest improvements over the SynBM plan, where the maximum OAR dose, and mean dose to normal brain (averaged for all patients) were reduced by 55cGy and 25cGy, respectively. Strategy B was limited by having a single isocenter, hence less jaw shielding and increased MLC leakage. The maximum OAR dose was reduced by 13cGy, however mean dose to normal brain increased by 84cGy. Strategy C reduced the maximum OAR dose and mean dose to normal brain by 32cGy and 9cGy, respectively. The results from this study indicate that, for intra-cranial HF-SRT of multiple BMs, Agility plans are equal or better than SynBM plans. Further planning is needed to investigate dose sparing using Strategy A and the SynBM.

  15. Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom

    DOE Patents [OSTI]

    Kroeger, D.M.; Hsu, H.S.; Brynestad, J.

    1995-03-07

    Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600--1,000 C for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process. 3 figs.

  16. Method of producing Pb-stabilized superconductor precursors and method of producing superconductor articles therefrom

    DOE Patents [OSTI]

    Kroeger, Donald M. (Knoxville, TN); Hsu, Huey S. (Knoxville, TN); Brynestad, Jorulf (Oak Ridge, TN)

    1995-01-01

    Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600.degree.-1000.degree. C. for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process.

  17. Methods for Post Irradiation Examination of Tritium Producing Burnable

    Office of Environmental Management (EM)

    Absorber Rods | Department of Energy for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013. PDF icon Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods More Documents & Publications Design and Fabrication of In-Reactor Experiment to Measure

  18. Producing Beneficial Materials from Biomass and Biodiesel Byproducts -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Producing Beneficial Materials from Biomass and Biodiesel Byproducts Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryResearchers at Berkeley Lab have created a process to produce olefins from polyols that may be biomass derived. The team is also the first to introduce a method of producing high purity allyl alcohol at a large scale by

  19. Plasma Characteristics of the Discharge Produced during Mechanoluminescence

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Plasma Characteristics of the Discharge Produced during Mechanoluminescence Citation Details In-Document Search Title: Plasma Characteristics of the Discharge Produced during Mechanoluminescence The conditions during light emission from the fracture of solids have been difficult to determine because such mechanoluminescence (ML) is usually weak. When ML is produced by acoustic cavitation of a liquid slurry of resorcinol crystals, however, we observe bright

  20. Cost-Effective Enzyme for Producing Biofuels from Cellulosic Biomass -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Cost-Effective Enzyme for Producing Biofuels from Cellulosic Biomass Inventors: Ming Woei Lau, Bruce Dale Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing SummaryProducing biofuels from cellulosic materials, such as corn stalks, wood chips, and other biomass, requires the use of enzymes to degrade the cellulosic biomass into its molecular components. The cost to produce these enzymes is high, a factor contributing to the

  1. How Much Energy Does Your State Produce? | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Does Your State Produce? How Much Energy Does Your State Produce? November 10, 2014 - 2:52pm Addthis Energy Production in Trillion Btu: 2012 Click on each state to learn more about how much energy it produces Source: EIA State Energy Data Systems Daniel Wood Daniel Wood Data Visualization and Cartographic Specialist, Office of Public Affairs More Energy Maps Interested in learning more about national energy trends? Learn how much you spend on energy and how much energy you consume. Here

  2. Geothermal Energy Production with Co-produced and Geopressured Resources

    Office of Environmental Management (EM)

    (Fact Sheet), Geothermal Technologies Program (GTP) | Department of Energy Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) Geothermal Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) This fact sheet provides an overview of geothermal energy production using co-produced and geopressured resources. PDF icon low_temp_copro_fs.pdf More Documents & Publications

  3. Chapter 7 - Advancing Systems and Technologies to Produce Cleaner Fuels |

    Office of Environmental Management (EM)

    Department of Energy 7 - Advancing Systems and Technologies to Produce Cleaner Fuels Chapter 7 - Advancing Systems and Technologies to Produce Cleaner Fuels Chapter 7 - Advancing Systems and Technologies to Produce Cleaner Fuels Fuels play a critical role throughout our economy. In 2013, fuels directly supplied about 99% of the energy needed by our national transportation system, 66% of that needed to generate our electricity, 68% of that needed by our industry, and 27% of that needed by our

  4. Producing Linear Alpha Olefins From Biomass - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Producing Linear Alpha Olefins From Biomass Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Linear alpha olefins (LAOs) are...

  5. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  6. Scientists propose a solution to a critical barrier to producing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientists propose a solution to a critical barrier to producing fusion By John Greenwald ... solution to a mystery that has long baffled researchers working to harness fusion. ...

  7. Geothermal Energy Production with Co-produced and Geopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) Geothermal Energy Production with Co-produced and Geopressured Resources (Fact Sheet),...

  8. Spotlight on Austin, Texas: Best Offer Ever Produces 564 Upgrades...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Record Time Spotlight on Austin, Texas: Best Offer Ever Produces 564 Upgrades in Record Time This Better Buildings case study from April 2011 focuses on grantee partner Austin....

  9. Host cells and methods for producing isoprenyl alkanoates (Patent...

    Office of Scientific and Technical Information (OSTI)

    from the National Technical Information Service, Springfield, VA at www.ntis.gov. The invention provides for a method of producing an isoprenyl alkanoate in a genetically modified...

  10. Particle Gas Target for High Density Laser Produced Plasmas Charles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Particle Gas Target for High Density Laser Produced Plasmas Charles H. Skinner, Nathaniel Fisch, and Ernest Valeo This invention is a novel "particle gas" cell for achieving plasma...

  11. Low-Temperature and Co-Produced Resources Fact Sheet

    SciTech Connect (OSTI)

    Geothermal Technologies Office, U.S. Department of Energy

    2013-02-01

    This two-page Geothermal Technologies Office fact sheet provides an overview of low-temperature and co-produced resources. It includes technology benefits and project highlights.

  12. Developing County-level Water Footprints of Biofuel Produced...

    Office of Scientific and Technical Information (OSTI)

    Developing County-level Water Footprints of Biofuel Produced from Switchgrass and Miscanthus x Giganteus in the United States Citation Details In-Document Search Title: Developing...

  13. Supersonic Heat Wave Propagation in Laser-Produced Underdense...

    Office of Scientific and Technical Information (OSTI)

    Conference: Supersonic Heat Wave Propagation in Laser-Produced Underdense Plasma for Efficient X-Ray Generation Citation Details In-Document Search Title: Supersonic Heat Wave...

  14. Supersonic Heat Wave Propagation in Laser-Produced Underdense...

    Office of Scientific and Technical Information (OSTI)

    Supersonic Heat Wave Propagation in Laser-Produced Underdense Plasma for Efficient X-Ray Generation Citation Details In-Document Search Title: Supersonic Heat Wave Propagation in...

  15. Energy Department Announces $12 Million for Technologies to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    residues and woody biomass. Carbon fiber derived from biomass may be less costly to manufacture and offer greater environmental benefits than traditional carbon fiber produced...

  16. Developing County-level Water Footprints of Biofuel Produced...

    Office of Scientific and Technical Information (OSTI)

    Water Footprints of Biofuel Produced from Switchgrass and Miscanthus x Giganteus in the United States Citation Details In-Document Search Title: Developing County-level Water ...

  17. EERE Success Story-California: Agricultural Residues Produce...

    Energy Savers [EERE]

    technology is expected to produce biofuel that reduces greenhouse gas emissions by 80% compared to fossil fuel and help make California a leader in advanced biofuel production. ...

  18. Recoding of Bacterial Genome Produces Proteins with New Functions...

    Office of Science (SC) Website

    implications for engineering organisms to produce novel proteins that perform new functions needed in processes relevant to the DOE mission, including biofuel production. ...

  19. Table 4. Biodiesel producers and production capacity by state...

    U.S. Energy Information Administration (EIA) Indexed Site

    Biodiesel producers and production capacity by state, December 2015" "State","Number of ... Administration, Form EIA-22M ""Monthly Biodiesel Production Survey""" "U.S. Energy ...

  20. From Gasoline to Grassoline: Microbes Produce Fuels Directly from Biomass

    DOE R&D Accomplishments [OSTI]

    Yarris, Lynn

    2011-03-28

    A microbe that can produce an advanced biofuel directly from biomass was developed by researchers with the U.S. Department of Energy's Joint BioEnergy Institute.

  1. NREL Produces Ethylene via Photosynthesis (Fact Sheet), Highlights...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the National Renewable Energy Laboratory (NREL) have demonstrated a new way to use photosynthesis to produce ethylene. NREL scientists introduced a gene for ethylene forming enzyme...

  2. Evaluation of cirrus statistics produced by general circulation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cirrus statistics produced by general circulation models using ARM data Hartsock, Daniel University of Utah Mace, Gerald University of Utah Benson, Sally University of Utah...

  3. Theoretical minimum energies to produce steel for selected conditions

    SciTech Connect (OSTI)

    Fruehan, R. J.; Fortini, O.; Paxton, H. W.; Brindle, R.

    2000-03-01

    An ITP study has determined the theoretical minimum energy requirements for producing steel from ore, scrap, and direct reduced iron. Dr. Richard Fruehan's report, Theoretical Minimum Energies to Produce Steel for Selected Conditions, provides insight into the potential energy savings (and associated reductions in carbon dioxide emissions) for ironmaking, steelmaking, and rolling processes (PDF459 KB).

  4. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

    2001-01-01

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  5. Rotating superconductor magnet for producing rotating lobed magnetic field lines

    DOE Patents [OSTI]

    Hilal, Sadek K. (Englewood Cliffs, NJ); Sampson, William B. (Bellport, NY); Leonard, Edward F. (Leonia, NJ)

    1978-01-01

    This invention provides a rotating superconductor magnet for producing a rotating lobed magnetic field, comprising a cryostat; a superconducting magnet in the cryostat having a collar for producing a lobed magnetic field having oppositely directed adjacent field lines; rotatable support means for selectively rotating the superconductor magnet; and means for energizing the superconductor magnet.

  6. ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conditions, March 2000 | Department of Energy Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000 ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000 PDF icon theoretical_minimum_energies.pdf More Documents & Publications Ironmaking Process Alternatives Screening Study ITP Steel: Steel Industry Marginal Opportunity Study September 2005 ITP Steel: Steel Industry Energy Bandwidth Stu

  7. Producing Beneficial Materials from Biomass and Biodiesel Byproducts

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2010-02-02

    Researchers at Berkeley Lab have created a process to produce olefins from polyols that may be biomass derived. The team is also the first to introduce a method of producing high purity allyl alcohol at a large scale by using glycerol as the starting material instead propylene, a petroleum feedstock....

  8. 06-09-2010 NNSA-B-10-0111

    National Nuclear Security Administration (NNSA)

    1 Sandia National Laboratories/New Mexico (SNL/NM) proposes to use a technique called Gas Filter Correlation (GFC) radiometry (a remote sensing technique) to detect Hydrogen Fluoride (HF) gas in the troposphere. This research and development project would use gas cells containing HF gas as a differential spectroscopy standard, from which to compare a spectral measurement of the atmosphere. ✖ ✖ Sandia Site Office Hydrogen Fluoride Remote Sensing Sandia National Laboratories - New Mexico

  9. Produced Water Treatment Using Microbial Fuel Cell Technology

    SciTech Connect (OSTI)

    Borole, A. P.; Campbell, R.

    2011-05-20

    ORNL has developed a treatment for produced water using a combination of microbial fuel cells and electrosorption. A collaboration between Campbell Applied Physics and ORNL was initiated to further investigate development of the technology and apply it to treatment of field produced water. The project successfully demonstrated the potential of microbial fuel cells to generate electricity from organics in produced water. A steady voltage was continuously generated for several days using the system developed in this study. In addition to the extraction of electrical energy from the organic contaminants, use of the energy at the representative voltage was demonstrated for salts removal or desalination of the produced water. Thus, the technology has potential to remove organic as well as ionic contaminants with minimal energy input using this technology. This is a novel energy-efficient method to treat produced water. Funding to test the technology at larger scale is being pursued to enable application development.

  10. Quantum-splitting oxide-based phosphors and method of producing the same

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Srivastava, Alok Mani

    2003-09-02

    Strontium, calcium, strontium calcium, strontium calcium magnesium, calcium magnesium aluminates, and strontium borates activated with Pr.sup.3+ exhibit characteristics of quantum-splitting phosphors under VUV excitation. A large emission peak at about 405 nm under VUV excitation is used conveniently to identify quantum-splitting phosphors. Improvements may be achieved with addition of fluorides or boric acid as a flux during the preparation of the phosphors. It is also possible to predict improvement in quantum efficiency by observing the ratio of emission intensities at about 480 nm and about 610 nm.

  11. Produced water volumes and management practices in the United States.

    SciTech Connect (OSTI)

    Clark, C. E.; Veil, J. A.

    2009-09-01

    Produced water volume generation and management in the United States are not well characterized at a national level. The U.S. Department of Energy (DOE) asked Argonne National Laboratory to compile data on produced water associated with oil and gas production to better understand the production volumes and management of this water. The purpose of this report is to improve understanding of produced water by providing detailed information on the volume of produced water generated in the United States and the ways in which produced water is disposed or reused. As the demand for fresh water resources increases, with no concomitant increase in surface or ground water supplies, alternate water sources, like produced water, may play an important role. Produced water is water from underground formations that is brought to the surface during oil or gas production. Because the water has been in contact with hydrocarbon-bearing formations, it contains some of the chemical characteristics of the formations and the hydrocarbons. It may include water from the reservoir, water previously injected into the formation, and any chemicals added during the production processes. The physical and chemical properties of produced water vary considerably depending on the geographic location of the field, the geologic formation, and the type of hydrocarbon product being produced. Produced water properties and volume also vary throughout the lifetime of a reservoir. Produced water is the largest volume by-product or waste stream associated with oil and gas exploration and production. Previous national produced water volume estimates are in the range of 15 to 20 billion barrels (bbl; 1 bbl = 42 U.S. gallons) generated each year in the United States (API 1988, 2000; Veil et al. 2004). However, the details on generation and management of produced water are not well understood on a national scale. Argonne National Laboratory developed detailed national-level information on the volume of produced water generated in the United States and the manner in which produced water is managed. This report presents an overview of produced water, summarizes the study, and presents results from the study at both the national level and the state level. Chapter 2 presents background information on produced water, describing its chemical and physical characteristics, where it is produced, and the potential impacts of produced water to the environment and to oil and gas operations. A review of relevant literature is also included. Chapter 3 describes the methods used to collect information, including outreach efforts to state oil and gas agencies and related federal programs. Because of the inconsistency in the level of detail provided by various state agencies, the approaches and assumptions used to extrapolate data values are also discussed. In Chapter 4, the data are presented, and national trends and observations are discussed. Chapter 5 presents detailed results for each state, while Chapter 6 presents results from federal sources for oil and gas production (i.e., offshore, onshore, and tribal lands). Chapter 7 summarizes the study and presents conclusions.

  12. Evaluation of DUF{sub 6}-G-Q-STU-001 (ALARA analysis supporting approval of authorized limits).

    SciTech Connect (OSTI)

    Ranek, N. L.; Croff, A. G.; Cheng, J.-J.; Gillette, J. L.; Avci, H. I.

    2004-06-29

    The U.S. Department of Energy (DOE) has selected Uranium Disposition Services, LLC (UDS) to proceed with disposition of the inventory of depleted uranium hexafluoride (DUF{sub 6}) for which DOE has management responsibility. To accomplish this task, UDS will construct and operate facilities at two DOE-owned sites, one near Paducah, Kentucky, and another near Portsmouth, Ohio, to convert DUF{sub 6} to uranium oxide (principally U{sub 3}O{sub 8}). The off-gas treatment system for the conversion process will produce aqueous hydrogen fluoride (AqHF), also known as hydrofluoric acid, and a relatively small amount of calcium fluoride (CaF{sub 2}), each containing some residual radioactive material. As part of its contractual charge, UDS must identify and implement a disposition for all three products generated by the DUF{sub 6} conversion facilities: uranium oxide, AqHF, and CaF{sub 2}. The UDS DUF{sub 6} Conversion Product Management Plan (DUF{sub 6}-UDS-PLN-004, September 2003) concludes that a viable commercial market exists for AqHF, which, if not sold, would have to be neutralized, producing a relatively large quantity of additional CaF{sub 2}. Although CaF{sub 2} has very limited market potential, there is some possibility that it also could be sold. If these potential markets could be developed, DOE would save the costs of neutralizing AqHF and/or disposing of the CaF{sub 2} neutralization product. Accordingly, UDS has decided to seek approval from DOE for unrestricted release of both AqHF and CaF{sub 2} that would be generated if AqHF could not be sold or if sales were interrupted. If AqHF were sold, the relatively small quantity of CaF{sub 2} still being generated by the DUF{sub 6} conversion process off-gas treatment system would most likely be disposed of as waste. The main product of conversion, depleted uranium oxide, will be reused to the extent possible or disposed of as waste, if no practical reuse option is found.

  13. Energy efficient microwave synthesis of mesoporous Ce0.5M0.5O2 (Ti, Zr, Hf) nanoparticles for low temperature CO oxidation in an ionic liquid – a comparative study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alammar, Tarek; Chow, Ying -Kit; Mudring, Anja -Verena

    2014-11-19

    Ce0.5M0.5O2 (M = Ti, Zr, Hf) nanoparticles have been successfully synthesized by microwave irradiation in the ionic liquid [C4mim][Tf2N] (1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide). The morphology, crystallinity, and chemical composition of the obtained materials were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), Raman spectroscopy, and N2–adsorption measurements. XRD and Raman spectroscopy analyses confirmed the formation of solid solutions with cubic fluorite structure. The catalytic activities of the Ce0.5M0.5O2 (M = Ti, Zr, Hf) nanoparticles were investigated in the low-temperature oxidation of CO. Ce0.5Zr0.5O2 nanospheres exhibit the best performance (100% conversion at 350 °C), followed by Ce0.5Hf0.5O2more » (55% conversion at 360 °C) and Ce0.5Ti0.5O2 (11% conversion at 350 °C). Heating the as-prepared Ce0.5Zr0.5O2 to 600 °C for extended time leads to a decrease in surface area and, as expected decreased catalytic activity. Depending on the ionic liquid the obtained Ce0.5Zr0.5O2 exhibits different morphologies, varying from nano-spheres in [C4mim][Tf2N] and [P66614][Tf2N] (P66614 = trishexyltetradecylphosphonium) to sheet-like assemblies in [C3mimOH][Tf2N] (C3mimOH = 1-(3-hydroxypropyl)-3-methylimidazolium). As a result, the microwave synthesis superiority to other heating methods like sonochemical synthesis and conventional heating was proven by comparative experiments where the catalytic activity of Ce0.5Zr0.5O2 obtained by alternate methods such as conventional heating was found to be poorer than that of the microwave-synthesised material.« less

  14. Treating and Reusing Produced Water | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at OGTC Seek Sustainable Produced Water Management Solutions Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Researchers at OGTC Seek Sustainable Produced Water Management Solutions Raymond Murphy 2015.04.28 Each year the US oil and gas industry generates around one trillion gallons of produced water as a byproduct of

  15. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX); Munsterman, Erwin Henh (Amsterdam, NL); Van Bergen, Petrus Franciscus (Amsterdam, NL); Van Den Berg, Franciscus Gondulfus Antonius (Amsterdam, NL)

    2009-10-20

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  16. Producing a trimethylpentanoic acid using hybrid polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2014-10-07

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing trimethylpentanoic acid. The present invention also provides for a host cell comprising the PKS and when cultured produces the trimethylpentanoic acid. The present invention also provides for a method of producing the trimethylpentanoic acid, comprising: providing a host cell of the present invention, and culturing said host cell in a suitable culture medium such that the trimethylpentanoic acid is produced, optionally isolating the trimethylpentanoic acid, and optionally, reducing the isolated trimethylpentanoic acid into a trimethylpentanol or an iso-octane.

  17. Produced Water R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale Gas » Produced Water R&D Produced Water R&D Developed as a result of lessons learned from the NETL funded demonstration project, the Altela 600 water treatment system (shown above) treats about 25,000 gallons per day of produced and flowback water from hydraulic fracturing. [Photo courtesy of Altela Inc.] Developed as a result of lessons learned from the NETL funded demonstration project, the Altela 600 water treatment system (shown above) treats about 25,000 gallons per day of

  18. VAPOR PRESSURES OF THE RUBIDIUM FLUORIDE-ZIRCONIUM FLUORIDE AND...

    Office of Scientific and Technical Information (OSTI)

    Have feedback or suggestions for a way to improve these results? Save Share this Record Citation Formats MLA APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Save to My ...

  19. Search for a standard model Higgs boson produced in association...

    Office of Scientific and Technical Information (OSTI)

    Search for a standard model Higgs boson produced in association with a top-quark pair and decaying to bottom quarks using a matrix element method Title: Search for a standard model...

  20. Search for a standard model Higgs boson produced in association...

    Office of Scientific and Technical Information (OSTI)

    standard model Higgs boson produced in association with a top-quark pair and decaying to bottom quarks using a matrix element method Khachatryan, V. Yerevan Physics Inst. (YerPhI)...

  1. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2012 ii This report...

  2. Reaction of Aluminum with Water to Produce Hydrogen: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A Study of...

  3. Performance profiles of major energy producers 1995, January 1997

    SciTech Connect (OSTI)

    1997-02-01

    This publication examines developments in the operations of the major U.S. energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area.

  4. Chelan County PUD - Sustainable Natural Alternative Power Producers...

    Broader source: Energy.gov (indexed) [DOE]

    on the system's production. The PUD distributes SNAP payments annually, on or around Earth Day. The amount paid per kilowatt-hour (kWh) to SNAP Producers is determined by...

  5. Process for producing peracids from aliphatic hydroxy carboxylic acids

    DOE Patents [OSTI]

    Chum, H.L.; Palasz, P.D.; Ratcliff, M.A.

    1984-12-20

    A process is described for producing peracids from lactic acid-containing solutions derived from biomass processing systems. It consists of adjusting the pH of the solution to about 8 to 9 and removing alkaline residue fractions therefrom to form a solution comprised substantially of lower aliphatic hydroxy acids. The solution is oxidized to produce volatile lower aliphatic aldehydes. The aldehydes are removed as they are generated and converted to peracids.

  6. Method for producing hydrogen and oxygen by use of algae

    DOE Patents [OSTI]

    Greenbaum, E.

    1982-06-16

    Efficiency of process for producing H/sub 2/ by subjecting algae in an aqueous phase to light irradiation is increased by culturing algae which has been bleached during a first period of irradiation in a culture medium in an aerobic atmosphere until it has regained color and then subjecting this algae to a second period of irradiation wherein hydrogen is produced at an enhanced rate.

  7. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Wednesday, 27 June 2012 00:00 Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough,

  8. Host cells and methods for producing isoprenyl alkanoates

    DOE Patents [OSTI]

    Lee, Taek Soon; Fortman, Jeffrey L.; Keasling, Jay D.

    2015-12-01

    The invention provides for a method of producing an isoprenyl alkanoate in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses an enzyme capable of catalyzing the esterification of an isoprenol and a straight-chain fatty acid, such as an alcohol acetyltransferase (AAT), wax ester synthase/diacylglycerol acyltransferase (WS/DGAT) or lipase, under a suitable condition so that the isoprenyl alkanoate is produced.

  9. Identification and Characterization of Non-Cellulose-Producing Mutants of

    Office of Scientific and Technical Information (OSTI)

    Gluconacetobacter hansenii Generated by Tn5 Transposon Mutagenesis (Journal Article) | SciTech Connect Identification and Characterization of Non-Cellulose-Producing Mutants of Gluconacetobacter hansenii Generated by Tn5 Transposon Mutagenesis Citation Details In-Document Search Title: Identification and Characterization of Non-Cellulose-Producing Mutants of Gluconacetobacter hansenii Generated by Tn5 Transposon Mutagenesis Authors: Deng, Ying ; Nagachar, Nivedita ; Xiao, Chaowen ; Tien,

  10. Methods for producing and using densified biomass products containing

    Office of Scientific and Technical Information (OSTI)

    pretreated biomass fibers (Patent) | SciTech Connect Methods for producing and using densified biomass products containing pretreated biomass fibers Citation Details In-Document Search Title: Methods for producing and using densified biomass products containing pretreated biomass fibers A process is provided comprising subjecting a quantity of plant biomass fibers to a pretreatment to cause at least a portion of lignin contained within each fiber to move to an outer surface of said fiber,

  11. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, M.; Ruckman, M.; Strongin, D.

    1994-04-26

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate. 4 figures.

  12. Method for producing hydrogen and oxygen by use of algae

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1984-01-01

    Efficiency of process for producing H.sub.2 by subjecting algae in an aqueous phase to light irradiation is increased by culturing algae which has been bleached during a first period of irradiation in a culture medium in an aerobic atmosphere until it has regained color and then subjecting this algae to a second period of irradiation wherein hydrogen is produced at an enhanced rate.

  13. Developing County-level Water Footprints of Biofuel Produced from

    Office of Scientific and Technical Information (OSTI)

    Switchgrass and Miscanthus x Giganteus in the United States (Technical Report) | SciTech Connect Technical Report: Developing County-level Water Footprints of Biofuel Produced from Switchgrass and Miscanthus x Giganteus in the United States Citation Details In-Document Search Title: Developing County-level Water Footprints of Biofuel Produced from Switchgrass and Miscanthus x Giganteus in the United States Authors: Wu, May M. [1] ; Chiu, Yi-Wen [1] + Show Author Affiliations Argonne National

  14. FINDING TRACERS FOR SUPERNOVA PRODUCED {sup 26}Al (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect FINDING TRACERS FOR SUPERNOVA PRODUCED {sup 26}Al Citation Details In-Document Search Title: FINDING TRACERS FOR SUPERNOVA PRODUCED {sup 26}Al We consider the cospatial production of elements in supernova explosions to find observationally detectable proxies for enhancement of {sup 26}Al in supernova ejecta and stellar systems. Using four progenitors, we explore a range of one-dimensional explosions at different energies and an asymmetric three-dimensional explosion. We find

  15. Towards a Computational Model of a Methane Producing Archaeum (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: Towards a Computational Model of a Methane Producing Archaeum Citation Details In-Document Search Title: Towards a Computational Model of a Methane Producing Archaeum Authors: Peterson, Joseph R. ; Labhsetwar, Piyush Search SciTech Connect for author "Labhsetwar, Piyush" Search SciTech Connect for ORCID "0000000159333609" Search orcid.org for ORCID "0000000159333609" ; Ellermeier, Jeremy

  16. Valuable Chemical Produced from Renewables Instead of Petroleum |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Valuable Chemical Produced from Renewables Instead of Petroleum Valuable Chemical Produced from Renewables Instead of Petroleum March 11, 2015 - 11:04am Addthis Fermenter used in the scale-up of malonic acid.| Photo courtesy of Roy Kaltschmidt/Berkeley Lab Fermenter used in the scale-up of malonic acid.| Photo courtesy of Roy Kaltschmidt/Berkeley Lab Researchers at Lygos, Inc., an industrial biotechnology company, achieved a critical breakthrough in the cleaner

  17. Directed Evolution of Microbe Producing Biofuels Using in Vivo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transcription Factor Based Biosensors - Energy Innovation Portal Directed Evolution of Microbe Producing Biofuels Using in Vivo Transcription Factor Based Biosensors Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryResearchers at the Joint BioEnergy Institute (JBEI) have invented a method of using transcription factors expressed in vivo to evolve, screen, and select for microorganisms producing an intracellular small molecule of interest,

  18. Carbon Films Produced from Ionic Liquid Precursors - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Carbon Films Produced from Ionic Liquid Precursors Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryResearchers at ORNL have invented a more effective method of preparing thin carbons films, a material that has become increasing important to the development of energy-saving storage batteries. Using this new method, it is possible to produce a very resilient, thermally stable porous carbon film characterized by a highly ordered arrangement of

  19. Co-cultured Synechococcus and Shewanella Produce Hydrocarbons without

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cellulosic Feedstock - Energy Innovation Portal Co-cultured Synechococcus and Shewanella Produce Hydrocarbons without Cellulosic Feedstock DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology <span id="Caption"><span id="ctl00_MainContentHolder_zoomimage_defaultCaption">Shewanella Oneidensis naturally produces hydrocarbons without cellulosic feedstock.</span></span> Shewanella Oneidensis naturally

  20. NREL Produces Ethylene via Photosynthesis - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Produces Ethylene via Photosynthesis Environmentally-friendly process offers intriguing alternative to fossil-fuel based ethylene for chemicals and transportation fuels September 25, 2012 Scientists at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) have demonstrated a better way to use photosynthesis to produce ethylene, a breakthrough that could change the way materials, chemicals, and transportation fuels are made, and help clean the air. NREL scientists introduced

  1. NREL Scientists Report First Solar Cell Producing More Electrons In

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photocurrent Than Solar Photons Entering Cell - News Releases | NREL Scientists Report First Solar Cell Producing More Electrons In Photocurrent Than Solar Photons Entering Cell December 15, 2011 Researchers from the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) have reported the first solar cell that produces a photocurrent that has an external quantum efficiency greater than 100 percent when photoexcited with photons from the high energy region of the solar

  2. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major quantities of a new cancer-treatment agent, actinium 225 (Ac-225). April 11, 2012 Los Alamos scientist Meiring Nortier holds a thorium foil test target for the proof-of-concept production experiments. Los Alamos scientist Meiring Nortier holds a thorium foil test target for the proof-of-concept production experiments.

  3. Process for producing peracids from aliphatic hydroxy carboxylic acids

    DOE Patents [OSTI]

    Chum, Helena L. (Arvada, CO); Ratcliff, Matthew A. (Lakewood, CO); Palasz, Peter D. (Lakewood, CO)

    1986-01-01

    A process for producing peracids from lactic acid-containing solutions derived from biomass processing systems comprising: adjusting the pH of the solution to about 8-9 and removing alkaline residue fractions therefrom to form a solution comprised substantially of lower aliphatic hydroxy acids; oxidizing the solution to produce volatile lower aliphatic aldehydes; removing said aldehydes as they are generated; and converting said aldehydes to peracids.

  4. Energy Department Announces $10 Million for Technologies to Produce

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Biofuel Products from Biomass | Department of Energy Technologies to Produce Advanced Biofuel Products from Biomass Energy Department Announces $10 Million for Technologies to Produce Advanced Biofuel Products from Biomass April 15, 2014 - 12:44pm Addthis The Energy Department today announced up to $10 million in funding to advance the production of advanced biofuels, substitutes for petroleum-based feedstocks, and bioproducts made from renewable, non-food-based biomass, such as

  5. Energy Department Announces $12 Million for Technologies to Produce

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Carbon Fiber from Biomass | Department of Energy Announces $12 Million for Technologies to Produce Renewable Carbon Fiber from Biomass Energy Department Announces $12 Million for Technologies to Produce Renewable Carbon Fiber from Biomass February 3, 2014 - 11:34am Addthis The Energy Department today announced up to $12 million in funding to advance the production of cost-competitive, high-performance carbon fiber material from renewable non-food-based feedstocks such as

  6. Towards a Computational Model of a Methane Producing Archaeum (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | DOE PAGES Towards a Computational Model of a Methane Producing Archaeum Title: Towards a Computational Model of a Methane Producing Archaeum Authors: Peterson, Joseph R. ; Labhsetwar, Piyush Search DOE PAGES for author "Labhsetwar, Piyush" Search DOE PAGES for ORCID "0000000159333609" Search orcid.org for ORCID "0000000159333609" ; Ellermeier, Jeremy R. ; Kohler, Petra R. A. ; Jain, Ankur Search DOE PAGES for author "Jain, Ankur" Search DOE

  7. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, Myron (Center Moriches, NY); Ruckman, Mark (Middle Island, NY); Strongin, Daniel (Port Jefferson, NY)

    1994-01-01

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate.

  8. Microbes Produce High Yields of Fatty Alcohols From Glucose - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Microbes Produce High Yields of Fatty Alcohols From Glucose Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Fatty alcohols are used in detergents, emulsifiers, lubricants and personal care items. More than 1.3 million tons of fatty alcohols are used worldwide each year, representing a $3 billion market. Currently, fatty alcohols are produced either through the processing of natural fats and oils or from petrochemicals.

  9. Method to produce large, uniform hollow spherical shells

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA)

    1985-01-01

    Large, uniform hollow spherical shells are produced by forming uniform size drops of heat decomposable or vaporizable material, evaporating the drops to form dried particles, coating the dried particles with a layer of shell forming material, and heating the composite particles to melt the outer layer and decompose or vaporize the inner particle to form an expanding inner gas bubble which expands the outer layer. By cycling the temperature and pressure on the hollow shells, spherical shells with uniform walls are produced.

  10. Producing a High Impact Technology | Department of Energy

    Energy Savers [EERE]

    Producing a High Impact Technology Producing a High Impact Technology November 3, 2015 - 2:43pm Addthis Amy Jiron Amy Jiron Technology Manager, Building Technologies Office The spectrum of commercial building efficiency technologies is large. Opportunities to save cost and energy diverge across market sectors, types, by systems and application, based on programming and occupant behavior and organizational mission. Fortunately, the Commercial Buildings Energy Consumption Survey (CBECS) provides a

  11. California: Agricultural Residues Produce Renewable Fuel | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Agricultural Residues Produce Renewable Fuel California: Agricultural Residues Produce Renewable Fuel April 18, 2013 - 12:00am Addthis Logos Technologies and EERE partnered with EdeniQ of Visalia, California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover (leaves and stalks), as well as other California-sourced indigenous, nonfood feedstock sources (wood chips and switchgrass). The project has completed 1,500 hours of

  12. Calpine: America's largest geothermal energy producer | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Calpine: America's largest geothermal energy producer Calpine: America's largest geothermal energy producer October 6, 2010 - 12:37pm Addthis Calpine operates 15 plants at The Geysers in northwest California, which generate enough clean energy daily to power a city the size of San Francisco.| Photo Courtesy of Calpine Calpine operates 15 plants at The Geysers in northwest California, which generate enough clean energy daily to power a city the size of San Francisco.| Photo Courtesy of

  13. Florida Project Produces Nation's First Cellulosic Ethanol at

    Office of Environmental Management (EM)

    Commercial-Scale | Department of Energy Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale July 31, 2013 - 1:37pm Addthis News Media Contact (202) 586-4940 WASHINGTON - The Energy Department today recognized the nation's first commercial-scale cellulosic ethanol production at INEOS Bio's Indian River BioEnergy Center in Vero Beach, Florida. Developed through a joint venture between

  14. Chapter 7: Advancing Systems and Technologies to Produce Cleaner Fuels

    Office of Environmental Management (EM)

    7: Advancing Systems and Technologies to Produce Cleaner Fuels September 2015 Quadrennial Technology Review 7 Advancing Systems and Technologies to Produce Cleaner Fuels Issues and RDD&D Opportunities  Fossil fuels account for 82% of total U.S. primary energy use.  Each fuel has strengths and weaknesses in relation to energy security, economic competitiveness, and environmental responsibility identified in Chapter 1.  Low-cost fuels can contribute to economic prosperity. Oil and gas

  15. City in Colorado Fueling Vehicles with Gas Produced from Wastewater

    Office of Environmental Management (EM)

    Treatment Facility | Department of Energy City in Colorado Fueling Vehicles with Gas Produced from Wastewater Treatment Facility City in Colorado Fueling Vehicles with Gas Produced from Wastewater Treatment Facility April 29, 2015 - 6:05pm Addthis Grand Junction's CNG station fuels the city's fleets and county buses and is available to fuel public vehicles as well. Pictured above, a Grand Valley Transit bus is preparing to refuel. Grand Junction's CNG station fuels the city's fleets and

  16. Produced water radionuclide hazard/risk assessment, Phase 1

    SciTech Connect (OSTI)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-06-01

    Petroleum production may be accompanied by the production of saline water, called ``produced water.`` Produced water discharged into freshwater streams, estuaries, coastal and outer continental shelf waters can contained enhanced levels of radium isotopes. This document reports on the first phase of a study to estimate the risk to human health and the environment from radium discharged in produced water. The study involved five major steps: (1) evaluate the usefulness of available produced water outfall data for developing estimates of radium environmental concentrations; (2) review the literature on the bioaccumulation of radium by aquatic organism; (3) review the literature on the effects of radiation on aquatic organisms; (4) review the information available concerning the human health risks associated with exposure to Ra-226 and Ra-228 and (5) perform a conservative, screening-level assessment of the health and environmental risks posed by Ra-226 and Ra-228 discharged in produced waters. A screening-level analysis was performed to determine whether radium discharged to coastal Louisiana in produced waters presents potential health or environmental risks requiring further study. This conservative assessment suggested that no detectable impact on populations of fish, molluscs or crustaceans from radium discharged in produced waters is likely. The analysis also suggested that there is a potential for risk were an individual to ingest a large amount of seafood harvested near a produced water discharge point over a lifetime. The number of excess cancers predicted per year under a conservative scenario is comparable to those expected to result from background concentrations of radium.

  17. Produced water radionuclide hazard/risk assessment, Phase 1

    SciTech Connect (OSTI)

    Hamilton, L.D.; Meinhold, A.F.; Nagy, J.

    1991-06-01

    Petroleum production may be accompanied by the production of saline water, called produced water.'' Produced water discharged into freshwater streams, estuaries, coastal and outer continental shelf waters can contained enhanced levels of radium isotopes. This document reports on the first phase of a study to estimate the risk to human health and the environment from radium discharged in produced water. The study involved five major steps: (1) evaluate the usefulness of available produced water outfall data for developing estimates of radium environmental concentrations; (2) review the literature on the bioaccumulation of radium by aquatic organism; (3) review the literature on the effects of radiation on aquatic organisms; (4) review the information available concerning the human health risks associated with exposure to Ra-226 and Ra-228 and (5) perform a conservative, screening-level assessment of the health and environmental risks posed by Ra-226 and Ra-228 discharged in produced waters. A screening-level analysis was performed to determine whether radium discharged to coastal Louisiana in produced waters presents potential health or environmental risks requiring further study. This conservative assessment suggested that no detectable impact on populations of fish, molluscs or crustaceans from radium discharged in produced waters is likely. The analysis also suggested that there is a potential for risk were an individual to ingest a large amount of seafood harvested near a produced water discharge point over a lifetime. The number of excess cancers predicted per year under a conservative scenario is comparable to those expected to result from background concentrations of radium.

  18. NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol

    Office of Environmental Management (EM)

    from Algae | Department of Energy NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 - 5:07pm Addthis A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) with funding from the U.S. Department of Energy's Bioenergy Technologies Office (BETO) has proven to be significantly more effective at

  19. DOE's Early Investment in Shale Gas Technology Producing Results Today |

    Office of Environmental Management (EM)

    Department of Energy Early Investment in Shale Gas Technology Producing Results Today DOE's Early Investment in Shale Gas Technology Producing Results Today February 2, 2011 - 12:00pm Addthis Washington, DC - A $92 million research investment in the 1970s by the U.S. Department of Energy (DOE) is today being credited with technological contributions that have stimulated development of domestic natural gas from shales. The result: more U.S. jobs, increased energy security, and higher revenues

  20. EERE Success Story-California: Agricultural Residues Produce Renewable

    Office of Environmental Management (EM)

    Fuel | Department of Energy Agricultural Residues Produce Renewable Fuel EERE Success Story-California: Agricultural Residues Produce Renewable Fuel April 18, 2013 - 12:00am Addthis Logos Technologies and EERE partnered with EdeniQ of Visalia, California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover (leaves and stalks), as well as other California-sourced indigenous, nonfood feedstock sources (wood chips and switchgrass). The

  1. First-principles studies of structural stabilities and enthalpies of formation of refractory intermetallics: TM and TM3 (T = Ti, Zr, Hf; M = Ru, Rh, Pd, Os, Ir, Pt)

    SciTech Connect (OSTI)

    Xing, Weiwei; Chen, X.; Li, Dianzhong; Li, Y. Y.; Fu, Chong Long; Meschel, S.

    2012-01-01

    Using first-principles local density functional approach, we have calculated the ground-state structural phase stabilities and enthalpies of formation of thirty-six binary transition-metal refractory TM and TM3 compounds formed by Group IV elements T (T = Ti, Zr, Hf) and platinum group elements M (M = Ru, Rh, Pd, Os, Ir, Pt) . We compared our results with the available experimental data and found good agreement between theory and experiment in both the trends of structural stabilities and the magnitudes of formation enthalpies. Moreover, based on our calculated results, an empirical relationship between cohesive energies ( E) and melting temperatures (Tm) was derived as Tm = 0.0292 E/kB (where kB is the Boltzmann constant) for both TM and TM3 compounds.

  2. Sub-250?nm low-threshold deep-ultraviolet AlGaN-based heterostructure laser employing HfO{sub 2}/SiO{sub 2} dielectric mirrors

    SciTech Connect (OSTI)

    Kao, Tsung-Ting; Liu, Yuh-Shiuan; Mahbub Satter, Md.; Li, Xiao-Hang; Lochner, Zachary; Douglas Yoder, P.; Detchprohm, Theeradetch; Dupuis, Russell D.; Shen, Shyh-Chiang Ryou, Jae-Hyun; Fischer, Alec M.; Wei, Yong; Xie, Hongen; Ponce, Fernando A.

    2013-11-18

    We report a sub-250-nm, optically pumped, deep-ultraviolet laser using an Al{sub x}Ga{sub 1?x}N-based multi-quantum-well structure grown on a bulk Al-polar c-plane AlN substrate. TE-polarization-dominant lasing action was observed at room temperature with a threshold pumping power density of 250?kW/cm{sup 2}. After employing high-reflectivity SiO{sub 2}/HfO{sub 2} dielectric mirrors on both facets, the threshold pumping power density was further reduced to 180?kW/cm{sup 2}. The internal loss and threshold modal gain can be calculated as 2?cm{sup ?1} and 10.9?cm{sup ?1}, respectively.

  3. Assessment of produced water contaminated soils to determine remediation requirements

    SciTech Connect (OSTI)

    Clodfelter, C.

    1995-12-31

    Produced water and drilling fluids can impact the agricultural properties of soil and result in potential regulatory and legal liabilities. Produced water typically is classified as saline or a brine and affects surface soils by increasing the sodium and chloride content. Sources of produced water which can lead to problems include spills from flowlines and tank batteries, permitted surface water discharges and pit areas, particularly the larger pits including reserve pits, emergency pits and saltwater disposal pits. Methods to assess produced water spills include soil sampling with various chemical analyses and surface geophysical methods. A variety of laboratory analytical methods are available for soil assessment which include electrical conductivity, sodium adsorption ratio, cation exchange capacity, exchangeable sodium percent and others. Limiting the list of analytical parameters to reduce cost and still obtain the data necessary to assess the extent of contamination and determine remediation requirements can be difficult. The advantage to using analytical techniques is that often regulatory remediation standards are tied to soil properties determined from laboratory analysis. Surface geophysical techniques can be an inexpensive method to rapidly determine the extent and relative magnitude of saline soils. Data interpretations can also provide an indication of the horizontal as well as the vertical extent of impacted soils. The following discussion focuses on produced water spills on soil and assessment of the impacted soil. Produced water typically contains dissolved hydrocarbons which are not addressed in this discussion.

  4. Scintillator materials containing lanthanum fluorides

    DOE Patents [OSTI]

    Moses, W.W.

    1991-05-14

    An improved radiation detector containing a crystalline mixture of LaF[sub 3] and CeF[sub 3] as the scintillator element is disclosed. Scintillators made with from 25% to 99.5% LaF[sub 3] and the remainder CeF[sub 3] have been found to provide a balance of good stopping power, high light yield and short decay constant that is equal to or superior to other known scintillator materials, and which may be processed from natural starting materials containing both rare earth elements. The radiation detectors disclosed are favorably suited for use in general purpose detection and in positron emission tomography. 2 figures.

  5. Scintillator materials containing lanthanum fluorides

    DOE Patents [OSTI]

    Moses, William W. (Berkeley, CA)

    1991-01-01

    An improved radiation detector containing a crystalline mixture of LaF.sub.3 and CeF.sub.3 as the scintillator element is disclosed. Scintillators made with from 25% to 99.5% LaF.sub.3 and the remainder CeF.sub.3 have been found to provide a balance of good stopping power, high light yield and short decay constant that is equal to or superior to other known scintillator materials, and which may be processed from natural starting materials containing both rare earth elements. The radiation detectors disclosed are favorably suited for use in general purpose detection and in positron emission tomography.

  6. Geothermal Produced Fluids: Characteristics, Treatment Technologies, and Management Options

    SciTech Connect (OSTI)

    Finster, Molly; Clark, Corrie; Schroeder, Jenna; Martino, Louis

    2015-10-01

    Geothermal power plants use geothermal fluids as a resource and create waste residuals as part of the power generation process. Both the geofluid resource and the waste stream are considered produced fluids. The chemical and physical nature of produced fluids can have a major impact on the geothermal power industry and can influence the feasibility of geothermal power development, exploration approaches, power plant design, operating practices, and the reuse or disposal of residuals. In general, produced fluids include anything that comes out of a geothermal field and that subsequently must be managed on the surface. These fluids vary greatly depending on the geothermal reservoir being harnessed, power plant design, and the life cycle stage in which the fluid exists, but generally include water and fluids used to drill geothermal wells, fluids used to stimulate wells in enhanced geothermal systems, and makeup and/or cooling water used during operation of a geothermal power plant. Additional geothermal-related produced fluids include many substances that are similar to waste streams from the oil and gas industry, such as scale, flash tank solids, precipitated solids from brine treatment, hydrogen sulfide, and cooling-tower-related waste. This review paper aims to provide baseline knowledge on specific technologies and technology areas associated with geothermal power production. Specifically, this research focused on the management techniques related to fluids produced and used during the operational stage of a geothermal power plant; the vast majority of which are employed in the generation of electricity. The general characteristics of produced fluids are discussed. Constituents of interest that tend to drive the selection of treatment technologies are described, including total dissolved solids, noncondensable gases, scale and corrosion, silicon dioxide, metal sulfides, calcium carbonate, corrosion, metals, and naturally occurring radioactive material. Management options for produced fluids that require additional treatment for these constituents are also discussed, including surface disposal, reuse and recycle, agricultural industrial and domestic uses, mineral extraction and recovery, and solid waste handling.

  7. Recycling produced water for algal cultivation for biofuels

    SciTech Connect (OSTI)

    Neal, Justin N.; Sullivan, Enid J.; Dean, Cynthia A.; Steichen, Seth A.

    2012-08-09

    Algal growth demands a continuous source of water of appropriate salinity and nutritional content. Fresh water sources are scarce in the deserts of the Southwestern United States, hence, salt water algae species are being investigated as a renewable biofuel source. The use of produced water from oil wells (PW) could offset the demand for fresh water in cultivation. Produced water can contain various concentrations of dissolved solids, metals and organic contaminants and often requires treatment beyond oil/water separation to make it suitable for algae cultivation. The produced water used in this study was taken from an oil well in Jal, New Mexico. An F/2-Si (minus silica) growth media commonly used to cultivate Nannochloropsis salina 1776 (NS 1776) was prepared using the produced water (F/2-Si PW) taking into account the metals and salts already present in the water. NS 1776 was seeded into a bioreactor containing 5L of the (F/2-Si PW) media. After eleven days the optical density at 750 nm (an indicator of algal growth) increased from 0 to 2.52. These results indicate algae are able to grow, though inhibited when compared with non-PW media, in the complex chemical conditions found in produced water. Savings from using nutrients present in the PW, such as P, K, and HCO{sub 3}{sup -}, results in a 44.38% cost savings over fresh water to mix the F/2-Si media.

  8. Method for producing high surface area chromia materials for catalysis

    DOE Patents [OSTI]

    Gash, Alexander E. (Brentwood, CA); Satcher, Joe (Patterson, CA); Tillotson, Thomas (Tracy, CA); Hrubesh, Lawrence (Pleasanton, CA); Simpson, Randall (Livermore, CA)

    2007-05-01

    Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m.sup.2/g and 520 m.sup.2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

  9. Electrochemical method of producing nano-scaled graphene platelets

    DOE Patents [OSTI]

    Zhamu, Aruna; Jang, Joan; Jang, Bor Z.

    2013-09-03

    A method of producing nano-scaled graphene platelets with an average thickness smaller than 30 nm from a layered graphite material. The method comprises (a) forming a carboxylic acid-intercalated graphite compound by an electrochemical reaction; (b) exposing the intercalated graphite compound to a thermal shock to produce exfoliated graphite; and (c) subjecting the exfoliated graphite to a mechanical shearing treatment to produce the nano-scaled graphene platelets. Preferred carboxylic acids are formic acid and acetic acid. The exfoliation step in the instant invention does not involve the evolution of undesirable species, such as NO.sub.x and SO.sub.x, which are common by-products of exfoliating conventional sulfuric or nitric acid-intercalated graphite compounds. The nano-scaled platelets are candidate reinforcement fillers for polymer nanocomposites. Nano-scaled graphene platelets are much lower-cost alternatives to carbon nano-tubes or carbon nano-fibers.

  10. Method and system for producing complex-shape objects

    DOE Patents [OSTI]

    Jeantette, Francisco P. (Albuquerque, NM); Keicher, David M. (Albuquerque, NM); Romero, Joseph A. (Albuquerque, NM); Schanwald, Lee P. (Albuquerque, NM)

    2000-01-01

    A method and system are provided for producing complex, three-dimensional, net shape objects from a variety of powdered materials. The system includes unique components to ensure a uniform and continuous flow of powdered materials as well as to focus and locate the flow of powdered materials with respect to a laser beam which results in the melting of the powdered material. The system also includes a controller so that the flow of molten powdered materials can map out and form complex, three-dimensional, net-shape objects by layering the molten powdered material. Advantageously, such complex, three-dimensional net-shape objects can be produced having material densities varying from 90% of theoretical to fully dense, as well as a variety of controlled physical properties. Additionally, such complex, three-dimensional objects can be produced from two or more different materials so that the composition of the object can be transitioned from one material to another.

  11. Engineered microorganisms capable of producing target compounds under anaerobic conditions

    DOE Patents [OSTI]

    Buelter, Thomas; Meinhold, Peter; Feldman, Reid M. Renny; Hawkins, Andrew C.; Urano, Jun; Bastian, Sabine; Arnold, Frances

    2012-01-17

    The present invention is generally provides recombinant microorganisms comprising engineered metabolic pathways capable of producing C3-C5 alcohols under aerobic and anaerobic conditions. The invention further provides ketol-acid reductoisomerase enzymes which have been mutated or modified to increase their NADH-dependent activity or to switch the cofactor preference from NADPH to NADH and are expressed in the modified microorganisms. In addition, the invention provides isobutyraldehyde dehydrogenase enzymes expressed in modified microorganisms. Also provided are methods of producing beneficial metabolites under aerobic and anaerobic conditions by contacting a suitable substrate with the modified microorganisms of the present invention.

  12. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

  13. Method of producing nano-scaled inorganic platelets

    DOE Patents [OSTI]

    Zhamu, Aruna; Jang, Bor Z.

    2012-11-13

    The present invention provides a method of exfoliating a layered material (e.g., transition metal dichalcogenide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm. The method comprises (a) dispersing particles of a non-graphite laminar compound in a liquid medium containing therein a surfactant or dispersing agent to obtain a stable suspension or slurry; and (b) exposing the suspension or slurry to ultrasonic waves at an energy level for a sufficient length of time to produce separated nano-scaled platelets. The nano-scaled platelets are candidate reinforcement fillers for polymer nanocomposites.

  14. Research Portfolio Report Small Producers: Operations/Improved Recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Producers: Operations/Improved Recovery Cover image: Drill rigs and pump jacks are some typical tools used in natural gas and oil opera- tions and for improved recovery Research Portfolio Report Small Producers: Operations/Improved Recovery DOE/NETL-2015/1698 Prepared by: Mari Nichols-Haining and Christine Rueter KeyLogic Systems, Inc. National Energy Technology Laboratory (NETL) Contact: James Ammer james.ammer@netl.doe.gov Contract DE-FE0004003 Activity 4003.200.03 DISCLAIMER This report

  15. Low-cost method for producing extreme ultraviolet lithography optics

    DOE Patents [OSTI]

    Folta, James A. (Livermore, CA); Montcalm, Claude (Fort Collins, CO); Taylor, John S. (Livermore, CA); Spiller, Eberhard A. (Mt. Kisco, NY)

    2003-11-21

    Spherical and non-spherical optical elements produced by standard optical figuring and polishing techniques are extremely expensive. Such surfaces can be cheaply produced by diamond turning; however, the roughness in the diamond turned surface prevent their use for EUV lithography. These ripples are smoothed with a coating of polyimide before applying a 60 period Mo/Si multilayer to reflect a wavelength of 134 .ANG. and have obtained peak reflectivities close to 63%. The savings in cost are about a factor of 100.

  16. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

  17. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    1992-01-01

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H.sub.2 O and/or CO.sub.2 and H.sub.2 in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate.

  18. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, J.L.; Clausen, E.C.

    1992-12-22

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H[sub 2]O and/or CO[sub 2] and H[sub 2] in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate. 3 figs.

  19. Process for producing amorphous and crystalline silicon nitride

    DOE Patents [OSTI]

    Morgan, P.E.D.; Pugar, E.A.

    1985-11-12

    A process for producing amorphous or crystalline silicon nitride is disclosed which comprises reacting silicon disulfide ammonia gas at elevated temperature. In a preferred embodiment silicon disulfide in the form of whiskers'' or needles is heated at temperature ranging from about 900 C to about 1,200 C to produce silicon nitride which retains the whisker or needle morphological characteristics of the silicon disulfide. Silicon carbide, e.g. in the form of whiskers, also can be prepared by reacting substituted ammonia, e.g. methylamine, or a hydrocarbon containing active hydrogen-containing groups, such as ethylene, with silicon disulfide, at elevated temperature, e.g. 900 C. 6 figs.

  20. Method and apparatus for producing small hollow spheres

    DOE Patents [OSTI]

    Hendricks, Charles D.

    1979-01-01

    Method and apparatus for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T.gtoreq.600.degree. C.). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10.sup.3 .mu.m) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants.

  1. LANL researchers improve path to producing uranium compounds, candidates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for advanced nuclear fuels Researchers improve path to producing uranium compounds LANL researchers improve path to producing uranium compounds, candidates for advanced nuclear fuels Enhance the ability to develop advanced nuclear fuels in a safer, simpler manner. April 7, 2011 This illustration shows the structures of UI4(1,4-dioxane)2 (left) and the UI3(1,4-dioxane)1.5 complexes. This illustration shows the structures of UI4(1,4-dioxane)2 (left) and the UI3(1,4-dioxane)1.5 complexes.

  2. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, D.J.; Armstrong, P.S.; Panitz, J.K.G.

    1998-03-17

    A solid electrolytic capacitor is described having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects. 2 figs.

  3. Methods for producing monodispersed particles of barium titanate

    DOE Patents [OSTI]

    Hu, Zhong-Cheng (Knoxville, TN)

    2001-01-01

    The present invention is a low-temperature controlled method for producing high-quality, ultrafine monodispersed nanocrystalline microsphere powders of barium titanate and other pure or composite oxide materials having particles ranging from nanosized to micronsized particles. The method of the subject invention comprises a two-stage process. The first stage produces high quality monodispersed hydrous titania microsphere particles prepared by homogeneous precipitation via dielectric tuning in alcohol-water mixed solutions of inorganic salts. Titanium tetrachloride is used as an inorganic salt precursor material. The second stage converts the pure hydrous titania microsphere particles into crystalline barium titanate microsphere powders via low-temperature, hydrothermal reactions.

  4. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, Donald J. (Albuquerque, NM); Armstrong, Pamela S. (Abingdon, MD); Panitz, Janda Kirk G. (Edgewood, NM)

    1998-01-01

    A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

  5. Midwest Producing Region Natural Gas in Underground Storage - Change in

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas from Same Month Previous Year (Percent) Midwest Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Midwest Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 37.40 45.00 76.80 72.40 37.80 19.80 9.30 5.40 3.90 4.50 12.10 15.50 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  6. Mountain Producing Region Natural Gas in Underground Storage - Change in

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas from Same Month Previous Year (Percent) Mountain Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Mountain Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 -4.70 13.00 35.00 41.50 36.90 27.10 22.30 18.60 16.40 14.60 18.60 22.30 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  7. Pacific Producing Region Natural Gas in Underground Storage - Change in

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas from Same Month Previous Year (Percent) Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Pacific Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 39.40 137.00 162.70 103.50 62.40 34.80 25.30 14.90 12.90 9.80 8.70 -0.90 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  8. South Central Producing Region Natural Gas in Underground Storage - Change

    U.S. Energy Information Administration (EIA) Indexed Site

    in Working Gas from Same Month Previous Year (Percent) South Central Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) South Central Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 24.30 27.20 70.30 75.70 64.30 50.50 39.00 35.90 29.90 21.20 22.90 24.80 - = No Data Reported; -- = Not Applicable; NA = Not

  9. East Producing Region Natural Gas in Underground Storage - Change in

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas from Same Month Previous Year (Percent) East Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) East Producing Region Natural Gas in Underground Storage - Change in Working Gas from Same Month Previous Year (Percent) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 18.70 25.80 44.60 46.20 30.10 21.40 13.70 11.10 6.70 2.90 9.90 15.30 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld

  10. Innovative Wave Power Device Starts Producing Clean Power in Hawaii |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Wave Power Device Starts Producing Clean Power in Hawaii Innovative Wave Power Device Starts Producing Clean Power in Hawaii July 6, 2015 - 6:31pm Addthis With support from the Energy Department and the U.S. Navy, a prototype wave energy device has advanced successfully from initial concept to grid-connected, open-sea pilot testing. The device, called Azura, was recently launched and installed in a 30-meter test berth at the Navy's Wave Energy Test Site (WETS) in Kaneohe

  11. Method to produce succinic acid from raw hydrolysates

    DOE Patents [OSTI]

    Donnelly, Mark I.; Sanville-Millard, Cynthia Y.; Nghiem, Nhuan Phu

    2004-06-01

    A method for producing succinic acid from industrial-grade hydrolysates is provided, comprising supplying an organism that contains mutations for the genes ptsG, pflB, and ldhA, allowing said organism to accumulate biomass, and allowing said organism to metabolize the hydrolysate. Also provided is a bacteria mutant characterized in that it produces succinic acid from substrate contained in industrial-grade hydrolysate in a ratio of between 0.6:1 and 1.3:1 succinic acid to substrate.

  12. EM's Liquid Waste Contractor Produces $21 Million in Savings with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    'Lean' System | Department of Energy Liquid Waste Contractor Produces $21 Million in Savings with 'Lean' System EM's Liquid Waste Contractor Produces $21 Million in Savings with 'Lean' System April 29, 2015 - 12:00pm Addthis SRR employees work through the Lean process. SRR employees work through the Lean process. “At the end of the waste disposition path, these mega-facilities allow us to give the decontaminated salt solution a safe, final destination,” DOE-Savannah River Waste

  13. Methods of producing adsorption media including a metal oxide

    DOE Patents [OSTI]

    Mann, Nicholas R; Tranter, Troy J

    2014-03-04

    Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

  14. Superconducting articles of manufacture and method of producing same

    DOE Patents [OSTI]

    Newkirk, Lawrence R. (Los Alamos, NM); Valencia, Flavio A. (Santa Fe, NM)

    1980-01-01

    Bulk coatings of Nb.sub.3 Ge with high superconducting transition temperatures bonded to metallic substrates and a chemical vapor deposition method for producing such coatings on metallic substrates are disclosed. In accordance with the method, a Nb.sub.3 Ge coating having a transition temperature in excess of 21.5 K may be tightly bonded to a copper substrate.

  15. Process for producing astatine-211 for radiopharmaceutical use

    DOE Patents [OSTI]

    Mirzadeh, Saed (East Setauket, NY); Lambrecht, Richard M. (Quogue, NY)

    1987-01-01

    A process for reliably and consistently producing astatine-211 in small controlled volumes of a solution, which is selected from a choice of solvents that are useful in selected radiopharmaceutical procedures in which the At-211 activities are to be applied.

  16. Certification of a weld produced by friction stir welding

    DOE Patents [OSTI]

    Obaditch, Chris; Grant, Glenn J

    2013-10-01

    Methods, devices, and systems for providing certification of friction stir welds are disclosed. A sensor is used to collect information related to a friction stir weld. Data from the sensor is compared to threshold values provided by an extrinsic standard setting organizations using a certification engine. The certification engine subsequently produces a report on the certification status of the weld.

  17. Electroplating method for producing ultralow-mass fissionable deposits

    DOE Patents [OSTI]

    Ruddy, Francis H. (Monroeville, PA)

    1989-01-01

    A method for producing ultralow-mass fissionable deposits for nuclear reactor dosimetry is described, including the steps of holding a radioactive parent until the radioactive parent reaches secular equilibrium with a daughter isotope, chemically separating the daughter from the parent, electroplating the daughter on a suitable substrate, and holding the electroplated daughter until the daughter decays to the fissionable deposit.

  18. Power systems utilizing the heat of produced formation fluid

    DOE Patents [OSTI]

    Lambirth, Gene Richard (Houston, TX)

    2011-01-11

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method includes treating a hydrocarbon containing formation. The method may include providing heat to the formation; producing heated fluid from the formation; and generating electricity from at least a portion of the heated fluid using a Kalina cycle.

  19. Multipass rotary shear comminution process to produce corn stover particles

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2015-04-14

    A process of comminution of corn stover having a grain direction to produce a mixture of corn stover, by feeding the corn stover in a direction of travel substantially randomly to the grain direction one or more times through a counter rotating pair of intermeshing arrays of cutting discs (D) arrayed axially perpendicular to the direction of corn stover travel.

  20. Process for producing astatine-211 for radiopharmaceutical use

    DOE Patents [OSTI]

    Mirzadeh, S.; Lambrecht, R.M.

    1984-04-10

    A process is described for reliably and consistently producing astatine-211 in small controlled volumes of a solution, which is selected from a choice of solvents that are useful in selected radiopharmaceutical procedures in which the At-211 activities are to be applied. 4 figures, 1 table.

  1. Method of producing hydrogen, and rendering a contaminated biomass inert

    DOE Patents [OSTI]

    Bingham, Dennis N. [Idaho Falls, ID; Klingler, Kerry M. [Idaho Falls, ID; Wilding, Bruce M. [Idaho Falls, ID

    2010-02-23

    A method for rendering a contaminated biomass inert includes providing a first composition, providing a second composition, reacting the first and second compositions together to form an alkaline hydroxide, providing a contaminated biomass feedstock and reacting the alkaline hydroxide with the contaminated biomass feedstock to render the contaminated biomass feedstock inert and further producing hydrogen gas, and a byproduct that includes the first composition.

  2. Horizontal natural gas storage caverns and methods for producing same

    DOE Patents [OSTI]

    Russo, Anthony (Albuquerque, NM)

    1995-01-01

    The invention provides caverns and methods for producing caverns in bedded salt deposits for the storage of materials that are not solvents for salt. The contemplated salt deposits are of the bedded, non-domed variety, more particularly salt found in layered formations that are sufficiently thick to enable the production of commercially usefully sized caverns completely encompassed by walls of salt of the formation. In a preferred method, a first bore hole is drilled into the salt formation and a cavity for receiving insolubles is leached from the salt formation. Thereafter, at a predetermined distance away from the first bore hole, a second bore hole is drilled towards the salt formation. As this drill approaches the salt, the drill assumes a slant approach and enters the salt and drills through it in a horizontal direction until it intersects the cavity for receiving insolubles. This produces a substantially horizontal conduit from which solvent is controlledly supplied to the surrounding salt formation, leaching the salt and producing a concentrated brine which is removed through the first bore hole. Insolubles are collected in the cavity for receiving insolubles. By controlledly supplying solvent, a horizontal cavern is produced with two bore holes extending therefrom.

  3. Method for producing sintered ceramic, layered, circular fuel pellets

    DOE Patents [OSTI]

    Harlow, John L. (East Berne, NY)

    1983-01-01

    A compacting die wherein the improvement comprises providing a screen in the die cavity, the screen being positioned parallel to the side walls of said die and dividing the die cavity into center and annular compartments. In addition, the use of this die in a method for producing an annular clad ceramic fuel material is disclosed.

  4. Process for producing ceramic nitrides and carbonitrides and their precursors

    DOE Patents [OSTI]

    Brown, Gilbert M. (Knoxville, TN); Maya, Leon (Oak Ridge, TN)

    1988-01-01

    A process for preparing ceramic nitrides and carbonitrides in the form of very pure, fine particulate powder. Appropriate precursor is prepared by reacting a transition metal alkylamide with ammonia to produce a mixture of metal amide and metal imide in the form of an easily pyrolyzable precipitate.

  5. Process for producing ceramic nitrides anc carbonitrides and their precursors

    DOE Patents [OSTI]

    Brown, G.M.; Maya, L.

    1987-02-25

    A process for preparing ceramic nitrides and carbon nitrides in the form of very pure, fine particulate powder. Appropriate precursors is prepared by reaching a transition metal alkylamide with ammonia to produce a mixture of metal amide and metal imide in the form of an easily pyrolyzable precipitate.

  6. Current Challenges in Commercially Producing Biofuels from Lignocellulosic Biomass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balan, Venkatesh

    2014-01-01

    Biofuels that are produced from biobased materials are a good alternative to petroleum based fuels. They offer several benefits to society and the environment. Producing second generation biofuels is even more challenging than producing first generation biofuels due the complexity of the biomass and issues related to producing, harvesting, and transporting less dense biomass to centralized biorefineries. In addition to this logistic challenge, other challenges with respect to processing steps in converting biomass to liquid transportation fuel like pretreatment, hydrolysis, microbial fermentation, and fuel separation still exist and are discussed in this review. The possible coproducts that could be producedmore » in the biorefinery and their importance to reduce the processing cost of biofuel are discussed. About $1 billion was spent in the year 2012 by the government agencies in US to meet the mandate to replace 30% existing liquid transportation fuels by 2022 which is 36 billion gallons/year. Other countries in the world have set their own targets to replace petroleum fuel by biofuels. Because of the challenges listed in this review and lack of government policies to create the demand for biofuels, it may take more time for the lignocellulosic biofuels to hit the market place than previously projected.« less

  7. Electric Power Produced from Nuclear Reactor | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration Electric Power Produced from Nuclear Reactor | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery

  8. Method for producing labeled single-stranded nucleic acid probes

    DOE Patents [OSTI]

    Dunn, John J. (Bellport, NY); Quesada, Mark A. (Middle Island, NY); Randesi, Matthew (Upton, NY)

    1999-10-19

    Disclosed is a method for the introduction of unidirectional deletions in a cloned DNA segment. More specifically, the method comprises providing a recombinant DNA construct comprising a DNA segment of interest inserted in a cloning vector, the cloning vector having an f1 endonuclease recognition sequence adjacent to the insertion site of the DNA segment of interest. The recombinant DNA construct is then contacted with the protein pII encoded by gene II of phage f1 thereby generating a single-stranded nick. The nicked DNA is then contacted with E. coli Exonuclease III thereby expanding the single-stranded nick into a single-stranded gap. The single-stranded gapped DNA is then contacted with a single-strand-specific endonuclease thereby producing a linearized DNA molecule containing a double-stranded deletion corresponding in size to the single-stranded gap. The DNA treated in this manner is then incubated with DNA ligase under conditions appropriate for ligation. Also disclosed is a method for producing single-stranded DNA probes. In this embodiment, single-stranded gapped DNA, produced as described above, is contacted with a DNA polymerase in the presence of labeled nucleotides to fill in the gap. This DNA is then linearized by digestion with a restriction enzyme which cuts outside the DNA segment of interest. The product of this digestion is then denatured to produce a labeled single-stranded nucleic acid probe.

  9. Membrane Technology for Produced Water in Lea County

    SciTech Connect (OSTI)

    Cecilia Nelson; Ashok Ghosh

    2011-06-30

    Southeastern New Mexico (SENM) is rich in mineral resources, including oil and gas. Produced water is a byproduct from oil and gas recovery operations. SENM generates approximately 400 million barrels per year of produced water with total dissolved solids (TDS) as high as ~ 200,000 ppm. Typically, produced water is disposed of by transporting it to injection wells or disposal ponds, costing around $1.2 billion per year with an estimated use of 0.3 million barrels of transportation fuel. New Mexico ranks first among U.S. states in potash production. Nationally, more than 85% of all potash produced comes from the Carlsbad potash district in SENM. Potash manufacturing processes use large quantities of water, including fresh water, for solution mining. If the produced water from oilfield operations can be treated and used economically in the potash industry, it will provide a beneficial use for the produced water as well as preserve valuable water resources in an area where fresh water is scarce. The goal of this current research was to develop a prototype desalination system that economically treats produced water from oil and/or natural gas operations for the beneficial use of industries located in southeastern New Mexico. Up until now, most water cleaning technologies have been developed for treating water with much lower quantities of TDS. Seawater with TDS of around 30,000 ppm is the highest concentration that has been seriously studied by researchers. Reverse osmosis (RO) technology is widely used; however the cost remains high due to high-energy consumption. Higher water fluxes and recoveries are possible with a properly designed Forward Osmosis (FO) process as large driving forces can be induced with properly chosen membranes and draw solution. Membrane fouling and breakdown is a frequent and costly problem that drives the cost of desalination very high. The technology developed by New Mexico Tech (NMT) researchers not only protects the membrane, but has also proven to generate higher water flux, based on the series of experiments conducted. Laboratory tests at NMT demonstrated that an unprecedented water flux of 1300 l/m2/hr (where typical flux is on the order of 0-3 l/m{sup 2}/hr) can be achieved from a properly designed membrane module. The patent pending NMT system, which was designed and developed at NMT was successful in reducing the possibility for concentration polarization and thereby increasing the permeate water flux, while still maintaining a high salt rejection rate of 96% or greater. For feed solutions having a dissolved contaminant concentration greater than 10,000 ppm, preliminary economic analysis demonstrates that a well-designed FO process will outperform an RO process. Most produced water generated in SENM has TDS higher than 10,000 ppm. Therefore, it is logical to use FO to desalinate the water. Since the issues associated with concentration polarization has only recently been solved by our mechanically enhanced membrane module, the level of system maturity is not at the same level as that for RO. Our efforts going forward will be directed at taking the technology to a higher level of system maturity. With the superior cost effectiveness for FO, it is imperative that this technology reach a point that is competitive with RO in order to meet the expanding need for water for industries in SENM. NMT seeks to demonstrate the greater cost effectiveness by proving the process through a scaled up model. To ensure success, NMT feels it is important to demonstrate this technology in a larger system, (~ 100,000 GPD), before venturing to the commercial scale. This will build confidence in the process with the commercial sector. In addition, it will be possible to develop some of the operational processes around renewable energy sources for the scaled up model. This will further lower the operating costs and enhance the environmentally clean aspect of the process.

  10. High capacity adsorption media and method of producing

    DOE Patents [OSTI]

    Tranter, Troy J.; Herbst, R. Scott; Mann, Nicholas R.; Todd, Terry A.

    2008-05-06

    A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

  11. High capacity adsorption media and method of producing

    DOE Patents [OSTI]

    Tranter, Troy J.; Mann, Nicholas R.; Todd, Terry A.; Herbst, Ronald S.

    2010-10-05

    A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving and/or suspending at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

  12. Nonsalt Producing Region Natural Gas Working Underground Storage (Billion

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Nonsalt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2006-Dec 12/29 841 2007-Jan 01/05 823 01/12 806 01/19 755 01/26 716 2007-Feb 02/02 666 02/09 613 02/16 564 02/23 538 2007-Mar 03/02 527 03/09 506 03/16 519 03/23 528 03/30 550 2007-Apr 04/06 560

  13. Producing Region Natural Gas Working Underground Storage (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    Feet) Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1993-Dec 12/31 570 1994-Jan 01/07 532 01/14 504 01/21 440 01/28 414 1994-Feb 02/04 365 02/11 330 02/18 310 02/25 309 1994-Mar 03/04 281 03/11 271 03/18 284 03/25 303 1994-Apr 04/01 287 04/08 293 04/15 308 04/22

  14. Salt Producing Region Natural Gas Working Underground Storage (Billion

    Gasoline and Diesel Fuel Update (EIA)

    Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2006-Dec 12/29 101 2007-Jan 01/05 109 01/12 107 01/19 96 01/26 91 2007-Feb 02/02 78 02/09 63 02/16 52 02/23 54 2007-Mar 03/02 59 03/09 58 03/16 64 03/23 70 03/30 78 2007-Apr 04/06 81 04/13 80 04/20

  15. Oil shale retorting with steam and produced gas

    SciTech Connect (OSTI)

    Merrill, L.S. Jr.; Wheaton, L.D.

    1991-08-20

    This patent describes a process for retorting oil shale in a vertical retort. It comprises introducing particles of oil shale into the retort, the particles of oil shale having a minimum size such that the particles are retained on a screen having openings 1/4 inch in size; contacting the particles of oil shale with hot gas to heat the particles of oil shale to a state of pyrolysis, thereby producing retort off-gas; removing the off-gas from the retort; cooling the off-gas; removing oil from the cooled off-gas; separating recycle gas from the off-gas, the recycle gas comprising steam and produced gas, the steam being present in amount, by volume, of at least 50% of the recycle gas so as to increase the yield of sand oil; and heating the recycle gas to form the hot gas.

  16. Method to produce large, uniform hollow spherical shells

    DOE Patents [OSTI]

    Hendricks, C.D.

    1983-09-26

    The invention is a method to produce large uniform hollow spherical shells by (1) forming uniform size drops of heat decomposable or vaporizable material, (2) evaporating the drops to form dried particles, (3) coating the dried particles with a layer of shell forming material and (4) heating the composite particles to melt the outer layer and to decompose or vaporize the inner particle to form an expanding inner gas bubble. The expanding gas bubble forms the molten outer layer into a shell of relatively large diameter. By cycling the temperature and pressure on the molten shell, nonuniformities in wall thickness can be reduced. The method of the invention is utilized to produce large uniform spherical shells, in the millimeter to centimeter diameter size range, from a variety of materials and of high quality, including sphericity, concentricity and surface smoothness, for use as laser fusion or other inertial confinement fusion targets as well as other applications.

  17. Method of producing gaseous products using a downflow reactor

    DOE Patents [OSTI]

    Cortright, Randy D; Rozmiarek, Robert T; Hornemann, Charles C

    2014-09-16

    Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.

  18. Method of producing novel silicon carbide articles. [Patent application

    DOE Patents [OSTI]

    Milewski, J.V.

    1982-06-18

    A method of producing articles comprising reaction-bonded silicon carbide (SiC) and graphite (and/or carbon) is given. The process converts the graphite (and/or carbon) in situ to SiC, thus providing the capability of economically obtaining articles made up wholly or partially of SiC having any size and shape in which graphite (and/or carbon) can be found or made. When the produced articles are made of an inner graphite (and/or carbon) substrate to which SiC is reaction bonded, these articles distinguish SiC-coated graphite articles found in the prior art by the feature of a strong bond having a gradual (as opposed to a sharply defined) interface which extends over a distance of mils. A method for forming SiC whisker-reinforced ceramic matrices is also given. The whisker-reinforced articles comprise SiC whiskers which substantially retain their structural integrity.

  19. Long-laser-pulse method of producing thin films

    DOE Patents [OSTI]

    Balooch, Mehdi (Berkeley, CA); Olander, Donald K. (Berkeley, CA); Russo, Richard E. (Walnut Creek, CA)

    1991-01-01

    A method of depositing thin films by means of laser vaporization employs a long-pulse laser (Nd-glass of about one millisecond duration) with a peak power density typically in the range 10.sup.5 -10.sup.6 W/cm.sup.2. The method may be used to produce high T.sub.c superconducting films of perovskite material. In one embodiment, a few hundred nanometers thick film of YBa.sub.2 Cu.sub.3 O.sub.7-x is produced on a SrTiO.sub.3 crystal substrate in one or two pulses. In situ-recrystallization and post-annealing, both at elevated temperature and in the presence of an oxidizing agen The invention described herein arose in the course of, or under, Contract No. DE-C03-76SF0098 between the United States Department of Energy and the University of California.

  20. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  1. Methods and apparatus for producing cryogenic inertially driven fusion targets

    DOE Patents [OSTI]

    Miller, John R. (Los Alamos, NM)

    1981-01-01

    A new technique for producing uniform layers of solid DT on microballoon surfaces. Local heating of the target, typically by means of a focused laser, within an isothermal freezing cell containing a low pressure cryogenic exchange gas such as helium, vaporizes the DT fuel. Removal of the laser heating source causes the DT gas to rapidly condense and freeze in a layer which exhibits a good degree of uniformity.

  2. Apparatus for producing cryogenic inertially driven fusion targets

    DOE Patents [OSTI]

    Miller, John R. (Los Alamos, NM)

    1981-01-01

    A new technique for producing uniform layers of solid DT on microballoon surfaces. Local heating of the target, typically by means of a focused laser, within an isothermal freezing cell containing a low pressure cryogenic exchange gas such as helium, vaporizes the DT fuel contained within the microballoon. Removal of the laser heating source causes the DT gas to rapidly condense and freeze in a layer which exhibits a good degree of uniformity.

  3. Water management practices used by Fayetteville shale gas producers.

    SciTech Connect (OSTI)

    Veil, J. A.

    2011-06-03

    Water issues continue to play an important role in producing natural gas from shale formations. This report examines water issues relating to shale gas production in the Fayetteville Shale. In particular, the report focuses on how gas producers obtain water supplies used for drilling and hydraulically fracturing wells, how that water is transported to the well sites and stored, and how the wastewater from the wells (flowback and produced water) is managed. Last year, Argonne National Laboratory made a similar evaluation of water issues in the Marcellus Shale (Veil 2010). Gas production in the Marcellus Shale involves at least three states, many oil and gas operators, and multiple wastewater management options. Consequently, Veil (2010) provided extensive information on water. This current study is less complicated for several reasons: (1) gas production in the Fayetteville Shale is somewhat more mature and stable than production in the Marcellus Shale; (2) the Fayetteville Shale underlies a single state (Arkansas); (3) there are only a few gas producers that operate the large majority of the wells in the Fayetteville Shale; (4) much of the water management information relating to the Marcellus Shale also applies to the Fayetteville Shale, therefore, it can be referenced from Veil (2010) rather than being recreated here; and (5) the author has previously published a report on the Fayetteville Shale (Veil 2007) and has helped to develop an informational website on the Fayetteville Shale (Argonne and University of Arkansas 2008), both of these sources, which are relevant to the subject of this report, are cited as references.

  4. Apparatus producing constant cable tension for intermittent demand

    DOE Patents [OSTI]

    Lauritzen, T.

    1984-05-23

    This invention relates to apparatus for producing constant tension in cable or the like when it is unreeled and reeled from a drum or spool under conditions of intermittent demand. The invention is particularly applicable to the handling of superconductive cable, but the invention is also applicable to the unreeling and reeling of other strands, such as electrical cable, wire, cord, other cables, fish line, wrapping paper and numerous other materials.

  5. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

    1987-01-01

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  6. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  7. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  8. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  9. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  10. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  11. Producing microchannels using graduated diffusion bonding of a stack of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    precision machined foils or sheets (laminates) to make a micro-channel reactor - Energy Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Producing microchannels using graduated diffusion bonding of a stack of precision machined foils or sheets (laminates) to make a micro-channel reactor A novel multi-step process for the diffusion bonding of laminates National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF

  12. Autogenic pressure reactors provide simple, rapid means of producing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery materials - Energy Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Autogenic pressure reactors provide simple, rapid means of producing battery materials Argonne National Laboratory Contact ANL About This Technology Spherical carbon particles prepared in an autogenic reaction Spherical carbon particles prepared in an autogenic reaction Technology Marketing Summary Rechargeable lithium-ion batteries have become

  13. Electrochemical power-producing cell. [Li/Se

    DOE Patents [OSTI]

    Cairns, E.J.; Chilenskas, A.A.; Steunenberg, R.K.; Shimotake, H.

    1972-05-30

    An electrochemical power-producing cell including a molten lithium metal anode, a molten selenium metal cathode, a paste electrolyte separating the anode from the cathode, an anode current collector, and a single layer of niobium expanded metal formed in corrugated shape as cathode current collector is described. In addition, means are provided for sealing the anode and the cathode from loss of lithium and selenium, respectively, and an insulator is provided between the anode housing and the paste electrolyte disk.

  14. New Process Helps Overcome Obstacles to Produce Renewable Fuels and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemicals - News Releases | NREL New Process Helps Overcome Obstacles to Produce Renewable Fuels and Chemicals Lignin Valorization Study Published in Proceedings of the National Academy of Sciences August 20, 2014 There's an old saying in the biofuels industry: "You can make anything from lignin except money." But now, a new study may pave the way to challenging that adage. The study from the Energy Department's National Renewable Energy Laboratory (NREL) demonstrates a concept

  15. Process for producing fine and ultrafine filament superconductor wire

    DOE Patents [OSTI]

    Kanithi, Hem C. (15 Briar Ct., Chesire, CT 06410)

    1992-01-01

    A process for producing a superconductor wire made up of a large number of round monofilament rods is provided for, comprising assembling a multiplicity of round monofilaments inside each of a multiplicity of thin wall hexagonal tubes and then assembling a number of said thin wall hexagonal tubes within an extrusion can and subsequently consolidating, extruding and drawing the entire assembly down to the desired wire size.

  16. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  17. Hybrid materials and methods for producing the same

    DOE Patents [OSTI]

    Luzzi, David E. (Wallingford, PA); Smith, Brian W. (Philadelphia, PA)

    2008-02-19

    A hybrid material is provided which comprises a first single-walled nanotube having a lumen, and a fill molecule contained within the lumen of the single-walled nanotube. A method for producing the hybrid material is also provided wherein a single-walled nanotube is contacted with a fill molecule to cause the fill molecule to enter the lumen of the single-walled nanotube.

  18. Hybrid materials and methods for producing the same

    DOE Patents [OSTI]

    Luzzi, David E. (Wallingford, PA); Smith, Brian W. (Schelton, CT)

    2003-04-08

    A hybrid material is provided which comprises a first single-walled nanotube having a lumen, and a fill molecule contained within the lumen of the single-walled nanotube. A method for producing the hybrid material is also provided wherein a single-walled nanotube is contacted with a fill molecule to cause the fill molecule to enter the lumen of the single-walled nanotube.

  19. Producing Clean, Renewable Diesel from Biomass | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean, Renewable Diesel from Biomass Producing Clean, Renewable Diesel from Biomass November 30, 2011 - 12:08pm Addthis ThermoChem Recovery International's process demonstration unit -- where wood waste and forest residue is converted into renewable fuel. | Courtesy of TRI. ThermoChem Recovery International's process demonstration unit -- where wood waste and forest residue is converted into renewable fuel. | Courtesy of TRI. Paul Bryan Biomass Program Manager, Office of Energy Efficiency &

  20. Financial News for Major Energy Producers, Third Quarter 2010

    Gasoline and Diesel Fuel Update (EIA)

    Producers, Third Quarter 2010 Release Date: January 5, 2011 Next Release Date: To Be Determined Report Sections: Corporate and Petroleum Net Income Worldwide Oil and Gas Production Operations Worldwide Refining/Marketing Operations Worldwide Petroleum Capital Expenditures Worldwide Downstream Natural Gas and Power, and Chemicals Operations Supplemental Figures Supplemental Tables Download this Report: Full Report in PDF-Format Past Issues in PDF-Format Additional Information FRS Home Financial

  1. Graphene Produces More Efficient Charge Transport Inside an Organic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Semiconductor | Stanford Synchrotron Radiation Lightsource Graphene Produces More Efficient Charge Transport Inside an Organic Semiconductor Friday, January 30, 2015 Graphene, a two dimensional semi-metal made of sp2 hybridized carbon, is an outstanding material which exhibits high mechanical and chemical stability, as well as high charge carrier mobility. Graphene has recently received considerable attention because it can be directly integrated into opto-electronic devices, enabling the

  2. Process for producing fine and ultrafine filament superconductor wire

    DOE Patents [OSTI]

    Kanithi, H.C.

    1992-02-18

    A process for producing a superconductor wire made up of a large number of round monofilament rods is provided for, comprising assembling a multiplicity of round monofilaments inside each of a multiplicity of thin wall hexagonal tubes and then assembling a number of said thin wall hexagonal tubes within an extrusion can and subsequently consolidating, extruding and drawing the entire assembly down to the desired wire size. 8 figs.

  3. Nuclear Physics Accelerator Technology Yields New Process for Producing

    Office of Science (SC) Website

    Boron-Nitride Nanotubes | U.S. DOE Office of Science (SC) Nuclear Physics Accelerator Technology Yields New Process for Producing Boron-Nitride Nanotubes Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301)

  4. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  5. Borrowing from Nature to Produce Highly Structured Biomimetic Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing from Nature to Produce Highly Structured Biomimetic Materials Print Doing Nature One Better Biological tissues such as those that make up our organs are amazing feats of structural engineering. Even more fantastic, the tissues assemble themselves from building blocks based on the proteins that cells synthesize without any outside direction. And, if this isn't mind-boggling enough, consider how all this takes place over large distances with both precision and accuracy. Chemists and

  6. Neutrons Reveal New Electrocatalyst Family for Producing Hydrogen Fuel |

    Office of Science (SC) Website

    U.S. DOE Office of Science (SC) Neutrons Reveal New Electrocatalyst Family for Producing Hydrogen Fuel Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More

  7. Method for producing microchannels in drawn material - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal 638,182 Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent Search Success Stories Find More Like This Return to Search Method for producing

  8. Method to Produce Highly Digestible, Pretreated Lignocellulosic Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using Anhydrous Liquid Ammonia - Energy Innovation Portal Method to Produce Highly Digestible, Pretreated Lignocellulosic Biomass Using Anhydrous Liquid Ammonia Inventors: Shishir Chundawat, Leonardo Sousa, Albert Cheh, Venkatesh Balan, Bruce Dale Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing SummaryIn the continuing push to develop alternative fuels, bioethanol is clearly a viable option. However, if it is to become a truly economical

  9. Sol-Char: Producing Char from Waste using Solar Energy

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-01-08

    A recent “Reinvent the Toilet Challenge” put forth by the Bill & Melinda Gates Foundation called for researchers to develop sanitation solutions that are affordable and desirable to use, render fecal waste harmless within a short time-span, are self-contained without the need for flush water or electricity, and produce valuable end products. Current waterless toilets – such as dry pit latrines, ventilated improved pit (VIP) latrines, and composting toilets – fall...

  10. Laser produced plasma diagnostics by cavity ringdown spectroscopy and applications

    SciTech Connect (OSTI)

    Milosevic, S.

    2012-05-25

    Laser-produced plasmas have many applications for which detailed characterization of the plume is requested. Cavity ring-down spectroscopy is a versatile absorption method which provides data on the plume and its surroundings, with spatial and temporal resolution. The measured absorption line shapes contain information about angular and velocity distributions within the plume. In various plasmas we have observed molecules or metastable atoms which were not present in the emission spectra.

  11. Theoretical Minimum Energies to Produce Steel for Selected Conditions

    SciTech Connect (OSTI)

    Fruehan, R.J.; Fortini, O.; Paxton, H.W.; Brindle, R.

    2000-05-01

    The energy used to produce liquid steel in today's integrated and electric arc furnace (EAF) facilities is significantly higher than the theoretical minimum energy requirements. This study presents the absolute minimum energy required to produce steel from ore and mixtures of scrap and scrap alternatives. Additional cases in which the assumptions are changed to more closely approximate actual operating conditions are also analyzed. The results, summarized in Table E-1, should give insight into the theoretical and practical potentials for reducing steelmaking energy requirements. The energy values have also been converted to carbon dioxide (CO{sub 2}) emissions in order to indicate the potential for reduction in emissions of this greenhouse gas (Table E-2). The study showed that increasing scrap melting has the largest impact on energy consumption. However, scrap should be viewed as having ''invested'' energy since at one time it was produced by reducing ore. Increasing scrap melting in the BOF mayor may not decrease energy if the ''invested'' energy in scrap is considered.

  12. Optimum position for wells producing at constant wellbore pressure

    SciTech Connect (OSTI)

    Camacho-Velazquez, R.; Rodriguez de la Garza, F.; Galindo-Nava, A.; Prats, M.

    1994-12-31

    This paper deals with the determination of the optimum position of several wells, producing at constant different wellbore pressures from a two-dimensional closed-boundary reservoirs, to maximize the cumulative production or the total flow rate. To achieve this objective they authors use an improved version of the analytical solution recently proposed by Rodriguez and Cinco-Ley and an optimization algorithm based on a quasi-Newton procedure with line search. At each iteration the algorithm approximates the negative of the objective function by a cuadratic relation derived from a Taylor series. The improvement of rodriguez and Cinco`s solution is attained in four ways. First, an approximation is obtained, which works better at earlier times (before the boundary dominated period starts) than the previous solution. Second, the infinite sums that are present in the solution are expressed in a condensed form, which is relevant for reducing the computer time when the optimization algorithm is used. Third, the solution is modified to take into account the possibility of having wells starting to produce at different times. This point allows them to deal with the problem of getting the optimum position for an infill drilling program. Last, the solution is extended to include the possibility of changing the value of wellbore pressure or being able to stimulate any of the wells at any time. When the wells are producing at different wellbore pressures it is found that the optimum position is a function of time, otherwise the optimum position is fixed.

  13. PEPPo: Using a Polarized Electron Beam to Produce Polarized Positrons

    SciTech Connect (OSTI)

    Adeyemi, Adeleke H.

    2015-09-01

    Polarized positron beams have been identified as either an essential or a significant ingredient for the experimental program of both the present and next generation of lepton accelerators (JLab, Super KEK B, ILC, CLIC). An experiment demonstrating a new method for producing polarized positrons has been performed at the Continuous Electron Beam Accelerator Facility at Jefferson Lab. The PEPPo (Polarized Electrons for Polarized Positrons) concept relies on the production of polarized e-/e+ pairs from the bremsstrahlung radiation of a longitudinally polarized electron beam interacting within a high Z conversion target. PEPPo demonstrated the effective transfer of spin-polarization of an 8.2 MeV/c polarized (P~85%) electron beam to positrons produced in varying thickness tungsten production targets, and collected and measured in the range of 3.1 to 6.2 MeV/c. In comparison to other methods this technique reveals a new pathway for producing either high energy or thermal polarized positron beams using a relatively low polarized electron beam energy (~10MeV) .This presentation will describe the PEPPo concept, the motivations of the experiment and high positron polarization achieved.

  14. Comment on Magnetic field mediated low-temperature resistivity upturn in electron-doped La{sub 1?x}Hf{sub x}MnO{sub 3} manganite oxides [J. Appl. Phys. 112, 123710 (2012)

    SciTech Connect (OSTI)

    Rozenberg, E.

    2014-01-21

    In a recent paper, Guo et al. [J. Appl. Phys. 112, 123710 (2012)] reported on characteristic features of the temperature (T) and magnetic field (H) dependences of electrical resistivity (?) in polycrystalline La{sub 1?x}Hf{sub x}MnO{sub 3} (x?=?0.2 and 0.3) manganites. In particular, shallow minima were observed at some T{sub min} below 100?K on ?(T) curves. Application of an external H???5?T leads first to a decrease in the T{sub min} value, while this value increases notably at H?>?0.75?T. The authors attributed this complex behavior to competitive electron-electron interaction and Kondo-like spin dependent scattering of carriers. It is shown in the comment that such interpretation is very questionable due to the fundamental inapplicability of this approach for analysis of low-T conductivity in polycrystalline manganites. It seems that the most likely reason for the appearance of the low temperature minima on ?(T) curves and their evolution upon field application is the well known grain boundary effects in magnetically and structurally inhomogeneous samples.

  15. Elastic properties of perovskite ATiO{sub 3} (A?=?Be, Mg, Ca, Sr, and Ba) and PbBO{sub 3} (B?=?Ti, Zr, and Hf): First principles calculations

    SciTech Connect (OSTI)

    Pandech, Narasak; Limpijumnong, Sukit; Sarasamak, Kanoknan

    2015-05-07

    The mechanical properties of perovskite oxides depend on two metal oxide lattices that are intercalated. This provides an opportunity for separate tuning of hardness, Poisson's ratio (transverse expansion in response to the compression), and shear strength. The elastic constants of series of perovskite oxides were studied by first principles approach. Both A-site and B-site cations were systematically varied in order to see their effects on the elastic parameters. To study the effects of A-site cations, we studied the elastic properties of perovskite ATiO{sub 3} for A being Be, Mg, Ca, Sr, or Ba, one at a time. Similarly, for B-site cations, we studied the elastic properties of PbBO{sub 3} for B being Ti, Zr, or Hf, one at a time. The density functional first principles calculations with local density approximation (LDA) and generalized gradient approximation (GGA) were employed. It is found that the maximum C{sub 11} elastic constant is achieved when the atomic size of the cations at A-site and B-site are comparable. We also found that C{sub 12} elastic constant is sensitive to B-site cations while C{sub 44} elastic constant is more sensitive to A-site cations. Details and explanations for such dependencies are discussed.

  16. Apparatus producing constant cable tension for intermittent demand

    DOE Patents [OSTI]

    Lauritzen, Ted (Lafayette, CA)

    1985-01-01

    The disclosed apparatus produces constant tension in superconducting electrical cable, or some other strand, under conditions of intermittent demand, as the cable is unreeled from a reel or reeled thereon. The apparatus comprises a pivotally supported swing frame on which the reel is rotatably supported, a rotary motor, a drive train connected between the motor and the reel and including an electrically controllable variable torque slip clutch, a servo transducer connected to the swing frame for producing servo input signals corresponding to the position thereof, a servo control system connected between the transducer and the clutch for regulating the torque transmitted by the clutch to maintain the swing frame in a predetermined position, at least one air cylinder connected to the swing frame for counteracting the tension in the cable, and pressure regulating means for supplying a constant air pressure to the cylinder to establish the constant tension in the cable, the servo system and the clutch being effective to produce torque on the reel in an amount sufficient to provide tension in the cable corresponding to the constant force exerted by the air cylinder. The drive train also preferably includes a fail-safe brake operable to its released position by electrical power in common with the servo system, for preventing rotation of the reel if there is a power failure. A shock absorber and biasing springs may also be connected to the swing frame, such springs biasing the frame toward its predetermined position. The tension in the cable may be measured by force measuring devices engageable with the bearings for the reel shaft, such bearings being supported for slight lateral movement. The reel shaft is driven by a Shmidt coupler which accommodates such movement.

  17. Online Produced Water Treatment Catalog and Decision Tool

    SciTech Connect (OSTI)

    J. Arthur

    2012-03-31

    The objective of this project was to create an internet-based Water Treatment Technology Catalog and Decision Tool that will increase production, decrease costs and enhance environmental protection. This is to be accomplished by pairing an operator's water treatment cost and capacity needs to specific water treatments. This project cataloged existing and emerging produced water treatment technologies and allows operators to identify the most cost-effective approaches for managing their produced water. The tool captures the cost and capabilities of each technology and the disposal and beneficial use options for each region. The tool then takes location, chemical composition, and volumetric data for the operator's water and identifies the most cost effective treatment options for that water. Regulatory requirements or limitations for each location are also addressed. The Produced Water Treatment Catalog and Decision Tool efficiently matches industry decision makers in unconventional natural gas basins with: 1) appropriate and applicable water treatment technologies for their project, 2) relevant information on regulatory and legal issues that may impact the success of their project, and 3) potential beneficial use demands specific to their project area. To ensure the success of this project, it was segmented into seven tasks conducted in three phases over a three year period. The tasks were overseen by a Project Advisory Council (PAC) made up of stakeholders including state and federal agency representatives and industry representatives. ALL Consulting has made the catalog and decision tool available on the Internet for the final year of the project. The second quarter of the second budget period, work was halted based on the February 18, 2011 budget availability; however previous project deliverables were submitted on time and the deliverables for Task 6 and 7 were completed ahead of schedule. Thus the application and catalog were deployed to the public Internet. NETL did not provide additional funds and work on the project stopped on February 18, 2011. NETL ended the project on March 31, 2012.

  18. Gelcasting polymeric precursors for producing net-shaped graphites

    DOE Patents [OSTI]

    Klett, James W.; Janney, Mark A.

    2005-02-15

    The present invention discloses a method for molding complex and intricately shaped high density monolithic carbon, carbon-carbon, graphite, and thermoplastic composites using gelcasting technology. The method comprising a polymeric carbon precursor, a solvent, a dispersant, an anti-foaming agent, a monomer system, and an initiator system. The components are combined to form a suspension which is poured into a mold and heat-treated to form a thermoplastic part. The thermoplastic part can then be further densified and heat-treated to produce a high density carbon or graphite composite. The present invention also discloses the products derived from this method.

  19. Gelcasting polymeric precursors for producing net-shaped graphites

    DOE Patents [OSTI]

    Klett, James W. (Knoxville, TN); Janney, Mark A. (Knoxville, TN)

    2002-01-01

    The present invention discloses a method for molding complex and intricately shaped high density monolithic carbon, carbon-carbon, graphite, and thermoplastic composites using gelcasting technology. The method comprising a polymeric carbon precursor, a solvent, a dispersant, an anti-foaming agent, a monomer system, and an initiator system. The components are combined to form a suspension which is poured into a mold and heat-treated to form a thermoplastic part. The thermoplastic part can then be further densified and heat-treated to produce a high density carbon or graphite composite. The present invention also discloses the products derived from this method.

  20. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, J.L.

    1987-07-07

    A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.