National Library of Energy BETA

Sample records for fluidized-bed combus tors

  1. Pulse enhanced fluidized bed combustion

    SciTech Connect (OSTI)

    Mueller, B.

    1996-12-31

    Information is outlined on pulse enhanced fluidized bed combustion. The following topics are discussed: what is pulse enhanced fluidized bed combustion?; pulse combustors; pulsed atmospheric fluidized bed combustor (PAFBC); advantages of PAFBC; performance advantages; PAFBC facts; and PAFBC contact points.

  2. Fluidized bed calciner apparatus

    DOE Patents [OSTI]

    Owen, Thomas J. (West Richland, WA); Klem, Jr., Michael J. (Richland, WA); Cash, Robert J. (Richland, WA)

    1988-01-01

    An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

  3. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  4. Stability of Gas-Fluidized Beds

    E-Print Network [OSTI]

    Mandich, Kevin Matthew

    Temperature in a Bubbling Fluidized Bed, To Be Submitted tomechanisms of bubbling in fluidized beds. A simpler analysiswith the nature of bubbling in fluidized beds. When bubbles

  5. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, R.G.

    1983-05-13

    The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  6. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, A.G.; Patel, J.G.

    1987-05-12

    An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

  7. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1987-05-12

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  8. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  9. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1995-01-01

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  10. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN)

    1993-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  11. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1996-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

  12. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1995-04-25

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

  13. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.

    1993-12-14

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

  14. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1996-02-27

    A fluidized bed reactor system is described which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves. 3 figs.

  15. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The general specifications for a Pulsed Atmospheric Fluidized Bed Combustor Design Report (PAFBC) plant are presented. The design tasks for the PAFBC are described in the following areas: Coal/Limestone preparation and feed system; pulse combustor; fluidized bed; boiler parts; and ash handling system.

  16. Pulse enhanced fluidized bed combustion

    SciTech Connect (OSTI)

    Mueller, B.; Golan, L. [South Carolina Energy Research and Development Center, Clemson, SC (United States); Toma, M.; Mansour, M. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

    1996-12-31

    Various technologies are available for the combustion of high-sulfur, high-ash fuels, particularly coal. From performance, economic and environmental standpoints, fluidized bed combustion (FBC) is the leading candidate for utilization of high sulfur coals. ThermoChem, Inc., and the South Carolina Energy Research and Development Center (SCERDC) are installing a hybrid fluidized bed combustion system at Clemson University. This hybrid system, known as the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC), will augment the University`s steam system by providing 50--60,000 lbs/hr of saturated process steam. The PAFBC, developed by Manufacturing and Technology Conversion International, Inc., (MTCI), integrates a pulse combustor with a bubbling-bed-type atmospheric fluidized bed coal combustor. The pulse combustion system imparts an acoustic effect that enhances combustion efficiency, SO{sub 2} capture, low NO{sub x} emissions, and heat transfer efficiency in the fluidized bed. These benefits of pulse combustion result in modestly sized PAFBC units with high throughput rates and lower costs when compared to conventional fluidized bed units.

  17. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, J.

    1996-03-19

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  18. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  19. Apparatus and process for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1985-10-01

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  20. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  1. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    During this first quarter, a lab-scale water-cooled pulse combustor was designed, fabricated, and integrated with old pilot-scale PAFBC test systems. Characterization tests on this pulse combustor firing different kinds of fuel -- natural gas, pulverized coal and fine coal -- were conducted (without fluidized bed operation) for the purpose of finalizing PAFBC full-scale design. Steady-state tests were performed. Heat transfer performance and combustion efficiency of a coal-fired pulse combustor were evaluated.

  2. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01

    fast bed and (b) the bubbling fluidized bed on gas mixingflow regimes. (A) A bubbling fluidized bed, (B) turbulent1.5, 1.6. 1. Bubbling fluidized bed gasifiers (BFB) (Figure

  3. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Design and Engineering of most components in the Pulsed Atmospheric Fluidized Bed System was completed prior to September 1992. The components remaining to be designed at that time were: Aerovalves for the Pulse Combustor; Gas and coal injectors for the Pulse Combustor; Lines for PC tailpipes; Air plenum and inlet silencer; Refractory lined hot gas duct connecting outlet hot cyclone to boiler; Structure and platforms, and ladders around PAFBC vessel access and major equipment. Design work is currently in progress on all of the above components. Items 1, 2, 3 and 4 are 50% completed, and items 5 6 are 75% complete.

  4. Fluidized-bed copper oxide process

    SciTech Connect (OSTI)

    Shah, P.P.; Takahashi, G.S.; Leshock, D.G.

    1991-10-14

    The fluidized-bed copper oxide process was developed to simultaneously remove sulfur dioxide and nitrogen oxide contaminants from the flue gas of coal-fired utility boilers. This dry and regenerable process uses a copper oxide sorbent in a fluidized-bed reactor. Contaminants are removed without generating waste material. (VC)

  5. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  6. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  7. Fluidized Bed Technology - Overview | Department of Energy

    Energy Savers [EERE]

    fluidized bed boilers as a standard package. This success is largely due to the Clean Coal Technology Program and the Energy Department's Fossil Energy and industry partners R&D....

  8. High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors

    E-Print Network [OSTI]

    Hou, Peggy Y.; MacAdam, S.; Niu, Y.; Stringer, J.

    2003-01-01

    a Laboratory Simulated Bubbling Fluidized Bed", Wear. 235,Tube Wastage in Bubbling Fluidized Bed, a Laboratory StudyWheeldon, "Wastage in bubbling fluidized-bed combustors: an

  9. Advanced Fluidized Bed Waste Heat Recovery Systems 

    E-Print Network [OSTI]

    Peterson, G. R.

    1988-01-01

    BED WASTE HEAT RECOVERY SYSTEMS G. R. PETERSON Project Manager U.S. Department of Energy, Idaho Operations Office Idaho Falls, Idaho ABSTRACT The U.S. Department of Energy, Office of Industri al Programs, has sponsored the development of a... Fluidized Bed Waste Heat Recovery System (FBWHRS) and a higher temperature variant, the Ceramic Tubular Distributor Plate (CTOP) Fluidized Bed Heat Exchanger (FBHX) system. Both systems recover energy from high-temperature flue gases and produce steam...

  10. Rivesville multicell fluidized bed boiler

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    One objective of the experimental MFB at Rivesville, WV, was the evaluation of alternate feed systems for injecting coal and limestone into a fluidized bed. A continuous, uniform feed flow to the fluid bed is essential in order to maintain stable operations. The feed system originally installed on the MFB was a gravity feed system with an air assist to help overcome the back pressure created by the fluid bed. The system contained belt, vibrating, and rotary feeders which have been proven adequate in other material handling applications. This system, while usable, had several operational and feeding problems during the MFB testing. A major portion of these problems occurred because the coal and limestone feed control points - a belt feeder and rotary feeder, respectively - were pressurized in the air assist system. These control points were not designed for pressurized service. An alternate feed system which could accept feed from the two control points, split the feed into six equal parts and eliminate the problems of the pressurized system was sought. An alternate feed system designed and built by the Fuller Company was installed and tested at the Rivesville facility. Fuller feed systems were installed on the north and south side of C cell at the Rivesville facility. The systems were designed to handle 10,000 lb/hr of coal and limestone apiece. The systems were installed in late 1979 and evaluated from December 1979 to December 1980. During this time period, nearly 1000 h of operating time was accumulated on each system.

  11. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  12. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

    1992-01-01

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  13. Particle withdrawal from fluidized bed systems

    DOE Patents [OSTI]

    Salvador, Louis A. (Greensburg, PA); Andermann, Ronald E. (Arlington Heights, IL); Rath, Lawrence K. (Mt. Pleasant, PA)

    1982-01-01

    Method and apparatus for removing ash formed within, and accumulated at the lower portion of, a fluidized bed coal gasification reactor vessel. A supplemental fluidizing gas, at a temperature substantially less than the average fluidized bed combustion operating temperature, is injected into the vessel and upwardly through the ash so as to form a discrete thermal interface region between the fluidized bed and the ash. The elevation of the interface region, which rises with ash accumulation, is monitored by a thermocouple and interrelated with a motor controlled outlet valve. When the interface rises above the temperature indicator, the valve opens to allow removal of some of the ash, and the valve is closed, or positioned at a minimum setting, when the interface drops to an elevation below that of the thermocouple.

  14. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  15. Fluidized bed electrowinning of copper. Final report

    SciTech Connect (OSTI)

    1997-07-01

    The objectives of the study were to: design and construct a 10,000- amp fluidized bed electrowinning cell for the recovery of copper from acidic sulfate solutions; demonstrate the technical feasibility of continuous particle recirculation from the electrowinning cell with the ultimate goal of continuous particle removal; and measure cell efficiency as a function of operating conditions.

  16. Particle pressures in fluidized beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction), they impart to the bed. So rather than directly measure the particle pressure, the authors inferred the values of the elasticity from measurements of instability growth in liquid beds; the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined) and then working backwards to determine the unknown coefficients, including the elasticity.

  17. Particle Pressures in Fluidized Beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction): they impart to the bed. So rather than directly measure the particle pressure, we inferred the values of the elasticity from measurements of instability growth in liquid beds the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined)and then working backwards to determine the unknown coefficients, including the elasticity.

  18. 138 Chemical Engineering Education FLUIDIZED BED

    E-Print Network [OSTI]

    Hesketh, Robert

    138 Chemical Engineering Education FLUIDIZED BED POLYMER COATING EXPERIMENT ROBERT P. HESKETH, C,2] and is a highly visual experiment in chemical engineering pro- cesses and experimentation. In addition for the chemical engineering profession. The field encom- passes many technologies, ranging from polymerization

  19. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C. Stuart (Knoxville, TN); Hawk, James A. (Oak Ridge, TN)

    1995-01-01

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

  20. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C.S.; Hawk, J.A.

    1995-07-25

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence. 9 figs.

  1. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

    1986-01-01

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  2. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  3. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  4. Coal-Fired Fluidized Bed Combustion Cogeneration 

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    1985-01-01

    BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed combustion, has encouraged many... steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However, this addition of cogeneration...

  5. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  6. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  7. Status of the fluidized bed unit

    SciTech Connect (OSTI)

    Williams, P.M.; Wade, J.F.

    1994-06-01

    Rocky Flats has a serious mixed waste problem. No technology or company has a license and available facilities to remedy this dilemma. One solution under study is to use a catalytic fluidized bed unit to destroy the combustible portion of the mixed waste. The fluidized bed thermal treatment program at Rocky Flats is building on knowledge gained over twenty years of successful development activity. The FBU has numerous technical advantages over other thermal technologies to treat Rocky Flats` mixed waste, the largest being the lower temperature (700{degrees}C versus 1000{degrees}C) which reduces acid corrosion and mechanical failures and obviates the need for ceramic lining. Successful demonstrations have taken place on bench, pilot, and full-scale tests using radioactive mixed wastes. The program is approaching implementation and licensing of a production-scale fluidized bed system for the safe treatment of mixed waste. The measure for success on this project is the ability to work closely with the community to jointly solve problems and respond to concerns of mixed waste treatment at Rocky Flats.

  8. Hydrodynamic aspects of a circulating fluidized bed with internals

    SciTech Connect (OSTI)

    Balasubramanian, N.; Srinivasakannan, C.

    1998-06-01

    An attempt is made to examine the influence of internals (baffles) in the riser of the circulating fluidized bed. Experiments are conducted in a circulating fluidized bed, having perforated plates with different free areas. It is noticed from the present work that a circulating fluidized bed having 45% free area gives uniform solids concentration and pressure drop along the length of the riser. In addition to the uniformity, the circulating fluidized bed with internals gives higher pressure drop (solids concentration) compared to a conventional circulating fluidized bed. For internals having 67.6% free area the pressure drop is higher at the lower portion of the riser compared to the upper portion, similar to a conventional circulating fluidized bed. For 30% free area plates the solids concentration varies axially within the stage and remains uniform from stage to stage.

  9. Fluidized Bed Technology - An R&D Success Story | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    line. The Nucla fluidized bed power plant in Colorado was operated in DOE's Clean Coal Technology Program. The technology progressed into larger scale utility applications...

  10. An experimental study of a vertical tube gas-fluidized bed

    E-Print Network [OSTI]

    Mandich, Kevin Matthew

    2010-01-01

    Temperature in a Bubbling Fluidized Bed: Simulations andfluidized bed of hollow microparticles prior to onset of bubbling.to the bubbling regime of the fluidized bed, while the

  11. Pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    NONE

    1998-03-01

    ThermoChem, under contract to the Department of Energy, conducted extensive research, development and demonstration work on a Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) to confirm that advanced technology can meet these performance objectives. The ThermoChem/MTCI PAFBC system integrates a pulse combustor with an atmospheric bubbling-bed type fluidized bed combustor (BFBC) In this modular configuration, the pulse combustor burns the fuel fines (typically less than 30 sieve or 600 microns) and the fluidized bed combusts the coarse fuel particles. Since the ThermoChem/MTCI PAFBC employs both the pulse combustor and the AFBC technologies, it can handle the full-size range of coarse and fines. The oscillating flow field in the pulse combustor provides for high interphase and intraparticle mass transfer rates. Therefore, the fuel fines essentially burn under kinetic control. Due to the reasonably high temperature (>1093 C but less than the temperature for ash fusion to prevent slagging), combustion of fuel fines is substantially complete at the exit of the pulse combustor. The additional residence time of 1 to 2 seconds in the freeboard of the PAFBC unit then ensures high carbon conversion and, in turn, high combustion efficiency. A laboratory unit was successfully designed, constructed and tested for over 600 hours to confirm that the PAFBC technology could meet the performance objectives. Subsequently, a 50,000 lb/hr PAFBC demonstration steam boiler was designed, constructed and tested at Clemson University in Clemson, South Carolina. This Final Report presents the detailed results of this extensive and successful PAFBC research, development and demonstration project.

  12. Pyrolysis reactor and fluidized bed combustion chamber

    DOE Patents [OSTI]

    Green, Norman W. (Upland, CA)

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  13. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  14. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  15. Combined fluidized bed retort and combustor

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Notestein, John E. (Morgantown, WV); Mei, Joseph S. (Morgantown, WV); Zeng, Li-Wen (Morgantown, WV)

    1984-01-01

    The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

  16. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H. (Mt. Lebanon, PA)

    1984-01-01

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  17. Predictive models of circulating fluidized bed combustors

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  18. Fundamentals of fluidized bed chemical processes

    SciTech Connect (OSTI)

    Yates, J.G.

    1983-01-01

    Chemical processes based on the use of fluidized solids, although widely used on an industrial scale for some four decades, are currently increasing in importance as industry looks for improved methods for handling and reacting solid materials. This book provides background necessary for an understanding of the technique of gas-solid fluidization. Contents: Some Fundamental Aspects of Fluidization-General Features of Gas-Solid Fluidization; Minimum Fluidization Velocity; Inter-particle forces; Liquid-Solid Fluidization; Bubbles; Slugging; Entrainment and Elutriation; Particle Movement; Bed Viscosity; Fluidization Under Pressure. Fluidized-Bed Reactor Models-ome Individual Models; Model Comparisons; Multiple Region Models. Catalytic Cracking-Process Developments Riser Cracking; Catalysis; Process Chemistry; Kinetics; Process Models. Combustion and Gasification-Plant Developments; Oil and Gas Combustion; Desulphurization; No/sub x/ Emissions; Coal Gassification. Miscellaneous Processes-Phthalic Anhydride (1,3-isobezofurandione); Acrylonitrile (prop-3-enenitrile); Vinyl Chloride (chloroethene); Titanium Dioxide; Uranium Processing; Sulphide Roasting; Indexes.

  19. Fluidized bed boiler having a segmented grate

    DOE Patents [OSTI]

    Waryasz, Richard E. (Longmeadow, MA)

    1984-01-01

    A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

  20. Behavior of fluidized beds similar to equilibrium states

    E-Print Network [OSTI]

    Kengo Ichiki; Hisao Hayakawa

    1997-04-25

    Systematic simulations are carried out based on the model of fluidized beds proposed by the present authors [K.Ichiki and H.Hayakawa, Phys. Rev. E vol.52, 658 (1995)]. From our simulation, we confirm that fluidization is a continuous transition. We also confirm the existence of two types of fluidized phases, the channeling phase and the bubbling phase. We find the close relations between the averaged behaviors in fluidized beds and quasi equilibrium states in dense liquids. In fluidized beds, (i) the flow rate plays the role of the effective temperature, and (ii) the existence of a kind of the fluctuation-dissipation relation is suggested.

  1. The backflow cell model for fluidized bed catalytic reactors 

    E-Print Network [OSTI]

    Ganapathy, E. V

    1967-01-01

    that the backmixing of gas in a small fluidized bed with high length to diameter rati. o is relatively small. Hence, it was recommended. that reaction rate studies in fluidized bed reactors be correlated on the basis oi' piston flow~ neglecting mixing. Nay (19... Major Subject Chemical En ineerin THE BACKFLOW CELL MODEL FOR FLUIDIZED BED CATALYTIC REACTORS A Thesis E. V. Ganapathy Approved as to style and content by: chairman of Committee ~H+d d D p t t Member Member) May 1967 SO THE BACKFLOW CELL...

  2. Gas phase hydrodynamics inside a circulating fluidized bed

    E-Print Network [OSTI]

    Moran, James C. (James Christopher)

    2001-01-01

    Circulating Fluidized Beds (CFB's) offer many advantages over traditional pulverized coal burners in the power generation industry. They operate at lower temperatures, have better environmental emissions and better fuel ...

  3. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

    1983-12-20

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  4. Development and applications of clean coal fluidized bed technology

    SciTech Connect (OSTI)

    Eskin, N.; Hepbasli, A. [Ege University, Izmir (Turkey). Faculty of Engineering

    2006-09-15

    Power generation in Europe and elsewhere relies heavily on coal and coal-based fuels as the source of energy. The reliance will increase in the future due to the decreasing stability of price and security of oil supply. In other words, the studies on fluidized bed combustion systems, which is one of the clean coal technologies, will maintain its importance. The main objective of the present study is to introduce the development and the applications of the fluidized bed technology (FBT) and to review the fluidized bed combustion studies conducted in Turkey. The industrial applications of the fluidized bed technology in the country date back to the 1980s. Since then, the number of the fluidized bed boilers has increased. The majority of the installations are in the textile sector. In Turkey, there is also a circulating fluidized bed thermal power plant with a capacity of 2 x 160 MW under construction at Can in Canakkale. It is expected that the FBT has had, or will have, a significant and increasing role in dictating the energy strategies for Turkey.

  5. Fluidized bed pyrolysis of terrestrial biomass feedstocks

    SciTech Connect (OSTI)

    Besler, S.; Agblevor, F.A.; Davis, M.F. [National Renewable Energy Lab., Golden, CO (United States)] [and others

    1994-12-31

    Hybrid poplar, switchgrass, and corn stover were pyrolyzed in a bench scale fluidized-bed reactor to examine the influence of storage time on thermochemical converting of these materials. The influence of storage on the thermochemical conversion of the biomass feedstocks was assessed based on pyrolysis product yields and chemical and instrumental analyses of the pyrolysis products. Although char and gas yields from corn stover feedstock were influenced by storage time, hybrid poplar and switchgrass were not significantly affected. Liquid, char, and gas yields were feedstock dependent. Total liquid yields (organic+water) varied from 58%-73% depending on the feedstock. Char yields varied from 14%-19% while gas yields ranged from 11%-15%. The chemical composition of the pyrolysis oils from hybrid polar feedstock was slightly changed by storage, however, corn stover and switchgrass feedstock showed no significant changes. Additionally, stored corn stover and hybrid poplar pyrolysis oils showed a significant decrease in their higher heating values compared to the fresh material.

  6. COMPUTATIONAL MODELING OF CIRCULATING FLUIDIZED BED REACTORS

    SciTech Connect (OSTI)

    Ibrahim, Essam A

    2013-01-09

    Details of numerical simulations of two-phase gas-solid turbulent flow in the riser section of Circulating Fluidized Bed Reactor (CFBR) using Computational Fluid Dynamics (CFD) technique are reported. Two CFBR riser configurations are considered and modeled. Each of these two riser models consist of inlet, exit, connecting elbows and a main pipe. Both riser configurations are cylindrical and have the same diameter but differ in their inlet lengths and main pipe height to enable investigation of riser geometrical scaling effects. In addition, two types of solid particles are exploited in the solid phase of the two-phase gas-solid riser flow simulations to study the influence of solid loading ratio on flow patterns. The gaseous phase in the two-phase flow is represented by standard atmospheric air. The CFD-based FLUENT software is employed to obtain steady state and transient solutions for flow modulations in the riser. The physical dimensions, types and numbers of computation meshes, and solution methodology utilized in the present work are stated. Flow parameters, such as static and dynamic pressure, species velocity, and volume fractions are monitored and analyzed. The differences in the computational results between the two models, under steady and transient conditions, are compared, contrasted, and discussed.

  7. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  8. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock & Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  9. An Analysis of the Use of Fluidized-Bed Heat Exchangers for Heat Recovery 

    E-Print Network [OSTI]

    Vogel, G. J.; Grogan, P. J.

    1980-01-01

    The principles of fluidized-bed operation and the factors affecting the performance of a fluidized-bed waste heat boiler (FBWHB) are discussed in detail. Factors included in the discussion are bed temperature and pressure, heat transfer coefficient...

  10. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    SciTech Connect (OSTI)

    Rokkam, Ram

    2012-11-02

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  11. Pulsed atmospheric fluidized bed combustion. Technical progress report, January 1995--April 1995

    SciTech Connect (OSTI)

    NONE

    1995-05-31

    Progress is reported on the design of a pulsed fluidized bed combustor and component, fabrication, and construction site activities.

  12. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

    1980-01-01

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  13. Pressurized fluidized-bed combustion technology exchange workshop

    SciTech Connect (OSTI)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  14. Coal-feeding mechanism for a fluidized bed combustion chamber

    DOE Patents [OSTI]

    Gall, Robert L. (Morgantown, WV)

    1981-01-01

    The present invention is directed to a fuel-feeding mechanism for a fluidized bed combustor. In accordance with the present invention a perforated conveyor belt is utilized in place of the fixed grid normally disposed at the lower end of the fluidized bed combustion zone. The conveyor belt is fed with fuel, e.g. coal, at one end thereof so that the air passing through the perforations dislodges the coal from the belt and feeds the coal into the fluidized zone in a substantially uniform manner.

  15. Fluidized-Bed Waste-Heat Recovery System Advances 

    E-Print Network [OSTI]

    Patch, K. D.; Cole, W. E.

    1986-01-01

    stream_source_info ESL-IE-86-06-09.pdf.txt stream_content_type text/plain stream_size 23561 Content-Encoding ISO-8859-1 stream_name ESL-IE-86-06-09.pdf.txt Content-Type text/plain; charset=ISO-8859-1 FLUIDIZED-BED WASTE-HEAT... RECOVERY SYSTEM ADVANCES Keith D. Patch William E. Cole Thermo Electron Corporation Waltham, Massachusetts ABSTRACT The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is a combustion air preheater designed for existing unrecuperated...

  16. Emergent Behavior in a Low-Order Fluidized-Bed Bubble Model

    E-Print Network [OSTI]

    Tennessee, University of

    Emergent Behavior in a Low-Order Fluidized-Bed Bubble Model John S. Halow National Energy of this type of model to describe the dynamics of voids in bubbling fluidized beds. The model considers vertical interactions between neighboring bubbles in fluidized beds. Emergent collective behavior is shown

  17. Characterizing the Hydrodynamics of Bubbling Fluidized Beds with Multivariate Pressure Measurements

    E-Print Network [OSTI]

    Tennessee, University of

    Characterizing the Hydrodynamics of Bubbling Fluidized Beds with Multivariate Pressure Measurements mounted on the walls of a bubbling fluidized bed. Our objective was to identify multivariate dynamic of bubbling fluidized beds with multivariate pressure measurements. 2000 AIChE Annual Meeting (Los Angeles

  18. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  19. Fluidized bed combustor and coal gun-tube assembly therefor

    DOE Patents [OSTI]

    Hosek, William S. (Mt. Tabor, NJ); Garruto, Edward J. (Wayne, NJ)

    1984-01-01

    A coal supply gun assembly for a fluidized bed combustor which includes heat exchange elements extending above the bed's distributor plate assembly and in which the gun's nozzles are disposed relative to the heat exchange elements to only discharge granular coal material between adjacent heat exchange elements and in a path which is substantially equidistant from adjacent heat exchange elements.

  20. Heat exchanger support apparatus in a fluidized bed

    DOE Patents [OSTI]

    Lawton, Carl W. (West Hartford, CT)

    1982-01-01

    A heat exchanger is mounted in the upper portion of a fluidized combusting bed for the control of the temperature of the bed. A support, made up of tubes, is extended from the perforated plate of the fluidized bed up to the heat exchanger. The tubular support framework for the heat exchanger has liquid circulated therethrough to prevent deterioration of the support.

  1. Current state of atmospheric fluidized-bed combustion technology

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This paper examines atmospheric fluidized-bed combustion (AFBC) technology, a coal burning method that has several environmental and technical advantages over the more conventional technologies, such as pulverized-coal methods. The AFBC approach injects an air stream into a boiler in such a way that it mixes with solid fuel and sorbent to create a dense phase region or fluidized bed. This method makes it possible to use a much wider range of low-quality fuels and to burn them at lower temperatures with less pollutant by-product. The paper presents a comprehensive overview of AFBC technology to date. It includes worldwide development of this technology since the 1950s necessary to meet ever-stricter emissions requirements while providing greater fuel flexibility.

  2. Combustion of refuse derived fuel in a fluidized bed

    SciTech Connect (OSTI)

    Piao, Guilin; Aono, Shigeru; Mori, Shigekatsu; Deguchi, Seiichi; Fujima, Yukihisa; Kondoh, Motohiro; Yamaguchi, Masataka

    1998-12-31

    Power generation from Refuse Derived Fuel (RDF) is an attractive utilization technology of municipal solid waste. To explain the behavior of RDF-fired fluidized bed incinerator, the commercial size RDF was continuously burnt in a 30 x 30 cm bubbling type fluidized-bed combustor. It was found that 12 kg/h of RDF feed rate was too high feed for this test unit and the Co level was higher than 500 ppm. However, 10 kg/h of RDF was a proper feed rate and the Co level was kept under 150 ppm. Secondary air injection and changing air ratio from the pipe grid were effective for the complete combustion of RDE. It was also found that HCl concentration in flue gas was controlled by the calcium component contained in RDF and its level was decreased with decreasing the combustor temperature.

  3. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  4. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  5. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  6. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  7. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  8. A NEW INTERPHASE FORCE IN TWO-PHASE FLUIDIZED BEDS

    SciTech Connect (OSTI)

    D. ZHANG; W. VANDERHEYDEN

    2001-05-01

    Mesoscale structures such as particle clusters have been observed both in experiments and in numerical simulations of circulating fluidized beds. In a numerical simulation, in order to account for the effects of such mesoscale structures, the computational grids have to be fine enough. The use of such fine grids is impractical in engineering applications due to excessive computational costs. To predict the macroscopic behavior of a fluidized bed with reasonable computation cost, they perform a second average over the averaged equations for two-phase flows. A mesoscale inter-phase exchange force is found to be the correlation of the particle volume fraction and the pressure gradient. This force is related to the mesoscale added mass of the two-phase flow. Typically, added mass for particle scale interactions is negligible in gas-solid flows since the gas density is small compared to density of solid particles. However, for a mesoscale structure, such as a bubble, the surrounding media is the mixture of gas and particles. The surrounding fluid density experienced by the mesoscale structure is the density of the surrounding mixture. Therefore, the added mass of a mesoscale structure, such as bubbles, cannot be neglected. The property of this new force is studied based on the numerical simulation of a fluidized bed using high grid resolution. It is shown that this force is important in the region where the particle volume fraction is high. The effects of the inhomogeneity to the interphase drag are also studied.

  9. Fluidized-bed combustion of scrap tires: Technical note

    SciTech Connect (OSTI)

    Shang, J.Y.; Mei, J.S.; Notestein, J.E.

    1981-10-01

    An introduction to fluidized-bed combustion (FBC) is presented in Section 2.0. Based on this discussion of its technical development, FBC is then presented as a means of scrap tire disposal. In Section 3.0, scrap tire disposal is reviewed in the categories of (1) physical applications, (2) chemical applications, (3) pyrolysis, and (4) incineration for thermal energy recovery. Scrap tire disposal is reviewed on the basis of (1) environmental acceptability, (2) conservation of resources, (3) impact on existing industries, (4) operational feasibility, and (5) special features. The focus of this report is the fluidized-bed incineration of scrap tires for thermal energy recovery. The factors that affect scrap tire combustion are discussed in Section 4.0. These factors are (1) agitation, (2) temperature, (3) excess air, (4) residence time, (5) feed uniformity, (6) solid waste handling, and (7) pollutants emission control. In reviewing these incineration processes, (1) fuel flexibility, (2) environmental acceptability, (3) combustion efficiency, and (4) operational reliability are discussed. The results from a tire incineration experiment conducted at the Morgantown Energy Technology Center are presented in Section 5.0, and a conceptual fluidized-bed combustor is discussed in Section 6.0. Future considerations in the FBC of scrap tires are discussed in Section 7.0. 8 refs., 6 figs., 6 tabs.

  10. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Strandberg, Gerald W. (Farragut, TN)

    1989-01-01

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  11. Fluidized-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor. 2 figs.

  12. Numerical and experimental studies of IFE target layering in a cryogenic fluidized bed

    E-Print Network [OSTI]

    Boehm, Kurt Julian

    2009-01-01

    most gas-solid fluidized beds show a bubbling or chuggingfluidized state which is governed by bubbling behavior, the prediction of the bed

  13. Dynamical Simulation of Fluidized Beds --- Hydrodynamically Interacting Granular Particles

    E-Print Network [OSTI]

    Kengo Ichiki; Hisao Hayakawa

    1995-03-01

    A numerical simulation of a gas-fluidized bed is performed without introduction of any empirical parameters. Realistic bubbles and slugs are observed in our simulation. It is found that the convective motion of particles is important for the bubbling phase and there is no convection in the slugging phase. From the simulation results, non-Gaussian distributions are found in the particle velocities and the relation between the deviation from Gaussian and the local density of particles is suggested. It is also shown that the power spectra of particle velocities obey power laws. A brief explanation on the relationship between the simulation results and the Kolmogorov scaling argument is discussed.

  14. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G. (Akron, OH); Weitzel, Paul S. (Canal Fulton, OH)

    1990-01-01

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  15. Wavy Instability in Liquid-Fluidized Beds Maxime Nicolas, John Hinch, and E lisabeth Guazzelli*,

    E-Print Network [OSTI]

    Hinch, John

    . Gas-fluidized beds are very unstable and rapidly attain a bubbling regime. In this regime, bubblesWavy Instability in Liquid-Fluidized Beds Maxime Nicolas, John Hinch, and EÄ lisabeth Guazzelli. The validity of the two-phase Newtonian model is then questioned. 1. Introduction To fluidize a bed

  16. Foam Control using a Fluidized Bed of Hydrophobic Particles by Clara Mata*

    E-Print Network [OSTI]

    Joseph, Daniel D.

    Foam Control using a Fluidized Bed of Hydrophobic Particles by Clara Mata* & D. D. Joseph may be strongly suppressed by fluidizing hydrophilic particles in the bubbly mixture below the foam different tests (particle-induced film rupture and foam shake test), but they did not use a fluidized bed

  17. Pulsed atmospheric fluidized bed combustion. Technical progress report, April 1992--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The general specifications for a Pulsed Atmospheric Fluidized Bed Combustor Design Report (PAFBC) plant are presented. The design tasks for the PAFBC are described in the following areas: Coal/Limestone preparation and feed system; pulse combustor; fluidized bed; boiler parts; and ash handling system.

  18. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOROF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOR F Iis fed into a hydro-gasifier reactor. One such process was

  19. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    Sibashis Banerjee; Alvin Chen; Rutton Patel; Dale Snider; Ken Williams; Timothy O'Hern; Paul Tortora

    2008-02-29

    The work detailed in this report addresses Enabling Technologies within Computational Technology by integrating a “breakthrough” particle-fluid computational technology into traditional Process Science and Engineering Technology. The work completed under this DOE project addresses five major development areas 1) gas chemistry in dense fluidized beds 2) thermal cracking of liquid film on solids producing gas products 3) liquid injection in a fluidized bed with particle-to-particle liquid film transport 4) solid-gas chemistry and 5) first level validation of models. Because of the nature of the research using tightly coupled solids and fluid phases with a Lagrangian description of the solids and continuum description of fluid, the work provides ground-breaking advances in reactor prediction capability. This capability has been tested against experimental data where available. The commercial product arising out of this work is called Barracuda and is suitable for a wide (dense-to-dilute) range of industrial scale gas-solid flows with and without reactions. Commercial applications include dense gas-solid beds, gasifiers, riser reactors and cyclones.

  20. Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-34 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed

    E-Print Network [OSTI]

    Laughlin, Robert B.

    : - Bubbling fluidized bed combustion (BFBC) is a combustion method where the velocity of the gasflow upwards fluidized bed combustion, where the interaction between gas and particles is more intensive than in bubbling fluidized bed combustion In fluidized bed combustion, the combustion takes place in a bed of particles

  1. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Petersen, James N. (Moscow, ID); Davison, Brian H. (Knoxville, TN)

    1996-01-01

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, as larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor.

  2. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, C.D.; Petersen, J.N.; Davison, B.H.

    1996-07-09

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, and larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. 8 figs.

  3. Empirical models of emissions and energy efficiencies of coal-fired fluidized bed power plants

    E-Print Network [OSTI]

    Gruhl, Jim

    Mass and energy balances of fluidized bed energy technologies are to a significant degree dependent upon the specific design being investigated. It is difficult to make any generally accurate comments. about these balances. ...

  4. Modeling of char oxidation in fluidized bed biomass gasifiers : effects of transport and chemical kinetics

    E-Print Network [OSTI]

    Brooks, Amelia (Amelia Samek)

    2015-01-01

    Technologies for the conversion of biomass to liquid fuels are important to develop because the demand for liquid fuels remains unchanged even with the necessity of limiting dependence on fossil fuels. Fluidized Bed Biomass ...

  5. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University 

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01

    Operation of the 100,000 lb/hr capacity, coal fired fluidized bed steam generator at Georgetown University began in July 1979. This project, which was co-funded by Georgetown University and the U. S. Department of Energy, ...

  6. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  7. FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL

    SciTech Connect (OSTI)

    Williams, M

    2008-05-09

    Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

  8. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, J.; Koskinen, J.

    1995-08-22

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  9. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI); Koskinen, Jari (Karhula, FI)

    1995-01-01

    Hot gases from a pressurized fluidized bed reactor system are purified. Under superatmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a flitrate cake on the surface of the separator, and a reducing agent--such as an NO.sub.x reducing agent (like ammonia), is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1-20 cm/s) during passage of the gas through the filtrate cake while at superatmospheric pressure. Separation takes place within a distinct pressure vessel the interior of which is at a pressure of about 2-100 bar, and-introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine).

  10. Repowering with pressurized fluidized-bed combustion units

    SciTech Connect (OSTI)

    Goidich, S.J. ); Rubow, L.N. ); Kumar, S. . Environmental Services and Technologies Div.); Mukherjee, D. ); Childress, N.B. )

    1991-05-01

    Turbocharged pressurized fluidized bed combustion (PFBC) power plants operating with a gas turbine inlet temperature lower than 800{degrees}F can produce electricity more efficiently (34.2 vs. 33.5% net plant efficiency) and at a lower cost of electricity (87.8 vs. 96. 6 mill/kWh over 30 years) than conventional pulverized-coal-fired plants with scrubbers. Since the PFBC process produces lower NO{sub x} emissions than conventional pulverized-coal combustion systems and captures sulfur as part of the combustion process, and since major equipment components can be shop-assembled and shipped by barge, retrofit of an existing unit with a turbocharged PFBC boiler can be a cost-effective means for extending the life of the unit and meeting NSPS without retrofitting flue gas desulfurization systems. Using the Wisconsin Electric Power Company's Port Washington Unit 5 as an example, preliminary engineering and economic evaluations were made to investigate the merits of turbocharged PFBC retrofits. This report describes the conceptual designs of the new, major plant components; discusses how the new components are integrated with the existing balance-of-plant equipment; describes the proposed plant control system; and presents an overall economic evaluation. Because design and economic evaluations were prepared on the basis of a commercial design, first-of-a-kind costs and test programs are not included. 5 refs., 58 figs., 55 tabs.

  11. Task 3.8 - pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    NONE

    1995-03-01

    The focus of this work on pressurized fluidized-bed combustion (PFBC) is the development of sorbents for in-bed alkali control. The goal is to generate fundamental process information for development of a second-generation PFBC. Immediate objectives focus on the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals. The studies reported here focus on emission control strategies applied in the bed. Data from shakedown testing, alkali sampling, sulfur sorbent performance tests, and refuse-derived fuel (RDF) and lignite combustion tests are presented in detail. Initial results from the characterization of alkali gettering indicate that in-bed getters can remove a significant amount of alkali from the bed. Using kaolin as a sorbent, sodium levels in the flue gas were reduced from 3.6 ppm to less than 0.22 ppm. Sulfur was also reduced by 60% using the kaolin sorbent. Preliminary sulfur sorbent testing, which was designed to develop a reliable technique to predice sorbent performance, indicate that although the total sulfur capture is significantly lower than that observed in a full-scale PFBC, the emission trends are similar. RDF and RDF-lignite fuels had combustion efficiencies exceeding 99.0% in all test cases. Sulfur dioxide emission was significantly lower for the RDF fuels than for lignite fuel alone. Nitrogen oxide emission was also lower for the RDF-based fuels than for the lignite fuel. Both emission gases were well below current regulatory limits. Carbon monoxide and hydrocarbon emissions appeared to be slightly higher for the fuels containing RDF, but were below 9 ppm for the worst case. Analysis of volatile organic compound emission does not indicate an emission problem for these fuels. Chromium appears to be the only RCRA metal that might present some disposal problem; however, processing of the RDF with the wet resource recovery method should reduce chromium levels. 2 refs., 13 figs., 15 tabs.

  12. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  13. Method and apparatus for improving heat transfer in a fluidized bed

    DOE Patents [OSTI]

    Lessor, Delbert L. (Richland, WA); Robertus, Robert J. (Richland, WA)

    1990-01-01

    An apparatus contains a fluidized bed that includes particles of different triboelectrical types, each particle type acquiring an opposite polarity upon contact. The contact may occur between particles of the two types or between particles of etiher type and structure or fluid present in the apparatus. A fluidizing gas flow is passed through the particles to produce the fluidized bed. Immersed within the bed are electrodes. An alternating EMF source connected to the electrodes applies an alternating electric field across the fluidized bed to cause particles of the first type to move relative to particles of the second type and relative to the gas flow. In a heat exchanger incorporating the apparatus, the electrodes are conduits conveying a fluid to be heated. The two particle types alternately contact each conduit to transfer heat from a hot gas flow to the second fluid within the conduit.

  14. Particle simulation of vibrated gas-fluidized beds of cohesive fine powders

    E-Print Network [OSTI]

    Sung Joon Moon; I. G. Kevrekidis; S. Sundaresan

    2006-08-09

    We use three-dimensional particle dynamics simulations, coupled with volume-averaged gas phase hydrodynamics, to study vertically vibrated gas-fluidized beds of fine, cohesive powders. The volume-averaged interstitial gas flow is restricted to be one-dimensional (1D). This simplified model captures the spontaneous development of 1D traveling waves, which corresponds to bubble formation in real fluidized beds. We use this model to probe the manner in which vibration and gas flow combine to influence the dynamics of cohesive particles. We find that as the gas flow rate increases, cyclic pressure pulsation produced by vibration becomes more and more significant than direct impact, and in a fully fluidized bed this pulsation is virtually the only relevant mechanism. We demonstrate that vibration assists fluidization by creating large tensile stresses during transient periods, which helps break up the cohesive assembly into agglomerates.

  15. Design and performance of a high-pressure Fischer-Tropsch fluidized bed reactor

    SciTech Connect (OSTI)

    Weimer, A.W.; Quarderer, G.J.; Cochran, G.A.; Conway, M.M. )

    1988-01-01

    A 900 kg/day, CO/H/sub 2/, high-pressure, fluidized bed, pilot reactor was designed from first principles to achieve high reactant conversions and heat removal rates for the Fischer-Tropsch (F-T) synthesis of liquefied petroleum gases (LPG's). Suppressed bubble growth at high pressure allowed high reactant conversions which nearly matched those obtained at identical conditions in a lab scale fixed bed reactor. For GHSV approximately 1400 hr/sup -1/ and T = 658 {Kappa} at P approximately 7000 {kappa}Pa, reactant conversion exceeded 75%. The reactor heat removal capability exceeded twice design performance with the fluidized bed easily operating under thermally stable conditions. The fluidized catalyst was a potassium promoted, molybdenum on carbon (Mo/{Kappa}/C) catalyst which did not produce any detrimental waxy products. Long catalyst lifetimes of 1000 hrs on steam between regenerations allowed the fluidized bed to be operated in a batch mode.

  16. Atmospheric fluidized bed combustion (AFBC) plants: an operations and maintenance study

    SciTech Connect (OSTI)

    Jack A. Fuller; Harvie Beavers; Robert Bessette [West Virginia University, Morgantown, WV (United States). College of Business and Economics

    2006-06-15

    The authors analyzed data from a fluidized bed boiler survey distributed during the spring of 2003 to develop appropriate AFBC (Atmospheric Fluidized Bed Combustion) performance benchmarks. The survey was sent to members of CIBO (Council of Industrial Boiler Owners), who sponsored the survey, as well as to other firms who had an operating AFBC boiler on-site. There were three primary purposes for the collection and analysis of the data contained in this fluidized bed boiler survey: (1) To develop AFBC benchmarks on technical, cost, revenue, and environmental issues; (2) to inform AFBC owners and operators of contemporary concerns and issues in the industry; (3) to improve decision making in the industry with respect to current and future plant start-ups and ongoing operations.

  17. Numerical Analysis of using a Fluidized Bed as a Prototypic Mass Production Device for IFE Target Layering

    E-Print Network [OSTI]

    Raffray, A. René

    of the target to reduce the heat transfer onto the target during injection into the reactor chamber1 . After several topics, including the effect of unbalanced spheres on the bed behavior and ultimately for the fluidized bed model, as it affects the unbalance of the individual spheres. Keywords- Fluidized bed, IFE

  18. Exploratory and basic fluidized-bed combustion studies. Quarterly report, January-March 1980

    SciTech Connect (OSTI)

    Johnson, I.; Myles, K.M.; Swift, W.M.

    1980-12-01

    This work supports development studies for both atmospheric and pressurized fluidized-bed coal combustion. Laboratory and process development studies are aimed at providing needed information on limestone utilization, removal of particulates and alkali metal compounds from the flue gas, control of SO/sub 2/ and trace pollutants emissions, and other aspects of fluidized-bed combustion. This report presents information on: (1) the development of a limestone utilization predictive methodology, (2) studies of particle breakup and elutriation, (3) basic studies on limestone sulfation enhancement by hydration, (4) studies of the kinetics of the hydration process, and (5) an investigation of various hydration process concepts.

  19. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  20. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  1. Production of activated carbon from coconut shell char in a fluidized bed reactor

    SciTech Connect (OSTI)

    Sai, P.M.S.; Ahmed, J. [Bhabha Atomic Research Centre, Kalpakkam (India). Centralised Waste Management Facility; Krishnaiah, K. [Indian Inst. of Tech., Madras (India). Dept. of Chemical Engineering

    1997-09-01

    Activated carbon is produced from coconut shell char using steam or carbon dioxide as the reacting gas in a 100 mm diameter fluidized bed reactor. The effect of process parameters such as reaction time, fluidizing velocity, particle size, static bed height, temperature of activation, fluidizing medium, and solid raw material on activation is studied. The product is characterized by determination of iodine number and BET surface area. The product obtained in the fluidized bed reactor is much superior in quality to the activated carbons produced by conventional processes. Based on the experimental observations, the optimum values of process parameters are identified.

  2. A Fluidized Bed Chiller: A New Approach in Making Slush-Ice 

    E-Print Network [OSTI]

    Klaren, D. G.; Van Der Meer, J. S.

    1991-01-01

    stream_source_info ESL-IE-91-06-05.pdf.txt stream_content_type text/plain stream_size 29778 Content-Encoding ISO-8859-1 stream_name ESL-IE-91-06-05.pdf.txt Content-Type text/plain; charset=ISO-8859-1 A FLUIDIZED BED... CHILLER: A NEW APPROACH IN MAKING SLUSH-ICE Dr.Ir. D.G. Klaren M.Sc. Technical Director Gebr. Scheffers B.V. Schiedam, The Netherlands ABSTRACT A fluidized bed heat exchanger already successfully applied for heat transfer applications involving...

  3. Evaluation of models for the prediction of fluidized-bed reactor performance 

    E-Print Network [OSTI]

    Frederick, John Michael

    1980-01-01

    of typical gas bubble L4] Fig. 8 Sketch of two bubbles coalescing in a fluidized bed L4] presence of splitting, the coalescence quality tends to produce a wide d1stribution of bubble sizes throughout the reactor. A parameter has been dev1sed that 1s... reactor Modes of fluidizaiton Geldhart's classification of fluidized bed particles . Distributors commonly used in industry Stages of bubble formation Idealised jet-to-bubble emergance pattern Sketch of a typical gas bubble ~Pa e 13 18 Sketch...

  4. Characterization of Biofilm in 200W Fluidized Bed Reactors

    SciTech Connect (OSTI)

    Lee, Michelle H.; Saurey, Sabrina D.; Lee, Brady D.; Parker, Kent E.; Eisenhauer, Emalee ER; Cordova, Elsa A.; Golovich, Elizabeth C.

    2014-09-29

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry evaluations, a more complete understanding of the balance between system additions (nutrients, groundwater) and biology can be achieved, thus increasing long-term predictions of performance. These analyses uniquely provide information that can be used in optimizing the overall performance, efficiency, and stability of the system both in real time as well as over the long-term, as the system design is altered or improved and/or new streams are added.

  5. Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial

    E-Print Network [OSTI]

    . Stabilization of excess activated and EBPR sludge in an anaerobic digester results in significant releases of nuElectrochemical struvite precipitation from digestate with a fluidized bed cathode microbial conditions. Soluble phosphorus removal using digester effluent ranged from 70 to 85% with current generation

  6. How Bubbly Mixtures Foam and Foam Control Using a Fluidized Bed

    E-Print Network [OSTI]

    Joseph, Daniel D.

    How Bubbly Mixtures Foam and Foam Control Using a Fluidized Bed by Jos e Guiti anz Daniel Joseph to the top because it has a higher gas fraction than the bubbly mixture from which it comes. The high gas slit bubble reactor which when used with aqueous anionic surfactants gives rise to foam. This reactor

  7. Investigation of heat transfer and combustion in the advanced fluidized bed combustor (FBC)

    SciTech Connect (OSTI)

    Dr. Seong W. Lee

    1998-10-01

    The objective of this project is to predict the heat transfer and combustion performance in newly-designed fluidized bed combustor (FBC) and to provide the design guide lines and innovative concept for small-scale boiler and furnace. The major accomplishments are summarized.

  8. Experimental development of a multi-solid fluidized bed reactor concept

    SciTech Connect (OSTI)

    Litt, R.D.; Paisley, M.A.; Tewksbury, T.L.

    1990-02-01

    Battelle's Columbus Division is developing a coal mild gasification process based upon the Multi-Solid Fluidized bed reactor system to produce high quality liquid and gaseous products. This process uses 2-stages to gasify coal at high throughputs to produce a range of products in compact reactors without requiring an oxygen plant. 8 refs., 14 figs., 12 tabs.

  9. FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    HEWITT WM

    2011-04-08

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

  10. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1982-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  11. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1983-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  12. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion system. Final technical report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-11-01

    Research is presented on erosion and corrosion of fluidized bed combustor component materials. The characteristics of erosion of in-bed tubes was investigated. Anti-corrosion measures were also evaluated.

  13. The design of a fluidized bed for testing of a robotic burrowing device which mimics razor clams

    E-Print Network [OSTI]

    Dorsch, Daniel Scott

    2012-01-01

    This thesis reviews the design of a fluidized bed test setup for testing digging kinematics of RoboClam, a burrowing device based on Atlantic Razor Clams. This test bed allows for in-lab testing in an environment covered ...

  14. The development of a cyclonic combustor for high particulate, low caloric value gas produced by a fluidized bed 

    E-Print Network [OSTI]

    Cardenas, Manuel Moises

    1985-01-01

    THE DEVELOPMENT OF A CYCLONIC COMBUSTOR FOR HIGH PARTICULATE, LOW CALORIC VALUE GAS PRODUCED BY A FLUIDIZED BED A Thesis by MANUEL MOISES CARDENAS JR. Submitted to the Graduate College of Texas ALM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1985 Major Subject: Mechanical Engineering THE DEVELOPMENT OF A CYCLONIC COMBUSTOR FOR HIGH PARTICULATE, LOW CALORIC VALUE GAS PRODUCED BY A FLUIDIZED BED A Thesis MANUEL MOISES CARDENAS JR...

  15. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; Songgeng Li

    2006-04-01

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2006 through March 31, 2006. Work was performed on the following activities. First, the fabrication and manufacture of the CFBC Facility were completed. The riser, primary cyclone and secondary cyclone of Circulating Fluidized Bed (CFB) Combustor have been erected. Second, the Mercury Control Workshop and the Grand Opening of Institute for Combustion Science and Environmental Technology (ICSET) were successfully held on February 22 and 23, 2006, respectively. Third, effects of hydrogen chlorine (HCl) and sulfur dioxide (SO{sub 2}) on mercury oxidation were studied in a drop tube reactor. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  16. Proceedings of the sixth international conference on fluidized bed combustion. Volume II. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. The papers covered recent developments in atmospheric and pressurized fluidized-bed combustion, especially the design, operation and control of pilot and demonstration plants. The cleanup of combustion products and the erosion, corrosion and fouling of gas turbines was emphasized also. Fifty-five papers from Volume 2 of the proceedings have been entered individually into EDB and ERA; five papers had been entered previously from other sources. (LTN)

  17. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  18. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Kunlei Liu; John T. Riley

    2004-01-01

    The purpose of this report is to summarize the progress made on the project ''Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion (CFBC) System'' in this quarter (September-December of 2003). The main tasks in this quarter consisted of the following four parts. First, all documents for managing this project have been prepared and sent to the Office of Project Management at the US Department of Energy's (DOE's) National Energy Technology Laboratory (NETL). Second, plans for the renovation of space for a new combustion laboratory for the CFBC system has progressed smoothly. Third, considerable progress in the design of the CFBC system has been made. Finally, a lab-scale simulated fluidized-bed combustion facility has been set up in order to make some fundamental investigations of the co-firing of coal with waste materials in the next quarter. Proposed work for the next quarter has been outlined in this report.

  19. Design and performance of a fluidized-bed incinerator for TRU combustible wastes

    SciTech Connect (OSTI)

    Meile, L.J.; Meyer, F.G.

    1982-01-01

    Problems encountered in the incineration of glovebox generated waste at Rocky Flats Plant (RFP) led to the development of a fluidized-bed incineration (FBI) system for transuranic (TRU) combustible wastes. Laboratory and pilot-scale testing of the process preceded the installation of an 82-kg/h production demonstration incinerator at RFP. The FBI process is discussed, and the design of the demonstration incinerator is described. Operating experience and process performance for both the pilot and demonstration units are presented.

  20. Power plant computer aided design software char properties generated by a fluidized bed gasifier 

    E-Print Network [OSTI]

    Siebold, Walter Joachim

    1987-01-01

    POWER PLANT COMPUTER AIDED DESIGN SOFTWARE CHAR PROPERTIES GENERATED BY A FLUIDIZED BED GASIFIER A Thesis by WALTER JOACHIM SIEBOLD Submitted to the Graduate College of Texas ASM University In partial fulfillment of the requirements... incorporates the application of many engineering disciplines. Some of the design parameters are company's well kept secrets. However, using basic engineering fundamentals, a rough power plant layout can be designed. The power plant design shoul d star...

  1. Pulsed atmospheric fluidized bed combustion. Technical progress report, January 1992--March 1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    During this first quarter, a lab-scale water-cooled pulse combustor was designed, fabricated, and integrated with old pilot-scale PAFBC test systems. Characterization tests on this pulse combustor firing different kinds of fuel -- natural gas, pulverized coal and fine coal -- were conducted (without fluidized bed operation) for the purpose of finalizing PAFBC full-scale design. Steady-state tests were performed. Heat transfer performance and combustion efficiency of a coal-fired pulse combustor were evaluated.

  2. Proceedings of the sixth international conference on fluidized bed combustion. Volume III. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. Forty-five papers from Vol. III of the proceedings have been entered individually into EDB and ERA. Two papers had been entered previously from other sources. (LTN)

  3. Automatic control of air to fuel ratio in a fluidized bed gasifier 

    E-Print Network [OSTI]

    Ling, Peter P.

    1984-01-01

    Co. , 1982). In the past decade digital computers have been produced which can improve the performance of electromechanical system for complex processes. Control in Gasifier Operation In a coal gasification system, although no automatic A/F ratio... in the gasifier/combustor furnace were computed. However, no A/F ratio control was attempted in their study. ln Exxon's batch fluidized bed combustion unit (Yaverbaum, 1977), pulverized coal was pneumatically injected into the unit. The fuel rate...

  4. Analysis and optimized design of airlocks for fluidized bed gasifier fuel feed systems 

    E-Print Network [OSTI]

    Nuboer, Benito Frans

    1991-01-01

    influence the total cost of the conversion system. Based on the experience gained in the design and operation of five feeding systems for gasifiers, Miles concluded that three individual operations are required: a) introduction of the feed stock into a...ANALYSIS AND OPTIMIZED DESIGN OF AIRLOCKS FOR FLUIDIZED BED GASIFIER FUEL FEED SYSTEMS A Thesis by BENITO FRANS NUBOER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

  5. Proceedings of the Sixth International Conference on Fluidized Bed Combustion. Volume 1. Plenary sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held at the Atlanta Hilton, Atlanta, Georgia, April 9-11, 1980. The papers in this volume involved presentation of the research and development programs of the US (US DOE, TVA, EPRI and US EPA), United Kingdom, Federal Republic of Germany and the People's Republic of China. Eight papers from Vol. 1 (Plenary Sessions) of the proceedings have been entered individually into EDB and ERA. (LTN)

  6. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  7. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  8. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  9. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G.; Gerritsen, W.; Stewart, A.; Robinson, K.

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  10. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. ); Gerritsen, W.; Stewart, A.; Robinson, K. )

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  11. Experimental and computational studies of hydrodynamics in three-phase and two-phase fluidized beds

    SciTech Connect (OSTI)

    Bahary, M.

    1994-12-01

    The objective of the present study was to investigate the hydrodynamics of three-phase fluidized beds, their rheology, and experimentally verify a predictive three fluid hydrodynamic model developed at the Illinois Institute of Technology, Chicago. The recent reviews show that there exist no such models in the literature. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid, and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. In this thesis, a three fluid model is presented. The input into the model can be particulate viscosities either measured with a Brookfield viscometer or derived using the mathematical techniques of kinetic theory of granular flows pioneered by Savage and others. The computer simulation of a three-phase fluidized bed in an asymmetric mode qualitatively predicts the gas, liquid and solid hold-ups (volume fractions) and flow patterns in the industrially important churn-turbulent (bubbly coalesced) regimes. The computations in a fluidized bed with a symmetric distributor incorrectly showed no bubble coalescence. A combination of X-ray and {gamma}-ray densitometers was used to measure the solids and the liquid volume fractions in a two dimensional bed in the bubble coalesced regime. There is a good agreement between the theory for an asymmetric distributor and the experiments.

  12. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-06-30

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

  13. Method of removing sulfur emissions from a fluidized-bed combustion process

    DOE Patents [OSTI]

    Vogel, Gerhard John (Elmhurst, IL); Jonke, Albert A. (Elmhurst, IL); Snyder, Robert B. (Naperville, IL)

    1978-01-01

    Alkali metal or alkaline earth metal oxides are impregnated within refractory support material such as alumina and introduced into a fluidized-bed process for the combustion of coal. Sulfur dioxide produced during combustion reacts with the metal oxide to form metal sulfates within the porous support material. The support material is removed from the process and the metal sulfate regenerated to metal oxide by chemical reduction. Suitable pore sizes are originally developed within the support material by heat-treating to accommodate both the sulfation and regeneration while still maintaining good particle strength.

  14. A simplified model for the combustion of coal in a continuous flow fluidized bed 

    E-Print Network [OSTI]

    Richardson, Thomas Wade

    1982-01-01

    Calibration Numbers. 120 LIST OF FIGURES ~Fi ure ~Pa e 1 Modes of Fluidization. 2 Liquidlike Behavior of Fluidized Beds. 3 Continuous Reaction Model. 12 4 Shrinking Core Model 5 Two-Film Model. 6 Differential Control Volume. 13 14 34 7 Proximate... for approximating polynomial outside surface area (m ), (chapter 3 only) cross-sectional Area of the bed (cml), (chapter 4 only) surface area normal to the direction of heat flow (mt) boundary within which the element is defined frequency factor constant molar...

  15. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, October 1992--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Design and Engineering of most components in the Pulsed Atmospheric Fluidized Bed System was completed prior to September 1992. The components remaining to be designed at that time were: Aerovalves for the Pulse Combustor; Gas and coal injectors for the Pulse Combustor; Lines for PC tailpipes; Air plenum and inlet silencer; Refractory lined hot gas duct connecting outlet hot cyclone to boiler; Structure and platforms, and ladders around PAFBC vessel access and major equipment. Design work is currently in progress on all of the above components. Items 1, 2, 3 and 4 are 50% completed, and items 5 & 6 are 75% complete.

  16. Fluidized bed heat exchanger with water cooled air distributor and dust hopper

    DOE Patents [OSTI]

    Jukkola, Walfred W. (Westport, CT); Leon, Albert M. (Mamaroneck, NY); Van Dyk, Jr., Garritt C. (Bethel, CT); McCoy, Daniel E. (Williamsport, PA); Fisher, Barry L. (Montgomery, PA); Saiers, Timothy L. (Williamsport, PA); Karstetter, Marlin E. (Loganton, PA)

    1981-11-24

    A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

  17. Concept for a super-clean super-efficient pressurized fluidized-bed combustion system

    SciTech Connect (OSTI)

    Mollott, D.J.; Reed, M.

    1994-12-31

    A paper study for a highly efficient, environmentally benign, coal-fired electric power generation system, is presented. This system falls in the category of pressurized fluidized-bed combustion (PFBC) systems which has been dubbed super-clean super-efficient PFBC`s. The system presented starts with the second-generation PFBC concept and adds on advanced gas turbine, a solid oxide fuel cell, a supercritical steam cycle, a second low-temperature rankine cycle which pulls energy from the steam condenser, and inlet air cooling. The thermodynamic efficiency of the system is calculated to be 61.8 percent based on higher heating value (HHV).

  18. Performance and gas cleanup criterion for a cotton gin waste fluidized-bed gasifier 

    E-Print Network [OSTI]

    Craig, Joe David

    1980-01-01

    to gasify cottin gin waste. General objectives are: 1) Design and construct a fluidized-bed gasification reactor based on results of a study by Groves (1979). 2) Evaluate performance of the scaled up reactor based on Groves' empirical prediction equation... of Groves (1979). A gasifier of this type would supply about 238 megajoules of heat per hour based on converting 90 percent of the produced gas to heat. If the produced gas were used in an internal combustion engine with 20 per- e nt conversion effic...

  19. In-bed tube bank for a fluidized-bed combustor

    DOE Patents [OSTI]

    Hemenway, Jr., Lloyd F. (Morgantown, WV)

    1990-01-01

    An in-bed tube bank (10) for a fluidized bed combustor. The tube bank (10) of the present invention comprises one or more fluid communicating boiler tubes (30) which define a plurality of selectively spaced boiler tube sections (32). The tube sections (32) are substantially parallel to one another and aligned in a common plane. The tube bank (10) further comprises support members (34) for joining adjacent tube sections (32), the support members (34) engaging and extending along a selected length of the tube sections (32) and spanning the preselected space therebetween.

  20. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  1. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  2. IEEE TRANSACTIONS ON CONTROL SYSTEMS TECHNOLOGY, VOL. 8, NO. 2, MARCH 2000 247 A Model of a Bubbling Fluidized Bed Combustor

    E-Print Network [OSTI]

    Campi, Marco

    Prandoni Abstract--Fluidized bed techniques are employed in coal com- bustion power plants, because an appearance in the power plant realm. Compared to a conventional power plant equipped with pollutant abatement, because of the wide contact surface between solid and gas. Known since the 1920's, fluidized bed

  3. Technical and economic assessment of fluidized bed augmented compressed air energy storage system. Volume III. Preconceptual design

    SciTech Connect (OSTI)

    Giramonti, A.J.; Lessard, R.D.; Merrick, D.; Hobson, M.J.

    1981-09-01

    A technical and economic assessment of fluidized bed combustion augmented compressed air energy storage systems is presented. The results of this assessment effort are presented in three volumes. Volume III - Preconceptual Design contains the system analysis which led to the identification of a preferred component configuration for a fluidized bed combustion augmented compressed air energy storage system, the results of the effort which transformed the preferred configuration into preconceptual power plant design, and an introductory evaluation of the performance of the power plant system during part-load operation and while load following.

  4. Predictive models of circulating fluidized bed combustors. 12th technical progress report

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  5. Atmospheric fluidized bed combustion for small scale market sectors. Final report

    SciTech Connect (OSTI)

    Ashworth, R.A.; Plessinger, D.A.; Sommer, T.M. [Energy and Environmental Research Corp., Orville, OH (United States); Keener, H.M. [Ohio Agricultural Research and Development Center, OH (United States); Webner, R.L. [Will-Burt Co., Orrville, OH (United States)

    1997-03-31

    The objective of this project was to demonstrate and promote the commercialization of coal-fired atmospheric fluidized bed combustion (AFBC) systems, with limestone addition for SO{sub 2} emissions control and a baghouse for particulate emissions control. This AFBC system was targeted for small scale industrial-commercial-institutional space and process heat applications. A cost effective and environmentally acceptable AFBC technology in this size range would displace a considerable amount of gas/oil with coal while resulting in significant total cost savings to the owner/operators. In the Proof-of-Concept Phase, a 2.2 x 10{sup 6} Btu/hr unit was installed and successfully operated at Cedar Lane Farms (CLF), a commercial nursery in Ohio. The heat from the fluidized bed was used to heat hot water which was recirculated through greenhouses for cool weather heating. The system was designed to be fully automated with minimal operator attention required. The AFBC system installed at CLF was an improved design that incorporated flyash/sorbent reinjection and an underbed feed system to improve limestone utilization. With these additions it was possible to lower the Ca/S ratio from {approximately} 3.0 to 2.0, and still maintain an SO{sub 2} emissions level of 1.2 lb/10{sup 6} Btu when burning the same high sulfur Ohio coal tested at OARDC.

  6. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Songgeng Li; John T. Riley

    2005-10-01

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2005 through September 30, 2005. The following tasks have been completed. First, the construction of the Circulating Fluidized-Bed (CFB) Combustor Building was completed. The experimental facilities have been moved into the CFB Combustor Building. Second, the fabrication and manufacture of the CFBC Facility is in the final stage and is expected to be completed before November 30, 2005. Third, the drop tube reactor has been remodeled and installed to meet the specific requirements for the investigation of the effects of flue gas composition on mercury oxidation. This study will start in the next quarter. Fourth, the effect of sulfur dioxide on molecular chlorine via the Deacon reaction was investigated. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  7. Simulation of NOx emission in circulating fluidized beds burning low-grade fuels

    SciTech Connect (OSTI)

    Afsin Gungor

    2009-05-15

    Nitrogen oxides are a major environmental pollutant resulting from combustion. This paper presents a modeling study of pollutant NOx emission resulting from low-grade fuel combustion in a circulating fluidized bed. The simulation model accounts for the axial and radial distribution of NOx emission in a circulating fluidized bed (CFB). The model results are compared with and validated against experimental data both for small-size and industrial-size CFBs that use different types of low-grade fuels given in the literature. The present study proves that CFB combustion demonstrated by both experimental data and model predictions produces low and acceptable levels of NOx emissions resulting from the combustion of low-grade fuels. Developed model can also investigate the effects of different operational parameters on overall NOx emission. As a result of this investigation, both experimental data and model predictions show that NOx emission increases with the bed temperature but decreases with excess air if other parameters are kept unchanged. 37 refs., 5 figs., 5 tabs.

  8. Pressurized Fluidized Bed Combustion Second-Generation System Research and Development

    SciTech Connect (OSTI)

    A. Robertson; D. Horazak; R. Newby; H. Goldstein

    2002-11-01

    Research is being conducted under United States Department of Energy (DOE) Contract DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant--called a Second-Generation or Advanced Pressurized Circulating Fluidized Bed Combustion (APCFB) plant--offers the promise of efficiencies greater than 45% (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized-coal-fired plants with scrubbers. The APCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed boiler (PCFB), and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2300 F and higher. A conceptual design was previously prepared for this new type of plant and an economic analysis presented, all based on the use of a Siemens Westinghouse W501F gas turbine with projected carbonizer, PCFB, and topping combustor performance data. Having tested these components at the pilot plant stage, the referenced conceptual design is being updated to reflect more accurate performance predictions together with the use of the more advanced Siemens Westinghouse W501G gas turbine and a conventional 2400 psig/1050 F/1050 F/2-1/2 in. steam turbine. This report describes the updated plant which is projected to have an HHV efficiency of 48% and identifies work completed for the October 2001 through September 2002 time period.

  9. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan, Kunlei Liu; John T. Riley

    2004-07-30

    This report presents the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the quarter April 1--June 30, 2004. The following tasks have been completed. First, the final specifications for the renovation of the new Combustion Laboratory and the construction of the CFB Combustor Building have been delivered to the architect, and invitations for construction bids for the two tasks have been released. Second, the component parts of the CFBC system have been designed after the design work for assembly parts of the CFBC system was completed. Third, the literature pertaining to Polychlorinated Dibenzo-p-Dioxins (PCDD) and Polychlorinated Dibenzofurans (PCDF) released during the incineration of solid waste, including municipal solid waste (MSW) and refuse-derived fuel (RDF) have been reviewed, and an experimental plan for fundamental research of MSW incineration on a simulated fluidized-bed combustion (FBC) facility has been prepared. Finally, the proposed work for the next quarter has been outlined in this report.

  10. Two stage, low temperature, catalyzed fluidized bed incineration with in situ neutralization for radioactive mixed wastes

    SciTech Connect (OSTI)

    Wade, J.F.; Williams, P.M.

    1995-05-17

    A two stage, low temperature, catalyzed fluidized bed incineration process is proving successful at incinerating hazardous wastes containing nuclear material. The process operates at 550{degrees}C and 650{degrees}C in its two stages. Acid gas neutralization takes place in situ using sodium carbonate as a sorbent in the first stage bed. The feed material to the incinerator is hazardous waste-as defined by the Resource Conservation and Recovery Act-mixed with radioactive materials. The radioactive materials are plutonium, uranium, and americium that are byproducts of nuclear weapons production. Despite its low temperature operation, this system successfully destroyed poly-chlorinated biphenyls at a 99.99992% destruction and removal efficiency. Radionuclides and volatile heavy metals leave the fluidized beds and enter the air pollution control system in minimal amounts. Recently collected modeling and experimental data show the process minimizes dioxin and furan production. The report also discusses air pollution, ash solidification, and other data collected from pilot- and demonstration-scale testing. The testing took place at Rocky Flats Environmental Technology Site, a US Department of Energy facility, in the 1970s, 1980s, and 1990s.

  11. Fluidized bed steam reformed mineral waste form performance testing to support Hanford Supplemental Low Activity Waste Immobilization Technology Selection

    SciTech Connect (OSTI)

    Jantzen, C. M.; Pierce, E. M.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Crawford, C. L.; Daniel, W. E.; Fox, K. M.; Herman, C. C.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.; Brown, C. F.; Qafoku, N. P.; Neeway, J. J.; Valenta, M. M.; Gill, G. A.; Swanberg, D. J.; Robbins, R. A.; Thompson, L. E.

    2015-10-01

    This report describes the benchscale testing with simulant and radioactive Hanford Tank Blends, mineral product characterization and testing, and monolith testing and characterization. These projects were funded by DOE EM-31 Technology Development & Deployment (TDD) Program Technical Task Plan WP-5.2.1-2010-001 and are entitled “Fluidized Bed Steam Reformer Low-Level Waste Form Qualification”, Inter-Entity Work Order (IEWO) M0SRV00054 with Washington River Protection Solutions (WRPS) entitled “Fluidized Bed Steam Reforming Treatability Studies Using Savannah River Site (SRS) Low Activity Waste and Hanford Low Activity Waste Tank Samples”, and IEWO M0SRV00080, “Fluidized Bed Steam Reforming Waste Form Qualification Testing Using SRS Low Activity Waste and Hanford Low Activity Waste Tank Samples”. This was a multi-organizational program that included Savannah River National Laboratory (SRNL), THOR® Treatment Technologies (TTT), Pacific Northwest National Laboratory (PNNL), Oak Ridge National Laboratory (ORNL), Office of River Protection (ORP), and Washington River Protection Solutions (WRPS). The SRNL testing of the non-radioactive pilot-scale Fluidized Bed Steam Reformer (FBSR) products made by TTT, subsequent SRNL monolith formulation and testing and studies of these products, and SRNL Waste Treatment Plant Secondary Waste (WTP-SW) radioactive campaign were funded by DOE Advanced Remediation Technologies (ART) Phase 2 Project in connection with a Work-For-Others (WFO) between SRNL and TTT.

  12. Limitations on fluid grid sizing for using volume-averaged fluid equations in discrete element models of fluidized beds

    E-Print Network [OSTI]

    Boyce, Christopher M.; Holland, Daniel; Dennis, John S.; Scott, Stuart A.

    2015-10-13

    Bubbling and slugging fluidization were simulated in 3D cylindrical fluidized beds using a discrete element model with computational fluid dynamics (DEM-CFD). A CFD grid was used in which the volume of all fluid cells was equal. Ninety simulations...

  13. A Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System for Effective Domestic

    E-Print Network [OSTI]

    interest in the use of wastewater as a source of renewable energy.1 Microbial fuel cells (MFCs) are beingA Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System, Pennsylvania 16802, United States *S Supporting Information ABSTRACT: Microbial fuel cells (MFCs

  14. A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace

    SciTech Connect (OSTI)

    Murray, J.P.

    1989-01-01

    A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

  15. Operating costs and plant options analysis for the Shamokin fluidized bed boiler

    SciTech Connect (OSTI)

    Klett, M.G.; Dowdy, T.E.; Litman, R.

    1984-03-01

    This report presents the results of a study that examined the operating costs and options to improve the Shamokin Atmospheric Fluidized Bed Combustion Demonstration Plant located near Shamokin, Pennsylvania. The purpose of this study was to perform an operating cost analysis and compare the results with projected operating costs. An analysis was also made to identify possible cost savings options. Two base case scenarios were developed for this study: the first scenario assumed that the plant operated in a manner similar to operations during the extended test program; and the second scenario was concerned with two options. One option assumed upgrading the plant to achieve continuous full load operation, restarting, and used revised costs and revenues. The second assumed reconfiguring the plant for cogeneration.

  16. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Zhongxian Cheng; Yan Cao; John Smith

    2006-09-30

    This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2006 through September 30, 2006. The following activities have been completed: the steel floor grating around the riser in all levels and the three-phase power supply for CFBC System was installed. Erection of downcomers, loop seals, ash bunker, thermal expansion joints, fuel and bed material bunkers with load cells, rotary air-lock valves and fuel flow monitors is underway. Pilot-scale slipstream tests conducted with bromine compound addition were performed for two typical types of coal. The purposes of the tests were to study the effect of bromine addition on mercury oxidization. From the test results, it was observed that there was a strong oxidization effect for Powder River Basin (PRB) coal. The proposed work for next quarter and project schedule are also described.

  17. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tingwen; Dietiker, Jean-François; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numericalmore »results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.« less

  18. Rocky Flats Plant fluidized-bed incinerator. Engineering design and reference manual

    SciTech Connect (OSTI)

    Meile, L.J.

    1982-11-05

    The information in this manual is being presented to complete the documentation of the fluidized-bed incineration (FBI) process development at the Rocky Flats Plant. The information pertains to the 82-kg/hour demonstration unit at the Rocky Flats Plant. This document continues the presentation of design reference material in the aeas of equipment drawings, space requirements, and unit costs. In addition, appendices contain an operating procedure and an operational safety analysis of the process. The cost figures presented are based on 1978 dollars and have not been converted to a current dollar value. Also, the cost of modifications are not included, since they would be insignificant if they were incorporated into a new installation.

  19. Development of a trial burn plan for a mixed waste fluidized bed incinerator

    SciTech Connect (OSTI)

    Kabot, F.J.; Ziegler, D.L.

    1988-01-01

    One of the more important elements of the incinerator permitting process under RCRA is the development of the Trial Burn Plan. This document describes the incinerator and defines the incinerator's process envelope within which the trial burns will be conducted. The data obtained during the trial burns will be the basis for the incinerator's operating permit. This paper describes the development of the Trial Burn Plan for a unique fluidized bed incinerator to be used for the incineration of hazardous and mixed wastes at the Department of Energy's Rocky Flats Plant. It describes a review process of the Trial Burn Plan involving a public comment period that actually preceded the trial burns. 2 refs., 1 fig.

  20. Continuous Ethanol Production Using Immobilized-Cell/Enzyme Biocatalysts in Fluidized-Bed Bioreactor (FBR)

    SciTech Connect (OSTI)

    Nghiem, NP

    2003-11-16

    The immobilized-cell fluidized-bed bioreactor (FBR) was developed at Oak Ridge National Laboratory (ORNL). Previous studies at ORNL using immobilized Zymomonas mobilis in FBR at both laboratory and demonstration scale (4-in-ID by 20-ft-tall) have shown that the system was more than 50 times as productive as industrial benchmarks (batch and fed-batch free cell fermentations for ethanol production from glucose). Economic analysis showed that a continuous process employing the FBR technology to produce ethanol from corn-derived glucose would offer savings of three to six cents per gallon of ethanol compared to a typical batch process. The application of the FBR technology for ethanol production was extended to investigate more complex feedstocks, which included starch and lignocellulosic-derived mixed sugars. Economic analysis and mathematical modeling of the reactor were included in the investigation. This report summarizes the results of these extensive studies.

  1. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Songgeng Li

    2006-01-01

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period October 1, 2005 through December 31, 2005. Work was performed on the following activities. First, the fabrication and manufacture of the CFBC Facility is nearly completed. The erection of the CFBC facility is expected to start in the second week of February, 2006. Second, effect of flue gas components on mercury oxidation was investigated in a drop tube reactor. As a first step, experiment for mercury oxidation by chlorine was investigated. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  2. Pulsed atmospheric fluidized bed combustion. Technical progress report, April--June, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-07-27

    This report of activities for the second quarter of 1994 is arranged in the following order: (1) Design Activities, including Process, Mechanical, Civil and Structural, and Electrical and Instrumentation; (2) Fabrication Activities; (3) Site Construction Activities; (4) Planned Activities for Next Quarter; and (5) Schedule. In order to achieve higher horizontal penetration of the flue gases from the pulse combustor, a conical deflector must be introduced under the exit of the pulse combustor. The conical surface of the deflector will be optimally shaped to maximize redirection of the flue gases as desired. The paper discusses the design of the fluidized bed, feed system, and ash system. Drawings are included of many of the subsystems and of the auxiliary systems required at the construction site, e.g. electrical system, lighting system, and control room lay out.

  3. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    SciTech Connect (OSTI)

    Li, Tingwen; Dietiker, Jean-François; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numerical results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.

  4. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles.more »It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.« less

  5. Synthetic aggregate compositions derived from spent bed materials from fluidized bed combustion and fly ash

    DOE Patents [OSTI]

    Boyle, Michael J. (Aston, PA)

    1994-01-01

    Cementitious compositions useful as lightweight aggregates are formed from a blend of spent bed material from fluidized bed combustion and fly ash. The proportions of the blend are chosen so that ensuing reactions eliminate undesirable constituents. The blend is then mixed with water and formed into a shaped article. The shaped article is preferably either a pellet or a "brick" shape that is later crushed. The shaped articles are cured at ambient temperature while saturated with water. It has been found that if used sufficiently, the resulting aggregate will exhibit minimal dimensional change over time. The aggregate can be certified by also forming standardized test shapes, e.g., cylinders while forming the shaped articles and measuring the properties of the test shapes using standardized techniques including X-ray diffraction.

  6. Process for generating electricity in a pressurized fluidized-bed combustor system

    DOE Patents [OSTI]

    Kasper, Stanley (Pittsburgh, PA)

    1991-01-01

    A process and apparatus for generating electricity using a gas turbine as part of a pressurized fluidized-bed combustor system wherein coal is fed as a fuel in a slurry in which other constituents, including a sulfur sorbent such as limestone, are added. The coal is combusted with air in a pressurized combustion chamber wherein most of the residual sulfur in the coal is captured by the sulfur sorbent. After particulates are removed from the flue gas, the gas expands in a turbine, thereby generating electric power. The spent flue gas is cooled by heat exchange with system combustion air and/or system liquid streams, and the condensate is returned to the feed slurry.

  7. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  8. Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant

    DOE Patents [OSTI]

    Cole, Rossa W. (E. Rutherford, NJ); Zoll, August H. (Cedar Grove, NJ)

    1982-01-01

    In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

  9. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  10. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities 

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01

    . The plants analyzed employ fluidized bed boilers for generation of steam for process and building/heating/cooling demands, in conjunction with electric power co-generation. Results of the analysis are presented, using life cycle costs and investment payback...

  11. Low temperature SO{sub 2} removal with solid sorbents in a circulating fluidized bed absorber. Final report

    SciTech Connect (OSTI)

    Lee, S.K.; Keener, T.C.

    1994-10-10

    A novel flue gas desulfurization technology has been developed at the University of Cincinnati incorporating a circulating fluidized bed absorber (CFBA) reactor with dry sorbent. The main features of CFBA are high sorbent/gas mixing ratios, excellent heat and mass transfer characteristics, and the ability to recycle partially utilized sorbent. Subsequently, higher SO{sub 2} removal efficiencies with higher overall sorbent utilization can be realized compared with other dry sorbent injection scrubber systems.

  12. " "," ",,," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," "

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981" ,"DataWorking17.2 116.9 107.6 104.9612.94. Total First Use.53

  13. ,,,"with Any"," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," "

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 Relative Standard Errors for Table 5.7;" "10.3 Relative53

  14. Development of algorithms for capacitance imaging techniques for fluidized bed flow fields

    SciTech Connect (OSTI)

    Loudin, W.J.

    1991-01-01

    The objective of this research is to provide support for the instrumentation concept of a High Resolution Capacitance Imaging System (HRCIS). The work involves the development and evaluation of the mathematical theory and associated models and algorithms which reduce the electronic measurements to valid physical characterizations. The research and development require the investigation of techniques to solve large systems of equations based on capacitance measurements for various electrode configurations in order to estimate densities of materials in a cross-section of a fluidized bed. Capacitance measurements are made for 400 connections of the 32-electrode system; 400 corresponding electric-field curves are constructed by solving a second order partial differential equation. These curves are used to partition the circular disk into 193 regions called pixels, and the density of material in each pixel is to be estimated. Two methods of approximating densities have been developed and consideration of a third method has been initiated. One method (Method 1) is based on products of displacement currents for intersecting electric-field curves on a cross section. For each pixel one point of intersection is chosen, and the product of the capacitance measurements is found. Both the product and the square-root-of-product seem to yield good relative distribution of densities.

  15. Development of algorithms for capacitance imaging techniques for fluidized bed flow fields. 1990 Annual report

    SciTech Connect (OSTI)

    Loudin, W.J.

    1991-01-01

    The objective of this research is to provide support for the instrumentation concept of a High Resolution Capacitance Imaging System (HRCIS). The work involves the development and evaluation of the mathematical theory and associated models and algorithms which reduce the electronic measurements to valid physical characterizations. The research and development require the investigation of techniques to solve large systems of equations based on capacitance measurements for various electrode configurations in order to estimate densities of materials in a cross-section of a fluidized bed. Capacitance measurements are made for 400 connections of the 32-electrode system; 400 corresponding electric-field curves are constructed by solving a second order partial differential equation. These curves are used to partition the circular disk into 193 regions called pixels, and the density of material in each pixel is to be estimated. Two methods of approximating densities have been developed and consideration of a third method has been initiated. One method (Method 1) is based on products of displacement currents for intersecting electric-field curves on a cross section. For each pixel one point of intersection is chosen, and the product of the capacitance measurements is found. Both the product and the square-root-of-product seem to yield good relative distribution of densities.

  16. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  17. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  18. Data summary of municipal solid waste management alternatives. Volume 5, Appendix C, Fluidized-bed combustion

    SciTech Connect (OSTI)

    1992-10-01

    This appendix provides information on fluidized-bed combustion (FBC) technology as it has been applied to municipal waste combustion (MWC). A review of the literature was conducted to determine: (1) to what extent FBC technology has been applied to MWC, in terms of number and size of units was well as technology configuration; (2) the operating history of facilities employing FBC technology; and (3) the cost of these facilities as compared to conventional MSW installations. Where available in the literature, data on operating and performance characteristics are presented. Tabular comparisons of facility operating/cost data and emissions data have been complied and are presented. The literature review shows that FBC technology shows considerable promise in terms of providing improvements over conventional technology in areas such as NOx and acid gas control, and ash leachability. In addition, the most likely configuration to be applied to the first large scale FBC dedicated to municipal solid waste (MSW) will employ circulating bed (CFB) technology. Projected capital costs for the Robbins, Illinois 1600 ton per day CFB-based waste-to-energy facility are competitive with conventional systems, in the range of $125,000 per ton per day of MSW receiving capacity.

  19. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  20. Bed-inventory Overturn Mechanism for Pant-leg Circulating Fluidized Bed Boilers

    E-Print Network [OSTI]

    Wang, Zhe; Yang, Zhiwei; West, Logan; Li, Zheng

    2011-01-01

    A numerical model was established to investigate the lateral mass transfer as well as the mechanism of bed-inventory overturn inside a pant-leg circulating fluidized bed (CFB), which are of great importance to maintain safe and efficient operation of the CFB. Results show that the special flow structure in which the solid particle volume fraction along the central line of the pant-leg CFB is relative high enlarges the lateral mass transfer rate and make it more possible for bed inventory overturn. Although the lateral pressure difference generated from lateral mass transfer inhibits continuing lateral mass transfer, providing the pant-leg CFB with self-balancing ability to some extent, the primary flow rate change due to the outlet pressure change often disable the self-balancing ability by continually enhancing the flow rate difference. As the flow rate of the primary air fan is more sensitive to its outlet pressure, it is easier to lead to bed inventory overturn. While when the solid particle is easier to c...

  1. The development of a 20-inch indirect fired fluidized bed gasifier

    SciTech Connect (OSTI)

    Flanigan, V.J.; Sitton, O.C.; Huang, W.E

    1988-03-01

    This report discusses the design, fabrication and operation of a 20'' I.D. fluidized bed gasifier producing medium Btu gas. The reactor is indirectly heated using 30 x 1-inch U-tubes inserted in the inert bed. The U-tubes are heated using flue gases produced from a propane burner system located at the bottom of the reactor. The feed material was dry wood chips fed into the bed with a 6in. auger. The reactor was fed both into the bed and at the top of the bed. The fluidizing medium was superheated steam which was superheated to 1000/degree/F. The gas produced from the reactor was passed through a cyclone for char removal and routed to the flare for combustion and disposal. The parameters measured during the experimental runs were wood feed rate, steam flow rate, steam temperatures, bed temperatures, free board temperatures, product gas temperatures, bed differential pressures, char production, gas production, gas analyses, and tar production. The parameters measured in the laboratory were moisture contents (wood and char), ash contents (wood and char), and tar content. 9 refs., 19 figs., 11 tabs.

  2. Comminution phenomena during the fluidized bed combustion of a commercial refuse-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A.; Chirone, R.; D`Anna, G.

    1995-12-31

    A commercial densified refuse-derived fuel (RDF), obtained as pellets from municipal solid wastes, was burned in two laboratory scale bubbling fluidized bed combustors, having an internal diameter of 41 mm. The apparatus were both batchwise operated at 850 C by injecting batches of RDF particles into a bed of silica sand (300--400 {micro}m as size range) fluidized at a superficial gas velocity of 0.8 m/s. RDF particles with equivalent mean diameter ranging from 4 to 9 mm were used. Different experimental procedures were set up to separately investigate comminution phenomena of fuel particles. Results were compared with those obtained burning a South African bituminous coal. Results pointed out that RDF particles undergo a strong primary fragmentation phenomenon, with a probability of particle breakage equal to 1 for fuel particles larger than 6 mm. Attrition and char fragmentation phenomena are particularly relevant under both inert and oxidizing conditions, generating a large amount of unburned fines which may affect overall combustion efficiency.

  3. Design considerations and operating experience in firing refuse derived fuel in a circulating fluidized bed combustor

    SciTech Connect (OSTI)

    Piekos, S.J.; Matuny, M.

    1997-12-31

    The worldwide demand for cleaner, more efficient methods to dispose of municipal solid waste has stimulated interest in processing solid waste to produce refuse derived fuel (RDF) for use in circulating fluidized bed (CFB) boilers. The combination of waste processing and materials recovery systems and CFB boiler technology provides the greatest recovery of useful resources from trash and uses the cleanest combustion technology available today to generate power. Foster Wheeler Power Systems along with Foster Wheeler Energy Corporation and several other Foster Wheeler sister companies designed, built, and now operates a 1600 tons per day (TPD) (1450 metric tons) municipal waste-to-energy project located in Robbins, Illinois, a suburb of Chicago. This project incorporates waste processing systems to recover recyclable materials and produce RDF. It is the first project in the United States to use CFB boiler technology to combust RDF. This paper will provide an overview of the Robbins, Illinois waste-to-energy project and will examine the technical and environmental reasons for selecting RDF waste processing and CFB combustion technology. Additionally, this paper will present experience with handling and combusting RDF and review the special design features incorporated into the CFB boiler and waste processing system that make it work.

  4. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  5. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, J.

    1996-02-20

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  6. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  7. Engineering systems analysis of pressurized fluidized-bed-combustion power systems

    SciTech Connect (OSTI)

    Graves, R.L.; Griffin, F.P.; Lackey, M.E.

    1982-04-01

    This effort was conducted to provde supporting data for the research and development program on pressurized fluidized bed combustor (PFBC) systems being continued under the auspices of the Office of Coal Utilization of DOE. This report deals with the first phase of the effort, designated Task 1, which was scoped to be a somewhat broad review of PFBC technology and an analysis to determine its potential and sensitivity to key development needs. Background information pertaining to the application of PFBC to the market for coal-fired technology is included. The status of development is reviewed and the deficiencies in data are identified. Responses to a survey of PFBC developers are reviewed with emphasis on the high risk areas of the PFBC concept. Some of these problems are: uncertainty of life of gas turbine components; lack of demonstration of load following; and hot solids handling. Some high risk areas, such as the gas cleanup or gas turbine systems, can be relieved by reducing the severity of design conditions such as the turbine inlet temperature. Alternate turbine designs or plant configurations are also possible solutions. Analyses were performed to determine whether the advantages held by PFBC systems in cost, efficiency, and emissions would be nullified by measures taken to reduce risk. In general, the results showed that the attractive features of the PFBC could be preserved.

  8. Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

    2014-05-01

    Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

  9. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  10. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; John Smith

    2008-05-31

    On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new particulate filtration technologies. Major tasks during this period of the funded project's timeframe included: (1) Conducting pretests on a laboratory-scale simulated FBC system; (2) Completing detailed design of the bench-scale CFBC system; (3) Contracting potential bidders to fabricate of the component parts of CFBC system; (4) Assembling CFBC parts and integrating system; (5) Resolving problems identified during pretests; (6) Testing with available Powder River Basin (PRB) coal and co-firing of PRB coal with first wood pallet and then chicken wastes; and (7) Tuning of CFBC load. Following construction system and start-up of this 0.6 MW CFBC system, a variety of combustion tests using a wide range of fuels (high-sulfur coals, low-rank coals, MSW, agricultural waste, and RDF) under varying conditions were performed to analyze and monitor air pollutant emissions. Data for atmospheric pollutants and the methodologies required to reduce pollutant emissions were provided. Integration with a selective catalytic reduction (SCR) slipstream unit did mimic the effect of flue gas composition, including trace metals, on the performance of the SCR catalyst to be investigated. In addition, the following activities were also conducted: (1) Developed advanced mercury oxidant and adsorption additives; (2) Performed laboratory-scale tests on oxygen-fuel combustion and chemical looping combustion; and (3) Conducted statistical analysis of mercury emissions in a full-scale CFBC system.

  11. ADVANCED SORBENT DEVELOPMENT PROGRAM; DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E. AYALA; V.S. VENKATARAMANI

    1998-09-30

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 °C (900-1000 °F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.?s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 °C (650 °F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 °C (650-1000 °F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 °C (700 °F) to 538 °C (1000 °F) and regeneration tempera-tures up to 760 °C (1400 °F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent develop-ment at General Electric?s Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  12. ADVANCED SORBENT DEVELOPMENT PROGRAM DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E Ayala; V.S. Venkataramani; Javad Abbasian; Rachid B. Slimane; Brett E. Williams; Minoo K. Zarnegar; James R. Wangerow; Andy H. Hill

    2000-03-31

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000 F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.'s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration temperatures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent development at General Electric's Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  13. Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed chemical processing systems at Building 9212, Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is located within the Y-12 Plant on DOE`s Oak Ridge Reservation in Oak Ridge, Tennessee. The proposed replacement system would be based upon modern design criteria and safety analyses. The replacement AHF supply and distribution system equipment would be located on the existing Dock 8/8A at Building 9212. Utilities would be extended to the dock to service the process equipment. The following process equipment modules would be prefabricated for installation at the modified dock: an AHF cylinder enclosure, an AHF supply manifold and vaporizer module, an AHF sump tank and transfer skid, and an AHF supply off-gas scrubber assembly module. The fluidized-bed reactor system would be constructed in an area adjacent to the existing system in Building 9212. The replacement equipment would consist of a new reduction fluidized-bed reactor, a hydrofluorination fluidized-bed reactor, and associated air emission control equipment. The no-action alternative, which is the continued operation of the existing AHF supply and fluidized-bed reactor systems, was also evaluated.

  14. Characterization of a fluidized-bed combustion ash to determine potential for environmental impact. Final report

    SciTech Connect (OSTI)

    Hassett, D.J.; Henderson, A.K.; Pflughoeft-Hassett, D.F.; Mann, M.D.; Eylands, K.E.

    1997-10-01

    A 440-megawatt, circulating fluidized-bed combustion (CFBC), lignite-fired power plant is planned for construction in Choctaw County north of Ackerman, Mississippi. This power plant will utilize Mississippi lignite from the first lignite mine in that state. Malcolm Pirnie, Inc., is working with the power plant developer in the current planning and permitting efforts for this proposed construction project. In order to accommodate Mississippi state regulatory agencies and meet appropriate permit requirements, Malcolm Pirnie needed to provide an indication of the characteristics of the by-products anticipated to be produced at the proposed plant. Since the Mississippi lignite is from a newly tapped mine and the CFBC technology is relatively new, Malcolm Pirnie contacted with the Energy and Environmental Research Center (EERC) to develop and perform a test plan for the production and characterization of ash similar to ash that will be eventually produced at the proposed power plant. The work performed at the EERC included two primary phases: production of by-products in a bench-scale CFBC unit using lignite provided by Malcolm Pirnie with test conditions delineated by Malcolm Pirnie to represent expected operating conditions for the full-scale plant; and an extensive characterization of the by-products produced, focusing on Mississippi regulatory requirements for leachability, with the understanding that return of the by-product to the mine site was an anticipated by-product management plan. The overall focus of this project was the environmental assessment of the by-product expected to be produced at the proposed power plant. Emphasis was placed on the leachability of potentially problematic trace elements in the by-products. The leaching research documented in this report was performed to determine trends of leachability of trace elements under leaching conditions appropriate for evaluating land disposal in monofills, such as returning the by-products to the mine site.

  15. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  16. Novel fluidized bed reactor for integrated NOx adsorption-reduction with hydrocarbons

    SciTech Connect (OSTI)

    Terris T. Yang; Hsiaotao T. Bi [University of British Columbia, Vancouver, BC (Canada). Department of Chemical & Biological Engineering

    2009-07-01

    In order to avoid the negative impact of excessive oxygen in the combustion flue gases on the selectivity of most hydrocarbon selective catalytic reduction (HC-SCR) catalysts, an integrated NOx adsorption-reduction process has been proposed in this study for the treatment of flue gases under lean burn conditions by decoupling the adsorption and reduction into two different zones. The hypothesis has been validated in a novel internal circulating fluidized bed (ICFB) reactor using Fe/ZSM-5 as the catalyst and propylene as the reducing agent. Effects of propylene to the NOx molar ratio, flue gas oxygen concentration, and gas velocity on NOx conversion were studied using simulated flue gases. The results showed that increasing the ratio of HC:NO improved the reduction performance of Fe/ZSM-5 in the ICFB reactor. NOx conversion decreased with an increasing flue gas flow velocity in the annulus U{sub A} but increased with an increasing reductant gas flow velocity in the draft tube U{sub D}. The NOx adsorption ratio decreased with increasing U{sub A}. In most cases, NOx conversion was higher than the adsorption ratio due to the relatively poor adsorption performance of the catalyst. Fe/ZSM-5 showed a promising reduction performance and a strong inhibiting ability on the negative impact of excessive O{sub 2} in the ICFB reactor, proving that such an ICFB reactor possessed the ability to overcome the negative impact of excessive O{sub 2} in the flue gas using Fe/ZSM-5 as the deNOx catalyst. 22 refs., 10 figs.

  17. Experimental study of the hydrodynamics and cluster formation in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Gautam, M.; Johnson, E.

    1991-01-01

    A novel non-invasive gas-solid flow measuring technique being developed and tested for studying the hydrodynamics inside the riser of a Circulating Fluidized Bed (CFB). First of the two aims of the overall program, namely, design, development and testing of the technique to characterize the particle and gas velocities in two-phase flows was accomplished in the past year. The fringe-model'' laser Doppler anemometry concept has been modified and extended by using particles coated with a fluorescent dye and introducing a narrow band pass filter in the receiving optics. The technique permits optical discrimination between the scattered light (laser wavelength from undyed particles) and the fluorescence emission (longer wavelength). Results from extensive testing of various dye-solvent combinations, counter processor settings, signal-to noise optimization and subsequent flow measurements in the test section have shown that the technique can effectively discriminate between two classes of particles--the smaller seed particles for the gas phase data and the larger bed particles. Use of a two-watt Argon-Ion laser assisted in the non-intrusive probing of the gas-solid flow and in enhancing the signal-to-noise ratio. An uncertainty analysis of LDA measurements is presented. Design of the cold flow CFB model, presently under fabrication, is outlined in this report. The Plexiglas CFB model will be employed for the riser core-annular flow studies using the fluorescence-emission based laser-Doppler anemometry. The results from this study will present a unique detailed description of the complex gas-solid behavior in the CFB riser.

  18. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  19. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  20. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  1. Sulfur removal in advanced two stage pressurized fluidized bed combustion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Abbasian, J.; Chowdiah, P.; Hill, A.H.; Rue, D.M. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-09-01

    The objective of this study is to obtain data on the rates of reaction between hydrogen sulfide (H{sub 2}S) and uncalcined calcium-based sorbents under operating conditions relevant to first stage (carbonizer) of Advanced Two-Stage Pressurized Fluidized-Bed Combustors (PFBC). In these systems the CO{sub 2} partial pressure in the first stage generally exceeds the equilibrium value for calcium carbonate decomposition. Therefore, removal of sulfur compounds takes place through the reaction between H{sub 2}S and calcium carbonate. To achieve this objective, the rates of reaction between hydrogen sulfide and uncalcined calcium-based sorbents will be determined by conducting tests in pressurized thermogravimetric analyzer (TGA) and high-pressure/high-temperature fluidized-bed reactor (HPTR) units. The effects of sorbent type, sorbent particle size, reactor temperature and pressure, and CO{sub 2} and H{sub 2}S partial pressures on the sulfidation reaction rate will be determined. During this quarter a series of sulfidation tests were conducted in the high-pressure/high-temperature fluidized-bed reactor (HPTR) units. The effects of sorbent type, sorbent particle size, reactor temperature and pressure, and CO{sub 2} and H{sub 2}S partial pressures on the sulfidation reaction rate will be determined. During this quarter a series of sulfidation tests were conducted in the high-pressure high-temperature thermogravimetric analyzer (HPTGA unit) using limestone and dolomite. The results suggest that half-calcined dolomite is much more reactive than uncalcined limestone. Also, temperature in the range of 800 to 950 C did not significantly affect the sulfidation reaction rates for both limestone and dolomite.

  2. Functionalization of polymers using an atmospheric plasma jet in a fluidized bed reactor and the impact on SLM-processes

    SciTech Connect (OSTI)

    Sachs, M. Schmitt, A. Schmidt, J. Peukert, W. Wirth, K-E

    2014-05-15

    In order to improve thermoplastics (e.g. Polyamide, Polypropylene and Polyethylene) for Selective Laser Beam Melting (SLM) processes a new approach to functionalize temperature sensitive polymer powders in a large scale is investigated. This is achieved by combining an atmospheric pressure plasma jet and a fluidized bed reactor. Using pressurized air as the plasma gas, radicals like OH* are created. The functionalization leads to an increase of the hydrophilicity of the treated polymer powder without changing the bulk properties. Using the polymers in a SLM process to build single layers of melted material leads to an improvement of the melted layers.

  3. A One-Dimensional (1-D) Three-Region Model for a Bubbling Fluidized-Bed Adsorber

    SciTech Connect (OSTI)

    Lee, Andrew; Miller, David C.

    2012-01-01

    A general one-dimensional (1-D), three-region model for a bubbling fluidized-bed adsorber with internal heat exchangers has been developed. The model can predict the hydrodynamics of the bed and provides axial profiles for all temperatures, concentrations, and velocities. The model is computationally fast and flexible and allows for any system of adsorption and desorption reactions to be modeled, making the model applicable to any adsorption process. The model has been implemented in both gPROMS and Aspen Custom Modeler, and the behavior of the model has been verified.

  4. Combustion of liquid paint wastes in fluidized bed boiler as element of waste management system in the paint factory

    SciTech Connect (OSTI)

    Soko, W.A.; Biaecka, B.

    1998-12-31

    In this paper the solution to waste problems in the paint industry is presented by describing their combustion in a fluidized bed boiler as a part of the waste management system in the paint factory. Based on the Cleaner Production idea and concept of integration of design process with a future exploitation of equipment, some modifications of the waste management scheme in the factory are discussed to reduce the quantity of toxic wastes. To verify this concept combustion tests of paint production wastes and cocombustion of paint wastes with coal in an adopted industrial boiler were done. Results of these tests are presented in the paper.

  5. Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-11-01

    The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

  6. Solids circulation around a jet in a fluidized bed gasifier. Final technical report, September 1, 1978-September 30, 1980

    SciTech Connect (OSTI)

    Gidaspow, D.; Ettehadieh, B.; Lin, C.; Goyal, A.; Lyczkowski, R.W.

    1980-01-01

    The object of this investigation was to develop an experimentally verified hydrodynamic model to predict solids circulation around a jet in a fluidized bed gasifier. Hydrodynamic models of fluidization use the principles of conservation of mass, momentum and energy. To account for unequal velocities of solid and fluid phases, separate phase momentum balances are developed. Other fluid bed models used in the scale-up of gasifiers do not employ the principles of conservation of momentum. Therefore, these models cannot predict fluid and particle motion. In such models solids mixing is described by means of empirical transfer coefficients. A two dimensional unsteady state computer code was developed to give gas and solid velocities, void fractions and pressure in a fluid bed with a jet. The growth, propagation and collapse of bubbles was calculated. Time-averaged void fractions were calculated that showed an agreement with void fractions measured with a gamma ray densitometer. Calculated gas and solid velocities in the jet appeared to be reasonable. Pressure and void oscillations also appear to be reasonable. A simple analytical formula for the rate of solids circulation was developed from the equations of change. It agrees with Westinghouse fluidization data in a bed with a draft tube. One dimensional hydrodynamic models were applied to modeling of entrained-flow coal gasification reactors and compared with data. Further development of the hydrodynamic models should make the scale-up and simulation of fluidized bed reactors a reality.

  7. Sulfur removal in advanced two stage pressurized fluidized bed combustion. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Abbasian, J.; Hill, A.; Wangerow, J.R. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31

    The objective of this study is to obtain data on the rates and the extent of sulfation reactions involving partially sulfided calcium-based sorbents, and oxygen as well as sulfur dioxide, at operating conditions closely simulating those prevailing in the second stage (combustor) of Advanced Two-Stage Pressurized Fluidized-Bed Combustors (PFBC). In these systems the CO{sub 2} partial pressure generally exceeds the equilibrium value for calcium carbonate decomposition. Therefore, calcium sulfate is produced through the reactions between SO{sub 2} and calcium carbonate as well as the reaction between calcium sulfide and oxygen. To achieve this objective, the rates of reaction involving SO{sub 2} and oxygen (gaseous reactant); and calcium sulfide and calcium carbonate (solid reactants), will be determined by conducting tests in a pressurized thermogravimetric analyzer (HPTGA) unit. The effects of sorbent type, sorbent particle size, reactor temperature and pressure; and O{sub 2} as well as SO{sub 2} partial pressures on the sulfation reactions rate will be determined. During this quarter, samples of the selected limestone and dolomite were sulfided in the fluidized-bed reactor. These tests were conducted in both calcining and non-calcining operating conditions to produce partially-sulfided sorbents containing calcium oxide and calcium carbonate, respectively. These samples which represent the carbonizer discharge material, will be used as the feed material in the sulfation tests to be conducted in the HPTGA unit during the next quarter.

  8. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R.; Reuther, R.B.; Bonk, D.L.

    1996-09-01

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  9. Distribution of polycyclic aromatic hydrocarbons in fly ash during coal and residual char combustion in a pressurized fluidized bed

    SciTech Connect (OSTI)

    Hongcang Zhou; Baosheng Jin; Rui Xiao; Zhaoping Zhong; Yaji Huang

    2009-04-15

    To investigate the distribution of polycyclic aromatic hydrocarbons (PAHs) in fly ash, the combustion of coal and residual char was performed in a pressurized spouted fluidized bed. After Soxhlet extraction and Kuderna-Danish (K-D) concentration, the contents of 16 PAHs recommended by the United States Environmental Protection Agency (U.S. EPA) in coal, residual char, and fly ash were analyzed by a high-performance liquid chromatography (HPLC) coupled with fluorescence and diode array detection. The experimental results show that the combustion efficiency is lower and the carbon content in fly ash is higher during coal pressurized combustion, compared to the residual char pressurized combustion at the pressure of 0.3 MPa. Under the same pressure, the PAH amounts in fly ash produced from residual char combustion are lower than that in fly ash produced from coal combustion. The total PAHs in fly ash produced from coal and residual char combustion are dominated by three- and four-ring PAHs. The amounts of PAHs in fly ash produced from residual char combustion increase and then decrease with the increase of pressure in a fluidized bed. 21 refs., 1 fig., 4 tabs.

  10. Zevenhoven & Kilpinen NITROGEN 18.1.2004 4-35 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed

    E-Print Network [OSTI]

    Zevenhoven, Ron

    oxide by air staging, and reduction of nitric oxide with char. In circulating fluidized bed combustion reactions between gas and particles become important, e.g., reduction of nitric oxide with char, which or noncatalytic. For example, the reduction of nitric oxide with char #12;Zevenhoven & Kilpinen NITROGEN 18

  11. JV Task 108 - Circulating Fluidized-Bed Combustion and Combustion Testing of Turkish Tufanbeyli Coal

    SciTech Connect (OSTI)

    Douglas Hajicek; Jay Gunderson; Ann Henderson; Stephen Sollom; Joshua Stanislowski

    2007-08-15

    Two combustion tests were performed at the Energy & Environmental Research Center (EERC) using Tufanbeyli coal from Turkey. The tests were performed in a circulating fluidized-bed combustor (CFBC) and a pulverized coal-fired furnace, referred to as the combustion test facility (CTF). One of the goals of the project was to determine the type of furnace best suited to this coal. The coal is high in moisture, ash, and sulfur and has a low heating value. Both the moisture and the sulfur proved problematic for the CTF tests. The fuel had to be dried to less than 37% moisture before it could be pulverized and further dried to about 25% moisture to allow more uniform feeding into the combustor. During some tests, water was injected into the furnace to simulate the level of flue gas moisture had the fuel been fed without drying. A spray dryer was used downstream of the baghouse to remove sufficient sulfur to meet the EERC emission standards permitted by the North Dakota Department of Health. In addition to a test matrix varying excess air, burner swirl, and load, two longer-term tests were performed to evaluate the fouling potential of the coal at two different temperatures. At the lower temperature (1051 C), very little ash was deposited on the probes, but deposition did occur on the walls upstream of the probe bank, forcing an early end to the test after 2 hours and 40 minutes of testing. At the higher temperature (1116 C), ash deposition on the probes was significant, resulting in termination of the test after only 40 minutes. The same coal was burned in the CFBC, but because the CFBC uses a larger size of material, it was able to feed this coal at a higher moisture content (average of 40.1%) compared to the CTF (ranging from 24.2% to 26.9%). Sulfur control was achieved with the addition of limestone to the bed, although the high calcium-to-sulfur rate required to reduce SO{sub 2} emissions resulted in heat loss (through limestone calcination) and additional ash handling. A more efficient downstream sulfur scrubber capable of operation at a much lower Ca/S ratio would result in significantly higher boiler efficiency for this coal. At the operating temperature of a typical CFBC, bed agglomeration and convective pass fouling are not likely to be significant problems with this fuel. Compared to pulverized coal-firing, CFBC technology is clearly the better choice for this fuel. It provides more efficient sulfur capture, lower NO{sub x} emissions, better solids-handling capability, and can utilize a wetter feedstock, requiring less crushing and sizing. The lower operating temperature of CFBC boilers (820 C) reduces the risk of fouling and agglomeration. Care must be taken to minimize heat loss in the system to accommodate the low heating value of the coal.

  12. Final Environmental Impact Statement for the JEA Circulating Fluidized Bed Combustor Project

    SciTech Connect (OSTI)

    N /A

    2000-06-30

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the Clean Coal Technology Program. The project would demonstrate circulating fluidized bed (CFB) combustion technology at JEA's existing Northside Generating Station in Jacksonville, Florida, about 9 miles northeast of the downtown area of Jacksonville. The new CFB combustor would use coal and petroleum coke to generate nearly 300 MW of electricity by repowering the existing Unit 2 steam turbine, a 297.5-MW unit that has been out of service since 1983. The proposed project is expected to demonstrate emission levels of sulfur dioxide (SO{sub 2}), oxides of nitrogen (NO{sub x}), and particulate matter that would be lower than Clean Air Act limits while at the same time producing power more efficiently and at less cost than conventional coal utilization technologies. At their own risk, JEA has begun initial construction activities without DOE funding. Construction would take approximately two years and, consistent with the original JEA schedule, would be completed in December 2001. Demonstration of the proposed project would be conducted during a 2-year period from March 2002 until March 2004. In addition, JEA plans to repower the currently operating Unit 1 steam turbine about 6 to 12 months after the Unit 2 repowering without cost-shared funding from DOE. Although the proposed project consists of only the Unit 2 repowering, this EIS analyzes the Unit 1 repowering as a related action. The EIS also considers three reasonably foreseeable scenarios that could result from the no-action alternative in which DOE would not provide cost-shared funding for the proposed project. The proposed action, in which DOE would provide cost-shared finding for the proposed project, is DOE's preferred alternative. The EIS evaluates the principal environmental issues, including air quality, traffic, noise, and ecological resources, that could result from construction and operation of the proposed project. Key findings include that maximum modeled increases in ground-level concentrations of SO{sub 2} nitrogen dioxide (NO{sub 2}), and particulate matter (for the proposed project alone or in conjunction with the related action) would always be less than 10% of their corresponding standards for increases in pollutants. For potential cumulative air quality impacts, results of modeling regional sources and the proposed project indicate that the maximum 24-hour average SO{sub 2} concentration would closely approach (i.e., 97%) but not exceed the corresponding Florida standard. After the Unit 1 repowering, results indicate that the maximum 24-hour average SO{sub 2} concentration would be 91% of the Florida standard. Concentrations for other averaging periods and pollutants would be lower percentages of their standards. Regarding toxic air pollutants from the proposed project, the maximum annual cancer risk to a member of the public would be approximately 1 in 1 million; given the conservative assumptions in the estimate, the risk would probably be less. With regard to threatened and endangered species, impacts to manatees, gopher tortoises, and other species would be negligible or non-existent. Construction-induced traffic would result in noticeable congestion. In the unlikely event that all coal were transported by rail, up to 3 additional trains per week would exacerbate impacts associated with noise, vibration, and blocked roads at on-grade rail crossings. Additional train traffic could be minimized by relying more heavily on barges and ships for coal transport, which is likely to be a more economic fuel delivery mode. During construction of the proposed project, noise levels would increase from the current operational levels. Except possibly during steam blowouts and possibly during operation of equipment used to construct a nearby segment of a conveyor, construction noise should not appreciably affect the background noise of nearby residences or exceed local nois

  13. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  14. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke

    2001-07-13

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences, Foster Wheeler Energy Services, Inc., Parsons Energy and Chemicals Group, Inc., and Cofiring Alternatives. During this reporting period, work focused on completing the biofuel characterization and the design of the conceptual fluidized bed system.

  15. Mild hydrocracking of an unstable feedstock in a three-phase fluidized-bed reactor; Behavior of the process and of the chemical compounds

    SciTech Connect (OSTI)

    Souza, G.L.M.; Afonso, J.C.; Schmal, M.; Cordoso, J.N. (Universidade Federal, Rio de Janeiro, RJ (Brazil))

    1992-09-01

    The mild hydrocracking (400[degrees]C, 125 atm) of an unstable feedstock (shale oil) was performed in a three-phase fluidized-bed reactor with a commercial sulfided Ni-Mo catalyst. The hydroprocessing was monitored with respect to the physicochemical properties and the chemical composition of the natural and treated oil. The unit attained steady state after 36 h on stream for almost all parameters (viscosity, density, conversion, selectivity, etc.). Chemical composition data of the feedstock and the treated oil were, in general, in good agreement with the physicochemical characterizations. In this paper the mild hydrocracking in a three-phase fluidized-bed reactor is shown to be an alternative process for the treatment of unstable feedstocks.

  16. Overall and average local heat transfer from a horizontal cylinder in a gas-fluidized bed with an opposing oscillatory flow

    SciTech Connect (OSTI)

    Pence, D.V. [Univ. of Rhode Island, Kingston, RI (United States). Dept. of Mechanical Engineering and Applied Mechanics; Beasley, D.E. [Clemson Univ., SC (United States). Dept. of Mechanical Engineering

    1996-12-31

    The Pulsed Atmospheric Fluidized Bed Combustor (PAFBC), a hybrid combustor concept that couples a pulsed combustor with an atmospheric bubbling fluidized bed, has technical advantages in energy efficiency and emissions. The present study examines fundamental aspects of heat transfer in this hybrid combustor by measuring the effect of an opposing oscillatory flow on the overall and time-averaged local heat transfer in a laboratory scale bubbling gas-fluidized bed. This opposing secondary flow consisted of a steady mean component and an oscillating component thereby modeling the flow in the tailpipe of a pulsed combustor. Data were acquired for a monodisperse distribution of particles with a mean diameter of 345 {micro}m and total fluidization ratios ranging from 1.1 through 2.7. Overall and time-averaged local heat flux measurements from the surface of a submerged horizontal cylinder show that heat transfer characteristics are significantly altered by an opposing oscillatory flow. Increases in overall heat transfer on the order of 12% were identified for operating conditions with low primary and secondary flow rates and low pulse frequencies. These enhancements were identified to be a consequence of significant localized enhancements. The fundamental trends and magnitude of the particle Nusselt number are effectively characterized by a modified form of the Strouhal number.

  17. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect (OSTI)

    DeLallo, M.; Zaharchuk, R.

    1994-01-01

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  18. Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  19. Energy and environmental research emphasizing low-rank coal -- Task 3.8, Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Mann, M.D.; Henderson, A.K.; Swanson, M.L.

    1995-03-01

    The goal of the PFBC activity is to generate fundamental process information that will further the development of an economical and environmentally acceptable second-generation PFBC. The immediate objectives focus on generic issues, including the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals in PFBC. A great deal of PFBC performance relates to the chemistry of the bed and the contact between gas and solids that occurs during combustion. These factors can be studied in a suitably designed bench-scale reactor. The present studies are focusing on the emission control strategies applied in the bed, rather than in hot-gas cleaning. Emission components include alkali and heavy metals in addition to SO{sub 2}, NO{sub x}, N{sub 2}O, and CO. The report presents: a description of the pressurized fluidized-bed reactor (PFBR); a description of the alkali sampling probe; shakedown testing of the bench-scale PFBR; results from alkali sampling; results from sulfur sorbent performance tests; and results from refuse-derived fuel and lignite combustion tests.

  20. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome somemore »of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.« less

  1. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk

    2010-04-15

    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  2. Technical and economic assessment of fluidized bed augmented compressed air energy-storage system. Volume II. Introduction and technology assessment

    SciTech Connect (OSTI)

    Giramonti, A.J.; Lessard, R.D.; Merrick, D.; Hobson, M.J.

    1981-09-01

    The results are described of a study subcontracted by PNL to the United Technologies Research Center on the engineering feasibility and economics of a CAES concept which uses a coal fired, fluidized bed combustor (FBC) to heat the air being returned from storage during the power production cycle. By burning coal instead of fuel oil, the CAES/FBC concept can completely eliminate the dependence of compressed air energy storage on petroleum fuels. The results of this assessment effort are presented in three volumes. Volume II presents a discussion of program background and an in-depth coverage of both fluid bed combustion and turbomachinery technology pertinent to their application in a CAES power plant system. The CAES/FBC concept appears technically feasible and economically competitive with conventional CAES. However, significant advancement is required in FBC technology before serious commercial commitment to CAES/FBC can be realized. At present, other elements of DOE, industrial groups, and other countries are performing the required R and D for advancement of FBC technology. The CAES/FBC will be reevaluated at a later date when FBC technology has matured and many of the concerns now plaguing FBC are resolved. (LCL)

  3. Environmental assessment of the atlas bio-energy waste wood fluidized bed gasification power plant. Final report

    SciTech Connect (OSTI)

    Holzman, M.I.

    1995-08-01

    The Atlas Bio-Energy Corporation is proposing to develop and operate a 3 MW power plant in Brooklyn, New York that will produce electricity by gasification of waste wood and combustion of the produced low-Btu gas in a conventional package steam boiler coupled to a steam-electric generator. The objectives of this project were to assist Atlas in addressing the environmental permit requirements for the proposed power plant and to evaluate the environmental and economic impacts of the project compared to more conventional small power plants. The project`s goal was to help promote the commercialization of biomass gasification as an environmentally acceptable and economically attractive alternative to conventional wood combustion. The specific components of this research included: (1) Development of a permitting strategy plan; (2) Characterization of New York City waste wood; (3) Characterization of fluidized bed gasifier/boiler emissions; (4) Performance of an environmental impact analysis; (5) Preparation of an economic evaluation; and (6) Discussion of operational and maintenance concerns. The project is being performed in two phases. Phase I, which is the subject of this report, involves the environmental permitting and environmental/economic assessment of the project. Pending NYSERDA participation, Phase II will include development and implementation of a demonstration program to evaluate the environmental and economic impacts of the full-scale gasification project.

  4. The O{sub 2}-enriched air gasification of coal, plastics and wood in a fluidized bed reactor

    SciTech Connect (OSTI)

    Mastellone, Maria Laura, E-mail: mlaura.mastellone@unina2.it [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy); Zaccariello, Lucio; Santoro, Donato; Arena, Umberto [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy)

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer The effect of the O{sub 2} in the gasification stream of a BFB gasifier has been studied. Black-Right-Pointing-Pointer Main advantage of the O{sub 2}-enriched air is the increasing of the bed temperature. Black-Right-Pointing-Pointer No remarkable effects on tar reduction. Decreasing of recognized PAHs. Black-Right-Pointing-Pointer Gasification reactions completed inside the dense bed and splashing zone. Black-Right-Pointing-Pointer Polycondensation reactions occur mainly in the freeboard region. - Abstract: The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery.

  5. Ethanol Production from Rice-Straw Hydrolysate Using Zymomonas Mobilis in a Continuous Fluidized-Bed Reactor (FBR)

    SciTech Connect (OSTI)

    deJesus, D.; Nghiem, N.P.

    2001-01-01

    Rice-straw hydrolysate obtained by the Arkenol's concentrated acid hydrolysis process was fermented to ethanol using a recombinant Zymomonas mobilis strain capable of utilizing both glucose and xylose in a continuous fluidized-bed reactor (FBR). The parameters studied included biocatalyst stability with and without antibiotic, feed composition, and retention time. Xylose utilization in the presence of tetracycline remained stable for at least 17 days. This was a significant improvement over the old strain, Z. mobilis CP4 (pZB5), which started to lose xylose utilization capability after seven days. In the absence of tetracycline, the xylose utilization rate started to decrease almost immediately. With tetracycline in the feed for the first six days, stability of xylose utilization was maintained for four days after the antibiotic was removed from the feed. The xylose utilization rate started to decrease on day 11. In the presence of tetracycline using the Arkenol's hydrolysate diluted to 48 g/L glucose and 13 g/L xylose at a retention time of 4.5 h, 95% xylose conversion and complete glucose conversion occurred. The ethanol concentration was 29 g/L, which gave a yield of 0.48 g/g sugar consumed or 94% of the theoretical yield. Using the Arkenol's hydrolysate diluted to 83 g/L glucose and 28 g/L xylose, 92% xylose conversion and complete glucose conversion were obtained. The ethanol concentration was 48 g/L, which gave a yield of 0.45 g/ g sugar consumed or 88% of the theoretical yield. Maximum productivity of 25.5 g/L-h was obtained at a retention time of 1.9 h. In this case, 84% xylose conversion was obtained.

  6. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  7. Fluidized Bed Steam Reforming (FBSR) Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (GNEP)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Williams, M.R. [Savannah River National Laboratory, Aiken, SC (United States)

    2008-07-01

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NOx in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 deg. C) compared to vitrification (1150-1300 deg. C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {>=}1000 deg. C. Pollucite mineralization creates secondary aqueous waste streams and NOx. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O. (authors)

  8. FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP

    SciTech Connect (OSTI)

    Jantzen, C; Michael Williams, M

    2008-01-11

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  9. PFBC (pressurized fluidized bed combustion) turbocharged boiler design and economic study: Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    A coal combustion technology that promises to reduce the cost of electrical power is pressurized fluidized bed combustion (PFBC). Since a PFBC boiler is physically smaller than a conventional pulverized coal fired boiler with a flue gas desulfurization system (PC/FGD) and the same power rating shop assembly and modularized shipment to the power plant site can be considered. Modular construction can substantially reduce the overall design/construction time. Emission controls are equivalent to, or better than, conventional PC/FGD units, and the PFBC combustor can tolerate coals with a wider range of characteristics. Two PFBC plants and the reference PC/FGD plant were each to have four nominal 250 MW(e) units to be completed for start-up at one year intervals. To establish a well defined consistent design basis for all units, the turbine-generator and steam cycle of a recently constructed 250 MW(e) unit (designed by Fluor and built under Fluor construction management) was selected and made the common element in both of the PFBC plants and the reference PC/FGD plant. Steam conditions of 2400 psia, 1000/sup 0/F were to be identical for all units as were the steam flows for the design load range of 50% to steam turbine valves-wide-open with inlet steam pressure 5% over design pressure (VWO 5% OP). The study produced three plant designs - a 4-unit turbocharged PFBC using bubbling bed technology, a 4-unit turbocharged PFBC using circulating bed technology, and a 4-unit PC/FGD reference plant using conventional pulverized coal technology coupled with wet limestone scrubber technology. The hot gas clean-up system, operating at these more modest temperatures, is capable of reducing the particulate in the gas to a level which meets EPA/NSPS standards without further cleanup. With this level of cleanup, service conditions for the turbocharger turbine are tolerable in commercially available designs and materials. 48 figs., 14 tabs.

  10. Chaotic behavior control in fluidized bed systems using artificial neural network. Quarterly progress report, October 1, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Bodruzzaman, M.; Essawy, M.A.

    1996-02-27

    Pressurized fluidized-bed combustors (FBC) are becoming very popular, efficient, and environmentally acceptable replica for conventional boilers in Coal-fired and chemical plants. In this paper, we present neural network-based methods for chaotic behavior monitoring and control in FBC systems, in addition to chaos analysis of FBC data, in order to localize chaotic modes in them. Both of the normal and abnormal mixing processes in FBC systems are known to undergo chaotic behavior. Even though, this type of behavior is not always undesirable, it is a challenge to most types of conventional control methods, due to its unpredictable nature. The performance, reliability, availability and operating cost of an FBC system will be significantly improved, if an appropriate control method is available to control its abnormal operation and switch it to normal when exists. Since this abnormal operation develops only at certain times due to a sequence of transient behavior, then an appropriate abnormal behavior monitoring method is also necessary. Those methods has to be fast enough for on-line operation, such that the control methods would be applied before the system reaches a non-return point in its transients. It was found that both normal and abnormal behavior of FBC systems are chaotic. However, the abnormal behavior has a higher order chaos. Hence, the appropriate control system should be capable of switching the system behavior from its high order chaos condition to low order chaos. It is to mention that most conventional chaos control methods are designed to switch a chaotic behavior to a periodic orbit. Since this is not the goal for the FBC case, further developments are needed. We propose neural network-based control methods which are known for their flexibility and capability to control both non-linear and chaotic systems. A special type of recurrent neural network, known as Dynamic System Imitator (DSI), will be used for the monitoring and control purposes.

  11. Chaotic behavior control in fluidized bed systems using artificial neural network. Quarterly progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    Bodruzzaman, M.; Essawy, M.A.

    1996-07-30

    We have developed techniques to control the chaotic behavior in the Fluidized Bed (FBC) Systems using Artificial Neural Networks (ANNs). For those techniques to cross from theory to implementation, the computer programs we are developing have to be interfaced with the outside world, as a necessary step towards the actual interface with an FBC system or its experimental mock up. For this reason we are working on a Data Acquisition Board setup that will enable communication between our programs and external systems. Communication is planned to be enabled in both ways to deliver feedback signals from a system to the control programs in one way, and the control signals from the control programs to the controlled system in the other way. On the other hand, since most of our programs are PC based, they have to follow the revolutionary progress in the PC technology. Our programs were developed in the DOS environment using an early version of Microsoft C compiler. For those programs to meet the current needs of most PC users, we are working on converting those programs to the Windows environment, using a very advanced and up to date C++ compiler. This compiler is known as the Microsoft Visual C++ Version 4.0. This compiler enables the implementation of very professional and sophisticated Windows 95, 32 bit applications. It also allows a simple utilization of the Object Oriented Programming (OOP) techniques, and lots of powerful graphical and communication tools known as the Microsoft Foundation Classes (MFC). This compiler also allows creating Dynamic Link Libraries (DLLS) that can be liked together or with other Windows programs. These two main aspects, the computer-system interface and the DOS-Windows migration will give our programs a leap frog towards their real implementation.

  12. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 3. Heat transfer between a supernatant gas and a flowing shallow fluidized bed of solids. Final technical report, October 1, 1986

    SciTech Connect (OSTI)

    Boyd, J.H.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Volume II describes the details of heat-transfer studies in a dry fluidized-bed system (called ''heat tray''), which has been proposed for heat recovery from hot gases and for heat management in exothermic reactions. In particular, this report presents the results of bench-scale and pilot-scale experimental studies which quantify heat transfer between a hot supernatant gas (S-gas) and a flowing shallow fluidized bed of solids. A fractional-factorial design of experiments has been performed on two heat-tray systems using three different solids. The results show that fine fluid cracking catalyst (FCC) particles out-perform larger alumina spheres as a fluidized solid. Heat transfer coefficients between the supernatant gas and the shallow fluidized bed approaches 440 W/m/sup 2/-K using FCC with a heat-exchange area of 0.124 m/sup 2/. Various S-gas inlet nozzle configurations have been studied, with a nozzle height equal to one-half of the static bed height (0.051 m) giving the best results. The study shows that short heat-tray lengths (< 0.8 m) are desirable and that S-gas redistributors are needed to compartmentalize the unit. An economic analysis shows that the proposed heat tray would be economically feasible for adaption as a boiler feedwater preheater in a small steam-generation facility, using boiler combustion gases as the S-gas. The payback time for the system would be as short as 1.9 years when used continuously. The heat transfer results from a supernatant gas to a flowing shallow fluidized bed represent the only data reported thus far, and have led to a better understanding of the heat management in the proposed ''heat-tray'' reactor for Fischer-Tropsch synthesis. 20 refs., 46 figs., 15 tabs.

  13. On-line instrumentation for the real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor - a feasibility study

    SciTech Connect (OSTI)

    D'Silva, A.P.; Iles, M.; Rice, G.; Fassel, V.A.

    1984-04-01

    When polynuclear aromatic hydrocargons in the vapor phase are diluted preferably in a rare gas and undergo supersonic jet expansion, rotationally cooled molecules with absorption bandwidths of the order of 0.01 nm (FWHM) are obtained. Selective excitation with a tunable dye laser into such narrow absorption bands leads to the observation of highly specific luminescence spectra. Such an approach has been utilized for the on-line, real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor.

  14. High-temperature-staged fluidized-bed combustion (HITS), bench scale experimental test program conducted during 1980. Final report

    SciTech Connect (OSTI)

    Anderson, R E; Jassowski, D M; Newton, R A; Rudnicki, M L

    1981-04-01

    An experimental program was conducted to evaluate the process feasibility of the first stage of the HITS two-stage coal combustion system. Tests were run in a small (12-in. ID) fluidized bed facility at the Energy Engineering Laboratory, Aerojet Energy Conversion Company, Sacramento, California. The first stage reactor was run with low (0.70%) and high (4.06%) sulfur coals with ash fusion temperatures of 2450/sup 0/ and 2220/sup 0/F, respectively. Limestone was used to scavenge the sulfur. The produced low-Btu gas was burned in a combustor. Bed temperature and inlet gas percent oxygen were varied in the course of testing. Key results are summarized as follows: the process was stable and readily controllable, and generated a free-flowing char product using coals with low (2220/sup 0/F) and high (2450/sup 0/F) ash fusion temperatures at bed temperatures of at least 1700/sup 0/ and 1800/sup 0/F, respectively; the gaseous product was found to have a total heating value of about 120 Btu/SCF at 1350/sup 0/F, and the practicality of cleaning the hot product gas and delivering it to the combustor was demonstrated; sulfur capture efficiencies above 80% were demonstrated for both low and high sulfur coals with a calcium/sulfur mole ratio of approximately two; gasification rates of about 5,000 SCF/ft/sup 2/-hr were obtained for coal input rates ranging from 40 to 135 lbm/hr, as required to maintain the desired bed temperatures; and the gaseous product yielded combustion temperatures in excess of 3000/sup 0/F when burned with preheated (900/sup 0/F) air. The above test results support the promise of the HITS system to provide a practical means of converting high sulfur coal to a clean gas for industrial applications. Sulfur capture, gas heating value, and gas production rate are all in the range required for an effective system. Planning is underway for additional testing of the system in the 12-in. fluid bed facility, including demonstration of the second stage char burnup reactor.

  15. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  16. Second generation pressurized fluidized-bed combustion (PFBC) research and development, Phase 2 -- Task 4, carbonizer testing. Volume 1, Test results

    SciTech Connect (OSTI)

    Froehlich, R.; Robertson, A.; Vanhook, J.; Goyal, A.; Rehmat, A.; Newby, R.

    1994-11-01

    During the period beginning November 1991 and ending September 1992, a series of tests were conducted at Foster Wheeler Development Corporation in a fluidized-bed coal carbonizer to determine its performance characteristics. The carbonizer was operated for 533 hours in a jetting fluidized-bed configuration during which 36 set points (steady-state periods) were achieved. Extensive data were collected on the feed and product stream compositions, heating values, temperatures, and flow rates. With these data, elemental and energy balances were computed to evaluate and confirm accuracy of the data. The carbonizer data were not as self-consistent as could be desired (balance closure imperfection). A software package developed by Science Ventures, Inc., of California, called BALAID, was used to reconcile the carbonizer data; the details of the reconciliation have been given in Volume 1 of this report. The reconciled data for the carbonizer were rigorously analyzed, correlations were developed, and the model was updated accordingly. The model was then used in simulating each of the 36 steady-state periods achieved in the pilot plant. The details are given in this Volume of the report.

  17. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; John Gaudlip; Matthew Lapinsky; Rhett McLaren; William Serencsits; Neil Raskin; Tom Steitz; Joseph J. Battista

    2003-03-26

    The Pennsylvania State University, utilizing funds furnished by the U.S. Department of Energy's Biomass Power Program, investigated the installation of a state-of-the-art circulating fluidized bed boiler at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring biofuels and coal-based feedstocks. The study was performed using a team that included personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Foster Wheeler Energy Corporation; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. The activities included assessing potential feedstocks at the University Park campus and surrounding region with an emphasis on biomass materials, collecting and analyzing potential feedstocks, assessing agglomeration, deposition, and corrosion tendencies, identifying the optimum location for the boiler system through an internal site selection process, performing a three circulating fluidized bed (CFB) boiler design and a 15-year boiler plant transition plan, determining the costs associated with installing the boiler system, developing a preliminary test program, determining the associated costs for the test program, and exploring potential emissions credits when using the biomass CFB boiler.

  18. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke; Joseph J. Battista

    2001-03-31

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Services, Inc., and Cofiring Alternatives.

  19. Fluidized bed combustion

    SciTech Connect (OSTI)

    Sowards, N.K.; Murphy, M.L.

    1991-10-29

    This patent describes a vessel. It comprises a fluid bed for continuously incinerating fuel comprising tire segments and the like which comprise metallic wire tramp and for concurrently removing tramp and bed materials at a bottom effluent exit means of the vessel, the vessel further comprising static air distributor means at the periphery of the bed comprising a substantially centrally unobstructed relatively large central region in which the fluid bed and fuel only are disposed and through which bed material and tramp migrate without obstruction to and through the effluent exit means, downwardly and inwardly stepped lower vessel wall means and a plurality of peripherally located centrally directed vertically and horizontally offset spaced air influent means surrounding the central region and associated with the stepped lower vessel wall means by which the bed is supported and fluidized.

  20. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  1. The Lakeland McIntosh Unit 4 demonstration project utilizing Foster Wheeler`s pressurized circulating fluidized-bed combustion technology

    SciTech Connect (OSTI)

    McClung, J.D.; Provol, S.J.; Morehead, H.T.; Dodd, A.M.

    1997-12-31

    The City of Lakeland, Florida, Foster Wheeler and the Westinghouse Electric Corporation have embarked on the demonstration of a Clean Coal Technology at the City of Lakeland`s McIntosh Power Station in lakeland, Polk County, Florida. The project will demonstrate the Pressurized Circulating Fluidized Bed Combustion (PCFB) technology developed by Foster Wheeler and Westinghouse. The Lakeland McIntosh Unit 4 Project is a nominal 170 MW power plant designed to burn a range of low- to high-sulfur coals. The combined cycle plant employs a Westinghouse 251B12 gas turbine engine in conjunction with a steam turbine operating in a 2400/1000/1000 steam cycle. The plant will demonstrate both the PCFB and topped PCFB combustion technologies. This paper provides a process description of the Foster Wheeler PCFB and Topped PCFB technologies and their application to the Lakeland McIntosh Unit 4 Project.

  2. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Curtis Jawdy

    2000-10-09

    The Pennsylvania State University, under contract to the US Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal or coal refuse, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Corporation, Foster Wheeler Development Corporation, and Cofiring Alternatives. The major emphasis of work during this reporting period was to assess the types and quantities of potential feedstocks and collect samples of them for analysis. Approximately twenty different biomass, animal waste, and other wastes were collected and analyzed.

  3. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, April 1-June 30, 1983

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. Experimental work was initiated on the unsteady-state Fischer-Tropsch synthesis using a fully-automated vibrofluidized microreactor system and a computer-controlled on-line gas chromatographic (GC) system for product analysis. Both the reactor and GC systems performed well in all experiments, and no mechanical problems were observed throughout the experiments lasting as long as twenty hours. Preliminary estimates indicated that the conversion of CO to carbon was only on the order of one-tenth of one percent. This encouraging result provided evidence that it should be possible to experimentally identify cycling conditions which could prevent carbon deposits on the catalyst while treating a synthesis gas of low H/sub 2/:CO ratio.

  4. Development and Implementation of 3-D, High Speed Capacitance Tomography for Imaging Large-Scale, Cold-Flow Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Qussai Marashdeh

    2012-09-30

    A detailed understanding of multiphase flow behavior inside a Circulating Fluidized Bed (CFB) requires a 3-D technique capable of visualizing the flow field in real-time. Electrical Capacitance Volume Tomography (ECVT) is a newly developed technique that can provide such measurements. The attractiveness of the technique is in its low profile sensors, fast imaging speed and scalability to different section sizes, low operating cost, and safety. Moreover, the flexibility of ECVT sensors enable them to be designed around virtually any geometry, rendering them suitable to be used for measurement of solid flows in exit regions of the CFB. Tech4Imaging LLC has worked under contract with the U.S. Department of Energyâ??s National Energy Technology Laboratory (DOE NETL) to develop an ECVT system for cold flow visualization and install it on a 12 inch ID circulating fluidized bed. The objective of this project was to help advance multi-phase flow science through implementation of an ECVT system on a cold flow model at DOE NETL. This project has responded to multi-phase community and industry needs of developing a tool that can be used to develop flow models, validate computational fluid dynamics simulations, provide detailed real-time feedback of process variables, and provide a comprehensive understating of multi-phase flow behavior. In this project, a complete ECVT system was successfully developed after considering different potential electronics and sensor designs. The system was tested at various flow conditions and with different materials, yielding real-time images of flow interaction in a gas-solid flow system. The system was installed on a 12 inch ID CFB of the US Department of Energy, Morgantown Labs. Technical and economic assessment of Scale-up and Commercialization of ECVT was also conducted. Experiments conducted with larger sensors in conditions similar to industrial settings are very promising. ECVT has also the potential to be developed for imaging multi-phase flow systems in high temperature and high pressure conditions, typical in many industrial applications.

  5. Dynamic Modeling and Control Studies of a Two-Stage Bubbling Fluidized Bed Adsorber-Reactor for Solid-Sorbent CO{sub 2} Capture

    SciTech Connect (OSTI)

    Modekurti, Srinivasarao; Bhattacharyya, Debangsu; Zitney, Stephen E.

    2013-07-31

    A one-dimensional, non-isothermal, pressure-driven dynamic model has been developed for a two-stage bubbling fluidized bed (BFB) adsorber-reactor for solid-sorbent carbon dioxide (CO{sub 2}) capture using Aspen Custom Modeler® (ACM). The BFB model for the flow of gas through a continuous phase of downward moving solids considers three regions: emulsion, bubble, and cloud-wake. Both the upper and lower reactor stages are of overflow-type configuration, i.e., the solids leave from the top of each stage. In addition, dynamic models have been developed for the downcomer that transfers solids between the stages and the exit hopper that removes solids from the bottom of the bed. The models of all auxiliary equipment such as valves and gas distributor have been integrated with the main model of the two-stage adsorber reactor. Using the developed dynamic model, the transient responses of various process variables such as CO{sub 2} capture rate and flue gas outlet temperatures have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the incoming flue gas from pulverized coal-fired power plants. In control studies, the performance of a proportional-integral-derivative (PID) controller, feedback-augmented feedforward controller, and linear model predictive controller (LMPC) are evaluated for maintaining the overall CO{sub 2} capture rate at a desired level in the face of typical disturbances.

  6. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    SciTech Connect (OSTI)

    Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

    2014-01-10

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

  7. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume VI. FBC-Data Base-Management-System (FBC-DBMS) development

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The primary goal of the Fluidized Bed Combustor Data Base, (FBCDB), situated in MIT's Energy laboratory, is to establish a data repository for the express use of designers and research personnel involved in FBC development. DBMS is a software that provides an efficient way of storing, retrieving, updating and manipulating data using an English-like query language. It is anticipated that the FBCDB would play an active and a direct role in the development of FBC technology as well as in the FBC commercial application. After some in-house experience and after a careful and extensive review of commercially available database systems, it was determined that the Model 204 DBMS by Computer Corporation of America was the most suitable to our needs. The setup of a prototype in-house database also allowed us to investigate and understand fully the particular problems involved in coordinating FBC development with a DBMS. Various difficult aspects were encountered and solutions had been sought. For instance, we found that it was necessary to rename the variables to avoid repetition as well as to increase usefulness of our database and, hence, we had designed a classification system for which variables were classified under category to achieve standardization of variable names. The primary content of FBCDB is a collection of data points defined by the value of a number of specific FBC variables. A user may interactively access the database from a computer terminal at any location, retrieve, examine, and manipulate the data as well as produce tables or graphs of the results.

  8. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    1982-10-21

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  9. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  10. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of alkali chlorides and sulfates gives increased sintering. At the same time, increased amounts calcium salts in the ash appear to reduce sintering tendency. Thus, the results suggest that a calcium based sorbent for SO{sub 2} and HCl capture might reduce problems related to ash sintering. An extensive literature exists, however, that states otherwise.

  11. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect (OSTI)

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the TTT steam reforming process ability to destroy organics in the Tank 48 simulant and produce a soluble carbonate waste form. The ESTD was operated at varying feed rates and Denitration and Mineralization Reformer (DMR) temperatures, and at a constant Carbon Reduction Reformer (CRR) temperature of 950 C. The process produced a dissolvable carbonate product suitable for processing downstream. ESTD testing was performed in 2009 at the Hazen facility to demonstrate the long term operability of an integrated FBSR processing system with carbonate product and carbonate slurry handling capability. The final testing demonstrated the integrated TTT FBSR capability to process the Tank 48 simulant from a slurry feed into a greater than 99.9% organic free and primarily dissolved carbonate FBSR product slurry. This paper will discuss the SRNL analytical results of samples analyzed from the 2008 and 2009 THOR{reg_sign} steam reforming ESTD performed with Tank 48H simulant at HRI in Golden, Colorado. The final analytical results will be compared to prior analytical results from samples in terms of organic, nitrite, and nitrate destruction.

  12. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  13. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, September 1, 1982-March 31, 1983. [Large number of references

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past several months, the design, construction and steady-state testing of a fully-automated vibrofluidized microreactor system have been successfully completed, and a computer-controlled gas chromatographic (GC) system for gas-product analysis has also been tied to the reactor system. Work on unsteady-state Fischer-Tropsch synthesis experiments is to be initiated shortly. In addition, supporting hydrodynamic and heat-transfer studies in several shallow fluidized-bed systems have produced some encouraging data. The results indicate very high heat-transfer coefficients of 300-400 W/m/sup 2/-/sup 0/K between a shallow bed and its immersed horizontal heat-transfer tube, and of about 7000 W/m/sup 2/-/sup 0/K between a supernatant gas stream and a shallow bed which closely simulates the microreactor system in use.

  14. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, July 1, 1983-April 30, 1984

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1984-05-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past ten months, numerous steady-state and unsteady-state Fischer-Tropsch synthesis experiments from a low H/sub 2/:CO gas were performed using a computer-controlled vibrofluidized microreactor and gas chromatographic (GC) system. The results have revealed specific directions for design and operational improvements of the microreactor system so as to effectively control the cycling of reactant gases during unsteady-state Fischer-Tropsch synthesis, and several modified microreactor systems have been constructed and tested.

  15. Fischer-Tropsch synthesis from a low HH/sub 2/:CO gas in a dry fluidized-bed system. Volume 1. Project summary. Final technical report, October 1, 1986. [Heat tray

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1986-10-01

    The objective of this project is to experimentally develop and demonstrate a dry fluidized-bed reactor system (called ''heat tray'') for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of an iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. The project has been carried out in two key tasks: (1) development of a microreactor system for unsteady-state Fischer-Tropsch synthesis, simulating the life history of an iron catalyst particle in a ''heat-tray'' reactor; and (2) supporting fluidization studies. The present Volume I summarizes the key conclusions and recommendations from this project, and the accompanying Volumes II and III describes the details of experimental investigations and results. 12 refs., 8 figs., 2 tabs.

  16. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

  17. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-09-18

    Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

  18. Steam gasification of coal at low-medium (600-800{sup o}C) temperature with simultaneous CO{sub 2} capture in a bubbling fluidized bed at atmospheric pressure. 2. Results and recommendations for scaling up

    SciTech Connect (OSTI)

    Corella, J.; Toledo, J.M.; Molina, G. [Universidad Complutense de Madrid, Madrid (Spain). Dept. of Chemical Engineering

    2008-03-19

    A gasification gas with an H{sub 2} content as high as 80 vol %, dry basis has been obtained by gasification of coal with pure steam at 600-800{sup o}C. The gasifier used was an atmospheric and bubbling fluidized bed operating with CaO in the bed as the CO{sub 2} sorbent. The research was carried out at a small pilot plant scale with continuous feeding of coal and batch mode introduction of the CaO. The gas composition and gas quality (tar content) is given for the following variables of operation: (a) type of in-bed sorbent used, (b) the amount of CaO in the bed related to the amount of coal fed, (c) temperature in the gasifier bed, (d) weight hourly space velocity (h{sup -1}) of the coal in the gasifier, and (e) time(-on-stream). To capture CaO at atmospheric pressure, the gasification with in-bed CaO had to be carried out at low-medium (600-800{sup o}C) gasification temperatures. For this reason, the tar content in the gasification gas was high (up to 52 g/Nm{sup 3}), which lowered the value of the H{sub 2}-rich gasification raw gas. It is demonstrated that a gas rich in H{sub 2} (80 vol % H{sub 2}, dry basis), and with very low CO{sub 2} and tar contents, can be obtained only if the coal gasification, at atmospheric pressure and with pure steam, is carried out at (CaO/coal) ratios above 10-15.

  19. Second-generation pressurized fluidized-bed combustion plant: Conceptual design and optimization of a second-generation PFB combustion plant. Phase 2, Annual report, October 1991--September 1992

    SciTech Connect (OSTI)

    Robertson, A.; Domeracki, W.; Newby, R.; Rehmat, A.; Horazak, D.

    1992-10-01

    After many years of experimental testing and development work, coal-fired pressurized fluidized bed (PFB) combustion combined-cycle power plants are moving toward reality. Under the US Department of Energy`s Clean Coal Technology Program, a 70-MWe PFB combustion retrofit, utilizing a 1525{degrees}F gas turbine inlet temperature, has been built and operated as a demonstration plant at the American Electric Power Company`s Tidd Plant in Brilliant, Ohio. As PFB combustion technology moves closer and closer to commercialization, interest is turning toward the development of an even more efficient and more cost-effective PFB combustion plant. The targeted goals of this ``second-generation`` plant are a 45-percent efficiency and a cost of electricity (COE) that is at least 20 percent lower than the COE of a conventional pulverized-coal (PC)-fired plant with stack gas scrubbing. In addition, plant emissions should be within New Source Performance Standards (NSPS) and the plant should have high availability, be able to burn different ranks of coal, and incorporate modular construction technologies. In response to this need, a team of companies led by Foster Wheeler Development Corporation (FWDC). The key components in the proposed second-generation plant are the carbonizer, CPFBC, ceramic cross-flow filter, and topping combustor. Unfortunately, none of these components has been operated at proposed plant operating conditions, and experimental tests must be conducted to explore/determine their performance throughout the proposed plant operating envelope. The major thrust of Phase 2 is to design, construct, test, and evaluate the performance of the key components of the proposed plant.

  20. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 2. Development of microreactor systems for unsteady-state Fischer-Tropsch synthesis. Final technical report. [408 references

    SciTech Connect (OSTI)

    Whiting, G.K.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Vibrofluidized microreactor systems have been developed for studies of unsteady-state Fischer-Tropsch synthesis. This development is aimed at preventing carbon deposition on a fused-iron catalyst in a novel reactor called the ''heat tray.'' This reactor involves a supernatant gas flowing over a shallow fluidized bed of catalyst particles. Three systems were built: (1) a vibrofluidized-bed microreactor system for obtaining baseline carbon deposition information under industrially important reaction conditions; (2) a sliding-plug vibrofluidized-bed microreactor system for rapid switching of feed gases in the F-T synthesis; and (3) a cold-flow microreactor model for studying the gas mixing characteristics of the sliding-plug vibrofluidized-bed microreactor. The results show that catalyst defluidization occurred under steady-state synthesis conditions below 395 C using a feed gas of H/sub 2//CO ratio of 2:1 or less. Above 395 C, the probability of hydrocarbon chain growth (..cap alpha.. < 0.50 to prevent accumulation of high-molecular-weight species that cause defluidization. Carbon deposition was rapid above 395 C when a feed gas of H/sub 2//CO ratio of 2:1 or less was used. Cold-flow microreactor model studies show that rapid (on the order of seconds), quantitative switching of feed gases over a vibrofluidized bed of catalyst could be achieved. Vibrofluidization of the catalyst bed induced little backmixing of feed gas over the investigated flow-rate range of 417 to 1650 actual mm/sup 3//s. Further, cold-flow microreactor model studies showed intense solid mixing when a bed of fused-iron catalyst (150 to 300 microns) was vibrofluidized at 24 cycles per second with a peak-to-peak amplitude of 4 mm. The development of the microreactor systems provided an easy way of accurately determining integral fluid-bed kinetics in a laboratory reactor. 408 refs., 156 figs., 27 tabs.

  1. Improving Tor performance through better path selection

    E-Print Network [OSTI]

    Chen, Fallon Ting

    2010-01-01

    S. Rollyson, “Improving tor onion routing client latency,”approach in “Improving Tor Onion Routing Client Latency” [C. Pasquale, Chair Tor, the Onion Router, is a popular

  2. State of Industrial Fluidized Bed Combustion 

    E-Print Network [OSTI]

    Mesko, J. E.

    1982-01-01

    A new combustion technique has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal limits. Low quality fuels can be burned directly...

  3. State of Fluidized Bed Combustion Technology 

    E-Print Network [OSTI]

    Pope, M.

    1979-01-01

    A new combustion technology has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal EPA limits. Low quality fuels can be burned...

  4. Mathematical modeling of fluidized bed reactors 

    E-Print Network [OSTI]

    Nasif, Nilufer Havva

    1985-01-01

    -C. Computational Procedure. II-C-1. Bed Expansion II-C-2. Total Number of Mass Transfer Units II-C-3. Effective Bubble Size (s) II-C-4. Conversion. III COMPARISON OF MATHEMATICAL MODELS FOR A FIRST ORDER REACTION. III-A. The Davidson and Harrison Model (DHM...) Page 14 18 18 19 21 22 22 III-A-1. III-A-2. DHPM Model with Constant Bubble Size. DHPM Model with Variable Bubble Size, 22 23 III-A-3. III-A-4. DHPF Model with Size. DHPF Model with Size. Constant Bubble Variable Bubble 24 25...

  5. Fluidized bed gasification of agricultural residue 

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01

    at the operat- ing conditions used. The experimental data were also used to develop an empirical model based on temperature, fuel to air ratio, and their interactions. Cotton gin wastes were gasified with air to provide a fuel gas suitable for use... system include material balances for each of the components, process operating conditions, and applicable equilibrium relationships. Gumz (1950) applied these meth- ods to estimate the equilibrium gas composition from a fixed bed coal gasifier...

  6. Circulating Fluidized Bed Combustion Boiler Project 

    E-Print Network [OSTI]

    Farbstein, S. B.; Moreland, T.

    1984-01-01

    the bottom of the combustion chamber as bottom ash and from the baghouse as fly ash. A portion of the heat is absorbed in the combustion chamber, and the remaining heat is recovered in the convection section of the boiler. There are no tubes...-sulfur Illinois coal. Limestone use is projected at 11-14.000 tons per year. Solid residue (ash, spent limestone and calcium sulfate) to be disposed will be 15-22,000 tons per year. This projected use of limestone is based on the use of Illinois No. 6 coal...

  7. Stability of Gas-Fluidized Beds

    E-Print Network [OSTI]

    Mandich, Kevin Matthew

    between the domi- nant disturbance frequency obtained fromcorresponding to the disturbance frequency of the leadingis dominant, the disturbance frequency decreases with Re. (

  8. Fluidized bed paint stripping and sludge burning

    SciTech Connect (OSTI)

    Bhatia, J.; Staffin, H.K.

    1986-01-01

    High volume automated painting, as encountered in the painting of automobiles and appliances, requires that the item being painted be positioned in a conveying frame or fixture so that the painting machine or robot achieves a reproducible, high quality paint job. These conveying frames or fixtures are extensive fabrications carefully designed to position and support the item being painted. In the case of automotive painting, they are rather large and involve substantial weights, because they must be capable of supporting and positioning auto bodies and large sub-assemblies.

  9. Fluidized Bed Technology - Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive

  10. Torchestra : reducing interactive trac delays over Tor

    E-Print Network [OSTI]

    Gopal, Deepika

    2012-01-01

    and Paul Syverson. Tor: The Second- Generation Onion Router.Hovav Shacham, Chair Tor is an onion routing network thatTor Architecture Tor stands for “The Onion Router” and is a

  11. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE (WTP-SW) BY FLUIDIZED BED STEAM REFORMING (FBSR) USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

    2014-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150°C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750°C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford’s WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing. The granular products (both simulant and radioactive) were tested and a subset of the granular material (both simulant and radioactive) were stabilized in a geopolymer matrix. Extensive testing and characterization of the granular and monolith material were made including the following: ? ASTM C1285 (Product Consistency Test) testing of granular and monolith; ? ASTM C1308 accelerated leach testing of the radioactive monolith; ? ASTM C192 compression testing of monoliths; and ? EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) testing. The significant findings of the testing completed on simulant and radioactive WTP-SW are given below: ? Data indicates {sup 99}Tc, Re, Cs, and I

  12. A Tor Design Proposal November 30, 2005

    E-Print Network [OSTI]

    by the observation that Tor is currently difficult to install and that users are generally unfamiliar with onionFoxTor A Tor Design Proposal November 30, 2005 1.0 Design Overview ..........................................................................4 3.0 Tor User Interface Design

  13. DefenestraTor: Throwing out Windows in Tor Mashael AlSabah1

    E-Print Network [OSTI]

    Goldberg, Ian

    by source-routing their traffic through three Tor routers using onion routing [14]. Context. ConventionalDefenestraTor: Throwing out Windows in Tor Mashael AlSabah1 , Kevin Bauer1, , Ian Goldberg1 , Dirk, San Diego {dlmccoy,savage,voelker}@cs.ucsd.edu Abstract. Tor is one of the most widely used privacy

  14. A Tune-up for Tor: Improving Security and Performance in the Tor Network Robin Snader

    E-Print Network [OSTI]

    Borisov, Nikita

    -run replacement net- work using the second-generation onion routing design -- Tor [8] -- has been operationalA Tune-up for Tor: Improving Security and Performance in the Tor Network Robin Snader Department The Tor anonymous communication network uses self- reported bandwidth values to select routers

  15. DefenestraTor: Throwing Out Windows in Tor Mashael AlSabah1

    E-Print Network [OSTI]

    Voelker, Geoffrey M.

    by source-routing their traffic through three Tor routers using onion routing [14]. Context. ConventionalDefenestraTor: Throwing Out Windows in Tor Mashael AlSabah1 , Kevin Bauer1, , Ian Goldberg1 , Dirk, San Diego {dlmccoy,savage,voelker}@cs.ucsd.edu Abstract. Tor is one of the most widely used privacy

  16. Another Tor is possible Amadou Moctar Kane

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    a very little number of onion router (OR) in the Tor network (about 6000 OR for around 300,000 users path. More recently, Tor was created from the Onion Routing principles. It was originally FundedAnother Tor is possible Amadou Moctar Kane KSecurity, BP 47136, Dakar, Senegal. amadou1@gmail

  17. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01

    a problem which is green house gas (CO 2 ) emission. Nearly2013) The control of green house gas (CO 2 ) emission is an

  18. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    - OPERATIONS O F F I C E ABSTRACT Allied Chemical Corporation a t the Idaho National Engineering Labora- t o r y i s devel o p i n g 1 i q u i d-f 1 u i d i zed- bed she 1 1...

  19. Particle Receiver Integrated with Fluidized Bed (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01

    National Renewable Energy Laboratory is one of the 2012 SunShot CSP R&D awardees for their advanced receivers. This fact sheet explains the motivation, description, and impact of the project.

  20. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    Hanford Envelope A composite (68 tank) simulant tested Redesigned for Shielded Cell Facility (SCF) in 2006 7 INEEL SAIC STAR FACILITY 6" TTT HAZEN FACILITY 6" TTT HAZEN FACILITY...

  1. Technical evaluation: pressurized fluidized-bed combustion technology...

    Office of Scientific and Technical Information (OSTI)

    COMBUSTORS; TECHNOLOGY ASSESSMENT; ECONOMICS; ENVIRONMENTAL IMPACTS; PERFORMANCE; AIR POLLUTION CONTROL; DESIGN; EFFICIENCY; GAS TURBINES; HOT GAS CLEANUP; RESEARCH...

  2. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01

    the gasification processes in a BFB coal gasifier, chemicalby a partition wall in the BFB reactor. Solid and gas mixingand right compartment in the BFB reactor. A larger space is

  3. EIS-0289: JEA Circulating Fluidized Bed Combustor Project

    Broader source: Energy.gov [DOE]

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the...

  4. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming...

    Office of Environmental Management (EM)

    River Company (WSRC) for the United States Department of Energy under Contract No. DEA-AC09-96SR18500 and is an account of work performed under that contract. Neither the...

  5. Heavy oil upgrading via fluidized bed processing and hydrogenation processing

    SciTech Connect (OSTI)

    Dawson, F.N. Jr. [California Synfuels Research Corp., Palos Verdes, CA (United States)

    1995-09-01

    California is the second largest crude oil producer in the lower 48 states. Nearly half of its production is heavy oil, difficult to transport and costly to refine. Given better methods of processing, production could be expanded. Likewise, huge worldwide reserves of heavy oils could be better exploited if more attractive processing methods were available. Midway Sunset crude at 11.8 API gravity, is a fairly difficult crude to process. It has about 1.5 percent sulfur, a very high nitrogen content, in the range of 0.7--0.8%, and metals of approximately 120--170 ppm, vanadium plus nickel. The authors will be reporting here results of the pilot plant testing to see whether non-catalytic fluid bed cracking technology, operated at low conversion, followed by hydrogenation would be economically attractive. Results suggest that this approach is competitive with delayed coking and with atmospheric resid desulfurization. This approach successfully combines carbon removal and hydrogen addition techniques for heavy oil upgrading. Comparative yields, product quality and economic considerations are reviewed in this study.

  6. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  7. Combustion of Cattle Manure in a Fluidized Bed Combustor 

    E-Print Network [OSTI]

    Annamalai, K.; Colaluca, M. A.; Ibrahim, M. Y.; Sweeten, J. M.

    1988-01-01

    from -ZO to +ZO percent while keeping bed temperature constant at 650 0 e (lZ00?F) and u/u mf - 1.5. The concentrations of eo z , eo, eH 4 , e H , and e H Z 4 3 6 diminished with the increase in percentage of excess air (Figure 4). Even though... there is increased production of eo due to oxidation of Z eo, eH 4 , etc., the air dilution effect had a tendency to reduce eo Z concentration. The eo and hydrocarbons appear to have decreased with more excess air. Similar results were observed and Madan [la...

  8. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Membrane Bioreactor for Energy-Efficient Wastewater Reuse More Documents & Publications Energy Positive Water Resource Recovery Workshop Presentations Anaerobic MBR: Challenges...

  9. Waste Heat Recovery in Cement Plants By Fluidized Beds 

    E-Print Network [OSTI]

    Fraley, L. D.; Ksiao, H. K.; Thunem, C. B.

    1984-01-01

    , the industry has reduced the fuel requirement per ton of cement from about 7 million Btu per ton in old plants to less than 3 million Btu per ton in the most modern plants....

  10. Circulating Fluidized Bed (CFB) Boilers Market will grow due...

    Open Energy Info (EERE)

    Energy Concerns to Push Global Market to Grow at 8.1% CAGR from 2013 to 2019 Oil Shale Market is Estimated to Reach USD 7,400.70 Million by 2022 more Group members (32)...

  11. Experimental study of fluidized bed combustion of feedlot manure 

    E-Print Network [OSTI]

    Madan, Ajit M.

    1984-01-01

    . CHAPTER II LITERATURE REVIEH Most of the previous research has dealt with fuel characteristics, pyrolysis and gasification or partial oxida- tion of feedlot manure (Walawender, et al. , 1973; Huffman, 1978; Kreis, 1979; Raman, et al. , 1981). A review... from manure A to manure B. The pyrolysis starts around 200 C and is complete at about 700 C. This trace was used to obtain the kinetics of pyrolysis of manure global preexponential factor as 0. 02 per sec. and the global activation energy as 1400 KJ...

  12. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    2004-07-01

    Enabling Computational Technology Will Directly Impact the Energy Requirements of Catalytic and Non-Catalytic Reaction Processes.

  13. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01

    processes in a BFB coal gasifier, chemical engineeringbed biomass steam gasifier, Powder Technology 180 (2008)The reaction condition of gasifier is 800 o C and 400 psi.

  14. Pressurized fluidized bed combustion low temperature cycle demonstration plant

    SciTech Connect (OSTI)

    Mukherjee, D.K.

    1984-06-01

    The merits of the turbocharged PFBC cycle are well known. Brown Boveri have been working in the past on a concept to commercialize this technology. As the leader of a team, with Foster Wheeler, Burns and Roe and Research Cottrell, Brown Boveri have conceived a turbocharged PFBC retrofit demonstration plant (20 MWe/40 MWe, net heat rate 11,000 BTU/kWh) which is discussed below. Several old power stations in the USA have small coal-fired electric generatin units which are inactive. The boilers are usually unreliable and their overhauling is uneconomical. The balance of the systems is quite often in a relatively good condition. In this retrofit concept the existing conventional boiler is replaced by a field-assembled PFBC steam generator with pneumatic feed system. It is considered that the steam turbogenerator with its complete condensing plant, together with the coal handling and the storage system can be used. The estimated total construction cost for the retrofit installation amounts to $28,000,000 for the 20 MWe and to $40,200,000 for the 40 MWe plant. This price is accurate to within plus/minus 20%. An extrapolation of these costs for a 80 MWe retrofit unit using barge transport for shop-fabricated and assembled components and applying coal-water slurry feed system result in an investment cost of $600/kW approximately. The cost of a retrofit plant looks attractive and indicates that the PFBC turbocharged cycle is economical compared to the conventional plant with FGD, as has been reported before. Improved cost prediction for a 80 MWe unit is only possible if a conceptual design is carried out.

  15. Neural Network Based Montioring and Control of Fluidized Bed.

    SciTech Connect (OSTI)

    Bodruzzaman, M.; Essawy, M.A.

    1996-04-01

    The goal of this project was to develop chaos analysis and neural network-based modeling techniques and apply them to the pressure-drop data obtained from the Fluid Bed Combustion (FBC) system (a small scale prototype model) located at the Federal Energy Technology Center (FETC)-Morgantown. The second goal was to develop neural network-based chaos control techniques and provide a suggestive prototype for possible real-time application to the FBC system. The experimental pressure data were collected from a cold FBC experimental set-up at the Morgantown Center. We have performed several analysis on these data in order to unveil their dynamical and chaotic characteristics. The phase-space attractors were constructed from the one dimensional time series data, using the time-delay embedding method, for both normal and abnormal conditions. Several identifying parameters were also computed from these attractors such as the correlation dimension, the Kolmogorov entropy, and the Lyapunov exponents. These chaotic attractor parameters can be used to discriminate between the normal and abnormal operating conditions of the FBC system. It was found that, the abnormal data has higher correlation dimension, larger Kolmogorov entropy and larger positive Lyapunov exponents as compared to the normal data. Chaotic system control using neural network based techniques were also investigated and compared to conventional chaotic system control techniques. Both types of chaotic system control techniques were applied to some typical chaotic systems such as the logistic, the Henon, and the Lorenz systems. A prototype model for real-time implementation of these techniques has been suggested to control the FBC system. These models can be implemented for real-time control in a next phase of the project after obtaining further measurements from the experimental model. After testing the control algorithms developed for the FBC model, the next step is to implement them on hardware and link them to the experimental system. In this report, the hardware implementation issues of the control algorithms are also discussed.

  16. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  17. Zirconium Nitride Coating Fabrication via Fluidized Bed Chemical Vapor Deposition 

    E-Print Network [OSTI]

    Sudderth, Laura

    2015-04-30

    heated to 60-75 °C. Coatings were qualitatively characterized using energy dispersive X-ray spectroscopy, wavelength dispersive X-ray spectroscopy, and X-ray distribution mapping. Zirconium-based coatings up to 2.2 ± 0.3 ?m thick after 2 days...

  18. 3-D capacitance density imaging of fluidized bed

    DOE Patents [OSTI]

    Fasching, George E. (653 Vista Pl., Morgantown, WV 26505)

    1990-01-01

    A three-dimensional capacitance density imaging of a gasified bed or the like in a containment vessel is achieved using a plurality of electrodes provided circumferentially about the bed in levels and along the bed in channels. The electrodes are individually and selectively excited electrically at each level to produce a plurality of current flux field patterns generated in the bed at each level. The current flux field patterns are suitably sensed and a density pattern of the bed at each level determined. By combining the determined density patterns at each level, a three-dimensional density image of the bed is achieved.

  19. Global Circulating Fluidized Bed Boilers Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:BoreOpenGilliamOhio: EnergyGlenwillow,Iowa:BusCirculating

  20. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street LightingFrom theHighI _s - s i s i^ -RS 1

  1. Circulating Fluidized Bed Boilers Market Analysis | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point, Louisiana: EnergyEnergy Information

  2. Circulating Fluidized Bed Boilers Market Size | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point, Louisiana: EnergyEnergy Information

  3. Circulating Fluidized Bed Boilers Market Trends | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point, Louisiana: EnergyEnergy Information

  4. Circulating Fluidized Bed Boilers Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point, Louisiana: EnergyEnergy Information

  5. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaics »Tankless WaterEnergyJanuary28-982 DOE Hydrogen

  6. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaics »TanklessResearchEnergy2 DOE

  7. From Onions to Shallots: Rewarding Tor Relays with TEARS

    E-Print Network [OSTI]

    From Onions to Shallots: Rewarding Tor Relays with TEARS Rob Jansen1 , Andrew Miller2 , Paul.ford@yale.edu Abstract. The Tor anonymity network depends on volunteers to oper- ate relays, and might offer higher be deployed in the existing Tor network or operate alongside it. 1 Introduction Tor is the most popular

  8. A revocable anonymity in Tor Amadou Moctar Kane

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    . 1 Introduction Tor (The Onion Router) is a free software designed for online anonymity and resistingA revocable anonymity in Tor Amadou Moctar Kane KSecurity, BP 47136, Dakar, Senegal. amadou1@gmail in Tor, which was presented in our recent paper entitled "Another Tor is possible". Compared

  9. A TorPath to TorCoin: Proof-of-Bandwidth Altcoins for Compensating Relays

    E-Print Network [OSTI]

    Coins, so that anyone can verify a TorCoin by checking the blockchain. #12;2 Motivation and Related Work

  10. Enhancing Tor Performance For Bandwidth-Intensive Applications

    E-Print Network [OSTI]

    of the feedback control inherent in Tor's approach to load management ­ namely, probing and circuit selection. We

  11. Enhancing Tor Performance For BandwidthIntensive Applications +

    E-Print Network [OSTI]

    of the feedback control inherent in Tor's approach to load management -- namely, probing and circuit selection. We

  12. Challenges in protecting Tor hidden services from botnet abuse

    E-Print Network [OSTI]

    Hopper, Nicholas J.

    Challenges in protecting Tor hidden services from botnet abuse Nicholas Hopper University of Minnesota, Minneapolis, MN USA hopper@cs.umn.edu Abstract. In August 2013, the Tor network experienced and control server as a Tor hidden service, so that all infected nodes contacted the command and control

  13. The Path Less Travelled: Overcoming Tor's Bottlenecks with Traffic Splitting

    E-Print Network [OSTI]

    Goldberg, Ian

    The Path Less Travelled: Overcoming Tor's Bottlenecks with Traffic Splitting Mashael AlSabah, Kevin of Computer Science University of Waterloo Abstract. Tor is the most popular low-latency anonymity network, Tor has a variety of performance problems that result in poor quality of service, a strong

  14. PIR-Tor: Scalable Anonymous Communication Using Private Information Retrieval

    E-Print Network [OSTI]

    Goldberg, Ian

    PIR-Tor: Scalable Anonymous Communication Using Private Information Retrieval Prateek Mittal1 Femi like Tor do not scale well as they require all users to maintain up-to- date information about all available Tor relays in the sys- tem. Current proposals for scaling anonymous commu- nication advocate

  15. Compromising Tor Anonymity Exploiting P2P Information Leakage

    E-Print Network [OSTI]

    Castelluccia, Claude

    communications. Whereas the cryptographic foundations of Tor, based on onion- routing [4,5,6,7], are knownCompromising Tor Anonymity Exploiting P2P Information Leakage Pere Manils, Abdelberi Chaabane attacks targeting BitTorrent users on top of Tor that reveal their real IP addresses. In a second step, we

  16. The Sniper Attack: Anonymously Deanonymizing and Disabling the Tor Network

    E-Print Network [OSTI]

    Johnson, Aaron

    }@informatik.hu-berlin.de Abstract--Tor is a distributed onion-routing network used for achieving anonymity and resisting censorship and transferring roughly 3 GiB/s in aggregate [8]. Tor uses onion routing [25] to route clients' traffic throughThe Sniper Attack: Anonymously Deanonymizing and Disabling the Tor Network Rob Jansen Florian

  17. Recruiting New Tor Relays with BRAIDS Rob Jansen Nicholas Hopper

    E-Print Network [OSTI]

    Hopper, Nicholas J.

    . INTRODUCTION Tor [53] uses Onion Routing [24] to create a practical sys- tem for low-latency anonymity [14Recruiting New Tor Relays with BRAIDS Rob Jansen Nicholas Hopper University of Minnesota Minneapolis, MN 55455 USA {jansen, hopper, kyd}@cs.umn.edu Yongdae Kim ABSTRACT Tor, a distributed Internet

  18. Throttling Tor Bandwidth Parasites Rob Jansen Paul Syverson

    E-Print Network [OSTI]

    Throttling Tor Bandwidth Parasites Rob Jansen Paul Syverson U.S. Naval Research Laboratory {rob.g.jansen, paul.syverson}@nrl.navy.mil Nicholas Hopper University of Minnesota hopper@cs.umn.edu Abstract Tor of the available network capacity is consumed by a small percentage of Tor users, resulting in severe service degra

  19. Identifying Proxy Nodes in a Tor Anonymization Circuit Sambuddho Chakravarty

    E-Print Network [OSTI]

    Keromytis, Angelos D.

    Identifying Proxy Nodes in a Tor Anonymization Circuit Sambuddho Chakravarty Columbia University, and effective mechanism that exposes the identity of Tor relays participating in a given circuit. Such an attack), we create observable fluctuations that propagate through the Tor network and the Internet to the end

  20. On the Security of the Tor Authentication Protocol

    E-Print Network [OSTI]

    Goldberg, Ian

    On the Security of the Tor Authentication Protocol Ian Goldberg David R. Cheriton School@cs.uwaterloo.ca Abstract. Tor is a popular anonymous Internet communication sys- tem, used by an estimated 250,000 users to anonymously exchange over five terabytes of data per day. The security of Tor depends on properly

  1. The Sniper Attack: Anonymously Deanonymizing and Disabling the Tor Network

    E-Print Network [OSTI]

    }@informatik.hu-berlin.de Abstract--Tor is a distributed onion-routing network used for achieving anonymity and resisting censorshipB/s in aggregate [4]. Tor uses onion routing [5] to route clients' traffic through a circuit of geo- graphicallyThe Sniper Attack: Anonymously Deanonymizing and Disabling the Tor Network Rob Jansen Florian

  2. Tor: The Second-Generation Onion Router Roger Dingledine

    E-Print Network [OSTI]

    Tor: The Second-Generation Onion Router Roger Dingledine The Free Haven Project arma a single multiply encrypted data structure (an onion) to lay each circuit, Tor now uses an incremental@itd.nrl.navy.mil Abstract We present Tor, a circuit-based low-latency anonymous com- munication service. This second

  3. Shining Light in Dark Places: Understanding the Tor Network

    E-Print Network [OSTI]

    Washington at Seattle, University of

    Shining Light in Dark Places: Understanding the Tor Network Damon McCoy1 , Kevin Bauer1 , Dirk used? (2) How is Tor being mis-used? (3) Who is using Tor? To sample the results, we show that web such as web browsing, file sharing, and instant messaging. Since its initial development, researchers have

  4. mTOR Signaling in Growth Control and Disease

    E-Print Network [OSTI]

    Laplante, Mathieu

    The mechanistic target of rapamycin (mTOR) signaling pathway senses and integrates a variety of environmental cues to regulate organismal growth and homeostasis. The pathway regulates many major cellular processes and is ...

  5. mTOR and cancer: many loops in one pathway

    E-Print Network [OSTI]

    Efeyan, Alejo

    The mammalian target of rapamycin (mTOR) is a master regulator of cell growth and division that responds to a variety of stimuli, including nutrient, energy, and growth factors. In the last years, a significant number of ...

  6. Notes on Use of VecTor Programs: The VecTor analysis programs operate in a DOS-environment. Various input files are created or

    E-Print Network [OSTI]

    Vecchio, Frank J.

    Notes on Use of VecTor Programs: The VecTor analysis programs operate in a DOS-environment. Various input files are created or edited using standard text editors; output files are similarly viewed using Works, and output results can be viewed using the post-processor Augustus. Each VecTor program requires

  7. Low-Cost Traffic Analysis of Tor Steven J. Murdoch and George Danezis

    E-Print Network [OSTI]

    Danezis, George

    .Murdoch,George.Danezis}@cl.cam.ac.uk Abstract Tor is the second generation Onion Router, supporting the anonymous transport of TCP streams over, available for public use, already has 50 nodes acting as onion routers (as of November 2004). Tor aimsLow-Cost Traffic Analysis of Tor Steven J. Murdoch and George Danezis University of Cambridge

  8. SkypeMorph: Protocol Obfuscation for Tor Bridges Hooman Mohajeri Moghaddam Baiyu Li

    E-Print Network [OSTI]

    Goldberg, Ian

    SkypeMorph: Protocol Obfuscation for Tor Bridges Hooman Mohajeri Moghaddam Baiyu Li Mohammad {hmohajer,b5li,mderakhs,iang}@cs.uwaterloo.ca ABSTRACT The Tor network is designed to provide users with low- latency anonymous communications. Tor clients build cir- cuits with publicly listed relays to anonymously

  9. Improving Tor using a TCP-over-DTLS Tunnel Joel Reardon

    E-Print Network [OSTI]

    Goldberg, Ian

    Improving Tor using a TCP-over-DTLS Tunnel Joel Reardon Google Switzerland GmbH Brandschenkestrasse. Waterloo, ON, Canada iang@cs.uwaterloo.ca Abstract The Tor network gives anonymity to Internet users by re. This interference greatly contributes to Tor's notorious latency problems. Our solution is to use a TCP

  10. (Nothing else) MATor(s): Monitoring the Anonymity of Tor's Path Selection

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    & Future Work 26 1 #12;1 Introduction The onion routing network Tor is a widely employed low(Nothing else) MATor(s): Monitoring the Anonymity of Tor's Path Selection Michael Backes1,2 Aniket we present MATOR: a framework for rigorously assessing the degree of anonymity in the Tor network

  11. IEEE TRANSACTIONS ON DEPENDABLE AND SECURE COMPUTING 1 Improving Security and Performance in the Tor

    E-Print Network [OSTI]

    Borisov, Nikita

    using the second-generation onion routing design -- Tor [3] -- has been operational for several years in the Tor Network through Tunable Path Selection Robin Snader and Nikita Borisov, Member, IEEE Abstract--The Tor anonymous communication network uses self-reported bandwidth values to select routers for building

  12. Usability of Anonymous Web Browsing: An Examination of Tor Interfaces and Deployability

    E-Print Network [OSTI]

    Van Oorschot, Paul

    --Privacy General Terms Human Factors, Security Keywords Anonymity, browsing, onion routing, privacy, Privoxy, TorUsability of Anonymous Web Browsing: An Examination of Tor Interfaces and Deployability Jeremy of Information and Technology (SITE) University of Ottawa cadams@site.uottawa.ca ABSTRACT Tor is a popular

  13. TorScan: Tracing Long-lived Connections and Differential Scanning Attacks

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    successor of the original Onion Routing Project. The Tor network is a low-latency anonymity network whichTorScan: Tracing Long-lived Connections and Differential Scanning Attacks Alex Biryukov, Ivan Pustogarov, Ralf-Philipp Weinmann University of Luxembourg Abstract. Tor is a widely used anonymity network

  14. On the risks of serving whenever you surf Vulnerabilities in Tor's blocking resistance design

    E-Print Network [OSTI]

    Hopper, Nicholas J.

    , the Tor network consists of roughly 2000 "Onion Routers" that voluntarily relay traffic between who can observe a Tor client's network connections and even control some Onion Routers shouldOn the risks of serving whenever you surf Vulnerabilities in Tor's blocking resistance design Jon

  15. XPay: Practical anonymous payments for Tor routing and other networked services

    E-Print Network [OSTI]

    Carbunar, Bogdan

    XPay: Practical anonymous payments for Tor routing and other networked services Yao Chen, Radu Sion for Tor. We then propose micro- payment protocols of increasingly complex requirements for networked overheads of under 4% and 0.9 ms respectively (in ORPay for Tor), provide full anonymity (both for payers

  16. An Improved Algorithm for Tor Circuit Scheduling Cheriton School of Computer Science

    E-Print Network [OSTI]

    Goldberg, Ian

    Terms Measurement, Performance, Security Keywords Tor, latency, onion routing Permission to make digitalAn Improved Algorithm for Tor Circuit Scheduling Can Tang Cheriton School of Computer Science Science University of Waterloo Waterloo, ON, Canada iang@cs.uwaterloo.ca ABSTRACT Tor is a popular

  17. Aldo Morselli, INFN Roma Tor Vergata 1 Search for Dark Matter in the Sky

    E-Print Network [OSTI]

    Morselli, Aldo

    Aldo Morselli, INFN Roma Tor Vergata 1 Search for Dark Matter in the Sky Aldo Morselli INFN Roma Tor Vergata 14 Jun 2012 Dark Side of the Univers 2012 Buzios 10-15 June #12;Aldo Morselli, INFN Roma press/web releases. #12;Aldo Morselli, INFN Roma Tor Vergata 10 The Fermi LAT gamma-ray sky 3-year all

  18. Power Transformer faulT DeTecTor

    E-Print Network [OSTI]

    Mucina, Ladislav

    Power Transformer faulT DeTecTor Summary of technology Power transformers are major parts of the power distribution network, used to step up and step down voltages for transmission between power stations and electricity consumers. Transformers are prone to failure due to external damage or general

  19. Valeria Cardellini Universit di Roma "Tor Vergata," Italy

    E-Print Network [OSTI]

    Buyya, Rajkumar

    "Tor Vergata," Italy Kalinka Regina Lucas Jaquie Castelo Branco Universidade de São Paulo, Brazil Júlio Cezar Estrella Universidade de São Paulo, Brazil Francisco José Monaco Universidade de São Paulo, Brazil: Jamie Snavely Cover Design: Nick Newcomer Published in the United States of America by Information

  20. Multiphase flow simulations of a moving fluidized bed regenerator in a carbon capture unit

    SciTech Connect (OSTI)

    Sarkar, Avik; Pan, Wenxiao; Suh, Dong-Myung; Huckaby, E. D.; Sun, Xin

    2014-10-01

    To accelerate the commercialization and deployment of carbon capture technologies, computational fluid dynamics (CFD)-based tools may be used to model and analyze the performance of carbon capture devices. This work presents multiphase CFD-based flow simulations for the regeneration device responsible for extracting CO2 from CO2-loaded sorbent particles before the particles are recycled. The use of solid particle sorbents in this design is a departure from previously reported systems, where aqueous sorbents are employed. Another new feature is the inclusion of a series of perforated plates along the regenerator height. The influence of these plates on sorbent distribution is examined for varying sorbent holdup, fluidizing gas velocity, and particle size. The residence time distribution of sorbents is also measured to classify the low regime as plug flow or well-mixed flow. The purpose of this work is to better understand the sorbent flow characteristics before reaction kinetics of CO2 desorption can be implemented.

  1. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    applications including coal gasification, fer- tilizers fromin hydro-gasification reactions, such as coal and biomass,

  2. Supplementary Information for: Electrochemical struvite precipitation from digestate with a fluidized bed

    E-Print Network [OSTI]

    Supplementary Information for: Electrochemical struvite precipitation from digestate for a) magnesium, b) phosphate, c) calcium and d) ammonium for the influent digestate as a function

  3. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

  4. Study of granular temperature in dense fluidized beds by diffusing wave spectroscopy 

    E-Print Network [OSTI]

    Zivkovic, Vladimir

    2009-01-01

    Diffusing wave spectroscopy (DWS), a non-intrusive multiple scattering technique, can be used to study the fundamentals of particle motion in dynamic dense granular media and measure the mean of the square of the particle ...

  5. The performance of fluidized beds, packed beds, and screens as fuel cell electrodes

    E-Print Network [OSTI]

    Ruflin, Justin, 1981-

    2006-01-01

    At present, most fuel cells employ porous gas diffusion (PGD) electrodes. Although much effort has been spent on their development, the performance and cost of PGD electrodes are still major obstacles to the successful ...

  6. Method and apparatus for gasifying with a fluidized bed gasifier having integrated pretreating facilities

    DOE Patents [OSTI]

    Rice, Louis F. (Arcadia, CA)

    1981-01-01

    An integral gasifier including a pretreater section and a gasifier section separated by a distribution grid is defined by a single vessel. The pretreater section pretreats coal or other carbon-containing material to be gasified to prevent caking and agglomeration of the coal in the gasifier. The level of the coal bed of the pretreater section and thus the holding or residence time in said bed is selectively regulated by the amount of pretreated coal which is lifted up a lift pipe into the gasifier section. Thus, the holding time in the pretreater section can be varied according to the amount of pretreat necessary for the particular coal to be gasified.

  7. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  8. Apparatus for high flux photocatalytic pollution control using a rotating fluidized bed reactor

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2003-06-24

    An apparatus based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. An apparatus for high-flux photocatalytic pollution control is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

  9. EA-0646: Pulsed Atmospheric Fluidized-Bed Combustor Development Thermochem, Inc.

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to develop a more economical, efficient, and environmentally acceptable coal-fired combustion technology in Baltimore, Maryland that can be...

  10. Simulation and Life Cycle Assessment of Algae Gasification Process in Dual Fluidized Bed Gasifiers

    E-Print Network [OSTI]

    Azadi, Pooya; Brownbridge, George; Mosbach, Sebastian; Inderwildi, Oliver; Kraft, Markus

    2015-01-01

    , Switzerland. and thus vastly different chemical structures — within a par- ent biomass feedstock: i) focusing on direct conversion of, at least, one of the fractions to molecules with a similar carbon number and chemical structure to that of the desired...

  11. Numerical and experimental studies of IFE target layering in a cryogenic fluidized bed

    E-Print Network [OSTI]

    Boehm, Kurt Julian

    2009-01-01

    individual particle is determined. Knowing the properties of the gas, the Prandtl number is given as a constant

  12. An experimental study of a vertical tube gas-fluidized bed

    E-Print Network [OSTI]

    Mandich, Kevin Matthew

    2010-01-01

    vi ?,T v(r,t) w(r,t) Power spectrum of wall acceleration atcontribution to the wall acceleration power spectrum occursat the wall is computed by integrating the power spectral

  13. NUMERICAL AND EXPERIMENTAL ANALYSIS OF A FLUIDIZED BED FOR IFE TARGET LAYERING Kurt J. Boehm1

    E-Print Network [OSTI]

    Raffray, A. René

    energy (IFE) power plant, multiple laser beams are utilized to implode a direct drive (DD) spherical fuel to provide enough power for an economic power plant, about 500,000 shells need to be produced per day controlled gas stream. Concerns exist, however, including the effect of unbalanced spheres on the bed

  14. Multi-scale chemistry modeling of the thermochemical conversion of biomass in a fluidized bed gasifier

    E-Print Network [OSTI]

    Stark, Addison Killean

    2015-01-01

    The thermochemical conversion of biomass to fuels via syn-gas offers a promising approach to producing fungible substitutes for petroleum derived fuels and chemicals. In order for these fuels to be adopted, they must be ...

  15. Evaluation of cement production using a pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    DeLallo, M.; Eshbach, R.

    1994-01-01

    There are several primary conclusions which can be reached and used to define research required in establishing the feasibility of using PFBC-derived materials as cement feedstock. 1. With appropriate blending almost any material containing the required cement-making materials can be utilized to manufacture cement. However, extensive blending with multiple materials or the use of ash in relatively small quantities would compromise the worth of this concept. 2. The composition of a potential feedstock must be considered not only with respect to the presence of required materials, but just as significantly, with respect to the presence and concentration of known deleterious materials. 3. The processing costs for rendering the feedstock into an acceptable composition and the energy costs associated with both processing and burning must be considered. It should be noted that the cost of energy to produce cement, expressed as a percentage of the price of the product is higher than for any other major industrial product. Energy consumption is, therefore, a major issue. 4. The need for conformance to environmental regulations has a profound effect on the cement industry since waste materials can neither be discharged to the atmosphere or be shipped to a landfill. 5. Fifth, the need for achieving uniformity in the composition of the cement is critical to controlling its quality. Unfortunately, certain materials in very small concentrations have the capability to affect the rate and extent to which the cementitious compound in portland cement are able to form. Particularly critical are variations in the ash, the sulfur content of the coal or the amount and composition of the stack dust returned to the kiln.

  16. Pulsed atmospheric fluidized bed combustion. Technical progress report, July 1994--September 1994

    SciTech Connect (OSTI)

    Not Available

    1994-11-30

    No changes in the process design were encountered during this period. Minor modifications in the combustor vessel and pulse combustor water jacket were made for ease of operation and maintenance. The combustor vessel column location in the foundation was rotated to 90 degrees to accomodate change in bed module orientation. Landings for the platform staircase were added in the structural drawings. Design and drawings for embedded conduits and grounding system were completed.

  17. Numerical and experimental studies of IFE target layering in a cryogenic fluidized bed

    E-Print Network [OSTI]

    Boehm, Kurt Julian

    2009-01-01

    target for inertial confinement fusion“, J. Vac. Sci.Tritium”, Inertial Confinement Fusion, ICF Quarterly Report,set up by the Inertial Confinement Fusion (ICF) group at

  18. Study of factors affecting syngas quality and their interactions in fluidized bed gasification of lignite coal

    E-Print Network [OSTI]

    Spiteri, Raymond J.

    by optimization of the response surface of each index. Ó 2012 Elsevier Ltd. All rights reserved. 1. Introduction in specialized downstream units such as clean fuel combustion, pro- duction of Fischer­Tropsch liquids, and fuel cells, plus a

  19. Operating Experience with a Large Fluidized-Bed Gasifier of Woodwaste 

    E-Print Network [OSTI]

    Guard, R. F. W.

    1982-01-01

    it is consuming over a hundred tons of wood a day, and so between one and two tons of ash have to be trucked out. The ash is collected in bins which are carried to a nearby dump for dis posal. We have commissioned a research group to tell us whether...B lB", GAS ANALYSIS (%) CO 11. 9 11'" H 8.6 7.5 1 ' 2 CH 4.5 4. B'': 4 C H 1.9 1.5'" 2 x N ,C0 ,H 0 Balance Balance 2 2 2 GAS PRODUCTION (scf/lb) dry wood 45.2 45.5'" SENSIBLE HEAT LOSS (%) 1.0 1.8 ASH CONTENT OF CHAR (%) up to 50 25...

  20. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  1. Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor

    SciTech Connect (OSTI)

    Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W.

    2007-06-15

    The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

  2. Performance Model of the Fluidized Bed Copper Oxide Process for SO2/NOx Control

    E-Print Network [OSTI]

    Frey, H. Christopher

    technology for controlling SO2 and NOx emissions from coal-fired power plants. The development strategies for coal-fired power plants. Details of the IECM's copper oxide process, power plant air preheater via the power plant air preheater. The net chemical reactions occurring in the absorber are: CuO (s

  3. Numerical and experimental studies of IFE target layering in a cryogenic fluidized bed

    E-Print Network [OSTI]

    Boehm, Kurt Julian

    2009-01-01

    Production for Inertial Fusion Energy”. HAPL project review,injection in an inertial fusion energy chamber”, FusionProperties for Fusion Energy”, University of California

  4. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    combustion of petroleum-based fuels in conventional engines can cause serious environmental pollution

  5. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

  6. Low Temperature Chemical Vapor Deposition of Zirconium Nitride in a Fluidized Bed 

    E-Print Network [OSTI]

    Arrieta, Marie

    2012-10-19

    thick) on uranium-molybdenum (UMo) particulate fuel. Plate-type fuel with U-xMo (x = 3 to 10 wt.%) particle fuel dispersed in an aluminum matrix is under development at Idaho National Laboratory (INL) for the Reduced Enrichment for Research and Test...

  7. Fuel characteristics and theoretical performance of a fluidized bed combustor with manure as a fuel 

    E-Print Network [OSTI]

    Park, Joon Hwa

    1984-01-01

    . Bio-gas is produced naturally and uncontrolled under anaerobic conditions typical of' septic tanks, and sewage treatment plants. In many cases, bio-gas has been collected and burned to supply the heat requirements of anaerobic digestion or used...

  8. Instrumentation and Evaluation of a Pilot Scale Fluidized Bed Biomass Gasification System 

    E-Print Network [OSTI]

    Maglinao, Amado L

    2009-12-04

    DAQ. ...................................................... 11 Table 2 Bulk density and loading factor ........................................................ 18 Table 3 Sample gasification data readings ..................................................... 22 Table 4 Properties of the three... BED BIOMASS GASIFICATION SYSTEM OVERVIEW The conversion of biomass into energy (also called bioenergy) encompasses wide range of different types and sources of biomass, conversion options and end-use applications. These can be done through either...

  9. Fluidized Bed Technology - An R&D Success Story | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,EnergyFinancingWIPPFixedFloridaBatteries:3060ofAn

  10. Vehicle Technologies Office: AVTA- Diesel Internal Combusion Engine Vehicles

    Broader source: Energy.gov [DOE]

    The Advanced Vehicle Testing Activity (AVTA) uses standard procedures and test specifications to test and collect data from vehicles on dynamometers, closed test tracks, and on-the-road. Downloadable data on the following vehicles is available: 2014 Chevrolet Cruze Diesel, 2013 Volkswagen Jetta TDI, and 2009 Volkswagen Jetta TDI.

  11. One Bad Apple Spoils the Bunch: Exploiting P2P Applications to Trace and Profile Tor Users

    E-Print Network [OSTI]

    Castelluccia, Claude

    that a source wants to leak top secret documents anonymously. It is considered secure to do so through Tor using uses another insecure application on Tor. Is it then possible to associate the top secret documents.g., the one leaking top secret documents) with the IP address of a Tor user. This attack against Tor consists

  12. Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass

    E-Print Network [OSTI]

    FAN, XIN

    2012-01-01

    sewage sludge in a bubbling fluidized bed, Fuel, 2006, 85,fluid velocity. Bubbling fluidized beds have relatively lowbeds, bubbling and circulating fluidized beds, entrained

  13. Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01

    and Bubbling Fluidized Beds ..in Circulating and Bubbling Fluidized Beds Description: Bothfluidized bed with a bubbling fluidized bed. Both are direct

  14. Selective ATP-Competitive Inhibitors of TOR Suppress Rapamycin-Insensitive Function of TORC2 in S. cerevisiae

    E-Print Network [OSTI]

    Liu, Qingsong

    The target of rapamycin (TOR) is a critical regulator of growth, survival, and energy metabolism. The allosteric TORC1 inhibitor rapamycin has been used extensively to elucidate the TOR related signal pathway but is limited ...

  15. Improving efficiency and simplicity of Tor circuit establishment and hidden services

    E-Print Network [OSTI]

    Improving efficiency and simplicity of Tor circuit establishment and hidden services Lasse Øverlier Code 5540, Washington, DC 20375 syverson@itd.nrl.navy.mil, http://chacs.nrl.navy.mil/ / http://www.onion in the Tor anonymizing network by using predistributed Diffie-Hellman values. We eliminate the use of RSA

  16. GSA TEAs ToRs (revised August 2014) Page 1 of 2

    E-Print Network [OSTI]

    Calgary, University of

    GSA TEAs ToRs (revised August 2014) Page 1 of 2 PURPOSE OF THE AWARD: Every year, the GSA presents;GSA TEAs ToRs (revised August 2014) Page 2 of 2 Successful applications will be kept for 2 years after

  17. GSA TEAs ToRs (revised August 2014) Page 1 of 2

    E-Print Network [OSTI]

    Calgary, University of

    GSA TEAs ToRs (revised August 2014) Page 1 of 2 PURPOSE OF THE AWARD: Every year, the GSA presents #12;GSA TEAs ToRs (revised August 2014) Page 2 of 2 Other Regulations: 1. The Teaching & Supervisory faith to remain for the full academic year. 2. The activities of the TEAs-administering committee

  18. Shadow: Running Tor in a Box for Accurate and Efficient Experimentation U.S. Naval Research Laboratory

    E-Print Network [OSTI]

    Shadow: Running Tor in a Box for Accurate and Efficient Experimentation Rob Jansen U.S. Naval@cs.umn.edu Abstract Tor is a large and popular overlay network providing both anonymity to its users and a platform Tor experimentation tech- niques are limited in scale, are inaccurate, or create results

  19. Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology

    E-Print Network [OSTI]

    Li, Yang

    2013-01-01

    circulating fluidized bed (CFB) and fixed fluidized bed (reactors are more advanced than CFB reactors with about 40%

  20. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01

    2 0 Emissions form a Bubbling Fluidized Bed Combustor," Fuelcontrol SO emissions bubbling fluidized-bed coal combustor

  1. Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production

    E-Print Network [OSTI]

    Liu, Zhongzhe

    2013-01-01

    of sawdust in a bubbling fluidized bed. Int J Hydrogenapplication, fluidized bed or bubbling bed should be used

  2. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01

    control SO emissions bubbling fluidized-bed coal combustorN 2 0 Emissions form a Bubbling Fluidized Bed Combustor,"

  3. mTOR Complex 1 Regulates Lipin 1 Localization to Control the SREBP Pathway

    E-Print Network [OSTI]

    Peterson, Timothy R.

    The nutrient- and growth factor-responsive kinase mTOR complex 1 (mTORC1) regulates many processes that control growth, including protein synthesis, autophagy, and lipogenesis. Through unknown mechanisms, mTORC1 promotes ...

  4. Regulation of mTOR complex 1 in response to growth factors and nutrients

    E-Print Network [OSTI]

    Sancak, Yasemin S. (Yasemin Shechner)

    2010-01-01

    In multicellular organisms, cells ensure the simultaneous availability of growth factors and nutrients before they invest in cellular processes that lead to growth. The TOR kinase is a master regulator of cellular growth ...

  5. Regulation of the mTOR Complex 1 Pathway by Nutrients, Growth Factors, and Stress

    E-Print Network [OSTI]

    Sengupta, Shomit

    The large serine/threonine protein kinase mTOR regulates cellular and organismal homeostasis by coordinating anabolic and catabolic processes with nutrient, energy, and oxygen availability and growth factor signaling. Cells ...

  6. Biodegradation of phenolic wastewaters in a three-phase fluidized bed bioreactor with the KMT{reg_sign} biomass support

    SciTech Connect (OSTI)

    Sokol, W.; Halfini, M.R.

    1996-12-31

    A treatment of wastewater from a local refinery in a three-phase fluidised bed bioreactor with the KMT{sup R} biomass support was investigated. It was found that after adding mineral salts to the wastewater to be treated, a reduction in the COD values increased from about 55% to almost 90%. The reduction in COD was increasing with an increase in both a superficial air velocity and a ratio of bed volume to bioreactor volume (V{sub b}/V{sub r}). The highest value of (V{sub b}/V{sub r}) which could be applied in the experiments was 0.7, because at larger (V{sub b}/V{sub r}) movement of the whole bed was impossible. The bioreactor as operated was not successful in degrading thiocyanates, cyanides, nitrates and ammonia. However, results of independent experiments that have been started to adapt the symbiotic populations of microorganisms that may effectively degrade those compounds are promising. Stratification of the support media coated with the biomass led to their movement to the base of the bioreactor where concentration of organic compounds was highest. This was desirable since the compounds could penetrate far into the biofilm so most of the biomass grown on the support was active. 6 refs., 3 figs.

  7. Novel Magnetically Fluidized Bed Reactor Development for the Looping Process: Coal to Hydrogen Production R&D

    SciTech Connect (OSTI)

    Mei, Renwei; Hahn, David; Klausner, James; Petrasch, Jorg; Mehdizadeh, Ayyoub; Allen, Kyle; Rahmatian, Nima; Stehle, Richard; Bobek, Mike; Al-Raqom, Fotouh; Greek, Ben; Li, Like; Chen, Chen; Singh, Abhishek; Takagi, Midori; Barde, Amey; Nili, Saman

    2013-09-30

    The coal to hydrogen project utilizes the iron/iron oxide looping process to produce high purity hydrogen. The input energy for the process is provided by syngas coming from gasification process of coal. The reaction pathways for this process have been studied and favorable conditions for energy efficient operation have been identified. The Magnetically Stabilized Porous Structure (MSPS) is invented. It is fabricated from iron and silica particles and its repeatable high performance has been demonstrated through many experiments under various conditions in thermogravimetric analyzer, a lab-scale reactor, and a large scale reactor. The chemical reaction kinetics for both oxidation and reduction steps has been investigated thoroughly inside MSPS as well as on the surface of very smooth iron rod. Hydrogen, CO, and syngas have been tested individually as the reducing agent in reduction step and their performance is compared. Syngas is found to be the most pragmatic reducing agent for the two-step water splitting process. The transport properties of MSPS including porosity, permeability, and effective thermal conductivity are determined based on high resolution 3D CT x-ray images obtained at Argonne National Laboratory and pore-level simulations using a lattice Boltzmann Equation (LBE)-based mesoscopic model developed during this investigation. The results of those measurements and simulations provide necessary inputs to the development of a reliable volume-averaging-based continuum model that is used to simulate the dynamics of the redox process in MSPS. Extensive efforts have been devoted to simulate the redox process in MSPS by developing a continuum model consist of various modules for conductive and radiative heat transfer, fluid flow, species transport, and reaction kinetics. Both the Lagrangian and Eulerian approaches for species transport of chemically reacting flow in porous media have been investigated and verified numerically. Both approaches lead to correct prediction of hydrogen production rates over a large range of experimental conditions in the laboratory scale reactor and the bench-scale reactor. In the economic analysis, a comparison of the hydrogen production plants using iron/iron oxide looping cycle and the conventional process has been presented. Plant configurations are developed for the iron/iron oxide looping cycle. The study suggests a higher electric power generation but a lower hydrogen production efficiency comparing with the conventional process. Additionally, it was shown that the price of H{sub 2} obtained from our reactor can be as low as $1.7/kg, which is 22% lower than the current price of the H{sub 2} obtained from reforming plants.

  8. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal (Birmingham, AL); Liu, Guohai (Birmingham, AL); Peng, WanWang (Birmingham, AL)

    2010-08-10

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  9. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Quarterly report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-01-01

    This technical report summarizes the research work performed and progress achieved during the period of October 1, 1995 to December 31, 1995. A series of material wastage tests was carried out on cooled AISI 1018 steel and three thermal-sprayed coating specimens at an elevated environmental temperature (3000{degrees}C) using a nozzle type erosion tester. Test conditions simulated the erosion conditions at the in-bed tubes of fluidized combustors (FBCs). Angular silica quartz particles of average size 742 {micro}m were used for erodent particles for tests at an impact angle of 30{degrees}, at a particle velocity of 2.5 m/s for exposure periods up to 96 hours. The specimens were water-cooled on backside. Material wastage rates were determined from thickness loss measurements of specimens. Test results were compared with material wastage test results from testing isothermal specimens. The morphology of specimens was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It was found that the cooled specimens had greater material wastage than that of the isothermal specimens. The material wastage rate of cooling specimen for AISI 1018 was greater than that for thermal- sprayed coatings. The success in reduction of erosion wastage by cooled-coating specimens was related to the coatings, composition and morphology.

  10. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01

    The objective of this project is to demonstrate that cocombustion of municipal solid waste and oil shale can reduce emissions of gaseous pollutants (SO{sub 2} and HCl) to acceptable levels. Tests in 6- and 15-inch units showed that the oil shale absorbs acid gas pollutants and produces an ash which could be, at the least, disposed of in a normal landfill. Further analysis of the results are underway to estimate scale-up to commercial size. Additional work will be done to evaluate the cementitious properties of oil shale ash.

  11. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

  12. Design and performance requirements for a fluidized bed boiler firing municipal refuse derived fuel in Ravenna, Italy

    SciTech Connect (OSTI)

    Murphy, M.L.

    1999-07-01

    In early 1998, the City of Ravenna, Italy, commissioned a fluid bed boiler/waste-to-energy system to combust approximately 50,000 tonnes per year of processed municipal waste and generate electrical power. Much of the fuel preparation and processing equipment was already in place and the primary focus of this project was to implement an environmentally acceptable energy conversion process compatible with the 6.0 tonnes/hr of fuel being processed. The fluid bed boiler system being provided will incorporate state of the art environmental controls for abatement of all pollutants, including products of incomplete combustion (PICs), NO{sub x}, acid gases, and particulates. The project will deliver an average of 70,000 pounds per hour of steam to generate approximately 7 MW of electricity. The following is a description of the process and equipment being utilized for the energy conversion and boiler island, including the environmental abatement equipment. Design specifications for the plant including fuel and emission limits are presented herein. The facility is scheduled for startup in mid-1999.

  13. Neural network-based monitoring and control of fluidized bed. Quarterly progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Bodruzzaman, M.

    1995-12-31

    This report summarizes work on chaotic behavior control in FBC systems. An update is given to the chaos control method designed to control the chaotic behavior in an FBC system; this method inludes a fully recurrent neural network called the Dynamic System Imitator (DSI). DSI mimics the behavior of a wide variety of dynamic systems in the real world; it was used for modeling linear, nonlinear and chaotic systems, and is also used for iterative prediction of chaotic system behavior. A general methodology for using the DSI to control a nonlinear system is applied to control the chaotic behavior of the Lorenz System. A plan is also outlined for using this method to the FBC system for predicting and controlling its chaotic behavior. Chaotic pressure data from an experimental FBC system was obtained (from METC) on normal and abnormal mixing. Results of chaos analysis applied to these data are presented. These techniques are used to identify the system behavior at different conditions, estimate system order, construct the system attractor, and locate the chaotic behavior in the pressure-drop time series data. Preliminary analysis show that both normal and abnormal conditions of FBC have chaotic characteristics. Objective is to develop a neuro-chaos controller to preserve the normal operational performance of the system.

  14. Free-Piston Diesel Engine Dynamics and Control Tor A. Johansen1, Olav Egeland

    E-Print Network [OSTI]

    Johansen, Tor Arne

    Free-Piston Diesel Engine Dynamics and Control Tor A. Johansen1, Olav Egeland , Erling Aa. Kv rner ASA, Postboks 169, N-1325 Lysaker, Norway. Abstract Free-piston diesel engines. This paper present a dynamic mathematical model of a free-piston diesel engine, a control oriented dynamic

  15. Konkuk University, August 27 2009 Aldo Morselli, INFN Roma Tor Vergata 1 Aldo Morselli

    E-Print Network [OSTI]

    Morselli, Aldo

    the galactic plane loss term: fragmentation loss term: radioactive decaydiffusion coefficient is function of rigidity diffusion coefficient in the impulse space, quasi-linear MHD: primary spectra injection index, August 27 2009 Aldo Morselli, INFN Roma Tor Vergata 16 Comparison between the cosmic rays and the Solar S

  16. Scineghe08 8-11/10/08 Aldo Morselli, INFN Roma Tor Vergata 1 Aldo Morselli

    E-Print Network [OSTI]

    Morselli, Aldo

    Dark Matter from Space #12;Scineghe08 8-11/10/08 Aldo Morselli, INFN Roma Tor Vergata 2 Dark Energy 76% CDM Baryons 4%Cold Dark Matter 20% Dark Matter in the era of precision cosmology CDM ~ 5 b #12: primary spectra injection index implemented in Galprop ( Strong & Moskalenko, available on the Web) #12

  17. Changing of the Guards: A Framework for Understanding and Improving Entry Guard Selection in Tor

    E-Print Network [OSTI]

    Goldberg, Ian

    utilizes special nodes called entry guards as each client's long-term entry point into the anonymityChanging of the Guards: A Framework for Understanding and Improving Entry Guard Selection in Tor network. While the use of entry guards provides clear and well-studied secu- rity benefits, it is unclear

  18. RapTOR: Automated sequencing library preparation and suppression for rapid pathogen characterization ( 7th Annual SFAF Meeting, 2012)

    ScienceCinema (OSTI)

    Lane, Todd [SNL

    2013-02-11

    Todd Lane on "RapTOR: Automated sequencing library preparation and suppression for rapid pathogen characterization" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  19. The Production of High Levels of Renewable Natural Gas from Biomass Using Steam Hydrogasification

    E-Print Network [OSTI]

    Thanmongkhon, Yoothana

    2014-01-01

    96 4.2.2 Bubbling Fluidized Bed4-3 Summary of the bubbling fluidized bed gasifier designC H O N S 4.2.2 Bubbling Fluidized Bed Gasifier A Bubbling

  20. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    surfaces and heat transfer in bubbling fluidized beds- II.of heat transfer in bubbling fluidized beds. Chem. Eng. Sci.coefficient in bubbling fluidized bed with fast response

  1. Aldo Morselli, INFN, Sezione di Roma 2 & Universit di Roma Tor Vergata, aldo.morselli@roma2.infn.it 1 Dark Matter

    E-Print Network [OSTI]

    Morselli, Aldo

    .it 1 Search for Dark Matter with space experiments Aldo Morselli INFN & Università di Roma Tor Vergata 22 - June 2006 International Workshop The Dark Side of the Universe Madrid, June 20-24, 2006 #12;Aldo & Moskalenko, available on the Web) #12;Aldo Morselli, INFN, Sezione di Roma 2 & Università di Roma Tor Vergata

  2. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Liquid fluidized bed heat exchanger flow distribution models Cole L T Allen C A GEOTHERMAL ENERGY FOSSIL FUELED POWER PLANTS FLUIDIZED BED HEAT EXCHANGERS DESIGN FLOW MODELS FLOW...

  3. Renewable Energy RFPs | OpenEI Community

    Open Energy Info (EERE)

    Blog entry Circulating Fluidized Bed Boilers Market Trends Circulating Fluidized Bed (CFB) Boilers Market will grow due to High Demand for CFB Boilers John55364 13 May 2015 -...

  4. Renewable Energy RFPs | OpenEI Community

    Open Energy Info (EERE)

    Blog entry Circulating Fluidized Bed Boilers Market Analysis Circulating Fluidized Bed (CFB) Boilers Market will grow due to High Demand for CFB Boilers John55364 13 May 2015 -...

  5. Aldo Morselli, INFN Roma Tor Vergata Detector Techniques for Cosmology, Astroparticle and General Physics May 29 2015 1 Aldo Morselli

    E-Print Network [OSTI]

    Morselli, Aldo

    and General Physics Poster Review FRONTIER DETECTORS FOR FRONTIER PHYSICS 13th Pisa Meeting on Advanced and General Physics May 29 2015 2 The Tunka Radio Extension (Tunka-Rex) ­ Radio Measurements of Cosmic Rays Techniques for Cosmology, Astroparticle and General Physics : 24 Posters #12;Aldo Morselli, INFN Roma Tor

  6. Tools 10 , University of Southampton, July 1 2010 Aldo Morselli, INFN Roma Tor Vergata 1 Aldo Morselli

    E-Print Network [OSTI]

    Morselli, Aldo

    Tools 10 , University of Southampton, July 1 2010 Aldo Morselli, INFN Roma Tor Vergata 1 Aldo July 1 TOOLS 2010 - Tools for SUSY and the New Physics, Sharpening our Tools 29 June 2010 to 02 July 2010 University of Southampton #12;Tools 10 , University of Southampton, July 1 2010 Aldo Morselli

  7. mTOR phosphorylates IMP2 to promote IGF2 mRNA translation by internal ribosomal entry

    E-Print Network [OSTI]

    Dai, Ning

    Variants in the IMP2 (insulin-like growth factor 2 [IGF2] mRNA-binding protein 2) gene are implicated in susceptibility to type 2 diabetes. We describe the ability of mammalian target of rapamycin (mTOR) to regulate the ...

  8. Appl Phys B (2012) 107:619636 DOI 10.1007/s00340-012-4984-y

    E-Print Network [OSTI]

    Daraio, Chiara

    2012-01-01

    and optimised operation of gas turbine combustion systems, respectively, the development of cost- effective in the development of gas turbines F. Guethe · D. Guyot · G. Singla · N. Noiray · B. Schuermans Received: 10 October Abstract To optimise the operation of gas turbine combus- tors with respect to emission, cycle efficiency

  9. Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings

    E-Print Network [OSTI]

    Ghoniem, Nasr M.

    2002-01-01

    blades and vanes of gas turbine engines, turbine shrouds and combus- tor cans. These coatings increase. Keywords: Plasma spraying; Gas tunnel-type; Thermal barrier-composite coatings; Aluminum oxide; ZirconiumVacuum 65 (2002) 415­425 Plasma spraying of micro-composite thermal barrier coatings S. Sharafata

  10. Development of a concentrating solar power system using fluidized-bed technology for thermal energy conversion and solid particles for thermal energy storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ma, Z.; Mehos, M.; Glatzmaier, G.; Sakadjian, B. B.

    2015-05-01

    Concentrating solar power (CSP) is an effective way to convert solar energy into electricity with an economic energy-storage capability for grid-scale, dispatchable renewable power generation. However, CSP plants need to reduce costs to be competitive with other power generation methods. Two ways to reduce CSP cost are to increase solar-to-electric efficiency by supporting a high-efficiency power conversion system, and to use low-cost materials in the system. The current nitrate-based molten-salt systems have limited potential for cost reduction and improved power-conversion efficiency with high operating temperatures. Even with significant improvements in operating performance, these systems face challenges in satisfying the costmore »and performance targets. This paper introduces a novel CSP system with high-temperature capability that can be integrated into a high-efficiency CSP plant and that meets the low-cost, high-performance CSP targets. Unlike a conventional salt-based CSP plant, this design uses gas/solid, two-phase flow as the heat-transfer fluid (HTF); separated solid particles as storage media; and stable, inexpensive materials for the high-temperature receiver and energy storage containment. We highlight the economic and performance benefits of this innovative CSP system design, which has thermal energy storage capability for base-load power generation.« less

  11. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  12. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the third quarter, April 1, 1989-June 30, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Barbour, F.A.; Turner, T.F.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-07-01

    This research project is for the development of a technical and economical feasible process for drying and stability fine particles of high-moisture subbituminous coal. Research conducted in this quarter focused upon thermogravimetric analysis (TGA) of both feed coals; continuation of the bench-scale IFB drying experiments; and initiation of the characterization of the products from the bench-scale drying experiments to determine their moisture reabsorption, dustiness, and spontaneous ignition properties. Thirty 4-hr and six 12-hr bench-scale IFB drying tests were conducted this quarter making a total of forty-one 4-hr (19 using Eagle Butte feed coal and 22 using Usibelli feed coal) and six 12-hr (3 using each feed coal) tests conducted thus far. IFB reactor slopes of 3, 6, 9, 12, and 15 degrees were investigated for each feed coal. During the tests using Eagle Butte coal, gas-to-solids ratios ranging from approximately 0.7 to 9.7 lb/lb (kg/kg) and average IFB reactor temperatures ranging from approximately 370 to 700/degree/F (188 to 371/degree/C) were tested. 5 refs., 41 figs., 7 tabs.

  13. Engineering test report: paint waste reduction fluidized-bed process demonstration at Letterkenny Army Depot Chambersburg, Pennsylvania. Final report, May 90-Jul 91

    SciTech Connect (OSTI)

    Murphy, J.P.; Parker, D.

    1991-07-01

    Degreasing and removal of paint from metal parts are processes performed at several Army depots across the country as part of vehicle and equipment rebuilding operations. These processes generate many tons of hazardous waste and release some hazardous materials into the workplace because most of them incorporate toxic chlorinated solvents or caustic soda. These substances also produce sludges that are classified as hazardous waste. U.S. Army Depot Support Command (DESCOM), as part of its hazardous waste minimization program, has established as a goal the elimination of hazardous waste generation from paint stripping operations. Through specific research and development projects, the U.S. Army's Toxic and Hazardous Materials Agency (USATHAMA) assists Army Depots in developing and evaluating methods for minimizing the quantities of hazardous wastes that they generate.

  14. The identification of the mTOR-regulated phosphoproteome and a mediator of feedback inhibition to P13K-Akt

    E-Print Network [OSTI]

    Hsu, Peggy Ping

    2011-01-01

    The mTOR protein kinase nucleates two complexes, mTORC1 and mTORC2. Collectively, the two complexes regulate processes important for cell growth and proliferation, including protein synthesis, autophagy, metabolism, and ...

  15. China Energy Primer

    E-Print Network [OSTI]

    Ni, Chun Chun

    2010-01-01

    circulating fluidized bed (CFB) power plants, and launchincluding constructing IGCC CFB pilot projects. Chapter 2

  16. Rapamycin targeting mTOR and hedgehog signaling pathways blocks human rhabdomyosarcoma growth in xenograft murine model

    SciTech Connect (OSTI)

    Kaylani, Samer Z. [Division of Hematology and Oncology, Department of Pediatrics, University of Alabama at Birmingham, 1600 7th Avenue South, ACC 414, Birmingham, AL 35233 (United States)] [Division of Hematology and Oncology, Department of Pediatrics, University of Alabama at Birmingham, 1600 7th Avenue South, ACC 414, Birmingham, AL 35233 (United States); Xu, Jianmin; Srivastava, Ritesh K. [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)] [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States); Kopelovich, Levy [Division of Cancer Prevention, National Cancer Institute, Bethesda (United States)] [Division of Cancer Prevention, National Cancer Institute, Bethesda (United States); Pressey, Joseph G. [Division of Hematology and Oncology, Department of Pediatrics, University of Alabama at Birmingham, 1600 7th Avenue South, ACC 414, Birmingham, AL 35233 (United States)] [Division of Hematology and Oncology, Department of Pediatrics, University of Alabama at Birmingham, 1600 7th Avenue South, ACC 414, Birmingham, AL 35233 (United States); Athar, Mohammad, E-mail: mathar@uab.edu [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)] [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)

    2013-06-14

    Graphical abstract: Intervention of poorly differentiated RMS by rapamycin: In poorly differentiated RMS, rapamycin blocks mTOR and Hh signaling pathways concomitantly. This leads to dampening in cell cycle regulation and induction of apoptosis. This study provides a rationale for the therapeutic intervention of poorly differentiated RMS by treating patients with rapamycin alone or in combination with other chemotherapeutic agents. -- Highlights: •Rapamycin abrogates RMS tumor growth by modulating proliferation and apoptosis. •Co-targeting mTOR/Hh pathways underlie the molecular basis of effectiveness. •Reduction in mTOR/Hh pathways diminish EMT leading to reduced invasiveness. -- Abstract: Rhabdomyosarcomas (RMS) represent the most common childhood soft-tissue sarcoma. Over the past few decades outcomes for low and intermediate risk RMS patients have slowly improved while patients with metastatic or relapsed RMS still face a grim prognosis. New chemotherapeutic agents or combinations of chemotherapies have largely failed to improve the outcome. Based on the identification of novel molecular targets, potential therapeutic approaches in RMS may offer a decreased reliance on conventional chemotherapy. Thus, identification of effective therapeutic agents that specifically target relevant pathways may be particularly beneficial for patients with metastatic and refractory RMS. The PI3K/AKT/mTOR pathway has been found to be a potentially attractive target in RMS therapy. In this study, we provide evidence that rapamycin (sirolimus) abrogates growth of RMS development in a RMS xenograft mouse model. As compared to a vehicle-treated control group, more than 95% inhibition in tumor growth was observed in mice receiving parenteral administration of rapamycin. The residual tumors in rapamycin-treated group showed significant reduction in the expression of biomarkers indicative of proliferation and tumor invasiveness. These tumors also showed enhanced apoptosis. Interestingly, the mechanism by which rapamycin diminished RMS tumor growth involved simultaneous inhibition of mTOR and hedgehog (Hh) pathways. Diminution in these pathways in this model of RMS also inhibited epithelial mesenchymal transition (EMT) which then dampened the invasiveness of these tumors. Our data provide bases for using rapamycin either alone or in combination with traditional chemotherapeutic drugs to block the pathogenesis of high risk RMS.

  17. The Cleveland MuseuM of naTural hisTorY nuMber 56 GEOLOGY AND PALEONTOLOGY OF LEMUDONG'O, KENYA

    E-Print Network [OSTI]

    Hlusko, Leslea J.

    The Cleveland MuseuM of naTural hisTorY nuMber 56 GEOLOGY AND PALEONTOLOGY OF LEMUDONG'O, KENYA J. Hlusko GEOLOGY, GEOCHEMISTRY, AND STRATIGRAPHY OF THE LEMUDONG'O FORMATION, KENYA RIFT VALLEY 53: Cultural and Physical Anthropology; Archaeology; Botany; Geology; Paleobotany; Invertebrate and Vertebrate

  18. Integrated Dynamic Analysis of Floating Offshore Wind Turbines Bjrn Skaare*, Tor David Hanson*, Finn Gunnar Nielsen*, Rune Yttervik*, Anders Melchior Hansen**,

    E-Print Network [OSTI]

    Integrated Dynamic Analysis of Floating Offshore Wind Turbines Bjørn Skaare*, Tor David Hanson of floating wind turbines exposed to forces from wind, waves and current has been developed for Hydro Oil & Energy's floating wind turbine concept, HYWIND. Two existing, independent, computer program systems

  19. Aldo Morselli, INFN & Universit di Roma Tor Vergata, aldo.morselli@roma2.infn.it 1 Dark Matter Indirect Search

    E-Print Network [OSTI]

    Morselli, Aldo

    Aldo Morselli, INFN & Università di Roma Tor Vergata, aldo.morselli@roma2.infn.it 1 Dark Matter Indirect Search : News from the sky Prospects for the detection of Dark Matter CIECEM Matalacañs, Spain & Moskalenko, available on the Web) semi-analitical solution: Maurin et al, astro-ph/0101231 #12;Aldo Morselli

  20. MicroRNA-101 mediates the suppressive effect of laminar shear stress on mTOR expression in vascular endothelial cells

    SciTech Connect (OSTI)

    Chen, Kui; Fan, Wendong; Wang, Xing; Ke, Xiao [Division of Cardiology, First Affiliated Hospital of Sun Yat-sen University, Guangzhou 510080 (China)] [Division of Cardiology, First Affiliated Hospital of Sun Yat-sen University, Guangzhou 510080 (China); Wu, Guifu, E-mail: eecpchina@yahoo.com.cn [Key Laboratory on Assisted Circulation, Ministry of Health, Guangzhou 510080 (China)] [Key Laboratory on Assisted Circulation, Ministry of Health, Guangzhou 510080 (China); Hu, Chengheng, E-mail: huchenghengpci@yahoo.com.cn [Division of Cardiology, First Affiliated Hospital of Sun Yat-sen University, Guangzhou 510080 (China)] [Division of Cardiology, First Affiliated Hospital of Sun Yat-sen University, Guangzhou 510080 (China)

    2012-10-12

    Highlights: Black-Right-Pointing-Pointer Laminar shear stress upregulates miR-101 expression in vascular endothelial cells. Black-Right-Pointing-Pointer miR-101 represses mTOR expression through a specific 3 Prime UTR binding site. Black-Right-Pointing-Pointer Overexpression of miR-101 inhibits G1/S transition and endothelial cell proliferation. Black-Right-Pointing-Pointer Blockade of miR-101 attenuates the suppressive effect of laminar flow on mTOR expression. -- Abstract: Shear stress associated with blood flow plays an important role in regulating gene expression and cell function in endothelial cells (ECs). MicroRNAs (miRNAs) are highly conserved, small non-coding RNAs that negatively regulate the expression of target genes by binding to the mRNA 3 Prime -untranslated region (3 Prime UTR) at the posttranscriptional level involved in diverse cellular processes. This study demonstrates that microRNA-101 in response to laminar shear stress (LSS) is involved in the flow regulation of gene expression in ECs. qRT-PCR analysis showed that miR-101 expression was significantly upregulated in human umbilical vein endothelial cells (HUVECs) exposed to 12 dyn/cm{sup 2} laminar shear stress for 12 h. We found that transfection of miR-101 significantly decreased the luciferase activity of plasmid reporter containing the 3 Prime UTR of mammalian target of rapamycin (mTOR) gene. Western analysis revealed that the protein level of mTOR was significantly reduced in ECs transfected with miR-101. Furthermore, miR-101 overexpression induced cell cycle arrest at the G1/S transition and suppressed endothelial cell proliferation. Finally, transfection of miR-101 inhibitors attenuated the suppressive effects of LSS on mTOR expression, which identified the efficacy of loss-of-function of miR-101 in laminar flow-treated ECs. In conclusion, we have demonstrated that upregulation of miR-101 in response to LSS contributes to the suppressive effects of LSS on mTOR expression and EC proliferation. These studies advance our understanding of the posttranscriptional mechanisms by which shear stress modulates endothelial homeostasis.

  1. Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    Liquid-fluidized-bed heat exchanger flow distribution models Cole, L.T.; Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS; FLUIDIZED BED HEAT EXCHANGERS; DESIGN;...

  2. Renewable Energy RFPs | OpenEI Community

    Open Energy Info (EERE)

    sort icon Blog entry Circulating Fluidized Bed Boilers Market Circulating Fluidized Bed (CFB) Boilers Market will grow due to High Demand for CFB Boilers John55364 13 May 2015 -...

  3. Renewable Energy RFPs | OpenEI Community

    Open Energy Info (EERE)

    icon Blog entry Circulating Fluidized Bed Boilers Market Size Circulating Fluidized Bed (CFB) Boilers Market will grow due to High Demand for CFB Boilers John55364 13 May 2015 -...

  4. Published: November 17, 2011 r 2011 American Chemical Society 425 dx.doi.org/10.1021/ie2014058 |Ind. Eng. Chem. Res. 2012, 51, 425433

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of reactors:2 fixed bed, slurry bubble column (SBCR), fluidized bed, and circulating fluidized bed reactor fixed bed reactor for the FT synthesis. The Pearl GTL plant has 24 parallel fixed bed reactors each

  5. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    IMPACTORS; PERFORMANCE TESTING; FLUE GAS; PARTICLE SIZE; FLUIDIZED-BED COMBUSTION; AIR FILTERS; DISTRIBUTION; MEASURING INSTRUMENTS; SORTING; CHEMICAL REACTIONS; COMBUSTION;...

  6. CT Scan Not Only a Medical Technique NETL Wins Two 2008

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Materials for CO 2 Capture and Conversions 5 Coal Seam Carbon Sequestration Simulation 6 Fluidized-Bed Combustion Testing...

  7. Separation of Fischer-Tropsch Wax from Catalyst Using Near-Critical Fluid Extraction: Analysis of Process

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    fixed-bed, fluidized-bed, and circulating-fluid- ized-bed reactors.3 However, slurry bubble column (SBC

  8. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    MISCELLANEOUSMATHEMATICS, COMPUTING, AND INFORMATION SCIENCE; FLUIDIZED BEDS; FLUID MECHANICS; CHARS; CIRCULATING SYSTEMS; KINETICS; MATHEMATICAL MODELS; MULTIPHASE FLOW;...

  9. Submitted to KONA: Powder and Particle 1997-06-01. Revised 1997-08-15. Measuring Slugging Bed Dynamics with Acoustic Sensors

    E-Print Network [OSTI]

    Tennessee, University of

    with rising bubbles seem to be a characteristic feature of many fluidized beds. Acoustic measurements are also of fluidized beds, dynamic pressure measurements are routinely employed to assess the quality and/or regime taps is constrained by severe process conditions or cost (e.g., pressurized fluidized-bed combustion

  10. Copyright by SIAM. Unauthorized reproduction of this article is prohibited. SIAM J. APPL. MATH. c 2011 Society for Industrial and Applied Mathematics

    E-Print Network [OSTI]

    Hinch, John

    of understanding the formation of bubbles in fluidized beds, we investigate the stability of stratified particulate concentration of particles. This mechanism might be related to the formation of bubbles in fluidized beds. Key words. gravitational overturning, fluidized beds, bubble formation, secondary instability, concentration

  11. Sei Vojany Station repowering reconstruction assessment feasibility study. Volume 2. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    Six technologies are considered for application to the proposed Vojany Power Station EVO III. These technologies are: Conventional pulverized coal (PC) with SOx and NOx control; Atmospheric circulating fluidized bed (CFB); Atmospheric bubbling fluidized bed (BFB); Pressurized fluidized bed combustion combined cycle (PFBC-CC); Integrated coal gasification combined cycle (IGCC); and Gas fired combustion turbine combined cycle (CTCC).

  12. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  13. Please cite this article in press as: K.J. Boehm, et al., Modeling results for mass production layering in a fluidized bed, Fusion Eng. Des. (2011), doi:10.1016/j.fusengdes.2010.08.004

    E-Print Network [OSTI]

    Raffray, A. René

    2011-01-01

    production layering device for inertial fusion energy (IFE) fuel pellets are presented. In an IFE power plant GModel FUSION-5362; No.of Pages11 Fusion Engineering and Design xxx (2011) xxx­xxx Contents lists.B. Alexanderb , D.T. Goodinb a Center for Energy Research, M/C 0438 460D EBU II, University of California, San

  14. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  15. Engineer, design, construct, test, and evaluate a pressurized fluidized-bed pilot plant using high-sulfur coal for production of electric power. Phase III: pilot-plant construction. Quarterly report, June 1-August 31, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Technical progress during the period June 1 through August 31, 1980 included the following activities: The PSD permit approval was obtained from the US Environmental Protection Agency. The building permit was obtained from the Borough of Wood-Ridge. Installation designs incorporating modifications to the Total Energy System, Gas Turbine, Free Power Turbine and Waste Heat Boiler are in an advanced stage. Procurement has been initiated on all long lead material. The upper and lower PFB Vessel fabrication was started. Quotations for the Substructure Construction (Bid Package No. 1) are under review in preparation for issuing a purchase order in October 1980. Request for quotation on Structural Steelwork have been issued to potential bidders. Groundbreaking ceremonies took place on June 30, 1980 with the Assistant Secretary of the Department of Energy presiding and the Governor of New Jersey, a Congressional delegation and State Commissioner of Energy and Environment, Borough Officials among other dignitaries in attendance.

  16. VOLUME 75, NUMBER 12 P H Y S I C A L R E V I E W L E T T E R S 18 SEPTEMBER 1995 Self-Organization and Chaos in a Fluidized Bed

    E-Print Network [OSTI]

    Tennessee, University of

    flow tested, the behavior becomes extremely complex ("turbulent"). PACS numbers: 05.45.+b, 47.52.+j "fluidized"). This turbulence promotes heat and mass transfer as well as chemical reac- tions between. A schematic illustration of our experimental apparatus is shown in Fig. 1. The cylindrical vessel is 10.2 cm

  17. Vorinostat, an HDAC inhibitor attenuates epidermoid squamous cell carcinoma growth by dampening mTOR signaling pathway in a human xenograft murine model

    SciTech Connect (OSTI)

    Kurundkar, Deepali; Srivastava, Ritesh K.; Chaudhary, Sandeep C. [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)] [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States); Ballestas, Mary E. [Department of Pediatrics Infectious Disease, Children's of Alabama, School of Medicine, University of Alabama at Birmingham, AL (United States)] [Department of Pediatrics Infectious Disease, Children's of Alabama, School of Medicine, University of Alabama at Birmingham, AL (United States); Kopelovich, Levy [Division of Cancer Prevention, National Cancer Institute, 6130 Executive Blvd., Suite 2114, Bethesda, MD 20892 (United States)] [Division of Cancer Prevention, National Cancer Institute, 6130 Executive Blvd., Suite 2114, Bethesda, MD 20892 (United States); Elmets, Craig A. [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)] [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States); Athar, Mohammad, E-mail: mathar@uab.edu [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)] [Department of Dermatology and Skin Diseases Research Center, University of Alabama at Birmingham, 1530 3rd Avenue South, VH 509, Birmingham, AL 35294-0019 (United States)

    2013-01-15

    Histone deacetylase (HDAC) inhibitors are potent anticancer agents and show efficacy against various human neoplasms. Vorinostat is a potent HDAC inhibitor and has shown potential to inhibit growth of human xenograft tumors. However, its effect on the growth of skin neoplasm remains undefined. In this study, we show that vorinostat (2 ?M) reduced expression of HDAC1, 2, 3, and 7 in epidermoid carcinoma A431 cells. Consistently, it increased acetylation of histone H3 and p53. Vorinostat (100 mg/kg body weight, IP) treatment reduced human xenograft tumor growth in highly immunosuppressed nu/nu mice. Histologically, the vorinostat-treated tumor showed features of well-differentiation with large necrotic areas. Based on proliferating cell nuclear antigen (PCNA) staining and expression of cyclins D1, D2, E, and A, vorinostat seems to impair proliferation by down-regulating the expression of these proteins. However, it also induced apoptosis. The mechanism by which vorinostat blocks proliferation and makes tumor cells prone to apoptosis, involved inhibition of mTOR signaling which was accompanied by reduction in cell survival AKT and extracellular-signal regulated kinase (ERK) signaling pathways. Our data provide a novel mechanism-based therapeutic intervention for cutaneous squamous cell carcinoma (SCC). Vorinostat may be utilized to cure skin neoplasms in organ transplant recipient (OTR). These patients have high morbidity and surgical removal of these lesions which frequently develop in these patients, is difficult. -- Highlights: ? Vorinostat reduces SCC growth in a xenograft murine model. ? Vorinostat dampens proliferation and induces apoptosis in tumor cells. ? Diminution in mTOR, Akt and ERK signaling underlies inhibition in proliferation. ? Vorinostat by inhibiting HDACs inhibits epithelial–mesenchymal transition.

  18. Ascofuranone suppresses EGF-induced HIF-1? protein synthesis by inhibition of the Akt/mTOR/p70S6K pathway in MDA-MB-231 breast cancer cells

    SciTech Connect (OSTI)

    Jeong, Yun-Jeong; Cho, Hyun-Ji [Research Institute of Biomedical Engineering and Department of Medicine, Catholic University of Daegu School of Medicine, Daegu 705-718 (Korea, Republic of); Magae, Junji [Magae Bioscience Institute, 49-4 Fujimidai, Tsukuba 300-1263 (Japan); Lee, In-Kyu [Department of Internal Medicine, Kyungpook National University School of Medicine, Daegu 700-721 (Korea, Republic of); Park, Keun-Gyu, E-mail: kpark@knu.ac.kr [Department of Internal Medicine, Kyungpook National University School of Medicine, Daegu 700-721 (Korea, Republic of); Chang, Young-Chae, E-mail: ycchang@cu.ac.kr [Research Institute of Biomedical Engineering and Department of Medicine, Catholic University of Daegu School of Medicine, Daegu 705-718 (Korea, Republic of)

    2013-12-15

    Hypoxia-inducible factor (HIF)-1 plays an important role in tumor progression, angiogenesis and metastasis. In this study, we investigated the potential molecular mechanisms underlying the anti-angiogenic effect of ascofuranone, an isoprenoid antibiotic from Ascochyta viciae, in epidermal growth factor (EGF)-1 responsive human breast cancer cells. Ascofuranone significantly and selectively suppressed EGF-induced HIF-1? protein accumulation, whereas it did not affect the expression of HIF-1?. Furthermore, ascofuranone inhibited the transcriptional activation of vascular endothelial growth factor (VEGF) by reducing protein HIF-1?. Mechanistically, we found that the inhibitory effects of ascofuranone on HIF-1? protein expression are associated with the inhibition of synthesis HIF-1? through an EGF-dependent mechanism. In addition, ascofuranone suppressed EGF-induced phosphorylation of Akt/mTOR/p70S6 kinase, but the phosphorylation of ERK/JNK/p38 kinase was not affected by ascofuranone. These results suggest that ascofuranone suppresses EGF-induced HIF-1? protein translation through the inhibition of Akt/mTOR/p70S6 kinase signaling pathways and plays a novel role in the anti-angiogenic action. - Highlights: • Inhibitory effect of ascofuranone on HIF-1? expression is EGF-specific regulation. • Ascofuranone decreases HIF-1? protein synthesis through Akt/mTOR pathways. • Ascofuranone suppresses EGF-induced VEGF production and tumor angiogenesis.

  19. Ind. Eng. Chem.Res. 1990, 29, 2339-2346 2339 Lewis, W. K.; Gilliland, E. R. Glass Werner, Solid-catalyzedreaction

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , R.; Kojima, H.; Nagai, Y.; Nakagawa, K.; Yu, S. Behavior of bubbles in the gas-solid fluidized bed-catalyzedreaction in a fluidized bed. AIChE J. 1959,5(4), 419. McFatter, W. E.; Resen, F. L. Technical data of cat cracker Model 11 Cracker. Pet. Refin. 1956,35(4), 201. May, W. G. Fluidized-bed reactor studies. Chem.Eng. Prog. 1959, 55

  20. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    of circulating fluidized beds Kinetic theory approach Gidaspow D Bezburuah R Ding J COAL LIGNITE AND PEAT ENGINEERING GENERAL AND MISCELLANEOUS MATHEMATICS COMPUTING AND...

  1. Gidaspow, D.; Bezburuah, R.; Ding, J. 01 COAL, LIGNITE, AND PEAT...

    Office of Scientific and Technical Information (OSTI)

    fluidized beds: Kinetic theory approach Gidaspow, D.; Bezburuah, R.; Ding, J. 01 COAL, LIGNITE, AND PEAT; 42 ENGINEERING; 99 GENERAL AND MISCELLANEOUSMATHEMATICS,...

  2. Evaluation of wall boundary condition parameters for gas-solids...

    Office of Scientific and Technical Information (OSTI)

    predictions of various gas-solids fluidized beds. Several models for the granular flow wall boundary condition are available in the open literature for numerical modeling of...

  3. Industry

    E-Print Network [OSTI]

    Bernstein, Lenny

    2008-01-01

    A.T, 2001: Prospects for biogas harvesting at Sungunn WongseRenewables Biomass, Biogas, PV, Wind turbines, Hydropowermill, fluidized bed kiln Biogas, Biomass Cullet preheating

  4. Studies of the regeneration of activated bauxite used as granular...

    Office of Scientific and Technical Information (OSTI)

    GRANULAR BED FILTERS; HOT GAS CLEANUP; POTASSIUM CHLORIDES; SORPTION; SODIUM CHLORIDES; AIR POLLUTION CONTROL; COAL; FLUIDIZED-BED COMBUSTORS; ALKALI METAL COMPOUNDS; ALUMINIUM...

  5. Reducing the environmental impact on solid wastes from a fluidized...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; COAL; FLUIDIZED-BED COMBUSTION; WASTE MANAGEMENT; AIR POLLUTION ABATEMENT; ALUMINIUM OXIDES; CALCIUM OXIDES; CHEMICAL ACTIVATION;...

  6. The Production of High Levels of Renewable Natural Gas from Biomass Using Steam Hydrogasification

    E-Print Network [OSTI]

    Thanmongkhon, Yoothana

    2014-01-01

    A Bubbling Fluidized Bed (BFB) Gasifier sponsored by thehydrogasification using BFB gasifier achieved approximatelyimplement with the bench scale BFB gasifier to demonstrate

  7. Method for producing and regenerating a synthetic CO[sub 2] acceptor

    DOE Patents [OSTI]

    Lancet, M. S.; Curran, G. P.; Gorin, E.

    1982-05-18

    A method is described for producing a synthetic CO[sub 2] acceptor by feeding a mixture of finely divided silica and at least one finely divided calcium compound selected from the group consisting of calcium oxide and calcium carbonate to a fluidized bed; operating the fluidized bed at suitable conditions to produce pellets of synthetic CO[sub 2] acceptor and recovering the pellets of synthetic CO[sub 2] acceptor from the fluidized bed. Optionally, spent synthetic CO[sub 2] acceptor can be charged to the fluidized bed to produce regenerated pellets of synthetic CO[sub 2] acceptor. 1 fig.

  8. The Micromechanics of Colloidal Dispersions

    E-Print Network [OSTI]

    Maryland at College Park, University of

    ) Shinbrot & Muzzio (2000) Zoueshtiagh & Thomas (2000) Pattern Formation Fluidized bed (Jackson 2000) #12 Granular Dynamics (St >>1) Bubble Dynamics ( u = 0) Stokesian Dynamics (Re

  9. Method for producing and regenerating a synthetic CO.sub.2 acceptor

    DOE Patents [OSTI]

    Lancet, Michael S. (Pittsburgh, PA); Curran, George P. (Pittsburgh, PA); Gorin, Everett (San Rafael, CA)

    1982-01-01

    A method for producing a synthetic CO.sub.2 acceptor by feeding a mixture of finely divided silica and at least one finely divided calcium compound selected from the group consisting of calcium oxide and calcium carbonate to a fluidized bed; operating the fluidized bed at suitable conditions to produce pellets of synthetic CO.sub.2 acceptor and recovering the pellets of synthetic CO.sub.2 acceptor from the fluidized bed. Optionally, spent synthetic CO.sub.2 acceptor can be charged to the fluidized bed to produce regenerated pellets of synthetic CO.sub.2 acceptor.

  10. Soil separator and sampler and method of sampling

    DOE Patents [OSTI]

    O'Brien, Barry H. (Idaho Falls, ID) [Idaho Falls, ID; Ritter, Paul D. (Idaho Falls, ID) [Idaho Falls, ID

    2010-02-16

    A soil sampler includes a fluidized bed for receiving a soil sample. The fluidized bed may be in communication with a vacuum for drawing air through the fluidized bed and suspending particulate matter of the soil sample in the air. In a method of sampling, the air may be drawn across a filter, separating the particulate matter. Optionally, a baffle or a cyclone may be included within the fluidized bed for disentrainment, or dedusting, so only the finest particulate matter, including asbestos, will be trapped on the filter. The filter may be removable, and may be tested to determine the content of asbestos and other hazardous particulate matter in the soil sample.

  11. Coated Particle Fuel Development Lab (CPFDL) | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRISO Coating 50 mm Fluidized Bed Chemical Vapor Deposition System Computer control of coating temperature and gas composition Particle Classification Tabler, roller micrometer,...

  12. baepgfb-mac4a | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Progam: Pressurized Circulating Fluidized Bed Demonstration Project (June...

  13. Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass

    E-Print Network [OSTI]

    FAN, XIN

    2012-01-01

    fluidised bed biomass gasifier, Fuel, 2007, 86, 1417-1429.utilizing a down draft gasifier, Biomass and Bioenergy,fixed bed and fluidized bed gasifier, Biomass and Bioenergy,

  14. Alternative Energy Development and China's Energy Future

    E-Print Network [OSTI]

    Zheng, Nina

    2012-01-01

    systems known as fixed bed gasifier are used for generatingpower. These fixed bed gasifiers are very small in scaleknown as fluidized bed gasifier with generation capacity of

  15. EIS-0361: Notice of Intent to Prepare an Environmental Impact...

    Broader source: Energy.gov (indexed) [DOE]

    that would use an innovative atmosphericpressure circulating fluidized-bed (ACFB) boiler as the source of heat for the co-production of electricity, steam and structural...

  16. Utilization of Process Off-Gas as a Fuel for Improved Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with waste heat utilization. The calcining process is composed of the petroleum coke charger (black), fluidized bed calciner with electrodes and nitrogen supply (red), and gas...

  17. Sound speed and attenuation in water-saturated glass beads as a function of frequency and porosity

    E-Print Network [OSTI]

    the frequency and porosity dependency. To begin to address this deficiency, a fluidized bed technique was used meaningful comparisons to various models of sound propagation. Towards this end, a fluidized bed apparatus and then al- lowed to rest overnight to dissolve trapped gas bubbles. Sediment porosity was controlled

  18. Appl. Magn. Reson. (2007) 32, 93112 DOI 10.1007/s00723-007-0002-7

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    2007-01-01

    Applied Magnetic Resonance Noninvasive Measurements of Gas Exchange in a Three- Dimensional Fluidized Bed agreement with previously unverified predictions from well-known models of fluidized bed be- havior of the bed and expand while rising [2, 3]. Bubbles agitate the bed but also provide a route for gas to escape

  19. Powder Technology, 64 (1991) 3-41 Fundamental and practical developments

    E-Print Network [OSTI]

    Liu, Y. A.

    1991-01-01

    eliminates gas bubbling from (i.e., magnetically `stabilizes') a fluidized bed of magnetizable particles not be spatially uniform and the bed may not be stabilized (i.e., bubbling). Following a discussion, including the fluidized-bed high-gradient magnetic separation (FBHGMS), the magnetic valve for solids (MVS

  20. Results obtained by both techniques show a good correlation (three maxima are observed) and thus provide a study of cement microstructure

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    , a parameter crucial in many models of bubble behavior in fluidized beds [1,2]. More chaotic and random motion.01.071 NMR measurement of gas-phase dynamics in a gas-fluidized particle bed using laser-polarized xenon NMR in a fluidized bed. Previous NMR measurements studied the solid particles, which give strong conventional NMR

  1. Practical Aspects of the Implementation of Reduced-Order Models Based on Proper Orthogonal Decomposition 

    E-Print Network [OSTI]

    Brenner, Thomas Andrew

    2012-07-16

    . . . . . . . . . . . . . . . . . . . . . . . . 40 IV Number of modes used in the three-dimensional case. . . . . . . . . . 41 V Parameters of a bubbling fluidized bed. . . . . . . . . . . . . . . . . . 44 VI Parameters of a channel with a bump. . . . . . . . . . . . . . . . . . 94 VII Summary... LIST OF TABLES TABLE Page I Parameters of a non-isothermal fluidized bed. . . . . . . . . . . . . . 28 II Number of modes used in the non-isothermal case. . . . . . . . . . . 29 III Isothermal case parameters...

  2. PREPRINT. Paper has been published in Chemical Engineering Journal 64:1 (1996) 191-197.

    E-Print Network [OSTI]

    Tennessee, University of

    1996-01-01

    trains in gas-fluidized beds predicts chaotic behavior [5]. Previous investigators have shown that liquid in fluidized beds. 2. Experimental apparatus and procedure Our experimental apparatus consists of a plexiglass-temporal dynamics in a train of rising bubbles K. Nguyena , C.S. Dawb , P. Chakkaa , M. Chenga , D.D. Brunsa , C

  3. 4/3 law of Granular Particles Flowing through a Vertical Pipe

    E-Print Network [OSTI]

    Hayakawa, Hisao

    excitations under vertical vibration [5,6] and a fluidized bed due to air injected inside a box containing dimensional realiza­ tion of a fluidized bed is also a typical example of unusual features of granular motion behaviors [1], such as convection [2], size segregation [3], bubbling [4], standing waves and localized

  4. International Conference on Multiphase Flow, ICMF 2010, Tampa, FL, May 30 June 4, 2010

    E-Print Network [OSTI]

    Apte, Sourabh V.

    disciplines with applications to cavitation, sprays and spray combustion, coal combustion and fluidized beds) dis- cusses present modeling strategies used for numerical simulation of gas/solid fluidized beds Simulation of Bubble and Particle Interactions with Vortical Flows Using a Discrete Element Model Justin Finn

  5. technology offer SandTES -High Temperature Sand Thermal Energy Storage

    E-Print Network [OSTI]

    Szmolyan, Peter

    technology offer SandTES - High Temperature Sand Thermal Energy Storage key words: High Temperature Energy Storage | Fluidized Bed | Sand | The invention consists of a fluidized bed with internal heat together with Dr. Eisl of ENRAG GmbH. Background Thermal energy storage (TES) systems are essential

  6. technology offer Vienna University of Technology | Research and Transfer Support | Claudia Doubek

    E-Print Network [OSTI]

    Arnold, Anton

    for the fluidized bed is minimized. An appropriate fluidization air heat recovery concept minimizes exergy losses) Industrial Heat recovery ("Ash Cooler" after a fluidized bed combustion chamber) Development Status A cold exchange per volume unit of the heat exchanger unit Optimization of heat recovery Testing of material

  7. Process for converting cellulosic materials into fuels and chemicals

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Faison, Brendlyn D. (Knoxville, TN); Davison, Brian H. (Knoxville, TN); Woodward, Jonathan (Oak Ridge, TN)

    1994-01-01

    A process for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attritor and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system.

  8. Sampling and analysis of hydrocarbons in combustion gases. Annual report, October 1979-September 1980

    SciTech Connect (OSTI)

    Johnson, I.; Myles, K.M.; Siczek, A.A.

    1981-04-01

    The purpose of these studies is to develop a method for the chemical analysis of ultratrace levels of polycyclic organic compounds in the flue gases from fluidized-bed combustors. Methods which have the potential for real time analysis have been studied. Two methods, double mass spectrometry and laser ionization mass spectrometry, appear to be promising. A brief review of current analytical methods has been made. A brief examination of fly ash from fluidized-bed combustion revealed no carcinogenic species although samples collected during fluidized-bed combustor startup were found to be mutagenic.

  9. Production of low BTU gas from biomass 

    E-Print Network [OSTI]

    Lee, Yung N.

    1981-01-01

    and transported with little difficulty. It was decided to use a fluidized bed reactor for the gasification. Fluidized bed reactors offer many advantages when utilized as a medium for gasifi- cation of solid fuels. Some of them are excellent mixing...6 (g) n m +CH8 (g) + Reactions (1) and (2) were reported to be rapid and proceed to completion. Jensen (1975) studied the gasifi- cation of coal with steam. A batch fluidized bed re- actor was used to alleviate the fusion problem usually...

  10. Targeting mTOR in Pancreatic Cancer

    E-Print Network [OSTI]

    Soares, Heloisa Prado

    2015-01-01

    Parsons J, Kern SE. Progression model for pancreatic cancer.Clinical Cancer Research. 2000;6(N8):2969-72.Martinelli P. Pancreatic Cancer Development and Progression:

  11. ENERGY ANALYSIS PROGRAM FY-1979.

    E-Print Network [OSTI]

    Authors, Various

    2013-01-01

    for Combus- tion Turbine-Steam Turbine Combined Cycle Powercycle system and a steam turbine design, respectively. The

  12. Characterization of Biofilm in 200W

    E-Print Network [OSTI]

    PNNL-23679 Characterization of Biofilm in 200W Fluidized Bed Reactors September 2014 MH Lee E ER Eisenhauer SD Saurey EA Cordova BD Lee EC Golovich KE Parker #12;#12;PNNL-23679 Characterization of Biofilm

  13. Thermal and chemical remediation of mixed waste

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Swift, William M. (Downers Grove, IL)

    1994-01-01

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500.degree. C. by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO.sub.3. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed.

  14. Thermal and chemical remediation of mixed waste

    DOE Patents [OSTI]

    Nelson, P.A.; Swift, W.M.

    1994-08-09

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500 C by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO[sub 3]. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed. 3 figs.

  15. technology offer Research and Transfer Support | Tanja Sovic

    E-Print Network [OSTI]

    Szmolyan, Peter

    Technology Purpose of solids Importance of gas-solid contact (biomass) gasification heat transport, catalyst circulating fluidized bed reactors in a novel way to improve scale-up potential of gasification and CO2

  16. DECOMPOSITION OF CALCIUM SULFATE: A REVIEW OF THE LITERATURE

    Office of Scientific and Technical Information (OSTI)

    R. Ederer, J. W; Bishop, and A. K. Scott, "Study of the Characterization and Control of Air Pollutants from a Fluidized-Bed Boiler - The SO2 Acceptor Process," U.S. Environ-:...

  17. Rotary bed reactor for chemical-looping combustion with carbon capture

    E-Print Network [OSTI]

    Zhao, Zhenlong

    2012-01-01

    Chemical-looping combustion (CLC) is a novel and promising technology for power generation with inherent CO2 capture. Currently almost all the research has been focused on developing CLC based inter-connected fluidized bed ...

  18. CFD-DEM modelling of two-phase pneumatic conveying with experimental validation. 

    E-Print Network [OSTI]

    Ebrahimi, Mohammadreza

    2014-11-27

    A wide range of industrial processes involve multiphase granular flows. These include catalytic reactions in fluidized beds, the pneumatic conveying of raw materials and gas-particle separators. Due to the complex nature ...

  19. PHYSICS OF FLUIDS 26, 093302 (2014) The motion of solid spherical particles falling in a cellular

    E-Print Network [OSTI]

    Bergougnoux, Laurence

    2014-01-01

    in a fundamental way. Examples include fluidized-bed reactors, the treatment of waste materials in clarifiers) the surrounding fluid (R = 0) and on light gas bubbles (R = 2). A linear stability analysis of the equilibrium

  20. CX-012043: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Oxy-Fired Pressurized Fluidized Bed Combustion - Phase II CX(s) Applied: B3.6 Date: 04/04/2014 Location(s): California Offices(s): National Energy Technology Laboratory