Sample records for fluidized solids technique

  1. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01T23:59:59.000Z

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  2. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17T23:59:59.000Z

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  3. Solids feed nozzle for fluidized bed

    DOE Patents [OSTI]

    Zielinski, Edward A. (Harwinton, CT)

    1982-01-01T23:59:59.000Z

    The vertical fuel pipe of a fluidized bed extends up through the perforated support structure of the bed to discharge granulated solid fuel into the expanded bed. A cap, as a deflecting structure, is supported above the discharge of the fuel pipe and is shaped and arranged to divert the carrier fluid and granulated fuel into the combusting bed. The diverter structure is spaced above the end of the fuel pipe and provided with a configuration on its underside to form a venturi section which generates a low pressure in the stream into which the granules of solid fuel are drawn to lengthen their residence time in the combustion zone of the bed adjacent the fuel pipe.

  4. Characteristics of mixing of solid particles in a fluidized bed

    SciTech Connect (OSTI)

    Berg, B.V.; Rudenko, S.S.; Stepanov, L.V.

    1984-01-01T23:59:59.000Z

    Results of experimental investigations of the horizontal mixing of solid particles in a fluidized bed of fine-grain material fluidized by air are considered. It is found that the intensity of horizontal transport is substantially nonuniform over the height of the bed.

  5. MODELING AND SIMULATION OF SOLID FLUIDIZATION IN A RESIN COLUMN

    SciTech Connect (OSTI)

    Lee, S.

    2014-06-24T23:59:59.000Z

    The objective of the present work is to model the resin particles within the column during fluidization and sedimentation processes using computation fluid dynamics (CFD) approach. The calculated results will help interpret experimental results, and they will assist in providing guidance on specific details of testing design and establishing a basic understanding of particle’s hydraulic characteristics within the column. The model is benchmarked against the literature data and the test data (2003) conducted at Savannah River Site (SRS). The paper presents the benchmarking results and the modeling predictions of the SRS resin column using the improved literature correlations applicable for liquid-solid granular flow.

  6. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-06-30T23:59:59.000Z

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

  7. Solid fuel feed system for a fluidized bed

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01T23:59:59.000Z

    A fluidized bed for the combustion of coal, with limestone, is replenished with crushed coal from a system discharging the coal laterally from a station below the surface level of the bed. A compartment, or feed box, is mounted at one side of the bed and its interior separated from the bed by a weir plate beneath which the coal flows laterally into the bed while bed material is received into the compartment above the plate to maintain a predetermined minimum level of material in the compartment.

  8. Grid-region heat transfer in a gas solid fluidized bed

    SciTech Connect (OSTI)

    Wang, R.C.

    1986-01-01T23:59:59.000Z

    The grid region heat transfer to a horizontal tube in a gas-solid fluidized bed was studied experimentally and theoretically. A preliminary experimental study was first conducted to investigate semi-quantitatively the heat transfer characteristics in the grid region as well as in the bubbling region of the gas-solid fluidized bed using a simple hot water circulation system. Experimental parameters included particle size, static bed height, superficial gas velocity, distributor open area, distributor hole sizes, distributor hole numbers, and vertical locations of the heating tube. An additional experimental study was then carried out to study quantitatively the heat transfer coefficient in each grid region phase, i.e., jet phase, emulsion phase and dead phase using an artificial jet and an electrically heated tube. The observed heat transfer coefficients for each phase were correlated as a function of experimental parameters. The observed results are also compared with results estimated from a heat transfer model, which is based on plausible heat transfer mechanisms in the grid region of a gas-solid fluidized bed.

  9. Atmospheric fluidized bed combustion of municipal solid waste: test program results

    SciTech Connect (OSTI)

    Preuit, L C; Wilson, K B

    1980-05-01T23:59:59.000Z

    Air classified municipal solid waste (MSW) was fired in an atmospheric fluidized bed combustor at low excess air to simulate boiler conditions. The 7 ft/sup 2/ combustor at Combustion Power Company's energy laboratory in Menlo Park, CA, incorporates water tubes for heat extraction and recycles elutriated particles to the bed. System operation was stable while firing processed MSW for the duration of a 300-h test. Low excess air, low exhaust gas emissions, and constant bed temperature demonstrated feasibility of steam generation from fluidized bed combustion of MSW. During the 300-h test, combustion efficiency averaged 99%. Excess air was typically 44% while an average bed temperature of 1400/sup 0/F and an average superficial gas velocity of 4.6 fps were maintained. Typical exhaust emission levels were 30 ppM SO/sub 2/, 160 ppM NO/sub x/, 200 ppM CO, and 25 ppM hydrocarbons. No agglomeration of bed material or detrimental change in fluidization properties was experienced. A conceptual design study of a full scale plant to be located at Stanford University was based on process conditions from the 300-h test. The plant would produce 250,000 lb/hr steam at the maximum firing rate of 1000 tons per day (TPD) processed MSW. The average 800 TPD firing rate would utilize approximately 1200 TPD raw MSW from surrounding communities. The Stanford Solid Waste energy Program was aimed at development of a MSW-fired fluidized bed boiler and cogeneration plant to supply most of the energy needs of Stanford University.

  10. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Final report

    SciTech Connect (OSTI)

    NONE

    1996-06-30T23:59:59.000Z

    The problem addressed by our invention is that of municipal solid waste utilization. The dimensions of the problem can be visualized by the common comparison that the average individual in America creates in five years time an amount of solid waste equivalent in weight to the Statue of Liberty. The combustible portion of the more than 11 billion tons of solid waste (including municipal solid waste) produced in the United States each year, if converted into useful energy, could provide 32 quads per year of badly needed domestic energy, or more than one-third of our annual energy consumption. Conversion efficiency and many other factors make such a production level unrealistic, but it is clear that we are dealing with a very significant potential resource. This report describes research pertaining to the co-combustion of oil shale with solid municipal wastes in a circulating fluidized bed. The oil shale adds significant fuel content and also constituents that can possible produce a useful cementitious ash.

  11. Robust techniques for developing empirical models of fluidized bed combustors

    E-Print Network [OSTI]

    Gruhl, Jim

    This report is designed to provide a review of those data analysis techniques that are most useful for fitting m-dimensional empirical surfaces to very large sets of data. One issue explored is the improvement

  12. Data summary of municipal solid waste management alternatives. Volume 5, Appendix C, Fluidized-bed combustion

    SciTech Connect (OSTI)

    none,

    1992-10-01T23:59:59.000Z

    This appendix provides information on fluidized-bed combustion (FBC) technology as it has been applied to municipal waste combustion (MWC). A review of the literature was conducted to determine: (1) to what extent FBC technology has been applied to MWC, in terms of number and size of units was well as technology configuration; (2) the operating history of facilities employing FBC technology; and (3) the cost of these facilities as compared to conventional MSW installations. Where available in the literature, data on operating and performance characteristics are presented. Tabular comparisons of facility operating/cost data and emissions data have been complied and are presented. The literature review shows that FBC technology shows considerable promise in terms of providing improvements over conventional technology in areas such as NOx and acid gas control, and ash leachability. In addition, the most likely configuration to be applied to the first large scale FBC dedicated to municipal solid waste (MSW) will employ circulating bed (CFB) technology. Projected capital costs for the Robbins, Illinois 1600 ton per day CFB-based waste-to-energy facility are competitive with conventional systems, in the range of $125,000 per ton per day of MSW receiving capacity.

  13. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01T23:59:59.000Z

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  14. Development of algorithms for capacitance imaging techniques for fluidized bed flow fields

    SciTech Connect (OSTI)

    Loudin, W.J.

    1991-01-01T23:59:59.000Z

    The objective of this research is to provide support for the instrumentation concept of a High Resolution Capacitance Imaging System (HRCIS). The work involves the development and evaluation of the mathematical theory and associated models and algorithms which reduce the electronic measurements to valid physical characterizations. The research and development require the investigation of techniques to solve large systems of equations based on capacitance measurements for various electrode configurations in order to estimate densities of materials in a cross-section of a fluidized bed. Capacitance measurements are made for 400 connections of the 32-electrode system; 400 corresponding electric-field curves are constructed by solving a second order partial differential equation. These curves are used to partition the circular disk into 193 regions called pixels, and the density of material in each pixel is to be estimated. Two methods of approximating densities have been developed and consideration of a third method has been initiated. One method (Method 1) is based on products of displacement currents for intersecting electric-field curves on a cross section. For each pixel one point of intersection is chosen, and the product of the capacitance measurements is found. Both the product and the square-root-of-product seem to yield good relative distribution of densities.

  15. Development of algorithms for capacitance imaging techniques for fluidized bed flow fields. 1990 Annual report

    SciTech Connect (OSTI)

    Loudin, W.J.

    1991-01-01T23:59:59.000Z

    The objective of this research is to provide support for the instrumentation concept of a High Resolution Capacitance Imaging System (HRCIS). The work involves the development and evaluation of the mathematical theory and associated models and algorithms which reduce the electronic measurements to valid physical characterizations. The research and development require the investigation of techniques to solve large systems of equations based on capacitance measurements for various electrode configurations in order to estimate densities of materials in a cross-section of a fluidized bed. Capacitance measurements are made for 400 connections of the 32-electrode system; 400 corresponding electric-field curves are constructed by solving a second order partial differential equation. These curves are used to partition the circular disk into 193 regions called pixels, and the density of material in each pixel is to be estimated. Two methods of approximating densities have been developed and consideration of a third method has been initiated. One method (Method 1) is based on products of displacement currents for intersecting electric-field curves on a cross section. For each pixel one point of intersection is chosen, and the product of the capacitance measurements is found. Both the product and the square-root-of-product seem to yield good relative distribution of densities.

  16. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, A.G.; Patel, J.G.

    1987-05-12T23:59:59.000Z

    An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

  17. A blurred interface formulation of The Reference Map Technique for Fluid-Solid Interactions and Fluid-Solid-Solid Interactions

    E-Print Network [OSTI]

    Valkov, Boris Ivanov

    2014-01-01T23:59:59.000Z

    In this work we present a blurred interface method for Fluid-Solid Interactions (FSI) and multiple solids immersed in a fluid or FSSI (Fluid-Solid-Solid Interactions) based on the reference map technique as presented by ...

  18. Fluidized-bed combustion

    SciTech Connect (OSTI)

    Botros, P E

    1990-04-01T23:59:59.000Z

    This report describes the activities of the Morgantown Energy Technology Center's research and development program in fluidized-bed combustion from October 1, 1987, to September 30, 1989. The Department of Energy program involves atmospheric and pressurized systems. Demonstrations of industrial-scale atmospheric systems are being completed, and smaller boilers are being explored. These systems include vortex, multi-solid, spouted, dual-sided, air-cooled, pulsed, and waste-fired fluidized-beds. Combustion of low-rank coal, components, and erosion are being studied. In pressurized combustion, first-generation, combined-cycle power plants are being tested, and second-generation, advanced-cycle systems are being designed and cost evaluated. Research in coal devolatilization, metal wastage, tube corrosion, and fluidization also supports this area. 52 refs., 24 figs., 3 tabs.

  19. Dynamic Modeling and Control Studies of a Two-Stage Bubbling Fluidized Bed Adsorber-Reactor for Solid-Sorbent CO{sub 2} Capture

    SciTech Connect (OSTI)

    Modekurti, Srinivasarao; Bhattacharyya, Debangsu; Zitney, Stephen E.

    2013-07-31T23:59:59.000Z

    A one-dimensional, non-isothermal, pressure-driven dynamic model has been developed for a two-stage bubbling fluidized bed (BFB) adsorber-reactor for solid-sorbent carbon dioxide (CO{sub 2}) capture using Aspen Custom Modeler® (ACM). The BFB model for the flow of gas through a continuous phase of downward moving solids considers three regions: emulsion, bubble, and cloud-wake. Both the upper and lower reactor stages are of overflow-type configuration, i.e., the solids leave from the top of each stage. In addition, dynamic models have been developed for the downcomer that transfers solids between the stages and the exit hopper that removes solids from the bottom of the bed. The models of all auxiliary equipment such as valves and gas distributor have been integrated with the main model of the two-stage adsorber reactor. Using the developed dynamic model, the transient responses of various process variables such as CO{sub 2} capture rate and flue gas outlet temperatures have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the incoming flue gas from pulverized coal-fired power plants. In control studies, the performance of a proportional-integral-derivative (PID) controller, feedback-augmented feedforward controller, and linear model predictive controller (LMPC) are evaluated for maintaining the overall CO{sub 2} capture rate at a desired level in the face of typical disturbances.

  20. Scaling of pressurized fluidized beds

    SciTech Connect (OSTI)

    Guralnik, S.; Glicksman, L.R.

    1994-10-01T23:59:59.000Z

    The project has two primary objectives. The first is to verify a set of hydrodynamic scaling relationships for commercial pressurized fluidized bed combustors (PFBC). The second objective is to investigate solids mixing in pressurized bubbling fluidized beds. American Electric Power`s (AEP) Tidd combined-cycle demonstration plant will provide time-varying pressure drop data to serve as the basis for the scaling verification. The verification will involve demonstrating that a properly scaled cold model and the Tidd PFBC exhibit hydrodynamically similar behavior. An important issue in PFBC design is the spacing of fuel feed ports. The feed spacing is dictated by the fuel distribution and the mixing characteristics within the bed. After completing the scaling verification, the cold model will be used to study the characteristics of PFBCs. A thermal tracer technique will be utilized to study mixing both near the fuel feed region and in the far field. The results allow the coal feed and distributor to be designed for optimal heating.

  1. Low temperature SO{sub 2} removal with solid sorbents in a circulating fluidized bed absorber. Final report

    SciTech Connect (OSTI)

    Lee, S.K.; Keener, T.C.

    1994-10-10T23:59:59.000Z

    A novel flue gas desulfurization technology has been developed at the University of Cincinnati incorporating a circulating fluidized bed absorber (CFBA) reactor with dry sorbent. The main features of CFBA are high sorbent/gas mixing ratios, excellent heat and mass transfer characteristics, and the ability to recycle partially utilized sorbent. Subsequently, higher SO{sub 2} removal efficiencies with higher overall sorbent utilization can be realized compared with other dry sorbent injection scrubber systems.

  2. Combined fluidized bed retort and combustor

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Notestein, John E. (Morgantown, WV); Mei, Joseph S. (Morgantown, WV); Zeng, Li-Wen (Morgantown, WV)

    1984-01-01T23:59:59.000Z

    The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

  3. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal (Birmingham, AL); Liu, Guohai (Birmingham, AL); Peng, WanWang (Birmingham, AL)

    2010-08-10T23:59:59.000Z

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  4. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C. Stuart (Knoxville, TN); Hawk, James A. (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

  5. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

    1984-01-01T23:59:59.000Z

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  6. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2006-10-10T23:59:59.000Z

    Low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures provide solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one aspect the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another aspect, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe and Cu, or alloys thereof.

  7. Fundamental study on transient bubble (slug) behavior by characterizing transient forces of solid particles in fluidized beds. Topical report, January 1991--June 1992

    SciTech Connect (OSTI)

    Kono, H.

    1992-10-01T23:59:59.000Z

    The objective of this work is to recognize and interpret the signals of transient motion of bubbles (slugs) in fluidized beds (METC/DOE) by measuring and utilizing the signals of transient gas phase pressure fluctuation, and also by taking the video pictures of transient motions of the bubbles and emulsion phase in fluidized beds. The two signals were measured simultaneously in a three dimensional fluidized bed. Correlation study on the voidage signal and pressure fluctuation was carried out. A domain concept was introduced and new bubble classification was suggested. A video recording approach was also developed to record the transient bubble motion in a two dimensional fluidized bed with a special consideration. This new approach enhances the understanding of bubble image and the physical meaning of transient particle forces. The fundamental mechanism of bubble flow was experimentally investigated and interesting new findings of the transient bubble flow were obtained.

  8. Finial Scientific/Technical Report: Application of a Circulating Fluidized Bed Process for the Chemical Looping Combustion of Solid Fuel

    SciTech Connect (OSTI)

    Dr. Wei-Ping Pan; Dr. John T. Riley

    2005-10-10T23:59:59.000Z

    Chemical Looping Combustion is a novel combustion technology for the inherent separation of the greenhouse gas, CO{sub 2}. In 1983, Richter and Knoche proposed reversible combustion, which utilized both the oxidation and reduction of metal. Metal associated with its oxidized form as an oxygen carrier was circulated between two reactors--oxidizer and reducer. In the reducer, the solid oxygen carrier reacts with the fuel to produce CO{sub 2}, H{sub 2}O and elemental metal only. Pure CO{sub 2} will be obtained in the exit gas stream from the reducer after H{sub 2}O is condensed. The pure CO{sub 2} is ready for subsequent sequestration. In the oxidizer, the elemental metal reacts with air to form metal oxide and separate oxygen from nitrogen. Only nitrogen and some unused oxygen are emitted from the oxidizer. The advantage of CLC compared to normal combustion is that CO{sub 2} is not diluted with nitrogen but obtained in a relatively pure form without any energy needed for separation. In addition to the energy-free purification of CO{sub 2}, the CLC process also provides two other benefits. First, NO{sub x} formation can be largely eliminated. Secondly, the thermal efficiency of a CLC system is very high. Presently, the CLC process has only been used with natural gas. An oxygen carrier based on an energy balance analysis and thermodynamics analysis was selected. Copper (Cu) seems to be the best choice for the CLC system for solid fuels. From this project, the mechanisms of CuO reduction by solid fuels may be as follows: (1) If pyrolysis products of solid fuels are available, reduction of CuO could start at about 400 C or less. (2) If pyrolysis products of solid fuels are unavailable and the reduction temperature is lower, reduction of CuO could occur at an onset temperature of about 500 C, char gasification reactivity in CO{sub 2} was lower at lower temperatures. (3) If pyrolysis products of solid fuels are unavailable and the reduction temperature is higher than 750 C, all reaction reactivities were improved, especially the CO{sub 2} gasification reactivity of char. Thus, the reduction of CuO by the gasification product CO could proceed quickly. Based on the results obtained, the following coal characteristics would be desirable for the Chemical Looping Combustion process: high volatile matter with a high reactivity of the char produced. PRB coal meets these criteria while being comparatively less expensive and also very abundant. The high moisture content present in PRB coal might also increase the reactivity for char gasification through the development of pore structure and specific surface area in the char during pyrolysis. Biomass materials are also suitable, considering the reaction mechanism of CLC system of solid fuels. The feasibility of the chemical looping combustion process of solid fuels was verified by focusing on PRB coal and biomass. Based on PRB coal as the preferred solid fuel in the development of the CLC system, the mass, energy and system in a dual reactor recirculation system has been determined. In the Cu oxidation tests, it was confirmed that the heating rate is the most important effect on the Cu oxidation process. Lower heating rates and lower operational temperatures would result in incomplete conversion of Cu to CuO. Cu{sub 2}O may be the intermediate product. The operating temperature did not affect the reaction rate of the oxidation process. Under any operating conditions, the exothermic properties are clearly shown.

  9. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1983-01-01T23:59:59.000Z

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  10. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1982-01-01T23:59:59.000Z

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  11. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    The objective of this project is to demonstrate that cocombustion of municipal solid waste and oil shale can reduce emissions of gaseous pollutants (SO{sub 2} and HCl) to acceptable levels. Tests in 6- and 15-inch units showed that the oil shale absorbs acid gas pollutants and produces an ash which could be, at the least, disposed of in a normal landfill. Further analysis of the results are underway to estimate scale-up to commercial size. Additional work will be done to evaluate the cementitious properties of oil shale ash.

  12. Dynamic modeling and control of a solid-sorbent CO{sub 2} capture process with two-stage bubbling fluidized bed adsorber reactor

    SciTech Connect (OSTI)

    Modekurti, S.; Bhattacharyya, D.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Solid-sorbent-based CO{sub 2} capture processes have strong potential for reducing the overall energy penalty for post-combustion capture from the flue gas of a conventional pulverized coal power plant. However, the commercial success of this technology is contingent upon it operating over a wide range of capture rates, transient events, malfunctions, and disturbances, as well as under uncertainties. To study these operational aspects, a dynamic model of a solid-sorbent-based CO{sub 2} capture process has been developed. In this work, a one-dimensional (1D), non-isothermal, dynamic model of a two-stage bubbling fluidized bed (BFB) adsorber-reactor system with overflow-type weir configuration has been developed in Aspen Custom Modeler (ACM). The physical and chemical properties of the sorbent used in this study are based on a sorbent (32D) developed at National Energy Technology Laboratory (NETL). Each BFB is divided into bubble, emulsion, and cloud-wake regions with the assumptions that the bubble region is free of solids while both gas and solid phases coexist in the emulsion and cloud-wake regions. The BFB dynamic model includes 1D partial differential equations (PDEs) for mass and energy balances, along with comprehensive reaction kinetics. In addition to the two BFB models, the adsorber-reactor system includes 1D PDE-based dynamic models of the downcomer and outlet hopper, as well as models of distributors, control valves, and other pressure-drop devices. Consistent boundary and initial conditions are considered for simulating the dynamic model. Equipment items are sized and appropriate heat transfer options, wherever needed, are provided. Finally, a valid pressure-flow network is developed and a lower-level control system is designed. Using ACM, the transient responses of various process variables such as flue gas and sorbent temperatures, overall CO{sub 2} capture, level of solids in the downcomer and hopper have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the flue gas. To maintain the overall CO{sub 2} capture at a desired level in face of the typical disturbances, two control strategies were considered–a proportional-integral-derivative (PID)-based feedback control strategy and a feedforward-augmented feedback control strategy. Dynamic simulation results show that both the strategies result in unacceptable overshoot/undershoot and a long settling time. To improve the control system performance, a linear model predictive controller (LMPC) is designed. In summary, the overall results illustrate how optimizing the operation and control of carbon capture systems can have a significant impact on the extent and the rate at which commercial-scale capture processes will be scaled-up, deployed, and used in the years to come.

  13. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994

    SciTech Connect (OSTI)

    Not Available

    1995-01-01T23:59:59.000Z

    The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

  14. Sampling and instrumentation for fluidized-bed combustion. Annual report, October 1978-September 1979

    SciTech Connect (OSTI)

    Johnson, I.; Podolski, W.F.; Myles, K.M.

    1980-09-01T23:59:59.000Z

    In the first section of this report, background information is presented on instrumentation for fluidized-bed combustion, i.e., for process control, scientific investigation, and safety in planned and operating fluidized-bed combustion systems. The objective of this study is to update and extend the fluidized-bed portion of a preceding report, A Study of the State-of-the-Art of Instrumentation for Process Control and Safety in Large-Scale Coal Gasification, Liquefaction, and Fluidized-Bed Combustion Systems, ANL-76-4. The second section of this report describes two prototype mass flow rate instruments installed on the solids feed lines of an existing ANL fluidized-bed combustor. The Fossil Instrumentation Group at ANL designed, fabricated, and installed these instruments in cooperation with Chemical Engineering Division personnel - one on the coal feedline and one on the coal/limestone feedline. Each instrument consisted of a capacitive sensor spoolpiece and an associated preamplifier and signal conditioning. One channel of each instrument provides three outputs. One delivers a density signal while two others deliver two signals for measuring velocity by cross-correlation. Operation was verified by using laboratory signal analyzers to process the signals. The third section of this report summarizes the results of a Spectron Development Laboratory subcontract from ANL to investigate analytical techniques suitable for monitoring the concentration of gaseous alkali compounds in the hot gas stream from a fluidized-bed combustor. It was concluded from the study that the concept of using the Na/sub 2/SO/sub 4/ dew point to detect the onset of hot corrosion conditions is the most attractive of the techniques evaluated.

  15. Dynamics of a shallow fluidized bed Lev S. Tsimring,1

    E-Print Network [OSTI]

    Hasty, Jeff

    Fluidized beds are widely used in industry for mixing solid particles with gases or liquids 1 . In most, and sliding back due to gravity. Near the threshold of instability, the system shows critical behavior

  16. An experimental study of the hydrodynamics and cluster formation in a circulating fluidized bed. Topical report, January 1, 1991--June 30, 1992

    SciTech Connect (OSTI)

    Gautam, M.; Jurewicz, J.; Heping, Y.; Clifton, K.

    1992-07-01T23:59:59.000Z

    This research program involves two major aspects. First, to evaluate techniques to effectively probe the polydisperse gas-solid flows and second, to apply these techniques to study the gas-solid flow structure and clusters in the riser of a circulating fluidized bed riser. Amongst the non-intrusive techniques a modified laser Doppler technique based on the fluorescence-emission concept has been adopted and the other techniques involve pitot-static pressure probes. A circulating fluidized bed (CFB) facility has been designed, built and is currently operational at West Virginia University. The design provides for maximum versatility in investigating the hydrodynamics of the CFB riser. Two stage cyclones are employed to capture the particles exhausted from the riser. Measurements of gas velocity distribution were carried out in the circulating fluidized bed riser. with particles having a mean diameter of 112 {mu}m and a density of 2305 kg/m{sup 3} and another set of particles with a mean diameter of 145 {mu}m and a density of 2245 kg/m{sup 3}. The experimental results showed that the local gas velocity varied with the radial position, elevation, solids circulation rate, superficial velocity and particle size. A general formula for gas velocity distribution in the circulating fluidized bed riser was obtained based on the particle circulation, superficial velocity and particle diameter. The pressure drops across the L-valve were also studied for different particle sizes, L-valve diameters and aeration. The solids flowrate was found to be a function of the L-valve geometry, operating parameters and solids properties. Pressure drop of L-valve increases with increasing solids diameter and decreasing diameter of the L-valve. Pressure drop across standpipe increases as the solids diameter and diameter of the standpipe decrease.

  17. Reversed flow fluidized-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Mei, Joseph S. (Morgantown, WV); Wilson, John S. (Morgantown, WV)

    1984-01-01T23:59:59.000Z

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  18. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, R.G.

    1983-05-13T23:59:59.000Z

    The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  19. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06T23:59:59.000Z

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  20. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

    1986-01-01T23:59:59.000Z

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  1. Solid-Cryogen Cooling Technique for Superconducting Magnets of NMR and MRI

    E-Print Network [OSTI]

    Iwasa, Yukikazu

    This paper describes a solid-cryogen cooling technique currently being developed at the M.I.T. Francis Bitter Magnet Laboratory for application to superconducting magnets of NMR and MRI. The technique is particularly ...

  2. Circulating fluidized bed hydrodynamics experiments for the multiphase fluid dynamics research consortium (MFDRC).

    SciTech Connect (OSTI)

    Oelfke, John Barry; Torczynski, John Robert; O'Hern, Timothy John; Tortora, Paul Richard; Bhusarapu, Satish (; ); Trujillo, Steven Mathew

    2006-08-01T23:59:59.000Z

    An experimental program was conducted to study the multiphase gas-solid flow in a pilot-scale circulating fluidized bed (CFB). This report describes the CFB experimental facility assembled for this program, the diagnostics developed and/or applied to make measurements in the riser section of the CFB, and the data acquired for several different flow conditions. Primary data acquired included pressures around the flow loop and solids loadings at selected locations in the riser. Tomographic techniques using gamma radiation and electrical capacitance were used to determine radial profiles of solids volume fraction in the riser, and axial profiles of the integrated solids volume fraction were produced. Computer Aided Radioactive Particle Tracking was used to measure solids velocities, fluxes, and residence time distributions. In addition, a series of computational fluid dynamics simulations was performed using the commercial code Arenaflow{trademark}.

  3. Control of a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Shim, Hoowang; Rickards, Gretchen; Famouri, Parviz; Turton, Richard (WVU); Sams, W. Neal (EG& G); Koduro, Praveen; Patankar, Amol; Davari, Assad (WVUIT); Lawson, Larry; Boyle, Edward J. (DOE)

    2001-11-06T23:59:59.000Z

    Two methods for optimally controlling the operation of a circulating fluidized bed are being investigated, neural network control and Kalman filter control. The neural network controls the solids circulation rate by adjusting the flow of move air in the non-mechanical valve. Presented is the method of training the neural network from data generated by the circulating fluidized bed (CFB), the results of a sensitivity study indicating that adjusting the move air can control solids flow, and the results of controlling solids circulation rate. The Kalman filter approach uses a dynamic model and a measurement model of the standpipe section of the CFB. Presented are results showing that a Kalman filter can successfully find the standpipe bed height.

  4. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2008-04-01T23:59:59.000Z

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  5. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2012-10-09T23:59:59.000Z

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  6. Experimental and computational studies of hydrodynamics in three-phase and two-phase fluidized beds

    SciTech Connect (OSTI)

    Bahary, M.

    1994-12-01T23:59:59.000Z

    The objective of the present study was to investigate the hydrodynamics of three-phase fluidized beds, their rheology, and experimentally verify a predictive three fluid hydrodynamic model developed at the Illinois Institute of Technology, Chicago. The recent reviews show that there exist no such models in the literature. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid, and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. In this thesis, a three fluid model is presented. The input into the model can be particulate viscosities either measured with a Brookfield viscometer or derived using the mathematical techniques of kinetic theory of granular flows pioneered by Savage and others. The computer simulation of a three-phase fluidized bed in an asymmetric mode qualitatively predicts the gas, liquid and solid hold-ups (volume fractions) and flow patterns in the industrially important churn-turbulent (bubbly coalesced) regimes. The computations in a fluidized bed with a symmetric distributor incorrectly showed no bubble coalescence. A combination of X-ray and {gamma}-ray densitometers was used to measure the solids and the liquid volume fractions in a two dimensional bed in the bubble coalesced regime. There is a good agreement between the theory for an asymmetric distributor and the experiments.

  7. An Analysis of the Use of Fluidized-Bed Heat Exchangers for Heat Recovery 

    E-Print Network [OSTI]

    Vogel, G. J.; Grogan, P. J.

    1980-01-01T23:59:59.000Z

    . the Fifth International Conf. on Fluidized Bed Combustion, Washington, D.C., Dec. 1977, MITRE Corp., M78-68 (Dec. 1978). 11. 3. Virr, M.J., "Commercialization of Small Scale Fluidized Combustion Techniques," Proc. of the Fourth International Conf.... on Fluidized-Bed Com- 12. bustion, McLean, Va., Dec. 1975,MITRE Corp., M76-36 (1976). 4. Elliott, D.E., and M.J. Virr, "Small-Scale 13. Applications of Fluidized-Bed Combustion and Heat Transfer," Proc. of the Third International Conf. on Fluidized...

  8. Application of Verified Optimization Techniques to Parameter Identification for Solid Oxide Fuel Cells

    E-Print Network [OSTI]

    Appelrath, Hans-Jürgen

    Application of Verified Optimization Techniques to Parameter Identification for Solid Oxide Fuel at the latest, design and development of solid oxide fuel cells (SOFC) have been in the focus of research electrochemical reactions in each individual fuel cell. We consider different model dimensions resulting

  9. Advanced atmospheric fluidized-bed combustion design: the staged cascading fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1985-02-19T23:59:59.000Z

    The distinctive features of the Staged Cascade Fluidized Bed Combustor (SCFBC) are: combustion is accomplished in two cascaded fluidized beds, with coal fed between the beds; sulfation occurs in two cascaded fluidized beds with the spent sorbent being reactivated between the beds; all heat exchange tubes are submerged in a series of cascaded fluidized beds to improve heat transfer efficiency; the lowest stage provides cooling of spent bed materials and preheating of incoming air; and all of the fluidized beds are shallow, roughly 4'' to 8'' expanded bed depth. The SCFBC does not require external convective section, economizer, air preheater, or spent solids cooling system, as does the AFBC. All the functions of those traditional components are performed within the SCFBC. The shallow beds and low pressure drop distributor plates of the SCFBC have cumulative pressure drop essentially equal to the pressure drop across the single deep bed of a conventional AFBC. Better fuel utilization is achieved in the SCFBC, which achieves a carbon burnout of 97.1% vs 95.0% for the AFBC. The SCFBC advantage is due to the staging of combustion in two beds. The thermal efficiency of the SCFBC is higher than that of the AFBC (85.4%) vs 31.65%). The SCFBC accomplishes the specified SO removal with a significantly reduced amount of limestone adsorbent. The SCFBC has several other technical advantages over the AFBC which are mentioned. 11 figs., 23 tabs.

  10. Fluidized wall for protecting fusion chamber walls

    DOE Patents [OSTI]

    Maniscalco, James A. (Danville, CA); Meier, Wayne R. (Livermore, CA)

    1982-01-01T23:59:59.000Z

    Apparatus for protecting the inner wall of a fusion chamber from microexplosion debris, x-rays, neutrons, etc. produced by deuterium-tritium (DT) targets imploded within the fusion chamber. The apparatus utilizes a fluidized wall similar to a waterfall comprising liquid lithium or solid pellets of lithium-ceramic, the waterfall forming a blanket to prevent damage of the structural materials of the chamber.

  11. Staged fluidized-bed coal combustor for boiler retrofit

    SciTech Connect (OSTI)

    Rehmat, A. (Institute of Gas Technology, Chicago, IL (United States)); Dorfman, L.; Shibayama, G. (Fluor-Daniels, Inc., Chicago, IL (United States)); Waibel, R. (Zink (J.) and Co., Tulsa, OK (United States))

    1991-01-01T23:59:59.000Z

    The Advanced Staged Fluidized-Bed Coal Combustion System (ASC) is a novel clean coal technology for either coal-fired repowering of existing boilers or for incremental power generation using combined-cycle gas turbines. This new technology combines staged combustion for gaseous emission control, in-situ sulfur capture, and an ash agglomeration/vitrification process for the agglomeration/vitrification of ash and spent sorbent, thus rendering solid waste environmentally benign. The market for ASC is expected to be for clean coal-fired repowering of generating units up to 250 MW, especially for units where space is limited. The expected tightening of the environmental requirements on leachable solids residue by-products could considerably increase the marketability for ASC. ASC consists of modular low-pressure vessels in which coal is partially combusted and gasified using stacked fluidized-bed processes to produce low-to-medium-Btu, high-temperature gas. This relatively clean fuel gas is used to repower/refuel existing pulverized-coal, natural gas, or oil-fired boilers using bottom firing and reburning techniques. The benefits of ASC coal-fired repowering include the ability to repower boilers without obtaining additional space while meeting the more stringent environmental requirements of the future. Low NO{sub x}, SO{sub x}, and particulate levels are expected while a nonleachable solid residue with trace metal encapsulation is produced. ASC also minimizes boiler modification and life-extension expenditures. Repowered efficiencies can be restored to the initial operating plant efficiency, and the existing boiler capacity can be increased by 10%. Preliminary cost estimates indicate that ASC will have up to a $250/kW capital cost advantage over existing coal-fired repowering options. 4 figs., 4 tabs.

  12. Contributed papers Study of gas-fluidization dynamics with laser-polarized 129

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    Gas fluidization is a process in which solid particles experience fluid-like suspension in an upward. Bubbles, or void spaces with volume much larger than that of a single particle, emerge when the gas flowContributed papers Study of gas-fluidization dynamics with laser-polarized 129 Xe Ruopeng Wanga

  13. Use of fluidized bed coal combustion techniques to study efficiency, emission reduction, boiler effects, and waste utilization: Final report, July 1, 1985-February 28, 1986

    SciTech Connect (OSTI)

    Hesketh, H.E.; Rajan, S.

    1986-05-01T23:59:59.000Z

    This study program, funded by the US Department of Energy through the Southern Illinois University Coal Research Center's Coal Technology Laboratory, was conducted during the period from July 1984 through February 1986. Two lines of testing were carried out simultaneously. One consisted of using a laboratory-scale atmospheric fluidized bed combustor (AFBC) to acquire thermodynamic data and operating characteristics for Illinois coal combustion. The other included acquisition, installation, shakedown, and operation of a large one million Btu/h pilot-scale AFBC (plus boiler and associated instrumentation). Both programs were to study Illinois reference and gob (waste) type coals.

  14. Bed drain cover assembly for a fluidized bed

    DOE Patents [OSTI]

    Comparato, Joseph R. (Bloomfield, CT); Jacobs, Martin (Hartford, CT)

    1982-01-01T23:59:59.000Z

    A loose fitting movable cover plate (36), suitable for the severe service encountered in a fluidized bed combustor (10), restricts the flow of solids into the combustor drain lines (30) during shutdown of the bed. This cover makes it possible to empty spent solids from the bed drain lines which would otherwise plug the piping between the drain and the downstream metering device. This enables use of multiple drain lines each with a separate metering device for the control of solids flow rate.

  15. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1996-02-27T23:59:59.000Z

    A fluidized bed reactor system is described which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves. 3 figs.

  16. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  17. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1995-01-01T23:59:59.000Z

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  18. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1996-01-01T23:59:59.000Z

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

  19. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.

    1993-12-14T23:59:59.000Z

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

  20. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1995-04-25T23:59:59.000Z

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

  1. A simplified model for the combustion of coal in a continuous flow fluidized bed

    E-Print Network [OSTI]

    Richardson, Thomas Wade

    1982-01-01T23:59:59.000Z

    with ease of handling. 2. The rapid mixing of solids to nearly isothermal conditions throughout the reactor, hence the operation can be controlled simply and reliably. 3. The circulation of solids between two fluidized beds makes it possible...A SIMPLIFIED MODEL FOR THE COMBUSTION OF COAL IN A CONTINUOUS FLOW FLUIDIZED BED A Thesis by THOMAS WADE RICHARDSON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  2. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1981-01-01T23:59:59.000Z

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  3. Use of fluidized bed coal combustion techniques to study efficiency, emission reduction, boiler effects, and waste utilization. Annual report, January 1-June 30, 1985

    SciTech Connect (OSTI)

    Hesketh, H.E.; Rajan, S.

    1985-09-01T23:59:59.000Z

    The acquisition of thermodynamic and operating data on a wide variety of waste coals in a laboratory-scale atmospheric fluidized bed combustor (AFBC) unit is reported. The coals tested include: (1) low and medium heating value gob pile wastes, with ash content as high as 60%; (2) pelletized gob waste fines; (3) various cuts taken from beneficiation plant rejects with low heating values and high ash content; and (4) a partially devolatilized char produced from a caking Illinois coal. These waste coals could be successfully burned in the bench-scale unit with the exception of the high ash content beneficiation plant reject with a low heating value of 1700 Btu/lb. Some of the waste coals exhibited better combustion characteristics than others. The results obtained and the recommendations for improving the combustion and emission characteristics of the waste coals are discussed. Shakedown tests have been completed with the 1-ft diameter, 1 MBtu/h pilot-scale AFBC unit, and the results are reported. 1 ref., 15 figs., 8 tabs.

  4. Comparison study of solid-liquid separation techniques for oilfield pit closures

    SciTech Connect (OSTI)

    Wojtanowicz, A.C.; Field, S.D.; Osterman, M.C.

    1986-01-01T23:59:59.000Z

    Extensive bench-scale and full-scale experiments were conducted at the LSU Solids Control Environmental Laboratory in order to evaluate application of the solids-liquid separation technology to oilfield waste pit volume reduction. The experiments addressed chemical conditioning of various pit slurries such as water-base and oil-base mud reserve pit slurries, mixed sludge from offshore operations, and oil production pit slurry. Effective treatment was found for the majority of the waste samples with pH adjustment and with nonionic and low-charge anionic, high molecular weight polymers. Ultimate dewaterability of various samples was determined by use of the belt press bench simulator. Bench simulators of belt press filtration, vacuum filtration and centrifuge sedimentation were used for design and optimization of the full-scale tests. Alternative solid-liquid separation techniques such as vacuum filtration, belt press filtration, screw press filtration and centrifuging were pilot-tested using field-size equipment and 200 bbls samples of water-base mud, reserve pit slurry and production pit sludge. The test data were analyzed at various operating conditions using a new graphical technique. Also, four typical oilfield solid-bowl centrifuges and a modern solid-bowl dewatering decanter were compared in a series of full-scale tests. Finally a preliminary process study on the mechanism of centrifuge separation of flocculated sludges was performed.

  5. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

    1983-01-01T23:59:59.000Z

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  6. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14T23:59:59.000Z

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  7. Measuring and modeling solids movement in a large, cold fluidized bed test facility. Second quarterly report, January 1, 1980-March 31, 1980

    SciTech Connect (OSTI)

    Fitzgerald, T. J.; Mrazek, R. V.; Crane, S. D.

    1980-03-01T23:59:59.000Z

    The plume model is developed to represent a tube-filled AFBC with large particles, in which air-entrained coal enters in a number of feed ports from below. It assumes that the volatiles are rapidly released from the coal at the feed entry ports to rise as plumes of combustible vapors. Graphs have been prepared to display the predictions of this model for narrow size cuts of a typical coal feed. For a feed of wide size distribution, use these single size charts and properly sum. The lowest carbon efficiency always comes with an intermediate size of feed coal, not with very large or very small feed sizes. Thus the coal feed to the AFBC should try to avoid this critical size. The plume behavior, whether it breaks the surface of the bed, the temperature jump above the bed, concentration variations across the bed, etc., are all governed by one dimensionless group HD/u/sub 0/L/sub 2//sup 2/, which depends primarily on the spacing of feed ports in the bed. For a given coal feed, the carbon efficiency depends only on superficial gas velocity in the bed, the excess air, and elutriation rate constant. A special case and simplification of this model views the coal as being uniformly distributed all over the bed before the volatiles are released. Here analysis is very much simpler, not involving plumes and no volatiles leaving the bed. This plumeless model should reasonably represent AFBC using large feed particles, introduced across the top of the bed and then rapidly mixed by large scale convective flow of solids. The analysis shows that, even in beds with plumes, the simpler plumeless model can be used with negligible error to calculate carbon efficiency; for volatile efficiency, temperature jumps and composition variations across the bed, the complete plume model must be used.

  8. Fluidized-bed sorbents

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1994-10-01T23:59:59.000Z

    The objectives of this project are to identify and demonstrate methods for enhancing long-term chemical reactivity and attrition resistance of zinc oxide-based mixed metal-oxide sorbents for desulfurization of hot coal-derived gases in a high-temperature, high-pressure (HTHP) fluidized-bed reactor. In this program, regenerable ZnO-based mixed metal-oxide sorbents are being developed and tested. These include zinc ferrite, zinc titanate, and Z-SORB sorbents. The Z-SORB sorbent is a proprietary sorbent developed by Phillips Petroleum Company (PPCo).

  9. Staged fluidized-bed combustion and filter system

    DOE Patents [OSTI]

    Mei, Joseph S. (Morgantown, WV); Halow, John S. (Waynesburg, PA)

    1994-01-01T23:59:59.000Z

    A staged fluidized-bed combustion and filter system for substantially reducing the quantity of waste through the complete combustion into ash-type solids and gaseous products. The device has two fluidized-bed portions, the first primarily as a combustor/pyrolyzer bed, and the second as a combustor/filter bed. The two portions each have internal baffles to define stages so that material moving therein as fluidized beds travel in an extended route through those stages. Fluidization and movement is achieved by the introduction of gases into each stage through a directional nozzle. Gases produced in the combustor/pyrolyzer bed are permitted to travel into corresponding stages of the combustor/filter bed through screen filters that permit gas flow but inhibit solids flow. Any catalyst used in the combustor/filter bed is recycled. The two beds share a common wall to minimize total volume of the system. A slightly modified embodiment can be used for hot gas desulfurization and sorbent regeneration. Either side-by-side rectangular beds or concentric beds can be used. The system is particularly suited to the processing of radioactive and chemically hazardous waste.

  10. Fluidized bed controls refinery emissions

    SciTech Connect (OSTI)

    Abdulally, I.F.; Kersey, B.R.

    1986-05-01T23:59:59.000Z

    In early 1983, two fluidized bed, waste heat boilers entered into service at the Ashland Petroleum Company refinery site in Ashland, Kentucky. These fluidized bed units are coupled to the regeneration end of a newly developed reduced crude conversion (RCC) process and served the purpose of reducing CO, SO/sub 2/ and NO/sub x/ emissions while recuperating waste heat from the regenerator process off gases.

  11. Advanced atmospheric fluidized-bed combustion design - spouted bed

    SciTech Connect (OSTI)

    Shirley, F.W.; Litt, R.D.

    1985-11-27T23:59:59.000Z

    This report describes the Spouted-Fluidized Bed Boiler that is an advanced atmospheric fluidized bed combustor (FBC). The objective of this system design study is to develop an advanced AFBC with improved performance and reduced capital and operating costs compared to a conventional AFBC and an oil-fired system. The Spouted-Fluidized Bed (SFB) system is a special type of FBC with a distinctive jet of air in the bed to establish an identifiable solids circulation pattern. This feature is expected to provide: reduced NO/sub x/ emissions because of the fuel rich spout zone; high calcium utilization, calcium-to-sulfur ratio of 1.5, because of the spout attrition and mixing; high fuel utilization because of the solids circulation and spout attrition; improved thermal efficiency because of reduced solids heat loss; and improved fuel flexibility because of the spout phenomena. The SFB was compared to a conventional AFBC and an oil-fired package boiler for 15,000 pound per hour system. The evaluation showed that the operating cost advantages of the SFB resulted from savings in fuel, limestone, and waste disposal. The relative levelized cost for steam from the three systems in constant 1985 dollars is: SFB - $10 per thousand pounds; AFBC - $11 per thousand pounds; oil-fired - $14 per thousand pounds. 18 refs., 5 figs., 11 tabs.

  12. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    Sibashis Banerjee; Alvin Chen; Rutton Patel; Dale Snider; Ken Williams; Timothy O'Hern; Paul Tortora

    2008-02-29T23:59:59.000Z

    The work detailed in this report addresses Enabling Technologies within Computational Technology by integrating a “breakthrough” particle-fluid computational technology into traditional Process Science and Engineering Technology. The work completed under this DOE project addresses five major development areas 1) gas chemistry in dense fluidized beds 2) thermal cracking of liquid film on solids producing gas products 3) liquid injection in a fluidized bed with particle-to-particle liquid film transport 4) solid-gas chemistry and 5) first level validation of models. Because of the nature of the research using tightly coupled solids and fluid phases with a Lagrangian description of the solids and continuum description of fluid, the work provides ground-breaking advances in reactor prediction capability. This capability has been tested against experimental data where available. The commercial product arising out of this work is called Barracuda and is suitable for a wide (dense-to-dilute) range of industrial scale gas-solid flows with and without reactions. Commercial applications include dense gas-solid beds, gasifiers, riser reactors and cyclones.

  13. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01T23:59:59.000Z

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  14. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, J.

    1996-03-19T23:59:59.000Z

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  15. A NEW INTERPHASE FORCE IN TWO-PHASE FLUIDIZED BEDS

    SciTech Connect (OSTI)

    D. ZHANG; W. VANDERHEYDEN

    2001-05-01T23:59:59.000Z

    Mesoscale structures such as particle clusters have been observed both in experiments and in numerical simulations of circulating fluidized beds. In a numerical simulation, in order to account for the effects of such mesoscale structures, the computational grids have to be fine enough. The use of such fine grids is impractical in engineering applications due to excessive computational costs. To predict the macroscopic behavior of a fluidized bed with reasonable computation cost, they perform a second average over the averaged equations for two-phase flows. A mesoscale inter-phase exchange force is found to be the correlation of the particle volume fraction and the pressure gradient. This force is related to the mesoscale added mass of the two-phase flow. Typically, added mass for particle scale interactions is negligible in gas-solid flows since the gas density is small compared to density of solid particles. However, for a mesoscale structure, such as a bubble, the surrounding media is the mixture of gas and particles. The surrounding fluid density experienced by the mesoscale structure is the density of the surrounding mixture. Therefore, the added mass of a mesoscale structure, such as bubbles, cannot be neglected. The property of this new force is studied based on the numerical simulation of a fluidized bed using high grid resolution. It is shown that this force is important in the region where the particle volume fraction is high. The effects of the inhomogeneity to the interphase drag are also studied.

  16. Fluidized bed combustion of alternate fuels. Final report

    SciTech Connect (OSTI)

    Howe, W.C.; Divilio, R.J. [Combustion Systems, Inc., Aptos, CA (United States)

    1993-12-01T23:59:59.000Z

    Fluidized bed combustion (FBC) technology offers the opportunity combust a broader range of fuels than previously possible with other technologies. FBC boilers are currently being used throughout the world to dispose of a wide range of solid and semi-solid waste fuels, including municipal and industrial solid wastes and sludges, agricultural wastes, and coal mining or cleaning wastes. FBCs can also accommodate cofiring waste fuels in units designed for coal or other solid fuels with relative ease compared to conventional technology. The capacity and experience base for coal-fired FBCs has increased in recent years so that utility-scale reheat units of 200-300 MWe in size are now commercially available, and larger units are now being considered. As utilities install fluidized bed boilers to generate power, it is anticipated that many will at some point consider cofiring one or more waste fuels either together or with coal to reduce the quantity and cost of the primary fuel, and in many cases, help offset the environmental impact of other disposal options such as landfills. In order to assist the industry in their evaluations, this report summarizes the fuel characteristics, experience base, and technical issues associated with burning selected fuels using FBC technology, including: Municipal Solid Wastes; Biomass; Sewage Sludge; Paper Manufacturing and Recycling Wastes; Scrap Tires; and Automobile Wastes.

  17. Studies with a laboratory atmospheric fluidized bed combustor system

    SciTech Connect (OSTI)

    Orndorff, W.W.; Su, Shi; Napier, J. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

    1996-12-31T23:59:59.000Z

    Growing public concerns over acid rain and municipal solid waste problems have created interest in the development of atmospheric fluidized bed combustion systems. A computer controlled 12-inch laboratory atmospheric fluidized bed combustor (AFBC) system has been developed at Western Kentucky University. On-line analysis by gas chromatography, Fourier-transform infrared (FTIR) spectrometry, and mass spectrometry (MS) allows extensive analysis of the flux gases. Laboratory experiments with a thermogravimetric analyzer (TGA) interfaced with FTIR and MS systems are used to screen fuel blends for runs in the AFBC system. Current experiments being conducted include co-firing blends of refuse derived fuels with coal and extended burns with coals containing different levels of chlorine.

  18. Physical-chemical NO/sub x/ mechanisms in fluidized bed combustion

    SciTech Connect (OSTI)

    Bywater, R. J.

    1980-11-03T23:59:59.000Z

    Fluidized bed combustors operate in the large-particle (> 1 mm) high-velocity (> 1 m/s) fluidization regime which differs from most previous applications. These characteristics foster a distinctive volatiles evolution structure in the vicinity of the coal injectors of bottom-fed atmospheric fluidized beds (AFBC). The evolution of coal volatiles associated with bottom-fed AFBC was defined as the focal point. The major effort of the work was concerned with a group combustion model of dense gas/solids mixtures of devolatilizing coal being injected into the bottom of an AFBC. Critical development needs were defined in the area of solids circulation and injector design which impact both basic FBC design and NO/sub x/ emissions. Results of model calculations identified important new physical-chemical mechanisms influencing NO/sub x/ emissions.

  19. Char binder for fluidized beds

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Accortt, Joseph I. (Simsbury, CT)

    1981-01-01T23:59:59.000Z

    An arrangement that utilizes agglomerating coal as a binder to bond coal fines and recycled char into an agglomerate mass that will have suitable retention time when introduced into a fluidized bed 14 for combustion. The simultaneous use of coal for a primary fuel and as a binder effects significant savings in the elimination of non-essential materials and processing steps.

  20. Agglomeration of sorbent and ash carry-over for use in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Rohargi, N.D.T.

    1983-04-01T23:59:59.000Z

    Agglomeration of elutriated sorbent, ash and char from a fluidized-bed boiler, with spent bed overflow material and water, has been identified as a potentially attractive technique for reducing sorbent consumption in atmospheric fluidized-bed combustors. The agglomerated products are returned to the combustor to improve the calcium utilization of the sorbent and to complete the combustion of elutriated carbon material. In this experimental programme, agglomerates were collected during test runs on the 1.8 m x 1.8 m fluidized-bed combustor. Agglomerate characteristics, such as handling strength, sulfur capture activity carbon utilization and resistance to attrition, were determined as functions of agglomeration processing variables. These variables include feed composition, feed particle size, amount of water addition, curing time, and curing atmosphere or drying conditions. Ca/S feed ratio requirements for a commercial AFBC that uses the agglomeration process were projected on the basis of the Westinghouse model for fluidized-bed desulphurization.

  1. Investigation of sulfation characteristics of AFBC ashes using SEM-EDX technique

    SciTech Connect (OSTI)

    Selcuk, N.; Oymak, O.; Barlas, D. [Middle East Technical Univ., Ankara (Turkey). Dept. of Chemical Engineering

    1995-12-31T23:59:59.000Z

    A study was carried out for the determination of sulfation characteristics of both ash and sorbent particles sampled from a pilot scale atmospheric fluidized bed combustor burning low quality lignite with and without limestone addition. Solid samples were analyzed by using SEM-EDX (Scanning Electron Microscope combined with Energy Dispersive X-Ray analysis) technique. Sulfur distribution was investigated within ash particles with an average particle diameter of 645{micro}m (without limestone addition) and within solid particles with average particle diameters of 191{micro}m and 645{micro}m (with limestone addition). It was observed that sulfation takes place volumetrically for both ash and sorbent particles sampled from the bed. The results of this investigation show that the sulfation reaction proceeds according to the shrinking unreacted core model as suggested by laboratory experiments carried out under simulated fluidized bed combustion conditions. However, it is a volumetric reaction due to the residence time ({approximately}1h) the particles spend in the bed of the pilot scale FBC under consideration. It should be noted that the average size of these sorbent particles fall in the range commonly used in fluidized beds of practical interest. Investigation of sulfation characteristics of samples directly obtained from fluidized bed combustors by SEM-EDX analysis is not available to date.

  2. Experimental study of the hydrodynamics and cluster formation in a Circulating Fluidized Bed. Annual report, 1990

    SciTech Connect (OSTI)

    Gautam, M.; Johnson, E.

    1991-01-01T23:59:59.000Z

    A novel non-invasive gas-solid flow measuring technique being developed and tested for studying the hydrodynamics inside the riser of a Circulating Fluidized Bed (CFB). First of the two aims of the overall program, namely, design, development and testing of the technique to characterize the particle and gas velocities in two-phase flows was accomplished in the past year. The ``fringe-model`` laser Doppler anemometry concept has been modified and extended by using particles coated with a fluorescent dye and introducing a narrow band pass filter in the receiving optics. The technique permits optical discrimination between the scattered light (laser wavelength from undyed particles) and the fluorescence emission (longer wavelength). Results from extensive testing of various dye-solvent combinations, counter processor settings, signal-to noise optimization and subsequent flow measurements in the test section have shown that the technique can effectively discriminate between two classes of particles--the smaller seed particles for the gas phase data and the larger bed particles. Use of a two-watt Argon-Ion laser assisted in the non-intrusive probing of the gas-solid flow and in enhancing the signal-to-noise ratio. An uncertainty analysis of LDA measurements is presented. Design of the cold flow CFB model, presently under fabrication, is outlined in this report. The Plexiglas CFB model will be employed for the riser core-annular flow studies using the fluorescence-emission based laser-Doppler anemometry. The results from this study will present a unique detailed description of the complex gas-solid behavior in the CFB riser.

  3. Experimental study of the hydrodynamics and cluster formation in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Gautam, M.; Johnson, E.

    1991-01-01T23:59:59.000Z

    A novel non-invasive gas-solid flow measuring technique being developed and tested for studying the hydrodynamics inside the riser of a Circulating Fluidized Bed (CFB). First of the two aims of the overall program, namely, design, development and testing of the technique to characterize the particle and gas velocities in two-phase flows was accomplished in the past year. The fringe-model'' laser Doppler anemometry concept has been modified and extended by using particles coated with a fluorescent dye and introducing a narrow band pass filter in the receiving optics. The technique permits optical discrimination between the scattered light (laser wavelength from undyed particles) and the fluorescence emission (longer wavelength). Results from extensive testing of various dye-solvent combinations, counter processor settings, signal-to noise optimization and subsequent flow measurements in the test section have shown that the technique can effectively discriminate between two classes of particles--the smaller seed particles for the gas phase data and the larger bed particles. Use of a two-watt Argon-Ion laser assisted in the non-intrusive probing of the gas-solid flow and in enhancing the signal-to-noise ratio. An uncertainty analysis of LDA measurements is presented. Design of the cold flow CFB model, presently under fabrication, is outlined in this report. The Plexiglas CFB model will be employed for the riser core-annular flow studies using the fluorescence-emission based laser-Doppler anemometry. The results from this study will present a unique detailed description of the complex gas-solid behavior in the CFB riser.

  4. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse...

  5. Fluidized bed gasification of agricultural residue

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    and Kinetics Development of Gasification Systems Fixed Bed Gasifiers Fluidized Bed Gasifiers Fluidization 6 7 12 12 13 16 III DEVELOPMENT OF EXPERIMENTAL SYSTEM . . . 20 IV Feed Preparation and Analysis Experimental Apparatus Experimental Method..., wheat, and rice in Texas were produced at an average rate of 20 million tons (18 Tg) per year (LePori and Lacewell, 1977). The main impetus of the project being implemented is to design and build a fluidized bed combustion prototype with subsequent...

  6. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01T23:59:59.000Z

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  7. Advanced Fluidized Bed Waste Heat Recovery Systems

    E-Print Network [OSTI]

    Peterson, G. R.

    ADVANCED FLUIDIZED BED WASTE HEAT RECOVERY SYSTEMS G. R. PETERSON Project Manager U.S. Department of Energy, Idaho Operations Office Idaho Falls, Idaho ABSTRACT The U.S. Department of Energy, Office of Industri al Programs, has sponsored... the development of a Fluidized Bed Waste Heat Recovery System (FBWHRS) and a higher temperature variant, the Ceramic Tubular Distributor Plate (CTOP) Fluidized Bed Heat Exchanger (FBHX) system. Both systems recover energy from high-temperature flue gases...

  8. Fluidized bed combustor and tube construction therefor

    DOE Patents [OSTI]

    De Feo, Angelo (Passaic, NJ); Hosek, William (Morris, NJ)

    1981-01-01T23:59:59.000Z

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  9. Tube construction for fluidized bed combustor

    DOE Patents [OSTI]

    De Feo, Angelo (Totowa, NJ); Hosek, William (Mt. Tabor, NJ)

    1984-01-01T23:59:59.000Z

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  10. Fluidized Bed Technology - Overview | Department of Energy

    Office of Environmental Management (EM)

    fluidized bed boilers as a standard package. This success is largely due to the Clean Coal Technology Program and the Energy Department's Fossil Energy and industry partners...

  11. A new technique to monitor ground-water quality at municipal solid waste landfills

    E-Print Network [OSTI]

    Hart, Steven Charles

    1989-01-01T23:59:59.000Z

    government substantially increased its role in managing solid waste when Congress passed the Resource Conservation and Recovery Act (RCRA, 1976). Subtitle D of this act requires the Federal government to establish guidelines and provide technical... assistance to the States for the planning and developing of nonhazardous solid waste management programs. Under authority of Sections 1003(a)(3) and 40D4(a) of RCRA, the EPA issued the "Criteria for Classification of Solid Maste Disposal Facilities...

  12. Metal wastage design guidelines for bubbling fluidized-bed combustors. Final report

    SciTech Connect (OSTI)

    Lyczkowski, R.W.; Podolski, W.F.; Bouillard, J.X.; Folga, S.M. [Argonne National Lab., IL (United States)

    1992-11-01T23:59:59.000Z

    These metal wastage design guidelines identify relationships between metal wastage and (1) design parameters (such as tube size, tube spacing and pitch, tube bundle and fluidized-bed height to distributor, and heat exchanger tube material properties) and (2) operating parameters (such as fluidizing velocity, particle size, particle hardness, and angularity). The guidelines are of both a quantitative and qualitative nature. Simplified mechanistic models are described, which account for the essential hydrodynamics and metal wastage processes occurring in bubbling fluidized beds. The empirical correlational approach complements the use of these models in the development of these design guidelines. Data used for model and guideline validation are summarized and referenced. Sample calculations and recommended design procedures are included. The influences of dependent variables on metal wastage, such as solids velocity, bubble size, and in-bed pressure fluctuations, are discussed.

  13. FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE

    E-Print Network [OSTI]

    M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

    A fluidized bed combustion unit has been designed and installed to study the fluidized bed combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm inside diameter and 130 cm height fitted with a perforated plate air distributor of 611 holes, each of 1

  14. Stability of flows in fluidized beds

    SciTech Connect (OSTI)

    Rajagopal, C.

    1992-01-01T23:59:59.000Z

    In this paper we carry out a systematic linearized stability analysis of the state of uniform fluidization for a fluid infused with granular particles. We carry out an interesting optimization procedure which leads to bounds for certain parameters, within which the state of uniform fluidization is stable. We find that this stability depends critically on the structure of the pressure-like term. (VC)

  15. Continuous austempering fluidized bed furnace. Final report

    SciTech Connect (OSTI)

    Srinivasan, M.N. [Lamar Univ., Beaumont, TX (United States). Dept. of Mechanical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Mechanical Engineering

    1997-09-23T23:59:59.000Z

    The intended objective of this project was to show the benefits of using a fluidized bed furnace for austenitizing and austempering of steel castings in a continuous manner. The division of responsibilities was as follows: (1) design of the fluidized bed furnace--Kemp Development Corporation; (2) fabrication of the fluidized bed furnace--Quality Electric Steel, Inc.; (3) procedure for austempering of steel castings, analysis of the results after austempering--Texas A and M University (Texas Engineering Experiment Station). The Department of Energy provided funding to Texas A and M University and Kemp Development Corporation. The responsibility of Quality Electric Steel was to fabricate the fluidized bed, make test castings and perform austempering of the steel castings in the fluidized bed, at their own expense. The project goals had to be reviewed several times due to financial constraints and technical difficulties encountered during the course of the project. The modifications made and the associated events are listed in chronological order.

  16. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01T23:59:59.000Z

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  17. Development of a lidar polarimeter technique of measuring suspended solids in water

    E-Print Network [OSTI]

    Presley, David W

    1980-01-01T23:59:59.000Z

    of depolarization would indicate the relative concentration of scattering particles. The laboratory measurements supported the hypothesis and established the potential of measuri ng suspended solids, turbi dity and transmi ssi vi ty using a lidar polarimeter...

  18. Fluidic, Solid-State, and Hybrid Reconfiguration Techniques in a Frequency and Polarization Reconfigurable Antenna

    E-Print Network [OSTI]

    Barrera, Joel Daniel

    2014-12-16T23:59:59.000Z

    antenna structure. The fluidic mechanisms use high strength dielectric fluids or liquid metal loaded across the gap discontinuities and the solid-state mechanisms uses readily available RF PIN and varactor diodes integrated across the gaps to enable...

  19. Fluidic, Solid-State, and Hybrid Reconfiguration Techniques in a Frequency and Polarization Reconfigurable Antenna 

    E-Print Network [OSTI]

    Barrera, Joel Daniel

    2014-12-16T23:59:59.000Z

    antenna structure. The fluidic mechanisms use high strength dielectric fluids or liquid metal loaded across the gap discontinuities and the solid-state mechanisms uses readily available RF PIN and varactor diodes integrated across the gaps to enable...

  20. Syngas combustor for fluidized bed applications

    SciTech Connect (OSTI)

    Brushwood, J.

    1999-07-01T23:59:59.000Z

    The Siemens Westinghouse Multi-Annular Swirl Burner (MASB) is a rich-quench-lean gas turbine combustor for use primarily on synthetic fuel gases made by gasifying solid fuels (coal or biomass). These fuels contain high amounts of fuel bound nitrogen, primarily as ammonia, which are converted to molecular nitrogen rather than to nitrogen oxides in the rich zone of this combustor. The combustor can operate in many modes. In second-generation pressurized fluidized bed combustion (PFBC) applications, the fuel gas is burned in a hot, depleted oxygen air stream generated in a fluid bed coal combustor. In 1-1/2 generation PFBC applications, natural gas is burned in this vitiated air stream. In an integrated gasification combined cycle (IGCC) application, the synthetic fuel gas is burned in turbine compressor air. In this paper, the MASB technology is described. Recent results of tests at the University of Tennessee Space Institute (UTSI) for these various operation modes on a full scale basket are summarized. The start-up and simple cycle operating experience on propane at the Wilsonville Power Systems Development Facility (PSDF) are also described. In addition, the design issues related to the integration of the MASB in the City of Lakeland PCFB Clean Coal Demonstration Project is summarized.

  1. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tingwen; Dietiker, Jean-Francois; Shahnam, Mehrdad

    2012-12-01T23:59:59.000Z

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numerical results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.

  2. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tingwen; Dietiker, Jean-Francois; Shahnam, Mehrdad

    2012-12-01T23:59:59.000Z

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numericalmore »results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.« less

  3. Attrition resistant fluidizable reforming catalyst

    DOE Patents [OSTI]

    Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

    2011-03-29T23:59:59.000Z

    A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

  4. Pulse atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this reporting period, a total of eight shakedown and debugging coal combustion tests were performed in the AFBC. A start-up procedure was established, system improvements implemented, and preliminary material and heat balances made based on these tests. The pulse combustor for the AFBC system was fabricated and installed and a series of tests was conducted on the system. 17 figs., 5 tabs.

  5. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H. (Mt. Lebanon, PA)

    1984-01-01T23:59:59.000Z

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  6. Flow Regime Study in a High Density Circulating Fluidized Bed Riser with an Abrupt Exit

    SciTech Connect (OSTI)

    Mei, J.S.; Shadle, L.J.; Yue, P.C.; Monazam, E.R. (REM Engineering Services)

    2007-01-01T23:59:59.000Z

    Flow regime study was conducted in a 0.3 m diameter, 15.5 m height circulating fluidized bed (CFB) riser with an abrupt exit at the National Energy Technology Laboratory of the U.S. Department of Energy. Local particle velocities were measured at various radial positions and riser heights using an optical fiber probe. On-line measurement of solid circulating rate was continuously recorded by the Spiral. Glass beads of mean diameter 61 ?m and particle density of 2,500 kg/m3 were used as bed material. The CFB riser was operated at various superficial gas velocities ranging from 3 to 7.6 m/s and solid mass flux from 20 to 550 kg/m2-s. At a constant riser gas velocity, transition from fast fluidization to dense suspension upflow (DSU) regime started at the bottom of the riser with increasing solid flux. Except at comparatively low riser gas velocity and solid flux, the apparent solid holdup at the top exit region was higher than the middle section of the riser. The solid fraction at this top region could be much higher than 7% under high riser gas velocity and solid mass flux. The local particle velocity showed downward flow near the wall at the top of the riser due to its abrupt exit. This abrupt geometry reflected the solids and, therefore, caused solid particles traveling downward along the wall. However, at location below, but near, the top of the riser the local particle velocities were observed flowing upward at the wall. Therefore, DSU was identified in the upper region of the riser with an abrupt exit while the fully developed region, lower in the riser, was still exhibiting core-annular flow structure. Our data were compared with the flow regime boundaries proposed by Kim et al. [1] for distinguishing the dilute pneumatic transport, fast fluidization, and DSU.

  7. Circulating Fluidized Bed Combustion Boiler Project

    E-Print Network [OSTI]

    Farbstein, S. B.; Moreland, T.

    1984-01-01T23:59:59.000Z

    The project to build a PYROFLOW circulating fluidized bed combustion (FBC) boiler at the BFGoodrich Chemical Plant at Henry, Illinois, is described. This project is being partially funded by Illinois to demonstrate the feasibility of utilizing high...

  8. Particle withdrawal from fluidized bed systems

    DOE Patents [OSTI]

    Salvador, Louis A. (Greensburg, PA); Andermann, Ronald E. (Arlington Heights, IL); Rath, Lawrence K. (Mt. Pleasant, PA)

    1982-01-01T23:59:59.000Z

    Method and apparatus for removing ash formed within, and accumulated at the lower portion of, a fluidized bed coal gasification reactor vessel. A supplemental fluidizing gas, at a temperature substantially less than the average fluidized bed combustion operating temperature, is injected into the vessel and upwardly through the ash so as to form a discrete thermal interface region between the fluidized bed and the ash. The elevation of the interface region, which rises with ash accumulation, is monitored by a thermocouple and interrelated with a motor controlled outlet valve. When the interface rises above the temperature indicator, the valve opens to allow removal of some of the ash, and the valve is closed, or positioned at a minimum setting, when the interface drops to an elevation below that of the thermocouple.

  9. Coal-Fired Fluidized Bed Combustion Cogeneration

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    COAL-FIRED FLUIDIZED BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed... combustion, has encouraged many steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However...

  10. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06T23:59:59.000Z

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  11. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-11-01T23:59:59.000Z

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  12. Automatic control of air to fuel ratio in a fluidized bed gasifier 

    E-Print Network [OSTI]

    Ling, Peter P.

    1984-01-01T23:59:59.000Z

    ) gas through fluidized bed gasification is under study by individuals in the Agricultural Engineering Department of Texas A&N University. The basic goal of this project is to convert solid organic material into a combustible gas and then use the gas... of the ASAE (American society of Agricultural Engineers). Desrosors (1981) showed the importance of A/F ratio control in his wood gasification study. He pointed out that the composition and chemical energy of the final output gas is greatly affected...

  13. Performance simulation of fluidized-bed coal combustors

    SciTech Connect (OSTI)

    Chandran, R.R.; Sutherland, D.D. (The Babcock and Wilcox Co., R and D Div., Alliance, OH (US))

    1988-06-01T23:59:59.000Z

    A code, referred to as FBCSIM, is being developed to predict large-scale atmospheric fluidized-bed combustor (AFBC) performance with fundamental fuel data from bench-scale test units as input. This work is carried out as a part of AFBC fuels characterization program sponsored by the Electric Power Research Institute (EPRI). The code accounts for the physics of fluidization, which is unit specific, and the chemistry of combustion, which is fuel specific. The code includes a 3-D model and modules on bed hydrodynamics, chemical kinetics, solid distribution, and transport phenomena. The model for in-bed combustion incorporates a two-region particle mixing formulation. The code for in-bed combustion has been validated for different AFBC unit sizes (0.1, 2, and 20 MW) and different coals (two bituminous and a lignite). Sensitivity analyses have been carried out to identify the controlling variables and guide experimental work. Computer simulations have also been performed to delineate system response to operational parameters.

  14. Performance simulation of fluidized-bed coal combustors

    SciTech Connect (OSTI)

    Chandran, R.R.; Sutherland, D.D. (Babcock Wilcox Company, Alliance, OH (USA))

    1988-01-01T23:59:59.000Z

    A code, referred to as FBCSIM, is being developed to predict large-scale atmospheric fluidized-bed combustor (AFBC) performance with fundamental fuel data from bench-scale test units as input. This work is carried out as a part of AFBC fuels characterization program sponsored by the Electric Power Research Institute (EPRI). The code accounts for the physics of fluidization, which is unit specific, and the chemistry of combustion, which is fuel specific. The code includes a 3-D model and modules on bed hydrodynamics, chemical kinetics, solid distribution, and transport phenomena. The model for in-bed combustion incorporates a two-region particle mixing formulation. The code for in-bed combustion has been validated for different AFBC unit sizes (0.1, 2, and 20 MW) and different coals (two bituminous and a lignite). Sensitivity analyses have been carried out to identify the controlling variables and guide experimental work. Computer simulations have also been performed to delineate system response to operational parameters.

  15. Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors

    SciTech Connect (OSTI)

    Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

    1980-09-01T23:59:59.000Z

    The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

  16. Comparison study of solid/liquid separation techniques for oilfield pit closures

    SciTech Connect (OSTI)

    Wojtanowicz, A.K.; Field, S.D.; Osterman, M.C.

    1987-07-01T23:59:59.000Z

    Vacuum filtration, belt-press filtration, screw-press filtration, and centrifuging techniques were evaluated in full-scale experiments for use in oilfield waste volume reduction. Centrifuging and belt-press filtration proved applicable to oilfield pit cleanups. Also, an effective chemical conditioning (coagulation and flocculation) was found for deliquoring seven types of oilfield waste slurries before separation.

  17. Computational Fluid Dynamics Simulation of Fluidized Bed Polymerization Reactors

    SciTech Connect (OSTI)

    Rong Fan

    2006-08-09T23:59:59.000Z

    Fluidized beds (FB) reactors are widely used in the polymerization industry due to their superior heat- and mass-transfer characteristics. Nevertheless, problems associated with local overheating of polymer particles and excessive agglomeration leading to FB reactors defluidization still persist and limit the range of operating temperatures that can be safely achieved in plant-scale reactors. Many people have been worked on the modeling of FB polymerization reactors, and quite a few models are available in the open literature, such as the well-mixed model developed by McAuley, Talbot, and Harris (1994), the constant bubble size model (Choi and Ray, 1985) and the heterogeneous three phase model (Fernandes and Lona, 2002). Most these research works focus on the kinetic aspects, but from industrial viewpoint, the behavior of FB reactors should be modeled by considering the particle and fluid dynamics in the reactor. Computational fluid dynamics (CFD) is a powerful tool for understanding the effect of fluid dynamics on chemical reactor performance. For single-phase flows, CFD models for turbulent reacting flows are now well understood and routinely applied to investigate complex flows with detailed chemistry. For multiphase flows, the state-of-the-art in CFD models is changing rapidly and it is now possible to predict reasonably well the flow characteristics of gas-solid FB reactors with mono-dispersed, non-cohesive solids. This thesis is organized into seven chapters. In Chapter 2, an overview of fluidized bed polymerization reactors is given, and a simplified two-site kinetic mechanism are discussed. Some basic theories used in our work are given in detail in Chapter 3. First, the governing equations and other constitutive equations for the multi-fluid model are summarized, and the kinetic theory for describing the solid stress tensor is discussed. The detailed derivation of DQMOM for the population balance equation is given as the second section. In this section, monovariate population balance, bivariate population balance, aggregation and breakage equation and DQMOM-Multi-Fluid model are described. In the last section of Chapter 3, numerical methods involved in the multi-fluid model and time-splitting method are presented. Chapter 4 is based on a paper about application of DQMOM to polydisperse gas-solid fluidized beds. Results for a constant aggregation and breakage kernel and a kernel developed from kinetic theory are shown. The effect of the aggregation success factor and the fragment distribution function are investigated. Chapter 5 shows the work on validation of mixing and segregation phenomena in gas-solid fluidized beds with a binary mixture or a continuous size distribution. The simulation results are compared with available experiment data and discrete-particle simulation. Chapter 6 presents the project with Univation Technologies on CFD simulation of a Polyethylene pilot-scale FB reactor, The fluid dynamics, mass/heat transfer and particle size distribution are investigated through CFD simulation and validated with available experimental data. The conclusions of this study and future work are discussed in Chapter 7.

  18. Waste Heat Recovery in Cement Plants By Fluidized Beds

    E-Print Network [OSTI]

    Fraley, L. D.; Ksiao, H. K.; Thunem, C. B.

    1984-01-01T23:59:59.000Z

    the alkali bypass gas stream with a specially designed fluidized bed cooler. The heat recovery tubes are kept clean by the scrubbing action of the fluidized bed. A circulating fluidized bed combustor utilizes hot air from the clinker cooler as preheated... combustion air. Air from the clinker cooler which is in excess of the combustion air required for the circulating fluidized bed, is used for preheating of boiler feedwater. A conventional economizer located in the gas stream is used for this service...

  19. Design and operation of a coal-washery sludge fired 75 t/h steam fluidized bed combustion boiler

    SciTech Connect (OSTI)

    Jiang, X.; Chi, Y.; Yan, J. [and others

    1999-07-01T23:59:59.000Z

    Based upon the coal-washery sludge fluidized bed agglomerating combustion technology developed by Zhejiang University and the design and operation experience accumulated from the 35 t/h stream fluidized bed boilers, a coal-washery sludge fired 75 t/h steam circulating fluidized bed boiler (12 MWe) for cogeneration application was designed. The design features of the boiler can be summarized as follows: (1) Combination of solid particle impact separator (in furnace circulation) and moderate temperature ({approximately}500 C) uniflow cyclone; (2) Low solid circulation rate; (3) Loop-seal for solid particle recirculation; (4) Air duct oil burner for boiler start-up; and (5) Coal-Washery sludge firing or co-firing of coal-washery sludge and coal. The boiler is installed at Dongtan Coal Mine Cogeneration Plant in Shandong Province of China. The daily disposal capacity of coal-washery sludge is over 300 tons. The first trial operation of the boiler was on Dec. 18, 1997. The cogeneration plant has been in commercial operation since May 1998. This boiler is the largest capacity boiler to dispose of coal-washery sludge in China. The successful operation of this boiler has sped up the commercialization process of the coal-washery sludge fluidized bed combustion technology.

  20. Advanced atmospheric fluidized-bed combustion design: the staged cascading fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1985-04-05T23:59:59.000Z

    Better fuel utilization is achieved in the SCFBC, which achieves a carbon burnout of 97.1% versus 95.0% for the AFBC. The SCFBC advantage is due to the staging of combustion in two beds. The thermal efficiency of the SCFBC is higher than that of the AFBC (85.4% versus 81.65%) due to two factors. First, the better fuel efficiency mentioned above contributes to this advantage. Second, the spent solids leaving the lowest combustion stage of the SCFBC are cooled by the incoming air, reducing heat loss with the spent solids. The SCFBC accomplishes the specified SO/sub 2/ removal with a significantly reduced amount of limestone adsorbent. The SCFBC achieved a sulfur capture efficiency of 81.6% with a calcium to sulfur ratio of 2.05, while the AFBC capture efficiency was 90% with a calcium to sulfur ratio of 3.5. The SCFBC has several other technical advantages over the AFBC. Stages of combustion air in the SCFBC can reduce NOx emissions to one-half to one-third of that achievable with the AFBC. The SCFBC achieves a higher volumetric heat release than the conventional AFBC by a factor of three to one. The SCFBC can achieve higher turndown ratios than the AFBC by changing fluidized bed depths to tailor heat transfer rates to the turned down condition. Turndown ratios of 7 to 1 are possible with the SCFBC compared with a ratio of 3 to 1 achievable in a single bed conventional AFBC. The capitol cost of the SCFBC is 24.0% lower than that of the AFBC and the annual operating cost is 7.4% lower.

  1. Mixing and combustion in a coal-limestone fluidized bed combustor

    SciTech Connect (OSTI)

    Kirkpatrick, M.O.

    1987-01-01T23:59:59.000Z

    Task 1 was to investigate experimentally the characteristics of solids mixing between coal and limestone in a cold fluidized bed; Task 2 was to derive a model to describe the behavior of solids mixing observed in Task 1; and Task 3 was to develop a combustor model, which couples the mixing model derived in Task 2 with a combustion model, to simulate the mixing and combustion behavior in a hot coal-limestone fluidized bed combustor. In Task 1, the experiments were carried out in a 0.203 m diameter cold fluidized bed with coal and limestone of different sizes the the fluidized particles. Experimental parameters examined included operation time, air flow rate, bed height, initial bed setup, relative particle size and relative amount of the two particles. In the second task, the mixing model considered the downward or upward movement of a particle in the bed as being governed by certain probability laws; these laws were, in turn, affected by the bubbles. The distance of the upward movement was governed by the residence time of a particle staying in a bubble wake; the distance of downward movement, however, was determined from a material balance consideration. In all, the model took into account the effects of time, flow rate, initial bed setup and relative particle size on solids mixing. Dynamic coal concentration profiles under different operating conditions were generated by the simulation and were found to represent the experimental data reasonably well. In addition to the operation parameters included in Tasks 1 and 2, the model developed in Task 3 also considered the inlet size distribution of coal, size reduction of coal due to combustion and coal elutriation. This model was a capable of predicting the dynamic mixing and combustion behavior in a combustor under specific operation conditions.

  2. Innovative Coal Solids-Flow Monitoring and Measurement Using Phase-Doppler and Mie Scattering Techniques

    SciTech Connect (OSTI)

    Stephen Seong Lee

    2010-01-19T23:59:59.000Z

    Fuel flow to individual burners is complicated and difficult to determine on coal fired boilers, since coal solids were transported in a gas suspension that is governed by the complex physics of two-phase flow. The objectives of the project were the measurements of suspended coal solids-flows in the simulated test conditions. Various extractive methods were performed manually and can give only a snapshot result of fuel distribution. In order to measure particle diameter & velocity, laser based phase-Doppler particle analyzer (PDPA) and particle image velocimetry (PIV) were carefully applied. Statistical methods were used to analyze particle characteristics to see which factors have significant effect. The transparent duct model was carefully designed and fabricated for the laser-based-instrumentation of solids-flow monitoring (LISM). The experiments were conducted with two different kinds of particles with four different particle diameters. The particle types were organic particles and saw dust particles with the diameter range of 75-150 micron, 150-250 micron, 250-355 micron and 355-425 micron. The densities of the particles were measured to see how the densities affected the test results. Also the experiment was conducted with humid particles and fog particles. To generate humid particles, the humidifier was used. A pipe was connected to the humidifier to lead the particle flow to the intersection of the laser beam. The test results of the particle diameter indicated that, the mean diameter of humid particles was between 6.1703 microns and 6.6947 microns when the humid particle flow was low. When the humid particle flow was high, the mean diameter was between 6.6728 microns and 7.1872 microns. The test results of the particle mean velocity indicated that the mean velocity was between 1.3394 m/sec and 1.4556 m/sec at low humid particle flow. When the humid particle flow was high, the mean velocity was between 1.5694 m/sec and 1.7856 m/sec. The Air Flow Module, TQ AF 17 and shell ondina oil were used to generate fog particles. After the oil was heated inside the fog generator, the blower was used to generate the fog. The fog flew along the pipe to the intersection of the laser beam. The mean diameter of the fog particles was 5.765 microns. Compared with the humid particle diameter, we observed that the mean diameter of the fog particles was smaller than the humid particles. The test results of particle mean velocity was about 3.76 m/sec. Compared with the mean velocity of the humid particles, we can observed the mean velocity of fog particles were greater than humid particles. The experiments were conducted with four different kinds of particles with five different particle diameters. The particle types were organic particles, coal particles, potato particles and wheat particles with the diameter range of 63-75 micron, less than 150 micron, 150-250 micron, 250-355 micron and 355-425 micron. To control the flow rate, the control gate of the particle dispensing hopper was adjusted to 1/16 open rate, 1/8 open rate and 1/4 open rate. The captured image range was 0 cm to 5 cm from the control gate, 5 cm to 10 cm from the control gate and 10 cm to 15 cm from the control gate. Some of these experiments were conducted under both open environment conditions and closed environment conditions. Thus these experiments had a total of five parameters which were type of particles, diameter of particles, flow rate, observation range, and environment conditions. The coal particles (diameter between 63 and 75 microns) tested under the closed environment condition had three factors that were considered as the affecting factors. They were open rate, observation range, and environment conditions. In this experiment, the interaction of open rate and observation range had a significant effect on the lower limit. On the upper limit, the open rate and environment conditions had a significant effect. In addition, the interaction of open rate and environment conditions had a significant effect. The coal particles tested (diameter between 63 and 75

  3. Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The US DOE pressurized fluidized bed combustion (PFBC) research and development program is designed to develop the technology and data base required for the successful commercialization of the PFBC concept. A cooperative program with the US, West Germany, and the UK has resulted in the construction of the 25 MWe IEA-Grimethorpe combined-cycle pilot plant in England which will be tested in 1981. A 13 MWe coal-fired gas turbine (air cycle) at Curtis-Wright has been designed and construction scheduled. Start-up is planned to begin in early 1983. A 75 MWe pilot plant is planned for completion in 1986. Each of these PFBC combined-cycle programs is discussed. The current status of PFB technology may be summarized as follows: turbine erosion tolerance/hot gas cleanup issues have emerged as the barrier technology issues; promising turbine corrosion-resistant materials have been identified, but long-term exposure data is lacking; first-generation PFB combustor technology development is maturing at the PDU level; however, scale-up to larger size has not been demonstrated; and in-bed heat exchanger materials have been identified, but long-term exposure data is lacking. The DOE-PFB development plan is directed at the resolution of these key technical issues. (LCL)

  4. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

    1992-01-01T23:59:59.000Z

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  5. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15T23:59:59.000Z

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  6. A Study of Vertical Gas Jets in a Bubbling Fluidized Bed

    SciTech Connect (OSTI)

    Steven Ceccio; Jennifer Curtis

    2011-01-18T23:59:59.000Z

    A detailed experimental study of a vertical gas jet impinging a fluidized bed of particles has been conducted with the help of Laser Doppler Velocimetry measurements. Mean and fluctuating velocity profiles of the two phases have been presented and analyzed for different fluidization states of the emulsion. The results of this work would be greatly helpful in understanding the complex two-phase mixing phenomenon that occurs in bubbling beds, such as in coal and biomass gasification, and also in building more fundamental gas-solid Eulerian/Lagrangian models which can be incorporated into existing CFD codes. Relevant simulations to supplement the experimental findings have also been conducted using the Department of Energyâ??s open source code MFIX. The goal of these simulations was two-fold. One was to check the two-dimensional nature of the experimental results. The other was an attempt to improve the existing dense phase Eulerian framework through validation with the experimental results. In particular the sensitivity of existing frictional models in predicting the flow was investigated. The simulation results provide insight on wall-bounded turbulent jets and the effect frictional models have on gas-solid bubbling flows. Additionally, some empirical minimum fluidization correlations were validated for non-spherical particles with the idea of extending the present study to non-spherical particles which are more common in industries.

  7. Agglomeration of sorbent and ash carry-over for use in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.; Kealrns, D.L.; Newby, R.A.; Ulerich, N.H.

    1983-04-01T23:59:59.000Z

    Agglomeration of elutriated sorbent, ash, and char from a fluidized-bed boiler, with spent bed overflow material and water, has been identified as a potentially attractive technique for reducing sorbent consumption in atmospheric fluidized-bed combustors (AFBC). The agglomerated products are returned to the combustor to improv the calcium utilization of the sorbent and to complete the combustion of elutriated carbon material. In this experimental program, agglomerates were formed from Babcock and Wilcox (BandW) raw materials (Carbon limestone, spent bed overflow, cyclone and baghouse catch) collected during test runs on the 1.8 m X 1.8 m fluidized-bed combustor. Agglomerate characteristics, such as handling strength, sulfur capture activity, carbon utilization, and resistance to attrition, were determined as functions of agglomeration processing variables. These variables include feed composition, feed particle size, amount of water addition, curing time, and curing atmosphere or drying conditions. Calcium-to-sulfur (Ca/S) feed ratio requirements for a commercial AFBC that uses the agglomeration process were projected on the basis of the Westinghouse model for fluidized-bed desulfurization.

  8. Multistage fluidized bed reactor performance characterization for adsorption of carbon dioxide

    SciTech Connect (OSTI)

    Roy, S.; Mohanty, C.R.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-12-15T23:59:59.000Z

    Carbon dioxide and its different compounds are generated as primary greenhouse gases from the flue gases of coal-fired thermal power plants, boilers, and other stationary combustion processes. This greenhouse gas causes global warming after being emitted to the environment. To deal with this problem, a new dry scrubbing process was tested in this study. A three-stage countercurrent fluidized bed adsorber was developed, designed, and fabricated. It was used as a removal apparatus and operated in a continuous regime for the two-phase system. The height of each stage was 0.30 m, and the inner diameter was 0.10 m. The paper presents the removal of CO{sub 2} from gas mixtures by chemical sorption on porous granular calcium oxide particles in the reactor at ambient temperature. The advantages of a multistage fluidized bed reactor for high mass transfer and high gas-solid contact can enhance the removal of the gas when using a dry method. The effects of the operating parameters such as sorbent, superficial gas velocity, and the Weir height on CO{sub 2} removal efficiency in the multistage fluidized bed were investigated. The results indicate that the removal efficiency of the carbon dioxide was around 71% at a high solid flow rate corresponding to lower gas velocity at room temperature. In comparison with wet scrubbers, this dry process appears to have lower cost, less complicated configuration, and simpler disposal of used sorbent. The results in this study assume importance from the perspective of use of a multistage fluidized bed adsorber for control of gaseous pollutants at high temperature.

  9. Fluidized bed electrowinning of copper. Final report

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    The objectives of the study were to: design and construct a 10,000- amp fluidized bed electrowinning cell for the recovery of copper from acidic sulfate solutions; demonstrate the technical feasibility of continuous particle recirculation from the electrowinning cell with the ultimate goal of continuous particle removal; and measure cell efficiency as a function of operating conditions.

  10. Particle Pressures in Fluidized Beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01T23:59:59.000Z

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction): they impart to the bed. So rather than directly measure the particle pressure, we inferred the values of the elasticity from measurements of instability growth in liquid beds the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined)and then working backwards to determine the unknown coefficients, including the elasticity.

  11. Particle pressures in fluidized beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01T23:59:59.000Z

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction), they impart to the bed. So rather than directly measure the particle pressure, the authors inferred the values of the elasticity from measurements of instability growth in liquid beds; the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined) and then working backwards to determine the unknown coefficients, including the elasticity.

  12. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  13. Bed material agglomeration during fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Smeenk, J.L.

    1996-01-01T23:59:59.000Z

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion of coal and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed combustors (FBCs) indicate that at least five boilers were experiencing some form of bed material agglomeration. Deposit formation was reported at nine sites with deposits most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Three general types of mineralogic reactions were observed to occur in the agglomerates and deposits. Although alkalies may play a role with some {open_quotes}high alkali{close_quotes} lignites, we found agglomeration was initiated due to fluxing reactions between iron (II) from pyrites and aluminosilicates from clays. This is indicated by the high amounts of iron, silica, and alumina in the agglomerates and the mineralogy of the agglomerates. Agglomeration likely originated in the dense phase of the FBC bed within the volatile plume which forms when coal is introduced to the boiler. Secondary mineral reactions appear to occur after the agglomerates have formed and tend to strengthen the agglomerates. When calcium is present in high amounts, most of the minerals in the resulting deposits are in the melilite group (gehlenite, melilite, and akermanite) and pyroxene group (diopside and augite). During these solid-phase reactions, the temperature of formation of the melilite minerals can be lowered by a reduction of the partial pressure of CO{sub 2} (Diopside + Calcite {r_arrow}Akermanite).

  14. Apparatus for high flux photocatalytic pollution control using a rotating fluidized bed reactor

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2003-06-24T23:59:59.000Z

    An apparatus based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. An apparatus for high-flux photocatalytic pollution control is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

  15. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

    1983-12-20T23:59:59.000Z

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  16. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01T23:59:59.000Z

    bed, Chemical Engineering Research and Design, Volume 90,Design of a Dual Fluidized Bed Reactor by Minyoung Yun Master of Science, Graduate Program in Chemical and Environmental Engineering

  17. Fluidized Bed Technology - An R&D Success Story | Department...

    Energy Savers [EERE]

    product line. The Nucla fluidized bed power plant in Colorado was operated in DOE's Clean Coal Technology Program. The technology progressed into larger scale utility applications...

  18. Alexandria fluidized-bed process development unit: cold-mode testing

    SciTech Connect (OSTI)

    None

    1981-02-01T23:59:59.000Z

    The objectives of the current test program include: validation of predictions from the Massachusetts Institute of Technology (MIT) Coal Atmospheric Fluidized Bed Combustor System Model; experimental studies supporting AFBC process developments; and the collection of transient data for process control design. This topical report summarizes results from cold mode testing, i.e., experiments performed without combustion for MIT Model verification. During these tests, sulfated limestone (generated from normal AFBC operations) was fluidized with air at temperatures ranging from 80 to 500/sup 0/F in the 3' x 3' (nominal) size PDU at Alexandria, VA. The MIT Model predictions tested include: slumped bed height, minimum fluidization velocity, and expanded bed height. In all cases, there were large discrepancies between the Model predictions and corresponding experimental results. Other results obtained included solids size distribution and particle size profiles in the bed. Size distribution was adequately modeled by the Rosin-Rammler equation. No transient process data was collected due to hardware problems with the Data Acquisition System. Tests were also performed to determine the effect of maldistribution of air, caused by leaks in the air distributor, on experimental results. The data indicated that effects of these leaks seemed to be undetectable.

  19. Flow Mapping in a Gas-Solid Riser via Computer Automated Radioactive Particle Tracking (CARPT)

    SciTech Connect (OSTI)

    Muthanna Al-Dahhan; Milorad P. Dudukovic; Satish Bhusarapu; Timothy J. O'hern; Steven Trujillo; Michael R. Prairie

    2005-06-04T23:59:59.000Z

    Statement of the Problem: Developing and disseminating a general and experimentally validated model for turbulent multiphase fluid dynamics suitable for engineering design purposes in industrial scale applications of riser reactors and pneumatic conveying, require collecting reliable data on solids trajectories, velocities ? averaged and instantaneous, solids holdup distribution and solids fluxes in the riser as a function of operating conditions. Such data are currently not available on the same system. Multiphase Fluid Dynamics Research Consortium (MFDRC) was established to address these issues on a chosen example of circulating fluidized bed (CFB) reactor, which is widely used in petroleum and chemical industry including coal combustion. This project addresses the problem of lacking reliable data to advance CFB technology. Project Objectives: The objective of this project is to advance the understanding of the solids flow pattern and mixing in a well-developed flow region of a gas-solid riser, operated at different gas flow rates and solids loading using the state-of-the-art non-intrusive measurements. This work creates an insight and reliable database for local solids fluid-dynamic quantities in a pilot-plant scale CFB, which can then be used to validate/develop phenomenological models for the riser. This study also attempts to provide benchmark data for validation of Computational Fluid Dynamic (CFD) codes and their current closures. Technical Approach: Non-Invasive Computer Automated Radioactive Particle Tracking (CARPT) technique provides complete Eulerian solids flow field (time average velocity map and various turbulence parameters such as the Reynolds stresses, turbulent kinetic energy, and eddy diffusivities). It also gives directly the Lagrangian information of solids flow and yields the true solids residence time distribution (RTD). Another radiation based technique, Computed Tomography (CT) yields detailed time averaged local holdup profiles at various planes. Together, these two techniques can provide the needed local solids flow dynamic information for the same setup under identical operating conditions, and the data obtained can be used as a benchmark for development, and refinement of the appropriate riser models. For the above reasons these two techniques were implemented in this study on a fully developed section of the riser. To derive the global mixing information in the riser, accurate solids RTD is needed and was obtained by monitoring the entry and exit of a single radioactive tracer. Other global parameters such as Cycle Time Distribution (CTD), overall solids holdup in the riser, solids recycle percentage at the bottom section of the riser were evaluated from different solids travel time distributions. Besides, to measure accurately and in-situ the overall solids mass flux, a novel method was applied.

  20. Fluidized bed gasification of agricultural residue 

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    is the only energy derived from such a system. The biomass energy project, of' which this re- search into gasification is a part, was designed to investi- gate both combustion and gasification as means to recover energy from agricultural wastes...FLUIDIZED BED GASIFICATION OF AGRICULTURAL RESIDUES A Thesis by JOHN DAVID GROVES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1979 Major...

  1. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26T23:59:59.000Z

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  2. Cluster Dynamics in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Guenther, C.P.; Breault, R.W.

    2006-11-01T23:59:59.000Z

    A common hydrodynamic feature in industrial scale circulating fluidized beds is the presence of clusters. The continuous formation and destruction of clusters strongly influences particle hold-up, pressure drop, heat transfer at the wall, and mixing. In this paper fiber optic data is analyzed using discrete wavelet analysis to characterize the dynamic behavior of clusters. Five radial positions at three different axial locations under five different operating were analyzed using discrete wavelets. Results are summarized with respect to cluster size and frequency.

  3. NUCLA Circulating Atmospheric Fluidized Bed Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    The objective of this DOE Cooperative Agreement is to conduct a cost-shared clean coal technology project to demonstrate the feasibility of circulating fluidized bed combustion technology and to evaluate economic, environmental, and operational benefits of CFB steam generators on a utility scale. At the conclusion of the Phase 2 program, testing related to satisfying these objectives was completed. Data analysis and reporting are scheduled for completion by October 1991. (VC)

  4. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01T23:59:59.000Z

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  5. Status of the fluidized bed unit

    SciTech Connect (OSTI)

    Williams, P.M.; Wade, J.F.

    1994-06-01T23:59:59.000Z

    Rocky Flats has a serious mixed waste problem. No technology or company has a license and available facilities to remedy this dilemma. One solution under study is to use a catalytic fluidized bed unit to destroy the combustible portion of the mixed waste. The fluidized bed thermal treatment program at Rocky Flats is building on knowledge gained over twenty years of successful development activity. The FBU has numerous technical advantages over other thermal technologies to treat Rocky Flats` mixed waste, the largest being the lower temperature (700{degrees}C versus 1000{degrees}C) which reduces acid corrosion and mechanical failures and obviates the need for ceramic lining. Successful demonstrations have taken place on bench, pilot, and full-scale tests using radioactive mixed wastes. The program is approaching implementation and licensing of a production-scale fluidized bed system for the safe treatment of mixed waste. The measure for success on this project is the ability to work closely with the community to jointly solve problems and respond to concerns of mixed waste treatment at Rocky Flats.

  6. Heat exchanger support apparatus in a fluidized bed

    DOE Patents [OSTI]

    Lawton, Carl W. (West Hartford, CT)

    1982-01-01T23:59:59.000Z

    A heat exchanger is mounted in the upper portion of a fluidized combusting bed for the control of the temperature of the bed. A support, made up of tubes, is extended from the perforated plate of the fluidized bed up to the heat exchanger. The tubular support framework for the heat exchanger has liquid circulated therethrough to prevent deterioration of the support.

  7. Pressure Fluctuations as a Diagnostic Tool for Fluidized Beds

    SciTech Connect (OSTI)

    Ethan Bure; Joel R. Schroeder; Ramon De La Cruz; Robert C. Brown

    1998-05-01T23:59:59.000Z

    The purpose of this project was to investigate the origin of pressure fluctuations in fluidized bed systems. The study assessed the potential for using pressure fluctuations as an indicator of fluidized bed hydrodynamics in both laboratory scale cold-models and industrial scale boilers. Both bubbling fluidized beds and circulating fluidized beds were evaluated. Testing including both cold-flow models and laboratory and industrial-scale combustors operating at elevated temperatures. The study yielded several conclusions on the relationship of pressure fluctuations and hydrodynamic behavior in fluidized beds. The study revealed the importance of collecting sufficiently long data sets to capture low frequency (on the order of 1 Hz) pressure phenomena in fluidized beds. Past research has tended toward truncated data sets collected with high frequency response transducers, which miss much of the spectral structure of fluidized bed hydrodynamics. As a result, many previous studies have drawn conclusions concerning hydrodynamic similitude between model and prototype fluidized beds that is insupportable from the low resolution data presented.

  8. Development and Implementation of 3-D, High Speed Capacitance Tomography for Imaging Large-Scale, Cold-Flow Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Qussai Marashdeh

    2012-09-30T23:59:59.000Z

    A detailed understanding of multiphase flow behavior inside a Circulating Fluidized Bed (CFB) requires a 3-D technique capable of visualizing the flow field in real-time. Electrical Capacitance Volume Tomography (ECVT) is a newly developed technique that can provide such measurements. The attractiveness of the technique is in its low profile sensors, fast imaging speed and scalability to different section sizes, low operating cost, and safety. Moreover, the flexibility of ECVT sensors enable them to be designed around virtually any geometry, rendering them suitable to be used for measurement of solid flows in exit regions of the CFB. Tech4Imaging LLC has worked under contract with the U.S. Department of Energyâ??s National Energy Technology Laboratory (DOE NETL) to develop an ECVT system for cold flow visualization and install it on a 12 inch ID circulating fluidized bed. The objective of this project was to help advance multi-phase flow science through implementation of an ECVT system on a cold flow model at DOE NETL. This project has responded to multi-phase community and industry needs of developing a tool that can be used to develop flow models, validate computational fluid dynamics simulations, provide detailed real-time feedback of process variables, and provide a comprehensive understating of multi-phase flow behavior. In this project, a complete ECVT system was successfully developed after considering different potential electronics and sensor designs. The system was tested at various flow conditions and with different materials, yielding real-time images of flow interaction in a gas-solid flow system. The system was installed on a 12 inch ID CFB of the US Department of Energy, Morgantown Labs. Technical and economic assessment of Scale-up and Commercialization of ECVT was also conducted. Experiments conducted with larger sensors in conditions similar to industrial settings are very promising. ECVT has also the potential to be developed for imaging multi-phase flow systems in high temperature and high pressure conditions, typical in many industrial applications.

  9. Results obtained by both techniques show a good correlation (three maxima are observed) and thus provide a study of cement microstructure

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    , Fabbri A, Azouni A. Cold Regions Science and Technology, Accepted in 2006. doi:10.1016/j.mri.2007.01.071 NMR measurement of gas-phase dynamics in a gas-fluidized particle bed using laser-polarized xenon NMR, Harvard University, USA Gas fluidization is a process in which solid particles experience fluid

  10. Pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    NONE

    1998-03-01T23:59:59.000Z

    ThermoChem, under contract to the Department of Energy, conducted extensive research, development and demonstration work on a Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) to confirm that advanced technology can meet these performance objectives. The ThermoChem/MTCI PAFBC system integrates a pulse combustor with an atmospheric bubbling-bed type fluidized bed combustor (BFBC) In this modular configuration, the pulse combustor burns the fuel fines (typically less than 30 sieve or 600 microns) and the fluidized bed combusts the coarse fuel particles. Since the ThermoChem/MTCI PAFBC employs both the pulse combustor and the AFBC technologies, it can handle the full-size range of coarse and fines. The oscillating flow field in the pulse combustor provides for high interphase and intraparticle mass transfer rates. Therefore, the fuel fines essentially burn under kinetic control. Due to the reasonably high temperature (>1093 C but less than the temperature for ash fusion to prevent slagging), combustion of fuel fines is substantially complete at the exit of the pulse combustor. The additional residence time of 1 to 2 seconds in the freeboard of the PAFBC unit then ensures high carbon conversion and, in turn, high combustion efficiency. A laboratory unit was successfully designed, constructed and tested for over 600 hours to confirm that the PAFBC technology could meet the performance objectives. Subsequently, a 50,000 lb/hr PAFBC demonstration steam boiler was designed, constructed and tested at Clemson University in Clemson, South Carolina. This Final Report presents the detailed results of this extensive and successful PAFBC research, development and demonstration project.

  11. Second-generation pressurized fluidized bed combustion

    SciTech Connect (OSTI)

    Wolowodiuk, W.; Robertson, A.

    1992-05-01T23:59:59.000Z

    Under the sponsorship of the United States Department of Energy, Foster Wheeler Corporation is developing second-generation pressurized fluidized bed combustion (PFBC) power plant technology that will enable this type of plant to operate with net plant efficiencies in the range of 43 to 46 percent (based on the higher heating value of the coal), with a reduction in the cost of electricity of at least 20 percent. A three-phase program is under way. Its scope encompasses the conceptual design of a commercial plant through the process of gathering needed experimental test data to obtain design parameters.

  12. Second-generation pressurized fluidized bed combustion

    SciTech Connect (OSTI)

    Wolowodiuk, W.; Robertson, A.

    1992-01-01T23:59:59.000Z

    Under the sponsorship of the United States Department of Energy, Foster Wheeler Corporation is developing second-generation pressurized fluidized bed combustion (PFBC) power plant technology that will enable this type of plant to operate with net plant efficiencies in the range of 43 to 46 percent (based on the higher heating value of the coal), with a reduction in the cost of electricity of at least 20 percent. A three-phase program is under way. Its scope encompasses the conceptual design of a commercial plant through the process of gathering needed experimental test data to obtain design parameters.

  13. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  14. Fluidized bed boiler convective zone tube replacement

    SciTech Connect (OSTI)

    Not Available

    1991-03-21T23:59:59.000Z

    A major problem with the Georgetown University Atomspheric-Pressure, Fluidized-Bed Combustor-Boiler (GU AFBC) experienced during the first six years of operation was tube erosion. Previous corrective measures for in-bed tube erosion appeared to be effective, but excessive wear of the convective zone tubes was still occurring, and the entire heat transfer tube bundle in the boiler required replacement. In the planned project,the eroded tubes would be replaced, and the convective zone modified to eliminate the problem. Progress is discussed.

  15. Nucla circulating atmospheric fluidized bed demonstration project

    SciTech Connect (OSTI)

    Not Available

    1991-01-31T23:59:59.000Z

    During the fourth quarter of 1990, steady-state performance testing at the Nucla Circulating Fluidized Bed (CFB) resumed under sponsorship of the US Department of Energy. Co-sponsorship of the Demonstration Test Program by the Electric Power Research Institute (EPRI) was completed on June 15, 1990. From October through December, 1990, Colorado-Ute Electric Association (CUEA) completed a total of 23 steady-state performance tests, 4 dynamic tests, and set operating records during November and December as the result of improved unit operating reliability. Highlight events and achievements during this period of operation are presented.

  16. NUCLA Circulating Atmospheric Fluidized Bed Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This Annual Report on Colorado-Ute Electric Association's NUCLA Circulating Fluidized Bed (CFB) Demonstration Program covers the period from February 1987 through December 1988. The outline for presentation in this report includes a summary of unit operations along with individual sections covering progress in study plan areas that commenced during this reporting period. These include cold-mode shakedown and calibration, plant commercial performance statistics, unit start-up (cold), coal and limestone preparation and handling, ash handling system performance and operating experience, tubular air heater, baghouse operation and performance, materials monitoring, and reliability monitoring. During this reporting period, the coal-mode shakedown and calibration plan was completed. (VC)

  17. Solid fuel combustion system for gas turbine engine

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN)

    1993-01-01T23:59:59.000Z

    A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

  18. Coal-feeding mechanism for a fluidized bed combustion chamber

    DOE Patents [OSTI]

    Gall, Robert L. (Morgantown, WV)

    1981-01-01T23:59:59.000Z

    The present invention is directed to a fuel-feeding mechanism for a fluidized bed combustor. In accordance with the present invention a perforated conveyor belt is utilized in place of the fixed grid normally disposed at the lower end of the fluidized bed combustion zone. The conveyor belt is fed with fuel, e.g. coal, at one end thereof so that the air passing through the perforations dislodges the coal from the belt and feeds the coal into the fluidized zone in a substantially uniform manner.

  19. Fluidized-Bed Waste-Heat Recovery System Advances

    E-Print Network [OSTI]

    Patch, K. D.; Cole, W. E.

    . The unit consists of a hot-stage raining bed (outside dimensions 5 ft in diameter and 8 ft high) mounted above a cold-stage fluidized bed (6 ft by 4 ft by 1-1/2 ft), a particle circulating sys tem, a burner system simulating a furnace, a com bustion... and the stability of the fluidized bed. From previous work, it was shown Figure 4. Predicted Design Flow Performance of that a 2: 1 turndown can be achieved with stable the FBWHR Laboratory System fluidization. EFFECT OF PARTICLE CIRCULATION RATE Five tests...

  20. Data summary of municipal solid waste management alternatives

    SciTech Connect (OSTI)

    Not Available

    1992-10-01T23:59:59.000Z

    This appendix contains the numerically indexed bibliography for the complete group of reports on municipal solid waste management alternatives. The list references information on the following topics: mass burn technologies, RDF technologies, fluidized bed combustion, pyrolysis and gasification of MSW, materials recovery- recycling technologies, sanitary landfills, composting and anaerobic digestion of MSW.

  1. Gas phase hydrodynamics inside a circulating fluidized bed

    E-Print Network [OSTI]

    Moran, James C. (James Christopher)

    2001-01-01T23:59:59.000Z

    Circulating Fluidized Beds (CFB's) offer many advantages over traditional pulverized coal burners in the power generation industry. They operate at lower temperatures, have better environmental emissions and better fuel ...

  2. EA-0575: Fundamental Fluidization Research Project, Morgantown, West Virginia

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to design, construct, and operate a 2-foot diameter, 50-foot high pressurized fluidization with particular emphasis on operation in the...

  3. Application of a fluidized bed combustor to the DARS process

    SciTech Connect (OSTI)

    Scott-Young, R.E. [Australian Paper, Burnie, Tasmania (Australia). Pulp Mill and Services Unit

    1995-12-31T23:59:59.000Z

    Australian Paper has built the world`s first and only operational Direct Alkali Recovery System (DARS) to recover caustic soda for a soda AQ chemical pulp mill. At the heart of the DARS process, concentrated spent pulping liquor is burnt in a fluidized bed. The bed material is made up of coarse, dense iron oxide pellets which require a high fluidizing velocity. Bubbling is violent and gives robust fluidization of the iron and sodium compounds. The plant suffered a protracted startup because of equipment failures, air flow instability problems, and process and equipment design errors. A large amount of post construction development work was required. This paper discusses the experiences and knowledge gained in adapting a fluidized bed to the DARS process.

  4. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3...

  5. Generalizing the flash technique in the front-face configuration to measure the thermal diffusivity of semitransparent solids

    SciTech Connect (OSTI)

    Pech-May, Nelson Wilbur [Departamento de Física Aplicada I, Escuela Técnica Superior de Ingeniería, Universidad del País Vasco UPV/EHU, Alameda Urquijo s/n, 48013 Bilbao (Spain); Department of Applied Physics, CINVESTAV Unidad Mérida, carretera Antigua a Progreso km6, A.P. 73 Cordemex, Mérida Yucatán 97310, México (Mexico); Mendioroz, Arantza; Salazar, Agustín, E-mail: agustin.salazar@ehu.es [Departamento de Física Aplicada I, Escuela Técnica Superior de Ingeniería, Universidad del País Vasco UPV/EHU, Alameda Urquijo s/n, 48013 Bilbao (Spain)

    2014-10-15T23:59:59.000Z

    In this work, we have extended the front-face flash method to retrieve simultaneously the thermal diffusivity and the optical absorption coefficient of semitransparent plates. A complete theoretical model that allows calculating the front surface temperature rise of the sample has been developed. It takes into consideration additional effects, such as multiple reflections of the heating light beam inside the sample, heat losses by convection and radiation, transparency of the sample to infrared wavelengths, and heating pulse duration. Measurements performed on calibrated solids, covering a wide range of absorption coefficients (from transparent to opaque) and thermal diffusivities, validate the proposed method.

  6. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11T23:59:59.000Z

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  7. Combustion of Cattle Manure in a Fluidized Bed Combustor

    E-Print Network [OSTI]

    Annamalai, K.; Colaluca, M. A.; Ibrahim, M. Y.; Sweeten, J. M.

    COMBUSTION OF CATTLE MANURE IN A FLUIDIZED BED COMBUSTOR K. ANNAMALAI M. A. COLALUCA Associate Professor Associate Professor Mechanical Engineering Mechanical Engineering Department Department Texas A&M University Texas A&M University College... combustion technology has been used for the energy conversion of marginal fuels, such a technology is being explored for the combustion of feedlot manure. A fluidized bed combustor of 0.15 m (6 in.) diameter was used for the combustion tests on manure...

  8. Experimental study of fluidized bed combustion of feedlot manure

    E-Print Network [OSTI]

    Madan, Ajit M.

    1984-01-01T23:59:59.000Z

    combustion experiments were conducted in a circulating mode in pilot plant fluidized bed combustion unit at York-Shipley (Sweeten, J. , et a1. , 1984). A total of four experimental runs were conducted. However, combustion effeciency based on these limited...EXPERIMENTAL STUDY OF FLUIDIZED BED COMBUSTION OF FEEDLOT MANURE A Thesis by Ajit M. Madan Submitted to the Braduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December...

  9. Advanced design for pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    Moussa, N.A.; Fowle, A.A.; Delichatsios, M.M.; Caron, R.N.; Wilson, R.P.

    1982-12-01T23:59:59.000Z

    In a pulsed bed, the fluidizing air is made to oscillate while flowing through the bed. The objectives of the work reported were to investigate the potential advantages and limitations of a pulsed atmospheric fluidized bed combustor, based on existing data and analyses, to develop conceptual bench-scale designs, and to formulate a research and development plan for experimental validation and development of the pulsation concept for improving the performance of an AFBC. (LEW)

  10. Development and applications of clean coal fluidized bed technology

    SciTech Connect (OSTI)

    Eskin, N.; Hepbasli, A. [Ege University, Izmir (Turkey). Faculty of Engineering

    2006-09-15T23:59:59.000Z

    Power generation in Europe and elsewhere relies heavily on coal and coal-based fuels as the source of energy. The reliance will increase in the future due to the decreasing stability of price and security of oil supply. In other words, the studies on fluidized bed combustion systems, which is one of the clean coal technologies, will maintain its importance. The main objective of the present study is to introduce the development and the applications of the fluidized bed technology (FBT) and to review the fluidized bed combustion studies conducted in Turkey. The industrial applications of the fluidized bed technology in the country date back to the 1980s. Since then, the number of the fluidized bed boilers has increased. The majority of the installations are in the textile sector. In Turkey, there is also a circulating fluidized bed thermal power plant with a capacity of 2 x 160 MW under construction at Can in Canakkale. It is expected that the FBT has had, or will have, a significant and increasing role in dictating the energy strategies for Turkey.

  11. Development of Criteria and Identification of Particle Cluster Size Based on Measurements of Void Fraction in Gas-Solid Systems

    SciTech Connect (OSTI)

    David Roelant; Seckin Gokaltun

    2009-06-30T23:59:59.000Z

    A circulating fluidized bed (CFB) built at FIU was used to study particle motion in the riser in order to simulate flow regimes in a cold gasifier. High speed imaging was used in order to capture the dynamics of the particles flowing in the riser. The imaging method used here is called the shadow sizing technique which allowed the determination of particle areas and trajectories at various flow rates in the riser. The solid volume fraction and particle velocities calculated using the images acquired during the experiments can be related to granular temperature in order to detect formations of clusters in the riser section of the CFB. The shadow sizing technique was observed to be an effective method in detecting dynamics of particles in motion and formation of clusters when supported with high-speed imaging.

  12. Dynamics of Gas-Fluidized Granular Rods

    E-Print Network [OSTI]

    L. J. Daniels; Y. Park; T. C. Lubensky; D. J. Durian

    2008-11-17T23:59:59.000Z

    We study a quasi-two-dimensional monolayer of granular rods fluidized by a spatially and temporally homogeneous upflow of air. By tracking the position and orientation of the particles, we characterize the dynamics of the system with sufficient resolution to observe ballistic motion at the shortest time scales. Particle anisotropy gives rise to dynamical anisotropy and superdiffusive dynamics parallel to the rod's long axis, causing the parallel and perpendicular mean squared displacements to become diffusive on different timescales. The distributions of free times and free paths between collisions deviate from exponential behavior, underscoring the non-thermal character of the particle motion. The dynamics show evidence of rotational-translational coupling similar to that of an anisotropic Brownian particle. We model rotational-translation coupling in the single-particle dynamics with a modified Langevin model using non-thermal noise sources. This suggests a phenomenological approach to thinking about collections of self-propelling particles in terms of enhanced memory effects.

  13. Advanced control strategies for fluidized bed dryers

    SciTech Connect (OSTI)

    Siettos, C.I.; Kiranoudis, C.T.; Bafas, G.V.

    1999-11-01T23:59:59.000Z

    Generating the best possible control strategy comprises a necessity for industrial processes, by virtue of product quality, cost reduction and design simplicity. Three different control approaches, namely an Input-Output linearizing, a fuzzy logic and a PID controller, are evaluated for the control of a fluidized bed dryer, a typical non-linear drying process of wide applicability. Based on several closed loop characteristics such as settling times, maximum overshoots and dynamic performance criteria such as IAE, ISE and ITAE, it is shown that the Input-Output linearizing and the fuzzy logic controller exhibit a better performance compared to the PID controller tuned optimally with respect to IAE, for a wide range of disturbances; yet, the relevant advantage of the fuzzy logic over the conventional nonlinear controller issues upon its design simplicity. Typical load rejection and set-point tracking examples are given to illustrate the effectiveness of the proposed approach.

  14. Fluidized bed boiler having a segmented grate

    DOE Patents [OSTI]

    Waryasz, Richard E. (Longmeadow, MA)

    1984-01-01T23:59:59.000Z

    A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

  15. Nucla circulating atmospheric fluidized bed demonstration project

    SciTech Connect (OSTI)

    Keith, Raymond E.

    1991-10-01T23:59:59.000Z

    Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute's decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

  16. Pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    Not Available

    1989-11-01T23:59:59.000Z

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  17. (Pulsed atmospheric fluidized bed combustion (PAFBC))

    SciTech Connect (OSTI)

    Not Available

    1988-10-01T23:59:59.000Z

    This first Quarterly Technical Progress Report presents the results of work accomplished during the period April 19 through July 24,1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. the program scope consisted of two tasks; the first was to establish preliminary feasibility by the use of theoretical and state-of-the-art information. This task was completed during the first quarter of the contract period and a topical report entitled, Pulsed Atmospheric Fluidized Bed combustion (PAFBC) - Preliminary Feasibility Study'' was prepared as a decision point to proceed'' deliverable in accordance with the terms of the contract. This first quarterly progress report therefore covers the contract activities subsequent to the approval of the feasibility study and the decision to proceed with the Task 2 effort. As the initial quarterly technical progress report, this document includes a subsection on background which will be omitted in subsequent reports. All effort during this period was devoted to the design and analysis of the PAFBC. Design drawings were prepared and fabrication and procurement initiated. Quotations were evaluated and a fabrication contract awarded. A site adjacent to the MTCI building was chosen for the installation of the PAFBC. Some ancillary components were purchased, renovated, and tested. Some delays in delivery of components have resulted in some schedule delay. It is anticipated that the program pace will accelerate as soon as parts are received and installation and assembly are initiated. 10 figs.,1 tab.

  18. Application of a fiber optic probe to the hydrodynamic study of an industrial fluidized bed furnace

    SciTech Connect (OSTI)

    Saberi, B.; Shakourzadeh, K. [Technical Univ. of Compiegne (France); Militzer, J. [Technical Univ. of Nova Scotia, Halifax, Nova Scotia (Canada)

    1997-12-31T23:59:59.000Z

    A fiber optic probe technique is used to establish the hydrodynamic characteristics of an industrial scale (0.9 m internal diameter and 2.5 m tall) bubbling fluidized bed. This measurement technique allows for the bubbling phenomenon to be studied locally. Bubble parameters such as size, velocity and frequency can be measured with an adequate accuracy. This, however, is not a straight forward procedure, since among other things the shape of the bubble and the position at which fiber intercepts the bubble are unknown. This requires a statistical treatment of the data and the use of a correction factor. A geometrical and statistical analysis of the bubble/probe interactions shows that the correction factor is approximately unitary and thus the bubble size distribution can be obtained directly from the statistical treatment of the results of relatively large number of series of measurements. In addition, sampling rate and sample duration have to be determined as a function of the bubble size and velocity. Several combinations of sampling time and sampling rate have been tested allowing for the best combination of these parameters to be determined. After treatment of the acquired signals, the mean bubble size and velocity were calculated. The results obtained were compared to the measured expansion of the bed and the overall gas flow rate. This confirmed the accuracy of the measurements and the usefulness of this technique to establish the hydrodynamics of bubbling fluidized beds.

  19. Alexandria fluidized-bed process-development unit. Hot-mode testing

    SciTech Connect (OSTI)

    Not Available

    1982-12-01T23:59:59.000Z

    The objectives of the current test program include validation of predictions from the Massachusetts Institute of Technology (MIT) Atmospheric Fluidized Bed Coal Combustor System Model, continuation of experimental studies supporting AFBC process development, and collection of transient data for later process control studies. This topical report summarizes results from hot mode testing, i.e., experiments performed with combustion in the Process Development Unit for Model verification. During these tests, coal and limestone were fluidized and combusted with air at temperatures ranging from 1400 to 1580/sup 0/F in the 3' x 3' (nominal) size Process Development Unit (PDU) at Alexandria, Virginia. MIT Model predictions tested include: combustion efficiency, carbon loading, gas and solids concentrations, bed temperature, expanded bed height, overall heat transfer coefficient and sulfur retention by the coal/limestone system. Although not corresponding exactly, the Model predictions and experimental values for the overall heat transfer coefficients were relatively close in agreement. In all other cases, there were some discrepancies between the Model predictions and corresponding experimental PDU results. Transient process data were collected by the Data Acquisition System (DAS). Six parameters were recorded continuously on a six channel recorder. Variances were observed in the recorded transient data in response to input step changes.

  20. An Analysis of the Use of Fluidized-Bed Heat Exchangers for Heat Recovery

    E-Print Network [OSTI]

    Vogel, G. J.; Grogan, P. J.

    1980-01-01T23:59:59.000Z

    The principles of fluidized-bed operation and the factors affecting the performance of a fluidized-bed waste heat boiler (FBWHB) are discussed in detail. Factors included in the discussion are bed temperature and pressure, heat transfer coefficient...

  1. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    GASIFIER IN A FLUIDIZED BED REACTOR Inventors: Joseph M .a steam hydro-gasification reactor (SHR) the carbonaceous0012] Fluidized bed reactors are well known and used in a

  2. Review of fluidized bed combustion technology in the United States

    SciTech Connect (OSTI)

    Krishnan, R.P.; Daw, C.S.; Jones, J.E. Jr.

    1984-01-01T23:59:59.000Z

    The United States (US) initiated work in fluidized bed combustion (FBC) in the mid-1960s, with primary emphasis on industrial applications. With passage of the Clean Air Act in 1970, the environmental benefits of the technology soon attracted interest. This provided the impetus for expanded effort focused on the reduced NO/sub x/ emissions resulting from lower combustion temperature and SO/sub 2/ capture by means of chemical reaction with limestone or dolomite in the fluidized bed. The oil embargo in 1973 further stimulated interest in FBC technology. Several manufacturers presently offer atmospheric fluidized bed combustion (AFBC) and circulating fluidized bed combustion (CFBC) units for industrial application in the United States. However, FBC for electric power generation remains in the development and demonstration phase. The Tennessee Valley Authority (TVA) and Electric Power Research Institute (EPRI) are operating a 20-MW AFBC utility pilot plant and are proceeding with plans for a 160-MW(e) demonstration plant with other participants. Research has been under way on pressurized fluidized bed combustion (PFBC) at Grimethorpe in South Yorkshire, England, and within the United States at the Curtiss-Wright Pilot Plant, and at other smaller test facilities. An emerging turbocharged PFBC concept will likely stimulate more near-term interest in PFBC technology for both industrial and utility applications. The major US programs and test facilities are described; remaining technical uncertainties are discussed, and the future outlook for the technology is assessed.

  3. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01T23:59:59.000Z

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock & Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  4. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01T23:59:59.000Z

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  5. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Hopper, J.R.

    1996-06-01T23:59:59.000Z

    Experiments were conducted in a 1-in. quartz fluidized bed combustor enclosed in an electric furnace. Coal samples were burned in the bed with a sorbent under specific combustion conditions and the amount of metal capture by the sorbent determined. Three different cao samples from the Illinois Basin Coal Sample Bank were tested. Metals involved were Cd, Pb, and Cr; the sorbents included bauxite, zeolite, and lime. Potential metal-sorbent reactions were identified. Results indicated that metal capture by sorbent can be as high as 96%, depending on the metal species and sorbent. All 3 sorbents were capable of capturing Pb, zeolite and lime were able to capture Cr, and bauxite was the only sorbent capable of capturing Cd. Thermodynamic equilibrium calculations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}, CdAl{sub 2}O{sub 4}, and CdSiO{sub 3} solids under the combustion conditions.

  6. Combustion engineering issues for solid fuel systems

    SciTech Connect (OSTI)

    Bruce Miller; David Tillman [Pennsylvania State University, University Park, PA (United States). Energy Institute

    2008-05-15T23:59:59.000Z

    The book combines modeling, policy/regulation and fuel properties with cutting edge breakthroughs in solid fuel combustion for electricity generation and industrial applications. This book provides real-life experiences and tips for addressing the various technical, operational and regulatory issues that are associated with the use of fuels. Contents are: Introduction; Coal Characteristics; Characteristics of Alternative Fuels; Characteristics and Behavior of Inorganic Constituents; Fuel Blending for Combustion Management; Fuel Preparation; Conventional Firing Systems; Fluidized-Bed Firing Systems; Post-Combustion Emissions Control; Some Computer Applications for Combustion Engineering with Solid Fuels; Gasification; Policy Considerations for Combustion Engineering.

  7. Fluidized bed pyrolysis of terrestrial biomass feedstocks

    SciTech Connect (OSTI)

    Besler, S.; Agblevor, F.A.; Davis, M.F. [National Renewable Energy Lab., Golden, CO (United States)] [and others

    1994-12-31T23:59:59.000Z

    Hybrid poplar, switchgrass, and corn stover were pyrolyzed in a bench scale fluidized-bed reactor to examine the influence of storage time on thermochemical converting of these materials. The influence of storage on the thermochemical conversion of the biomass feedstocks was assessed based on pyrolysis product yields and chemical and instrumental analyses of the pyrolysis products. Although char and gas yields from corn stover feedstock were influenced by storage time, hybrid poplar and switchgrass were not significantly affected. Liquid, char, and gas yields were feedstock dependent. Total liquid yields (organic+water) varied from 58%-73% depending on the feedstock. Char yields varied from 14%-19% while gas yields ranged from 11%-15%. The chemical composition of the pyrolysis oils from hybrid polar feedstock was slightly changed by storage, however, corn stover and switchgrass feedstock showed no significant changes. Additionally, stored corn stover and hybrid poplar pyrolysis oils showed a significant decrease in their higher heating values compared to the fresh material.

  8. Performance analysis of co-firing waste materials in an advanced pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Bonk, D.L.; McDaniel, H.M. [USDOE Morgantown Energy Technology Center, WV (United States); DeLallo, M.R. Jr.; Zaharchuk, R. [Gilbert/Commonwealth, Inc., Reading, PA (United States)

    1995-07-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal wastes. Leading this approach is the atmospheric fluidized-bed combustor (AFBC). It has demonstrated its commercial acceptance in the utility market as a reliable source of power by burning a variety of waste and alternative fuels. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economical feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. The results and conclusions developed are generally applicable to current and advanced PFBC design concepts. Wastes considered for co-firing include municipal solid waste (MSW), sewage sludge, and industrial de-inking sludge. Conceptual designs of two power plants rated at 250 MWe and 150 MWe were developed. Heat and material balances were completed for each plant along with environmental issues. With the PFBC`s operation at high temperature and pressure, efforts were centered on defining feeding systems capable of operating at these conditions. Air emissions and solid wastes were characterized to assess the environmental performance comparing them to state and Federal regulations. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  9. The Development and Optimization of Techniques for Monitoring Water Quality on-Board Spacecraft Using Colorimetric Solid-Phase Extraction (C-SPE)

    SciTech Connect (OSTI)

    April Hill

    2007-12-01T23:59:59.000Z

    The main focus of this dissertation is the design, development, and ground and microgravity validation of methods for monitoring drinking water quality on-board NASA spacecraft using clorimetric-solid phase extraction (C-SPE). The Introduction will overview the need for in-flight water quality analysis and will detail some of the challenges associated with operations in the absence of gravity. The ability of C-SPE methods to meet these challenges will then be discussed, followed by a literature review on existing applications of C-SPE and similar techniques. Finally, a brief discussion of diffuse reflectance spectroscopy theory, which provides a means for analyte identification and quantification in C-SPE analyses, is presented. Following the Introduction, four research chapters are presented as separate manuscripts. Chapter 1 reports the results from microgravity testing of existing C-SPE methods and procedures aboard NASA's C-9 microgravity simulator. Chapter 2 discusses the development of a C-SPE method for determining the total concentration of biocidal silver (i.e., in both dissolved and colloidal forms) in water samples. Chapter 3 presents the first application of the C-SPE technique to the determination of an organic analyte (i.e., formaldehyde). Chapter 4, which is a departure from the main focus of the thesis, details the results of an investigation into the effect of substrate rotation on the kinetics involved in the antigen and labeling steps in sandwich immunoassays. These research chapters are followed by general conclusions and a prospectus section.

  10. CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION

    SciTech Connect (OSTI)

    Crawford, C

    2008-07-31T23:59:59.000Z

    The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

  11. Combustion of waste fuels in a fluidized-bed boiler

    SciTech Connect (OSTI)

    Zylkowski, J.; Ehrlich, S.

    1983-01-01T23:59:59.000Z

    This paper reports on a project whose objectives are to determine the impact of the waste fuels on Atmospheric Fluidized Bed Combustion (AFBC) operating procedures, boiler performance, and emissions and to assess the potential for fuel-specific operating problems. The low-grade waste fuels investigated are hogged railroad ties, shredded rubber tires, peat, refuse-derived fuel, and one or more agricultiral wastes. The Northern States Power (NSP) Company converted their French Island Unit No. 2 stoker-fired boiler to a fluidized-bed combustor designed to burn wood waste. NSP and EPRI are investigating cofiring other waste fuels with wood waste. Topics considered include fluidized-bed boiler conversion, fuel resources, economic justification, environmental considerations, the wood-handling system, an auxiliary fuel system, the air quality control system, ash handling and disposal, and the alternate fuels test program.

  12. Methods of forming a fluidized bed of circulating particles

    DOE Patents [OSTI]

    Marshall, Douglas W. (Blackfoot, ID)

    2011-05-24T23:59:59.000Z

    There is disclosed an apparatus for forming a fluidized bed of circulating particles. In an embodiment, the apparatus includes a bottom portion having a sidewall, the sidewall defining a curvilinear profile, and the bottom portion configured to contain a bed of particles; and a gas inlet configured to produce a column of gas to carry entrained particles therein. There is disclosed a method of forming a fluidized bed of circulating particles. In an embodiment, the method includes positioning particles within a bottom portion having a sidewall, the sidewall defining a curvilinear profile; producing a column of gas directed upwardly through a gas inlet; carrying entrained particles in the column of gas to produce a fountain of particles over the fluidized bed of circulating particles and subside in the particle bed until being directed inwardly into the column of gas within the curvilinear profile.

  13. Description of emission control using fluidized-bed, heat-exchange technology

    SciTech Connect (OSTI)

    Vogel, G.J.; Grogan, P.J.

    1980-06-01T23:59:59.000Z

    Environmental effects of fluidized-bed, waste-heat recovery technology are identified. The report focuses on a particular configuration of fluidized-bed, heat-exchange technology for a hypothetical industrial application. The application is a lead smelter where a fluidized-bed, waste-heat boiler (FBWHB) is used to control environmental pollutants and to produce steam for process use. Basic thermodynamic and kinetic information for the major sulfur dioxide (SO/sub 2/) and NO/sub x/ removal processes is presented and their application to fluidized-bed, waste heat recovery technology is discussed. Particulate control in fluidized-bed heat exchangers is also discussed.

  14. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    SciTech Connect (OSTI)

    Rokkam, Ram [Ames Laboratory

    2012-11-02T23:59:59.000Z

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  15. Attrition and elutriation phenomena in industrial atmospheric fluidized bed combustors

    SciTech Connect (OSTI)

    Wells, J.W.; Krishnan, R.P.

    1980-01-01T23:59:59.000Z

    Attrition and elutriation in large-scale AFBC systems depend on the design of the feed system, bed hydrodynamics and freeboard cooling. At present, no generalized correlation exists to predict these effects. It is suggested that routine solid samples for size analysis be taken before the solids enter the bed. In this way, correlations can be developed to predict the attrition in the feed system and in the bed separately. Secondly, data on the solids loading in the freeboard should be taken and related to bubble size, bubble velocity, bubble frequency and bed expansion. Such information can be obtained in a cold bed for lack of measuring techniques in hot beds. Accurate rate expressions for attrition and elutriation specific to coal ash, limestone, and char can then be developed to predict the performance of AFBC systems.

  16. Refractory experience in circulating fluidized bed combustors, Task 7

    SciTech Connect (OSTI)

    Vincent, R.Q.

    1989-11-01T23:59:59.000Z

    This report describes the results of an investigation into the status of the design and selection of refractory materials for coal-fueled circulating fluidized-bed combustors. The survey concentrated on operating units in the United States manufactured by six different boiler vendors: Babcock and Wilcox, Combustion Engineering, Foster Wheeler, Keeler Dorr-Oliver, Pyropower, and Riley Stoker. Information was obtained from the boiler vendors, refractory suppliers and installers, and the owners/operators of over forty units. This work is in support of DOE's Clean Coal Technology program, which includes circulating fluidized-bed technology as one of the selected concepts being evaluated.

  17. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

    1980-01-01T23:59:59.000Z

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  18. Numerical Modeling of Reactive Multiphase Flow for FCC and Hot Gas Desulfurization Circulating Fluidized Beds

    SciTech Connect (OSTI)

    None

    2005-07-01T23:59:59.000Z

    This work was carried out to understand the behavior of the solid and gas phases in a CFB riser. Only the riser is modeled as a straight pipe. A model with linear algebraic approximation to solids viscosity of the form, {musubs} = 5.34{epsisubs}, ({espisubs} is the solids volume fraction) with an appropriate boundary condition at the wall obtained by approximate momentum balance solution at the wall to acount for the solids recirculation is tested against experimental results. The work done was to predict the flow patterns in the CFB risers from available experimental data, including data from a 7.5-cm-ID CFB riser at the Illinois Institute of Technology and data from a 20.0-cm-ID CFB riser at the Particulate Solid Research, Inc., facility. This research aims at modeling the removal of hydrogen sulfide from hot coal gas using zinc oxide as the sorbent in a circulating fluidized bed and in the process indentifying the parameters that affect the performance of the sulfidation reactor. Two different gas-solid reaction models, the unreacted shrinking core (USC) and the grain model were applied to take into account chemical reaction resistances. Also two different approaches were used to affect the hydrodynamics of the process streams. The first model takes into account the effect of micro-scale particle clustering by adjusting the gas-particle drag law and the second one assumes a turbulent core with pseudo-steady state boundary condition at the wall. A comparison is made with experimental results.

  19. Plant response to FBC waste-coal slurry solid mixtures. [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect (OSTI)

    Darmody, R.G.; Dunker, R.E. [Illinois Univ., Urbana, IL (United States); Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Urbana, IL (United States)

    1994-03-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. Our approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful, this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. This is the first quarter of the project. We have designed the experiment, secured greenhouse space, purchased the seeds, collected and dried the FBC and CSS samples. The samples represent a typical range of properties. We retrieved two FBC and two CSS samples. One CSS sample appears to have a higher pyrite content than the other.

  20. Measurement of alkali-vapor emission from pressurized fluidized-bed combustion of Illinois coals

    SciTech Connect (OSTI)

    Lee, S.H.D.; Teats, F.G.; Swift, W.M. (Argonne National Lab., IL (United States)); Banerjee, D.D. (Illinois Clean Coal Inst., Carterville, IL (United States))

    1993-01-01T23:59:59.000Z

    Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging from 910 to 950[degree]C and a system pressure of 9.2 atm absolute. Alkali-vapor emission (Na and K) in the PFBC flue gas was determined by the analytical activated-bauxite sorber bed technique developed at Argonne National Laboratory. The test results showed that sodium is the major alkali-vapor species present in the PFBC flue gas, and that the level of sodium-vapor emission increases linearly with both Na and Cl contents in the coals. This suggests that the sodium-vapor emission results from direct vaporization of NaCl present in the coals. The measured alkali-vapor concentration (Na + K), 67 to 190 ppbW, is more than 2.5 times greater than the allowable alkali limit of 24 ppb for an industrial gas turbine. Combusting these coals in a PFBC for power generation may require developing a method to control alkali vapors.

  1. Measurement of alkali-vapor emission from pressurized fluidized-bed combustion of Illinois coals

    SciTech Connect (OSTI)

    Lee, S.H.D.; Teats, F.G.; Swift, W.M. [Argonne National Lab., IL (United States); Banerjee, D.D. [Illinois Clean Coal Inst., Carterville, IL (United States)

    1993-04-01T23:59:59.000Z

    Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging from 910 to 950{degree}C and a system pressure of 9.2 atm absolute. Alkali-vapor emission (Na and K) in the PFBC flue gas was determined by the analytical activated-bauxite sorber bed technique developed at Argonne National Laboratory. The test results showed that sodium is the major alkali-vapor species present in the PFBC flue gas, and that the level of sodium-vapor emission increases linearly with both Na and Cl contents in the coals. This suggests that the sodium-vapor emission results from direct vaporization of NaCl present in the coals. The measured alkali-vapor concentration (Na + K), 67 to 190 ppbW, is more than 2.5 times greater than the allowable alkali limit of 24 ppb for an industrial gas turbine. Combusting these coals in a PFBC for power generation may require developing a method to control alkali vapors.

  2. Atmospheric fluidized-bed combustion performance guidelines

    SciTech Connect (OSTI)

    Sotelo, E. (Sotelo (Ernest), Berkeley, CA (USA))

    1991-03-01T23:59:59.000Z

    Performance specifications for conventional coal-fired boilers typically call for tests to be conducted in accordance with the ASME Performance Test Code for Steam Generating Units, PTC 4.1. The Code establishes procedures for conducting performance tests primarily to determine efficiency and capacity. The current edition of the PTC 4.1 is not entirely applicable to atmospheric fluidized-bed combustion boilers, however. AFBC boilers typically are equipped with integral sulfur capture through the addition of a sorbent material along with the fuel feed to the combustor, and this new technology introduces heat losses and credits that are not described in PTC 4.1. These heat losses and credits include combustion heat loss due to the calcination of the sorbent, heat credit due to sulfation, and the effects of calcination and sulfation on the dry flue gas flow, all of which significantly affect boiler efficiency calculations. The limitations of the current issue of the PTC 4.1 is recognized and the Code is now being reviewed to include heat losses and credits common to AFBC boilers. While this work will take some time, there is an immediate need for procedures for performance testing of AFBC boilers. These Guidelines are prepared to meet that need in the interim. The Guidelines detail procedures for boiler efficiency tests. They introduce technical and economic issues that may influence the test level of detail and accuracy. Methods of identifying required measurements, selection of measurement schemes, and assessment of measured versus estimated values are presented. A case study is used to illustrate the procedures and indicate which are the major credits and losses in the efficiency of a typical AFBC boiler. 6 figs., 8 tabs.

  3. FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-12-22T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as an alternative technology for the immobilization of a wide variety of aqueous high sodium containing radioactive wastes at various DOE facilities in the United States. The addition of clay, charcoal, and a catalyst as co-reactants converts aqueous Low Activity Wastes (LAW) to a granular or ''mineralized'' waste form while converting organic components to CO{sub 2} and steam, and nitrate/nitrite components, if any, to N{sub 2}. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage-like structures that atomically bond radionuclides like Tc-99 and anions such as SO{sub 4}, I, F, and Cl. The granular product has been shown to be as durable as LAW glass. Shallow land burial requires that the mineralized waste form be able to sustain the weight of soil overburden and potential intrusion by future generations. The strength requirement necessitates binding the granular product into a monolith. FBSR mineral products were formulated into a variety of monoliths including various cements, Ceramicrete, and hydroceramics. All but one of the nine monoliths tested met the <2g/m{sup 2} durability specification for Na and Re (simulant for Tc-99) when tested using the Product Consistency Test (PCT; ASTM C1285). Of the nine monoliths tested the cements produced with 80-87 wt% FBSR product, the Ceramicrete, and the hydroceramic produced with 83.3 wt% FBSR product, met the compressive strength and durability requirements for an LAW waste form.

  4. Development of a countercurrent multistage fluidized-bed reactor and mathematical modeling for prediction of removal efficiency of sulfur dioxide from flue gases

    SciTech Connect (OSTI)

    Mohanty, C.R.; Malavia, G.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-02-15T23:59:59.000Z

    A bubbling countercurrent multistage fluidized-bed reactor for the sorption of sulfur dioxide by hydrated lime particles was simulated employing a two-phase model, with the bubble phase assumed to be in plug flow and with the emulsion phase either in plug flow (EGPF model) or in perfectly mixed flow (EGPM model). The model calculations were compared with experimental data in term of percentage removal efficiency of sulfur dioxide. Both models were applied to understand the influence of operating parameters on the reactor performance. The comparison showed that the EGPF model agreed well with the experimental data. From the perspective of use of a multistage fluidized-bed reactor as air pollution control equipment in industry, the model could be considered general enough for predicting the performance of reactors for gas-solid treatment.

  5. (Pulsed atmospheric fluidized-bed combustion). [Installation of the pulsed atmospheric fluidized-bed combustion components

    SciTech Connect (OSTI)

    Not Available

    1988-10-01T23:59:59.000Z

    This second Quarterly Technical Progress Report presents the results of work accomplished during the period July 25 through October 30, 1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in environmentally acceptable manner. Progress during this period accelerated rapidly. The site for the installation of the PAFBC was completed. All of the system components, including the fabrication of the furnace, were also completed. Additional component testing and inspection was also completed. By the end of this period the AFBC was completely assembled and installed at the site adjacent to the MTCI facility and shakedown tests were initiated. 20 figs., 2 tabs.

  6. DMEC-1 Pressurized Circulating Fluidized-Bed Demonstration Project

    SciTech Connect (OSTI)

    Kruempel, G.E.; Ambrose, S.J. [Midwest Power, Des Moines, IA (United States); Provol, S.J. [Pyropower Corp., San Diego, CA (United States)

    1992-12-01T23:59:59.000Z

    The DMEC-1 project will demonstrate the use of Pyropower`s PYROFLOW pressurized circulating fluidized bed technology to repower an existing coal fired generating station. This will be the first commercial application of this technology in the world. The project is now in budget period 1, the preliminary design phase.

  7. Modified sedimentation-dispersion model for solids in a three-phase slurry column

    SciTech Connect (OSTI)

    Smith, D.N.; Ruether, J.A.; Shah, Y.T.; Badgujar, M.N.

    1986-03-01T23:59:59.000Z

    Solids distribution data for a three-phase, batch-fluidized slurry bubble column (SBC) are presented, using air as the gas phase, pure liquids and solutions as the liquid phase, and glass beads and carborundum catalyst powder as the solid phase. Solids distribution data for the three-phase SBC operated in a continuous mode of operation are also presented, using nitrogen as the gas phase, water as the liquid phase, and glass beads as the solid phase. A new model to provide a reasonable approach to predict solids concentration distributions for systems containing polydispersed solids is presented. The model is a modification of standard sedimentation-dispersion model published earlier. Empirical correlations for prediction of hindered settling velocity and solids dispersion coefficient for systems containing polydispersed solids are presented. A new method of evaluating critical gas velocity (CGV) from concentrations of the sample withdrawn at the same port of the SBC is presented. Also presented is a new mapping for CGV which separates the two regimes in the SBC, namely, incomplete fluidization and complete fluidization.

  8. Avalanche-like fluidization of an attractive dispersion

    E-Print Network [OSTI]

    Aika Kurokawa; Valérie Vidal; Kei Kurita; Thibaut Divoux; Sébastien Manneville

    2015-05-22T23:59:59.000Z

    We report on the transient dynamics of an attractive silica dispersion that displays strong physical aging. Extensive rheology coupled to ultrasonic velocimetry allows us to characterize the global stress response together with the local dynamics of the gel during shear startup experiments. In practice, after being rejuvenated by a preshear, the dispersion is left to age during a time $t_w$ before being submitted to a constant shear rate $\\dot \\gamma$. We investigate in detail the effects of both $t_w$ and $\\dot \\gamma$ on the fluidization dynamics and build a complete phase diagram of the gel behavior. At large enough shear rates, the gel is fully fluidized and flows homogeneously independently of its age. Under lower shear rates, the strong interplay between aging and shear rejuvenation leads, together with wall slip, to a more complex phenomenology. The gel may either display transient shear banding towards complete fluidization, or steady-state shear banding. In the former case, we unravel that the progressive fluidization occurs by successive steps that appear as peaks on the global stress relaxation signal. Flow imaging reveals that the shear band grows up to complete fluidization of the material by sudden avalanche-like events that are correlated to large peaks in the slip velocity at the moving wall. In the case of steady-state shear banding, we recover the classical scenario involving a critical shear rate $ \\dot \\gamma_c$ below which no homogeneous steady flow is possible. We show here that $\\dot \\gamma_c$ displays a nonlinear behavior with $t_w$. Our work paves the way for a thorough description of transient flows of weak attractive gels, and highlights the subtle interplay between shear, wall slip and aging that constitutes a major challenge in terms of modeling that has yet not been met.

  9. Performance of low-rank coal in atmospheric fluidized bed combustion. Technology transfer report

    SciTech Connect (OSTI)

    Hajicek, D.R.; Zobeck, B.J.; Mann, M.D.; Miller, B.G.; Ellman, R.C.; Benson, S.A.; Goblirsch, G.M.; Cooper, J.L.; Guillory, J.L.; Eklund, A.G.

    1985-10-01T23:59:59.000Z

    This report presents test data generated at GFETC and discusses the implications of this data in regard to the technical and economic feasibility of using low-rank coals in the AFBC. Atmospheric fluidized bed combustion offers a number of potential advantages over conventional pulverized coal combustion due to the intense turbulence in the fluidized bed and long residence times of solids in the bed without a long linear flow path. Advantages of the AFBC include flexibility to handle varying fuels, sulfur capture by limestone, high combustion efficiency, compact combustor size, lower NO/sub x/ emissions, and reduced slagging and fouling problems. Low-rank coals with high alkali-to-sulfur ratios offer a significant additional advantage: the ability to absorb significant sulfur on the alkaline ash. Results verify that AFBC is particularly well suited for the direct combustion of low-rank coals. With combustion temperatures above 1450/sup 0/F at 20% excess air or higher, the combustion efficiencies while burning low-rank coal were found to be above 98%, with efficiencies above 99% for most tests. The CO emissions were very low, typically below 0.05 lb/MMBtu or 50 ppMv. Overall heat transfer coefficients to water-cooled tubes while burning low-rank coals were comparable to those obtained with other fuels in AFBC, or 20 to 60 Btu/h-ft/sup 2/-/sup 0/F. These are considerably higher than those obtained in conventional coal-fired systems which are typically 5 to 15 Btu/h-ft/sup 2/-/sup 0/F. Factors influencing heat transfer included mass velocity, bed particle size, bed temperature, and ash recycle.

  10. Preliminary assessment of alternative atmospheric fluidized-bed-combustion power-plant systems. Final report

    SciTech Connect (OSTI)

    Bianchini, J.; Rogali, R.; Wysocki, J.; Bradley, W.

    1982-02-01T23:59:59.000Z

    This report presents a technical and economic evaluation of alternative atmospheric fluidized-bed combustion (AFBC) power plant systems with nominal capacities of 1000 MWe. Both eastern and western coal-fired power plants are evaluated for the following systems: baseline AFBC power plants with limestone beds; AFBC power plants with inert beds and wet FGC systems; AFBC power plant with inert beds and a dry FGD system (western coal only); AFBC power plants with limestone beds and limestone precalcination; AFBC power plants with limestone beds and agglomeration and recycle of spent solids; AFBC power plant with limestone beds and sorbent regeneration (eastern coal only); and reference pulverized coal-fired (PCF) power plants with wet FGC systems. The eastern coal-fired plants burn Illinois bituminous coal with a higher heating value of 10,1000 Btu/lb and a sulfur content of 4%. The western coal-fired plants burn Wyoming subbituminous coal with a higher heating value of 8020 Btu/lb and a sulfur content of 0.48%. The capital and operating cost estimates are based on boiler designs developed by Babcock and Wilcox, Inc., and on sorbent requirements estimated by Westinghouse R and D Center. Sorbent requirements for the baseline AFBC power plants are based on a calcium to sulfur mole ratio of 5:1 for the eastern coal-fired plant and 0.7:1 for the western coal-fired plant. The Ca/S mole ratio for the western coal plant allows for 30 percent utilization of the alkaline coal ash to reduce sorbent requirements to the fluidized bed combustor. The economic analyses are based on a plant located in the East Central region of the United States with a 30-year life and a 70 percent capacity factor.

  11. Data summary of municipal solid waste management alternatives. Volume 12, Numerically indexed bibliography

    SciTech Connect (OSTI)

    none,

    1992-10-01T23:59:59.000Z

    This appendix contains the numerically indexed bibliography for the complete group of reports on municipal solid waste management alternatives. The list references information on the following topics: mass burn technologies, RDF technologies, fluidized bed combustion, pyrolysis and gasification of MSW, materials recovery- recycling technologies, sanitary landfills, composting and anaerobic digestion of MSW.

  12. Highly Attrition Resistant Zinc Oxide-Based Sorbents for H2S Removal by Spray Drying Technique

    SciTech Connect (OSTI)

    Ryu, C.K.; Lee, J.B.; Ahn, D.H.; Kim, J.J.; Yi, C.K.

    2002-09-19T23:59:59.000Z

    Primary issues for the fluidized-bed/transport reactor process are high attrition resistant sorbent, its high sorption capacity and regenerability, durability, and cost. The overall objective of this project is the development of a superior attrition resistant zinc oxide-based sorbent for hot gas cleanup in integrated coal gasification combined cycle (IGCC). Sorbents applicable to a fluidized-bed hot gas desulfurization process must have a high attrition resistance to withstand the fast solid circulation between a desulfurizer and a regenerator, fast kinetic reactions, and high sulfur sorption capacity. The oxidative regeneration of zinc-based sorbent usually initiated at greater than 600 C with highly exothermic nature causing deactivation of sorbent as well as complication of sulfidation process by side reaction. Focusing on solving the sorbent attrition and regenerability of zinc oxide-based sorbent, we have adapted multi-binder matrices and direct incorporation of regeneration promoter. The sorbent forming was done with a spray drying technique that is easily scalable to commercial quantity.

  13. Synthetic aggregate compositions derived from spent bed materials from fluidized bed combustion and fly ash

    DOE Patents [OSTI]

    Boyle, Michael J. (Aston, PA)

    1994-01-01T23:59:59.000Z

    Cementitious compositions useful as lightweight aggregates are formed from a blend of spent bed material from fluidized bed combustion and fly ash. The proportions of the blend are chosen so that ensuing reactions eliminate undesirable constituents. The blend is then mixed with water and formed into a shaped article. The shaped article is preferably either a pellet or a "brick" shape that is later crushed. The shaped articles are cured at ambient temperature while saturated with water. It has been found that if used sufficiently, the resulting aggregate will exhibit minimal dimensional change over time. The aggregate can be certified by also forming standardized test shapes, e.g., cylinders while forming the shaped articles and measuring the properties of the test shapes using standardized techniques including X-ray diffraction.

  14. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Strandberg, Gerald W. (Farragut, TN)

    1989-01-01T23:59:59.000Z

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  15. Fluidized-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14T23:59:59.000Z

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor. 2 figs.

  16. Factors affecting the performance of a codisposal atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Huang, W.C.

    1982-01-01T23:59:59.000Z

    The paper describes the operation of the codisposal atmospheric fluidized-bed combustor (AFBC) installed at Duluth, Minnesota. The facility utilizes refuse-derived fuel to codispose sewage sludge without auxiliary fuel. Operating parameters affecting the combustor performance are discussed with emphasis on temperature distribution, bed fluidization, residence time, freeboard height and flyash properties. Optimum operating conditions are presented and some new concepts and trends of future development in fluidized bed technology are touched on.

  17. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume V. Appendix: stability and instability in fluidized-bed combustion

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01T23:59:59.000Z

    This document is the fifth of the seven volumes series of our Phase II Final Report. The material developed in this volume has not been incorporated into the system model. It will be used as a precursor of a transient model to be developed in the next phase of our model work. There have been various fluidized combustor models of differing complexity and scope published in the literature. Most of these models have identified and predicted - often in satisfactory agreement with results from pilot units - the key steady state combustor characteristics such as the mass of carbon in the bed (carbon loading), the combustion efficiency, the sulfur retention by the solid sorbent and the pollutant (mainly NO/sub x/) emissions. These models, however, cannot be in most instances successfully used to study the extinction and ignition characteristics of the combustor because they are isothermal in structure in the sense that the bed temperature is not an output variable but rather an input one and must be a priori specified. In order to remedy these inadequacies of the previous models, we here present a comprehensive account of the formulation and some typical results of a new nonisothermal model which has been developed in order to study, among other things, the ignition and extinction characteristics of the AFBC units. This model is able to predict the temperature patterns in the bed, the carbon loading, the combustion efficiency and the O/sub 2/ and CO concentration profiles in the combustor for the different design or operational characteristics.

  18. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    SciTech Connect (OSTI)

    Nguyen, C.T.

    1980-03-01T23:59:59.000Z

    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  19. Performance and gas cleanup criterion for a cotton gin waste fluidized-bed gasifier 

    E-Print Network [OSTI]

    Craig, Joe David

    1980-01-01T23:59:59.000Z

    . The basic results of Groves (1979) gave strong incentives to des1gn a scaled up fluidized-bed gasifier. High heat transfer rates from bed to fore1gn particles, the thermal flywheel characteristic of the bed, and the violent mixing and agitation occuring... fluidized beds. Among the advantages are high heat transfer rates from bed to foreign particles, the bed acts as a thermal flywheel and violent mixing and agitation occur. The fluidized-bed unit 13 )ur Fluidized Sand Bed Ll pright Cylinder A...

  20. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect (OSTI)

    DeLallo, M.; Zaharchuk, R.

    1994-01-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  1. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M. (Mamaroneck, NY)

    1982-01-01T23:59:59.000Z

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  2. Sulfur removal in advanced two stage pressurized fluidized bed combustion. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Abbasian, J.; Hill, A.; Wangerow, J.R. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31T23:59:59.000Z

    The objective of this study is to obtain data on the rates and the extent of sulfation reactions involving partially sulfided calcium-based sorbents, and oxygen as well as sulfur dioxide, at operating conditions closely simulating those prevailing in the second stage (combustor) of Advanced Two-Stage Pressurized Fluidized-Bed Combustors (PFBC). In these systems the CO{sub 2} partial pressure generally exceeds the equilibrium value for calcium carbonate decomposition. Therefore, calcium sulfate is produced through the reactions between SO{sub 2} and calcium carbonate as well as the reaction between calcium sulfide and oxygen. To achieve this objective, the rates of reaction involving SO{sub 2} and oxygen (gaseous reactant); and calcium sulfide and calcium carbonate (solid reactants), will be determined by conducting tests in a pressurized thermogravimetric analyzer (HPTGA) unit. The effects of sorbent type, sorbent particle size, reactor temperature and pressure; and O{sub 2} as well as SO{sub 2} partial pressures on the sulfation reactions rate will be determined. During this quarter, samples of the selected limestone and dolomite were sulfided in the fluidized-bed reactor. These tests were conducted in both calcining and non-calcining operating conditions to produce partially-sulfided sorbents containing calcium oxide and calcium carbonate, respectively. These samples which represent the carbonizer discharge material, will be used as the feed material in the sulfation tests to be conducted in the HPTGA unit during the next quarter.

  3. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01T23:59:59.000Z

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  4. Four Rivers second generation Pressurized Circulating Fluidized Bed Combustion Project

    SciTech Connect (OSTI)

    Holley, E.P.; Lewnard, J.J. [Air Products and Chemicals, Inc. (United States); von Wedel, G. [LLB Lurgi Lentjes Babcock Energietechnik (GmbH); Richardson, K.W. [Foster Wheeler Energy Corp. (United States); Morehead, H.T. [Westinghouse Electric Corp. (United States)

    1995-04-01T23:59:59.000Z

    Air Products has been selected in the DOE Clean Coal Technology Round V program to build, own, and operate the first commercial power plant using second generation Pressurized Circulating Fluidized Bed (PCFB) combustion technology. The four Rivers Energy Project (Four Rivers) will produce up to 400,000 lb/hr steam, or an equivalent gross capacity of 95 MWe. The unit will be used to repower an Air Products chemicals manufacturing facility in Calvert City, Kentucky.

  5. NUCLA Circulating Atmospheric Fluidized Bed Demonstration Project. 1990 Annual report

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    The objective of this DOE Cooperative Agreement is to conduct a cost-shared clean coal technology project to demonstrate the feasibility of circulating fluidized bed combustion technology and to evaluate economic, environmental, and operational benefits of CFB steam generators on a utility scale. At the conclusion of the Phase 2 program, testing related to satisfying these objectives was completed. Data analysis and reporting are scheduled for completion by October 1991. (VC)

  6. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01T23:59:59.000Z

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  7. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  8. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  9. Spectral methods applied to fluidized bed combustors. Final report

    SciTech Connect (OSTI)

    Brown, R.C.; Christofides, N.J.; Junk, K.W.; Raines, T.S.; Thiede, T.D.

    1996-08-01T23:59:59.000Z

    The objective of this project was to develop methods for characterizing fuels and sorbents from time-series data obtained during transient operation of fluidized bed boilers. These methods aimed at determining time constants for devolatilization and char burnout using carbon dioxide (CO{sub 2}) profiles and from time constants for the calcination and sulfation processes using CO{sub 2} and sulfur dioxide (SO{sub 2}) profiles.

  10. Propagating Waves in a Monolayer of Gas-Fluidized Rods

    E-Print Network [OSTI]

    L. J. Daniels; D. J. Durian

    2010-11-12T23:59:59.000Z

    We report on an observation of propagating compression waves in a quasi-two-dimensional monolayer of apolar granular rods fluidized by an upflow of air. The collective wave speed is an order of magnitude faster than the speed of the particles. This gives rise to anomalously large number fluctuations dN ~ $N^{0.72 \\pm 0.04}$, which are greater than ordinary number fluctuations of N^{1/2}. We characterize the waves by calculating the spatiotemporal power spectrum of the density. The position of observed peaks, as a function of frequency w and wavevector k, yields a linear dispersion relationship in the long-time, long-wavelength limit and a wavespeed c = w/k. Repeating this analysis for systems at different densities and air speeds, we observe a linear increase in the wavespeed with increasing packing fraction with no dependence on the airflow. Although air-fluidized rods self-propel individually or in dilute collections, the parallel and perpendicular root-mean-square speeds of the rods indicate that they no longer self-propel when propagating waves are present. Based on this mutual exclusivity, we map out the phase behavior for the existence of waves vs self-propulsion as a function of density and fluidizing airflow.

  11. Pulsed atmospheric fluidized-bed combustor development. Environmental Assessment

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    Pulsed atmospheric fluidized-bed combustion (PAFBC) is a unique and innovative coal-fueled technology that has the potential to meet these conditions and provide heat and/or process steam to small industrial, commercial, institutional and residential complexes. The potential of Pulse Atmospheric Fluidized Bed Combustion (PAFBC) technology has been amply demonstrated under the sponsorship of a previous DOE/METC contract (DE-AC21-88MC25069). The environmental performance of a coal-fired laboratory-scale system (1.5 million British Thermal Units per hour) (MMBtu/hr) significantly surpassed that of conventional bubbling and circulating fluidized-bed combustion units (see Table 1 for performance comparison). Prompted by these encouraging results in combustion, sulfur capture, emissions control, and enhanced heat transfer, Island Creek Coal Company (ICC) and Baltimore Thermal Energy Corporation expressed interest in the technology and offered to participate by providing host sites for field testing. EA`s have been submitted independently for each of these field test sites. This submission addresses the preliminary testing of the PAFBC unit at Manufacturing and Technology Conversion International`s (MTCI) Baltimore, MD facility.

  12. State of the art of pressurized fluidized bed combustion systems

    SciTech Connect (OSTI)

    Graves, R.L.

    1980-09-01T23:59:59.000Z

    This report was prepared at the request of the Tennessee Valley Authority (TVA) to clarify the development status of the pressurized fluidized bed combustor (PFBC) and to place in perspective the problems which are yet to be solved before commercialization of the concept is practical. This report, in essence, supersedes the interim report published in 1979, Assessment of the State of the Art of Pressurized Fluidized Bed Combustion Systems. A brief overview of the PFBC concept is included citing potential advantages and disadvantages relative to atmospheric fluidized bed combustion (AFBC) and conventional pulverized coal plants. A survey of existing and developing PFBC experimental facilities is presented in some detail which includes the major accomplishments at the respective facilities. Recent data on plant emissions, turbine/gas cleanup systems, and overall efficiency are provided. Findings of several design studies are also discussed. The results of recent gas turbine and cascade tests have been encouraging although the full assessment of the accomplishments have not been made. The delay in construction of the Grimethorpe plant causes further delay in proof-testing full-size, rotating turbomachinery. Several parameters are recommended for further assessment in design studies including: (1) effect of turbine life on cost of power; and (2) effect of reduced gas turbine inlet temperature and pressure on cost of power.

  13. Air fluidized balls in a background of smaller beads

    E-Print Network [OSTI]

    M. E. Beverland; L. J. Daniels; D. J. Durian

    2010-12-02T23:59:59.000Z

    We report on quasi-two-dimensional granular systems in which either one or two large balls is fluidized by an upflow of air in the presence of a background of several hundred smaller beads. A single large ball is observed to propel ballistically in nearly circular orbits, in direct contrast to the Brownian behavior of a large ball fluidized in the absence of this background. Further, the large ball motion satisfies a Langevin equation with an additional speed-dependent force acting in the direction of motion. This results in a non-zero average speed of the large ball that is an order of magnitude faster than the root mean square speed of the background balls. Two large balls fluidized in the absence of the small-bead background experience a repulsive force depending only on the separation of the two balls. With the background beads present, by contrast, the ball-ball interaction becomes velocity-dependent and attractive. The attraction is long-ranged and inconsistent with a depletion model; instead, it is mediated by local fluctuations in the density of the background beads which depends on the large balls' motion.

  14. Erosion of heat exchanger tubes in fluidized beds

    SciTech Connect (OSTI)

    Johnson, E.K.; Flemmer, R.L.C.

    1991-01-01T23:59:59.000Z

    This final report describes the activities of the 3-year project entitled Erosion of Heat Exchanger Tubes In Fluidized Beds.'' which was completed at the end of 1990. Project accomplishments include the collection of a substantial body of wear data In a 24in. [times] 24in. fluidized bed, comparative wear results In a 6in. [times] 6in. fluidized bed, the development of a dragometer and the collection of a comprehensive set of drag force data in the 24in. [times] 24in. bed, Fast Fourier Transform (FFT) analysis of bubble probe data to establish dominant bubble frequencies in the 24in. [times] 24in. bed, the use of a heat flux gauge for measurement of heat transfer coefficients in the 24in. [times] 24in. bed and the modeling of the tube wear in the 24in. [times] 24in. bed. Analysis of the wear data from the 24in. square bed indicates that tube wear increases with increase in superficial velocity, and with increase in tube height. The latter effect is a result of the tubes higher up in the bed seeing greater movement of dense phase than tubes lower down In the bed. In addition, tube wear was found to decrease with increase in particle size, for constant superficial velocity. Three models of tube wear were formulated and provided acceptable prediction of wear when compared with the experimental data.

  15. Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-11-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

  16. Natural-sorbent attrition and elutriation characteristics in fluidized-bed coal combustors

    SciTech Connect (OSTI)

    Wilson, W.I.; Fee, D.C.; Myles, K.M.; Johnson, I.; Fan, L.S.

    1981-01-01T23:59:59.000Z

    Laboratory test methods have been developed to measure the attrition and elutriation characteristics of limestones in an atmospheric-pressure fluidized-bed coal combustor (AFBC) at 850/sup 0/C. The attrition constant and elutriation rate were determined for a group of limestones when the system is assumed to be at steady state; that is, after sorbent breakup due to thermal shock and decrepitation during calcination of the sorbent feed are completed. An attrition model has been developed to analyze the laboratory data to predict sorbent performance in AFBCs. The attrition model assumes that the particle disintegration occurs from the abrasive removal of material from the surface of the particle rather than by particle fracture. The attrition constants of the limestones tested ranged from 1.5 x 10/sup -6/ sec/sup -1/ to 9.2 x 10/sup -8/ sec/sup -1/, and the elutriation rate had a fractional mass loss which ranged from 8.1 x 10/sup -8/ min/sup -1/ to 1.0 x 10/sup -3/ min/sup -1/. The test methods and techniques utilized by the model are undergoing refinement to improve the accuracy of the prediction. The attrition and elutriation of a sorbent in a fluidized-bed combustor affects the sorbent performance in a complex manner. The obvious case is the extreme situation where so much sorbent material is lost from the bed via attrition and elutriation that a constant bed height cannot be maintained. Because this aspect is an important consideration in sorbent selection, standard laboratory test methods have been developed to measure the attrition and elutriation characteristics of limestones in AFBCs.

  17. Stability of flows in fluidized beds. Technical status report, December 8, 1991--March 7, 1992

    SciTech Connect (OSTI)

    Rajagopal, C.

    1992-08-01T23:59:59.000Z

    In this paper we carry out a systematic linearized stability analysis of the state of uniform fluidization for a fluid infused with granular particles. We carry out an interesting optimization procedure which leads to bounds for certain parameters, within which the state of uniform fluidization is stable. We find that this stability depends critically on the structure of the pressure-like term. (VC)

  18. Zevenhoven & Kilpinen NITROGEN 13.4.2002 4-34 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed

    E-Print Network [OSTI]

    Laughlin, Robert B.

    the nitric oxide emission, the laughing gas emission at fluidized bed combustion must be accounted for too fluidized bed combustion, where the interaction between gas and particles is more intensive than in bubbling fluidized bed combustion In fluidized bed combustion, the combustion takes place in a bed of particles

  19. Zevenhoven & Kilpinen NITROGEN 18.1.2004 4-35 4.11 Chemistry of nitrogen oxides at atmospheric fluidized bed

    E-Print Network [OSTI]

    Zevenhoven, Ron

    the nitric oxide emission, the laughing gas emission at fluidized bed combustion must be accounted for too fluidized bed combustion, where the interaction between gas and particles is more intensive than in bubbling fluidized bed combustion In fluidized bed combustion, the combustion takes place in a bed of particles

  20. Post-Combustion and Pre-Combustion CO2 Capture Solid Sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Stevens, R.W.; Robinson, Clark

    2007-11-01T23:59:59.000Z

    Combustion of fossil fuels is one of the major sources of the greenhouse gas CO2. Pressure swing adsorption/sorption (PSA/PSS) and temperature swing adsorption/sorption (TSA/TSS) are some of the potential techniques that could be utilized for removal of CO2 from fuel gas streams. It is very important to develop sorbents to remove CO2 from fuel gas streams that are applicable for a wide range of temperatures. NETL researchers have developed novel CO2 capture sorbents for low, moderate, and high temperature applications. A novel liquid impregnated solid sorbent was developed for CO2 removal in the temperature range of ambient to 60 °C. The sorbent is regenerable at 60 – 80 °C. The sorbent formulations were prepared to be suitable for various reactor configurations (i.e., fixed and fluidized bed). Minimum fluidization gas velocities were also determined. Multi-cycle tests conducted in an atmospheric bench scale reactor with simulated flue gas indicated that the sorbent retains its CO2 sorption capacity with a CO2 removal efficiency of approximately 99% and was unaffected by presence of water vapor. The sorbent was subsequently commercially prepared by Süd Chemie to determine the viability of the sorbent for mass production. Subsequent testing showed that the commercially-synthesized sorbent possesses the same properties as the lab-synthesized equivalent. An innovative solid sorbent containing mixture of alkali earth and alkali compounds was developed for CO2 removal at 200 – 315°C from high pressure gas streams suitable for IGCC systems. The sorbent showed very high capacity for CO2 removal from a gas streams containing 28% CO2 at 200 °C and at 20 atm during a lab scale reactor test. This sorbent can be regenerated at 20 atm and at 375 °C utilizing a gas stream containing steam. High pressure enhanced the CO2 sorption process. Bench scale testing showed consistent capacities and regenerability. A unique high temperature solid sorbent was developed for CO2 capture at temperatures of 500 – 700°C. Bench scale testing of the sorbent yielded very high CO2 capture capacity from a gas stream containing 10% CO2, 30% H2, 15% H2O, and 25% He. Regeneration of the sorbent is possible at 800 – 900 °C.

  1. Engineering systems analysis of pressurized fluidized-bed-combustion power systems

    SciTech Connect (OSTI)

    Graves, R.L.; Griffin, F.P.; Lackey, M.E.

    1982-04-01T23:59:59.000Z

    This effort was conducted to provde supporting data for the research and development program on pressurized fluidized bed combustor (PFBC) systems being continued under the auspices of the Office of Coal Utilization of DOE. This report deals with the first phase of the effort, designated Task 1, which was scoped to be a somewhat broad review of PFBC technology and an analysis to determine its potential and sensitivity to key development needs. Background information pertaining to the application of PFBC to the market for coal-fired technology is included. The status of development is reviewed and the deficiencies in data are identified. Responses to a survey of PFBC developers are reviewed with emphasis on the high risk areas of the PFBC concept. Some of these problems are: uncertainty of life of gas turbine components; lack of demonstration of load following; and hot solids handling. Some high risk areas, such as the gas cleanup or gas turbine systems, can be relieved by reducing the severity of design conditions such as the turbine inlet temperature. Alternate turbine designs or plant configurations are also possible solutions. Analyses were performed to determine whether the advantages held by PFBC systems in cost, efficiency, and emissions would be nullified by measures taken to reduce risk. In general, the results showed that the attractive features of the PFBC could be preserved.

  2. Mineralogy and pore water chemistry of a boiler ash from a MSW fluidized-bed incinerator

    SciTech Connect (OSTI)

    Bodenan, F., E-mail: f.bodenan@brgm.f [BRGM - French Geological Survey, Environment and Processes Division, BP 36009, 3 Av. C. Guillemin, 45060 Orleans Cedex (France); Guyonnet, D.; Piantone, P.; Blanc, P. [BRGM - French Geological Survey, Environment and Processes Division, BP 36009, 3 Av. C. Guillemin, 45060 Orleans Cedex (France)

    2010-07-15T23:59:59.000Z

    This paper presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from a municipal solid waste fluidized-bed incinerator, subject to 18 months of dynamic leaching in a large percolation column experiment. A particular focus is on the redox behaviour of Cr(VI) in relation to metal aluminium Al{sup 0}, as chromium may represent an environmental or health hazard. The leaching behaviour and interaction between Cr(VI) and Al{sup 0} are interpreted on the basis of mineralogical evolutions observed over the 18-month period and of saturation indices calculated with the geochemical code PhreeqC and reviewed thermodynamic data. Results of mineralogical analyses show in particular the alteration of mineral phases during leaching (e.g. quartz and metal aluminium grains), while geochemical calculations suggest equilibria of percolating fluids with respect to specific mineral phases (e.g. monohydrocalcite and aluminium hydroxide). The combination of leaching data on a large scale and mineralogical analyses document the coupled leaching behaviour of aluminium and chromium, with chromium appearing in the pore fluids in its hexavalent and mobile state once metal aluminium is no longer available for chromium reduction.

  3. Pressurized circulating fluidized-bed combustion for power generation

    SciTech Connect (OSTI)

    Weimer, R.F.

    1995-08-01T23:59:59.000Z

    Second-generation Pressurized Circulating Fluidized Bed Combustion (PCFBC) is the culmination of years of effort in the development of a new generation of power plants which can operate on lower-quality fuels with substantially improved efficiencies, meet environmental requirements, and provide a lower cost of electricity. Air Products was selected in the DOE Clean Coal Technology Round V program to build, own, and operate the first commercial power plant using second-generation PCFBC technology, to be located at an Air Products chemicals manufacturing facility in Calvert City, Kentucky. This paper describes the second-generation PCFBC concept and its critical technology components.

  4. The backflow cell model for fluidized bed catalytic reactors

    E-Print Network [OSTI]

    Ganapathy, E. V

    1967-01-01T23:59:59.000Z

    THE BACKFLOW CELL MODEL FOR FLUIDI2ED BED CATALYTIC REACTORS A Thesis By E. V. Ganapathy Submitted to the Graduate College of the Texas A&M University in partial fulfillment of' the requirements for the degree of MASTER OF SCIENCE May 1967... Major Subject Chemical En ineerin THE BACKFLOW CELL MODEL FOR FLUIDIZED BED CATALYTIC REACTORS A Thesis E. V. Ganapathy Approved as to style and content by: chairman of Committee ~H+d d D p t t Member Member) May 1967 SO THE BACKFLOW CELL...

  5. Four Rivers second generation pressurized circulating fluidized bed combustion project

    SciTech Connect (OSTI)

    Holley, E.P.; Lewnard, J.J. [Air Products and Chemicals, Inc., Allentown, PA (United States); Wedel, G. von; Richardson, K.W.; Morehead, H.T.

    1995-12-31T23:59:59.000Z

    Air Products has been selected in the DOE Clean Coal Technology Round 5 program to build, own, and operate the first commercial power plant using second generation Pressurized Circulating Fluidized Bed (PCFB) combustion technology. The Four Rivers Energy Project (Four Rivers) will produce approximately 70 MW electricity, and will produce up to 400,000 lb/hr steam, or an equivalent gross capacity of 95 MWe. The unit will be used to repower an Air Products chemicals manufacturing facility in Calvert City, Kentucky.

  6. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G. (Akron, OH); Weitzel, Paul S. (Canal Fulton, OH)

    1990-01-01T23:59:59.000Z

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  7. NUCLA Circulating Atmospheric Fluidized Bed Demonstration Project. Annual report, 1988

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This Annual Report on Colorado-Ute Electric Association`s NUCLA Circulating Fluidized Bed (CFB) Demonstration Program covers the period from February 1987 through December 1988. The outline for presentation in this report includes a summary of unit operations along with individual sections covering progress in study plan areas that commenced during this reporting period. These include cold-mode shakedown and calibration, plant commercial performance statistics, unit start-up (cold), coal and limestone preparation and handling, ash handling system performance and operating experience, tubular air heater, baghouse operation and performance, materials monitoring, and reliability monitoring. During this reporting period, the coal-mode shakedown and calibration plan was completed. (VC)

  8. Pressure Fluctuations as a Disgnostic Tool for Fluidized Beds.

    SciTech Connect (OSTI)

    Brown, R.C.; Schroeder, J.R.

    1997-10-28T23:59:59.000Z

    The validity of using bubbling fluidized bed (BFB) similitude parameters to match a hot BFB to a cold BFB is being studied. Sand in a BFB combustor and copper powder in cold BFB model have been analyzed and found to be out of similitude. In the analysis process, it was determined that the condition of the screen covering the pressure tap affects the quality of pressure data recorded. In addition, distributor plate design and condition will affect the hydrodynamics of the bed. Additional tests are planned to evaluate the validity of similitude concepts in BFB.

  9. Georgetown University atmospheric fluidized bed boiler cogeneration system

    SciTech Connect (OSTI)

    Podbielski, V.; Shaff, D.P.

    1991-08-01T23:59:59.000Z

    This report presents the results of one year of operation of the cogeneration system capability of the Georgetown University coal- fired, atmospheric fluidized-bed (AFB) boiler. The AFB was designed and installed under a separate contract with the US Department of Energy. The AFB project funded by DOE to demonstrate that high sulfur coal could be burned in an environmentally acceptable manner in a urban environment such as Georgetown. In addition, operational data from the unit would assist the industry in moving directly into design and construction of commercially warranted industrial size AFB boilers. 9 figs., 3 tabs.

  10. Heat transfer from a horizontal finned tube bundle in bubbling fluidized beds of small and large particles

    SciTech Connect (OSTI)

    Devaru, C.B. [Jayachamaraja College of Engineering, Mysore (India). Dept. of Mechanical Engineering; Kolar, A.K. [Indian Inst. of Technology, Madras (India). Dept. of Mechanical Engineering

    1995-12-31T23:59:59.000Z

    Steady state average heat transfer coefficient measurements were made by the local thermal simulation technique in a cold, square, bubbling air-fluidized bed (0.305 m x 0.305 m) with immersed horizontal finned tube bundles (in-line and staggered) with integral 60{degree} V-thread. Studies were conducted using beds of small (average particle diameter less than 1 mm) sand particles and of large (average particle diameter greater thin 1 mm) particles (raagi, mustard, millet and coriander). The fin pitch varied from 0.8 to 5.0 mm and the fin height varied from 0.69 to 4.4 mm. The tube pitch ratios used were 1.75 and 3.5. The influence of bed particle diameter, fluidizing velocity, fin pitch, and tube pitch ratio on average heat transfer coefficient was studied. Fin pitch and bed particle diameter are the most significant parameters affecting heat transfer coefficient within the range of experimental conditions. Bed pressure drop depends only on static bed height. New direct correlations, incorporating easily measurable quantities, for average heat transfer coefficient for finned tube bundles (in-line and staggered) are proposed.

  11. HELIUM, SOLID 1 Helium, Solid

    E-Print Network [OSTI]

    Glyde, Henry R.

    HELIUM, SOLID 1 Helium, Solid Henry R. Glyde Introduction Helium was first solidified at the famous focused on the melting curve, the specific heat, and the thermal conductivity of solid helium as a test criterion of melting does not hold in solid helium. This pioneering work up to 1957 is elegantly

  12. Incineration of biological sludge in a fluidized bed

    SciTech Connect (OSTI)

    Ku, W.C.P.

    1988-01-01T23:59:59.000Z

    Incineration rate, ash properties, and percentage destruction of the combustible material were evaluated under different operating conditions. Experimental measurements were made for temperature, air flow rate, sludge size, ash size and sludge composition. A model based on the heat transfer consideration was derived to describe the drying and devolatilization process during sludge incineration. The model assumes that the drying and devolatilization of a sludge particle is manly caused by the heat flowing into the sludge particle from the bed. Parameters affecting the simulation results included sludge size, inert particle size, sludge heat capacity, sludge heat conductivity, operating flow rate and incinerator temperature. A model developed to simulate a batch type air-sand fluidized bed considered the incineration process as being composed of three consecutive operations, namely, drying, devolatilization, and char combustion. The simulation model predicted the dynamic characteristics of sludge incineration in the bed including its percentage completion and the incinerator temperature. The effects of sludge moisture level, sludge size and incinerator operating conditions on the incinerator behavior were also evaluated. The model developed to simulate the behavior of a fluidized bed incinerator under continuous operation was capable of predicting the time to reach steady state, the stack gas composition, the percentage combustion and the auxiliary heat required under various operating conditions, including sludge feed rate and size, air feed rate, and incinerator temperature.

  13. Atmospheric fluidized bed combustor development program. Final report

    SciTech Connect (OSTI)

    Ashworth, R.A.; Melick, T.A.; Plessinger, D.A.; Sommer, T.M. [Energy and Environmental Research Corp., Orville, OH (United States); Keener, H.M. [Ohio State Univ., Columbus, OH (United States). Ohio Agricultural Research and Development Center; Webner, R.L. [Will-Burt, Orrville, OH (United States)

    1995-12-01T23:59:59.000Z

    The objective of this project was to demonstrate and promote the commercialization of a coal-fired atmospheric fluidized bed combustion (AFBC) system, with limestone addition for SO{sub 2} emissions control and a baghouse for particulate emissions control. This AFBC system was targeted for small scale industrial-commercial-institutional space and process heat applications in the 1 x 10{sup 6} to 10 x 10{sup 6} Btu/hr capacity range. A cost effective and environmentally acceptable AFBC technology in this size range would displace a considerable amount of gas/oil with coal while resulting in significant total cost savings to the owner/operators. The project itself was separated into three levels: (1) feasibility, (2--3) subsystem development and integration, and (4) proof-of-concept. In Level (1), the technical and economic feasibility of a 1 million Btu/hr coal-fired AFBC air heater was evaluated. In Level (2--3), the complete EER fluidized bed combustor (1.5 million Btu/hr) system was developed and tested. The goal or reducing SO{sub 2} emissions to 1.2 lb/10{sup 6} Btu, from high sulfur Ohio coal, was achieved by adding limestone with a Ca/S (coal) ratio of {approximately} 3.0. Finally, in Level (4), the proof-of-concept system, a 2.2 million Btu/hr unit was installed and successfully operated at Cedar Lane Farms, a commercial nursery in Ohio.

  14. Polycyclic aromatic compounds in fluidized bed combustion of coal

    SciTech Connect (OSTI)

    Walsh, P.M.; Beer, J.M.; Biermann, K.; Chiu, K.S.

    1983-08-01T23:59:59.000Z

    Polycyclic aromatic compounds (PAC) have been determined in the gas and particulate effluents from fluidized bed combustion of coal, lignite, and oil shale by a number of investigators. A bibliography of the reports of these investigations is contained in a paper by Chiu, Walsh, Beer, and Biemann (1983). The concentrations of PAC in the effluents are often quite low, but depend upon the combustor configuration and operating conditions. The goal of the present investigation is to develop a mechanism consistent with measured rates of formation and destruction of PAC in atmospheric pressure fluidized bed combustion (AFBC), so that a rational approach may be taken to adjustment of conditions for minimization of PAC in the effluents. PAC are determined in samples taken from the freeboard (space above the bed), rather than from the exhaust, to observe the evolution of the PAC distribution within the combustor. Mass fractions of the most abundant PAC observed in the freeboard during AFBC of high volatile bituminous coal were reported by Chiu, et al (1983). Some correlation of the rates of disappearance of PAC with particle concentration was noted by Dutta, Chiu, Walsh, Beer, and Biemann (1983). In the present paper theoretical estimates of the rates at which PAC might be consumed by heterogeneous reactions are compared with experimental rates estimated from PAC profiles determined by Chiu et al (1983).

  15. A Fluidized Bed Chiller: A New Approach in Making Slush-Ice

    E-Print Network [OSTI]

    Klaren, D. G.; Van Der Meer, J. S.

    production of 11000 lbs/day. The system consists of a fluidized bed chiller and a storage vessel for ice integrated within a circulation system. Through a plate-and-frame heat exchanger this cool lhermal storage system is connected to the actual user...A FLUIDIZED BED CHILLER: A NEW APPROACH IN MAKING SLUSH-ICE Dr.Ir. D.G. Klaren M.Sc. Technical Director Gebr. Scheffers B.V. Schiedam, The Netherlands ABSTRACT A fluidized bed heat exchanger already successfully applied for heat transfer...

  16. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.

    1983-02-01T23:59:59.000Z

    Trace element constituents in fly ash from an experimental atmospheric fluidized bed combustor (AFBC) are reported and compared with pulverized coal combustor (PCC) data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed using spark source mass spectrometry. Fluidized bed combustion ash was similar to PCC ash in minor and trace element composition, but AFBC ash showed less size dependence of elemental composition. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  17. Instrumentation and Evaluation of a Pilot Scale Fluidized Bed Biomass Gasification System

    E-Print Network [OSTI]

    Maglinao, Amado L

    2009-12-04T23:59:59.000Z

    A pilot scale fluidized bed biomass gasifier developed at Texas A&M University in College Station, Texas was instrumented with thermocouples, pressure transducers and motor controllers for monitoring gasification temperature and pressure, air flow...

  18. Numerical and experimental studies of IFE target layering in a cryogenic fluidized bed

    E-Print Network [OSTI]

    Boehm, Kurt Julian

    2009-01-01T23:59:59.000Z

    and the heat transfer for a fixed bed with large isometricis fixed and homogeneous over the entire bed domain. Thus,fixed, Cartesian coordinate system described in the fluidized bed

  19. Low Temperature Chemical Vapor Deposition of Zirconium Nitride in a Fluidized Bed 

    E-Print Network [OSTI]

    Arrieta, Marie

    2012-10-19T23:59:59.000Z

    The objective of this research was to design, assemble, and demonstrate the initial performance of a fluidized bed chemical vapor deposition (FB-CVD) system capable of producing thin, uniform zirconium nitride (ZrN) coatings (1 to 10 micrometers...

  20. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

  1. Empirical models of emissions and energy efficiencies of coal-fired fluidized bed power plants

    E-Print Network [OSTI]

    Gruhl, Jim

    Mass and energy balances of fluidized bed energy technologies are to a significant degree dependent upon the specific design being investigated. It is difficult to make any generally accurate comments. about these balances. ...

  2. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.; Carpenter, R.L.; Newton, G.J.

    1983-02-01T23:59:59.000Z

    Fluidized bed coal combustion is a promising technology for using coal in an environmentally acceptable manner. Trace elemental constituents in fly ash from an experimental atmospheric pressure fluidized bed combustor (AFBC) are reported and compared with pulverized-coal combustor (PCC) ash data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed by using spark source mass spectrometry.Fluidized bed combustor ash was similar to PCC ash in minor and trace element composition. However, AFBC ash showed less size dependence of elemental composition than has been reported for PCC ash. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  3. Instrumentation and Evaluation of a Pilot Scale Fluidized Bed Biomass Gasification System 

    E-Print Network [OSTI]

    Maglinao, Amado L

    2009-12-04T23:59:59.000Z

    A pilot scale fluidized bed biomass gasifier developed at Texas A&M University in College Station, Texas was instrumented with thermocouples, pressure transducers and motor controllers for monitoring gasification temperature and pressure, air flow...

  4. Fluidized bed pyrolysis of bitumen-impregnated sandstone at sub-atmospheric conditions

    SciTech Connect (OSTI)

    Fletcher, J.V.; Deo, M.D.; Hanson, F.V.

    1993-03-01T23:59:59.000Z

    A 15.2 cm diameter fluidized bed reactor was designed, built, and operated to study the pyrolysis of oil sands at pressures slightly less than atmospheric. Fluidizing gas flow through the reactor was caused by reducing the pressure above the bed with a gas pump operating in the vacuum mode. Pyrolysis energy was supplied by a propane burner, and the hot propane combustion gases were used for fluidization. The fluidized bed pyrolysis at reduced pressure using combustion gases allowed the reactor to be operated at significantly lower temperatures than previously reported. At 450{degree}, over 80% of the bitumen fed was recovered as a liquid product, and the spent sand contained less than 1% coke. The liquid product recovery system, by design, yielded three liquid streams with distinctly different properties.

  5. Fluidized bed pyrolysis of bitumen-impregnated sandstone at sub-atmospheric conditions

    SciTech Connect (OSTI)

    Fletcher, J.V.; Deo, M.D.; Hanson, F.V.

    1993-01-01T23:59:59.000Z

    A 15.2 cm diameter fluidized bed reactor was designed, built, and operated to study the pyrolysis of oil sands at pressures slightly less than atmospheric. Fluidizing gas flow through the reactor was caused by reducing the pressure above the bed with a gas pump operating in the vacuum mode. Pyrolysis energy was supplied by a propane burner, and the hot propane combustion gases were used for fluidization. The fluidized bed pyrolysis at reduced pressure using combustion gases allowed the reactor to be operated at significantly lower temperatures than previously reported. At 450[degree], over 80% of the bitumen fed was recovered as a liquid product, and the spent sand contained less than 1% coke. The liquid product recovery system, by design, yielded three liquid streams with distinctly different properties.

  6. Evaluation of models for the prediction of fluidized-bed reactor performance

    E-Print Network [OSTI]

    Frederick, John Michael

    1980-01-01T23:59:59.000Z

    on surface tension. The mechanism behind the formation of fluidized bed bubbles is strictly the circulation of the fluidizing gas within the bed material (See Fig. 5, p. 11). Eventhough there exist mechanical differences in the formation of the bubbles... of the bubble and changes in bubble rise velocity often result in bubble coalescence. In a fluidised bed the phenomena may be roughly explained by considering the wake traveling behind the bubble and coalescence occurs when the trailing bubble moves...

  7. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, C.D.; Petersen, J.N.; Davison, B.H.

    1996-07-09T23:59:59.000Z

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, and larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. 8 figs.

  8. Development of second-generation pressurized fluidized bed combustion process

    SciTech Connect (OSTI)

    Wolowodiuk, W.; Robertson, A. [Foster Wheeler Development Corp., Livingston, NJ (United States); Bonk, D. [USDOE Morgantown Energy Technology Center, WV (United States)

    1994-10-01T23:59:59.000Z

    Under the sponsorship of the United States Department of Energy, Foster Wheeler Development Corporation, and its team members, Westinghouse, Gilbert/Commonwealth, and the Institute of Gas Technology are developing second-generation pressurized fluidized bed combustion technology capable of achieving net plant efficiency in excess of 45 percent based on the higher heating value of the coal. A three-phase program entails design and costing of a 500 MWe power plant and identification of developments needed to commercialize this technology (Phase 1), testing of individual components (Phase 2), and finally testing these components in an integrated mode (Phase 3). This paper briefly describes the results of the first two phases as well as the progress on the third phase. Since other projects which use the same technology are in construction or in negotiation stages -- namely, the Power System Development Facility and the Four Rivers Energy Modernization Projects -- brief descriptions of these are also included.

  9. Sulfur capture in an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Baars, D.M.; Hunter, C.A.; Keitelman, E.N.

    1981-06-01T23:59:59.000Z

    Sulfur capture in an atmospheric fluidized-bed combustor (AFBC) both with and without recycle of fines elutriated from the bed was studied. Two empirical correlations, one by Babcock and Wilcox and the other by Westinghouse, correlate sulfur capture as a function of the calcium-to-sulfur mole ratio and gas residence time. Both correlations fit the experimental no-recycle results quite well. Of the limestones tested with no recycle, Vulcan Materials exhibits the best sulfur-capture performance. Data collected with Reed limestone indicates that recycle improves sulfur-capture compared with once-through performance. However, there is a decreasing effect on sulfur capture as the recycle rate is increased to large values. At 90% sulfur capture, the fractional reduction of fresh limestone feed attributable to recycle is 24 to 35% over a gas-residence time range of 0.7 to 0.4 s.

  10. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Petersen, James N. (Moscow, ID); Davison, Brian H. (Knoxville, TN)

    1996-01-01T23:59:59.000Z

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, as larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor.

  11. Nucla circulating atmospheric fluidized bed demonstration project. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute`s decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

  12. Testing fluidized bed incinerators for energy-efficient operation for the Southtowns Sewage Treatment Agency. Final report

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    Two methods for improving the energy efficiency of fluidized bed sludge incinerators were evaluated. The first method used paper pulp and polymer as conditioning agents for municipal sludge instead of lime and ferric chloride. Automatic control of the incinerator was the second method evaluated for energy savings. To evaluate the use of paper pulp and polymer as conditioning agents, varying quantities of paper pulp were added to the liquid sludge to determine the optimal sludge-to-paper pulp ratio. The effect of the paper pulp and polymer-conditioned sludge on plant operations also was evaluated. When compared to sludge conditioned with lime and ferric chloride, the paper pulp and polymer-conditioned sludge had similar cake release and feed characteristics, higher BTU values for the dry sludge solids, required less auxiliary fuel for incineration, and generated less ash for disposal. The paper pulp and polymer did not have any appreciable negative effects on the operation of the wastewater treatment plant. It was estimated that processing and incinerating the sludge conditioned with paper pulp and polymer resulted in a cost savings of up to $91.73 per dry ton of activated sludge solids. To evaluate the effect of automatic control, all the incinerator operating parameters including air flow rates, fuel oil feed rates, and sludge feed rates, were automatically monitored and controlled to minimize auxiliary fuel oil use and to keep the incinerator running at optimal conditions. Although effective, the estimated cost savings for automatic control of the incinerator were small.

  13. Metal behavior during fluidized bed thermal treatment of soil

    SciTech Connect (OSTI)

    Ho, T.C.; Lee, H.T.; Shiao, C.C.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering; Bostick, W.D. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.

    1995-12-31T23:59:59.000Z

    The Superfund dumpsites are frequently composed of soils contaminated with hazardous organic constituents and toxic heavy metals. While thermal treatment is an effective method of remediating the contaminated soils, the major environmental concerns are the emissions of toxic metal fumes during the treatment and the leaching of metals from the treated soil. The US EPA has reported that metals can account for almost all of the identified cancer risks from waste incineration systems. Research leading to better understanding of their behavior and better controlling of their emissions is urgently needed. In this study, the behavior of metals during the fluidized bed thermal treatment of artificially prepared metal-contaminated clay was experimentally and theoretically investigated. The objective of the study was to evaluate the effects of operating conditions on metal volatilization and metal leachability associated with the process. Metal experiments were carried out in a well instrumented 76 mm (3 inch) i.d. fluidized bed incinerator. The metals involved were compounds of lead and cadmium and the operating parameters included metal concentration, air flow rate, treatment temperature and treatment duration. The observed results indicated that metal volatilization is mainly a function of treatment temperature and treatment duration. The degree of volatilization was observed to range from 5 to 40% depending on the operating conditions. Cadmium leachability was observed to be relatively high compared to that of lead. In addition to the experimental study, a theoretical model based on the laws of heat and mass transfer operations and reaction kinetics was derived to simulate the metal volatilization process. The derived model was found to predict reasonably well the experimental observations.

  14. A study of the economics of conveying solid matter by fluidized particle flow

    E-Print Network [OSTI]

    Boy, Hans Peter

    1966-01-01T23:59:59.000Z

    of Petroleum Engineering, who aided in critically reading the paper. In addition, the writer would like to thank Donald H. Campbell, a fellow student, for aid in microscopic rock and sediment study and interpretation. Geology of the Northwest Wortham Area... sedimentary rocks are exposed within the area. These strata strike north-northeast and dip southeast less than one degree (less than 90 feet per mile). The oldest unit exposed within the area is the Kemp Formation of the Navarro Group (Upper Cretaceous...

  15. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; John Smith

    2008-05-31T23:59:59.000Z

    On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new particulate filtration technologies. Major tasks during this period of the funded project's timeframe included: (1) Conducting pretests on a laboratory-scale simulated FBC system; (2) Completing detailed design of the bench-scale CFBC system; (3) Contracting potential bidders to fabricate of the component parts of CFBC system; (4) Assembling CFBC parts and integrating system; (5) Resolving problems identified during pretests; (6) Testing with available Powder River Basin (PRB) coal and co-firing of PRB coal with first wood pallet and then chicken wastes; and (7) Tuning of CFBC load. Following construction system and start-up of this 0.6 MW CFBC system, a variety of combustion tests using a wide range of fuels (high-sulfur coals, low-rank coals, MSW, agricultural waste, and RDF) under varying conditions were performed to analyze and monitor air pollutant emissions. Data for atmospheric pollutants and the methodologies required to reduce pollutant emissions were provided. Integration with a selective catalytic reduction (SCR) slipstream unit did mimic the effect of flue gas composition, including trace metals, on the performance of the SCR catalyst to be investigated. In addition, the following activities were also conducted: (1) Developed advanced mercury oxidant and adsorption additives; (2) Performed laboratory-scale tests on oxygen-fuel combustion and chemical looping combustion; and (3) Conducted statistical analysis of mercury emissions in a full-scale CFBC system.

  16. Fluidized-Bed Waste-Heat Recovery System development. Semiannual report, 1 August 1982-31 January 1983

    SciTech Connect (OSTI)

    Cole, W.E.; DeSaro, R.; Joshi, C.

    1983-02-01T23:59:59.000Z

    The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, a recirculating medium is heated by the flue gas in a fluidized bed. The hot medium is then removed from the bed and placed in a second fluidized bed where it is fluidized by the combustion air. Through this process, the combustion air is heated. The cooled medium is then returned to the first bed. Initial development of this concept is for the aluminum smelting industry.

  17. Dispersion and combustion of a bitumen-based emulsion in bubbling fluidized bed

    SciTech Connect (OSTI)

    Miccio, F.; Miccio, M.; Repetto, L.; Gradassi, A.T.

    1999-07-01T23:59:59.000Z

    An experimental program was carried out with ORIMULSION{reg{underscore}sign} as a part of an R and D project aimed at demonstrating the feasibility of contemporary combustion and desulfurization in atmospheric bubbling fluidized bed. ORIMULSION is a bitumen-based emulsion that is produced in Venezuela's Orinoco region with 30% w/w water and about 3% w/w sulfur content (on a dry basis). Two atmospheric, pre-pilot, bubbling bed units were used: a 140 mm ID reactor and a 370 mm ID combustor. The first one provides qualitative and quantitative information on dispersion and in-bed retention of ORIMULSION: to this end the bed is operated batchwise in hot tests without combustion and the fuel can be injected into the bed with or without a gaseous atomization stream. With the second one, steady-state combustion tests are carried out under typical conditions of bubbling FBC. The outcome of the experiments and significance of the results are fully discussed in the paper with reference to the ORIMULSION combustion mechanism. Among the other findings, the following ones appear particularly relevant. (1) A carbon condensed phase is actually formed with the structure of tiny carbon deposits on bed particles, but at a very low rate, as a consequence, combustion (and pollutant formation) is dominated by homogeneous mechanisms. (2) Combustion efficiency is always very high, with values approaching 100% in those tests with higher excess air. (3) The in-bed combustion efficiency is enhanced by those fuel injection conditions that lead to dispersion into fine droplets and to effective mixing within the bed; therefore, contrarily to the case of water suspensions of solid fuels, intense atomization of ORIMULSION is recommended.

  18. Solids Accumulation Scouting Studies

    SciTech Connect (OSTI)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.

    2012-09-26T23:59:59.000Z

    The objective of Solids Accumulation activities was to perform scaled testing to understand the behavior of remaining solids in a Double Shell Tank (DST), specifically AW-105, at Hanford during multiple fill, mix, and transfer operations. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles containing plutonium could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste staging tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids: Gibbsite, Zirconia, Sand, and Stainless Steel, with stainless steel particles representing the heavier particles, e.g., plutonium, and supernatant were charged to the test tank and rotating liquid jets were used to mix most of the solids while the simulant was pumped out. Subsequently, the volume and shape of the mounds of residual solids and the spatial concentration profiles for the surrogate for heavier particles were measured. Several techniques were developed and equipment designed to accomplish the measurements needed and they included: 1. Magnetic particle separator to remove simulant stainless steel solids. A device was designed and built to capture these solids, which represent the heavier solids during a waste transfer from a staging tank. 2. Photographic equipment to determine the volume of the solids mounds. The mounds were photographed as they were exposed at different tank waste levels to develop a composite of topographical areas. 3. Laser rangefinders to determine the volume of the solids mounds. The mounds were scanned after tank supernatant was removed. 4. Core sampler to determine the stainless steel solids distribution within the solids mounds. This sampler was designed and built to remove small sections of the mounds to evaluate concentrations of the stainless steel solids at different special locations. 5. Computer driven positioner that placed the laser rangefinders and the core sampler in appropriate locations over solids mounds that accumulated on the bottom of a scaled staging tank where mixing is poor. These devices and techniques were effective to estimate the movement, location, and concentrations of the solids representing heavier particles and could perform well at a larger scale The experiment contained two campaigns with each comprised of ten cycles to fill and empty the scaled staging tank. The tank was filled without mixing, but emptied, while mixing, in seven batches; the first six were of equal volumes of 13.1 gallons each to represent the planned fullscale batches of 145,000 gallons, and the last, partial, batch of 6.9 gallons represented a full-scale partial batch of 76,000 gallons that will leave a 72-inch heel in the staging tank for the next cycle. The sole difference between the two campaigns was the energy to mix the scaled staging tank, i.e., the nozzle velocity and jet rotational speed of the two jet pumps. Campaign 1 used 22.9 ft/s, at 1.54 rpm based on past testing and Campaign 2 used 23.9 ft/s at 1.75 rpm, based on visual observation of minimum velocity that allowed fast settling solids, i.e., sand and stainless steel, to accumulate on the scaled tank bottom.

  19. ME 290D Solid Modeling, Fall 2014 http://www.me.berkeley.edu/~mcmains/290D/

    E-Print Network [OSTI]

    McMains, Sara

    -making/Casting Morphing 3D Printing Fixturing Tolerancing Tools & Techniques drawn from: Solid modeling Graph

  20. IEEE TRANSACTIONS ON CONTROL SYSTEMS TECHNOLOGY, VOL. 8, NO. 2, MARCH 2000 247 A Model of a Bubbling Fluidized Bed Combustor

    E-Print Network [OSTI]

    Campi, Marco

    of NO and an improvement in the desulphurization process (the limestone present in the fluidized bed reacts with SO2

  1. Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-12-01T23:59:59.000Z

    Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

  2. Scaling of pressurized fluidized beds. First quarterly progress report, October 1, 1992--January 15, 1993

    SciTech Connect (OSTI)

    Glicksman, L.; Farrell, P.

    1993-09-01T23:59:59.000Z

    Some preliminary work has been done to develop potential cold scale model designs to simulate the bed hydrodynamics of the American Electric Power Tidd pressurized bubbling fluidized bed combustor. The first design is based on the full set of scaling parameters presented in Equation (1), the second design was developed using the simplified set of scaling parameters given in Equation (2). The first design is roughly a 1:1 representation of a section of the core of the Tidd bed combustor. The additional flexibility provided by the simplified set of scaling parameters is particularly useful for developing experimental models of pressurized fluidized bed combustors where the full set of scaling relationships does not provide any reduction in the size of the models. Both the full and the simplified set of scaling relationships have been verified for applications to circulating fluidized bed combustors operating at atmospheric pressure. Currently there is a interest in fluidized bed combustors which operate at elevated pressures ({approximately}12 atm) for combined-cycle applications. One of the primary goals of this stud r is to verify both the till set and the simplified set of scaling relationships for applications to pressurized bubbling fluidized bed combustors.

  3. A Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System for Effective Domestic

    E-Print Network [OSTI]

    A Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System treatment process, consisting of microbial fuel cells and an anaerobic fluidized bed membrane bioreactor that is currently required for typical activated sludge or aerobic membrane bioreactor processes. In addition, MFCs

  4. Scaled-bed modeling for fluidized-bed combustors. Semi-annual report, October 1, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Fitzgerald, T.J.; Crane, S.D.

    1981-03-01T23:59:59.000Z

    Progress is reported in developing scaled models of coal-fired fluidized-bed combustors which can be used with confidence to obtain performance data for predicting the performance of full scale units. Construction of two 1/4 scale atmospheric pressure fluidized bed combustors is nearing completion. (LCL)

  5. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  6. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS

    SciTech Connect (OSTI)

    Jantzen, C

    2006-01-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

  7. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, J.; Koskinen, J.

    1995-08-22T23:59:59.000Z

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  8. Characterization of fuels for atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Daw, C.S. (Oak Ridge National Lab., TN (USA)); Rowley, D.R.; Perna, M.A. (Babcock and Wilcox Co., Alliance, OH (USA). Research Center); Stallings, J.W. (Electric Power Research Inst., Palo Alto, CA (USA)); Divilio, R.J. (Combustion Systems, Inc., Silver Spring, MD (USA))

    1990-01-01T23:59:59.000Z

    The Electric Power Research Institute (EPRI) has sponsored a fuels characterization program for the past several years with the intention of assisting utilities and boiler manufacturers in evaluating fuel quality impact on atmospheric fluidized bed combustion (AFBC) performance. The goal has been to provide an improved framework for making fuel switching decisions and consolidating operating experience. Results from this program include a set of bench-scale testing procedures, a fuel characterization data base, and a performance simulation model that links fuel characteristics to combustion performance. This paper reviews the major results of the fuels characterization program. The testing procedures, data base, and performance simulation models are briefly described and their application illustrated with examples. Performance predictions for the B W 1-ft{sup 2} bench-scale AFBC and the Tennessee Valley Authority (TVA) 20 MW(e) AFBC Pilot Plant are compared with actual test data. The relationship of coal rank to combustion is discussed. 11 refs., 12 figs., 5 tabs.

  9. Development of a fluidized bed air heater. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-11-01T23:59:59.000Z

    The development and design of a coal-fired atmospheric fluidized bed combustion (AFBC) air heater is described. Clean air at low pressure is heated by passing it through tubes placed in the bed of the combustor. The purpose of the program was to develop coal-fired equipment that could provide clean hot air for industrial process applications. Development was carried out using two AFBC test units. The first had a bed of 2.25 ft/sup 2/ and the second a bed of 18 ft/sup 2/. The latter incorporated full-scale components applicable to a system of 28 x 10/sup 6/ Btu/hr output. Approximately 180 runs for a total of 2000 hours of operation were made. The delivered air temperature was 800/sup 0/F with heat exchanger tubes operated at 1300/sup 0/F. Results of the test program and a description of the design concepts are presented. A heating system design was carried out for a specific manufacturing plant located in Minnesota. The system would furnish hot air at 800/sup 0/F and hot water at 250/sup 0/F for process and space heating needs. Results of this design study are summarized. 56 figs., 26 tabs.

  10. Atmospheric fluidized-bed combustion testing of western Kentucky limestones

    SciTech Connect (OSTI)

    Zimmerman, G.P.; Holcomb, R.S.; Guymon, R.H.

    1982-09-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) is studying and testing the burning of coal in an atmospheric fluidized-bed combustor (AFBC) as a means of generating electricity and/or process heat in an environmentally acceptable manner. The abundant, high-sulfur coal resources in this country can be utilized effectively in such a system. The ORNL test program supporting the 20-MW(e) AFBC pilot plant planned for operation by the Tennessee Valley Authority (TVA) in 1982 is described. During the test program 625 hours of coal combustion were accumulated in a 25-cm-diam bench scale AFBC. The fuel was Kentucky No. 9 coal with about 4% sulfur. Five different limestones from the Western Kentucky area were tested for their ability to reduce sulfur dioxide emissions. The bench scale combustor was operated under a variety of conditions including changes in bed temperature, bed height and superficial velocity. At a superficial velocity of 1.2 m/s, four of the five limestones achieved 90% sulfur retention with weight ratios of limestone feed to coal feed near 0.40:1 under no recycle (once through) operation. Carbon utilization (based on carbon loss data) averaged 84% for these tests. Two of the more promising stones were tested by recycling the material elutriated from the combustor. The amount of fresh limestone required for 90% sulfur retention was reduced by up to 50%. Carbon utilization approaching 98% was obtained under these conditions.

  11. (Pulsed atmospheric fluidized bed combustion (PAFBC)). [Comparing PAFBC vs. AFBC

    SciTech Connect (OSTI)

    Not Available

    1989-05-01T23:59:59.000Z

    The fourth Quarterly Technical Progress Report presents the results of work accomplished during the period February 6 through April 30, 1989. the overall objective of the program is the development of a pulsed atmospheric, fluidized bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this past quarter, a baseline for comparing PAFBC vs. AFBC performance was established and the initial series of PAFBC coal-fired combustion tests was completed. The AFBC baseline was representative of bubbling bed units with the exception of emissions which were somewhat higher and attributable to the size constraints of the AFBC unit. However, it still provided a valid baseline for referencing and optimizing PAFBC performance. Initial coal combustion tests in the pulsed fluid-bed verified enhanced performance in comparison to the non-pulsed beds, providing reduced NO{sub x}, CO, and SO{sub 2} emissions as well as higher steam generation rates and considerably lower entrainment losses. 9 figs., 4 tabs.

  12. Modules for estimating solid waste from fossil-fuel technologies

    SciTech Connect (OSTI)

    Crowther, M.A.; Thode, H.C. Jr.; Morris, S.C.

    1980-10-01T23:59:59.000Z

    Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solid wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides.

  13. Rivesville multicell fluidized bed boiler. Annual technical progress report. July 1978-June 1979

    SciTech Connect (OSTI)

    Not Available

    1980-08-01T23:59:59.000Z

    Design, construction and test program of a 300,000 lb/hr steam generating capacity multicell fluidized bed boiler (MFB), as a pollution free method of burning high-sulfur or highly corrosive coals, is being carried out. The concept involves burning fuels such as coal, in a fluidized bed of limestone particles that react with the sulfur compounds formed during combustion to reduce air pollution. Nitrogen oxide emissions are also reduced at the lower combustion temperatures. The CaSO/sub 4/ produced in the furnace is discharged with the ash or regenerated to CaO for reuse in the fluidized bed. Information is presented on continued operation of the Rivesville MFB steam generating plant in a commercial mode and for determining performance and emission characteristics; studies and tests on flyash characterization and reinjection, fuel feed eductors and needles, air distributor, corrosion-erosion and sulfur capture; engineering studies to improve MFB performance and reliability.

  14. Analysis and characterization of atmospheric fluidized-bed-combustion agglomerates. Final report

    SciTech Connect (OSTI)

    Brekke, D.W.; Karner, F.R.

    1982-06-01T23:59:59.000Z

    The combustion of high-sodium low-rank coal in an Atmospheric Fluidized Bed Combustor (AFBC) can produce agglomeration of varying severity. Agglomerates and bed materials produced by a 0.2 m/sup 2/ AFBC were studied by polarized light microscopy, scanning electron microscopy, and electron microprobe analysis of thin sections. Bulk samples were studied using x-ray diffraction and x-ray fluorescence techniques. A physio-chemical or geochemical approach was used to characterize the materials and to postulate a mechanism of formation of the agglomerates. Quartz bed materials typically have nodular ash coatings with a matrix of finer sulfate ash richer in calcium and sulfur. Quartz bed agglomerates have additional calcium-rich sulfur-poor glass binding the grains together. Limestone bed materials typically have nodular ash coatings and have concentric alteration zones of calcium-rich areas with additional sulfur, iron, and sodium. Limestone agglomerates have additional sulfation and masses of coarse CaSO/sub 4/ crystals. Agglomerate formation in quartz bed materials follows a 4-stage process: an initial ash coating of about 50 microns thickness; thickened nodular coatings and initial sulfation; initial agglomeration by a cement of sulfated aluminosilicate ash; and bonding by recrystallized sulfated ash which has partly melted and solidified. Agglomerate formation in limestone bed materials follows a 3-stage process: initial bed grain alteration or calcining and sulfation producing concentric zones; thickened nodular ash coatings and continued sulfation; and agglomeration and growth of large CaSO/sub 4/ crystals. The agglomeration process is believed to be dependent upon temperature excursions caused by ash buildup in the bed with accompanying interaction between ash and bed material. Sodium appears to play a critical but presently largely unknown, role in the reactions producing agglomerates.

  15. Environmental assessment: source test and evaluation report - B and W/Alliance atmospheric fluidized-bed combustor. Final report

    SciTech Connect (OSTI)

    Kindya, R.J.; Hall, R.R.; Young, C.W.; Fennelly, P.

    1981-04-01T23:59:59.000Z

    The report gives results of a comprehensive emission sampling and analysis of a pilot-scale, atmospheric-pressure, coal-fired, fluidized-bed combustor (AFBC). Screening data on organic and inorganic pollutants and indications of biological activity were obtained. The Babcock and Wilcox/Electric Power Research Institute AFBC at Alliance, OH. (B and W/EPRI/Alliance), with a coal-firing capacity of 880 kg/hr was tested. Air pollutant emissions of trace elements were measured upstream of particulate controls. Assuming a control efficiency of 99.9%, necessary to meet the utility boiler Federal NSPS for particulate of 13 ng/J, emissions of trace elements are not significant. Elemental concentrations do not appear to be significantly different from other FBCs or conventional coal combustion systems. Limited further analyses for specific polynuclear aromatic compounds indicate that emissions of these compounds are probably of no concern. Analysis of laboratory-generated leachates from solid waste samples reveals that trace metal concentrations are well below Federal hazardous waste criteria. Positive test results for mutagenicity and cytotoxicity screening tests require further investigation.

  16. Refractory experience in circulating fluidized bed combustors, Task 7. Final report

    SciTech Connect (OSTI)

    Vincent, R.Q.

    1989-11-01T23:59:59.000Z

    This report describes the results of an investigation into the status of the design and selection of refractory materials for coal-fueled circulating fluidized-bed combustors. The survey concentrated on operating units in the United States manufactured by six different boiler vendors: Babcock and Wilcox, Combustion Engineering, Foster Wheeler, Keeler Dorr-Oliver, Pyropower, and Riley Stoker. Information was obtained from the boiler vendors, refractory suppliers and installers, and the owners/operators of over forty units. This work is in support of DOE`s Clean Coal Technology program, which includes circulating fluidized-bed technology as one of the selected concepts being evaluated.

  17. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16T23:59:59.000Z

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  18. Plant response to FBC waste-coal slurry solid mixtures. [Quarterly] technical report, December 1--February 28, 1994

    SciTech Connect (OSTI)

    Darmody, R.G. [Illinois Univ., Urbana, IL (United States); Dunker, R.E. [Illinois Univ., Urbana, IL (United States). Dept. of Agronomy; Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-06-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. Our approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. This is the second quarter of the project. We have designed the experiment, secured greenhouse space, purchased the seeds, collected, dried, and are analyzing the FBC and CSS samples. The samples represent a typical range of properties. We retrieved two FBC and two CSS samples. One CSS sample had a relatively high CaCO{sub 3} content relative to the pyrite content and will require no FBC to neutralize the potential acidity. The other CSS sample will require from 4.2 to 2.7% FBC material to neutralize its potential acidity.

  19. Alexandria fluidized-bed process-development plant: bubble characteristics

    SciTech Connect (OSTI)

    Not Available

    1982-12-01T23:59:59.000Z

    Recent studies at DOE's Alexandria Atmospheric Fluidized-Bed Combustion (AFBC) Process Development Unit (PDU) have involved experimental verifications of predictions from the Massachusetts Institute of Technology's Coal AFBC Systems Model. Although Model predictions were quite accurate in many instances, there appeared to be several significant discrepancies between predicted values and association experimental data from the 3' x 3' (nominal) combustor at Alexandria. Experimental work at Alexandria related to the MIT Model was initiated in 1980. Readers should consult previous reports for an evaluation of the Model and a comparison between the Model predictions and Alexandria experimental data. As a result of these studies, a number of information gaps within the Model's database were identified, primarily related to the fluid dynamics submodel, which might account for some of the discrepancies noted. In an attempt to support further development and calibration of the MIT Model, facilities at the Alexandria PDU were committed to providing experimental data to alleviate some of the information gaps. The specific information gap focused upon during the period of January to August 1982 involved the bubble growth submodel within the fluid dynamics portion. The specific objective involved a series of tests designed to measure bubble characteristics within both cold and hot beds. Measurements were made under a variety of different conditions. The insights gained from the bubble characteristic related testing have been passed on to DOE and MIT, and used as the basis for implementing additional model refinements. Additional model verification activity is being carried out by DOE/METC. It is recognized that additional work will be necessary for the FBC Model to achieve the goal of being a useful aid for boiler designers.

  20. Pressurized fluidized-bed hydroretorting of Eastern oil shales

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. (Institute of Gas Technology, Chicago, IL (United States)); Schultz, C.W. (Alabama Univ., University, AL (United States)); Parekh, B.K. (Kentucky Univ., Lexington, KY (United States)); Misra, M. (Nevada Univ., Reno, NV (United States)); Bonner, W.P. (Tennessee Technological Univ., Cookeville, TN (United States))

    1992-11-01T23:59:59.000Z

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  1. Voidage and pressure profile characteristics of sand-iron ore-coal-FCC single-particle systems in the riser of a pilot plant circulating fluidized bed

    SciTech Connect (OSTI)

    Das, M.; Meikap, B.C.; Saha, R.K. [Indian Institute for Technology, Kharagpur (India). Dept. for Chemical Engineering

    2008-06-15T23:59:59.000Z

    Hydrodynamic behaviors of single system of particles were investigated in a circulating fluidized bed (CFB) unit. Particles belonging to Geldart groups A and B like sand of various sizes (90, 300, 417, 522, 599, and 622 mu m), FCC catalyst (120 mu m), iron ore (166 and 140 {mu} m), and coal (335 and 168 {mu} m) were used to study the hydrodynamic characteristics. Superficial air velocity used in the present study ranged between 2.01 and 4.681 m/s and corresponding mass fluxes were 12.5-50 kg/(m{sup 2} s). A CFB needs the creation of some special hydrodynamic conditions, namely a certain combination of superficial gas velocity, solids circulation rate, particle diameter, density of particle, etc. which can give rise to a state wherein the solid particles are subjected to an upward velocity greater than the terminal or free fall velocity of the majority of the individual particles. The hydrodynamics of the bed was investigated in depth and theoretical analysis is presented to support the findings. Based on gas-solid momentum balance in the riser, a distinction between apparent and real voidage has been made. The effects of acceleration and friction on the real voidage have been estimated. Results indicated a 0.995 voidage for higher superficial gas velocity of 4.681. m/s.

  2. Solid electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA)

    1993-06-15T23:59:59.000Z

    This invention pertains to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized (encapsulated) in a solid organic polymer matrix. In particular, this invention relates to solid polymer electrolytes derived by immobilizing complexes (solvates) formed between a Li salt such as LiAsF.sub.6, LiCF.sub.3 SO.sub.3 or LiClO.sub.4 and a mixture of aprotic organic solvents having high dielectric constants such as ethylene carbonate (EC) (dielectric constant=89.6) and propylene carbonate (PC) (dielectric constant=64.4) in a polymer matrix such as polyacrylonitrile, poly(tetraethylene glycol diacrylate), or poly(vinyl pyrrolidinone).

  3. Performance of the Fluidized Bed Steam Reforming product under hydraulically unsaturated conditions

    SciTech Connect (OSTI)

    Neeway, James J [ORNL] [ORNL; Rod, Kenton A. [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Bowden, Mark E [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Pierce, Eric M [ORNL] [ORNL; Qafoku, Nikolla [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Williams, Benjamin D [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Brown, Christopher F [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL)

    2014-01-01T23:59:59.000Z

    Several candidates for supplemental low-activity waste (LAW) immobilization at the Hanford site in Washington State, USA are being considered. One waste sequestering technology considered is Fluidized Bed Steam Reforming (FBSR). The granular product resulting from the FBSR process is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals with a 1:1:1 molar ratio of Na, Al and Si. To demonstrate the durability of the product, which can be disposed of at the unsaturated Integrated Disposal Facility (IDF) at Hanford, a series of tests has been performed using the Pressurized Unsaturated Flow (PUF) system, which allows for the accelerated weathering of the solid materials. The system maintains hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that will be present at the IDF. Two materials were tested using the system: 1) the FBSR granular product and 2) the FBSR granular product encapsulated in a geopolymer to form a monolith. Results of the experiments show a trend of relatively constant effluent concentration of Na, Si, Al, and Cs as a function of time from both materials. The elements I and Re show a steady release throughout the yearlong test from the granular material but their concentrations seem to be increasing at one year from the monolith material. This result suggests that these two elements may be present in the sodalite cage structure rather than in the predominant nepheline phase because their release occurs at a different rate compared to nepheline phase. Also, these elements to not seem to reprecipitate when released from the starting material. Calculated one-year release rates for Si are on the order of 10 6 g/(m2 d) for the granular material and 10 5 g/(m2 d) for the monolith material while Re release is seen to be two orders of magnitude higher than Si release rates. SEM imaging and XRD analysis show how the alteration of the two materials is dependent on their depth in the column. This phenomenom is a result of depth-dependent solution concentrations giving rise chemical environments that may be supersaturated with respect to a number of mineral phases.

  4. Factors in reactor design for carbon dioxide capture with solid, regenerable sorbents

    SciTech Connect (OSTI)

    Hoffman, J.S.; Richards, G.A.; Pennline, H.W.; Fischer, Daniel (Mid-Atlantic Technology Research & Innovation Center, South Charleston, WV); Keller, George (Mid-Atlantic Technology Research & Innovation Center, South Charleston, WV)

    2008-06-01T23:59:59.000Z

    Fossil-fuel burning power plants, which produce a substantial amount of electric power within the United States, are point sources that can emit significant quantities of carbon dioxide (CO2). In a carbon sequestration scenario, the CO2 must first be captured from the point source, or flue gas, and then be permanently stored. Since the capture/separation step dominates the cost of sequestration, various capture/separation technologies are being investigated, and regenerable, solid sorbents are the basis for one promising technique for capturing CO2 from flue gas. The solid sorbent must be able to absorb the CO2 in the first step and then be regenerated by releasing the CO2 in the second step. Due to the low operating pressure of a conventional pulverized coal-fired combustor and its subsequent low partial pressure of CO2, it is envisioned that temperature swing absorption is applicable to the sorbent capture technology. Various CO2 capture sorbents are being examined in this research area, for example physical adsorbents as well as chemical absorbents. However, with respect to process development, various reactor configurations are presently being considered. The reactor designs range from stationary beds of sorbent to those systems where the sorbent is transported between the absorber and regenerator. Emphasis is placed on design implications of employing a regenerable solid sorbent system. Key sorbent parameters required for the sorbents have been identified, including the heat of adsorption, heat capacity of the solid, delta CO2 loading between the absorption and regeneration steps, and any role co-sorption of competitive gases, such as moisture, may play. Other sorbent properties, such as the effect of acid gases within the flue gas or the attrition of the sorbent, must be considered in the reactor design. These factors all impact the reactor design for a particular type of sorbent. For a generic sorbent, reactor designs have been formulated, including a stationary, isothermal reactor, a fluidized bed, and a moving bed. Through calculations, benefits and disadvantages of the designs have been outlined. The implication of the sorbent properties (and thus desired experimental information) on sorbent reactor design are described, and recommendations for operation of these types of capture systems are discussed.

  5. Investigation of chemical looping combustion by solid fuels. 1. Process analysis

    SciTech Connect (OSTI)

    Yan Cao; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2006-10-15T23:59:59.000Z

    This paper is the first in a series of two, where we present the concept of a CLC process of solid fuels using a circulating fluidized bed with three loop seals. The riser of this circulating fluidized bed was used as the oxidizer of the oxygen carrier; one of the loop seals was used as the reducer of the oxygen carrier and the separator for ash and oxygen carrier, and the other two loop seals were used for pressure balance in the solid recycle process. Pressure profiles of recycled solids using this process are presented in detail. For the development of an oxygen carrier, we focused on the establishment of a theoretical frame of oxygen transfer capability, reaction enthalpy, a chemical equilibrium, and kinetics. Analysis results indicated that Cu-, Ni-, and Co-based oxygen carriers may be the optimum oxygen carriers for the CLC of solid fuels. Thermodynamic analysis indicated that CO{sub 2} can be concentrated and purified to at least 99% purity for the gas-solid reaction mode or even higher for the solid-solid reaction mode on the basis of the selected oxygen carriers. A Cu-based oxygen carrier is the choice that has the potential to make the reducer self-sustaining or autothermal because of its exothermic nature during reduction. This would be beneficial for simplifying the operation of the reducer. The tendency of the Cu-based oxygen carriers to agglomerate can be eliminated by decreasing the operating temperature in the CLC system. In the second part of the series, we will evaluate the reduction kinetics of selected Cu-based oxygen carriers by coal and other 'opportunity solid fuels' using a simultaneous differential scanning calorimetry-thermogravimetric analysis to simulate a microreactor, using an X-ray diffractometer and a scanning electron microscope to characterize the solid residues, and a thermogravimetric analysis coupled with mass spectra to characterize the evolved gas compositions. 46 refs., 5 figs., 2 tabs.

  6. FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS

    E-Print Network [OSTI]

    , and gasification reactions. Our fixed-bed experiments showed that the carbohydrate-derived fraction of poplar-fluidizable (fixed-bed) commercial catalysts.1 These multicomponent catalysts, which generally contain Ni, K, Ca-Chemie manufactured the fixed-bed catalyst from which the ground and sieved catalyst was made. This material consisted

  7. Alumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed reactor

    E-Print Network [OSTI]

    George, Steven M.

    /high-temperature (HP/HT) synthesis methods [4­7] led to the discovery of polycrystalline diamond grit and the manufacture of polycrystalline diamond compact (PDC) materials [8]. PDC cutters are well known and widely usedAlumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed

  8. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01T23:59:59.000Z

    Operation of the 100,000 lb/hr capacity, coal fired fluidized bed steam generator at Georgetown University began in July 1979. This project, which was co-funded by Georgetown University and the U. S. Department of Energy, involved expansion...

  9. Operating Experience with a Large Fluidized-Bed Gasifier of Woodwaste

    E-Print Network [OSTI]

    Guard, R. F. W.

    1982-01-01T23:59:59.000Z

    of natural gas for his factory. He ordered an Omnifuel fluidized-bed gasifier, which has been in operation since April, 1981, and which is currently believed to be the largest commercial biomass gasifier in operation with a rating of 80 million BTU...

  10. FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    HEWITT WM

    2011-04-08T23:59:59.000Z

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

  11. Materials performance in coal-fired fluidized-bed combustion environments

    SciTech Connect (OSTI)

    Natesan, K.

    1993-07-01T23:59:59.000Z

    Development of cogeneration systems that involve combustion of coal in a fluidized bed for the generation of electricity and process heat has been in progress for a number of years. This paper addresses some of the key components in these systems, materials requirements/performance, and areas where additional effort is needed to improve the viability of these concepts for electric power generation.

  12. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University 

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01T23:59:59.000Z

    of the heating and cooling plant with this new coal fired facility. Previously existing units at the University heating and cooling plant normally fire natural gas. The fluidized bed steam generating facility at Georgetown University is the only new coal fired...

  13. Performance and gas cleanup criterion for a cotton gin waste fluidized-bed gasifier

    E-Print Network [OSTI]

    Craig, Joe David

    1980-01-01T23:59:59.000Z

    feedstock, preferably used with very little preprocessing; however, the design should be able to handle other biomass feedstocks with little or no modification. The design heating value of gin waste is 16. 3 MJ/Kg. 2) It should be a fluidized bed type...

  14. Characterization of Biofilm in 200W Fluidized Bed Reactors

    SciTech Connect (OSTI)

    Lee, Michelle H.; Saurey, Sabrina D.; Lee, Brady D.; Parker, Kent E.; Eisenhauer, Emalee ER; Cordova, Elsa A.; Golovich, Elizabeth C.

    2014-09-29T23:59:59.000Z

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry evaluations, a more complete understanding of the balance between system additions (nutrients, groundwater) and biology can be achieved, thus increasing long-term predictions of performance. These analyses uniquely provide information that can be used in optimizing the overall performance, efficiency, and stability of the system both in real time as well as over the long-term, as the system design is altered or improved and/or new streams are added.

  15. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion system. Final technical report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-11-01T23:59:59.000Z

    Research is presented on erosion and corrosion of fluidized bed combustor component materials. The characteristics of erosion of in-bed tubes was investigated. Anti-corrosion measures were also evaluated.

  16. Cold flow tudy of a fluidized bed reactor for catalytic conversion of methanol to low molecular weight hydrocarbons

    E-Print Network [OSTI]

    Mehta, Shirish Ramniklal

    1982-01-01T23:59:59.000Z

    COLD FLOW STUDY OF A FLUIDIZED BED REACTOR FOR CATALYTIC CONVERSION OF METHANOL TO LOW MOLECULAR WEIGHT HYDROCAREONS A Thesis by SHIRISH RAMNIKLAL MEHTA Submitted to the Graduate College of Texas A&M University in partial fulfilment... of the requirement for the degree of MASTER OF SCIENCE March 1982 Major Subject: Chemical Engineering COLD FLOW STUDY OF A FLUIDIZED BED REACTOR FOR CATALYTIC CONVERSION OF METHANOL TO LOW MOLECULAR WEIGHT HYDROCARBON A Thesis by SHIRISH RAMNIKLAL MEHTA...

  17. High Extraction Phosphors for Solid State Lighting

    SciTech Connect (OSTI)

    Chris Summers; Hisham Menkara; Brent Wagner

    2011-09-30T23:59:59.000Z

    We have developed high-index, high efficiency bulk luminescent materials and novel nano-sized phosphors for improved solid-state white LED lamps. These advances can potentially contribute to reducing the loss in luminous efficiencies due to scattering, re-absorption, and thermal quenching. The bulk and nanostructured luminescent materials investigated are index matched to GaN and have broad and size-tunable absorption bands, size and impurity tuned emission bands, size-driven elimination of scattering effects, and a separation between absorption and emission bands. These innovations were accomplished through the use of novel synthesis techniques suitable for high volume production for LED lamp applications. The program produced a full-color set of high quantum yield phosphors with high chemical stability. In the bulk phosphor study, the ZnSeS:Cu,Ag phosphor was optimized to achieve >91% efficiency using erbium (Er) and other activators as sensitizers. Detailed analysis of temperature quenching effects on a large number of ZnSeS:Cu,Ag,X and strontium- and calcium-thiogallate phosphors lead to a breakthrough in the understanding of the â??anti-quenchingâ? behavior and a physical bandgap model was developed of this phenomena. In a follow up to this study, optimized phosphor blends for high efficiency and color performance were developed and demonstrated a 2-component phosphor system with good white chromaticity, color temperature, and high color rendering. By extending the protocols of quantum dot synthesis, â??largeâ? nanocrystals, greater than 20 nm in diameter were synthesized and exhibited bulk-like behavior and blue light absorption. The optimization of ZnSe:Mn nanophosphors achieved ~85% QE The limitations of core-shell nanocrystal systems were addressed by investigating alternative deltadoped structures. To address the manufacturability of these systems, a one-pot manufacturing protocol was developed for ZnSe:Mn nanophosphors. To enhance the stability of these material systems, the encapsulation of ZnSeS particle phosphors and ZnSeS screens with Al{sub 2}O{sub 3} and TiO{sub 2} using ALD was shown to improve the stability by >8X and also increased the luminescence efficiency due to improved surface passivation and optical coupling. A large-volume fluidized bed ALD system was designed that can be adapted to a commercial ALD or vapor deposition system. Throughout the program, optical simulations were developed to evaluate and optimize various phosphor mixtures and device configurations. For example, to define the scattering properties of nanophosphors in an LED device or in a stand-off screen geometry. Also this work significantly promoted and assisted in the implementation of realistic phosphor material models into commercial modeling programs.

  18. Chaotic behavior control in fluidized bed systems using artificial neural network. Quarterly progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    Bodruzzaman, M.; Essawy, M.A.

    1996-07-30T23:59:59.000Z

    We have developed techniques to control the chaotic behavior in the Fluidized Bed (FBC) Systems using Artificial Neural Networks (ANNs). For those techniques to cross from theory to implementation, the computer programs we are developing have to be interfaced with the outside world, as a necessary step towards the actual interface with an FBC system or its experimental mock up. For this reason we are working on a Data Acquisition Board setup that will enable communication between our programs and external systems. Communication is planned to be enabled in both ways to deliver feedback signals from a system to the control programs in one way, and the control signals from the control programs to the controlled system in the other way. On the other hand, since most of our programs are PC based, they have to follow the revolutionary progress in the PC technology. Our programs were developed in the DOS environment using an early version of Microsoft C compiler. For those programs to meet the current needs of most PC users, we are working on converting those programs to the Windows environment, using a very advanced and up to date C++ compiler. This compiler is known as the Microsoft Visual C++ Version 4.0. This compiler enables the implementation of very professional and sophisticated Windows 95, 32 bit applications. It also allows a simple utilization of the Object Oriented Programming (OOP) techniques, and lots of powerful graphical and communication tools known as the Microsoft Foundation Classes (MFC). This compiler also allows creating Dynamic Link Libraries (DLLS) that can be liked together or with other Windows programs. These two main aspects, the computer-system interface and the DOS-Windows migration will give our programs a leap frog towards their real implementation.

  19. FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-09-13T23:59:59.000Z

    The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

  20. Effects of scale-up on oil and gas yields in a solid-recycle bed oil shale retorting process

    SciTech Connect (OSTI)

    Carter, S.D.; Taulbee, D.N.; Vego, A. [Univ. of Kentucky, Lexington, KY (United States)

    1994-12-31T23:59:59.000Z

    Fluidized bed pyrolysis of oil shale in a non-hydrogen atmosphere has been shown to significantly increase oil yield in laboratory-scale reactors compared to the Fischer assay by many workers. The enhancement in oil yield by this relatively simple and efficient thermal technique has led to the development of several oil shale retorting processes based on fluidized bed and related technologies over the past fifteen years. Since 1986, the Center for Applied Energy Research (CAER) has been developing one such process, KENTORT II, which is mainly tailored for the Devonian oil shales that occur in the eastern U.S. The process contains three main fluidized bed zones to pyrolyze, gasify, and combust the oil shale. A fourth fluidized bed zone serves to cool the spent shale prior to exiting the system. The autothermal process utilizes processed shale recirculation to transfer heat from the combustion to the gasification and pyrolysis zones. The CAER is currently testing the KENTORT II process in a 22.7-kg/hr process-development unit (PDU).

  1. The O{sub 2}-enriched air gasification of coal, plastics and wood in a fluidized bed reactor

    SciTech Connect (OSTI)

    Mastellone, Maria Laura, E-mail: mlaura.mastellone@unina2.it [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy); Zaccariello, Lucio; Santoro, Donato; Arena, Umberto [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy)

    2012-04-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer The effect of the O{sub 2} in the gasification stream of a BFB gasifier has been studied. Black-Right-Pointing-Pointer Main advantage of the O{sub 2}-enriched air is the increasing of the bed temperature. Black-Right-Pointing-Pointer No remarkable effects on tar reduction. Decreasing of recognized PAHs. Black-Right-Pointing-Pointer Gasification reactions completed inside the dense bed and splashing zone. Black-Right-Pointing-Pointer Polycondensation reactions occur mainly in the freeboard region. - Abstract: The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery.

  2. The Evaluation of the Mechanical Strength of Epoxy-Based Resin as a Plugging Material, and the Development of a Novel Plug and Abandon Technique Using Vitrified Solid Epoxy-Based Resin Beads

    E-Print Network [OSTI]

    Abuelaish, Ahmed

    2012-07-16T23:59:59.000Z

    mixtures, however, remained relatively constant, with the greatest drop being only 11%. The use of solid epoxy beads was found to have a compressive strength 50% greater than Portland cements I&II. In addition, the application mentioned herein eliminates...

  3. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Wang, K.S.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1997-07-01T23:59:59.000Z

    This study investigated the potential of employing suitable sorbents to capture toxic trace metallic substances during fluidized bed coal combustion. Metal capture experiments were carried out in a 25.4 mm (1 inch) quartz fluidized bed combustor enclosed in an electric furnace. The metals involved were cadmium, lead, chromium, arsenic and selenium, and the sorbents tested included bauxite, zeolite and lime. In addition to the experimental investigations, potential metal-sorbent reactions were also identified through chemical equilibrium calculations based on the minimization of system free energy. The observed experimental results indicated that metal capture by sorbents can be as high as 88% depending on the metal species and sorbent involved. Results from thermodynamic equilibrium simulations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}(s), CdAl{sub 2}O{sub 4}(s) and CdSiO{sub 3}(s) under the combustion conditions.

  4. Testing of Western Kentucky No. 9 coal in an atmospheric fluidized-bed combustor. Technical report

    SciTech Connect (OSTI)

    Pettit, R.

    1984-05-01T23:59:59.000Z

    This report deals with the characterization of a western Kentucky No. 9 coal as an atmospheric fluidized-bed combustor (AFBC) feedstock. It is the first of a series of four reports, each dealing with a different Kentucky coal. All of the coal tests were conducted using an Oregon dolomite from the central Kentucky region. The tests were conducted in a 2 ft. 8 in. x 2 ft. 5 in. atmospheric fluidized bed combustor. The Western Kentucky No. 9 coal tested had a heating value of 12200 Btu/lb. The Oregon dolomite used contained 61% CaCO3 and 31% MgCO3. Detailed feedstock analyses are presented in Appendix E. Seven steady-state test runs were conducted over a two-week period. The runs were at one of 100%, 85%, or 70% loads. The air flowrate, bed temperature, and stack sulfur dioxide emissions rate were kept approximately constant during these tests to facilitate comparison.

  5. Proceedings of the sixth international conference on fluidized bed combustion. Volume II. Technical sessions

    SciTech Connect (OSTI)

    none,

    1980-08-01T23:59:59.000Z

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. The papers covered recent developments in atmospheric and pressurized fluidized-bed combustion, especially the design, operation and control of pilot and demonstration plants. The cleanup of combustion products and the erosion, corrosion and fouling of gas turbines was emphasized also. Fifty-five papers from Volume 2 of the proceedings have been entered individually into EDB and ERA; five papers had been entered previously from other sources. (LTN)

  6. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; Songgeng Li

    2006-04-01T23:59:59.000Z

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2006 through March 31, 2006. Work was performed on the following activities. First, the fabrication and manufacture of the CFBC Facility were completed. The riser, primary cyclone and secondary cyclone of Circulating Fluidized Bed (CFB) Combustor have been erected. Second, the Mercury Control Workshop and the Grand Opening of Institute for Combustion Science and Environmental Technology (ICSET) were successfully held on February 22 and 23, 2006, respectively. Third, effects of hydrogen chlorine (HCl) and sulfur dioxide (SO{sub 2}) on mercury oxidation were studied in a drop tube reactor. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  7. INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER

    SciTech Connect (OSTI)

    Kevin Whitty

    2003-12-01T23:59:59.000Z

    The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

  8. Proceedings of the sixth international conference on fluidized bed combustion. Volume III. Technical sessions

    SciTech Connect (OSTI)

    none,

    1980-08-01T23:59:59.000Z

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. Forty-five papers from Vol. III of the proceedings have been entered individually into EDB and ERA. Two papers had been entered previously from other sources. (LTN)

  9. Fuel characteristics and theoretical performance of a fluidized bed combustor with manure as a fuel

    E-Print Network [OSTI]

    Park, Joon Hwa

    1984-01-01T23:59:59.000Z

    convert cattle manure to a more useful form of energy. A small pilot plant having a capacity of 450 kg/day has been constructed to evaluate gasification of manure by partial oxidation. The reactor operates as a counter-current fluidized bed in which... and gasification appear most uniquely adapted to the quality of manure collected from Texas cattle feedlots. Miles ( 12) conducted combustion pile burning trials to determine appropriate conditions for burning old feedlot manure that contained soil particles...

  10. Proceedings of the Sixth International Conference on Fluidized Bed Combustion. Volume 1. Plenary sessions

    SciTech Connect (OSTI)

    none,

    1980-08-01T23:59:59.000Z

    The Sixth International Conference on Fluidized Bed Combustion was held at the Atlanta Hilton, Atlanta, Georgia, April 9-11, 1980. The papers in this volume involved presentation of the research and development programs of the US (US DOE, TVA, EPRI and US EPA), United Kingdom, Federal Republic of Germany and the People's Republic of China. Eight papers from Vol. 1 (Plenary Sessions) of the proceedings have been entered individually into EDB and ERA. (LTN)

  11. Design and performance of a fluidized-bed incinerator for TRU combustible wastes

    SciTech Connect (OSTI)

    Meile, L.J.; Meyer, F.G.

    1982-01-01T23:59:59.000Z

    Problems encountered in the incineration of glovebox generated waste at Rocky Flats Plant (RFP) led to the development of a fluidized-bed incineration (FBI) system for transuranic (TRU) combustible wastes. Laboratory and pilot-scale testing of the process preceded the installation of an 82-kg/h production demonstration incinerator at RFP. The FBI process is discussed, and the design of the demonstration incinerator is described. Operating experience and process performance for both the pilot and demonstration units are presented.

  12. Capture of toxic metals by vaious sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Hopper, J.R.

    1995-12-31T23:59:59.000Z

    This study investigated the potential of employing suitable sorbents to capture trace metallic substances during fluidized bed coal combustion. The objectives of the study were to demonstrate the capture process, identify effective sorbents, and characterize the capture efficiency. Experiments were carried out in a 25.4 mm (1 ``) quartz fluidized bed coal combustor enclosed in an electric furnace. In an experiment, a coal sample from the DOE Coal Sample Bank or the Illinois Basin Coal Sample Bank was burned in the bed with a sorbent under various combustion conditions and the amount of metal capture by the sorbent was determined. The metals involved in the study were arsenic, cadmium, lead, mercury and selenium, and the sorbents tested included bauxite, zeolite and lime. The combustion conditions examined included bed temperature, particle size, fluidization velocity (percent excess air), and sorbent bed height. In addition to the experimental investigations, potential metal-sorbent reactions were also identified through performing chemical equilibrium analyses based on the minimization of system free energy.

  13. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. [Argonne National Lab., IL (United States); Gerritsen, W.; Stewart, A.; Robinson, K. [Rockwell International Corp., Canoga Park, CA (United States)

    1991-02-01T23:59:59.000Z

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  14. Fluidized-bed waste-heat recovery system development: Final report

    SciTech Connect (OSTI)

    Patch, K.D.; Cole, W.E.

    1988-06-01T23:59:59.000Z

    A major energy loss in industry is the heat content of the flue gases from industrial process heaters. One effective way to utilize the energy, which is applicable to all processes, is to preheat the combustion air for the process heater. Although recuperators are available to preheat this air when the flue gases are clean, recuperators to recover the heat from dirty and corrosive flue gases do not exist. The Fluidized-Bed Waste-Heat Recovery (FBWHR) system is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, recirculating alumina particles are heated by the flue gas in a raining bed. The hot particles are then removed from the bed and placed in a fluidized bed where they are fluidized by the combustion air. Through this process, the combustion air is preheated. The cooled particles are then returned to the raining bed. Initial development of this concept is for the aluminum smelting industry. In this final report, the design, development, fabrication, and installation of a full-scale FBWHR system is detailed.

  15. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. (Argonne National Lab., IL (United States)); Gerritsen, W.; Stewart, A.; Robinson, K. (Rockwell International Corp., Canoga Park, CA (United States))

    1991-02-01T23:59:59.000Z

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  16. Economics of co-firing waste materials in an advanced pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Bonk, D.L.; McDaniel, H.M. [Dept. of Energy, Morgantown, WV (United States). Morgantown Energy Technology Center; DeLallo, M.R. Jr.; Zaharchuk, R. [Gilbert/Commonwealth, Inc., Reading, PA (United States)

    1995-04-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach is the atmospheric fluidized bed combustor (AFBC). It has demonstrated its commercial acceptance in the utility market as a reliable source of power by burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. The results and conclusions developed are generally applicable to current and advanced PFBC design concepts.

  17. High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors

    SciTech Connect (OSTI)

    Hou, Peggy Y.; MacAdam, S.; Niu, Y.; Stringer, J.

    2003-04-22T23:59:59.000Z

    Heat-exchanger tubes in fluidized bed combustors (FBCs) often suffer material loss due to combined corrosion and erosion. Most severe damage is believed to be caused by the impact of dense packets of bed material on the lower parts of the tubes. In order to understand this phenomenon, a unique laboratory test rig at Berkeley was designed to simulate the particle hammering interactions between in-bed particles and tubes in bubbling fluidized bed combustors. In this design, a rod shaped specimen is actuated a short distance within a partially fluidized bed. The downward specimen motion is controlled to produce similar frequencies, velocities and impact forces as those experienced by the impacting particle aggregates in practical systems. Room temperature studies have shown that the degradation mechanism is a three-body abrasion process. This paper describes the characteristics of this test rig, reviews results at elevated temperatures and compares them to field experience. At higher temperatures, deposits of the bed material on tube surfaces can act as a protective layer. The deposition depended strongly on the type of bed material, the degree of tube surface oxidation and the tube and bed temperatures. With HCl present in the bed, wastage was increased due to enhanced oxidation and reduced oxide scale adherence.

  18. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01T23:59:59.000Z

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  19. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01T23:59:59.000Z

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  20. Study of the combustion of low rank coal in a fluidized bed

    SciTech Connect (OSTI)

    Glaser, R.; Grimes, R.W.

    1991-09-01T23:59:59.000Z

    This report describes the results of preliminary combustion tests performed with Eagle Butte Coal in a bubbling, fluidized-bed combustion system. The system was designed for the combustion of low-rank coals and industrial wastes. The work, as proposed, was aimed at not only the evaluation of co-firing of waste material with coal, but also at developing modifications to first generation bubbling bed designs to improve the combustion performance during co-firing. However, the funding for the work was redirected and the combustion tests were suspended soon after the shakedown testing was completed. Consequently, this report describes the results of the tests completed prior to the redirection of the effort and funding. A total of 33 combustion tests were performed in a 6-inch diameter fluidized-bed combustor. Oxygen concentrations were measured at two points in the system; the vent line and at the interface between the fluid bed and the freeboard. These measurements provided a measure of the amount of conversion of coal within the fluidized bed compared to the conversion in the freeboard region. Typically, 75 to 80% of the conversion occurred within the bed. Several experiments were performed in which special bed internals were placed in the bed. The internals were designed to reduce bubble size in the bed thus increasing the surface area of the bubbles and hence promoting oxygen diffusion into the emulsion phase.

  1. Development of the fluidized bed thermal treatment process for treating mixed waste

    SciTech Connect (OSTI)

    Semones, G.B.; Williams, P.M.; Stiefvater, S.P.; Mitchell, D.L.; Roecker, B.D.

    1993-05-01T23:59:59.000Z

    A fluidized bed system is being developed at Rocky Flats for the treatment of mixed waste (a mixture of radioactive and chemically hazardous waste). The current program builds on experience gained in the 1970`s and 1980`s in tests with bench-scale, pilot-scale, and demonstration-scale fluidized bed systems. The system operates at low temperatures ({approx} 525--600{degree}C) which eliminates many of the disadvantages associated with high temperature thermal treatment processes. The process has shown the ability to destroy polychlorinated biphenyls (PCB`s) with 99.9999% (``six-nines``) destruction efficiency in tests monitored by the Environmental Protection Agency (EPA). The bed makes use of in situ neutralization of acidic off-gases by incorporating sodium carbonate (Na{sub 2}CO{sub 3}) in the bed media. This eliminates using wet scrubbers to treat the off-gas; these produce a high volume of secondary waste. Once in operation, it is expected that the fluidized bed process will yield up to a 40:1 reduction in the volume of the waste.

  2. Erosion of heat exchanger tubes in fluidized beds. Annual report, 1990

    SciTech Connect (OSTI)

    Johnson, E.K.; Flemmer, R.L.C.

    1991-01-01T23:59:59.000Z

    This final report describes the activities of the 3-year project entitled ``Erosion of Heat Exchanger Tubes In Fluidized Beds.`` which was completed at the end of 1990. Project accomplishments include the collection of a substantial body of wear data In a 24in. {times} 24in. fluidized bed, comparative wear results In a 6in. {times} 6in. fluidized bed, the development of a dragometer and the collection of a comprehensive set of drag force data in the 24in. {times} 24in. bed, Fast Fourier Transform (FFT) analysis of bubble probe data to establish dominant bubble frequencies in the 24in. {times} 24in. bed, the use of a heat flux gauge for measurement of heat transfer coefficients in the 24in. {times} 24in. bed and the modeling of the tube wear in the 24in. {times} 24in. bed. Analysis of the wear data from the 24in. square bed indicates that tube wear increases with increase in superficial velocity, and with increase in tube height. The latter effect is a result of the tubes higher up in the bed seeing greater movement of dense phase than tubes lower down In the bed. In addition, tube wear was found to decrease with increase in particle size, for constant superficial velocity. Three models of tube wear were formulated and provided acceptable prediction of wear when compared with the experimental data.

  3. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Andy Wu; John T. Riley

    2005-07-30T23:59:59.000Z

    This purpose of this report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period April 1, 2005 through June 30, 2005. The following tasks have been completed. First, the new Combustion Laboratory was occupied on June 15, 2005, and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building is in the final painting stage. Second, the fabrication and manufacturing contract for the CFBC Facility was awarded to Sterling Boiler & Mechanical, Inc. of Evansville, Indiana. Sterling is manufacturing the assembly and component parts of the CFBC system. The erection of the CFBC system is expected to start September 1, 2005. Third, mercury emissions from the cofiring of coal and chicken waste was studied experimentally in the laboratory-scale simulated fluidized-bed combustion facility. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described.

  4. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Andy Wu; John T. Riley

    2005-04-30T23:59:59.000Z

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2005 through March 31, 2005. The following tasks have been completed. First, the renovation of the new Combustion Laboratory is nearly complete, and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building is in the final stages. Second, the fabrication and manufacture of the CFBC Facility is being discussed with a potential contractor. Discussions with potential contactor regarding the availability of materials and current machining capabilities have resulted in the modification of the original designs. The selection of the fabrication contractor for the CFBC Facility is expected during the next quarter. Third, co-firing experiments conducted with coal and chicken waste have been initiated in the laboratory-scale simulated fluidized-bed facility. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  5. The yield of Amorphous Solids Under Stress Control at Low Temperatures

    E-Print Network [OSTI]

    Valery Ilyin; Itamar Procaccia; Carmel Shor; Murari Singh

    2015-04-21T23:59:59.000Z

    The yield of amorphous solids like metallic glasses under external stress was discussed asserting that it is related to the glass transition by increasing temperature, or that it can be understood using statistical theories of various sorts. Here we study the approach to stress-controlled yield and argue that neither assertions can be supported, at least at low temperatures. The yield of amorphous solids at low temperatures is a highly structured phenomenon, characterized by a specific series of mechanical instabilities, and having no similarity at all to fluidization by increased temperature, real or fictive. The series of instabilities followed by stress controlled yield at low but finite temperature protocols can be predicted by analyzing athermal quasi-static strain controlled protocols, making the latter highly relevant for the deep understanding of the mechanical properties of amorphous solids.

  6. Circulating fluidized bed gasification of a tire-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A. [Ist. di Ricerche Sulla Combustione-C.N.R., Napoli (Italy)

    1997-12-31T23:59:59.000Z

    A market available tire-derived fuel (TDF) was continuously fed in a laboratory scale CFB gasifier operated with air and steam as oxidizers. Silica sand, having a Sauter mean diameter of 155 {micro}m, was used as bed material. The riser and the recirculation column were maintained at 850 C by means of electric heaters driven by electronic controllers. The experiments were carried out at fixed values of solids mass flux (10 kg/sm{sup 2}) and superficial gas velocity in the primary (1.7 m/s) as well as in the secondary zone (2.7 m/s). The equivalence ratios and the H{sub 2}O/TDF d.a.f. ratio were varied between 0.3 and 0.6 and between 0.4 and 1.3, respectively. For each run, data from pressure electronic transducers, thermocouples and gas analyzers were processed to evaluate riser axial profiles of pressure, temperature and gas concentration (in terms of CO, H{sub 2}, CH{sub 4}, C{sub n}H{sub m} and CO{sub 2} content). Collecting, sieving and analyzing solids hold-up in the riser allowed estimation of the amount of carbon particles and their size distribution. Carbon conversion efficiency, specific gas yield and energy output were also determined.

  7. JV Task 108 - Circulating Fluidized-Bed Combustion and Combustion Testing of Turkish Tufanbeyli Coal

    SciTech Connect (OSTI)

    Douglas Hajicek; Jay Gunderson; Ann Henderson; Stephen Sollom; Joshua Stanislowski

    2007-08-15T23:59:59.000Z

    Two combustion tests were performed at the Energy & Environmental Research Center (EERC) using Tufanbeyli coal from Turkey. The tests were performed in a circulating fluidized-bed combustor (CFBC) and a pulverized coal-fired furnace, referred to as the combustion test facility (CTF). One of the goals of the project was to determine the type of furnace best suited to this coal. The coal is high in moisture, ash, and sulfur and has a low heating value. Both the moisture and the sulfur proved problematic for the CTF tests. The fuel had to be dried to less than 37% moisture before it could be pulverized and further dried to about 25% moisture to allow more uniform feeding into the combustor. During some tests, water was injected into the furnace to simulate the level of flue gas moisture had the fuel been fed without drying. A spray dryer was used downstream of the baghouse to remove sufficient sulfur to meet the EERC emission standards permitted by the North Dakota Department of Health. In addition to a test matrix varying excess air, burner swirl, and load, two longer-term tests were performed to evaluate the fouling potential of the coal at two different temperatures. At the lower temperature (1051 C), very little ash was deposited on the probes, but deposition did occur on the walls upstream of the probe bank, forcing an early end to the test after 2 hours and 40 minutes of testing. At the higher temperature (1116 C), ash deposition on the probes was significant, resulting in termination of the test after only 40 minutes. The same coal was burned in the CFBC, but because the CFBC uses a larger size of material, it was able to feed this coal at a higher moisture content (average of 40.1%) compared to the CTF (ranging from 24.2% to 26.9%). Sulfur control was achieved with the addition of limestone to the bed, although the high calcium-to-sulfur rate required to reduce SO{sub 2} emissions resulted in heat loss (through limestone calcination) and additional ash handling. A more efficient downstream sulfur scrubber capable of operation at a much lower Ca/S ratio would result in significantly higher boiler efficiency for this coal. At the operating temperature of a typical CFBC, bed agglomeration and convective pass fouling are not likely to be significant problems with this fuel. Compared to pulverized coal-firing, CFBC technology is clearly the better choice for this fuel. It provides more efficient sulfur capture, lower NO{sub x} emissions, better solids-handling capability, and can utilize a wetter feedstock, requiring less crushing and sizing. The lower operating temperature of CFBC boilers (820 C) reduces the risk of fouling and agglomeration. Care must be taken to minimize heat loss in the system to accommodate the low heating value of the coal.

  8. Neural Network Based Montioring and Control of Fluidized Bed.

    SciTech Connect (OSTI)

    Bodruzzaman, M.; Essawy, M.A.

    1996-04-01T23:59:59.000Z

    The goal of this project was to develop chaos analysis and neural network-based modeling techniques and apply them to the pressure-drop data obtained from the Fluid Bed Combustion (FBC) system (a small scale prototype model) located at the Federal Energy Technology Center (FETC)-Morgantown. The second goal was to develop neural network-based chaos control techniques and provide a suggestive prototype for possible real-time application to the FBC system. The experimental pressure data were collected from a cold FBC experimental set-up at the Morgantown Center. We have performed several analysis on these data in order to unveil their dynamical and chaotic characteristics. The phase-space attractors were constructed from the one dimensional time series data, using the time-delay embedding method, for both normal and abnormal conditions. Several identifying parameters were also computed from these attractors such as the correlation dimension, the Kolmogorov entropy, and the Lyapunov exponents. These chaotic attractor parameters can be used to discriminate between the normal and abnormal operating conditions of the FBC system. It was found that, the abnormal data has higher correlation dimension, larger Kolmogorov entropy and larger positive Lyapunov exponents as compared to the normal data. Chaotic system control using neural network based techniques were also investigated and compared to conventional chaotic system control techniques. Both types of chaotic system control techniques were applied to some typical chaotic systems such as the logistic, the Henon, and the Lorenz systems. A prototype model for real-time implementation of these techniques has been suggested to control the FBC system. These models can be implemented for real-time control in a next phase of the project after obtaining further measurements from the experimental model. After testing the control algorithms developed for the FBC model, the next step is to implement them on hardware and link them to the experimental system. In this report, the hardware implementation issues of the control algorithms are also discussed.

  9. Apparatus and method for determining solids circulation rate

    DOE Patents [OSTI]

    Ludlow, J. Christopher (Morgantown, WV); Spenik, James L. (Morgantown, WV)

    2012-02-14T23:59:59.000Z

    The invention relates to a method of determining bed velocity and solids circulation rate in a standpipe experiencing a moving packed bed flow, such as the in the standpipe section of a circulating bed fluidized reactor The method utilizes in-situ measurement of differential pressure over known axial lengths of the standpipe in conjunction with in-situ gas velocity measurement for a novel application of Ergun equations allowing determination of standpipe void fraction and moving packed bed velocity. The method takes advantage of the moving packed bed property of constant void fraction in order to integrate measured parameters into simultaneous solution of Ergun-based equations and conservation of mass equations across multiple sections of the standpipe.

  10. Review article Components manufacturing for solid oxide fuel cells

    E-Print Network [OSTI]

    Gleixner, Stacy

    of solid oxide fuel cell (SOFC) components is given and the fabrication techniques of ceramic components Elsevier Science B.V. All rights reserved. Keywords: Solid oxide fuel cell (SOFC); Components manufacturingReview article Components manufacturing for solid oxide fuel cells F. Tietz *, H.-P. Buchkremer, D

  11. Etude de l'empoussirement des poudres par un test de fluidisation Study of dustiness of powders by a fluidized bed test

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Etude de l'empoussièrement des poudres par un test de fluidisation Study of dustiness of powders by a fluidized bed test MOUFAREJ ABOU JAOUDE Marie-Thérèsea , LEFRANCOIS Emmanuelb , LE BIHAN Olivierc of this study is to use a fluidized bed as a dustiness test based on entrainment and elutriation phenomena

  12. Solid Waste (New Mexico)

    Broader source: Energy.gov [DOE]

    The New Mexico Environment Department's Solid Waste Bureau manages solid waste in the state. The Bureau implements and enforces the rules established by the Environmental Improvement Board.

  13. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Unknown

    2003-01-30T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1--December 31, 2002 time period.

  14. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2003-07-23T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2003 time period.

  15. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2003-10-29T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the July 1--September 30, 2003 time period.

  16. Development of an alternative kraft black liquor recovery process based on low-temperature processing in fluidized beds. Final technical report on Annex 9, Task 1

    SciTech Connect (OSTI)

    Kubes, G.J.

    1994-03-24T23:59:59.000Z

    The overall objective of this research program was to provide the fundamental knowledge and experimental data from pilot scale operation for an alternative black liquor recovery technology which would have a higher overall energy efficiency, would not suffer from the smelt-water explosion hazard and would be lower in capital cost. In addition, the alternative process would be more flexible and well suited for incremental recovery capacity or for new pulping processes, such as the new sulfide-sulfide-AQ process. The research program consists of number of specific research objectives with the aim to achieve the ultimate objective of developing an alternative recovery process which is shown in Figure 1. The specific objectives are linked to individual unit operations and they represent the following research topics: (1) superheated steam drying of kraft black liquors; (2) fast pyrolysis of black liquor; (3) hydrogen sulfide absorption from flue gas; (4) reduction of sodium sulfate in solid phase with gaseous hydrogen; and (5) verification of the fundamental results in fluidized bed pilot plant. The accomplishments in each of these objectives are described.

  17. Technical and economic assessment of fluidized bed augmented compressed air energy storage system. Volume III. Preconceptual design

    SciTech Connect (OSTI)

    Giramonti, A.J.; Lessard, R.D.; Merrick, D.; Hobson, M.J.

    1981-09-01T23:59:59.000Z

    A technical and economic assessment of fluidized bed combustion augmented compressed air energy storage systems is presented. The results of this assessment effort are presented in three volumes. Volume III - Preconceptual Design contains the system analysis which led to the identification of a preferred component configuration for a fluidized bed combustion augmented compressed air energy storage system, the results of the effort which transformed the preferred configuration into preconceptual power plant design, and an introductory evaluation of the performance of the power plant system during part-load operation and while load following.

  18. Bench-scale testing of fluidized-bed sorbents -- ZT-4

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1995-12-01T23:59:59.000Z

    The objectives of this project are to identify and demonstrate methods for enhancing long-term chemical reactivity and attrition resistance of zinc oxide-based mixed metal-oxide sorbents for desulfurization of hot coal-derived gases in a high-temperature, high-pressure (HTHP) fluidized-bed reactor. Specific objectives of this study are the following: {sm_bullet} Investigating various manufacturing methods to produce fluidizable zinc ferrite and zinc titanate sorbents in a particle size range of 50 to 400 {mu}m; Characterizating and screening the formulations for chemical reactivity, attrition resistance, and structural properties; Testing selected formulations in an HTHP bench-scale fluidized-bed reactor to obtain an unbiased ranking of the promising sorbents; Investigating the effect of various process variables, such as temperature, nature of coal gas, gas velocity, and chemical composition of the sorbent, on the performance of the sorbent; Life-cycle testing of the superior zinc ferrite and zinc titanate formulations under HTHP conditions to determine their long-term chemical reactivity and mechanical strength; Addressing various reactor design issues; Generating a database on sorbent properties and performance (e.g., rates of reaction, attrition rate) to be used in the design and scaleup of future commercial hot-gas desulfurization systems; Transferring sorbent manufacturing technology to the private sector; Producing large batches (in tonnage quantities) of the sorbent to demonstrate commercial feasibility of the preparation method; and Coordinate testing of superior formulations in pilot plants with real and/or simulated coal gas.

  19. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; John Smith

    2007-03-31T23:59:59.000Z

    This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period January 1, 2007 through March 31, 2007. The effort in this quarter has concentrated on installing the CFBC Facility and for conducting cold fluidization operations tests in the CFBC facility. The assembly of the ash recirculation pipe duct from the cyclones back to the bed area of the combustor, including the upper and lower loop seals was completed. The electric bed pre-heater was installed to heat the fluidizing air as it enters the wind box. The induced draft fan along with its machine base and power supply was received and installed. The flue gas duct from secondary cyclone outlet to induced draft fan inlet was received and installed, as well as the induced fan flue gas discharge duct. Pressure testing from the forced draft fan to the outlet of the induced fan was completed. In related research a pilot-scale halogen addition test was conducted in the empty slipstream reactor (without (Selective Catalytic Reduction) SCR catalyst loading) and the SCR slipstream reactor with two commercial SCR catalysts. The greatest benefits of conducting slipstream tests can be flexible control and isolation of specific factors. This facility is currently used in full-scale utility and will be combined into 0.6MW CFBC in the future. This work attempts to first investigate performance of the SCR catalyst in the flue gas atmosphere when burning Powder River Basin (PRB), including the impact of PRB coal flue gas composition on the reduction of nitrogen oxides (NOx) and the oxidation of elemental mercury (Hg(0)) under SCR conditions. Secondly, the impacts of hydrogen halogens (Hydrogen fluoride (HF), Hydrogen chloride (HCl), Hydrogen Bromide (HBr) and Hydrogen Iodine (HI)) on Hg(0) oxidation and their mechanisms can be explored.

  20. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Noble, S.D.

    1993-04-01T23:59:59.000Z

    The purpose of this project is to determine the physical and chemical reactions which lead to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. A survey of agglomeration and deposit formation in industrial fluidized bed boilers is in progress. Preliminary results indicate that at least five boilers were experiencing some form of bed material agglomeration. In these instances it was observed that large particles were forming within the bed which were larger that the feed. Four operators could confirm that the larger bed particles had formed due to bed particles sticking together or agglomerating. Deposit formation was reported at nine sites with these deposits being found most commonly at coal feed locations and in cyclones. Other deposit locations included side walls and return loops. Examples of these agglomerates and deposits have been received from five of the surveyed facilities. Also during this quarter, a bulk sample of Illinois No. 6 coal was obtained from the Fossil Energy Program at Ames Laboratory here at Iowa State University and prepared for combustion tests. This sample was first ground to a top-size of 3/8`` using a jaw crusher then a size fraction of 3/8`` {times} 8 (US mesh) was then obtained by sieving using a Gilson Test-Master. This size fraction was selected for the preliminary laboratory-scale experiments designed to simulate the dense bed conditions that exist in the bottom of CFB combustors. To ensure uniformity of fuel composition among combustion runs, the sized coal was riffled using, a cone and long row method and stored in bags for each experiment. During this quarter additional modifications were made to achieve better control of fluidization regimes and to aid in monitoring the hydrodynamic and chemical conditions within the reactor.

  1. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2004-07-01T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy Contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. Under this contract a series of pilot plant tests are being conducted to ascertain PGM performance with a variety of fuels. The performance and economics of a PGM based plant designed for the co-production of hydrogen and electricity will also be determined. This report describes the work performed during the April-June 30, 2004 time period.

  2. Plant response to FBC waste-coal slurry solid mixtures. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Darmody, R.G.; Dunker, R.E. [Univ. of Illinois, Urbana, IL (United States); Dreher, G.B.; Roy, W.R.; Steel, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-09-01T23:59:59.000Z

    The goal of this project is to test the feasibility of stabilizing coal slurry solids (CSS) wastes by directly seeding plants into the waste. This is not done conventionally because the waste can generate toxic amounts of sulfuric acid. The approach is to neutralize the potential acidity by mixing fluidized bed combustion (FBC) waste into the slurry. If successful, this approach would both help dispose of FBC wastes while providing a more economical slurry stabilization technique. The project involves growing forage plants in CSS-FBC mixtures in the greenhouse. In the first two quarters the authors designed the experiment, secured greenhouse space, purchased the seeds, collected, dried, analyzed the FBC and CSS samples. The samples represent a typical range of properties. They retrieved two FBC and two CSS samples. One CSS sample had a relatively high CaCO{sub 3} content relative to the pyrite content and required no FBC to neutralize the potential acidity. The other CSS sample required from 4.2 to 2.7% FBC material to neutralize its potential acidity. This report covers the third quarter of the project. The authors produced the CSS-FBC mixtures, analyzed the soil fertility parameters of the mixtures,, planted the crops, and monitored their growth. All mixtures support at least some plant growth, although some plants did better than others. It is too early to analyze the results statistically. Next quarter the plants will be harvested, yields calculated, mineral uptake evaluated, and a final report will be written on plant response to CSS-FBC mixtures.

  3. Fluidized bed heat exchanger with water cooled air distributor and dust hopper

    DOE Patents [OSTI]

    Jukkola, Walfred W. (Westport, CT); Leon, Albert M. (Mamaroneck, NY); Van Dyk, Jr., Garritt C. (Bethel, CT); McCoy, Daniel E. (Williamsport, PA); Fisher, Barry L. (Montgomery, PA); Saiers, Timothy L. (Williamsport, PA); Karstetter, Marlin E. (Loganton, PA)

    1981-11-24T23:59:59.000Z

    A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

  4. Analysis of fluidized beds for the simultaneous aerosol separation and heat recovery

    SciTech Connect (OSTI)

    El-Halwagi, M.M. [Auburn Univ., AL (United States)

    1993-01-01T23:59:59.000Z

    A mathematical model is developed to describe the performance of fluidized beds for the simultaneous heat recovery and aerosol separation. This new concept is analyzed in light of the various transport processes taking place within the bed. A two-phase model is developed for the system in which heat and aerosol particles are transferred from the bubble phase to the emulsion phase. In addition to aerosol separation via diffusion, interception, impaction and electrostatic precipitation, thermophoretic collection is also analyzed. The results indicate that high thermal and separation efficiencies can be obtained.

  5. Automatic control of air to fuel ratio in a fluidized bed gasifier

    E-Print Network [OSTI]

    Ling, Peter P.

    1984-01-01T23:59:59.000Z

    efficient but was not as convenient for small research unit. Fuel Bin First Auger Air Lock Fluidised Bed Gasifier Feed Motor Gear Reducer Second Auger Bleed-off Valve and Valve Actuator Blower Laminar Flow Element PIG. 3. The A/F Ratio Control...AUTOMATIC CONTROL OF AIR TO FUEL RATIO IN A FLUIDIZED BED GASIFIER A Thesis by PETER P. LING Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1984...

  6. Wavelet analysis to characterize cluster dynamics in a circulating fluidized bed

    SciTech Connect (OSTI)

    Guenther, C.; Breault, R.W.

    2007-04-30T23:59:59.000Z

    A common hydrodynamic feature in heavily loaded circulating fluidized beds is the presence of clusters. The continuous formation and destruction of clusters strongly influences particle hold-up, pressure drop, heat transfer at the wall, and mixing. In this paper fiber optic data is analyzed using discrete wavelet analysis to characterize the dynamic behavior of clusters. Five radial positions at three different axial locations under five different operating conditions spanning three different flow regimes were analyzed using discrete wavelets. Results are summarized with respect to cluster size and frequency.

  7. Pulse atmospheric fluidized bed combustion. Technical progress report, November 1988--January 1989

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this reporting period, a total of eight shakedown and debugging coal combustion tests were performed in the AFBC. A start-up procedure was established, system improvements implemented, and preliminary material and heat balances made based on these tests. The pulse combustor for the AFBC system was fabricated and installed and a series of tests was conducted on the system. 17 figs., 5 tabs.

  8. Nucla circulating atmospheric fluidized bed demonstration project. Quarterly technical progress report, October--December 1990

    SciTech Connect (OSTI)

    Not Available

    1991-01-31T23:59:59.000Z

    During the fourth quarter of 1990, steady-state performance testing at the Nucla Circulating Fluidized Bed (CFB) resumed under sponsorship of the US Department of Energy. Co-sponsorship of the Demonstration Test Program by the Electric Power Research Institute (EPRI) was completed on June 15, 1990. From October through December, 1990, Colorado-Ute Electric Association (CUEA) completed a total of 23 steady-state performance tests, 4 dynamic tests, and set operating records during November and December as the result of improved unit operating reliability. Highlight events and achievements during this period of operation are presented.

  9. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1993-10-19T23:59:59.000Z

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 [mu]m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO[sub 3]; and then indurating it at 800 to 900 C for a time sufficient to produce attrition-resistant granules.

  10. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30T23:59:59.000Z

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  11. PSNH's Northern Wood power project repowers coal-fired plant with new fluidized-bed combustor

    SciTech Connect (OSTI)

    Peltier, R.

    2007-08-15T23:59:59.000Z

    The Northern Wood Power project permanently replaced a 50-MW coal-burning boiler (Unit 5) at Public Service of New Hampshire's Schiller station with a state-of-the-art circulating fluidized bed wood-burning boiler of the same capacity. The project, completed in December 2006, reduced emissions and expanded the local market for low-grade wood. For planning and executing the multiyear, $75 million project at no cost to its ratepayers, PSNH wins Power's 2007 Marmaduke Award for excellence in O & M. The award is named for Marmaduke Surfaceblow, the fictional marine engineer/plant troubleshoot par excellence. 7 figs., 1 tab.

  12. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    None

    1982-10-21T23:59:59.000Z

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  13. Atmospheric fluidized bed combustion advanced system concepts applicable to small industrial and commercial markets. Topical report, Level 2

    SciTech Connect (OSTI)

    Ake, T.R.; Dixit, V.B.; Mongeon, R.K.

    1992-09-01T23:59:59.000Z

    As part of an overall strategy to promote FBC coal combustion and to improve the marketability of the eastern coals, the US Department of Energy`s Morgantown Energy Research Center awarded a three level contract to Riley Stoker Corporation to develop advanced Multi Solids Fluidized Bed (MSFB) boiler designs. The first level of this contract targeted the small package boiler (10,000--50,000 lb/hr steam) and industrial size boiler (75,000--150,000 lb/hr steam) markets. Two representative sizes, 30,000 lb/hr and 110,000 lb/hr of steam, were selected for the two categories for a detailed technical and economic evaluation. Technically, both the designs showed promise, however, the advanced industrial design was favored on economic considerations. It was thus selected for further study in the second level of the contract. Results of this Level-2 effort, presented in this report, consisted of testing the design concept in Riley`s 4.4 MBtu/hr pilot MSFB facility located at Riley Research Center in Worcester, Mass. The design and economics of the proof of concept facility developed in Level-1 of the contract were then revised in accordance with the findings of the pilot test program. A host site for commercial demonstration in Level-3 of the contract was also secured. It was determined that co-firing coal in combination with paper de-inking sludge will broaden the applicability of the design beyond conventional markets. International Paper (IP), the largest paper company in the world, is willing to participate in this part of the program. IP has offered its Hammermill operation at Lockhaven, Pa, site of a future paper de-inking plant, for the proof of concept installation. This plant will go in operation in 1994. It is recommended that METC proceed to the commercial demonstration of the design developed. The approach necessary to satisfy the needs of the customer while meeting the objectives of this program is presented along with a recommended plan of action.

  14. Laboratory studies on corrosion of materials for fluidized bed combustion applications

    SciTech Connect (OSTI)

    Natesan, K.

    1990-10-01T23:59:59.000Z

    An extensive corrosion test program was conducted at Argonne National Laboratory to evaluate the corrosion performance of metallic structural materials in environments that simulate both steady-state and off-normal exposure conditions anticipated in fluidized bed combustion (FBC) systems. This report discusses the possible roles of key parameters, such as sorbent and gas chemistries, metal temperature, gas cycling conditions, and alloy pretreatment, in the corrosion process. Data on scale thickness and intergranular penetration depth are presented for several alloys as a function of the chemistry of the exposure environment, deposit chemistry, and exposure time. Test results were obtained to compare the corrosion behavior of materials in the presence of reagent grade sorbent compounds and spent-bed materials from bubbling- and circulating-fluid-bed systems. Finally, the laboratory test results were compared with metal wastage information developed over the years in several fluidized bed test facilities. Metallic alloys chosen for the tests were carbon steel, Fe-2 1/4Cr-1Mo and Fe-9Cr-1Mo ferritic steels. Types 304 and 310 stainless steel, and Incoloy 800. 26 refs., 61 figs., 8 tabs.

  15. Atmospheric fluidized bed combustion for small scale market sectors. Final report

    SciTech Connect (OSTI)

    Ashworth, R.A.; Plessinger, D.A.; Sommer, T.M. [Energy and Environmental Research Corp., Orville, OH (United States); Keener, H.M. [Ohio Agricultural Research and Development Center, OH (United States); Webner, R.L. [Will-Burt Co., Orrville, OH (United States)

    1997-03-31T23:59:59.000Z

    The objective of this project was to demonstrate and promote the commercialization of coal-fired atmospheric fluidized bed combustion (AFBC) systems, with limestone addition for SO{sub 2} emissions control and a baghouse for particulate emissions control. This AFBC system was targeted for small scale industrial-commercial-institutional space and process heat applications. A cost effective and environmentally acceptable AFBC technology in this size range would displace a considerable amount of gas/oil with coal while resulting in significant total cost savings to the owner/operators. In the Proof-of-Concept Phase, a 2.2 x 10{sup 6} Btu/hr unit was installed and successfully operated at Cedar Lane Farms (CLF), a commercial nursery in Ohio. The heat from the fluidized bed was used to heat hot water which was recirculated through greenhouses for cool weather heating. The system was designed to be fully automated with minimal operator attention required. The AFBC system installed at CLF was an improved design that incorporated flyash/sorbent reinjection and an underbed feed system to improve limestone utilization. With these additions it was possible to lower the Ca/S ratio from {approximately} 3.0 to 2.0, and still maintain an SO{sub 2} emissions level of 1.2 lb/10{sup 6} Btu when burning the same high sulfur Ohio coal tested at OARDC.

  16. Influence of salts on the sulfur retention of limestone in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Smith, G.W.; Lenc, J.F.; Shearer, J.A.; Chopra, O.K.; Myles, K.M.; Johnson, I.

    1981-06-01T23:59:59.000Z

    Increased utilization of the available CaO can reduce the amount of limestone required for SO/sub 2/ retention in atmospheric fluidized-bed combustion systems. In laboratory experiments, a pretreatment with inorganic salts, such as NaCl, CaCl/sub 2/, or Na/sub 2/CO/sub 3/, has been found to be an effective method of improving the CaO utilization. This report provides quantitative information on the effectiveness of the same sulfation-enhancement salts in reducing the limestone requirements in an atmospheric fluidized-bed combustor (AFBC). Some laboratory experiments indicated that only 0.1 mol % of salt was required to produce the structural changes in the limestone necessary to increase the CaO utilization. In contrast, the AFBC runs indicated that as much as 2.0 mol % salt was required to obtain a significant increase in the CaO utilization. The increased utilization of the salt-treated limestone in the AFBC reduced the total amount of limestone needed to meet the EPA emission standard for sulfur dioxide to one-half of that required when no treatment is used.

  17. The corrosive environment in the fluidized-bed heat-exchanger for CCGT service

    SciTech Connect (OSTI)

    Rocazella, M.A.; Holt, C.F.; Wright, I.C.

    1983-01-01T23:59:59.000Z

    Corrosion and combustion diagnostic data were gathered in Battelle's 0.6m diameter coal-fired atmospheric fluidized-bed combustor (AFBC). Corrosion probes, constructed from ring specimens of candidate heatexchanger alloys, were exposed to the fluidized-bed environment during three different combustion experiments (50%, 20% and 0% excess air). An in-situ oxygen probe was used to monitor the oxygen partial pressure at the exposure locations. Two different mechanisms of material degradation were identified, i.e., both corrosion and erosion. An adherent deposit of bed material formed on all areas of the corrosion probes. The corrosion behavior of the alloys beneath the deposit, and the corresponding corrosion product morphologies, appeared to correlate well with predictions based on the oxygen partial pressure measurements from the exposure location. The results suggest the oxygen probe may be a useful diagnostic tool for locating regions with high corrosive potentials. However, the upstream faces of the corrosion probes were subjected to enhanced mechanical damage, and this periodic removal of both the deposit and corrosion products resulted in significantly more metal degradation. Also, this corrosion/erosion process may locally deplete the alloy in chromium, leaving it susceptible to severe sulfidation and/or accelerated oxidation. It was suggested that these locations would be the first to experience heat-exchanger tube failure, and the coupled corrosion/erosion process would be the failure mechanism.

  18. Synthesis gas formation by catalytic oxidation of methane in fluidized bed reactors

    SciTech Connect (OSTI)

    Bharadwaj, S.S.; Schmidt, L.D. (Univ. of Minnesota, Minneapolis (United States))

    1994-03-01T23:59:59.000Z

    The production of synthesis gas (CO + H[sub 2]) by the catalytic partial oxidation of CH[sub 4] in air or O[sub 2] in static fluidized beds at atmospheric pressure has been examined over Pt, Rh, and Ni catalysts coated on 100-[mu]m [alpha]-Al[sub 2]O[sub 3] beads. With CH[sub 4]/air feeds, CO and H[sub 2] selectivities as high as 95% with >90% CH[sub 4] conversion were obtained on Rh and Ni catalysts at contact times of 0.1-0.5 sec. Pt catalysts were found to have significantly lower selectivities for all the three catalysts were improved by heating the reaction mixture above the autothermal reactor temperature and using O[sub 2] instead of air. The selectivities and conversions were fairly constant over the range of contact time s used. Probable reaction pathways for CH[sub 4] oxidation in fluidized beds are discussed. 31 refs., 6 figs.

  19. Pressurized Fluidized Bed Combustion Second-Generation System Research and Development

    SciTech Connect (OSTI)

    A. Robertson; D. Horazak; R. Newby; H. Goldstein

    2002-11-01T23:59:59.000Z

    Research is being conducted under United States Department of Energy (DOE) Contract DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant--called a Second-Generation or Advanced Pressurized Circulating Fluidized Bed Combustion (APCFB) plant--offers the promise of efficiencies greater than 45% (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized-coal-fired plants with scrubbers. The APCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed boiler (PCFB), and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2300 F and higher. A conceptual design was previously prepared for this new type of plant and an economic analysis presented, all based on the use of a Siemens Westinghouse W501F gas turbine with projected carbonizer, PCFB, and topping combustor performance data. Having tested these components at the pilot plant stage, the referenced conceptual design is being updated to reflect more accurate performance predictions together with the use of the more advanced Siemens Westinghouse W501G gas turbine and a conventional 2400 psig/1050 F/1050 F/2-1/2 in. steam turbine. This report describes the updated plant which is projected to have an HHV efficiency of 48% and identifies work completed for the October 2001 through September 2002 time period.

  20. Fluidized-bed atomic layer deposition reactor for the synthesis of core-shell nanoparticles

    SciTech Connect (OSTI)

    Didden, Arjen P.; Middelkoop, Joost; Krol, Roel van de, E-mail: roel.vandekrol@helmholtzberlin.de [Delft University of Technology, Faculty of Applied Sciences, Department of Chemical Engineering, P.O. Box 5045, 2600 GA Delft (Netherlands); Besling, Wim F. A. [NXP Semiconductors, High Tech Campus 32, 5656 AE Eindhoven (Netherlands)] [NXP Semiconductors, High Tech Campus 32, 5656 AE Eindhoven (Netherlands); Nanu, Diana E. [Thin Film Factory B.V., Hemma Oddastrjitte 5, 8927 AA Leeuwarden (Netherlands)] [Thin Film Factory B.V., Hemma Oddastrjitte 5, 8927 AA Leeuwarden (Netherlands)

    2014-01-15T23:59:59.000Z

    The design of a fluidized bed atomic layer deposition (ALD) reactor is described in detail. The reactor consists of three parts that have all been placed in one protective cabinet: precursor dosing, reactor, and residual gas treatment section. In the precursor dosing section, the chemicals needed for the ALD reaction are injected into the carrier gas using different methods for different precursors. The reactor section is designed in such a way that a homogeneous fluidized bed can be obtained with a constant, actively controlled, reactor pressure. Furthermore, no filters are required inside the reactor chamber, minimizing the risk of pressure increase due to fouling. The residual gas treatment section consists of a decomposition furnace to remove residual precursor and a particle filter and is installed to protect the pump. In order to demonstrate the performance of the reactor, SiO{sub 2} particles have been coated with TiO{sub 2} using tetrakis-dimethylamino titanium (TDMAT) and H{sub 2}O as precursors. Experiments with varying pulse times show that saturated growth can be obtained with TDMAT pulse times larger than 600 s. Analysis of the powder with High-Angle Annular Dark-Field Scanning Transmission Electron Microscopy (HAADF-STEM) and energy dispersive X-ray spectroscopy confirmed that after 50 cycles, all SiO{sub 2} particles were coated with a 1.6 nm homogenous shell of TiO{sub 2}.

  1. The development of a 20-inch indirect fired fluidized bed gasifier

    SciTech Connect (OSTI)

    Flanigan, V.J.; Sitton, O.C.; Huang, W.E

    1988-03-01T23:59:59.000Z

    This report discusses the design, fabrication and operation of a 20'' I.D. fluidized bed gasifier producing medium Btu gas. The reactor is indirectly heated using 30 x 1-inch U-tubes inserted in the inert bed. The U-tubes are heated using flue gases produced from a propane burner system located at the bottom of the reactor. The feed material was dry wood chips fed into the bed with a 6in. auger. The reactor was fed both into the bed and at the top of the bed. The fluidizing medium was superheated steam which was superheated to 1000/degree/F. The gas produced from the reactor was passed through a cyclone for char removal and routed to the flare for combustion and disposal. The parameters measured during the experimental runs were wood feed rate, steam flow rate, steam temperatures, bed temperatures, free board temperatures, product gas temperatures, bed differential pressures, char production, gas production, gas analyses, and tar production. The parameters measured in the laboratory were moisture contents (wood and char), ash contents (wood and char), and tar content. 9 refs., 19 figs., 11 tabs.

  2. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Songgeng Li; John T. Riley

    2005-10-01T23:59:59.000Z

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2005 through September 30, 2005. The following tasks have been completed. First, the construction of the Circulating Fluidized-Bed (CFB) Combustor Building was completed. The experimental facilities have been moved into the CFB Combustor Building. Second, the fabrication and manufacture of the CFBC Facility is in the final stage and is expected to be completed before November 30, 2005. Third, the drop tube reactor has been remodeled and installed to meet the specific requirements for the investigation of the effects of flue gas composition on mercury oxidation. This study will start in the next quarter. Fourth, the effect of sulfur dioxide on molecular chlorine via the Deacon reaction was investigated. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  3. Influence of sulfation-enhancement salt additives on the corrosion behavior of materials in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Chopra, O.K.; Smith, G.W.; Lenc, J.F.; Myles, K.M.; Johnson, I.

    1981-12-01T23:59:59.000Z

    Increased utilization of CaO can reduce the amount of limestone required for SO/sub 2/ retention in atmospheric fluidized-bed combustion (AFBC) systems. A recently developed method of improving the utilization involves treating the limestone with various salts, such as NaCl, CaCl/sub 2/, or Na/sub 2/CO/sub 3/. The present report provides information on the influence of these sulfation-enhancement salt additives on corrosion of candidate structural materials for AFBC systems. Four 100-h and two 1000-h corrosion test runs were conducted in a 152-mm-ID fluidized-bed coal combustor. In each run, three air-cooled corrosion probes and four uncooled corrosion coupon holders, each with seven specimens, were installed at various locations in the fluidized bed and freeboard sections of the combustor. The temperature of the corrosion specimens ranged from 400 to 850/sup 0/C. As controls, some of the runs were made without any salt additions. The results indicate that the presence of salt has no effect on the corrosion behavior of the various iron- and nickel-base alloys that were placed in the freeboard section of the combustor. Although the uncooled alloys within the fluidized bed do undergo oxidation/sulfidation corrosion, the addition of CaCl/sub 2/ does not further affect the corrosion rate; the addition of NaCl or Na/sub 2/CO/sub 3/ increases the corrosion rates for the high-nickel alloys, but not for the stainless steels. The observed corrosion rates for all of the alloys from within the fluidized bed containing approximately 2 mol % CaCl/sub 2/ or Na/sub 2/CO/sub 3/ are in good agreement with the rates reported in other similar studies without salt additions. The corrosion data and a metallographic evaluation of the corrosion specimens are presented.

  4. REMOTE DETECTION OF INTERNAL PIPELINE CORROSION USING FLUIDIZED SENSORS

    SciTech Connect (OSTI)

    Narasi Sridhar; Garth Tormoen; Ashok Sabata

    2005-10-31T23:59:59.000Z

    Pipelines present a unique challenge to monitoring because of the great geographical distances they cover, their burial depth, their age, and the need to keep the product flowing without much interruption. Most other engineering structures that require monitoring do not pose such combined challenges. In this regard, a pipeline system can be considered analogous to the blood vessels in the human body. The human body has an extensive ''pipeline'' through which blood and other fluids are transported. The brain can generally sense damage to the system at any location and alert the body to provide temporary repair, unless the damage is severe. This is accomplished through a vast network of fixed and floating sensors combined with a vast and extremely complex communication/decision making system. The project described in this report mimics the distributed sensor system of our body, albeit in a much more rudimentary fashion. Internal corrosion is an important factor in pipeline integrity management. At present, the methods to assess internal corrosion in pipelines all have certain limitations. In-line inspection tools are costly and cannot be used in all pipelines. Because there is a significant time interval between inspections, any impact due to upsets in pipeline operations can be missed. Internal Corrosion Direct Assessment (ICDA) is a procedure that can be used to identify locations of possible internal corrosion. However, the uncertainties in the procedure require excavation and location of damage using more detailed inspection tools. Non-intrusive monitoring techniques can be used to monitor internal corrosion, but these tools also require pipeline excavation and are limited in the spatial extent of corrosion they can examine. Therefore, a floating sensor system that can deposit at locations of water accumulation and communicate the corrosion information to an external location is needed. To accomplish this, the project is divided into four main tasks related to wireless data transmission, corrosion sensor development, sensor system motion and delivery, and consideration of other pipeline operations issues. In the first year of the program, focus was on sensor development and wireless data transmission. The second year of the program, which was discontinued due to funding shortfall, would have focused on further wireless transmission development, packaging of sensor on wireless, and other operational issues. Because, the second year funding has been discontinued, recommendations are made for future studies.

  5. Laser cooling of solids

    SciTech Connect (OSTI)

    Epstein, Richard I [Los Alamos National Laboratory; Sheik-bahae, Mansoor [UNM

    2008-01-01T23:59:59.000Z

    We present an overview of solid-state optical refrigeration also known as laser cooling in solids by fluorescence upconversion. The idea of cooling a solid-state optical material by simply shining a laser beam onto it may sound counter intuitive but is rapidly becoming a promising technology for future cryocooler. We chart the evolution of this science in rare-earth doped solids and semiconductors.

  6. Laboratory-Scale Burning and Characterizing of Composite Solid Propellant for Studying Novel Nanoparticle Synthesis Methods 

    E-Print Network [OSTI]

    Allen, Tyler Winston

    2013-04-29T23:59:59.000Z

    This thesis examines the effects of nanoparticle, metal-oxide additives on the burning rate of composite solid propellants. Recent advancements in chemical synthesis techniques have allowed for the production of improved solid rocket propellant nano...

  7. Structure and dynamics studies by solid-state nuclear magnetic resonance spectroscopy

    E-Print Network [OSTI]

    Itin, Boris

    2002-01-01T23:59:59.000Z

    The major goal of this work is the development of high resolution solid state 205T1 NMR techniques and their application to the elucidation of the mechanism and dynamics of ion exchange in biological solids. The thesis ...

  8. 3rd International Symposium on Advanced Fluid/Solid Science and Technology in Experimental Mechanics, 7-10 December. 2008, Tainan, Taiwan Detection of wave propagation by a nonstationary cross-spectral density technique

    E-Print Network [OSTI]

    Texas at Arlington, University of

    Mechanics, 7-10 December. 2008, Tainan, Taiwan Detection of wave propagation by a nonstationary cross for the propagation time, and was applied to a shock and a detonation wave. The results show that by including prone to error than the cross-correlation technique. Key words Wave propagation, Cross-spectrum, Time

  9. Tetraphenylborate Solids Stability Tests

    SciTech Connect (OSTI)

    Walker, D.D. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

    1997-12-19T23:59:59.000Z

    Tetraphenylborate solids provide a potentially large source of benzene in the slurries produced in the In-Tank Precipitation process. The stability of the solids is an important consideration in the safety analysis of the process and we desire an understanding of the factors that influence the rate of conversion of the solids to benzene.

  10. Solid State Division

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M. (eds.)

    1989-08-01T23:59:59.000Z

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  11. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01T23:59:59.000Z

    Economic analysis of the construction and operation of by-product electric power and steam/power cogeneration systems in coal fired fluidized-bed steam cycles, located at individual industrial sites analyzed by the author, is being presented...

  12. Solid Waste Management Written Program

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Solid Waste Management Program Written Program Cornell University 8/28/2012 #12;Solid Waste.................................................................... 4 4.2.1 Compost Solid Waste Treatment Facility.................................................................... 4 4.2.2 Pathological Solid Waste Treatment Facility

  13. Contamination and solid state welds.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-05-01T23:59:59.000Z

    Since sensitivity to contamination is one of the verities of solid state joining, there is a need for assessing contamination of the part(s) to be joined, preferably nondestructively while it can be remedied. As the surfaces that are joined in pinch welds are inaccessible and thus provide a greater challenge, most of the discussion is of the search for the origin and effect of contamination on pinch welding and ways to detect and mitigate it. An example of contamination and the investigation and remediation of such a system is presented. Suggestions are made for techniques for nondestructive evaluation of contamination of surfaces for other solid state welds as well as for pinch welds. Surfaces that have good visual access are amenable to inspection by diffuse reflection infrared Fourier transform (DRIFT) spectroscopy. Although other techniques are useful for specific classes of contaminants (such as hydrocarbons), DRIFT can be used most classes of contaminants. Surfaces such as the interior of open tubes or stems that are to be pinch welded can be inspected using infrared reflection spectroscopy. It must be demonstrated whether or not this tool can detect graphite based contamination, which has been seen in stems. For tubes with one closed end, the technique that should be investigated is emission infrared spectroscopy.

  14. Process for generating electricity in a pressurized fluidized-bed combustor system

    DOE Patents [OSTI]

    Kasper, Stanley (Pittsburgh, PA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for generating electricity using a gas turbine as part of a pressurized fluidized-bed combustor system wherein coal is fed as a fuel in a slurry in which other constituents, including a sulfur sorbent such as limestone, are added. The coal is combusted with air in a pressurized combustion chamber wherein most of the residual sulfur in the coal is captured by the sulfur sorbent. After particulates are removed from the flue gas, the gas expands in a turbine, thereby generating electric power. The spent flue gas is cooled by heat exchange with system combustion air and/or system liquid streams, and the condensate is returned to the feed slurry.

  15. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Zhongxian Cheng; Yan Cao; John Smith

    2006-09-30T23:59:59.000Z

    This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2006 through September 30, 2006. The following activities have been completed: the steel floor grating around the riser in all levels and the three-phase power supply for CFBC System was installed. Erection of downcomers, loop seals, ash bunker, thermal expansion joints, fuel and bed material bunkers with load cells, rotary air-lock valves and fuel flow monitors is underway. Pilot-scale slipstream tests conducted with bromine compound addition were performed for two typical types of coal. The purposes of the tests were to study the effect of bromine addition on mercury oxidization. From the test results, it was observed that there was a strong oxidization effect for Powder River Basin (PRB) coal. The proposed work for next quarter and project schedule are also described.

  16. [Pulsed atmospheric fluidized-bed combustion]. Technical progress report, August--October 1988

    SciTech Connect (OSTI)

    Not Available

    1988-10-01T23:59:59.000Z

    This second Quarterly Technical Progress Report presents the results of work accomplished during the period July 25 through October 30, 1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in environmentally acceptable manner. Progress during this period accelerated rapidly. The site for the installation of the PAFBC was completed. All of the system components, including the fabrication of the furnace, were also completed. Additional component testing and inspection was also completed. By the end of this period the AFBC was completely assembled and installed at the site adjacent to the MTCI facility and shakedown tests were initiated. 20 figs., 2 tabs.

  17. The effect of bed temperature on oxygen partial pressures in an atmospheric fluidized bed combustor

    SciTech Connect (OSTI)

    Malik, S.R. [PCSIR, Karachi (Pakistan). Fuel Research Centre; Gibbs, B.M. [Univ. of Leeds (United Kingdom). Dept. of Fuel and Energy

    1996-12-31T23:59:59.000Z

    One of the factors which cause corrosion of in-bed material is the existence of low oxygen levels. Therefore, oxygen`s partial pressure measurements are important for corrosion studies in atmospheric fluidized bed combustor (AFBC). The effect of bed temperature on oxygen levels has been discussed in this paper. The experiments were conducted on a 0.3 meters square combustor. In-bed oxygen partial pressures were measured using zirconia oxygen probes and recorded on a computerized data logging system. Detail statistical analysis of the data has been presented. The probability density function (PDF) was the most important statistical parameter which reveals not only how long environment is exposed to oxidizing reducing conditions but also the probability whether corrosion could occur.

  18. Testing of Oregon dolomite from central Kentucky in an atmospheric fluidized-bed combustor. Technical report

    SciTech Connect (OSTI)

    Not Available

    1984-12-01T23:59:59.000Z

    This report is the first in a series of six limestone reports, and describes the results of testing of an Oregon dolomite from central Kentucky (1/8 in. x 0, 63% CaCO/sub 3/, 31% MgCO/sub 3/) in a 2 ft/ 8 in. x 2 ft. 5 in., 0.75-MW AFBC. All six limestones (or dolomites) were tested using the same coal, a washed Western Kentucky No. 9 coal (1/4 in. x 0, 3.1% sulfur, 9% ash, 13230 Btu/lb.). Operating problems encountered are described. On the basis of numbers, it was concluded that an economic re-evaluation of low-superficial-velocity fluidized beds is warranted, and that it is feasible to burn high-sulfur coals efficiently in an AFBC when Oregon dolomite from central Kentucky is used as the sulfur sorbent.

  19. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22T23:59:59.000Z

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  20. Bed material agglomeration during fluidized bed combustion. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Smeenk, J.L.

    1995-04-01T23:59:59.000Z

    Experiments performed support the hypothesis that a reducing atmosphere during fluidized bed coal combustion contributes to the formation of agglomerates. Reducing conditions are imposed by controlling the amount of combustion air supplied to the combustor, 50% of theoretical in these experiments. These localized reducing conditions may arise from either poor lateral bed mixing or oxygen-starved conditions due to the coal feed locations. Deviations from steady-state operating conditions in bed pressure drop may be used to detect agglomerate formation. Interpretation of the bed pressure drop was made more straightforward by employing a moving average difference method. During steady-state operation, the difference between the moving point averages should be close to zero, within {plus_minus}0.03 inches of water. Instability within the combustor, experienced once agglomerates begin to form, can be recognized as larger deviations from zero, on the magnitude of {plus_minus}0.15 inches of water.

  1. Rocky Flats Plant fluidized-bed incinerator. Engineering design and reference manual

    SciTech Connect (OSTI)

    Meile, L.J.

    1982-11-05T23:59:59.000Z

    The information in this manual is being presented to complete the documentation of the fluidized-bed incineration (FBI) process development at the Rocky Flats Plant. The information pertains to the 82-kg/hour demonstration unit at the Rocky Flats Plant. This document continues the presentation of design reference material in the aeas of equipment drawings, space requirements, and unit costs. In addition, appendices contain an operating procedure and an operational safety analysis of the process. The cost figures presented are based on 1978 dollars and have not been converted to a current dollar value. Also, the cost of modifications are not included, since they would be insignificant if they were incorporated into a new installation.

  2. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Songgeng Li

    2006-01-01T23:59:59.000Z

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period October 1, 2005 through December 31, 2005. Work was performed on the following activities. First, the fabrication and manufacture of the CFBC Facility is nearly completed. The erection of the CFBC facility is expected to start in the second week of February, 2006. Second, effect of flue gas components on mercury oxidation was investigated in a drop tube reactor. As a first step, experiment for mercury oxidation by chlorine was investigated. The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter is described in this report.

  3. [Pulsed atmospheric fluidized bed combustion (PAFBC)]. Technical progress report, May--July 1988

    SciTech Connect (OSTI)

    Not Available

    1988-10-01T23:59:59.000Z

    This first Quarterly Technical Progress Report presents the results of work accomplished during the period April 19 through July 24,1988. The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. the program scope consisted of two tasks; the first was to establish preliminary feasibility by the use of theoretical and state-of-the-art information. This task was completed during the first quarter of the contract period and a topical report entitled, ``Pulsed Atmospheric Fluidized Bed combustion (PAFBC) - Preliminary Feasibility Study`` was prepared as a ``decision point to proceed`` deliverable in accordance with the terms of the contract. This first quarterly progress report therefore covers the contract activities subsequent to the approval of the feasibility study and the decision to proceed with the Task 2 effort. As the initial quarterly technical progress report, this document includes a subsection on background which will be omitted in subsequent reports. All effort during this period was devoted to the design and analysis of the PAFBC. Design drawings were prepared and fabrication and procurement initiated. Quotations were evaluated and a fabrication contract awarded. A site adjacent to the MTCI building was chosen for the installation of the PAFBC. Some ancillary components were purchased, renovated, and tested. Some delays in delivery of components have resulted in some schedule delay. It is anticipated that the program pace will accelerate as soon as parts are received and installation and assembly are initiated. 10 figs.,1 tab.

  4. Characterizing and modeling combustion of mild-gasification chars in pressurized fluidized beds

    SciTech Connect (OSTI)

    Daw, C.S.

    1995-10-01T23:59:59.000Z

    Oak Ridge National Laboratory (ORNL) is supported by the Morgantown Energy Technology Center (METC) of the Department of Energy (DOE) under FWP-FEAA310 to characterize the fuel properties of liquid and char coproducts from the mild gasification of coal, Because most of the energy content of coals subjected to mild gasification is retained in the byproduct char, efficient and cost-effective utilization of the char is essential in insuring that candidate gasification processes are commercially viable. One potential use for char of particular interest to DOE is pressurized fluidized bed combustion (PFBC). PFBC is of particular interest because it has the potential for 10 to 30 percent greater overall energy efficiency than atmospheric fluidized bed combustion (AFBC), While bench-scale tools and analytical procedures for characterizing fuels for AFBC have been recently demonstrated, no such tools have been reliably demonstrated for PFBC. This report summarizes the results of joint research collaboration between ORNL and B&W that has been directed at modifying the previously developed AFBC fuel characterization procedures to be applicable for mild-gasification chars and PFBC conditions. The specific objectives were to: (1) characterize the combustion reactivity of a selected set of candidate mild- gasification chars at PFB conditions; (2) compare the measured char characteristics with those of more conventional PFBC fuels; (3) modify an AFBC computer code previously developed by B&W and ORNL for the Electric Power Research Institute (EPRI) to predict PFBC performance; and (4) apply the modified code and measured char combustion characteristics to make performance predictions for the candidate chars relative to more conventional fuels.

  5. Staged combustion for reduced NO/sub x/ emissions from an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Duqum, J.N.; Fortino, R.T.; Loudin, K.L.

    1989-06-01T23:59:59.000Z

    To reduce exhaust NO/sub x/ below existing levels in an atmospheric fluidized-bed combustor, two-stage combustion was studied on the 6' /times/ 6' (6 /times/ 6) atmospheric fluidized-bed combustion (AFBC) facility at the Babcock and Wilcox (B and W) Alliance, Ohio, Research Center. This report documents the tests and related numerical modeling. The two-stage testing was conducted with Pittsburgh No. 8 coal. NO/sub x/ was reduced to a minimum level of 132 ppM at the stack, or about 50% below baseline NO/sub x/ with overfire air (OFA). Combustion efficiency was maintained at 98% at these minimum NO/sub x/ conditions. Although acceptable sulfur capture was not maintained, tests with overbed fly ash recycle and higher OFA jet velocity indicated that sulfur capture can be brought to acceptable levels by improving freeboard mixing. Numerical modeling was investigated as a means of scaling the results of staged combustion from the 6 /times/ 6 AFBC facility to larger AFBC units. B and W's existing three-dimensional models for pulverized-coal combustion and NO/sub x/ formation and reduction were applied to the 6 /times/ 6 freeboard. Lagrangian particle transport models were found capable of predicting elutriation. Exit flue gas temperatures were well predicted, but internal freeboard temperatures were underpredicted. B and W's NO/sub x/ model under predicted reaction rates for fuel NO/sub x/ production and reduction. The OFA ports for this project were designed using mixing analysis without combustion. This type of analysis can help in the design of OFA ports for larger units such as Tennessee Valley Authority's 20-MW pilot-scale plant. However, additional computer code validation is required before combustion and NO/sub x/ analyses can be used for scale-up. 37 refs., 43 figs.

  6. An experimental study of temperature of burning coal particle in fluidized bed

    SciTech Connect (OSTI)

    Mirko Komatina; Vasilije Manovic; Dragoljub Dakic [University of Belgrade, Belgrade (Serbia and Montenegro). Faculty of Mechanical Engineering

    2006-02-01T23:59:59.000Z

    The purpose of this study was to investigate the temperature of coal particle during combustion in fluidized bed (FB). It is necessary to know the coal particle temperature in order to predict kinetics of chemical reactions within and at the surface of coal particle, accurate NOx and SO{sub 2} emission, fragmentation, attrition, the possibility of ash melting, etc. The experimental investigations were conducted in order to obtain the reliable data on the temperature of particle burning in the FB. A method using thermocouple was developed and applied for measurements. Thermocouple was inserted in the center of the particle shaped into spherical form with various diameters: 5, 7, 8, and 10 mm. Two characteristic types of low-rank Serbian coals were investigated. Experiments were done at the FB temperature in the range of 590-710{sup o}C. Two types of experiments were performed: (I) combustion using air as fluidization gas and (ii) devolatilization with N{sub 2} followed by combustion of obtained char in air. The temperature histories of particles during all stages after introducing in the FB were analyzed. Temperature difference between the burning particle and the FB was defined as a criterion, for comparison. It was shown that the temperature profile depends on the type of the coal and the particle size. The higher temperature difference between the burning particle and the FB was obtained for smaller particles and for lignite (130-180{sup o}C) in comparison to the brown coal (70-130{sup o}C). The obtained results indicated that a primary role in the temperature history of coal particle have the mass and heat transfer through combusting particle. 24 refs., 6 figs., 3 tabs.

  7. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L. [Univ. Federico II of Naples, Napoli (Italy). Dept. of Chemical Engineering] [Univ. Federico II of Naples, Napoli (Italy). Dept. of Chemical Engineering; Arena, U. [National Research Council, Napoli (Italy). Inst. for Combustion Research] [National Research Council, Napoli (Italy). Inst. for Combustion Research; [Univ. of Naples, Caserta (Italy). Dept. of Environmental Sciences

    1999-05-01T23:59:59.000Z

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  8. Creating Addressable Aqueous Microcompartments above Solid Supported

    E-Print Network [OSTI]

    combinatorial libraries of solid supported fluid lipid membranes because these systems retain many a novel soft lithographic technique5 for partitioning and addressing aqueous solutions above supported methodology affords the ability to create a large number of aqueous compartments consisting of various

  9. Solid State Processing of Fully Dense Anistropic Nanocomposition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This will be accomplished by a revolutionary solid-state processing technique called Friction Consolidation and Extrusion (FC&E). Processing of sintered (Nd, Dy)-Fe-B type magnets...

  10. Development of methods to predict agglomeration and deposition in fluidized-bed combustion systems (FBCS). Topical report

    SciTech Connect (OSTI)

    Mann, M.D.; Henderson, A.K.; Swanson, M.L.; Allan, S.E.

    1996-02-01T23:59:59.000Z

    The successful design and operation of advanced combustion systems require the ability to control and mitigate ash-related problems. The major ash-related problems are slag flow control, slag attack on the refractory, ash deposition on heat-transfer surfaces, corrosion and erosion of equipment materials, and emissions control. These problems are the result of physical and chemical interactions of the fuels, bed materials, and system components. The interactions that take place and ultimately control ash behavior in fluidized-bed combustion (FBC) systems are controlled by the abundance and association of the inorganic components in coal and by the system conditions. Because of the complexity of the materials and processes involved, the design and operations engineer often lacks the information needed to predict ash behavior and reduce ash-related problems. The deposition of ashes from the fluidized bed combustion of lignite and petroleum coke is described in this paper.

  11. Verification of sub-grid filtered drag models for gas-particle fluidized beds with immersed cylinder arrays

    SciTech Connect (OSTI)

    Sarkar, Avik; Sun, Xin; Sundaresan, Sankaran

    2014-03-01T23:59:59.000Z

    The accuracy of coarse-grid multiphase CFD simulations of fluidized beds may be improved via the inclusion of filtered constitutive models. In our previous study (Sarkar et al., Chem. Eng. Sci., 104, 399-412), we developed such a set of filtered drag relationships for beds with immersed arrays of cooling tubes. Verification of these filtered drag models is addressed in this work. Predictions from coarse-grid simulations with the sub-grid filtered corrections are compared against accurate, highly-resolved simulations of full-scale turbulent and bubbling fluidized beds. The filtered drag models offer a computationally efficient yet accurate alternative for obtaining macroscopic predictions, but the spatial resolution of meso-scale clustering heterogeneities is sacrificed.

  12. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  13. Solid Waste Management (Connecticut)

    Broader source: Energy.gov [DOE]

    Solid waste facilities operating in Connecticut must abide by these regulations, which describe requirements and procedures for issuing construction and operating permits; environmental...

  14. Solid Waste Permits (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Environmental Quality administers the rules and regulations governing the storage, collection, processing, recovery, and reuse of solid waste protect the air,...

  15. Solid Waste Management (Indiana)

    Broader source: Energy.gov [DOE]

    The state supports the implementation of source reduction, recycling, and other alternative solid waste management practices over incineration and land disposal. The Indiana Department of...

  16. Solid Waste Management (Michigan)

    Broader source: Energy.gov [DOE]

    This Act encourages the Department of Environmental Quality and Health Department representatives to develop and encourage methods for disposing solid waste that are environmentally sound, that...

  17. ADVANCING THE FUNDAMENTAL UNDERSTANDING AND SCALE-UP OF TRISO FUEL COATERS VIA ADVANCED MEASUREMENT AND COMPUTATIONAL TECHNIQUES

    SciTech Connect (OSTI)

    Biswas, Pratim; Al-Dahhan, Muthanna

    2012-11-01T23:59:59.000Z

    Tri-isotropic (TRISO) fuel particle coating is critical for the future use of nuclear energy produced byadvanced gas reactors (AGRs). The fuel kernels are coated using chemical vapor deposition in a spouted fluidized bed. The challenges encountered in operating TRISO fuel coaters are due to the fact that in modern AGRs, such as High Temperature Gas Reactors (HTGRs), the acceptable level of defective/failed coated particles is essentially zero. This specification requires processes that produce coated spherical particles with even coatings having extremely low defect fractions. Unfortunately, the scale-up and design of the current processes and coaters have been based on empirical approaches and are operated as?black boxes. Hence, a voluminous amount of experimental development and trial and error work has been conducted. It has been clearly demonstrated that the quality of the coating applied to the fuel kernels is impacted by the hydrodynamics, solids flow field, and flow regime characteristics of the spouted bed coaters, which themselves are influenced by design parameters and operating variables. Further complicating the outlook for future fuel-coating technology and nuclear energy production is the fact that a variety of new concepts will involve fuel kernels of different sizes and with compositions of different densities. Therefore, without a fundamental understanding the underlying phenomena of the spouted bed TRISO coater, a significant amount of effort is required for production of each type of particle with a significant risk of not meeting the specifications. This difficulty will significantly and negatively impact the applications of AGRs for power generation and cause further challenges to them as an alternative source of commercial energy production. Accordingly, the proposed work seeks to overcome such hurdles and advance the scale-up, design, and performance of TRISO fuel particle spouted bed coaters. The overall objectives of the proposed work are to advance the fundamental understanding of the hydrodynamics by systematically investigating the effect of design and operating variables, to evaluate the reported dimensionless groups as scaling factors, and to establish a reliable scale-up methodology for the TRISO fuel particle spouted bed coaters based on hydrodynamic similarity via advanced measurement and computational techniques. An additional objective is to develop an on-line non-invasive measurement technique based on gamma ray densitometry (i.e. Nuclear Gauge Densitometry) that can be installed and used for coater process monitoring to ensure proper performance and operation and to facilitate the developed scale-up methodology. To achieve the objectives set for the project, the work will use optical probes and gamma ray computed tomography (CT) (for the measurements of solids/voidage holdup cross-sectional distribution and radial profiles along the bed height, spouted diameter, and fountain height) and radioactive particle tracking (RPT) (for the measurements of the 3D solids flow field, velocity, turbulent parameters, circulation time, solids lagrangian trajectories, and many other of spouted bed related hydrodynamic parameters). In addition, gas dynamic measurement techniques and pressure transducers will be utilized to complement the obtained information. The measurements obtained by these techniques will be used as benchmark data to evaluate and validate the computational fluid dynamic (CFD) models (two fluid model or discrete particle model) and their closures. The validated CFD models and closures will be used to facilitate the developed methodology for scale-up, design and hydrodynamic similarity. Successful execution of this work and the proposed tasks will advance the fundamental understanding of the coater flow field and quantify it for proper and safe design, scale-up, and performance. Such achievements will overcome the barriers to AGR applications and will help assure that the US maintains nuclear energy as a feasible option to meet the nationÃ?Â?Ã?Â?Ã

  18. Design of slurry bubble column reactors: novel technique for optimum catalyst size selection contractual origin of the invention

    DOE Patents [OSTI]

    Gamwo, Isaac K. (Murrysville, PA); Gidaspow, Dimitri (Northbrook, IL); Jung, Jonghwun (Naperville, IL)

    2009-11-17T23:59:59.000Z

    A method for determining optimum catalyst particle size for a gas-solid, liquid-solid, or gas-liquid-solid fluidized bed reactor such as a slurry bubble column reactor (SBCR) for converting synthesis gas into liquid fuels considers the complete granular temperature balance based on the kinetic theory of granular flow, the effect of a volumetric mass transfer coefficient between the liquid and the gas, and the water gas shift reaction. The granular temperature of the catalyst particles representing the kinetic energy of the catalyst particles is measured and the volumetric mass transfer coefficient between the gas and liquid phases is calculated using the granular temperature. Catalyst particle size is varied from 20 .mu.m to 120 .mu.m and a maximum mass transfer coefficient corresponding to optimum liquid hydrocarbon fuel production is determined. Optimum catalyst particle size for maximum methanol production in a SBCR was determined to be in the range of 60-70 .mu.m.

  19. Hot-gas desulfurization. II. Use of gasifier ash in a fluidized-bed process. Final report

    SciTech Connect (OSTI)

    Schrodt, J.T.

    1981-02-01T23:59:59.000Z

    Three gasifier coal ashes were used as reactant/sorbents in batch fluidized-beds to remove hydrogen sulfide from hot, made-up fuel gases. It is predominantly the iron oxide in the ash that reacts with and removes the hydrogen sulfide; the sulfur reappears in ferrous sulfide. Sulfided ashes were regenerated by hot, fluidizing streams of oxygen in air; the sulfur is recovered as sulfur dioxide, exclusively. Ash sorption efficiency and sulfur capacity increase and stabilize after several cycles of use. These two parameters vary directly with the iron oxide content of the ash and process temperature, but are independent of particle size in the range 0.01 - 0.02 cm. A western Kentucky No. 9 ash containing 22 weight percent iron as iron oxide sorbed 4.3 weight percent sulfur at 1200/sup 0/F with an ash sorption efficiency of 0.83 at ten percent breakthrough. A global, fluidized-bed, reaction rate model was fitted to the data and it was concluded that chemical kinetics is the controlling mechanism with a predicted activation energy of 19,600 Btu/lb mol. Iron oxide reduction and the water-gas-shift reaction were two side reactions that occurred during desulfurization. The regeneration reaction occurred very rapidly in the fluid-bed regime, and it is suspected that mass transfer is the controlling phenomenon.

  20. Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

    SciTech Connect (OSTI)

    Turgut Gur

    2010-04-30T23:59:59.000Z

    This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

  1. Experimental and theoretical investigation on the mechanism of transient bubble images in fluidized-bed combustors: Systematic interpretation and analysis. Final report, July 1992--July 1995

    SciTech Connect (OSTI)

    Hisashi O. Kono

    1995-08-01T23:59:59.000Z

    For the improvement of the design and operation of the FBC systems, the insight into the intrinsic transient bubbling phenomena in freely bubbling fluidized beds is of vital importance. The authors have found several basic new bubbling mechanisms in this work experimentally, and some of them have not been published in past literature. Using the two dimensional fluidized bed, the images of transient bubbling behavior were recorded by videos, and processed and analyzed by computers. As the results of experiments, the following new experimental facts were found: (1) transient bubbles change and fluctuate their size and shape over very short time intervals (on the order of 30 milliseconds); (2) bubble disappearance and reappearance occurred in the emulsion phase in addition to the known phenomena of coalescence and splitting. The bubble interaction occurred between the bubbles and adjacent emulsion phase and also among the transient bubbles; (3) bubble`s velocity fluctuated significantly, e.g., 0.6 to 3.0 m/s; (4) under one single specific fluidization condition, two different fluidization patterns appeared to occur randomly shifting from one pattern to the other or vice versa; (5) the erosion rates of in-bed tubes at ambient and elevated temperature could be predicted using material property data and transient behavior of bubbles. By introducing a new quantitative criterion which the authors call a gas stress index in the emulsion phase, the comparison of the fluidization quality between two and three dimensional fluidized beds was accomplished. They found reasonable correspondence between the two beds, and concluded that the new findings of transient bubble behavior should hold true for both types of fluidized beds. 32 refs., 85 figs., 13 tabs.

  2. Optical on line techniques for nuclear applications

    SciTech Connect (OSTI)

    Doizi, D. [CEA, Nuclear Energy Div. DEN, DANS/DPC/SECR/LSRM (France); Pailloux, A.; Maury, C.; Sirven, J. B.; Dauvois, V.; Roujou, J. L.; Rosset, C. D. [CEA, Nuclear Energy Div. DEN, DANS/DPC (France); Hartmann, J. M. [CNRS., UMR 7583, LISA, Creteil (France)

    2011-07-01T23:59:59.000Z

    Optical on line techniques enable non intrusive physical measurements in harsh environments (high temperature, high pressure, radioactivity, ...). Optical absorption spectrometries such as UV-Visible, FTIR, CRDS have been successfully used to study gas phase speciation in different nuclear applications. LIBS which relies on laser matter interactions is a on line optical technique for solids and liquids elementary analysis. (authors)

  3. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E.; Grohmann, Karel; Himmel, Michael E.; Richard, Christopher J.

    1993-03-02T23:59:59.000Z

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  4. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO); Grohmann, Karel (Littleton, CO); Himmel, Michael E. (Littleton, CO); Richard, Christopher J. (Lakewood, CO)

    1993-01-01T23:59:59.000Z

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  5. Solid Flame: Fundamentals and

    E-Print Network [OSTI]

    Mukasyan, Alexander

    ;Self-propagating High-temperature Synthesis (SHS) Or Combustion Synthesis TECHNOLOGY FOR MATERIAL (solid) ignition front propagation cooling The Phenomenon of Wave Localization for Solid State Self-propagating) 1.0000 Temperature (K) 2744 Gas products amount (mol) 6.00E-15 Products heat capacity (J/K) 74

  6. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  7. Four stage, fluidized bed gasification process minimizes NO{sub x}

    SciTech Connect (OSTI)

    Lewis, F.M.; Haug, R.T.

    1999-07-01T23:59:59.000Z

    In 1981, after a long and thorough study of alternative methods of sewage sludge (biosolids) disposal, the City of Los Angeles (CLA) embarked on a pilot test program to incinerate dried sewage sludge from its Hyperion Wastewater Treatment Plant. This dried sludge is typically 47% ash, 53% combustible, and has an average higher heating value (HHV), moisture, ash-free (MAF) of 10,675 Btu/Lbm. The dried sludge is called sludge derived fuel (SDF). Approximately 8% of the MAF fraction of SDF is fuel-bound nitrogen. When SDF, with its extremely high fuel-bound nitrogen, was combusted in conventional multiple hearth and fluidized bed pilot plant furnaces, NO{sub x} emissions were extremely high ({gt}1,000 ppm). Faced with this dilemma, the CLA initiated an R and D program to reduce NO{sub x}. The pilot tests with a sub-stoichiometric fluid bed and an excess air afterburner (two-stages) reduced NO{sub x} to 400--600 ppm. With one intermediate stage added (three-stage), NO{sub x} was reduced to 130--150 ppm. However, when the following four-stage process was developed and tested, NO{sub x} was reduced to 50--75 ppm. Stage 1: Sub-stoichiometric fluidized bed operating at a nominal 30% stoichiometric air (SA). Stage 2:Sub-stoichiometric zone operating at a nominal 80% SA. Stage 3: Stoichiometric zone operating at a nominal 100% SA. Stage 4: Excess air zone (Afterburner) operating at a nominal 135% SA (35% excess air). After pilot testing was complete and design parameters established, three full-size, fluid bed gasifiers (two operational--one standby) were designed, constructed and operated until 1996. This paper describes the design, operation, and emission testing of these four-stage fluid bed gasifiers with special emphasis on the problems of (a) pneumatic feeding of SDF powder into the pressurized bed and (b) baghouse fabrics (expanded PTEE membrane on PTFE scrim). Final emission test results for NO{sub x} and other criteria pollutants are also presented.

  8. Closures for Course-Grid Simulation of Fluidized Gas-Particle Flows

    SciTech Connect (OSTI)

    Sankaran Sundaresan

    2010-02-14T23:59:59.000Z

    Gas-particle flows in fluidized beds and riser reactors are inherently unstable, and they manifest fluctuations over a wide range of length and time scales. Two-fluid models for such flows reveal unstable modes whose length scale is as small as ten particle diameters. Yet, because of limited computational resources, gas-particle flows in large fluidized beds are invariably simulated by solving discretized versions of the two-fluid model equations over a coarse spatial grid. Such coarse-grid simulations do not resolve the small-scale spatial structures which are known to affect the macroscale flow structures both qualitatively and quantitatively. Thus there is a need to develop filtered two-fluid models which are suitable for coarse-grid simulations and capturing the effect of the small-scale structures through closures in terms of the filtered variables. The overall objective of the project is to develop validated closures for filtered two-fluid models for gas-particle flows, with the transport gasifier as a primary, motivating example. In this project, highly resolved three-dimensional simulations of a kinetic theory based two-fluid model for gas-particle flows have been performed and the statistical information on structures in the 100-1000 particle diameters length scale has been extracted. Based on these results, closures for filtered two-fluid models have been constructed. The filtered model equations and closures have been validated against experimental data and the results obtained in highly resolved simulations of gas-particle flows. The proposed project enables more accurate simulations of not only the transport gasifier, but also many other non-reacting and reacting gas-particle flows in a variety of chemical reactors. The results of this study are in the form of closures which can readily be incorporated into existing multi-phase flow codes such as MFIX (www.mfix.org). Therefore, the benefits of this study can be realized quickly. The training provided by this project has prepared a PhD student to enter research and development careers in DOE laboratories or chemicals/energy-related industries.

  9. Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed chemical processing systems at Building 9212, Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is located within the Y-12 Plant on DOE`s Oak Ridge Reservation in Oak Ridge, Tennessee. The proposed replacement system would be based upon modern design criteria and safety analyses. The replacement AHF supply and distribution system equipment would be located on the existing Dock 8/8A at Building 9212. Utilities would be extended to the dock to service the process equipment. The following process equipment modules would be prefabricated for installation at the modified dock: an AHF cylinder enclosure, an AHF supply manifold and vaporizer module, an AHF sump tank and transfer skid, and an AHF supply off-gas scrubber assembly module. The fluidized-bed reactor system would be constructed in an area adjacent to the existing system in Building 9212. The replacement equipment would consist of a new reduction fluidized-bed reactor, a hydrofluorination fluidized-bed reactor, and associated air emission control equipment. The no-action alternative, which is the continued operation of the existing AHF supply and fluidized-bed reactor systems, was also evaluated.

  10. Management of Solid Waste (Oklahoma)

    Broader source: Energy.gov [DOE]

    The Solid Waste Management Division of the Department of Environmental Quality regulates solid waste disposal or any person who generates, collects, transports, processes, and/or disposes of solid...

  11. Course 28123 Chemical/Biochemical Engineering Laboratory

    E-Print Network [OSTI]

    Simaan, Nabil

    and solid extraction, organic synthesis, fixed bed enzyme reactor, solids handling, combustion/ high, filtration, drying in a tunnel, spray drying, fluidization and fluidized bed drying, distillation, absorption

  12. Solid Waste Management Act (Oklahoma)

    Broader source: Energy.gov [DOE]

    This Act establishes rules for the permitting, posting of security, construction, operation, closure, maintenance and remediation of solid waste disposal sites; disposal of solid waste in ways that...

  13. Solid Waste Rules (New Hampshire)

    Broader source: Energy.gov [DOE]

    The solid waste statute applies to construction and demolition debris, appliances, recyclables, and the facilities that collect, process, and dispose of solid waste. DES oversees the management of...

  14. Solid Waste Management (North Carolina)

    Broader source: Energy.gov [DOE]

    The Solid Waste Program regulates safe management of solid waste through guidance, technical assistance, regulations, permitting, environmental monitoring, compliance evaluation and enforcement....

  15. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01T23:59:59.000Z

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  16. Design considerations for sludge fired fluidized bed incinerator-cum-boiler

    SciTech Connect (OSTI)

    Bapat, D.W.; Vishwanathan, K. [Thermax Ltd., Pune (India). Research and Development Centre

    1997-12-31T23:59:59.000Z

    Thermal Limited, a major player in the field of Fluidized Bed Boilers in India, has supplied on a turnkey basis, three boilers each of 22.5 tons per hour capacity as a part of Cogeneration system for PT. South Pacific Viscose, Indonesia. The plant generates huge volumes of sludge from its effluent Treatment Plant (ETP). The sludge produced from the ETP has a moisture content of about 98%, which is subsequently reduced to about 78% using a decanter before feeding the sludge into the boiler. The waste sludge has a negative heating value ({minus}150 kcal/kg on NCV basis) and required coal as support fuel for burning. The plant`s requirement was to incinerate the entire sludge generated in the plant, which meant that nearly 50% of the fuel fed to the boiler consisted of the waste sludge. Additional requirements were to burn coal and oil as back-up fuels. This paper deals with the challenges encountered and various design features provided in the configuration of the incinerator-cum-boiler including conveying, feeding and spreading arrangement of the waste sludge for effective incineration in addition to burning coal and oil. Also included in the paper is a brief description of the automatic control logics for combustion control and bed temperature control.

  17. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.N.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1996-12-31T23:59:59.000Z

    Toxic trace metallic elements such as arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, and selenium are usually contained in coal in various forms and trace amounts. These metals will either stay in the ash or be vaporized during high temperature combustion. Portions of the vaporized metals may eventually be emitted from a combustion system in the form of metal fumes or particulates with diameters less than 1 micron, which are potentially hazardous to the environment. Current practice of controlling trace metal emissions during coal combustion employs conventional air pollution control devices (APCDs), such as electrostatic precipitators and baghouses, to collect fly ash and metal fumes. The control may not always be effective on metal fumes due to their extremely fine sizes. This study is to explore the opportunities for improved control of toxic trace metal emissions from coal-fired combustion systems. Specifically, the technology proposed is to employ suitable sorbents to reduce the amount of metal volatilization and capture volatilized metal vapors during fluidized bed coal combustion. The objective of the study was to investigate experimentally and theoretically the metal capture process.

  18. Effect of pressure on second-generation pressurized fluidized bed combustion plants

    SciTech Connect (OSTI)

    Robertson, A. [Foster Wheeler Development Corp., Livingston, NJ (United States); Bonk, D.L. [USDOE Morgantown Energy Technology Center, WV (United States)

    1993-06-01T23:59:59.000Z

    In the search for a more efficient, less costly, and more environmentally responsible method for generating electrical power from coal, research and development has turned to advanced pressurized fluidized bed combustion (PFBC) and coal gasification technologies. A logical extension of this work is the second- generation PFBC plant, which incorporates key components of each of these technologies. In this new type of plant, coal devolatilized/carbonized before it is injected into the PFB combustor bed, and the low Btu fuel gas produced by this process is burned in a gas turbine topping combustor. By integrating coal carbonization with PFB coal/char combustion, gas turbine inlet temperatures higher than 1149{degrees}C (2100{degrees}F) can be achieved. The carbonizer, PFB combustor, and particulate-capturing hot gas cleanup systems operate at 871{degrees}C (1600{degrees}F), permitting sulfur capture by lime-based sorbents and minimizing the release of coal contaminants to the gases. This paper presents the performance and economics of this new type of plant and provides a brief overview of the pilot plant test programs being conducted to support its development.

  19. Pressurized fluidized-bed hydroretorting of eastern oil shales. Progress report, September 1992--November 1992

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S.

    1992-12-01T23:59:59.000Z

    This report presents the work performed during the program quarter from September 1, 1992 though November 30, 1992. The Institute of Gas Technology (IGT) is the prime contractor for the program extension to develop the Pressurized Fluidized-Bed Hydroretorting II system technology. Four institutions are working with IGT as subcontractors. Task achievements are discussed for the following active tasks of the program: Subtask 3.7 innovative reactor concept testing; Subtask 3.9 catalytic hydroretorting; Subtask 3.10 autocatalysis in hydroretorting; Subtask 3.11 shale oil upgrading and evaluation; Subtask 4.1.3 stirred ball mill grinding; Subtask 4.1.5 alternative technology evaluation; Subtask 4.1.6 ultrafine size separation; Subtask 4.2.1 column flotation tests; Subtask 4.4 integrated grinding and flotation; Subtask 4.7 economic analysis; Subtask 6.2.2 wastewater treatability; Subtask 6.2.3 waste management facility conceptual design; and Subtask 8 project management and reporting.

  20. Pressurized Fluidized-Bed Hydroretorting of eastern oil shales. Final report, June 1992--January 1993

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Erekson, E.J.; Rue, D.M.; Lau, F.S. [Institute of Gas Technology, Chicago, IL (United States); Schultz, C.W.; Hatcher, W.E. [Alabama Univ., University, AL (United States). Mineral Resources Inst.; Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research; Bonner, W.P. [Tennessee Technological Univ., Cookeville, TN (United States)

    1993-03-01T23:59:59.000Z

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in September 1987 by the US Department of Energy was to perform the research necessary to develop the pressurized fluidized-bed hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation and upgrading, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The program was divided into the following active tasks: Task 3 -- Testing of Process Improvement Concepts; Task 4 -- Beneficiation Research; Task 6 -- Environmental Data and Mitigation Analyses; and Task 9 -- Information Required for the National Environmental Policy Act. In order to accomplish all of the program objectives, tho Institute of Gas Technology (ICT), the prime contractor, worked with four other institutions: The University of Alabama/Mineral Resources Institute (MRI), the University of Alabama College of Engineering (UA), University of Kentucky Center for Applied Energy Research (UK-CAER), and Tennessee Technological University (TTU). This report presents the work performed by IGT from June 1, 1992 through January 31, 1993.

  1. Technology assessment for an atmospheric fluidized-bed combustion demonstration plant

    SciTech Connect (OSTI)

    Siman-Tov, M; Jones, Jr, J E

    1980-01-01T23:59:59.000Z

    This study assesses the atmospheric fluidized-bed combustion (AFBC) technology with respect to design, construction, and operation of a demonstration power plant in the range of 150 to 250 MW(e) capacity and identifies the most critical research and development needs for the plant project. The general conclusion of these studies is that AFBC is feasible for large power plants and that it has a generally good potential for providing an economically and environmentally acceptable alternative to conventional coal-fired power plants. Several areas of technical uncertainty must, however, be resolved in order to ensure success of an AFBC demonstration plant project. Much of the existing data base for AFBC comes from small-scale test units, and much of it is still inconclusive. A number of operational and design problems exist that do not yet have conclusive answers. A focused research and development program aimed at the early resolution of these problems should be carried out to ensure successful construction and operation of the proposed AFBC demonstration plant and early commercialization of the technology. A large flexible feeding test facility designed to investigate the feeding problems and possibilities should be constructed. A materials-test facility is also needed for testing, evaluating and selecting materials, as well as demonstrating their long-term compatibility. An intermediate-size pilot plant with sufficient flexibility to test alternate solutions to the above-mentioned problems will considerably strengthen the demonstration program.

  2. Market Assessment and Technical Feasibility Study of Pressurized Fluidized Bed Combustion Ash Use

    SciTech Connect (OSTI)

    Bland, A.E.; Brown, T.H. [Western Research Inst., Laramie, WY (United States)

    1996-12-31T23:59:59.000Z

    Western Research Institute in conjunction with the Electric Power Research Institute, Foster Wheeler Energy International, Inc. and the U.S. Department of Energy Technology Center (METC), has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for pressurized fluidized bed combustion (PFBC) ashes. The assessment is designed to address six applications, including: (1) structural fill, (2) road base construction, (3) supplementary cementing materials in portland cement, (4) synthetic aggregate, and (5) agricultural/soil amendment applications. Ash from low-sulfur subbituminous coal-fired Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, and ash from the high-sulfur bituminous coal-fired American Electric Power (AEP) bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing. This paper addresses the technical feasibility of ash use options for PFBC unit using low- sulfur coal and limestone sorbent (karhula ash) and high-sulfur coal and dolomite sorbents (AEP Tidd ash).

  3. Testing of Eastern Kentucky Amburgy coal in an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1985-01-01T23:59:59.000Z

    This report is the third in a series of four coal reports, and describes the results of testing of an Eastern Kentucky Amburgy coal (1/4 in. x 0, 3.3% sulfur, 11% ash, 12920 Btu/lb.) in a 2 ft. 8 in. x 2 ft. 5 in., 0.75-MW AFBC. All 4 coal tests were conducted using Oregon dolomite from central Kentucky (1/8 in. x 0, 62% CaCO/sub 3/, 31% MgCO/sub 3/) as the sulfur sorbent. Results obtained from eight steady-state test runs at three different loads at a constant superficial velocity of 5.4 ft./s are presented. Operating problems encountered are described. On the basis of numbers, it was concluded that an economic re-evaluation of low-superficial-velocity fluidized beds is warranted, and that it is feasible to burn eastern Kentucky Amburgy coal efficiently in an AFBC while keeping emissions below EPA limits.

  4. Mechanical properties and corrosion behavior of materials exposed to an experimental, atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Ganesan, P.; Sagues, A.; Sethi, V.

    1984-06-01T23:59:59.000Z

    A joint materials test program developed by the Institute for Mining and Minerals Research (IMMR) and the Tennessee Valley Authority (TVA) involved the postexposure mechanical properties and corrosion behavior of candidate structural materials in an experimental, atmospheric fluidized-bed combustor (AFBC). This combustor was operated by Accurex Corporation at Research Triangle Park, North Carolina, under the direction of TVA. The materials studied were Type 304, Type 310, and INCOLOY alloy 800 in the form of disc coupons with and without crevice configurations. Type 304 was also used for mechanical property measurements. The alloys were exposed to the combustor environment at about840/sup 0/C for approximately 330 hours. The ranking in terms of decreasing weight loss was: (1) Type 304, (2) Type 310, and (3) INCOLOY alloy 800. The presence of tight crevices did not enhance the corrosion rate. In addition, the corrosion rates, based on the weight loss (typically 1 to 6 mpy), indicated that the alloys performed reasonably well when considering materials wastage. However, optical microscopy observations showed intergranular corrosion penetration in INCOLOY alloy 800 and Type 304. The mechanical properties of Type 304 were inferior to the unexposed alloy. A comparison of the data obtained from the combustor-exposed 304ss tensile samples with data from control samples exposed in vacuum to a similar thermal history indicated that the chemistry of the AFBC environment did not play a major role in the observed degradation of the mechanical properties.

  5. Testing of Western Kentucky No. 11 coal in an atmospheric fluidized bed combustor

    SciTech Connect (OSTI)

    Not Available

    1985-01-01T23:59:59.000Z

    This report is the second of a series of four coal reports, and describes the results of testing of a Western Kentucky No. 11 coal (1/4 in. x 0, 3.8% sulfur, 33% ash, 83/50 Btu/lb.) in a 2 ft. 8 in. x 2 ft. 5 in., 0.75-MW AFBC. All four coal tests were conducted using Oregon dolomite from central Kentucky (1/8 in. x 0, 62% CaCO/sub 3/, 31% MgCO/sub 3/) as the sulfur sorbent. Results obtained from eight steady-state test runs at three different loads at a constant superficial velocity of 5 ft./s are presented. Operating problems encountered are described, and include problems with large variations in coal ash and Btu contents, cyclone downleg blockage, moisture in feed material, and fouling of heat-transfer surfaces caused by high carryover rates. On the basis of numbers, it was concluded that an economic re-evaluation of low-superficial-velocity fluidized beds is warranted, and that it is feasible to burn Western Kentucky No. 11 coal efficiently in an AFBC provided that the boiler control system is designed to handle large variations in coal ash and Btu contents.

  6. Testing of Eastern Kentucky Hazard coal in an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1985-01-01T23:59:59.000Z

    This report is the fourth in a series of four coal reports, and describes the results of testing of an Eastern Kentucky Hazard No. 9 coal (1/4 in. x 0, 3.4% sulfur, 11% ash, 12640 Btu/lb.) in a 2 ft. 8 in. x 2 ft. 5 in., 0.75-MW AFBC. All four coal tests were conducted using Oregon dolomite from central Kentucky (1/8 in. x 0, 62% C-CO/sub 2/, 31% MgCO/sub 2/) as the sulfur sorbent. Results obtained from eight steady-state test runs at three different loads at a constant superficial velocity of 5.4 ft./s are presented. Operating problems encountered are described. On the basis of numbers, it was concluded that an economic re-evaluation of low-superficial velocity fluidized beds is warranted, and that it is feasible to burn Eastern Kentucky Hazard No. 9 coal efficiently in an AFBC while keeping emissions below EPA limits.

  7. [Pulsed atmospheric fluidized bed combustion (PAFBC)]. Technical progress report, February 1989--April 1989

    SciTech Connect (OSTI)

    Not Available

    1989-05-01T23:59:59.000Z

    The fourth Quarterly Technical Progress Report presents the results of work accomplished during the period February 6 through April 30, 1989. the overall objective of the program is the development of a pulsed atmospheric, fluidized bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this past quarter, a baseline for comparing PAFBC vs. AFBC performance was established and the initial series of PAFBC coal-fired combustion tests was completed. The AFBC baseline was representative of bubbling bed units with the exception of emissions which were somewhat higher and attributable to the size constraints of the AFBC unit. However, it still provided a valid baseline for referencing and optimizing PAFBC performance. Initial coal combustion tests in the pulsed fluid-bed verified enhanced performance in comparison to the non-pulsed beds, providing reduced NO{sub x}, CO, and SO{sub 2} emissions as well as higher steam generation rates and considerably lower entrainment losses. 9 figs., 4 tabs.

  8. Atmospheric fluidized-bed combustion (AFBC) co-firing of coal and hospital waste. Environmental Assessment

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    The proposed project involves co-firing of coal and medical waste (including infectious medical waste) in an atmospheric fluidized-bed combustor (AFBC) to safely dispose of medical waste and produce steam for hospital needs. Combustion at the design temperature and residence time (duration) in the AFBC has been proven to render infectious medical waste free of disease producing organisms. The project would be located at the Veterans Affairs (VA) Medical Center in Lebanon, Pennsylvania. The estimated cost of the proposed AFBC facility is nearly $4 million. It would be jointly funded by DOE, Veterans Affairs, and Donlee Technologies, Inc., of York, Pennsylvania, under a cooperative agreement between DOE and Donlee. Under the terms of this agreement, $3.708 million in cost-shared financial assistance would be jointly provided by DOE and the Veterans Affairs (50/50), with $278,000 provided by Donlee. The purposes of the proposed project are to: (1) provide the VA Medical Center and the Good Samaritan Hospital (GSH), also of Lebanon, Pennsylvania, with a solution for disposal of their medical waste; and (2) demonstrate that a new coal-burning technology can safely incinerate infectious medical waste, produce steam to meet hospital needs, and comply with environmental regulations.

  9. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26T23:59:59.000Z

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  10. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01T23:59:59.000Z

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  11. Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor

    SciTech Connect (OSTI)

    Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

    1991-12-31T23:59:59.000Z

    The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

  12. Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor

    SciTech Connect (OSTI)

    Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

    1991-01-01T23:59:59.000Z

    The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

  13. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, J.

    1996-02-20T23:59:59.000Z

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  14. Some investigations on heat transfer in a hot circulating fluidized bed

    SciTech Connect (OSTI)

    Nag, P.K.; Reddy, B.V. [Indian Inst. of Tech., Kharagpur (India). Dept. of Mechanical Engineering

    1995-12-31T23:59:59.000Z

    An experimental investigation has been made to study the heat transfer characteristics at different bed heights along the riser column in a Circulating Fluidized Bed (CFB) unit of 102 mm x 102 mm in bed cross-section, 5.25 m in height with a return leg of the same dimensions. The test probes have dimensions of 42.5 mm in O.D., 70 mm in height, and half of its outer surface is exposed to the bed. Three such test sections made of mild steel are located at 1.8 m, 2.3 m and 3.4 m (probe 3, probe 2 and probe 1 respectively) above the distributor plate in the riser column. The variation of the heat transfer coefficient at different bed heights, and the influence of operating parameters are investigated. PG and coal (of mean size 800 {micro}m) are burned. The primary superficial air velocity is varied between 3.0 to 7.0 m/s. Local sand of mean size 248 {micro}m is used as the bed material. The present data is compared with the published literature.

  15. Gas turbine blade materials' corrosion in the effluent from a pressurized fluidized bed combustor

    SciTech Connect (OSTI)

    Mc Carron, R.L.; Brobst, R.P.

    1984-06-01T23:59:59.000Z

    Two nominally 200-hour tests were conducted in the General Electric Company's Pressurized Fluidized Bed (PFB) Coal Combustion facility in Malta, NY. The purpose of the tests was to evaluate the influence of bed operating temperature and dolomite composition on the degradation of gas turbine vane and blade base alloys and protective coating/cladding systems in the effluent from a PFB. Operating conditions were as follows: 1710/sup 0/-1770/sup 0/F (932/sup 0/C-966/sup 0/C) bed temperature and Pfizer dolomite (0.1 wt% sodium plus potassium), and 1630/sup 0/-1690/sup 0/F (888/sup 0/-921/sup 0/C) bed temperature and Tymochtee dolomite (0.9 wt% sodium plus potassium). Brookville seam coal with 4.5 wt% sulfur, 0.3 wt% alkali, and 0.17 wt% chlorine was used in both tests. Bare nickel and cobalt-base vane and blade alloys were susceptible to hot corrosion over the entire temperature range investigated, 1100/sup 0/1600/sup 0/F (593/sup 0/-871/sup 0/C). CoCrAlY and FeCrAlY overlay coatings showed good corrosion resistance at temperatures above 1450/sup 0/F, but were susceptible to pitting attack at lower temperatures. A platinum-aluminide diffusion coating showed excellent corrosion resistance at all temperatures.

  16. Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

    2014-05-01T23:59:59.000Z

    Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

  17. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01T23:59:59.000Z

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  18. Model building techniques for analysis.

    SciTech Connect (OSTI)

    Walther, Howard P.; McDaniel, Karen Lynn; Keener, Donald; Cordova, Theresa Elena; Henry, Ronald C.; Brooks, Sean; Martin, Wilbur D.

    2009-09-01T23:59:59.000Z

    The practice of mechanical engineering for product development has evolved into a complex activity that requires a team of specialists for success. Sandia National Laboratories (SNL) has product engineers, mechanical designers, design engineers, manufacturing engineers, mechanical analysts and experimentalists, qualification engineers, and others that contribute through product realization teams to develop new mechanical hardware. The goal of SNL's Design Group is to change product development by enabling design teams to collaborate within a virtual model-based environment whereby analysis is used to guide design decisions. Computer-aided design (CAD) models using PTC's Pro/ENGINEER software tools are heavily relied upon in the product definition stage of parts and assemblies at SNL. The three-dimensional CAD solid model acts as the design solid model that is filled with all of the detailed design definition needed to manufacture the parts. Analysis is an important part of the product development process. The CAD design solid model (DSM) is the foundation for the creation of the analysis solid model (ASM). Creating an ASM from the DSM currently is a time-consuming effort; the turnaround time for results of a design needs to be decreased to have an impact on the overall product development. This effort can be decreased immensely through simple Pro/ENGINEER modeling techniques that summarize to the method features are created in a part model. This document contains recommended modeling techniques that increase the efficiency of the creation of the ASM from the DSM.

  19. Data summary of municipal solid waste management alternatives

    SciTech Connect (OSTI)

    Not Available

    1992-10-01T23:59:59.000Z

    This appendix provides information on fluidized-bed combustion (FBC) technology as it has been applied to municipal waste combustion (MWC). A review of the literature was conducted to determine: (1) to what extent FBC technology has been applied to MWC, in terms of number and size of units was well as technology configuration; (2) the operating history of facilities employing FBC technology; and (3) the cost of these facilities as compared to conventional MSW installations. Where available in the literature, data on operating and performance characteristics are presented. Tabular comparisons of facility operating/cost data and emissions data have been complied and are presented. The literature review shows that FBC technology shows considerable promise in terms of providing improvements over conventional technology in areas such as NOx and acid gas control, and ash leachability. In addition, the most likely configuration to be applied to the first large scale FBC dedicated to municipal solid waste (MSW) will employ circulating bed (CFB) technology. Projected capital costs for the Robbins, Illinois 1600 ton per day CFB-based waste-to-energy facility are competitive with conventional systems, in the range of $125,000 per ton per day of MSW receiving capacity.

  20. Solid Waste Management (Kansas)

    Broader source: Energy.gov [DOE]

    This act aims to establish and maintain a cooperative state and local program of planning and technical and financial assistance for comprehensive solid waste management. No person shall construct,...

  1. Solid model design simplification

    SciTech Connect (OSTI)

    Ames, A.L.; Rivera, J.J.; Webb, A.J.; Hensinger, D.M.

    1997-12-01T23:59:59.000Z

    This paper documents an investigation of approaches to improving the quality of Pro/Engineer-created solid model data for use by downstream applications. The investigation identified a number of sources of problems caused by deficiencies in Pro/Engineer`s geometric engine, and developed prototype software capable of detecting many of these problems and guiding users towards simplified, useable models. The prototype software was tested using Sandia production solid models, and provided significant leverage in attacking the simplification problem.

  2. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA); Choe, Hyoun S. (Waltham, MA)

    1995-01-01T23:59:59.000Z

    This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

  3. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, K.M.; Alamgir, M.; Choe, H.S.

    1995-12-12T23:59:59.000Z

    This invention relates to Li ion (Li{sup +}) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF{sub 3}SO{sub 2}){sub 2}, LiAsF{sub 6}, and LiClO{sub 4}. 2 figs.

  4. EXPERIMENTAL METHODS TO ESTIMATE ACCUMULATED SOLIDS IN NUCLEAR WASTE TANKS

    SciTech Connect (OSTI)

    Duignan, M.; Steeper, T.; Steimke, J.

    2012-12-10T23:59:59.000Z

    The Department of Energy has a large number of nuclear waste tanks. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles, e.g., plutonium containing, could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids and supernatant were charged to the test tank and rotating liquid jets were used to remove most of the solids. Then the volume and shape of the residual solids and the spatial concentration profiles for the surrogate for plutonium were measured. This paper discusses the overall test results, which indicated heavy solids only accumulate during the first few transfer cycles, along with the techniques and equipment designed and employed in the test. Those techniques include: Magnetic particle separator to remove stainless steel solids, the plutonium surrogate from a flowing stream; Magnetic wand used to manually remove stainless steel solids from samples and the tank heel; Photographs were used to determine the volume and shape of the solids mounds by developing a composite of topographical areas; Laser rangefinders to determine the volume and shape of the solids mounds; Core sampler to determine the stainless steel solids distribution within the solids mounds; Computer driven positioner that placed the laser rangefinders and the core sampler over solids mounds that accumulated on the bottom of a scaled staging tank in locations where jet velocities were low. These devices and techniques were very effective to estimate the movement, location, and concentrations of the solids representing plutonium and are expected to perform well at a larger scale. The operation of the techniques and their measurement accuracies will be discussed as well as the overall results of the accumulated solids test.

  5. The use of FBC wastes in the reclamation of coal slurry solids

    SciTech Connect (OSTI)

    Dreher, G.B.

    1991-01-01T23:59:59.000Z

    Fluidized bed combustion (FBC) is a relatively new technology that is used commercially for the combustion of coal. In Illinois, this technology is valuable because it allows the combustion of Illinois high sulfur coal without pollution of the atmosphere with vast quantities of sulfur oxides. In FBC, coal is mixed with limestone or dolomite either before injection into the combustion chamber or in the combustion chamber. As the coal burns, sulfur in the coal is oxidized to SO{sub 2} and this is trapped by reaction with the limestone or dolomite to form gypsum (CaSO{sub 4}{center dot}2H{sub 2}O). Solid by-products from FBC are generally a mixture of calcium oxide, gypsum, coal ash, and unburned coal. The present research project is designed to provide initial data on one possible use of FBC waste. FBC wastes from five different locations in the Illinois are mixed with coal slurry solids from two different coal preparation plants at Illinois coal mines. In mixtures of FBC waste and coal slurry solids, the alkaline components of the FBC waste are expected to react with acid produced by the oxidation of pyrite in the coal slurry solid. An objective of this research is to determine the chemical composition of aqueous leachates from mixtures of FBC wastes, generated under various operating conditions, and the coal slurry solids. These data will be used in future research into the ability of such mixtures to support seed germination and plant growth. The ultimate of this and future research is to determine whether mixed FBC waste and coal slurry solids can be slurry pond reclamation.

  6. Electrophoretically-deposited solid film lubricants

    SciTech Connect (OSTI)

    Dugger, M.T.; Panitz, J.K.J.; Vanecek, C.W.

    1995-04-01T23:59:59.000Z

    An aqueous-based process that uses electrophoresis to attract powdered lubricant in suspension to a charged target was developed. The deposition process yields coatings with low friction, complies with environmental safety regulations, requires minimal equipment, and has several advantages over processes involving organic binders or vacuum techniques. This work focuses on development of the deposition process, includes an analysis of the friction coefficient of the material in sliding contact with stainless steel under a range of conditions, and a functional evaluation of coating performance in a precision mechanical device application. Results show that solid lubricant films with friction coefficients as low as 0.03 can be produced. A 0.03 friction coefficient is superior to solid lubricants with binder systems and is comparable to friction coefficients generated with more costly vacuum techniques.

  7. Fabricating the Solid Core Heatpipe Reactor

    SciTech Connect (OSTI)

    Ring, Peter J.; Sayre, Edwin D. [Advanced Methods and Materials, Inc., 1190 Mountain View-Alviso Road, Suite P, Sunnyvale, CA 94089 (United States); Houts, Mike [NASA Marshall Space Flight Center, Huntsville, Alabama 35812 (United States)

    2006-01-20T23:59:59.000Z

    The solid core heatpipe nuclear reactor has the potential to be the most dependable concept for the nuclear space power system. The design of the conversion system employed permits multiple failure modes instead of the single failure mode of other concepts. Regardless of the material used for the reactor, either stainless steel, high-temperature alloys, Nb1Zr, Tantalum Alloys or MoRe Alloys, making the solid core by machining holes in a large diameter billet is not satisfactory. This is because the large diameter billet will have large grains that are detrimental to the performance of the reactor due to grain boundary diffusion. The ideal fabrication method for the solid core is by hot isostatic pressure diffusion bonding (HIPing). By this technique, wrought fine-grained tubes of the alloy chosen are assembled into the final shape with solid cusps and seal welded so that there is a vacuum in between all surfaces to be diffusion bonded. This welded structure is then HIPed for diffusion bonding. A solid core made of Type 321 stainless steel has been satisfactorily produced by Advanced Methods and Materials and is undergoing evaluation by NASA Marshall Space Flight Center.

  8. Sulfur removal in advanced two stage pressurized fluidized bed combustion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Abbasian, J.; Chowdiah, P.; Hill, A.H.; Rue, D.M. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-09-01T23:59:59.000Z

    The objective of this study is to obtain data on the rates of reaction between hydrogen sulfide (H{sub 2}S) and uncalcined calcium-based sorbents under operating conditions relevant to first stage (carbonizer) of Advanced Two-Stage Pressurized Fluidized-Bed Combustors (PFBC). In these systems the CO{sub 2} partial pressure in the first stage generally exceeds the equilibrium value for calcium carbonate decomposition. Therefore, removal of sulfur compounds takes place through the reaction between H{sub 2}S and calcium carbonate. To achieve this objective, the rates of reaction between hydrogen sulfide and uncalcined calcium-based sorbents will be determined by conducting tests in pressurized thermogravimetric analyzer (TGA) and high-pressure/high-temperature fluidized-bed reactor (HPTR) units. The effects of sorbent type, sorbent particle size, reactor temperature and pressure, and CO{sub 2} and H{sub 2}S partial pressures on the sulfidation reaction rate will be determined. During this quarter a series of sulfidation tests were conducted in the high-pressure/high-temperature fluidized-bed reactor (HPTR) units. The effects of sorbent type, sorbent particle size, reactor temperature and pressure, and CO{sub 2} and H{sub 2}S partial pressures on the sulfidation reaction rate will be determined. During this quarter a series of sulfidation tests were conducted in the high-pressure high-temperature thermogravimetric analyzer (HPTGA unit) using limestone and dolomite. The results suggest that half-calcined dolomite is much more reactive than uncalcined limestone. Also, temperature in the range of 800 to 950 C did not significantly affect the sulfidation reaction rates for both limestone and dolomite.

  9. Solid Target Options S. Childress

    E-Print Network [OSTI]

    McDonald, Kirk

    power is higher than for existing solid target designs - but not by a large factor. · NuMI graphite beam power) · High beam power solid targets frequently use higher z materials for increased yield plusSolid Target Options NuFACT'00 S. Childress Solid Target Options · The choice of a primary beam

  10. Oxidation/corrosion of metallic and ceramic materials in an aluminum remelt furnace. [For fluidized bed waste heat recovery systems

    SciTech Connect (OSTI)

    Federer, J.I.; Jones, P.J.

    1985-12-01T23:59:59.000Z

    Both metallic alloys and ceramic materials are candidates for the distributor plate and other components of fluidized bed waste heat recovery (FBWHR) systems. Eleven Fe-, Ni-, and Co-base alloys were exposed to air at elevated temperatures in laboratory furnaces and to flue gases in an aluminum remelt furnace to assess their resistance to oxidation and corrosion. Four SiC ceramics and two oxide ceramics were also tested in the aluminum remelt furnace. Some alloys were coated with aluminum or SiO2 by commercial processes in an effort to enhance their oxidation and corrosion resistance.

  11. A One-Dimensional (1-D) Three-Region Model for a Bubbling Fluidized-Bed Adsorber

    SciTech Connect (OSTI)

    Lee, Andrew; Miller, David C.

    2012-01-01T23:59:59.000Z

    A general one-dimensional (1-D), three-region model for a bubbling fluidized-bed adsorber with internal heat exchangers has been developed. The model can predict the hydrodynamics of the bed and provides axial profiles for all temperatures, concentrations, and velocities. The model is computationally fast and flexible and allows for any system of adsorption and desorption reactions to be modeled, making the model applicable to any adsorption process. The model has been implemented in both gPROMS and Aspen Custom Modeler, and the behavior of the model has been verified.

  12. Validation testing of the EERC pilot-scale circulating fluidized-bed combustor using Salt Creek coal

    SciTech Connect (OSTI)

    Mann, M.D.; Hajicek, D.R.; Moe, T.A.; Henderson, A.K.

    1991-09-01T23:59:59.000Z

    The overall goal of the project was to provide a technical basis for assessing the economic and environmental feasibility of circulating fluidized-bed combustion (CFBC) technology, focusing on the effect of system configuration and coal properties on performance. Other underlying goals of the program were to (1) design and construct a CFBC test facility, thereby providing a test facility at an independent laboratory; (2) demonstrate that the test unit is capable of meeting the original design objectives; and (3) assess the ability of the unit to provide scalable data. The purpose of this interim report is to present data from validation testing to establish the scalability of data generated from this unit.

  13. Validation testing of the EERC pilot-scale circulating fluidized-bed combustor using Salt Creek coal. Final report

    SciTech Connect (OSTI)

    Mann, M.D.; Hajicek, D.R.; Moe, T.A.; Henderson, A.K.

    1991-09-01T23:59:59.000Z

    The overall goal of the project was to provide a technical basis for assessing the economic and environmental feasibility of circulating fluidized-bed combustion (CFBC) technology, focusing on the effect of system configuration and coal properties on performance. Other underlying goals of the program were to (1) design and construct a CFBC test facility, thereby providing a test facility at an independent laboratory; (2) demonstrate that the test unit is capable of meeting the original design objectives; and (3) assess the ability of the unit to provide scalable data. The purpose of this interim report is to present data from validation testing to establish the scalability of data generated from this unit.

  14. ADVANCED SORBENT DEVELOPMENT PROGRAM DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E Ayala; V.S. Venkataramani; Javad Abbasian; Rachid B. Slimane; Brett E. Williams; Minoo K. Zarnegar; James R. Wangerow; Andy H. Hill

    2000-03-31T23:59:59.000Z

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000 F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.'s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration temperatures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent development at General Electric's Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  15. An adaptive mesh refinement technique for dynamics of solids

    E-Print Network [OSTI]

    Trivedi, Abhishek

    2007-01-01T23:59:59.000Z

    which supports the Burger-Olinger algorithm for parallelmethod based on the Burger-Olinger algorithm [DAGH web site

  16. An adaptive mesh refinement technique for dynamics of solids

    E-Print Network [OSTI]

    Trivedi, Abhishek

    2007-01-01T23:59:59.000Z

    adaptations; right: cut-off grid with a solution contour.adaptations; right: cut-off grid with a solution contour.

  17. Electrochemical Techniques

    SciTech Connect (OSTI)

    Chen, Gang; Lin, Yuehe

    2008-07-20T23:59:59.000Z

    Sensitive and selective detection techniques are of crucial importance for capillary electrophoresis (CE), microfluidic chips, and other microfluidic systems. Electrochemical detectors have attracted considerable interest for microfluidic systems with features that include high sensitivity, inherent miniaturization of both the detection and control instrumentation, low cost and power demands, and high compatibility with microfabrication technology. The commonly used electrochemical detectors can be classified into three general modes: conductimetry, potentiometry, and amperometry.

  18. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  19. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  20. Fluidized Bed Steam Reformed (FBSR) Mineral Waste Forms: Characterization and Durability Testing

    SciTech Connect (OSTI)

    Jantzen, Carol M.; Lorier, Troy H.; Pareizs, John M.; Marra, James C. [Savannah River National Laboratory, Aiken, SC, 29803 (United States)

    2007-07-01T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a mineralizing technology for the immobilization of a wide variety of wastes that are high in organics, nitrates-nitrites, halides, and/or sulfates. These wastes include the decontaminated High Level Waste (HLW) supernates referred to as low activity waste (LAW) at Department of Energy (DOE) sites in the United States and waste streams that may be generated by the advanced nuclear fuel cycle flowsheets that are being considered by the Global Nuclear Energy Partnership (GNEP) initiative. The organics are pyrolyzed into CO{sub 2} and steam in the absence of air. The FBSR mineral waste form is a granular but can subsequently be made into a monolith for disposal if necessary. The waste form is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals (sodalite, nosean, and nepheline) with cage and ring structures that sequester radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. Iron bearing spinel minerals are also formed and these phases stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Dissolution rates ({eta}) and activation energies of dissolution are parameters needed for Performance Assessments (PA) to be completed on the FBSR mineral waste form. These parameters are defined in this study by Single Pass Flow Through (SPFT) testing. The dissolution rate ({eta}) and the activation energies for dissolution calculated in this study agree with the available rate and activation energy data for natural single crystal nepheline. (authors)

  1. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    SciTech Connect (OSTI)

    Zhen Fan

    2006-05-30T23:59:59.000Z

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  2. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01T23:59:59.000Z

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  3. Characterization of a fluidized-bed combustion ash to determine potential for environmental impact. Final report

    SciTech Connect (OSTI)

    Hassett, D.J.; Henderson, A.K.; Pflughoeft-Hassett, D.F.; Mann, M.D.; Eylands, K.E.

    1997-10-01T23:59:59.000Z

    A 440-megawatt, circulating fluidized-bed combustion (CFBC), lignite-fired power plant is planned for construction in Choctaw County north of Ackerman, Mississippi. This power plant will utilize Mississippi lignite from the first lignite mine in that state. Malcolm Pirnie, Inc., is working with the power plant developer in the current planning and permitting efforts for this proposed construction project. In order to accommodate Mississippi state regulatory agencies and meet appropriate permit requirements, Malcolm Pirnie needed to provide an indication of the characteristics of the by-products anticipated to be produced at the proposed plant. Since the Mississippi lignite is from a newly tapped mine and the CFBC technology is relatively new, Malcolm Pirnie contacted with the Energy and Environmental Research Center (EERC) to develop and perform a test plan for the production and characterization of ash similar to ash that will be eventually produced at the proposed power plant. The work performed at the EERC included two primary phases: production of by-products in a bench-scale CFBC unit using lignite provided by Malcolm Pirnie with test conditions delineated by Malcolm Pirnie to represent expected operating conditions for the full-scale plant; and an extensive characterization of the by-products produced, focusing on Mississippi regulatory requirements for leachability, with the understanding that return of the by-product to the mine site was an anticipated by-product management plan. The overall focus of this project was the environmental assessment of the by-product expected to be produced at the proposed power plant. Emphasis was placed on the leachability of potentially problematic trace elements in the by-products. The leaching research documented in this report was performed to determine trends of leachability of trace elements under leaching conditions appropriate for evaluating land disposal in monofills, such as returning the by-products to the mine site.

  4. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31T23:59:59.000Z

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  5. Interim operations report for atmospheric fluidized-bed combustion conversion at Northern States Power Company

    SciTech Connect (OSTI)

    Thimsen, D. (Hamilton Maurer International, Inc., Falcon Heights, MN (USA))

    1991-03-01T23:59:59.000Z

    Northern States Power Company converted its Black Dog Station Unit No. 2 boiler from a front wall fired pulverized coal boiler to a bubbling atmospheric fluidized bed combustor (AFBC) boiler. The resulting unit was uprated from 85 MWe to 130 MWe burning western subbituminous coal. This report describes the AFBC operating and maintenance experience in the startup period from initial operation in June 1986 through March 1989 when a turbine oil fire caused a forced outage of 8 months. A brief review of the construction history is given in Section 1. Section 2 chronicles the AFBC operation. Section 3 describes how the boiler is restarted under several conditions. The performance history of the systems in the AFBC that are peculiar to the AFBC process or directly impacted by the AFBC process are described in detail in Section 4. The AFBC conversion at the Black Dog station has met nearly all of the original design objectives: (1) The unit can operate at rated output of 130 MWe burning western subbituminous coal, (2) The design life of the unit has been extended 25 years, (3) It has been shown that the EPA New Source Performance Standards for NO{sub x} and SO{sub 2} can be met with no flue gas treatment, (4) Operators have conducted over 200 routine daily unit restarts confirming the ability of the unit to serve in daily cycling mode, and (5) A variety of fuels have been successfully burned in the AFBC. The only objective that remains partially achieved is routine operation at full load. The boiler/turbine/generator have been shown to be fully capable of operation at full load, but the electrostatic precipitators (which were largely unchanged during the retrofit) have been inadequate to allow full load operation while remaining within permitted opacity and particulate emissions. The unit is currently dispatched in daily cycling service and is limited to operation below 106 MWe by its emissions control permit. 12 refs., 34 figs., 6 tabs.

  6. Assessment of atmospheric fluidized-bed combustion recycle systems. Final report

    SciTech Connect (OSTI)

    Rogali, R.; Wysocki, J.; Kursman, S.

    1981-10-01T23:59:59.000Z

    This report presents a technical and economic evaluation of AFBC power plants with recycle systems, and a comparison of these plants with AFBC power plants with carbon burnup beds (CBB) and with pulverized coal-fired (PCF) power plants with flue gas desulfurization (FGD) systems. The analysis considers 1000 MWe plants burning both eastern and western coals. The capital and operating cost estimates are based on boiler designs developed by Babcock and Wilcox, Inc., and on sorbent requirements estimated by Burns and Roe, Inc. The economic analyses are based on a plant located in the East Central region of the United States with a 30-year life and a 70 percent capacity factor. The eastern coal-fired plants are designed to burn Illinois bituminous coal with a higher heating value of 10,100 Btu/lb and a sulfur content of 4%. The required calcium to sulfur mole ratios for the eastern plants are 3.8:1 and 2.5:1 for the AFBC/CBB and AFBC/recycle plants, respectively. The western coal-fired plants are designed to burn Wyoming subbituminous coal with a higher heating value of 8,020 Btu/lb and a sulfur content of 0.48%. The required calcium to sulfur mole ratios for the western plants are 0.7:1 and 0.4:1 for the AFBC/CBB and AFBC/recycle plants, respectively. These Ca/S mole ratios allow for 30 percent utilization of the alkaline coal ash to reduce sorbent requirements to the fluidized bed combustor. The analyses indicate that the AFBC/recycle plants have an economic advantage over the AFBC/CBB plants and over the PCF/FGD plants for both eastern and western coal.

  7. An atmospheric pressure, fluidized bed combustion system burning high-chlorine coals in the convection section

    SciTech Connect (OSTI)

    Liu, K.; Xie, W.; Pan, W.P.; Riley, J.T.

    2000-03-01T23:59:59.000Z

    The possibility of fireside corrosion in power plant boiler components is always a major concern when the fuels include high-sulfur and high-chlorine coals (or refuse waste). Sulfur and chloride products may play important roles especially in fireside corrosion in atmospheric pressure, fluidized bed combustion (AFBC) systems, caused by the capture of sulfur and chlorine by limestone used as bed material in the combustor, and the resulting deposition of sulfur- or chlorine-rich compounds onto metallic surfaces. Results were reported from tests in a 0.1-MW{sub th} AFBC system where 1,000-h test burns were conducted using two coals with widely differing chlorine levels, and limestone was used as the sulfur sorbent. Coupons of three stainless steels (Types 304 [UNS S30400], 309 [UNS S30900], 347 [UNS S34700]) were exposed to the hot flue gases in the freeboard ({approximately} 10- cm below the location of the convection pass tubes). Deposits formed on the alloys contained high sulfur concentrations in their outer parts, as well as sodium, potassium, magnesium, and calcium. Sulfur appeared to be associated with calcium and magnesium, suggesting that the fly ash may have reacted further after being deposited on the surface of the coupon. Areas of high sulfur concentration also correlated well with areas of high chromium content of the inner layers of the scales. cross sections of samples indicated that sulfur had penetrated into the alloy and reacted to form sulfide corrosion products. There was no direct evidence to show that alkali chlorides were involved in the corrosion process. No chloride was identified in the alloy samples. There was slight oxide spallation observed on all three alloys, with the degree of spallation in the following order: Type 304 > Type 347 > Type 309.

  8. Pressurized fluidized-bed hydroretorting of Eastern oil shales. Annual report, June 1991--May 1992

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. [Institute of Gas Technology, Chicago, IL (United States); Schultz, C.W. [Alabama Univ., University, AL (United States); Parekh, B.K. [Kentucky Univ., Lexington, KY (United States); Misra, M. [Nevada Univ., Reno, NV (United States); Bonner, W.P. [Tennessee Technological Univ., Cookeville, TN (United States)

    1992-11-01T23:59:59.000Z

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  9. Solid state switch

    DOE Patents [OSTI]

    Merritt, B.T.; Dreifuerst, G.R.

    1994-07-19T23:59:59.000Z

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1,500 A peak, 1.0 [mu]s pulsewidth, and 4,500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry. 6 figs.

  10. Evaluation of dust cake filtration at high temperature with effluence from an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Dennis, R.A.

    1990-08-01T23:59:59.000Z

    In the spring of 1989, two separate test series were simultaneously conducted at the US Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) to examine applied and fundamental behavior of dust cake filtration under high temperature and high pressure (HTHP) conditions. The purpose was to provide information on dust-cake filtration properties to gas stream cleanup researchers associated with the Tidd 70 megawatt (MW) pressurized fluidized-bed combustor (PFBC). The two test facilities included (1) a high-pressure natural-gas combustor with injected particulate, which was fed to two full-size candle filters; and (2) an atmospheric fluidized-bed combustor (AFBC) with coal and limestone sorbent to generate a particulate-laden combustion exhaust gas, which was sent to a single full-size candle filter and a small-scale disc filter. Several major conclusions from these studies are noted below. On average reducing the mean particulate size by 33% and the associated loading carried in the filtrate will increase the dust cake specific flow resistance (K{sub 2}) by 498%. High-temperature and high-pressure filtration can be successfully performed with ceramic candle filters at moderate filtration face velocities and reasonable system pressure drops. Off-line filter cleaning can produce a filter system with a higher apparent permeability than that produced from on-line filter cleaning at the same face velocity. 19 refs., 89 figs., 13 tabs.

  11. Tennessee Valley Authority atmospheric fluidized-bed combustor simulation interim annual report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Wells, J.W.; Krishnan, R.P.

    1980-10-01T23:59:59.000Z

    This report contains a detailed description of the work performed during 1979 for the Tennessee Valley Authority in support of the TVA Fluidized-Bed Combustor (FBC) Demonstration Plant Program. The work was carried out under task 4, modeling and simulation of atmospheric fluidized-bed combustor (AFBC) systems. The overall objective of this task is to develop a steady-state mathematical model with the capability of predicting trends in bed performance under various feed and operating conditions. As part of this effort, three predictive subprograms (subcodes) were developed during 1979: (1) bubble-growth subcode, (2) sorbent-coal ash elutriation and attrition subcode, and (3) coal combustion subcode. These codes, which are currently being tested with experimental data, are capable of predicting how some of the important operating variables in the AFBC affect its performance. After testing against field data, these subcodes will be incorporated into an overall AFBC system code, which was developed earlier at ORNL for analysis of the Department of Energy (DOE) Component Test and Integration Unit (CTIU) at Morgantown, West Virginia. In addition to these predictive subcodes, the overall system code previously developed for the CTIU is described. The material balance is closed, based on vendor-supplied data. This balance is then used to predict the heat transfer characteristics of the surfaces (submerged and freeboard) in the AFBC. Existing correlations for heat transfer in AFBC are used in the code along with thermophysical properties of the various streams.

  12. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R. [Parsons Power Group, Inc., Reading, PA (United States); Reuther, R.B.; Bonk, D.L. [USDOE Morgantown Energy Technology Center, WV (United States)

    1996-09-01T23:59:59.000Z

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  13. Meeting Department of Defense non-hazardous solid waste goals

    SciTech Connect (OSTI)

    Eakes, W.S.; Comstock, J.

    1999-07-01T23:59:59.000Z

    This paper will discuss the previous and present Department of Defense (DOD) non-hazardous solid waste goals and how Navy and Marine Corps installation collect solid waste data and measure the goals. The installation and central data collection systems used, data collection problems and solutions, data quality, and the yearly measure. The paper will also discuss the original solid waste reduction and diversion goal and how the Navy and Marine Corps performed. The new DOD landfill and incineration diversion goal will be discussed and some techniques the Navy will use to meet the new goals.

  14. Solid polymer electrolyte compositions

    DOE Patents [OSTI]

    Garbe, James E. (Stillwater, MN); Atanasoski, Radoslav (Edina, MN); Hamrock, Steven J. (St. Paul, MN); Le, Dinh Ba (St. Paul, MN)

    2001-01-01T23:59:59.000Z

    An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

  15. The use of FBC wastes in the reclamation of coal slurry solids. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-10-01T23:59:59.000Z

    Fluidized bed combustion (FBC) is a relatively new technology that is used commercially for the combustion of coal. In Illinois, this technology is valuable because it allows the combustion of Illinois high sulfur coal without pollution of the atmosphere with vast quantities of sulfur oxides. In FBC, coal is mixed with limestone or dolomite either before injection into the combustion chamber or in the combustion chamber. As the coal burns, sulfur in the coal is oxidized to S0{sub 2} and this is trapped by reaction with the limestone or dolomite to form gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). Solid by-products from FBC are generally a mixture of calcium oxide, gypsum, coal ash, and unburned coal. The present research project is designed to provide initial data on one possible use of FBC waste. FBC wastes from five different locations in Illinois are mixed with coal slurry solids (CSS) from two different coal preparation plants at Illinois coal mines. In mixtures of FBC waste and coal slurry solids, the alkaline components of the FBC waste are expected to react with acid produced by the oxidation of pyrite in the coal slurry solid. An objective of this research is to determine the chemical composition of aqueous leachates from mixtures of FBC wastes, generated under various operating conditions, and the coal slurry solids. These data will be used in future research into the ability of such mixtures to support seed germination and plant growth. The final goal of this and future research is to determine whether mixed FBC waste and coal slurry solids can be used as a satisfactory growing medium in slurry pond reclamation. The chemical analyses of the 8 starting solids (5 FBC wastes, 2 Css samples, and 1 agricultural limestone sample) were completed.

  16. Economic disposal of solid oilfield wastes

    SciTech Connect (OSTI)

    Bruno, M.S.; Qian, H.X.

    1995-09-01T23:59:59.000Z

    A variety of solid oilfield wastes, including produced sand, tank bottoms, and crude contaminated soils, are generated during drilling, production, and storage processes. Crude oil and crude-contaminated sands or soils are generally designated as nonhazardous wastes. However, these materials still must be disposed of in an environmentally acceptable manner. The problems can become most pressing as oil fields in urban areas reach the end of their productive lives and the productive lives and the properties are redeveloped for residential use. An economically and environmentally sound solution is to reinject the solid waste into sand formations through slurry fracture muds and cuttings in Alaska, the Gulf of Mexico, and the North Sea; naturally occurring radioactive materials in Alaska and the Gulf of Mexico; and large volumes of produced oily sand in the provinces of Alberta and Saskatchewan, Canada. The technique offers a number of economic and environmental advantages for disposal of solid oilfield wastes. When reinjecting into depleted oil sands, the crude waste is simply being returned to its place of origin. The long-term liability to the operator is eliminated, in marked contrast to surface storage or landfill disposal. Finally, fracture-injection costs are less than typical transport and landfill disposal costs for moderate to large quantities of solid waste

  17. Solid Waste Act (New Mexico)

    Broader source: Energy.gov [DOE]

    The main purpose of the Solid Waste Act is to authorize and direct the establishment of a comprehensive solid waste management program. The act states details about specific waste management...

  18. Solid Waste Management Program (Missouri)

    Broader source: Energy.gov [DOE]

    The Solid Waste Management Program in the Department of Natural Resources regulates the management of solid waste in the state of Missouri. A permit is required prior to the construction or...

  19. Delaware Solid Waste Authority (Delaware)

    Broader source: Energy.gov [DOE]

    The Delaware Solid Waste Authority (DSWA) runs three landfills, all of which recover methane and generate electricity with a total capacity of 24 MWs. The DSWA Solid Waste Plan includes goals,...

  20. Solid Waste Disposal Act (Texas)

    Broader source: Energy.gov [DOE]

    The Texas Commission on Environmental Quality is responsible for the regulation and management of municipal solid waste and hazardous waste. A fee is applied to all solid waste disposed in the...