National Library of Energy BETA

Sample records for fluidized bed steam

  1. Fast fluidized bed steam generator

    DOE Patents [OSTI]

    Bryers, Richard W. (Flemington, NJ); Taylor, Thomas E. (Bergenfield, NJ)

    1980-01-01

    A steam generator in which a high-velocity, combustion-supporting gas is passed through a bed of particulate material to provide a fluidized bed having a dense-phase portion and an entrained-phase portion for the combustion of fuel material. A first set of heat transfer elements connected to a steam drum is vertically disposed above the dense-phase fluidized bed to form a first flow circuit for heat transfer fluid which is heated primarily by the entrained-phase fluidized bed. A second set of heat transfer elements connected to the steam drum and forming the wall structure of the furnace provides a second flow circuit for the heat transfer fluid, the lower portion of which is heated by the dense-phase fluidized bed and the upper portion by the entrained-phase fluidized bed.

  2. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)

    Energy Savers [EERE]

    Technology for Tank 48H Treatment Project (TTP) | Department of Energy Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed Steam Reformer System. PDF

  3. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  4. FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL

    SciTech Connect (OSTI)

    Williams, M

    2008-05-09

    Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

  5. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  6. FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    HEWITT WM

    2011-04-08

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

  7. Fluidized bed steam reformed mineral waste form performance testing to support Hanford Supplemental Low Activity Waste Immobilization Technology Selection

    SciTech Connect (OSTI)

    Jantzen, C. M.; Pierce, E. M.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Crawford, C. L.; Daniel, W. E.; Fox, K. M.; Herman, C. C.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.; Brown, C. F.; Qafoku, N. P.; Neeway, J. J.; Valenta, M. M.; Gill, G. A.; Swanberg, D. J.; Robbins, R. A.; Thompson, L. E.

    2015-10-01

    This report describes the benchscale testing with simulant and radioactive Hanford Tank Blends, mineral product characterization and testing, and monolith testing and characterization. These projects were funded by DOE EM-31 Technology Development & Deployment (TDD) Program Technical Task Plan WP-5.2.1-2010-001 and are entitled “Fluidized Bed Steam Reformer Low-Level Waste Form Qualification”, Inter-Entity Work Order (IEWO) M0SRV00054 with Washington River Protection Solutions (WRPS) entitled “Fluidized Bed Steam Reforming Treatability Studies Using Savannah River Site (SRS) Low Activity Waste and Hanford Low Activity Waste Tank Samples”, and IEWO M0SRV00080, “Fluidized Bed Steam Reforming Waste Form Qualification Testing Using SRS Low Activity Waste and Hanford Low Activity Waste Tank Samples”. This was a multi-organizational program that included Savannah River National Laboratory (SRNL), THOR® Treatment Technologies (TTT), Pacific Northwest National Laboratory (PNNL), Oak Ridge National Laboratory (ORNL), Office of River Protection (ORP), and Washington River Protection Solutions (WRPS). The SRNL testing of the non-radioactive pilot-scale Fluidized Bed Steam Reformer (FBSR) products made by TTT, subsequent SRNL monolith formulation and testing and studies of these products, and SRNL Waste Treatment Plant Secondary Waste (WTP-SW) radioactive campaign were funded by DOE Advanced Remediation Technologies (ART) Phase 2 Project in connection with a Work-For-Others (WFO) between SRNL and TTT.

  8. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  9. Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-11-01

    The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 25, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

  10. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification

    Office of Environmental Management (EM)

    Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3 Incentive and Objectives FBSR sodium-aluminosilicate (NAS) waste form has been identified as a promising supplemental treatment technology for Hanford LAW Objectives: Reduce the risk associated with implementing the FBSR NAS waste form as a supplemental treatment technology for Hanford LAW Conduct test with actual tank

  11. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  12. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  13. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  14. Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-12-01

    Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Offices (NE-ID) and State of Idahos top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

  15. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  16. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  17. Fluidized bed calciner apparatus

    DOE Patents [OSTI]

    Owen, Thomas J. (West Richland, WA); Klem, Jr., Michael J. (Richland, WA); Cash, Robert J. (Richland, WA)

    1988-01-01

    An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

  18. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C. Stuart (Knoxville, TN); Hawk, James A. (Oak Ridge, TN)

    1995-01-01

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

  19. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, R.G.

    1983-05-13

    The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  20. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA)

    1984-01-01

    Method and apparatus for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  1. Preparation and initial characterization of fluidized bed steam reforming pure-phase standards

    SciTech Connect (OSTI)

    Missimer, D. M.; Rutherford, R. L.

    2013-03-21

    Hanford is investigating the Fluidized Bed Steam Reforming (FBSR) process for their Low Activity Waste. The FBSR process offers a low-temperature continuous method by which liquid waste can be processed with the addition of clay into a sodium aluminosilicate (NAS) waste form. The NAS waste form is mainly comprised of nepheline (NaAlSiO{sub 4}), sodalite (Na{sub 8}[AlSiO{sub 4}]{sub 6}Cl{sub 2}), and nosean (Na{sub 8}[AlSiO{sub 4}]{sub 6}SO{sub 4}). Anions such as perrhenate (ReO{sub 4}{sup -}), pertechnetate (TcO{sub 4}{sup -}), and iodine (I{sup -}) are expected to replace sulfate in the nosean structure and/or chloride in the sodalite mineral structure (atomically bonded inside the aluminosilicate cages that these mineral structures possess). In the FBSR waste form, each of these phases can exist in a variety of solid solutions that differ from the idealized forms observed in single crystals in nature. The lack of understanding of the durability of these stoichiometric or idealized mineral phases complicates the ability to deconvolute the durability of the mixed phase FBSR product since it is a combination of different NAS phases. To better understand the behavior, fabrication and testing of the individual phases of the FBSR product is required. Analytical Development (AD) of the Science and Technology directorate of the Savannah River National Laboratory (SRNL) was requested to prepare the series of phase-pure standards, consisting of nepheline, nosean, and Cl, Re, and I sodalite. Once prepared, X-ray Diffraction (XRD) analyses were used to confirm the products were phase pure. These standards are being used for subsequent characterization studies consisting of the following: single-pass flow-through (SPFT) testing, development of thermodynamic data, and x-ray diffraction (XRD) calibration curves. In addition to the above mentioned phase-pure standards, AD was tasked with fabricating a mixed Tc-Re sodalite.

  2. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, A.G.; Patel, J.G.

    1987-05-12

    An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

  3. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1987-05-12

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  4. Fluidized bed combustion

    SciTech Connect (OSTI)

    Sowards, N.K.; Murphy, M.L.

    1991-10-29

    This patent describes a vessel. It comprises a fluid bed for continuously incinerating fuel comprising tire segments and the like which comprise metallic wire tramp and for concurrently removing tramp and bed materials at a bottom effluent exit means of the vessel, the vessel further comprising static air distributor means at the periphery of the bed comprising a substantially centrally unobstructed relatively large central region in which the fluid bed and fuel only are disposed and through which bed material and tramp migrate without obstruction to and through the effluent exit means, downwardly and inwardly stepped lower vessel wall means and a plurality of peripherally located centrally directed vertically and horizontally offset spaced air influent means surrounding the central region and associated with the stepped lower vessel wall means by which the bed is supported and fluidized.

  5. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.

    1993-12-14

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

  6. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1996-02-27

    A fluidized bed reactor system is described which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves. 3 figs.

  7. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1995-04-25

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

  8. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1996-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

  9. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1995-01-01

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  10. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN)

    1993-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  11. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  12. Internal dust recirculation system for a fluidized bed heat exchanger

    DOE Patents [OSTI]

    Gamble, Robert L. (Wayne, NJ); Garcia-Mallol, Juan A. (Morristown, NJ)

    1981-01-01

    A fluidized bed heat exchanger in which air is passed through a bed of particulate material containing fuel disposed in a housing. A steam/water natural circulation system is provided in a heat exchange relation to the bed and includes a steam drum disposed adjacent the bed and a tube bank extending between the steam drum and a water drum. The tube bank is located in the path of the effluent gases exiting from the bed and a baffle system is provided to separate the solid particulate matter from the effluent gases. The particulate matter is collected and injected back into the fluidized bed.

  13. Fluidized bed heat exchanger utilizing angularly extending heat exchange tubes

    DOE Patents [OSTI]

    Talmud, Fred M. (Berkeley Heights, NJ); Garcia-Mallol, Juan-Antonio (Morristown, NJ)

    1980-01-01

    A fluidized bed heat exchanger in which air is passed through a bed of particulate material containing fuel disposed in a housing. A steam/water natural circulation system is provided and includes a steam drum disposed adjacent the fluidized bed and a series of tubes connected at one end to the steam drum. A portion of the tubes are connected to a water drum and in the path of the air and the gaseous products of combustion exiting from the bed. Another portion of the tubes pass through the bed and extend at an angle to the upper surface of the bed.

  14. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    SciTech Connect (OSTI)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome some of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.

  15. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome somemore » of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.« less

  16. Secondary Waste Form Screening Test ResultsTHOR Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  17. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    SciTech Connect (OSTI)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome some of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.

  18. Fluidized bed deposition of diamond

    DOE Patents [OSTI]

    Laia, Jr., Joseph R. (Los Alamos, NM); Carroll, David W. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Anderson, Wallace E. (Los Alamos, NM); Valone, Steven M. (Santa Fe, NM)

    1998-01-01

    A process for coating a substrate with diamond or diamond-like material including maintaining a substrate within a bed of particles capable of being fluidized, the particles having substantially uniform dimensions and the substrate characterized as having different dimensions than the bed particles, fluidizing the bed of particles, and depositing a coating of diamond or diamond-like material upon the substrate by chemical vapor deposition of a carbon-containing precursor gas mixture, the precursor gas mixture introduced into the fluidized bed under conditions resulting in excitation mechanisms sufficient to form the diamond coating.

  19. Fluidized Bed Steam Reforming (FBSR) Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (GNEP)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Williams, M.R. [Savannah River National Laboratory, Aiken, SC (United States)

    2008-07-01

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NOx in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 deg. C) compared to vitrification (1150-1300 deg. C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {>=}1000 deg. C. Pollucite mineralization creates secondary aqueous waste streams and NOx. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O. (authors)

  20. FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP

    SciTech Connect (OSTI)

    Jantzen, C; Michael Williams, M

    2008-01-11

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  1. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  2. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  3. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, J.

    1996-03-19

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  4. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  5. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  6. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  7. Bed material agglomeration during fluidized bed combustion

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  8. Staged cascade fluidized bed combustor

    DOE Patents [OSTI]

    Cannon, Joseph N.; De Lucia, David E.; Jackson, William M.; Porter, James H.

    1984-01-01

    A fluid bed combustor comprising a plurality of fluidized bed stages interconnected by downcomers providing controlled solids transfer from stage to stage. Each stage is formed from a number of heat transfer tubes carried by a multiapertured web which passes fluidizing air to upper stages. The combustor cross section is tapered inwardly from the middle towards the top and bottom ends. Sorbent materials, as well as non-volatile solid fuels, are added to the top stages of the combustor, and volatile solid fuels are added at an intermediate stage.

  9. Apparatus and process for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1985-10-01

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  10. Distribution plate for recirculating fluidized bed

    DOE Patents [OSTI]

    Yang, Wen-ching; Vidt, Edward J.; Keairns, Dale L.

    1977-01-01

    A distribution plate for a recirculating fluidized bed has a centrally disposed opening and a plurality of apertures adjacent the periphery to eliminate dead spots within the bed.

  11. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

    1983-12-20

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  12. Fluidized Bed Technology - Overview | Department of Energy

    Office of Environmental Management (EM)

    Overview Fluidized Bed Technology - Overview Fluidized beds suspend solid fuels on upward-blowing jets of air during the combustion process. The result is a turbulent mixing of gas and solids. The tumbling action, much like a bubbling fluid, provides more effective chemical reactions and heat transfer. Fluidized-bed combustion evolved from efforts to find a combustion process able to control pollutant emissions without external emission controls (such as scrubbers). The technology burns fuel at

  13. Fundamentals of fluidized bed chemical processes

    SciTech Connect (OSTI)

    Yates, J.G.

    1983-01-01

    Chemical processes based on the use of fluidized solids, although widely used on an industrial scale for some four decades, are currently increasing in importance as industry looks for improved methods for handling and reacting solid materials. This book provides background necessary for an understanding of the technique of gas-solid fluidization. Contents: Some Fundamental Aspects of Fluidization-General Features of Gas-Solid Fluidization; Minimum Fluidization Velocity; Inter-particle forces; Liquid-Solid Fluidization; Bubbles; Slugging; Entrainment and Elutriation; Particle Movement; Bed Viscosity; Fluidization Under Pressure. Fluidized-Bed Reactor Models-ome Individual Models; Model Comparisons; Multiple Region Models. Catalytic Cracking-Process Developments Riser Cracking; Catalysis; Process Chemistry; Kinetics; Process Models. Combustion and Gasification-Plant Developments; Oil and Gas Combustion; Desulphurization; No/sub x/ Emissions; Coal Gassification. Miscellaneous Processes-Phthalic Anhydride (1,3-isobezofurandione); Acrylonitrile (prop-3-enenitrile); Vinyl Chloride (chloroethene); Titanium Dioxide; Uranium Processing; Sulphide Roasting; Indexes.

  14. Tube construction for fluidized bed combustor

    DOE Patents [OSTI]

    De Feo, Angelo; Hosek, William

    1984-01-01

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  15. Fluidized bed combustor and tube construction therefor

    DOE Patents [OSTI]

    De Feo, Angelo; Hosek, William

    1981-01-01

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  16. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  17. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    SciTech Connect (OSTI)

    Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

    2014-01-10

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

  18. Pressurized fluidized-bed combustion technology exchange workshop

    SciTech Connect (OSTI)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  19. Combined fluidized bed retort and combustor

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Notestein, John E. (Morgantown, WV); Mei, Joseph S. (Morgantown, WV); Zeng, Li-Wen (Morgantown, WV)

    1984-01-01

    The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

  20. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H. (Mt. Lebanon, PA)

    1984-01-01

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  1. Rivesville multicell fluidized bed boiler

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    One objective of the experimental MFB at Rivesville, WV, was the evaluation of alternate feed systems for injecting coal and limestone into a fluidized bed. A continuous, uniform feed flow to the fluid bed is essential in order to maintain stable operations. The feed system originally installed on the MFB was a gravity feed system with an air assist to help overcome the back pressure created by the fluid bed. The system contained belt, vibrating, and rotary feeders which have been proven adequate in other material handling applications. This system, while usable, had several operational and feeding problems during the MFB testing. A major portion of these problems occurred because the coal and limestone feed control points - a belt feeder and rotary feeder, respectively - were pressurized in the air assist system. These control points were not designed for pressurized service. An alternate feed system which could accept feed from the two control points, split the feed into six equal parts and eliminate the problems of the pressurized system was sought. An alternate feed system designed and built by the Fuller Company was installed and tested at the Rivesville facility. Fuller feed systems were installed on the north and south side of C cell at the Rivesville facility. The systems were designed to handle 10,000 lb/hr of coal and limestone apiece. The systems were installed in late 1979 and evaluated from December 1979 to December 1980. During this time period, nearly 1000 h of operating time was accumulated on each system.

  2. " "," ",,," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," "

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Relative Standard Errors for Table 8.3;" " Unit: Percents." " "," ",,," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," " " "," "

  3. ,,,"with Any"," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," "

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Relative Standard Errors for Table 8.3;" " Unit: Percents." ,,,"Establishments" ,,,"with Any"," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion Turbines with Heat Recovery",,,"Combined-Cycle Combusion Turbines",,,"Internal Combusion Engines with Heat Recovery",,," Steam Turbines Supplied by Heat Recovered from High-Temperature Processes",,,," "

  4. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  5. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  6. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J.; Kydd, Paul H.

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  7. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect (OSTI)

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the TTT steam reforming process ability to destroy organics in the Tank 48 simulant and produce a soluble carbonate waste form. The ESTD was operated at varying feed rates and Denitration and Mineralization Reformer (DMR) temperatures, and at a constant Carbon Reduction Reformer (CRR) temperature of 950 C. The process produced a dissolvable carbonate product suitable for processing downstream. ESTD testing was performed in 2009 at the Hazen facility to demonstrate the long term operability of an integrated FBSR processing system with carbonate product and carbonate slurry handling capability. The final testing demonstrated the integrated TTT FBSR capability to process the Tank 48 simulant from a slurry feed into a greater than 99.9% organic free and primarily dissolved carbonate FBSR product slurry. This paper will discuss the SRNL analytical results of samples analyzed from the 2008 and 2009 THOR{reg_sign} steam reforming ESTD performed with Tank 48H simulant at HRI in Golden, Colorado. The final analytical results will be compared to prior analytical results from samples in terms of organic, nitrite, and nitrate destruction.

  8. Gas fluidized-bed stirred media mill

    DOE Patents [OSTI]

    Sadler, III, Leon Y. (Tuscaloosa, AL)

    1997-01-01

    A gas fluidized-bed stirred media mill is provided for comminuting solid ticles. The mill includes a housing enclosing a porous fluidizing gas diffuser plate, a baffled rotor and stator, a hollow drive shaft with lateral vents, and baffled gas exhaust exit ports. In operation, fluidizing gas is forced through the mill, fluidizing the raw material and milling media. The rotating rotor, stator and milling media comminute the raw material to be ground. Small entrained particles may be carried from the mill by the gas through the exit ports when the particles reach a very fine size.

  9. Particle withdrawal from fluidized bed systems

    DOE Patents [OSTI]

    Salvador, Louis A. (Greensburg, PA); Andermann, Ronald E. (Arlington Heights, IL); Rath, Lawrence K. (Mt. Pleasant, PA)

    1982-01-01

    Method and apparatus for removing ash formed within, and accumulated at the lower portion of, a fluidized bed coal gasification reactor vessel. A supplemental fluidizing gas, at a temperature substantially less than the average fluidized bed combustion operating temperature, is injected into the vessel and upwardly through the ash so as to form a discrete thermal interface region between the fluidized bed and the ash. The elevation of the interface region, which rises with ash accumulation, is monitored by a thermocouple and interrelated with a motor controlled outlet valve. When the interface rises above the temperature indicator, the valve opens to allow removal of some of the ash, and the valve is closed, or positioned at a minimum setting, when the interface drops to an elevation below that of the thermocouple.

  10. Particle Pressures in Fluidized Beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction): they impart to the bed. So rather than directly measure the particle pressure, we inferred the values of the elasticity from measurements of instability growth in liquid beds the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined)and then working backwards to determine the unknown coefficients, including the elasticity.

  11. Particle pressures in fluidized beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction), they impart to the bed. So rather than directly measure the particle pressure, the authors inferred the values of the elasticity from measurements of instability growth in liquid beds; the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined) and then working backwards to determine the unknown coefficients, including the elasticity.

  12. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  13. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  14. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  15. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

    1992-01-01

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  16. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  17. Bed drain cover assembly for a fluidized bed

    DOE Patents [OSTI]

    Comparato, Joseph R. (Bloomfield, CT); Jacobs, Martin (Hartford, CT)

    1982-01-01

    A loose fitting movable cover plate (36), suitable for the severe service encountered in a fluidized bed combustor (10), restricts the flow of solids into the combustor drain lines (30) during shutdown of the bed. This cover makes it possible to empty spent solids from the bed drain lines which would otherwise plug the piping between the drain and the downstream metering device. This enables use of multiple drain lines each with a separate metering device for the control of solids flow rate.

  18. Reversed flow fluidized-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu; Mei, Joseph S.; Wilson, John S.

    1984-01-01

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  19. Fluidized bed electrowinning of copper. Final report

    SciTech Connect (OSTI)

    1997-07-01

    The objectives of the study were to: design and construct a 10,000- amp fluidized bed electrowinning cell for the recovery of copper from acidic sulfate solutions; demonstrate the technical feasibility of continuous particle recirculation from the electrowinning cell with the ultimate goal of continuous particle removal; and measure cell efficiency as a function of operating conditions.

  20. Solids feed nozzle for fluidized bed

    DOE Patents [OSTI]

    Zielinski, Edward A. (Harwinton, CT)

    1982-01-01

    The vertical fuel pipe of a fluidized bed extends up through the perforated support structure of the bed to discharge granulated solid fuel into the expanded bed. A cap, as a deflecting structure, is supported above the discharge of the fuel pipe and is shaped and arranged to divert the carrier fluid and granulated fuel into the combusting bed. The diverter structure is spaced above the end of the fuel pipe and provided with a configuration on its underside to form a venturi section which generates a low pressure in the stream into which the granules of solid fuel are drawn to lengthen their residence time in the combustion zone of the bed adjacent the fuel pipe.

  1. Design and performance of a high-pressure Fischer-Tropsch fluidized bed reactor

    SciTech Connect (OSTI)

    Weimer, A.W.; Quarderer, G.J.; Cochran, G.A.; Conway, M.M. )

    1988-01-01

    A 900 kg/day, CO/H/sub 2/, high-pressure, fluidized bed, pilot reactor was designed from first principles to achieve high reactant conversions and heat removal rates for the Fischer-Tropsch (F-T) synthesis of liquefied petroleum gases (LPG's). Suppressed bubble growth at high pressure allowed high reactant conversions which nearly matched those obtained at identical conditions in a lab scale fixed bed reactor. For GHSV approximately 1400 hr/sup -1/ and T = 658 {Kappa} at P approximately 7000 {kappa}Pa, reactant conversion exceeded 75%. The reactor heat removal capability exceeded twice design performance with the fluidized bed easily operating under thermally stable conditions. The fluidized catalyst was a potassium promoted, molybdenum on carbon (Mo/{Kappa}/C) catalyst which did not produce any detrimental waxy products. Long catalyst lifetimes of 1000 hrs on steam between regenerations allowed the fluidized bed to be operated in a batch mode.

  2. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

    1986-01-01

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  3. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  4. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  5. Status of the fluidized bed unit

    SciTech Connect (OSTI)

    Williams, P.M.; Wade, J.F.

    1994-06-01

    Rocky Flats has a serious mixed waste problem. No technology or company has a license and available facilities to remedy this dilemma. One solution under study is to use a catalytic fluidized bed unit to destroy the combustible portion of the mixed waste. The fluidized bed thermal treatment program at Rocky Flats is building on knowledge gained over twenty years of successful development activity. The FBU has numerous technical advantages over other thermal technologies to treat Rocky Flats` mixed waste, the largest being the lower temperature (700{degrees}C versus 1000{degrees}C) which reduces acid corrosion and mechanical failures and obviates the need for ceramic lining. Successful demonstrations have taken place on bench, pilot, and full-scale tests using radioactive mixed wastes. The program is approaching implementation and licensing of a production-scale fluidized bed system for the safe treatment of mixed waste. The measure for success on this project is the ability to work closely with the community to jointly solve problems and respond to concerns of mixed waste treatment at Rocky Flats.

  6. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for total constituents and durability tested as a granular waste form. A subset of the granular material was stabilized in a clay based geopolymer matrix at 42% and 65% FBSR loadings and durability tested as a monolith waste form. The 65 wt% FBSR loaded monolith made with clay (radioactive) was more durable than the 67-68 wt% FBSR loaded monoliths made from fly ash (non-radioactive) based on short term PCT testing. Long term, 90 to 107 day, ASTM C1308 testing (similar to ANSI/ANS 16.1 testing) was only performed on two fly ash geopolymer monoliths at 67-68 wt% FBSR loading and three clay geopolymer monoliths at 42 wt% FBSR loading. More clay geopolymers need to be made and tested at longer times at higher FBSR loadings for comparison to the fly ash monoliths. Monoliths made with metakaolin (heat treated) clay are of a more constant composition and are very reactive as the heat treated clay is amorphous and alkali activated. The monoliths made with fly ash are subject to the inherent compositional variation found in fly ash as it is a waste product from burning coal and it contains unreactive components such as mullite. However, both the fly ash and the clay based monoliths perform well in long term ASTM C1308 testing. Extensive testing and characterization of the granular and monolith material were made including the following American Society of Testing and Materials (ASTM) tests: ASTM C1285 testing (Product Consistency Test) of granular and monolithic waste forms; Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant  Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of clay; ASTM C1308 Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional Leaching from Cylindrical Waste Forms; Comparison of BSR non-radioactive waste forms to monolithic ESTD non-radioactive waste forms made from fly ash; Testing of BSR non-radioactive monoliths made from clay for comparison to non-radioactive monoliths made from fly ash; ASTM C39 Compressive Strength of Cylindrical Concrete Specimens; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms; EPA Manual SW-846 Method 1311, Toxicity Characteristic Leaching Procedure (TCLP); Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant; Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR non-radioactive waste forms.

  7. Hydrodynamic aspects of a circulating fluidized bed with internals

    SciTech Connect (OSTI)

    Balasubramanian, N.; Srinivasakannan, C.

    1998-06-01

    An attempt is made to examine the influence of internals (baffles) in the riser of the circulating fluidized bed. Experiments are conducted in a circulating fluidized bed, having perforated plates with different free areas. It is noticed from the present work that a circulating fluidized bed having 45% free area gives uniform solids concentration and pressure drop along the length of the riser. In addition to the uniformity, the circulating fluidized bed with internals gives higher pressure drop (solids concentration) compared to a conventional circulating fluidized bed. For internals having 67.6% free area the pressure drop is higher at the lower portion of the riser compared to the upper portion, similar to a conventional circulating fluidized bed. For 30% free area plates the solids concentration varies axially within the stage and remains uniform from stage to stage.

  8. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wastewater Reuse | Department of Energy The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse Presentation by Perry McCarty, Stanford University, during the "Targeting High-Value Challenges" panel at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop held March 18-19, 2015. PDF icon The Anaerobic Fluidized Bed Membrane Bioreactor for

  9. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse Presentation by Perry McCarty, Stanford University, during the "Targeting High-Value ...

  10. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  11. Pyrolysis reactor and fluidized bed combustion chamber

    DOE Patents [OSTI]

    Green, Norman W. (Upland, CA)

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  12. Fluidized bed boiler having a segmented grate

    DOE Patents [OSTI]

    Waryasz, Richard E. (Longmeadow, MA)

    1984-01-01

    A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

  13. Predictive models of circulating fluidized bed combustors

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  14. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-09-18

    Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

  15. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  16. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  17. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-06-30

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

  18. Fluidized Bed Technology - An R&D Success Story | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A 500-kilowatt fluidized bed test plant built in Alexandria, Virginia, in 1965 probably ... It provided much of the design data for a 30-megawatt prototype unit at the Monongahela ...

  19. Fluidized Bed Technology- An R&D Success Story

    Broader source: Energy.gov [DOE]

    In the early 1990s, POWER magazine called the development of fluidized bed coal combustors "the commercial success story of the last decade in the power generation business." The success, perhaps...

  20. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  1. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  2. Staged fluidized-bed combustion and filter system

    DOE Patents [OSTI]

    Mei, Joseph S. (Morgantown, WV); Halow, John S. (Waynesburg, PA)

    1994-01-01

    A staged fluidized-bed combustion and filter system for substantially reducing the quantity of waste through the complete combustion into ash-type solids and gaseous products. The device has two fluidized-bed portions, the first primarily as a combustor/pyrolyzer bed, and the second as a combustor/filter bed. The two portions each have internal baffles to define stages so that material moving therein as fluidized beds travel in an extended route through those stages. Fluidization and movement is achieved by the introduction of gases into each stage through a directional nozzle. Gases produced in the combustor/pyrolyzer bed are permitted to travel into corresponding stages of the combustor/filter bed through screen filters that permit gas flow but inhibit solids flow. Any catalyst used in the combustor/filter bed is recycled. The two beds share a common wall to minimize total volume of the system. A slightly modified embodiment can be used for hot gas desulfurization and sorbent regeneration. Either side-by-side rectangular beds or concentric beds can be used. The system is particularly suited to the processing of radioactive and chemically hazardous waste.

  3. Project Profile: Particle Receiver Integrated with a Fluidized Bed |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Concentrating Solar Power » Project Profile: Particle Receiver Integrated with a Fluidized Bed Project Profile: Particle Receiver Integrated with a Fluidized Bed NREL logo The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), are developing a novel receiver that uses falling particles instead of liquid for the heat-transfer fluid (HTF). The research team

  4. Development and applications of clean coal fluidized bed technology

    SciTech Connect (OSTI)

    Eskin, N.; Hepbasli, A.

    2006-09-15

    Power generation in Europe and elsewhere relies heavily on coal and coal-based fuels as the source of energy. The reliance will increase in the future due to the decreasing stability of price and security of oil supply. In other words, the studies on fluidized bed combustion systems, which is one of the clean coal technologies, will maintain its importance. The main objective of the present study is to introduce the development and the applications of the fluidized bed technology (FBT) and to review the fluidized bed combustion studies conducted in Turkey. The industrial applications of the fluidized bed technology in the country date back to the 1980s. Since then, the number of the fluidized bed boilers has increased. The majority of the installations are in the textile sector. In Turkey, there is also a circulating fluidized bed thermal power plant with a capacity of 2 x 160 MW under construction at Can in Canakkale. It is expected that the FBT has had, or will have, a significant and increasing role in dictating the energy strategies for Turkey.

  5. Coal-feeding mechanism for a fluidized bed combustion chamber

    DOE Patents [OSTI]

    Gall, Robert L. (Morgantown, WV)

    1981-01-01

    The present invention is directed to a fuel-feeding mechanism for a fluidized bed combustor. In accordance with the present invention a perforated conveyor belt is utilized in place of the fixed grid normally disposed at the lower end of the fluidized bed combustion zone. The conveyor belt is fed with fuel, e.g. coal, at one end thereof so that the air passing through the perforations dislodges the coal from the belt and feeds the coal into the fluidized zone in a substantially uniform manner.

  6. Fluidized bed heat exchanger with water cooled air distributor and dust hopper

    DOE Patents [OSTI]

    Jukkola, Walfred W.; Leon, Albert M.; Van Dyk, Jr., Garritt C.; McCoy, Daniel E.; Fisher, Barry L.; Saiers, Timothy L.; Karstetter, Marlin E.

    1981-11-24

    A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

  7. Methods of forming a fluidized bed of circulating particles

    DOE Patents [OSTI]

    Marshall, Douglas W. (Blackfoot, ID)

    2011-05-24

    There is disclosed an apparatus for forming a fluidized bed of circulating particles. In an embodiment, the apparatus includes a bottom portion having a sidewall, the sidewall defining a curvilinear profile, and the bottom portion configured to contain a bed of particles; and a gas inlet configured to produce a column of gas to carry entrained particles therein. There is disclosed a method of forming a fluidized bed of circulating particles. In an embodiment, the method includes positioning particles within a bottom portion having a sidewall, the sidewall defining a curvilinear profile; producing a column of gas directed upwardly through a gas inlet; carrying entrained particles in the column of gas to produce a fountain of particles over the fluidized bed of circulating particles and subside in the particle bed until being directed inwardly into the column of gas within the curvilinear profile.

  8. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  9. COMPUTATIONAL MODELING OF CIRCULATING FLUIDIZED BED REACTORS

    SciTech Connect (OSTI)

    Ibrahim, Essam A

    2013-01-09

    Details of numerical simulations of two-phase gas-solid turbulent flow in the riser section of Circulating Fluidized Bed Reactor (CFBR) using Computational Fluid Dynamics (CFD) technique are reported. Two CFBR riser configurations are considered and modeled. Each of these two riser models consist of inlet, exit, connecting elbows and a main pipe. Both riser configurations are cylindrical and have the same diameter but differ in their inlet lengths and main pipe height to enable investigation of riser geometrical scaling effects. In addition, two types of solid particles are exploited in the solid phase of the two-phase gas-solid riser flow simulations to study the influence of solid loading ratio on flow patterns. The gaseous phase in the two-phase flow is represented by standard atmospheric air. The CFD-based FLUENT software is employed to obtain steady state and transient solutions for flow modulations in the riser. The physical dimensions, types and numbers of computation meshes, and solution methodology utilized in the present work are stated. Flow parameters, such as static and dynamic pressure, species velocity, and volume fractions are monitored and analyzed. The differences in the computational results between the two models, under steady and transient conditions, are compared, contrasted, and discussed.

  10. Fluidized bed combustor and coal gun-tube assembly therefor

    DOE Patents [OSTI]

    Hosek, William S. (Mt. Tabor, NJ); Garruto, Edward J. (Wayne, NJ)

    1984-01-01

    A coal supply gun assembly for a fluidized bed combustor which includes heat exchange elements extending above the bed's distributor plate assembly and in which the gun's nozzles are disposed relative to the heat exchange elements to only discharge granular coal material between adjacent heat exchange elements and in a path which is substantially equidistant from adjacent heat exchange elements.

  11. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  12. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock & Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  13. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  14. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    SciTech Connect (OSTI)

    Rokkam, Ram

    2012-11-02

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  15. Metallic species derived from fluidized bed coal combustion. [59 references

    SciTech Connect (OSTI)

    Natusch, D.F.S.; Taylor, D.R.

    1980-01-01

    Samples of fly ash generated by the combustion of Montana Rosebud coal in an experimental 18 inch fluidized bed combustor were collected. The use of a heated cascade impactor permitted collection of size fractionated material that avoided condensation of volatile gases on the particles. Elemental concentration trends were determined as a function of size and temperature and the results compared to published reports for conventional power plants. The behavior of trace metals appears to be substantially different in the two systems due to lower operating temperatures and the addition of limestone to the fluidized bed. Corrosion of the impactor plates was observed at the highest temperature and lowest limestone feed rate sampled during the study. Data from the elemental concentration and leaching studies suggest that corrosion is most likely due to reactions involving sodium sulfate. However, it is concluded that corrosion is less of a potential problem in fluidized-bed systems than in conventional coal-fired systems.

  16. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1991-06-01

    Advanced integrated gasification combined cycle (IGCC) power systems require the development of high-temperature desulfurization sorbents capable of removing hydrogen sulfide from coal gasifier down to very low levels. The objective of this investigation was to identify and demonstrate methods for enhancing the long-term chemical reactivity and mechanical strength of zinc ferrite, a leading regenerable sorbent, for fluidized-bed applications. Fluidized sorbent beds offer significant potential in IGCC systems because of their ability to control the highly exothermic regeneration involved. However, fluidized beds require a durable, attrition-resistant sorbent in the 100--300 {mu}m size range. A bench-scale high-temperature, high- pressure (HTHP) fluidized-bed reactor (7.6-cm I.D.) system capable of operating up to 24 atm and 800{degree}C was designed, built and tested. A total of 175 sulfidation-regeneration cycles were carried out using KRW-type coal gas with various zinc ferrite formulations. A number of sorbent manufacturing techniques including spray drying, impregnation, crushing and screening, and granulation were investigated. While fluidizable sorbents prepared by crushing durable pellets and screening had acceptable sulfur capacity, they underwent excessive attrition during multicycle testing. The sorbent formulations prepared by a proprietary technique were found to have excellent attrition resistance and acceptable chemical reactivity during multicycle testing. However, zinc ferrite was found to be limited to 550{degree}C, beyond which excessive sorbent weakening due to chemical transformations, e.g., iron oxide reduction, was observed.

  17. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  18. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

    1980-01-01

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  19. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  20. Fluidized bed combustor and removable windbox and tube assembly therefor

    DOE Patents [OSTI]

    DeFeo, Angelo (Totowa, NJ); Hosek, William S. (Mt. Tabor, NJ)

    1981-01-01

    A fluidized bed combustor comprises a housing having a chamber therein with a top having a discharge for the gases which are generated in the chamber and a bottom with a discharge for heated fluid. An assembly is arranged in the lower portion of the chamber and the assembly includes a lower plate which is mounted on a support flange of the housing so that it is spaced from the bottom of the chamber and defines a fluid plenum between it and the bottom of the chamber for the discharge of heated fluid. The assembly includes a heat exchanger inlet plenum having tubes therethrough for the passage of fluidizer air and a windbox above the heat exchanger plenum which has a distributor plate top wall. A portion of the chamber above the top wall defines a fluidized bed.

  1. Fluidized bed combustor and removable windbox and tube assembly therefor

    DOE Patents [OSTI]

    DeFeo, Angelo (Totowa, NJ); Hosek, William (Mt. Tabor, NJ)

    1983-01-01

    A fluidized bed combustor comprises a housing having a chamber therein with a top having a discharge for the gases which are generated in the chamber and a bottom with a discharge for heated fluid. An assembly is arranged in the lower portion of the chamber and the assembly includes a lower plate which is mounted on a support flange of the housing so that it is spaced from the bottom of the chamber and defines a fluid plenum between it and the bottom of the chamber for the discharge of heated fluid. The assembly includes a heat exchanger inlet plenum having tubes therethrough for the passage of fluidizer air and a windbox above the heat exchanger plenum which has a distributor plate top wall. A portion of the chamber above the top wall defines a fluidized bed.

  2. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect (OSTI)

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  3. A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace

    SciTech Connect (OSTI)

    Murray, J.P.

    1989-01-01

    A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

  4. Combustion of refuse derived fuel in a fluidized bed

    SciTech Connect (OSTI)

    Piao, Guilin; Aono, Shigeru; Mori, Shigekatsu; Deguchi, Seiichi; Fujima, Yukihisa; Kondoh, Motohiro; Yamaguchi, Masataka

    1998-12-31

    Power generation from Refuse Derived Fuel (RDF) is an attractive utilization technology of municipal solid waste. To explain the behavior of RDF-fired fluidized bed incinerator, the commercial size RDF was continuously burnt in a 30 x 30 cm bubbling type fluidized-bed combustor. It was found that 12 kg/h of RDF feed rate was too high feed for this test unit and the Co level was higher than 500 ppm. However, 10 kg/h of RDF was a proper feed rate and the Co level was kept under 150 ppm. Secondary air injection and changing air ratio from the pipe grid were effective for the complete combustion of RDE. It was also found that HCl concentration in flue gas was controlled by the calcium component contained in RDF and its level was decreased with decreasing the combustor temperature.

  5. Current state of atmospheric fluidized-bed combustion technology

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This paper examines atmospheric fluidized-bed combustion (AFBC) technology, a coal burning method that has several environmental and technical advantages over the more conventional technologies, such as pulverized-coal methods. The AFBC approach injects an air stream into a boiler in such a way that it mixes with solid fuel and sorbent to create a dense phase region or fluidized bed. This method makes it possible to use a much wider range of low-quality fuels and to burn them at lower temperatures with less pollutant by-product. The paper presents a comprehensive overview of AFBC technology to date. It includes worldwide development of this technology since the 1950s necessary to meet ever-stricter emissions requirements while providing greater fuel flexibility.

  6. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  7. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  8. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  9. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE (WTP-SW) BY FLUIDIZED BED STEAM REFORMING (FBSR) USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

    2014-08-21

    The U.S. Department of Energys Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanfords tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanfords WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing. The granular products (both simulant and radioactive) were tested and a subset of the granular material (both simulant and radioactive) were stabilized in a geopolymer matrix. Extensive testing and characterization of the granular and monolith material were made including the following: ? ASTM C1285 (Product Consistency Test) testing of granular and monolith; ? ASTM C1308 accelerated leach testing of the radioactive monolith; ? ASTM C192 compression testing of monoliths; and ? EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) testing. The significant findings of the testing completed on simulant and radioactive WTP-SW are given below: ? Data indicates {sup 99}Tc, Re, Cs, and I

  10. Fluidized-bed combustion of scrap tires: Technical note

    SciTech Connect (OSTI)

    Shang, J.Y.; Mei, J.S.; Notestein, J.E.

    1981-10-01

    An introduction to fluidized-bed combustion (FBC) is presented in Section 2.0. Based on this discussion of its technical development, FBC is then presented as a means of scrap tire disposal. In Section 3.0, scrap tire disposal is reviewed in the categories of (1) physical applications, (2) chemical applications, (3) pyrolysis, and (4) incineration for thermal energy recovery. Scrap tire disposal is reviewed on the basis of (1) environmental acceptability, (2) conservation of resources, (3) impact on existing industries, (4) operational feasibility, and (5) special features. The focus of this report is the fluidized-bed incineration of scrap tires for thermal energy recovery. The factors that affect scrap tire combustion are discussed in Section 4.0. These factors are (1) agitation, (2) temperature, (3) excess air, (4) residence time, (5) feed uniformity, (6) solid waste handling, and (7) pollutants emission control. In reviewing these incineration processes, (1) fuel flexibility, (2) environmental acceptability, (3) combustion efficiency, and (4) operational reliability are discussed. The results from a tire incineration experiment conducted at the Morgantown Energy Technology Center are presented in Section 5.0, and a conceptual fluidized-bed combustor is discussed in Section 6.0. Future considerations in the FBC of scrap tires are discussed in Section 7.0. 8 refs., 6 figs., 6 tabs.

  11. A NEW INTERPHASE FORCE IN TWO-PHASE FLUIDIZED BEDS

    SciTech Connect (OSTI)

    D. ZHANG; W. VANDERHEYDEN

    2001-05-01

    Mesoscale structures such as particle clusters have been observed both in experiments and in numerical simulations of circulating fluidized beds. In a numerical simulation, in order to account for the effects of such mesoscale structures, the computational grids have to be fine enough. The use of such fine grids is impractical in engineering applications due to excessive computational costs. To predict the macroscopic behavior of a fluidized bed with reasonable computation cost, they perform a second average over the averaged equations for two-phase flows. A mesoscale inter-phase exchange force is found to be the correlation of the particle volume fraction and the pressure gradient. This force is related to the mesoscale added mass of the two-phase flow. Typically, added mass for particle scale interactions is negligible in gas-solid flows since the gas density is small compared to density of solid particles. However, for a mesoscale structure, such as a bubble, the surrounding media is the mixture of gas and particles. The surrounding fluid density experienced by the mesoscale structure is the density of the surrounding mixture. Therefore, the added mass of a mesoscale structure, such as bubbles, cannot be neglected. The property of this new force is studied based on the numerical simulation of a fluidized bed using high grid resolution. It is shown that this force is important in the region where the particle volume fraction is high. The effects of the inhomogeneity to the interphase drag are also studied.

  12. Bed material agglomeration during fluidized bed combustion. Technical progress report, September 30, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  13. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Strandberg, Gerald W. (Farragut, TN)

    1989-01-01

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  14. Fluidized-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor. 2 figs.

  15. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion system. Final technical report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-11-01

    Research is presented on erosion and corrosion of fluidized bed combustor component materials. The characteristics of erosion of in-bed tubes was investigated. Anti-corrosion measures were also evaluated.

  16. Fluidized-bed combustion and gasification of biomass

    SciTech Connect (OSTI)

    LePori, W.A.; Anthony, R.G.; Lalk, T.R.; Craig, J.D.

    1981-01-01

    A 0.61 meter (2 ft) diameter fluidized-bed combustion reactor was used for tests on direct combustion of cotton gin trash. Raw gin trash was continuously augered into the unit with fuel and air rates set to maintain bed temperatures of 760/sup 0/ to 816/sup 0/C (1400/sup 0/ to 1500/sup 0/F). Particulate emissions in the hot stack gases were measured and found to be lower than federal standards for incinerators. Mild steel and stainless alloy samples were placed in the hot stack gas stream to study corrosion and erosion of materials. High rates of potassium, calcium, and sodium deposits accumulated on the samples, and high erosion rates were found. A 0.3 meter (13 in) diameter fluidized-bed gasifier was used to convert raw gin trash into a combustible gas with bed temperatures between 683/sup 0/C and 881/sup 0/C (1261/sup 0/F and 1618/sup 0/F). By limiting the amount of oxygen compared to the fuel feed, only partial combustion occurs, producing heat and endothermic gasification chemical reactions. The combustible gas was composed primarily of carbon monoxide and hydrogen. It had a heating value ranging from 3.40 to 4.82 M Joules per standard cubic meter (98 to 142 Btu/scf), and about 50 percent of the heat value of the gin trash was converted into this low energy gas.

  17. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1983-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  18. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1982-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  19. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    Sibashis Banerjee; Alvin Chen; Rutton Patel; Dale Snider; Ken Williams; Timothy O'Hern; Paul Tortora

    2008-02-29

    The work detailed in this report addresses Enabling Technologies within Computational Technology by integrating a breakthrough particle-fluid computational technology into traditional Process Science and Engineering Technology. The work completed under this DOE project addresses five major development areas 1) gas chemistry in dense fluidized beds 2) thermal cracking of liquid film on solids producing gas products 3) liquid injection in a fluidized bed with particle-to-particle liquid film transport 4) solid-gas chemistry and 5) first level validation of models. Because of the nature of the research using tightly coupled solids and fluid phases with a Lagrangian description of the solids and continuum description of fluid, the work provides ground-breaking advances in reactor prediction capability. This capability has been tested against experimental data where available. The commercial product arising out of this work is called Barracuda and is suitable for a wide (dense-to-dilute) range of industrial scale gas-solid flows with and without reactions. Commercial applications include dense gas-solid beds, gasifiers, riser reactors and cyclones.

  20. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS ICP-1151 January 1979 IDAHO OPERATIONS OFFICE UNDER CONTRACT EY-76-C-07-1540 Printed i n the United States of America Available from National Technical Information Service US. Department of Commerce 5285 Port Royal Road Springfield, Virginia 22161 Price: Printed Copy $4.00; Microfiche $3.00 I NOTICE This report was prepared as an account of work sponsored by the United States Government. Neither the United States nor the Department of

  1. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G. (Akron, OH); Weitzel, Paul S. (Canal Fulton, OH)

    1990-01-01

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  2. Volatiles combustion in fluidized beds. [Quarterly] technical progress report, 4 December 1994--4 March 1995

    SciTech Connect (OSTI)

    Pendergrass II, R.A.; Mansker, L.D.; Hesketh, R.P.

    1995-08-01

    The goal of this project is to investigate the conditions in which volatiles will bum within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 December, 1994 through, 3 March 1995 is presented in this technical progress report. The research consists of the application of a detailed chemical kinetics model for propane combustion and planned improvements in the experimental system.

  3. Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

    SciTech Connect (OSTI)

    Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

    1996-02-29

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

  4. In-bed tube bank for a fluidized-bed combustor

    DOE Patents [OSTI]

    Hemenway, Jr., Lloyd F. (Morgantown, WV)

    1990-01-01

    An in-bed tube bank (10) for a fluidized bed combustor. The tube bank (10) of the present invention comprises one or more fluid communicating boiler tubes (30) which define a plurality of selectively spaced boiler tube sections (32). The tube sections (32) are substantially parallel to one another and aligned in a common plane. The tube bank (10) further comprises support members (34) for joining adjacent tube sections (32), the support members (34) engaging and extending along a selected length of the tube sections (32) and spanning the preselected space therebetween.

  5. Emission factors for several toxic air pollutants from fluidized-bed combustion of coal

    SciTech Connect (OSTI)

    Smith, A.E.

    1986-03-01

    Clean coal technologies such as fluidized-bed combustion have the potential to emit the same trace elements as conventional combustors. Since the US Environmental Protection Agency (EPA) is likely to promulgate National Emission Standards for Hazardous Air Pollutants for several trace elements, the feasibility of using fluidized-bed combustors to reduce sulfur dioxide emissions may depend in part on the relative amounts of trace elements emitted by fluidized-bed and conventional combustors. Emissions of trace elements from both atmospheric and pressurized fluidized-bed combustors were compared with those from conventional combustors by developing fluidized-bed emission factors from information available in the literature and comparing them with the emission factors for conventional combustors recommended in a literature search conducted for EPA. The comparisons are based on the mass of emission per unit of heat input for antimony, arsenic, beryllium, cadmium, chromium, cobalt, copper, lead, manganese, mercury, nickel, vanadium, and zinc. When inaccuracies in the data were taken into account, the trace element emissions from atmospheric fluidized-bed combustion seem to be somewhat higher than those from a conventional utility boiler burning pulverized coal and somewhat lower than those from pressurized fluidized-bed combustion.

  6. Capacitance-level/density monitor for fluidized-bed combustor

    DOE Patents [OSTI]

    Fasching, George E.; Utt, Carroll E.

    1982-01-01

    A multiple segment three-terminal type capacitance probe with segment selection, capacitance detection and compensation circuitry and read-out control for level/density measurements in a fluidized-bed vessel is provided. The probe is driven at a high excitation frequency of up to 50 kHz to sense quadrature (capacitive) current related to probe/vessel capacitance while being relatively insensitive to the resistance current component. Compensation circuitry is provided for generating a negative current of equal magnitude to cancel out only the resistive component current. Clock-operated control circuitry separately selects the probe segments in a predetermined order for detecting and storing this capacitance measurement. The selected segment acts as a guarded electrode and is connected to the read-out circuitry while all unselected segments are connected to the probe body, which together form the probe guard electrode. The selected probe segment capacitance component signal is directed to a corresponding segment channel sample and hold circuit dedicated to that segment to store the signal derived from that segment. This provides parallel outputs for display, computer input, etc., for the detected capacitance values. The rate of segment sampling may be varied to either monitor the dynamic density profile of the bed (high sampling rate) or monitor average bed characteristics (slower sampling rate).

  7. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, C.D.; Petersen, J.N.; Davison, B.H.

    1996-07-09

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, and larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. 8 figs.

  8. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Petersen, James N. (Moscow, ID); Davison, Brian H. (Knoxville, TN)

    1996-01-01

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, as larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor.

  9. Characterization of Biofilm in 200W Fluidized Bed Reactors

    SciTech Connect (OSTI)

    Lee, Michelle H.; Saurey, Sabrina D.; Lee, Brady D.; Parker, Kent E.; Eisenhauer, Emalee ER; Cordova, Elsa A.; Golovich, Elizabeth C.

    2014-09-29

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry evaluations, a more complete understanding of the balance between system additions (nutrients, groundwater) and biology can be achieved, thus increasing long-term predictions of performance. These analyses uniquely provide information that can be used in optimizing the overall performance, efficiency, and stability of the system both in real time as well as over the long-term, as the system design is altered or improved and/or new streams are added.

  10. Method and apparatus for improving heat transfer in a fluidized bed

    DOE Patents [OSTI]

    Lessor, Delbert L. (Richland, WA); Robertus, Robert J. (Richland, WA)

    1990-01-01

    An apparatus contains a fluidized bed that includes particles of different triboelectrical types, each particle type acquiring an opposite polarity upon contact. The contact may occur between particles of the two types or between particles of etiher type and structure or fluid present in the apparatus. A fluidizing gas flow is passed through the particles to produce the fluidized bed. Immersed within the bed are electrodes. An alternating EMF source connected to the electrodes applies an alternating electric field across the fluidized bed to cause particles of the first type to move relative to particles of the second type and relative to the gas flow. In a heat exchanger incorporating the apparatus, the electrodes are conduits conveying a fluid to be heated. The two particle types alternately contact each conduit to transfer heat from a hot gas flow to the second fluid within the conduit.

  11. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  12. Synthetic aggregate compositions derived from spent bed materials from fluidized bed combustion and fly ash

    DOE Patents [OSTI]

    Boyle, Michael J.

    1994-01-01

    Cementitious compositions useful as lightweight aggregates are formed from a blend of spent bed material from fluidized bed combustion and fly ash. The proportions of the blend are chosen so that ensuing reactions eliminate undesirable constituents. The blend is then mixed with water and formed into a shaped article. The shaped article is preferably either a pellet or a "brick" shape that is later crushed. The shaped articles are cured at ambient temperature while saturated with water. It has been found that if used sufficiently, the resulting aggregate will exhibit minimal dimensional change over time. The aggregate can be certified by also forming standardized test shapes, e.g., cylinders while forming the shaped articles and measuring the properties of the test shapes using standardized techniques including X-ray diffraction.

  13. Computer modeling of a CFB (circulating fluidized bed) gasifier

    SciTech Connect (OSTI)

    Gidaspow, D.; Ding, J.

    1990-06-01

    The overall objective of this investigation is to develop experimentally verified models for circulating fluidized bed (CFB) combustors. This report presents an extension of our cold flow modeling of a CFB given in our first quarterly report of this project and published in Numerical Methods for Multiphase Flows'' edited by I. Celik, D. Hughes, C. T. Crowe and D. Lankford, FED-Vol.91, American Society of Mechanical Engineering, pp47--56 (1990). The title of the paper is Multiphase Navier-Stokes Equation Solver'' by D. Gidaspow, J. Ding and U.K. Jayaswal. To the two dimensional code described in the above paper we added the energy equations and the conservation of species equations to describe a synthesis gas from char producer. Under the simulation conditions the injected oxygen reacted near the inlet. The solid-gas mixing was sufficiently rapid that no undesirable hot spots were produced. This simulation illustrates the code's capability to model CFB reactors. 15 refs., 20 figs.

  14. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI); Koskinen, Jari (Karhula, FI)

    1995-01-01

    Hot gases from a pressurized fluidized bed reactor system are purified. Under superatmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a flitrate cake on the surface of the separator, and a reducing agent--such as an NO.sub.x reducing agent (like ammonia), is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1-20 cm/s) during passage of the gas through the filtrate cake while at superatmospheric pressure. Separation takes place within a distinct pressure vessel the interior of which is at a pressure of about 2-100 bar, and-introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine).

  15. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, J.; Koskinen, J.

    1995-08-22

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  16. Repowering with pressurized fluidized-bed combustion units

    SciTech Connect (OSTI)

    Goidich, S.J. ); Rubow, L.N. ); Kumar, S. . Environmental Services and Technologies Div.); Mukherjee, D. ); Childress, N.B. )

    1991-05-01

    Turbocharged pressurized fluidized bed combustion (PFBC) power plants operating with a gas turbine inlet temperature lower than 800{degrees}F can produce electricity more efficiently (34.2 vs. 33.5% net plant efficiency) and at a lower cost of electricity (87.8 vs. 96. 6 mill/kWh over 30 years) than conventional pulverized-coal-fired plants with scrubbers. Since the PFBC process produces lower NO{sub x} emissions than conventional pulverized-coal combustion systems and captures sulfur as part of the combustion process, and since major equipment components can be shop-assembled and shipped by barge, retrofit of an existing unit with a turbocharged PFBC boiler can be a cost-effective means for extending the life of the unit and meeting NSPS without retrofitting flue gas desulfurization systems. Using the Wisconsin Electric Power Company's Port Washington Unit 5 as an example, preliminary engineering and economic evaluations were made to investigate the merits of turbocharged PFBC retrofits. This report describes the conceptual designs of the new, major plant components; discusses how the new components are integrated with the existing balance-of-plant equipment; describes the proposed plant control system; and presents an overall economic evaluation. Because design and economic evaluations were prepared on the basis of a commercial design, first-of-a-kind costs and test programs are not included. 5 refs., 58 figs., 55 tabs.

  17. Hydrodynamics of circulating fluidized beds: Kinetic theory approach...

    Office of Scientific and Technical Information (OSTI)

    Resource Type: Conference Resource Relation: Conference: 7th international conference on fluidization, Gold Coast (Australia), 3-8 May 1992 Research Org: Illinois Inst. of Tech., ...

  18. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  19. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  20. Pressurized fluidized-bed hydroretorting of Eastern oil shales

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. ); Schultz, C.W. ); Parekh, B.K. ); Misra, M. ); Bonner, W.P. )

    1992-11-01

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  1. PFBC (pressurized fluidized bed combustion) turbocharged boiler design and economic study: Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    A coal combustion technology that promises to reduce the cost of electrical power is pressurized fluidized bed combustion (PFBC). Since a PFBC boiler is physically smaller than a conventional pulverized coal fired boiler with a flue gas desulfurization system (PC/FGD) and the same power rating shop assembly and modularized shipment to the power plant site can be considered. Modular construction can substantially reduce the overall design/construction time. Emission controls are equivalent to, or better than, conventional PC/FGD units, and the PFBC combustor can tolerate coals with a wider range of characteristics. Two PFBC plants and the reference PC/FGD plant were each to have four nominal 250 MW(e) units to be completed for start-up at one year intervals. To establish a well defined consistent design basis for all units, the turbine-generator and steam cycle of a recently constructed 250 MW(e) unit (designed by Fluor and built under Fluor construction management) was selected and made the common element in both of the PFBC plants and the reference PC/FGD plant. Steam conditions of 2400 psia, 1000/sup 0/F were to be identical for all units as were the steam flows for the design load range of 50% to steam turbine valves-wide-open with inlet steam pressure 5% over design pressure (VWO 5% OP). The study produced three plant designs - a 4-unit turbocharged PFBC using bubbling bed technology, a 4-unit turbocharged PFBC using circulating bed technology, and a 4-unit PC/FGD reference plant using conventional pulverized coal technology coupled with wet limestone scrubber technology. The hot gas clean-up system, operating at these more modest temperatures, is capable of reducing the particulate in the gas to a level which meets EPA/NSPS standards without further cleanup. With this level of cleanup, service conditions for the turbocharger turbine are tolerable in commercially available designs and materials. 48 figs., 14 tabs.

  2. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Andy Wu; John T. Riley

    2005-01-30

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period October 1, 2004 through December 31, 2004. The following tasks have been completed. First, the renovation of the new Combustion Laboratory and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building have proceeded well. Second, the detailed design of supporting and hanging structures for the CFBC was completed. Third, the laboratory-scale simulated fluidized-bed facility was modified after completing a series of pretests. The two problems identified during the pretest were solved. Fourth, the carbonization of chicken waste and coal was investigated in a tube furnace and a Thermogravimetric Analyzer (TGA). The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter has been outlined in this report.

  3. ADVANCED SORBENT DEVELOPMENT PROGRAM; DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E. AYALA; V.S. VENKATARAMANI

    1998-09-30

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.?s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration tempera-tures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent develop-ment at General Electric?s Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  4. 3-D capacitance density imaging of fluidized bed

    DOE Patents [OSTI]

    Fasching, George E. (653 Vista Pl., Morgantown, WV 26505)

    1990-01-01

    A three-dimensional capacitance density imaging of a gasified bed or the like in a containment vessel is achieved using a plurality of electrodes provided circumferentially about the bed in levels and along the bed in channels. The electrodes are individually and selectively excited electrically at each level to produce a plurality of current flux field patterns generated in the bed at each level. The current flux field patterns are suitably sensed and a density pattern of the bed at each level determined. By combining the determined density patterns at each level, a three-dimensional density image of the bed is achieved.

  5. Investigation of heat transfer and combustion in the advanced fluidized bed combustor (FBC)

    SciTech Connect (OSTI)

    Dr. Seong W. Lee

    1998-10-01

    The objective of this project is to predict the heat transfer and combustion performance in newly-designed fluidized bed combustor (FBC) and to provide the design guide lines and innovative concept for small-scale boiler and furnace. The major accomplishments are summarized.

  6. Experimental development of a multi-solid fluidized bed reactor concept

    SciTech Connect (OSTI)

    Litt, R.D.; Paisley, M.A.; Tewksbury, T.L.

    1990-02-01

    Battelle's Columbus Division is developing a coal mild gasification process based upon the Multi-Solid Fluidized bed reactor system to produce high quality liquid and gaseous products. This process uses 2-stages to gasify coal at high throughputs to produce a range of products in compact reactors without requiring an oxygen plant. 8 refs., 14 figs., 12 tabs.

  7. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    & EC Spatial Imaging via X-ray Micro-tomography Computed Tomography Changes in Pore Structure Moisture Distribution XMT-CT Scan Void Space (Black), Particles (White), Water...

  8. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming...

    Office of Environmental Management (EM)

    denitration mineralization reformer (DMR) (polyethylene (PE) beads, PG, PE beads + PG, Sugar, Coal, Sugar + Coal). Only coal as DMR reductant produced acceptable results....

  9. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 3. Heat transfer between a supernatant gas and a flowing shallow fluidized bed of solids. Final technical report, October 1, 1986

    SciTech Connect (OSTI)

    Boyd, J.H.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Volume II describes the details of heat-transfer studies in a dry fluidized-bed system (called ''heat tray''), which has been proposed for heat recovery from hot gases and for heat management in exothermic reactions. In particular, this report presents the results of bench-scale and pilot-scale experimental studies which quantify heat transfer between a hot supernatant gas (S-gas) and a flowing shallow fluidized bed of solids. A fractional-factorial design of experiments has been performed on two heat-tray systems using three different solids. The results show that fine fluid cracking catalyst (FCC) particles out-perform larger alumina spheres as a fluidized solid. Heat transfer coefficients between the supernatant gas and the shallow fluidized bed approaches 440 W/m/sup 2/-K using FCC with a heat-exchange area of 0.124 m/sup 2/. Various S-gas inlet nozzle configurations have been studied, with a nozzle height equal to one-half of the static bed height (0.051 m) giving the best results. The study shows that short heat-tray lengths (< 0.8 m) are desirable and that S-gas redistributors are needed to compartmentalize the unit. An economic analysis shows that the proposed heat tray would be economically feasible for adaption as a boiler feedwater preheater in a small steam-generation facility, using boiler combustion gases as the S-gas. The payback time for the system would be as short as 1.9 years when used continuously. The heat transfer results from a supernatant gas to a flowing shallow fluidized bed represent the only data reported thus far, and have led to a better understanding of the heat management in the proposed ''heat-tray'' reactor for Fischer-Tropsch synthesis. 20 refs., 46 figs., 15 tabs.

  10. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    SciTech Connect (OSTI)

    Zhen Fan

    2006-05-30

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  11. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Kunlei Liu; John T. Riley

    2004-01-01

    The purpose of this report is to summarize the progress made on the project ''Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion (CFBC) System'' in this quarter (September-December of 2003). The main tasks in this quarter consisted of the following four parts. First, all documents for managing this project have been prepared and sent to the Office of Project Management at the US Department of Energy's (DOE's) National Energy Technology Laboratory (NETL). Second, plans for the renovation of space for a new combustion laboratory for the CFBC system has progressed smoothly. Third, considerable progress in the design of the CFBC system has been made. Finally, a lab-scale simulated fluidized-bed combustion facility has been set up in order to make some fundamental investigations of the co-firing of coal with waste materials in the next quarter. Proposed work for the next quarter has been outlined in this report.

  12. Proceedings of the sixth international conference on fluidized bed combustion. Volume II. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. The papers covered recent developments in atmospheric and pressurized fluidized-bed combustion, especially the design, operation and control of pilot and demonstration plants. The cleanup of combustion products and the erosion, corrosion and fouling of gas turbines was emphasized also. Fifty-five papers from Volume 2 of the proceedings have been entered individually into EDB and ERA; five papers had been entered previously from other sources. (LTN)

  13. Proceedings of the sixth international conference on fluidized bed combustion. Volume III. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. Forty-five papers from Vol. III of the proceedings have been entered individually into EDB and ERA. Two papers had been entered previously from other sources. (LTN)

  14. Proceedings of the Sixth International Conference on Fluidized Bed Combustion. Volume 1. Plenary sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held at the Atlanta Hilton, Atlanta, Georgia, April 9-11, 1980. The papers in this volume involved presentation of the research and development programs of the US (US DOE, TVA, EPRI and US EPA), United Kingdom, Federal Republic of Germany and the People's Republic of China. Eight papers from Vol. 1 (Plenary Sessions) of the proceedings have been entered individually into EDB and ERA. (LTN)

  15. Apparatus for high flux photocatalytic pollution control using a rotating fluidized bed reactor

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2003-06-24

    An apparatus based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. An apparatus for high-flux photocatalytic pollution control is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

  16. Design and performance of a fluidized-bed incinerator for TRU combustible wastes

    SciTech Connect (OSTI)

    Meile, L.J.; Meyer, F.G.

    1982-01-01

    Problems encountered in the incineration of glovebox generated waste at Rocky Flats Plant (RFP) led to the development of a fluidized-bed incineration (FBI) system for transuranic (TRU) combustible wastes. Laboratory and pilot-scale testing of the process preceded the installation of an 82-kg/h production demonstration incinerator at RFP. The FBI process is discussed, and the design of the demonstration incinerator is described. Operating experience and process performance for both the pilot and demonstration units are presented.

  17. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G.; Gerritsen, W.; Stewart, A.; Robinson, K.

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  18. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. ); Gerritsen, W.; Stewart, A.; Robinson, K. )

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  19. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  20. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    - OPERATIONS O F F I C E ABSTRACT Allied Chemical Corporation a t the Idaho National Engineering Labora- t o r y i s devel o p i n g 1 i q u i d-f 1 u i d i zed- bed she 1 1...

  1. Characterization of emissions from a fluidized-bed wood chip home heating furnace. Final report Apr 82-May 83

    SciTech Connect (OSTI)

    Truesdale, R.S.

    1984-03-01

    The report gives results of measurements of emissions from a residential wood-chip combustor, operated in both a fluidized-bed and cyclone-fired mode, and their comparison with those from a conventional woodstove and industrial wood-fired boilers. In general, the combustion efficiency of the fluidized-bed and cyclone-fired wood-chip burner is higher than that of conventional woodstoves. Concomitant with this increase in efficiency is a decrease in most emissions. For the fluidized-bed tests, significant reductions of total hydrocarbons and CO were observed, compared to woodstove emissions. The cyclone test showed PAH levels far below those of conventional woodstoves, approaching levels measured in industrial wood-fired boilers. A baghouse, installed during two fluidized-bed tests, was extremely effective in reducing both particulate and PAH emissions. Method 5 samples from above the fluid bed suggest that appreciable PAH is formed in the upper region of the furnace or in the watertube heat exchangers. In general, the cyclone-fired mode was more effective in reducing emissions from residential wood combustion than the fluidized-bed mode.

  2. Pressurized fluidized bed combustion low temperature cycle demonstration plant

    SciTech Connect (OSTI)

    Mukherjee, D.K.

    1984-06-01

    The merits of the turbocharged PFBC cycle are well known. Brown Boveri have been working in the past on a concept to commercialize this technology. As the leader of a team, with Foster Wheeler, Burns and Roe and Research Cottrell, Brown Boveri have conceived a turbocharged PFBC retrofit demonstration plant (20 MWe/40 MWe, net heat rate 11,000 BTU/kWh) which is discussed below. Several old power stations in the USA have small coal-fired electric generatin units which are inactive. The boilers are usually unreliable and their overhauling is uneconomical. The balance of the systems is quite often in a relatively good condition. In this retrofit concept the existing conventional boiler is replaced by a field-assembled PFBC steam generator with pneumatic feed system. It is considered that the steam turbogenerator with its complete condensing plant, together with the coal handling and the storage system can be used. The estimated total construction cost for the retrofit installation amounts to $28,000,000 for the 20 MWe and to $40,200,000 for the 40 MWe plant. This price is accurate to within plus/minus 20%. An extrapolation of these costs for a 80 MWe retrofit unit using barge transport for shop-fabricated and assembled components and applying coal-water slurry feed system result in an investment cost of $600/kW approximately. The cost of a retrofit plant looks attractive and indicates that the PFBC turbocharged cycle is economical compared to the conventional plant with FGD, as has been reported before. Improved cost prediction for a 80 MWe unit is only possible if a conceptual design is carried out.

  3. Final Environmental Impact Statement for the JEA Circulating Fluidized Bed Combustor Project

    SciTech Connect (OSTI)

    N /A

    2000-06-30

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the Clean Coal Technology Program. The project would demonstrate circulating fluidized bed (CFB) combustion technology at JEA's existing Northside Generating Station in Jacksonville, Florida, about 9 miles northeast of the downtown area of Jacksonville. The new CFB combustor would use coal and petroleum coke to generate nearly 300 MW of electricity by repowering the existing Unit 2 steam turbine, a 297.5-MW unit that has been out of service since 1983. The proposed project is expected to demonstrate emission levels of sulfur dioxide (SO{sub 2}), oxides of nitrogen (NO{sub x}), and particulate matter that would be lower than Clean Air Act limits while at the same time producing power more efficiently and at less cost than conventional coal utilization technologies. At their own risk, JEA has begun initial construction activities without DOE funding. Construction would take approximately two years and, consistent with the original JEA schedule, would be completed in December 2001. Demonstration of the proposed project would be conducted during a 2-year period from March 2002 until March 2004. In addition, JEA plans to repower the currently operating Unit 1 steam turbine about 6 to 12 months after the Unit 2 repowering without cost-shared funding from DOE. Although the proposed project consists of only the Unit 2 repowering, this EIS analyzes the Unit 1 repowering as a related action. The EIS also considers three reasonably foreseeable scenarios that could result from the no-action alternative in which DOE would not provide cost-shared funding for the proposed project. The proposed action, in which DOE would provide cost-shared finding for the proposed project, is DOE's preferred alternative. The EIS evaluates the principal environmental issues, including air quality, traffic, noise, and ecological resources, that could result from construction and operation of the proposed project. Key findings include that maximum modeled increases in ground-level concentrations of SO{sub 2} nitrogen dioxide (NO{sub 2}), and particulate matter (for the proposed project alone or in conjunction with the related action) would always be less than 10% of their corresponding standards for increases in pollutants. For potential cumulative air quality impacts, results of modeling regional sources and the proposed project indicate that the maximum 24-hour average SO{sub 2} concentration would closely approach (i.e., 97%) but not exceed the corresponding Florida standard. After the Unit 1 repowering, results indicate that the maximum 24-hour average SO{sub 2} concentration would be 91% of the Florida standard. Concentrations for other averaging periods and pollutants would be lower percentages of their standards. Regarding toxic air pollutants from the proposed project, the maximum annual cancer risk to a member of the public would be approximately 1 in 1 million; given the conservative assumptions in the estimate, the risk would probably be less. With regard to threatened and endangered species, impacts to manatees, gopher tortoises, and other species would be negligible or non-existent. Construction-induced traffic would result in noticeable congestion. In the unlikely event that all coal were transported by rail, up to 3 additional trains per week would exacerbate impacts associated with noise, vibration, and blocked roads at on-grade rail crossings. Additional train traffic could be minimized by relying more heavily on barges and ships for coal transport, which is likely to be a more economic fuel delivery mode. During construction of the proposed project, noise levels would increase from the current operational levels. Except possibly during steam blowouts and possibly during operation of equipment used to construct a nearby segment of a conveyor, construction noise should not appreciably affect the background noise of nearby residences or exceed local nois

  4. The Lakeland McIntosh Unit 4 demonstration project utilizing Foster Wheeler`s pressurized circulating fluidized-bed combustion technology

    SciTech Connect (OSTI)

    McClung, J.D.; Provol, S.J.; Morehead, H.T.; Dodd, A.M.

    1997-12-31

    The City of Lakeland, Florida, Foster Wheeler and the Westinghouse Electric Corporation have embarked on the demonstration of a Clean Coal Technology at the City of Lakeland`s McIntosh Power Station in lakeland, Polk County, Florida. The project will demonstrate the Pressurized Circulating Fluidized Bed Combustion (PCFB) technology developed by Foster Wheeler and Westinghouse. The Lakeland McIntosh Unit 4 Project is a nominal 170 MW power plant designed to burn a range of low- to high-sulfur coals. The combined cycle plant employs a Westinghouse 251B12 gas turbine engine in conjunction with a steam turbine operating in a 2400/1000/1000 steam cycle. The plant will demonstrate both the PCFB and topped PCFB combustion technologies. This paper provides a process description of the Foster Wheeler PCFB and Topped PCFB technologies and their application to the Lakeland McIntosh Unit 4 Project.

  5. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume V. Appendix: stability and instability in fluidized-bed combustion

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the fifth of the seven volumes series of our Phase II Final Report. The material developed in this volume has not been incorporated into the system model. It will be used as a precursor of a transient model to be developed in the next phase of our model work. There have been various fluidized combustor models of differing complexity and scope published in the literature. Most of these models have identified and predicted - often in satisfactory agreement with results from pilot units - the key steady state combustor characteristics such as the mass of carbon in the bed (carbon loading), the combustion efficiency, the sulfur retention by the solid sorbent and the pollutant (mainly NO/sub x/) emissions. These models, however, cannot be in most instances successfully used to study the extinction and ignition characteristics of the combustor because they are isothermal in structure in the sense that the bed temperature is not an output variable but rather an input one and must be a priori specified. In order to remedy these inadequacies of the previous models, we here present a comprehensive account of the formulation and some typical results of a new nonisothermal model which has been developed in order to study, among other things, the ignition and extinction characteristics of the AFBC units. This model is able to predict the temperature patterns in the bed, the carbon loading, the combustion efficiency and the O/sub 2/ and CO concentration profiles in the combustor for the different design or operational characteristics.

  6. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    SciTech Connect (OSTI)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles. It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.

  7. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tingwen; Dietiker, Jean-François; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numericalmore » results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.« less

  8. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    SciTech Connect (OSTI)

    Li, Tingwen; Dietiker, Jean-Franois; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numerical results show that CFD can predict the complex gassolids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.

  9. Simulation of NOx emission in circulating fluidized beds burning low-grade fuels

    SciTech Connect (OSTI)

    Afsin Gungor

    2009-05-15

    Nitrogen oxides are a major environmental pollutant resulting from combustion. This paper presents a modeling study of pollutant NOx emission resulting from low-grade fuel combustion in a circulating fluidized bed. The simulation model accounts for the axial and radial distribution of NOx emission in a circulating fluidized bed (CFB). The model results are compared with and validated against experimental data both for small-size and industrial-size CFBs that use different types of low-grade fuels given in the literature. The present study proves that CFB combustion demonstrated by both experimental data and model predictions produces low and acceptable levels of NOx emissions resulting from the combustion of low-grade fuels. Developed model can also investigate the effects of different operational parameters on overall NOx emission. As a result of this investigation, both experimental data and model predictions show that NOx emission increases with the bed temperature but decreases with excess air if other parameters are kept unchanged. 37 refs., 5 figs., 5 tabs.

  10. Two stage, low temperature, catalyzed fluidized bed incineration with in situ neutralization for radioactive mixed wastes

    SciTech Connect (OSTI)

    Wade, J.F.; Williams, P.M.

    1995-05-17

    A two stage, low temperature, catalyzed fluidized bed incineration process is proving successful at incinerating hazardous wastes containing nuclear material. The process operates at 550{degrees}C and 650{degrees}C in its two stages. Acid gas neutralization takes place in situ using sodium carbonate as a sorbent in the first stage bed. The feed material to the incinerator is hazardous waste-as defined by the Resource Conservation and Recovery Act-mixed with radioactive materials. The radioactive materials are plutonium, uranium, and americium that are byproducts of nuclear weapons production. Despite its low temperature operation, this system successfully destroyed poly-chlorinated biphenyls at a 99.99992% destruction and removal efficiency. Radionuclides and volatile heavy metals leave the fluidized beds and enter the air pollution control system in minimal amounts. Recently collected modeling and experimental data show the process minimizes dioxin and furan production. The report also discusses air pollution, ash solidification, and other data collected from pilot- and demonstration-scale testing. The testing took place at Rocky Flats Environmental Technology Site, a US Department of Energy facility, in the 1970s, 1980s, and 1990s.

  11. Method of removing sulfur emissions from a fluidized-bed combustion process

    DOE Patents [OSTI]

    Vogel, Gerhard John (Elmhurst, IL); Jonke, Albert A. (Elmhurst, IL); Snyder, Robert B. (Naperville, IL)

    1978-01-01

    Alkali metal or alkaline earth metal oxides are impregnated within refractory support material such as alumina and introduced into a fluidized-bed process for the combustion of coal. Sulfur dioxide produced during combustion reacts with the metal oxide to form metal sulfates within the porous support material. The support material is removed from the process and the metal sulfate regenerated to metal oxide by chemical reduction. Suitable pore sizes are originally developed within the support material by heat-treating to accommodate both the sulfation and regeneration while still maintaining good particle strength.

  12. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Zhongxian Cheng; Yan Cao; John Smith

    2006-09-30

    This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2006 through September 30, 2006. The following activities have been completed: the steel floor grating around the riser in all levels and the three-phase power supply for CFBC System was installed. Erection of downcomers, loop seals, ash bunker, thermal expansion joints, fuel and bed material bunkers with load cells, rotary air-lock valves and fuel flow monitors is underway. Pilot-scale slipstream tests conducted with bromine compound addition were performed for two typical types of coal. The purposes of the tests were to study the effect of bromine addition on mercury oxidization. From the test results, it was observed that there was a strong oxidization effect for Powder River Basin (PRB) coal. The proposed work for next quarter and project schedule are also described.

  13. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  14. Comminution phenomena during the fluidized bed combustion of a commercial refuse-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A.; Chirone, R.; D`Anna, G.

    1995-12-31

    A commercial densified refuse-derived fuel (RDF), obtained as pellets from municipal solid wastes, was burned in two laboratory scale bubbling fluidized bed combustors, having an internal diameter of 41 mm. The apparatus were both batchwise operated at 850 C by injecting batches of RDF particles into a bed of silica sand (300--400 {micro}m as size range) fluidized at a superficial gas velocity of 0.8 m/s. RDF particles with equivalent mean diameter ranging from 4 to 9 mm were used. Different experimental procedures were set up to separately investigate comminution phenomena of fuel particles. Results were compared with those obtained burning a South African bituminous coal. Results pointed out that RDF particles undergo a strong primary fragmentation phenomenon, with a probability of particle breakage equal to 1 for fuel particles larger than 6 mm. Attrition and char fragmentation phenomena are particularly relevant under both inert and oxidizing conditions, generating a large amount of unburned fines which may affect overall combustion efficiency.

  15. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan, Kunlei Liu; John T. Riley

    2004-07-30

    This report presents the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the quarter April 1--June 30, 2004. The following tasks have been completed. First, the final specifications for the renovation of the new Combustion Laboratory and the construction of the CFB Combustor Building have been delivered to the architect, and invitations for construction bids for the two tasks have been released. Second, the component parts of the CFBC system have been designed after the design work for assembly parts of the CFBC system was completed. Third, the literature pertaining to Polychlorinated Dibenzo-p-Dioxins (PCDD) and Polychlorinated Dibenzofurans (PCDF) released during the incineration of solid waste, including municipal solid waste (MSW) and refuse-derived fuel (RDF) have been reviewed, and an experimental plan for fundamental research of MSW incineration on a simulated fluidized-bed combustion (FBC) facility has been prepared. Finally, the proposed work for the next quarter has been outlined in this report.

  16. Predictive models of circulating fluidized bed combustors. 12th technical progress report

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  17. Solids circulation around a jet in a fluidized bed gasifier. Final technical report, September 1, 1978-September 30, 1980

    SciTech Connect (OSTI)

    Gidaspow, D.; Ettehadieh, B.; Lin, C.; Goyal, A.; Lyczkowski, R.W.

    1980-01-01

    The object of this investigation was to develop an experimentally verified hydrodynamic model to predict solids circulation around a jet in a fluidized bed gasifier. Hydrodynamic models of fluidization use the principles of conservation of mass, momentum and energy. To account for unequal velocities of solid and fluid phases, separate phase momentum balances are developed. Other fluid bed models used in the scale-up of gasifiers do not employ the principles of conservation of momentum. Therefore, these models cannot predict fluid and particle motion. In such models solids mixing is described by means of empirical transfer coefficients. A two dimensional unsteady state computer code was developed to give gas and solid velocities, void fractions and pressure in a fluid bed with a jet. The growth, propagation and collapse of bubbles was calculated. Time-averaged void fractions were calculated that showed an agreement with void fractions measured with a gamma ray densitometer. Calculated gas and solid velocities in the jet appeared to be reasonable. Pressure and void oscillations also appear to be reasonable. A simple analytical formula for the rate of solids circulation was developed from the equations of change. It agrees with Westinghouse fluidization data in a bed with a draft tube. One dimensional hydrodynamic models were applied to modeling of entrained-flow coal gasification reactors and compared with data. Further development of the hydrodynamic models should make the scale-up and simulation of fluidized bed reactors a reality.

  18. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke

    2001-10-12

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels.

  19. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Tom Steitz

    2002-07-12

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives.

  20. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke; Joseph J. Battista

    2001-03-31

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Services, Inc., and Cofiring Alternatives.

  1. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles.more » It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.« less

  2. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  3. Continuous Ethanol Production Using Immobilized-Cell/Enzyme Biocatalysts in Fluidized-Bed Bioreactor (FBR)

    SciTech Connect (OSTI)

    Nghiem, NP

    2003-11-16

    The immobilized-cell fluidized-bed bioreactor (FBR) was developed at Oak Ridge National Laboratory (ORNL). Previous studies at ORNL using immobilized Zymomonas mobilis in FBR at both laboratory and demonstration scale (4-in-ID by 20-ft-tall) have shown that the system was more than 50 times as productive as industrial benchmarks (batch and fed-batch free cell fermentations for ethanol production from glucose). Economic analysis showed that a continuous process employing the FBR technology to produce ethanol from corn-derived glucose would offer savings of three to six cents per gallon of ethanol compared to a typical batch process. The application of the FBR technology for ethanol production was extended to investigate more complex feedstocks, which included starch and lignocellulosic-derived mixed sugars. Economic analysis and mathematical modeling of the reactor were included in the investigation. This report summarizes the results of these extensive studies.

  4. Rocky Flats Plant fluidized-bed incinerator. Engineering design and reference manual

    SciTech Connect (OSTI)

    Meile, L.J.

    1982-11-05

    The information in this manual is being presented to complete the documentation of the fluidized-bed incineration (FBI) process development at the Rocky Flats Plant. The information pertains to the 82-kg/hour demonstration unit at the Rocky Flats Plant. This document continues the presentation of design reference material in the aeas of equipment drawings, space requirements, and unit costs. In addition, appendices contain an operating procedure and an operational safety analysis of the process. The cost figures presented are based on 1978 dollars and have not been converted to a current dollar value. Also, the cost of modifications are not included, since they would be insignificant if they were incorporated into a new installation.

  5. Development of a trial burn plan for a mixed waste fluidized bed incinerator

    SciTech Connect (OSTI)

    Kabot, F.J.; Ziegler, D.L.

    1988-01-01

    One of the more important elements of the incinerator permitting process under RCRA is the development of the Trial Burn Plan. This document describes the incinerator and defines the incinerator's process envelope within which the trial burns will be conducted. The data obtained during the trial burns will be the basis for the incinerator's operating permit. This paper describes the development of the Trial Burn Plan for a unique fluidized bed incinerator to be used for the incineration of hazardous and mixed wastes at the Department of Energy's Rocky Flats Plant. It describes a review process of the Trial Burn Plan involving a public comment period that actually preceded the trial burns. 2 refs., 1 fig.

  6. Process for generating electricity in a pressurized fluidized-bed combustor system

    DOE Patents [OSTI]

    Kasper, Stanley (Pittsburgh, PA)

    1991-01-01

    A process and apparatus for generating electricity using a gas turbine as part of a pressurized fluidized-bed combustor system wherein coal is fed as a fuel in a slurry in which other constituents, including a sulfur sorbent such as limestone, are added. The coal is combusted with air in a pressurized combustion chamber wherein most of the residual sulfur in the coal is captured by the sulfur sorbent. After particulates are removed from the flue gas, the gas expands in a turbine, thereby generating electric power. The spent flue gas is cooled by heat exchange with system combustion air and/or system liquid streams, and the condensate is returned to the feed slurry.

  7. Apparatus, components and operating methods for circulating fluidized bed transport gasifiers and reactors

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2015-02-24

    The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed "transport gasifier." The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

  8. Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant

    DOE Patents [OSTI]

    Cole, Rossa W. (E. Rutherford, NJ); Zoll, August H. (Cedar Grove, NJ)

    1982-01-01

    In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

  9. Data summary of municipal solid waste management alternatives. Volume 5, Appendix C, Fluidized-bed combustion

    SciTech Connect (OSTI)

    1992-10-01

    This appendix provides information on fluidized-bed combustion (FBC) technology as it has been applied to municipal waste combustion (MWC). A review of the literature was conducted to determine: (1) to what extent FBC technology has been applied to MWC, in terms of number and size of units was well as technology configuration; (2) the operating history of facilities employing FBC technology; and (3) the cost of these facilities as compared to conventional MSW installations. Where available in the literature, data on operating and performance characteristics are presented. Tabular comparisons of facility operating/cost data and emissions data have been complied and are presented. The literature review shows that FBC technology shows considerable promise in terms of providing improvements over conventional technology in areas such as NOx and acid gas control, and ash leachability. In addition, the most likely configuration to be applied to the first large scale FBC dedicated to municipal solid waste (MSW) will employ circulating bed (CFB) technology. Projected capital costs for the Robbins, Illinois 1600 ton per day CFB-based waste-to-energy facility are competitive with conventional systems, in the range of $125,000 per ton per day of MSW receiving capacity.

  10. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, J.

    1996-02-20

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  11. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  12. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Quarterly report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-01-01

    This technical report summarizes the research work performed and progress achieved during the period of October 1, 1995 to December 31, 1995. A series of material wastage tests was carried out on cooled AISI 1018 steel and three thermal-sprayed coating specimens at an elevated environmental temperature (3000{degrees}C) using a nozzle type erosion tester. Test conditions simulated the erosion conditions at the in-bed tubes of fluidized combustors (FBCs). Angular silica quartz particles of average size 742 {micro}m were used for erodent particles for tests at an impact angle of 30{degrees}, at a particle velocity of 2.5 m/s for exposure periods up to 96 hours. The specimens were water-cooled on backside. Material wastage rates were determined from thickness loss measurements of specimens. Test results were compared with material wastage test results from testing isothermal specimens. The morphology of specimens was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It was found that the cooled specimens had greater material wastage than that of the isothermal specimens. The material wastage rate of cooling specimen for AISI 1018 was greater than that for thermal- sprayed coatings. The success in reduction of erosion wastage by cooled-coating specimens was related to the coatings, composition and morphology.

  13. Process steam production from cotton gin trash

    SciTech Connect (OSTI)

    LePori, W.A.; Carney, D.B.; Lalk, T.R.; Anthony, R.G.

    1981-01-01

    A steam producing system based on fluidized-bed gasification of biomass materials is discussed. Limited experimental results are discussed and show that steam has been produced at rates of 334.3 kg/hr. (737 lbs/hr.) with 2.8 kg of stream produced for each kilogram of cotton gin trash (2.8 lb/lb.). ref.

  14. Design considerations and operating experience in firing refuse derived fuel in a circulating fluidized bed combustor

    SciTech Connect (OSTI)

    Piekos, S.J.; Matuny, M.

    1997-12-31

    The worldwide demand for cleaner, more efficient methods to dispose of municipal solid waste has stimulated interest in processing solid waste to produce refuse derived fuel (RDF) for use in circulating fluidized bed (CFB) boilers. The combination of waste processing and materials recovery systems and CFB boiler technology provides the greatest recovery of useful resources from trash and uses the cleanest combustion technology available today to generate power. Foster Wheeler Power Systems along with Foster Wheeler Energy Corporation and several other Foster Wheeler sister companies designed, built, and now operates a 1600 tons per day (TPD) (1450 metric tons) municipal waste-to-energy project located in Robbins, Illinois, a suburb of Chicago. This project incorporates waste processing systems to recover recyclable materials and produce RDF. It is the first project in the United States to use CFB boiler technology to combust RDF. This paper will provide an overview of the Robbins, Illinois waste-to-energy project and will examine the technical and environmental reasons for selecting RDF waste processing and CFB combustion technology. Additionally, this paper will present experience with handling and combusting RDF and review the special design features incorporated into the CFB boiler and waste processing system that make it work.

  15. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  16. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  17. Engineering systems analysis of pressurized fluidized-bed-combustion power systems

    SciTech Connect (OSTI)

    Graves, R.L.; Griffin, F.P.; Lackey, M.E.

    1982-04-01

    This effort was conducted to provde supporting data for the research and development program on pressurized fluidized bed combustor (PFBC) systems being continued under the auspices of the Office of Coal Utilization of DOE. This report deals with the first phase of the effort, designated Task 1, which was scoped to be a somewhat broad review of PFBC technology and an analysis to determine its potential and sensitivity to key development needs. Background information pertaining to the application of PFBC to the market for coal-fired technology is included. The status of development is reviewed and the deficiencies in data are identified. Responses to a survey of PFBC developers are reviewed with emphasis on the high risk areas of the PFBC concept. Some of these problems are: uncertainty of life of gas turbine components; lack of demonstration of load following; and hot solids handling. Some high risk areas, such as the gas cleanup or gas turbine systems, can be relieved by reducing the severity of design conditions such as the turbine inlet temperature. Alternate turbine designs or plant configurations are also possible solutions. Analyses were performed to determine whether the advantages held by PFBC systems in cost, efficiency, and emissions would be nullified by measures taken to reduce risk. In general, the results showed that the attractive features of the PFBC could be preserved.

  18. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  19. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; John Smith

    2008-05-31

    On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new particulate filtration technologies. Major tasks during this period of the funded project's timeframe included: (1) Conducting pretests on a laboratory-scale simulated FBC system; (2) Completing detailed design of the bench-scale CFBC system; (3) Contracting potential bidders to fabricate of the component parts of CFBC system; (4) Assembling CFBC parts and integrating system; (5) Resolving problems identified during pretests; (6) Testing with available Powder River Basin (PRB) coal and co-firing of PRB coal with first wood pallet and then chicken wastes; and (7) Tuning of CFBC load. Following construction system and start-up of this 0.6 MW CFBC system, a variety of combustion tests using a wide range of fuels (high-sulfur coals, low-rank coals, MSW, agricultural waste, and RDF) under varying conditions were performed to analyze and monitor air pollutant emissions. Data for atmospheric pollutants and the methodologies required to reduce pollutant emissions were provided. Integration with a selective catalytic reduction (SCR) slipstream unit did mimic the effect of flue gas composition, including trace metals, on the performance of the SCR catalyst to be investigated. In addition, the following activities were also conducted: (1) Developed advanced mercury oxidant and adsorption additives; (2) Performed laboratory-scale tests on oxygen-fuel combustion and chemical looping combustion; and (3) Conducted statistical analysis of mercury emissions in a full-scale CFBC system.

  20. Pressurized fluidized-bed hydroretorting of Eastern oil shales. Annual report, June 1991--May 1992

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S.; Schultz, C.W.; Parekh, B.K.; Misra, M.; Bonner, W.P.

    1992-11-01

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  1. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  2. Coal pyrolysis by hot solids from a fluidized-bed combustor. Final technical report, June 1977-June 1982

    SciTech Connect (OSTI)

    Longwell, J.P.; Evans, L.B.; Howard, J.B.; Peters, W.A.; Floess, J.K.; Fong, L.; Chen, C.; Yeboah, J.

    1982-06-01

    The effect of adding calcined dolomite stone to the fluidized-bed pyrolysis of coal and oil shale on product quality and product distribution has been studied. This work has provided information relevant to systems where heat is generated by fluidized-bed combustion in the presence of a sulfur acceptor (dolomite) and where the hot stone from the combustor is used in a second reactor to provide heat for pyrolysis. A scoping economic analysis indicated that, for coal, the pyrolysis gas and liquids produced are lower cost than gas and liquids produced by single-product gasification and liquefaction processes. The presence of calcium oxide during pyrolysis was found to improve gas heating value by CO/sub 2/ removal and to essentially eliminate H/sub 2/S. Gas yield was increased at the expense of liquid yield (20 to 30% reduction). Tar properties were improved by reduction of oxygen content, however, little sulfur or nitrogen removal was observed. Used stone from a fluidized-bed combustor gave results comparable to fresh stone with little reduction of the calcium sulfate present in the used stone. Since Colorado oil shale contains dolomite and calcite, stones from spent-shale combustion might be expected to have similar effects on product yields. CO/sub 2/ and H/sub 2/S removal from the gas were observed. Fortunately, liquid yields were not reduced within the 5% experimental error of this work. It is indicated that CaO tends to remove phenols and polycyclic aromatics which are present in much lower concentration in shale oil than in coal tar.

  3. Pebble Bed Boiling Water Reactor Concept With Superheated Steam

    SciTech Connect (OSTI)

    Tsiklauri, G.; Newman, D.; Meriwether, G.; Korolev, V. [Pacific Northwest National Laboratory, P.O. Box 999 Richland, WA 99352 (United States)

    2002-07-01

    An Advanced Nuclear Reactor concept is presented which extends Boiling Water Reactor technology with micro-fuel elements (MFE) and produces superheated steam. A nuclear plant with MFE is highly efficient and safe, due to ceramic-clad nuclear fuel. Water is used as both moderator and coolant. The fuel consists of spheres of about 1.5 mm diameter of UO{sub 2} with several external coatings of different carbonaceous materials. The outer coating of the particles is SiC, manufactured with chemical vapor disposition (CVD) technology. Endurance of the integrity of the SiC coating in water, air and steam has been demonstrated experimentally in Germany, Russia and Japan. This paper describes a result of a preliminary design and analysis of 3750 MWt (1500 MWe) plant with standard pressure of 16 MPa, which is widely achieved in the vessel of pressurized-water type reactors. The superheated steam outlet temperature of 550 deg. C elevates the steam cycle to high thermal efficiency of 42%. (authors)

  4. Functionalization of polymers using an atmospheric plasma jet in a fluidized bed reactor and the impact on SLM-processes

    SciTech Connect (OSTI)

    Sachs, M. Schmitt, A. Schmidt, J. Peukert, W. Wirth, K-E

    2014-05-15

    In order to improve thermoplastics (e.g. Polyamide, Polypropylene and Polyethylene) for Selective Laser Beam Melting (SLM) processes a new approach to functionalize temperature sensitive polymer powders in a large scale is investigated. This is achieved by combining an atmospheric pressure plasma jet and a fluidized bed reactor. Using pressurized air as the plasma gas, radicals like OH* are created. The functionalization leads to an increase of the hydrophilicity of the treated polymer powder without changing the bulk properties. Using the polymers in a SLM process to build single layers of melted material leads to an improvement of the melted layers.

  5. Combustion of liquid paint wastes in fluidized bed boiler as element of waste management system in the paint factory

    SciTech Connect (OSTI)

    Soko, W.A.; Biaecka, B.

    1998-12-31

    In this paper the solution to waste problems in the paint industry is presented by describing their combustion in a fluidized bed boiler as a part of the waste management system in the paint factory. Based on the Cleaner Production idea and concept of integration of design process with a future exploitation of equipment, some modifications of the waste management scheme in the factory are discussed to reduce the quantity of toxic wastes. To verify this concept combustion tests of paint production wastes and cocombustion of paint wastes with coal in an adopted industrial boiler were done. Results of these tests are presented in the paper.

  6. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R.; Reuther, R.B.; Bonk, D.L.

    1996-09-01

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  7. Distribution of polycyclic aromatic hydrocarbons in fly ash during coal and residual char combustion in a pressurized fluidized bed

    SciTech Connect (OSTI)

    Hongcang Zhou; Baosheng Jin; Rui Xiao; Zhaoping Zhong; Yaji Huang

    2009-04-15

    To investigate the distribution of polycyclic aromatic hydrocarbons (PAHs) in fly ash, the combustion of coal and residual char was performed in a pressurized spouted fluidized bed. After Soxhlet extraction and Kuderna-Danish (K-D) concentration, the contents of 16 PAHs recommended by the United States Environmental Protection Agency (U.S. EPA) in coal, residual char, and fly ash were analyzed by a high-performance liquid chromatography (HPLC) coupled with fluorescence and diode array detection. The experimental results show that the combustion efficiency is lower and the carbon content in fly ash is higher during coal pressurized combustion, compared to the residual char pressurized combustion at the pressure of 0.3 MPa. Under the same pressure, the PAH amounts in fly ash produced from residual char combustion are lower than that in fly ash produced from coal combustion. The total PAHs in fly ash produced from coal and residual char combustion are dominated by three- and four-ring PAHs. The amounts of PAHs in fly ash produced from residual char combustion increase and then decrease with the increase of pressure in a fluidized bed. 21 refs., 1 fig., 4 tabs.

  8. Energy and environmental research emphasizing low-rank coal -- Task 3.8, Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Mann, M.D.; Henderson, A.K.; Swanson, M.L.

    1995-03-01

    The goal of the PFBC activity is to generate fundamental process information that will further the development of an economical and environmentally acceptable second-generation PFBC. The immediate objectives focus on generic issues, including the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals in PFBC. A great deal of PFBC performance relates to the chemistry of the bed and the contact between gas and solids that occurs during combustion. These factors can be studied in a suitably designed bench-scale reactor. The present studies are focusing on the emission control strategies applied in the bed, rather than in hot-gas cleaning. Emission components include alkali and heavy metals in addition to SO{sub 2}, NO{sub x}, N{sub 2}O, and CO. The report presents: a description of the pressurized fluidized-bed reactor (PFBR); a description of the alkali sampling probe; shakedown testing of the bench-scale PFBR; results from alkali sampling; results from sulfur sorbent performance tests; and results from refuse-derived fuel and lignite combustion tests.

  9. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume 1. Model evolution and development

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The Energy Laboratory of the Massachusetts Institute of Technology (M.I.T.), under Department of Energy (DOE) sponsorship, has been engaged in the development of a comprehensive mechanistic model of Fluidized Bed Combustors (FBC). The primary aims of this modeling effort are the generation and to the extent possible, validation of an analytical framework for the design and scale-up of fluidized bed combustors. In parallel with this modeling effort, M.I.T. also embarked upon the development of an FBC-Data Base Management System (FBC-DBMS) aimed at facilitating the coordination, interpretation and utilization of the experimental data that are or will become available from diverse sources, as well as in the identification of areas of large uncertainty or having a paucity of experimental results. The synergistic operation of the FBC-Model and FBC-Data Base promises to offer a powerful tool for the design and optimization of FBC's and represents the ultimate goal of the M.I.T. effort. The modeling effort was initially focused upon evaluation and application of state-of-the-art models. The initial system model was divided into five basic components: fluid dynamics, combustion, sulfur capture, heat transfer and emissions. Due to the technical complexity of modeling FBC operation and the initial primitive nature of models for these components, it was deemed necessary to be able to incorporate evolutionary improvements in understanding and correlating FBC phenomena: the M.I.T. system model is, therefore, modular in nature, i.e., each sub-model can be replaced by an updated or equivalent sub-model without necessitating reprogramming of the entire system model.

  10. The Nucla Circulating Fluidized-Bed Demonstration Project: A U.S. DOE post-project assessment

    SciTech Connect (OSTI)

    1995-06-01

    This report is a post-project assessment of the Nucla Circulating Fluidized-Bed (CFB) Demonstration Project, the second project to be completed in the DOE Clean Coal Technology Program. Nucla was the first successful utility repowering project in the US, increasing the capacity of the original power station from 36 MW(e) to 110 MW(e) and extending its life by 30 years. In the CFB boiler, combustion and desulfurization both take place in the fluidized bed. Calcium in the sorbent captures sulfur dioxide and the relatively low combustion temperatures limit NOx formation. Hot cyclones separate the larger particles from the gas and recirculates them to the lower zones of the combustion chambers. This continuous circulation of coal char and sorbent particles is the novel feature of CFB technology. This demonstration project significantly advanced the environmental, operational, and economic potential of atmospheric CFB technology, precipitating a large number of orders for atmospheric CFB equipment. By 1994, more than 200 atmospheric CFB boilers have been constructed worldwide. Although at least six CFB units have been operated, the Nucla project`s CFB database continues to be an important and unique resource for the design of yet larger atmospheric CFB systems. The post-project assessment report is an independent DOE appraisal of the success a completed project had in achieving its objectives and aiding in the commercialization of the demonstrated technology. The report also provides an assessment of the expected technical, environmental, and economic performance of the commercial version of the technology as well as an analysis of the commercial market.

  11. Attrition resistant fluidizable reforming catalyst

    DOE Patents [OSTI]

    Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

    2011-03-29

    A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

  12. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    1982-10-21

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  13. Technical and economic assessment of fluidized bed augmented compressed air energy-storage system. Volume II. Introduction and technology assessment

    SciTech Connect (OSTI)

    Giramonti, A.J.; Lessard, R.D.; Merrick, D.; Hobson, M.J.

    1981-09-01

    The results are described of a study subcontracted by PNL to the United Technologies Research Center on the engineering feasibility and economics of a CAES concept which uses a coal fired, fluidized bed combustor (FBC) to heat the air being returned from storage during the power production cycle. By burning coal instead of fuel oil, the CAES/FBC concept can completely eliminate the dependence of compressed air energy storage on petroleum fuels. The results of this assessment effort are presented in three volumes. Volume II presents a discussion of program background and an in-depth coverage of both fluid bed combustion and turbomachinery technology pertinent to their application in a CAES power plant system. The CAES/FBC concept appears technically feasible and economically competitive with conventional CAES. However, significant advancement is required in FBC technology before serious commercial commitment to CAES/FBC can be realized. At present, other elements of DOE, industrial groups, and other countries are performing the required R and D for advancement of FBC technology. The CAES/FBC will be reevaluated at a later date when FBC technology has matured and many of the concerns now plaguing FBC are resolved. (LCL)

  14. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  15. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume II. Detailed description of the model

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the second of a seven volume series of our Phase II Final Report. This volume deals with detailed descriptions of the structure of each program member (subroutines and functions), the interrelation between the members of a submodel, and the interrelation between the various submodels as such. The systems model for fluidized bed combustors (FBC-II) consists of a systematic combination of the following interrelated areas: fluid mechanics and bubble growth, char combustion and associated kinetics for particle burnout, sulfur capture, NO/sub x/ formation and reduction, freeboard reactions, and heat transfer. Program outline is shown in Figure 1.1. Input variables (supplied by the user are inspected to check that they lie inside the allowed range of values and are input to the various routines as needed. The necessary physical and fluid mechanical properties are calculated and utilized in estimating char combustion and sulfur capture in the bed and the freeboard. NO/sub x/ and CO emissions are estimated by taking into account all relevant chemical reactions. A material and energy balance is made over the bed. Figure 1.1 shows a block diagram of the systems program. In this diagram, the overall structure of the FBC program is illustrated in terms of the various submodels that together constitute the systems program. A more detailed outline of the systems program is shown in Figure 1.2. In this figure, all important subroutine members of the FBC program are shown, and their linkage to each other, as well as to the main program is indicated. A description of the exact sequence in which these various routines are called at time of program execution is provided in Chapter 8 under the executive routine MAIN.

  16. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  17. High-temperature-staged fluidized-bed combustion (HITS), bench scale experimental test program conducted during 1980. Final report

    SciTech Connect (OSTI)

    Anderson, R E; Jassowski, D M; Newton, R A; Rudnicki, M L

    1981-04-01

    An experimental program was conducted to evaluate the process feasibility of the first stage of the HITS two-stage coal combustion system. Tests were run in a small (12-in. ID) fluidized bed facility at the Energy Engineering Laboratory, Aerojet Energy Conversion Company, Sacramento, California. The first stage reactor was run with low (0.70%) and high (4.06%) sulfur coals with ash fusion temperatures of 2450/sup 0/ and 2220/sup 0/F, respectively. Limestone was used to scavenge the sulfur. The produced low-Btu gas was burned in a combustor. Bed temperature and inlet gas percent oxygen were varied in the course of testing. Key results are summarized as follows: the process was stable and readily controllable, and generated a free-flowing char product using coals with low (2220/sup 0/F) and high (2450/sup 0/F) ash fusion temperatures at bed temperatures of at least 1700/sup 0/ and 1800/sup 0/F, respectively; the gaseous product was found to have a total heating value of about 120 Btu/SCF at 1350/sup 0/F, and the practicality of cleaning the hot product gas and delivering it to the combustor was demonstrated; sulfur capture efficiencies above 80% were demonstrated for both low and high sulfur coals with a calcium/sulfur mole ratio of approximately two; gasification rates of about 5,000 SCF/ft/sup 2/-hr were obtained for coal input rates ranging from 40 to 135 lbm/hr, as required to maintain the desired bed temperatures; and the gaseous product yielded combustion temperatures in excess of 3000/sup 0/F when burned with preheated (900/sup 0/F) air. The above test results support the promise of the HITS system to provide a practical means of converting high sulfur coal to a clean gas for industrial applications. Sulfur capture, gas heating value, and gas production rate are all in the range required for an effective system. Planning is underway for additional testing of the system in the 12-in. fluid bed facility, including demonstration of the second stage char burnup reactor.

  18. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke

    2001-07-13

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences, Foster Wheeler Energy Services, Inc., Parsons Energy and Chemicals Group, Inc., and Cofiring Alternatives. During this reporting period, work focused on completing the biofuel characterization and the design of the conceptual fluidized bed system.

  19. Method and apparatus for gasifying with a fluidized bed gasifier having integrated pretreating facilities

    DOE Patents [OSTI]

    Rice, Louis F. (Arcadia, CA)

    1981-01-01

    An integral gasifier including a pretreater section and a gasifier section separated by a distribution grid is defined by a single vessel. The pretreater section pretreats coal or other carbon-containing material to be gasified to prevent caking and agglomeration of the coal in the gasifier. The level of the coal bed of the pretreater section and thus the holding or residence time in said bed is selectively regulated by the amount of pretreated coal which is lifted up a lift pipe into the gasifier section. Thus, the holding time in the pretreater section can be varied according to the amount of pretreat necessary for the particular coal to be gasified.

  20. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect (OSTI)

    DeLallo, M.; Zaharchuk, R.

    1994-01-01

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  1. Multiphase flow simulations of a moving fluidized bed regenerator in a carbon capture unit

    SciTech Connect (OSTI)

    Sarkar, Avik; Pan, Wenxiao; Suh, Dong-Myung; Huckaby, E. D.; Sun, Xin

    2014-10-01

    To accelerate the commercialization and deployment of carbon capture technologies, computational fluid dynamics (CFD)-based tools may be used to model and analyze the performance of carbon capture devices. This work presents multiphase CFD-based flow simulations for the regeneration device responsible for extracting CO2 from CO2-loaded sorbent particles before the particles are recycled. The use of solid particle sorbents in this design is a departure from previously reported systems, where aqueous sorbents are employed. Another new feature is the inclusion of a series of perforated plates along the regenerator height. The influence of these plates on sorbent distribution is examined for varying sorbent holdup, fluidizing gas velocity, and particle size. The residence time distribution of sorbents is also measured to classify the low regime as plug flow or well-mixed flow. The purpose of this work is to better understand the sorbent flow characteristics before reaction kinetics of CO2 desorption can be implemented.

  2. Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents

    SciTech Connect (OSTI)

    Gupta, R.P.; Turk, B.S.; Gangwal, S.K.

    1996-12-31

    Successful development of regenerable mixed-metal oxide sorbents for removal of reduced sulfur species (such as H{sub 2}S and COS) from coal-derived fuel gas streams at high=temperature, high-pressure (HTHP) conditions is a key to commercialization of the integrated-gasification-combined-cycle (IGCC) power systems. Among the various available coal-to-electricity pathways, IGCC power plants have the most potential with high thermal efficiency, simple system configuration, low emissions of SO{sub 2}, NO{sub x} and other contaminants, modular design, and low capital cost. Due to these advantages, the power plants of the 21st century are projected to utilize IGCC technology worldwide. Sorbents developed for sulfur removal are primarily zinc oxide-based inorganic materials, because of their ability to reduce fuel gas sulfur level to a few parts-per-million (ppm). This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. Specific objectives are to develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{mu}m particle size range for transport reactor applications using semicommercial- to full commercial-scale spray dryers, to transfer sorbent production technology to private sector, and to provide technical support for Sierra Pacific`s Clean Coal Technology Demonstration plant and METC`s hot-gas desulfurization process development unit (PDU), both employing a transport reactor system.

  3. Fluidized-bed copper oxide process. Phase IV. Conceptual design and economic evaluation, Volume I. Final report

    SciTech Connect (OSTI)

    1994-11-30

    Universal Oil Products, Inc. (UOP) of Des Plaines, Illinois has contracted A.E. Roberts & Associates, Inc. (AERA) of Atlanta, Georgia to prepare a sensitivity analysis for the development of the Fluidized-bed Copper Oxide (FBCO) process. As proposed by AERA in September 1991, development of the FBCO process design for a 500 mega-watt (MW) unit was divided into three tasks: (1) Establishment of a Conceptual Design, (2) Conceptual Design, (3) Cost Analysis Task 1 determined the basis for a conceptual design for the 500 megawatt (MW) FBCO process. It was completed by AERA in September of 1992, and a report was submitted at that time {open_quotes}Establishment of the Design Basis for Application to a 500 MW Coal-fired Facility.{close_quotes} Task 2 gathered all pertinent data available to date and reviewed its applicability to the 500 MW FBCO process. Work on this task was carried out on a joint basis by the AERA team members: Roberts & Schaefers worked on the dense phase transport aspect of the design; Cornell and Carnegie Mellon Universities worked on the design kinetics and modeling; and AERA contributed commercial power and combustion experience. Task 3 provides budgetary cost estimates for the FBCO process and competing alternative technologies for sulfur dioxide and nitrogen oxide removal.

  4. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk

    2010-04-15

    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  5. Managing steam: An engineering guide to industrial, commercial, and utility systems

    SciTech Connect (OSTI)

    Makansi, J.

    1985-01-01

    This book is a guide to steam production, utilization, handling, transport, system optimization, and condensation and recovery. This book incudes a description of how steam, condensate, and hot water are used in various industrial, commercial, institutional, and utility sectors and explains how steam is generated and distributed. Waste-heat recovery, fluidized-bed boilers, and cogeneration systems and boiler control theory are discussed. The book also describes different types of valves, valve components, regulators, steam traps, and metering devices available for managing steam and condensate and discusses maintaining steam systems for optimum service and longer life.

  6. Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor

    SciTech Connect (OSTI)

    Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W.

    2007-06-15

    The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

  7. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  8. Design and performance requirements for a fluidized bed boiler firing municipal refuse derived fuel in Ravenna, Italy

    SciTech Connect (OSTI)

    Murphy, M.L.

    1999-07-01

    In early 1998, the City of Ravenna, Italy, commissioned a fluid bed boiler/waste-to-energy system to combust approximately 50,000 tonnes per year of processed municipal waste and generate electrical power. Much of the fuel preparation and processing equipment was already in place and the primary focus of this project was to implement an environmentally acceptable energy conversion process compatible with the 6.0 tonnes/hr of fuel being processed. The fluid bed boiler system being provided will incorporate state of the art environmental controls for abatement of all pollutants, including products of incomplete combustion (PICs), NO{sub x}, acid gases, and particulates. The project will deliver an average of 70,000 pounds per hour of steam to generate approximately 7 MW of electricity. The following is a description of the process and equipment being utilized for the energy conversion and boiler island, including the environmental abatement equipment. Design specifications for the plant including fuel and emission limits are presented herein. The facility is scheduled for startup in mid-1999.

  9. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume IV. FBC-Model-II manual

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the fourth of the seven volume series of our Phase II Final Report. The purpose of this manual is to describe how to access and use M.I.T.'s Fluidized Bed Combustor (FBC) System Program. Presently, the FBC program is stored in a Honeywell Computer System and can be accessed using the Multics interactive system. The intention in writing this manual is to answer the questions that may arise regarding the mechanics of operating the system program, as well as warn the user of possible pitfalls and mistakes that could be made. No attempt is made here to describe the internals of the systems program. The manual describes the procedures an individual would follow to become an active user of the system program. It then explains the various options available for reaching the Multics interactive system on Honeywell 6180 computer on which the program runs. For users outside the Metropolitan Boston area, a public network for data communications is described which is relatively inexpensive. As the system program is approached through Multics using a special command facility TPSA, a separate introduction is provided for Multics TPSA. This facility allows commands appropriate for testing the program and carrying out parametric studies to be executed in a convenient way. Multics TPSA was formulated to meet the needs of the FBC project in particular. Finally, some sample sessions are presented which illustrate the login and logout procedures, the command language, and the data manipulation features of the FBC program. The use of commands helpful in debugging the program is also illustrated.

  10. Ethanol Production from Rice-Straw Hydrolysate Using Zymomonas Mobilis in a Continuous Fluidized-Bed Reactor (FBR)

    SciTech Connect (OSTI)

    deJesus, D.; Nghiem, N.P.

    2001-01-01

    Rice-straw hydrolysate obtained by the Arkenol's concentrated acid hydrolysis process was fermented to ethanol using a recombinant Zymomonas mobilis strain capable of utilizing both glucose and xylose in a continuous fluidized-bed reactor (FBR). The parameters studied included biocatalyst stability with and without antibiotic, feed composition, and retention time. Xylose utilization in the presence of tetracycline remained stable for at least 17 days. This was a significant improvement over the old strain, Z. mobilis CP4 (pZB5), which started to lose xylose utilization capability after seven days. In the absence of tetracycline, the xylose utilization rate started to decrease almost immediately. With tetracycline in the feed for the first six days, stability of xylose utilization was maintained for four days after the antibiotic was removed from the feed. The xylose utilization rate started to decrease on day 11. In the presence of tetracycline using the Arkenol's hydrolysate diluted to 48 g/L glucose and 13 g/L xylose at a retention time of 4.5 h, 95% xylose conversion and complete glucose conversion occurred. The ethanol concentration was 29 g/L, which gave a yield of 0.48 g/g sugar consumed or 94% of the theoretical yield. Using the Arkenol's hydrolysate diluted to 83 g/L glucose and 28 g/L xylose, 92% xylose conversion and complete glucose conversion were obtained. The ethanol concentration was 48 g/L, which gave a yield of 0.45 g/ g sugar consumed or 88% of the theoretical yield. Maximum productivity of 25.5 g/L-h was obtained at a retention time of 1.9 h. In this case, 84% xylose conversion was obtained.

  11. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    SciTech Connect (OSTI)

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFDDAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting the reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.

  12. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFD–DAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting themore »reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.« less

  13. On-line instrumentation for the real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor - a feasibility study

    SciTech Connect (OSTI)

    D'Silva, A.P.; Iles, M.; Rice, G.; Fassel, V.A.

    1984-04-01

    When polynuclear aromatic hydrocargons in the vapor phase are diluted preferably in a rare gas and undergo supersonic jet expansion, rotationally cooled molecules with absorption bandwidths of the order of 0.01 nm (FWHM) are obtained. Selective excitation with a tunable dye laser into such narrow absorption bands leads to the observation of highly specific luminescence spectra. Such an approach has been utilized for the on-line, real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor.

  14. Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 2, Task 3, Testing of process improvement concepts: Final report, September 1987--May 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    This final report, Volume 2, on ``Process Improvement Concepts`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). Results of work on electroseparation of shale oil and fines conducted by IIT is included in this report, as well as work conducted by IGT to evaluate the restricted pipe discharge system. The work was conducted as part of the overall program on ``Pressurized Fluidized-Bed Hydroretorting of Eastern Oil Shales.``

  15. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; John Gaudlip; Matthew Lapinsky; Rhett McLaren; William Serencsits; Neil Raskin; Tom Steitz; Joseph J. Battista

    2003-03-26

    The Pennsylvania State University, utilizing funds furnished by the U.S. Department of Energy's Biomass Power Program, investigated the installation of a state-of-the-art circulating fluidized bed boiler at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring biofuels and coal-based feedstocks. The study was performed using a team that included personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Foster Wheeler Energy Corporation; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. The activities included assessing potential feedstocks at the University Park campus and surrounding region with an emphasis on biomass materials, collecting and analyzing potential feedstocks, assessing agglomeration, deposition, and corrosion tendencies, identifying the optimum location for the boiler system through an internal site selection process, performing a three circulating fluidized bed (CFB) boiler design and a 15-year boiler plant transition plan, determining the costs associated with installing the boiler system, developing a preliminary test program, determining the associated costs for the test program, and exploring potential emissions credits when using the biomass CFB boiler.

  16. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, April 1-June 30, 1983

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. Experimental work was initiated on the unsteady-state Fischer-Tropsch synthesis using a fully-automated vibrofluidized microreactor system and a computer-controlled on-line gas chromatographic (GC) system for product analysis. Both the reactor and GC systems performed well in all experiments, and no mechanical problems were observed throughout the experiments lasting as long as twenty hours. Preliminary estimates indicated that the conversion of CO to carbon was only on the order of one-tenth of one percent. This encouraging result provided evidence that it should be possible to experimentally identify cycling conditions which could prevent carbon deposits on the catalyst while treating a synthesis gas of low H/sub 2/:CO ratio.

  17. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Tom Steitz

    2002-10-14

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. During this reporting period, the final technical design and cost estimate were submitted to Penn State by Foster Wheeler. In addition, Penn State initiated the internal site selection process to finalize the site for the boiler plant.

  18. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Curtis Jawdy

    2000-10-09

    The Pennsylvania State University, under contract to the US Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal or coal refuse, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Corporation, Foster Wheeler Development Corporation, and Cofiring Alternatives. The major emphasis of work during this reporting period was to assess the types and quantities of potential feedstocks and collect samples of them for analysis. Approximately twenty different biomass, animal waste, and other wastes were collected and analyzed.

  19. A 50-month gasifier mechanistic study and downstream unit process development program for the pressurized ash-agglomerating fluidized-bed gasification system

    SciTech Connect (OSTI)

    Haldipur, G.B.; Schmidt, D.K.; Smith, K.J.

    1989-03-01

    This technology development program scope included studies of those processes and components necessary to convert coal, oxidant and steam into a clean fuel gas. The configuration of the processes and components constitutes a Gasifier Island which is a key concept in the application of the KRW gasification and cleanup technologies. This Gasifier Island typically consists of process units that perform the following functions: feedstock preparation, gasification, desulfurization, heat recovery, particulate removal, and solid waste treatment. The processing has been conducted in a variety of gasifier operating modes including air-blown and oxygen-blown, both with and without in-bed desulfurization which includes injection of limestone or dolomite sorbent. Process configurations downstream of the gasifier have included recycle and non-recycle cyclones, sintered filters, and zinc ferrite fixed beds. Because of the developmental nature of the KRW technology program and the flexibility of the pilot plant itself, a wide range of gasifier-cleanup process configurations has been investigated. The KRW pilot plant program evaluated a system comprised of the following major process elements: gasifier and in-bed desulfurizer, particulate cleanup train, external sulfur polishing bed, and solid waste disposal system.

  20. Combined heat and power systems that consist of biomass fired fluidised bed combustors and modern steam engines

    SciTech Connect (OSTI)

    Joseph, S.D.; Errey, S.; Thomas, M.; Kruger, P.

    1996-12-31

    Biomass energy is widely used in many processing industries in the ASEAN region. The residue produced by agricultural and wood processing plant is either inefficiently combusted in simple furnaces or in the open, or disposed of in land fill sites or in rivers. Many of these industries are paying high prices for electricity in rural areas and/or supply is unreliable. An ASEAN/Australian cooperation program has been under way for the last ten years to introduce clean burning biomass fired heat and/or combined heat and power equipment. It aims to transfer Australian know how in the design and manufacture of fluidised bed CHP technology to the ASEAN region. The main participants involved in the program include SIRIM and UKM in Malaysia, PCIERD, FPRI and Asia Ratan in the Philippines, King Monkutt Institute of Technology (KMITT) in Thailand, LIPI and ITB in Indonesia, and the University of Singapore. In this paper an outline of the program will be given including results of market research and development undertaken into fluidised bed combustion, the proposed plant design and costings, and research and development undertaken into modem steam engine technology. It will be shown that all of the projects to be undertaken are financially viable. In particular the use of simple low cost high efficient steam engines ensures that the smaller CHP plant (50-100 kWe) can be viable.

  1. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume III. Model predictions and results

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the third of a seven volume series of our Phase II Final Report. This volume deals with parametric studies carried out using the FBC model. A comparison with available pilot plant data is included where such data are available. This volume in essence documents model performance; describing predictions on bubble growth, combustion characteristics, sulfur capture, heat transfer and related parameters. The model has approximately forty input variables which are at the disposal of the user. The user has the option to change a few or all of these input variables. In the parametric studies reported here, a large number of input variables whose variation is less critical to the predicted results, were maintained constant at the default values. On the other hand, those parameters whose selection is very important in design and operation of the FBC's were varied in suitable operating regions. The chief among such parameters are: bed temperature, coal feed size distribution (2 parameters), average bed-sorbent size, calcium to sulfur molar ratio, superficial velocity, excess air fraction, and bed weight (or bed height). The computations for obtaining the parametric relationships are based upon selection of a geometrical design for the combustor. Bed cross-section is 6' x 6', bed height is 4', and the freeboard height is 16'. The heat transfer tubes have 2'' OD, a pitch of 10'', and are located on an equilateral triangle pattern. The air distributor is a perforated plate with 0.1'' diameter holes on a rectangular grid with 0.75'' center-to-center spacing.

  2. Biodegradation of phenolic wastewaters in a three-phase fluidized bed bioreactor with the KMT{reg_sign} biomass support

    SciTech Connect (OSTI)

    Sokol, W.; Halfini, M.R.

    1996-12-31

    A treatment of wastewater from a local refinery in a three-phase fluidised bed bioreactor with the KMT{sup R} biomass support was investigated. It was found that after adding mineral salts to the wastewater to be treated, a reduction in the COD values increased from about 55% to almost 90%. The reduction in COD was increasing with an increase in both a superficial air velocity and a ratio of bed volume to bioreactor volume (V{sub b}/V{sub r}). The highest value of (V{sub b}/V{sub r}) which could be applied in the experiments was 0.7, because at larger (V{sub b}/V{sub r}) movement of the whole bed was impossible. The bioreactor as operated was not successful in degrading thiocyanates, cyanides, nitrates and ammonia. However, results of independent experiments that have been started to adapt the symbiotic populations of microorganisms that may effectively degrade those compounds are promising. Stratification of the support media coated with the biomass led to their movement to the base of the bioreactor where concentration of organic compounds was highest. This was desirable since the compounds could penetrate far into the biofilm so most of the biomass grown on the support was active. 6 refs., 3 figs.

  3. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

  4. Reducing the environmental impact on solid wastes from a fluidized...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; COAL; FLUIDIZED-BED COMBUSTION; WASTE MANAGEMENT; AIR POLLUTION ABATEMENT; ALUMINIUM OXIDES; CALCIUM OXIDES; CHEMICAL ACTIVATION;...

  5. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume VII. FBC Data-Base-Management System (FBC-DBMS) users manual

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The primary goal of the Fluidized Bed Combustor Data Base (FBCDB) is to establish a data repository for the express use of designers and research personnel involved in FBC development. FBCDB is implemented on MIT's 370/168 computer, using the Model 204 Data Base Management System (DBMS) developed by Computer Corporation of America. DBMS is a software that provides an efficient way of storing, retrieving, updating and manipulating data using an English-like query language. The primary content of FBCDB is a collection of data points defined by the value of a number of specific FBC variables. A user may interactively access the data base from a computer terminal at any location, retrieve, examine, and manipulate the data as well as produce tables or graphs of the results. More than 20 program segments are currently available in M204 User Language to simplify the user interface for the FBC design or research personnel. However, there are still many complex and advanced retrieving as well as applications programs to be written for this purpose. Although there are currently 71 entries, and about 2000 groups reposited in the system, this size of data is only an intermediate portion of our selection. The usefulness of the system at the present time is, therefore, limited. This version of FBCDB will be released on a limited scale to obtain review and comments. The document is intended as a reference guide to the use of FBCDB. It has been structured to introduce the user to the basics of FBCDB, summarize what the available segments in FBCDB can do, and give detailed information on the operation of FBCDB. This document represents a preliminary draft of a Users Manual. The draft will be updated when the data base system becomes fully implemented. Any suggestions as to how this manual may be improved will be appreciated.

  6. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume VI. FBC-Data Base-Management-System (FBC-DBMS) development

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The primary goal of the Fluidized Bed Combustor Data Base, (FBCDB), situated in MIT's Energy laboratory, is to establish a data repository for the express use of designers and research personnel involved in FBC development. DBMS is a software that provides an efficient way of storing, retrieving, updating and manipulating data using an English-like query language. It is anticipated that the FBCDB would play an active and a direct role in the development of FBC technology as well as in the FBC commercial application. After some in-house experience and after a careful and extensive review of commercially available database systems, it was determined that the Model 204 DBMS by Computer Corporation of America was the most suitable to our needs. The setup of a prototype in-house database also allowed us to investigate and understand fully the particular problems involved in coordinating FBC development with a DBMS. Various difficult aspects were encountered and solutions had been sought. For instance, we found that it was necessary to rename the variables to avoid repetition as well as to increase usefulness of our database and, hence, we had designed a classification system for which variables were classified under category to achieve standardization of variable names. The primary content of FBCDB is a collection of data points defined by the value of a number of specific FBC variables. A user may interactively access the database from a computer terminal at any location, retrieve, examine, and manipulate the data as well as produce tables or graphs of the results.

  7. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of alkali chlorides and sulfates gives increased sintering. At the same time, increased amounts calcium salts in the ash appear to reduce sintering tendency. Thus, the results suggest that a calcium based sorbent for SO{sub 2} and HCl capture might reduce problems related to ash sintering. An extensive literature exists, however, that states otherwise.

  8. Fischer-Tropsch synthesis from a low HH/sub 2/:CO gas in a dry fluidized-bed system. Volume 1. Project summary. Final technical report, October 1, 1986. [Heat tray

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1986-10-01

    The objective of this project is to experimentally develop and demonstrate a dry fluidized-bed reactor system (called ''heat tray'') for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of an iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. The project has been carried out in two key tasks: (1) development of a microreactor system for unsteady-state Fischer-Tropsch synthesis, simulating the life history of an iron catalyst particle in a ''heat-tray'' reactor; and (2) supporting fluidization studies. The present Volume I summarizes the key conclusions and recommendations from this project, and the accompanying Volumes II and III describes the details of experimental investigations and results. 12 refs., 8 figs., 2 tabs.

  9. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, September 1, 1982-March 31, 1983. [Large number of references

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past several months, the design, construction and steady-state testing of a fully-automated vibrofluidized microreactor system have been successfully completed, and a computer-controlled gas chromatographic (GC) system for gas-product analysis has also been tied to the reactor system. Work on unsteady-state Fischer-Tropsch synthesis experiments is to be initiated shortly. In addition, supporting hydrodynamic and heat-transfer studies in several shallow fluidized-bed systems have produced some encouraging data. The results indicate very high heat-transfer coefficients of 300-400 W/m/sup 2/-/sup 0/K between a shallow bed and its immersed horizontal heat-transfer tube, and of about 7000 W/m/sup 2/-/sup 0/K between a supernatant gas stream and a shallow bed which closely simulates the microreactor system in use.

  10. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 2. Development of microreactor systems for unsteady-state Fischer-Tropsch synthesis. Final technical report. [408 references

    SciTech Connect (OSTI)

    Whiting, G.K.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Vibrofluidized microreactor systems have been developed for studies of unsteady-state Fischer-Tropsch synthesis. This development is aimed at preventing carbon deposition on a fused-iron catalyst in a novel reactor called the ''heat tray.'' This reactor involves a supernatant gas flowing over a shallow fluidized bed of catalyst particles. Three systems were built: (1) a vibrofluidized-bed microreactor system for obtaining baseline carbon deposition information under industrially important reaction conditions; (2) a sliding-plug vibrofluidized-bed microreactor system for rapid switching of feed gases in the F-T synthesis; and (3) a cold-flow microreactor model for studying the gas mixing characteristics of the sliding-plug vibrofluidized-bed microreactor. The results show that catalyst defluidization occurred under steady-state synthesis conditions below 395 C using a feed gas of H/sub 2//CO ratio of 2:1 or less. Above 395 C, the probability of hydrocarbon chain growth (..cap alpha.. < 0.50 to prevent accumulation of high-molecular-weight species that cause defluidization. Carbon deposition was rapid above 395 C when a feed gas of H/sub 2//CO ratio of 2:1 or less was used. Cold-flow microreactor model studies show that rapid (on the order of seconds), quantitative switching of feed gases over a vibrofluidized bed of catalyst could be achieved. Vibrofluidization of the catalyst bed induced little backmixing of feed gas over the investigated flow-rate range of 417 to 1650 actual mm/sup 3//s. Further, cold-flow microreactor model studies showed intense solid mixing when a bed of fused-iron catalyst (150 to 300 microns) was vibrofluidized at 24 cycles per second with a peak-to-peak amplitude of 4 mm. The development of the microreactor systems provided an easy way of accurately determining integral fluid-bed kinetics in a laboratory reactor. 408 refs., 156 figs., 27 tabs.

  11. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an opportunity fuel for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an opportunity fuel for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administrations National Goal to Reduce Emissions Intensity. 8

  12. Evaluation of wall boundary condition parameters for gas-solids fluidized

    Office of Scientific and Technical Information (OSTI)

    bed simulations (Journal Article) | SciTech Connect Evaluation of wall boundary condition parameters for gas-solids fluidized bed simulations Citation Details In-Document Search Title: Evaluation of wall boundary condition parameters for gas-solids fluidized bed simulations Wall boundary conditions for the solids phase have significant effects on numerical predictions of various gas-solids fluidized beds. Several models for the granular flow wall boundary condition are available in the open

  13. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, July 1, 1983-April 30, 1984

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1984-05-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past ten months, numerous steady-state and unsteady-state Fischer-Tropsch synthesis experiments from a low H/sub 2/:CO gas were performed using a computer-controlled vibrofluidized microreactor and gas chromatographic (GC) system. The results have revealed specific directions for design and operational improvements of the microreactor system so as to effectively control the cycling of reactant gases during unsteady-state Fischer-Tropsch synthesis, and several modified microreactor systems have been constructed and tested.

  14. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  15. Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 4, Task 5, Operation of PFH on beneficiated shale, Task 6, Environmental data and mitigation analyses and Task 7, Sample procurement, preparation, and characterization: Final report, September 1987--May 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    The objective of Task 5 (Operation of Pressurized Fluidized-Bed Hydro-Retorting (PFH) on Beneficiated Shale) was to modify the PFH process to facilitate its use for fine-sized, beneficiated Eastern shales. This task was divided into 3 subtasks: Non-Reactive Testing, Reactive Testing, and Data Analysis and Correlations. The potential environment impacts of PFH processing of oil shale must be assessed throughout the development program to ensure that the appropriate technologies are in place to mitigate any adverse effects. The overall objectives of Task 6 (Environmental Data and Mitigation Analyses) were to obtain environmental data relating to PFH and shale beneficiation and to analyze the potential environmental impacts of the integrated PFH process. The task was divided into the following four subtasks. Characterization of Processed Shales (IGT), 6.2. Water Availability and Treatment Studies, 6.3. Heavy Metals Removal and 6.4. PFH Systems Analysis. The objective of Task 7 (Sample Procurement, Preparation, and Characterization) was to procure, prepare, and characterize raw and beneficiated bulk samples of Eastern oil shale for all of the experimental tasks in the program. Accomplishments for these tasks are presented.

  16. Second-generation pressurized fluidized-bed combustion plant: Conceptual design and optimization of a second-generation PFB combustion plant. Phase 2, Annual report, October 1991--September 1992

    SciTech Connect (OSTI)

    Robertson, A.; Domeracki, W.; Newby, R.; Rehmat, A.; Horazak, D.

    1992-10-01

    After many years of experimental testing and development work, coal-fired pressurized fluidized bed (PFB) combustion combined-cycle power plants are moving toward reality. Under the US Department of Energy`s Clean Coal Technology Program, a 70-MWe PFB combustion retrofit, utilizing a 1525{degrees}F gas turbine inlet temperature, has been built and operated as a demonstration plant at the American Electric Power Company`s Tidd Plant in Brilliant, Ohio. As PFB combustion technology moves closer and closer to commercialization, interest is turning toward the development of an even more efficient and more cost-effective PFB combustion plant. The targeted goals of this ``second-generation`` plant are a 45-percent efficiency and a cost of electricity (COE) that is at least 20 percent lower than the COE of a conventional pulverized-coal (PC)-fired plant with stack gas scrubbing. In addition, plant emissions should be within New Source Performance Standards (NSPS) and the plant should have high availability, be able to burn different ranks of coal, and incorporate modular construction technologies. In response to this need, a team of companies led by Foster Wheeler Development Corporation (FWDC). The key components in the proposed second-generation plant are the carbonizer, CPFBC, ceramic cross-flow filter, and topping combustor. Unfortunately, none of these components has been operated at proposed plant operating conditions, and experimental tests must be conducted to explore/determine their performance throughout the proposed plant operating envelope. The major thrust of Phase 2 is to design, construct, test, and evaluate the performance of the key components of the proposed plant.

  17. STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

    SciTech Connect (OSTI)

    Burket, P

    2009-02-24

    This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

  18. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  19. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 85 citations and includes a subject term index and title list.)

  20. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 84 citations and includes a subject term index and title list.)

  1. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  2. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 119 citations and includes a subject term index and title list.)

  3. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  4. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    SciTech Connect (OSTI)

    Nguyen, C.T.

    1980-03-01

    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  5. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  6. Fluidized Bed Technology - Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... temperatures and corrosive environment. New ceramics and ceramic-metallic composites are showing promise. Those passing laboratory screening tests will undergo testing at the PSDF

  7. Fluidized bed paint stripping and sludge burning

    SciTech Connect (OSTI)

    Bhatia, J.; Staffin, H.K.

    1986-01-01

    High volume automated painting, as encountered in the painting of automobiles and appliances, requires that the item being painted be positioned in a conveying frame or fixture so that the painting machine or robot achieves a reproducible, high quality paint job. These conveying frames or fixtures are extensive fabrications carefully designed to position and support the item being painted. In the case of automotive painting, they are rather large and involve substantial weights, because they must be capable of supporting and positioning auto bodies and large sub-assemblies.

  8. Boiler and steam generator corrosion: Fossil-fuel power plants. March 1977-December 1989 (A Bibliography from the NTIS data base). Report for March 1977-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. Hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 88 citations fully indexed and including a title list.)

  9. State-of-the-art review and report on critical aspects and scale-up considerations in the design of fluidized-bed reactors. Final report on Phase 1

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Information is given on the design of distributor plates and opening geometry to provide uniform flow over the reactor area. The design of granular bed filters is also considered. Pressure drops and particle size in the bed are discussed. (LTN)

  10. Process for purifying geothermal steam

    DOE Patents [OSTI]

    Li, Charles T. (Richland, WA)

    1980-01-01

    Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

  11. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  12. Spray-dried fluid-bed sorbents tests - CMP-5

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1995-12-01

    The objective of this study is to determine the feasibility of manufacturing highly reactive and attrition-resistant zinc titanate sorbents by spray drying, suitable for bubbling (conventional) as well as transport-type fluidized-bed reactor systems.

  13. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    SciTech Connect (OSTI)

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  14. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-06-08

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

  15. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-04-21

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

  16. CIRCULATING MOVING BED COMBUSTION PROOF OF CONCEPT

    SciTech Connect (OSTI)

    Jukkola, Glen

    2010-06-30

    Circulating Moving Bed (CMB) combustion technology has its roots in traditional circulating fluidized bed technology and involves a novel method of solid fuel combustion and heat transfer. CMB technology represents a step change in improved performance and cost relative to conventional PC and FBC boilers. The CMB heat exchanger preheats the energy cycle working fluid, steam or air, to the high temperature levels required in systems for advanced power generation. Unique features of the CMB are the reduction of the heat transfer surfaces by about 60% as a result of the enhanced heat transfer rates, flexibility of operation, and about 30% lower cost over existing technology. The CMB Phase I project ran from July 2001 through March 2003. Its objective was to continue development of the CMB technology with a series of proof of concept tests. The tests were conducted at a scale that provided design data for scale up to a demonstration plant. These objectives were met by conducting a series of experiments in ALSTOM Power’s Multi-use Test Facility (MTF). The MTF was modified to operate under CMB conditions of commercial interest. The objective of the tests were to evaluate gas-to-solids heat transfer in the upper furnace, assess agglomeration in the high temperature CMB bubbling bed, and evaluate solids-to-tube heat transfer in the moving bed heat exchanger. The Phase I program results showed that there are still some significant technical uncertainties that needed to be resolved before the technology can be confidently scaled up for a successful demonstration plant design. Work remained in three primary areas: • scale up of gas to solid heat transfer • high temperature finned surface design • the overall requirements of mechanical and process design. The CMB Phase II workscope built upon the results of Phase I and specifically addressed the remaining technical uncertainties. It included a scaled MTF heat transfer test to provide the necessary data to scale up gas-to-solids heat transfer. A stress test rig was built and tested to provide validation data for a stress model needed to support high temperature finned surface design. Additional cold flow model tests and MTF tests were conducted to address mechanical and process design issues. This information was then used to design and cost a commercial CMB design concept. Finally, the MBHE was reconfigured into a slice arrangement and tested for an extended duration at a commercial CFB plant.

  17. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  18. Superheated steam power plant with steam to steam reheater. [LMFBR

    SciTech Connect (OSTI)

    Silvestri, G.J.

    1981-06-23

    A desuperheater is disposed in a steam supply line supplying superheated steam to a shell and tube reheater.

  19. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  20. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    SciTech Connect (OSTI)

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na{sub 2}CO{sub 3} {center_dot} H{sub 2}O], sodium carbonate, [Na{sub 2}CO{sub 3}], and trona, [Na{sub 3}H(CO{sub 3}){sub 2} {center_dot} 2H{sub 2}O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements > 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

  1. High-pressure three-phase fluidization: Hydrodynamics and heat transfer

    SciTech Connect (OSTI)

    Luo, X.; Jiang, P.; Fan, L.S.

    1997-10-01

    High-pressure operations are common in industrial applications of gas-liquid-solid fluidized-bed reactors for resid hydrotreating, Fischer-Tropsch synthesis, coal methanation, methanol synthesis, polymerization, and other reactions. The phase holdups and the heat-transfer behavior were studied experimentally in three-phase fluidized beds over a pressure range of 0.1--15.6 MPa. Bubble characteristics in the bed are examined by direct flow visualization. Pressure effects on the bubble coalescence and breakup are analyzed mechanistically. The study indicates that the pressure affects the hydrodynamics and heat-transfer properties of a three-phase fluidized bed significantly. The average bubble size decreases and the bubble-size distribution becomes narrower with an increase in pressure. The bubble-size reduction leads to an increase in the transition gas velocity from the dispersed bubble regime to the coalesced bubble regime, an increase in the gas holdup, and a decrease in the liquid and solids holdups. The pressure effect is insignificant above 6 MPa. The heat-transfer coefficient between an immersed surface and the bed increases to a maximum at pressure 6--8 MPa and then decreases with an increase in pressure at a given gas and liquid flow rate. This variation is attributed to the pressure effects on phase holdups and physical properties of the gas and liquid phases. A mechanistic analysis revealed that the major heat-transfer resistance in high-pressure three-phase fluidized beds resides in a liquid film surrounding the heat-0transfer surface. An empirical correlation is proposed to predict the heat-transfer coefficient under high-pressure conditions.

  2. Technical evaluation: pressurized fluidized-bed combustion technology...

    Office of Scientific and Technical Information (OSTI)

    COMBUSTORS; TECHNOLOGY ASSESSMENT; ECONOMICS; ENVIRONMENTAL IMPACTS; PERFORMANCE; AIR POLLUTION CONTROL; DESIGN; EFFICIENCY; GAS TURBINES; HOT GAS CLEANUP; RESEARCH...

  3. EIS-0289: JEA Circulating Fluidized Bed Combustor Project

    Broader source: Energy.gov [DOE]

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the...

  4. Fast pyrolysis of sweet soghum bagasse in a fluidized bed

    SciTech Connect (OSTI)

    Palm, M.; Peacocke, C.; Bridgewater, A.V.; Piskorz, J.; Scott, D.S.

    1993-12-31

    Samples of Italian sorghum bagasse were dried and ground and then pyrolyzed in the Waterloo Fast Pyrolysis bench scale reactor unit. Results were typical of agricultural grasses of this kind, and resembled those obtained from similar tests of sugar cane bagasse. A maximum liquid yield (dry feed basis) of 68% by weight of dry feed was achieved, with a corresponding char yield (ash included) of 16%. The high ash content of the bagasse (9.2%) gave a char with a very high ash content ({approx}50%), with calcium as the most abundant cation. Yields of hydroxyacetaldehyde were comparable to those obtained from softwoods. Deionized bagasse gave significant yields of anhydrosugars on pyrolysis. Sorghum bagasse appears to be a suitable feedstock, either for pyrolysis to yield an alternative fuel oil, or after pretreatment and pyrolysis, to yield a solution of fermentable sugars.

  5. Particle Receiver Integrated with Fluidized Bed (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01

    National Renewable Energy Laboratory is one of the 2012 SunShot CSP R&D awardees for their advanced receivers. This fact sheet explains the motivation, description, and impact of the project.

  6. Circulating Fluidized Bed (CFB) Boilers Market will grow due...

    Open Energy Info (EERE)

    Energy Concerns to Push Global Market to Grow at 8.1% CAGR from 2013 to 2019 Oil Shale Market is Estimated to Reach USD 7,400.70 Million by 2022 more Group members (32)...

  7. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    2004-07-01

    Enabling Computational Technology Will Directly Impact the Energy Requirements of Catalytic and Non-Catalytic Reaction Processes.

  8. Method of removing cesium from steam

    DOE Patents [OSTI]

    Carson, Jr., Neill J. (Clarendon Hills, IL); Noland, Robert A. (Oak Park, IL); Ruther, Westly E. (Skokie, IL)

    1991-01-01

    Method for removal of radioactive cesium from a hot vapor, such as high temperature steam, including the steps of passing input hot vapor containing radioactive cesium into a bed of silicate glass particles and chemically incorporating radioactive cesium in the silicate glass particles at a temperature of at least about 700.degree. F.

  9. Process for the conversion of alcohols and oxygenates to hydrocarbons in a turbulent fluid bed reactor

    SciTech Connect (OSTI)

    Avidan, A. A.; Kam, A. Y.

    1985-04-23

    Improvements in converting C/sub 1/-C/sub 3/ monohydric alcohols, particularly methanol, related oxygenates of said alcohols and/or oxygenates produced by Fischer-Tropsch synthesis to light olefins, gasoline boiling range hydrocarbons and/or distillate boiling range hydrocarbons are obtained in a fluidized bed of ZSM-5 type zeolite catalyst operating under conditions effective to provide fluidization in the turbulent regime.

  10. Inspect and Repair Steam Traps, Energy Tips: STEAM, Steam Tip...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    leaking traps should account for less than 5% of the trap population. If your steam distribution system includes more than 500 traps, a steam trap survey will probably reveal...

  11. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Golden, CO)

    1986-01-01

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  12. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    1984-06-27

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  13. Particle Receiver Integrated with Fludized Bed | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particle Receiver Integrated with Fludized Bed Particle Receiver Integrated with Fludized Bed This fact sheet describes a project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program to NREL which features a particle receiver with a fluidized bed. The research team is working to develop a technology that uses gas/solid, two-phase flow as a heat-transfer fluid and separated, stable, solid particles as a thermal energy storage medium. This project provides a pathway

  14. Steam Digest Volume IV

    SciTech Connect (OSTI)

    2004-07-01

    This edition of the Steam Digest is a compendium of 2003 articles on the technical and financial benefits of steam efficiency, presented by the stakeholders of the U.S. Department of Energy's BestPractices Steam effort.

  15. Achieve Steam System Excellence - Steam Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Achieve Steam System Excellence - Steam Overview Achieve Steam System Excellence - Steam Overview This fact sheet describes a steam systems approach to help companies operate and maintain their industrial steam plants and thermal manufacturing processes more efficiently. PDF icon Achieve Steam System Excellence - Steam Overview (December 2002) More Documents & Publications Save Energy Now in Your Steam Systems J.R. Simplot: Burner Upgrade Project Improves Performance and Saves Energy at a

  16. Steam Field | Open Energy Information

    Open Energy Info (EERE)

    Steam Field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Steam Field Dictionary.png Steam Field: No definition has been...

  17. Steam Oxidation of Advanced Steam Turbine Alloys

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2008-01-01

    Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650C to 800C) to steam at 34.5 MPa (650C to 760C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

  18. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

    1994-01-01

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

  19. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

  20. Steam Technical Brief: Steam Pressure Reduction: Opportunities and Issues

    SciTech Connect (OSTI)

    2010-06-25

    A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

  1. Steam Digest 2001

    SciTech Connect (OSTI)

    Not Available

    2002-01-01

    Steam Digest 2001 chronicles BestPractices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  2. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, D.O.; Montoya, P.C.; Muir, J.F.; Wayland, J.R. Jr.

    1985-06-19

    The present invention relates to an empirical electrical method for remote sensing of steam quality utilizing flow-through grids which allow measurement of the electrical properties of a flowing two-phase mixture. The measurement of steam quality in the oil field is important to the efficient application of steam assisted recovery of oil. Because of the increased energy content in higher quality steam it is important to maintain the highest possible steam quality at the injection sandface. The effectiveness of a steaming operation without a measure of steam quality downhole close to the point of injection would be difficult to determine. Therefore, a need exists for the remote sensing of steam quality.

  3. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, David O. (Albuquerque, NM); Montoya, Paul C. (Albuquerque, NM); Muir, James F. (Albuquerque, NM); Wayland, Jr., J. Robert (Albuquerque, NM)

    1987-01-01

    An empirical method for the remote sensing of steam quality that can be easily adapted to downhole steam quality measurements by measuring the electrical properties of two-phase flow across electrode grids at low frequencies.

  4. COAL CLEANING VIA LIQUID-FLUIDIZED CLASSIFICAITON (LFBC) WITH SELECTIVE SOLVENT SWELLING

    SciTech Connect (OSTI)

    J. M. Calo

    2000-12-01

    The concept of coal beneficiation due to particle segregation in water-fluidized beds, and its improvement via selective solvent-swelling of organic material-rich coal particles, was investigated in this study. Particle size distributions and their behavior were determined using image analysis techniques, and beneficiation effects were explored via measurements of the ash content of segregated particle samples collected from different height locations in a 5 cm diameter liquid-fluidized bed column (LFBC). Both acetone and phenol were found to be effective swelling agents for both Kentucky No.9 and Illinois No.6 coals, considerably increasing mean particle diameters, and shifting particle size distributions to larger sizes. Acetone was a somewhat more effective swelling solvent than phenol. The use of phenol was investigated, however, to demonstrate that low cost, waste solvents can be effective as well. For unswollen coal particles, the trend of increasing particle size from top to bottom in the LFBC was observed in all cases. Since the organic matter in the coal tends to concentrate in the smaller particles, the larger particles are typically denser. Consequently, the LFBC naturally tends to separate coal particles according to mineral matter content, both due to density and size. The data for small (40-100 {micro}m), solvent-swollen particles clearly showed improved beneficiation with respect to segregation in the water-fluidized bed than was achieved with the corresponding unswollen particles. This size range is quite similar to that used in pulverized coal combustion. The original process concept was amply demonstrated in this project. Additional work remains to be done, however, in order to develop this concept into a full-scale process.

  5. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, M.J.

    1987-05-04

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

  6. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1993-10-19

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 [mu]m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO[sub 3]; and then indurating it at 800 to 900 C for a time sufficient to produce attrition-resistant granules.

  7. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, Raghubir P.; Gangwal, Santosh K.; Jain, Suresh C.

    1993-01-01

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

  8. Geothermal Steam Power Plant | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Steam Power Plant (Redirected from Dry Steam) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home General List of Dry Steam Plants List of Flash Steam Plants...

  9. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, James E. (Simi Valley, CA)

    1987-01-01

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

  10. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, J.E.

    1987-08-25

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

  11. Downhole steam injector

    DOE Patents [OSTI]

    Donaldson, A. Burl (Albuquerque, NM); Hoke, Donald E. (Albuquerque, NM)

    1983-01-01

    An improved downhole steam injector has an angled water orifice to swirl the water through the device for improved heat transfer before it is converted to steam. The injector also has a sloped diameter reduction in the steam chamber to throw water that collects along the side of the chamber during slant drilling into the flame for conversion to steam. In addition, the output of the flame chamber is beveled to reduce hot spots and increase efficiency, and the fuel-oxidant inputs are arranged to minimize coking.

  12. Effect of bed pressure drop on performance of a CFB boiler

    SciTech Connect (OSTI)

    Hairui Yang; Hai Zhang; Shi Yang; Guangxi Yue; Jun Su; Zhiping Fu

    2009-05-15

    The effect of bed pressure drop and bed inventory on the performances of a circulating fluidized bed (CFB) boiler was studied. By using the state specification design theory, the fluidization state of the gas-solids flow in the furnace of conventional CFB boilers was reconstructed to operate at a much lower bed pressure drop by reducing bed inventory and control bed quality. Through theoretical analysis, it was suggested that there would exist a theoretical optimal value of bed pressure drop, around which the boiler operation can achieve the maximal combustion efficiency and with significant reduction of the wear of the heating surface and fan energy consumption. The analysis was validated by field tests carried out in a 75 t/h CFB boiler. At full boiler load, when bed pressure drop was reduced from 7.3 to 3.2 kPa, the height of the dense zone in the lower furnace decreased, but the solid suspension density profile in the upper furnace and solid flow rate were barely influenced. Consequently, the average heat transfer coefficient in the furnace was kept nearly the same and the furnace temperature increment was less than 17{sup o}C. It was also found that the carbon content in the fly ash decreased first with decreasing bed pressure drop and then increased with further increasing bed pressure drop. The turning point with minimal carbon content was referred to as the point with optimal bed pressure drop. For this boiler, at the optimum point the bed pressure was around 5.7 kPa with the overall excess air ratio of 1.06. When the boiler was operated around this optimal point, not only the combustion efficiency was improved, but also fan energy consumption and wear of heating surface were reduced. 23 refs., 6 figs., 4 tabs.

  13. Steam Technical Brief: Industrial Steam System Process-Control Schemes

    SciTech Connect (OSTI)

    2003-07-01

    This BestPractices Steam Technical Brief was developed to provide a basic understanding of the different process-control schemes used in a typical steam system.

  14. Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica

    Office of Scientific and Technical Information (OSTI)

    for CO{sub 2} Capture (Journal Article) | SciTech Connect Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica for CO{sub 2} Capture Citation Details In-Document Search Title: Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica for CO{sub 2} Capture An amine sorbent, prepared by impregnation of polyethyleneimine on silica, was tested for steam stability. The stability of the sorbent was investigated in a fixed bed reactor using multiple steam cycles

  15. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, Michael J. (Plainfield, IL)

    1988-01-01

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

  16. Ukraine Steam Partnership

    SciTech Connect (OSTI)

    Gurvinder Singh

    2000-02-15

    The Ukraine Steam Partnership program is designed to implement energy efficiency improvements in industrial steam systems. These improvements are to be made by the private plants and local government departments responsible for generation and delivery of energy to end-users. One of the activities planned under this program was to provide a two-day training workshop on industrial steam systems focusing on energy efficiency issues related to the generation, distribution, and consumption of steam. The workshop was geared towards plant managers, who are not only technically oriented, but are also key decision makers in their respective companies. The Agency for Rational Energy Use and Ecology (ARENA-ECO), a non-governmental, not-for-profit organization founded to promote energy efficiency and environmental protection in Ukraine, in conjunction with the Alliance staff in Kiev sent out invitations to potential participants in all the regions of Ukraine. The purpose of this report is the describe the proceedings from the workshop and provide recommendations from the workshop's roundtable discussion. The workshop was broken down into two main areas: (1) Energy efficient boiler house steam generation; and Energy efficient steam distribution and consumption. The workshop also covered the following topics: (1) Ukrainian boilers; (2) Water treatment systems; (3) A profile of UKRESCO (Ukrainian Energy Services Company); (4) Turbine expanders and electricity generation; (5) Enterprise energy audit basics; and (6) Experience of steam use in Donetsk oblast.

  17. Steam generator tube failures

    SciTech Connect (OSTI)

    MacDonald, P.E.; Shah, V.N.; Ward, L.W.; Ellison, P.G.

    1996-04-01

    A review and summary of the available information on steam generator tubing failures and the impact of these failures on plant safety is presented. The following topics are covered: pressurized water reactor (PWR), Canadian deuterium uranium (CANDU) reactor, and Russian water moderated, water cooled energy reactor (VVER) steam generator degradation, PWR steam generator tube ruptures, the thermal-hydraulic response of a PWR plant with a faulted steam generator, the risk significance of steam generator tube rupture accidents, tubing inspection requirements and fitness-for-service criteria in various countries, and defect detection reliability and sizing accuracy. A significant number of steam generator tubes are defective and are removed from service or repaired each year. This wide spread damage has been caused by many diverse degradation mechanisms, some of which are difficult to detect and predict. In addition, spontaneous tube ruptures have occurred at the rate of about one every 2 years over the last 20 years, and incipient tube ruptures (tube failures usually identified with leak detection monitors just before rupture) have been occurring at the rate of about one per year. These ruptures have caused complex plant transients which have not always been easy for the reactor operators to control. Our analysis shows that if more than 15 tubes rupture during a main steam line break, the system response could lead to core melting. Although spontaneous and induced steam generator tube ruptures are small contributors to the total core damage frequency calculated in probabilistic risk assessments, they are risk significant because the radionuclides are likely to bypass the reactor containment building. The frequency of steam generator tube ruptures can be significantly reduced through appropriate and timely inspections and repairs or removal from service.

  18. Fluidized wall for protecting fusion chamber walls

    DOE Patents [OSTI]

    Maniscalco, James A. (Danville, CA); Meier, Wayne R. (Livermore, CA)

    1982-01-01

    Apparatus for protecting the inner wall of a fusion chamber from microexplosion debris, x-rays, neutrons, etc. produced by deuterium-tritium (DT) targets imploded within the fusion chamber. The apparatus utilizes a fluidized wall similar to a waterfall comprising liquid lithium or solid pellets of lithium-ceramic, the waterfall forming a blanket to prevent damage of the structural materials of the chamber.

  19. Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Systems Steam Systems Many manufacturing facilities can recapture energy by installing more efficient steam equipment and processes and applying energy management practices. Use the software tools, training, and publications listed below to optimize performance and save energy. Steam Tools Tools to assess your energy system: Steam System Modeler Qualified Specialists Qualified Specialists have passed a rigorous competency examination on a specific industrial system assessment tool. Locate

  20. Method for fluidizing and coating ultrafine particles, device for fluidizing and coating ultrafine particles

    DOE Patents [OSTI]

    Li, Jie; Liu, Yung Y

    2015-01-20

    The invention provides a method for dispersing particles within a reaction field, the method comprising confining the particles to the reaction field using a standing wave. The invention also provides a system for coating particles, the system comprising a reaction zone; a means for producing fluidized particles within the reaction zone; a fluid to produce a standing wave within the reaction zone; and a means for introducing coating moieties to the reaction zone. The invention also provides a method for coating particles, the method comprising fluidizing the particles, subjecting the particles to a standing wave; and contacting the subjected particles with a coating moiety.

  1. DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST

    SciTech Connect (OSTI)

    BANNING DL

    2010-08-03

    This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

  2. Inspect and Repair Steam Traps - Steam Tip Sheet #1

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  3. Steam Generator Group Project. Task 6. Channel head decontamination

    SciTech Connect (OSTI)

    Allen, R.P.; Clark, R.L.; Reece, W.D.

    1984-08-01

    The Steam Generator Group Project utilizes a retired-from-service pressurized-water-reactor steam generator as a test bed and source of specimens for research. An important preparatory step to primary side research activities was reduction of the radiation field in the steam generator channel head. This task report describes the channel head decontamination activities. Though not a programmatic research objective it was judged beneficial to explore the use of dilute reagent chemical decontamination techniques. These techniques presented potential for reduced personnel exposure and reduced secondary radwaste generation, over currently used abrasive blasting techniques. Two techniques with extensive laboratory research and vendors prepared to offer commercial application were tested, one on either side of the channel head. As indicated in the report, both techniques accomplished similar decontamination objectives. Neither technique damaged the generator channel head or tubing materials, as applied. This report provides details of the decontamination operations. Application system and operating conditions are described.

  4. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, L.C.; Simpson, M.L.

    1995-01-17

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

  5. Simplifying steam trap selection

    SciTech Connect (OSTI)

    Debat, R.J. )

    1994-01-01

    In the current economic world order, there is an obligation to eliminate waste and conserve economic and natural resources. One trap blowing 100-lb of steam through a 1/4-in. orifice can cost more than $12,000 a year in wasted energy. Richard J. Debat of Armstrong International, Inc. explains the operating principles of the four basic types of steam traps as the first step in simplifying the selection process so the right trap can be specified for a given application.

  6. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, Lonnie C. (Powell, TN); Simpson, Marc L. (Knoxville, TN)

    1995-01-01

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

  7. Inspect and Repair Steam Traps

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on inspecting and repairing steam traps provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  8. Steam Pressure Reduction: Opportunities and Issues

    Broader source: Energy.gov [DOE]

    This brief details industrial steam generation systems best practices and opportunities for reducing steam system operating pressure.

  9. Steam System Survey Guide | Department of Energy

    Energy Savers [EERE]

    Steam System Survey Guide Steam System Survey Guide This guide provides technical information for steam system operational personnel and plant energy managers on some of the major opportunities available to improve the energy efficiency and productivity of industrial steam systems. The guide covers five main areas of investigation: (1) profiling a steam system, (2) identifying steam properties for the steam system, (3) improving boiler operations, (4) improving resource utilization in the steam

  10. DOE - Fossil Energy: A Bed for Burning Coal?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4-Bed for Burning Coal An Energy Lesson Cleaning Up Coal A "Bed" for Burning Coal? It was a wet, chilly day in Washington DC in 1979 when a few scientists and engineers joined with government and college officials on the campus of Georgetown University to celebrate the completion of one of the world's most advanced coal combustors. It was a small coal burner by today's standards, but large enough to provide heat and steam for much of the university campus. But the new boiler built

  11. EA-0575: Fundamental Fluidization Research Project, Morgantown, West Virginia

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to design, construct, and operate a 2-foot diameter, 50-foot high pressurized fluidization with particular emphasis on operation in the...

  12. Method for retorting oil shale

    DOE Patents [OSTI]

    Shang, Jer-Yu; Lui, A.P.

    1985-08-16

    The recovery of oil from oil shale is provided in a fluidized bed by using a fluidizing medium of a binary mixture of carbon dioxide and 5 steam. The mixture with a steam concentration in the range of about 20 to 75 volume percent steam provides an increase in oil yield over that achievable by using a fluidizing gas of carbon dioxide or steam alone when the mixture contains higher steam concentrations. The operating parameters for the fluidized bed retorted are essentially the same as those utilized with other gaseous fluidizing mediums with the significant gain being in the oil yield recovered which is attributable solely to the use of the binary mixture of carbon dioxide and steam. 2 figs.

  13. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, Roy C. (Livermore, CA); Kobsa, Irvin R. (San Jose, CA)

    1994-01-01

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof.

  14. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, R.C.; Kobsa, I.R.

    1994-02-01

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

  15. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  16. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, E.P. Jr.

    1999-01-12

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed there between. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock. 2 figs.

  17. Steam Technical Brief: Industrial Steam System Heat-Transfer Solutions

    SciTech Connect (OSTI)

    2010-06-25

    This BestPractices Steam Technical Brief provides an overview of considerations for selecting the best heat-transfer solution for various applications.

  18. Sea bed mechanics

    SciTech Connect (OSTI)

    Sleath, J.F.A.

    1984-01-01

    This book provides a discussion on sea bed processes with engineering applications. It brings together the material currently available only in technical reports of research papers. It provides formulae and background references necessary for design calculation of problems such as sea bed or coastal erosion, and sub-marine pipeline stability. It also covers dissipation of wave energy, formation of ripples and dunes, and the transportation of sediments.

  19. Ancient Salt Beds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ancient Salt Beds Dr. Jack Griffith The key to the search for life on other planets may go through WIPP's ancient salt beds. In 2008, a team of scientists led by Jack Griffith, from the University of North Carolina, Chapel Hill, retrieved salt samples from the WIPP underground and studied them with a transmission electron microscopy lab at the Lineberger Comprehensive Cancer Center of the University of North Carolina School of Medicine. In examining fluid inclusions in the salt and solid halite

  20. Steam Pressure Reduction: Opportunities and Issues; A BestPractices Steam Technical Brief

    SciTech Connect (OSTI)

    Not Available

    2005-11-01

    A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

  1. Evaluation of cement production using a pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    DeLallo, M.; Eshbach, R.

    1994-01-01

    There are several primary conclusions which can be reached and used to define research required in establishing the feasibility of using PFBC-derived materials as cement feedstock. 1. With appropriate blending almost any material containing the required cement-making materials can be utilized to manufacture cement. However, extensive blending with multiple materials or the use of ash in relatively small quantities would compromise the worth of this concept. 2. The composition of a potential feedstock must be considered not only with respect to the presence of required materials, but just as significantly, with respect to the presence and concentration of known deleterious materials. 3. The processing costs for rendering the feedstock into an acceptable composition and the energy costs associated with both processing and burning must be considered. It should be noted that the cost of energy to produce cement, expressed as a percentage of the price of the product is higher than for any other major industrial product. Energy consumption is, therefore, a major issue. 4. The need for conformance to environmental regulations has a profound effect on the cement industry since waste materials can neither be discharged to the atmosphere or be shipped to a landfill. 5. Fifth, the need for achieving uniformity in the composition of the cement is critical to controlling its quality. Unfortunately, certain materials in very small concentrations have the capability to affect the rate and extent to which the cementitious compound in portland cement are able to form. Particularly critical are variations in the ash, the sulfur content of the coal or the amount and composition of the stack dust returned to the kiln.

  2. EA-0646: Pulsed Atmospheric Fluidized-Bed Combustor Development Thermochem, Inc.

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to develop a more economical, efficient, and environmentally acceptable coal-fired combustion technology in Baltimore, Maryland that can be...

  3. Downhole steam injector. [Patent application

    SciTech Connect (OSTI)

    Donaldson, A.B.; Hoke, E.

    1981-06-03

    An improved downhole steam injector has an angled water orifice to swirl the water through the device for improved heat transfer before it is converted to steam. The injector also has a sloped diameter reduction in the steam chamber to throw water that collects along the side of the chamber during slant drilling into the flame for conversion to steam. In addition, the output of the flame chamber is beveled to reduce hot spots and increase efficiency, and the fuel-oxidant inputs are arranged to minimize coking.

  4. dist_steam.pdf

    Gasoline and Diesel Fuel Update (EIA)

    District Steam Usage Form 1999 Commercial Buildings Energy Consumption Survey (CBECS) 1. Timely submission of this report is mandatory under Public Law 93-275, as amended. 2. This completed questionnaire is due by 3. Data reported on this questionnaire are for the entire building identified in the label to the right. 4. Data may be submitted directly on this questionnaire or in any other format, such as a computer-generated listing, which provides the same i nformation and is conve nient for y

  5. Steam System Survey Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1/263 Steam System Survey Guide Greg Harrell, Ph.D., P.E. DOCUMENT AVAILABILITY Reports produced after January 1, 1996, are generally available free via the U.S. Department of Energy (DOE) Information Bridge. Web site http://www.osti.gov/bridge Reports produced before January 1, 1996, may be purchased by members of the public from the following source. National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone 703-605-6000 (1-800-553-6847) TDD 703-487-4639 Fax

  6. Steam-system upgrades | Open Energy Information

    Open Energy Info (EERE)

    upgrades Jump to: navigation, search TODO: Add description List of Steam-system upgrades Incentives Retrieved from "http:en.openei.orgwindex.php?titleSteam-systemupgrades&old...

  7. Benchmark the Fuel Cost of Steam Generation

    Broader source: Energy.gov [DOE]

    This tip sheet on benchmarking the fuel cost of steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  8. Steam Digest 2001: Office of Industrial Technologies

    SciTech Connect (OSTI)

    None, None

    2002-01-01

    Steam Digest 2001 chronicles Best Practices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  9. Standard Steam Trust LLC | Open Energy Information

    Open Energy Info (EERE)

    (Redirected from Standard Steam Trust) Jump to: navigation, search Name: Standard Steam Trust LLC Place: Denver, Colorado Sector: Geothermal energy Product: Subsidiary of...

  10. Steam boosted internal combustion engine

    SciTech Connect (OSTI)

    Green, M.A.

    1987-01-20

    A device is described to supplement the power produced by burning fuel in an internal combustion engine with steam, the device comprising: a means for producing a constant flow of water past a boiler means; a means for allowing the water to flow in the direction of the boiler; a boiler means external to the internal combustion engine to convert the water into superheated steam; a means for controlling the pressure of the water such that the water pressure is greater than the pressure of the steam produced by the boiler; and a means for injection of the superheated steam directly into a cylinder of the internal combustion engine, a means for producing a constant flow of water at a pressure greater than the pressure of the superheated steam, wherein the constant flow means at greater pressure comprises a chamber with a gaseous component, with the gaseous component being of constant volume and exerting constant pressure upon water within the chamber.

  11. Thermal valorization of post-consumer film waste in a bubbling bed gasifier

    SciTech Connect (OSTI)

    Martnez-Lera, S., E-mail: susanamartinezlera@gmail.com; Torrico, J.; Pallars, J.; Gil, A.

    2013-07-15

    Highlights: Film waste from packaging is a common waste, a fraction of which is not recyclable. Gasification can make use of the high energy value of the non-recyclable fraction. This waste and two reference polymers were gasified in a bubbling bed reactor. This experimental research proves technical feasibility of the process. It also analyzes impact of composition and ER on the performance of the plant. - Abstract: The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes. A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m{sup 3} and cold gas efficiencies up to 60%.

  12. Development of the first demonstration CFB boiler for gas and steam cogeneration

    SciTech Connect (OSTI)

    Fang, M; Luo, Z.; Li, X.; Wang, Q.; Shi, Z.; Ni, M.; Cen, K.

    1997-12-31

    To solve the shortage of gas and steam supply in the small towns of the country, a new gas steam cogeneration system has been developed. On the basis of the fundamental research on the system, a demonstration gas steam cogeneration system has been designed. As the phase 1 of the project, a 75t/h demonstration CFB boiler for gas steam cogeneration has been erected and operated at Yangzhong Thermal Power Plant of China. This paper introduces the first 75t/h demonstration CFB boiler for gas steam cogeneration. Due to the need of gas steam cogeneration process, the boiler has the features of high temperature cyclone separation, high solid recycle ratio, staged combustion and an external heat exchanger adjusting bed temperature and heat load. The operation results show that the boiler has wide fuel adaptability and the heating value of the coal changes from 14MJ/Kg to 25MJ/Kg. The heat load changes from 85t/h to 28t/h while steam parameter is maintained at the normal conditions. The combustion efficiency of the boiler attain 98%. The boiler design and operation experiences may be a guide to the design and operation of larger CFB units in the future.

  13. Steam Pressure Reduction: Opportunities and Issues; A BestPractices Steam Technical Brief

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BestPractices Steam Technical Brief Steam Pressure Reduction: Opportunities and Issues BestPractices Technical Brief Steam Pressure Reduction: Opportunities and Issues  Steam Pressure Reduction: Opportunities and Issues  Introduction Steam generation systems are found in industry and in the commercial and institutional sectors. Some of these plants employ large watertube boilers to produce saturated steam at pressures of 250 pounds per square inch (psig) or lower. They distribute steam

  14. CX-004445: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Waste Treatment Plant Secondary Waste Radioactive Fluidized Bed Steam Reforming (Module A)CX(s) Applied: B3.6Date: 10/25/2010Location(s): Aiken, South CarolinaOffice(s): Savannah River Operations Office

  15. Trends in packaged steam generators

    SciTech Connect (OSTI)

    Ganapathy, V. [ABCO Industries, Abilene, TX (United States)

    1996-09-01

    Oil and gas-fired packaged steam generators are used in many industrial plants. They generate saturated or superheated steam up to 250,000 lb/hr, 1000 psig, and 950 F. They may be used for continuous steam generation or as standby boilers in cogeneration systems. Numerous variables affect the design of this equipment. A few important considerations should be addressed at an early point by the plant engineer specifying or evaluating equipment options. These considerations include trends such as customized designs that minimize operating costs and ensure emissions regulations are met. The paper discusses efficiency considerations first.

  16. Closures for Course-Grid Simulation of Fluidized Gas-Particle Flows

    SciTech Connect (OSTI)

    Sankaran Sundaresan

    2010-02-14

    Gas-particle flows in fluidized beds and riser reactors are inherently unstable, and they manifest fluctuations over a wide range of length and time scales. Two-fluid models for such flows reveal unstable modes whose length scale is as small as ten particle diameters. Yet, because of limited computational resources, gas-particle flows in large fluidized beds are invariably simulated by solving discretized versions of the two-fluid model equations over a coarse spatial grid. Such coarse-grid simulations do not resolve the small-scale spatial structures which are known to affect the macroscale flow structures both qualitatively and quantitatively. Thus there is a need to develop filtered two-fluid models which are suitable for coarse-grid simulations and capturing the effect of the small-scale structures through closures in terms of the filtered variables. The overall objective of the project is to develop validated closures for filtered two-fluid models for gas-particle flows, with the transport gasifier as a primary, motivating example. In this project, highly resolved three-dimensional simulations of a kinetic theory based two-fluid model for gas-particle flows have been performed and the statistical information on structures in the 100-1000 particle diameters length scale has been extracted. Based on these results, closures for filtered two-fluid models have been constructed. The filtered model equations and closures have been validated against experimental data and the results obtained in highly resolved simulations of gas-particle flows. The proposed project enables more accurate simulations of not only the transport gasifier, but also many other non-reacting and reacting gas-particle flows in a variety of chemical reactors. The results of this study are in the form of closures which can readily be incorporated into existing multi-phase flow codes such as MFIX (www.mfix.org). Therefore, the benefits of this study can be realized quickly. The training provided by this project has prepared a PhD student to enter research and development careers in DOE laboratories or chemicals/energy-related industries.

  17. Wet-steam erosion of steam turbine disks and shafts

    SciTech Connect (OSTI)

    Averkina, N. V.; Zheleznyak, I. V.; Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G.; Shishkin, V. I.

    2011-01-15

    A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

  18. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1985-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  19. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1983-01-01

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  20. Technology Maturation Plans (TMPs) | Department of Energy

    Energy Savers [EERE]

    Tank Waste and Waste Processing » Technology Maturation Plans (TMPs) Technology Maturation Plans (TMPs) Documents Available for Download November 1, 2007 Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed Steam Reformer System. November 1,

  1. Durable zinc oxide containing sorbents for moving bed and fluid-bed applications

    SciTech Connect (OSTI)

    Siriwardane, R.V.

    1998-12-31

    A series of novel regenerable desulfurization sorbents operational at a wide range of temperatures (260--600 C) has been developed by the in-house research staff at the US Department of Energy`s Federal Energy Technology Center. The sorbent, identified as METC10, has demonstrated very high attrition resistance as well as very high and stable reactivity conducted under numerous testing regimes under both simulated and actual fuel gas conditions. The METC10 sorbent suitable for moving bed reactor applications is the only sorbent which has exceeded all the criteria required for use in the Tampa Electric Company (TECO) Clean Coal Technology (CCT) demonstration project. The required criteria for the TECO project included, a sulfur loading of 6.7 lb/ft{sup 3} while maintaining the outlet H{sub 2}S level < 20 ppmv, attrition of < 5 wt% after 25 cycle test and regeneration under the very drastic conditions of 10% SO{sub 2} at 510 C under 5--7 atmospheres. In addition, the sorbent was also tested at temperatures ranging from 370 C to 260 C with simulated coal gas. At this low temperature, it was possible to achieve a sulfur loading > 6 lb/ft{sup 3}, indicating that the sorbent is suitable for applications over a wide range of temperatures. It was also possible to prepare METC10 sorbent suitable for fluidized/transport reactor bed applications utilizing spray drying technique. These sorbents had both high attrition resistance (> 95%) and high sulfur capacity (> 14 wt%), and showed stable reactivity during multi-cycle testing.

  2. Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

    DOE Patents [OSTI]

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-09-23

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  3. Guide to Orifice Plate Steam Traps

    SciTech Connect (OSTI)

    Oland, C.B.

    2001-01-11

    This guide was prepared to serve as a foundation for making informed decisions about when orifice plate steam traps should be considered for use in new or existing steam systems. It presents background information about different types of steam traps and defines their unique functional and operational characteristics. The advantages and disadvantages associated with using orifice plate steam traps are provided to highlight their capabilities and limitations. Finally, recommendations for using orifice plate steam traps are presented, and possible applications are identified.

  4. Steam System Modeler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam System Modeler Steam System Modeler April 17, 2014 - 11:34am Addthis There is often flexibility in the operational conditions and requirements of any steam system. In order to optimize performance, the impacts of potential adjustments need to be understood individually and collectively. The Steam System Modeler allows you to create up to a 3-pressure-header basic model of your current steam system. A second model can then be created by adjusting a series of characteristics simulating

  5. switched-bed regenerators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    switched-bed regenerators - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  6. Steam reforming catalyst

    DOE Patents [OSTI]

    Kramarz, Kurt W. (Murrysville, PA); Bloom, Ira D. (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Wilkenhoener, Rolf (Oakbrook Terrace, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel. A vapor of the hydrocarbon fuel and steam is brought in contact with a two-part catalyst having a dehydrogenation powder portion and an oxide-ion conducting powder portion at a temperature not less than about 770.degree.C. for a time sufficient to generate the hydrogen rich. The H.sub.2 content of the hydrogen gas is greater than about 70 percent by volume. The dehydrogenation portion of the catalyst includes a group VIII metal, and the oxide-ion conducting portion is selected from a ceramic oxide from the group crystallizing in the fluorite or perovskite structure and mixtures thereof. The oxide-ion conducting portion of the catalyst is a ceramic powder of one or more of ZrO.sub.2, CeO.sub.2, Bi.sub.2 O.sub.3, (BiVO).sub.4, and LaGaO.sub.3.

  7. Thermostatic steam trap

    SciTech Connect (OSTI)

    Anderson, A.H.; Mac Nicol, A.E.

    1987-03-03

    A thermostatic trap is described for a heating system having a feed pipe connected to a source of steam and a discharge pipe for discharge of condensate and comprising: housing means defining a volume and comprising a bowl shaped body, a removable cover therefor, a housing inlet pipe portion projecting from a side wall portion of the body and adapted for connection to the discharge pipe. A housing outlet pipe portion projects from a bottom wall portion of the body, and an outlet orifice defined by the bottom wall portion and extends between the volume and the outlet pipe portion; a valve body means retained within the volume and comprising an end wall, a side wall and a retaining ring portion that together define a valve chamber. The end wall defines a valve inlet opening communicating with the chamber and an annular valve seat within the chamber and encircling the valve inlet opening. The valve body means comprises a valve outlet pipe that defines a valve outlet opening axially aligned with the valve inlet opening and communicating with the chamber, the outlet pipe being fixed in the outlet orifice; a resilient, annular seal means disposed within the valve chamber and encircling the valve inlet opening; and a bi-metallic disc disposed within the valve chamber between the annular seal means and the outlet opening and having an outer peripheral portion retained by the retaining ring portion of the valve body means.

  8. Inspect and Repair Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inspect and Repair Steam Traps Inspect and Repair Steam Traps This tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #1 PDF icon Inspect and Repair Steam Traps (January 2012) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam Recover Heat

  9. Deaerators in Industrial Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deaerators in Industrial Steam Systems Deaerators in Industrial Steam Systems This tip sheet on deaerators provides how-to advice for improving industrial steam systems using...

  10. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    Broader source: Energy.gov [DOE]

    This tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  11. Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed

    SciTech Connect (OSTI)

    Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li

    2008-05-15

    Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

  12. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M.; Saccani, C.

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  13. How three smart managers control steam costs

    SciTech Connect (OSTI)

    Kendall, R.

    1982-11-01

    Three steam-intensive companies report innovative ways to reduce steam-production costs. Goodyear Tire and Rubber Co. concentrated on regular maintenance, process modifications, and heat recovery, but also has an on-going policy of seeking further cost savings. Future efforts will explore computer-based boiler controls. Zenith Radio Corporation's color picture tube-making process uses 12% less steam after 700 mechanical steam traps were replaced with fixed-orifice traps. Petro-Tex Chemical Corp. reduced steam costs by monitoring and optimizing process units and by making capital investments to improve steam management. (DCK)

  14. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  15. Use Steam Jet Ejectors or Thermoscompressors to Reduce Venting of Low-Pressure Steam - Steam Tip Sheet #29

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  16. Combine waste-to-energy, recycling with fluid-bed boiler

    SciTech Connect (OSTI)

    Murphy, M.L.

    1995-04-01

    This article describes a plant that will be the first to incorporate a fluidized-bed boiler to burn refuse-derived fuel exclusively. An effective long-term solid-waste management program will soon be a reality for Bladen, Cumberland, and Hoke counties, North Carolina. The key element of the program is a 600-ton/day waste-to-energy (WTE) facility, scheduled to begin commercial operation later this year. The BCH Energy project, which gets its name from the initials of the three counties it serves, will become the first fluidized-bed boiler in the US designed to be fueled solely by refuse-derived fuel (RDF). As such, it provides an innovative and efficient approach to solid-waste management in several ways: (1) Maximizes community participation in a recovery and recycling effort. (2) Maximizes additional waste handling and hauling efforts. (3) Significantly reducing waste flow into landfill. (4) Eliminating use of fossil fuel for a nearby chemical plant`s energy load. (5) Substantially improves air quality through use of the latest combustion and emissions control technology.

  17. NUCLEAR FLASH TYPE STEAM GENERATOR

    DOE Patents [OSTI]

    Johns, F.L.; Gronemeyer, E.C.; Dusbabek, M.R.

    1962-09-01

    A nuclear steam generating apparatus is designed so that steam may be generated from water heated directly by the nuclear heat source. The apparatus comprises a pair of pressure vessels mounted one within the other, the inner vessel containing a nuclear reactor heat source in the lower portion thereof to which water is pumped. A series of small ports are disposed in the upper portion of the inner vessel for jetting heated water under pressure outwardly into the atmosphere within the interior of the outer vessel, at which time part of the jetted water flashes into steam. The invention eliminates the necessity of any intermediate heat transfer medium and components ordinarily required for handling that medium. (AEC)

  18. Method for packing chromatographic beds

    DOE Patents [OSTI]

    Freeman, David H. (Potomac, MD); Angeles, Rosalie M. (Germantown, MD); Keller, Suzanne (Rockville, MD)

    1991-01-01

    Column chromatography beds are packed through the application of static force. A slurry of the chromatography bed material and a non-viscous liquid is filled into the column plugged at one end, and allowed to settle. The column is transferred to a centrifuge, and centrifuged for a brief period of time to achieve a predetermined packing level, at a range generally of 100-5,000 gravities. Thereafter, the plug is removed, other fixtures may be secured, and the liquid is allowed to flow out through the bed. This results in an evenly packed bed, with no channeling or preferential flow characteristics.

  19. Device and Method for Fluidizing and Coating of Ultrafine Particles |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Device and Method for Fluidizing and Coating of Ultrafine Particles Technology available for licensing: An ultrathin surface coating composed of metal oxides that, when applied to granular electrode materials on a large scale, promises to solve the structural instability of electrode materials and the resulting rapid fade of cell capacity at high voltages and high temperatures in lithium-ion batteries A low-cost, scalable process for increasing structural

  20. Industrial Steam System Process-Control Schemes

    Broader source: Energy.gov [DOE]

    This brief provides a basic understanding of the different process-control schemes used in a typical steam system.

  1. Best Management Practice #8: Steam Boiler Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  2. Dynamic bed reactor

    DOE Patents [OSTI]

    Stormo, Keith E. (Moscow, ID)

    1996-07-02

    A dynamic bed reactor is disclosed in which a compressible open cell foam matrix is periodically compressed and expanded to move a liquid or fluid through the matrix. In preferred embodiments, the matrix contains an active material such as an enzyme, biological cell, chelating agent, oligonucleotide, adsorbent or other material that acts upon the liquid or fluid passing through the matrix. The active material may be physically immobilized in the matrix, or attached by covalent or ionic bonds. Microbeads, substantially all of which have diameters less than 50 microns, can be used to immobilize the active material in the matrix and further improve reactor efficiency. A particularly preferred matrix is made of open cell polyurethane foam, which adsorbs pollutants such as polychlorophenol or o-nitrophenol. The reactors of the present invention allow unidirectional non-laminar flow through the matrix, and promote intimate exposure of liquid reactants to active agents such as microorganisms immobilized in the matrix.

  3. Materials Performance in USC Steam

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk

    2010-05-01

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 C).

  4. National SCADA Test Bed | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cybersecurity Energy Delivery Systems Cybersecurity National SCADA Test Bed National SCADA Test Bed Created in 2003, the National SCADA Test Bed (NSTB) is a one-of-a-kind ...

  5. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  6. Steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian David (Mauldin, SC); Barb, Kevin Joseph (Halfmoon, NY); Li, Ming Cheng (Cincinnati, OH); Hyde, Susan Marie (Schenectady, NY); Mashey, Thomas Charles (Coxsackie, NY); Wesorick, Ronald Richard (Albany, NY); Glynn, Christopher Charles (Hamilton, OH); Hemsworth, Martin C. (Cincinnati, OH)

    2002-01-01

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows.

  7. Closed loop steam cooled airfoil

    DOE Patents [OSTI]

    Widrig, Scott M.; Rudolph, Ronald J.; Wagner, Gregg P.

    2006-04-18

    An airfoil, a method of manufacturing an airfoil, and a system for cooling an airfoil is provided. The cooling system can be used with an airfoil located in the first stages of a combustion turbine within a combined cycle power generation plant and involves flowing closed loop steam through a pin array set within an airfoil. The airfoil can comprise a cavity having a cooling chamber bounded by an interior wall and an exterior wall so that steam can enter the cavity, pass through the pin array, and then return to the cavity to thereby cool the airfoil. The method of manufacturing an airfoil can include a type of lost wax investment casting process in which a pin array is cast into an airfoil to form a cooling chamber.

  8. Insulate Steam Distribution and Condensate Return Lines | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Insulate Steam Distribution and Condensate Return Lines Insulate Steam Distribution and Condensate Return Lines This tip sheet on insulating steam distribution and condensate return lines provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #2 PDF icon Insulate Steam Distribution and Condensate Return Lines (January 2012) More Documents & Publications Use a Vent Condenser to Recover Flash Steam Energy

  9. Consider Steam Turbine Drives for Rotating Equipment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Turbine Drives for Rotating Equipment Consider Steam Turbine Drives for Rotating Equipment This tip sheet outlines the benefits of steam turbine drives for rotating equipment as part of optimized steam systems. STEAM TIP SHEET #21 PDF icon Consider Steam Turbine Drives for Rotating Equipment (January 2012) More Documents & Publications Improving Steam System Performance: A Sourcebook for Industry, Second Edition Adjustable Speed Drive Part-Load Efficiency Benchmark the Fuel Cost of

  10. Steam System Energy Conservation Measures

    Energy Science and Technology Software Center (OSTI)

    2010-12-31

    This software requires inputs of simple system inventory information and calculates the energy and cost benefits of various retrofit opportunities. This tool includes energy conservation measures for: fixing steam leaks. This tool calculates energy savings, demand reduction, cost savings, and building life cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits of a project.

  11. Steam Turbine Materials and Corrosion

    SciTech Connect (OSTI)

    Holcomb, G.H.; Hsu, D.H.

    2008-07-01

    Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energys Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760 C. In prior years this project examined the steamside oxidation of alloys for use in high- and intermediate-pressure USC turbines. This steamside oxidation research is continuing and progress is presented, with emphasis on chromia evaporation.

  12. Significant Silica Solubility in Geothermal Steam

    SciTech Connect (OSTI)

    James, Russell

    1986-01-21

    Although it is widely believed that silica solubility in low pressure (5 to 10 bar) geothermal steam is negligible, when one takes into account steam flows exceeding 10 million tonnes a year--at Wairakei, for instance--it is found that the amount transmitted in the vapor has the potential to give significant deposits on turbine nozzles and blades. A 150 MWe power station, when based on flows from a hot water reservoir at (a) 250 C or (b) 315 C, and with separator pressures of 6 bar, is found to carry about 100 and 200 kg/year respectively in the steam phase. In the case of a similar sized station exploiting a dry steam reservoir such as The Geysers, equivalent silica flows are obtained, dissolved in steam and carried as dust--the latter as solid particles precipitating from the vapor en route from source to turbine, and not preexisting in the formations as is commonly considered. Choking or coating of subterranean rock near such dry steam wells due to exsolving silica, may be the principal cause of declining steam discharge under production. Silica from completely dry or superheated steam can also seal the cap and sides of steam reservoirs when expanding below the criticus temperature (236 C) in a way previously thought possible only by hot water or wet steam.

  13. MODELING AND SIMULATION OF SOLID FLUIDIZATION IN A RESIN COLUMN

    SciTech Connect (OSTI)

    Lee, S.

    2014-06-24

    The objective of the present work is to model the resin particles within the column during fluidization and sedimentation processes using computation fluid dynamics (CFD) approach. The calculated results will help interpret experimental results, and they will assist in providing guidance on specific details of testing design and establishing a basic understanding of particles hydraulic characteristics within the column. The model is benchmarked against the literature data and the test data (2003) conducted at Savannah River Site (SRS). The paper presents the benchmarking results and the modeling predictions of the SRS resin column using the improved literature correlations applicable for liquid-solid granular flow.

  14. Optical steam quality measurement system and method

    DOE Patents [OSTI]

    Davidson, James R.; Partin, Judy K.

    2006-04-25

    An optical measurement system is presented that offers precision on-line monitoring of the quality of steam. Multiple wavelengths of radiant energy are passed through the steam from an emitter to a detector. By comparing the amount of radiant energy absorbed by the flow of steam for each wavelength, a highly accurate measurement of the steam quality can be determined on a continuous basis in real-time. In an embodiment of the present invention, the emitter, comprises three separate radiant energy sources for transmitting specific wavelengths of radiant energy through the steam. In a further embodiment, the wavelengths of radiant energy are combined into a single beam of radiant energy for transmission through the steam using time or wavelength division multiplexing. In yet a further embodiment, the single beam of radiant energy is transmitted using specialized optical elements.

  15. Benchmark the Fuel Cost of Steam Generation - Steam Tip Sheet #15

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on benchmarking the fuel cost of steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  16. Steam Technical Brief: How to Calculate the True Cost of Steam

    SciTech Connect (OSTI)

    2010-06-25

    This BestPractice Steam Technical Brief helps you calculate the true cost of steam. Knowing the correct cost is important for many reasons and all of them have to do with improving the company's bottom line.

  17. Steam Systems, Retrofit Measure Packages, Hydronic Systems

    Energy Savers [EERE]

    Program www.buildingamerica.gov Decker Homes Buildings Technologies Program Steam Systems, Retrofit Measure Packages, Hydronic Systems Russell Ruch Elevate Energy Peter Ludwig Elevate Energy July 16, 2014 Building America Webinar: Retrofitting Central Space Conditioning Strategies for Multifamily Buildings Contents * Retrofit Measure Packages for steam and hydronic MF buildings that save 25-30% * System Balancing * Steam * Hydronic 2 | Building America Program www.buildingamerica.gov Background

  18. Industrial Steam System Heat-Transfer SolutionsL: A BestPractices Steam Technical Brief

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Technical Brief Industrial Steam System Heat-Transfer Solutions U.S. Department of Energy Energy Efficiency and Renewable Energy Bringing you a prosperous future where energy is clean, abundant, reliable, and affordable Industrial Technologies Program Boosting the productivity and competitiveness of U.S. industry through improvements in energy and environmental performance Industrial Steam System Heat-Transfer Solutions 1 Introduction This Best Practices Steam Technical Brief provides an

  19. Steam Technical Brief: Industrial Heat Pumps for Steam and Fuel Savings

    SciTech Connect (OSTI)

    2010-06-25

    The purpose of this Steam Techcial Brief is to introduce heat-pump technology and its applicaiton in industrial processes.

  20. Greenville Steam Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleGreenvilleSteamBiomassFacility&oldid397532" Feedback Contact needs updating Image needs updating...

  1. Covered Product Category: Commercial Steam Cookers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, which are covered by the ENERGY STAR program.

  2. Warm or Steaming Ground | Open Energy Information

    Open Energy Info (EERE)

    causing steam to form when water is present. Other definitions:Wikipedia Reegle Modern Geothermal Features Typical list of modern geothermal features Hot Springs Fumaroles...

  3. Minimize Boiler Blowdown - Steam Tip Sheet #9

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Standard Steam Trust LLC | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Standard Steam Trust LLC Place: Denver, Colorado Sector: Geothermal energy Product: Subsidiary of Denver-based geothermal project developer, Terra...

  5. Designing an ultrasupercritical steam turbine

    SciTech Connect (OSTI)

    Klotz, H.; Davis, K.; Pickering, E.

    2009-07-15

    Carbon emissions produced by the combustion of coal may be collected and stored in the future, but a better approach is to reduce the carbon produced through efficient combustion technologies. Increasing the efficiency of new plants using ultrasupercritical (USC) technology will net less carbon released per megawatt-hour using the world's abundant coal reserves while producing electricity at the lowest possible cost. The article shows how increasing the steam turbine operating conditions for a new USC project in the USA and quantify the potential CO{sub 2} reduction this advanced design makes possible. 7 figs., 3 tabs.

  6. Steam turbine materials and corrosion

    SciTech Connect (OSTI)

    Holcomb, G.R.; Alman, D.E.; Dogan, O.N.; Rawers, J.C.; Schrems, K.K.; Ziomek-Moroz, M.

    2007-12-01

    Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energys Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which would require steam temperatures of up to 760C. This project examines the steamside oxidation of candidate alloys for use in USC systems, with emphasis placed on applications in high- and intermediate-pressure turbines. As part of this research a concern has arisen about the possibility of high chromia evaporation rates of protective scales in the turbine. A model to calculate chromia evaporation rates is presented.

  7. Benchmark the Fuel Cost of Steam Generation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benchmark the Fuel Cost of Steam Generation Benchmark the Fuel Cost of Steam Generation This tip sheet on benchmarking the fuel cost of steam provides how-to advice for improving...

  8. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David; Baddour, Frederick G.; Sahir, Asad

    2015-10-06

    Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design reportmore » led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this study is based on future projections, the impacts of uncertainties in the underlying assumptions are quantified via sensitivity analysis. As a result, this analysis indicates that catalyst researchers should prioritize by: carbon efficiency > catalyst cost > catalyst lifetime, after initially testing for basic operational feasibility.« less

  9. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility

    SciTech Connect (OSTI)

    Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David; Baddour, Frederick G.; Sahir, Asad

    2015-10-06

    Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this study is based on future projections, the impacts of uncertainties in the underlying assumptions are quantified via sensitivity analysis. As a result, this analysis indicates that catalyst researchers should prioritize by: carbon efficiency > catalyst cost > catalyst lifetime, after initially testing for basic operational feasibility.

  10. Subject: Yellow Alert- Steam Valve Near-Miss Title: Yellow Alert- Steam Valve Near-Miss

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yellow Alert- Steam Valve Near-Miss Title: Yellow Alert- Steam Valve Near-Miss Date: 1/7/2002 Identifier: RFETS-02-0004 Lessons Learned: A near miss during troubleshooting of a steam control valve shows the importance of complete, detailed planning and clear communication between the individuals involved in the work. Discussion: On 12/12/01 while maintenance personnel were de-coupling an actuator from the facility service steam 100-psi steam control valve in order to troubleshoot a problem with

  11. Combine waste-to-energy, recycling with fluid-bed boiler

    SciTech Connect (OSTI)

    Murphy, M.L.

    1995-09-01

    An effective long-term solid-waste management program will soon be a reality for Bladen, Cumberland, and Hoke counties, North Carolina. The key element of the program is a 600-ton/day waste-to-energy (WTE) facility, scheduled to begin commercial operation later this year. The BCH Energy project, which gets its name from the initials of the three counties it serves, will become the first fluidized-bed boiler in the US designed to be fueled solely by refuse-derived fuel (RDF). As such, it provides an innovative and efficient approach to solid-waste management in several ways: (1) maximimizes community participation in a recovery and recycling effort; (2) maximizes additional waste handling and hauling efforts; (3) significantly reducing waste flow into landfill; (4) eliminating use of fossil fuel for a nearby chemical plant`s energy load; and (5) substantially improves air quality through use of the latest combustoin and emissions control technology.

  12. Novel Magnetically Fluidized Bed Reactor Development for the Looping Process: Coal to Hydrogen Production R&D

    SciTech Connect (OSTI)

    Mei, Renwei; Hahn, David; Klausner, James; Petrasch, Jorg; Mehdizadeh, Ayyoub; Allen, Kyle; Rahmatian, Nima; Stehle, Richard; Bobek, Mike; Al-Raqom, Fotouh; Greek, Ben; Li, Like; Chen, Chen; Singh, Abhishek; Takagi, Midori; Barde, Amey; Nili, Saman

    2013-09-30

    The coal to hydrogen project utilizes the iron/iron oxide looping process to produce high purity hydrogen. The input energy for the process is provided by syngas coming from gasification process of coal. The reaction pathways for this process have been studied and favorable conditions for energy efficient operation have been identified. The Magnetically Stabilized Porous Structure (MSPS) is invented. It is fabricated from iron and silica particles and its repeatable high performance has been demonstrated through many experiments under various conditions in thermogravimetric analyzer, a lab-scale reactor, and a large scale reactor. The chemical reaction kinetics for both oxidation and reduction steps has been investigated thoroughly inside MSPS as well as on the surface of very smooth iron rod. Hydrogen, CO, and syngas have been tested individually as the reducing agent in reduction step and their performance is compared. Syngas is found to be the most pragmatic reducing agent for the two-step water splitting process. The transport properties of MSPS including porosity, permeability, and effective thermal conductivity are determined based on high resolution 3D CT x-ray images obtained at Argonne National Laboratory and pore-level simulations using a lattice Boltzmann Equation (LBE)-based mesoscopic model developed during this investigation. The results of those measurements and simulations provide necessary inputs to the development of a reliable volume-averaging-based continuum model that is used to simulate the dynamics of the redox process in MSPS. Extensive efforts have been devoted to simulate the redox process in MSPS by developing a continuum model consist of various modules for conductive and radiative heat transfer, fluid flow, species transport, and reaction kinetics. Both the Lagrangian and Eulerian approaches for species transport of chemically reacting flow in porous media have been investigated and verified numerically. Both approaches lead to correct prediction of hydrogen production rates over a large range of experimental conditions in the laboratory scale reactor and the bench-scale reactor. In the economic analysis, a comparison of the hydrogen production plants using iron/iron oxide looping cycle and the conventional process has been presented. Plant configurations are developed for the iron/iron oxide looping cycle. The study suggests a higher electric power generation but a lower hydrogen production efficiency comparing with the conventional process. Additionally, it was shown that the price of H{sub 2} obtained from our reactor can be as low as $1.7/kg, which is 22% lower than the current price of the H{sub 2} obtained from reforming plants.

  13. A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system

    SciTech Connect (OSTI)

    Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

    2000-07-01

    Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

  14. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01

    The objective of this project is to demonstrate that cocombustion of municipal solid waste and oil shale can reduce emissions of gaseous pollutants (SO{sub 2} and HCl) to acceptable levels. Tests in 6- and 15-inch units showed that the oil shale absorbs acid gas pollutants and produces an ash which could be, at the least, disposed of in a normal landfill. Further analysis of the results are underway to estimate scale-up to commercial size. Additional work will be done to evaluate the cementitious properties of oil shale ash.

  15. Method and apparatus for the separation of a gas-solids mixture in a circulating fluidized bed reactor

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, WanWang

    2010-08-10

    The system of the present invention includes a centripetal cyclone for separating particulate material from a particulate laden gas solids stream. The cyclone includes a housing defining a conduit extending between an upstream inlet and a downstream outlet. In operation, when a particulate laden gas-solids stream passes through the upstream housing inlet, the particulate laden gas-solids stream is directed through the conduit and at least a portion of the solids in the particulate laden gas-solids stream are subjected to a centripetal force within the conduit.

  16. Fluidized-bed combustion 1000-hour test program. Volume IV. Engineering details and post-test inspections

    SciTech Connect (OSTI)

    Roberts, A. G.; Barker, S. N.; Phillips, R. N.; Pillai, K. K.; Raven, P.; Wood, P.

    1981-09-01

    Volume IV of the report on the 1000 hour programme consists of three appendices giving details of the enginmering/construction aspects of the plant and reports from Stal-Laval Turbin A.B. Appendix N has been entered individually. (LTN)

  17. Geothermal Steam Act of 1970 | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Steam Act of 1970 Jump to: navigation, search To encourage the development of geothermal energy, the United States government passed the Geothermal Steam Act in 1970...

  18. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Use Vapor Recompression to Recover Low-Pressure Waste Steam Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Consider Installing High-Pressure Boilers with ...

  19. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Presented at the 2007 ...

  20. Integrated vacuum absorption steam cycle gas separation (Patent...

    Office of Scientific and Technical Information (OSTI)

    Integrated vacuum absorption steam cycle gas separation Citation Details In-Document Search Title: Integrated vacuum absorption steam cycle gas separation You are accessing a...

  1. TRANSPORT AND PHASE EQUILIBRIA PROPERITIES FOR STEAM FLOODING...

    Office of Scientific and Technical Information (OSTI)

    TRANSPORT AND PHASE EQUILIBRIA PROPERITIES FOR STEAM FLOODING OF HEAVY OILS Citation Details In-Document Search Title: TRANSPORT AND PHASE EQUILIBRIA PROPERITIES FOR STEAM FLOODING...

  2. Water-Efficient Technology Opportunity: Steam Sterilizer Condensate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Sterilizer Condensate Retrofit Kit Water-Efficient Technology Opportunity: Steam ... sterilizer condensate retrofit kits as a water-saving technology that is relevant to the ...

  3. Steam System Balancing and Tuning for Multifamily Residential...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam System Balancing and Tuning for Multifamily Residential Buildings Chicago, Illinois PROJECT INFORMATION Project Name: Steam System Balancing and Tuning for Multifamily ...

  4. Paducah Package Steam Boilers to Provide Efficiency, Environmental Benefits

    Broader source: Energy.gov [DOE]

    PADUCAH, Ky. – Five modern, modular steam boilers have replaced three larger coal-fired boilers that comprised the steam plant at EM’s Paducah Site.

  5. Steam drying of products containing solvent mixtures

    SciTech Connect (OSTI)

    Pothmann, E.; Schluender, E.U. [Univ. Karlsruhe (Germany). Inst. fuer Thermische Verfahrenstechnik

    1995-12-31

    Drying experiments with single, porous spheres wetted with mixtures of 2-propanol and water were performed using superheated steam, air, or steam-air mixtures as drying agent. Both the drying rate and the moisture composition were determined experimentally for different temperatures and compositions of the drying agent and for different initial compositions of the moisture. It is shown that evaporation of 2-propanol is enhanced by using superheated steam as drying agent instead of air due to steam condensing on the sample. While the overall drying rate increases with rising steam temperature, the evaporation rate of 2-propanol is hardly affected. When drying samples containing mixtures of 2-propanol and water, internal boiling can occur depending on the vapor-liquid equilibrium. Vapor generated inside the sample may cause mechanical dewatering of the sample which greatly increases the drying rate.

  6. Fluidizable particulate materials and methods of making same

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC)

    1999-01-01

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  7. Fluidizable particulate materials and methods of making same

    SciTech Connect (OSTI)

    Gupta, R.P.

    1999-10-26

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  8. Insulate Steam Distribution and Condensate Return Lines, Energy Tips: STEAM, Steam Tip Sheet #2 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Insulate Steam Distribution and Condensate Return Lines Uninsulated steam distribution and condensate return lines are a constant source of wasted energy. The table shows typical heat loss from uninsulated steam distribution lines. Insulation can typically reduce energy losses by 90% and help ensure proper steam pressure at plant equipment. Any surface over 120°F should be insulated, including boiler surfaces, steam and condensate return piping, and fttings. Insulation frequently becomes

  9. Consider Steam Turbine Drives for Rotating Equipment, Energy Tips: STEAM, Steam Tip Sheet #21 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Consider Steam Turbine Drives for Rotating Equipment Steam turbines are well suited as prime movers for driving boiler feedwater pumps, forced or induced-draft fans, blowers, air compressors, and other rotating equipment. This service generally calls for a backpressure noncondensing steam turbine. The low-pressure steam turbine exhaust is available for feedwater heating, preheating of deaerator makeup water, and/or process requirements. Steam turbine drives are equipped with throttling valves

  10. Customizing pays off in steam generators

    SciTech Connect (OSTI)

    Ganapathy, V. (ABCO Industries, Inc., Abilene, TX (United States))

    1995-01-01

    Packaged steam generators are the workhorses of chemical process plants, power plants and cogeneration systems. They are available as oil- or gas-fired models, and are used to generate either high-pressure superheated steam (400 to 1,200 psig, at 500 to 900 F) or saturated steam at low pressures (100 to 300 psig). In today's emission- and efficiency- conscious environment, steam generators have to be custom designed. Gone are the days when a boiler supplier--or for that matter an end user--could look up a model number from a list of standard sizes and select one for a particular need. Thus, before selecting a system, it is desirable to know the features of oil- and gas-fired steam generators, and the important variables that influence their selection, design and performance. It is imperative that all of these data are supplied to the boiler supplier so that the engineers may come up with the right design. Some of the parameters which are discussed in this paper are: duty, steam temperature, steam purity, emissions, and furnace design. Superheaters, economizers, and overall performance are also discussed.

  11. Internal combustion engine injection superheated steam

    SciTech Connect (OSTI)

    Mahoney, F.G.

    1991-01-22

    This patent describes a method for introducing water vapor to the combustion chambers of an internal combustion engine. It comprises: introducing a metered amount of liquid water into a heat exchanger; contacting the heat exchanger directly with hot exhaust gases emanating from the exhaust manifold; maintaining the water in the heat exchanger for a period sufficient to vaporize the water into steam and superheat same; reducing pressure and increasing temperature to create superheated steam; introducing the superheated steam into the air supply proximate to the air induction system, upstream of any carburetion, of the internal combustion engine.

  12. Save Energy Now in Your Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Systems Save Energy Now in Your Steam Systems This brief outlines typical ways to increase steam system efficiency through changes in distribution, generation, and recovery. PDF icon Save Energy Now in Your Steam Systems (January 2006) More Documents & Publications Save Energy Now in Your Process Heating Systems Install an Automatic Blowdown-Control System

  13. Assessing the impact of energy losses in steam systems

    SciTech Connect (OSTI)

    Fischer, D.W.

    1995-07-10

    This article examines the impact of steam leaks on the efficiency of the process steam system. The topics include steam losses under various operating conditions and orifice sizes, failed drip traps, the significance of small leaks, energy losses and pollutants generated by trap failure, steps to take to conserve steam and energy through repair and maintenance.

  14. Industrial Heat Pumps for Steam and Fuel Savings: A BestPractices Steam Technical Brief

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Pumps for Steam and Fuel Savings U.S. Department of Energy Energy Efficiency and Renewable Energy Bringing you a prosperous future where energy is clean, abundant, reliable, and affordable Industrial Technologies Program Boosting the productivity and competitiveness of U.S. industry through improvements in energy and environmental performance Industrial Heat Pumps for Steam and Fuel Savings 1 Industrial Heat Pumps for Steam and Fuel Savings Industrial heat pumps are a class of active

  15. Benchmark the Fuel Cost of Steam Generation, Energy Tips: STEAM, Steam Tip Sheet #15 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Benchmark the Fuel Cost of Steam Generation Benchmarking the fuel cost of steam generation, in dollars per 1,000 pounds ($/1,000 lb) of steam, is an effective way to assess the effciency of your steam system. This cost is dependent upon fuel type, unit fuel cost, boiler effciency, feedwater temperature, and steam pressure. This calculation provides a good frst approximation for the cost of generating steam and serves as a tracking device to allow for boiler performance monitoring. Table 1

  16. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    DOE Patents [OSTI]

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  17. Hartford Steam Co | Open Energy Information

    Open Energy Info (EERE)

    Co Jump to: navigation, search Name: Hartford Steam Co Place: Connecticut Phone Number: 860-725-7005 Website: www.hartfordsteam.com Outage Hotline: 860-725-7005 References: EIA...

  18. Consider Steam Turbine Drives for Rotating Equipment

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on steam turbine drives for rotating equipment provides how-to advice for improving the system using low-cost, proven practices and technologies.

  19. Steam turbine upgrading: low-hanging fruit

    SciTech Connect (OSTI)

    Peltier, R.

    2006-04-15

    The thermodynamic performance of the steam turbine, more than any other plant component, determines overall plant efficiency. Upgrading steam path components and using computerized design tools and manufacturing techniques to minimise internal leaks are two ways to give tired steam turbines a new lease on life. The article presents three case studies that illustrate how to do that. These are at Unit 1 of Dairyland's J.P. Madgett Station in Alma, WI, a coal-fired subcritical steam plant; the four units at AmerenUE's 600 MW coal-fired Labadie plant west of St. Louis; and Unit 3 of KeyPlan Corp's Northport Power Station on Long Island. 8 figs.

  20. Industrial Steam System Heat-Transfer Solutions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat-Transfer Solutions Industrial Steam System Heat-Transfer Solutions This brief provides an overview of considerations for selecting the best heat-transfer equipment for various steam systems and applications. PDF icon Industrial Steam System Heat-Transfer Solutions (June 2003) More Documents & Publications Industrial Steam System Process-Control Schemes Considerations When Selecting a Condensing Economizer Steam Pressure Reduction: Opportunities and Issues

  1. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam, Energy Tips: STEAM, Steam Tip Sheet #29 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam Large industrial plants often vent signifcant quantities of low-pressure steam to the atmosphere, wasting energy, water, and water-treatment chemicals. Recovery of the latent heat content of low-pressure steam reduces the boiler load, resulting in energy and fuel cost savings. Low-pressure steam's potential uses include driving evaporation and distillation processes, producing hot water, space heating,

  2. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  3. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, James F. (Bonneville County, ID); Koenig, John F. (Idaho Falls, ID)

    1985-01-01

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  4. Oxidation of advanced steam turbine alloys

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.

    2006-03-01

    Advanced or ultra supercritical (USC) steam power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energys Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

  5. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, J.F.; Koenig, J.F.

    1984-05-29

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  6. Battery using a metal particle bed electrode

    DOE Patents [OSTI]

    Evans, James V.; Savaskan, Gultekin

    1991-01-01

    A zinc-air battery in a case including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit.

  7. Z-Bed Recovery Water Disposal

    Office of Environmental Management (EM)

    Z-Bed Recovery Water Disposal Tritium Programs Engineering Louis Boone Josh Segura Savannah River Nuclear Solutions, LLC M-TRT-H-00087 Rev 0 Date: 4/10/2014 Tritium Facilities Purpose * Provide detailed explanation of the plan to capture and dispose of Z-Bed Recovery (ZR) water. Agenda * New Technology * Background * Z-Bed Recovery Water Disposal * Cost Saving * Alternatives New Technology * Dry Disconnect Fittings * Double Door Transfer Container (DDTC) * Bucket (Stainless Steel ASME pressure

  8. Battery using a metal particle bed electrode

    DOE Patents [OSTI]

    Evans, J.V.; Savaskan, G.

    1991-04-09

    A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

  9. National SCADA Test Bed | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cybersecurity » Energy Delivery Systems Cybersecurity » National SCADA Test Bed National SCADA Test Bed Created in 2003, the National SCADA Test Bed (NSTB) is a one-of-a-kind national resource that draws on the integrated expertise and capabilities of the Argonne, Idaho, Lawrence Berkeley, Los Alamos, Oak Ridge, Pacific Northwest, and Sandia National Laboratories to address the cybersecurity challenges of energy delivery systems. Core and Frontier Research The NSTB core capabilities combine a

  10. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in themore » mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.« less

  11. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    SciTech Connect (OSTI)

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in the mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.

  12. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  13. Ultra supercritical turbines--steam oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

    2004-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  14. Model-free adaptive control of advanced power plants

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L.; Wang, Qiang

    2015-08-18

    A novel 3-Input-3-Output (3.times.3) Model-Free Adaptive (MFA) controller with a set of artificial neural networks as part of the controller is introduced. A 3.times.3 MFA control system using the inventive 3.times.3 MFA controller is described to control key process variables including Power, Steam Throttle Pressure, and Steam Temperature of boiler-turbine-generator (BTG) units in conventional and advanced power plants. Those advanced power plants may comprise Once-Through Supercritical (OTSC) Boilers, Circulating Fluidized-Bed (CFB) Boilers, and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  15. CERTS Microgrid Laboratory Test Bed

    SciTech Connect (OSTI)

    Eto, Joe; Lasseter, Robert; Schenkman, Ben; Stevens, John; Klapp, Dave; Volkommer, Harry; Linton, Ed; Hurtado, Hector; Roy, Jean

    2009-06-18

    The objective of the CERTS Microgrid Test Bed project was to enhance the ease of integrating energy sources into a microgrid. The project accomplished this objective by developing and demonstrating three advanced techniques, collectively referred to as the CERTS Microgrid concept, that significantly reduce the level of custom field engineering needed to operate microgrids consisting of generating sources less than 100kW. The techniques comprising the CERTS Microgrid concept are: 1) a method for effecting automatic and seamless transitions between grid-connected and islanded modes of operation, islanding the microgrid's load from a disturbance, thereby maintaining a higher level of service, without impacting the integrity of the utility's electrical power grid; 2) an approach to electrical protection within a limited source microgrid that does not depend on high fault currents; and 3) a method for microgrid control that achieves voltage and frequency stability under islanded conditions without requiring high-speed communications between sources. These techniques were demonstrated at a full-scale test bed built near Columbus, Ohio and operated by American Electric Power. The testing fully confirmed earlier research that had been conducted initially through analytical simulations, then through laboratory emulations,and finally through factory acceptance testing of individual microgrid components. The islanding and resychronization method met all Institute of Electrical and Electronics Engineers Standard 1547 and power quality requirements. The electrical protection system was able to distinguish between normal and faulted operation. The controls were found to be robust under all conditions, including difficult motor starts and high impedance faults. The results from these tests are expected to lead to additional testing of enhancements to the basic techniques at the test bed to improve the business case for microgrid technologies, as well to field demonstrations involving microgrids that involve one or more of the CERTS Microgrid concepts. Future planned microgrid work involves unattended continuous operation of the microgrid for 30 to 60 days to determine how utility faults impact the operation of the microgrid and to gage the power quality and reliability improvements offered by microgrids.

  16. Cover Heated, Open Vessels - Steam Tip Sheet #19

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on covering heated, open vessels provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  17. Industrial Heat Pumps for Steam and Fuel Savings | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Pumps for Steam and Fuel Savings Industrial Heat Pumps for Steam and Fuel Savings This brief introduces heat-pump technology and its application in industrial processes as ...

  18. Install and Automatic Blowdown Control System - Steam Tip Sheet #23

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on installing automatic blowdown controls provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  19. Review of Orifice Plate Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of Orifice Plate Steam Traps Review of Orifice Plate Steam Traps This guide was prepared to serve as a foundation for making informed decisions about when orifice plate...

  20. Pre-In-Plant Training Webinar (Steam) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Jim, Rich, and Mark have been excellent. An asset here, Deb and Steve at the corporate ... Steam trap's jobs are obviously several, but the cardinal two are trap the steam and make ...

  1. Use a Vent Condenser to Recover Flash Steam Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Vent Condenser to Recover Flash Steam Energy Use a Vent Condenser to Recover Flash Steam Energy This tip sheet on using vent condensers to recover flash steam energy provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #13 PDF icon Use a Vent Condenser to Recover Flash Steam Energy (January 2012) More Documents & Publications Recover Heat from Boiler Blowdown Deaerators in Industrial Steam Systems Use Steam Jet

  2. Building Controls Virtual Test Bed

    Energy Science and Technology Software Center (OSTI)

    2008-04-01

    The Building Controls Virtual Test Bed (BCVTB) is a modular software environment that is based on the Ptolemy II software environment. The BCVTB can be used for design and analysis of heterogenous systems, such as building energy and controls systems. Our additions to Ptolemy II allow users to Couple to Ptolemy II simulation software such as EnergyPlus, MATLAB/Simulink or Dymola for data exchange during run-time. Future versions of the BCVTS will also contain an interfacemore » to BACnet which is a communication protocol for building Control systems, and interfaces to digital/analog converters that allow communication with controls hardware. Through Ptolemy II, the BCVTB provides a graphical model building environment, synchronizes the exchanged data and visualizes the system evolution during run- time.« less

  3. CERTS Microgrid Laboratory Test Bed

    SciTech Connect (OSTI)

    ETO, J.; LASSETER, R.; SCHENKMAN, B.; STEVENS, J.; KLAPP, D.; VOLKOMMER, H.; LINTON, E.; HURTADO, H.; ROY, J.

    2010-06-08

    The objective of the CERTS Microgrid Test Bed project was to enhance the ease of integrating energy sources into a microgrid. The project accomplished this objective by developing and demonstrating three advanced techniques, collectively referred to as the CERTS Microgrid concept, that significantly reduce the level of custom field engineering needed to operate microgrids consisting of generating sources less than 100kW. The techniques comprising the CERTS Microgrid concept are: 1 a method for effecting automatic and seamless transitions between grid-connected and islanded modes of operation, islanding the microgrid's load from a disturbance, thereby maintaining a higher level of service, without impacting the integrity of the utility's electrical power grid; 2 an approach to electrical protection within a limited source microgrid that does not depend on high fault currents; and 3 a method for microgrid control that achieves voltage and frequency stability under islanded conditions without requiring high-speed communications between sources.

  4. How to Calculate the True Cost of Steam

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A BestPractices Steam Technical Brief How To Calculate The True Cost of Steam U.S. Department of Energy Energy Efficiency and Renewable Energy Bringing you a prosperous future where energy is clean, abundant, reliable, and affordable Industrial Technologies Program Boosting the productivity and competitiveness of U.S. industry through improvements in energy and environmental performance How To Calculate The True Cost of Steam Knowing the correct cost of steam is important for many reasons, and

  5. Save Energy Now in Your Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Save Energy Now in Your Steam Systems Save Energy Now in Your Steam Systems This brief outlines typical ways to increase steam system efficiency through changes in distribution, generation, and recovery. PDF icon Save Energy Now in Your Steam Systems (January 2006) More Documents & Publications Install an Automatic Blowdown-Control System Save Energy Now in Your Process Heating Systems Save Energy Now in Your Motor-Driven Systems Advanced Manufacturing Home Key Activities Research &

  6. Covered Product Category: Commercial Steam Cookers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Cookers Covered Product Category: Commercial Steam Cookers The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, which are covered by the ENERGY STAR program. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law. Meeting Energy Efficiency Requirements for Commercial Steam Cookers ENERGY STAR sets efficiency requirements

  7. Best Management Practice #8: Steam Boiler Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Steam Boiler Systems Best Management Practice #8: Steam Boiler Systems Steam boilers are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size and the amount of condensate returned. Operations and Maintenance Options To maintain water efficiency in operations and maintenance, federal agencies should do the following. Develop and implement a

  8. Improving Steam System Performance: A Sourcebook for Industry, Second Edition

    SciTech Connect (OSTI)

    2012-02-23

    This sourcebook is designed to provide steam system users with a reference that describes the basic steam system components, outlines opportunities for energy and performance improvements, and discusses the benefits of a systems approach in identifying and implementing these improvement opportunities. The sourcebook is divided into three main sections: steam system basics, performance improvement opportunities, and where to find help.

  9. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  10. Improving Steam System Performance: A Sourcebook for Industry, Second Edition

    Broader source: Energy.gov [DOE]

    This sourcebook is designed to provide steam system users with a reference that describes the basic steam system components, outlines opportunities for energy and performance improvements, and discusses the benefits of a systems approach in identifying and implementing these improvement opportunities. The sourcebook is divided into three main sections: steam system basics, performance improvement opportunities, and where to find help.

  11. Water spray ejector system for steam injected engine

    SciTech Connect (OSTI)

    Hines, W.R.

    1991-10-08

    This paper describes a method of increasing the power output of a steam injected gas turbine engine. It comprises: a compressor, a combustor having a dome which receives fuel and steam from a dual flow nozzle, and a turbine in series combination with a gas flow path passing therethrough, and a system for injection of superheated steam into the gas flow path, the method comprising spraying water into the steam injection system where the water is evaporated by the superheated steam, mixing the evaporated water with the existing steam in the steam injection system so that the resultant steam is at a temperature of at least 28 degrees celsius (50 degrees fahrenheit) superheat and additional steam is added to the dome from the fuel nozzle to obtain a resultant increased mass flow of superheated steam mixture for injection into the gas flow path, and controlling the amount of water sprayed into the steam injection system to maximize the mass flow of superheated steam without quenching the flame.

  12. Replace Pressure-Reducing Valves with Backpressure Turbogenerators (International Fact Sheet), Energy Tips-Steam, Steam Tip Sheet #20c

    SciTech Connect (OSTI)

    Not Available

    2010-10-01

    This English/Chinese ITP steam tip sheet on replacing pressure-reducing valves provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  13. Use Low-Grade Waste Steam to Power Absorption Chillers - Steam Tip Sheet #14

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on waste steam to power absorption chillers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  14. Consider Steam Turbine Drives for Rotating Equipment - Steam Tip Sheet #21

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on steam turbine drives for rotating equipment provides how-to advice for improving the system using low-cost, proven practices and technologies.

  15. Natural gas-assisted steam electrolyzer

    DOE Patents [OSTI]

    Pham, Ai-Quoc (San Jose, CA); Wallman, P. Henrik (Berkeley, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01

    An efficient method of producing hydrogen by high temperature steam electrolysis that will lower the electricity consumption to an estimated 65 percent lower than has been achievable with previous steam electrolyzer systems. This is accomplished with a natural gas-assisted steam electrolyzer, which significantly reduces the electricity consumption. Since this natural gas-assisted steam electrolyzer replaces one unit of electrical energy by one unit of energy content in natural gas at one-quarter the cost, the hydrogen production cost will be significantly reduced. Also, it is possible to vary the ratio between the electricity and the natural gas supplied to the system in response to fluctuations in relative prices for these two energy sources. In one approach an appropriate catalyst on the anode side of the electrolyzer will promote the partial oxidation of natural gas to CO and hydrogen, called Syn-Gas, and the CO can also be shifted to CO.sub.2 to give additional hydrogen. In another approach the natural gas is used in the anode side of the electrolyzer to burn out the oxygen resulting from electrolysis, thus reducing or eliminating the potential difference across the electrolyzer membrane.

  16. Fuel cell integrated with steam reformer

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

    1987-01-01

    A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

  17. Gas turbine row #1 steam cooled vane

    DOE Patents [OSTI]

    Cunha, Frank J. (Longwood, FL)

    2000-01-01

    A design for a vane segment having a closed-loop steam cooling system is provided. The vane segment comprises an outer shroud, an inner shroud and an airfoil, each component having a target surface on the inside surface of its walls. A plurality of rectangular waffle structures are provided on the target surface to enhance heat transfer between each component and cooling steam. Channel systems are provided in the shrouds to improve the flow of steam through the shrouds. Insert legs located in cavities in the airfoil are also provided. Each insert leg comprises outer channels located on a perimeter of the leg, each outer channel having an outer wall and impingement holes on the outer wall for producing impingement jets of cooling steam to contact the airfoil's target surface. Each insert leg further comprises a plurality of substantially rectangular-shaped ribs located on the outer wall and a plurality of openings located between outer channels of the leg to minimize cross flow degradation.

  18. Purchasing Energy-Efficient Commercial Steam Cookers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, a product category covered by ENERGY STAR efficiency requirements. Federal laws and requirements mandate that agencies purchase ENERGY STAR-qualified products or FEMP-designated products in all product categories covered by these programs and in any acquisition actions that are not specifically exempted by law.

  19. Task 1Steam Oxidation (NETL-US)

    SciTech Connect (OSTI)

    G. R. Holcomb

    2010-05-01

    The proposed steam in let temperature in the Advanced Ultra Supercritical (AUSC) steam turbine is high enough (760C) Ihat traditional turbine casing and valve body materials such as ferr;tic/manensitic steels will not suffice due to temperature lim itations of this class of materials. Cast versions of three traditionally wrought Ni-based superalloys (Haynes 263. Haynes 282, and Nimonic 105) were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantia l: 2-5,000 kg each half and on the order of 100 nun thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equi valem microslruclUre . A multi_step homogenization heat treatment was d~ve loped to better disperse the al loy constituents. These castings were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (al 760 and 800 "C).

  20. Low chemical concentrating steam generating cycle

    DOE Patents [OSTI]

    Mangus, James D. (Greensburg, PA)

    1983-01-01

    A steam cycle for a nuclear power plant having two optional modes of operation. A once-through mode of operation uses direct feed of coolant water to an evaporator avoiding excessive chemical concentration buildup. A recirculation mode of operation uses a recirculation loop to direct a portion of flow from the evaporator back through the evaporator to effectively increase evaporator flow.