National Library of Energy BETA

Sample records for fluidized bed boiler

  1. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  2. Rapid ignition of fluidized bed boiler

    DOE Patents [OSTI]

    Osborn, Liman D.

    1976-12-14

    A fluidized bed boiler is started up by directing into the static bed of inert and carbonaceous granules a downwardly angled burner so that the hot gases cause spouting. Air is introduced into the bed at a rate insufficient to fluidize the entire bed. Three regions are now formed in the bed, a region of lowest gas resistance, a fluidized region and a static region with a mobile region at the interface of the fluidized and static regions. Particles are transferred by the spouting action to form a conical heap with the carbonaceous granules concentrated at the top. The hot burner gases ignite the carbonaceous matter on the top of the bed which becomes distributed in the bed by the spouting action and bed movement. Thereafter the rate of air introduction is increased to fluidize the entire bed, the spouter/burner is shut off, and the entire fluidized bed is ignited.

  3. Rivesville multicell fluidized bed boiler

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    One objective of the experimental MFB at Rivesville, WV, was the evaluation of alternate feed systems for injecting coal and limestone into a fluidized bed. A continuous, uniform feed flow to the fluid bed is essential in order to maintain stable operations. The feed system originally installed on the MFB was a gravity feed system with an air assist to help overcome the back pressure created by the fluid bed. The system contained belt, vibrating, and rotary feeders which have been proven adequate in other material handling applications. This system, while usable, had several operational and feeding problems during the MFB testing. A major portion of these problems occurred because the coal and limestone feed control points - a belt feeder and rotary feeder, respectively - were pressurized in the air assist system. These control points were not designed for pressurized service. An alternate feed system which could accept feed from the two control points, split the feed into six equal parts and eliminate the problems of the pressurized system was sought. An alternate feed system designed and built by the Fuller Company was installed and tested at the Rivesville facility. Fuller feed systems were installed on the north and south side of C cell at the Rivesville facility. The systems were designed to handle 10,000 lb/hr of coal and limestone apiece. The systems were installed in late 1979 and evaluated from December 1979 to December 1980. During this time period, nearly 1000 h of operating time was accumulated on each system.

  4. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  5. Fluidized bed boiler having a segmented grate

    DOE Patents [OSTI]

    Waryasz, Richard E.

    1984-01-01

    A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

  6. Standby cooling system for a fluidized bed boiler

    DOE Patents [OSTI]

    Crispin, Larry G.; Weitzel, Paul S.

    1990-01-01

    A system for protecting components including the heat exchangers of a fluidized bed boiler against thermal mismatch. The system includes an injection tank containing an emergency supply of heated and pressurized feedwater. A heater is associated with the injection tank to maintain the temperature of the feedwater in the tank at or about the same temperature as that of the feedwater in the heat exchangers. A pressurized gas is supplied to the injection tank to cause feedwater to flow from the injection tank to the heat exchangers during thermal mismatch.

  7. Model-free adaptive control of supercritical circulating fluidized-bed boilers

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L

    2014-12-16

    A novel 3-Input-3-Output (3.times.3) Fuel-Air Ratio Model-Free Adaptive (MFA) controller is introduced, which can effectively control key process variables including Bed Temperature, Excess O2, and Furnace Negative Pressure of combustion processes of advanced boilers. A novel 7-input-7-output (7.times.7) MFA control system is also described for controlling a combined 3-Input-3-Output (3.times.3) process of Boiler-Turbine-Generator (BTG) units and a 5.times.5 CFB combustion process of advanced boilers. Those boilers include Circulating Fluidized-Bed (CFB) Boilers and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  8. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  9. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  10. Combustion of liquid paint wastes in fluidized bed boiler as element of waste management system in the paint factory

    SciTech Connect (OSTI)

    Soko, W.A.; Biaecka, B.

    1998-12-31

    In this paper the solution to waste problems in the paint industry is presented by describing their combustion in a fluidized bed boiler as a part of the waste management system in the paint factory. Based on the Cleaner Production idea and concept of integration of design process with a future exploitation of equipment, some modifications of the waste management scheme in the factory are discussed to reduce the quantity of toxic wastes. To verify this concept combustion tests of paint production wastes and cocombustion of paint wastes with coal in an adopted industrial boiler were done. Results of these tests are presented in the paper.

  11. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  12. Fluidized-bed combustion

    SciTech Connect (OSTI)

    Botros, P E

    1990-04-01

    This report describes the activities of the Morgantown Energy Technology Center's research and development program in fluidized-bed combustion from October 1, 1987, to September 30, 1989. The Department of Energy program involves atmospheric and pressurized systems. Demonstrations of industrial-scale atmospheric systems are being completed, and smaller boilers are being explored. These systems include vortex, multi-solid, spouted, dual-sided, air-cooled, pulsed, and waste-fired fluidized-beds. Combustion of low-rank coal, components, and erosion are being studied. In pressurized combustion, first-generation, combined-cycle power plants are being tested, and second-generation, advanced-cycle systems are being designed and cost evaluated. Research in coal devolatilization, metal wastage, tube corrosion, and fluidization also supports this area. 52 refs., 24 figs., 3 tabs.

  13. Bed material agglomeration during fluidized bed combustion

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  14. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  15. PFBC (pressurized fluidized bed combustion) turbocharged boiler design and economic study: Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    A coal combustion technology that promises to reduce the cost of electrical power is pressurized fluidized bed combustion (PFBC). Since a PFBC boiler is physically smaller than a conventional pulverized coal fired boiler with a flue gas desulfurization system (PC/FGD) and the same power rating shop assembly and modularized shipment to the power plant site can be considered. Modular construction can substantially reduce the overall design/construction time. Emission controls are equivalent to, or better than, conventional PC/FGD units, and the PFBC combustor can tolerate coals with a wider range of characteristics. Two PFBC plants and the reference PC/FGD plant were each to have four nominal 250 MW(e) units to be completed for start-up at one year intervals. To establish a well defined consistent design basis for all units, the turbine-generator and steam cycle of a recently constructed 250 MW(e) unit (designed by Fluor and built under Fluor construction management) was selected and made the common element in both of the PFBC plants and the reference PC/FGD plant. Steam conditions of 2400 psia, 1000/sup 0/F were to be identical for all units as were the steam flows for the design load range of 50% to steam turbine valves-wide-open with inlet steam pressure 5% over design pressure (VWO 5% OP). The study produced three plant designs - a 4-unit turbocharged PFBC using bubbling bed technology, a 4-unit turbocharged PFBC using circulating bed technology, and a 4-unit PC/FGD reference plant using conventional pulverized coal technology coupled with wet limestone scrubber technology. The hot gas clean-up system, operating at these more modest temperatures, is capable of reducing the particulate in the gas to a level which meets EPA/NSPS standards without further cleanup. With this level of cleanup, service conditions for the turbocharger turbine are tolerable in commercially available designs and materials. 48 figs., 14 tabs.

  16. Fluidized bed calciner apparatus

    DOE Patents [OSTI]

    Owen, Thomas J.; Klem, Jr., Michael J.; Cash, Robert J.

    1988-01-01

    An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

  17. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; John Gaudlip; Matthew Lapinsky; Rhett McLaren; William Serencsits; Neil Raskin; Tom Steitz; Joseph J. Battista

    2003-03-26

    The Pennsylvania State University, utilizing funds furnished by the U.S. Department of Energy's Biomass Power Program, investigated the installation of a state-of-the-art circulating fluidized bed boiler at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring biofuels and coal-based feedstocks. The study was performed using a team that included personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Foster Wheeler Energy Corporation; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. The activities included assessing potential feedstocks at the University Park campus and surrounding region with an emphasis on biomass materials, collecting and analyzing potential feedstocks, assessing agglomeration, deposition, and corrosion tendencies, identifying the optimum location for the boiler system through an internal site selection process, performing a three circulating fluidized bed (CFB) boiler design and a 15-year boiler plant transition plan, determining the costs associated with installing the boiler system, developing a preliminary test program, determining the associated costs for the test program, and exploring potential emissions credits when using the biomass CFB boiler.

  18. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C. Stuart; Hawk, James A.

    1995-01-01

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

  19. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C.S.; Hawk, J.A.

    1995-07-25

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence. 9 figs.

  20. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, R.G.

    1983-05-13

    The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  1. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA)

    1984-01-01

    Method and apparatus for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  2. Fluidized Bed Technology- Overview

    Broader source: Energy.gov [DOE]

    Fluidized beds suspend solid fuels on upward-blowing jets of air during the combustion process. The result is a turbulent mixing of gas and solids. The tumbling action, much like a bubbling fluid,...

  3. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke

    2001-07-13

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences, Foster Wheeler Energy Services, Inc., Parsons Energy and Chemicals Group, Inc., and Cofiring Alternatives. During this reporting period, work focused on completing the biofuel characterization and the design of the conceptual fluidized bed system.

  4. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke

    2001-10-12

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels.

  5. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Tom Steitz

    2002-07-12

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives.

  6. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Dale Lamke; Joseph J. Battista

    2001-03-31

    The Pennsylvania State University, under contract to the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed (CFB) boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. Penn State currently operates an aging stoker-fired steam plant at its University Park campus and has spent considerable resources over the last ten to fifteen years investigating boiler replacements and performing life extension studies. This effort, in combination with a variety of agricultural and other wastes generated at the agricultural-based university and the surrounding rural community, has led Penn State to assemble a team of fluidized bed and cofiring experts to assess the feasibility of installing a CFB boiler for cofiring biomass and other wastes along with coal-based fuels. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Services, Inc., and Cofiring Alternatives.

  7. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, A.G.; Patel, J.G.

    1987-05-12

    An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

  8. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G.; Patel, Jitendra G.

    1987-05-12

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  9. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Sharon Falcone Miller; Robert Cooper; Douglas Donovan; John Gaudlip; Matthew Lapinsky; William Serencsits; Neil Raskin; Tom Steitz

    2002-10-14

    The Pennsylvania State University, under contract to the U.S. Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute, Office of Physical Plant, and College of Agricultural Sciences; Foster Wheeler Energy Services, Inc.; Parsons Energy and Chemicals Group, Inc.; and Cofiring Alternatives. During this reporting period, the final technical design and cost estimate were submitted to Penn State by Foster Wheeler. In addition, Penn State initiated the internal site selection process to finalize the site for the boiler plant.

  10. Fluidized bed combustion

    SciTech Connect (OSTI)

    Sowards, N.K.; Murphy, M.L.

    1991-10-29

    This patent describes a vessel. It comprises a fluid bed for continuously incinerating fuel comprising tire segments and the like which comprise metallic wire tramp and for concurrently removing tramp and bed materials at a bottom effluent exit means of the vessel, the vessel further comprising static air distributor means at the periphery of the bed comprising a substantially centrally unobstructed relatively large central region in which the fluid bed and fuel only are disposed and through which bed material and tramp migrate without obstruction to and through the effluent exit means, downwardly and inwardly stepped lower vessel wall means and a plurality of peripherally located centrally directed vertically and horizontally offset spaced air influent means surrounding the central region and associated with the stepped lower vessel wall means by which the bed is supported and fluidized.

  11. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1996-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

  12. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1995-04-25

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

  13. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1996-02-27

    A fluidized bed reactor system is described which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves. 3 figs.

  14. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.

    1993-12-14

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

  15. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1995-01-01

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  16. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN)

    1993-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  17. Design and performance requirements for a fluidized bed boiler firing municipal refuse derived fuel in Ravenna, Italy

    SciTech Connect (OSTI)

    Murphy, M.L.

    1999-07-01

    In early 1998, the City of Ravenna, Italy, commissioned a fluid bed boiler/waste-to-energy system to combust approximately 50,000 tonnes per year of processed municipal waste and generate electrical power. Much of the fuel preparation and processing equipment was already in place and the primary focus of this project was to implement an environmentally acceptable energy conversion process compatible with the 6.0 tonnes/hr of fuel being processed. The fluid bed boiler system being provided will incorporate state of the art environmental controls for abatement of all pollutants, including products of incomplete combustion (PICs), NO{sub x}, acid gases, and particulates. The project will deliver an average of 70,000 pounds per hour of steam to generate approximately 7 MW of electricity. The following is a description of the process and equipment being utilized for the energy conversion and boiler island, including the environmental abatement equipment. Design specifications for the plant including fuel and emission limits are presented herein. The facility is scheduled for startup in mid-1999.

  18. FEASIBILITY ANALYSIS FOR INSTALLING A CIRCULATING FLUIDIZED BED BOILER FOR COFIRING MULTIPLE BIOFUELS AND OTHER WASTES WITH COAL AT PENN STATE UNIVERSITY

    SciTech Connect (OSTI)

    Bruce G. Miller; Curtis Jawdy

    2000-10-09

    The Pennsylvania State University, under contract to the US Department of Energy, National Energy Technology Laboratory is performing a feasibility analysis on installing a state-of-the-art circulating fluidized bed boiler and ceramic filter emission control device at Penn State's University Park campus for cofiring multiple biofuels and other wastes with coal or coal refuse, and developing a test program to evaluate cofiring multiple biofuels and coal-based feedstocks. The objective of the project is being accomplished using a team that includes personnel from Penn State's Energy Institute and the Office of Physical Plant, Foster Wheeler Energy Corporation, Foster Wheeler Development Corporation, and Cofiring Alternatives. The major emphasis of work during this reporting period was to assess the types and quantities of potential feedstocks and collect samples of them for analysis. Approximately twenty different biomass, animal waste, and other wastes were collected and analyzed.

  19. Fast fluidized bed steam generator

    DOE Patents [OSTI]

    Bryers, Richard W. (Flemington, NJ); Taylor, Thomas E. (Bergenfield, NJ)

    1980-01-01

    A steam generator in which a high-velocity, combustion-supporting gas is passed through a bed of particulate material to provide a fluidized bed having a dense-phase portion and an entrained-phase portion for the combustion of fuel material. A first set of heat transfer elements connected to a steam drum is vertically disposed above the dense-phase fluidized bed to form a first flow circuit for heat transfer fluid which is heated primarily by the entrained-phase fluidized bed. A second set of heat transfer elements connected to the steam drum and forming the wall structure of the furnace provides a second flow circuit for the heat transfer fluid, the lower portion of which is heated by the dense-phase fluidized bed and the upper portion by the entrained-phase fluidized bed.

  20. Fluidized bed deposition of diamond

    DOE Patents [OSTI]

    Laia, Jr., Joseph R.; Carroll, David W.; Trkula, Mitchell; Anderson, Wallace E.; Valone, Steven M.

    1998-01-01

    A process for coating a substrate with diamond or diamond-like material including maintaining a substrate within a bed of particles capable of being fluidized, the particles having substantially uniform dimensions and the substrate characterized as having different dimensions than the bed particles, fluidizing the bed of particles, and depositing a coating of diamond or diamond-like material upon the substrate by chemical vapor deposition of a carbon-containing precursor gas mixture, the precursor gas mixture introduced into the fluidized bed under conditions resulting in excitation mechanisms sufficient to form the diamond coating.

  1. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, Juhani

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  2. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, J.

    1996-03-19

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  3. Staged cascade fluidized bed combustor

    DOE Patents [OSTI]

    Cannon, Joseph N.; De Lucia, David E.; Jackson, William M.; Porter, James H.

    1984-01-01

    A fluid bed combustor comprising a plurality of fluidized bed stages interconnected by downcomers providing controlled solids transfer from stage to stage. Each stage is formed from a number of heat transfer tubes carried by a multiapertured web which passes fluidizing air to upper stages. The combustor cross section is tapered inwardly from the middle towards the top and bottom ends. Sorbent materials, as well as non-volatile solid fuels, are added to the top stages of the combustor, and volatile solid fuels are added at an intermediate stage.

  4. Apparatus and process for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G.; Patel, Jitendra G.

    1985-10-01

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  5. Distribution plate for recirculating fluidized bed

    DOE Patents [OSTI]

    Yang, Wen-ching; Vidt, Edward J.; Keairns, Dale L.

    1977-01-01

    A distribution plate for a recirculating fluidized bed has a centrally disposed opening and a plurality of apertures adjacent the periphery to eliminate dead spots within the bed.

  6. Char binder for fluidized beds

    DOE Patents [OSTI]

    Borio, Richard W.; Accortt, Joseph I.

    1981-01-01

    An arrangement that utilizes agglomerating coal as a binder to bond coal fines and recycled char into an agglomerate mass that will have suitable retention time when introduced into a fluidized bed 14 for combustion. The simultaneous use of coal for a primary fuel and as a binder effects significant savings in the elimination of non-essential materials and processing steps.

  7. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I.; Rogers, Lynn M.

    1983-12-20

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  8. Development and applications of clean coal fluidized bed technology

    SciTech Connect (OSTI)

    Eskin, N.; Hepbasli, A.

    2006-09-15

    Power generation in Europe and elsewhere relies heavily on coal and coal-based fuels as the source of energy. The reliance will increase in the future due to the decreasing stability of price and security of oil supply. In other words, the studies on fluidized bed combustion systems, which is one of the clean coal technologies, will maintain its importance. The main objective of the present study is to introduce the development and the applications of the fluidized bed technology (FBT) and to review the fluidized bed combustion studies conducted in Turkey. The industrial applications of the fluidized bed technology in the country date back to the 1980s. Since then, the number of the fluidized bed boilers has increased. The majority of the installations are in the textile sector. In Turkey, there is also a circulating fluidized bed thermal power plant with a capacity of 2 x 160 MW under construction at Can in Canakkale. It is expected that the FBT has had, or will have, a significant and increasing role in dictating the energy strategies for Turkey.

  9. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    The char residue is not wasted; it can also be used to generate electricity by fueling ... SYSTEMS; COAL; COAL GASIFICATION; ELECTRICITY; FLUIDIZED BEDS; GAS TURBINES; ...

  10. DEVELOPMENT OF PRESSURIZED CIRCULATIONG FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    The char residue is not wasted; it can also be used to generate electricity by fueling ... CHARS; COAL; COAL GASIFICATION; ELECTRICITY; FLUIDIZED BEDS; GAS TURBINES; ...

  11. Fundamentals of fluidized bed chemical processes

    SciTech Connect (OSTI)

    Yates, J.G.

    1983-01-01

    Chemical processes based on the use of fluidized solids, although widely used on an industrial scale for some four decades, are currently increasing in importance as industry looks for improved methods for handling and reacting solid materials. This book provides background necessary for an understanding of the technique of gas-solid fluidization. Contents: Some Fundamental Aspects of Fluidization-General Features of Gas-Solid Fluidization; Minimum Fluidization Velocity; Inter-particle forces; Liquid-Solid Fluidization; Bubbles; Slugging; Entrainment and Elutriation; Particle Movement; Bed Viscosity; Fluidization Under Pressure. Fluidized-Bed Reactor Models-ome Individual Models; Model Comparisons; Multiple Region Models. Catalytic Cracking-Process Developments Riser Cracking; Catalysis; Process Chemistry; Kinetics; Process Models. Combustion and Gasification-Plant Developments; Oil and Gas Combustion; Desulphurization; No/sub x/ Emissions; Coal Gassification. Miscellaneous Processes-Phthalic Anhydride (1,3-isobezofurandione); Acrylonitrile (prop-3-enenitrile); Vinyl Chloride (chloroethene); Titanium Dioxide; Uranium Processing; Sulphide Roasting; Indexes.

  12. Bed material agglomeration during fluidized bed combustion. Technical progress report, September 30, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Brown, R.C.; Dawson, M.R.; Noble, S.

    1993-02-01

    The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

  13. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse ...

  14. Tube construction for fluidized bed combustor

    DOE Patents [OSTI]

    De Feo, Angelo; Hosek, William

    1984-01-01

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  15. Fluidized bed combustor and tube construction therefor

    DOE Patents [OSTI]

    De Feo, Angelo; Hosek, William

    1981-01-01

    A fluidized bed combustor comprises a reactor or a housing which has a windbox distributor plate adjacent the lower end thereof which contains a multiplicity of hole and air discharge nozzles for discharging air and coal into a fluidized bed which is maintained above the distributor plate and below a take-off connection or flue to a cyclone separator in which some of the products of combustion are treated to remove the dust which is returned into the fluidized bed. A windbox is spaced below the fluidized bed and it has a plurality of tubes passing therethrough with the passage of combustion air and fluidizing air which passes through an air space so that fluidizing air is discharged into the reaction chamber fluidized bed at the bottom thereof to maintain the bed in a fluidized condition. A fluid, such as air, is passed through the tubes which extend through the windbox and provide a preheating of the combustion air and into an annular space between telescoped inner and outer tubes which comprise heat exchanger tubes or cooling tubes which extend upwardly through the distributor plate into the fluidized bed. The heat exchanger tubes are advantageously arranged so that they may be exposed in groups within the reactor in a cluster which is arranged within holding rings.

  16. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter; Salvador, Louis A.

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  17. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H.

    1984-01-01

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  18. Combined fluidized bed retort and combustor

    DOE Patents [OSTI]

    Shang, Jer-Yu; Notestein, John E.; Mei, Joseph S.; Zeng, Li-Wen

    1984-01-01

    The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

  19. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  20. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  1. In-bed tube bank for a fluidized-bed combustor

    DOE Patents [OSTI]

    Hemenway, Jr., Lloyd F.

    1990-01-01

    An in-bed tube bank (10) for a fluidized bed combustor. The tube bank (10) of the present invention comprises one or more fluid communicating boiler tubes (30) which define a plurality of selectively spaced boiler tube sections (32). The tube sections (32) are substantially parallel to one another and aligned in a common plane. The tube bank (10) further comprises support members (34) for joining adjacent tube sections (32), the support members (34) engaging and extending along a selected length of the tube sections (32) and spanning the preselected space therebetween.

  2. Gas fluidized-bed stirred media mill

    DOE Patents [OSTI]

    Sadler, III, Leon Y.

    1997-01-01

    A gas fluidized-bed stirred media mill is provided for comminuting solid ticles. The mill includes a housing enclosing a porous fluidizing gas diffuser plate, a baffled rotor and stator, a hollow drive shaft with lateral vents, and baffled gas exhaust exit ports. In operation, fluidizing gas is forced through the mill, fluidizing the raw material and milling media. The rotating rotor, stator and milling media comminute the raw material to be ground. Small entrained particles may be carried from the mill by the gas through the exit ports when the particles reach a very fine size.

  3. Particle withdrawal from fluidized bed systems

    DOE Patents [OSTI]

    Salvador, Louis A.; Andermann, Ronald E.; Rath, Lawrence K.

    1982-01-01

    Method and apparatus for removing ash formed within, and accumulated at the lower portion of, a fluidized bed coal gasification reactor vessel. A supplemental fluidizing gas, at a temperature substantially less than the average fluidized bed combustion operating temperature, is injected into the vessel and upwardly through the ash so as to form a discrete thermal interface region between the fluidized bed and the ash. The elevation of the interface region, which rises with ash accumulation, is monitored by a thermocouple and interrelated with a motor controlled outlet valve. When the interface rises above the temperature indicator, the valve opens to allow removal of some of the ash, and the valve is closed, or positioned at a minimum setting, when the interface drops to an elevation below that of the thermocouple.

  4. Wear prediction in a fluidized bed

    SciTech Connect (OSTI)

    Boyle, E.J.; Rogers, W.A.

    1993-06-01

    A procedure to model the wear of surfaces exposed to a fluidized bed is formulated. A stochastic methodology adapting the kinetic theory of gases to granular flows is used to develop an impact wear model. This uses a single-particle wear model to account for impact wear from all possible-particle collisions. An adaptation of a single-particle abrasion model to describe the effects of many abrading particles is used to account for abrasive wear. Parameters describing granular flow within the fluidized bed, necessary for evaluation of the wear expressions, are determined by numerical solution of the fluidized bed hydrodynamic equations. Additional parameters, describing the contact between fluidized particles and the wearing surface, are determined by optimization based on wear measurements. The modeling procedure was used to analyze several bubbling and turbulent fluidized bed experiments with single-tube and tube bundle configurations. Quantitative agreement between the measured and predicted wear rates was found, with some exceptions for local wear predictions. This work demonstrates a methodology for wear predictions in fluidized beds.

  5. Current state of atmospheric fluidized-bed combustion technology

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This paper examines atmospheric fluidized-bed combustion (AFBC) technology, a coal burning method that has several environmental and technical advantages over the more conventional technologies, such as pulverized-coal methods. The AFBC approach injects an air stream into a boiler in such a way that it mixes with solid fuel and sorbent to create a dense phase region or fluidized bed. This method makes it possible to use a much wider range of low-quality fuels and to burn them at lower temperatures with less pollutant by-product. The paper presents a comprehensive overview of AFBC technology to date. It includes worldwide development of this technology since the 1950s necessary to meet ever-stricter emissions requirements while providing greater fuel flexibility.

  6. Particle Pressures in Fluidized Beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction): they impart to the bed. So rather than directly measure the particle pressure, we inferred the values of the elasticity from measurements of instability growth in liquid beds the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined)and then working backwards to determine the unknown coefficients, including the elasticity.

  7. Particle pressures in fluidized beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction), they impart to the bed. So rather than directly measure the particle pressure, the authors inferred the values of the elasticity from measurements of instability growth in liquid beds; the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined) and then working backwards to determine the unknown coefficients, including the elasticity.

  8. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A.; Wesselhoft, Robert D.; Dunkleman, John J.; Aquino, Dolores C.; Gouker, Toby R.

    1984-01-01

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  9. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C.; Zboray, James A.

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  10. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  11. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y.; Cha, Chang Y.; Merriam, Norman W.

    1992-01-01

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  12. Particle motion at fluidized bed tube surfaces

    SciTech Connect (OSTI)

    Drennen, J.F.; Hocking, W.R.; Howard, D.A.

    1990-06-01

    Metal loss from in-bed heat transfer tubes in fluidized bed combustors is recognized as a problem that is affecting the commercialization of FBC technology for coal utilization. A program has been initiated to address the erosion aspect of the wastage problem. Objectives were: (1) to develop a method for measuring the particle impact velocities and mass flux at a fluidized bed tube surface, (2) to obtain wear data from test tubes in an operating cold flow model, and (3) to correlate the results. An instrumented probe was develop during Phase I that could be used to obtain the three orthogonal velocity components and mass flux at a fluidized bed tube surface. The sensors were contained in a 2 inch diameter schedule 40 pipe that can be installed in the cold flow model in place of one of the test tubes. This arrangement allows measurements to be made non-intrusively. The velocity measuring portion used a Laser Doppler Velocimeter (LDV) for obtaining the resultant impact velocity and impact angle of the bed particles at the immersed tube surface. Mass flux was derived from the output of a high speed force transducer that measured the individual particle impact momentum signals. The above system was used successfully to measure particle impact velocities and momentum during a limited test program. Test were run in a 1 ft {times} 2 ft ambient temperature fluidized bed test facility using sand and acrylic test tubes. Measurements were taken in the center of the bed at eight circumferential location, by rotating the probe to the desired tube angle. Tube erosion data were also taken at locations corresponding to the above measurement points. The instrumentation provided a wealth of information about the internal hydrodynamics of the fluidized bed. 3 refs., 49 figs., 17 tabs.

  13. Emission factors for several toxic air pollutants from fluidized-bed combustion of coal

    SciTech Connect (OSTI)

    Smith, A.E.

    1986-03-01

    Clean coal technologies such as fluidized-bed combustion have the potential to emit the same trace elements as conventional combustors. Since the US Environmental Protection Agency (EPA) is likely to promulgate National Emission Standards for Hazardous Air Pollutants for several trace elements, the feasibility of using fluidized-bed combustors to reduce sulfur dioxide emissions may depend in part on the relative amounts of trace elements emitted by fluidized-bed and conventional combustors. Emissions of trace elements from both atmospheric and pressurized fluidized-bed combustors were compared with those from conventional combustors by developing fluidized-bed emission factors from information available in the literature and comparing them with the emission factors for conventional combustors recommended in a literature search conducted for EPA. The comparisons are based on the mass of emission per unit of heat input for antimony, arsenic, beryllium, cadmium, chromium, cobalt, copper, lead, manganese, mercury, nickel, vanadium, and zinc. When inaccuracies in the data were taken into account, the trace element emissions from atmospheric fluidized-bed combustion seem to be somewhat higher than those from a conventional utility boiler burning pulverized coal and somewhat lower than those from pressurized fluidized-bed combustion.

  14. Bed drain cover assembly for a fluidized bed

    DOE Patents [OSTI]

    Comparato, Joseph R. (Bloomfield, CT); Jacobs, Martin (Hartford, CT)

    1982-01-01

    A loose fitting movable cover plate (36), suitable for the severe service encountered in a fluidized bed combustor (10), restricts the flow of solids into the combustor drain lines (30) during shutdown of the bed. This cover makes it possible to empty spent solids from the bed drain lines which would otherwise plug the piping between the drain and the downstream metering device. This enables use of multiple drain lines each with a separate metering device for the control of solids flow rate.

  15. Reversed flow fluidized-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu; Mei, Joseph S.; Wilson, John S.

    1984-01-01

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  16. Fluidized bed electrowinning of copper. Final report

    SciTech Connect (OSTI)

    1997-07-01

    The objectives of the study were to: design and construct a 10,000- amp fluidized bed electrowinning cell for the recovery of copper from acidic sulfate solutions; demonstrate the technical feasibility of continuous particle recirculation from the electrowinning cell with the ultimate goal of continuous particle removal; and measure cell efficiency as a function of operating conditions.

  17. Investigation of heat transfer and combustion in the advanced fluidized bed combustor (FBC)

    SciTech Connect (OSTI)

    Dr. Seong W. Lee

    1998-10-01

    The objective of this project is to predict the heat transfer and combustion performance in newly-designed fluidized bed combustor (FBC) and to provide the design guide lines and innovative concept for small-scale boiler and furnace. The major accomplishments are summarized.

  18. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  19. Effect of bed pressure drop on performance of a CFB boiler

    SciTech Connect (OSTI)

    Hairui Yang; Hai Zhang; Shi Yang; Guangxi Yue; Jun Su; Zhiping Fu

    2009-05-15

    The effect of bed pressure drop and bed inventory on the performances of a circulating fluidized bed (CFB) boiler was studied. By using the state specification design theory, the fluidization state of the gas-solids flow in the furnace of conventional CFB boilers was reconstructed to operate at a much lower bed pressure drop by reducing bed inventory and control bed quality. Through theoretical analysis, it was suggested that there would exist a theoretical optimal value of bed pressure drop, around which the boiler operation can achieve the maximal combustion efficiency and with significant reduction of the wear of the heating surface and fan energy consumption. The analysis was validated by field tests carried out in a 75 t/h CFB boiler. At full boiler load, when bed pressure drop was reduced from 7.3 to 3.2 kPa, the height of the dense zone in the lower furnace decreased, but the solid suspension density profile in the upper furnace and solid flow rate were barely influenced. Consequently, the average heat transfer coefficient in the furnace was kept nearly the same and the furnace temperature increment was less than 17{sup o}C. It was also found that the carbon content in the fly ash decreased first with decreasing bed pressure drop and then increased with further increasing bed pressure drop. The turning point with minimal carbon content was referred to as the point with optimal bed pressure drop. For this boiler, at the optimum point the bed pressure was around 5.7 kPa with the overall excess air ratio of 1.06. When the boiler was operated around this optimal point, not only the combustion efficiency was improved, but also fan energy consumption and wear of heating surface were reduced. 23 refs., 6 figs., 4 tabs.

  20. Solids feed nozzle for fluidized bed

    DOE Patents [OSTI]

    Zielinski, Edward A.

    1982-01-01

    The vertical fuel pipe of a fluidized bed extends up through the perforated support structure of the bed to discharge granulated solid fuel into the expanded bed. A cap, as a deflecting structure, is supported above the discharge of the fuel pipe and is shaped and arranged to divert the carrier fluid and granulated fuel into the combusting bed. The diverter structure is spaced above the end of the fuel pipe and provided with a configuration on its underside to form a venturi section which generates a low pressure in the stream into which the granules of solid fuel are drawn to lengthen their residence time in the combustion zone of the bed adjacent the fuel pipe.

  1. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  2. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C.; DaPrato, Philip L.; Gouker, Toby R.; Knoer, Peter

    1986-01-01

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  3. Pulsed atmospheric fluidized bed combustor apparatus

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1993-10-26

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g., organic and medical waste, drying materials, heating air, calcining and the like.

  4. Status of the fluidized bed unit

    SciTech Connect (OSTI)

    Williams, P.M.; Wade, J.F.

    1994-06-01

    Rocky Flats has a serious mixed waste problem. No technology or company has a license and available facilities to remedy this dilemma. One solution under study is to use a catalytic fluidized bed unit to destroy the combustible portion of the mixed waste. The fluidized bed thermal treatment program at Rocky Flats is building on knowledge gained over twenty years of successful development activity. The FBU has numerous technical advantages over other thermal technologies to treat Rocky Flats` mixed waste, the largest being the lower temperature (700{degrees}C versus 1000{degrees}C) which reduces acid corrosion and mechanical failures and obviates the need for ceramic lining. Successful demonstrations have taken place on bench, pilot, and full-scale tests using radioactive mixed wastes. The program is approaching implementation and licensing of a production-scale fluidized bed system for the safe treatment of mixed waste. The measure for success on this project is the ability to work closely with the community to jointly solve problems and respond to concerns of mixed waste treatment at Rocky Flats.

  5. Hydrodynamic aspects of a circulating fluidized bed with internals

    SciTech Connect (OSTI)

    Balasubramanian, N.; Srinivasakannan, C.

    1998-06-01

    An attempt is made to examine the influence of internals (baffles) in the riser of the circulating fluidized bed. Experiments are conducted in a circulating fluidized bed, having perforated plates with different free areas. It is noticed from the present work that a circulating fluidized bed having 45% free area gives uniform solids concentration and pressure drop along the length of the riser. In addition to the uniformity, the circulating fluidized bed with internals gives higher pressure drop (solids concentration) compared to a conventional circulating fluidized bed. For internals having 67.6% free area the pressure drop is higher at the lower portion of the riser compared to the upper portion, similar to a conventional circulating fluidized bed. For 30% free area plates the solids concentration varies axially within the stage and remains uniform from stage to stage.

  6. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wastewater Reuse | Department of Energy The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient Wastewater Reuse Presentation by Perry McCarty, Stanford University, during the "Targeting High-Value Challenges" panel at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop held March 18-19, 2015. PDF icon The Anaerobic Fluidized Bed Membrane Bioreactor for

  7. Technical evaluation: pressurized fluidized-bed combustion technology...

    Office of Scientific and Technical Information (OSTI)

    The evaluation concludes with a broad survey of the principal related research and ... FLUIDIZED-BED COMBUSTORS; TECHNOLOGY ASSESSMENT; ECONOMICS; ENVIRONMENTAL IMPACTS; ...

  8. Pyrolysis reactor and fluidized bed combustion chamber

    DOE Patents [OSTI]

    Green, Norman W.

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  9. Electrode assembly for a fluidized bed apparatus

    DOE Patents [OSTI]

    Schora, Jr., Frank C.; Matthews, Charles W.; Knowlton, Ted M.

    1976-11-23

    An electrode assembly comprising a high voltage electrode having a generally cylindrical shape and being electrically connected to a high voltage source, where the cylinder walls may be open to flow of fluids and solids; an electrically grounded support electrode supporting said high voltage electrode by an electrically insulating support where both of the electrically grounded and electrically insulating support may be hollow; and an electrically grounded liner electrode arranged concentrically around both the high voltage and support electrodes. This assembly is specifically adapted for use in a fluidized bed chemical reactor as an improved heating means therefor.

  10. Metal wastage in fluidized-bed combustors

    SciTech Connect (OSTI)

    Berry, G.F.; Podolski, W.F.; Reimann, K.J.; Lyczkowski, R.W.; Youngdahl, C.A.

    1987-01-01

    Objectives of the research are (1) to develop guidelines for the design and operation of fluidized-bed combustion (FBC) units with minimum metal wastage rates and (2) to develop continuous erosion monitors for use in pilot plant and full-scale FBC units. The design guidelines will be developed from the understanding gained from the experimental studies and analytical model development activities. The computational models are being developed in order to predict the rates of metal wastage for specific FBC designs and operating conditions. 14 refs., 6 figs.

  11. Metal wastage in fluidized-bed combustors

    SciTech Connect (OSTI)

    Podolski, W.F.; Reimann, K.J.; Swift, W.M.; Carls, E.L.

    1989-01-01

    This paper presents an overview and status of a cooperative research joint venture on metal wastage in fluidized bed combustors. The participants are the US Department of Energy/Morgantown Energy Technology Center, Argonne National Laboratory, Electric Power Research Institute, State of Illinois Center for Research on Sulfur in Coal, Tennessee Valley Authority, ASEA Babcock, Combustion Engineering, and Foster Wheeler. Tasks are being carried out in three main technical areas: (1) hydrodynamic and erosion modeling (the subject of a separate paper), (2) erosion monitor development, and (3) experimental testing and model validation. The latter two areas are discussed in this paper. 7 refs., 11 figs., 1 tab.

  12. Predictive models of circulating fluidized bed combustors

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  13. Internal dust recirculation system for a fluidized bed heat exchanger

    DOE Patents [OSTI]

    Gamble, Robert L.; Garcia-Mallol, Juan A.

    1981-01-01

    A fluidized bed heat exchanger in which air is passed through a bed of particulate material containing fuel disposed in a housing. A steam/water natural circulation system is provided in a heat exchange relation to the bed and includes a steam drum disposed adjacent the bed and a tube bank extending between the steam drum and a water drum. The tube bank is located in the path of the effluent gases exiting from the bed and a baffle system is provided to separate the solid particulate matter from the effluent gases. The particulate matter is collected and injected back into the fluidized bed.

  14. Fluidized bed heat exchanger utilizing angularly extending heat exchange tubes

    DOE Patents [OSTI]

    Talmud, Fred M.; Garcia-Mallol, Juan-Antonio

    1980-01-01

    A fluidized bed heat exchanger in which air is passed through a bed of particulate material containing fuel disposed in a housing. A steam/water natural circulation system is provided and includes a steam drum disposed adjacent the fluidized bed and a series of tubes connected at one end to the steam drum. A portion of the tubes are connected to a water drum and in the path of the air and the gaseous products of combustion exiting from the bed. Another portion of the tubes pass through the bed and extend at an angle to the upper surface of the bed.

  15. Characterization of emissions from a fluidized-bed wood chip home heating furnace. Final report Apr 82-May 83

    SciTech Connect (OSTI)

    Truesdale, R.S.

    1984-03-01

    The report gives results of measurements of emissions from a residential wood-chip combustor, operated in both a fluidized-bed and cyclone-fired mode, and their comparison with those from a conventional woodstove and industrial wood-fired boilers. In general, the combustion efficiency of the fluidized-bed and cyclone-fired wood-chip burner is higher than that of conventional woodstoves. Concomitant with this increase in efficiency is a decrease in most emissions. For the fluidized-bed tests, significant reductions of total hydrocarbons and CO were observed, compared to woodstove emissions. The cyclone test showed PAH levels far below those of conventional woodstoves, approaching levels measured in industrial wood-fired boilers. A baghouse, installed during two fluidized-bed tests, was extremely effective in reducing both particulate and PAH emissions. Method 5 samples from above the fluid bed suggest that appreciable PAH is formed in the upper region of the furnace or in the watertube heat exchangers. In general, the cyclone-fired mode was more effective in reducing emissions from residential wood combustion than the fluidized-bed mode.

  16. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    ... J. Shakiri, "Heat Transfer for Immersed Surfaces in Liquid-Fluidized-Beds", Chemical Engi- neering Science, Vol. 31, 1976, pp. 619-624. 5. W. Hamilton, " A Correlation of Heat ...

  17. Fluidized Bed Technology - An R&D Success Story | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Nucla fluidized bed power plant in Colorado was operated in DOE's Clean Coal ... when it replaced two of the plant's obsolete and inefficient oil- and gas-fired units. ...

  18. Fluidized Bed Technology- An R&D Success Story

    Office of Energy Efficiency and Renewable Energy (EERE)

    In the early 1990s, POWER magazine called the development of fluidized bed coal combustors "the commercial success story of the last decade in the power generation business." The success, perhaps...

  19. Staged fluidized-bed combustion and filter system

    DOE Patents [OSTI]

    Mei, Joseph S.; Halow, John S.

    1994-01-01

    A staged fluidized-bed combustion and filter system for substantially reducing the quantity of waste through the complete combustion into ash-type solids and gaseous products. The device has two fluidized-bed portions, the first primarily as a combustor/pyrolyzer bed, and the second as a combustor/filter bed. The two portions each have internal baffles to define stages so that material moving therein as fluidized beds travel in an extended route through those stages. Fluidization and movement is achieved by the introduction of gases into each stage through a directional nozzle. Gases produced in the combustor/pyrolyzer bed are permitted to travel into corresponding stages of the combustor/filter bed through screen filters that permit gas flow but inhibit solids flow. Any catalyst used in the combustor/filter bed is recycled. The two beds share a common wall to minimize total volume of the system. A slightly modified embodiment can be used for hot gas desulfurization and sorbent regeneration. Either side-by-side rectangular beds or concentric beds can be used. The system is particularly suited to the processing of radioactive and chemically hazardous waste.

  20. Coal-feeding mechanism for a fluidized bed combustion chamber

    DOE Patents [OSTI]

    Gall, Robert L.

    1981-01-01

    The present invention is directed to a fuel-feeding mechanism for a fluidized bed combustor. In accordance with the present invention a perforated conveyor belt is utilized in place of the fixed grid normally disposed at the lower end of the fluidized bed combustion zone. The conveyor belt is fed with fuel, e.g. coal, at one end thereof so that the air passing through the perforations dislodges the coal from the belt and feeds the coal into the fluidized zone in a substantially uniform manner.

  1. Methods of forming a fluidized bed of circulating particles

    DOE Patents [OSTI]

    Marshall, Douglas W.

    2011-05-24

    There is disclosed an apparatus for forming a fluidized bed of circulating particles. In an embodiment, the apparatus includes a bottom portion having a sidewall, the sidewall defining a curvilinear profile, and the bottom portion configured to contain a bed of particles; and a gas inlet configured to produce a column of gas to carry entrained particles therein. There is disclosed a method of forming a fluidized bed of circulating particles. In an embodiment, the method includes positioning particles within a bottom portion having a sidewall, the sidewall defining a curvilinear profile; producing a column of gas directed upwardly through a gas inlet; carrying entrained particles in the column of gas to produce a fountain of particles over the fluidized bed of circulating particles and subside in the particle bed until being directed inwardly into the column of gas within the curvilinear profile.

  2. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  3. COMPUTATIONAL MODELING OF CIRCULATING FLUIDIZED BED REACTORS

    SciTech Connect (OSTI)

    Ibrahim, Essam A

    2013-01-09

    Details of numerical simulations of two-phase gas-solid turbulent flow in the riser section of Circulating Fluidized Bed Reactor (CFBR) using Computational Fluid Dynamics (CFD) technique are reported. Two CFBR riser configurations are considered and modeled. Each of these two riser models consist of inlet, exit, connecting elbows and a main pipe. Both riser configurations are cylindrical and have the same diameter but differ in their inlet lengths and main pipe height to enable investigation of riser geometrical scaling effects. In addition, two types of solid particles are exploited in the solid phase of the two-phase gas-solid riser flow simulations to study the influence of solid loading ratio on flow patterns. The gaseous phase in the two-phase flow is represented by standard atmospheric air. The CFD-based FLUENT software is employed to obtain steady state and transient solutions for flow modulations in the riser. The physical dimensions, types and numbers of computation meshes, and solution methodology utilized in the present work are stated. Flow parameters, such as static and dynamic pressure, species velocity, and volume fractions are monitored and analyzed. The differences in the computational results between the two models, under steady and transient conditions, are compared, contrasted, and discussed.

  4. Repowering with pressurized fluidized-bed combustion units

    SciTech Connect (OSTI)

    Goidich, S.J. ); Rubow, L.N. ); Kumar, S. . Environmental Services and Technologies Div.); Mukherjee, D. ); Childress, N.B. )

    1991-05-01

    Turbocharged pressurized fluidized bed combustion (PFBC) power plants operating with a gas turbine inlet temperature lower than 800{degrees}F can produce electricity more efficiently (34.2 vs. 33.5% net plant efficiency) and at a lower cost of electricity (87.8 vs. 96. 6 mill/kWh over 30 years) than conventional pulverized-coal-fired plants with scrubbers. Since the PFBC process produces lower NO{sub x} emissions than conventional pulverized-coal combustion systems and captures sulfur as part of the combustion process, and since major equipment components can be shop-assembled and shipped by barge, retrofit of an existing unit with a turbocharged PFBC boiler can be a cost-effective means for extending the life of the unit and meeting NSPS without retrofitting flue gas desulfurization systems. Using the Wisconsin Electric Power Company's Port Washington Unit 5 as an example, preliminary engineering and economic evaluations were made to investigate the merits of turbocharged PFBC retrofits. This report describes the conceptual designs of the new, major plant components; discusses how the new components are integrated with the existing balance-of-plant equipment; describes the proposed plant control system; and presents an overall economic evaluation. Because design and economic evaluations were prepared on the basis of a commercial design, first-of-a-kind costs and test programs are not included. 5 refs., 58 figs., 55 tabs.

  5. Fluidized bed combustor and coal gun-tube assembly therefor

    DOE Patents [OSTI]

    Hosek, William S. (Mt. Tabor, NJ); Garruto, Edward J. (Wayne, NJ)

    1984-01-01

    A coal supply gun assembly for a fluidized bed combustor which includes heat exchange elements extending above the bed's distributor plate assembly and in which the gun's nozzles are disposed relative to the heat exchange elements to only discharge granular coal material between adjacent heat exchange elements and in a path which is substantially equidistant from adjacent heat exchange elements.

  6. Solid fuel feed system for a fluidized bed

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A fluidized bed for the combustion of coal, with limestone, is replenished with crushed coal from a system discharging the coal laterally from a station below the surface level of the bed. A compartment, or feed box, is mounted at one side of the bed and its interior separated from the bed by a weir plate beneath which the coal flows laterally into the bed while bed material is received into the compartment above the plate to maintain a predetermined minimum level of material in the compartment.

  7. Erosion of heat exchanger tubes in fluidized beds

    SciTech Connect (OSTI)

    Johnson, E.K.; Flemmer, R.L.C.

    1991-01-01

    This final report describes the activities of the 3-year project entitled Erosion of Heat Exchanger Tubes In Fluidized Beds.'' which was completed at the end of 1990. Project accomplishments include the collection of a substantial body of wear data In a 24in. [times] 24in. fluidized bed, comparative wear results In a 6in. [times] 6in. fluidized bed, the development of a dragometer and the collection of a comprehensive set of drag force data in the 24in. [times] 24in. bed, Fast Fourier Transform (FFT) analysis of bubble probe data to establish dominant bubble frequencies in the 24in. [times] 24in. bed, the use of a heat flux gauge for measurement of heat transfer coefficients in the 24in. [times] 24in. bed and the modeling of the tube wear in the 24in. [times] 24in. bed. Analysis of the wear data from the 24in. square bed indicates that tube wear increases with increase in superficial velocity, and with increase in tube height. The latter effect is a result of the tubes higher up in the bed seeing greater movement of dense phase than tubes lower down In the bed. In addition, tube wear was found to decrease with increase in particle size, for constant superficial velocity. Three models of tube wear were formulated and provided acceptable prediction of wear when compared with the experimental data.

  8. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  9. Materials performance in fluidized-bed air heaters

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.

    1991-12-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed and use of air heaters to generate hot air for turbine systems has been in progress for a number of years. The US Department of Energy (DOE) sponsored the Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) to assess the performance of various heat exchanger materials and establish confidence in the resultant designs of fluidized-bed-combustion air heater systems. Westinghouse Electric Corporation, in association with Babcock & Wilcox, Foster Wheeler, and ABB/Combustion Engineering, prepared specifications and hardware for the ACAHE. Argonne National Laboratory, through a contract with the Rocketdyne Division of Rockwell International, conducted tests in the DOE 1.8 {times} 1.8 m atmospheric fluidized-bed combustion facility in El Segundo, California. This paper presents an assessment of the materials performance in fluidized bed environments and examines guidelines for materials selection on the basis of corrosion resistance in air and in combustion environments, mechanical properties, fabricability/thermal stability, and cost.

  10. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y.; Merriam, Norman W.; Boysen, John E.

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  11. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    SciTech Connect (OSTI)

    Rokkam, Ram

    2012-11-02

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  12. Metallic species derived from fluidized bed coal combustion. [59 references

    SciTech Connect (OSTI)

    Natusch, D.F.S.; Taylor, D.R.

    1980-01-01

    Samples of fly ash generated by the combustion of Montana Rosebud coal in an experimental 18 inch fluidized bed combustor were collected. The use of a heated cascade impactor permitted collection of size fractionated material that avoided condensation of volatile gases on the particles. Elemental concentration trends were determined as a function of size and temperature and the results compared to published reports for conventional power plants. The behavior of trace metals appears to be substantially different in the two systems due to lower operating temperatures and the addition of limestone to the fluidized bed. Corrosion of the impactor plates was observed at the highest temperature and lowest limestone feed rate sampled during the study. Data from the elemental concentration and leaching studies suggest that corrosion is most likely due to reactions involving sodium sulfate. However, it is concluded that corrosion is less of a potential problem in fluidized-bed systems than in conventional coal-fired systems.

  13. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1991-06-01

    Advanced integrated gasification combined cycle (IGCC) power systems require the development of high-temperature desulfurization sorbents capable of removing hydrogen sulfide from coal gasifier down to very low levels. The objective of this investigation was to identify and demonstrate methods for enhancing the long-term chemical reactivity and mechanical strength of zinc ferrite, a leading regenerable sorbent, for fluidized-bed applications. Fluidized sorbent beds offer significant potential in IGCC systems because of their ability to control the highly exothermic regeneration involved. However, fluidized beds require a durable, attrition-resistant sorbent in the 100--300 {mu}m size range. A bench-scale high-temperature, high- pressure (HTHP) fluidized-bed reactor (7.6-cm I.D.) system capable of operating up to 24 atm and 800{degree}C was designed, built and tested. A total of 175 sulfidation-regeneration cycles were carried out using KRW-type coal gas with various zinc ferrite formulations. A number of sorbent manufacturing techniques including spray drying, impregnation, crushing and screening, and granulation were investigated. While fluidizable sorbents prepared by crushing durable pellets and screening had acceptable sulfur capacity, they underwent excessive attrition during multicycle testing. The sorbent formulations prepared by a proprietary technique were found to have excellent attrition resistance and acceptable chemical reactivity during multicycle testing. However, zinc ferrite was found to be limited to 550{degree}C, beyond which excessive sorbent weakening due to chemical transformations, e.g., iron oxide reduction, was observed.

  14. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T.; Steinberg, Meyer

    1980-01-01

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  15. Pressurized fluidized-bed combustion technology exchange workshop

    SciTech Connect (OSTI)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  16. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  17. Fluidized bed combustor and removable windbox and tube assembly therefor

    DOE Patents [OSTI]

    DeFeo, Angelo (Totowa, NJ); Hosek, William S. (Mt. Tabor, NJ)

    1981-01-01

    A fluidized bed combustor comprises a housing having a chamber therein with a top having a discharge for the gases which are generated in the chamber and a bottom with a discharge for heated fluid. An assembly is arranged in the lower portion of the chamber and the assembly includes a lower plate which is mounted on a support flange of the housing so that it is spaced from the bottom of the chamber and defines a fluid plenum between it and the bottom of the chamber for the discharge of heated fluid. The assembly includes a heat exchanger inlet plenum having tubes therethrough for the passage of fluidizer air and a windbox above the heat exchanger plenum which has a distributor plate top wall. A portion of the chamber above the top wall defines a fluidized bed.

  18. Fluidized bed combustor and removable windbox and tube assembly therefor

    DOE Patents [OSTI]

    DeFeo, Angelo (Totowa, NJ); Hosek, William (Mt. Tabor, NJ)

    1983-01-01

    A fluidized bed combustor comprises a housing having a chamber therein with a top having a discharge for the gases which are generated in the chamber and a bottom with a discharge for heated fluid. An assembly is arranged in the lower portion of the chamber and the assembly includes a lower plate which is mounted on a support flange of the housing so that it is spaced from the bottom of the chamber and defines a fluid plenum between it and the bottom of the chamber for the discharge of heated fluid. The assembly includes a heat exchanger inlet plenum having tubes therethrough for the passage of fluidizer air and a windbox above the heat exchanger plenum which has a distributor plate top wall. A portion of the chamber above the top wall defines a fluidized bed.

  19. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J.; Kydd, Paul H.

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  20. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M.

    1982-01-01

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  1. Volatiles combustion in fluidized beds. Technical progress report, 4 March 1993--3 June 1993

    SciTech Connect (OSTI)

    Hesketh, R.P.

    1993-09-01

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization will be performed to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 March, 1993 through 3 June, 1993 is reported in this technical progress report. The work during this time period consists primarily of the startup and trouble shooting of the fluidized bed reactor and gas phase modeling of methane and propane.

  2. Design considerations and operating experience in firing refuse derived fuel in a circulating fluidized bed combustor

    SciTech Connect (OSTI)

    Piekos, S.J.; Matuny, M.

    1997-12-31

    The worldwide demand for cleaner, more efficient methods to dispose of municipal solid waste has stimulated interest in processing solid waste to produce refuse derived fuel (RDF) for use in circulating fluidized bed (CFB) boilers. The combination of waste processing and materials recovery systems and CFB boiler technology provides the greatest recovery of useful resources from trash and uses the cleanest combustion technology available today to generate power. Foster Wheeler Power Systems along with Foster Wheeler Energy Corporation and several other Foster Wheeler sister companies designed, built, and now operates a 1600 tons per day (TPD) (1450 metric tons) municipal waste-to-energy project located in Robbins, Illinois, a suburb of Chicago. This project incorporates waste processing systems to recover recyclable materials and produce RDF. It is the first project in the United States to use CFB boiler technology to combust RDF. This paper will provide an overview of the Robbins, Illinois waste-to-energy project and will examine the technical and environmental reasons for selecting RDF waste processing and CFB combustion technology. Additionally, this paper will present experience with handling and combusting RDF and review the special design features incorporated into the CFB boiler and waste processing system that make it work.

  3. Combine waste-to-energy, recycling with fluid-bed boiler

    SciTech Connect (OSTI)

    Murphy, M.L.

    1995-04-01

    This article describes a plant that will be the first to incorporate a fluidized-bed boiler to burn refuse-derived fuel exclusively. An effective long-term solid-waste management program will soon be a reality for Bladen, Cumberland, and Hoke counties, North Carolina. The key element of the program is a 600-ton/day waste-to-energy (WTE) facility, scheduled to begin commercial operation later this year. The BCH Energy project, which gets its name from the initials of the three counties it serves, will become the first fluidized-bed boiler in the US designed to be fueled solely by refuse-derived fuel (RDF). As such, it provides an innovative and efficient approach to solid-waste management in several ways: (1) Maximizes community participation in a recovery and recycling effort. (2) Maximizes additional waste handling and hauling efforts. (3) Significantly reducing waste flow into landfill. (4) Eliminating use of fossil fuel for a nearby chemical plant`s energy load. (5) Substantially improves air quality through use of the latest combustion and emissions control technology.

  4. Combustion of refuse derived fuel in a fluidized bed

    SciTech Connect (OSTI)

    Piao, Guilin; Aono, Shigeru; Mori, Shigekatsu; Deguchi, Seiichi; Fujima, Yukihisa; Kondoh, Motohiro; Yamaguchi, Masataka

    1998-12-31

    Power generation from Refuse Derived Fuel (RDF) is an attractive utilization technology of municipal solid waste. To explain the behavior of RDF-fired fluidized bed incinerator, the commercial size RDF was continuously burnt in a 30 x 30 cm bubbling type fluidized-bed combustor. It was found that 12 kg/h of RDF feed rate was too high feed for this test unit and the Co level was higher than 500 ppm. However, 10 kg/h of RDF was a proper feed rate and the Co level was kept under 150 ppm. Secondary air injection and changing air ratio from the pipe grid were effective for the complete combustion of RDE. It was also found that HCl concentration in flue gas was controlled by the calcium component contained in RDF and its level was decreased with decreasing the combustor temperature.

  5. Pulsed atmospheric fluidized bed combustor apparatus and process

    DOE Patents [OSTI]

    Mansour, Momtaz N. (Columbia, MD)

    1992-01-01

    A pulsed atmospheric fluidized bed reactor system is disclosed and claimed along with a process for utilization of same for the combustion of, e.g. high sulfur content coal. The system affords a economical, ecologically acceptable alternative to oil and gas fired combustors. The apparatus may also be employed for endothermic reaction, combustion of waste products, e.g. organic and medical waste, drying, calcining and the like.

  6. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  7. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  8. Fluidized-bed combustion of scrap tires: Technical note

    SciTech Connect (OSTI)

    Shang, J.Y.; Mei, J.S.; Notestein, J.E.

    1981-10-01

    An introduction to fluidized-bed combustion (FBC) is presented in Section 2.0. Based on this discussion of its technical development, FBC is then presented as a means of scrap tire disposal. In Section 3.0, scrap tire disposal is reviewed in the categories of (1) physical applications, (2) chemical applications, (3) pyrolysis, and (4) incineration for thermal energy recovery. Scrap tire disposal is reviewed on the basis of (1) environmental acceptability, (2) conservation of resources, (3) impact on existing industries, (4) operational feasibility, and (5) special features. The focus of this report is the fluidized-bed incineration of scrap tires for thermal energy recovery. The factors that affect scrap tire combustion are discussed in Section 4.0. These factors are (1) agitation, (2) temperature, (3) excess air, (4) residence time, (5) feed uniformity, (6) solid waste handling, and (7) pollutants emission control. In reviewing these incineration processes, (1) fuel flexibility, (2) environmental acceptability, (3) combustion efficiency, and (4) operational reliability are discussed. The results from a tire incineration experiment conducted at the Morgantown Energy Technology Center are presented in Section 5.0, and a conceptual fluidized-bed combustor is discussed in Section 6.0. Future considerations in the FBC of scrap tires are discussed in Section 7.0. 8 refs., 6 figs., 6 tabs.

  9. A NEW INTERPHASE FORCE IN TWO-PHASE FLUIDIZED BEDS

    SciTech Connect (OSTI)

    D. ZHANG; W. VANDERHEYDEN

    2001-05-01

    Mesoscale structures such as particle clusters have been observed both in experiments and in numerical simulations of circulating fluidized beds. In a numerical simulation, in order to account for the effects of such mesoscale structures, the computational grids have to be fine enough. The use of such fine grids is impractical in engineering applications due to excessive computational costs. To predict the macroscopic behavior of a fluidized bed with reasonable computation cost, they perform a second average over the averaged equations for two-phase flows. A mesoscale inter-phase exchange force is found to be the correlation of the particle volume fraction and the pressure gradient. This force is related to the mesoscale added mass of the two-phase flow. Typically, added mass for particle scale interactions is negligible in gas-solid flows since the gas density is small compared to density of solid particles. However, for a mesoscale structure, such as a bubble, the surrounding media is the mixture of gas and particles. The surrounding fluid density experienced by the mesoscale structure is the density of the surrounding mixture. Therefore, the added mass of a mesoscale structure, such as bubbles, cannot be neglected. The property of this new force is studied based on the numerical simulation of a fluidized bed using high grid resolution. It is shown that this force is important in the region where the particle volume fraction is high. The effects of the inhomogeneity to the interphase drag are also studied.

  10. Fluidized-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor. 2 figs.

  11. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOE Patents [OSTI]

    Scott, Charles D.; Strandberg, Gerald W.

    1989-01-01

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  12. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion system. Final technical report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-11-01

    Research is presented on erosion and corrosion of fluidized bed combustor component materials. The characteristics of erosion of in-bed tubes was investigated. Anti-corrosion measures were also evaluated.

  13. Fluidized-bed combustion and gasification of biomass

    SciTech Connect (OSTI)

    LePori, W.A.; Anthony, R.G.; Lalk, T.R.; Craig, J.D.

    1981-01-01

    A 0.61 meter (2 ft) diameter fluidized-bed combustion reactor was used for tests on direct combustion of cotton gin trash. Raw gin trash was continuously augered into the unit with fuel and air rates set to maintain bed temperatures of 760/sup 0/ to 816/sup 0/C (1400/sup 0/ to 1500/sup 0/F). Particulate emissions in the hot stack gases were measured and found to be lower than federal standards for incinerators. Mild steel and stainless alloy samples were placed in the hot stack gas stream to study corrosion and erosion of materials. High rates of potassium, calcium, and sodium deposits accumulated on the samples, and high erosion rates were found. A 0.3 meter (13 in) diameter fluidized-bed gasifier was used to convert raw gin trash into a combustible gas with bed temperatures between 683/sup 0/C and 881/sup 0/C (1261/sup 0/F and 1618/sup 0/F). By limiting the amount of oxygen compared to the fuel feed, only partial combustion occurs, producing heat and endothermic gasification chemical reactions. The combustible gas was composed primarily of carbon monoxide and hydrogen. It had a heating value ranging from 3.40 to 4.82 M Joules per standard cubic meter (98 to 142 Btu/scf), and about 50 percent of the heat value of the gin trash was converted into this low energy gas.

  14. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1983-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  15. Apparatus and method for controlling heat transfer between a fluidized bed and tubes immersed therein

    DOE Patents [OSTI]

    Hodges, James L. (3 Hilltop Ave., Vernon, CT 06066); Cerkanowicz, Anthony E. (8 Fieldstone Dr., Livingston, NJ 07039)

    1982-01-01

    In a fluidized bed of solid particles having one or more heat exchange tubes immersed therein, the rate of heat transfer between the fluidized particles and a fluid flowing through the immersed heat exchange tubes is controlled by rotating an arcuate shield apparatus about each tube to selectively expose various portions of the tube to the fluidized particles.

  16. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    Sibashis Banerjee; Alvin Chen; Rutton Patel; Dale Snider; Ken Williams; Timothy O'Hern; Paul Tortora

    2008-02-29

    The work detailed in this report addresses Enabling Technologies within Computational Technology by integrating a breakthrough particle-fluid computational technology into traditional Process Science and Engineering Technology. The work completed under this DOE project addresses five major development areas 1) gas chemistry in dense fluidized beds 2) thermal cracking of liquid film on solids producing gas products 3) liquid injection in a fluidized bed with particle-to-particle liquid film transport 4) solid-gas chemistry and 5) first level validation of models. Because of the nature of the research using tightly coupled solids and fluid phases with a Lagrangian description of the solids and continuum description of fluid, the work provides ground-breaking advances in reactor prediction capability. This capability has been tested against experimental data where available. The commercial product arising out of this work is called Barracuda and is suitable for a wide (dense-to-dilute) range of industrial scale gas-solid flows with and without reactions. Commercial applications include dense gas-solid beds, gasifiers, riser reactors and cyclones.

  17. Volatiles combustion in fluidized beds. [Quarterly] technical progress report, 4 December 1994--4 March 1995

    SciTech Connect (OSTI)

    Pendergrass II, R.A.; Mansker, L.D.; Hesketh, R.P.

    1995-08-01

    The goal of this project is to investigate the conditions in which volatiles will bum within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. The work conducted during the period 4 December, 1994 through, 3 March 1995 is presented in this technical progress report. The research consists of the application of a detailed chemical kinetics model for propane combustion and planned improvements in the experimental system.

  18. The local heat transfer mathematical model between vibrated fluidized beds and horizontal tubes

    SciTech Connect (OSTI)

    Zhu, Xuejun; Ye, Shichao; Pan, Xiaoheng

    2008-05-15

    A dimensionless mathematical model is proposed to predict the local heat transfer coefficients between vibrated fluidized beds and immersed horizontal tubes, and the effects of the thickness of gas film and the contact time of particle packets are well considered. Experiments using the glass beads (the average diameter bar d{sub p}=1.83mm) were conducted in a two-dimensional vibrated fluidized bed (240 mm x 80 mm). The local heat transfer law between vibrated fluidized bed and horizontal tube surface has been investigated. The results show that the values of theoretical prediction are in good agreement with experimental data, so the model is able to predict the local heat transfer coefficients between vibrated fluidized beds and immersed horizontal tubes reasonably well, and the error is in range of {+-}15%. The results can provide references for future designing and researching on the vibrated fluidized beds with immersed horizontal tubes. (author)

  19. Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

    SciTech Connect (OSTI)

    Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

    1996-02-29

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

  20. Combine waste-to-energy, recycling with fluid-bed boiler

    SciTech Connect (OSTI)

    Murphy, M.L.

    1995-09-01

    An effective long-term solid-waste management program will soon be a reality for Bladen, Cumberland, and Hoke counties, North Carolina. The key element of the program is a 600-ton/day waste-to-energy (WTE) facility, scheduled to begin commercial operation later this year. The BCH Energy project, which gets its name from the initials of the three counties it serves, will become the first fluidized-bed boiler in the US designed to be fueled solely by refuse-derived fuel (RDF). As such, it provides an innovative and efficient approach to solid-waste management in several ways: (1) maximimizes community participation in a recovery and recycling effort; (2) maximizes additional waste handling and hauling efforts; (3) significantly reducing waste flow into landfill; (4) eliminating use of fossil fuel for a nearby chemical plant`s energy load; and (5) substantially improves air quality through use of the latest combustoin and emissions control technology.

  1. Tubing wastage in fluidized-bed coal combustors (Grimethorpe PFBC (pressurized fluidized-bed combustion) Tube Bank E'')

    SciTech Connect (OSTI)

    Witherell, C.E.

    1989-10-04

    Samples of evaporator tubing from Tube Bank E'' of the Grimethorpe pressurized fluidized-bed combustion (PFBC) facility in the UK were examined in the third of a series of studies being conducted at Lawrence Livermore National Laboratory (LLNL) under sponsorship of the US Department of Energy's Morgantown Energy Technology Center (METC). The program is being conducted to identify the mechanism or mechanisms responsible for metal loss (wastage) of in-bed carbon-steel evaporator tubes in bubbling-bed coal combustors. Results of examination suggest that bed conditions were less aggressive than in previous experiments in this combustor; however, tubing wastage was observed in some samples. Observations made on these tubes are consistent with the hypothesis of tubing wastage proposed in reports of previous LLNL studies conducted under this program that the dominant cause of metal loss is exfoliation of the normally-protective oxide scale by impacting bed particulates. Good correlation was also observed with trends noted earlier that microstructure of the tubing steel plays a role in its wastage response. 12 refs., 29 figs., 3 tabs.

  2. Corrosion assessment in FBC (fluidized-bed combustion) systems

    SciTech Connect (OSTI)

    Natesan, K.

    1990-01-01

    Metallic materials selected for the construction of heat exchangers and tube support structure in fluidized-bed combustion (FBC) systems must withstand the dynamic corrosive conditions prevalent in these systems. Oxidation-sulfidation interactions leading to accelerated metal wastage of components can occur owing to the presence of sorbent deposits on metal surface and/or the low-oxygen partial pressures in the exposure environment. A number of laboratory tests were conducted to examine the influence of deposit chemistry, gas chemistry, and alloy pretreatment on corrosion of high-chromium alloys, such as, Incoloy 800 and Type 310 stainless steel. Detailed chemical and physical analyses of spent-bed materials were made and correlated with the observed corrosion behavior of the alloys. A comparative analysis was made of the influence of bubbling-bed and circulating-bed deposits on corrosion of several candidate alloys. Finally, a comparison was made of the laboratory corrosion test data with the metal wastage information developed over the years in several FBC test facilities. 5 refs., 20 figs., 3 tabs.

  3. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  4. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  5. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  6. Workshop on wear potential of bed material in fluidized-bed combustors

    SciTech Connect (OSTI)

    Not Available

    1991-11-01

    A workshop was held in November 1990 at Argonne National Laboratory to investigate the wear potential of bed material in fluidized-bed combustors (FBCs). The overall objective was to relate feedstock analyses to bed-material characteristics. The potential effects of quartz, alkali, chlorine, particle angularity, particle coatings, and coal rank were discussed. It was concluded that inadequate data exist to draw substantive conclusions, although in the case of two specific FBC facilities, high wastage rates could be related to the accumulation of quartz particles in the bed. The primary research needs identified in the workshop were for standardized methodologies for sampling solids, for measuring their characteristics, and for correlating those characteristics with some measure of materials wastage.

  7. Capacitance-level/density monitor for fluidized-bed combustor

    DOE Patents [OSTI]

    Fasching, George E.; Utt, Carroll E.

    1982-01-01

    A multiple segment three-terminal type capacitance probe with segment selection, capacitance detection and compensation circuitry and read-out control for level/density measurements in a fluidized-bed vessel is provided. The probe is driven at a high excitation frequency of up to 50 kHz to sense quadrature (capacitive) current related to probe/vessel capacitance while being relatively insensitive to the resistance current component. Compensation circuitry is provided for generating a negative current of equal magnitude to cancel out only the resistive component current. Clock-operated control circuitry separately selects the probe segments in a predetermined order for detecting and storing this capacitance measurement. The selected segment acts as a guarded electrode and is connected to the read-out circuitry while all unselected segments are connected to the probe body, which together form the probe guard electrode. The selected probe segment capacitance component signal is directed to a corresponding segment channel sample and hold circuit dedicated to that segment to store the signal derived from that segment. This provides parallel outputs for display, computer input, etc., for the detected capacitance values. The rate of segment sampling may be varied to either monitor the dynamic density profile of the bed (high sampling rate) or monitor average bed characteristics (slower sampling rate).

  8. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, Charles D.; Petersen, James N.; Davison, Brian H.

    1996-01-01

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, as larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor.

  9. Erosivity of particles in circulating fluidized bed combustors

    SciTech Connect (OSTI)

    Levy, A.V.; Wang, B.Q.; Geng, G.Q. ); Mack, W. )

    1989-01-01

    The metal wastage of superheater tubes in the convection pass region of circulating fluidized bed combustors (CFBC) is a current problem. An investigation was carried out to determine what kinds of metal loss rates and mechanisms occurred when the various types of particles in CFBC's were used as the erodent in a laboratory blast nozzle tester. The laboratory tests were compared to in-service exposures. A loss mechanism was established that was based on metal losses and the observed microstructures of E-C surfaces. It was additionally determined that more angular and larger size particles have a greater level of erosivity and that the particles must be strong enough not to shatter upon impact in order to be erosive. Favorable comparisons between laboratory and in-service loss mechanisms are reported.

  10. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, C.D.; Petersen, J.N.; Davison, B.H.

    1996-07-09

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, and larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. 8 figs.

  11. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  12. Characterization of Biofilm in 200W Fluidized Bed Reactors

    SciTech Connect (OSTI)

    Lee, Michelle H.; Saurey, Sabrina D.; Lee, Brady D.; Parker, Kent E.; Eisenhauer, Emalee ER; Cordova, Elsa A.; Golovich, Elizabeth C.

    2014-09-29

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry evaluations, a more complete understanding of the balance between system additions (nutrients, groundwater) and biology can be achieved, thus increasing long-term predictions of performance. These analyses uniquely provide information that can be used in optimizing the overall performance, efficiency, and stability of the system both in real time as well as over the long-term, as the system design is altered or improved and/or new streams are added.

  13. Method and apparatus for improving heat transfer in a fluidized bed

    DOE Patents [OSTI]

    Lessor, Delbert L. (Richland, WA); Robertus, Robert J. (Richland, WA)

    1990-01-01

    An apparatus contains a fluidized bed that includes particles of different triboelectrical types, each particle type acquiring an opposite polarity upon contact. The contact may occur between particles of the two types or between particles of etiher type and structure or fluid present in the apparatus. A fluidizing gas flow is passed through the particles to produce the fluidized bed. Immersed within the bed are electrodes. An alternating EMF source connected to the electrodes applies an alternating electric field across the fluidized bed to cause particles of the first type to move relative to particles of the second type and relative to the gas flow. In a heat exchanger incorporating the apparatus, the electrodes are conduits conveying a fluid to be heated. The two particle types alternately contact each conduit to transfer heat from a hot gas flow to the second fluid within the conduit.

  14. Design and performance of a high-pressure Fischer-Tropsch fluidized bed reactor

    SciTech Connect (OSTI)

    Weimer, A.W.; Quarderer, G.J.; Cochran, G.A.; Conway, M.M. )

    1988-01-01

    A 900 kg/day, CO/H/sub 2/, high-pressure, fluidized bed, pilot reactor was designed from first principles to achieve high reactant conversions and heat removal rates for the Fischer-Tropsch (F-T) synthesis of liquefied petroleum gases (LPG's). Suppressed bubble growth at high pressure allowed high reactant conversions which nearly matched those obtained at identical conditions in a lab scale fixed bed reactor. For GHSV approximately 1400 hr/sup -1/ and T = 658 {Kappa} at P approximately 7000 {kappa}Pa, reactant conversion exceeded 75%. The reactor heat removal capability exceeded twice design performance with the fluidized bed easily operating under thermally stable conditions. The fluidized catalyst was a potassium promoted, molybdenum on carbon (Mo/{Kappa}/C) catalyst which did not produce any detrimental waxy products. Long catalyst lifetimes of 1000 hrs on steam between regenerations allowed the fluidized bed to be operated in a batch mode.

  15. Circulating Fluidized Bed (CFB) Boilers Market will grow due...

    Open Energy Info (EERE)

    Energy Concerns to Push Global Market to Grow at 8.1% CAGR from 2013 to 2019 Oil Shale Market is Estimated to Reach USD 7,400.70 Million by 2022 more Group members (32)...

  16. Synthetic aggregate compositions derived from spent bed materials from fluidized bed combustion and fly ash

    DOE Patents [OSTI]

    Boyle, Michael J.

    1994-01-01

    Cementitious compositions useful as lightweight aggregates are formed from a blend of spent bed material from fluidized bed combustion and fly ash. The proportions of the blend are chosen so that ensuing reactions eliminate undesirable constituents. The blend is then mixed with water and formed into a shaped article. The shaped article is preferably either a pellet or a "brick" shape that is later crushed. The shaped articles are cured at ambient temperature while saturated with water. It has been found that if used sufficiently, the resulting aggregate will exhibit minimal dimensional change over time. The aggregate can be certified by also forming standardized test shapes, e.g., cylinders while forming the shaped articles and measuring the properties of the test shapes using standardized techniques including X-ray diffraction.

  17. FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL

    SciTech Connect (OSTI)

    Williams, M

    2008-05-09

    Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

  18. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, J.; Koskinen, J.

    1995-08-22

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  19. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, Juhani; Koskinen, Jari

    1995-01-01

    Hot gases from a pressurized fluidized bed reactor system are purified. Under superatmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a flitrate cake on the surface of the separator, and a reducing agent--such as an NO.sub.x reducing agent (like ammonia), is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1-20 cm/s) during passage of the gas through the filtrate cake while at superatmospheric pressure. Separation takes place within a distinct pressure vessel the interior of which is at a pressure of about 2-100 bar, and-introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine).

  20. Computer modeling of a CFB (circulating fluidized bed) gasifier

    SciTech Connect (OSTI)

    Gidaspow, D.; Ding, J.

    1990-06-01

    The overall objective of this investigation is to develop experimentally verified models for circulating fluidized bed (CFB) combustors. This report presents an extension of our cold flow modeling of a CFB given in our first quarterly report of this project and published in Numerical Methods for Multiphase Flows'' edited by I. Celik, D. Hughes, C. T. Crowe and D. Lankford, FED-Vol.91, American Society of Mechanical Engineering, pp47--56 (1990). The title of the paper is Multiphase Navier-Stokes Equation Solver'' by D. Gidaspow, J. Ding and U.K. Jayaswal. To the two dimensional code described in the above paper we added the energy equations and the conservation of species equations to describe a synthesis gas from char producer. Under the simulation conditions the injected oxygen reacted near the inlet. The solid-gas mixing was sufficiently rapid that no undesirable hot spots were produced. This simulation illustrates the code's capability to model CFB reactors. 15 refs., 20 figs.

  1. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 3. Heat transfer between a supernatant gas and a flowing shallow fluidized bed of solids. Final technical report, October 1, 1986

    SciTech Connect (OSTI)

    Boyd, J.H.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Volume II describes the details of heat-transfer studies in a dry fluidized-bed system (called ''heat tray''), which has been proposed for heat recovery from hot gases and for heat management in exothermic reactions. In particular, this report presents the results of bench-scale and pilot-scale experimental studies which quantify heat transfer between a hot supernatant gas (S-gas) and a flowing shallow fluidized bed of solids. A fractional-factorial design of experiments has been performed on two heat-tray systems using three different solids. The results show that fine fluid cracking catalyst (FCC) particles out-perform larger alumina spheres as a fluidized solid. Heat transfer coefficients between the supernatant gas and the shallow fluidized bed approaches 440 W/m/sup 2/-K using FCC with a heat-exchange area of 0.124 m/sup 2/. Various S-gas inlet nozzle configurations have been studied, with a nozzle height equal to one-half of the static bed height (0.051 m) giving the best results. The study shows that short heat-tray lengths (< 0.8 m) are desirable and that S-gas redistributors are needed to compartmentalize the unit. An economic analysis shows that the proposed heat tray would be economically feasible for adaption as a boiler feedwater preheater in a small steam-generation facility, using boiler combustion gases as the S-gas. The payback time for the system would be as short as 1.9 years when used continuously. The heat transfer results from a supernatant gas to a flowing shallow fluidized bed represent the only data reported thus far, and have led to a better understanding of the heat management in the proposed ''heat-tray'' reactor for Fischer-Tropsch synthesis. 20 refs., 46 figs., 15 tabs.

  2. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-06-30

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

  3. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  4. Erosion of heat exchanger tubes in fluidized beds. Annual report, 1990

    SciTech Connect (OSTI)

    Johnson, E.K.; Flemmer, R.L.C.

    1991-01-01

    This final report describes the activities of the 3-year project entitled ``Erosion of Heat Exchanger Tubes In Fluidized Beds.`` which was completed at the end of 1990. Project accomplishments include the collection of a substantial body of wear data In a 24in. {times} 24in. fluidized bed, comparative wear results In a 6in. {times} 6in. fluidized bed, the development of a dragometer and the collection of a comprehensive set of drag force data in the 24in. {times} 24in. bed, Fast Fourier Transform (FFT) analysis of bubble probe data to establish dominant bubble frequencies in the 24in. {times} 24in. bed, the use of a heat flux gauge for measurement of heat transfer coefficients in the 24in. {times} 24in. bed and the modeling of the tube wear in the 24in. {times} 24in. bed. Analysis of the wear data from the 24in. square bed indicates that tube wear increases with increase in superficial velocity, and with increase in tube height. The latter effect is a result of the tubes higher up in the bed seeing greater movement of dense phase than tubes lower down In the bed. In addition, tube wear was found to decrease with increase in particle size, for constant superficial velocity. Three models of tube wear were formulated and provided acceptable prediction of wear when compared with the experimental data.

  5. Pressurized fluidized-bed hydroretorting of Eastern oil shales

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S. ); Schultz, C.W. ); Parekh, B.K. ); Misra, M. ); Bonner, W.P. )

    1992-11-01

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  6. The Nucla Circulating Fluidized-Bed Demonstration Project: A U.S. DOE post-project assessment

    SciTech Connect (OSTI)

    1995-06-01

    This report is a post-project assessment of the Nucla Circulating Fluidized-Bed (CFB) Demonstration Project, the second project to be completed in the DOE Clean Coal Technology Program. Nucla was the first successful utility repowering project in the US, increasing the capacity of the original power station from 36 MW(e) to 110 MW(e) and extending its life by 30 years. In the CFB boiler, combustion and desulfurization both take place in the fluidized bed. Calcium in the sorbent captures sulfur dioxide and the relatively low combustion temperatures limit NOx formation. Hot cyclones separate the larger particles from the gas and recirculates them to the lower zones of the combustion chambers. This continuous circulation of coal char and sorbent particles is the novel feature of CFB technology. This demonstration project significantly advanced the environmental, operational, and economic potential of atmospheric CFB technology, precipitating a large number of orders for atmospheric CFB equipment. By 1994, more than 200 atmospheric CFB boilers have been constructed worldwide. Although at least six CFB units have been operated, the Nucla project`s CFB database continues to be an important and unique resource for the design of yet larger atmospheric CFB systems. The post-project assessment report is an independent DOE appraisal of the success a completed project had in achieving its objectives and aiding in the commercialization of the demonstrated technology. The report also provides an assessment of the expected technical, environmental, and economic performance of the commercial version of the technology as well as an analysis of the commercial market.

  7. High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors

    SciTech Connect (OSTI)

    Hou, Peggy Y.; MacAdam, S.; Niu, Y.; Stringer, J.

    2003-04-22

    Heat-exchanger tubes in fluidized bed combustors (FBCs) often suffer material loss due to combined corrosion and erosion. Most severe damage is believed to be caused by the impact of dense packets of bed material on the lower parts of the tubes. In order to understand this phenomenon, a unique laboratory test rig at Berkeley was designed to simulate the particle hammering interactions between in-bed particles and tubes in bubbling fluidized bed combustors. In this design, a rod shaped specimen is actuated a short distance within a partially fluidized bed. The downward specimen motion is controlled to produce similar frequencies, velocities and impact forces as those experienced by the impacting particle aggregates in practical systems. Room temperature studies have shown that the degradation mechanism is a three-body abrasion process. This paper describes the characteristics of this test rig, reviews results at elevated temperatures and compares them to field experience. At higher temperatures, deposits of the bed material on tube surfaces can act as a protective layer. The deposition depended strongly on the type of bed material, the degree of tube surface oxidation and the tube and bed temperatures. With HCl present in the bed, wastage was increased due to enhanced oxidation and reduced oxide scale adherence.

  8. A 2.5D Computational Method to Simulate Cylindrical Fluidized Beds

    SciTech Connect (OSTI)

    Li, Tingwen; Benyahia, Sofiane; Dietiker, Jeff; Musser, Jordan; Sun, Xin

    2015-02-17

    In this paper, the limitations of axisymmetric and Cartesian two-dimensional (2D) simulations of cylindrical gas-solid fluidized beds are discussed. A new method has been proposed to carry out pseudo-two-dimensional (2.5D) simulations of a cylindrical fluidized bed by appropriately combining computational domains of Cartesian 2D and axisymmetric simulations. The proposed method was implemented in the open-source code MFIX and applied to the simulation of a lab-scale bubbling fluidized bed with necessary sensitivity study. After a careful grid study to ensure the numerical results are grid independent, detailed comparisons of the flow hydrodynamics were presented against axisymmetric and Cartesian 2D simulations. Furthermore, the 2.5D simulation results have been compared to the three-dimensional (3D) simulation for evaluation. This new approach yields better agreement with the 3D simulation results than with axisymmetric and Cartesian 2D simulations.

  9. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Andy Wu; John T. Riley

    2005-01-30

    This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period October 1, 2004 through December 31, 2004. The following tasks have been completed. First, the renovation of the new Combustion Laboratory and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building have proceeded well. Second, the detailed design of supporting and hanging structures for the CFBC was completed. Third, the laboratory-scale simulated fluidized-bed facility was modified after completing a series of pretests. The two problems identified during the pretest were solved. Fourth, the carbonization of chicken waste and coal was investigated in a tube furnace and a Thermogravimetric Analyzer (TGA). The experimental results from this study are presented in this report. Finally, the proposed work for the next quarter has been outlined in this report.

  10. Metal wastage design guidelines for bubbling fluidized-bed combustors. Final report

    SciTech Connect (OSTI)

    Lyczkowski, R.W.; Podolski, W.F.; Bouillard, J.X.; Folga, S.M.

    1992-11-01

    These metal wastage design guidelines identify relationships between metal wastage and (1) design parameters (such as tube size, tube spacing and pitch, tube bundle and fluidized-bed height to distributor, and heat exchanger tube material properties) and (2) operating parameters (such as fluidizing velocity, particle size, particle hardness, and angularity). The guidelines are of both a quantitative and qualitative nature. Simplified mechanistic models are described, which account for the essential hydrodynamics and metal wastage processes occurring in bubbling fluidized beds. The empirical correlational approach complements the use of these models in the development of these design guidelines. Data used for model and guideline validation are summarized and referenced. Sample calculations and recommended design procedures are included. The influences of dependent variables on metal wastage, such as solids velocity, bubble size, and in-bed pressure fluctuations, are discussed.

  11. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Technical progress report No. 14, [January 1, 1996--March 31, 1996

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-04-01

    The material wastage tests were continued to analyze erosion phenomena under the simulated erosion conditions of in-bed tubes in fluidized bed combustors. AISI 1018 steel and three thermal sprayed coating specimens were tested at an elevated temperature (300{degrees}C) using nozzle type erosion tester. Bed ashes retrieved from the operating biomass-fired boiler were used for erodent particles at a particle loading of 375 g, at particle impact angle of 30{degrees}, at particle velocity 60 m/s for exposure periods of 4 hours. The specimens were water-cooled on the backside. The material wastage of specimens was determined by thickness measurements. Test results can be seen that the cooled specimen had greater material wastage than that of the uncooled specimens. In addition, all of thermal-sprayed coating specimens for both cooled and uncooled specimens could reduce the erosion wastage rates as compared with 1018 steel. Among the three thermal-sprayed coatings, a DS-105 specimen of high velocity oxygen fuel spraying exhibited the lowest erosion wastage rate. When tested a higher particle velocity (60 m/s), but at the same elevated temperature (300{degrees}C), the material wastage rate of all three coatings was about 6 to 18 times higher than that of the material wastage at a low particle velocity (2.5 m/s).

  12. ADVANCED SORBENT DEVELOPMENT PROGRAM; DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E. AYALA; V.S. VENKATARAMANI

    1998-09-30

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.?s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration tempera-tures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent develop-ment at General Electric?s Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  13. 3-D capacitance density imaging of fluidized bed

    DOE Patents [OSTI]

    Fasching, George E.

    1990-01-01

    A three-dimensional capacitance density imaging of a gasified bed or the like in a containment vessel is achieved using a plurality of electrodes provided circumferentially about the bed in levels and along the bed in channels. The electrodes are individually and selectively excited electrically at each level to produce a plurality of current flux field patterns generated in the bed at each level. The current flux field patterns are suitably sensed and a density pattern of the bed at each level determined. By combining the determined density patterns at each level, a three-dimensional density image of the bed is achieved.

  14. FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    HEWITT WM

    2011-04-08

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

  15. Materials performance in coal-fired fluidized-bed combustion environments

    SciTech Connect (OSTI)

    Natesan, K.

    1993-07-01

    Development of cogeneration systems that involve combustion of coal in a fluidized bed for the generation of electricity and process heat has been in progress for a number of years. This paper addresses some of the key components in these systems, materials requirements/performance, and areas where additional effort is needed to improve the viability of these concepts for electric power generation.

  16. Experimental development of a multi-solid fluidized bed reactor concept

    SciTech Connect (OSTI)

    Litt, R.D.; Paisley, M.A.; Tewksbury, T.L.

    1990-02-01

    Battelle's Columbus Division is developing a coal mild gasification process based upon the Multi-Solid Fluidized bed reactor system to produce high quality liquid and gaseous products. This process uses 2-stages to gasify coal at high throughputs to produce a range of products in compact reactors without requiring an oxygen plant. 8 refs., 14 figs., 12 tabs.

  17. An assessment of performance of materials for FBC (fluidized-bed combustion) air heater applications

    SciTech Connect (OSTI)

    Natesan, K.; Miller, S.A.; Podolski, W.F.

    1986-10-01

    The major materials issue in the commercialization of fluidized-bed combustion (FBC) systems for utility cogeneration applications is the corrosion/erosion degradation of in-bed components. To examine this issue, pertinent materials information was collected from 13 sources that included 16 different experimental fluidized-bed combustors (four pressurized, the other atmospheric), and a detailed analysis of the data was performed. The data analysis confirmed that austenitic stainless steels (notably Types 304 and 310) and cobalt-base alloys (notably Haynes 188) are superior to nickel-base alloys. Type 347 stainless steel and Incoloy 800H are questionable from the point of view of metal wastage. Very limited data are available for claddings and coatings. The correlations of the corrosion rate data presented in this paper for several of the more promising alloy candidates for air heater application provide guidelines for the selection of materials with reasonably assured performance in a corrosive environment.

  18. Fluidized bed heat exchanger with water cooled air distributor and dust hopper

    DOE Patents [OSTI]

    Jukkola, Walfred W.; Leon, Albert M.; Van Dyk, Jr., Garritt C.; McCoy, Daniel E.; Fisher, Barry L.; Saiers, Timothy L.; Karstetter, Marlin E.

    1981-11-24

    A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

  19. Proceedings of the sixth international conference on fluidized bed combustion. Volume II. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. The papers covered recent developments in atmospheric and pressurized fluidized-bed combustion, especially the design, operation and control of pilot and demonstration plants. The cleanup of combustion products and the erosion, corrosion and fouling of gas turbines was emphasized also. Fifty-five papers from Volume 2 of the proceedings have been entered individually into EDB and ERA; five papers had been entered previously from other sources. (LTN)

  20. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan; Kunlei Liu; John T. Riley

    2004-01-01

    The purpose of this report is to summarize the progress made on the project ''Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion (CFBC) System'' in this quarter (September-December of 2003). The main tasks in this quarter consisted of the following four parts. First, all documents for managing this project have been prepared and sent to the Office of Project Management at the US Department of Energy's (DOE's) National Energy Technology Laboratory (NETL). Second, plans for the renovation of space for a new combustion laboratory for the CFBC system has progressed smoothly. Third, considerable progress in the design of the CFBC system has been made. Finally, a lab-scale simulated fluidized-bed combustion facility has been set up in order to make some fundamental investigations of the co-firing of coal with waste materials in the next quarter. Proposed work for the next quarter has been outlined in this report.

  1. Proceedings of the Sixth International Conference on Fluidized Bed Combustion. Volume 1. Plenary sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held at the Atlanta Hilton, Atlanta, Georgia, April 9-11, 1980. The papers in this volume involved presentation of the research and development programs of the US (US DOE, TVA, EPRI and US EPA), United Kingdom, Federal Republic of Germany and the People's Republic of China. Eight papers from Vol. 1 (Plenary Sessions) of the proceedings have been entered individually into EDB and ERA. (LTN)

  2. Design and performance of a fluidized-bed incinerator for TRU combustible wastes

    SciTech Connect (OSTI)

    Meile, L.J.; Meyer, F.G.

    1982-01-01

    Problems encountered in the incineration of glovebox generated waste at Rocky Flats Plant (RFP) led to the development of a fluidized-bed incineration (FBI) system for transuranic (TRU) combustible wastes. Laboratory and pilot-scale testing of the process preceded the installation of an 82-kg/h production demonstration incinerator at RFP. The FBI process is discussed, and the design of the demonstration incinerator is described. Operating experience and process performance for both the pilot and demonstration units are presented.

  3. Proceedings of the sixth international conference on fluidized bed combustion. Volume III. Technical sessions

    SciTech Connect (OSTI)

    1980-08-01

    The Sixth International Conference on Fluidized Bed Combustion was held April 9-11, 1980, at the Atlanta Hilton, Atlanta, Georgia. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the US Environmental Protection Agency, and the Tennessee Valley Authority. Forty-five papers from Vol. III of the proceedings have been entered individually into EDB and ERA. Two papers had been entered previously from other sources. (LTN)

  4. Apparatus for high flux photocatalytic pollution control using a rotating fluidized bed reactor

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2003-06-24

    An apparatus based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. An apparatus for high-flux photocatalytic pollution control is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

  5. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  6. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  7. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  8. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  9. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G.; Gerritsen, W.; Stewart, A.; Robinson, K.

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock & Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  10. Materials performance in the atmospheric fluidized-bed cogeneration air heater experiment

    SciTech Connect (OSTI)

    Natesan, K.; Podolski, W.; Wang, D.Y.; Teats, F.G. ); Gerritsen, W.; Stewart, A.; Robinson, K. )

    1991-02-01

    The Atmospheric Fluidized-Bed Cogeneration Air Heater Experiment (ACAHE) sponsored by the US Department of Energy (DOE) was initiated to assess the performance of various heat-exchanger materials to be used in fluidized-bed combustion air heater systems. Westinghouse Electric Corporation, through subcontracts with Babcock Wilcox, Foster Wheeler, and ABB Combustion Engineering Systems, prepared specifications and hardware for the ACAHE tests. Argonne National Laboratory contracted with Rockwell International to conduct tests in the DOE atmospheric fluidized-bed combustion facility. This report presents an overview of the project, a description of the facility and the test hardware, the test operating conditions, a summary of the operation, and the results of analyzing specimens from several uncooled and cooled probes exposed in the facility. Extensive microstructural analyses of the base alloys, claddings, coatings, and weldments were performed on specimens exposed in several probes for different lengths of time. Alloy penetration data were determined for several of the materials as a function of specimen orientation and the exposure location in the combustor. Finally, the data were compared with earlier laboratory test data, and the long-term performance of candidate materials for air-heater applications was assessed.

  11. Pressurized fluidized bed combustion low temperature cycle demonstration plant

    SciTech Connect (OSTI)

    Mukherjee, D.K.

    1984-06-01

    The merits of the turbocharged PFBC cycle are well known. Brown Boveri have been working in the past on a concept to commercialize this technology. As the leader of a team, with Foster Wheeler, Burns and Roe and Research Cottrell, Brown Boveri have conceived a turbocharged PFBC retrofit demonstration plant (20 MWe/40 MWe, net heat rate 11,000 BTU/kWh) which is discussed below. Several old power stations in the USA have small coal-fired electric generatin units which are inactive. The boilers are usually unreliable and their overhauling is uneconomical. The balance of the systems is quite often in a relatively good condition. In this retrofit concept the existing conventional boiler is replaced by a field-assembled PFBC steam generator with pneumatic feed system. It is considered that the steam turbogenerator with its complete condensing plant, together with the coal handling and the storage system can be used. The estimated total construction cost for the retrofit installation amounts to $28,000,000 for the 20 MWe and to $40,200,000 for the 40 MWe plant. This price is accurate to within plus/minus 20%. An extrapolation of these costs for a 80 MWe retrofit unit using barge transport for shop-fabricated and assembled components and applying coal-water slurry feed system result in an investment cost of $600/kW approximately. The cost of a retrofit plant looks attractive and indicates that the PFBC turbocharged cycle is economical compared to the conventional plant with FGD, as has been reported before. Improved cost prediction for a 80 MWe unit is only possible if a conceptual design is carried out.

  12. Effect of operating and design parameters on fluidized-bed combustor in-bed tube metal wastage

    SciTech Connect (OSTI)

    Deffenbaugh, D.M.; Wei, W.; Page, R.A.

    1988-04-01

    The overall program objective is to determine the effect of operating and design parameters of fluidized-bed combustors (FBCs) on in-bed tube metal wastage. The overall program approach is: (1) develop an experimental approach for acquiring tube metal wastage data under controlled and measurable conditions that reproduce the combined local mechanical and chemical environment that exists at the FBC in-bed tube surface, (2) document the precise local mechanical and chemical environment at the in-bed tube surface of an FBC and correlate these local data with global bed operating and design parameters, (3) use the above experimental approach over the entire range of documented local environments to develop a complete database of tube metal wastage results, and (4) analyze this database to determine the effect of operating and design parameters on in-bed tube metal wastage. The project consisted of a literature review, facility design and fabrication, experimentation, and data analysis. The following chapters of this report summarize each of these activities. 80 refs., 47 figs., 11 tabs.

  13. Laboratory studies on corrosion of materials for fluidized bed combustion applications

    SciTech Connect (OSTI)

    Natesan, K.

    1990-10-01

    An extensive corrosion test program was conducted at Argonne National Laboratory to evaluate the corrosion performance of metallic structural materials in environments that simulate both steady-state and off-normal exposure conditions anticipated in fluidized bed combustion (FBC) systems. This report discusses the possible roles of key parameters, such as sorbent and gas chemistries, metal temperature, gas cycling conditions, and alloy pretreatment, in the corrosion process. Data on scale thickness and intergranular penetration depth are presented for several alloys as a function of the chemistry of the exposure environment, deposit chemistry, and exposure time. Test results were obtained to compare the corrosion behavior of materials in the presence of reagent grade sorbent compounds and spent-bed materials from bubbling- and circulating-fluid-bed systems. Finally, the laboratory test results were compared with metal wastage information developed over the years in several fluidized bed test facilities. Metallic alloys chosen for the tests were carbon steel, Fe-2 1/4Cr-1Mo and Fe-9Cr-1Mo ferritic steels. Types 304 and 310 stainless steel, and Incoloy 800. 26 refs., 61 figs., 8 tabs.

  14. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume V. Appendix: stability and instability in fluidized-bed combustion

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the fifth of the seven volumes series of our Phase II Final Report. The material developed in this volume has not been incorporated into the system model. It will be used as a precursor of a transient model to be developed in the next phase of our model work. There have been various fluidized combustor models of differing complexity and scope published in the literature. Most of these models have identified and predicted - often in satisfactory agreement with results from pilot units - the key steady state combustor characteristics such as the mass of carbon in the bed (carbon loading), the combustion efficiency, the sulfur retention by the solid sorbent and the pollutant (mainly NO/sub x/) emissions. These models, however, cannot be in most instances successfully used to study the extinction and ignition characteristics of the combustor because they are isothermal in structure in the sense that the bed temperature is not an output variable but rather an input one and must be a priori specified. In order to remedy these inadequacies of the previous models, we here present a comprehensive account of the formulation and some typical results of a new nonisothermal model which has been developed in order to study, among other things, the ignition and extinction characteristics of the AFBC units. This model is able to predict the temperature patterns in the bed, the carbon loading, the combustion efficiency and the O/sub 2/ and CO concentration profiles in the combustor for the different design or operational characteristics.

  15. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    SciTech Connect (OSTI)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles. It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.

  16. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tingwen; Dietiker, Jean-François; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numericalmore » results show that CFD can predict the complex gas–solids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.« less

  17. MFIX simulation of NETL/PSRI challenge problem of circulating fluidized bed

    SciTech Connect (OSTI)

    Li, Tingwen; Dietiker, Jean-Franois; Shahnam, Mehrdad

    2012-12-01

    In this paper, numerical simulations of NETL/PSRI challenge problem of circulating fluidized bed (CFB) using the open-source code Multiphase Flow with Interphase eXchange (MFIX) are reported. Two rounds of simulation results are reported including the first-round blind test and the second-round modeling refinement. Three-dimensional high fidelity simulations are conducted to model a 12-inch diameter pilot-scale CFB riser. Detailed comparisons between numerical results and experimental data are made with respect to axial pressure gradient profile, radial profiles of solids velocity and solids mass flux along different radial directions at various elevations for operating conditions covering different fluidization regimes. Overall, the numerical results show that CFD can predict the complex gassolids flow behavior in the CFB riser reasonably well. In addition, lessons learnt from modeling this challenge problem are presented.

  18. Corrosion behavior of materials in FBC (fluidized-bed combustion) environments

    SciTech Connect (OSTI)

    Natesan, K.

    1990-04-01

    Oxidation-sulfidation interactions that lead to accelerated metal wastage of components can occur in fluidized-bed combustion (FBC) systems, owing to the presence of sorbent deposits on metal surfaces and/or the low oxygen partial pressures in the exposure environment. Laboratory tests were conducted to examine the influence of deposit and gas chemistry and alloy pretreatment on corrosion of high-chromium alloys such as Incoloy 800 and Type 310 stainless steel. Detailed chemical and physical analyses that were conducted on spent-bed materials were correlated with the observed corrosion behavior of the alloys. The influence of bubbling- and circulating-bed deposits on the corrosion of several candidate alloys was comparatively analyzed. 6 refs., 8 figs.

  19. Heavy oil upgrading via fluidized bed processing and hydrogenation processing

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1995-09-01

    California is the second largest crude oil producer in the lower 48 states. Nearly half of its production is heavy oil, difficult to transport and costly to refine. Given better methods of processing, production could be expanded. Likewise, huge worldwide reserves of heavy oils could be better exploited if more attractive processing methods were available. Midway Sunset crude at 11.8 API gravity, is a fairly difficult crude to process. It has about 1.5 percent sulfur, a very high nitrogen content, in the range of 0.7--0.8%, and metals of approximately 120--170 ppm, vanadium plus nickel. The authors will be reporting here results of the pilot plant testing to see whether non-catalytic fluid bed cracking technology, operated at low conversion, followed by hydrogenation would be economically attractive. Results suggest that this approach is competitive with delayed coking and with atmospheric resid desulfurization. This approach successfully combines carbon removal and hydrogen addition techniques for heavy oil upgrading. Comparative yields, product quality and economic considerations are reviewed in this study.

  20. Two stage, low temperature, catalyzed fluidized bed incineration with in situ neutralization for radioactive mixed wastes

    SciTech Connect (OSTI)

    Wade, J.F.; Williams, P.M.

    1995-05-17

    A two stage, low temperature, catalyzed fluidized bed incineration process is proving successful at incinerating hazardous wastes containing nuclear material. The process operates at 550{degrees}C and 650{degrees}C in its two stages. Acid gas neutralization takes place in situ using sodium carbonate as a sorbent in the first stage bed. The feed material to the incinerator is hazardous waste-as defined by the Resource Conservation and Recovery Act-mixed with radioactive materials. The radioactive materials are plutonium, uranium, and americium that are byproducts of nuclear weapons production. Despite its low temperature operation, this system successfully destroyed poly-chlorinated biphenyls at a 99.99992% destruction and removal efficiency. Radionuclides and volatile heavy metals leave the fluidized beds and enter the air pollution control system in minimal amounts. Recently collected modeling and experimental data show the process minimizes dioxin and furan production. The report also discusses air pollution, ash solidification, and other data collected from pilot- and demonstration-scale testing. The testing took place at Rocky Flats Environmental Technology Site, a US Department of Energy facility, in the 1970s, 1980s, and 1990s.

  1. Simulation of NOx emission in circulating fluidized beds burning low-grade fuels

    SciTech Connect (OSTI)

    Afsin Gungor

    2009-05-15

    Nitrogen oxides are a major environmental pollutant resulting from combustion. This paper presents a modeling study of pollutant NOx emission resulting from low-grade fuel combustion in a circulating fluidized bed. The simulation model accounts for the axial and radial distribution of NOx emission in a circulating fluidized bed (CFB). The model results are compared with and validated against experimental data both for small-size and industrial-size CFBs that use different types of low-grade fuels given in the literature. The present study proves that CFB combustion demonstrated by both experimental data and model predictions produces low and acceptable levels of NOx emissions resulting from the combustion of low-grade fuels. Developed model can also investigate the effects of different operational parameters on overall NOx emission. As a result of this investigation, both experimental data and model predictions show that NOx emission increases with the bed temperature but decreases with excess air if other parameters are kept unchanged. 37 refs., 5 figs., 5 tabs.

  2. Second-generation pressurized fluidized bed combustion plant: Phase 1, Task 2 topical report---Grimethorpe tube bundle E'' wastage evaluation

    SciTech Connect (OSTI)

    Kegel, W.

    1989-08-01

    Foster Wheeler Development Corporation (FWDC) took part in a pressurized fluidized bed combustion (PFBC) test program at the Grimethorpe PFBC facility in England. FWDC's participation included generating data to assess comparative wear rates and patterns on several different tubing alloys and surface protection techniques. The alloys and protection techniques are being used in, or are planned for, commercial atmospheric and pressurized fluidized bed boilers. Tubular specimens which were grouped into ten classes: carbon steel; finned carbon steel; finned 2-1/4%Cr-1%Mo; finned and studded carbon steel; finned and studded 2-1/4%Cr-1%Mo; finned and studded Type 347H stainless steel; chromized carbon steel; chromized 2-1/4%Cr-1%Mo; finned, studded and chromized carbon steel; and finned, studded and chromized 2-1/4%Cr-1%Mo. The materials are typical of those normally used in boiler service for carrying water, generating steam, and superheating steam. The test program and spanned approximately 1400 operating hours and was composed of three test sequences. Each test in the A2 series was run with a different fuel feedstock. The first utilized a UK coal (dry); the second evaluated a US coal/water mixture (slurry); the third test employed a UK coal slurry. Test runs with UK coal included a limestone sorbent while dolomite was used in the second test sequence. Exposed test specimens were removed for independent surface scale analysis before FWDC began metal wastage evaluations. The specimens were then inspected visually, analyzed dimensionally, and examined metallographically. 5 refs., 75 figs., 14 tabs.

  3. Method of removing sulfur emissions from a fluidized-bed combustion process

    DOE Patents [OSTI]

    Vogel, Gerhard John; Jonke, Albert A.; Snyder, Robert B.

    1978-01-01

    Alkali metal or alkaline earth metal oxides are impregnated within refractory support material such as alumina and introduced into a fluidized-bed process for the combustion of coal. Sulfur dioxide produced during combustion reacts with the metal oxide to form metal sulfates within the porous support material. The support material is removed from the process and the metal sulfate regenerated to metal oxide by chemical reduction. Suitable pore sizes are originally developed within the support material by heat-treating to accommodate both the sulfation and regeneration while still maintaining good particle strength.

  4. Tube bank metal wastage in the Grimethorpe PFBC. [Pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1984-02-01

    The 2 m x 2 m PFBC facility at Grimethorpe, England is designed to explore the pressurized fluidized-bed combustion of coal over a wide range of conditions. A significant degree of metal wastage was observed on the fireside surfaces of the tube bank which occurred during 468 coal-burning hours of hot shakedown and hot commissioning testing. This paper described the operating conditions during testing, the erosion of the metal surfaces, and the repair and modifications undertaken. 1 reference, 4 figures, 2 tables.

  5. A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace

    SciTech Connect (OSTI)

    Murray, J.P.

    1989-01-01

    A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

  6. Tube bank wastage in the Grimethorpe pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Not Available

    1987-04-01

    The coal-fired pressurized fluidized bed combustion (PFBC) at Grimethorpe, England, was run for over 3600 hours of combustion testing under the joint sponsorship of the governments of the Federal Republic of Germany, the United Kingdom, and the US. Early in the course of these tests, significant metal wastage was experienced, especially on the inbed heat transfer tubes. This paper describes the modifications to design and new alloys which were tested in the PFBC. Operating conditions for three tube banks are given. A new tube bank, D, has been designed which incorporates a variety of alloy types, a number of tubes designed to operate at higher temperatures than those typical of the rest of the tube bank, and some tubes fitted with fins. The datum fluidizing velocity has been reduced to 0.8 m/sec. The effects of these variables: metal surface temperature, alloy chromium content, fin or stud arrangements, and fluidizing velocity, will be investigated in a continuing program funded by British Coal and the Central Electricity Generating Board of the UK, with some participation from the US Department of Energy and the Electric Power Research Institute. 3 references, 5 figures, 1 table.

  7. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUID BED BOILERS (Phase II--Evaluation of the Oxyfuel CFB Concept)

    SciTech Connect (OSTI)

    John L. Marion; Nsakala ya Nsakala

    2003-11-09

    The overall project goal is to determine if carbon dioxide can be captured and sequestered at a cost of about $10/ton of carbon avoided, using a newly constructed Circulating Fluidized Bed combustor while burning coal with a mixture of oxygen and recycled flue gas, instead of air. This project is structured in two Phases. Phase I was performed between September 28, 2001 and May 15, 2002. Results from Phase I were documented in a Topical Report issued on May 15, 2003 (Nsakala, et al., 2003), with the recommendation to evaluate, during Phase II, the Oxyfuel-fired CFB concept. DOE NETL accepted this recommendation, and, hence approved the project continuation into Phase II. Phase 2. The second phase of the project--which includes pilot-scale tests of an oxygen-fired circulating fluidized bed test facility with performance and economic analyses--is currently underway at ALSTOM's Power Plant Laboratories, located in Windsor, CT (US). The objective of the pilot-scale testing is to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in oxygen/carbon dioxide mixtures. Results will be used in the design of oxygen-fired CFB boilers--both retrofit and new Greenfield--as well as to provide a generic performance database for other researchers. At the conclusion of Phase 2, revised costs and performance will be estimated for both retrofit and new Greenfield design concepts with CO2 capture, purification, compression, and liquefaction.

  8. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Zhongxian Cheng; Yan Cao; John Smith

    2006-09-30

    This report is to present the progress made on the project entitled ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2006 through September 30, 2006. The following activities have been completed: the steel floor grating around the riser in all levels and the three-phase power supply for CFBC System was installed. Erection of downcomers, loop seals, ash bunker, thermal expansion joints, fuel and bed material bunkers with load cells, rotary air-lock valves and fuel flow monitors is underway. Pilot-scale slipstream tests conducted with bromine compound addition were performed for two typical types of coal. The purposes of the tests were to study the effect of bromine addition on mercury oxidization. From the test results, it was observed that there was a strong oxidization effect for Powder River Basin (PRB) coal. The proposed work for next quarter and project schedule are also described.

  9. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  10. Predictive models of circulating fluidized bed combustors. 12th technical progress report

    SciTech Connect (OSTI)

    Gidaspow, D.

    1992-07-01

    Steady flows influenced by walls cannot be described by inviscid models. Flows in circulating fluidized beds have significant wall effects. Particles in the form of clusters or layers can be seen to run down the walls. Hence modeling of circulating fluidized beds (CFB) without a viscosity is not possible. However, in interpreting Equations (8-1) and (8-2) it must be kept in mind that CFB or most other two phase flows are never in a true steady state. Then the viscosity in Equations (8-1) and (8-2) may not be the true fluid viscosity to be discussed next, but an Eddy type viscosity caused by two phase flow oscillations usually referred to as turbulence. In view of the transient nature of two-phase flow, the drag and the boundary layer thickness may not be proportional to the square root of the intrinsic viscosity but depend upon it to a much smaller extent. As another example, liquid-solid flow and settling of colloidal particles in a lamella electrosettler the settling process is only moderately affected by viscosity. Inviscid flow with settling is a good first approximation to this electric field driven process. The physical meaning of the particulate phase viscosity is described in detail in the chapter on kinetic theory. Here the conventional derivation resented in single phase fluid mechanics is generalized to multiphase flow.

  11. Comminution phenomena during the fluidized bed combustion of a commercial refuse-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A.; Chirone, R.; D`Anna, G.

    1995-12-31

    A commercial densified refuse-derived fuel (RDF), obtained as pellets from municipal solid wastes, was burned in two laboratory scale bubbling fluidized bed combustors, having an internal diameter of 41 mm. The apparatus were both batchwise operated at 850 C by injecting batches of RDF particles into a bed of silica sand (300--400 {micro}m as size range) fluidized at a superficial gas velocity of 0.8 m/s. RDF particles with equivalent mean diameter ranging from 4 to 9 mm were used. Different experimental procedures were set up to separately investigate comminution phenomena of fuel particles. Results were compared with those obtained burning a South African bituminous coal. Results pointed out that RDF particles undergo a strong primary fragmentation phenomenon, with a probability of particle breakage equal to 1 for fuel particles larger than 6 mm. Attrition and char fragmentation phenomena are particularly relevant under both inert and oxidizing conditions, generating a large amount of unburned fines which may affect overall combustion efficiency.

  12. ESTABLISHMENT OF AN ENVIRONMENTAL CONTROL TECHNOLOGY LABORATORY WITH A CIRCULATING FLUIDIZED-BED COMBUSTION SYSTEM

    SciTech Connect (OSTI)

    Wei-Ping Pan, Kunlei Liu; John T. Riley

    2004-07-30

    This report presents the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the quarter April 1--June 30, 2004. The following tasks have been completed. First, the final specifications for the renovation of the new Combustion Laboratory and the construction of the CFB Combustor Building have been delivered to the architect, and invitations for construction bids for the two tasks have been released. Second, the component parts of the CFBC system have been designed after the design work for assembly parts of the CFBC system was completed. Third, the literature pertaining to Polychlorinated Dibenzo-p-Dioxins (PCDD) and Polychlorinated Dibenzofurans (PCDF) released during the incineration of solid waste, including municipal solid waste (MSW) and refuse-derived fuel (RDF) have been reviewed, and an experimental plan for fundamental research of MSW incineration on a simulated fluidized-bed combustion (FBC) facility has been prepared. Finally, the proposed work for the next quarter has been outlined in this report.

  13. Solids circulation around a jet in a fluidized bed gasifier. Final technical report, September 1, 1978-September 30, 1980

    SciTech Connect (OSTI)

    Gidaspow, D.; Ettehadieh, B.; Lin, C.; Goyal, A.; Lyczkowski, R.W.

    1980-01-01

    The object of this investigation was to develop an experimentally verified hydrodynamic model to predict solids circulation around a jet in a fluidized bed gasifier. Hydrodynamic models of fluidization use the principles of conservation of mass, momentum and energy. To account for unequal velocities of solid and fluid phases, separate phase momentum balances are developed. Other fluid bed models used in the scale-up of gasifiers do not employ the principles of conservation of momentum. Therefore, these models cannot predict fluid and particle motion. In such models solids mixing is described by means of empirical transfer coefficients. A two dimensional unsteady state computer code was developed to give gas and solid velocities, void fractions and pressure in a fluid bed with a jet. The growth, propagation and collapse of bubbles was calculated. Time-averaged void fractions were calculated that showed an agreement with void fractions measured with a gamma ray densitometer. Calculated gas and solid velocities in the jet appeared to be reasonable. Pressure and void oscillations also appear to be reasonable. A simple analytical formula for the rate of solids circulation was developed from the equations of change. It agrees with Westinghouse fluidization data in a bed with a draft tube. One dimensional hydrodynamic models were applied to modeling of entrained-flow coal gasification reactors and compared with data. Further development of the hydrodynamic models should make the scale-up and simulation of fluidized bed reactors a reality.

  14. Temperature dependence of steel wastage in a bubbling fluidized bed simulator

    SciTech Connect (OSTI)

    MacAdam, S.S. ); Stringer, J. )

    1993-02-01

    Tubes within bubbling fluidized bed combustors have in many instances suffered wastage. The wastage can be quite high at temperatures near 300 C, but it typically shows an abrupt decrease at approximately 400 C. Superheater tubes that operate at higher temperatures generally do not experience wastage. It is widely believed that this decrease in wastage with temperature is due to the development of a continuous oxide layer that protects the metal substrate by virtue of its hardness and resistance to spalling. In this study, the temperature effect is examined using a wear rig specially designed to simulate the impact conditions relevant to in-bed tubes. It was discovered that wastage for mild steel can decrease from a relatively high value to essential zero within the temperature range of 400 to 430 C. This decrease was attributable not to the presence of an oxide scale but to the development of a protective deposit layer. The deposit consisted of an agglomeration of submicron bed material particles. The submicron dust is created through the normal attrition process and it tends to form an adherent coating on the bulk bed particles. Deposition on the specimen occurs by transfer of agglomerated material from bulk particles during impact. Subsequent impacts compact the deposit into a continuous protective layer.

  15. Characterization and analysis of metal wastage in coal-fired fluidized-bed combustors

    SciTech Connect (OSTI)

    Nazemi, A.H.; Madsen, M.M.; Malone, G.A.

    1985-08-01

    As an integral part of its program in fluidized-bed combustion technology development, the US Department of Energy/Morgantown Energy Technology Center (DOE/METC) supports a number of projects directed toward providing both theoretical and experimental results which will guide solutions to the metal loss problem. As a part of this effort, METC and the MITRE Corporation have undertaken a project to compile and analyze metal loss data obtained from a variety of FBC systems ranging from small-scale experimental units to industrial-size facilities and to establish a functional relationship between metal loss for several alloy types and various FBC design and operating parameters. To date, metal loss and operating information have been categorized for forty-four alloys in twenty separate FBC systems worldwide. Review of the tabulated data indicate the following trends: metal temperatures above 1200/sup 0/F significantly increase rates of metal loss; system operation with high excess air reduces metal loss, but does not eliminate it; use of coals with high ash sintering temperatures does not significantly reduce metal loss; degree of metal loss is much lower for surfaces exposed in the freeboard than for in-bed surfaces; the rate of metal loss decreases with time of exposure; iron-based stainless steels are relatively resistant to conditions which cause metal loss; cobalt-based alloys and high-chromium steels show significant resistance to metal loss; nickel-based alloys are most susceptible to metal loss; sulfidation/oxidation attack on metals within fluidized beds are more likely to occur if sorbent is present; and metal attack will occur irrespective of coal and sorbent type. 25 refs., 14 figs., 12 tabs.

  16. Fluidized bed steam reformed mineral waste form performance testing to support Hanford Supplemental Low Activity Waste Immobilization Technology Selection

    SciTech Connect (OSTI)

    Jantzen, C. M.; Pierce, E. M.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Crawford, C. L.; Daniel, W. E.; Fox, K. M.; Herman, C. C.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.; Brown, C. F.; Qafoku, N. P.; Neeway, J. J.; Valenta, M. M.; Gill, G. A.; Swanberg, D. J.; Robbins, R. A.; Thompson, L. E.

    2015-10-01

    This report describes the benchscale testing with simulant and radioactive Hanford Tank Blends, mineral product characterization and testing, and monolith testing and characterization. These projects were funded by DOE EM-31 Technology Development & Deployment (TDD) Program Technical Task Plan WP-5.2.1-2010-001 and are entitled “Fluidized Bed Steam Reformer Low-Level Waste Form Qualification”, Inter-Entity Work Order (IEWO) M0SRV00054 with Washington River Protection Solutions (WRPS) entitled “Fluidized Bed Steam Reforming Treatability Studies Using Savannah River Site (SRS) Low Activity Waste and Hanford Low Activity Waste Tank Samples”, and IEWO M0SRV00080, “Fluidized Bed Steam Reforming Waste Form Qualification Testing Using SRS Low Activity Waste and Hanford Low Activity Waste Tank Samples”. This was a multi-organizational program that included Savannah River National Laboratory (SRNL), THOR® Treatment Technologies (TTT), Pacific Northwest National Laboratory (PNNL), Oak Ridge National Laboratory (ORNL), Office of River Protection (ORP), and Washington River Protection Solutions (WRPS). The SRNL testing of the non-radioactive pilot-scale Fluidized Bed Steam Reformer (FBSR) products made by TTT, subsequent SRNL monolith formulation and testing and studies of these products, and SRNL Waste Treatment Plant Secondary Waste (WTP-SW) radioactive campaign were funded by DOE Advanced Remediation Technologies (ART) Phase 2 Project in connection with a Work-For-Others (WFO) between SRNL and TTT.

  17. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles.more » It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.« less

  18. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  19. Development of a trial burn plan for a mixed waste fluidized bed incinerator

    SciTech Connect (OSTI)

    Kabot, F.J.; Ziegler, D.L.

    1988-01-01

    One of the more important elements of the incinerator permitting process under RCRA is the development of the Trial Burn Plan. This document describes the incinerator and defines the incinerator's process envelope within which the trial burns will be conducted. The data obtained during the trial burns will be the basis for the incinerator's operating permit. This paper describes the development of the Trial Burn Plan for a unique fluidized bed incinerator to be used for the incineration of hazardous and mixed wastes at the Department of Energy's Rocky Flats Plant. It describes a review process of the Trial Burn Plan involving a public comment period that actually preceded the trial burns. 2 refs., 1 fig.

  20. Rocky Flats Plant fluidized-bed incinerator. Engineering design and reference manual

    SciTech Connect (OSTI)

    Meile, L.J.

    1982-11-05

    The information in this manual is being presented to complete the documentation of the fluidized-bed incineration (FBI) process development at the Rocky Flats Plant. The information pertains to the 82-kg/hour demonstration unit at the Rocky Flats Plant. This document continues the presentation of design reference material in the aeas of equipment drawings, space requirements, and unit costs. In addition, appendices contain an operating procedure and an operational safety analysis of the process. The cost figures presented are based on 1978 dollars and have not been converted to a current dollar value. Also, the cost of modifications are not included, since they would be insignificant if they were incorporated into a new installation.

  1. Apparatus, components and operating methods for circulating fluidized bed transport gasifiers and reactors

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2015-02-24

    The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed "transport gasifier." The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

  2. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  3. Circulating fluidized bed hydrodynamics experiments for the multiphase fluid dynamics research consortium (MFDRC).

    SciTech Connect (OSTI)

    Oelfke, John Barry; Torczynski, John Robert; O'Hern, Timothy John; Tortora, Paul Richard; Bhusarapu, Satish; Trujillo, Steven Mathew

    2006-08-01

    An experimental program was conducted to study the multiphase gas-solid flow in a pilot-scale circulating fluidized bed (CFB). This report describes the CFB experimental facility assembled for this program, the diagnostics developed and/or applied to make measurements in the riser section of the CFB, and the data acquired for several different flow conditions. Primary data acquired included pressures around the flow loop and solids loadings at selected locations in the riser. Tomographic techniques using gamma radiation and electrical capacitance were used to determine radial profiles of solids volume fraction in the riser, and axial profiles of the integrated solids volume fraction were produced. Computer Aided Radioactive Particle Tracking was used to measure solids velocities, fluxes, and residence time distributions. In addition, a series of computational fluid dynamics simulations was performed using the commercial code Arenaflow{trademark}.

  4. Continuous Ethanol Production Using Immobilized-Cell/Enzyme Biocatalysts in Fluidized-Bed Bioreactor (FBR)

    SciTech Connect (OSTI)

    Nghiem, NP

    2003-11-16

    The immobilized-cell fluidized-bed bioreactor (FBR) was developed at Oak Ridge National Laboratory (ORNL). Previous studies at ORNL using immobilized Zymomonas mobilis in FBR at both laboratory and demonstration scale (4-in-ID by 20-ft-tall) have shown that the system was more than 50 times as productive as industrial benchmarks (batch and fed-batch free cell fermentations for ethanol production from glucose). Economic analysis showed that a continuous process employing the FBR technology to produce ethanol from corn-derived glucose would offer savings of three to six cents per gallon of ethanol compared to a typical batch process. The application of the FBR technology for ethanol production was extended to investigate more complex feedstocks, which included starch and lignocellulosic-derived mixed sugars. Economic analysis and mathematical modeling of the reactor were included in the investigation. This report summarizes the results of these extensive studies.

  5. Process for generating electricity in a pressurized fluidized-bed combustor system

    DOE Patents [OSTI]

    Kasper, Stanley

    1991-01-01

    A process and apparatus for generating electricity using a gas turbine as part of a pressurized fluidized-bed combustor system wherein coal is fed as a fuel in a slurry in which other constituents, including a sulfur sorbent such as limestone, are added. The coal is combusted with air in a pressurized combustion chamber wherein most of the residual sulfur in the coal is captured by the sulfur sorbent. After particulates are removed from the flue gas, the gas expands in a turbine, thereby generating electric power. The spent flue gas is cooled by heat exchange with system combustion air and/or system liquid streams, and the condensate is returned to the feed slurry.

  6. Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor

    SciTech Connect (OSTI)

    Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W.

    2007-06-15

    The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

  7. Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant

    DOE Patents [OSTI]

    Cole, Rossa W.; Zoll, August H.

    1982-01-01

    In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

  8. Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-11-01

    The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 25, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

  9. Data summary of municipal solid waste management alternatives. Volume 5, Appendix C, Fluidized-bed combustion

    SciTech Connect (OSTI)

    1992-10-01

    This appendix provides information on fluidized-bed combustion (FBC) technology as it has been applied to municipal waste combustion (MWC). A review of the literature was conducted to determine: (1) to what extent FBC technology has been applied to MWC, in terms of number and size of units was well as technology configuration; (2) the operating history of facilities employing FBC technology; and (3) the cost of these facilities as compared to conventional MSW installations. Where available in the literature, data on operating and performance characteristics are presented. Tabular comparisons of facility operating/cost data and emissions data have been complied and are presented. The literature review shows that FBC technology shows considerable promise in terms of providing improvements over conventional technology in areas such as NOx and acid gas control, and ash leachability. In addition, the most likely configuration to be applied to the first large scale FBC dedicated to municipal solid waste (MSW) will employ circulating bed (CFB) technology. Projected capital costs for the Robbins, Illinois 1600 ton per day CFB-based waste-to-energy facility are competitive with conventional systems, in the range of $125,000 per ton per day of MSW receiving capacity.

  10. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, J.

    1996-02-20

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  11. Pressurized fluidized bed reactor and a method of operating the same

    DOE Patents [OSTI]

    Isaksson, Juhani

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  12. A study of parameters influencing metal wastage in fluidized bed combustors

    SciTech Connect (OSTI)

    Podolski, W.F.; Lyczkowski, R. ); Montrone, E. ); Drennen, J. ); Ai, Y.H.; Chao, B.T. )

    1991-01-01

    Fluidized bed combustion (FBC) technology is a means of burning high-sulfur coal and various other feedstocks in an efficient, cost-effective, and environmentally acceptable manner. Unfortunately, the wearing or wastage of metal heat exchanger tubes in bubbling FBCs has been reported in a large number of units in commercial service. Presently, it is not possible to explain why some FBC units, or regions of a specific bed, undergo rapid metal loss and others do not. An eight-member cooperative R D venture was formed in 1985 to investigate metal wastage in FBCs. The objectives of the R D effort are to hydrodynamics and erosion in FBCs, (2) develop guidelines for the design and operation of FBC units with minimum metal wastage rates, and (3) demonstrate the feasibility of a continuous erosion monitor for use in pilot plant and full-scale FBC units. Computational models are being refined and used to predict the rates of metal wastage for specific FBC designs and operating conditions. The design guidelines will emerge from the understanding gained from experimental studies and analytical modeling activities. This paper updates the status of ongoing experimental studies. 8 refs., 10 figs., 3 tabs.

  13. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Quarterly report

    SciTech Connect (OSTI)

    Lee, Seong W.

    1996-01-01

    This technical report summarizes the research work performed and progress achieved during the period of October 1, 1995 to December 31, 1995. A series of material wastage tests was carried out on cooled AISI 1018 steel and three thermal-sprayed coating specimens at an elevated environmental temperature (3000{degrees}C) using a nozzle type erosion tester. Test conditions simulated the erosion conditions at the in-bed tubes of fluidized combustors (FBCs). Angular silica quartz particles of average size 742 {micro}m were used for erodent particles for tests at an impact angle of 30{degrees}, at a particle velocity of 2.5 m/s for exposure periods up to 96 hours. The specimens were water-cooled on backside. Material wastage rates were determined from thickness loss measurements of specimens. Test results were compared with material wastage test results from testing isothermal specimens. The morphology of specimens was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). It was found that the cooled specimens had greater material wastage than that of the isothermal specimens. The material wastage rate of cooling specimen for AISI 1018 was greater than that for thermal- sprayed coatings. The success in reduction of erosion wastage by cooled-coating specimens was related to the coatings, composition and morphology.

  14. Development of a high-temperature erosion monitor for FBC (fluidized bed combustion) heat exchanger tubes

    SciTech Connect (OSTI)

    Reimann, K.J.

    1990-05-01

    Metal wastage in tubing of heat exchangers used in fluidized bed combustion (FBC) could affect plant operation and threaten the successful development of FBC technology. Monitoring of such wastage during operation would be very beneficial. The development of a high-temperature erosion monitor was undertaken as part of a larger program to understand and ameliorate wastage processes. Two sensor principles, i.e., electromagnetic acoustic and piezoelectric transducers based on time-of-flight measurements, were evaluated. Spatial restrictions and high-energy requirements of electromagnetic acoustic transducers favored piezoelectric transducers as a prototype. Requirements for good coupling between sensor and tubing led to the exploration of two methods for accomplishing this task: pressure coupling and brazing. Initial disappointments with brazing led to the construction of a pressure-coupled transducer that was tested successfully to temperatures of up to 500{degree}C. A brazing method to bond the lithium niobate crystal to stainless steel was finally perfected, but will require additional work for brazing to ferritic steel. The prototype pressure-coupled transducer also needs more development to compensate for the expansion of components and oxidation of coupling surfaces. 3 refs., 15 figs., 1 tab.

  15. Engineering systems analysis of pressurized fluidized-bed-combustion power systems

    SciTech Connect (OSTI)

    Graves, R.L.; Griffin, F.P.; Lackey, M.E.

    1982-04-01

    This effort was conducted to provde supporting data for the research and development program on pressurized fluidized bed combustor (PFBC) systems being continued under the auspices of the Office of Coal Utilization of DOE. This report deals with the first phase of the effort, designated Task 1, which was scoped to be a somewhat broad review of PFBC technology and an analysis to determine its potential and sensitivity to key development needs. Background information pertaining to the application of PFBC to the market for coal-fired technology is included. The status of development is reviewed and the deficiencies in data are identified. Responses to a survey of PFBC developers are reviewed with emphasis on the high risk areas of the PFBC concept. Some of these problems are: uncertainty of life of gas turbine components; lack of demonstration of load following; and hot solids handling. Some high risk areas, such as the gas cleanup or gas turbine systems, can be relieved by reducing the severity of design conditions such as the turbine inlet temperature. Alternate turbine designs or plant configurations are also possible solutions. Analyses were performed to determine whether the advantages held by PFBC systems in cost, efficiency, and emissions would be nullified by measures taken to reduce risk. In general, the results showed that the attractive features of the PFBC could be preserved.

  16. Indirectly heated fluidized bed biomass gasification using a latent heat ballast

    SciTech Connect (OSTI)

    Pletka, R.; Brown, R.; Smeenk, J.

    1998-12-31

    The objective of this study is to improve the heating value of gas produced during gasification of biomass fuels using an indirectly heated gasifier based on latent heat ballasting. The latent heat ballast consists of lithium fluoride salt encased in tubes suspended in the reactor. The lithium fluoride has a melting point that is near the desired gasification temperature. With the ballast a single reactor operating in a cyclic mode stores energy during a combustion phase and releases it during a pyrolysis phase. Tests were carried out in a fluidized bed reactor to evaluate the concept. The time to cool the reactor during the pyrolysis phase from 1,172 K (1,650 F) to 922 K (1,200 F) increased 102% by use of the ballast system. This extended pyrolysis time allowed 33% more biomass to be gasified during a cycle. Additionally, the total fuel fraction pyrolyzed to produce useful gas increased from 74--80%. Higher heating values of 14.2 to 16.6 MJ/Nm{sup 3} (382--445 Btu/scf) on a dry basis were obtained from the ballasted gasifier.

  17. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  18. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  19. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  20. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  1. Experimental and theoretical investigation on the mechanism of transient bubble images in fluidized-bed combustors: Systematic interpretation and analysis. Final report, July 1992--July 1995

    SciTech Connect (OSTI)

    Hisashi O. Kono

    1995-08-01

    For the improvement of the design and operation of the FBC systems, the insight into the intrinsic transient bubbling phenomena in freely bubbling fluidized beds is of vital importance. The authors have found several basic new bubbling mechanisms in this work experimentally, and some of them have not been published in past literature. Using the two dimensional fluidized bed, the images of transient bubbling behavior were recorded by videos, and processed and analyzed by computers. As the results of experiments, the following new experimental facts were found: (1) transient bubbles change and fluctuate their size and shape over very short time intervals (on the order of 30 milliseconds); (2) bubble disappearance and reappearance occurred in the emulsion phase in addition to the known phenomena of coalescence and splitting. The bubble interaction occurred between the bubbles and adjacent emulsion phase and also among the transient bubbles; (3) bubble`s velocity fluctuated significantly, e.g., 0.6 to 3.0 m/s; (4) under one single specific fluidization condition, two different fluidization patterns appeared to occur randomly shifting from one pattern to the other or vice versa; (5) the erosion rates of in-bed tubes at ambient and elevated temperature could be predicted using material property data and transient behavior of bubbles. By introducing a new quantitative criterion which the authors call a gas stress index in the emulsion phase, the comparison of the fluidization quality between two and three dimensional fluidized beds was accomplished. They found reasonable correspondence between the two beds, and concluded that the new findings of transient bubble behavior should hold true for both types of fluidized beds. 32 refs., 85 figs., 13 tabs.

  2. Establishment of an Environmental Control Technology Laboratory with a Circulating Fluidized-Bed Combustion System

    SciTech Connect (OSTI)

    Wei-Ping Pan; Yan Cao; John Smith

    2008-05-31

    On February 14, 2002, President Bush announced the Clear Skies Initiative, a legislative proposal to control the emissions of nitrogen oxides (NO{sub x}), sulfur dioxide (SO{sub 2}), and mercury from power plants. In response to this initiative, the National Energy Technology Laboratory organized a Combustion Technology University Alliance and hosted a Solid Fuel Combustion Technology Alliance Workshop. The workshop identified multi-pollutant control; improved sorbents and catalysts; mercury monitoring and capture; and improved understanding of the underlying reaction chemistry occurring during combustion as the most pressing research needs related to controlling environmental emissions from fossil-fueled power plants. The Environmental Control Technology Laboratory will help meet these challenges and offer solutions for problems associated with emissions from fossil-fueled power plants. The goal of this project was to develop the capability and technology database needed to support municipal, regional, and national electric power generating facilities to improve the efficiency of operation and solve operational and environmental problems. In order to effectively provide the scientific data and the methodologies required to address these issues, the project included the following aspects: (1) Establishing an Environmental Control Technology Laboratory using a laboratory-scale, simulated fluidized-bed combustion (FBC) system; (2) Designing, constructing, and operating a bench-scale (0.6 MW{sub th}), circulating fluidized-bed combustion (CFBC) system as the main component of the Environmental Control Technology Laboratory; (3) Developing a combustion technology for co-firing municipal solid waste (MSW), agricultural waste, and refuse-derived fuel (RDF) with high sulfur coals; (4) Developing a control strategy for gaseous emissions, including NO{sub x}, SO{sub 2}, organic compounds, and heavy metals; and (5) Developing new mercury capturing sorbents and new particulate filtration technologies. Major tasks during this period of the funded project's timeframe included: (1) Conducting pretests on a laboratory-scale simulated FBC system; (2) Completing detailed design of the bench-scale CFBC system; (3) Contracting potential bidders to fabricate of the component parts of CFBC system; (4) Assembling CFBC parts and integrating system; (5) Resolving problems identified during pretests; (6) Testing with available Powder River Basin (PRB) coal and co-firing of PRB coal with first wood pallet and then chicken wastes; and (7) Tuning of CFBC load. Following construction system and start-up of this 0.6 MW CFBC system, a variety of combustion tests using a wide range of fuels (high-sulfur coals, low-rank coals, MSW, agricultural waste, and RDF) under varying conditions were performed to analyze and monitor air pollutant emissions. Data for atmospheric pollutants and the methodologies required to reduce pollutant emissions were provided. Integration with a selective catalytic reduction (SCR) slipstream unit did mimic the effect of flue gas composition, including trace metals, on the performance of the SCR catalyst to be investigated. In addition, the following activities were also conducted: (1) Developed advanced mercury oxidant and adsorption additives; (2) Performed laboratory-scale tests on oxygen-fuel combustion and chemical looping combustion; and (3) Conducted statistical analysis of mercury emissions in a full-scale CFBC system.

  3. Pressurized fluidized-bed hydroretorting of Eastern oil shales. Annual report, June 1991--May 1992

    SciTech Connect (OSTI)

    Roberts, M.J.; Mensinger, M.C.; Rue, D.M.; Lau, F.S.; Schultz, C.W.; Parekh, B.K.; Misra, M.; Bonner, W.P.

    1992-11-01

    The Devonian oil shales of the Eastern United States are a significant domestic energy resource. The overall objective of the multi-year program, initiated in October 1987 by the US Department of Energy is to perform the research necessary to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) process for producing oil from Eastern oil shales. The program also incorporates research on technologies in areas such as raw shale preparation, beneficiation, product separation, and waste disposal that have the potential of improving the economics and/or environmental acceptability of recovering oil from oil shales using the PFH process. The results of the original 3-year program, which was concluded in May 1991, have been summarized in a four-volume final report published by IGT. DOE subsequently approved a 1-year extension to the program to further develop the PFH process specifically for application to beneficiated shale as feedstock. Studies have shown that beneficiated shale is the preferred feedstock for pressurized hydroretorting. The program extension is divided into the following active tasks. Task 3. testing of process improvement concepts; Task 4. beneficiation research; Task 5. operation of PFH on beneficiated shale; Task 6. environmental data and mitigation analyses; Task 7. sample procurement, preparation, and characterization; and Task 8. project management and reporting. In order to accomplish all the program objectives, the Institute of Gas Technology (IGT), the prime contractor, worked with four other institutions: the University of Alabama/Mineral Resources Institute (MRI), the University of Kentucky Center for Applied Energy Research (UK-CAER), the University of Nevada (UN) at Reno, and Tennessee Technological University (TTU). This report presents the work performed during the program extension from June 1, 1991 through May 31, 1992.

  4. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    SciTech Connect (OSTI)

    Zhen Fan

    2006-05-30

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  5. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  6. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  7. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  8. Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-12-01

    Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Offices (NE-ID) and State of Idahos top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

  9. Coal pyrolysis by hot solids from a fluidized-bed combustor. Final technical report, June 1977-June 1982

    SciTech Connect (OSTI)

    Longwell, J.P.; Evans, L.B.; Howard, J.B.; Peters, W.A.; Floess, J.K.; Fong, L.; Chen, C.; Yeboah, J.

    1982-06-01

    The effect of adding calcined dolomite stone to the fluidized-bed pyrolysis of coal and oil shale on product quality and product distribution has been studied. This work has provided information relevant to systems where heat is generated by fluidized-bed combustion in the presence of a sulfur acceptor (dolomite) and where the hot stone from the combustor is used in a second reactor to provide heat for pyrolysis. A scoping economic analysis indicated that, for coal, the pyrolysis gas and liquids produced are lower cost than gas and liquids produced by single-product gasification and liquefaction processes. The presence of calcium oxide during pyrolysis was found to improve gas heating value by CO/sub 2/ removal and to essentially eliminate H/sub 2/S. Gas yield was increased at the expense of liquid yield (20 to 30% reduction). Tar properties were improved by reduction of oxygen content, however, little sulfur or nitrogen removal was observed. Used stone from a fluidized-bed combustor gave results comparable to fresh stone with little reduction of the calcium sulfate present in the used stone. Since Colorado oil shale contains dolomite and calcite, stones from spent-shale combustion might be expected to have similar effects on product yields. CO/sub 2/ and H/sub 2/S removal from the gas were observed. Fortunately, liquid yields were not reduced within the 5% experimental error of this work. It is indicated that CaO tends to remove phenols and polycyclic aromatics which are present in much lower concentration in shale oil than in coal tar.

  10. Functionalization of polymers using an atmospheric plasma jet in a fluidized bed reactor and the impact on SLM-processes

    SciTech Connect (OSTI)

    Sachs, M. Schmitt, A. Schmidt, J. Peukert, W. Wirth, K-E

    2014-05-15

    In order to improve thermoplastics (e.g. Polyamide, Polypropylene and Polyethylene) for Selective Laser Beam Melting (SLM) processes a new approach to functionalize temperature sensitive polymer powders in a large scale is investigated. This is achieved by combining an atmospheric pressure plasma jet and a fluidized bed reactor. Using pressurized air as the plasma gas, radicals like OH* are created. The functionalization leads to an increase of the hydrophilicity of the treated polymer powder without changing the bulk properties. Using the polymers in a SLM process to build single layers of melted material leads to an improvement of the melted layers.

  11. Effect of operating and design parameters on fluidized bed combustor in-bed tube metal wastage: Experimentation test plan: Quarterly report

    SciTech Connect (OSTI)

    Blaylock, N.W.; Deffenbaugh, D.M.

    1986-06-13

    The objective of this quarterly report is to summarize the work activities for the period from February 1, 1986 to April 30, 1986 for DOE Project No. DE-AC21-85MC22077 (SwRI Project 06-8863). The major effort during this period has been the development of an experimental test plan. The overall objective of this project is to study the phenomenon of in-bed tube metal wastage in a fluidized-bed coal combustor. This work includes a literature review, test plan development, design and fabrication of a test rig, and experimental program and data analysis. The literature review has been completed and reported on in last quarter's progress report. The experimental test plan is completed and documented in this report. The rig design will be initiated next quarter. 2 figs., 8 tabs.

  12. Preparation and initial characterization of fluidized bed steam reforming pure-phase standards

    SciTech Connect (OSTI)

    Missimer, D. M.; Rutherford, R. L.

    2013-03-21

    Hanford is investigating the Fluidized Bed Steam Reforming (FBSR) process for their Low Activity Waste. The FBSR process offers a low-temperature continuous method by which liquid waste can be processed with the addition of clay into a sodium aluminosilicate (NAS) waste form. The NAS waste form is mainly comprised of nepheline (NaAlSiO{sub 4}), sodalite (Na{sub 8}[AlSiO{sub 4}]{sub 6}Cl{sub 2}), and nosean (Na{sub 8}[AlSiO{sub 4}]{sub 6}SO{sub 4}). Anions such as perrhenate (ReO{sub 4}{sup -}), pertechnetate (TcO{sub 4}{sup -}), and iodine (I{sup -}) are expected to replace sulfate in the nosean structure and/or chloride in the sodalite mineral structure (atomically bonded inside the aluminosilicate cages that these mineral structures possess). In the FBSR waste form, each of these phases can exist in a variety of solid solutions that differ from the idealized forms observed in single crystals in nature. The lack of understanding of the durability of these stoichiometric or idealized mineral phases complicates the ability to deconvolute the durability of the mixed phase FBSR product since it is a combination of different NAS phases. To better understand the behavior, fabrication and testing of the individual phases of the FBSR product is required. Analytical Development (AD) of the Science and Technology directorate of the Savannah River National Laboratory (SRNL) was requested to prepare the series of phase-pure standards, consisting of nepheline, nosean, and Cl, Re, and I sodalite. Once prepared, X-ray Diffraction (XRD) analyses were used to confirm the products were phase pure. These standards are being used for subsequent characterization studies consisting of the following: single-pass flow-through (SPFT) testing, development of thermodynamic data, and x-ray diffraction (XRD) calibration curves. In addition to the above mentioned phase-pure standards, AD was tasked with fabricating a mixed Tc-Re sodalite.

  13. Distribution of polycyclic aromatic hydrocarbons in fly ash during coal and residual char combustion in a pressurized fluidized bed

    SciTech Connect (OSTI)

    Hongcang Zhou; Baosheng Jin; Rui Xiao; Zhaoping Zhong; Yaji Huang

    2009-04-15

    To investigate the distribution of polycyclic aromatic hydrocarbons (PAHs) in fly ash, the combustion of coal and residual char was performed in a pressurized spouted fluidized bed. After Soxhlet extraction and Kuderna-Danish (K-D) concentration, the contents of 16 PAHs recommended by the United States Environmental Protection Agency (U.S. EPA) in coal, residual char, and fly ash were analyzed by a high-performance liquid chromatography (HPLC) coupled with fluorescence and diode array detection. The experimental results show that the combustion efficiency is lower and the carbon content in fly ash is higher during coal pressurized combustion, compared to the residual char pressurized combustion at the pressure of 0.3 MPa. Under the same pressure, the PAH amounts in fly ash produced from residual char combustion are lower than that in fly ash produced from coal combustion. The total PAHs in fly ash produced from coal and residual char combustion are dominated by three- and four-ring PAHs. The amounts of PAHs in fly ash produced from residual char combustion increase and then decrease with the increase of pressure in a fluidized bed. 21 refs., 1 fig., 4 tabs.

  14. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R.; Reuther, R.B.; Bonk, D.L.

    1996-09-01

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  15. Analysis/control of in-bed tube erosion phenomena in the Fluidized Bed Combustion (FBC) system. Technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect (OSTI)

    Lee, S.W.

    1994-04-01

    This technical report summarizes the research work performed and progress achieved during the period of January 1, 1994 to March 31, 1994. The metal wastage mechanisms and rate that occur in 1018 carbon steel used in in-bed tube of the bubbling fluidized bed combustor (BFBC) are discussed with particle-surface collision frequency around tube. The distribution of particle-surface collision frequency around tube was affected by the location of tube and bed height. A series of material wastage tests was carried out using 742 {mu}m, quartz silica (SiO{sub 2}) on 1018 steel at elevated temperature (300 {degrees}C) which occurs in-bed locations of BFBC. The morphologies of the specimens were examined and analyzed by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). The maximum collision frequency around the periphery of the tube was found at 45 {degrees}, 315 {degrees} from bottom center, 0{degrees}, which was correlated with maximum material wastage rate of the specimens.

  16. Effect of operating and design parameters on fluidized-bed combustor in-bed tube metal wastage, literature review. Quarterly report

    SciTech Connect (OSTI)

    Wei, W.; Deffenbaugh, D.

    1986-02-01

    This review documents the current state-of-the-art in the three general areas of corrosion, erosion/corrosion. Both the corrosion and erosion studies identify certain relevant parameters for each process. The investigations into the combined erosion/corrosion process point and the complexity of this physical phenomenon even in simple flow fields under well known chemical environments. When applied to the problem of tube metal wastage in a fluidized bed, the issue becomes extremely difficult. The investigation of this complicated process in this extremely complex flow field with a chemical environment that is not well documented requires an extremely careful approach. In order to attack this problem, we propose a new mathematical framework for a model of the erosion/corrosion which is based on physically realistic concepts of the processes occurring, and includes the effects and interactions of the relevant parameters. The resulting ''model'' is a modified corrosion model that treats erosion as an interrelated process that serves to thin the corrosive scale. Once this framework is completed and a range of values for each parameter is identified, a statistical analysis will provide a prioritized list of experiments required to investigate this complex process. This statistical test plan will then be used as guidance for developing design specifications for a test rig. The balance of the project will include the detailed design and fabrication of the rig and a year long test program. The resulting data will then be analyzed and incorporated into the model to gain insight into the process of tube metal wastage in fluidized-bed combustors. 83 refs., 20 figs., 5 tabs.

  17. Energy and environmental research emphasizing low-rank coal -- Task 3.8, Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Mann, M.D.; Henderson, A.K.; Swanson, M.L.

    1995-03-01

    The goal of the PFBC activity is to generate fundamental process information that will further the development of an economical and environmentally acceptable second-generation PFBC. The immediate objectives focus on generic issues, including the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals in PFBC. A great deal of PFBC performance relates to the chemistry of the bed and the contact between gas and solids that occurs during combustion. These factors can be studied in a suitably designed bench-scale reactor. The present studies are focusing on the emission control strategies applied in the bed, rather than in hot-gas cleaning. Emission components include alkali and heavy metals in addition to SO{sub 2}, NO{sub x}, N{sub 2}O, and CO. The report presents: a description of the pressurized fluidized-bed reactor (PFBR); a description of the alkali sampling probe; shakedown testing of the bench-scale PFBR; results from alkali sampling; results from sulfur sorbent performance tests; and results from refuse-derived fuel and lignite combustion tests.

  18. Functionalization of polymer powders for SLS-processes using an atmospheric plasma jet in a fluidized bed reactor

    SciTech Connect (OSTI)

    Sachs, Marius; Schmitt, Adeliene; Schmidt, Jochen; Peukert, Wolfgang; Wirth, Karl-Ernst

    2015-05-22

    Recently additive manufacturing processes such as selective laser sintering (SLS) of polymers have gained more importance for industrial applications [1]. Tailor-made modification of polymers is essential in order to make these processes more efficient and to cover the industrial demands. The so far used polymer materials show weak performance regarding the mechanical stability of processed parts. To overcome this limitation, a new route to functionalize the surface of commercially available polymer particles (PA12; PE-HD; PP) using an atmospheric plasma jet in combination with a fluidized bed reactor has been investigated. Consequently, an improvement of adhesion and wettability [2] of the polymer surface without restraining the bulk properties of the powder is achieved. The atmospheric plasma jet process can provide reactive species at moderate temperatures which are suitable for polymer material. The functionalization of the polymer powders improves the quality of the devices build in a SLS-process.

  19. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume 1. Model evolution and development

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The Energy Laboratory of the Massachusetts Institute of Technology (M.I.T.), under Department of Energy (DOE) sponsorship, has been engaged in the development of a comprehensive mechanistic model of Fluidized Bed Combustors (FBC). The primary aims of this modeling effort are the generation and to the extent possible, validation of an analytical framework for the design and scale-up of fluidized bed combustors. In parallel with this modeling effort, M.I.T. also embarked upon the development of an FBC-Data Base Management System (FBC-DBMS) aimed at facilitating the coordination, interpretation and utilization of the experimental data that are or will become available from diverse sources, as well as in the identification of areas of large uncertainty or having a paucity of experimental results. The synergistic operation of the FBC-Model and FBC-Data Base promises to offer a powerful tool for the design and optimization of FBC's and represents the ultimate goal of the M.I.T. effort. The modeling effort was initially focused upon evaluation and application of state-of-the-art models. The initial system model was divided into five basic components: fluid dynamics, combustion, sulfur capture, heat transfer and emissions. Due to the technical complexity of modeling FBC operation and the initial primitive nature of models for these components, it was deemed necessary to be able to incorporate evolutionary improvements in understanding and correlating FBC phenomena: the M.I.T. system model is, therefore, modular in nature, i.e., each sub-model can be replaced by an updated or equivalent sub-model without necessitating reprogramming of the entire system model.

  20. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of alkali chlorides and sulfates gives increased sintering. At the same time, increased amounts calcium salts in the ash appear to reduce sintering tendency. Thus, the results suggest that a calcium based sorbent for SO{sub 2} and HCl capture might reduce problems related to ash sintering. An extensive literature exists, however, that states otherwise.

  1. Final Environmental Impact Statement for the JEA Circulating Fluidized Bed Combustor Project

    SciTech Connect (OSTI)

    N /A

    2000-06-30

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the Clean Coal Technology Program. The project would demonstrate circulating fluidized bed (CFB) combustion technology at JEA's existing Northside Generating Station in Jacksonville, Florida, about 9 miles northeast of the downtown area of Jacksonville. The new CFB combustor would use coal and petroleum coke to generate nearly 300 MW of electricity by repowering the existing Unit 2 steam turbine, a 297.5-MW unit that has been out of service since 1983. The proposed project is expected to demonstrate emission levels of sulfur dioxide (SO{sub 2}), oxides of nitrogen (NO{sub x}), and particulate matter that would be lower than Clean Air Act limits while at the same time producing power more efficiently and at less cost than conventional coal utilization technologies. At their own risk, JEA has begun initial construction activities without DOE funding. Construction would take approximately two years and, consistent with the original JEA schedule, would be completed in December 2001. Demonstration of the proposed project would be conducted during a 2-year period from March 2002 until March 2004. In addition, JEA plans to repower the currently operating Unit 1 steam turbine about 6 to 12 months after the Unit 2 repowering without cost-shared funding from DOE. Although the proposed project consists of only the Unit 2 repowering, this EIS analyzes the Unit 1 repowering as a related action. The EIS also considers three reasonably foreseeable scenarios that could result from the no-action alternative in which DOE would not provide cost-shared funding for the proposed project. The proposed action, in which DOE would provide cost-shared finding for the proposed project, is DOE's preferred alternative. The EIS evaluates the principal environmental issues, including air quality, traffic, noise, and ecological resources, that could result from construction and operation of the proposed project. Key findings include that maximum modeled increases in ground-level concentrations of SO{sub 2} nitrogen dioxide (NO{sub 2}), and particulate matter (for the proposed project alone or in conjunction with the related action) would always be less than 10% of their corresponding standards for increases in pollutants. For potential cumulative air quality impacts, results of modeling regional sources and the proposed project indicate that the maximum 24-hour average SO{sub 2} concentration would closely approach (i.e., 97%) but not exceed the corresponding Florida standard. After the Unit 1 repowering, results indicate that the maximum 24-hour average SO{sub 2} concentration would be 91% of the Florida standard. Concentrations for other averaging periods and pollutants would be lower percentages of their standards. Regarding toxic air pollutants from the proposed project, the maximum annual cancer risk to a member of the public would be approximately 1 in 1 million; given the conservative assumptions in the estimate, the risk would probably be less. With regard to threatened and endangered species, impacts to manatees, gopher tortoises, and other species would be negligible or non-existent. Construction-induced traffic would result in noticeable congestion. In the unlikely event that all coal were transported by rail, up to 3 additional trains per week would exacerbate impacts associated with noise, vibration, and blocked roads at on-grade rail crossings. Additional train traffic could be minimized by relying more heavily on barges and ships for coal transport, which is likely to be a more economic fuel delivery mode. During construction of the proposed project, noise levels would increase from the current operational levels. Except possibly during steam blowouts and possibly during operation of equipment used to construct a nearby segment of a conveyor, construction noise should not appreciably affect the background noise of nearby residences or exceed local noise limitations. The preferred alternative for management of the combustion ash would be to sell it as a by-product to offsite customers. If more than approximately 70% of the ash could be sold over the 30-year lifetime of Northside Generating Station, the 40-acre storage site would be sufficient for complete containment.

  2. Technical and economic assessment of fluidized bed augmented compressed air energy-storage system. Volume II. Introduction and technology assessment

    SciTech Connect (OSTI)

    Giramonti, A.J.; Lessard, R.D.; Merrick, D.; Hobson, M.J.

    1981-09-01

    The results are described of a study subcontracted by PNL to the United Technologies Research Center on the engineering feasibility and economics of a CAES concept which uses a coal fired, fluidized bed combustor (FBC) to heat the air being returned from storage during the power production cycle. By burning coal instead of fuel oil, the CAES/FBC concept can completely eliminate the dependence of compressed air energy storage on petroleum fuels. The results of this assessment effort are presented in three volumes. Volume II presents a discussion of program background and an in-depth coverage of both fluid bed combustion and turbomachinery technology pertinent to their application in a CAES power plant system. The CAES/FBC concept appears technically feasible and economically competitive with conventional CAES. However, significant advancement is required in FBC technology before serious commercial commitment to CAES/FBC can be realized. At present, other elements of DOE, industrial groups, and other countries are performing the required R and D for advancement of FBC technology. The CAES/FBC will be reevaluated at a later date when FBC technology has matured and many of the concerns now plaguing FBC are resolved. (LCL)

  3. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume II. Detailed description of the model

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the second of a seven volume series of our Phase II Final Report. This volume deals with detailed descriptions of the structure of each program member (subroutines and functions), the interrelation between the members of a submodel, and the interrelation between the various submodels as such. The systems model for fluidized bed combustors (FBC-II) consists of a systematic combination of the following interrelated areas: fluid mechanics and bubble growth, char combustion and associated kinetics for particle burnout, sulfur capture, NO/sub x/ formation and reduction, freeboard reactions, and heat transfer. Program outline is shown in Figure 1.1. Input variables (supplied by the user are inspected to check that they lie inside the allowed range of values and are input to the various routines as needed. The necessary physical and fluid mechanical properties are calculated and utilized in estimating char combustion and sulfur capture in the bed and the freeboard. NO/sub x/ and CO emissions are estimated by taking into account all relevant chemical reactions. A material and energy balance is made over the bed. Figure 1.1 shows a block diagram of the systems program. In this diagram, the overall structure of the FBC program is illustrated in terms of the various submodels that together constitute the systems program. A more detailed outline of the systems program is shown in Figure 1.2. In this figure, all important subroutine members of the FBC program are shown, and their linkage to each other, as well as to the main program is indicated. A description of the exact sequence in which these various routines are called at time of program execution is provided in Chapter 8 under the executive routine MAIN.

  4. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  5. High-temperature-staged fluidized-bed combustion (HITS), bench scale experimental test program conducted during 1980. Final report

    SciTech Connect (OSTI)

    Anderson, R E; Jassowski, D M; Newton, R A; Rudnicki, M L

    1981-04-01

    An experimental program was conducted to evaluate the process feasibility of the first stage of the HITS two-stage coal combustion system. Tests were run in a small (12-in. ID) fluidized bed facility at the Energy Engineering Laboratory, Aerojet Energy Conversion Company, Sacramento, California. The first stage reactor was run with low (0.70%) and high (4.06%) sulfur coals with ash fusion temperatures of 2450/sup 0/ and 2220/sup 0/F, respectively. Limestone was used to scavenge the sulfur. The produced low-Btu gas was burned in a combustor. Bed temperature and inlet gas percent oxygen were varied in the course of testing. Key results are summarized as follows: the process was stable and readily controllable, and generated a free-flowing char product using coals with low (2220/sup 0/F) and high (2450/sup 0/F) ash fusion temperatures at bed temperatures of at least 1700/sup 0/ and 1800/sup 0/F, respectively; the gaseous product was found to have a total heating value of about 120 Btu/SCF at 1350/sup 0/F, and the practicality of cleaning the hot product gas and delivering it to the combustor was demonstrated; sulfur capture efficiencies above 80% were demonstrated for both low and high sulfur coals with a calcium/sulfur mole ratio of approximately two; gasification rates of about 5,000 SCF/ft/sup 2/-hr were obtained for coal input rates ranging from 40 to 135 lbm/hr, as required to maintain the desired bed temperatures; and the gaseous product yielded combustion temperatures in excess of 3000/sup 0/F when burned with preheated (900/sup 0/F) air. The above test results support the promise of the HITS system to provide a practical means of converting high sulfur coal to a clean gas for industrial applications. Sulfur capture, gas heating value, and gas production rate are all in the range required for an effective system. Planning is underway for additional testing of the system in the 12-in. fluid bed facility, including demonstration of the second stage char burnup reactor.

  6. Method and apparatus for gasifying with a fluidized bed gasifier having integrated pretreating facilities

    DOE Patents [OSTI]

    Rice, Louis F.

    1981-01-01

    An integral gasifier including a pretreater section and a gasifier section separated by a distribution grid is defined by a single vessel. The pretreater section pretreats coal or other carbon-containing material to be gasified to prevent caking and agglomeration of the coal in the gasifier. The level of the coal bed of the pretreater section and thus the holding or residence time in said bed is selectively regulated by the amount of pretreated coal which is lifted up a lift pipe into the gasifier section. Thus, the holding time in the pretreater section can be varied according to the amount of pretreat necessary for the particular coal to be gasified.

  7. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect (OSTI)

    DeLallo, M.; Zaharchuk, R.

    1994-01-01

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  8. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Technical progress report No. 8, July 1994--September 1994

    SciTech Connect (OSTI)

    Lee, S.W.

    1994-10-01

    This technical report summarizes the research work performed and progress achieved during the period of July 1, 1994 to September 30, 1994. The metal wastage of AISI 1018 low carbon steel at different particle velocity was discussed to understand the erosion phenomena of in-bed tube in FBC system. At both low velocity (2.5 m/s) and high (30 m/s), the maximum metal wastage was occurred at 45{degrees} of impact angle. The erosion rates at low particle velocity were two (2) to three (3) orders of magnitude lower than those at high particle velocity. The characteristics of anti-erosion and design considerations were discussed and suggested for some basic design guidelines, which might be important to the designer of bubbling fluidized combustors. The working principle and mechanism of anti-erosion devices will be discussed. Based upon the understanding of the working principle and mechanism of anti-erosion devices, different types of ant-erosion tube will be designed for the cold model bench-scale FBC system.

  9. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system

    SciTech Connect (OSTI)

    Lee, S.W.

    1994-07-01

    This technical report summarizes the research work performed and progress achieved during the period of April 1, 1994 to June 30, 1994. The metal wastage tests were continued to understand the erosion phenomena of in-bed tube in FBC system. The plain carbon steel, AISI 1018 was used as the target materials along with quartz silica (SiO{sub 2}) as the erodent particles. For the high velocity test, the short exposure time (4 hours) minimized the oxide scale formation and potential weight gain. No oxidation layer could be seen on worn surfaces. The eroded surface of specimens tested under high particle velocity exhibited the typical ductile mode. The maximum material wastage was occurred at 45{degrees} of impact angle. The metal wastage rate of AISI 1018 carbon steel demonstrated higher wastage at a shallow angle than at a step angle with a maximum erosion rate occurring at impact angle of 45{degrees}. The morphologies of the specimens were examined and analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS).

  10. Bench-Scale Development of Fluidized-Bed Spray-Dried Sorbents

    SciTech Connect (OSTI)

    Gupta, R.P.; Turk, B.S.; Gangwal, S.K.

    1996-12-31

    Successful development of regenerable mixed-metal oxide sorbents for removal of reduced sulfur species (such as H{sub 2}S and COS) from coal-derived fuel gas streams at high=temperature, high-pressure (HTHP) conditions is a key to commercialization of the integrated-gasification-combined-cycle (IGCC) power systems. Among the various available coal-to-electricity pathways, IGCC power plants have the most potential with high thermal efficiency, simple system configuration, low emissions of SO{sub 2}, NO{sub x} and other contaminants, modular design, and low capital cost. Due to these advantages, the power plants of the 21st century are projected to utilize IGCC technology worldwide. Sorbents developed for sulfur removal are primarily zinc oxide-based inorganic materials, because of their ability to reduce fuel gas sulfur level to a few parts-per-million (ppm). This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. Specific objectives are to develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{mu}m particle size range for transport reactor applications using semicommercial- to full commercial-scale spray dryers, to transfer sorbent production technology to private sector, and to provide technical support for Sierra Pacific`s Clean Coal Technology Demonstration plant and METC`s hot-gas desulfurization process development unit (PDU), both employing a transport reactor system.

  11. Multiphase flow simulations of a moving fluidized bed regenerator in a carbon capture unit

    SciTech Connect (OSTI)

    Sarkar, Avik; Pan, Wenxiao; Suh, Dong-Myung; Huckaby, E. D.; Sun, Xin

    2014-10-01

    To accelerate the commercialization and deployment of carbon capture technologies, computational fluid dynamics (CFD)-based tools may be used to model and analyze the performance of carbon capture devices. This work presents multiphase CFD-based flow simulations for the regeneration device responsible for extracting CO2 from CO2-loaded sorbent particles before the particles are recycled. The use of solid particle sorbents in this design is a departure from previously reported systems, where aqueous sorbents are employed. Another new feature is the inclusion of a series of perforated plates along the regenerator height. The influence of these plates on sorbent distribution is examined for varying sorbent holdup, fluidizing gas velocity, and particle size. The residence time distribution of sorbents is also measured to classify the low regime as plug flow or well-mixed flow. The purpose of this work is to better understand the sorbent flow characteristics before reaction kinetics of CO2 desorption can be implemented.

  12. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    SciTech Connect (OSTI)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome some of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.

  13. Secondary Waste Form Screening Test ResultsTHOR Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  14. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk

    2010-04-15

    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  15. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome somemore » of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.« less

  16. Fluidized-bed copper oxide process. Phase IV. Conceptual design and economic evaluation, Volume I. Final report

    SciTech Connect (OSTI)

    1994-11-30

    Universal Oil Products, Inc. (UOP) of Des Plaines, Illinois has contracted A.E. Roberts & Associates, Inc. (AERA) of Atlanta, Georgia to prepare a sensitivity analysis for the development of the Fluidized-bed Copper Oxide (FBCO) process. As proposed by AERA in September 1991, development of the FBCO process design for a 500 mega-watt (MW) unit was divided into three tasks: (1) Establishment of a Conceptual Design, (2) Conceptual Design, (3) Cost Analysis Task 1 determined the basis for a conceptual design for the 500 megawatt (MW) FBCO process. It was completed by AERA in September of 1992, and a report was submitted at that time {open_quotes}Establishment of the Design Basis for Application to a 500 MW Coal-fired Facility.{close_quotes} Task 2 gathered all pertinent data available to date and reviewed its applicability to the 500 MW FBCO process. Work on this task was carried out on a joint basis by the AERA team members: Roberts & Schaefers worked on the dense phase transport aspect of the design; Cornell and Carnegie Mellon Universities worked on the design kinetics and modeling; and AERA contributed commercial power and combustion experience. Task 3 provides budgetary cost estimates for the FBCO process and competing alternative technologies for sulfur dioxide and nitrogen oxide removal.

  17. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  18. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

  19. Pulsed atmospheric fluidized bed combustion. Technical progress report, July 1993--September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-10-30

    This quarterly report is broken down between design and the status of the fabrication work being performed. The design section is divided between the following sections: Site layout, foundation design, structural design, piping design, pulse combustor components, and electrical & instrumentation design. As reported in the last quarterly report the location area of the PAFBC in the Clemson Energy Facility was inspected with a view to finalize the layout of the PAFBC plant. Some adjustments were made to the layout to accommodate Clemson University`s requirements and the available space. The most important changes are that the boiler and economizer were relocated in the structure above ground level in order to reduce the size of the footprint of the plant. Figure 1 is the plan view of the current layout. Figures 2 through 6 present different elevation views of the layout. The design of foundations for the entire plant is currently being executed by Industra Engineers Inc. of Greenville, SC. The different weights of various equipment located close to each other precludes the provision of independent foundations for each piece of equipment. One monolithic foundation platform for the whole area proves to be more economical for the current layout. In this quarter the design of the plant structures was completed. The drawings were sent out for expert review and approval. The drawings at this stage present complete structural and platform layout requirements. Changes will be made to various structural members based on the structural review and then detailed drawings of joint design and fabrication cutting plans will be prepared and issued for fabrication.

  20. Tubing wastage in fluidized-bed coal combustors: Test Series 2 NCB (IEA Grimethorpe) Ltd

    SciTech Connect (OSTI)

    Witherell, C.E.; Meisenheimer, R.G.

    1988-01-08

    This study of wasted heat-exchanger tubing from the Grimethorpe PFBC Facility was conducted to characterize affected fireside surfaces and identify the mechanism/s responsible. Examinations showed that the wasted surfaces are not typical of those produced by erosion alone, as oxide deposits are present on all surfaces. Continual exfoliation of the normally-protective oxide layer is probably responsible for a major portion of tubing wastage. There are also indications of direct metal loss occurring through a series of events wherein repeated formation and exfoliation of surface oxides produce an irregular metal interface that is mechanically deformed during combustor operation. Cold-worked metal protrusions, or platelets, on the roughened surface readily fracture from the tubing wall and are lost into the bed. In some combustors where metal temperatures generally are above 600 C (1100 F), sulfidation-oxidation corrosion has been identified as the mechanism responsible for metal loss. These occurrences have largely been confined to air heater tubes, uncooled support members, and the like. However, the more perplexing type of metal wastage in FBCs/endash/and that which is the subject of this study/endash/has occurred at much lower metal temperatures of about 400 C (750 F) in in-bed water-cooled tubes. There have been differences of opinion over its cause but the consensus is that erosion is a major factor, if not the sole cause. Examinations have shown that wasted surfaces of heat exchanger tubing from this combustor are the product of combined mechanical, chemical, and thermal effects, all interrelated to produce rapid and localized metal loss. 33 refs., 29 figs., 3 tabs.

  1. Ethanol Production from Rice-Straw Hydrolysate Using Zymomonas Mobilis in a Continuous Fluidized-Bed Reactor (FBR)

    SciTech Connect (OSTI)

    deJesus, D.; Nghiem, N.P.

    2001-01-01

    Rice-straw hydrolysate obtained by the Arkenol's concentrated acid hydrolysis process was fermented to ethanol using a recombinant Zymomonas mobilis strain capable of utilizing both glucose and xylose in a continuous fluidized-bed reactor (FBR). The parameters studied included biocatalyst stability with and without antibiotic, feed composition, and retention time. Xylose utilization in the presence of tetracycline remained stable for at least 17 days. This was a significant improvement over the old strain, Z. mobilis CP4 (pZB5), which started to lose xylose utilization capability after seven days. In the absence of tetracycline, the xylose utilization rate started to decrease almost immediately. With tetracycline in the feed for the first six days, stability of xylose utilization was maintained for four days after the antibiotic was removed from the feed. The xylose utilization rate started to decrease on day 11. In the presence of tetracycline using the Arkenol's hydrolysate diluted to 48 g/L glucose and 13 g/L xylose at a retention time of 4.5 h, 95% xylose conversion and complete glucose conversion occurred. The ethanol concentration was 29 g/L, which gave a yield of 0.48 g/g sugar consumed or 94% of the theoretical yield. Using the Arkenol's hydrolysate diluted to 83 g/L glucose and 28 g/L xylose, 92% xylose conversion and complete glucose conversion were obtained. The ethanol concentration was 48 g/L, which gave a yield of 0.45 g/ g sugar consumed or 88% of the theoretical yield. Maximum productivity of 25.5 g/L-h was obtained at a retention time of 1.9 h. In this case, 84% xylose conversion was obtained.

  2. Fluidized Bed Steam Reforming (FBSR) Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (GNEP)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Williams, M.R. [Savannah River National Laboratory, Aiken, SC (United States)

    2008-07-01

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NOx in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 deg. C) compared to vitrification (1150-1300 deg. C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {>=}1000 deg. C. Pollucite mineralization creates secondary aqueous waste streams and NOx. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O. (authors)

  3. FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP

    SciTech Connect (OSTI)

    Jantzen, C; Michael Williams, M

    2008-01-11

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  4. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume IV. FBC-Model-II manual

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the fourth of the seven volume series of our Phase II Final Report. The purpose of this manual is to describe how to access and use M.I.T.'s Fluidized Bed Combustor (FBC) System Program. Presently, the FBC program is stored in a Honeywell Computer System and can be accessed using the Multics interactive system. The intention in writing this manual is to answer the questions that may arise regarding the mechanics of operating the system program, as well as warn the user of possible pitfalls and mistakes that could be made. No attempt is made here to describe the internals of the systems program. The manual describes the procedures an individual would follow to become an active user of the system program. It then explains the various options available for reaching the Multics interactive system on Honeywell 6180 computer on which the program runs. For users outside the Metropolitan Boston area, a public network for data communications is described which is relatively inexpensive. As the system program is approached through Multics using a special command facility TPSA, a separate introduction is provided for Multics TPSA. This facility allows commands appropriate for testing the program and carrying out parametric studies to be executed in a convenient way. Multics TPSA was formulated to meet the needs of the FBC project in particular. Finally, some sample sessions are presented which illustrate the login and logout procedures, the command language, and the data manipulation features of the FBC program. The use of commands helpful in debugging the program is also illustrated.

  5. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  6. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFD–DAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting themore » reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.« less

  7. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    SciTech Connect (OSTI)

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFD–DAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting the reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.

  8. On-line instrumentation for the real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor - a feasibility study

    SciTech Connect (OSTI)

    D'Silva, A.P.; Iles, M.; Rice, G.; Fassel, V.A.

    1984-04-01

    When polynuclear aromatic hydrocargons in the vapor phase are diluted preferably in a rare gas and undergo supersonic jet expansion, rotationally cooled molecules with absorption bandwidths of the order of 0.01 nm (FWHM) are obtained. Selective excitation with a tunable dye laser into such narrow absorption bands leads to the observation of highly specific luminescence spectra. Such an approach has been utilized for the on-line, real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor.

  9. Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 2, Task 3, Testing of process improvement concepts: Final report, September 1987--May 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    This final report, Volume 2, on ``Process Improvement Concepts`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). Results of work on electroseparation of shale oil and fines conducted by IIT is included in this report, as well as work conducted by IGT to evaluate the restricted pipe discharge system. The work was conducted as part of the overall program on ``Pressurized Fluidized-Bed Hydroretorting of Eastern Oil Shales.``

  10. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  11. Composite coatings for elevated temperature erosion-corrosion protection in fossil-fueled boilers

    SciTech Connect (OSTI)

    Verstak, A.; Wang, B.; Baranovski, V.; Beliaev, A.

    1998-12-31

    Fluidized bed combustors components suffer severe erosion, frequently accomplished by corrosive gases attack at elevated temperatures. The tubes damage rate depends on the boiler design bed constituents and combustion parameters, however an accelerated metal wastage is usually found in the same specific areas of different boilers. New HVOF sprayed coatings are developed for the tube erosion-corrosion protection, based on Cr{sub 2}C{sub 2}/Ni-Cr, Cr-Ti-C/Ni-Cr-Mo, and Al{sub 2}O{sub 3}/NiAl composite materials. The combustion arc Fe-Cr-C coatings were found as an economical solution for relatively low erosion rate zones. The coatings properties and behavior under simulated elevated temperature erosion conditions and in the operating boilers are discussed.

  12. Gas turbines for coal-fired turbocharged PFBC boiler power plants

    SciTech Connect (OSTI)

    Wenglarz, R.; Drenker, S.

    1984-11-01

    A coal-fired turbocharged boiler using fluidized bed combustion at high pressure would be more compact than a pulverized coal fired boiler. The smaller boiler size could permit the utility industry to adopt efficient modular construction methods now widely used in other industries. A commercial turbocharger of the capacity needed to run a 250 MW /SUB e/ power plant does not exist; commercial gas turbines of the correct capacity exist, but they are not matched to this cycle's gas temperature of less than 538/sup 0/C (1000/sup 0/F). In order to avoid impeding the development of the technology, it will probably be desirable to use existing machines to the maximum extent possible. This paper explores the advantages and disadvantages of applying either standard gas turbines or modified standard gas turbines to the turbocharged boiler.

  13. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, April 1-June 30, 1983

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. Experimental work was initiated on the unsteady-state Fischer-Tropsch synthesis using a fully-automated vibrofluidized microreactor system and a computer-controlled on-line gas chromatographic (GC) system for product analysis. Both the reactor and GC systems performed well in all experiments, and no mechanical problems were observed throughout the experiments lasting as long as twenty hours. Preliminary estimates indicated that the conversion of CO to carbon was only on the order of one-tenth of one percent. This encouraging result provided evidence that it should be possible to experimentally identify cycling conditions which could prevent carbon deposits on the catalyst while treating a synthesis gas of low H/sub 2/:CO ratio.

  14. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  15. The Lakeland McIntosh Unit 4 demonstration project utilizing Foster Wheeler`s pressurized circulating fluidized-bed combustion technology

    SciTech Connect (OSTI)

    McClung, J.D.; Provol, S.J.; Morehead, H.T.; Dodd, A.M.

    1997-12-31

    The City of Lakeland, Florida, Foster Wheeler and the Westinghouse Electric Corporation have embarked on the demonstration of a Clean Coal Technology at the City of Lakeland`s McIntosh Power Station in lakeland, Polk County, Florida. The project will demonstrate the Pressurized Circulating Fluidized Bed Combustion (PCFB) technology developed by Foster Wheeler and Westinghouse. The Lakeland McIntosh Unit 4 Project is a nominal 170 MW power plant designed to burn a range of low- to high-sulfur coals. The combined cycle plant employs a Westinghouse 251B12 gas turbine engine in conjunction with a steam turbine operating in a 2400/1000/1000 steam cycle. The plant will demonstrate both the PCFB and topped PCFB combustion technologies. This paper provides a process description of the Foster Wheeler PCFB and Topped PCFB technologies and their application to the Lakeland McIntosh Unit 4 Project.

  16. Investigation of Fly Ash and Activated Carbon Obtained from Pulverized Coal Boilers

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely; Zheng Yao

    2006-08-31

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addressed the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addressed the possible connection between SCR reactors, fly ash properties and Hg capture. The project has determined the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed have also been determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control have been analyzed in an effort to determine the effects of SCR on the ash.

  17. INVESTIGATION OF FLY ASH AND ACTIVATED CARBON OBTAINED FROM PULVERIZED COAL BOILERS

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely

    2004-11-01

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addresses the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addresses the possible connection between SCR reactors, fly ash properties and Hg capture. The project is determining the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed are also being determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control, are being analyzed to determine the effect of SCR on the ash. These analyses will also determine the properties of ash which are important for Hg capture.

  18. INVESTIGATION OF FLY ASH AND ACTIVATED CARBON OBTAINED FROM PULVERIZED COAL BOILERS

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely

    2005-11-01

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addresses the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addresses the possible connection between SCR reactors, fly ash properties and Hg capture. The project is determining the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed are also being determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control, are being analyzed to determine the effect of SCR on the ash.

  19. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume III. Model predictions and results

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the third of a seven volume series of our Phase II Final Report. This volume deals with parametric studies carried out using the FBC model. A comparison with available pilot plant data is included where such data are available. This volume in essence documents model performance; describing predictions on bubble growth, combustion characteristics, sulfur capture, heat transfer and related parameters. The model has approximately forty input variables which are at the disposal of the user. The user has the option to change a few or all of these input variables. In the parametric studies reported here, a large number of input variables whose variation is less critical to the predicted results, were maintained constant at the default values. On the other hand, those parameters whose selection is very important in design and operation of the FBC's were varied in suitable operating regions. The chief among such parameters are: bed temperature, coal feed size distribution (2 parameters), average bed-sorbent size, calcium to sulfur molar ratio, superficial velocity, excess air fraction, and bed weight (or bed height). The computations for obtaining the parametric relationships are based upon selection of a geometrical design for the combustor. Bed cross-section is 6' x 6', bed height is 4', and the freeboard height is 16'. The heat transfer tubes have 2'' OD, a pitch of 10'', and are located on an equilateral triangle pattern. The air distributor is a perforated plate with 0.1'' diameter holes on a rectangular grid with 0.75'' center-to-center spacing.

  20. Postcombustion and its influences in 135 MWe CFB boilers

    SciTech Connect (OSTI)

    Shaohua Li; Hairui Yang; Hai Zhang; Qing Liu; Junfu Lu; Guangxi Yue

    2009-09-15

    In the cyclone of a circulating fluidized bed (CFB) boiler, a noticeable increment of flue gas temperature, caused by combustion of combustible gas and unburnt carbon content, is often found. Such phenomenon is defined as post combustion, and it could introduce overheating of reheated and superheated steam and extra heat loss of exhaust flue gas. In this paper, mathematical modeling and field measurements on post combustion in 135MWe commercial CFB boilers were conducted. A novel one-dimensional combustion model taking post combustion into account was developed. With this model, the overall combustion performance, including size distribution of various ashes, temperature profile, and carbon content profiles along the furnace height, heat release fraction in the cyclone and furnace were predicted. Field measurements were conducted by sampling gas and solid at different positions in the boiler under different loads. The measured data and corresponding model-calculated results were compared. Both prediction and field measurements showed post combustion introduced a temperature increment of flue gas in the cyclone of the 135MWe CFB boiler in the range of 20-50{sup o}C when a low-volatile bituminous coal was fired. Although it had little influence on ash size distribution, post combustion had a remarkable influence on the carbon content profile and temperature profile in the furnace. Moreover, it introduced about 4-7% heat release in the cyclone over the total heat release in the boiler. This fraction slightly increased with total air flow rate and boiler load. Model calculations were also conducted on other two 135MWe CFB boilers burning lignite and anthracite coal, respectively. The results confirmed that post combustion was sensitive to coal type and became more severe as the volatile content of the coal decreased. 15 refs., 11 figs., 4 tabs.

  1. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    SciTech Connect (OSTI)

    Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

    2014-01-10

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

  2. Biodegradation of phenolic wastewaters in a three-phase fluidized bed bioreactor with the KMT{reg_sign} biomass support

    SciTech Connect (OSTI)

    Sokol, W.; Halfini, M.R.

    1996-12-31

    A treatment of wastewater from a local refinery in a three-phase fluidised bed bioreactor with the KMT{sup R} biomass support was investigated. It was found that after adding mineral salts to the wastewater to be treated, a reduction in the COD values increased from about 55% to almost 90%. The reduction in COD was increasing with an increase in both a superficial air velocity and a ratio of bed volume to bioreactor volume (V{sub b}/V{sub r}). The highest value of (V{sub b}/V{sub r}) which could be applied in the experiments was 0.7, because at larger (V{sub b}/V{sub r}) movement of the whole bed was impossible. The bioreactor as operated was not successful in degrading thiocyanates, cyanides, nitrates and ammonia. However, results of independent experiments that have been started to adapt the symbiotic populations of microorganisms that may effectively degrade those compounds are promising. Stratification of the support media coated with the biomass led to their movement to the base of the bioreactor where concentration of organic compounds was highest. This was desirable since the compounds could penetrate far into the biofilm so most of the biomass grown on the support was active. 6 refs., 3 figs.

  3. A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system

    SciTech Connect (OSTI)

    Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

    2000-07-01

    Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

  4. Combustion of municipal solid wastes with oil shale in a circulating fluidized bed. Quarterly report, quarter ending 31 December 1994

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    The test plan is designed to demonstrate that oil shale co-combusted with municipal solid waste (MSW) can reduce gaseous pollutants (SO{sub 2}, CO) to acceptable levels (90%+ reduction) and produce a cementitious ash which will, at a minimum, be acceptable in normal land fills. The small-scale combustion testing will be accomplished in a 6-in. circulating fluid bed combustor (CFBC) at Hazen Research Laboratories. This work will be patterned after the study the authors conducted in 1988 when coal and oil shale were co-combusted in a program sponsored by the Electric Power Research Institute. The specific purpose of the test program will be to: determine the required ratio of oil shale to MSW by determining the ratio of absorbent to pollutant (A/P); determine the effect of temperature and resident time in the reactor; and determine if kinetic model developed for coal/oil shale mixture is applicable.

  5. Tubing wastage in fluidized-bed coal combustors: Examinations of tubing from Test Series 2, NCB (IEA Grimethorpe) Ltd. Facility

    SciTech Connect (OSTI)

    Witherell, C.E.; Meisenheimer, R.G.

    1987-10-30

    This study of wasted heat-exchanger tubing from the Grimethorpe PFBC Facility was conducted to characterize affected fireside surfaces and identify the mechanism/s responsible. Examinations showed that the wasted surfaces are not typical of those produced by erosion alone, as oxide deposits are present on all surfaces. Continual exfoliation of the normally-protective oxide layer is probably responsible for a major portion of tubing wastage. There are also indications of direct metal loss occurring through a series of events wherein repeatd formation and exfoliation of surface oxides produce an irregular metal interface that is mechanically deformed during combustor operation. The cold-worked metal protrusions, or platelets, on the roughened surface readily fracture from the tubing wall and are lost into the bed. 27 refs., 23 figs., 3 tabs.

  6. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. Technical progress report No. 12

    SciTech Connect (OSTI)

    Lee, S.W.

    1995-10-01

    This technical report summarizes the research work performed and progress achieved during the period of July 1, 1995 to October 30, 1995. The characteristics of resistant coatings were determined and related to metal wastage of in-bed tubes in FBC under various laboratory test conditions, The tests were conducted at high impact velocity, 30 m/s, and short exposure time (4 hours) to minimize oxidation of surrounding surface specimens. No oxidation layer founded on the worn surfaces of AISI 1018 carbon steel, The eroded surfaces and cross sections of coatings tested at high velocity were investigated, The surfaces of coating specimens were eroded through a combined mechanism of brittle and ductile modes, These mechanical properties of materials are strongly dependent on the composition and microstate of materials, rather than to their hardness, For high velocity testing, all of the coatings exhibited {open_quotes}brittle behavior{close_quotes}, i.e., the erosion rate at shallow angles was higher than at steep angles and maximum erosion rate at impact angle of 90{degrees}. Tests will be continued and compared with erosion test results for different thermal sprayed coatings.

  7. Reducing the environmental impact on solid wastes from a fluidized...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; COAL; FLUIDIZED-BED COMBUSTION; WASTE MANAGEMENT; AIR POLLUTION ABATEMENT; ALUMINIUM OXIDES; CALCIUM OXIDES; CHEMICAL ACTIVATION; COMPARATIVE ...

  8. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    1982-10-21

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  9. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume VII. FBC Data-Base-Management System (FBC-DBMS) users manual

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The primary goal of the Fluidized Bed Combustor Data Base (FBCDB) is to establish a data repository for the express use of designers and research personnel involved in FBC development. FBCDB is implemented on MIT's 370/168 computer, using the Model 204 Data Base Management System (DBMS) developed by Computer Corporation of America. DBMS is a software that provides an efficient way of storing, retrieving, updating and manipulating data using an English-like query language. The primary content of FBCDB is a collection of data points defined by the value of a number of specific FBC variables. A user may interactively access the data base from a computer terminal at any location, retrieve, examine, and manipulate the data as well as produce tables or graphs of the results. More than 20 program segments are currently available in M204 User Language to simplify the user interface for the FBC design or research personnel. However, there are still many complex and advanced retrieving as well as applications programs to be written for this purpose. Although there are currently 71 entries, and about 2000 groups reposited in the system, this size of data is only an intermediate portion of our selection. The usefulness of the system at the present time is, therefore, limited. This version of FBCDB will be released on a limited scale to obtain review and comments. The document is intended as a reference guide to the use of FBCDB. It has been structured to introduce the user to the basics of FBCDB, summarize what the available segments in FBCDB can do, and give detailed information on the operation of FBCDB. This document represents a preliminary draft of a Users Manual. The draft will be updated when the data base system becomes fully implemented. Any suggestions as to how this manual may be improved will be appreciated.

  10. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume VI. FBC-Data Base-Management-System (FBC-DBMS) development

    SciTech Connect (OSTI)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    The primary goal of the Fluidized Bed Combustor Data Base, (FBCDB), situated in MIT's Energy laboratory, is to establish a data repository for the express use of designers and research personnel involved in FBC development. DBMS is a software that provides an efficient way of storing, retrieving, updating and manipulating data using an English-like query language. It is anticipated that the FBCDB would play an active and a direct role in the development of FBC technology as well as in the FBC commercial application. After some in-house experience and after a careful and extensive review of commercially available database systems, it was determined that the Model 204 DBMS by Computer Corporation of America was the most suitable to our needs. The setup of a prototype in-house database also allowed us to investigate and understand fully the particular problems involved in coordinating FBC development with a DBMS. Various difficult aspects were encountered and solutions had been sought. For instance, we found that it was necessary to rename the variables to avoid repetition as well as to increase usefulness of our database and, hence, we had designed a classification system for which variables were classified under category to achieve standardization of variable names. The primary content of FBCDB is a collection of data points defined by the value of a number of specific FBC variables. A user may interactively access the database from a computer terminal at any location, retrieve, examine, and manipulate the data as well as produce tables or graphs of the results.

  11. Characterization and analysis of metal wastage in coal-fired fluidized-bed combustors. Statistical analysis plan

    SciTech Connect (OSTI)

    Nazemi, A.H.; Smith, E.P.

    1985-11-01

    Metal loss from in-bed heat exchangers has been a persistent problem in FBC systems. As part of its program in FBC technology development, the US Department of Energy/Morgantown Energy Technology Center (DOE/METC) supports a number of projects directed toward providing both theoretical and experimental results which will guide solutions to the metal loss problem. As a part of this effort, METC and The MITRE Corporation began a project in 1984 to collect and analyze metal loss data from various experimental, pilot-scale, and full-scale coal-fired FBC systems worldwide. The specific objective of this effort is to investigate the effects of unit design parameters and operating conditions on metal loss through the use of regression and analysis of variance techniques. To date, forty-one FBC systems worldwide have been identified and most of the data sets which characterize the metal loss occurrences in those units have been developed. The results of MITRE's effort to date were reported earlier (Interim Report No. DOE/MC/21351-1930, August 1985). This report describes the statistical procedures that MITRE will follow to analyze FBC metal loss data. The data will be analyzed using several regression techniques to find variables related to metal loss. Correlation and single variable regressions will be used to indicate important relationships. The joint relationships between the explanatory variables and metal loss will be examined by building multiple regression models. In order to prevent erroneous conclusions, diagnostics will be performed based on partial residual plots, residual analysis, and multicollinearity statistics. 7 refs.

  12. Fischer-Tropsch synthesis from a low HH/sub 2/:CO gas in a dry fluidized-bed system. Volume 1. Project summary. Final technical report, October 1, 1986. [Heat tray

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1986-10-01

    The objective of this project is to experimentally develop and demonstrate a dry fluidized-bed reactor system (called ''heat tray'') for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of an iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. The project has been carried out in two key tasks: (1) development of a microreactor system for unsteady-state Fischer-Tropsch synthesis, simulating the life history of an iron catalyst particle in a ''heat-tray'' reactor; and (2) supporting fluidization studies. The present Volume I summarizes the key conclusions and recommendations from this project, and the accompanying Volumes II and III describes the details of experimental investigations and results. 12 refs., 8 figs., 2 tabs.

  13. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, September 1, 1982-March 31, 1983. [Large number of references

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.; Konrad, K.

    1983-01-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/:CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past several months, the design, construction and steady-state testing of a fully-automated vibrofluidized microreactor system have been successfully completed, and a computer-controlled gas chromatographic (GC) system for gas-product analysis has also been tied to the reactor system. Work on unsteady-state Fischer-Tropsch synthesis experiments is to be initiated shortly. In addition, supporting hydrodynamic and heat-transfer studies in several shallow fluidized-bed systems have produced some encouraging data. The results indicate very high heat-transfer coefficients of 300-400 W/m/sup 2/-/sup 0/K between a shallow bed and its immersed horizontal heat-transfer tube, and of about 7000 W/m/sup 2/-/sup 0/K between a supernatant gas stream and a shallow bed which closely simulates the microreactor system in use.

  14. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Volume 2. Development of microreactor systems for unsteady-state Fischer-Tropsch synthesis. Final technical report. [408 references

    SciTech Connect (OSTI)

    Whiting, G.K.; Liu, Y.A.; Squires, A.M.

    1986-10-01

    Vibrofluidized microreactor systems have been developed for studies of unsteady-state Fischer-Tropsch synthesis. This development is aimed at preventing carbon deposition on a fused-iron catalyst in a novel reactor called the ''heat tray.'' This reactor involves a supernatant gas flowing over a shallow fluidized bed of catalyst particles. Three systems were built: (1) a vibrofluidized-bed microreactor system for obtaining baseline carbon deposition information under industrially important reaction conditions; (2) a sliding-plug vibrofluidized-bed microreactor system for rapid switching of feed gases in the F-T synthesis; and (3) a cold-flow microreactor model for studying the gas mixing characteristics of the sliding-plug vibrofluidized-bed microreactor. The results show that catalyst defluidization occurred under steady-state synthesis conditions below 395 C using a feed gas of H/sub 2//CO ratio of 2:1 or less. Above 395 C, the probability of hydrocarbon chain growth (..cap alpha.. < 0.50 to prevent accumulation of high-molecular-weight species that cause defluidization. Carbon deposition was rapid above 395 C when a feed gas of H/sub 2//CO ratio of 2:1 or less was used. Cold-flow microreactor model studies show that rapid (on the order of seconds), quantitative switching of feed gases over a vibrofluidized bed of catalyst could be achieved. Vibrofluidization of the catalyst bed induced little backmixing of feed gas over the investigated flow-rate range of 417 to 1650 actual mm/sup 3//s. Further, cold-flow microreactor model studies showed intense solid mixing when a bed of fused-iron catalyst (150 to 300 microns) was vibrofluidized at 24 cycles per second with a peak-to-peak amplitude of 4 mm. The development of the microreactor systems provided an easy way of accurately determining integral fluid-bed kinetics in a laboratory reactor. 408 refs., 156 figs., 27 tabs.

  15. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  16. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 85 citations and includes a subject term index and title list.)

  17. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 84 citations and includes a subject term index and title list.)

  18. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  19. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 119 citations and includes a subject term index and title list.)

  20. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  1. Evaluation of wall boundary condition parameters for gas-solids fluidized

    Office of Scientific and Technical Information (OSTI)

    bed simulations (Journal Article) | SciTech Connect Evaluation of wall boundary condition parameters for gas-solids fluidized bed simulations Citation Details In-Document Search Title: Evaluation of wall boundary condition parameters for gas-solids fluidized bed simulations Wall boundary conditions for the solids phase have significant effects on numerical predictions of various gas-solids fluidized beds. Several models for the granular flow wall boundary condition are available in the open

  2. Tapered bed bioreactor

    DOE Patents [OSTI]

    Scott, Charles D.; Hancher, Charles W.

    1977-01-01

    A vertically oriented conically shaped column is used as a fluidized bed bioreactor wherein biologically catalyzed reactions are conducted in a continuous manner. The column utilizes a packing material a support having attached thereto a biologically active catalytic material.

  3. Fischer-Tropsch synthesis from a low H/sub 2/:CO gas in a dry fluidized-bed system. Technical progress report, July 1, 1983-April 30, 1984

    SciTech Connect (OSTI)

    Liu, Y.A.; Squires, A.M.

    1984-05-01

    The objective of this project is to experimentally develop and demonstrate a novel dry fluidized-bed reactor system (called heat tray) for Fischer-Tropsch synthesis from a low H/sub 2/:CO gas. The new reactor involves conducting catalytic synthesis reactions primarily in a horizontal conveying zone, in which fine particles of iron catalyst are carried in a relatively dilute suspension by a large flow of reacting gas. A secondary reaction zone, in the form of a shallow fluidized bed of catalyst particles, is situated beneath the primary reaction zone. This shallow bed also has immersed horizontal heat-transfer tubes for removing reaction heat. A major thrust of the new reactor development is to prevent carbon deposits from forming on the iron catalyst, which cause deactivation and physical degradation. This is to be achieved by conducting the Fischer-Tropsch synthesis in an unsteady-state mode, particularly by alternately exposing the iron catalyst to a large flow of low H/sub 2/CO gas for a short period of time and to a small flow of H/sub 2/-rich gas for a long period of time. During the past ten months, numerous steady-state and unsteady-state Fischer-Tropsch synthesis experiments from a low H/sub 2/:CO gas were performed using a computer-controlled vibrofluidized microreactor and gas chromatographic (GC) system. The results have revealed specific directions for design and operational improvements of the microreactor system so as to effectively control the cycling of reactant gases during unsteady-state Fischer-Tropsch synthesis, and several modified microreactor systems have been constructed and tested.

  4. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect (OSTI)

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the TTT steam reforming process ability to destroy organics in the Tank 48 simulant and produce a soluble carbonate waste form. The ESTD was operated at varying feed rates and Denitration and Mineralization Reformer (DMR) temperatures, and at a constant Carbon Reduction Reformer (CRR) temperature of 950 C. The process produced a dissolvable carbonate product suitable for processing downstream. ESTD testing was performed in 2009 at the Hazen facility to demonstrate the long term operability of an integrated FBSR processing system with carbonate product and carbonate slurry handling capability. The final testing demonstrated the integrated TTT FBSR capability to process the Tank 48 simulant from a slurry feed into a greater than 99.9% organic free and primarily dissolved carbonate FBSR product slurry. This paper will discuss the SRNL analytical results of samples analyzed from the 2008 and 2009 THOR{reg_sign} steam reforming ESTD performed with Tank 48H simulant at HRI in Golden, Colorado. The final analytical results will be compared to prior analytical results from samples in terms of organic, nitrite, and nitrate destruction.

  5. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  6. Erosion-corrosion behavior of PFBC in-bed tubes

    SciTech Connect (OSTI)

    Tsumita, Yoshi; Namba, Kazuo; Kajigaya, Ichiro; Sonoya, Keiji

    1997-12-31

    In the design and operation of Pressurized Fluidized-Bed Combustion (PFBC) plant, it is important to investigate erosion-corrosion behavior of in-bed heat exchanger tubes, since such phenomena is complicated by interaction of erosion and corrosion due to high operating temperature. Investigations to clarify the erosion-corrosion mechanism of materials were performed by using laboratory test facility and PFBC pilot plant (3MW), to determine the specifications of in-bed tubes and assess their life for the first commercial PFBC plant having a capacity of 360MW. In the laboratory test, erosion-corrosion behavior of wide variety of coated materials, which include thermally sprayed coatings, diffusion coatings and hard metal claddings, and non-coated steel candidates for the typical boiler tubes were evaluated by using fluidized-bed type erosion test rig. The erosion tests were carried out in order to obtain the tanking of candidate materials. And test coupons of candidate materials were also inserted into IHI`s PFBC pilot plant in order to predict the material wastage of actual boiler environment. The following guidelines for selecting the appropriate materials and assessing the life of in-bed tubes were given by these test results. (1) At lower temperature, applying thermal spray coatings is the best solution to protect erosion damage. (2) At higher temperature, materials show enough erosion-corrosion resistance because of the formation of hard oxide scale on the surface. These results have been verified by long-term operational experience of the 71MW Wakamatsu PFBC, which is the first demonstration plant in Japan.

  7. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J.

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  8. Fluid bed material transfer method

    DOE Patents [OSTI]

    Pinske, Jr., Edward E.

    1994-01-01

    A fluidized bed apparatus comprising a pair of separated fluid bed enclosures, each enclosing a fluid bed carried on an air distributor plate supplied with fluidizing air from below the plate. At least one equalizing duct extending through sidewalls of both fluid bed enclosures and flexibly engaged therewith to communicate the fluid beds with each other. The equalizing duct being surrounded by insulation which is in turn encased by an outer duct having expansion means and being fixed between the sidewalls of the fluid bed enclosures.

  9. Boiler and steam generator corrosion: Fossil-fuel power plants. March 1977-December 1989 (A Bibliography from the NTIS data base). Report for March 1977-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. Hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 88 citations fully indexed and including a title list.)

  10. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for total constituents and durability tested as a granular waste form. A subset of the granular material was stabilized in a clay based geopolymer matrix at 42% and 65% FBSR loadings and durability tested as a monolith waste form. The 65 wt% FBSR loaded monolith made with clay (radioactive) was more durable than the 67-68 wt% FBSR loaded monoliths made from fly ash (non-radioactive) based on short term PCT testing. Long term, 90 to 107 day, ASTM C1308 testing (similar to ANSI/ANS 16.1 testing) was only performed on two fly ash geopolymer monoliths at 67-68 wt% FBSR loading and three clay geopolymer monoliths at 42 wt% FBSR loading. More clay geopolymers need to be made and tested at longer times at higher FBSR loadings for comparison to the fly ash monoliths. Monoliths made with metakaolin (heat treated) clay are of a more constant composition and are very reactive as the heat treated clay is amorphous and alkali activated. The monoliths made with fly ash are subject to the inherent compositional variation found in fly ash as it is a waste product from burning coal and it contains unreactive components such as mullite. However, both the fly ash and the clay based monoliths perform well in long term ASTM C1308 testing. Extensive testing and characterization of the granular and monolith material were made including the following American Society of Testing and Materials (ASTM) tests: ASTM C1285 testing (Product Consistency Test) of granular and monolithic waste forms; Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant  Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of clay; ASTM C1308 Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional Leaching from Cylindrical Waste Forms; Comparison of BSR non-radioactive waste forms to monolithic ESTD non-radioactive waste forms made from fly ash; Testing of BSR non-radioactive monoliths made from clay for comparison to non-radioactive monoliths made from fly ash; ASTM C39 Compressive Strength of Cylindrical Concrete Specimens; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms; EPA Manual SW-846 Method 1311, Toxicity Characteristic Leaching Procedure (TCLP); Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant; Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR non-radioactive waste forms.

  11. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  12. A 50-month gasifier mechanistic study and downstream unit process development program for the pressurized ash-agglomerating fluidized-bed gasification system

    SciTech Connect (OSTI)

    Haldipur, G.B.; Schmidt, D.K.; Smith, K.J.

    1989-03-01

    This technology development program scope included studies of those processes and components necessary to convert coal, oxidant and steam into a clean fuel gas. The configuration of the processes and components constitutes a Gasifier Island which is a key concept in the application of the KRW gasification and cleanup technologies. This Gasifier Island typically consists of process units that perform the following functions: feedstock preparation, gasification, desulfurization, heat recovery, particulate removal, and solid waste treatment. The processing has been conducted in a variety of gasifier operating modes including air-blown and oxygen-blown, both with and without in-bed desulfurization which includes injection of limestone or dolomite sorbent. Process configurations downstream of the gasifier have included recycle and non-recycle cyclones, sintered filters, and zinc ferrite fixed beds. Because of the developmental nature of the KRW technology program and the flexibility of the pilot plant itself, a wide range of gasifier-cleanup process configurations has been investigated. The KRW pilot plant program evaluated a system comprised of the following major process elements: gasifier and in-bed desulfurizer, particulate cleanup train, external sulfur polishing bed, and solid waste disposal system.

  13. Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 4, Task 5, Operation of PFH on beneficiated shale, Task 6, Environmental data and mitigation analyses and Task 7, Sample procurement, preparation, and characterization: Final report, September 1987--May 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    The objective of Task 5 (Operation of Pressurized Fluidized-Bed Hydro-Retorting (PFH) on Beneficiated Shale) was to modify the PFH process to facilitate its use for fine-sized, beneficiated Eastern shales. This task was divided into 3 subtasks: Non-Reactive Testing, Reactive Testing, and Data Analysis and Correlations. The potential environment impacts of PFH processing of oil shale must be assessed throughout the development program to ensure that the appropriate technologies are in place to mitigate any adverse effects. The overall objectives of Task 6 (Environmental Data and Mitigation Analyses) were to obtain environmental data relating to PFH and shale beneficiation and to analyze the potential environmental impacts of the integrated PFH process. The task was divided into the following four subtasks. Characterization of Processed Shales (IGT), 6.2. Water Availability and Treatment Studies, 6.3. Heavy Metals Removal and 6.4. PFH Systems Analysis. The objective of Task 7 (Sample Procurement, Preparation, and Characterization) was to procure, prepare, and characterize raw and beneficiated bulk samples of Eastern oil shale for all of the experimental tasks in the program. Accomplishments for these tasks are presented.

  14. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-09-18

    Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

  15. Super Boiler Update

    SciTech Connect (OSTI)

    2007-10-01

    This presentation from the 2007 American Boiler Manufacturers Association Manufacturers Conference provides an update of the First Generation Super Boiler.

  16. Radioactive demonstration of final mineralized waste forms for Hanford waste treatment plant secondary waste (WTP-SW) by fluidized bed steam reforming (FBSR) using the bench scale reformer platform

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

    2014-08-01

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as 137Cs, 129I, 99Tc, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150°C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW.

  17. Second-generation pressurized fluidized-bed combustion plant: Conceptual design and optimization of a second-generation PFB combustion plant. Phase 2, Annual report, October 1991--September 1992

    SciTech Connect (OSTI)

    Robertson, A.; Domeracki, W.; Newby, R.; Rehmat, A.; Horazak, D.

    1992-10-01

    After many years of experimental testing and development work, coal-fired pressurized fluidized bed (PFB) combustion combined-cycle power plants are moving toward reality. Under the US Department of Energy`s Clean Coal Technology Program, a 70-MWe PFB combustion retrofit, utilizing a 1525{degrees}F gas turbine inlet temperature, has been built and operated as a demonstration plant at the American Electric Power Company`s Tidd Plant in Brilliant, Ohio. As PFB combustion technology moves closer and closer to commercialization, interest is turning toward the development of an even more efficient and more cost-effective PFB combustion plant. The targeted goals of this ``second-generation`` plant are a 45-percent efficiency and a cost of electricity (COE) that is at least 20 percent lower than the COE of a conventional pulverized-coal (PC)-fired plant with stack gas scrubbing. In addition, plant emissions should be within New Source Performance Standards (NSPS) and the plant should have high availability, be able to burn different ranks of coal, and incorporate modular construction technologies. In response to this need, a team of companies led by Foster Wheeler Development Corporation (FWDC). The key components in the proposed second-generation plant are the carbonizer, CPFBC, ceramic cross-flow filter, and topping combustor. Unfortunately, none of these components has been operated at proposed plant operating conditions, and experimental tests must be conducted to explore/determine their performance throughout the proposed plant operating envelope. The major thrust of Phase 2 is to design, construct, test, and evaluate the performance of the key components of the proposed plant.

  18. Attrition resistant fluidizable reforming catalyst

    DOE Patents [OSTI]

    Parent, Yves O.; Magrini, Kim; Landin, Steven M.; Ritland, Marcus A.

    2011-03-29

    A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

  19. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  20. Analysis/control of in-bed tube erosion phenomena in the fluidized bed combustion (FBC) system. [Quarterly] technical progress report No. 11, April 1, 1995--June 30, 195

    SciTech Connect (OSTI)

    Lee, Seong W.

    1995-07-01

    This technical report summarizes the research work performed and progress achieved during the period of April 1, 1995 to June 30, 1995. In this study, the preliminary analysis of test data and understanding of the erosion behavior of resistant coatings for the in-bed tube materials were discussed for one the remedies of preventing in-bed tube erosion. The material wastage of the specimen was determined by weight and thickness loss measurements. The morphologies of the specimens were examined by scanning electron microscopy (SEM). For the material wastage. of the coating specimens, High Velocity Oxygen Fuel (HVOF) coatings (DS200) and the arc-sprayed coating at elevated temperature condition exhibited 2 to 3 times lower erosion wastage than that of AISI 1018 steel. For the angular dependence of erosion rate, two coatings exhibited the ductile behavior as demonstrated by higher wastage rates at shallow impact angle than that at steep impact angle. Tests will be continued and compared with erosion test results from higher velocity test conditions.

  1. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect (OSTI)

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan; Zhou, Chenn Q.

    2011-02-15

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  2. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    SciTech Connect (OSTI)

    Nguyen, C.T.

    1980-03-01

    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  3. Fluid-bed air-supply system

    DOE Patents [OSTI]

    Zielinski, Edward A.; Comparato, Joseph R.

    1979-01-01

    The air-supply system for a fluidized-bed furnace includes two air conduits for the same combustion zone. The conduits feed separate sets of holes in a distributor plate through which fluidizing air flows to reach the bed. During normal operation, only one conduit and set of holes is used, but the second conduit and set of holes is employed during start-up.

  4. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    SciTech Connect (OSTI)

    Sharp, William

    2011-12-01

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through the measured first melting point of fly ash deposits does not necessarily produce a step increase in corrosion rate. Corrosion rate typically accelerates at temperatures below the first melting temperature and mixed deposits may have a broad melting temperature range. Although the environment at a superheater tube surface is initially that of the ash deposits, this chemistry typically changes as the deposits mature. The corrosion rate is controlled by the environment and temperature at the tube surface, which can only be measured indirectly. Some results are counter-intuitive. Two boiler manufacturers and a consortium have developed models to predict fouling and corrosion in biomass boilers in order to specify tube materials for particular operating conditions. It would be very useful to compare the predictions of these models regarding corrosion rates and recommended alloys in the boiler environments where field tests will be performed in the current program. Manufacturers of biomass boilers have concluded that it is more cost-effective to restrict steam temperatures, to co-fire biofuels with high sulfur fuels and/or to use fuel additives rather than try to increase fuel efficiency by operating with superheater tube temperatures above melting temperature of fly ash deposits. Similar strategies have been developed for coal fired and waste-fired boilers. Additives are primarily used to replace alkali metal chloride deposits with higher melting temperature and less corrosive alkali metal sulfate or alkali aluminum silicate deposits. Design modifications that have been shown to control superheater corrosion include adding a radiant pass (empty chamber) between the furnace and the superheater, installing cool tubes immediately upstream of the superheater to trap high chloride deposits, designing superheater banks for quick replacement, using an external superheater that burns a less corrosive biomass fuel, moving circulating fluidized bed (CFB) superheaters from the convective pass into the hot recirculated fluidizing medium and adding an insulating layer to superheater tubes to raise their surface temperature above the dew point temperature of alkali chlorides. These design changes offer advantages but introduce other challenges. For example, operating with superheater temperatures above the dew point of alkali chlorides could require the use of creep-resistant tube alloys and doesn't eliminate chloride corrosion. Improved test methods that can be applied within this project include automated dimensional metrology to make a statistical analysis of depth of penetration and corrosion product thickness, and simultaneous thermal analysis measurements to quantify the melting of complex ashes and avoid the unreliability of the standard ash fusion test. Other important developments in testing include the installation of individually-temperature-controlled superheater loops for corrosion testing in operating boilers and temperature gradient testing.

  5. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  6. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  7. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals ...

  8. Fluidized Bed Technology - Overview | Department of Energy

    Energy Savers [EERE]

    The tumbling action, much like a bubbling fluid, provides more effective chemical ... flue gases into contact with a sulfur-absorbing chemical, such as limestone or dolomite. ...

  9. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    The char residue is not wasted; it can also be used to generate electricity by fueling ... plant designed for the co-production of hydrogen and electricity will also be determined. ...

  10. Fluidized bed paint stripping and sludge burning

    SciTech Connect (OSTI)

    Bhatia, J.; Staffin, H.K.

    1986-01-01

    High volume automated painting, as encountered in the painting of automobiles and appliances, requires that the item being painted be positioned in a conveying frame or fixture so that the painting machine or robot achieves a reproducible, high quality paint job. These conveying frames or fixtures are extensive fabrications carefully designed to position and support the item being painted. In the case of automotive painting, they are rather large and involve substantial weights, because they must be capable of supporting and positioning auto bodies and large sub-assemblies.

  11. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use ...

  12. DEVELOPMENT OF PRESSURIZED CIRCULATIONG FLUIDIZED BED PARTIAL...

    Office of Scientific and Technical Information (OSTI)

    Hence, PGM is a robust building block that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use ...

  13. State-of-the-art review and report on critical aspects and scale-up considerations in the design of fluidized-bed reactors. Final report on Phase 1

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Information is given on the design of distributor plates and opening geometry to provide uniform flow over the reactor area. The design of granular bed filters is also considered. Pressure drops and particle size in the bed are discussed. (LTN)

  14. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  15. Spray-dried fluid-bed sorbents tests - CMP-5

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1995-12-01

    The objective of this study is to determine the feasibility of manufacturing highly reactive and attrition-resistant zinc titanate sorbents by spray drying, suitable for bubbling (conventional) as well as transport-type fluidized-bed reactor systems.

  16. CIRCULATING MOVING BED COMBUSTION PROOF OF CONCEPT

    SciTech Connect (OSTI)

    Jukkola, Glen

    2010-06-30

    Circulating Moving Bed (CMB) combustion technology has its roots in traditional circulating fluidized bed technology and involves a novel method of solid fuel combustion and heat transfer. CMB technology represents a step change in improved performance and cost relative to conventional PC and FBC boilers. The CMB heat exchanger preheats the energy cycle working fluid, steam or air, to the high temperature levels required in systems for advanced power generation. Unique features of the CMB are the reduction of the heat transfer surfaces by about 60% as a result of the enhanced heat transfer rates, flexibility of operation, and about 30% lower cost over existing technology. The CMB Phase I project ran from July 2001 through March 2003. Its objective was to continue development of the CMB technology with a series of proof of concept tests. The tests were conducted at a scale that provided design data for scale up to a demonstration plant. These objectives were met by conducting a series of experiments in ALSTOM Power’s Multi-use Test Facility (MTF). The MTF was modified to operate under CMB conditions of commercial interest. The objective of the tests were to evaluate gas-to-solids heat transfer in the upper furnace, assess agglomeration in the high temperature CMB bubbling bed, and evaluate solids-to-tube heat transfer in the moving bed heat exchanger. The Phase I program results showed that there are still some significant technical uncertainties that needed to be resolved before the technology can be confidently scaled up for a successful demonstration plant design. Work remained in three primary areas: • scale up of gas to solid heat transfer • high temperature finned surface design • the overall requirements of mechanical and process design. The CMB Phase II workscope built upon the results of Phase I and specifically addressed the remaining technical uncertainties. It included a scaled MTF heat transfer test to provide the necessary data to scale up gas-to-solids heat transfer. A stress test rig was built and tested to provide validation data for a stress model needed to support high temperature finned surface design. Additional cold flow model tests and MTF tests were conducted to address mechanical and process design issues. This information was then used to design and cost a commercial CMB design concept. Finally, the MBHE was reconfigured into a slice arrangement and tested for an extended duration at a commercial CFB plant.

  17. Minimize Boiler Blowdown

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Second Generation Super Boiler Technology for Watertube Boilers

    SciTech Connect (OSTI)

    2007-07-01

    This factsheet describes a research project to develop a high-pressure watertube boiler system that incorporates and improves upon the capabilities of the firetube Super Boiler system.

  19. Promising Technology: Condensing Gas Boilers

    Broader source: Energy.gov [DOE]

    Condensing boilers achieve higher efficiencies than conventional boilers by capturing the latent heat from water vapor contained in the flue gases.

  20. Biomass Boiler for Food Processing Applications | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Boiler for Food Processing Applications Biomass Boiler for Food Processing Applications Biomass Boiler Uses a Combination of Wood Waste and Tire-Derived Fuel In 2011, the ...

  1. Covered Product Category: Commercial Boilers | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... mass boiler up to operating temperature, using low-mass boilers will reduce energy consumption. ... Water treatment can prolong boiler life as well as increase its efficiency. ...

  2. Boiler Combustion Control and Monitoring System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Products & Technologies Technology Deployment Boiler Combustion Control and Monitoring System Boiler Combustion Control and Monitoring System Technical staff are making ...

  3. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    SciTech Connect (OSTI)

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  4. Boiler MACT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combined Heat & Power Deployment » Boiler MACT Boiler MACT DOE currently provides technical assistance on combined heat and power (CHP) technologies to commercial and industrial facilities through its seven regional CHP Technical Assistance Partnerships (CHP TAPs). Starting in January 2013, DOE supplemented this effort by providing site-specific technical and cost assistance to the major source facilities affected by the Boiler Maximum Achievable Control Technology (Boiler MACT) rule.

  5. Recover Heat from Boiler Blowdown, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Recover Heat from Boiler Blowdown Heat can be recovered from boiler blowdown by using a heat exchanger to preheat boiler makeup water. Any boiler with continuous blowdown ...

  6. " "," ",,," Steam Turbines Supplied by Either Conventional or...

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Relative Standard Errors for Table 8.3;" " Unit: Percents." " "," ",,," Steam Turbines Supplied by Either Conventional or Fluidized Bed Boilers",,,"Conventional Combusion ...

  7. Second Generation PFBC Systems R&D (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; FLUIDIZED BED BOILERS; BURNERS; GAS TURBINES; PILOT PLANTS; STEAM GENERATION; SULFUR; AIR POLLUTION CONTROL; DESIGN Word Cloud More Like This ...

  8. Second-Generation PFBC Systems R&D (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 01 COAL, LIGNITE, AND PEAT; FLUIDIZED BED BOILERS; BURNERS; EFFICIENCY; GAS TURBINES; PILOT PLANTS; STEAM GENERATION; SULFUR; AIR POLLUTION CONTROL; DESIGN Word Cloud More ...

  9. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Nitrogen Oxides Uncontrolled Emission Factors Fuel, Code, Source and Emission Units Combustion System Type / Firing Configuration Tangential Boiler All Other Boiler Types Fuel EIA Fuel Code Source and Tables (As Appropriate) Emissions Units Lbs = Pounds MMCF = Million Cubic Feet MG = Thousand Gallons Cyclone Firing Boiler Fluidized Bed Firing Boiler Stoker Boiler Dry-Bottom Boilers Wet-Bottom Boilers Dry-Bottom Boilers Wet-Bottom Boilers Combustion Turbine Internal Combustion Engine

  10. High-pressure three-phase fluidization: Hydrodynamics and heat transfer

    SciTech Connect (OSTI)

    Luo, X.; Jiang, P.; Fan, L.S.

    1997-10-01

    High-pressure operations are common in industrial applications of gas-liquid-solid fluidized-bed reactors for resid hydrotreating, Fischer-Tropsch synthesis, coal methanation, methanol synthesis, polymerization, and other reactions. The phase holdups and the heat-transfer behavior were studied experimentally in three-phase fluidized beds over a pressure range of 0.1--15.6 MPa. Bubble characteristics in the bed are examined by direct flow visualization. Pressure effects on the bubble coalescence and breakup are analyzed mechanistically. The study indicates that the pressure affects the hydrodynamics and heat-transfer properties of a three-phase fluidized bed significantly. The average bubble size decreases and the bubble-size distribution becomes narrower with an increase in pressure. The bubble-size reduction leads to an increase in the transition gas velocity from the dispersed bubble regime to the coalesced bubble regime, an increase in the gas holdup, and a decrease in the liquid and solids holdups. The pressure effect is insignificant above 6 MPa. The heat-transfer coefficient between an immersed surface and the bed increases to a maximum at pressure 6--8 MPa and then decreases with an increase in pressure at a given gas and liquid flow rate. This variation is attributed to the pressure effects on phase holdups and physical properties of the gas and liquid phases. A mechanistic analysis revealed that the major heat-transfer resistance in high-pressure three-phase fluidized beds resides in a liquid film surrounding the heat-0transfer surface. An empirical correlation is proposed to predict the heat-transfer coefficient under high-pressure conditions.

  11. Super Boiler 2nd Generation Technology for Watertube Boilers

    SciTech Connect (OSTI)

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  12. Engineering development of advanced coal-fired low-emissions boiler system. Phase II subsystem test design and plan - an addendum to the Phase II RD & T Plan

    SciTech Connect (OSTI)

    1995-05-01

    Shortly after the year 2000 it is expected that new generating plants will be needed to meet the growing demand for electricity and to replace the aging plants that are nearing the end of their useful service life. The plants of the future will need to be extremely clean, highly efficient and economical. Continuing concerns over acid rain, air toxics, global climate changes, ozone depletion and solid waste disposal are expected to further then regulations. In the late 1980`s it was commonly believed that coal-fired power plants of the future would incorporate either some form of Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBS) technologies. However, recent advances In emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements In steam turbine and cycle design have clearly indicated that pulverized coal technology can continue to be competitive In both cost and performance. In recognition of the competitive potential for advanced pulverized coal-fired systems with other emerging advanced coal-fired technologies, DOE`s Pittsburgh Energy Technology Center (PETC) began a research and development initiative In late 1990 named, Combustion 2000, with the intention of preserving and expanding coal as a principal fuel In the Generation of electrical power. The project was designed for two stages of commercialization, the nearer-term Low Emission Boiler System (LEBS) program, and for the future, the High Performance Power System (HIPPS) program. B&W is participating In the LEBS program.

  13. A study of two-body forces in fluidization

    SciTech Connect (OSTI)

    Kashiwa, B. A.; Rauenzahn, Rick M.

    2004-01-01

    The effect of two-body forces on the structure of dynamic waves in fluidized beds is studied, with particular emphasis on expansion waves. Averaged equations of motion are used for the study, so the media appear to be interpenetrating continua. Both inertial and viscous two-body effects are considered for incompressible materials fluidized by an incompressible fluid. Inertial effects are included in the averaged momentum exchange force, using exact (classical) results for the potential flow generated by the motion of one submerged body relative to another body. Viscous effects are represented, in the limit of zero relative Reynolds number, by solutions to Stokes equations for the two-body problem. For simple one-dimensional motion the inertial force is repulsive always, giving a positive compressibility to the dispersed field total density; the force is of such a magnitude that the single-pressure continuum equations are unconditionally hyperbolic. The corresponding 1-D viscous force is attractive when the bodies move apart, and therefore introduces a negative compressibility to the dispersed field. Competition between the two-body inertial and viscous forces ultimately determines the nature of dynamic waves in a given fluidization system.

  14. Boiler Maximum Achievable Control Technology (MACT) Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact Sheet, April 2015 Boiler Maximum Achievable Control Technology (MACT) Technical Assistance - Fact ...

  15. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    A flexible whip suspended in a hopper is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  16. The Anaerobic Fluidized Bed Membrane Bioreactor for Energy-Efficient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 76,000 m 3 day recycled water * Irrigates 5,000 hectares * Through anaerobic biosolids treatment and cogeneration, produces 50% of WWTP's energy needs * No energy wasted ...

  17. EIS-0289: JEA Circulating Fluidized Bed Combustor Project

    Broader source: Energy.gov [DOE]

    This EIS assesses environmental issues associated with constructing and demonstrating a project that would be cost-shared by DOE and JEA (formerly the Jacksonville Electric Authority) under the...

  18. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)

    Energy Savers [EERE]

    Commercialization and Business Innovation Technology Commercialization and Business Innovation The SunShot Technology to Market subprogram aims to select award recipients whose innovative ideas will benefit the solar market beyond the 2020 SunShot goal. The program goal is for at least 50% of the funded solutions to have a lasting impact in the marketplace. Learn more about our technology commercialization and business innovation funding programs: SunShot Incubator Program Small Business

  19. Particle Receiver Integrated with Fluidized Bed (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01

    National Renewable Energy Laboratory is one of the 2012 SunShot CSP R&D awardees for their advanced receivers. This fact sheet explains the motivation, description, and impact of the project.

  20. Project Profile: Particle Receiver Integrated with a Fluidized Bed

    Broader source: Energy.gov [DOE]

    The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), are developing a novel receiver that uses falling particles instead of liquid for the heat-transfer fluid (HTF). The research team aims to build a receiver that operates at higher temperatures and efficiencies than the current state-of-the-art technology.

  1. Hydrodynamics of circulating fluidized beds: Kinetic theory approach...

    Office of Scientific and Technical Information (OSTI)

    GAS; TURBULENCE; VISCOSITY; DIFFERENTIAL EQUATIONS; EQUATIONS; FLUID FLOW; FLUIDS; GASES; MECHANICS; PARTIAL DIFFERENTIAL EQUATIONS; PYROLYSIS PRODUCTS 014000* -- Coal, Lignite, ...

  2. LIQUID-FLUIDIZED-BED HEAT' EXCHANGER FLOW DISTRIBUTION MODELS

    Office of Scientific and Technical Information (OSTI)

    ... T h i s paper reports r e s u l t s from f u l l scale instrumented plexiglass " u n i t c e l l " shell-and-tube heat exchanger models. These models allowed visual observation of ...

  3. Technical evaluation: pressurized fluidized-bed combustion technology...

    Office of Scientific and Technical Information (OSTI)

    COMBUSTORS; TECHNOLOGY ASSESSMENT; ECONOMICS; ENVIRONMENTAL IMPACTS; PERFORMANCE; AIR POLLUTION CONTROL; DESIGN; EFFICIENCY; GAS TURBINES; HOT GAS CLEANUP; RESEARCH PROGRAMS; ...

  4. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    & EC Spatial Imaging via X-ray Micro-tomography Computed Tomography Changes in Pore Structure Moisture Distribution XMT-CT Scan Void Space (Black), Particles (White), Water...

  5. Enhanced Productivity of Chemical Processes Using Dense Fluidized Beds

    SciTech Connect (OSTI)

    2004-07-01

    Enabling Computational Technology Will Directly Impact the Energy Requirements of Catalytic and Non-Catalytic Reaction Processes.

  6. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming...

    Office of Environmental Management (EM)

    ... Waste HTF High Temperature Filter INL Idaho National Laboratory IWTU Integrated Waste Treatment Unit MACT Maximum ... This is relatively "low fidelity" compared with the eventual ...

  7. Fast pyrolysis of sweet soghum bagasse in a fluidized bed

    SciTech Connect (OSTI)

    Palm, M.; Peacocke, C.; Bridgewater, A.V.; Piskorz, J.; Scott, D.S.

    1993-12-31

    Samples of Italian sorghum bagasse were dried and ground and then pyrolyzed in the Waterloo Fast Pyrolysis bench scale reactor unit. Results were typical of agricultural grasses of this kind, and resembled those obtained from similar tests of sugar cane bagasse. A maximum liquid yield (dry feed basis) of 68% by weight of dry feed was achieved, with a corresponding char yield (ash included) of 16%. The high ash content of the bagasse (9.2%) gave a char with a very high ash content ({approx}50%), with calcium as the most abundant cation. Yields of hydroxyacetaldehyde were comparable to those obtained from softwoods. Deionized bagasse gave significant yields of anhydrosugars on pyrolysis. Sorghum bagasse appears to be a suitable feedstock, either for pyrolysis to yield an alternative fuel oil, or after pretreatment and pyrolysis, to yield a solution of fermentable sugars.

  8. Process for the conversion of alcohols and oxygenates to hydrocarbons in a turbulent fluid bed reactor

    SciTech Connect (OSTI)

    Avidan, A. A.; Kam, A. Y.

    1985-04-23

    Improvements in converting C/sub 1/-C/sub 3/ monohydric alcohols, particularly methanol, related oxygenates of said alcohols and/or oxygenates produced by Fischer-Tropsch synthesis to light olefins, gasoline boiling range hydrocarbons and/or distillate boiling range hydrocarbons are obtained in a fluidized bed of ZSM-5 type zeolite catalyst operating under conditions effective to provide fluidization in the turbulent regime.

  9. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, James P.; Scahill, John W.

    1986-01-01

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  10. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    1984-06-27

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  11. Consider Installing High-Pressure Boilers with Backpressure Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators When specifying a new boiler, consider a high-pressure boiler with a backpressure steam ...

  12. Minimize Boiler Short Cycling Losses, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Minimize Boiler Short Cycling Losses Boiler "short cycling" occurs when an oversized boiler quickly satisfes process or space heating demands, and then shuts down until heat is ...

  13. Improve Your Boiler's Combustion Efficiency, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency Combustion Efficiency Operating your boiler ... due to the increased fue gas fow-thus lowering the overall boiler fuel-to-steam effciency. ...

  14. Minimize Boiler Short Cycling Losses | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minimize Boiler Short Cycling Losses Minimize Boiler Short Cycling Losses This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial...

  15. Particle Receiver Integrated with Fludized Bed | Department of Energy

    Office of Environmental Management (EM)

    Particle Receiver Integrated with Fludized Bed Particle Receiver Integrated with Fludized Bed This fact sheet describes a project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program to NREL which features a particle receiver with a fluidized bed. The research team is working to develop a technology that uses gas/solid, two-phase flow as a heat-transfer fluid and separated, stable, solid particles as a thermal energy storage medium. This project provides a pathway

  16. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  17. Furnaces and Boilers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat & Cool » Home Heating Systems » Furnaces and Boilers Furnaces and Boilers Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Upgrading to a high efficiency furnace or boiler is an effective way to save money on home heating. Most U.S. homes are heated with either furnaces or boilers. Furnaces heat air and distribute the heated air through the house using ducts. Boilers heat water, and provide either hot water or steam for heating. Steam

  18. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Many buildings have their own boilers, while other buildings have steam or hot water piped in from a central plant. Commercial boilers are manufactured for high- or low-pressure ...

  19. New Boilers, Big Savings for Minnesota County

    Broader source: Energy.gov [DOE]

    Why simply replacing the boilers at the Sherburne County Courthouse in Minnesota is going to save big.

  20. Development of the first demonstration CFB boiler for gas and steam cogeneration

    SciTech Connect (OSTI)

    Fang, M; Luo, Z.; Li, X.; Wang, Q.; Shi, Z.; Ni, M.; Cen, K.

    1997-12-31

    To solve the shortage of gas and steam supply in the small towns of the country, a new gas steam cogeneration system has been developed. On the basis of the fundamental research on the system, a demonstration gas steam cogeneration system has been designed. As the phase 1 of the project, a 75t/h demonstration CFB boiler for gas steam cogeneration has been erected and operated at Yangzhong Thermal Power Plant of China. This paper introduces the first 75t/h demonstration CFB boiler for gas steam cogeneration. Due to the need of gas steam cogeneration process, the boiler has the features of high temperature cyclone separation, high solid recycle ratio, staged combustion and an external heat exchanger adjusting bed temperature and heat load. The operation results show that the boiler has wide fuel adaptability and the heating value of the coal changes from 14MJ/Kg to 25MJ/Kg. The heat load changes from 85t/h to 28t/h while steam parameter is maintained at the normal conditions. The combustion efficiency of the boiler attain 98%. The boiler design and operation experiences may be a guide to the design and operation of larger CFB units in the future.

  1. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  2. Sootblowing optimization for improved boiler performance

    DOE Patents [OSTI]

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  3. Covered Product Category: Commercial Boilers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance and Federal efficiency requirements for commercial boilers, which is a FEMP-designated product category. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  4. Overall review of work carried out at Grimethorpe in collaboration with US DOE and EPRI and under IEA Agreement on PFBC (pressurised fluidised bed combustion), 1985-1987

    SciTech Connect (OSTI)

    Not Available

    1990-06-01

    Between 1984 and 1988, the Grimethorpe Pressurized Fluidized Bed Combustion (PFBC) Facility was operated for the UK BCC/CEGB Joint Programme on PFBC. Additional funding was obtained from the US Department of Energy (for investigation of operation using a wet slurry feed system), EPRI (for testing an advanced gas filtration device) and as an extension of the IEA Agreement in PFBC (for design of the wet slurry feed system, and further studies into the use of wet slurry). Co-operation with the US DOE extended to the investigation of metal wastage in a new tube bank, Tube Bank E', involving a US boiler manufacture, Foster Wheeler Development Corporation. The report outlines the results of this collaborative work including combustor performance, operation and performance of the wet slurry feeding system, operation and performance of the EPRI HTHP Filter, and performance of research instrumentation. It also summarizes materials aspects of the collaborative work, including those aspects of the tube bank metal wastage investigation which can be released into the public domain. 39 refs., 27 figs., 17 tabs.

  5. Boiler - tuning basics, part 1

    SciTech Connect (OSTI)

    Leopold, T.

    2009-03-15

    Tuning power plant controls takes nerves of steel and an intimate knowledge of plant systems gained only by experience. Tuning controls also requires equal parts art and science, which probably is why there are so few tuning experts in the power industry. In part 1 of a two-part series, the author explores a mix of the theoretical and practical aspects of tuning boiler control. 5 figs.

  6. COAL CLEANING VIA LIQUID-FLUIDIZED CLASSIFICAITON (LFBC) WITH SELECTIVE SOLVENT SWELLING

    SciTech Connect (OSTI)

    J. M. Calo

    2000-12-01

    The concept of coal beneficiation due to particle segregation in water-fluidized beds, and its improvement via selective solvent-swelling of organic material-rich coal particles, was investigated in this study. Particle size distributions and their behavior were determined using image analysis techniques, and beneficiation effects were explored via measurements of the ash content of segregated particle samples collected from different height locations in a 5 cm diameter liquid-fluidized bed column (LFBC). Both acetone and phenol were found to be effective swelling agents for both Kentucky No.9 and Illinois No.6 coals, considerably increasing mean particle diameters, and shifting particle size distributions to larger sizes. Acetone was a somewhat more effective swelling solvent than phenol. The use of phenol was investigated, however, to demonstrate that low cost, waste solvents can be effective as well. For unswollen coal particles, the trend of increasing particle size from top to bottom in the LFBC was observed in all cases. Since the organic matter in the coal tends to concentrate in the smaller particles, the larger particles are typically denser. Consequently, the LFBC naturally tends to separate coal particles according to mineral matter content, both due to density and size. The data for small (40-100 {micro}m), solvent-swollen particles clearly showed improved beneficiation with respect to segregation in the water-fluidized bed than was achieved with the corresponding unswollen particles. This size range is quite similar to that used in pulverized coal combustion. The original process concept was amply demonstrated in this project. Additional work remains to be done, however, in order to develop this concept into a full-scale process.

  7. Metallurgical failures in fossil fired boilers

    SciTech Connect (OSTI)

    French, D.N.

    1993-01-01

    This book provides a comprehensive catalog of the types of metallurgical failures common to boilers. The author uses actual case histories of boiler shutdowns, and documents the full range of causes of boiler tube failure. A blueprint is provided for cutting maintenance costs and upgrading the efficiency and reliability of any power plant operation. Individual chapters are processed separately for inclusion in the appropriate data bases.

  8. Minimize Boiler Blowdown - Steam Tip Sheet #9

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  9. Upgrade Boilers with Energy-Efficient Burners

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP steam tip sheet on upgrading boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  10. Stress-Assisted Corrosion in Boiler Tubes

    SciTech Connect (OSTI)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  11. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, Raghubir P.; Gangwal, Santosh K.; Jain, Suresh C.

    1993-01-01

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

  12. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1993-10-19

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 [mu]m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO[sub 3]; and then indurating it at 800 to 900 C for a time sufficient to produce attrition-resistant granules.

  13. Method of regulating the amount of underfire air for combustion of wood fuels in spreader-stroke boilers

    DOE Patents [OSTI]

    Tuttle, Kenneth L.

    1980-01-01

    A method of metering underfire air for increasing efficiency and reducing particulate emissions from wood-fire, spreader-stoker boilers is disclosed. A portion of the combustion air, approximately one pound of air per pound of wood, is fed through the grate into the fuel bed, while the remainder of the combustion air is distributed above the fuel in the furnace, and the fuel bed is maintained at a depth sufficient to consume all oxygen admitted under fire and to insure a continuous layer of fresh fuel thereover to entrap charred particles inside the fuel bed.

  14. Boiler efficiency calculation for multiple fuel burning boilers

    SciTech Connect (OSTI)

    Khodabakhsh, F.; Munukutla, S.; Clary, A.T.

    1996-12-31

    A rigorous method based on the output/loss approach is developed for calculating the coal flow rate for multiple fuel burning boilers. It is assumed that the ultimate analyses of all the fuels are known. In addition, it is assumed that the flow rates of all the fuels with the exception of coal are known. The calculations are performed iteratively, with the first iteration taking into consideration coal as the only fuel. The results converge to the correct answer after a few number of iterations, typically four or five.

  15. Gas-Fired Boilers and Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural gas supplies depend on having a natural gas distribution system in your area, and ... Steam boilers benefit from vent dampers more than hot water boilers, and bigger boilers ...

  16. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces May 16, 2013 - 3:15pm Addthis Diagram of an oil boiler. New tanks are generally double-wall or have a spill container...

  17. Improve Your Boiler's Combustion Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system. STEAM TIP SHEET 4 Improve...

  18. Minimize Boiler Blowdown, Energy Tips: STEAM, Steam Tip Sheet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Examine operating practices for boiler feedwater and blowdown rates developed by ... Minimize Boiler Blowdown Minimizing your blowdown rate can substantially reduce energy ...

  19. Return Condensate to the Boiler, Energy Tips: STEAM, Steam Tip...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduce operating costs through maximizing the return of hot condensate to the boiler. ... Return Condensate to the Boiler When steam transfers its heat in a manufacturing process, ...

  20. Return Condensate to the Boiler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Return Condensate to the Boiler (January 2012) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Minimize Boiler Blowdown ...

  1. Recovery of Water from Boiler Flue Gas Using Condensing Heat...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers Citation Details In-Document Search Title: Recovery of Water from Boiler Flue Gas Using ...

  2. Winning the fight against boiler tube failure

    SciTech Connect (OSTI)

    Cohen, J.; Dooley, B.

    1986-12-01

    Eliminating boiler tube failures could be worth $5 billion a year to the electric power industry. The causes and cures for the great majority of these ubiquitous failures are now known, with implications for change ranging from senior management to the maintenance crew. Methods for preventing boiler tube failure are discussed.

  3. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    SciTech Connect (OSTI)

    Baxter, Larry L.

    2008-06-09

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

  4. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  5. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  6. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L.; Foote, John P.

    1995-01-01

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  7. Clean Boiler Waterside Heat Transfer Surfaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Boiler Waterside Heat Transfer Surfaces Clean Boiler Waterside Heat Transfer Surfaces This tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #7 PDF icon Clean Boiler Waterside Heat Transfer Surfaces (April 2012) More Documents & Publications Consider Installing Turbulators on Two- and Three-Pass Firetube Boilers Improving Steam System

  8. Minimize Boiler Short Cycling Losses | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Short Cycling Losses Minimize Boiler Short Cycling Losses This tip sheet on minimizing boiler short cycling losses provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #16 PDF icon Minimize Boiler Short Cycling Losses (January 2012) More Documents & Publications 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking Upgrade Boilers with Energy-Efficient Burners Building America

  9. Paducah Package Steam Boilers to Provide Efficiency, Environmental Benefits

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Package Steam Boilers to Provide Efficiency, Environmental Benefits Paducah Package Steam Boilers to Provide Efficiency, Environmental Benefits October 29, 2015 - 12:10pm Addthis An aerial view of the package boilers installed into the site’s existing steam system. An aerial view of the package boilers installed into the site's existing steam system. Pipefitters Mike Askren, left, and Ron Parrot install the water inlet on one of the package boilers. Pipefitters

  10. Furnace and Boiler Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2:50pm Addthis Furnaces heat air and distribute the heated air through a building using ducts; boilers heat water, providing either hot water or steam for heating. Furnaces...

  11. Clean Boiler Waterside Heat Transfer Surfaces

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  12. Boiler scale prevention employing an organic chelant

    DOE Patents [OSTI]

    Wallace, Steven L.; Griffin, Jr., Freddie; Tvedt, Jr., Thorwald J.

    1984-01-01

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  13. Clean coal reference plants: Pulverized encoal PDF fired boiler. Topical report

    SciTech Connect (OSTI)

    1995-12-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications. This report describes the plant design.

  14. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect (OSTI)

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  15. Fluidized wall for protecting fusion chamber walls

    DOE Patents [OSTI]

    Maniscalco, James A.; Meier, Wayne R.

    1982-01-01

    Apparatus for protecting the inner wall of a fusion chamber from microexplosion debris, x-rays, neutrons, etc. produced by deuterium-tritium (DT) targets imploded within the fusion chamber. The apparatus utilizes a fluidized wall similar to a waterfall comprising liquid lithium or solid pellets of lithium-ceramic, the waterfall forming a blanket to prevent damage of the structural materials of the chamber.

  16. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Sulfur Dioxide Uncontrolled Emission Factors Fuel, Code, Source and Emission Units Combustion System Type / Firing Configuration Fuel EIA Fuel Code Source and Tables (As Appropriate) Emissions Units Lbs = Pounds MMCF = Million Cubic Feet MG = Thousand Gallons Cyclone Firing Boiler Fluidized Bed Firing Boiler Stoker Boiler Tangential Firing Boiler All Other Boiler Types Combustion Turbine Internal Combustion Engine Distillate Fuel Oil* DFO Source: 2, Table 3.1-2a, 3.4-1 & 1.3-1 Lbs per MG

  17. Method for fluidizing and coating ultrafine particles, device for fluidizing and coating ultrafine particles

    DOE Patents [OSTI]

    Li, Jie; Liu, Yung Y

    2015-01-20

    The invention provides a method for dispersing particles within a reaction field, the method comprising confining the particles to the reaction field using a standing wave. The invention also provides a system for coating particles, the system comprising a reaction zone; a means for producing fluidized particles within the reaction zone; a fluid to produce a standing wave within the reaction zone; and a means for introducing coating moieties to the reaction zone. The invention also provides a method for coating particles, the method comprising fluidizing the particles, subjecting the particles to a standing wave; and contacting the subjected particles with a coating moiety.

  18. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  19. CONTINUED DEVELOPMENT OF THE ROTARY COMBUSTOR FOR REFIRING PULVERIZED COAL BOILERS

    SciTech Connect (OSTI)

    Murray F. Abbott; Jamal B. Mereb; Simon P. Hanson; Michael J. Virr

    2000-11-01

    The Rotary Combustor is a novel concept for burning coal with low SO{sub 2} and NO{sub x} emissions. It burns crushed coal in a fluid bed where the bed is maintained in a rotating drum by centripetal force. Since this force may be varied, the combustor may be very compact, and thus be a direct replacement for a p.c. burner on existing boilers. The primary objective of this project is to demonstrate that a typical industrial boiler can be refired with the modified prototype Rotary Combustor to burn Ohio high-sulfur coal with low emissions of SO{sub 2} and NO{sub x}. The primary problem that must be resolved to demonstrate sustained operations with coal is temperature control in the rotating fluid bed. The prototype Rotary Combustor was assembled and installed on the T-850P CNB boiler at the CONSOL Energy site in South Park, Pennsylvania. Several design improvements were investigated and implemented during the assembly to improve the prototype Rotary Combustor operations compared to prior tests at Detroit Stoker in Monroe, Michigan. An Operating Manual and Safety Review were completed. The shakedown test phase was initiated. Two major problems were initially encountered: binding of the rotating drum at operating temperatures, and reduced fluid-bed pressure drop after short periods of operation. Plating the brush seal rotary land ring with a chrome carbide plasma spray and lubricating the seal prior to each test sufficiently resolved these problems to permit a limited number of operations tests. Unlike previous tests at Detroit Stoker, sustained operation of the prototype Rotary Combustor was accomplished burning a high-Btu fuel, metallurgical coke. The prototype Rotary Combustor was operated with coke in gasifier mode on two occasions. Fluid-bed temperature spiking was minimized with manual control of the feeds (coke, air and steam), and no clinker formation problems were encountered in either test. Emission levels of NO{sub x} were measured at about 270 ppmv which were higher those targeted for the device which were 100 ppmv. This was assumed to be because of the aforementioned temperature spiking. The primary operating problem remains control of the fluid-bed temperature. Although improvements were made, steam flow control was manual, and very coarse. To accomplish this will require finer control of the steam flow to the rotary drum air plenum, and development of an algorithm for automatic control using the Moore APACS{trademark}. This is the recommended succeeding step in the development of the Rotary Combustor for industrial or utility use.

  20. Boiler MACT Technical Assistance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  1. Ultra-Supercritical Pressure CFB Boiler Conceptual Design Study...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Ultra-Supercritical Pressure CFB Boiler ... Although CFB boilers as large as 300 MWe are now in operation, they are drum type, ...

  2. Upgrade Boilers with Energy-Efficient Burners, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Background The purpose of the burner is to mix molecules of fuel with molecules of air. A boiler will run only as well as the burner performs. A poorly designed boiler with an ...

  3. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler You are accessing a ...

  4. Conceptual Design of Supercritical O2-Based PC Boiler (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Conceptual Design of Supercritical O2-Based PC Boiler Citation Details In-Document Search Title: Conceptual Design of Supercritical O2-Based PC Boiler No abstract ...

  5. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  6. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  7. Slag monitoring for utility boilers: Final report

    SciTech Connect (OSTI)

    Anson, D.; Barrett, R.E.; Litt, R.D.; Paisley, M.A.

    1988-04-01

    This report provides a detailed description of commercially available slag monitoring techniques and some developing concepts for slag monitoring. Slag monitoring is currently being evaluated by several organizations as a means of controlling and optimizing sootblowers. The potential benefits from slag monitoring can represent significant savings in utility operating costs. Six types of heat flux meters are described as they are presently being used in utility boilers. These direct monitoring techniques determine local conditions within the furnace. Each application is described with current results and future plans. Boiler heat balance models provide an indirect technique for monitoring the general cleanliness/fouling of major boiler sections. Each model is described with current results at a representative installation. Several developing concepts of slag monitoring are described and evaluated. Four promising concepts, acoustic attenuation, a simplified heat balance model, sonic pyrometry, and ultrasonic pulse reflection, are recommended for further development and evaluation. 16 refs., 34 figs., 4 tabs.

  8. CHP Integrated with Packaged Boilers - Presentation by CMCE, Inc., June

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2011 | Department of Energy Integrated with Packaged Boilers - Presentation by CMCE, Inc., June 2011 CHP Integrated with Packaged Boilers - Presentation by CMCE, Inc., June 2011 Presentation on CHP Integrated with Packaged Boilers, given by Carlo Castaldini of CMCE, Inc., at the U.S. DOE Industrial Distributed Energy Portfolio Review Meeting in Washington, D.C. on June 1-2, 2011. PDF icon packaged_boilers_castaldini.pdf More Documents & Publications CHP Integrated with Burners for

  9. Waste combustion in boilers and industrial furnaces

    SciTech Connect (OSTI)

    1997-12-31

    This set of conference papers deals with the combustion of hazardous wastes in boilers and industrial furnaces. The majority of the papers pertain specifically to cement industry kiln incinerators and focus on environmental issues. In particular, stack emission requirements currently enforced or under consideration by the U.S. EPA are emphasized. The papers were drawn from seven areas: (1) proposed Maximum Achievable Control Technology rule, (2) trial burn planning and experience, (3) management and beneficial use of materials, (4) inorganic emissions and continuous emission monitoring, (5) organic emissions, (6) boiler and industrial furnace operations, and (7) risk assessment and communication.

  10. Model-free adaptive control of advanced power plants

    DOE Patents [OSTI]

    Cheng, George Shu-Xing; Mulkey, Steven L.; Wang, Qiang

    2015-08-18

    A novel 3-Input-3-Output (3.times.3) Model-Free Adaptive (MFA) controller with a set of artificial neural networks as part of the controller is introduced. A 3.times.3 MFA control system using the inventive 3.times.3 MFA controller is described to control key process variables including Power, Steam Throttle Pressure, and Steam Temperature of boiler-turbine-generator (BTG) units in conventional and advanced power plants. Those advanced power plants may comprise Once-Through Supercritical (OTSC) Boilers, Circulating Fluidized-Bed (CFB) Boilers, and Once-Through Supercritical Circulating Fluidized-Bed (OTSC CFB) Boilers.

  11. Characteristics and sources of intermediate size particles in recovery boilers : final project report.

    SciTech Connect (OSTI)

    Baxter, Larry L.; Shaddix, Christopher R.; Verrill, Christopher L.; Wessel, Richard A.

    2005-02-01

    As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

  12. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    SciTech Connect (OSTI)

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system—the Super Boiler—for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently up to 50% smaller in footprint, has a smaller diameter, and is up to 50% lower in weight, resulting in very compact design with reduced material cost and labor costs, while requiring less boiler room floor space. For enhanced energy efficiency, the heat recovery system uses a transport membrane condenser (TMC), a humidifying air heater (HAH), and a split-stage economizer to extract maximum energy from the flue gas. The TMC is a new innovation that pulls a major portion of water vapor produced by the combustion process from the flue gases along with its sensible and latent heat. This results in nearly 100% transfer of heat to the boiler feed water. The HAH improves the effectiveness of the TMC, particularly in steam systems that do not have a large amount of cold makeup water. In addition, the HAH humidifies the combustion air to reduce NOx formation. The split-stage economizer preheats boiler feed water in the same way as a conventional economizer, but extracts more heat by working in tandem with the TMC and HAH to reduce flue gas temperature. These components are designed to work synergistically to achieve energy efficiencies of 92-94% which is 10-15% higher than today’s typical firetube boilers.

  13. Best Management Practice #8: Steam Boiler Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  14. The next generation of oxy-fuel boiler systems

    SciTech Connect (OSTI)

    Ochs, Thomas L.; Gross, Alex; Patrick, Brian; Oryshchyn, Danylo B.; Summers, Cathy A.; Turner, Paul C.

    2005-01-01

    Research in the area of oxy-fuel combustion which is being pioneered by Jupiter Oxygen Corporation combined with boiler research conducted by the USDOE/Albany Research Center has been applied to designing the next generation of oxy-fuel combustion systems. The new systems will enhance control of boiler systems during turn-down and improve response time while improving boiler efficiency. These next generation boiler systems produce a combustion product that has been shown to be well suited for integrated pollutant removal. These systems have the promise of reducing boiler foot-print and boiler construction costs. The modularity of the system opens the possibility of using this design for replacement of boilers for retrofit on existing systems.

  15. EA-0575: Fundamental Fluidization Research Project, Morgantown, West Virginia

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to design, construct, and operate a 2-foot diameter, 50-foot high pressurized fluidization with particular emphasis on operation in the...

  16. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

  17. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

  18. Guide to Low-Emission Boiler and Combustion Equipment Selection

    SciTech Connect (OSTI)

    Oland, CB

    2002-05-06

    Boiler owners and operators who need additional generating capacity face a number of legal, political, environmental, economic, and technical challenges. Their key to success requires selection of an adequately sized low-emission boiler and combustion equipment that can be operated in compliance with emission standards established by state and federal regulatory agencies. Recognizing that many issues are involved in making informed selection decisions, the U.S. Department of Energy (DOE), Office of Industrial Technologies (OIT) sponsored efforts at the Oak Ridge National Laboratory (ORNL) to develop a guide for use in choosing low-emission boilers and combustion equipment. To ensure that the guide covers a broad range of technical and regulatory issues of particular interest to the commercial boiler industry, the guide was developed in cooperation with the American Boiler Manufacturers Association (ABMA), the Council of Industrial Boiler Owners (CIBO), and the U.S. Environmental Protection Agency (EPA). The guide presents topics pertaining to industrial, commercial, and institutional (ICI) boilers. Background information about various types of commercially available boilers is provided along with discussions about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and other important selection considerations. Although information in the guide is primarily applicable to new ICI boilers, it may also apply to existing boiler installations.

  19. Coal-fired boiler for petroleum refinery

    SciTech Connect (OSTI)

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  20. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  1. SOLID PARTICLE THERMAL ENERGY STORAGE DESIGN FOR A FLUIDIZED-BED

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONCENTRATING SOLAR POWER PLANT - Energy Innovation Portal 5667 Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent Search Success Stories Find More Like

  2. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  3. Evaluation of cement production using a pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    DeLallo, M.; Eshbach, R.

    1994-01-01

    There are several primary conclusions which can be reached and used to define research required in establishing the feasibility of using PFBC-derived materials as cement feedstock. 1. With appropriate blending almost any material containing the required cement-making materials can be utilized to manufacture cement. However, extensive blending with multiple materials or the use of ash in relatively small quantities would compromise the worth of this concept. 2. The composition of a potential feedstock must be considered not only with respect to the presence of required materials, but just as significantly, with respect to the presence and concentration of known deleterious materials. 3. The processing costs for rendering the feedstock into an acceptable composition and the energy costs associated with both processing and burning must be considered. It should be noted that the cost of energy to produce cement, expressed as a percentage of the price of the product is higher than for any other major industrial product. Energy consumption is, therefore, a major issue. 4. The need for conformance to environmental regulations has a profound effect on the cement industry since waste materials can neither be discharged to the atmosphere or be shipped to a landfill. 5. Fifth, the need for achieving uniformity in the composition of the cement is critical to controlling its quality. Unfortunately, certain materials in very small concentrations have the capability to affect the rate and extent to which the cementitious compound in portland cement are able to form. Particularly critical are variations in the ash, the sulfur content of the coal or the amount and composition of the stack dust returned to the kiln.

  4. EA-0646: Pulsed Atmospheric Fluidized-Bed Combustor Development Thermochem, Inc.

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to develop a more economical, efficient, and environmentally acceptable coal-fired combustion technology in Baltimore, Maryland that can be...

  5. Tube bank metal wastage in the Grimethorpe PFBC. [Pressurized fluidized bed combustor

    SciTech Connect (OSTI)

    Not Available

    1984-02-01

    During hot commissioning tests of the Grimethorpe PFBC plant, a significant degree of metal wastage was observed on the fireside surfaces of the tube bank. The investigation of this wastage is described and the remedial measures taken are discussed.

  6. Sea bed mechanics

    SciTech Connect (OSTI)

    Sleath, J.F.A.

    1984-01-01

    This book provides a discussion on sea bed processes with engineering applications. It brings together the material currently available only in technical reports of research papers. It provides formulae and background references necessary for design calculation of problems such as sea bed or coastal erosion, and sub-marine pipeline stability. It also covers dissipation of wave energy, formation of ripples and dunes, and the transportation of sediments.

  7. Ancient Salt Beds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ancient Salt Beds Dr. Jack Griffith The key to the search for life on other planets may go through WIPP's ancient salt beds. In 2008, a team of scientists led by Jack Griffith, from the University of North Carolina, Chapel Hill, retrieved salt samples from the WIPP underground and studied them with a transmission electron microscopy lab at the Lineberger Comprehensive Cancer Center of the University of North Carolina School of Medicine. In examining fluid inclusions in the salt and solid halite

  8. The development of an integrated multistage fluid bed retorting process. [Kentort II process--50-lb/hr

    SciTech Connect (OSTI)

    Carter, S.; Stehn, J.; Vego, A.; Taulbee, D.

    1992-05-01

    This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of January 1, 1992 through March 31, 1992. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The design of the 50-lb/hr KENTORT II retort was completed and fabrication is ready to begin. Data from the cold-flow model of the system and operating experience from the 5-lb/hr unit were used as the basis for the design. In another aspect of the program, a study of the cracking and coking kinetics of shale oil vapors was continued. A mathematical model was implemented to characterize the important mass transfer effects of the system. This model will be eventually broadened to become a general fluidized bed coking model. In addition, experiments were performed to examine the effects of surface area, initial carbon content and steam treatment on coking activity. From the data that has been collected to-date, it appears that the coking activity of the tested substrates can be explained in terms of porosity (surface area and pore volume) and the initial carbon content of the solid.

  9. The development of an integrated multistage fluid bed retorting process. Technical report, January 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Carter, S.; Stehn, J.; Vego, A.; Taulbee, D.

    1992-05-01

    This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of January 1, 1992 through March 31, 1992. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The design of the 50-lb/hr KENTORT II retort was completed and fabrication is ready to begin. Data from the cold-flow model of the system and operating experience from the 5-lb/hr unit were used as the basis for the design. In another aspect of the program, a study of the cracking and coking kinetics of shale oil vapors was continued. A mathematical model was implemented to characterize the important mass transfer effects of the system. This model will be eventually broadened to become a general fluidized bed coking model. In addition, experiments were performed to examine the effects of surface area, initial carbon content and steam treatment on coking activity. From the data that has been collected to-date, it appears that the coking activity of the tested substrates can be explained in terms of porosity (surface area and pore volume) and the initial carbon content of the solid.

  10. Guide to Low-Emission Boiler and Combustion Equipment Selection |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Low-Emission Boiler and Combustion Equipment Selection Guide to Low-Emission Boiler and Combustion Equipment Selection The guide provides background information about various types of industrial, commercial, and institutional (ICI) boilers along with discussion about the fuels that they burn and the emissions that they produce. Also included are discussions about emissions standards and compliance issues, technical details related to emissions control techniques, and

  11. Oxy-Combustion Boiler Material Development (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to ... Test coupons of boiler tube materials were coated with deposits representative of those ...

  12. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scale deposits occur when calcium, magnesium, and silica, commonly found in most water ... The boilers steam production may be reduced if the fring rate cannot be increased to ...

  13. Oil-Fired Boilers and Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil-Fired Boilers and Furnaces Oil-Fired Boilers and Furnaces Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the chances of an oil spill. Typically, the tank drip pan shown here is required only for single-wall tanks and would extend the full width of the tank. | Photo courtesy State of Massachusetts. Diagram of an oil boiler. New tanks are generally double-wall or have a spill container built underneath to reduce the chances of

  14. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    in the Northeast States Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Biomass Boiler and Furnace Emissions and Safety Regulations in the Northeast States Agency...

  15. Return Condensate to the Boiler - Steam Tip Sheet #8

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on returning condensate to boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  16. EECBG Success Story: New Boilers, Big Savings for Minnesota County

    Broader source: Energy.gov [DOE]

    Officials at Sherburne County's Government Center in Minnesota had a problem: the complex's original boilers, installed in 1972, were in desperate need of replacing. Learn more.

  17. Improve Your Boiler's Combustion Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012) More Documents & Publications Consider Installing a Condensing Economizer Use Feedwater Economizers for Waste Heat Recovery Clean Boiler Waterside Heat Transfer Surfaces

  18. Recover Heat from Boiler Blowdown | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Recover Heat from Boiler Blowdown (January 2012) More Documents & Publications Install an Automatic Blowdown-Control System Flash High-Pressure Condensate to Regenerate ...

  19. Field Test of Boiler Primary Loop Temperature Controller

    SciTech Connect (OSTI)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  20. Property:Building/SPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler...

    Open Energy Info (EERE)

    Oil-FiredBoiler Jump to: navigation, search This is a property of type String. Oil-fired boiler Pages using the property "BuildingSPPurchasedEngyPerAreaKwhM2Oil-FiredBoiler"...

  1. 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking 2015-02-13 Issuance: Test Procedure for Furnaces and Boilers; Notice of Proposed Rulemaking This ...

  2. Green wood chip gasification due under boiler

    SciTech Connect (OSTI)

    Not Available

    1981-12-14

    It is reported that Applied Engineering Co. has begun installing the first greenwood chip gasification system to be used in conjunction with fossil fuels at Florida Power Corp's Suwannee generating station near Lake City, Florida. The unit's design capacity is about 37 MMBTU/hour and will provide as much as 25% of the fuel requirements of a large utility type natural gas boiler under normal load conditions. The system is expected to back out as much as 1 million gal/year of fuel oil at a savings of approximately $850,000/year.

  3. Materials development for ultra-supercritical boilers

    SciTech Connect (OSTI)

    2005-09-30

    Progress is reported on a US Department of Energy project to develop high temperature, corrosion resistant alloys for use in ultra-supercritical steam cycles. The aim is to achieve boiler operation at 1,400{sup o}F/5,000 psi steam conditions with 47% net cycle efficiency. Most ferritic steel tested such as T92 and Save 12 showed severe corrosion. Nickel-based alloys, especially IN 740 and CCA 617, showed greatest resistance to oxidation with no evidence of exfoliation. Laboratory and in-plant tests have begun. 2 figs.

  4. Temperature dependence of wastage of in-bed tubes

    SciTech Connect (OSTI)

    Wright, I.G.; Sethi, V.K.; Stringer, J.

    1995-12-31

    Observations of the wastage of evaporator tubes immersed in combusting fluidized beds have suggested that a change in tube metal temperature, around the relatively narrow range of 300 to 400 C, can effect large changes in the rate and mode of tube wastage. A number of attempts has been made to reproduce this temperature dependence of metal wastage in the laboratory, with varying degrees of success. In this paper, the types of wastage temperature relationships developed by various research groups are reviewed in light of the erosion and corrosion conditions actually created in the laboratory simulations. In addition, the ability of the various scenarios proposed to explain this wastage phenomenon to rationalize the types of temperature dependence observed is examined.

  5. Thermal valorization of post-consumer film waste in a bubbling bed gasifier

    SciTech Connect (OSTI)

    Martnez-Lera, S., E-mail: susanamartinezlera@gmail.com; Torrico, J.; Pallars, J.; Gil, A.

    2013-07-15

    Highlights: Film waste from packaging is a common waste, a fraction of which is not recyclable. Gasification can make use of the high energy value of the non-recyclable fraction. This waste and two reference polymers were gasified in a bubbling bed reactor. This experimental research proves technical feasibility of the process. It also analyzes impact of composition and ER on the performance of the plant. - Abstract: The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes. A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m{sup 3} and cold gas efficiencies up to 60%.

  6. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-10-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2005.

  7. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2005-04-27

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of July 1 to September 30, 2004.

  8. Boiler Materials for Ultrasupercritical Coal Power Plants

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2006-01-31

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). A limiting factor in this can be the materials of construction. The project goal is to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi). This goal seems achievable based on a preliminary assessment of material capabilities. The project is further intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of October 1 to December 30, 2005.

  9. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; J. Shingledecker; J. Sarver; G. Stanko; M. Borden; W. Mohn; S. Goodstine; I. Perrin

    2004-10-30

    The U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) have recently initiated a project aimed at identifying, evaluating, and qualifying the materials needed for the construction of the critical components of coal-fired boilers capable of operating at much higher efficiencies than current generation of supercritical plants. This increased efficiency is expected to be achieved principally through the use of ultrasupercritical steam conditions (USC). The project goal initially was to assess/develop materials technology that will enable achieving turbine throttle steam conditions of 760 C (1400 F)/35 MPa (5000 psi), although this goal for the main steam temperature had to be revised down to 732 C (1350 F), based on a preliminary assessment of material capabilities. The project is intended to build further upon the alloy development and evaluation programs that have been carried out in Europe and Japan. Those programs have identified ferritic steels capable of meeting the strength requirements of USC plants up to approximately 620 C (1150 F) and nickel-based alloys suitable up to 700 C (1300 F). In this project, the maximum temperature capabilities of these and other available high-temperature alloys are being assessed to provide a basis for materials selection and application under a range of conditions prevailing in the boiler. This report provides a quarterly status report for the period of April to June 30, 2004.

  10. Establishing an energy efficiency recommendation for commercial boilers

    SciTech Connect (OSTI)

    Ware, Michelle J.

    2000-08-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of $40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over $25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings.

  11. Gas reburn retrofit on an industrial cyclone boiler

    SciTech Connect (OSTI)

    Farzan, H.; Latham, C.E.; Maringo, G.J.

    1996-01-01

    Eastman Kodak Company`s cyclone boiler (Unit No. 43), located in Rochester, New York, is being retrofitted with the gas reburning technology developed by Babcock & Wilcox (B & W) to reduce NO{sub x} emissions in order to comply with the Title I, ozone nonattainment, of the Clean Air Act Amendments (CAAA) of 1990. The required NO{sub x} reduction from baseline levels necessary to meet the presumptive limit set in New York`s regulation is about 47%. Eastman Kodak and the Gas Research Institute (GRI) are cosponsoring this project. B & W is the prime contractor and contract negotiations with Chevron as the gas supplier are presently being finalized. Equipment installation for the gas reburn system is scheduled for a September 1995 outage. No. 43 Boiler`s maximum continuous rating (MCR) is 550,000 pounds per hour of steam flow or approximately equivalent to 60 MW{sub e}. Because of the compact boiler design, there is insufficient gas residence time to use pulverized coal or oil as the reburn fuel, thus making it a prime candidate for gas reburn. Kodak currently has four cyclone boilers. Based on successful completion of this gas reburn project, modifying the other three cyclone boilers with gas reburn technology is anticipated. The paper will describe B & W`s gas reburn data from a cyclone-equipped pilot facility (B & W`s Small Boiler Simulator), gas reburn design information specific to Eastman Kodak No. 43 Boiler, and numerical modeling experiences based on the pilot-scale Small Boiler Simulator (SBS) results along with those from a full-scale commercial boiler.

  12. Closures for Course-Grid Simulation of Fluidized Gas-Particle Flows

    SciTech Connect (OSTI)

    Sankaran Sundaresan

    2010-02-14

    Gas-particle flows in fluidized beds and riser reactors are inherently unstable, and they manifest fluctuations over a wide range of length and time scales. Two-fluid models for such flows reveal unstable modes whose length scale is as small as ten particle diameters. Yet, because of limited computational resources, gas-particle flows in large fluidized beds are invariably simulated by solving discretized versions of the two-fluid model equations over a coarse spatial grid. Such coarse-grid simulations do not resolve the small-scale spatial structures which are known to affect the macroscale flow structures both qualitatively and quantitatively. Thus there is a need to develop filtered two-fluid models which are suitable for coarse-grid simulations and capturing the effect of the small-scale structures through closures in terms of the filtered variables. The overall objective of the project is to develop validated closures for filtered two-fluid models for gas-particle flows, with the transport gasifier as a primary, motivating example. In this project, highly resolved three-dimensional simulations of a kinetic theory based two-fluid model for gas-particle flows have been performed and the statistical information on structures in the 100-1000 particle diameters length scale has been extracted. Based on these results, closures for filtered two-fluid models have been constructed. The filtered model equations and closures have been validated against experimental data and the results obtained in highly resolved simulations of gas-particle flows. The proposed project enables more accurate simulations of not only the transport gasifier, but also many other non-reacting and reacting gas-particle flows in a variety of chemical reactors. The results of this study are in the form of closures which can readily be incorporated into existing multi-phase flow codes such as MFIX (www.mfix.org). Therefore, the benefits of this study can be realized quickly. The training provided by this project has prepared a PhD student to enter research and development careers in DOE laboratories or chemicals/energy-related industries.

  13. Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers

    SciTech Connect (OSTI)

    2005-05-01

    The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

  14. Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

    DOE Patents [OSTI]

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-09-23

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  15. Durable zinc oxide containing sorbents for moving bed and fluid-bed applications

    SciTech Connect (OSTI)

    Siriwardane, R.V.

    1998-12-31

    A series of novel regenerable desulfurization sorbents operational at a wide range of temperatures (260--600 C) has been developed by the in-house research staff at the US Department of Energy`s Federal Energy Technology Center. The sorbent, identified as METC10, has demonstrated very high attrition resistance as well as very high and stable reactivity conducted under numerous testing regimes under both simulated and actual fuel gas conditions. The METC10 sorbent suitable for moving bed reactor applications is the only sorbent which has exceeded all the criteria required for use in the Tampa Electric Company (TECO) Clean Coal Technology (CCT) demonstration project. The required criteria for the TECO project included, a sulfur loading of 6.7 lb/ft{sup 3} while maintaining the outlet H{sub 2}S level < 20 ppmv, attrition of < 5 wt% after 25 cycle test and regeneration under the very drastic conditions of 10% SO{sub 2} at 510 C under 5--7 atmospheres. In addition, the sorbent was also tested at temperatures ranging from 370 C to 260 C with simulated coal gas. At this low temperature, it was possible to achieve a sulfur loading > 6 lb/ft{sup 3}, indicating that the sorbent is suitable for applications over a wide range of temperatures. It was also possible to prepare METC10 sorbent suitable for fluidized/transport reactor bed applications utilizing spray drying technique. These sorbents had both high attrition resistance (> 95%) and high sulfur capacity (> 14 wt%), and showed stable reactivity during multi-cycle testing.

  16. Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Furnaces and Boilers, Comment Period Extension

  17. Boiler Maximum Achievable Control Technology (MACT) Technical Assistance- Fact Sheet, April 2015

    Broader source: Energy.gov [DOE]

    Fact sheet about the Boiler Maximum Achievable Control Technology (MACT) Technical Assistance Program

  18. Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Residential Boilers, Notice of Proposed Rulemaking

  19. 2015-12-29 Consumer Furnaces and Boilers Test Procedures Final Rule

    Broader source: Energy.gov [DOE]

    Energy Conservation Program for Consumer Products: Test Procedures for Consumer Furnaces and Boilers

  20. CHP Integrated with Burners for Packaged Boilers

    SciTech Connect (OSTI)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    The objective of this project was to engineer, design, fabricate, and field demonstrate a Boiler Burner Energy System Technology (BBEST) that integrates a low-cost, clean burning, gas-fired simple-cycle (unrecuperated) 100 kWe (net) microturbine (SCMT) with a new ultra low-NOx gas-fired burner (ULNB) into one compact Combined Heat and Power (CHP) product that can be retrofit on new and existing industrial and commercial boilers in place of conventional burners. The Scope of Work for this project was segmented into two principal phases: (Phase I) Hardware development, assembly and pre-test and (Phase II) Field installation and demonstration testing. Phase I was divided into five technical tasks (Task 2 to 6). These tasks covered the engineering, design, fabrication, testing and optimization of each key component of the CHP system principally, ULNB, SCMT, assembly BBEST CHP package, and integrated controls. Phase I work culminated with the laboratory testing of the completed BBEST assembly prior to shipment for field installation and demonstration. Phase II consisted of two remaining technical tasks (Task 7 and 8), which focused on the installation, startup, and field verification tests at a pre-selected industrial plant to document performance and attainment of all project objectives. Technical direction and administration was under the management of CMCE, Inc. Altex Technologies Corporation lead the design, assembly and testing of the system. Field demonstration was supported by Leva Energy, the commercialization firm founded by executives at CMCE and Altex. Leva Energy has applied for patent protection on the BBEST process under the trade name of Power Burner and holds the license for the burner currently used in the product. The commercial term Power Burner is used throughout this report to refer to the BBEST technology proposed for this project. The project was co-funded by the California Energy Commission and the Southern California Gas Company (SCG), a division of Sempra Energy. These match funds were provided via concurrent contracts and investments available via CMCE, Altex, and Leva Energy The project attained all its objectives and is considered a success. CMCE secured the support of GI&E from Italy to supply 100 kW Turbec T-100 microturbines for the project. One was purchased by the project’s subcontractor, Altex, and a second spare was purchased by CMCE under this project. The microturbines were then modified to convert from their original recuperated design to a simple cycle configuration. Replacement low-NOx silo combustors were designed and bench tested in order to achieve compliance with the California Air Resources Board (CARB) 2007 emission limits for NOx and CO when in CHP operation. The converted microturbine was then mated with a low NOx burner provided by Altex via an integration section that allowed flow control and heat recovery to minimize combustion blower requirements; manage burner turndown; and recover waste heat. A new fully integrated control system was designed and developed that allowed one-touch system operation in all three available modes of operation: (1) CHP with both microturbine and burner firing for boiler heat input greater than 2 MMBtu/hr; (2) burner head only (BHO) when the microturbine is under service; and (3) microturbine only when boiler heat input requirements fall below 2 MMBtu/hr. This capability resulted in a burner turndown performance of nearly 10/1, a key advantage for this technology over conventional low NOx burners. Key components were then assembled into a cabinet with additional support systems for generator cooling and fuel supply. System checkout and performance tests were performed in the laboratory. The assembled system and its support equipment were then shipped and installed at a host facility where final performance tests were conducted following efforts to secure fabrication, air, and operating permits. The installed power burner is now in commercial operation and has achieved all the performance goals.