Powered by Deep Web Technologies
Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Heating tar sands formations to visbreaking temperatures  

DOE Patents (OSTI)

Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat may be controlled so that at least a majority of the section reaches an average temperature of between 200.degree. C. and 240.degree. C., which results in visbreaking of at least some hydrocarbons in the section. At least some visbroken hydrocarbon fluids may be produced from the formation.

Karanikas, John Michael (Houston, TX); Colmenares, Tulio Rafael (Houston, TX); Zhang, Etuan (Houston, TX); Marino, Marian (Houston, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX); Ryan, Robert Charles (Houston, TX); Beer, Gary Lee (Houston, TX); Dombrowski, Robert James (Houston, TX); Jaiswal, Namit (Houston, TX)

2009-12-22T23:59:59.000Z

2

Hydrodesulfurization of Fluid Catalytic Cracking Decant Oils for the Production of Low-sulfur Needle Coke Feedstocks.  

E-Print Network (OSTI)

??Needle coke, produced by the delayed coking of fluid catalytic cracking decant oils, is the primary filler used in the production of graphite electrodes. The… (more)

Wincek, Ronald

2013-01-01T23:59:59.000Z

3

Dale Coke: Coke Farm  

E-Print Network (OSTI)

Dale Coke Photo by Benjamin J. Myers.2009. Coke FarmDale Coke grew up on an apricot orchard in California’s

Farmer, Ellen

2010-01-01T23:59:59.000Z

4

Spectroscopic studies on the formation of coke on individual Fluid Catalytic Cracking particles: the effect of poisoning metal compounds.  

E-Print Network (OSTI)

??The formation of coke on individual Fluid Catalytic Cracking (FCC) catalyst particles was studied using UV/Vis microspectroscopy and confocal fluorescence microscopy, with n-hexane cracking as… (more)

Goetze, J.G.

2013-01-01T23:59:59.000Z

5

3D Computational Fluid Dynamics Simulation of Natural Coke Steam Gasification in General and Improved Fluidized Beds  

Science Journals Connector (OSTI)

The thermal characteristics of natural coke steam gasification in a fluidized bed were three-dimensionally (3D) simulated based on the computational fluid dynamics (CFD) method using Fluent code. ... However, this technology seems difficult to carry out due to its abradability, hard ignition, hot burst, and so on. ... In short, all the results in this work have a significance to provide the theoretical basis for the design, operational optimization, and scale-up of the natural coke steam gasification process. ...

Ya-li Tang; Dai-jun Liu; Yu-hong Liu; Qian Luo

2010-09-30T23:59:59.000Z

6

coking coal  

Science Journals Connector (OSTI)

coking coal [A caking coal suitable for the production of coke for metallurgical use] ? Kokskohle f, verkokbare Kohle

2014-08-01T23:59:59.000Z

7

Co-gasification of Biomass and Non-biomass Feedstocks: Synergistic and Inhibition Effects of Switchgrass Mixed with Sub-bituminous Coal and Fluid Coke During CO2 Gasification  

Science Journals Connector (OSTI)

Co-gasification of biomass, namely, switchgrass, with coal and fluid coke was performed to investigate the availability of the gasification catalysts to the mixed feedstock, especially alkali and alkaline earth elements, naturally present on switchgrass. ...

Rozita Habibi; Jan Kopyscinski; Mohammad S. Masnadi; Jill Lam; John R. Grace; Charles A. Mims; Josephine M. Hill

2012-11-21T23:59:59.000Z

8

Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998  

SciTech Connect

The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

NONE

1998-08-15T23:59:59.000Z

9

Chemicals from Coal Coking  

Science Journals Connector (OSTI)

Chemicals from Coal Coking ... Since 2009, she has been at INCAR-CSIC, researching the preparation and characterization of carbon materials (cokes and fibers) and nanomaterials (nanotubes and graphenes) and their catalytic, environmental, and energy applications. ... He then joined the Fundamental Studies Section of the British Coke (later Carbonization) Research Association, eventually becoming Head of Fundamental Studies. ...

Marcos Granda; Clara Blanco; Patricia Alvarez; John W. Patrick; Rosa Menéndez

2013-09-30T23:59:59.000Z

10

Blast furnace coke quality in relation to petroleum coke addition  

SciTech Connect

The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

1995-12-01T23:59:59.000Z

11

100% Pet coke or pet coke blends combustion  

SciTech Connect

Information is outlined on the combustion of 100 percent petroleum coke or petroleum coke blends. Data are presented on NISCO overviews; fuel (coke) characteristics; delayed coke analysis (1995-96); limestone characteristics/effects; limestone preparation; ash characteristics; vortex finders; agglomerization; and NISCO performance results.

Swindle, D.L.

1996-12-31T23:59:59.000Z

12

MOLECULAR COMPOSITION OF NEEDLE COKE FEEDSTOCKS AND MESOPHASE DEVELOPMENT DURING CARBONIZATION.  

E-Print Network (OSTI)

??This study investigates the molecular composition of fluid catalytic cracking (FCC) decant oil and its derivatives that are used as feedstocks for delayed coking to… (more)

Wang, Guohua

2005-01-01T23:59:59.000Z

13

Coke yield and transport processes in agglomerates of bitumen and solids.  

E-Print Network (OSTI)

??Agglomerate formation is a common phenomenon that can cause operating problems in the fluid coking reactor. When agglomerates form they provide longer diffusion paths of… (more)

Ali, Mohamed Ali Hassan

2010-01-01T23:59:59.000Z

14

The effect of diabietic acid on the coking of oxidised solvent-extracted coal.  

E-Print Network (OSTI)

??Refcoal is a refined carbon source obtained by extraction of coal with dimethylformamide (DMF). During the coking process, Refcoal goes through a mesophase (fluid) stage… (more)

Ludere, Margaret Tshimangadzo

2008-01-01T23:59:59.000Z

15

Desulfurization of coke oven gas from the coking of coking coal blended with a sorbent and waste plastic  

Science Journals Connector (OSTI)

A new way to implement the simultaneous reutilization of solid waste, the desulfurization of coke oven gas (COG), and even the desulfurization of coke by the co-coking of coking coal (CC) and waste plastic (WP).....

Zhao Rongfang; Ye Shufeng; Xie Yusheng…

2007-03-01T23:59:59.000Z

16

Influence of coal preparation and coking conditions on coke reactivity  

Science Journals Connector (OSTI)

The influence of various technological factors on the high-temperature properties of coke is investigated. It is found that factors facilitating an orderly organic structure of the coke (fine grinding and comp...

D. V. Miroshnichenko

2009-02-01T23:59:59.000Z

17

Modified coal batch in coking  

Science Journals Connector (OSTI)

The influence of volatile products from low-metamorphic poorly clinkering G coal on plasticmass formation in rammed batch during coking is considered. An experimental batch of modified coke has been produced at P...

A. G. Starovoit; E. I. Malyi; M. S. Chemerinskii; M. A. Starovoit…

2013-05-01T23:59:59.000Z

18

Met coke world summit 2005  

SciTech Connect

Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

NONE

2005-07-01T23:59:59.000Z

19

Coking and gasification process  

DOE Patents (OSTI)

An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

1986-01-01T23:59:59.000Z

20

Integration of stripping of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

DeGeorge, Charles W. (Chester, NJ)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Coke and Coal Research  

Science Journals Connector (OSTI)

... A. Mott at the University of Sheffield, are concerned with problems affecting the hard coke industry, which enjoys facilities for large-scale experimentation through its member firms such as ... of the body organizing this work visited the Kingston and Fulham Laboratories of the British Coal Utilisation Research Association on September 9. Mr. J. G. Bennett, director of ...

1943-09-18T23:59:59.000Z

22

High coking value pitch  

SciTech Connect

A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

2014-06-10T23:59:59.000Z

23

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar  

Science Journals Connector (OSTI)

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar ... Study on the coking mechanism of coal and coal tar pitches. ...

Vedat Arslan

2006-08-16T23:59:59.000Z

24

Coke | OpenEI  

Open Energy Info (EERE)

18 18 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142278418 Varnish cache server Coke Dataset Summary Description UK National coal (and solid fuels and gases derived from processing coal) are published in Chapter 2 (Solid Fuels and Derived Gases) of the Digest of UK Energy Statistics (DUKES). Included here are the datasets for commodity balances (1998 - 2009); supply and consumption (2005 - 2009) of coal and other fuels (e.g. coke oven gas, blast furnace gas, benzole and tars, etc). Chapter 2 of the report is available: http://www.decc.gov.uk/assets/decc/Statistics/publications/dukes/308-dukes-2010-ch2.pdf Source UK Department of Energy and Climate Change (DECC)

25

Design and construction of coke battery 1A at Radlin coke plant, Poland  

SciTech Connect

In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

26

Factors influencing coke gasification with carbon dioxide.  

E-Print Network (OSTI)

??Of all coke properties the influence of the catalytic mineral matter on reactivity of metallurgical cokes is least understood. There is limited information about the… (more)

Grigore, Mihaela

2007-01-01T23:59:59.000Z

27

Coke from coal and petroleum  

DOE Patents (OSTI)

A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

1981-01-01T23:59:59.000Z

28

Definition: Petroleum coke | Open Energy Information  

Open Energy Info (EERE)

coke coke Jump to: navigation, search Dictionary.png Petroleum coke A residue high in carbon content and low in hydrogen that is the final product of thermal decomposition in the condensation process in cracking (breaking of carbon-carbon bonds). This product is reported as marketable coke or catalyst coke.Coke from petroleum has a heating value of 6.024 million Btu per barrel.[1] View on Wikipedia Wikipedia Definition Petroleum coke (often abbreviated Pet coke or petcoke) is a carbonaceous solid derived from oil refinery coker units or other cracking processes. Other coke has traditionally been derived from coal. This coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke directly out of the coker is often

29

Research on Coal and Coke  

Science Journals Connector (OSTI)

... THE third annual report of the Northern Coke Research Committee records the many-sided activities of its staff working in the Armstrong College ... activities of its staff working in the Armstrong College, Newcastle, on problems of the coals and ...

1932-10-22T23:59:59.000Z

30

Characteristics of coking coal burnout  

SciTech Connect

An attempt was made to clarify the characteristics of coking coal burnout by the morphological analysis of char and fly ash samples. Laboratory-scale combustion testing, simulating an ignition process, was carried out for three kinds of coal (two coking coals and one non-coking coal for reference), and sampled chars were analyzed for size, shape and type by image analysis. The full combustion process was examined in industrial-scale combustion testing for the same kinds of coal. Char sampled at the burner outlet and fly ash at the furnace exit were also analyzed. The difference between the char type, swelling properties, agglomeration, anisotropy and carbon burnout were compared at laboratory scale and at industrial scale. As a result, it was found that coking coals produced chars with relatively thicker walls, which mainly impeded char burnout, especially for low volatile coals.

Nakamura, M. [Ishikawajima-Harima Heavy Industries Co., Ltd., Tokyo (Japan); Bailey, J.G. [Univ. of Newcastle, New South Wales (Australia)

1996-12-31T23:59:59.000Z

31

Influence of petroleum coking additive on the quality of coal batch, coke, and tar  

Science Journals Connector (OSTI)

Given the shortage of coal with good coking properties, a petroleum coking additive is introduced in coal batch so as to expand the range of plasticity. This additive improves coke quality in every respect, excep...

I. I. Mel’nikov; V. M. Kryachuk; D. A. Mezin; A. A. Gorbunov…

2011-12-01T23:59:59.000Z

32

Evaluation of coal and its influence on coke quality and the coking process  

Science Journals Connector (OSTI)

The evaluation of coal batch is considered, along with its influence on coke quality and the coking properties. The quality of the coal available for coking at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat is ...

G. R. Gainieva; V. I. Byzova; N. N. Nazarov; L. D. Nikitin…

2008-10-01T23:59:59.000Z

33

Estimating Coke and Pepsi's Price and Advertising Strategies  

E-Print Network (OSTI)

Strategy Distributions for Coke (First Quarter 1977) a)Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISINGEconomics July, 1998 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

1998-01-01T23:59:59.000Z

34

Experimental study of elastoplastic mechanical properties of coke drum materials.  

E-Print Network (OSTI)

??Coke drums are vertical pressure vessels used in the delayed coking process in petroleum refineries. Significant temperature variation during the delayed coking process causes the… (more)

Chen, Jie

2010-01-01T23:59:59.000Z

35

New coke-sorting system at OAO Koks  

SciTech Connect

A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

36

Utilization of coke and functionalized coke-based composite for uptake of heavy metals from wastewater .  

E-Print Network (OSTI)

??This study investigated the functionalization of coke particles and their utilization for the preparation of coke-polymer composite. Looking at the possibility of using it for… (more)

Mdlalose, Lindani Mbalenhle

2014-01-01T23:59:59.000Z

37

Russian coking coal in 2008 and 2009  

Science Journals Connector (OSTI)

Coal resources and coke production in the second half of 2009 ... are considered. The unsuitability of the available coal for the production of high-strength coke is analyzed.

B. P. Kiselev

2010-10-01T23:59:59.000Z

38

Technological value of coal used for coking  

Science Journals Connector (OSTI)

The technological value of coal used for coking is analyzed, with particular attention to clinkering coal, the coke group, and lean additives, as well as G and GZhO coal. A relation is established between the tec...

A. S. Stankevich; V. S. Stankevich

2013-09-01T23:59:59.000Z

39

Oxidized coal in coking: A review  

Science Journals Connector (OSTI)

A literature review shows that the oxidation of coal changes its granulometric composition, packing density, ... clinkering properties, the quality of the resulting coke, and the yield of coking byproducts. On ac...

N. A. Desna; D. V. Miroshnichenko

2011-05-01T23:59:59.000Z

40

Russian coking coal in 2008 and 2009  

Science Journals Connector (OSTI)

The distribution and quality of Russian coal and coke resources are compared for periods before (the ... definition and determination of the technological value of coal. Analysis of coke strength suggests that, i...

B. P. Kiselev

2009-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Coal fractionation by density for coking purposes  

Science Journals Connector (OSTI)

Scarce coal with good coking properties may be obtained by separating less valuable coal into different density fractions. The use of valuable fractions released in enrichment ensures optimal coking-batch composi...

S. G. Gagarin

2010-09-01T23:59:59.000Z

42

The mechanism of coking pressure generation II: Effect of high volatile matter coking coal, semi-anthracite and coke breeze on coking pressure and contraction  

Science Journals Connector (OSTI)

One of the most important aspects of the cokemaking process is to control and limit the coking pressure since excessive coking pressure can lead to operational problems and oven wall damage. Following on from a previous paper on plastic layer permeability we have studied the effect of contraction of semi-coke on coking pressure and the effect of organic additives on contraction. A link between contraction (or simulated contraction) outside the plastic layer and coking pressure was demonstrated. The interaction between this contraction, local bulk density around the plastic layer and the dependence of the permeability of the plastic layer on bulk density was discussed as possible mechanisms for the generation of coking pressure. The effect of blending either a high volatile matter coal or one of two semi-anthracites with low volatile matter, high coking pressure coals on the coking pressure of the binary blends has been explained using this mechanism.

Merrick Mahoney; Seiji Nomura; Koichi Fukuda; Kenji Kato; Anthony Le Bas; David R. Jenkins; Sid McGuire

2010-01-01T23:59:59.000Z

43

Trends in the automation of coke production  

SciTech Connect

Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

44

Clean Production of Coke from Carbonaceous Fines  

SciTech Connect

In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

Craig N. Eatough

2004-11-16T23:59:59.000Z

45

Coke–pitch interactions during anode preparation  

Science Journals Connector (OSTI)

Abstract The information on the interactions between coke and pitch is of great value for the aluminum industry. This information can help choose the suitable coke and pitch pairs as well as the appropriate mixing parameters to be used during the production of anodes. In this study, the interaction mechanisms of pitch and coke at the mixing stage were studied by a sessile-drop test using two coal-tar pitches as the liquid and three petroleum cokes as the substrate. The results showed that the coke–pitch interactions are related to both pitch and coke chemical compositions. The contact angle of different coke–pitch systems decreased with increasing time and temperature. At high temperatures, decreasing the pitch viscosity facilitated the spreading of pitch and its penetration into the coke bed. The chemical behavior of petroleum cokes and coal tar pitches were studied using the FT-IR spectroscopy and XPS. The results showed that the wettability behavior of cokes by pitches depends on their physical properties as well as the presence of surface functional groups of coke and pitch which can form chemical bonds.

Arunima Sarkar; Duygu Kocaefe; Yasar Kocaefe; Dilip Sarkar; Dipankar Bhattacharyay; Brigitte Morais; Jérôme Chabot

2014-01-01T23:59:59.000Z

46

Integrated two stage coking and steam cracking process and apparatus therefor  

SciTech Connect

The invention relates to an improvement in an integrated, two stage coking and steam cracking process for the production of unsaturated light hydrocarbons. A heavy hydrocarbonaceous oil is first coked in a fluidized bed coking zone. The vaporous conversion product is passed to a dilute phase. High temperature cracking in the presence of steam is carried out on the vaporous coker conversion product by injecting into the vapors a stream of hot coke particles at a sufficient temperature and in sufficient amount to raise the coker vapors to steam cracking temperature and supply the endothermic heat of reaction. Solids are separated from product gas in a gas-solids separation zone such as one or more cyclones and sent to the fluid coking zone and the gas is quenched to stop olefin degradation reactions. According to the improvement, relatively low temperature steam is introduced into contact with the separated solids to superheat the steam and cool the solids. Suitably this is effected in a riser on the cyclone dipleg. The solids, after having given up heat to the steam, pass into the coking zone and the superheated steam passes into the dilute phase and serves as part of the dilution steam therefor. Conservation of fuel and mitigation of coke on reactor walls and equipment are advantages of the process.

Oldweiler, M.E.

1983-10-25T23:59:59.000Z

47

Effect of Indian Medium Coking Coal on Coke Quality in Non-recovery Stamp Charged Coke Oven  

Science Journals Connector (OSTI)

Abstract The maximum possibility of utilizing the Indian coking coals and inferior grade coking coal for producing metallurgical coke through non-recovery stamp charging technology was investigated. Indian indigenous coals contained low percent of vitrinite ( 15%) compared to imported coking coal. Therefore, the selection of appropriate proportion of different types of coals was a major challenge for coke makers. Coal blend selection criterion based on a single coefficient, named as composite coking potential (CCP), was developed. The use of increased proportion of semi-soft coal (crucible swelling number of 2.5) and high ash (? 15%) indigenous coal in the range of 20%–35% and 20%–65% respectively in the blends resulted in good quality of coke. Plant data of a non-recovery coke oven were used for developing and validating the model. The results showed that the coke strength after reaction (CSR) varied in the range of 63. 7%–67.7% and the M40 value was between 81.8 and 89.3 in both the cases.

H.P. Tiwari; P.K. Banerjee; V.K. Saxena; S.K. Haldar

2014-01-01T23:59:59.000Z

48

Using coke-battery flue gas to dry coal batch before coking  

Science Journals Connector (OSTI)

The utilization of heat from coke-battery flue gases and other potential secondary energy resources in drying coal batch prior to coking is considered. The main factors that influence ... . The reduction in moist...

A. Ya. Eremin; V. G. Mishchikhin; S. G. Stakheev; R. R. Gilyazetdinov…

2011-03-01T23:59:59.000Z

49

Selecting the optimum coke pushing sequence  

SciTech Connect

The sequence of pushing coke ovens is one of the most important aspects of battery operation. The sequence must satisfy a number of technical and process conditions: (1) achieve maximum heating-wall life by avoiding destructive expansion pressure in freshly charged ovens and during pushing of the finished coke; (2) ensure uniform brickwork temperature and prevent overheating by compensating for the high thermal flux in freshly charged ovens due to accumulated heat in adjacent ovens that are in the second half of the coking cycle; (3) ensure the most favorable working conditions and safety for operating personnel; (4) provide additional opportunities for repair personnel to perform various types of work, such as replacing coke-machine rails, without interrupting coal production; (5) perform the maximum number of coke-machine operations simultaneously: pushing, charging, and cleaning doors, frames, and standpipe elbows; and (6) reduce electricity consumption by minimizing idle travel of coke machines.

V.T. Krivoshein; A.V. Makarov [ZAO Trest Koksokhimmontazh (Russian Federation)

2007-01-15T23:59:59.000Z

50

Technological value of coal concentrates for coking  

Science Journals Connector (OSTI)

Options are outlined for calculating the technological value of coal and coal concentrates in the context of contractual obligations and the quality of the coke produced.

E. N. Stepanov; G. V. Larin; A. E. Stepanova; I. V. Semiokhina

2010-02-01T23:59:59.000Z

51

Estimating Coke and Pepsi's price and advertising strategies  

E-Print Network (OSTI)

Working Paper No. 789 ESTIMATING COKE AND PEPSI’ PRICE S ANDand Advertising Strategies: Coke and Pepsi) by Amos Golan,Revised, March 1999 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

1999-01-01T23:59:59.000Z

52

Interaction of low-metamorphic coal components in coking batch  

Science Journals Connector (OSTI)

The interaction of low-metamorphic coal components in coking batch during pyrolysis is studied. The characteristics of the resulting coke are presented, and the partial hydrogenation is...

E. I. Malyi; A. S. Koverya; M. A. Starovoit

2010-08-01T23:59:59.000Z

53

Clinkering properties of rammed coking coal and coal batches  

Science Journals Connector (OSTI)

The clinkering properties of rammed coking coal and coal batches are investigated. There is a close relation between the clinkering properties and coke quality.

V. M. Shmal’ko; M. A. Solov’ev

2009-03-01T23:59:59.000Z

54

Strength of the coke fillers of carbon materials  

SciTech Connect

Relationships between the ultimate compression strengths of coke fillers for carbon materials determined by various techniques and structures, final coke treatment temperatures, etc., are considered.

V.S. Ostrovskii [Research Institute of Structural Graphite Materials, Moscow (Russian Federation)

2008-12-15T23:59:59.000Z

55

New designs in the reconstruction of coke-sorting systems  

SciTech Connect

In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

56

12.2 Coke Production 12.2.1 General  

E-Print Network (OSTI)

Metallurgical coke is produced by the destructive distillation of coal in coke ovens. Prepared coal is heated in an oxygen-free atmosphere (–coked–) until most volatile components in the coal are removed. The material remaining is a carbon mass called coke. Metallurgical coke is used in iron and steel industry processes (primarily in blast furnaces) to reduce iron ore to iron. Over 90 percent of the total coke production is dedicated to blast furnace operations. Foundry coke comprises most of the balance and is used by foundries in furnaces for melting metal and in the preparation of molds. Foundry coke production uses a different blend of coking coals, longer coking times, and lower coking temperatures relative to those used for metallurgical coke. Most coke plants are collocated with iron and steel production facilities, and the demand for coke generally corresponds with the production of iron and steel. There has been a steady decline in the number of coke plants over the past several years for many reasons, including a decline in the demand for iron/steel, increased production of steel by mini-mills (electric arc furnaces that do not use coke), and the lowering of the coke:iron ratio used in the blast furnace (e. g., increased use of pulverized coal injection). There were 18 coke plants operating in the U. S. in 2007.

unknown authors

57

Determination of electrical resistivity of dry coke beds  

SciTech Connect

The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

Eidem, P.A.; Tangstad, M.; Bakken, J.A. [NTNU, Trondheim (Norway)

2008-02-15T23:59:59.000Z

58

Carol G. Cokely's recent Presentations Cokely, C. (2007). Incorporating Service Learing in to the AuD Curriculum. Invited  

E-Print Network (OSTI)

Carol G. Cokely's recent Presentations Cokely, C. (2007). Incorporating Service Learing in to the AuD Curriculum. Invited speaker, Teaching the Management of Hearing Loss, Pittsburgh, PA. Cokely, C, Pittsburgh, PA. Kricos, P.B., Weinstein, B., Lesner, S., Cokely, C., Milstein, D., & Chisolm, T. (2006) How

O'Toole, Alice J.

59

Delayed Coking of Decant Oil and Coal in a Laboratory-Scale Coking Unit  

Science Journals Connector (OSTI)

The fact that coke quality varies with the chemical composition of the precursor feedstock creates a significant incentive to examine the process of coking and how it relates to the composition of the feedstock. ... (7)?Derbyshire, F. J.; Odoerfer, G. A.; Rudnick, L. R.; Varghese, P.; Whitehurst, D. D. Fundamental studies in the conversion of coals to fuels of increased hydrogen content. ... Bituminous coal/petroleum co-cokes were produced by coking 4:1 blends of vacuum resid (VR)/coal and decant oil (DO)/coal at temperatures of 465 and 500 °C for reaction times of 12 and 18 h, under autogenous pressure in microautoclave reactors. ...

Ömer Gül; Leslie R. Rudnick; Harold H. Schobert

2006-05-18T23:59:59.000Z

60

Spatial variation of coke quality in the non-recovery beehive coke ovens.  

E-Print Network (OSTI)

??More than 50% of hot metal production worldwide takes place in blast furnaces. Coke is the most expensive raw material in the blast furnace. It… (more)

Segers, Magrieta

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Delayed coking of decant oil and coal in a laboratory-scale coking unit  

SciTech Connect

In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

2006-08-15T23:59:59.000Z

62

Market boundaries for coking-coal concentrates  

Science Journals Connector (OSTI)

The construction of geographic and commodity boundaries is considered in relation to the Russian market for coking-coal concentrates. In this market, uniform commodities ... construction of the market boundaries....

V. A. Brodskii

2011-05-01T23:59:59.000Z

63

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2004-09-26T23:59:59.000Z

64

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2003-09-26T23:59:59.000Z

65

Mozambique becomes a major coking coal exporter?  

SciTech Connect

In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

Ruffini, A.

2008-06-15T23:59:59.000Z

66

New and revised standards for coke production  

SciTech Connect

The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

67

Possibilities of coke manufacture in nonpollutant conditions  

SciTech Connect

The paper presents some possibilities to obtain coke briquettes from anthracite, using as binders petroleum pitch, wheat flour, cement, plaster, ashes from power-plants dried from the electrofilters. Specific thermal post-treatment were proposed for each case, such as: oxidation or heating at low temperatures (under 300 C). As a result the authors obtained coke briquettes to be used in small equipment, with no pollutant pyrogenetic treatment.

Barca, F.; Panaitescu, C.; Vidrighin, C.; Peleanu, I. [Politehnica Univ. Bucharest (Romania); Albastroiu, P. [S.C. ICEM S.A., Bucharest (Romania)

1994-12-31T23:59:59.000Z

68

Réactivité de l'anode et désulfuration : effet du niveau de calcination du coke.  

E-Print Network (OSTI)

??Les propriétés du coke et la performance des anodes sont affectées par le niveau de calcination du coke. Une densité de coke (VBD) élevée implique… (more)

Bergeron-Lagacé, Charles-Luc

2012-01-01T23:59:59.000Z

69

Physical, chemical and thermal changes of coals and coal maceral concentrates during coke formation.  

E-Print Network (OSTI)

??Research Doctorate - Doctor of Philosophy (PhD) The measured coke reactivity index (CRI) and coke strength after reaction (CSR) determined in experiments based on coke… (more)

Xie, Wei

2013-01-01T23:59:59.000Z

70

Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant  

SciTech Connect

Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

71

Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar  

SciTech Connect

In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

2006-10-15T23:59:59.000Z

72

Relationship between the technical parameters of cokes produced from blends of three Polish coals of different coking ability  

Science Journals Connector (OSTI)

The demand for metallurgical coke for blast furnaces is forcing the coking industry to look for new sources of coking coals. The physical and chemical parameters of coals used in coking blends determine the quality (reactivity and strength) of the finished cokes. This study examines the technical properties of the cokes produced from various blends of three Polish coals with different coking. These coals were collected from three mines: Zofiówka, Szczyg?owice, and Krupi?ski (Upper Silesian Coal Basin, Poland). The coal charges were coked in the laboratory scale, at temperatures of up to 1000 °C, in an inert atmosphere. The coke reactivity (index CRI) and the coke strength after reaction (CSR) were measured and correlated to the properties of parent coals using statistical analysis. The result of this study shows strong relationships between the concentration of the best coking coal (Zofiówka) in the blend and the CRI and CSR of the resulting coke. The CRI and CSR parameters for cokes obtained from single coals and from their blends show the additive character. This study also confirms the linear relationship between CRI and CSR parameters of the cokes.

A. Koszorek; M. Krzesi?ska; S. Pusz; B. Pilawa; B. Kwieci?ska

2009-01-01T23:59:59.000Z

73

Preparation and evaluation of hydrotreating catalysts based on activated carbon derived from oil sand petroleum coke  

Science Journals Connector (OSTI)

Novel Ni–Mo/activated carbon (AC) hydrotreating catalysts were prepared and evaluated for upgrading heavy vacuum gas oil (HVGO). The AC supports were derived from Alberta oil sand petroleum coke, i.e. fluid coke and/or delayed coke, hereafter referred to as OSP coke, through a chemical process. The BET surface area was as high as 2194 m2/g for the fluid coke derived AC and 2357 m2/g for the delayed coke derived AC. Both \\{ACs\\} contained a large number of micropores with pore volume as high as 1.2 cm3/g. Ni and Mo based active component precursors could be easily loaded on the activated carbon supports by chemical impregnation of nickel nitrate and ammonium molybdate followed by calcination in nitrogen at 773 K without further modification or oxidation treatment to the activated carbons. Scanning electron microscopy (SEM) observation showed highly porous surface structure of the bare activated carbon supports and well dispersed metal (oxide) precursor nanoparticles of 30–50 nm loaded on the AC supports. For comparison, two reference catalysts were also prepared by the same procedure but using commercial activated carbon and porous alumina as supports. After catalyst activation by sulfiding, the hydrotreating performance of the prepared catalysts was evaluated in a magnetically stirred autoclave with a HVGO feedstock to examine their hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities. Two commercial hydrotreating catalysts were also tested and compared under similar conditions with the same feed. The results showed that the catalysts based on the activated carbon supports prepared from OSP coke had better hydrotreating performance than the other catalysts. Scanning transmission electron microscopy (STEM) characterization of the catalysts after activation showed that small particles of nanostructure (2–5 nm in size) were evenly embedded in the carbon matrix except for some bigger particles that were located on the catalyst surface. Energy dispersive X-ray (EDX) spectroscopy revealed that these particles were composed of Ni, Mo and S elements. The dispersed nanoparticles formed the active sites and were responsible for the observed high HDS and HDN activity. Elemental analysis and surface characterization of the spent catalysts showed that the formation of coke precursors was favored on the alumina supported catalyst, which resulted in catalyst deactivation.

Yu Shi; Jinwen Chen; Jian Chen; Robb A. Macleod; Marek Malac

2012-01-01T23:59:59.000Z

74

Interactions among Different Fractions in the Thermoplastic State of Goonyella Coking Coal  

Science Journals Connector (OSTI)

An understanding of thermoplastic behavior in coking coal is essential in ascertaining appropriate procedures for the efficient conversion of slightly coking coals into good quality cokes. ... The conversion of coal into coke is detd. ...

Takahiro Yoshida; Toshimasa Takanohashi; Masashi Iino; Haruo Kumagai; Kenji Kato

2004-01-09T23:59:59.000Z

75

Hydrothermal Treatment of a Sub-bituminous Coal and Its Use in Coking Blends  

Science Journals Connector (OSTI)

Crucible coking determinations suggest that hydrothermal treatment can greatly increase the coke strength and the particle coke strength after reaction toward CO2 and decrease the coke reactivity when the hydrothermally treated coals were used in the coal blends instead of the raw coal. ... While the cokes from the crucible coking experiments were subjected to 800 rotations at a speed of 25 rpm, the weight percent of coke particles (>0.2 ... The coal charges were coked in the lab. ...

Hengfu Shui; Ye Wu; Zhicai Wang; Zhiping Lei; Changhui Lin; Shibiao Ren; Chunxiu Pan; Shigang Kang

2012-11-26T23:59:59.000Z

76

Elegest coal in coking batch at OAO EVRAZ ZSMK  

Science Journals Connector (OSTI)

The coking of batch with different proportions of Elegest coal from the Ulug-Khemsk Basin is investigated ... production conditions. The mechanical strength of the coke is improved when such coal is used in the b...

V. L. Osetkovskii; M. M. Naimark; V. G. Lupenko; A. E. Bazegskiy…

2013-03-01T23:59:59.000Z

77

Modification of poorly clinkering coal for use in coking  

Science Journals Connector (OSTI)

If coal is modified by the volatile products formed in pyrolysis, high-quality blast-furnace coke may be produced from batch with a smaller proportion of expensive clinkering coal. In such coking, the batch is mo...

E. I. Malyi

2014-03-01T23:59:59.000Z

78

Improving the preparation of coal batch for coking  

Science Journals Connector (OSTI)

Various methods of preparing coal for coking are analyzed. Laboratory experiments are conducted with a view to obtaining higher-quality coke from batch with a high content of poorly clinkering coal.

M. S. Chemerinskii; A. G. Starovoit; E. I. Malyi

2012-07-01T23:59:59.000Z

79

Coking of coal batch with different content of oxidized coal  

Science Journals Connector (OSTI)

The use of oxidized coal in coking batch increases the analytical moisture content and ... increases the oxygen content; reduces the gross coke yield and the yield of tar, benzene ... of carbon dioxide, pyrogenet...

D. V. Miroshnichenko; I. D. Drozdnik; Yu. S. Kaftan; N. B. Bidolenko…

2012-05-01T23:59:59.000Z

80

Kuznetsk Basin coking coal: Reserves and technological value  

Science Journals Connector (OSTI)

Reserves of Kuznetsk Basin coking coal are analyzed, in terms of rank composition and scope for coke production. The technological value of the coal is evaluated by the OOO VNITs Ugol...

V. P. Ivanov; V. Yu. Sushkov; A. A. Torgunakov; S. A. Pantykin

2008-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Determining the environmental and thermal characteristics of coke oven batteries  

Science Journals Connector (OSTI)

A method is proposed for assessing the environmental and thermal characteristics of coke oven batteries and is tested for coke oven batteries 1 and 5 at OAO Zaporozhkoks. On ... the basis of data for the environm...

E. I. Toryanik; A. L. Borisenko; A. S. Malysh; A. A. Lobov…

2009-12-01T23:59:59.000Z

82

Development of coke strength after reaction (CSR) at Dofasco  

SciTech Connect

In order to prevent coke degradation without detrimentally affecting blast furnace service life, Dofasco initiated a project to improve coke strength after reaction. The results of the program and Dofasco's prediction model are presented. 9 refs., 12 figs., 9 tabs.

T.W. Todoschuk; J.P. Price; J.F. Gransden

2004-03-01T23:59:59.000Z

83

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect

The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

2003-02-07T23:59:59.000Z

84

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation  

E-Print Network (OSTI)

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation and Coupled effect. Gascoin, P. Gillard, M. Bouchez, J. Steelant, Fuel Pyrolysis through Porous Media: Coke Formation Coke Formation and Coupled effect on Permeability2 G. Fau1* , N. Gascoin1 , P. Gillard1 , M. Bouchez2

Paris-Sud XI, Université de

85

Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE  

E-Print Network (OSTI)

Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

Karp, Larry S.

86

Influence of the coking properties of coal batch on coke properties  

Science Journals Connector (OSTI)

At OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK), research is undertaken to improve the optimization of coking batch. The basic approach, proposed by...K opt..., which characterizes the ...

D. A. Zavalishin; L. S. Belaya; G. R. Gainieva; V. G. Lupenko

2009-10-01T23:59:59.000Z

87

Preliminary Results from the Industrial Steam System Market Assessment  

E-Print Network (OSTI)

Distillation 92 6.433 113 2.8 123.3 238.8 Visbreaking 87 65 3 0.7 ( 1.3) 2.1 Coking Operations 170 1,771 110 14.1 (9A 115.1 Fluid Catalytic Cracking 100 5.051 166 23A 114A 189.8 Catalytic Hydrocracking 240 1,261 62 18.2 336 113.9 Catalytic Hydrotreating...

McGrath, G. P.; Wright, A. L.

88

Water protection in coke-plant design  

SciTech Connect

Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

89

Reducing dust emissions at OAO Alchevskkoks coke battery 10A  

SciTech Connect

Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

90

RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS  

SciTech Connect

The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

2002-05-01T23:59:59.000Z

91

Relation between the coking-chamber height, the coking pressure, and the packing density of regular or partially briquetted coal batch  

Science Journals Connector (OSTI)

Since coking coal is characterized by both elasticity and ductility in the plastic state, the coal charge of coke furnaces that contains a plastic layer exerts pressure (coking pressure) on the chamber walls. The...

L. V. Kopeliovich; V. I. Sukhorukov; V. I. Shvetsov

2012-07-01T23:59:59.000Z

92

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

1999-09-01T23:59:59.000Z

93

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

NONE

1998-09-01T23:59:59.000Z

94

Table 16. U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Exports U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 16. U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 162,796 79,217 201,795 242,013 340,944 -29.0 Canada* 73,859 17,837 112,348 91,696 161,596 -43.3 Mexico 88,535 60,517 86,721 149,052 176,163 -15.4 Other** 402 863 2,726 1,265 3,185 -60.3 South America Total 223 217 591 440 1,158 -62.0 Other** 223 217 591 440 1,158 -62.0 Europe Total 48,972 59,197 - 108,169 6 NM Other** 347 11,743 - 12,090 - - United Kingdom 48,625 47,454 - 96,079 6 NM Asia Total 317 553 633 870 4,778

95

Table 21. U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Imports U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 21. U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 10,284 2,293 159,462 12,577 183,712 -93.2 Canada 3,009 2,293 159,462 5,302 183,712 -97.1 Panama 7,275 - - 7,275 - - South America Total 25,267 13,030 88,424 38,297 106,612 -64.1 Brazil - - 78,595 - 78,595 - Colombia 25,267 13,030 9,829 38,297 28,017 36.7 Europe Total 6,044 40,281 165,027 46,325 485,791 -90.5 Czech Republic - 170 - 170 - - Spain 363 - - 363 - - Ukraine 5,681 40,111 5,047 45,792 53,543 -14.5 United Kingdom

96

Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions  

E-Print Network (OSTI)

generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

Paris-Sud XI, Université de

97

Effect of bulk density of coking coal on swelling pressure  

Science Journals Connector (OSTI)

Abstract Coking coals are the important raw materials for the iron and steel industries and play an important role on its sustainable development, especially on the stamp-charging coke making with the characteristics of increasing the bulk density. There is a significance on the reasonable usage of the coking coal resource with the reduced production cost, improved efficiency of the economy to develop the stamp-charging coke making technology. Important effects of the density of coking coal on the coking and caking properties were investigated. In the article, the maximum values of swelling pressure and variation of Laowan gas coal and Xinjian 1/3 coking coal, Longhu fat coal and Didao coking coal, which were mined at Shenyang and Qitaihe respectively, were investigated under different bulk densities during the coking. The results showed that when the values of density increased from 0.85 ton/m3 to 1.05 ton/m3, for the Laowan gas coal, swelling pressure variation and even the maximum value changed slightly. The swelling pressure was 3.63 \\{KPa\\} when the density was improved to 1.05 ton/m3; for the Xinjian 1/3 coking coal, the values of swelling pressure changed significantly and the maximum values was 82.88 \\{KPa\\} with the density improved to 1.05 when the coal was heated to 600°C. The coke porosity, which was investigated by automatic microphotometer, decreased from 47.4% to 33.1% with the increasing of the density from 0.85 ton/m3 to 1.05 ton/m3, and the decreased value was 14.3%. Meanwhile, the pore structures of four cokes were characterized by an optical microscope.

Jinfeng Bai; Chunwang Yang; Zhenning Zhao; Xiangyun Zhong; Yaru Zhang; Jun Xu; Bai Xi; Hongchun Liu

2013-01-01T23:59:59.000Z

98

Coke profile and effect on methane/ethylene conversion process.  

E-Print Network (OSTI)

??The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to… (more)

Al-Solami, Bandar

2012-01-01T23:59:59.000Z

99

Modélisation thermomécanique d'un piédroit de four à coke.  

E-Print Network (OSTI)

??Inscrite dans le cadre du projet européen Coke Oven Operating Limits, cette thèse porte sur la modélisation thermomécanique d'un piédroit de cokerie. Le piédroit est… (more)

Landreau, Matthieu

2009-01-01T23:59:59.000Z

100

The methods of steam coals usage for coke production  

SciTech Connect

Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Reducing power production costs by utilizing petroleum coke. Annual report  

SciTech Connect

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

Galbreath, K.C.

1998-07-01T23:59:59.000Z

102

Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information  

Open Energy Info (EERE)

navigation, search Name: Nippon Coke and Engineering & Sumitomo Corp JV Place: Tokyo, Japan Zip: 135-6007 Product: Japan-based natural graphite base anode materials joint...

103

Impact of Coal-Coking Effluent on Sediment Microbial Communities: a Multivariate Approach  

Science Journals Connector (OSTI)

...General Microbial Ecology Impact of Coal-Coking Effluent on Sediment Microbial...response to and recovery from coal-coking waste effluent was evaluated for...community response. Impact of coal-coking effluent on sediment microbial...

Gary S. Sayler; Timothy W. Sherrill; Richard E. Perkins; Lawrence M. Mallory; Michael P. Shiaris; Deana Pedersen

1982-11-01T23:59:59.000Z

104

Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination  

Energy.gov (U.S. Department of Energy (DOE))

Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

105

A novel technique for assessing the coking potential of coals/coal blends for non-recovery coke making process  

Science Journals Connector (OSTI)

Abstract In an effort to broaden the scope of coal selection, the authors have developed a novel procedure based on a coefficient, named as Composite Coking Potential (CCP). CCP value assesses the suitability of a coal/coal blend for producing coke of desired quality; measured by the parameter coke strength after reaction (CSR). The coking potential takes into account of various properties of the coals and their proportions in a given coal blend and convert them into a single value. This technique is having advantage since each of these parameters represents different aspects of the coking phenomena along with inter dependence of some of these parameters also exists. This makes the coal selection process extremely difficult and in majority of the cases, decision is taken based on experience. In this investigation, CCP model has been used for selecting the least expensive coal blends which will comply with the minimum coke quality requirements of blast furnace. The study confirms the inter relations between the CCP and the hot strength of coke i.e. CSR. Actual plant data of a non-recovery coke oven have been used for developing and validation of the model. The technique was successfully used in identifying cheaper coals for producing coke with desired quality.

H.P. Tiwari; P.K. Banerjee; V.K. Saxena

2013-01-01T23:59:59.000Z

106

DELAYED COKING OF SOLVENT EXTRACTED COAL FOR PRODUCTION OF ANODE GRADE COKE: CHARACTERIZATION OF SOLID AND LIQUID PRODUCTS.  

E-Print Network (OSTI)

??This study investigates the feasibility of using high temperature solvent extraction of coal to produce feedstock for the production of anode grade coke through delayed… (more)

Karri, Vamsi

2011-01-01T23:59:59.000Z

107

RELATION BETWEEN TEXTURE AND REACTIVITY IN METALLURGICAL COKES OBTAINED FROM COAL USING PETROLEUM COKE AS ADDITIVE  

E-Print Network (OSTI)

Reactivity to C O2 is, perhaps, the most importam quality parameter used to evaluate the performance of a metallurgical coke in the blast furnace [ 1]. A lot of effort has been made to study how it is influenced by the

J. J. Pis; J. A. Men~ndez; R. Alvarez; M. A. Diez; J. B. Parra

108

Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs  

E-Print Network (OSTI)

effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

Patel, S. S.

1982-01-01T23:59:59.000Z

109

Dry purification of aspirational air in coke-sorting systems with wet slaking of coke  

SciTech Connect

Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

110

Adsorptive removal of nitrogen from coal-based needle coke feedstocks using activated carbon.  

E-Print Network (OSTI)

??A low percentage of nitrogen in needle coke feedstocks is desired for the reduction of puffing during the process of graphitization of needle coke. The… (more)

Madala, Sreeja.

2009-01-01T23:59:59.000Z

111

Prediction of Coke Quality in Ironmaking Process: A Data Mining Approach.  

E-Print Network (OSTI)

??Coke is an indispensable material in Ironmaking process by blast furnace. To provide good and constant quality coke for stable and efficient blast furance operation… (more)

Hsieh, Hsu-huang

2006-01-01T23:59:59.000Z

112

Vacuum State/Refiner/Location  

U.S. Energy Information Administration (EIA) Indexed Site

Vacuum Vacuum State/Refiner/Location Barrels per Atmospheric Crude Oil Distillation Capacity Barrels per Operating Idle Operating Idle Downstream Charge Capacity Thermal Cracking Delayed Fluid Coking Visbreaking Other/Gas Calendar Day Stream Day Distillation Coking Oil Table 3. Capacity of Operable Petroleum Refineries by State as of January 1, 2013 (Barrels per Stream Day, Except Where Noted) ......................................................... Alabama 120,100 0 130,000 0 48,000 32,000 0 0 0 Goodway Refining LLC 4,100 0 5,000 0 0 0 0 0 0 ....................................................................................................................................................................................................

113

Effects of preheating and highly heat-conductive brick on coke quality  

SciTech Connect

In replacing the coke ovens available currently, the introduction of a combined technique of a preheated coal charging method (preheating temperature:175 C) and the use of highly heat-conductive brick is under examination for raising the productivity of coke ovens. With such background, a study of the effects of this combined technique on the coke quality, especially the coke size was conducted. The experimental results revealed that the primary size of coke produced by the combined technique is noticeably larger than that of the coke made from wet coal and after five revolutions of drum (equivalent to mechanical impact given at a time of dropping from coke oven chamber to wharf), the coke size reduces even compared with an ordinary coke. This may be due to the fact that the coke produced by the combined technique includes a lot of fissures inside the coke lump.

Fukuda, K.; Arima, T. [Nippon Steel Corp., Chiba (Japan). Process Technology, Research Labs.

1995-12-31T23:59:59.000Z

114

Research on the evolvement of morphology of coking coal during the coking process  

Science Journals Connector (OSTI)

Abstract The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising.

Xiangyun Zhong; Shiyong Wu; Yang Liu; Zhenning Zhao; Yaru Zhang; Jinfeng Bai; Jun Xu; Bai Xi

2013-01-01T23:59:59.000Z

115

Coke formation during pyrolysis of 1,2-dichloroethane  

SciTech Connect

Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

1995-12-31T23:59:59.000Z

116

Coke mineral transformations in the experimental blast furnace  

SciTech Connect

Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development (CCSD)

2008-09-15T23:59:59.000Z

117

Surveyor: A System for Generating Coherent Survey Articles for Scientific Topics Rahul Jha and Reed Coke  

E-Print Network (OSTI)

Coke Department of EECS University of Michigan Ann Arbor, MI, 48109 Dragomir Radev Department of EECS

Radev, Dragomir R.

118

Variation in coke properties within the blast-furnace shop  

SciTech Connect

In active production at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), samples of melt materials were taken during shutdown and during planned repairs at furnaces 1 and 8. In particular, coke was taken from the tuyere zone at different distances from the tuyere tip. The mass of the point samples was 2-15 kg, depending on the sampling zone. The material extracted from each zone underwent magnetic separation and screening by size class. The resulting coke sample was averaged out and divided into parts: one for determining the granulometric composition and mechanical strength; and the other for technical analysis and determination of the physicochemical properties of the coke.

E.N. Stepanov; I.I. Mel'nikov; V.P. Gridasov; A.A. Stepanova [OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), Magnitogorsk, (Russian Federation)

2009-04-15T23:59:59.000Z

119

Experimental Investigation of Natural Coke Steam Gasification in a Bench-Scale Fluidized Bed: Influences of Temperature and Oxygen Flow Rate  

Science Journals Connector (OSTI)

However, natural coke was restricted in application and research due to its hot burst, difficult ignition, and abradability. ... disordering as a cause is now a real possibility on the basis of correlated optical and x-ray diffraction data from samples analyzed from within a thermal aureole of a Tertiary dyke emplaced in Permian coal-bearing strata. ... The thermal characteristics of natural coke steam gasification in a fluidized bed were three-dimensionally (3D) simulated based on the computational fluid dynamics (CFD) method using Fluent code. ...

Wen-guo Xiang; Chang-sui Zhao; Ke-liang Pang

2009-01-05T23:59:59.000Z

120

Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry  

SciTech Connect

High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2005-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Graphitized needle cokes and natural graphites for lithium intercalation  

SciTech Connect

This paper examined effects of heat treatment and milling (before or after heat treatment) on the (electrochemical) intercalating ability of needle petroleum coke; natural graphite particles are included for comparison. 1 tab, 4 figs, 7 refs.

Tran, T.D.; Spellman, L.M.; Pekala, R.W. [Lawrence Livermore National Lab., CA (United States); Goldberger, W.M. [Superior Graphite Co., Chicago, IL (United States); Kinoshita, K. [Lawrence Berkeley National Lab., CA (United States)

1996-05-10T23:59:59.000Z

122

Co-gasification of petroleum coke and biomass  

Science Journals Connector (OSTI)

Abstract Gasification may be an attractive alternative for converting heavy oil residue – petroleum coke into valuable synthetic gas. Due to the low reactivity of petroleum coke, it is maybe preferable to convert it in combination with other fuels such as biomass. Co-gasification of petroleum coke and biomass was studied in an atmospheric bubbling fluidised bed reactor and a thermogravimetric analyser (TGA) at KTH Royal University of Technology. Biomass ash in the blends was found to have a catalytic effect on the reactivity of petroleum coke during co-gasification. Furthermore, this synergetic effect between biomass and petcoke was observed in the kinetics data. The activation energy Ea determined from the Arrhenius law for pure petcoke steam gasification in the TGA was 121.5 kJ/mol, whereas for the 50/50 mixture it was 96.3, and for the 20/80 blend – 83.5 kJ/mol.

Vera Nemanova; Araz Abedini; Truls Liliedahl; Klas Engvall

2014-01-01T23:59:59.000Z

123

Variation in mineral composition of coal during enrichment and coking  

Science Journals Connector (OSTI)

The parameters I b and B b used in developing an optimal coking-batch composition are determined from data on ... of the ash in Donetsk Basin and other coal. It is found that, when...

M. L. Ulanovskii; A. N. Likhenko

2009-06-01T23:59:59.000Z

124

Coking properties of coal pitch in coal batch  

Science Journals Connector (OSTI)

The coking properties of coal pitch depend significantly on its fractional composition, ... : 2: 2. This is typical of coal pitch with a softening temperature of 75– ... Such pitch is the best clinkering additive...

S. G. Gagarin; Yu. I. Neshin

2011-09-01T23:59:59.000Z

125

Coal preparation, coking, and slaking in China and Japan  

Science Journals Connector (OSTI)

In China and Japan, measures have been developed to maintain constant coke quality and hence permit economical and stable blast-furnace operation with the injection of coal-dust fuel; and to reduce the cost of th...

I. F. Kurunov; P. V. Lizogub; O. V. Golubev

2010-09-01T23:59:59.000Z

126

Coking theory: Internal stress in the coal batch  

Science Journals Connector (OSTI)

The development of local internal stress in the coal batch is analyzed on the basis of ... theoretical and experimental data. Its influence on coke quality is demonstrated. The influence of mineralized ... large ...

V. I. Sukhorukov

2011-09-01T23:59:59.000Z

127

Share a Coke - An Investigation of Social Media Marketing.  

E-Print Network (OSTI)

??This investigation examines the underlying factors behind audience participation in Coca-Cola’s ‘Share a Coke’ campaign, which became a trend on social media in Denmark in… (more)

Trougaard, Victor Frederic Wagn

2014-01-01T23:59:59.000Z

128

RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES  

SciTech Connect

Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

2003-06-01T23:59:59.000Z

129

Table 38. Coal Stocks at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Stocks at Coke Plants by Census Division Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 38. Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Census Division June 30, 2013 March 31, 2013 June 30, 2012 Percent Change (June 30) 2013 versus 2012 Middle Atlantic w w w w East North Central 1,313 1,177 1,326 -1.0 South Atlantic w w w w East South Central w w w w U.S. Total 2,500 2,207 2,295 8.9 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants.'

130

SOURCE ACTIVITY TITLE: SOLID FUEL TRANSFORMATION PLANTS Coke Oven Furnaces Coke Oven (Door Leakage and Extinction) NOSE CODE: 104.12 NFR CODE:  

E-Print Network (OSTI)

1 ACTIVITIES INCLUDED Coke-production in general can be divided into the following steps: Coal handling and storage, coke oven charging, coal coking, extinction of coke, and coke oven gas purification. Combustion in coke oven furnaces (SNAP 010406) is treated in this chapter as well as door leakage and extinction (SNAP 040201). Figure 1-1 gives a key plan of a coke plant with emission relevant process steps and the byproduct recovery section. Figure 1-1: Key plan of a coke plant (Rentz et al. 1995) C o a l S lu d g e B l a s t F u r n a c e G a s f r o m S t e e l M il l A i r E m is s io n s G a s H o ld e r

Ic Activities; So Nox Nmv

131

Priorities in the design of chemical shops at coke plants  

SciTech Connect

Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

132

Six years of ABB-CE, petcoke and fluid beds  

SciTech Connect

Combustion Engineering, Inc. (ABB-CE) has constructed twenty circulating fluidized bed (CFB) boilers and 2 bubbling fluidized bed (BFB) boilers throughout North America. The units were designed to fire a wide range of fuels from anthracite culm to coals, lignites and biomasses. Based on fuels economics, some plants have decided to use petroleum coke as a replacement or supplemental fuel. The fluid bed boiler can inherently handle a wide range of fuel types without requiring modification or down-rating. ABB-CE units have a significant amount of petroleum coke operating experience firing 100% petroleum coke with no supplemental fuel ranging from the first commercial CFB unit at New Brunswick Power to the largest CFB unit at Texas New Mexico Power. Petroleum coke is also being co-fired with anthracite culm at the Scott Paper CFB. The world`s largest operating BFB, the 160 MWe unit at TVA`s Shawnee plant, has also been co-firing petroleum coke. The ability of the fluidized bed technology to fire low volatile fuels such as petroleum cokes, efficiently and in an environmentally acceptable manner will result in the use of this technology as a preferred means of power generation. This report gives a brief description of the petroleum coke firing experiences with ABB-CE fluid bed steam generators over the last six years.

Tanca, M.

1994-12-31T23:59:59.000Z

133

Laboratory-Scale Coking of Coal?Petroleum Mixtures in Sealed Reactors  

Science Journals Connector (OSTI)

Further evidence for coal?petroleum interactions in this system is exhibited by the fact that (i) the product slates from the co-coking reactions are not linear combinations of the products from the feedstocks reacted individually and (ii) the fluidity profiles of the Powellton?resid mixtures are similar to those for two interacting coking coals. ... The boiling distribution of the oils from co-coking resembles that observed when the Powellton coal was coked in the absence of resid. ... In addition, the co-coking reactions show a “coke jump” that occurs at ?465 °C; this jump is not observed when the coal or petroleum feedstocks are reacted individually. ...

Anne E. Fickinger; Mark W. Badger; Gareth D. Mitchell; Harold H. Schobert

2004-05-19T23:59:59.000Z

134

Prediction of metallurgical coke strength from the petrographic composition of coal blends  

SciTech Connect

Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

2009-07-01T23:59:59.000Z

135

Preparation and coking properties of coal maceral concentrates  

Science Journals Connector (OSTI)

Abstract The concentrates with different maceral contents were obtained from Kailuan coking coals with different coal ranks ( R o,ran ? varying from 0.88% to 1.73%) by float–sink separation in lab. Then these concentrates were characterized by proximate analysis, ultimate analysis, petrography analysis and coking index determination. The results show that the vitrinite is characterized as nature of lower carbon content, higher hydrogen content, higher volatile matter and stronger caking property compared to inertinite. The relationships between variation rate of volatile matter and maximum volatile matter and coal ranks are identified, and a linear model is developed for fast determination of the maceral contents. Compared to inertinite-rich concentrate, the blending ratio of vitrinite-rich concentrate is increased by 13%, which is considered to be a potential technique based on maceral separation for expanding the coking coal resources.

Lei Zhang; Wenli Liu; Dongpo Men

2014-01-01T23:59:59.000Z

136

Coking Plants, Coal-to-gas Plants, Gas Production and Distribution  

Science Journals Connector (OSTI)

This environmental brief covers various coal upgrading technologies, incl. coking and low-temperature carbonization as processes yielding the target products coke and gas plus tar products and diverse...

1995-01-01T23:59:59.000Z

137

Determining the coking properties and technological value of coal and coal mixtures  

Science Journals Connector (OSTI)

A method is developed for determining the coking properties and technological value of coal from newly identified beds or new sections of existing mines. The coking properties are assessed on the basis of predict...

A. S. Stankevich; V. S. Stankevich

2012-01-01T23:59:59.000Z

138

Influence of frothing-agent oxidation on coking-coal flotation  

Science Journals Connector (OSTI)

The oxidation of frothing agents (KOBS, OPPG-3, and the tar fraction of peat bitumen) affects coking-coal flotation. The tar fraction of Krapivinsk-peat ... provides the basis for a frothing agent in coking-coal ...

M. Yu. Klimovich; S. I. Zherebtsov; Yu. V. Musin; A. I. Moiseev…

2008-12-01T23:59:59.000Z

139

Calculating the relative value of coal in Russian coking-coal markets  

Science Journals Connector (OSTI)

In order to improve the pricing of Russian coking coal, a method is proposed for calculating the relative technological value of purchased coking-coal batches. The basic idea is to compare the parameters of optim...

V. A. Brodskii; E. V. Brodskaya

2009-03-01T23:59:59.000Z

140

Coal resources at OOO Metinvest Holding and their optimal coking at PAO AKKhZ  

Science Journals Connector (OSTI)

The coal resources at OOO Metinvest Holding are considered, in a climate of increase requirements on coke quality and self-reliance. The parameters of high-quality coke are outlined, and the corresponding require...

V. G. Gusak; V. I. Gavrilyuk; M. S. Magomedov; A. A. Pasternak…

2013-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Role of coke characteristics in the regeneration of a catalyst for the MTG process  

SciTech Connect

The effect on combustion in air of the nature of the coke deposited in HZSM5 zeolites used in the MTG process has been studied. This coke is highly hydrogenated and unstable, and its H/C ratio decreases during combustion or when a previous thermal treatment is carried out. Coke H/C ratio greatly affects its reactivity during combustion; consequently, a severe thermal equilibration treatment is recommended for reproducibility of results. Combustion kinetics of equilibrated coke, when it is released from the catalyst, has been proven to be similar to that of the coke deposited on other catalysts for several processes. Lower coke reactivity for aging and combustion, on being deposited within the HZSM5 zeolite, must be attributed to air-coke contact restrictions due to the location of the coke, which partially impedes the flow of air into the crystals.

Ortega, J.M.; Gayubo, A.G.; Aguayo, A.T.; Benito, P.L.; Bilbao, J. [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica] [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica

1997-01-01T23:59:59.000Z

142

New packing in absorption systems for trapping benzene from coke-oven gas  

SciTech Connect

The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

143

Coke in the Cross Hairs: Water, India, and the University of Michigan  

E-Print Network (OSTI)

Coke in the Cross Hairs: Water, India, and the University of Michigan case 1-429-098 July 25, 2010, where "Killer Coke" banners had hung days before. Students were holed away studying for finals, the demonstrations were over and Coke was once again flowing from machines at the Michigan Union. That morning

Edwards, Paul N.

144

Table 33. Coal Carbonized at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Carbonized at Coke Plants by Census Division Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 33. Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,051 2,997 3,092 6,048 6,156 -1.8 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,471 5,280 5,296 10,751 10,579 1.6 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

145

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents (OSTI)

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

146

Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*  

E-Print Network (OSTI)

Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm variables are prices and advertising. We divide each firm's continuous price-advertising action space

Lansky, Joshua

147

Lummus process turns coal tar pitch to coke  

Science Journals Connector (OSTI)

Lummus Co. has developed a process for converting coal tar pitch to coke and now has a full-scale commercial plant in operation in Japan. The plant, which is owned by Nittetsu Chemical Industrial Co., a subsidiary of Yawata Iron and Steel, is producing ...

1968-12-09T23:59:59.000Z

148

The development of coke smelting and the industrial revolution  

E-Print Network (OSTI)

Abraham Darby and the origins of the industrial revolution in Britain. Alan Macfarlane talks to John about the reasons for the area near Birmingham becoming the epi-centre of the industrial development, and the development of coke furnaces and iron...

Macfarlane, Alan

2004-08-05T23:59:59.000Z

149

Coke quality for blast furnaces with coal-dust fuel  

SciTech Connect

Recently, plans have been developed for the introduction of pulverized coal injection (PCI) at various Russian metallurgical enterprises. The main incentive for switching to PCI is the recent price rises for Russian natural gas. The paper discusses the quality of coke for PCI into blast furnaces.

Y.A. Zolotukhin; N.S. Andreichikov [Eastern Coal-Chemistry Institute, Yekaterinburg (Russian Federation)

2009-07-01T23:59:59.000Z

150

Table 23. Coal Receipts at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Receipts at Coke Plants by Census Division Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 23. Coal Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,189 2,679 3,225 5,867 5,993 -2.1 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,770 4,962 5,370 10,732 10,440 2.8 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

151

Identifying Opportunities for Industrial Energy Conservation  

E-Print Network (OSTI)

. Cement Making 5. Vacuum Distillation 4. Cooking 6. Hydrocracking 5. Glass Melting 7. Hydrogen Production 6. Copper Smelting 8. Hydrorefining/Hydrotreating 7. Miscellaneous 9. Visbreaking 10. Petroleum Coking 11. Desulfurization C. Iron and Steel I...

Hoffman, A. R.

1981-01-01T23:59:59.000Z

152

The Role of Semifusinite in Plasticity Development for a Coking Coal  

Science Journals Connector (OSTI)

Coal rank is a factor of great importance in plasticity development during carbonization, since only some bituminous coals swell in a satisfactory manner and then resolidify to produce good commercial cokes. ... Diessel studied the carbonization behavior of the inertinite macerals in Australian coals by carrying out tests up to 1000 °C where the optical characteristics of the coked entities were correlated with their noncoked counterparts. ... For instance, large-scale coking experiments of some Australian coals containing more than 45% inertinite produced good quality coke, while a Carboniferous coal with that high of an inertinite content gave only a very poor coke. ...

M. Mercedes Maroto-Valer; Darrell N. Taulbee; John M. Andrésen; James C. Hower; Colin E. Snape

1998-08-27T23:59:59.000Z

153

Theoretical and experimental foundations for preparing coke for blast-furnace smelting  

SciTech Connect

This article examines the preparation of coke for blast-furnace smelting by a method that most fully meets the requirements of blast-furnace technology: screening of the -36 mm fraction, the separation of nut coke of the 15-36 mm fraction, and its charging into the furnace in a mixture with the iron-ore-bearing charge components. An analysis is made of trial use of coke of the Premium class on blast furnace No. 5 at the Enakievo Metallurgical Plant. Use of this coke makes it possible to reduce the consumption of skip coke by 3.2-4.1%.

A.L. Podkorytov; A.M. Kuznetsov; E.N. Dymchenko; V.P. Padalka; S.L. Yaroshevskii; A.V. Kuzin [Enakievo Metallurgical Plant, Enakievo (Ukraine)

2009-05-15T23:59:59.000Z

154

Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas  

SciTech Connect

The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

155

Characterization of Liquids Derived From Laboratory Coking of Decant Oil and Co-Coking of Pittsburgh Seam Bituminous Coal with Decant Oil  

Science Journals Connector (OSTI)

(41-43) Co-coking of decant oil/coal blend produced higher coke and gas yields but less liquid product than those of coking. ... When the same decant oil was blended with the Pittsburgh Seam coal and then delayed co-coked, the overhead liquid contained 2.1% gasoline, 3.6% jet fuel, 4.6% diesel, and 88.8% fuel oil on average. ... It is also possible that catalytic cracking reactions may occur via the coal mineral matter (e.g., clays, which are abundant minerals in coals, can serve as cracking catalysts) (Table 1). ...

Ömer Gül; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert

2009-04-21T23:59:59.000Z

156

Fluid catalytic cracking of heavy petroleum fractions  

SciTech Connect

A process is claimed for fluid catalytic cracking of residuum and other heavy oils comprising of gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment. The heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low btu gas stream comprising of sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1100/sup 0/F. To about 2200/sup 0/F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.

McHenry, K.W.

1981-06-30T23:59:59.000Z

157

Coke County, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Coke County, Texas: Energy Resources Coke County, Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 31.8277663°, -100.5296115° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":31.8277663,"lon":-100.5296115,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

158

Integrated coke, asphalt and jet fuel production process and apparatus  

DOE Patents (OSTI)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

Shang, Jer Y. (McLean, VA)

1991-01-01T23:59:59.000Z

159

Pricing of Australia's coking coal exports: A regional hedonic analysis  

Science Journals Connector (OSTI)

Black coal is Australia's most important export commodity, but the profitability of the domestic coal industry has been low relative to the mining sector average. As a consequence, a key policy issue in Australia has been the extent to which Japan's coal pricing and investment policies have influenced coal market outcomes. In this paper, a regional hedonic pricing model of Australia's coking coal exports is estimated for the period JFY1989 to 1996. Non-Japan regional intercept dummy variables were found to be significantly different from zero, although these varied across coal categories and years. However, the empirical evidence indicates that Japan does not pay significantly lower prices relative to other major export markets for coking coal of a given quality.

Lindsay Hogan; Sally Thorpe; Anthony Swan; Simon Middleton

1999-01-01T23:59:59.000Z

160

Coke profile and effect on methane/ethylene conversion process  

E-Print Network (OSTI)

balance in catalytic cracking. It is also extremely important in the dehydrogenation of butane to butadiene, because coke formation limits the cycle time before regeneration of the catalyst is needed. There are many add that equally important examples..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

Al-Solami, Bandar

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

New environmental concepts in the chemical and coke industries  

SciTech Connect

We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

2007-05-15T23:59:59.000Z

162

Table 17. Average Price of U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Exports Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 17. Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 240.59 241.38 218.40 240.85 225.80 6.7 Canada* 147.49 330.47 243.04 183.08 286.56 -36.1 Mexico 316.57 211.63 189.12 273.97 171.71 59.6 Other** 612.42 485.63 134.48 525.92 135.04 289.5 South America Total 140.65 156.15 322.70 148.29 250.36 -40.8 Other** 140.65 156.15 322.70 148.29 250.36 -40.8 Europe Total 259.26 255.24 - 257.06 427.83 -39.9 Other**

163

Table 22. Average Price of U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Imports Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 22. Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 263.21 252.66 353.05 261.29 356.01 -26.6 Canada 263.51 252.66 353.05 258.82 356.01 -27.3 Panama 263.09 - - 263.09 - - South America Total 196.86 194.14 175.88 195.94 181.01 8.2 Brazil - - 157.60 - 157.60 - Colombia 196.86 194.14 322.06 195.94 246.68 -20.6 Europe Total 181.55 232.13 385.65 225.53 384.96 -41.4 Czech Republic - 475.91 - 475.91 - - Spain 360.51

164

Influence of the permeability of the coal plastic layer on coking pressure  

Science Journals Connector (OSTI)

Ten coals of different rank and coking pressure characteristics were chosen in order to study the time of occurrence of the phenomena that take place during the coking of a coal and the way they affect the generation of dangerous coking pressures. Parameters derived from thermoplastic, thermogravimetric and permeability tests were studied together with semicoke contraction and the coking pressure generated by the coals in a movable wall oven. It was found that for safe coals, the maximum evolution of volatile matter occurs near the temperature of maximum fluidity. The position of the maximum rate of volatile matter evolution with respect to the zone of low permeability varies depending on the coking pressure characteristics of the coals. In addition, the relationship between the period of low permeability to the resolidification temperature may serve to indicate the degree of dangerousness of a coal. The fissure pattern of the semicoke was found to be related to the coking pressure and semicoke contraction.

M.D. Casal; E. Díaz-Faes; R. Alvarez; M.A. Díez; C. Barriocanal

2006-01-01T23:59:59.000Z

165

An Integrated Model of Coal/Coke Combustion in a Blast Furnace  

Science Journals Connector (OSTI)

A three?dimensional integrated mathematical model of the combustion of pulverized coal and coke is developed. The model is applied to the region of lance?blowpipe?tuyere?raceway?coke bed to simulate the operation of pulverized coal injection in an ironmaking blast furnace. The model integrates two parts: pulverized coal combustion model in the blowpipe?tuyere?raceway?coke bed and the coke combustion model in the coke bed. The model is validated against the measurements in terms of coal burnout and gas composition respectively. The comprehensive in?furnace phenomena are simulated in the raceway and coke bed in terms of flow temperature gas composition and coal burning characteristics. In addition underlying mechanisms for the in?furnace phenomena are analyzed. The model provides a cost?effective tool for understanding and optimizing the in?furnace flow?thermo?chemical characteristics of the PCI process in full?scale blast furnaces.

Y. S. Shen; B. Y. Guo; A. B. Yu; P. Austin; P. Zulli

2010-01-01T23:59:59.000Z

166

Assessing the utility of coal’s elementary composition in predicting the yield of coking products  

Science Journals Connector (OSTI)

Elementary analysis of the organic mass of coal does not provide sufficient information to predict the yield of coking products, since it does not reflect the...

M. L. Ulanovskii

2012-03-01T23:59:59.000Z

167

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network (OSTI)

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

168

Prediction of demand trends of coking coal in China based on grey linear regression composition model  

Science Journals Connector (OSTI)

The scarce of coking coal resources in China results in its short supply. By establishing a grey linear regression composition model, this paper has greatly improved the inadequacy of grey system prediction model and regression analysis method in trend prediction and finished the prediction of demand trends of coking coal in China with this model. As result of the prediction, it is estimated that in the next decade, the demand for coking coal in China will experience a growth trend; China's demand for coking coal will reach more than 1.535 billion tons by 2015, reach the maximum of 1.639 billion tons by 2020 and drop in 2025.

Hai-Dong Zhou; Qiang Wu; Min Fang; Zhong-Bao Ren; Li-Fei Jin

2013-01-01T23:59:59.000Z

169

Balance of supply and demand in the Russian market for coking-coal concentrates  

Science Journals Connector (OSTI)

Various methods are considered for calculating the balance of supply and demand in the Russian market for coking-coal concentrates within the planning (prediction) period....

V. A. Brodskii

2010-11-01T23:59:59.000Z

170

Co-gasification of biomass with coal and oil sands coke in a drop tube furnace.  

E-Print Network (OSTI)

??Chars were obtained from individual fuels and blends with different blend ratios of coal, coke and biomass in Drop Tube Furnace at different temperatures. Based… (more)

Gao, Chen

2010-01-01T23:59:59.000Z

171

Pyrolysis behavior of coal and petroleum coke at high temperature and high pressure.  

E-Print Network (OSTI)

??While pyrolysis of coal is a well-studied thermal process, little is known about pressurized pyrolysis of coal and petroleum coke. This study aims to interpret… (more)

Wagner, David Ray

2011-01-01T23:59:59.000Z

172

Development Of Reclamation Substrates For Alberta Oil Sands Using Mature Fine Tailings And Coke.  

E-Print Network (OSTI)

??Mature fine tailings and coke are waste products of the oil sands industry with potential for reclamation. A greenhouse study assessed whether substrates of various… (more)

Luna-Wolter, Gabriela L.

2012-01-01T23:59:59.000Z

173

Investigating factors that influence carbon dissolution from Coke into Molten iron.  

E-Print Network (OSTI)

??The need for more efficient blast furnaces is even greater now that there are stricter environmental regulations on greenhouse gas (GHG) emissions. Coke within the… (more)

Cham, S. Tsuey

2007-01-01T23:59:59.000Z

174

Simulation of Combustion and Thermal-flow Inside a Petroleum Coke Rotary Calcining Kiln.  

E-Print Network (OSTI)

??Calcined coke is the best material for making carbon anodes for smelting of alumina to aluminum. Calcining is an energy intensive industry and a significant… (more)

Zhang, Zexuan

2007-01-01T23:59:59.000Z

175

Characterization of Coke Properties at Tuyere Level of an Operating Blast Furnace.  

E-Print Network (OSTI)

??Coke performance in an operating blast furnace is often empirically related to popular bench-scale tests, which are performed at relative much lower temperatures. Due to… (more)

Ye, Zhuozhu

2014-01-01T23:59:59.000Z

176

Preparation of Activated Carbon from Oil Sands Coke by Chemical and Physical Activation Techniques.  

E-Print Network (OSTI)

??Oil sands coke is a by-product resulting from the upgrading of heavy crude bitumen to light synthetic oil. This research investigates the preparation of activated… (more)

Morshed, Golam

2012-01-01T23:59:59.000Z

177

The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties  

SciTech Connect

In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

2006-07-01T23:59:59.000Z

178

Developing indicators for the assessment and proper management of the different levels of exposure to polycyclic aromatic hydrocarbons (PAH)s generally associated with coke-oven workers.  

E-Print Network (OSTI)

??Coke ovens may occur in the aluminium, steel, graphite, electrical, and construction industries. In the work area coke-oven workers may be exposed to various chemical… (more)

Wang, Tianyuan

2011-01-01T23:59:59.000Z

179

CHARACTERIZATION OF COAL- AND PETROLEUM-DERIVED BINDER PITCHES AND THE INTERACTION OF PITCH/COKE MIXTURES IN PRE-BAKED CARBON ANODES.  

E-Print Network (OSTI)

??Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder.… (more)

Suriyapraphadilok, Uthaiporn

2008-01-01T23:59:59.000Z

180

The effects of petroleum coke amendments on macrophytes and aquatic invertebrates in northern Alberta, Canada constructed wetlands.  

E-Print Network (OSTI)

??Oil-sands operators of Fort McMurray, Alberta produce six million t/y of petroleum coke. The use of coke to stabilize clay-dominated mine tailings in constructed wetlands… (more)

Baker, Leanne F.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Predicting CSR and CRI of coke on the basis of the chemical and petrographic parameters of the coal batch and the coking conditions  

Science Journals Connector (OSTI)

A model is developed for predicting the postreactive strength CSR and reactivity CRI of coke. The model adequately reflects the dependence of ... on the chemical and petrographic parameters of the coal batch, tak...

A. S. Stankevich; R. R. Gilyazetdinov; N. K. Popova; D. A. Koshkarov

2008-09-01T23:59:59.000Z

182

Modification of sub-bituminous coal by steam treatment: Caking and coking properties  

Science Journals Connector (OSTI)

A Chinese sub-bituminous Shenfu (SF) coal was steam treated under atmospheric pressure and the caking and coking properties of the treated coals were evaluated by caking indexes (GRI) and crucible coking characterizations. The results show that steam treatment can obviously increase the GRI of SF coal. When the steam treated coals were used in the coal blends instead of SF raw coal, the micro-strength index (MSI) and particle coke strength after reaction (PSR) of the coke increased, and particle coke reactivity index (PRI) decreased, which are beneficial for metallurgical coke to increase the gas permeability in blast furnace. The quality of the coke obtained from 8% of 200 °C steam treated SF coal in coal blends gets to that of the coke obtained from the standard coal blends, in which there was no SF coal addition in the coal blends. The removal of oxygen groups, especially hydroxyl group thus favoring the breakage of the coal macromolecules and allowing the treated coal formation of much more amount of hydrocarbons, may be responsible for the modified results. The mechanism of the steam treatment was proposed based on the elemental analysis, thermo gravimetric (TG) and FTIR spectrometer characterizations of the steam treated coal.

Hengfu Shui; Haiping Li; Hongtao Chang; Zhicai Wang; Zhi Gao; Zhiping Lei; Shibiao Ren

2011-01-01T23:59:59.000Z

183

Study on Further Treatment of Coal Coking Wastewater by Ultrasound Wave, Fenton's Reagent and Coagulation  

Science Journals Connector (OSTI)

The study on further treatment of coal coking wastewater by ultrasound wave, Fenton's reagent and coagulation was carried out in this paper at the first time, Furthermore, this paper discussed the optimum cooperative reaction condition of their combined ... Keywords: ultrasound wave, coke plant wastewater, Fenton reagent, coagulation

Jun Shi; Liangbo Zhang

2009-10-01T23:59:59.000Z

184

Analytical input-output and supply chain study of China's coke and steel sectors  

E-Print Network (OSTI)

I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

Li, Yu, 1976-

2004-01-01T23:59:59.000Z

185

Cyanide Leaching from Soil Developed from Coking Plant Purifier Waste as Influenced by Citrate  

Science Journals Connector (OSTI)

...Coking Plant Purifier Waste as Influenced by Citrate...developed from gas purifier waste was investigated. Without...developed from gas purifier waste near a former coking...for the iron and steel industries. Their gas was a by-product...2003). During coal gasification, hydrogen cyanide...

Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar

186

Influence of coal on coke properties and blast-furnace operation  

SciTech Connect

With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

2007-07-01T23:59:59.000Z

187

Carbonization of Coal Effects of Variation of Rate of Heating during the Carbonization of a Typical Coking Coal  

Science Journals Connector (OSTI)

Carbonization of Coal Effects of Variation of Rate of Heating during the Carbonization of a Typical Coking Coal ...

William B. Warren

1935-01-01T23:59:59.000Z

188

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal  

Science Journals Connector (OSTI)

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal ...

William B. Warren

1935-01-01T23:59:59.000Z

189

Atmospheric Oxidation of Coal at Moderate Temperatures. Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals.  

Science Journals Connector (OSTI)

Atmospheric Oxidation of Coal at Moderate Temperatures. ... Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals. ...

L Schmidt; J Elder; J Davis

1940-01-01T23:59:59.000Z

190

Acidity deterioration and coke deposition in a HZSM5 zeolite in the MTG process  

Science Journals Connector (OSTI)

Summary The total acidity deterioration and the acidity strength distribution of a catalyst prepared from a H-ZSM-5 zeolite has been studied in the MTG process carried out in catalytic chamber and in an isothermal fixed bed integral reactor. The acidity deterioration has been related to coke deposition. The evolution of the acidic structure and of coke deposition has been analysed in situ by diffuse reflectance FTIR in a catalytic chamber. The effect of operating conditions (time on stream and temperature) on acidity deterioration, coke deposition and coke nature has been studied from experiments in a fixed integral reactor. The technique for studying acidity yields a reproducible measurement of total acidity and acidity strength distribution of the catalyst deactivated by coke. The NH3 adsorption-desorption is measured by combination of scanning differential calorimetry and the FTIR analysis of the products desorbed.

A.T. Aguayo; P.L. Benito; A.G. Gayubo; M. Olazar; J. Bilbao

1994-01-01T23:59:59.000Z

191

Innovative coke oven gas cleaning system for retrofit applications  

SciTech Connect

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

192

Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast  

E-Print Network (OSTI)

of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

Leu, Tzong-Shyng "Jeremy"

193

Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)  

E-Print Network (OSTI)

- 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

Boyer, Edmond

194

Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil  

SciTech Connect

In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

2009-05-15T23:59:59.000Z

195

Gas treatment and by-products recovery of Thailand`s first coke plant  

SciTech Connect

Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

1997-12-31T23:59:59.000Z

196

Nuclear Magnetic Resonance and Ruthenium Ion Catalyzed Oxidation Reaction Analysis for Further Development of Aromatic Ring Size through the Heat Treatment of Coking Coals at >500 °C  

Science Journals Connector (OSTI)

The strategy for coal blending is based on many empirical viewpoints, while scientific findings are believed to develop new criteria for obtaining high-quality coke from not only coking coals but also coking coals coupled with noncoking coals. ... by TEM and by comparing the microtextures of their cokes. ...

Koh Kidena; Koji Matsumoto; Satoru Murata; Masakatsu Nomura

2004-10-23T23:59:59.000Z

197

Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2008-09-15T23:59:59.000Z

198

Annual book of ASTM Standards 2005. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect

The first part covers standards for gaseous fuels. The standard part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrographic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2005-09-15T23:59:59.000Z

199

Investigation of the effects of heating rate on coking of shale during retorting  

SciTech Connect

The retorting of oil shale distributes organic carbon among three possible products: the liquid product, the noncondensible product, and the residual carbon (coke). The production of coke is detrimental because of the economic effects caused by the loss of organic carbon to this relatively intractable carbon form. Two reference oil shales, a Mahogany zone, Parachute Creek Member, Green River Formation oil shale from Colorado and a Clegg Creek Member, New Albany oil shale from Kentucky, were studied to evaluate the conditions that affect coke production during retorting. The variable that was studied in these experiments was the heating rate during retorting because heating rate has been indicated to have a direct effect on coke production (Burnham and Clarkson 1980). The six heating rates investigated covered the range from 1 to 650/degree/C/h (1.8 to 1169/degree/F/h). The data collected during these experiments were evaluated statistically in order to identify trends. The data for the eastern reference oil shale indicated a decrease in coke formation with increases in the heating rate. The liquid and noncondensible product yields both increased with increasing heating rate. The distribution of products in relation to retort heating rate follows the model suggested by Burnham and Clarkson (1980). Coke production during the retorting of western reference oil shale was found to be constant in relation to heating rate. The liquid product yield increased with increasing heating rate but the trend could not be verified at the 95% confidence level. The coke production observed in these experiments does not follow the prediction of the model. This may indicate that coke formation occurs early in the retorting process and may be limited by the availability of organic materials that form coke. 6 refs., 10 tabs.

Guffey, F.D.; Hunter, D.E.

1988-02-01T23:59:59.000Z

200

Caking and coking properties of the thermal dissolution soluble fraction of a fat coal  

Science Journals Connector (OSTI)

Abstract In the coal blending for coke-making, fat coal has a very important role for the caking and coking properties of the coal blends. In this study, a fat coal was thermally dissolved, and the caking and coking properties of the thermal dissolution soluble factions (TDSFs) from different solvents and temperatures were characterized. It was found that the caking properties of \\{TDSFs\\} were better than that of fat raw coal. The \\{TDSFs\\} obtained from non-polar solvents have a higher caking property than those obtained from polar solvents at the same thermal dissolution (TD) temperature. During TD process, polar solvents can thermally dissolve more polyaromatic compounds into TDSF, thus increasing the softening temperature and decreasing the caking property of the TDSF. For the same TD solvent, the \\{TDSFs\\} obtained from higher temperatures have a lower caking property compared to those obtained from lower temperatures because of more aromatic components and oxygen functional groups entering them. Crucible coking determinations were carried out to evaluate the coking property of the TDSFs. The result suggests that when 5% of TDSF and 5% of non-caking sub-bituminous coal were used instead of the same amount of fat coal and gas coal, respectively in the coal blends, the quality of the coke obtained could get to the level of the coke obtained from the standard coal blends (i.e. without TDSF and sub-bituminous coal). Therefore, the use of TDSF in coal blending for coke-making is one of the effective methods for opening the coking coal resources.

Hengfu Shui; Wenjuan Zhao; Chuanjun Shan; Tao Shui; Chunxiu Pan; Zhicai Wang; Zhiping Lei; Shibiao Ren; Shigang Kang

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Characterization of the origin and distribution of the minerals and phases in metallurgical cokes  

SciTech Connect

Three industrial metallurgical cokes were examined using X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray analysis (SEM/EDS). The study highlighted the difficulties and implications of identifying the inherent crystalline mineral phases in cokes using XRD such that increasing the ashing temperature led to the formation of anhydrite and destruction of metallic iron: microwave plasma ashing resulted in minimal alteration of the original coke mineralogy apart from the formation of bassanite and possibly jarosite. A preliminary scheme to characterize coke minerals is presented such that, physically, minerals can be classified as fine ({lt}50 {mu}m), coarse (50-100 {mu}m), and agglomerate ({gt}1000 {mu}m); chemically, minerals can be grouped as refractory, semirefractory, and reactive, while on the basis of distribution they can be described as discrete, disseminated, or pore inclusions. Quartz, cristobalite, mullite, and high melting point Al-silicates were found to be the predominant refractory phases while low melting point Al-silicates, e.g., containing high fluxing elements such as K, and Fe were the main semirefractory phases present in all cokes. A variety of iron containing phases including pyrrhotite, troilite, iron oxides, metallic iron, and iron silicates were also invariably present in all cokes while calcium phases were found to occur as sulfide, silicates, and phosphates. In general, iron and calcium phases can be categorized as reactive phases with few exceptions such as oldhamite (CaS). The study highlighted that most of the cokes possess a similar mineralogy, with the main distinction being in their relative abundance, particle size, and nature of distribution in the coke matrix. The study provides a basis to develop a mechanistic understanding of the influence of minerals on coke reactivity and strength at high temperatures. 41 refs., 13 figs., 4 tabs.

Sushil Gupta; Maria Dubikova; David French; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

2007-01-15T23:59:59.000Z

202

Energy efficiency of alternative coke-free metallurgical technologies  

SciTech Connect

Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

2009-02-15T23:59:59.000Z

203

Researches on the Chemistry of Coal. Part II. The Resinic Constituents and Coking Propensitie of Coals  

Science Journals Connector (OSTI)

1 March 1922 research-article Researches on the Chemistry of Coal. Part II. The Resinic Constituents and Coking Propensitie of Coals William A. Bone A. R. Pearson E. Sinkinson W. E. Stockings The Royal Society is...

1922-01-01T23:59:59.000Z

204

A relationship for the evaluation o coking values of coal tar pitches from their physical characteristics  

Science Journals Connector (OSTI)

A relationship has been proposed to evaluate the coking values of coal tar pitches from the knowledge of their ... It has been tried on 44 self-prepared coal tar pitches and 18 others obtained from ... -ranging c...

G. Bhatia; R. K. Aggarwal; O. P. Bahl

1987-11-01T23:59:59.000Z

205

THE PREDICTED COKE STRENGTH AFTER REACTION VALl JES OF BRITISH COLUMBIA COALS, WITH COMPARISONS TCOALS  

E-Print Network (OSTI)

This paper provides background to the coke strength after reaction (CSR) test and gives perspective regarding changes in the cokinp coal market. It provides it sumtnary of some of the predicted relationships hctween the ash chemistry of

D. Ryan; B. C. Geological; Survey Branch; John T. Price; Canada Centre For Mineral; Energy Technology

206

Kinetics of catalyst regeneration by coke combustion. II. Influence of temperature rise in the catalyst particles  

Science Journals Connector (OSTI)

A grain-pellet model has been used to study the effect of high reaction rates upon the temperature profiles developed during regeneration of coked catalyst particles. The possibility of falsification of kinetic.....

D. Lafarga; C. Royo; A. Monzón; M. Menéndez…

1991-08-01T23:59:59.000Z

207

Experimental Study on Co-gasification of Coal Liquefaction Residue and Petroleum Coke  

Science Journals Connector (OSTI)

An experimental study on co-gasification of coal liquefaction residue and petroleum coke in carbon dioxide was investigated by thermogravimetric analysis. The temperature of the experiment was 1173–1323 K, and the isothermal (1273 K) kinetics were ...

Xin Liu; Zhi-jie Zhou; Qi-jing Hu; Zheng-hua Dai; Fu-chen Wang

2011-06-20T23:59:59.000Z

208

Industrial experience with the thermal preparation of coal batch before coking  

Science Journals Connector (OSTI)

The basic industrial results obtained with thermal preparation of batch, followed by bed coking in horizontal furnaces, are briefly reviewed. Precarbon technology, which, in various forms, has been successfull...

Yu. S. Vasil’ev; A. I. Gordienko; G. V. Dolgarev

2008-07-01T23:59:59.000Z

209

Relationship between coking pressure generated by coal blends and the composition of their primary tars  

Science Journals Connector (OSTI)

Four coals that develop different pressures during the coking process were selected together with 10 blends (7 binary and 3 ternary) prepared with the same coals. Their semicoke contraction/expansion was measured by means of two tests (the Koppers-INCAR and the sole heated oven) and the variation in coking pressure during coking was determined in a movable wall oven. The coals and blends were then pyrolysed and the tars were analysed by gas chromatography (GC-FID–MS). The additivity law was applied to the properties used to evaluate the dangerousness of the blends and to the composition of the tar produced from the blends. Afterwards, the composition of the tar was studied in relation to contraction/expansion and the coking pressure generated by the coals and blends.

C. Barriocanal; M.A. Díez; R. Alvarez; M.D. Casal

2009-01-01T23:59:59.000Z

210

Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions  

Science Journals Connector (OSTI)

Abstract To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM.

Ha Myung Jeong; Myung Won Seo; Sang Mun Jeong; Byung Ki Na; Sang Jun Yoon; Jae Goo Lee; Woon Jae Lee

2014-01-01T23:59:59.000Z

211

Synthesis of super plasticizer NF-30 from coal coking by product washing oil and performance analysis  

Science Journals Connector (OSTI)

Super plasticizer was synthesized by using coal coking by product washing oil and industrial naphthalene....2 in exhaust (20%). Compared with NF, NF-30 have some advantages in lower cost, high water reducing rate...

Zifang Xu ???; Mingxu Zhang; Wenpei Hu

2013-10-01T23:59:59.000Z

212

Effect of Adsorption Contact Time on Coking Coal Particle Desorption Characteristics  

Science Journals Connector (OSTI)

Effect of Adsorption Contact Time on Coking Coal Particle Desorption Characteristics ... Esp. in the last decade a large amt. of data has been published characterizing coals from various coal basins world-wide for their gas sorption capacity. ...

Wei Zhao; Yuanping Cheng; Meng Yuan; Fenghua An

2014-03-20T23:59:59.000Z

213

High-Temperature Stress Relaxation Cracking and Stress Rupture Observed in a Coke Gasifier Failure  

Science Journals Connector (OSTI)

This article discusses the high-temperature metal degradation mechanisms that occurred in the failure of a nine-story tall coke gasifier, located in a refinery power plant. Cracking of gasifier internals, bulging...

Daniel J. Benac; Douglas B. Olson…

2011-06-01T23:59:59.000Z

214

Guide to ASTM test methods for the analysis of coal and coke  

SciTech Connect

The guide includes brief descriptions of all 56 ASTM test methods that cover the physical, chemical, and spectroscopic analytical techniques to qualitatively and quantitatively identify over 40 chemical and physical properties of coal, coke, their products, and by-products.

R.A. Kishore Nadkarni (ed.)

2008-07-01T23:59:59.000Z

215

The development of Coke Carried-Heat Gasification Coal-Fired Combined Cycle  

Science Journals Connector (OSTI)

Carried-Heat Partial Gasification Combined cycle is a novel combined cycle which was proposed by Thermal Engineering Department ... technology, Coke Carried-Heat Gasification Coal-Fired Combined Cycle, as the imp...

Li Zhao; Xiangdong Xu

1999-12-01T23:59:59.000Z

216

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions  

Science Journals Connector (OSTI)

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions† ... Hydrogen production via hydrocarbon steam reforming and water gas shift reactions was investigated over a monolith-supported Pt-based diesel oxidation catalyst. ...

Meshari AL-Harbi; Jin-Yong Luo; Robert Hayes; Martin Votsmeier; William S. Epling

2010-12-08T23:59:59.000Z

217

Current developments at Giprokoks for coke-battery construction and reconstruction  

SciTech Connect

Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

218

Producing and controlling of the pollutant in the coal`s coking process  

SciTech Connect

In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

1997-12-31T23:59:59.000Z

219

Three-dimensional simulation of combustion processes in coke-battery furnace chambers  

Science Journals Connector (OSTI)

A three-dimensional model of the heating wall in a coke battery is developed by means of the Fluent CFD program. The results of simulation are in satisfactory agreement with experimental data. The mathematical...

M. V. Isaev; I. A. Sultanguzin

2010-08-01T23:59:59.000Z

220

Experimental study on the effects of blast-cap configurations and charge patterns on coke descending in CDQ cooling shaft  

SciTech Connect

The coke descending behavior in a CDQ cooling shaft is studied experimentally by means of a tracing method with a digital camera. For three different blast-caps, the law of coke flow is studied under five conditions of coke charge. The experimental results show that, for the sake of the uniformity of the coke burden descending, a blast-cap with elliptical cross-section is a better choice than that with circular cross-section regardless of high or low placement. A coke charge pattern with a flat top burden surface is preferable to that with peak-valley surface, a double-peak superior to a one-peak. Trajectory and average velocity distribution of coke behavior depend weakly on whether the coke is continuously fed or not as the discharging began. The blast-caps have local effects on the descending coke and hardly affect whether the cokes flow smoothly or not in the case of coke burden with enough depth.

Y.H. Feng; X.X. Zhang; M.L. Wu [University of Science & Technology, Beijing (China). School of Mechanical Engineering

2008-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process  

DOE Patents (OSTI)

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

DeGeorge, Charles W. (Chester, NJ)

1981-01-01T23:59:59.000Z

222

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

223

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

SciTech Connect

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

224

Evaluation of fly ash from co-combustion of coal and petroleum coke for use in concrete  

SciTech Connect

An investigation of fly ash (FA) produced from various blends of coal and petroleum coke (pet coke) fired at Belledune Generating Station, New Brunswick, Canada, was conducted to establish its performance relative to FA derived from coal-only combustion and its compliance with CSA A3000. The FA samples were beneficiated by an electrostatic separation process to produce samples for testing with a range of loss-on-ignition (LOI) values. The results of these studies indicate that the combustion of pet coke results in very little inorganic residue (for example, typically less than 0.5% ash) and the main impact on FA resulting from the co-combustion of coal and up to 25% pet coke is an increase in the unburned carbon content and LOI values. The testing of FA after beneficiation indicates that FA produced from fuels with up to 25% pet coke performs as good as FA produced from the same coal without pet coke.

Scott, A.N.; Thomas, M.D.A.

2007-01-15T23:59:59.000Z

225

Characterization of tuyere-level core-drill coke samples from blast furnace operation  

SciTech Connect

A suite of tuyere-level coke samples have been withdrawn from a working blast furnace during coal injection, using the core-drilling technique. The samples have been characterized by size exclusion chromatography (SEC), Fourier transform Raman spectroscopy (FT-RS), and X-ray powder diffraction (XRD) spectroscopy. The 1-methyl-2-pyrrolidinone (NMP) extracts of the cokes sampled from the 'bosh', the rear of the 'bird's nest', and the 'dead man' zones were found by SEC to contain heavy soot-like materials (ca. 10{sup 7}-10{sup 8} apparent mass units). In contrast, NMP extracts of cokes taken from the raceway and the front of the 'bird's nest' only contained a small amount of material of relatively lower apparent molecular mass (up to ca. 10{sup 5} u). Since the feed coke contained no materials extractable by the present method, the soot-like materials are thought to have formed during the reactions of volatile matter released from the injectant coal, probably via dehydrogenation and repolymerization of the tars. The Raman spectra of the NMP-extracted core-drilled coke samples showed variations reflecting their temperature histories. Area ratios of D-band to G-band decreased as the exposure temperature increased, while intensity ratios of D to G band and those of 2D to G bands increased with temperature. The graphitic (G), defect (D), and random (R) fractions of the carbon structure of the cokes were also derived from the Raman spectra. The R fractions decreased with increasing temperature, whereas G fractions increased, while the D fractions showed a more complex variation with temperature. These data appear to give clues regarding the graphitization mechanism of tuyere-level cokes in the blast furnace. 41 refs., 9 figs., 6 tabs.

S. Dong; N. Paterson; S.G. Kazarian; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

226

Predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch  

Science Journals Connector (OSTI)

Mathematical models are developed for predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch.

M. B. Golovko; I. D. Drozdnik; D. V. Miroshnichenko; Yu. S. Kaftan

2012-06-01T23:59:59.000Z

227

Study of the sulphur in coal and its distribution between the gases and the residue in coking.  

E-Print Network (OSTI)

??Sulphur exists in metallurgical coke as a source of annoyance and difficulties in the economic progress of the metal industries. It ie present in coal… (more)

Wenger, Arthur W.

1923-01-01T23:59:59.000Z

228

Australia–Japan coking coal trade: A hedonic analysis under benchmark and fair treatment pricing  

Science Journals Connector (OSTI)

Given Japan's dominant position in the Asia–Pacific regional coal market and the continuing relatively low profitability of Australia's coal industry, the influence of the Japanese steel mills on coal pricing arrangements between Australia and Japan remains an issue in Australia. In Japanese fiscal year (JFY) 1996, the Japanese steel mills replaced benchmark pricing with the “fair treatment” pricing system whereby coal contract information is kept confidential. In this paper, Quandt's switching regime model is used to test for structural change in hedonic pricing relationships in the important Australia–Japan coking coal trade between JFY 1992 and 1997. There is statistical evidence of significant structural change in JFY 1996 for hard coking coal and in JFY 1995 for semisoft coking coal (when soft coking coal was merged with the semisoft category). The goodness of fit of the regressions is lower in each recent period. It is concluded that price discovery in the annual coal negotiations, particularly for hard coking coal, is relatively more difficult under fair treatment pricing.

Anthony Swan; Sally Thorpe; Lindsay Hogan

1999-01-01T23:59:59.000Z

229

Relationship between coking coal quality and its micro-Raman spectral characteristics  

Science Journals Connector (OSTI)

Abstract Micro-Raman spectroscopy examination of 20 samples of coking coals (Rr = 0.84–1.43%) was performed. Spectral parameters were correlated with the basic rank and technological properties of coals. The G band FWHM and the AG/AALL ratio decrease with the volatile matter content (Vdaf) decrease and the all maceral reflectance scan (Rscan) value increase. The correlations between these parameters are stronger than those, between the G band FWHM and the AG/AALL ratio, and the mean random vitrinite reflectance (Rr). Coking properties are weakly related to the Raman spectral characteristics of coal. Based on the Raman parameters G band FWHM and the AG/AALL ratio, it may be possible to evaluate the volatile matter content (Vdaf) and the all maceral reflectance scan (Rscan) value for coking coals.

Rafa? Morga; Iwona Jelonek; Krystyna Kruszewska

2014-01-01T23:59:59.000Z

230

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

231

Catalyst deactivation by coking in the MTG process in fixed and fluidized bed reactors  

Science Journals Connector (OSTI)

The validity of a kinetic model for describing the deactivation of a catalyst based on a HZSM5 zeolite has been studied by carrying out reaction in fixed and fluidized bed reactors. The kinetic model takes into account that activity is dependent on the concentration of the lumps of oxygenates, of light olefins and of the remaining products and shows that coke formation capability follows this order. The difference between the deactivation kinetic constants calculated for the fixed and fluidized bed reactors is explained by the effect of the steam produced in the reaction, where coke stripping attenuates deactivation. Future improvements in the deactivation kinetic model must take into account coke stripping by the steam produced in the reaction.

Andrés T. Aguayo; Ana G. Gayubo; JoséM. Ortega; Martin Olazar; Javier Bilbao

1997-01-01T23:59:59.000Z

232

Study on the Respirable Particulate Matter Generated from the Petroleum Coke and Coal Mixed-Fired CFB Boiler  

Science Journals Connector (OSTI)

The dust generated from the fuel combustion is one of the important sources for air pollution. This paper has made a comprehensive research on the particulate matter generated from the petroleum coke and coal mixed-fired circulating fluidized bed (CFB) ... Keywords: petroleum coke, respirable particulate matter, air pollution, circulating fluidized bed boiler

Yan Ma; Hao Bai; Lihua Zhao; Yang Ma; Daqiang Cang

2010-12-01T23:59:59.000Z

233

An active carbon catalyst prevents coke formation from asphaltenes during the hydrocracking of vacuum residue  

SciTech Connect

Active carbons were prepared by the steam activation of a brown coal char. The active carbon with mesopores showed greater adsorption selectivity for asphaltenes. The active carbon was effective at suppressing coke formation, even with the high hydrocracking conversion of vacuum residue. The analysis of the change in the composition of saturates, aromatics, resins, and asphaltenes in the cracked residue with conversion demonstrated the ability of active carbon to restrict the transformation of asphaltenes to coke. The active carbon that was richer in mesopores was presumably more effective at providing adsorption sites for the hydrocarbon free-radicals generated initially during thermal cracking to prevent them from coupling and polycondensing.

Fukuyama, H.; Terai, S. [Toyo Engineering Corp., Chiba (Japan). Technological Research Center

2007-07-01T23:59:59.000Z

234

Contribution to kinetic modeling of catalyst deactivation by coke in the MTG process  

SciTech Connect

The adequacy of a kinetic model for deactivation of a catalyst based on a H-ZSM5 used in the transformation of methanol into hydrocarbons has been proven. The model takes into account the pronounced effect on coke deposition of the concentration of reaction lumps and coke preferable deposition at the reactor inlet by degradation of oxygenates (methanol and dimethylether) on the catalyst acid sites. The kinetic model is in agreement with the experimental results of fixed and fluidized bed reactors within the 300-400 {degrees}C range. The deactivation is slightly smaller in fluidized bed but contribution of catalyst attrition to deactivation must be considered. 14 refs., 3 figs.

Gayubo, A.G.; Ortega, J.M.; Benito, P.L.; Aguayo, A.T.; Bilbao, J. [Universidad del Pais Vasco, Bilbao (Spain)

1996-12-31T23:59:59.000Z

235

Mechanism of physical transformations of mineral matter in the blast furnace coke with reference to its reactivity and strength  

SciTech Connect

Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength. 9 refs., 2 figs., 1 tab.

Stanislav S. Gornostayev; Jouko J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2006-12-15T23:59:59.000Z

236

Rates of Microbial Transformation of Polycyclic Aromatic Hydrocarbons in Water and Sediments in the Vicinity of a Coal-Coking Wastewater Discharge  

Science Journals Connector (OSTI)

...Sediments in the Vicinity of a Coal-Coking Wastewater Discharge Stephen E...collected in the vicinity of a coal-coking treated wastewater discharge from...sediments in the vicinity of a coal-coking wastewater discharge. | To facilitate...

Stephen E. Herbes

1981-01-01T23:59:59.000Z

237

Dissolution of refractories for gasification process of petroleum coke for the steel industry  

Science Journals Connector (OSTI)

The production of energizing gases such as H2 and CO by gasification process of solid fuels is a technology that has increased in recent years since it is an efficient and clean process. To enable the production of gases, it is necessary to use refractory materials capable of withstanding high temperatures, thermal shock and contact with aggressive media. Nowadays, there is not published literature on refractory materials used for furnaces lining for petroleum coke gasification at high temperatures (?1900 °C). Therefore, this paper deals with the study of alumina and magnesium aluminate/alumina-based refractories as candidates for the furnace lining used in the petroleum coke gasification for steel production. Refractory samples were made with some designed formulations which were subjected to chemical interactions with pellets made of petroleum coke and petroleum coke ash at 1650 °C for 4 h. After completing the tests, the formulations were cut transversely and were characterized by SEM-EDS and XRD to evaluate the resistance to slag penetration and formation of low melting point phases. The results show that slag penetration and corrosion in the refractory formulations occur due to the formation of hibonite, spinels (Ni2+, Fe2+, Mg2+)(Al, Fe)2O4 and gehlenite phases. However, these phases together stop the molten slag penetration.

R. Puente-Ornelas; C.J. Lizcano-Zulaica; A.M. Guzmán; P.C. Zambrano; T.K. Das-Roy

2012-01-01T23:59:59.000Z

238

Effect of Iron Species and Calcium Hydroxide on High-Sulfur Petroleum Coke CO2 Gasification  

Science Journals Connector (OSTI)

The effect of iron species on petroleum coke CO2 gasification was studied in the present work. The effects of the temperature (1173–1673 K), the catalyst types, catalyst loading (ranging from 0 to 5 wt %), and composition during the gasification of ...

Zhi-jie Zhou; Qi-jing Hu; Xin Liu; Guang-suo Yu; Fu-chen Wang

2012-01-24T23:59:59.000Z

239

The behaviors and fate of polycyclic aromatic hydrocarbons (PAHs) in a coking wastewater treatment plant  

Science Journals Connector (OSTI)

The occurrence, behaviors and fate of 18 \\{PAHs\\} were investigated in a coking wastewater treatment plant in Songshan coking plant, located in Shaoguan, Guangdong Province of China. It was found that the target compounds occurred widely in raw coking wastewater, treated effluent, sludge and gas samples. In raw coking wastewater, high molecular weight (MW) \\{PAHs\\} were the dominant compounds, while 3–6 ring \\{PAHs\\} predominated in the final effluent. The dominant compounds in gas samples were phenathrene, fluoranthene and pyrene, while they were fluoranthene, pyrene, chrysene and benzo[k]fluoranthene for sludge. The process achieved over 97% removal for all the PAHs, 47–92% of eliminations of these target compounds in liquid phase were achieved in biological stage. Different behaviors of \\{PAHs\\} were observed in the primary tank, anaerobic tank, aerobic tank, hydrolytic tank and coagulation tank units, while heavier and lower ones were mainly removed in anaerobic tank and aerobic tanks, respectively. Regarding the fate of PAHs, calculated fractions of mass losses for low MW \\{PAHs\\} due to transformation and adsorption to sludge accounted for 15–50% and 24–49%, respectively, while the rest was less than 1%. For high MW PAHs, the mass losses were mainly due to adsorption to sludge and separation with tar (contributing 56–76% and 22–39%, respectively), and the removal through transformation was less.

Wanhui Zhang; Chaohai Wei; Xinsheng Chai; Jingying He; Ying Cai; Man Ren; Bo Yan; Pingan Peng; Jiamo Fu

2012-01-01T23:59:59.000Z

240

Coke deposits formation and products selectivities for the MTG process in a fluidized bed reactor  

Science Journals Connector (OSTI)

Experiments were carried out in a demonstrative scale fluidized bed reactor for methanol conversion to gasoline (MTG). We investigated the kinetics of the coke deposits formation and their influence on the products selectivities. New reaction indexes were advanced for on line monitoring of the catalyst activity.

Grigore Pop; Gavril Musca; Eleonora Chirila; Rodica Boeru; Gheorghe Niculae; Natalia Natu; Gheorghe Ignatescu; Sorin Straja

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke  

Science Journals Connector (OSTI)

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke ... The ash pits have since gone through an extensive remedial process. ... The other metals investigated (i.e., Fe, Cu, Zn, and Pb) also were present predominantly as sulfates. ...

L. Jia; E. J. Anthony; J. P. Charland

2002-02-27T23:59:59.000Z

242

Coal flow aids reduce coke plant operating costs and improve production rates  

SciTech Connect

Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

2005-06-01T23:59:59.000Z

243

Optimization of experimental conditions for recovery of coking coal fines by oil agglomeration technique  

Science Journals Connector (OSTI)

The significance of coking coal in the metallurgical sector as well as the meager coking coal reserves across the globe increase the necessity to recover coking coal fines from the fine coking coal slurries generated from coal preparation and utilization activities. Oil agglomeration studies were carried out by varying the experimental conditions for maximum recovery of coking coal fines i.e., yield of the agglomerates. The various operational parameters studied were oil dosage, agitation speed, agglomeration time and pulp density. By using Taguchi experimental design, oil dosage (20%), agitation speed (1100 rpm), agglomeration time (3 min) and pulp density (4.5%) were identified as the optimized conditions. A confirmation experiment has also been carried out at the optimized conditions. The percentage contribution of each parameter on agglomerate yield was analyzed by adopting analysis of variance (ANOVA) statistical method as well as multiple linear regression analysis. The order of influence of the parameters on the agglomerate yield is of the following order: pulp density > oil dosage > agitation speed > agglomeration time. A mathematical model was developed to fit the set of experimental conditions with the yield obtained at each test run and also at the optimized conditions. The experimentally obtained yield was compared with the predicted yield of the model and the results indicate a maximum error of 5% between the two. A maximum yield of 90.42% predicted at the optimized conditions appeared to be in close agreement with the experimental yield thus indicating the accuracy of the model in predicting the results.

G.H.V.C. Chary; M.G. Dastidar

2010-01-01T23:59:59.000Z

244

Influence of the batch's coke-ore ratio and distribution on the porosity of the melting zone  

SciTech Connect

The variation in gas permeability in the melting zone is considered as a function of the height and configuration of the coke packing and the ore component of the batch.

V.P. Tarasov; L.V. Bykov; P.V. Tarasov [Priazovsk State Technical University, Mariupol (Ukraine)

2008-09-15T23:59:59.000Z

245

Deposition and characteristics of coke over a H-ZSM5 zeolite-based catalyst in the MTG process  

SciTech Connect

The influence of reaction conditions in the transformation of methanol into gasoline (temperature, time on stream, and contact time) on the deposition and nature of coke (composition, H/C ratio) and on its location in the porous structure of a H-ZSM5 zeolite-based catalyst has been studied in an isothermal fixed-bed integral reactor. The distribution of the coke within the porous structure of the catalyst is similar to that proposed for other reactions on H-ZSM5 zeolites, and the highly hydrogenated character of coke and its instability is noteworthy. Coke deposition has been related to catalyst acidic site deterioration and to a kinetic model for catalyst deactivation in an integral reactor.

Benito, P.L.; Gayubo, A.G.; Aguayo, A.T.; Olazar, M.; Bilbao, J. [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica] [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica

1996-11-01T23:59:59.000Z

246

Production of Syngas via Partial Oxidation and CO2 Reforming of Coke Oven Gas over a Ni Catalyst  

Science Journals Connector (OSTI)

Production of Syngas via Partial Oxidation and CO2 Reforming of Coke Oven Gas over a Ni Catalyst ... The yield of produced syngas increases with an increase in temperature. ...

Jianzhong Guo; Zhaoyin Hou; Jing Gao; Xiaoming Zheng

2008-04-05T23:59:59.000Z

247

Reducing the sulfur content of coke by increasing the content of thermally conditioned g coal in the batch  

Science Journals Connector (OSTI)

In periods of economic growth, Ukrainian coke plants face a shortage of Zh and K coal, because of the high demand. In periods of economic stagnation, conversely, there is an excess of Zh coal, on account of the d...

E. I. Malyi

2014-05-01T23:59:59.000Z

248

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

249

Linings with optimum heat-emission surfaces for cars receiving and transporting incandescent coke  

SciTech Connect

The least reliable components of the cars which receive and transport incandescent coke are the lining plates. This applies to both the quenching cars used for wet quenching and the hot-coke cars used in the dry cooling process. Technical advances have been described whereby the life of car linings is prolonged by increasing heat emission from the lining plate surfaces. As the heat emission level is enhanced the mean plate temperature is lowered and the lining life thereby prolonged; moreover, the between-servicings period is prolonged. This involves providing fins on the non-working (outer) plate surfaces. The problem of optimizing the size and shape of the fins with reference to heat emission remains unsolved: the requirement is maximum heat emission from plates of a given weight, or conversely minimum plate weight for a given heat emission level. 6 refs., 3 figs.

Kotlyar, B.D.; Pleshkov, P.I.; Gadyatskii, V.G. [and others

1992-12-31T23:59:59.000Z

250

Unsteady-state kinetic simulation of naphtha reforming and coke combustion processes in the fixed and moving catalyst beds  

Science Journals Connector (OSTI)

Abstract The work is dedicated to the construction of kinetics models for the naphtha reforming process and the adjacent process of catalyst regeneration by coke combustion. The proposed kinetic model for the reforming process is based on the use of common rate equations for the groups of similar reactions with account of difference in reaction rates for individual homologs within these groups by simple correlations with thermodynamic properties (first of all – with the values of Gibbs free energy) of individual reactions and by other simplification methods. Such approach gives the way to construct the kinetics models optimal from the point of view of compromise between accuracy and simplicity. The proposed naphtha reforming model is characterized with the high level of kinetic scheme detailization (62 individual and group reactants and 146 individual reactions), at the same it is rather simple and provides the accurate description of the experimental data using only 22 kinetic parameters. This model is thermodynamically consistent and provides accurate description of experimental data in a wide range of process parameters. Account of catalyst deactivation by coke deposition in the model gives the way to simulate transient reforming process performance both in fixed and moving catalyst beds. Kinetics of coke combustion for catalysts with moderate coke content (up to 3% mass) may described by simple kinetic equation with apparent reaction rate orders closed to unit for relative coke content and to 1/2 for oxygen. Demonstration simulations of naphtha reforming and coke combustion processes are presented.

Andrey N. Zagoruiko; Alexander S. Belyi; Mikhail D. Smolikov; Alexander S. Noskov

2014-01-01T23:59:59.000Z

251

Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine  

E-Print Network (OSTI)

OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf... MASTER OF SCIENCE December 1984 Major Subject: Agricultural Engineering OPERATING TEMPERATURE EFFECTS ON NOZZLE CORING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis by CHARLES MICHAEL YARBROUGH Approved as to style and content by: ayne A. Le...

Yarbrough, Charles Michael

2012-06-07T23:59:59.000Z

252

Profitability analysis of non-coking coal preparation for power plants in India  

SciTech Connect

Currently coal-based power plants produce about 70% of the total electricity generated in India, where non-coking (steam) coals are utilized mostly without any preparation. A massive capacity addition of at least 140,000 MWe is required (over the 81,000 MWe of current installed capacity) during the next 15 years to meet growing energy demand. Such a rapid expansion of power generation capacity poses a serious challenge to the environment (at emission controls) and transportation infrastructure in India. Furthermore, the high ash content of indigenous coals and concentration of coal mines in central and northeastern India away from urban centers exacerbate the problem. Thus, coal preparation is envisioned to play a major role in shaping the energy future of India. Under the Indo-US Coal Preparation Program, the US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is coordinating coal preparation activities for the US Agency for International Development. In this context, a detailed analysis of the washability characteristics of non-coking coals was performed using the PETC Coal Preparation Plant Simulator (CPPS) to identify coal preparation strategies for India. Based on these strategies, a profitability analysis of non-coking coal preparation has been conducted considering coal preparation and transportation costs, and coal quality impacts on power plant operations. This paper summarizes the results of this analysis and quantifies the significance of coal preparation for the Indian power sector.

Gollakota, S.V.; Rao, S.N. [Burns and Roe Services Corp., Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Staats, G.E. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center

1996-12-31T23:59:59.000Z

253

Fluid Volumes: The Program “FLUIDS  

Science Journals Connector (OSTI)

This chapter describes the program FLUIDS. The mathematical model underlying this program contains over 200 variables and describes control mechanisms of body fluid volumes and electrolytes as well as respirat...

Fredericus B. M. Min

1993-01-01T23:59:59.000Z

254

An example of alkalization of SiO{sub 2} in a blast furnace coke  

SciTech Connect

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2007-09-15T23:59:59.000Z

255

Co-coking of Hydrotreated Decant Oil/Coal Blends: Effect of Hydrotreatment Severity on the Yield Distribution and Quality of Distillate Fuels  

Science Journals Connector (OSTI)

The coke yield from delayed co-coking of hydrotreated DOs and coal blends was observed to be in the range of 15.9–24.4%. ... The coal used in this study (EI-106) was a 50:50 blend of the Powellton and Eagle seams, both very similar coals of high-volatile A bituminous rank from West Virginia. ... One of the hydrotreated DOs (EI-133) was coked alone. ...

Ömer Gül; Leslie R. Rudnick; Harold H. Schobert

2013-05-19T23:59:59.000Z

256

Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks  

SciTech Connect

Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

257

Introduction Fluid/Jeans  

E-Print Network (OSTI)

Introduction Fluid/DMSC Fluid/Jeans Comments Fluid/Kinetic Hybrid Modeling of the Thermosphere;Introduction Fluid/DMSC Fluid/Jeans Comments Outline 1 Fluid/DMSC 2 Fluid/Jeans 3 Comments Justin Erwin Fluid/Kinetic Hybrid Modeling of the Thermosphere of Pluto #12;Introduction Fluid/DMSC Fluid/Jeans Comments Motivation

Johnson, Robert E.

258

Application of artificial neural network to study the performance of jig for beneficiation of non-coking coal  

Science Journals Connector (OSTI)

Non-coking coal is the major resource of energy in India. Apart from its utilization in energy sector, the other major application of this coal is in metallurgical sector. The resource of high quality of non-coking coal is not available as per demand; as a result beneficiation of non-coking coal is now becoming essential. Jigging is one of the economical physical beneficiation processes for Indian high ash non-coking coal. At present scenario in coal washery in India, below 3 mm size is not being processed. Attempt has been taken to beneficiate the fine size non-coking coal fractions generated at different sizes of bed materials, feed rates and water rates using laboratory Denver mineral jig. The performance of jig was evaluated in term of Ep and imperfection value. Furthermore artificial neural network (ANN) model has been developed for determining combustible recovery and ash percent of the concentrate. The ANN architecture is made up of three layers (input – hidden – output). A back propagation algorithm was used for training of the ANN model. It has been observed that the predicted values by ANN model are in good agreement with the experimental results.

Lopamudra Panda; A.K. Sahoo; A. Tripathy; S.K. Biswal; A.K. Sahu

2012-01-01T23:59:59.000Z

259

Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001  

SciTech Connect

This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

2009-09-15T23:59:59.000Z

260

Split and collectorless flotation to medium coking coal fines for multi-product zero waste concept  

Science Journals Connector (OSTI)

The medium coking coal fines of ? 0.5 mm from Jharia coal field were taken for this investigation. The release analysis of the composite coal reveals that yield is very low at 10.0% ash, about 25% at 14% ash and 50% at 17% ash level. The low yield is caused by the presence of high ash finer fraction. The size-wise ash analysis of ? 0.5 mm coal indicated that ? 0.5 + 0.15 mm fraction contains less ash than ? 0.15 mm fraction. Thus, the composite feed was split into ? 0.5 + 0.15 mm and ? 0.15 mm fractions and subjected to flotation separately. The low ash bearing fraction (? 0.5 + 0.15 mm) was subjected to two stages collectorless flotation to achieve the concentrate with 10% ash. The cleaner concentrate (18.9%) with 10% ash was recovered which has an application in metallurgical industries. The concentrate of 30.2% yield with 12.5% ash could be achieved in one stage collectorless flotation which is suitable for use in coke making as sweetener. As the ? 0.15 mm fraction contains relatively high ash, collector aided flotation using sodium silicate was performed to get a concentrate of 23.6% yield with about 17% ash. The blending of this product with cleaner tail obtained from ? 0.5 + 0.15 mm produces about 35.0% yield with 17% ash and that can be utilized for coke making. The reject from the two fractions can be used for conventional thermal power plant or cement industries using a 23.5% ash after one stage collector aided flotation and the final tailings produced content ash of 61.6% can be used for fluidization combustion bed (FBC). This eventually leads to complete utilization of coal.

Shobhana Dey; K.K. Bhattacharyya

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Co-gasification of Biomass with Coal and Oil Sand Coke in a Drop Tube Furnace  

Science Journals Connector (OSTI)

From this work, a synergistic effect was observed for blends of coal with petcoke and an increase in the production of H2 and CO was obtained. ... Finally, blending biomass with coal?petcoke blends did not produce any significant change in H2 production, although slight variations were observed in the production of CO and CO2. ... In addn., co-gasification tests of binary blends of a bituminous coal with different types of biomass (up to 10%) and petroleum coke (up to 60%), as well as ternary blends of coal-petcoke-biomass (45-45-10%) were conducted to study the effect of blending on gas prodn. ...

Chen Gao; Farshid Vejahati; Hasan Katalambula; Rajender Gupta

2009-10-13T23:59:59.000Z

262

Matrix endor studies of the carbonization of West Canadian coking coals  

Science Journals Connector (OSTI)

Cretaceous bituminous coals of known rank R?0 max vitrinite reflectance) have been examined by ESR (electron spin resonance) and ENDOR (electron nuclear double resonance) techniques. Both highly oxidised (outcrop) and unoxidised mine?run Balmer coal from the Crowsnest field have been subjected to heat treatment (200?900°C) and the matrix proton ENDOR signal studied as a function of applied microwave and rf power. Changes in ENDOR line shape and intensity are described with particular emphasis on the presoftening region of the unoxidised coal. A comparative study of the carbonization of hvb and 1vb coking coal from the Crowsnest is reported.

P. R. West; S. E. Cannon

1981-01-01T23:59:59.000Z

263

Form EIA-5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants Document Number: 001 Version: 2.0 June 2011 i June 2011 Document History Number Date Section Description 1 2 June 2011 June 2011 Document initiation Revised screen shots and remove external user references. Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Document Changes/Maintenance POC: Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Project References: Coal Internet Data Collection (CIDC) User's Manual, September 2007 ii June 2011 Content 1. General System Overview ................................................................................. 1

264

Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke  

SciTech Connect

The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

Zubilin, I.G.; Umanskii, V.E.

1984-01-01T23:59:59.000Z

265

Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine  

SciTech Connect

The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

2007-03-15T23:59:59.000Z

266

Methane steam reforming at low temperature: Effect of light alkanes’ presence on coke formation  

Science Journals Connector (OSTI)

Abstract Steam reforming of natural gas for the production of hydrogen at low operation temperature offers significant financial and environmental advantages. However, the presence of higher hydrocarbons as minor components of natural gas can significantly affect the formation of coke and thus the effectiveness of the catalyst. In this study, the effect of the presence of C2–C3 alkanes in the feedstock on the carbon accumulation during low temperature steam reforming of methane is investigated over Ni and Rh catalysts supported on lanthanum doped ceria–zirconia mixed oxide. Both catalysts showed high resistance to coke formation and especially in the case of Rh/La/CeO2–ZrO2, the carbon accumulation detected was low even after 10 h on stream in steam reforming of all mixtures of hydrocarbons tested. The presence of higher alkanes in methane increased the amount of carbon on Ni(10)CeZrLa compared to pure methane as well as the nature of the carbonaceous species. Increase in the C-number of the additive alkane had almost no influence on the total amount of carbon formed (C/H feed ratio = constant) but favored the formation of filamentous carbon.

Sofia D. Angeli; Fotis G. Pilitsis; Angeliki A. Lemonidou

2015-01-01T23:59:59.000Z

267

A new technology for producing hydrogen and adjustable ratio syngas from coke oven gas  

SciTech Connect

About 15 billion Nm{sup 3} coke oven gas (COG) is emitted into the air in Shanxi Province in China as air pollutants. It is also a waste of precious chemical resources. In this study, COG was purified respectively by four methods including refrigeration, fiberglass, silica gel, and molecular sieve. Purified COG was separated by a prism membrane into two gas products. One consists mainly of H{sub 2} ({gt}90 vol %) and the other is rich in CH{sub 4} ({gt}60 vol %) with their exact compositions to vary with the membrane separation pressure and outlet gas flow ratio. The gas rich in CH{sub 4} was partially oxidized with oxygen in a high-temperature fixed-bed quartz reactor charged with coke particles of 10 mm size. At 1200-1300{sup o}C, a CH{sub 4} conversion of {gt}99% could be obtained. The H{sub 2}/CO ratio in the synthesis product gas can be adjusted in the range 0.3-1.4, very favorable for further C1 synthesis. 10 refs., 17 figs., 1t ab.

Jun Shen; Zhi-zhong Wang; Huai-wang Yang; Run-sheng Yao [Taiyuan University of Technology, Taiyuan (China). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

268

Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz  

SciTech Connect

The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-03-15T23:59:59.000Z

269

Features of hydrotreating catalytic cracking feed and heavy slow coking gas oils  

SciTech Connect

A possible means of more extensive processing of crude oil is the use, in catalytic cracking, of heavy coking gas oils (HCGOs), a feature of which is a higher content of polycyclic aromatic compounds and resins by comparison with straight-run vacuum distillates. The presence of these compounds in catalytic cracking feed causes a reduction in the product yield and increased coke formation. Therefore, one of the problems of hydrotreating feedstock of this kind is the hydrogenation of polycyclic arenes. Processes of extensive desulphurization and denitration occur in parallel, since the sulphur and nitrogen compounds of HCGO are chiefly condensed benzoderivatives of thiophene, pyridine and carbazole, and largely concentrated in heavy aromatic and resinous fractions. The composition of the saturated part of the cracking feed plays a large role in achieving the optimum yields of gaseous and gasoline fractions. Thus an increase in the proportion of cyclanes in the feed raises the gasoline yield. In this way, an investigation of the hydrocarbon conversions during the hydrotreatment of cracking feed is of great importance. The present paper sets out the results for studying the change in the group-structural characteristics of the hydrogenation products of a mixture containing 30% HCGOs according to data of {sup 1}H and {sup 13}C NMR spectroscopy. 7 refs., 7 figs., 1 tab.

Yefremov, N.I.; Kushnarev, D.F.; Frolov, P.A.; Chagovets, A.N.; Kalabin, G.A.

1993-12-31T23:59:59.000Z

270

Fluid inflation  

SciTech Connect

In this work we present an inflationary mechanism based on fluid dynamics. Starting with the action for a single barotropic perfect fluid, we outline the procedure to calculate the power spectrum and the bispectrum of the curvature perturbation. It is shown that a perfect barotropic fluid naturally gives rise to a non-attractor inflationary universe in which the curvature perturbation is not frozen on super-horizon scales. We show that a scale-invariant power spectrum can be obtained with the local non-Gaussianity parameter f{sub NL} = 5/2.

Chen, X. [Centre for Theoretical Cosmology, DAMTP, University of Cambridge, Cambridge CB3 0WA (United Kingdom); Firouzjahi, H. [School of Astronomy, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531, Tehran (Iran, Islamic Republic of); Namjoo, M.H. [School of Physics, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531, Tehran (Iran, Islamic Republic of); Sasaki, M., E-mail: x.chen@damtp.cam.ac.uk, E-mail: firouz@ipm.ir, E-mail: mh.namjoo@ipm.ir, E-mail: misao@yukawa.kyoto-u.ac.jp [Yukawa Institute for theoretical Physics, Kyoto University, Kyoto 606-8502 (Japan)

2013-09-01T23:59:59.000Z

271

Petroleum Coke  

U.S. Energy Information Administration (EIA) Indexed Site

81,811 82,516 82,971 84,053 85,190 84,889 1986-2013 East Coast (PADD 1) 12,198 10,887 9,316 9,766 9,003 7,430 1986-2013 Midwest (PADD 2) 15,005 15,507 16,480 16,834 17,611 17,597...

272

Co-Gasification of Biomass Wastes and Coal?Coke Blends in an Entrained Flow Gasifier: An Experimental Study  

Science Journals Connector (OSTI)

An experimental study of entrained flow, air-blown cogasification of biomass and a coal?coke mixture has been performed in order to evaluate the effect of the relative fuel/air ratio (ranging between 2.5 and 7.5), the reaction temperature (ranging between ...

Juan J. Hernández; Guadalupe Aranda-Almansa; Clara Serrano

2010-03-29T23:59:59.000Z

273

Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking  

SciTech Connect

1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

2007-09-15T23:59:59.000Z

274

Evaluation of pitches and cokes from solvent-extracted coal materials  

SciTech Connect

Three initial coal-extracted (C-E) samples were received from the West Virginia University (WVU) Chemical Engineering Department. Two samples had been hydrogenated to obtain pitches that satisfy Theological requirements. One of the hydrogenated (HC-E) samples had been extracted by toluene to remove ash and higher molecular weight aromatic compounds. We were unable to measure the softening point and viscosity of the non-hydro treated solid extract sample, Positive characteristics in the HC-E materials were softening points of 113-119{degrees}C, low sulfur and ash. The oxygen and nitrogen content of the HC-E samples may limit future usage in premium carbon and graphite products. Coking values were similar to petroleum pitches. Laboratory anode testing indicates that in combination with standard coal-tar pitch, the HC-E material can be used as a binder pitch.

McHenry, E.R.

1996-12-01T23:59:59.000Z

275

Comparative study of the performance of conventional and column flotation when treating coking coal fines  

Science Journals Connector (OSTI)

Investigations were carried out on coking coal fines by conventional cell and column flotation techniques. The effects of different operating parameters were evaluated for both conventional and column flotation. The coal fines were collected from Bhojudih washery, India. These coal fines averaged 24.4% ash, 19.8% volatile matter and 53.8% fixed carbon on a dry basis. A commercial grade sodium silicate, light diesel oil and pine oil were used as depressant, collector and frother respectively. The flotation performance was compared with release analysis. The conventional flotation results indicated that a clean coal with 14.4% ash could be obtained at 78.0% yield with 88.4% combustible recovery. The ash of the clean coal could be further reduced to 10.1% at 72.0% yield with 85.6% combustible recovery by using column flotation. The column flotation results were close to those obtained by release analysis.

M.S. Jena; S.K. Biswal; S.P. Das; P.S.R. Reddy

2008-01-01T23:59:59.000Z

276

Fouling in a 160 MWe FBC boiler firing coal and petroleum coke  

Science Journals Connector (OSTI)

The 160 MWe fluidized bed combustor (FBC) boiler owned and operated by the Tennessee Valley Authority (TVA) has recently been co-fired with coal and petroleum coke (up to 50%). However, it has suffered some fouling problems. On examination of the deposits it became clear that, in only a few cases could the fouling be partially attributed to alkali metals, and even in those cases the primarily limestone-derived materials were almost quantitatively sulphated to a level which was sufficient to cause strength development by itself. In other cases, it appeared that the fouling mechanism was carbonation of the free lime component of the deposit followed by sulphation. Finally, in a few deposits which were less sulphated than bed materials and fly ash, strength development appeared to have occurred by conversion of the free lime in the deposits to Ca(OH)2, followed by carbonation. This type of agglomeration has not been reported previously in a FBC.

E.J. Anthony; A.P. Iribarne; J.V. Iribarne; R. Talbot; L. Jia; D.L. Granatstein

2001-01-01T23:59:59.000Z

277

Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate  

SciTech Connect

Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

2004-07-01T23:59:59.000Z

278

Influence of coal thermoplastic properties on coking pressure generation: Part 2 – A study of binary coal blends and specific additives  

Science Journals Connector (OSTI)

A number of coal blends and pitch/coal blends were evaluated using rheometry, thermogravimetric analysis and microscopy to confirm and further elucidate the coking pressure mechanism previously proposed by Duffy et al. (2007) [1]. We confirm that blending a low rank, high fluidity, low coking pressure coal, with a high rank, low fluidity, high coking pressure coal can significantly reduce the coking pressure associated with the latter. Interestingly, blending does not necessarily result in a fluidity that is midway between that of the two coals; sometimes the fluidity of the blend is less than that of the low fluidity coal, especially when the coals are significantly different in rank. This occurs because the increase in complex viscosity (?*) through resolidification of the low rank, high fluidity coal counteracts the reduction in ?* resulting from softening of the high rank, low fluidity coal. It has also been confirmed that the ?* of the resultant blend can be estimated from the ?* of each component coal using a logarithmic additivity rule commonly employed for polymer blends. Polarised light microscopy has indicated that the degree of mixing between coals of different rank is minimal, with fusion restricted to the particle surface. It is therefore inappropriate to think of such a coal blend in the same way as a single coal, since each component coal behaves relatively independently. This limited fusion is important for understanding the coking pressure mechanism for blends. It is proposed here that the lower rank coal, which softens at lower temperature, is able to expand into the interparticle voids between the high rank coal that is yet to soften, and these voids can create channels for volatiles to traverse. Then, and importantly, when the high rank coal begins to expand, the pore structure developed in the resolidified structures of the low rank coal can facilitate removal of volatiles, while the resolidified material may also act as a suitable sorbent for volatile matter. This is considered to be the primary mechanism by which coal blending is able to alleviate coking pressure, and applies to addition of inert material also. Addition of a coal tar pitch was found to increase fluidity but also to extend the thermoplastic range to lower temperatures. This caused an increase in the swelling range, which was accompanied by a long plateau in ?*, a feature which has previously been observed for certain high fluidity, high pressure coals. Elasticity and ?* at the onset of expansion were also higher for both the pitch impregnated coals and the high pressure blends, which supports previous findings for singly charged high pressure coals, and confirms the potential use of such criteria for identifying potentially dangerous coals/blends.

John J. Duffy; Merrick R. Mahoney; Karen M. Steel

2010-01-01T23:59:59.000Z

279

Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report  

SciTech Connect

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

Stuart, L.M.

1994-05-27T23:59:59.000Z

280

Evaluating coking resources. 2. State standard GOST 25543-88 as a coding system for coal and coal mixtures in evaluating their technological properties  

Science Journals Connector (OSTI)

The codification of coal in State Standard 25543-88 is compared with the international codification of coal of medium and high rank. The ranking of coking coal on the basis of State Standard GOST...

Yu. A. Zolotukhin

2008-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Comparative Study of Gasification Performance between Bituminous Coal and Petroleum Coke in the Industrial Opposed Multiburner Entrained Flow Gasifier  

Science Journals Connector (OSTI)

SUMMARY : Co-gasification performance of coal and petroleum coke (petcoke) blends in a pilot-scale pressurized entrained-flow gasifier was studied exptl. ... Two different coals, including a subbituminous coal (Coal A) and a bituminous coal (Coal B), individually blended with a petcoke in the gasifier were considered. ... results suggested that, when the petcoke was mixed with Coal A over 70%, the slagging problem, which could shorten the operational period due to high ash content in the coal, was improved. ...

Zhonghua Sun; Zhenghua Dai; Zhijie Zhou; Jianliang Xu; Guangsuo Yu

2012-09-27T23:59:59.000Z

282

The association of XRCC1 haplotypes and chromosomal damage levels in peripheral blood lymphocyte among coke-oven workers  

SciTech Connect

Theoretically, a haplotype has a higher level of heterozygosity than individual single nucleotide polymorphism (SNP) and the association study based on the haplotype may have an increased power for detecting disease associations compared with SNP-based analysis. In this study, we investigated the effects of four haplotype-tagging SNPs (htSNP) and the inferred haplotype pairs of the X-ray cross-complementing group 1 (XRCC1) gene on chromosome damage detected by the cytokinesis-block micronucleus assay. The study included 141 coke-oven workers with exposure to a high level of polycyclic aromatic hydrocarbons and 66 nonexposed controls. The frequencies of total MN and MNed cells were borderline associated with the Arg{sup 194}Trp polymorphism (P = 0.053 and P = 0.050, respectively) but not associated with the Arg{sup 280}His, Arg{sup 399}Gln and Gln{sup 632}Gln polymorphisms among coke-oven workers. Five haplotypes, including CGGG, TGGG, CAGG, CGAG, and CGGA, were inferred based on the four htSNPs of XRCC1 gene. The haplotype CGGG was associated with the decreased frequencies of total MN and MNed cells, and the haplotypes TGGG and CGAG were associated with the increased frequencies of total MN and MNed cells with adjustment for covariates among coke-oven workers. This study showed that the haplotypes derived from htSNPs in the XRCC1 gene were more likely than single SNPs to correlate with the polycyclic aromatic hydrocarbon-induced chromosome damage among coke-oven workers.

Shuguang Leng; Juan Cheng; Linyuan Zhang; Yong Niu; Yufei Dai; Zufei Pan; Bin Li; Fengsheng He; Yuxin Zheng [Chinese Center for Disease Control and Prevention, Beijing (China). National Institute of Occupational Health and Poison Control

2005-05-15T23:59:59.000Z

283

Characterization of fly ashes from circulating fluidized bed combustion (CFBC) boilers cofiring coal and petroleum coke  

SciTech Connect

The chemistry, mineralogy, morphology, and particle size distribution were investigated in fly ashes from the burning of Datong (ShanXi, China) bituminous coal and the cofiring of Mideast high-sulfur petroleum coke (PC) with 30:70 (cal %) and 50:50 (cal %) blends of Datong bituminous coal in two commercial CFBC boilers. With the exception of CaO, the amounts of major oxides in the fly ashes from cofiring PC and coal were close to those of the common coal fly ashes. The PC-coal fly ashes were enriched in Ni, V, and Mo, implying these trace elements were mainly derived from PC. Ni and V, along with several other elements, such as Cr, Cu, Se, Pb, U, Th, and possibly As and Cd, increased in content with a decrease in temperature of the electrostatic precipitator (ESP). The results of chemistry, mineralogy, and morphology studies suggested that the desulfurization rate of the CFBC boilers at current conditions was low, and the PC tends to coarsen the fly ash particles and increase the loss on ignition (LOI) values, making these fly ashes unsuitable for use as a cement additive or a mineral admixture in concrete. Further studies on the combustion status of the CFBC boilers are needed if we want to be able to increase the desulfurization rate and produce high-quality fly ashes for broader and full utilization. 22 refs., 4 figs., 4 tabs.

Feihu Li; Jianping Zhai; Xiaoru Fu; Guanghong Sheng [Nanjing University, Nanjing (China). State Key Laboratory of Pollution Control & Resource Reuse, School of the Environment

2006-08-15T23:59:59.000Z

284

Coking” of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes  

Science Journals Connector (OSTI)

Deactivation of acidic zeolite catalysts during methanol conversion is investigated for elucidating how spatial constraints interfere mechanistically. Detailed product composition – including retained organic matter – is determined in a time resolved mode. At 270–300 °C with H-ZSM-5, first unsaturated hydrocarbons are formed—methane being the indicative co-product. Then the reaction rate increases auto-catalytically, but soon declines because of exhaustive pore filling. The retained organic matter consists mainly of ethyl-trimethyl-benzene- and isopropyl-dimethyl-benzene molecules. Alkylation of benzene rings with ethene and propene produces the deactivating molecules. At 475 °C, alkylation of benzene rings with olefins has shifted to the reverse, reactivating the H-ZSM-5 catalyst. Coke forms slowly on the surface of H-ZSM-5 crystallites. Spatial constraints suppress the formation of 2-ring aromatics. With the wide pore zeolite H-Y, fast deactivation is noticed—bigger aromatic molecules can be formed and are retained. Methanol reactions on the protonic catalyst sites are visualized as CH3+ attack for methylation and dehydrogenation, methane being the hydrogen-rich co-product. Methanol conversion on zeolites H-ZSM-58, H-EU-1 and H-Beta is comparatively investigated. Zone ageing is discussed for favorable reactor design. It is shown, how a multi-compound product composition is the source of information for elucidating complex reaction mechanisms.

Hans Schulz

2010-01-01T23:59:59.000Z

285

Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends  

SciTech Connect

Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

2008-05-15T23:59:59.000Z

286

Removal of ash from Indian Assam coking coal using sodium hydroxide and acid solutions  

SciTech Connect

Mineral matter (ash) removal from Assam coking coal by leaching with different concentrations of sodium hydroxide and acid (HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, and HF) solutions has been investigated at a temperature of 75 C. The parameters tested were concentration of NaOH, type of acid, concentration of acids, and number of acid leaching steps. Total ash removed increased with increase of NaOH and acid concentrations up to the range studied. For the same experimental conditions, treatment of caustic leached coal in HCl acid resulted in better demineralization than in H{sub 2}SO{sub 4} or HNO{sub 3} acid. In the NaOH-HNO{sub 3} leaching method, a higher concentration (>20%) of HNO{sub 3} acid had an adverse effect on the de-ashing of coal. The NaOH-HF leaching process has been found to be the most effective method of coal de-ashing. The two acid treatment steps (HCl-H{sub 2}SO{sub 4}/HCl-HNO{sub 3}) after caustic leaching are the next most effective methods of coal de-ashing. The removal of mineral matter (including S) from coal is expected to decrease the graphite reactivity and thus the atmospheric pollution (due to the generation of smaller quantities of CO and SO{sub 2} gases).

Kumar, M.; Shankar, R.H.

2000-03-01T23:59:59.000Z

287

Comparison of 3 MeV C{sup +} Ion-Irradiation Effects between The Nuclear Graphites made of Pitch and Petroleum Cokes  

SciTech Connect

Currently, all the commercially available nuclear graphite grades are being made from two different cokes, i.e., petroleum coke or coal-tar pitch coke, and a coal-tar pitch binder. Of these, since the coke composes most of the graphite volume, i.e., > 70 %, it is understood that a physical, chemical, thermal, and mechanical property as well as an irradiation-induced property change will be strongly dependent on the type of coke. To obtain first-hand information on the effects of the coke type, i.e., petroleum or pitch, on the irradiation sensitivity of graphite, specimens made of IG-110 of petroleum coke and IG-430 of pitch coke were irradiated up to {approx} 19 dpa by 3 MeV C{sup +} at room temperature, and the irradiation-induced changes in the hardness, Young's modulus, Raman spectrum, and oxidation properties were characterized. Results of the TEM show that the size and density of the Mrozowski cracks appeared to be far larger and higher in the IG-110 than the IG-430. Results of the hardness test revealed a slightly higher increase in the IG-430 than the IG-110 by around 10 dpa, and the Raman spectrum measurement showed a higher (FWHM){sub D}/(FWHM){sub G} value for IG-430 for 0.02 {approx} 0.25 dpa. Both the hardness and Raman measurement may imply a higher irradiation sensitivity of the IG-430 than the IG-110. Results of the Young's modulus measurements showed a large data scattering, which prevented us from estimating the differences between the grades. Oxidation experiments using a TG-DTA under a flow of dry air/He = 2.5 % (flow rate: 40 CC/min) at 750 and 1000 deg C show that the IG-110 of the petroleum coke exhibits a far higher oxidation rate than the IG-430. The discrepancy between the oxidation rate of the two grades increased with an increase in the oxidation temperature and the dose. Oxidized surface pore area was larger for IG-110. Judging from the results obtained from the present experimental conditions, the irradiation sensitivity appeared to be dependent on the degree of graphitization (thus, the perfection of graphite structure), and the differences in the oxidation property of the grades appeared to be largely affected by the structure of the Mrozowski cracks. Differences in the size and density of the Mrozowski cracks between the grades were attributed to the differences in the thermal conductivity of the grades. (authors)

Se-Hwan, Chi; Gen-Chan, Kim; Jong-Hwa, Chang [Nuclear Hydrogen Development and Demonstration Project, Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon (Korea, Republic of)

2006-07-01T23:59:59.000Z

288

Detection of natural oxidation of coking coal by TG-FTIR—mechanistic implications  

Science Journals Connector (OSTI)

The natural oxidation/weathering of coal continues to be a subject of interest both scientifically and industrially, in part due to the complexity of the molecular processes at hand as well as to the commercial implications involved. It is widely recognized that coking can be adversely affected by weathering whereas, combustion processes appear to be enhanced as result of oxidation. Combustion techniques are commonly used in the analysis of coal, and organic compounds in general, for the determination of elemental hydrogen, carbon and nitrogen. For oxygen, the method in common practice involves the determination by difference from directly determined values for moisture, ash, sulphur, hydrogen, carbon and nitrogen. This has led us to consider the use of thermogravimetry coupled to gas analysis by infrared spectroscopy (TG-FTIR) to measure organic oxygen in coal directly. Although this technique, developed by Solomon and coworkers, has been extensively used by our group and others, it appears not to have been considered for this particular purpose. Recently, we have shown that TG-FTIR is capable of measuring all the organic oxygen in both fresh and oxidized coal by simultaneous measurement of the three main oxygen-containing gases H2O, CO and CO2 evolved during rapid pyrolysis. This gives us a way of measuring quantitatively the oxygen introduced into the coal matrix during oxidation and at least a partial capability of establishing oxygen speciation. We have found, using TG-FTIR, that the early stages of coal oxidation results in the appearance of O-containing functional groups not present in the original coal. The nature of these functional groups is directly related to the oxidation reaction mechanism. These results will be presented and discussed in detail.

J.A. MacPhee; L. Giroux; J.-P. Charland; J.F. Gransden; J.T. Price

2004-01-01T23:59:59.000Z

289

A scanning electron microscope study on agglomeration in petroleum coke-fired FBC boilers  

Science Journals Connector (OSTI)

Ten samples originating from different boiler FBC systems burning petroleum coke and one laboratory sample were chosen to perform a study on the development, structure, and composition of deposits formed by agglomeration in various locations. The work focused on examination by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The possibility of a contribution of liquid phases in the adherence to solid surfaces and in agglomeration was discussed and checks by SEM, EDX, and analysis by neutron activation were performed; no evidence could be found either for liquid phases or for any role of vanadium or alkaline element compounds. The agglomerations result from the continued sintering of CaSO4 particles until they build up a strong framework that is indefinitely extended, into which particles of different and complex compositions are bound, without contributing to the cohesion. Chemical sintering occurring by the sulphation of CaO into CaSO4 appears to be an important contribution while CaO is still available, but sintering also occurs by mass transfer mechanisms and continues after the depletion of CaO. Deposits formed in regions only reached by fly ash (convection section), and also in in-bed deposits, grow from particles <50 ?m, mostly in the range of 10 ?m or less. In regions collecting bed ash (e.g., J-valves), the deposit grows from the sintering together of particles on the order of 100–300 ?m (originally bed ash particles), which themselves appear as conglomerates of extensively sintered smaller particles.

J.V Iribarne; E.J Anthony; A Iribarne

2003-01-01T23:59:59.000Z

290

A new mechanism for FBC agglomeration and fouling when firing 100% petroleum coke  

SciTech Connect

In a preliminary study of the problem of agglomeration development in the petroleum coke combustion ashes, samples from different locations in a combustor from an industrial CFBC boiler were analyzed. Various oxides and calcium compounds of vanadium were found, in all cases, amounting to a total of 0.1--0.2% of V. These compounds do not accumulate (i.e. their concentration in the deposit does not increase) in the course of the FBC operation. The deposits show abnormally high conversion to CaSO{sub 4}, in some cases with very little content of free CaO, and a new mechanism of agglomeration similar to chemical reaction sintering is proposed. Different possible mechanisms leading to the formation of agglomerates were examined and the hypothesis that currently seems to best fit with the data is that the agglomeration phenomenon is due to a ``molecular cramming`` effect caused by the nearly quantitative conversion of the CaO to CaSO{sub 4}. While the absence of fuel derived ash, which would normally provide discontinuities in the deposits allowing them to break up, instead permits the buildup of massive monolithic deposits in various parts of the CFBC primary reactor loop. This explanation is also consistent with the ability of Mg compounds to mitigate the problem, but it suggests that the effect of these compounds is to prevent the buildup of the deposits by providing ``inert material`` rather than by capturing vanadium oxides as has heretofore been supposed. Further systematic investigations are planned to definitively rule out a vanadate capture mechanisms and to explore whether sulfidization as opposed to sulfation plays any part in the buildup of these deposits.

Anthony, E.J. [CANMET, Ottawa, Ontario (Canada). Natural Resources Canada; Iribarne, A.P.; Iribarne, J.V. [Univ. of Toronto, Ontario (Canada)

1995-12-31T23:59:59.000Z

291

Fluid Inclusion Gas Analysis  

SciTech Connect

Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

Dilley, Lorie

2013-01-01T23:59:59.000Z

292

Effect of Pyrolysis and CO2 Gasification Pressure on the Surface Area and Pore Size Distribution of Petroleum Coke  

Science Journals Connector (OSTI)

Normalization of the reaction rate by the surface area indicated that the effect of the pressure on the physical characteristics of the petcoke was the main but not sole factor in the change of the reaction rate with the gasification pressure. ... As refiners are pushed toward producing cleaner transportation fuels from poorer quality crudes, the production of petroleum coke (petcoke) is increasing as a byproduct of heavy oil upgrading units. ... (1, 2) The majority of petcoke produced in Canada is currently stockpiled on the site of the plant. ...

Maryam Malekshahian; Josephine M. Hill

2011-10-03T23:59:59.000Z

293

Characteristics of a commercially aged Ni-Mo/Al2O3 hydrotreating catalyst: component distribution, nature of coke and effects of regeneration  

SciTech Connect

Information concerning the morphology and behavior of active components on commercially aged catalyst, the effects of regeneration conditions on activity, and insights into the nature of coke and contaminant metal deposits could lead to improved catalysts and operating conditions , yielding significant economic returns. Spent Ni-Mo/Al2O3 hydrotreating catalyst from a commercial hydrotreater was examined using TGA, SEM, STEM, XPS, and a microreactor. Information concerning intraparticle distributions of active components, characteristics of the coke and metal deposits, and catalytic activity for fresh, spent and regenerated catalyst was used to draw general conclusions concerning hydrotreating catalyst deactivation. It was found that catalytic activity was reduced and the nature of the hydrogenation function was altered due to bulk migration and agglomeration of molybdenum. This process was found to be accelerated by high-temperature regeneration. Results also indicated that iron deposits might catalyze formation of coke. Tentative generalizations and suggestions on improved reactor operation are presented.

Bogdanor, J.M.

1984-01-01T23:59:59.000Z

294

Effects of genetic polymorphisms of metabolic enzymes on cytokinesis-block micronucleus in peripheral blood lymphocyte among coke-oven workers  

SciTech Connect

Exploring the associations between genetic polymorphisms of metabolic enzymes and susceptibility to polycyclic aromatic hydrocarbon (PAH)-induced chromosomal damage is of great significance for understanding PAH carcinogenesis. Cytochrome P450, glutathione S-transferase, microsomal epoxide hydrolase, NAD(P)H:quinone oxidoreductase, and N-acetyltransferase are PAH-metabolizing enzymes. In this study, we genotyped for the polymorphisms of these genes and assessed their effects on cytokinesis-block micronucleus (CBMN) frequencies in peripheral blood lymphocytes among 141 coke-oven workers and 66 non-coke-oven worker controls. The geometric means of urinary 1-hydroxypyrene levels in coke-oven workers and the controls were 12.0 and 0.7 {mu}mol/mol creatinine, respectively. The CBMN frequency (number of micronuclei per 1,000 binucleated lymphocytes) was significantly higher in coke-oven workers (9.5 {+-} 6.6) than in the controls. Among the coke-oven workers, age was positively associated with CBMN frequency; the mEH His{sup 113} variant genotype exhibited significantly lower CBMN frequency than did the Tyr{sup 113}/Tyr{sup 113} genotype; the low mEH activity phenotype exhibited a lower CBMN frequency than did the high mEH activity phenotype; the GSTP1 Val{sup 105}/Val{sup 105} genotype exhibited a higher CBMN frequency than did the GSTP1 Ile{sup 105}/Ile{sup 105} or Ile{sup 105}/Val{sup 105} genotypes; the joint effect of high mEH activity phenotype and GSTM1 null genotype on CBMN frequencies was also found. Gene-environment interactions between occupational PAH exposure and polymorphisms of mEH and/or GSTM1 were also evident. These results indicate that the mEH, GSTP1, and GSTM1 polymorphisms may play a role in sensitivity or genetic susceptibility to the genotoxic effects of PAH exposure in the coke-oven workers.

Shuguang Leng; Yufei Dai; Yong Niu; Zufei Pan; Xiaohua Li; Juan Cheng; Fengsheng He; Yuxin Zheng [Chinese Center for Disease Control and Prevention, Beijing (China). National Institute for Occupational Health and Poison Control

2004-10-15T23:59:59.000Z

295

Physicochemical characterization of coke-plant soil for the assessment of polycyclic aromatic hydrocarbon availability and the feasibility of phytoremediation  

SciTech Connect

Coke oven site soil was characterized to assess the particle association and availability of polycyclic aromatic hydrocarbons (PAHs). We identified various carbonaceous materials including coal, coke, pitch, and tar decanter sludge. Most of the PAHs were associated with the polymeric matrix of tar sludge or hard pitch as discrete particles, coatings on soil mineral particles, or complex aggregates. The PAH availability from these particles was very low due to hindered diffusive release from solid tar or pitch with apparent diffusivities of 6 x 10{sup -15} for phenanthrene, 3 x 10{sup -15} for pyrene, and 1 x 10{sup -15} cm{sup 2}/s for benzo(a)pyrene. Significant concentrations of PAHs were observed in the interior of solid tar aggregates with up to 40,000 mg/kg total PAHs. The release of PAHs from the interior of such particles requires diffusion over a substantial distance, and semipermeable membrane device tests confirmed a very limited availability of PAHs. These findings explain the results from three years of phytoremediation of the site soil, for which no significant changes in the total PAH concentrations were observed in the test plot samples. The observed low bioavailability of PAHs probably inhibited PAH phytoremediation, as diffusion-limited mass transfer would limit the release of PAHs to the aqueous phase.

Ahn, S.; Werner, D.; Luthy, R.G. [Stanford University, Stanford, CA (United States). Dept. of Civil & Environmental Engineering

2005-09-01T23:59:59.000Z

296

Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China  

SciTech Connect

A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-08-01T23:59:59.000Z

297

Fluid transport container  

DOE Patents (OSTI)

An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitting for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container. 13 figs.

DeRoos, B.G.; Downing, J.P. Jr.; Neal, M.P.

1995-11-14T23:59:59.000Z

298

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

2 Relative Standard Errors for Table 7.2;" 2 Relative Standard Errors for Table 7.2;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

299

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

Relative Standard Errors for Table 7.1;" Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

300

Standardization of Thermo-Fluid Modeling in Modelica.Fluid  

E-Print Network (OSTI)

Thermo-Fluid Systems, Modelica 2003 Conference, Linköping,H. Tummescheit: The Modelica Fluid and Media Library forThermo-Fluid Pipe Networks, Modelica 2006 Conference, Vi-

Franke, Rudiger

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy  

SciTech Connect

Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2009-03-15T23:59:59.000Z

302

Environmentally safe fluid extractor  

DOE Patents (OSTI)

An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

Sungaila, Zenon F. (Orland Park, IL)

1993-01-01T23:59:59.000Z

303

HEAT TRANSFER FLUIDS  

E-Print Network (OSTI)

The choice of heat transfer fluids has significant effects on the performance, cost, and reliability of solar thermal systems. In this chapter, we evaluate existing heat transfer fluids such as oils and molten salts based ...

Lenert, Andrej

2012-01-01T23:59:59.000Z

304

Fluid force transducer  

DOE Patents (OSTI)

An electrical fluid force transducer for measuring the magnitude and direction of fluid forces caused by lateral fluid flow, includes a movable sleeve which is deflectable in response to the movement of fluid, and a rod fixed to the sleeve to translate forces applied to the sleeve to strain gauges attached to the rod, the strain gauges being connected in a bridge circuit arrangement enabling generation of a signal output indicative of the magnitude and direction of the force applied to the sleeve.

Jendrzejczyk, Joseph A. (Warrenville, IL)

1982-01-01T23:59:59.000Z

305

Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products  

SciTech Connect

A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

2007-07-01T23:59:59.000Z

306

Fiber optic fluid detector  

DOE Patents (OSTI)

Particular gases or liquids are detected with a fiber optic element having a cladding or coating of a material which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses. 10 figs.

Angel, S.M.

1987-02-27T23:59:59.000Z

307

Effects of polymerization and briquetting parameters on the tensile strength of briquettes formed from coal coke and aniline-formaldehyde resin  

SciTech Connect

In this work, the utilization of aniline (C{sub 6}H{sub 7}N) formaldehyde (HCHO) resins as a binding agent of coke briquetting was investigated. Aniline (AN) formaldehyde (F) resins are a family of thermoplastics synthesized by condensing AN and F in an acid solution exhibiting high dielectric strength. The tensile strength sharply increases as the ratio of F to AN from 0.5 to 1.6, and it reaches the highest values between 1.6 and 2.2 F/AN ratio; it then slightly decreases. The highest tensile strength of F-AN resin-coke briquette (23.66 MN/m{sup 2}) was obtained from the run with 1.5 of F/AN ratio by using (NH4){sub 2}S{sub 2}O{sub 8} catalyst at 310 K briquetting temperature. The tensile strength of F-AN resin-coke briquette slightly decreased with increasing the catalyst percent to 0.10%, and then it sharply decreased to zero with increasing the catalyst percent to 0.2%. The effect of pH on the tensile strength is irregular. As the pH of the mixture increases from 9.0 to 9.2, the tensile strength shows a sharp increase, and the curve reaches a plateau value between pH 9.3 and 9.9; then the tensile strength shows a slight increase after pH = 9.9.

Demirbas, A.; Simsek, T. [Selcuk University, Konya (Turkey)

2006-10-15T23:59:59.000Z

308

Production of syngas via partial oxidation and CO{sub 2} reforming of coke oven gas over a Ni catalyst  

SciTech Connect

The partial oxidation and CO{sub 2} reforming of coke oven gas (COG) to syngas was investigated on differently sized Ni catalysts in a fluidized-bed reactor. It was found that the catalytic performance of Ni depends strongly on its particle size. The small-sized Ni catalyst exhibited higher activity and higher selectivity in the partial oxidation of COG. The conversion of CH{sub 4} was kept at 80.7% at a lower temperature (750{sup o}C) and a wide space velocity (from 8000 to 80 000 h{sup -1}). CO{sub 2} reforming of COG is also an efficient route for syngas production. The H{sub 2}/CO ratio in the COG-derived syngas could be controlled by manipulating the concentration of O{sub 2} or CO{sub 2} added in the feed. The yield of produced syngas increases with an increase in temperature. 19 refs., 10 figs., 2 tabs.

Jianzhong Guo; Zhaoyin Hou; Jing Gao; Xiaoming Zheng [Zhejiang University, Hangzhou (China). Institute of Catalysis, Department of Chemistry

2008-05-15T23:59:59.000Z

309

Study on one-dimensional steady combustion of highly densified biomass briquette (bio-coke) in air flow  

Science Journals Connector (OSTI)

Abstract Combustion experiments on cylindrical bio-coke (BIC), a highly densified biomass briquette, have been conducted to observe whether quasi-one-dimensional steady combustion can be attained in room temperature air flow. In the experiments, the air flow velocity was the main test condition and the fuel consumption rate when the bottom surface of the BIC sample burned was evaluated as the regression rate of the combustion zone at the bottom surface. In addition, one-dimensional calculations based on an energy equation at the combustion zone were conducted to understand the mechanism that results in steady combustion and predict the effect of water and volatile matter content in BIC on the extinction limit. The results showed that steady combustion of the BIC sample could be attained in 4.67 m/s or more, and, in contrast, extinction was observed in 3.82 m/s or less. The critical regression rate explained by the combustion zone temperature was shown, and the reason combustion becomes unsteady could be explained by the energy balance at the combustion zone. Though the main reason for extinction was radiation heat loss, the heat loss by water and volatile matter was not negligible. Therefore, the effect of water and volatile matter content on steady combustion must be considered.

Takero Nakahara; Hui Yan; Hiroyuki Ito; Osamu Fujita

2014-01-01T23:59:59.000Z

310

Thermodynamics and Fluids  

Science Journals Connector (OSTI)

... AN important section of the work of modern chemical engineers lies in the application of thermodynamics to problems of fluid systems. This volume, the fourth in the series, is ... properties of physical systems and to the transport properties of fluids. The first section on thermodynamics has been written by Dr. R. Strickland Constable of the Chemical Engineering Department at ...

J. M. COULSON

1958-09-27T23:59:59.000Z

311

Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace  

SciTech Connect

Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

Dr. Chenn Zhou

2008-10-15T23:59:59.000Z

312

MAX Fluid Dynamics facility  

NLE Websites -- All DOE Office Websites (Extended Search)

MAX Fluid Dynamics facility MAX Fluid Dynamics facility Capabilities Engineering Experimentation Reactor Safety Testing and Analysis Overview Nuclear Reactor Severe Accident Experiments MAX NSTF SNAKE Aerosol Experiments System Components Laser Applications Robots Applications Other Facilities Other Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr MAX Fluid Dynamics facility Providing high resolution data for development of computational tools that model fluid flow and heat transfer within complex systems such as the core of a nuclear reactor. 1 2 3 4 5 Hot and cold air jets are mixed within a glass tank while laser-based anemometers and a high-speed infrared camera characterize fluid flow and heat transfer behavior. Click on image to view larger size image.

313

Fluid sampling tool  

DOE Patents (OSTI)

A fluid sampling tool is described for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall. 6 figs.

Garcia, A.R.; Johnston, R.G.; Martinez, R.K.

1999-05-25T23:59:59.000Z

314

IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY |  

Open Energy Info (EERE)

IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY Details Activities (1) Areas (1) Regions (0) Abstract: Fluid Inclusion Stratigraphy (FIS) is a method currently being developed for use in geothermal systems to identify fractures and fluid types. This paper is the third in a series of papers on the development of FIS. Fluid inclusion gas chemistry is analyzed and plotted on well log diagrams. The working hypothesis is that select gaseous species and species ratios indicate areas of groundwater and reservoir fluid flow and reservoir seals. Previously we showed that FIS analyses identify fluid types and

315

Multiphase fluid characterization system  

DOE Patents (OSTI)

A measurement system and method for permitting multiple independent measurements of several physical parameters of multiphase fluids flowing through pipes are described. Multiple acoustic transducers are placed in acoustic communication with or attached to the outside surface of a section of existing spool (metal pipe), typically less than 3 feet in length, for noninvasive measurements. Sound speed, sound attenuation, fluid density, fluid flow, container wall resonance characteristics, and Doppler measurements for gas volume fraction may be measured simultaneously by the system. Temperature measurements are made using a temperature sensor for oil-cut correction.

Sinha, Dipen N.

2014-09-02T23:59:59.000Z

316

Fluid pumping apparatus  

DOE Patents (OSTI)

A method and apparatus suitable for coupling seismic or other downhole sensors to a borehole wall in high temperature and pressure environments. In one embodiment, one or more metal bellows mounted to a sensor module are inflated to clamp the sensor module within the borehole and couple an associated seismic sensor to a borehole wall. Once the sensing operation is complete, the bellows are deflated and the sensor module is unclamped by deflation of the metal bellows. In a further embodiment, a magnetic drive pump in a pump module is used to supply fluid pressure for inflating the metal bellows using borehole fluid or fluid from a reservoir. The pump includes a magnetic drive motor configured with a rotor assembly to be exposed to borehole fluid pressure including a rotatable armature for driving an impeller and an associated coil under control of electronics isolated from borehole pressure.

West, Phillip B. (Idaho Falls, ID)

2006-01-17T23:59:59.000Z

317

Basic fluid system trainer  

DOE Patents (OSTI)

A trainer, mounted and housed within a mobile console, is used to teach and reinforce fluid principles to students. The system trainer has two centrifugal pumps, each driven by a corresponding two-speed electric motor. The motors are controlled by motor controllers for operating the pumps to circulate the fluid stored within a supply tank through a closed system. The pumps may be connected in series or in parallel. A number of valves are also included within the system to effect different flow paths for the fluid. In addition, temperature and pressure sensing instruments are installed throughout the closed system for measuring the characteristics of the fluid, as it passes through the different valves and pumps. These measurements are indicated on a front panel mounted to the console, as a teaching aid, to allow the students to observe the characteristics of the system.

Semans, Joseph P. (Uniontown, PA); Johnson, Peter G. (Pittsburgh, PA); LeBoeuf, Jr., Robert F. (Clairton, PA); Kromka, Joseph A. (Idaho Falls, ID); Goron, Ronald H. (Connellsville, PA); Hay, George D. (Venetia, PA)

1993-01-01T23:59:59.000Z

318

GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID | Open Energy  

Open Energy Info (EERE)

FLUID PROPENE AND PROPANE: INDICATORS OF FLUID FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Details Activities (1) Areas (1) Regions (0) Abstract: The use of fluid inclusion gas analysis propene/propene ratios is investigated. Ratios of these species are affected by geothermal fluid temperature and oxidations state. Our purpose is to determine if analyses of these species in fluid inclusions these species to can be used to interpret fluid type, history, or process. Analyses were performed on drill cuttings at 20ft intervals from four Coso geothermal wells. Two wells are good producers, one has cold-water entrants in the production zone, and the fourth is a non-producer. The ratios show distinct differences between

319

Numerical modeling of the aerodynamics, heat exchange, and combustion of a polydisperse ensemble of coke-ash particles in ascending axisymmetric two-phase flow  

SciTech Connect

A two-dimensional stationary model of motion, heat and mass exchange, and chemical reaction of polydisperse coke and ash particles in ascending gas-suspension flow has been constructed with allowance for the turbulent and pseudo turbulent mechanisms of transfer in the dispersed phase. The system of equations that describes motion and heat transfer in the solid phase has been closed at the level of the equations for the second moments of velocity and temperature pulsations, whereas the momentum equations of the carrying medium have been closed using the equation for turbulent gas energy, which allows for the influence of the particles and heterogeneous reactions.

B.B. Rokhman [National Academy of Sciences of Ukraine, Kiev (Ukraine). Institute of Coal Power Technologies

2009-07-15T23:59:59.000Z

320

Fluid driven reciprocating apparatus  

DOE Patents (OSTI)

An apparatus is described comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached. 13 figs.

Whitehead, J.C.

1997-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

View dependent fluid dynamics  

E-Print Network (OSTI)

VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2006 Major Subject: Visualization... Sciences VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Donald...

Barran, Brian Arthur

2006-08-16T23:59:59.000Z

322

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991  

SciTech Connect

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

323

Syngas production by CO2 reforming of coke oven gas over Ni/La2O3–ZrO2 catalysts  

Science Journals Connector (OSTI)

Abstract Syngas production by CO2 reforming of coke oven gas (COG) was studied in a fixed-bed reactor over Ni/La2O3–ZrO2 catalysts. The catalysts were prepared by sol–gel technique and tested by XRF, BET, XRD, H2-TPR, TEM and TG–DSC. The influence of nickel loadings and calcination temperature of the catalysts on reforming reaction was measured. The characterization results revealed that all of the catalysts present excellent resistance to coking. The catalyst with appropriate nickel content and calcination temperature has better dispersion of active metal and higher conversion. It is found that the Ni/La2O3–ZrO2 catalyst with 10 wt% nickel loading provides the best catalytic activity with the conversions of CH4 and CO2 both more than 95% at 800 °C under the atmospheric pressure. The Ni/La2O3–ZrO2 catalysts show excellent catalytic performance and anti-carbon property, which will be of great prospects for catalytic CO2 reforming of COG in the future.

Wei Tao; Hongwei Cheng; Weilin Yao; Xionggang Lu; Qiuhua Zhu; Guangshi Li; Zhongfu Zhou

2014-01-01T23:59:59.000Z

324

Total Number of Operable Refineries  

U.S. Energy Information Administration (EIA) Indexed Site

Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge Capacity (B/SD) Thermal Cracking Downstream Charge Capacity (B/SD) Thermal Cracking Total Coking Downstream Charge Capacity (B/SD) Thermal Cracking Delayed Coking Downstream Charge Capacity (B/SD Thermal Cracking Fluid Coking Downstream Charge Capacity (B/SD) Thermal Cracking Visbreaking Downstream Charge Capacity (B/SD) Thermal Cracking Other/Gas Oil Charge Capacity (B/SD) Catalytic Cracking Fresh Feed Charge Capacity (B/SD) Catalytic Cracking Recycle Charge Capacity (B/SD) Catalytic Hydro-Cracking Charge Capacity (B/SD) Catalytic Hydro-Cracking Distillate Charge Capacity (B/SD) Catalytic Hydro-Cracking Gas Oil Charge Capacity (B/SD) Catalytic Hydro-Cracking Residual Charge Capacity (B/SD) Catalytic Reforming Charge Capacity (B/SD) Catalytic Reforming Low Pressure Charge Capacity (B/SD) Catalytic Reforming High Pressure Charge Capacity (B/SD) Catalytic Hydrotreating/Desulfurization Charge Capacity (B/SD) Catalytic Hydrotreating Naphtha/Reformer Feed Charge Cap (B/SD) Catalytic Hydrotreating Gasoline Charge Capacity (B/SD) Catalytic Hydrotreating Heavy Gas Oil Charge Capacity (B/SD) Catalytic Hydrotreating Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Kerosene/Jet Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Diesel Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Other Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Residual/Other Charge Capacity (B/SD) Catalytic Hydrotreating Residual Charge Capacity (B/SD) Catalytic Hydrotreating Other Oils Charge Capacity (B/SD) Fuels Solvent Deasphalting Charge Capacity (B/SD) Catalytic Reforming Downstream Charge Capacity (B/CD) Total Coking Downstream Charge Capacity (B/CD) Catalytic Cracking Fresh Feed Downstream Charge Capacity (B/CD) Catalytic Hydro-Cracking Downstream Charge Capacity (B/CD) Period:

325

Atmospheric Crude Oil Distillation Operable Capacity  

Gasoline and Diesel Fuel Update (EIA)

(Barrels per Calendar Day) (Barrels per Calendar Day) Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge Capacity (B/SD) Thermal Cracking Downstream Charge Capacity (B/SD) Thermal Cracking Total Coking Downstream Charge Capacity (B/SD) Thermal Cracking Delayed Coking Downstream Charge Capacity (B/SD Thermal Cracking Fluid Coking Downstream Charge Capacity (B/SD) Thermal Cracking Visbreaking Downstream Charge Capacity (B/SD) Thermal Cracking Other/Gas Oil Charge Capacity (B/SD) Catalytic Cracking Fresh Feed Charge Capacity (B/SD) Catalytic Cracking Recycle Charge Capacity (B/SD) Catalytic Hydro-Cracking Charge Capacity (B/SD) Catalytic Hydro-Cracking Distillate Charge Capacity (B/SD) Catalytic Hydro-Cracking Gas Oil Charge Capacity (B/SD) Catalytic Hydro-Cracking Residual Charge Capacity (B/SD) Catalytic Reforming Charge Capacity (B/SD) Catalytic Reforming Low Pressure Charge Capacity (B/SD) Catalytic Reforming High Pressure Charge Capacity (B/SD) Catalytic Hydrotreating/Desulfurization Charge Capacity (B/SD) Catalytic Hydrotreating Naphtha/Reformer Feed Charge Cap (B/SD) Catalytic Hydrotreating Gasoline Charge Capacity (B/SD) Catalytic Hydrotreating Heavy Gas Oil Charge Capacity (B/SD) Catalytic Hydrotreating Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Kerosene/Jet Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Diesel Fuel Charge Capacity (B/SD) Catalytic Hydrotreating Other Distillate Charge Capacity (B/SD) Catalytic Hydrotreating Residual/Other Charge Capacity (B/SD) Catalytic Hydrotreating Residual Charge Capacity (B/SD) Catalytic Hydrotreating Other Oils Charge Capacity (B/SD) Fuels Solvent Deasphalting Charge Capacity (B/SD) Catalytic Reforming Downstream Charge Capacity (B/CD) Total Coking Downstream Charge Capacity (B/CD) Catalytic Cracking Fresh Feed Downstream Charge Capacity (B/CD) Catalytic Hydro-Cracking Downstream Charge Capacity (B/CD) Period:

326

Visually simulating realistic fluid motion  

E-Print Network (OSTI)

where 0 stands for obstacle cell, S surface cell, F full cell, I inlet cell, U outlet cell and the cells not marked are empty cells . . . . . . 34 12 Area weighting interpolation scheme for determining local fluid velocity for a marker k [9] . . 35... in the fluid. It is measured as the force on the face of a unit cube, inserted into the fluid. If the pressure varies in the fluid, the fluid will move due to the acceleration generated by the pressure force. The pressure at a point is isotropic in a fluid...

Naithani, Priyanka

2012-06-07T23:59:59.000Z

327

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID...  

Open Energy Info (EERE)

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

328

“From Coal to Coke  

Science Journals Connector (OSTI)

... IN the Sixth Coal Science Lecture, organized by the British ... Science Lecture, organized by the British Coal Utilization Research Association, and given at the Institution of Civil Engineers on October 16, ...

1957-11-02T23:59:59.000Z

329

Relativistic viscoelastic fluid mechanics  

SciTech Connect

A detailed study is carried out for the relativistic theory of viscoelasticity which was recently constructed on the basis of Onsager's linear nonequilibrium thermodynamics. After rederiving the theory using a local argument with the entropy current, we show that this theory universally reduces to the standard relativistic Navier-Stokes fluid mechanics in the long time limit. Since effects of elasticity are taken into account, the dynamics at short time scales is modified from that given by the Navier-Stokes equations, so that acausal problems intrinsic to relativistic Navier-Stokes fluids are significantly remedied. We in particular show that the wave equations for the propagation of disturbance around a hydrostatic equilibrium in Minkowski space-time become symmetric hyperbolic for some range of parameters, so that the model is free of acausality problems. This observation suggests that the relativistic viscoelastic model with such parameters can be regarded as a causal completion of relativistic Navier-Stokes fluid mechanics. By adjusting parameters to various values, this theory can treat a wide variety of materials including elastic materials, Maxwell materials, Kelvin-Voigt materials, and (a nonlinearly generalized version of) simplified Israel-Stewart fluids, and thus we expect the theory to be the most universal description of single-component relativistic continuum materials. We also show that the presence of strains and the corresponding change in temperature are naturally unified through the Tolman law in a generally covariant description of continuum mechanics.

Fukuma, Masafumi; Sakatani, Yuho [Department of Physics, Kyoto University, Kyoto 606-8502 (Japan)

2011-08-15T23:59:59.000Z

330

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

331

Magnetically stimulated fluid flow patterns  

ScienceCinema (OSTI)

Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

Martin, Jim; Solis, Kyle

2014-08-06T23:59:59.000Z

332

Fluid Flow Modeling in Fractures  

E-Print Network (OSTI)

In this paper we study fluid flow in fractures using numerical simulation and address the challenging issue of hydraulic property characterization in fractures. The methodology is based on Computational Fluid Dynamics, ...

Sarkar, Sudipta

2004-01-01T23:59:59.000Z

333

Oscillating fluid power generator  

SciTech Connect

A system and method for harvesting the kinetic energy of a fluid flow for power generation with a vertically oriented, aerodynamic wing structure comprising one or more airfoil elements pivotably attached to a mast. When activated by the moving fluid stream, the wing structure oscillates back and forth, generating lift first in one direction then in the opposite direction. This oscillating movement is converted to unidirectional rotational movement in order to provide motive power to an electricity generator. Unlike other oscillating devices, this device is designed to harvest the maximum aerodynamic lift forces available for a given oscillation cycle. Because the system is not subjected to the same intense forces and stresses as turbine systems, it can be constructed less expensively, reducing the cost of electricity generation. The system can be grouped in more compact clusters, be less evident in the landscape, and present reduced risk to avian species.

Morris, David C

2014-02-25T23:59:59.000Z

334

Downhole Fluid Analyzer Development  

SciTech Connect

A novel fiber optic downhole fluid analyzer has been developed for operation in production wells. This device will allow real-time determination of the oil, gas and water fractions of fluids from different zones in a multizone or multilateral completion environment. The device uses near infrared spectroscopy and induced fluorescence measurement to unambiguously determine the oil, water and gas concentrations at all but the highest water cuts. The only downhole components of the system are the fiber optic cable and windows. All of the active components--light sources, sensors, detection electronics and software--will be located at the surface, and will be able to operate multiple downhole probes. Laboratory testing has demonstrated that the sensor can accurately determine oil, water and gas fractions with a less than 5 percent standard error. Once installed in an intelligent completion, this sensor will give the operating company timely information about the fluids arising from various zones or multilaterals in a complex completion pattern, allowing informed decisions to be made on controlling production. The research and development tasks are discussed along with a market analysis.

Bill Turner

2006-11-28T23:59:59.000Z

335

Acoustic concentration of particles in fluid flow  

SciTech Connect

An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

Ward, Michael D. (Los Alamos, NM); Kaduchak, Gregory (Los Alamos, NM)

2010-11-23T23:59:59.000Z

336

Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report. Report No. 5 for reporting period May 1, 1999 through August 1, 1999  

SciTech Connect

The overall aim of the project is to demonstrate the performance and practical use of a probe for measuring the thickness of coke deposits located within the high-temperature tubes of a thermal cracking furnace. The objective of work during this period was to enhance the sensitivity and signal-to-noise ratio of the probe measurement. Testing identified that the primary source of signal noise was traced to imperfections in the sacrificial stand-off, which was formed using a casting procedure. Laminations, voids, and impurities contained in the casting result in attenuation and dispersion of the ultrasonic signal. This report describes the work performed to optimize the signal conductance of the sacrificial stand-off.

NONE

1999-08-15T23:59:59.000Z

337

Hydrogen production by reforming of simulated hot coke oven gas over nickel catalysts promoted with lanthanum and cerium in a membrane reactor  

SciTech Connect

Catalysts of Ni/Mg(Al)O promoted with lanthanum and cerium were tested in a BaCo{sub 0.7}Fe{sub 0.2}Nb{sub 0.1}O{sub 3{delta}} (BCFNO) membrane reactor by catalytic partial oxidation of simulated hot coke oven gas (COG) with toluene as a model tar compound under atmospheric pressure. Analysis of the catalysts suggested that the hydrotalcite precursor after thermal treatment lead to a good dispersion of nickel forming the solid solution NiO-MgO and spinel (Ni,Mg)Al{sub 2}O{sub 4}. The promoted catalysts had higher oxygen permeation flux, better catalytic activity, and better resistance to carbon formation, which will be promising catalysts in the catalytic partial oxidation reforming of hot COG. 29 refs., 11 figs., 2 tabs.

Hongwei Cheng; Xionggang Lu; Yuwen Zhang; Weizhong Ding [Shanghai University, Shanghai (China). Shanghai Key Laboratory of Modern Metallurgy and Materials Processing

2009-05-15T23:59:59.000Z

338

Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke  

Science Journals Connector (OSTI)

Abstract The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of \\{NAs\\} in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the \\{NAs\\} removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the \\{NAs\\} removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox® bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment.

Parastoo Pourrezaei; Alla Alpatova; Kambiz Khosravi; Przemys?aw Drzewicz; Yuan Chen; Pamela Chelme-Ayala; Mohamed Gamal El-Din

2014-01-01T23:59:59.000Z

339

The Co-cracking Experiment and Application Route of Waste Plastics and Heavy Oil  

Science Journals Connector (OSTI)

Abstract The co-cracking experiment of waste plastics and heavy oil was done in the condition of 400 °C and pressure not higher than 2.0 MPa. The experimental results showed that the yield of heavy oil and coke decreased but the light oil and gas yield increased with the increasing amount of waste plastics. The products of heavy oil's solidifying point, flash point, viscosity and density decreased and had a good pour point depression effect. Heavy oil containing heat conduction oil and solvent contributed to heat transfer, melting and transport and had the effect of dissolution and co-cracking. It would have a good prospect when the co-cracking of waste plastics and heavy oil was applied to the combination processes of visbreaking and delayed coking and catalytic cracking and delayed coking.

Shikui Wu; Kaixiong Xu; Lusen Jiang; Li Wang

2014-01-01T23:59:59.000Z

340

Volatiles in hydrothermal fluids- A mass spectrometric study of fluid  

Open Energy Info (EERE)

Volatiles in hydrothermal fluids- A mass spectrometric study of fluid Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Details Activities (4) Areas (4) Regions (0) Abstract: A system for analysis of inclusion gas contents based upon quadrupole mass spectrometry has been designed, assembled and tested during the first 7 months of funding. The system is currently being tested and calibrated using inclusions with known gas contents from active geothermal systems. Analyses are in progress on inclusions from the Salton Sea, Valles Caldera, Geysers, and Coso geothermal systems. Author(s): Mckibben, M. A.

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A heavy oil thermal cracking simulation program  

SciTech Connect

Correlations were developed to simulate the thermal cracking reaction of petroleum vacuum distillation residues through pilot plant data analysis. They use charge properties like specific gravity, viscosity, sulphur content and initial boiling point to give the yield and quality of products as a function of conversion, which is measured in terms of wt.% products with normal boiling point below 350{degrees}C. The mixture is represented with 24 lumps, and kinetic parameters for the reaction feed {r_arrow} products were also found as a function of feedstock properties. Finally, a computer program was developed to simulate fired heater operation for visbreaking and delayed coking units. 3 refs., 10 figs., 1 tab.

Maciel, R. [UNICAMP, Campinas (Brazil); Sugaya, M.F. [Petrobrais, Rio de Janeiro (Brazil)

1996-12-31T23:59:59.000Z

342

Notes 09. Fluid inertia and turbulence in fluid film bearings  

E-Print Network (OSTI)

When fluid inertia effects are important. Bulk-flow model for inertial flows. Turbulence and inertia in short length journal bearings and open end dampers....

San Andres, Luis

2009-01-01T23:59:59.000Z

343

Thermodynamic Model for Fluid-Fluid Interfacial Areas in Porous...  

NLE Websites -- All DOE Office Websites (Extended Search)

areas are important in controlling the rate of mass and energy transfer between fluid phases in porous media. We present a modified thermodynamically based model (TBM) to...

344

Fracturing Fluid Characterization Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

Documentation Page Documentation Page 1. Report No. DE - FC 21 - 92MC29077 2. 3. Recipient's Accession No. 5. Report Date August 31, 2000 4. Title and Subtitle Fracturing Fluid Characterization Facility 6. 7. Author(s) The University of Oklahoma 8. Performing Organization Rept. No. 10. Project/Task/Work Unit No. 9. Performing Organization Name and Address The University of Oklahoma Sarkeys Energy Center T301 100 E Boyd St Norman, OK 73019 11. Contract (C) or Grant (G) No. DOE:DE FC21 92 MC29077 13. Type of Report & Period Covered Final Report 09 30 92 - 03 31 00 12. Sponsoring Organization Name and Address US Dept of Energy - FETL 3610 Collins Ferry Road Morgantown, WV 26505 14. 15. Supplementary Notes Several technical papers were prepared and presented at various Society of Petroleum Engineers Conferences and US

345

Viscosity of Quantum Hall Fluids  

Science Journals Connector (OSTI)

The viscosity of quantum fluids with an energy gap at zero temperature is related to the adiabatic curvature on the space parametrizing flat background metrics. For quantum Hall fluids on two-dimensional tori, the quantum viscosity is computed. It turns out to be isotropic, constant, and proportional to the magnetic field strength.

J. E. Avron; R. Seiler; P. G. Zograf

1995-07-24T23:59:59.000Z

346

Fluid Mechanics and Homeland Security  

E-Print Network (OSTI)

Fluid Mechanics and Homeland Security Gary S. Settles Mechanical and Nuclear Engineering Department and sampling, explosive detection, microfluidics and labs-on-a-chip, chem- ical plume dispersal in urban security combines established fluids topics like plume dispersion with others that are new

Settles, Gary S.

347

LECTURES IN ELEMENTARY FLUID DYNAMICS  

E-Print Network (OSTI)

LECTURES IN ELEMENTARY FLUID DYNAMICS: Physics, Mathematics and Applications J. M. McDonough Departments of Mechanical Engineering and Mathematics University of Kentucky, Lexington, KY 40506-0503 c 1987, 1990, 2002, 2004, 2009 #12;Contents 1 Introduction 1 1.1 Importance of Fluids

McDonough, James M.

348

Effective perfect fluids in cosmology  

SciTech Connect

We describe the cosmological dynamics of perfect fluids within the framework of effective field theories. The effective action is a derivative expansion whose terms are selected by the symmetry requirements on the relevant long-distance degrees of freedom, which are identified with comoving coordinates. The perfect fluid is defined by requiring invariance of the action under internal volume-preserving diffeomorphisms and general covariance. At lowest order in derivatives, the dynamics is encoded in a single function of the entropy density that characterizes the properties of the fluid, such as the equation of state and the speed of sound. This framework allows a neat simultaneous description of fluid and metric perturbations. Longitudinal fluid perturbations are closely related to the adiabatic modes, while the transverse modes mix with vector metric perturbations as a consequence of vorticity conservation. This formalism features a large flexibility which can be of practical use for higher order perturbation theory and cosmological parameter estimation.

Ballesteros, Guillermo [Museo Storico della Fisica e Centro Studi e Ricerche Enrico Fermi, Piazza del Viminale 1, I-00184 Rome (Italy); Bellazzini, Brando, E-mail: guillermo.ballesteros@unige.ch, E-mail: brando.bellazzini@pd.infn.it [Dipartimento di Fisica, Università di Padova and INFN, Sezione di Padova, Via Marzolo 8, I-35131 Padova (Italy)

2013-04-01T23:59:59.000Z

349

"Code(a)","End Use","Electricity(b)","Fuel Oil","Diesel Fuel(c)"," Gas(d)","NGL(e)","Coke and Breeze)"  

U.S. Energy Information Administration (EIA) Indexed Site

3 Relative Standard Errors for Table 5.3;" 3 Relative Standard Errors for Table 5.3;" " Unit: Percents." " "," " " "," ",," ","Distillate"," "," " " "," ","Net Demand",,"Fuel Oil",,,"Coal" "NAICS"," ","for ","Residual","and","Natural","LPG and","(excluding Coal" "Code(a)","End Use","Electricity(b)","Fuel Oil","Diesel Fuel(c)"," Gas(d)","NGL(e)","Coke and Breeze)" ,,"Total United States" " 311 - 339","ALL MANUFACTURING INDUSTRIES" ,"TOTAL FUEL CONSUMPTION",2,3,6,2,4,9

350

oil-emulsion (rotary) drilling fluid  

Science Journals Connector (OSTI)

oil-emulsion (rotary) drilling fluid, oil-emulsion fluid [Used where low fluid-loss, very thin cake, and good lubrication of the drill pipe are of primary importance, such as in directional drilling ...

2014-08-01T23:59:59.000Z

351

oil-base(d) (rotary) drilling fluid  

Science Journals Connector (OSTI)

oil-base(d) (rotary) drilling fluid, oil-base(d) fluid [Used primarily for drilling-in or recomputing wells in formations subject ... with low formation pressures. See remark under “drilling fluid”] ...

2014-08-01T23:59:59.000Z

352

Lattice Boltzmann simulations of complex fluids  

Science Journals Connector (OSTI)

......research-article Articles Lattice Boltzmann simulations of complex fluids...OX1 3NP, UK We discuss how lattice Boltzmann simulations can be used to model...binary and lamellar fluids. lattice Boltzmann|complex fluids|shear flow......

J. M. YEOMANS; ALEXANDER J. WAGNER

2000-10-01T23:59:59.000Z

353

Multipurpose Acoustic Sensor for Downhole Fluid Monitoring  

Energy.gov (U.S. Department of Energy (DOE))

Novel sensor design based on acoustics. Determine in real-timeand in a single sensor packagemultiple parameters: temperature, pressure, fluid flow; and fluid properties, such as density, viscosity, fluid composition.

354

Finite element simulation of electrorheological fluids  

E-Print Network (OSTI)

Electrorheological (ER) fluids change their flow properties dramatically when an electric field is applied. These fluids are usually composed of dispersions of polarizable particles in an insulating base fluid or composed ...

Rhyou, Chanryeol, 1973-

2005-01-01T23:59:59.000Z

355

Computational fluid dynamic applications  

SciTech Connect

The rapid advancement of computational capability including speed and memory size has prompted the wide use of computational fluid dynamics (CFD) codes to simulate complex flow systems. CFD simulations are used to study the operating problems encountered in system, to evaluate the impacts of operation/design parameters on the performance of a system, and to investigate novel design concepts. CFD codes are generally developed based on the conservation laws of mass, momentum, and energy that govern the characteristics of a flow. The governing equations are simplified and discretized for a selected computational grid system. Numerical methods are selected to simplify and calculate approximate flow properties. For turbulent, reacting, and multiphase flow systems the complex processes relating to these aspects of the flow, i.e., turbulent diffusion, combustion kinetics, interfacial drag and heat and mass transfer, etc., are described in mathematical models, based on a combination of fundamental physics and empirical data, that are incorporated into the code. CFD simulation has been applied to a large variety of practical and industrial scale flow systems.

Chang, S.-L.; Lottes, S. A.; Zhou, C. Q.

2000-04-03T23:59:59.000Z

356

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

1993-11-30T23:59:59.000Z

357

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, Mark D. (1426 Socastee Dr., North Augusta, SC 29841); Sweeney, Chad E. (3600 Westhampton Dr., Martinez, GA 30907-3036); Spangler, Jr., B. Samuel (2715 Margate Dr., Augusta, GA 30909)

1993-01-01T23:59:59.000Z

358

Fluid sampling system  

DOE Patents (OSTI)

An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to be decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank. 4 figs.

Houck, E.D.

1994-10-11T23:59:59.000Z

359

Tracing Geothermal Fluids  

SciTech Connect

Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

Michael C. Adams; Greg Nash

2004-03-01T23:59:59.000Z

360

Detachment Energies of Spheroidal Particles from Fluid-Fluid Interfaces  

E-Print Network (OSTI)

The energy required to detach a single particle from a fluid-fluid interface is an important parameter for designing certain soft materials, for example, emulsions stabilised by colloidal particles, colloidosomes designed for targeted drug delivery, and bio-sensors composed of magnetic particles adsorbed at interfaces. For a fixed particle volume, prolate and oblate spheroids attach more strongly to interfaces because they have larger particle-interface areas. Calculating the detachment energy of spheroids necessitates the difficult measurement of particle-liquid surface tensions, in contrast with spheres, where the contact angle suffices. We develop a simplified detachment energy model for spheroids which depends only on the particle aspect ratio and the height of the particle centre of mass above the fluid-fluid interface. We use lattice Boltzmann simulations to validate the model and provide quantitative evidence that the approach can be applied to simulate particle-stabilized emulsions, and highlight the experimental implications of this validation.

Gary B. Davies; Timm Krüger; Peter V. Coveney; Jens Harting

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system  

Science Journals Connector (OSTI)

Dry reforming of diesel fuel, an endothermic reaction, is an attractive process for on-board hydrogen/syngas production to increase energy efficiency. For operating this dry reforming process in a vehicle, we can use the exhaust gas from an exhaust gas recirculation (EGR) system as a source of carbon dioxide. Catalytic dry reforming of heavy hydrocarbon is a very difficult reaction due to the high accumulation of carbon on the catalyst. Therefore, we attempted to use a non-equilibrium pulsed plasma for the dry reforming of model diesel fuel without a catalyst. We investigated dry reforming of model diesel fuel (n-dodecane) with a low-energy pulsed spark plasma, which is a kind of non-equilibrium plasma at a low temperature of 523?K. Through the reaction, we were able to obtain syngas (hydrogen and carbon monoxide) and a small amount of C2 hydrocarbon without coke formation at a ratio of CO2/Cfuel = 1.5 or higher. The reaction can be conducted at very low temperatures such as 523?K. Therefore, it is anticipated as a novel and effective process for on-board syngas production from diesel fuel using an EGR system.

Yasushi Sekine; Naotsugu Furukawa; Masahiko Matsukata; Eiichi Kikuchi

2011-01-01T23:59:59.000Z

362

Downhole Fluid Sampling | Open Energy Information  

Open Energy Info (EERE)

Downhole Fluid Sampling Downhole Fluid Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Downhole Fluid Sampling Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Water composition and source of fluids. Gas composition and source of fluids. Thermal: Water temperature. Distinguish magmatic/mantle heat inputs. Can be used to estimate reservoir fluid temperatures. Dictionary.png Downhole Fluid Sampling: Downhole fluid sampling is done to characterize the chemical, thermal, or hydrological properties of a surface or subsurface aqueous system. Downhole

363

Isotopic Analysis- Fluid | Open Energy Information  

Open Energy Info (EERE)

Isotopic Analysis- Fluid Isotopic Analysis- Fluid Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Isotopic Analysis- Fluid Details Activities (61) Areas (32) Regions (6) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Water rock interaction Stratigraphic/Structural: Hydrological: Origin of hydrothermal fluids; Mixing of hydrothermal fluids Thermal: Isotopic ratios can be used to characterize and locate subsurface thermal anomalies. Dictionary.png Isotopic Analysis- Fluid: Isotopes are atoms of the same element that have different numbers of neutrons. An isotopic analysis looks at a particular isotopic element(s) in

364

Gel Evolution in Oil Based Drilling Fluids.  

E-Print Network (OSTI)

?? Drilling fluids make up an essential part of the drilling operation. Successful drilling operations rely on adequate drilling fluid quality. With the development of… (more)

Sandvold, Ida

2012-01-01T23:59:59.000Z

365

Shale Gas Development Challenges: Fracture Fluids | Department...  

Office of Environmental Management (EM)

Fluids Shale Gas Development Challenges: Fracture Fluids More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary FracFocus 2.0 Task Force...

366

Chemically Reactive Working Fluids | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

367

Acoustic Concentration Of Particles In Fluid Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. Available for thumbnail of...

368

Fluid Gravity Engineering Rocket motor flow analysis  

E-Print Network (OSTI)

Fluid Gravity Engineering Capability · Rocket motor flow analysis -Internal (performance) -External young scientists/engineers Fluid Gravity Engineering Ltd #12;

Anand, Mahesh

369

Factorial tests on process operating conditions and bed fines on the circulating fluid bed performance  

SciTech Connect

A cold-flow circulating fluid bed (CFB) was operated using coke breeze with a packed-bed standpipe over a range of riser and standpipe air flows. The bed materials were selected to simulate solids flow in a CFB gasifier (carbonizer) but are generally relevant to most CFB processes. CFB tests were conducted primarily in the transport mode with sufficient gas velocity to achieve a uniform axial riser pressure profiles over most of the riser height. The independent variables tested included the riser gas velocity, aeration at the base of the standpipe, and concentration of fines (average particle size). The solids inventory and riser outlet pressure were maintained constant. Factorial tests were conducted in randomized order and in duplicate to provide and an unbiased estimate of the error. Fines were tested as a blocked variable. The gas velocity, standpipe aeration, and relative amount of fine particles were all found to be significant factors affecting both the riser solids holdup and solids flux. The riser pressure drop and mass circulation increased at the higher level of fines contrary to some earlier reports in the literature. The riser pressure drop was fitted using the general linear model (GLM), which explained more than 98% of the variation within the data, while a GLM for the mass circulation rate explained over 90%. The uncertainty of process operating variables was characterized independently through a series of duplicated flow proving experiments.

Shadle, L.J.; Spenik, James; Sarra, Angela; Ontko, J.S.

2004-07-21T23:59:59.000Z

370

Fluid catalytic cracking feed hydrotreatment and its severity impact on product yields and quality  

Science Journals Connector (OSTI)

This paper investigates the effect of fluid catalytic cracking (FCC) feed hydrotreatment and its severity increase on product yields and quality obtained in a commercial and a laboratory MAT FCC units. The hydrotreatment of Ural heavy vacuum gas oil reduces not only sulfur, nitrogen, Conradson carbon and metals content in the FCC feed but also increases the mononuclear aromatic hydrocarbons content by 8% absolute at almost no change in the total aromatics content. Regardless of this 8% increase of the mononuclear aromatics in the hydrotreated FCC feed the conversion increase in both commercial and laboratory MAT units was only 2%. The severity increase in the FCC feed hydrotreater leads to a higher conversion in the FCC, higher hydrogen transfer rate that results in higher isobutane/butylenes ratio, lower gasoline olefins content, and higher gasoline motor octane number. The hydrotreatment of the Ural heavy vacuum gas oil exhibited the same changes in FCC catalyst selectivities: lower coke and LCO selectivities and higher gasoline selectivity in both commercial riser FCC unit that has between 2 and 3 s time on stream, and the fixed bed reactor MAT unit, that has 30 s time on stream.

Dicho S. Stratiev; Ivelina K. Shishkova; Dimitar S. Dobrev

2012-01-01T23:59:59.000Z

371

Fluid Imaging | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit History Facebook icon Twitter icon » Fluid Imaging Jump to: navigation, search Contents 1 Geothermal Lab Call Projects for Fluid Imaging 2 Geothermal ARRA Funded Projects for Fluid Imaging Geothermal Lab Call Projects for Fluid Imaging Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":14,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

372

Bio-inspired fluid locomotion  

E-Print Network (OSTI)

We have developed several novel methods of locomotion at low Reynolds number, for both Newtonian and non-Newtonian fluids: Robosnails 1 and 2, which operate on a lubrication layer, and the three-link swimmer which moves ...

Chan, Brian, 1980-

2009-01-01T23:59:59.000Z

373

Self-similar perfect fluids  

E-Print Network (OSTI)

Space-times admitting an $r$-parameter Lie group of homotheties are studied for $r > 2$ devoting a special attention to those representing perfect fluid solutions to Einstein's field equations.

J. Carot; A. M. Sintes

2000-05-16T23:59:59.000Z

374

Biocatalytic transformations of hydrothermal fluids  

Science Journals Connector (OSTI)

...emission into oxygenated ambient seawater. The large metabolic and physiological...emission into oxygenated ambient seawater. The large metabolic and physiological...DNA (the reproducing genetic storage for each species), individual...where entrained oxygenated seawater mixes with hydrothermal fluid...

1997-01-01T23:59:59.000Z

375

Atomistic methods in fluid simulation  

Science Journals Connector (OSTI)

...easily describable by traditional methods, as ICF involves a complex coupling between fluid instabilities and combustion processes at very small length and times scales. One contribution of 13 to a Theme Issue Turbulent mixing and beyond . Figure...

2010-01-01T23:59:59.000Z

376

Transparent fluids for 157-nm immersion lithography  

E-Print Network (OSTI)

- gineers. [DOI: 10.1117/1.1637366] Subject terms: 157-nm lithography; immersion fluid; perfluoropolyether

Rollins, Andrew M.

377

Pitch-catch only ultrasonic fluid densitometer  

DOE Patents (OSTI)

The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

Greenwood, Margaret S. (Richland, WA); Harris, Robert V. (Pasco, WA)

1999-01-01T23:59:59.000Z

378

Pitch-catch only ultrasonic fluid densitometer  

DOE Patents (OSTI)

The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

Greenwood, M.S.; Harris, R.V.

1999-03-23T23:59:59.000Z

379

Fluid Mechanics IB Lecturer: Dr Natalia Berloff  

E-Print Network (OSTI)

-efficient aircraft design, hydroelectric power, chemical processing, jet-driven cutting tools · our fluid environment

380

DEVELOPMENT OF NEW DRILLING FLUIDS  

SciTech Connect

The goal of the project has been to develop new types of drill-in fluids (DIFs) and completion fluids (CFs) for use in natural gas reservoirs. Phase 1 of the project was a 24-month study to develop the concept of advanced type of fluids usable in well completions. Phase 1 tested this concept and created a kinetic mathematical model to accurately track the fluid's behavior under downhole conditions. Phase 2 includes tests of the new materials and practices. Work includes the preparation of new materials and the deployment of the new fluids and new practices to the field. The project addresses the special problem of formation damage issues related to the use of CFs and DIFs in open hole horizontal well completions. The concept of a ''removable filtercake'' has, as its basis, a mechanism to initiate or trigger the removal process. Our approach to developing such a mechanism is to identify the components of the filtercake and measure the change in the characteristics of these components when certain cleanup (filtercake removal) techniques are employed.

David B. Burnett

2003-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Association of polymorphisms in AhR, CYP1A1, GSTM1, and GSTT1 genes with levels of DNA damage in peripheral blood lymphocytes among coke-oven workers  

SciTech Connect

Accumulating evidence has shown that both DNA damage caused by the metabolites of polycyclic aromatic hydrocarbons (PAH) and genetic polymorphisms in PAH-metabolic genes contribute to individual susceptibility to PAH-induced carcinogenesis. However, the functional relevance of genetic polymorphisms in PAH-metabolic genes in exposed individuals is still unclear. In this study of 240 coke-oven workers (the exposed group) and 123 non-coke-oven workers (the control group), we genotyped for polymorphisms in the AhR, CYP1A1, GSTM1, and GSTT1 genes by PCR methods, and determined the levels of DNA damage in peripheral blood lymphocytes using the alkaline comet assay. It was found that the ln-transformed Olive tail moment (Olive TM) values in the exposed group were significantly higher than those in the control group. Furthermore, in the exposed group, the Olive TM values in subjects with the AhR Lys{sup 554} variant genotype were higher than those with the AhR Arg{sup 554}/Arg{sup 554} genotype. Similarly, the Olive TM values in the non-coke-oven workers with the CYP1A1 MspI CC + CT genotype were lower than the values of those with the CYP1A1 MspI TT genotype. However, these differences were not evident for GSTM1 and GSTT1. These results suggested that the polymorphism of AhR might modulate the effects of PAHs in the exposed group; however, the underlying molecular mechanisms by which this polymorphism may have affected the levels of PAH-induced DNA damage warrant further investigation.

Yongwen Chen; Yun Bai; Jing Yuan; Weihong Chen; Jianya Sun; Hong Wang; Huashan Liang; Liang Guo; Xiaobo Yang; Hao Tan; Yougong Su; Qingyi Wei; Tangchun Wu [Huazhong University of Science and Technology, Wuhan (China). Institute of Occupational Medicine and Ministry of Education Key Lab of Environment and Health

2006-09-15T23:59:59.000Z

382

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia Coal: Feedstock Flexibility Refinery Streams Gasification is a known method for converting petroleum coke (petcoke) and other refinery waste streams and residuals (vacuum residual, visbreaker tar, and deasphalter pitch) into power, steam and hydrogen for use in the production of cleaner transportation fuels. The main requirement for a gasification feedstock is that it contains both hydrogen and carbon. Below is a table that shows the specifications for a typical refinery feedstock. Specifications for a typical refinery feedstock A number of factors have increased the interest in gasification applications in petroleum refinery operations: Coking capacity has increased with the shift to heavier, more sour crude oils being supplied to the refiners.

383

Viscosity of a nucleonic fluid  

E-Print Network (OSTI)

The viscosity of nucleonic matter is studied both classically and in a quantum mechanical description. The collisions between particles are modeled as hard sphere scattering as a baseline for comparison and as scattering from an attractive square well potential. Properties associated with the unitary limit are developed which are shown to be approximately realized for a system of neutrons. The issue of near perfect fluid behavior of neutron matter is remarked on. Using some results from hard sphere molecular dynamics studies near perfect fluid behavior is discussed further.

Aram Z. Mekjian

2012-03-21T23:59:59.000Z

384

Kinetic Modeling for the Combined Pyrolysis and Steam Gasification of Petroleum Coke and Experimental Determination of the Rate Constants by Dynamic Thermogravimetry in the 500?1520 K Range  

Science Journals Connector (OSTI)

1 An important example of such hybridization is the endothermic steam gasification of petroleum coke (petcoke) to synthesis gas (syngas). ... A 2nd-Law analysis for generating electricity using the solar gasification products indicates the potential of doubling the specific electrical output and, consequently, halving the specific CO2 emissions, vis-à-vis conventional petcoke-fired power plants. ... 2 The overall chemical process can be represented by the simplified net reaction: where x and y are the elemental molar ratios of H/C and O/C in petcoke, respectively. ...

D. Trommer; A. Steinfeld

2006-03-28T23:59:59.000Z

385

Compressor bleed cooling fluid feed system  

DOE Patents (OSTI)

A compressor bleed cooling fluid feed system for a turbine engine for directing cooling fluids from a compressor to a turbine airfoil cooling system to supply cooling fluids to one or more airfoils of a rotor assembly is disclosed. The compressor bleed cooling fluid feed system may enable cooling fluids to be exhausted from a compressor exhaust plenum through a downstream compressor bleed collection chamber and into the turbine airfoil cooling system. As such, the suction created in the compressor exhaust plenum mitigates boundary layer growth along the inner surface while providing flow of cooling fluids to the turbine airfoils.

Donahoo, Eric E; Ross, Christopher W

2014-11-25T23:59:59.000Z

386

Directed flow fluid rinse trough  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs.

Kempka, Steven N. (9504 Lona La., Albuquerque, NM 87111); Walters, Robert N. (11872 LaGrange St., Boise, ID 83709)

1996-01-01T23:59:59.000Z

387

Directed flow fluid rinse trough  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs. 9 figs.

Kempka, S.N.; Walters, R.N.

1996-07-02T23:59:59.000Z

388

Working fluid for Rankine cycle  

SciTech Connect

A Rankine cycle working fluid is disclosed containing a mixture of 2,2,3,3tetrafluoropropanol and water, which is low toxic, incombustible, nonexplosive, noncorrosive and stable, and also has a high critical temperature and forms azeotropic-like composition. It is suited for use in a rankine cycle using heat source of low temperature.

Aomi, H.; Enjo, N.

1980-11-11T23:59:59.000Z

389

Inverse Fluid Convection Problems in Enclosures  

E-Print Network (OSTI)

Efficiency, security, and reliability of industrial and domestic processes essentially depend on the deep understanding of their actual processes of fluid flow and heat transfer. Actual processes of fluid flow control and ...

Zhao, Fu-Yun

2012-01-01T23:59:59.000Z

390

CRITICALITY CURVES FOR PLUTONIUM HYDRAULIC FLUID MIXTURES  

SciTech Connect

This Calculation Note performs and documents MCNP criticality calculations for plutonium (100% {sup 239}Pu) hydraulic fluid mixtures. Spherical geometry was used for these generalized criticality safety calculations and three geometries of neutron reflection are: {sm_bullet}bare, {sm_bullet}1 inch of hydraulic fluid, or {sm_bullet}12 inches of hydraulic fluid. This document shows the critical volume and critical mass for various concentrations of plutonium in hydraulic fluid. Between 1 and 2 gallons of hydraulic fluid were discovered in the bottom of HA-23S. This HA-23S hydraulic fluid was reported by engineering to be Fyrquel 220. The hydraulic fluid in GLovebox HA-23S is Fyrquel 220 which contains phosphorus. Critical spherical geometry in air is calculated with 0 in., 1 in., or 12 inches hydraulic fluid reflection.

WITTEKIND WD

2007-10-03T23:59:59.000Z

391

Engine with a solid working fluid  

Science Journals Connector (OSTI)

... fluids: the fluid may be steam, petrol vapour/air mixture or air (in the Stirling engine), but all depend on cycles involving simultaneous changes of temperature and pressure. Now ...

Robert W. Cahn

1975-05-22T23:59:59.000Z

392

Fluid sampling system for a nuclear reactor  

DOE Patents (OSTI)

A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

Lau, Louis K. (Monroeville, PA); Alper, Naum I. (Monroeville, PA)

1994-01-01T23:59:59.000Z

393

Specialized Materials and Fluids and Power Plants  

Energy.gov (U.S. Department of Energy (DOE))

Below are the project presentations and respective peer review results for Specialized Materials and Fluids and Power Plants.

394

Supercritical Fluid Attachment of Palladium Nanoparticles on...  

NLE Websites -- All DOE Office Websites (Extended Search)

Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Supercritical Fluid Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Abstract: Nanocomposite...

395

Fluid Interface Reactions, Structures and Transport  

NLE Websites -- All DOE Office Websites (Extended Search)

fluid by local bond relaxation, charge redistribution, dissolution, precipitation, sorption and porosity developmentdestruction. Heretofore, interfaces have been described...

396

2014 GRADUATE STUDIES ENVIRONMENTAL FLUID MECHANICS  

E-Print Network (OSTI)

for Civil and Environmental Engineers · Stochastic Hydrology · Water Resources Management · Fluid Mechanics2014 GRADUATE STUDIES ENVIRONMENTAL FLUID MECHANICS AND WATER RESOURCES ENGINEERING RESEARCH AREAS SELECTED COURSES FACILITIES The Environmental Fluid Mechanics and Water Resources program at the Georgia

Wang, Yuhang

397

Coking Coal Import Costs - EIA  

Gasoline and Diesel Fuel Update (EIA)

Import Costs for Selected Countries Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 48.67 46.59 49.25 78.98 108.68 126.85 120.51 163.26 NA France 52.47 60.26 62.05 75.46 109.69 133.48 124.63 212.51 NA Germany 51.30 59.53 64.00 74.74 113.48 135.72 133.45 182.72 NA Italy 55.48 57.67 60.39 77.24 103.02 112.05 118.05 118.97 NA Japan 41.13 42.14 41.73 61.40 88.80 93.10 88.43 184.13 NA Netherlands 55.37 55.55 63.00 78.99 104.06 125.70 125.84 187.06 NA Spain 52.32 57.10 60.44 79.30 116.50 134.81 124.87 211.23 NA United Kingdom 53.14 56.81 57.34 77.73 116.05 128.51 120.24 187.79 NA 1To convert U.S. dollars per metric ton to U.S. dollars per short ton

398

Quality fluctuations of coking coal  

Science Journals Connector (OSTI)

The quality fluctuations of coal from different sources is assessed, in terms of technical analysis, petrographic analysis, and plastometric data. Considerable fluctuations are seen in the moisture, ash, and s...

V. P. Lyalyuk; V. P. Sokolova; I. A. Lyakhova; D. A. Kassim

2013-01-01T23:59:59.000Z

399

Fundamental factors influencing coke strength.  

E-Print Network (OSTI)

??Research Doctorate - Doctor of Philosophy (PhD) In an ironmaking blast furnace solid-gas reactions are important and the rate of iron production is strongly dependent… (more)

Curran, Joel

2009-01-01T23:59:59.000Z

400

Fluid dynamics kill Wyoming icicle  

SciTech Connect

Control of a blowout in which a portion of the drill collar string was extending through the rotary table and into the derrick was compounded by ice building up on the derrick and substructure. However, the momentum kill procedure proved successful. Topics considered in this paper include oil wells, natural gas wells, sleeves, rotary drills, drilling rigs, fluid mechanics, occupational safety, blowouts, drill pipes, rotary drilling, ice removal, and freezing.

Grace, R.D.

1987-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Use of Clays as Drilling Fluids and Filters  

Science Journals Connector (OSTI)

In geotechnical engineering, drilling fluid is a fluid used to drill boreholes into the earth. In drilling rigs, drilling fluids help to do drill for exploration of oil and natural gas. Liquid drilling fluid is o...

Swapna Mukherjee

2013-01-01T23:59:59.000Z

402

Fluid Inclusion Analysis | Open Energy Information  

Open Energy Info (EERE)

Fluid Inclusion Analysis Fluid Inclusion Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Fluid Inclusion Analysis Details Activities (20) Areas (11) Regions (1) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Fluid composition at a point in time and space Thermal: The minimum temperature of fluid inclusion formation Cost Information Low-End Estimate (USD): 17.571,757 centUSD 0.0176 kUSD 1.757e-5 MUSD 1.757e-8 TUSD / sample Median Estimate (USD): 17.571,757 centUSD 0.0176 kUSD 1.757e-5 MUSD 1.757e-8 TUSD / sample High-End Estimate (USD): 26.782,678 centUSD

403

Hydrostatic bearings for a turbine fluid flow metering device  

DOE Patents (OSTI)

A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion. 3 figs.

Fincke, J.R.

1982-05-04T23:59:59.000Z

404

Multiple source/multiple target fluid transfer apparatus  

DOE Patents (OSTI)

A fluid transfer apparatus includes: (a) a plurality of orifices for connection with fluid sources; (b) a plurality of orifices for connection with fluid targets; (c) a set of fluid source conduits and fluid target conduits associated with the orifices; (d) a pump fluidically interposed between the source and target conduits to transfer fluid there between; (e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; (f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; (g) pump control means for controlling operation of the pump; (h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; (i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and (j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits. 6 figs.

Turner, T.D.

1997-08-26T23:59:59.000Z

405

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

Kronberg, James W. (Aiken, SC)

1995-01-01T23:59:59.000Z

406

Analysis of fluid inclusions in halite  

SciTech Connect

A technique has been developed to drill into fluid inclusions in halite, to extract the inclusions fluids, and to determine the concentration of all of the major and some of the minor constituents in these fluids. The minimum diameter of usable fluid inclusions is ca. 250 ..mu..m. After dilution, the fluids are analyzed by ion chromatography and coulometry. Uncertainties in the concentration of the major cations and anions is on the order of 4%. The analytical scheme provides much more precise analyses of inclusion fluids than have been available to date. The analyses are a useful starting point for reconstructing the composition of the sea water from which the evaporite brines evolved.

Lazar, B.; Holland, H.D.

1988-02-01T23:59:59.000Z

407

Apparatus for unloading pressurized fluid  

DOE Patents (OSTI)

An apparatus is described for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device. 2 figures.

Rehberger, K.M.

1994-01-04T23:59:59.000Z

408

System and method for filling a plurality of isolated vehicle fluid circuits through a common fluid fill port  

SciTech Connect

A vehicle having multiple isolated fluid circuits configured to be filled through a common fill port includes a first fluid circuit disposed within the vehicle, the first fluid circuit having a first fill port, a second fluid circuit disposed within the vehicle, and a conduit defining a fluid passageway between the first fluid circuit and second fluid circuit, the conduit including a valve. The valve is configured such that the first and second fluid circuits are fluidly coupled via the passageway when the valve is open, and are fluidly isolated when the valve is closed.

Sullivan, Scott C; Fansler, Douglas

2014-10-14T23:59:59.000Z

409

Studies of complexity in fluid systems  

SciTech Connect

This is the final report of Grant DE-FG02-92ER25119, ''Studies of Complexity in Fluids'', we have investigated turbulence, flow in granular materials, singularities in evolution of fluid surfaces and selective withdrawal fluid flows. We have studied numerical methods for dealing with complex phenomena, and done simulations on the formation of river networks. We have also studied contact-line deposition that occurs in a drying drop.

Nagel, Sidney R.

2000-06-12T23:59:59.000Z

410

Vibratory pumping of a free fluid stream  

DOE Patents (OSTI)

A vibratory fluid pump having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments.

Merrigan, Michael A. (Santa Cruz, NM); Woloshun, Keith A. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

411

Vibratory pumping of a free fluid stream  

DOE Patents (OSTI)

A vibratory fluid pump is described having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments. 3 figs.

Merrigan, M.A.; Woloshun, K.A.

1990-11-13T23:59:59.000Z

412

Hydrostatic bearings for a turbine fluid flow metering device  

DOE Patents (OSTI)

A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

Fincke, J.R.

1980-05-02T23:59:59.000Z

413

Heat Transfer Fluids Containing Nanoparticles | Argonne National...  

NLE Websites -- All DOE Office Websites (Extended Search)

Heat Transfer Fluids Containing Nanoparticles Technology available for licensing: A stable, nonreactive nanofluid that exhibits enhanced heat transfer properties with only a...

414

Sandia National Laboratories: Computational Fluid Dynamics Simulations...  

NLE Websites -- All DOE Office Websites (Extended Search)

Canal, Yakima Washington Sandia Publishes Five Reports on the Environmental Effects of Wave-Energy Converters Computational Fluid Dynamics Simulations Provide Insight for Rotor...

415

DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...  

Open Energy Info (EERE)

This is the fourth paper in a series on developing fluid inclusion stratigraphy (FIS) as a logging tool for geothermal bore holes. Here we address methods of displaying...

416

Fluid casting of particle-based articles  

DOE Patents (OSTI)

A method for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets or hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product.

Menchhofer, Paul (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

417

Particle-fluid heat/mass transfer: Newtonian and non-Newtonian fluids  

Science Journals Connector (OSTI)

A new model based on the boundary layer analysis is developed for particle-fluid heat/mass transfer. The proposed model enables a unified consideration ... results with data for Newtonian and non-Newtonian fluids

Y. Kawase

1992-01-01T23:59:59.000Z

418

Laser microfluidics : fluid actuation by light Laser microfluidics: fluid actuation by light  

E-Print Network (OSTI)

Laser microfluidics : fluid actuation by light Laser microfluidics: fluid actuation by light Jean.delville@cpmoh.u-bordeaux1.fr Abstract: The development of microfluidic devices is still hindered by the lack of robust to extend this concept to microfluidic two-phase flows. First, we investigate the destabilization of fluid

Paris-Sud XI, Université de

419

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS Int. J. Numer. Meth. Fluids 31: 345358 (1999)  

E-Print Network (OSTI)

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS Int. J. Numer. Meth. Fluids 31: 345­358 (1999 AND S. ROYc,3 a Engineering Science Program, MAES Department, 316A Perkins Hall, Uni6ersity of Tennessee Corporation, Burr Ridge, IL, USA SUMMARY The quest continues for accurate and efficient computational fluid

Roy, Subrata

420

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

Hazen, T.C.; Fliermans, C.B.

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater. 11 figs.

Kronberg, J.W.

1995-07-11T23:59:59.000Z

422

Foam vessel for cryogenic fluid storage  

DOE Patents (OSTI)

Cryogenic storage and separator vessels made of polyolefin foams are disclosed, as are methods of storing and separating cryogenic fluids and fluid mixtures using these vessels. In one embodiment, the polyolefin foams may be cross-linked, closed-cell polyethylene foams with a density of from about 2 pounds per cubic foot to a density of about 4 pounds per cubic foot.

Spear, Jonathan D (San Francisco, CA)

2011-07-05T23:59:59.000Z

423

It's The Fluids SEG Honorary Lecture  

E-Print Network (OSTI)

Coarse Sand w/o THF-Hydrates Coarse Sand w/ THF-Hydrates #12;Guest Molecules Gas Hydrate Crystal information please visit: #12;·WATER and BRINE (BRINE = H2O + Salt) ·HYDROCARBONS Oil Gas TYPES of PORE FLUIDS Gas Mixtures ·DRILLING MUD ·PRODUCTION FLUIDS Miscible Injectants (CO2, Enriched Gas) #12;From Ivar

424

Dense colloidal fluids form denser amorphous sediments  

E-Print Network (OSTI)

Dense colloidal fluids form denser amorphous sediments Shir R. Libera,b , Shai Borohovicha of their randomly packed solid sediments. We demonstrate that the most dilute fluids of colloidal hard spheres form loosely packed sediments, where the volume fraction of the particles approaches in frictional systems

Schofield, Andrew B.

425

Supercritical Fluid Extraction of Wood Pulps  

Science Journals Connector (OSTI)

......capillary column inlet system which was main tained...great concern in this study because (a) their relative...McNally and J.R. Wheeler. J. Chromatogr. 447...Chaplin, and N.R. Foster. J. Supercrit. Fluids...Wells, and N.R. Foster. J. Supercrit. Fluids......

A.J. Sequeira; L.T. Taylor

1992-10-01T23:59:59.000Z

426

Engineering Insights 2006 Complex Fluids Design Consortium  

E-Print Network (OSTI)

Engineering Insights 2006 Complex Fluids Design Consortium (CFDC) www.mrl.ucsb.edu/cfdc Overview;Engineering Insights 2006 Objectives -- continued · Create a world-class center for complex fluid and soft and Research Highlights Glenn Fredrickson October 18, 2006 #12;Engineering Insights 2006 What is the CFDC

California at Santa Barbara, University of

427

Definition: Isotopic Analysis- Fluid | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Isotopic Analysis- Fluid Jump to: navigation, search Dictionary.png Isotopic Analysis- Fluid Isotopes are atoms of the same element that have different numbers of neutrons. An isotopic analysis looks at a particular isotopic element(s) in a given system, while the conditions which increase/decrease the number of neutrons are well understood and measurable. Fluid isotopes are used to characterize a fluids origin, age, and/or interaction with rocks or other fluids based on unique isotopic ratios or concentrations.[1] View on Wikipedia Wikipedia Definition Isotope geochemistry is an aspect of geology based upon study of the relative and absolute concentrations of the elements and their isotopes in

428

Definition: Fluid Lab Analysis | Open Energy Information  

Open Energy Info (EERE)

Fluid Lab Analysis Fluid Lab Analysis Jump to: navigation, search Dictionary.png Fluid Lab Analysis Fluid lab analysis encompasses a broad array of techniques used for the analysis of water and gas samples. These analyses are used in a variety of disciplines to quantify the chemical components and properties of groundwater systems. In geothermal exploration and development, fluid analyses often provide a first look into the characteristics of a hydrothermal system, and are routinely used in ongoing monitoring of geothermal reservoirs.[1] View on Wikipedia Wikipedia Definition Water chemistry analyses are carried out to identify and quantify the chemical components and properties of a certain water. This include pH, major cations and anions, trace elements and isotopes. Water chemistry

429

Definition: Downhole Fluid Sampling | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Downhole Fluid Sampling Jump to: navigation, search Dictionary.png Downhole Fluid Sampling Downhole fluid sampling is done to characterize the chemical, thermal, or hydrological properties of a surface or subsurface aqueous system. Downhole fluid sampling is typically performed to monitor water quality, study recharge and flow in groundwater systems, and evaluate resource potential of geothermal reservoirs. Analysis of both the liquid and gas fractions of the reservoir fluid allows for detailed characterize the chemical, thermal, or hydrological properties of the subsurface hydrothermal system. View on Wikipedia Wikipedia Definition Ret Like Like You like this.Sign Up to see what your friends like.

430

Fluid Lab Analysis | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Fluid Lab Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Fluid Lab Analysis Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Lab Analysis Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Results can aid in the determination of fluid source regions and circulation pathways, and assist in determining the degree of mixing between different hydrothermal fluids. Thermal: Certain elements exhibit high spatial correlation with high-temperature geothermal systems; Isotopic ratios can be used to characterize and locate subsurface thermal anomalies.

431

Modelling anisotropic fluid spheres in general relativity  

E-Print Network (OSTI)

We argue that an arbitrary general relativistic anisotropic fluid sphere, (spherically symmetric but with transverse pressure not equal to radial pressure), can nevertheless be successfully modelled by suitable linear combinations of quite ordinary classical matter: an isotropic perfect fluid, a classical electromagnetic field, and a classical (minimally coupled) scalar field. While the most general decomposition is not unique, a preferred minimal decomposition can be constructed that is unique. We show how the classical energy conditions for the anisotropic fluid sphere can be related to energy conditions for the isotropic perfect fluid, electromagnetic field, and scalar field components of the model. Furthermore we show how this decomposition relates to the distribution of electric charge density and scalar charge density throughout the model that is used to mimic the anisotropic fluid sphere. Consequently, we can build physically reasonable matter models for almost any spherically symmetric spacetime.

Boonserm, Petarpa; Visser, Matt

2015-01-01T23:59:59.000Z

432

Euler's fluid equations: Optimal Control vs Optimization  

E-Print Network (OSTI)

An optimization method used in image-processing (metamorphosis) is found to imply Euler's equations for incompressible flow of an inviscid fluid, without requiring that the Lagrangian particle labels exactly follow the flow lines of the Eulerian velocity vector field. Thus, an optimal control problem and an optimization problem for incompressible ideal fluid flow both yield the \\emph {same} Euler fluid equations, although their Lagrangian parcel dynamics are \\emph{different}. This is a result of the \\emph{gauge freedom} in the definition of the fluid pressure for an incompressible flow, in combination with the symmetry of fluid dynamics under relabeling of their Lagrangian coordinates. Similar ideas are also illustrated for SO(N) rigid body motion.

Darryl D. Holm

2009-09-28T23:59:59.000Z

433

Pumping viscoelastic two-fluid media  

E-Print Network (OSTI)

Using a two-fluid model for viscoelastic polymer solutions, we study analytically fluid transport driven by a transverse, small amplitude traveling wave propagation. The pumping flow far from the waving boundary is shown to be strongly wave number and viscosity dependent, in contrast to a viscous Newtonian fluid. We find the two qualitatively different regimes: In one regime relevant to small wave numbers, the fluidic transport is almost the same as the Newtonian case, and uniform viscoelastic constitutive equations provide a good approximation. In the other regime, the pumping is substantially decreased because of the gel-like character. The boundary separating these two regimes is clarified. Our results suggest possible needs of two-fluid descriptions for the transport and locomotion in biological fluids with cilia and flagella.

Hirofumi Wada

2010-04-08T23:59:59.000Z

434

Separation of Fischer-Tropsch Wax from Catalyst Using Near-Critical Fluid Extraction: Analysis of Process  

E-Print Network (OSTI)

", can be produced from materials such as coal, natural gas, waste biomass, and petroleum coke. A great of coal and natural gas exist in many geographical regions that lack sufficient petroleum. Therefore

Kilpatrick, Peter K.

435

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION  

Open Energy Info (EERE)

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Details Activities (1) Areas (1) Regions (0) Abstract: Vein and alteration assemblages from eight Coso wells have been collected and their fluid-inclusion gases analyzed by quadrupole mass spectrometry. Four major types of alteration were sampled: 1) young calcite-hematite-pyrite veins; 2) wairakite or epidote veins and alteration that are spatially associated with deep reservoirs in the main field and eastern wells; 3) older sericite and pyrite wallrock alteration; and 4) stilbite-calcite veins that are common in cooler or marginal portions of

436

The fluid bed market: Status, trends, & outlook  

SciTech Connect

Fluidized bed combustion (FBC) technology has become a major commercial competitor for conventional solid fuel combustion systems. Since the mid-1980s, independent power producers (IPPs) and cogenerators in particular, pursuing opportunities created by PURPA, have led the way in deploying FBC boilers for electric power and cogeneration plants in the United States. Circulating FBC (CFBC) boilers became the predominant FBC choice for coal-, coke-, and coal waste-fired projects with unit capacities typically in the range of 300,000-600,000 lb/hr (35-70 MW (nominal)). Utility-type reheat units in the 115-165 MW (net) range are now in operation in the United States and Europe. A 250 MW CFBC unit is under construction for 1995 startup in France, and another is scheduled for 1998 startup in Pennsylvania. A 350 MW bubbling FBC boiler is being commissioned now in Japan. Several other CFBC projects that would employ 150-250 MW CFBC units are in various stages of planning in the United States, Puerto Rico, Europe, and Asia.

Simbeck, D.R.; Johnson, H.E.; Wilhelm, D.J. [SFA Pacific, Inc., Mountain View, CA (United States)

1994-12-31T23:59:59.000Z

437

Studying rheological behavior of nanoclay as oil well drilling fluid  

Science Journals Connector (OSTI)

Bentonite is commonly used to control the rheology and filtrate loss required for water-based drilling fluids. In this study, the effect ... modification on fluid viscosity and its dispersion in oil-wet fluids we...

M. Mohammadi; M. Kouhi; A. Sarrafi; M. Schaffie

2013-09-01T23:59:59.000Z

438

Thermal Storage and Advanced Heat Transfer Fluids (Fact Sheet)  

SciTech Connect

Fact sheet describing NREL CSP Program capabilities in the area of thermal storage and advanced heat transfer fluids: measuring thermophysical properties, measuring fluid flow and heat transfer, and simulating flow of thermal energy and fluid.

Not Available

2010-08-01T23:59:59.000Z

439

Heat Transfer in Wedge Flow of a Micropolar Fluid  

Science Journals Connector (OSTI)

The theory of fluids with microstructures was first given by Eringen ... , 1965), and they are called micropolar fluids. These fluids exhibit microrotational effects and microrotational inertia. The flow of such

V. M. Soundalgekar; H. S. Takhar

1980-01-01T23:59:59.000Z

440

The incorporation of bubbles into a computer graphics fluid simulation  

E-Print Network (OSTI)

We present methods for incorporating bubbles into a photorealistc fluid simulation. Previous methods of fluid simulation in computer graphics do not include bubbles. Our system automatically creates bubbles, which are simulated on top of the fluid...

Greenwood, Shannon Thomas

2005-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

A model of overall regulation of body fluids  

Science Journals Connector (OSTI)

A large-scale model of body fluid regulation was presented for the purpose of studying problems concerning body fluid disturbances and fluid therapy. This model, containing subsystems of circulation, respirati...

Noriaki Ikeda; Fumiaki Marumo; Masuo Shirataka…

1979-01-01T23:59:59.000Z

442

Arterial LDL Transport Incorporating Fluid Solid Interactions, Hyperthermia, and Atherosclerosis  

E-Print Network (OSTI)

of Mechanical Engineers, Fluids Engineering Division (FED, Bio-Medical Fluids Engineering 21, 8. Buckwalter, J.Fluid Solid Interactions, Hyperthermia, and Atherosclerosis by Stephen Chung Doctor of Philosophy, Graduate Program in Mechanical Engineering

Chung, Stephen

2013-01-01T23:59:59.000Z

443

Packing frustration in dense confined fluids  

E-Print Network (OSTI)

Packing frustration for confined fluids, i.e., the incompatibility between the preferred packing of the fluid particles and the packing constraints imposed by the confining surfaces, is studied for a dense hard-sphere fluid confined between planar hard surfaces at short separations. The detailed mechanism for the frustration is investigated via an analysis of the anisotropic pair distributions of the confined fluid, as obtained from integral equation theory for inhomogeneous fluids at pair correlation level within the anisotropic Percus-Yevick approximation. By examining the mean forces that arise from interparticle collisions around the periphery of each particle in the slit, we calculate the principal components of the mean force for the density profile - each component being the sum of collisional forces on a particle's hemisphere facing either surface. The variations of these components with the slit width give rise to rather intricate changes in the layer structure between the surfaces, but, as shown in this paper, the basis of these variations can be easily understood qualitatively and often also semi-quantitatively. It is found that the ordering of the fluid is in essence governed locally by the packing constraints at each single solid-fluid interface. A simple superposition of forces due to the presence of each surface gives surprisingly good estimates of the density profiles, but there remain nontrivial confinement effects that cannot be explained by superposition, most notably the magnitude of the excess adsorption of particles in the slit relative to bulk.

Kim Nygård; Sten Sarman; Roland Kjellander

2014-09-04T23:59:59.000Z

444

Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced...

445

Application of Neutron Imaging and Scattering to Fluid Flow and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS Environments Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS...

446

Development of Molten-Salt Heat Trasfer Fluid Technology for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar...

447

Fracture Network and Fluid Flow Imaging for EGS Applications...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fracture Network and Fluid Flow Imaging for EGS Applications from Multi-Dimensional Electrical Resistivity Structure Fracture Network and Fluid Flow Imaging for EGS Applications...

448

FLUID INCLUSION STRATIGRAPHY: NEW METHOD FOR GEOTHERMAL RESERVOIR...  

Open Energy Info (EERE)

RESERVOIR ASSESSMENT PRELIMINARY RESULTS Abstract Fluid Inclusion Stratigraphy (FIS) is a new technique developed for the oil industry in order to map borehole fluids....

449

Working Fluids Low Global Warming Potential Refrigerants - 2013...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Emerging Technologies...

450

FLUID GEOCHEMISTRY AT THE RAFT RIVER GEOTHERMAL FIELD, IDAHO...  

Open Energy Info (EERE)

deep structural controls on fluid pathways in the field, which has compartmentalized the fluids and limited the degree of mixing between them. Authors Ayling, B.; Molling, P.;...

451

Electric Power Generation from Coproduced Fluids from Oil and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Electric Power Generation from Coproduced Fluids from Oil and Gas Wells The primary objective of this...

452

Fluid injection and production apparatus and method  

SciTech Connect

This patent describes an apparatus for transporting fluid. It comprises: a first generally tubular assembly having a first end and a second end, the first assembly having at least one aperture therethrough; a second generally tubular assembly having a first end and a second end and being positioned within the first tubular assembly; a first means for selectively permitting fluid flow between the exterior and the interior of the second assembly; a third generally tubular assembly having a first end and a second end; and a second means for selectively permitting fluid flow between the exterior and the interior of the third assembly.

Deines, T.A.; Ellwood, D.E.

1992-07-28T23:59:59.000Z

453

Apparatus And Method For Fluid Analysis  

DOE Patents (OSTI)

The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

Wilson, Bary W. (Richland, WA); Peters, Timothy J. (Richland, WA); Shepard, Chester L. (West Richland, WA); Reeves, James H. (Richland, WA)

2003-05-13T23:59:59.000Z

454

Excitations of Bose Fluids in Nanotubes  

Science Journals Connector (OSTI)

We discuss the excitation spectra of Bose fluids in the quasi-one dimensional geometries which can be found in interstitial channels of nanotubes and inside individual nanotubes. We compute the collective excitat...

E. S. Hernández; M. W. Cole

2002-01-01T23:59:59.000Z

455

Geothermal Reservoir Evaluation Considering Fluid Adsorption  

E-Print Network (OSTI)

SGP-"R- 68 Geothermal Reservoir Evaluation Considering Fluid Adsorption and Composition Michael J. Economides September, 1983 Financial support was provided through the Stanford Geothermal Program Contract No Geothermal Program Interdisciplinary Research in Engineering and Earth Sciences STANFORD UNIVERSITY Stanford

Stanford University

456

Clay-based geothermal drilling fluids  

SciTech Connect

The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

1982-11-01T23:59:59.000Z

457

Geophysical Fluid Dynamics Laboratory Presented by  

E-Print Network (OSTI)

Dynamics Laboratory Outline: · Introduction · Software Infrastructure Projects: Completed Current consortium for climate-weather community 3 #12;Geophysical Fluid Dynamics Laboratory Software Infrastructure Projects ­ Completed: · Flexible Modeling System (FMS) · FMS Model: Hybrid programming model Memory

458

Controllable adhesion using field-activated fluids  

E-Print Network (OSTI)

We demonstrate that field-responsive magnetorheological fluids can be used for variable-strength controllable adhesion. The adhesive performance is measured experimentally in tensile tests (a.k.a. probe-tack experiments) ...

Ewoldt, Randy H.

459

Fluid Imaging of Enhanced Geothermal Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

eere.energy.gov Velocity & Resistivity Imaging Possibility & Potential Fluid Filled Fracture Network? VpVs Ratio Map 500 m below sea level Conductivity Map 500 m below sea level...

460

Modelling suspended sediment in environmental turbulent fluids  

E-Print Network (OSTI)

Modelling sediment transport in environmental turbulent fluids is a challenge. This article develops a sound model of the lateral transport of suspended sediment in environmental fluid flows such as floods and tsunamis. The model is systematically derived from a 3D turbulence model based on the Smagorinski large eddy closure. Embedding the physical dynamics into a family of problems and analysing linear dynamics of the system, centre manifold theory indicates the existence of slow manifold parametrised by macroscale variables. Computer algebra then constructs the slow manifold in terms of fluid depth, depth-averaged lateral velocities, and suspended sediment concentration. The model includes the effects of sediment erosion, advection, dispersion, and also the interactions between the sediment and turbulent fluid flow. Vertical distributions of the velocity and concentration in steady flow agree with the established experimental data. Numerical simulations of the suspended sediment under large waves show that ...

Cao, Meng

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Working Fluids Low Global Warming Potential Refrigerants  

NLE Websites -- All DOE Office Websites (Extended Search)

Working Fluids Low GWP Working Fluids Low GWP Refrigerants - CRADA Ed Vineyard Oak Ridge National Laboratory vineyardea@ornl.gov (865) 574-0576 3 April 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: - High GWP refrigerants increase CO 2 equivalent emissions for HVAC&R equipment - Low GWP alternatives may increase energy consumption, introduce safety risks, require significant modifications to equipment, and have higher costs

462

Working Fluids Low Global Warming Potential Refrigerants  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Working Fluids Low GWP Working Fluids Low GWP Refrigerants - CRADA Ed Vineyard Oak Ridge National Laboratory vineyardea@ornl.gov (865) 574-0576 3 April 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: - High GWP refrigerants increase CO 2 equivalent emissions for HVAC&R equipment - Low GWP alternatives may increase energy consumption, introduce safety risks, require significant modifications to equipment, and have higher costs

463

Parametric internal waves in a compressible fluid  

E-Print Network (OSTI)

We describe the effect of vibration on a confined volume of fluid which is density stratified due to its compressibility. We show that internal gravity-acoustic waves can be parametrically destabilized by the vibration. The resulting instability is similar to the classic Faraday instability of surface waves, albeit modified by the compressible nature of the fluid. It may be possible to observe experimentally near a gas-liquid critical point.

Kausik S. Das; Stephen W. Morris; A. Bhattacharyay

2007-10-11T23:59:59.000Z

464

Parametric internal waves in a compressible fluid  

E-Print Network (OSTI)

We describe the effect of vibration on a confined volume of fluid which is density stratified due to its compressibility. We show that internal gravity-acoustic waves can be parametrically destabilized by the vibration. The resulting instability is similar to the classic Faraday instability of surface waves, albeit modified by the compressible nature of the fluid. It may be possible to observe experimentally near a gas-liquid critical point.

Das, Kausik S; Bhattacharyay, A

2007-01-01T23:59:59.000Z

465

Nanoparticle enhanced ionic liquid heat transfer fluids  

DOE Patents (OSTI)

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

2014-08-12T23:59:59.000Z

466

Anisotropic surface tension of buckled fluid membrane  

E-Print Network (OSTI)

Solid sheets and fluid membranes exhibit buckling under lateral compression. Here, it is revealed that fluid membranes have anisotropic buckling surface tension contrary to solid sheets. Surprisingly, the surface tension perpendicular to the buckling direction shows stronger dependence than that parallel to it. Our theoretical predictions are supported by numerical simulations of a meshless membrane model. This anisotropic tension can be used to measure the membrane bending rigidity. It is also found phase synchronization occurs between multilayered buckled membranes.

Hiroshi Noguchi

2011-06-01T23:59:59.000Z

467

Fluid driven torsional dipole seismic source  

DOE Patents (OSTI)

A compressible fluid powered oscillating downhole seismic source device capable of periodically generating uncontaminated horizontally-propagated, shear waves is provided. A compressible fluid generated oscillation is created within the device which imparts an oscillation to a housing when the device is installed in a housing such as the cylinder off an existing downhole tool, thereby a torsional seismic source is established. Horizontal waves are transferred to the surrounding bore hole medium through downhole clamping.

Hardee, Harry C. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

468

Control system for fluid heated steam generator  

DOE Patents (OSTI)

A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

Boland, J.F.; Koenig, J.F.

1984-05-29T23:59:59.000Z

469

Stirling engine with air working fluid  

DOE Patents (OSTI)

A Stirling engine capable of utilizing air as a working fluid which includes a compact heat exchange module which includes heating tube units, regenerator and cooler positioned about the combustion chamber. This arrangement has the purpose and effect of allowing the construction of an efficient, high-speed, high power-density engine without the use of difficult to seal light gases as working fluids.

Corey, John A. (North Troy, NY)

1985-01-01T23:59:59.000Z

470

Viscosity of High Energy Nuclear Fluids  

E-Print Network (OSTI)

Relativistic high energy heavy ion collision cross sections have been interpreted in terms of almost ideal liquid droplets of nuclear matter. The experimental low viscosity of these nuclear fluids have been of considerable recent quantum chromodynamic interest. The viscosity is here discussed in terms of the string fragmentation models wherein the temperature dependence of the nuclear fluid viscosity obeys the Vogel-Fulcher-Tammann law.

V. Parihar; A. Widom; D. Drosdoff; Y. N. Srivastava

2007-03-15T23:59:59.000Z

471

High gliding fluid power generation system with fluid component separation and multiple condensers  

DOE Patents (OSTI)

An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

2014-10-14T23:59:59.000Z

472

Selection of fluids for tritium pumping systems  

SciTech Connect

The degradation characteristics of three types of vacuum pump fluids, polyphenyl ethers, perfluoropolyethers and hydrocarbon oils were reviewed. Fluid selection proved to be a critical factor in the long-term performance of tritium pumping systems and subsequent tritium recovery operations. Thermal degradation and tritium radiolysis of pump fluids produce contaminants which can damage equipment and interfere with tritium recovery operations. General characteristics of these fluids are as follows: polyphenyl ether has outstanding radiation resistance, is very stable under normal diffusion pump conditions, but breaks down in the presence of oxygen at anticipated operating temperatures. Perfluoropolyether fluids are very stable and do not react chemically with most gases. Thermal and mechanical degradation products are inert, but the radiolysis products are very corrosive. Most of the degradation products of hydrogen oils are volatile and the principal radiolysis product is methane. Our studies show that polyphenyl ethers and hydrocarbon oils are the preferred fluids for use in tritium pumping systems. No corrosive materials are formed and most of the degradation products can be removed with suitable filter systems.

Chastagner, P

1984-02-01T23:59:59.000Z

473

Lattice Boltzmann Methods for Fluid-Structure Interaction Problems  

E-Print Network (OSTI)

Lattice Boltzmann Methods for Fluid-Structure Interaction Problems Alfonso Caiazzo, Eric Lorenz, Firdaouss M, Lallemand P. Momentum transfer on a Boltzmann lattice fluid with Boundaries, Phys. Fluids 13, 3452-3459, 2002. [2] Caiazzo, A. Asymptotic Analysis of lattice Boltzmann Method for Fluid- Structure

474

Geophysical Fluid Dynamics Laboratory Review May 20 May 22, 2014  

E-Print Network (OSTI)

in modeling fluid dynamics and heat transfer in large facilities is being applied to the analysis of new might use 25% less fuel than a conventional vehicle. Cool Designs for Hot Spaces Computational Fluid Computational Fluid Dynamics model. (Image Right) Image showing the geometry of a typical Computational Fluid

475

New fluids help increase effectiveness of hydraulic fracturing  

SciTech Connect

It is important to choose the most effective fluid for hydraulic fracturing a particular formation. Fracturing fluids are used to initiate formation parting, extend the fracture into the reservoir, and to transport and distribute proppant. This paper discusses the fundamental of fluid types, viscosifiers, and fluid rheology.

Ebinger, C.D.; Hunt, E.

1989-06-05T23:59:59.000Z

476

Fundamentals of Engineering (FE) Exam Fluid Mechanics Review  

E-Print Network (OSTI)

one unit area layer of a substance over another � Viscosity (�): measure of a fluid's resistance Energy, Friction Loss, and Pipe Flow Momentum and Drag #12;Pressure � Gage pressure: measured relative Engineering March 22, 2013 #12;Morning (Fluid Mechanics) A. Flow measurement B. Fluid properties C. Fluid

Provancher, William

477

Boston University Department of Mechanical Engineering ME 303 Fluid Mechanics  

E-Print Network (OSTI)

Boston University Department of Mechanical Engineering ME 303 ­ Fluid Mechanics Fall 2011 Class: EK301 Engineering Mechanics Course Textbook: Fundamentals of Fluid Mechanics, 6th ed., Munson B. Reference Texts: Fluid Mechanics, Landau and Lifshitz, Vol. 6 Fluid Mechanics, Y. Cengel and J. Cimbala

478

"Nanotechnology Enabled Advanced Industrial Heat Transfer Fluids"  

SciTech Connect

ABSTRACT Nanotechnology Enabled Advanced industrial Heat Transfer Fluids” Improving the efficiency of Industrial Heat Exchangers offers a great opportunity to improve overall process efficiencies in diverse industries such as pharmaceutical, materials manufacturing and food processing. The higher efficiencies can come in part from improved heat transfer during both cooling and heating of the material being processed. Additionally, there is great interest in enhancing the performance and reducing the weight of heat exchangers used in automotives in order to increase fuel efficiency. The goal of the Phase I program was to develop nanoparticle containing heat transfer fluids (e.g., antifreeze, water, silicone and hydrocarbon-based oils) that are used in transportation and in the chemical industry for heating, cooling and recovering waste heat. Much work has been done to date at investigating the potential use of nanoparticle-enhanced thermal fluids to improve heat transfer in heat exchangers. In most cases the effect in a commercial heat transfer fluid has been marginal at best. In the Phase I work, we demonstrated that the thermal conductivity, and hence heat transfer, of a fluid containing nanoparticles can be dramatically increased when subjected to an external influence. The increase in thermal conductivity was significantly larger than what is predicted by commonly used thermal models for two-phase materials. Additionally, the surface of the nanoparticles was engineered so as to have a minimal influence on the viscosity of the fluid. As a result, a nanoparticle-laden fluid was successfully developed that can lead to enhanced heat transfer in both industrial and automotive heat exchangers

Dr. Ganesh Skandan; Dr. Amit Singhal; Mr. Kenneth Eberts; Mr. Damian Sobrevilla; Prof. Jerry Shan; Stephen Tse; Toby Rossmann

2008-06-12T23:59:59.000Z

479

Fluid samplers: sampling music keyboards having fluidly continuous action and sound, without being electrophones  

Science Journals Connector (OSTI)

Present-day sampling music keyboards are electronic instruments that fall under the last (5th) category of the Hornbostel Sachs musical instrument classification scheme. Conversely, we first propose an entirely acoustic/mechanical mellotron-like sampling ... Keywords: fluid sampling, fluid user-interfaces, hydraulophones, interactive art, tangible user interfaces, water-based immersive multimedia

Steve Mann; Ryan E. Janzen

2007-09-01T23:59:59.000Z

480

Br-Cl-Na systematics in Illinois basin fluids: Constraints on fluid origin and evolution  

SciTech Connect

The authors present here bromide, chloride, and sodium data for fluids from reservoirs of Ordovician through Pennsylvania age in the Illinois basic which suggest that remnant marine fluids contribute significantly to fluid Cl budgets. Cl/Br and NaBr ratios for Ordovician through Devonian formation fluids are relatively uniform and near those for seawater, despite greater than a factor of ten range in Cl concentration. In contrast, fluids from Mississippian and Pennsylvanian reservoirs, separated from older reservoirs by the New Albany Shale Group, have more variable fluid Cl/Br and Na/Br ratios, most of which are significantly greater then those of seawater. The 1:1 stoichiometry of Cl and Na increases for Mississippian and Pennsylvanian formation fluids is consistent with halite dissolution. Nevertheless, Br systematics and mass-balance considerations indicate that he overall Cl budget of Illinois basin formation fluids appears to be more significantly influenced by the contribution from subaerially evaporated seawater than by halite dissolution.

Walter, L.M.; Huston, T.J. (Washington Univ., St. Louis, Missouri (USA)); Stueber, A.M. (Southern Illinois Univ., Edwardsville (USA))

1990-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid coking visbreaking" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Phys. Fluids. Two spheres in a free stream of a second-order fluid  

E-Print Network (OSTI)

Phys. Fluids. Two spheres in a free stream of a second-order fluid A. M. Ardekani1 , R. H. Rangel1 , and D. D. Joseph1,2 1 Department of Mechanical and Aerospace Engineering University of California, Irvine, CA 92697 and 2 Department of Aerospace Engineering and Mechanics University of Minnesota, MN

Joseph, Daniel D.

482

Advanced binary cycles: Optimum working fluids  

SciTech Connect

A computer model (Cycle Analysis Simulation Tool, CAST) and a methodology have been developed to perform value analysis for small, low- to moderate-temperature binary geothermal power plants. The value analysis method allows for incremental changes in the levelized electricity cost (LEC) to be determined between a baseline plant and a modified plant. Thermodynamic cycle analyses and component sizing are carried out in the model followed by economic analysis which provides LEC results. The emphasis of the present work is on evaluating the effect of mixed working fluids instead of pure fluids on the LEC of a geothermal binary plant that uses a simple Organic Rankine Cycle. Four resources were studied spanning the range of 265 F to 375 F. A variety of isobutane and propane based mixtures, in addition to pure fluids, were used as working fluids. This study shows that the use of propane mixtures at a 265 F resource can reduce the LEC by 24% when compared to a base case value that utilizes commercial isobutane as its working fluid. The cost savings drop to 6% for a 375 F resource, where an isobutane mixture is favored. Supercritical cycles were found to have the lowest cost at all resources.

Gawlik, K.; Hassani, V. [National Renewable Energy Lab., Golden, CO (United States)

1997-12-31T23:59:59.000Z

483

Electrorheological fluid under elongation, compression, and shearing  

Science Journals Connector (OSTI)

Electrorheological (ER) fluid based on zeolite and silicone oil under elongation, compression, and shearing was investigated at room temperature. Dc electric fields were applied on the ER fluid when elongation and compression were carried out on a self-constructed test system. The shear yield stress, presenting the macroscopic interactions of particles in the ER fluid along the direction of shearing and perpendicular to the direction of the electric field, was also obtained by a HAAKE RV20 rheometer. The tensile yield stress, presenting the macroscopic interactions of particles in the ER fluid along the direction of the electric field, was achieved as the peak value in the elongating curve with an elongating yield strain of 0.15–0.20. A shear yield angle of about 15°–18.5° reasonably connected tensile yield stress with shear yield stress, agreeing with the shear yield angle tested well by other researchers. The compressing tests showed that the ER fluid has a high compressive modulus under a small compressive strain lower than 0.1. The compressive stress has an exponential relationship with the compressive strain when it is higher than 0.1, and it is much higher than shear yield stress.

Y. Tian; Y. Meng; H. Mao; S. Wen

2002-03-06T23:59:59.000Z

484

Ultrasonic fluid flow measurement method and apparatus  

DOE Patents (OSTI)

An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible.

Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

1993-01-01T23:59:59.000Z

485

Ultrasonic fluid flow measurement method and apparatus  

DOE Patents (OSTI)

An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible. 3 figures.

Kronberg, J.W.

1993-10-12T23:59:59.000Z

486

Fluid-bed combustion of solid wastes  

SciTech Connect

For over ten years combustion Power Company has been conducting experimental programs and developing fluid bed systems for agencies of the federal government and for private industry and institutions. Many of these activities have involved systems for the combustion of solid waste materials. Discussed here will be three categories of programs, development of Municipal Solid Waste (MSW) fired fluid beds, development of wood waste fired fluid beds, and industrial installations. Research and development work on wood wastes has led to the design and construction of two large industrial fluid bed combustors. In one of these, a fluid bed is used for the generation of steam with a fuel that was previously suited only for landfill. Rocks and inerts are continuously removed from this combustor using a patented system. The second FBC is designed to use a variety of fuels as the source of energy to dry hog fuel for use in a high performance power boiler. Here the FBC burns green hog fuel, log yard debris, fly ash (char) from the boiler, and dried wood fines to produce a hot gas system for the wood dryer. A significant advantage of the fluidized bed reactor over conventional incinerators is its ability to reduce noxious gas emission and, finally, the fluidized bed is unique in its ability to efficiently consume low quality fuels. The relatively high inerts and moisture content of solid wastes pose no serious problem and require no associated additional devices for their removal.

Vander Molen, R.H.

1980-01-01T23:59:59.000Z

487

A theoretical approach for assessing the role of rock and fluid properties in the development of abnormal fluid pressures  

E-Print Network (OSTI)

and shales. The important parameters determining the extent of fluid pressure preservation are the geothermal gradient, the thermal loading rate, and the hydraulic diffusivity, K/Ss, of the rock . The highest fluid pressure development is expected... Variation of fluid expansivity and fluid compressibility with depth for a 25C/km geothermal gradient Page 14 Pressure response in different rock types and for various boundary conditions under . constant fluid mass 25 Values of or/Bf as a function...

Hastings, Thomas Worcester

2012-06-07T23:59:59.000Z

488

High-Energy-Density Plasmas, Fluids  

NLE Websites -- All DOE Office Websites (Extended Search)

High-Energy-Density Plasmas, Fluids High-Energy-Density Plasmas, Fluids /science-innovation/_assets/images/icon-science.jpg High-Energy-Density Plasmas, Fluids National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. TRIDENT target chamber Sasi Palaniyappan, right, and Rahul Shah left inside a target chamber where the TRIDENT short pulse laser is aimed at a very thin diamond- foil target, a fraction of a micrometer thick. The laser delivers a power on target of 150 Terawatts focused into a 7 micrometer spot, yielding laser brilliance over 100 times more intense than needed to make the target electrons fully relativistic. These experiments test novel methods of producing intense

489

Thermal Fluid Multiphysics Optimization of Spherical Tokamak  

SciTech Connect

An experimental Fusion Nuclear Science Facility (FNSF) is required that will create the environment that simultaneously achieves high energy neutrons and high ion fluence necessary in order to bridge the gaps from ITER to the realization of a fusion nuclear power plant. One concept for achieving this is a high duty cycle spherical torus. This study will focus on thermal modeling of the spherical torus centerpost using computational fluid dynamics to effectively model the thermal transfer of the cooling fluid to the centerpost. The design of the fluid channels is optimized in order to minimize the temperature in the centerpost. Results indicate the feasibility of water cooling for a long-pulse spherical torus FNSF.

Lumsdaine, Arnold [ORNL; Tipton, Joseph B [ORNL; Peng, Yueng Kay Martin [ORNL

2012-01-01T23:59:59.000Z

490

Carbon-bearing fluids at nanoscale interfaces  

SciTech Connect

The behaviour of fluids at mineral surfaces or in confined geometries (pores, fractures) typically differs from their bulk behaviour in many ways due to the effects of large internal surfaces and geometrical confinement. We summarize research performed on C-O-H fluids at nanoscale interfaces in materials of interest to the earth and material sciences (e.g., silica, alumina, zeolites, clays, rocks, etc.), emphasizing those techniques that assess microstructural modification and/or dynamical behaviour such as gravimetric analysis, small-angle (SANS) neutron scattering, and nuclear magnetic resonance (NMR). Molecular dynamics (MD) simulations will be described that provide atomistic characterization of interfacial and confined fluid behaviour as well as aid in the interpretation of the neutron scattering results.

Cole, David [Ohio State University; Ok, Salim [Ohio State University, Columbus; Phan, A [Ohio State University, Columbus; Rother, Gernot [ORNL; Striolo, Alberto [Oklahoma University; Vlcek, Lukas [ORNL

2013-01-01T23:59:59.000Z

491

Detecting low levels of radionuclides in fluids  

DOE Patents (OSTI)

An apparatus and method for detecting low levels of one or more radionuclides in a fluid sample uses a substrate that includes an ion exchange resin or other sorbent material to collect the radionuclides. A collecting apparatus includes a collecting chamber that exposes the substrate to a measured amount of the fluid sample such that radionuclides in the fluid sample are collected by the ion exchange resin. A drying apparatus, which can include a drying chamber, then dries the substrate. A measuring apparatus measures emissions from radionuclides collected on the substrate. The substrate is positioned in a measuring chamber proximate to a detector, which provides a signal in response to emissions from the radionuclides. Other analysis methods can be used to detect non-radioactive analytes, which can be collected with other types of sorbent materials.

Patch, Keith D. (Lexington, MA); Morgan, Dean T. (Sudbury, MA)

2000-01-01T23:59:59.000Z

492

Convective heat transfer in the vertical channel flow of a clear fluid adjacent to a nanofluid layer: a two-fluid model  

Science Journals Connector (OSTI)

A two-fluid vertical channel flow and convective heat transfer model in which one of the two fluids is a nanofluid demonstrates that the nanofluid can modify the fluid velocity at the interface of the two fluids,...

Robert A. Van Gorder; K. V. Prasad; K. Vajravelu

2012-07-01T23:59:59.000Z

493

The Geometric Structure of Complex Fluids  

E-Print Network (OSTI)

This paper develops the theory of affine Euler-Poincar\\'e and affine Lie-Poisson reductions and applies these processes to various examples of complex fluids, including Yang-Mills and Hall magnetohydrodynamics for fluids and superfluids, spin glasses, microfluids, and liquid crystals. As a consequence of the Lagrangian approach, the variational formulation of the equations is determined. On the Hamiltonian side, the associated Poisson brackets are obtained by reduction of a canonical cotangent bundle. A Kelvin-Noether circulation theorem is presented and is applied to these examples.

François Gay-Balmaz; Tudor S. Ratiu

2009-03-25T23:59:59.000Z

494

Geomechanical Simulation of Fluid-Driven Fractures  

SciTech Connect

The project supported graduate students working on experimental and numerical modeling of rock fracture, with the following objectives: (a) perform laboratory testing of fluid-saturated rock; (b) develop predictive models for simulation of fracture; and (c) establish educational frameworks for geologic sequestration issues related to rock fracture. These objectives were achieved through (i) using a novel apparatus to produce faulting in a fluid-saturated rock; (ii) modeling fracture with a boundary element method; and (iii) developing curricula for training geoengineers in experimental mechanics, numerical modeling of fracture, and poroelasticity.

Makhnenko, R.; Nikolskiy, D.; Mogilevskaya, S.; Labuz, J.

2012-11-30T23:59:59.000Z

495

Homothetic perfect fluid space-times  

E-Print Network (OSTI)

A brief summary of results on homotheties in General Relativity is given, including general information about space-times admitting an r-parameter group of homothetic transformations for r>2, as well as some specific results on perfect fluids. Attention is then focussed on inhomogeneous models, in particular on those with a homothetic group $H_4$ (acting multiply transitively) and $H_3$. A classification of all possible Lie algebra structures along with (local) coordinate expressions for the metric and homothetic vectors is then provided (irrespectively of the matter content), and some new perfect fluid solutions are given and briefly discussed.

J. Carot; A. M. Sintes

1996-07-24T23:59:59.000Z

496

Vibration of Nanoparticles in Viscous Fluids  

Science Journals Connector (OSTI)

In this article, we present results of a rigorous finite-element analysis and commensurate scaling theory that enable interpretation and analysis of these experiments, for the extensional vibrational modes of axisymmetric nanoparticles immersed in viscous fluids. ... (51) Vibration of the particle accelerates the fluid, which increases the effective mass of the vibrating particle. ... Using low-frequency Raman scattering, the authors clearly demonstrate that single-domain NCs vibrate differently than their multiply twinned counterparts, through the splitting of the quadrupolar vibrations, which is only obsd. ...

Debadi Chakraborty; Emma van Leeuwen; Matthew Pelton; John E. Sader

2013-03-21T23:59:59.000Z

497

Friction-Induced Fluid Heating in Nanoscale Helium Flows  

SciTech Connect

We investigate the mechanism of friction-induced fluid heating in nanoconfinements. Molecular dynamics simulations are used to study the temperature variations of liquid helium in nanoscale Poiseuille flows. It is found that the fluid heating is dominated by different sources of friction as the external driving force is changed. For small external force, the fluid heating is mainly caused by the internal viscous friction in the fluid. When the external force is large and causes fluid slip at the surfaces of channel walls, the friction at the fluid-solid interface dominates over the internal friction in the fluid and is the major contribution to fluid heating. An asymmetric temperature gradient in the fluid is developed in the case of nonidentical walls and the general temperature gradient may change sign as the dominant heating factor changes from internal to interfacial friction with increasing external force.

Li Zhigang [Department of Mechanical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

2010-05-21T23:59:59.000Z

498

Method and apparatus for chemically altering fluids in continuous flow  

DOE Patents (OSTI)

The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation.

Heath, William O. (Richland, WA); Virden, Jr., Judson W. (Richland, WA); Richardson, R. L. (West Richland, WA); Bergsman, Theresa M. (Richland, WA)

1993-01-01T23:59:59.000Z

499

Method and apparatus for chemically altering fluids in continuous flow  

DOE Patents (OSTI)

The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation. 4 figures.

Heath, W.O.; Virden, J.W. Jr.; Richardson, R.L.; Bergsman, T.M.

1993-10-19T23:59:59.000Z

500

Accounting for Remaining Injected Fracturing Fluid  

E-Print Network (OSTI)

The technology of multi-stage fracturing of horizontal wells made the development of shale gas reservoirs become greatly successful during the past decades. A large amount of fracturing fluid, usually from 53,000 bbls to 81,400 bbls, is injected...

Zhang, Yannan

2013-12-06T23:59:59.000Z