Powered by Deep Web Technologies
Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Year/PAD District Cokers Catalytic Crackers Hydrocrackers Capacity  

U.S. Energy Information Administration (EIA) Indexed Site

Cokers Catalytic Crackers Hydrocrackers Capacity Inputs Capacity Inputs Capacity Inputs Table 8. Capacity and Fresh Feed Input to Selected Downstream Units at U.S. Refineries, 2011 - 2013 (Barrels per Calendar Day) Reformers Capacity Inputs 2011 2,396,787 5,794,214 1,687,745 2,093,849 4,952,455 1,466,627 2,570,970 3,346,457 93,700 673,300 41,500 37,932 490,729 18,030 PADD I 188,389 266,950 373,897 1,176,972 254,000 350,063 1,017,616 223,751 PADD II 664,852 812,244 1,318,440 2,933,842 841,285 1,183,318 2,570,348 744,638 PADD III 1,243,427 1,629,967 80,350 185,800 28,200 63,362 158,192 18,214 PADD IV 96,649 120,190 530,400 824,300 522,760 459,175 715,570 461,995 PADD V 377,652 517,106 2012 2,499,293 5,611,191 1,706,540 2,173,336 4,901,284 1,528,708 2,614,571 3,246,874 74,900 489,300 20,000

2

Fluid catalytic cracking of heavy petroleum fractions  

SciTech Connect

A process is claimed for fluid catalytic cracking of residuum and other heavy oils comprising of gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment. The heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low btu gas stream comprising of sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1100/sup 0/F. To about 2200/sup 0/F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.

McHenry, K.W.

1981-06-30T23:59:59.000Z

3

Energy Recovery System for Fluid Catalytic Cracking Units  

E-Print Network (OSTI)

This paper describes the power and heat recovery processes and equipment for modern fluid catalytic cracking (FCC) units made possible by improvements in catalyst fines removal technology and the availability of erosion resistant high temperature...

Wen, H.; Lou, S. C.

1982-01-01T23:59:59.000Z

4

Improved high efficiency third stage separator cyclones for separation of fines from fluid catalytic cracking flue gas  

SciTech Connect

Stairmand type small diameter (0.254 m) multicyclones were cold flow tested for fluid catalytic cracking third stage separator application. The gas discharge from the cyclone dust outlet into the common collection hopper was found to far exceed the hopper bleed rate (underflow). The excess gas reentrained dust from the hopper back into cyclones, which lowered collection efficiencies. Vortex {open_quotes}stabilization{close_quotes} using apex cones was unsuccessful whereas a Mobil proprietary cyclone modification was successful in minimizing excess gas discharge and dust reentrainment at the cyclone-hopper boundary. In tests at 700 {degrees}C, the modified cyclones captured all particles above 4 {mu}m. Mobil-Kellogg incorporated the modified cyclones in a new third stage separator design which is targeted for achieving lowest opacity and <50 mg/Nm{sup 3} emissions at the stack. The first such unit will be commercialized in Mobil`s newest catalytic cracker (M.W. Kellogg design) under construction in Altona, Australia in late 1996. 5 refs., 4 figs., 2 tabs.

Chitnis, G.K.; Schatz, K.W. [Mobil Technology Co., Paulsboro, NJ (United States); Bussey, B.K. [M.W. Kellogg Co., Houston, TX (United States)

1996-12-31T23:59:59.000Z

5

Steam Cracker Furnace Energy Improvements  

E-Print Network (OSTI)

Channel, ~ 25 mi. east of Houston ? Includes 4 manufacturing sites, 2 technology/engineering offices ?Significant community involvement Baytown Refinery Page 4 Steam Cracking to Olefins ? Process 60+ years old; ExxonMobil one of pioneers... Steam Cracker Furnace Energy Improvements Tim Gandler Energy Coordinator Baytown Olefins Plant, Baytown Tx 2010 Industrial Energy Technology Conference May, 2010 Page 2 ? Baytown Complex ? Steam Cracking to Olefins ? Furnace overview...

Gandler, T.

6

Educating Consumers: New Content on Diesel Vehicles, Diesel Exhaust Fluid, and Selective Catalytic Reduction Technologies on the AFDC  

Energy.gov (U.S. Department of Energy (DOE))

Showcases new content added to the AFDC including: Diesel Vehicles, Diesel Exhaust Fluid, Selective Catalytic Reduction Technologies, and an upcoming Deisel Exhaust Fluid Locator.

7

Reaction kinetics of olefin saturation in the hydrodesulfurization of fluid catalytic cracked naphtha  

E-Print Network (OSTI)

U.S. governmental agencies are calling for strict environmental regulations on the quality of gasoline. Fluid catalytic cracked naphtha is an important blending component of the gasoline pool. The majority of the sulfur in the gasoline pool comes...

Schumann, Brian Herbert

2012-06-07T23:59:59.000Z

8

Hydrodesulfurization of Fluid Catalytic Cracking Decant Oils for the Production of Low-sulfur Needle Coke Feedstocks.  

E-Print Network (OSTI)

??Needle coke, produced by the delayed coking of fluid catalytic cracking decant oils, is the primary filler used in the production of graphite electrodes. The… (more)

Wincek, Ronald

2013-01-01T23:59:59.000Z

9

Investigation of Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal-biomass Catalytic Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics Background The U.S. Department of Energy (DOE) supports research and development efforts targeted to improve efficiency and reduce the negative environmental effects of the use of fossil fuels. One way to achieve these goals is to combine coal with biomass to create synthesis gas (syngas) for use in turbines and refineries to produce energy, fuels,

10

Spectroscopic studies on the formation of coke on individual Fluid Catalytic Cracking particles: the effect of poisoning metal compounds.  

E-Print Network (OSTI)

??The formation of coke on individual Fluid Catalytic Cracking (FCC) catalyst particles was studied using UV/Vis microspectroscopy and confocal fluorescence microscopy, with n-hexane cracking as… (more)

Goetze, J.G.

2013-01-01T23:59:59.000Z

11

Methods applied to investigate the major VCE that occured in the TOTAL refinery's Fluid Catalytic Cracking Unit at La Mede,  

E-Print Network (OSTI)

95-35 Methods applied to investigate the major Ć?VCE that occured in the TOTAL refinery's Fluid.V.C.E, occured in the Gas Plant of the TOTAL refinery's Fluid Catalytic Cracking Ć¼nit at La Mede, France sources: control room hard copy and electronically stored records: no deviation of process operating

Paris-Sud XI, UniversitƩ de

12

Modeling an EDC Cracker using Computational Fluid Dynamics (CFD).  

E-Print Network (OSTI)

?? The process used by the Norwegian company Hydro for making Vinyl Chloride Monomer (VCM) from natural gas and sodium chloride has been studied. A… (more)

Kaggerud, Torbjųrn Herder

2007-01-01T23:59:59.000Z

13

Fluid catalytic cracking feed hydrotreatment and its severity impact on product yields and quality  

Science Journals Connector (OSTI)

This paper investigates the effect of fluid catalytic cracking (FCC) feed hydrotreatment and its severity increase on product yields and quality obtained in a commercial and a laboratory MAT FCC units. The hydrotreatment of Ural heavy vacuum gas oil reduces not only sulfur, nitrogen, Conradson carbon and metals content in the FCC feed but also increases the mononuclear aromatic hydrocarbons content by 8% absolute at almost no change in the total aromatics content. Regardless of this 8% increase of the mononuclear aromatics in the hydrotreated FCC feed the conversion increase in both commercial and laboratory MAT units was only 2%. The severity increase in the FCC feed hydrotreater leads to a higher conversion in the FCC, higher hydrogen transfer rate that results in higher isobutane/butylenes ratio, lower gasoline olefins content, and higher gasoline motor octane number. The hydrotreatment of the Ural heavy vacuum gas oil exhibited the same changes in FCC catalyst selectivities: lower coke and LCO selectivities and higher gasoline selectivity in both commercial riser FCC unit that has between 2 and 3 s time on stream, and the fixed bed reactor MAT unit, that has 30 s time on stream.

Dicho S. Stratiev; Ivelina K. Shishkova; Dimitar S. Dobrev

2012-01-01T23:59:59.000Z

14

Design of a turbomachine set for a fluid catalytic cracking plant and its shop-testing under full-load conditions  

SciTech Connect

In fluid catalytic cracking plants, heavy hydrocarbons are converted into low-boiling point products. Starting from a concise description of the energy recovery system, this paper details the design features of a turbo machine set for an FCC plant, with the emphasis on the design of the four-stage 12,000 kW process gas expander. 6 refs.

Turanskyj, L.; Woelk, G.U.

1982-04-01T23:59:59.000Z

15

Have You Ever Seen a Cat Cracker in Person? | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Have You Ever Seen a Cat Cracker in Person? Have You Ever Seen a Cat Cracker in Person? Have You Ever Seen a Cat Cracker in Person? June 8, 2011 - 2:47pm Addthis Ginny Simmons Ginny Simmons Former Managing Editor for Energy.gov, Office of Public Affairs Want a surefire bet to be hipper at the Department of Energy? Well, I have no idea. But I do know how to have a bit more fun: learn the energy slang. Folks in the energy sector have some great nicknames for the energy infrastructure and processes they use every day. Here are a few: Wheeling Electricity "wheeling" is when electricity is moved through a local grid for use in another area. Christmas Tree A Christmas tree is a set of valves, pipes, and fittings used to control the flow of oil and gas as it leaves a well and enters a pipeline. Doghouse

16

Optimization of the Decoking Procedure of an Ethane Cracker with a Steam/Air Mixture  

Science Journals Connector (OSTI)

On the basis of the results of this study, the air and steam flow to the reactor tubes during the decoking procedure are adapted to propose an optimized decoking procedure that allows reducing the required decoking time of an industrial ethane cracking furnace by a factor of 3. In the new decoking conditions for the ethane cracker, the air flow rate is raised by a factor of 3, while the steam dilution is lowered by a factor of 4.5. ... Heterogeneities, e.g., cracked coke due to the difference in the thermal expansion coefficient of the coke and reactor tube material, and their influence on the decoking kinetics, e.g., fast ignition resulting in local hot spots, are not taken into account in the simulations. ... Based on our results, this paper aims to provide a closer insight into the coking problem in industrial steam crackers. ...

G. J. Heynderickx; E. M. Schools; G. B. Marin

2006-10-03T23:59:59.000Z

17

Different process schemes for converting light straight run and fluid catalytic cracking naphthas in a FCC unit for maximum propylene production  

Science Journals Connector (OSTI)

Light straight run (LSR) and fluid catalytic cracking (FCCN) naphthas were cracked in a transported bed reactor (MicroDowner) and in a fixed bed reactor (MAT) over a commercial Y zeolite based catalyst, over a commercial ZSM-5 zeolite based additive, and over a mixture of both at selected conditions. Based on the mechanisms through which naphtha hydrocarbons are converted, we evaluated the best alternatives for processing these streams to produce light olefins and/or to reduce olefins content in commercial gasoline. The experimental set-up allowed us to simulate the cracking behaviour of the different naphtha streams in a fluid catalytic cracking (FCC) unit by different processing schemes. Results indicate that LSR only cracks at high severity, yielding large amounts of dry gas. Despite its high olefins content, FCCN practically does not crack when it is fed together with gas oil feed. When cracking FCCN alone at typical gas oil cracking conditions, olefins are transformed preferentially into naphtha-range isoparaffins and aromatics, and when cracking FCCN at high severity, olefins are transformed preferentially into propylene and butylenes. Finally, cracking naphtha in the stripper produces some propylene and increases the aromatics in the remaining gasoline.

Avelino Corma; FranciscoV Melo; Laurent Sauvanaud; F.J Ortega

2004-01-01T23:59:59.000Z

18

Catalytic reactor  

DOE Patents (OSTI)

A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

Aaron, Timothy Mark (East Amherst, NY); Shah, Minish Mahendra (East Amherst, NY); Jibb, Richard John (Amherst, NY)

2009-03-10T23:59:59.000Z

19

Method and apparatus for a catalytic firebox reactor  

DOE Patents (OSTI)

A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

Smith, Lance L. (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Ulkarim, Hasan (Hamden, CT); Castaldi, Marco J. (Bridgeport, CT); Pfefferle, William C. (Madison, CT)

2001-01-01T23:59:59.000Z

20

Evaluation of absorption/stripping for second phase expansion of KG gas cracker  

SciTech Connect

This report addresses technology evaluation for a second phase expansion of BP Chemical Ltd.`s (BPCL) KG cracker. Its primary objective was to determine if the absorption/stripping technology being developed by BPCL is competitive with cryogenic demethanization technology. The expansion basis for this evaluation is a 150,000 MTA ethylene increment. This increment represents an increase in KG`s capacity from 450,000 MTA after the current expansion to an ultimate capacity of 600,000 MTA. Two recovery systems for a 150,000 MTA expansion are compared: (1) Case A - Absorption/Stripping Expansion; and (2) Case B - ARS Expansion. Another objective of this report was to confirm the magnitude of the economic advantages of the absorption/stripping technology for grass roots applications. For that evaluation, absorption/stripping was compared with the original 350,000 MTA KG recovery system. The two additional 350,000 MTA grass roots cases evaluated are: (1) Case C - Absorption/Stripping - Grass Roots Design; (2) Case D - Conventional Cryogenic Recovery (Original KG 350,000 MTA design).

NONE

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

ZSM-5- and MgAl2O4-Based Bifunctional Additives for Enhancing the Production of Propene and Removal of SO2 in the Fluid Catalytic Cracking (FCC) Process  

Science Journals Connector (OSTI)

ZSM-5- and MgAl2O4-Based Bifunctional Additives for Enhancing the Production of Propene and Removal of SO2 in the Fluid Catalytic Cracking (FCC) Process† ... The effects of adding the bifunctional additives containing MgAl2O4 and the commercial propene additive ZSM-5/kaolin to the base catalyst in cracking of vacuum gas oil (VGO) were investigated. ... Those additives adsorb SOx and then transfer sulfur back into the riser, where it is released as H2S, which is removed in the usual way (Claus process). ...

Xiaoling Xu; Xiaoli Ran; Qiukai Cui; Chunyi Li; Honghong Shan

2010-01-26T23:59:59.000Z

22

Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology  

SciTech Connect

The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

Swanson, Michael; Henderson, Ann

2012-04-01T23:59:59.000Z

23

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

Ergun, Sabri

2013-01-01T23:59:59.000Z

24

Catalytic Coherence  

Science Journals Connector (OSTI)

Because of conservation of energy we cannot directly turn a quantum system with a definite energy into a superposition of different energies. However, if we have access to an additional resource in terms of a system with a high degree of coherence, as for standard models of laser light, we can overcome this limitation. The question is to what extent coherence gets degraded when utilized. Here it is shown that coherence can be turned into a catalyst, meaning that we can use it repeatedly without ever diminishing its power to enable coherent operations. This finding stands in contrast to the degradation of other quantum resources and has direct consequences for quantum thermodynamics, as it shows that latent energy that may be locked into superpositions of energy eigenstates can be released catalytically.

Johan Åberg

2014-10-07T23:59:59.000Z

25

CATALYTIC LIQUEFACTION OF BIOMASS  

E-Print Network (OSTI)

liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

Seth, Manu

2012-01-01T23:59:59.000Z

26

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

Ergun, Sabri

2013-01-01T23:59:59.000Z

27

Fluid Catalytic Cracking Power Recovery Computer Simulation  

E-Print Network (OSTI)

re covery available in new plants results in the air string being almost self sustaining, 8S far as direct input power. With some processes, it is possible to produce excess power on the order of 1,000 to 9,000 HP. Waste heat recovery in the form...

Samurin, N. A.

1979-01-01T23:59:59.000Z

28

Rich catalytic injection  

DOE Patents (OSTI)

A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

Veninger, Albert (Coventry, CT)

2008-12-30T23:59:59.000Z

29

Cumene by catalytic distillation  

SciTech Connect

Catalytic distillation, a combination of catalytic reaction and distillation in a single column, has several advantages when used in a process to make cumene from benzene and propylene. An extremely high purity cumene is obtained in high yield. The catalytic distillation principle was used in an earlier process to make MTBE. A unit, started up up in Houston refinery in 1981, operated successfully for four years. Since then, three other MTBE units of this design have gone into service.

Shoemaker, J.D.; Jones, E.M. Jr.

1987-06-01T23:59:59.000Z

30

Catalytic distillation structure  

SciTech Connect

Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

Smith, Jr., Lawrence A. (Bellaire, TX)

1984-01-01T23:59:59.000Z

31

Sequential tasks performed by catalytic pumps for colloidal crystallization  

E-Print Network (OSTI)

Gold-platinum catalytic pumps immersed in a chemical fuel are used to manipulate silica colloids. The manipulation relies on the electric field and the fluid flow generated by the pump. Catalytic pumps perform various tasks, such as the repulsion of colloids, the attraction of colloids, and the guided crystallization of colloids. We demonstrate that catalytic pumps can execute these tasks sequentially over time. Switching from one task to the next is related to the local change of the proton concentration, which modifies the colloid zeta potential and consequently the electric force acting on the colloids.

Ali Afshar Farniya; Maria J. Esplandiu; Adrian Bachtold

2014-10-20T23:59:59.000Z

32

Catalytic steam reforming of hydrocarbons  

SciTech Connect

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

33

Catalytic distillation process  

DOE Patents (OSTI)

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, L.A. Jr.

1982-06-22T23:59:59.000Z

34

Catalytic distillation process  

DOE Patents (OSTI)

A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, Jr., Lawrence A. (Bellaire, TX)

1982-01-01T23:59:59.000Z

35

Catalytic Combustion Processes  

Science Journals Connector (OSTI)

This work presents experimental data on the effect of catalytic additives on the combustion characteristics of ammonium nitrate and perchlorate and the explosives of different classes. Burning rates are determ...

A. P. Glaskova

1991-01-01T23:59:59.000Z

36

Catalytic distillation structure  

DOE Patents (OSTI)

Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

Smith, L.A. Jr.

1984-04-17T23:59:59.000Z

37

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

38

Catalytic Reforming Downstream Processing of Fresh Feed Input  

U.S. Energy Information Administration (EIA) Indexed Site

Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 2,563 2,667 2,739 2,807 2,705 2,609 2010-2013 PADD 1 176 178 180 173 156 167 2010-2013 East Coast 166 164 163 161 140 153 2010-2013 Appalachian No. 1 9 14 16 12 15 14 2010-2013 PADD 2 642 638 668 695 677 615 2010-2013 Ind., Ill. and Ky. 426 411 426 460 450 399 2010-2013 Minn., Wis., N. Dak., S. Dak. 67 62 70 72 72 57 2010-2013 Okla., Kans., Mo.

39

Catalytic nanoporous membranes  

DOE Patents (OSTI)

A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

2013-08-27T23:59:59.000Z

40

Catalytic Solutions Inc CSI | Open Energy Information  

Open Energy Info (EERE)

Developer of the breakthrough catalytic coating technology and the Mixed Phase Catalyst (MPCTM), and also manufacturer of catalytic converters. References: Catalytic...

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

42

CSD: Research: Catalytic Science  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Science Catalytic Science The DOE Chemical Energy program supports basic research in the area of chemical transformations or conversions which are fundamental to new or existing concepts of energy production and storage. A further goal of the program is to identify and develop environmentally benign approaches to the synthesis of chemicals via routes requiring a minimal consumption of energy. These objectives lead naturally to an emphasis on catalysis. Novel homogeneous and heterogeneous catalysts are constantly being sought to enable the synthesis of desired products from nontraditional reactants, often with the aim of minimizing the production of toxic intermediates or byproducts, or to enable the more efficient production of products via existing reaction pathways. To this end, efforts are undertaken to

43

Catalytic reactor for low-Btu fuels  

DOE Patents (OSTI)

An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

2009-04-21T23:59:59.000Z

44

Catalytic distillation : design and application of a catalytic distillation column.  

E-Print Network (OSTI)

??Catalytic Distillation (CD) is a hybrid technology that utilizes the dynamics of si- multaneous reaction and separation in a single process unit to achieve a… (more)

Nieuwoudt, Josias Jakobus (Jako)

2005-01-01T23:59:59.000Z

45

Cumene by Catalytic Distillation  

SciTech Connect

The novel concept of Catalytic Distillation has been commercialized in the CRandL MTBE process, in which combined reaction and distillation provide energy savings over conventional processes. This concept has now been extended to production of cumene from benzene and propylene. In this case the advantages of the technique are not only energy savings but significant reductions in by-product losses and capital requirements. In this paper the development of the process is discussed and the economics of commercial operation are presented.

Jones, E.M.; Mawer, J.

1986-01-01T23:59:59.000Z

46

Novel Catalytic Membrane Reactors  

SciTech Connect

There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

Stuart Nemser, PhD

2010-10-01T23:59:59.000Z

47

5, 35333559, 2005 Catalytic conversion  

E-Print Network (OSTI)

measurement technique, employing selective gas- phase catalytic conversion of methanol to formaldehyde it the second most abundant organic trace gas after methane. Methanol can play an important role in upper tropoACPD 5, 3533Ā­3559, 2005 Catalytic conversion of methanol to formaldehyde S. J. Solomon et al. Title

Paris-Sud XI, UniversitƩ de

48

Catalytic steam gasification of coals  

Science Journals Connector (OSTI)

Catalytic steam gasification of coals ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ...

P. Pereira; G. A. Somorjai; H. Heinemann

1992-07-01T23:59:59.000Z

49

The catalytic oxidation of propane  

E-Print Network (OSTI)

THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

Sanderson, Charles Frederick

2013-10-04T23:59:59.000Z

50

Energy Conservation Revamps in Fluid Catalytic Cracking Systems  

E-Print Network (OSTI)

and product recovery through revamping. Older FCCU designs did not take full advantage of the heat available in the main fractionator. These older designs typically reject large amounts of heat to air or water cooling while using steam to reboil towers...

Wilson, J. W.; Sloan, H. D.

1984-01-01T23:59:59.000Z

51

Catalytic distillation extends its reach  

SciTech Connect

Since the early 1980s, catalytic distillation processes have been selected by more than a hundred operators for various applications. Since such a unit performs both reaction and distillation simultaneously, a combined column can replace a separate, fixed-bed reactor and distillation column, thereby eliminating equipment and reducing capital costs. And, compared to the conventional approach, catalytic distillation may also improve other factors, such as reactant conversion, selectivity, mass transfer, operating pressure, oligomer formation and catalyst fouling. The constant washing of the catalyst by liquid flowing down the column and the distillation of high-boiling foulants results in extended catalyst life. Four selective hydrogenation applications of catalytic distillation are discussed: Butadiene selective hydrogenation combined within an MTBE unit; Pentadiene selective hydrogenation; C{sub 4} acetylene conversion; and Benzene saturation.

Rock, K.; McGuirk, T. [Catalytic Distillation Technologies, Houston, TX (United States); Gildert, G.R. [Catalytic Distillation Technologies, Pasadena, TX (United States)

1997-07-01T23:59:59.000Z

52

Fluid Volumes: The Program “FLUIDS”  

Science Journals Connector (OSTI)

This chapter describes the program FLUIDS. The mathematical model underlying this program contains over 200 variables and describes control mechanisms of body fluid volumes and electrolytes as well as respirat...

Fredericus B. M. Min

1993-01-01T23:59:59.000Z

53

Understanding ammonia selective catalytic reduction kinetics...  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation,...

54

Introduction Fluid/Jeans  

E-Print Network (OSTI)

Introduction Fluid/DMSC Fluid/Jeans Comments Fluid/Kinetic Hybrid Modeling of the Thermosphere;Introduction Fluid/DMSC Fluid/Jeans Comments Outline 1 Fluid/DMSC 2 Fluid/Jeans 3 Comments Justin Erwin Fluid/Kinetic Hybrid Modeling of the Thermosphere of Pluto #12;Introduction Fluid/DMSC Fluid/Jeans Comments Motivation

Johnson, Robert E.

55

Catalytic Device International LLC | Open Energy Information  

Open Energy Info (EERE)

Catalytic Device International LLC Catalytic Device International LLC Jump to: navigation, search Name Catalytic Device International LLC Place Pleasanton, California Product California-based, firm focused on portable, heat-on-demand products. References Catalytic Device International LLC[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Catalytic Device International LLC is a company located in Pleasanton, California . References ā†‘ "Catalytic Device International LLC" Retrieved from "http://en.openei.org/w/index.php?title=Catalytic_Device_International_LLC&oldid=343285" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages

56

Fluid inflation  

SciTech Connect

In this work we present an inflationary mechanism based on fluid dynamics. Starting with the action for a single barotropic perfect fluid, we outline the procedure to calculate the power spectrum and the bispectrum of the curvature perturbation. It is shown that a perfect barotropic fluid naturally gives rise to a non-attractor inflationary universe in which the curvature perturbation is not frozen on super-horizon scales. We show that a scale-invariant power spectrum can be obtained with the local non-Gaussianity parameter f{sub NL} = 5/2.

Chen, X. [Centre for Theoretical Cosmology, DAMTP, University of Cambridge, Cambridge CB3 0WA (United Kingdom); Firouzjahi, H. [School of Astronomy, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531, Tehran (Iran, Islamic Republic of); Namjoo, M.H. [School of Physics, Institute for Research in Fundamental Sciences (IPM), P.O. Box 19395-5531, Tehran (Iran, Islamic Republic of); Sasaki, M., E-mail: x.chen@damtp.cam.ac.uk, E-mail: firouz@ipm.ir, E-mail: mh.namjoo@ipm.ir, E-mail: misao@yukawa.kyoto-u.ac.jp [Yukawa Institute for theoretical Physics, Kyoto University, Kyoto 606-8502 (Japan)

2013-09-01T23:59:59.000Z

57

Fluid Bed Combustion Applied to Industrial Waste  

E-Print Network (OSTI)

of its relatively recent application to coal fired steam production, fluid beds have been uti lized in industry for over 60 years. Beginning in Germany in the twenties for coal gasification, the technology was applied to catalytic cracking of heavy... system cost), use of minimum excess air required, and maintaining the min"imum reactor temperature neces sary to sustain combustion. For superautogenous fuels, where incineration. only is desired, minimum capital cost is achieved by using direct bed...

Mullen, J. F.; Sneyd, R. J.

58

Bifunctional Catalysts for the Selective Catalytic Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems...

59

Synthesis, Characterization, and Catalytic Function of Novel...  

NLE Websites -- All DOE Office Websites (Extended Search)

Function of Novel Highly Dispersed Tungsten Oxide Catalysts on Mesoporous Silica . Synthesis, Characterization, and Catalytic Function of Novel Highly Dispersed Tungsten Oxide...

60

Utilization of char from biomass gasification in catalytic applications  

E-Print Network (OSTI)

Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Submitted Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Utilization takes place during catalytic decomposition. This thesis focuses on the utilization of char as a catalyst

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

62

Measurement of diesel solid nanoparticle emissions using a catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic...

63

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products...

64

Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels This fact sheet provides an overview of the...

65

Catalytic Hydrothermal Gasification of Biomass  

SciTech Connect

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

66

Catalytic converter with thermoelectric generator  

SciTech Connect

The unique design of an electrically heated catalyst (EHC) and the inclusion of an ECO valve in the exhaust of an internal combustion engine will meet the strict new emission requirements, especially at vehicle cold start, adopted by several states in this country as well as in Europe and Japan. The catalytic converter (CC) has been a most useful tool in pollution abatement for the automobile. But the emission requirements are becoming more stringent and, along with other improvements, the CC must be improved to meet these new standards. Coupled with the ECO valve, the EHC can meet these new emission limits. In an internal combustion engine vehicle (ICEV), approximately 80% of the energy consumed leaves the vehicle as waste heat: out the tail pipe, through the radiator, or convected/radiated off the engine. Included with the waste heat out the tail pipe are the products of combustion which must meet strict emission requirements. The design of a new CC is presented here. This is an automobile CC that has the capability of producing electrical power and reducing the quantity of emissions at vehicle cold start, the Thermoelectric Catalytic Power Generator. The CC utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. Thus an electrically heated catalyst (EHC) will be used to augment the abatement of tail pipe emissions. Included with the EHC in the exhaust stream of the automobile is the ECO valve. This valve restricts the flow of pollutants out the tail pipe of the vehicle for a specified amount of time until the EHC comes up to operating temperature. Then the ECO valve opens and allows the full exhaust, now treated by the EHC, to leave the vehicle.

Parise, R.J.

1998-07-01T23:59:59.000Z

67

Lattice Boltzmann simulation of catalytic reactions  

Science Journals Connector (OSTI)

A lattice Boltzmann model is developed to simulate finite-rate catalytic surface chemistry. Diffusive wall boundary conditions are established to account for catalytic reactions in multicomponent mixtures. Implementation of wall boundary conditions with chemical reactions is based on a general second-order accurate interpolation scheme. Results of lattice Boltzmann simulations for a four-component mixture with a global catalytic methane oxidation reaction in a straight channel are in excellent agreement with a finite volume Navier-Stokes solver in terms of both the flow field and species concentrations.

S. Arcidiacono; J. Mantzaras; I. V. Karlin

2008-10-28T23:59:59.000Z

68

Glycoside hydrolases: Catalytic base/nucleophile diversity  

NLE Websites -- All DOE Office Websites (Extended Search)

Glycoside Glycoside Hydrolases: Catalytic Base/Nucleophile Diversity Thu V. Vuong, David B. Wilson Department of Molecular Biology and Genetics, Cornell University, 458 Biotechnology Building, Ithaca, New York 14850; telephone: 607-255-5706; fax: 607-255-2428; e-mail: dbw3@cornell.edu Received 1 April 2010; revision received 27 May 2010; accepted 2 June 2010 Published online 15 June 2010 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/bit.22838 ABSTRACT: Recent studies have shown that a number of glycoside hydrolase families do not follow the classical catalytic mechanisms, as they lack a typical catalytic base/ nucleophile. A variety of mechanisms are used to replace this function, including substrate-assisted catalysis, a network of several residues, and the use of non-carboxylate residues or exogenous nucleophiles. Removal of the catalytic base/ nucleophile

69

Preparation, Characterization, and Catalytic Properties of Tungsten...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract: The structure and catalytic activity of tungsten oxide clusters formed via sublimation of monodispersed cyclic (WO3)3 onto FeO(111)Pt(111) surface has been studied...

70

Bifunctional Catalysts for the Selective Catalytic Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...

71

Microsecond Catalytic Partial Oxidation of Alkanes  

Science Journals Connector (OSTI)

...HICKMAN A. D. , PRODUCTION OF SYNGAS BY DIRECT CATALYTIC-OXIDATION OF METHANE...PFEFFERLE D. L. , CATALYSIS IN COMBUSTION , CATALYSIS...a-alu-mina monoliths coated with Rh (for syngas) (1, 2) or with Pt (for olefins...

Duane A. Goetsch; Lanny D. Schmidt

1996-03-15T23:59:59.000Z

72

Vacuum-insulated catalytic converter  

DOE Patents (OSTI)

A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

Benson, David K. (Golden, CO)

2001-01-01T23:59:59.000Z

73

Feedstock Economics for Global Steam Crackers  

E-Print Network (OSTI)

, butane, wide range naphtha, and atmospheric gas oil. The 10 regions considered in the study are the US Gulf Coast, Brazil, Western Canada, China, Indonesia, Japan, Saudi Arabia, 54 South Korea, Taiwan. and West Ger-many. lhe business climate... fabricated, while those in Saudi Arabia have a hJgh cont~nt of foreign shop fabrication into modules, and local assembly of the various modules. Location Factor Country 0.85 South k'orea 0.90 Taiwan 0.96 West Germany 1.00 US Gulf Coast 1.12 Japan...

McCormack, G.; Pavone, T.

74

Combustion Air Preheat on Steam Cracker Furnaces  

E-Print Network (OSTI)

Industrial Energy Technology Conference Volume II, Houston, TX, April 17-20, 1983 FIGURE 6 TYPICAL SEAL ARRANGEMENT FIGURE 1 TYPICAL CHANGEOVER PATTERN 50 GAS TURBlNEICRACKlNO FOONACE SYSTEM GTE/AIR FLOW VI nME O...-_T.,.;'..;.;,M;,;;;E;.:"? .;;.S...

Kenney, W. F.

1983-01-01T23:59:59.000Z

75

VOC Destruction by Catalytic Combustion Microturbine  

SciTech Connect

This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

Tom Barton

2009-03-10T23:59:59.000Z

76

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse is conducting a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1-Implementation Plan, Phase 2-Validation Testing and Phase 3-Field Testing. The Phase 1 program has been completed. Phase II was initiated in October 2004. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCL{trademark}) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to react part of the fuel, increasing the fuel/air mixture temperature. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the catalytic concept will be demonstrated through subscale testing. Phase III will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina; P. Szedlacsek

2006-03-31T23:59:59.000Z

77

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina

2008-01-31T23:59:59.000Z

78

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy’s National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 – Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

Laster, W. R.; Anoshkina, E.

2008-01-31T23:59:59.000Z

79

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

80

Fluid Inclusion Gas Analysis  

SciTech Connect

Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

Dilley, Lorie

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Catalytic gasification of tars from a dumping site  

Science Journals Connector (OSTI)

The work deals with catalytic gasification, pyrolysis and non-catalytic gasification of tar from an industrial dumping site. ... were carried out in a vertical stainless steel gasification reactor at 800 °C. Crus...

Lukįš Gašparovi?; Lukįš Šugįr…

2013-10-01T23:59:59.000Z

82

Rapid Deployment of Rich Catalytic Combustion  

SciTech Connect

The overall objective of this research under the Turbines Program is the deployment of fuel flexible rich catalytic combustion technology into high-pressure ratio industrial gas turbines. The resulting combustion systems will provide fuel flexibility for gas turbines to burn coal derived synthesis gas or natural gas and achieve NO{sub x} emissions of 2 ppmvd or less (at 15 percent O{sub 2}), cost effectively. This advance will signify a major step towards environmentally friendly electric power generation and coal-based energy independence for the United States. Under Phase 1 of the Program, Pratt & Whitney (P&W) performed a system integration study of rich catalytic combustion in a small high-pressure ratio industrial gas turbine with a silo combustion system that is easily scalable to a larger multi-chamber gas turbine system. An implementation plan for this technology also was studied. The principal achievement of the Phase 1 effort was the sizing of the catalytic module in a manner which allowed a single reactor (rather than multiple reactors) to be used by the combustion system, a conclusion regarding the amount of air that should be allocated to the reaction zone to achieve low emissions, definition of a combustion staging strategy to achieve low emissions, and mechanical integration of a Ceramic Matrix Composite (CMC) combustor liner with the catalytic module.

Richard S. Tuthill

2004-06-10T23:59:59.000Z

83

Catalytic wet oxidation of phenolic wastes  

E-Print Network (OSTI)

Possible catalyst deactivation problems High capital, low operating Supercritical water oxidation (SCWO) Feasible only at high organic concentra- tions High Fast reaction, complete oxidation Severe reaction conditions, canosion problems... of milder reaction conditions and is much less energy intensive. Thus, catalytic wet oxidation would be an alternative to solvent extraction, supercritical water oxidation, homogeneous oxidation, and incineration. It should also be feasible at low...

Thomas, Brook James

1995-01-01T23:59:59.000Z

84

Catalytic Partial Oxidation Pilot Plant Study  

Science Journals Connector (OSTI)

Foster Wheeler Corporation, 585 North Dairy Ashford Street, Houston, Texas 77079 ... This is accomplished in this study with a new reactor system named the catalytic hot oxygen reactor (CHOR). ... Studying the integration of the reactor with the rest of the plant and developing detailed process economics in parallel with the system development are necessary. ...

Vasilis Papavassiliou; Perry Pacouloute; KT Wu; Raymont Drnevich; Dionisios Vlachos; John Hemmings; Leo Bonnel

2009-11-24T23:59:59.000Z

85

Remediation of water contamination using catalytic technologies  

Science Journals Connector (OSTI)

Remediation of contaminated ground and underground water is becoming a critical issue in Europe and worldwide. We discuss here the role of catalysis in water remediation, with reference to two specific examples of catalytic water remediation technologies: (i) the elimination of nitrate and pesticides from water contaminated as a result of agricultural practices and (ii) the conversion of methyl tert-butyl ether (MTBE) in contaminated underground water. Of particular interest is a technology based on catalytic membranes for remediation of water contaminated by nitrate, which offers various advantages with respect to conventional technologies. Using a Pd-Cu-based catalytic membrane, a reaction temperature below 15 °C, a mixed 4:1 CO2:H2 feed and controlling bulk solution pH by \\{HCl\\} addition, it is possible to obtain a nitrate conversion higher than 80% even with ammonium ion formation below 0.5 ppm, i.e. the maximum concentration allowed to meet the requirements for drinking water quality. In MTBE conversion in contaminated underground water, acid zeolites with suitable pore structures (channel structure and pore openings) such as H-ZSM-5 and H-BEA can be used as catalytic permeable reactive barriers for in situ remediation. These zeolites not only act as adsorbents for both MTBE and its reaction products, but also effectively catalyze the hydrolysis of MTBE to t-butyl alcohol (TBA) and methanol (MeOH) which then can be rapidly biodegraded by indigenous microorganisms.

Gabriele Centi; Siglinda Perathoner

2003-01-01T23:59:59.000Z

86

Fluid transport container  

DOE Patents (OSTI)

An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitting for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container. 13 figs.

DeRoos, B.G.; Downing, J.P. Jr.; Neal, M.P.

1995-11-14T23:59:59.000Z

87

Catalytic fast pyrolysis of lignocellulosic biomass  

SciTech Connect

Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

2014-11-21T23:59:59.000Z

88

Standardization of Thermo-Fluid Modeling in Modelica.Fluid  

E-Print Network (OSTI)

Thermo-Fluid Systems, Modelica 2003 Conference, Linköping,H. Tummescheit: The Modelica Fluid and Media Library forThermo-Fluid Pipe Networks, Modelica 2006 Conference, Vi-

Franke, Rudiger

2010-01-01T23:59:59.000Z

89

Environmentally safe fluid extractor  

DOE Patents (OSTI)

An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

Sungaila, Zenon F. (Orland Park, IL)

1993-01-01T23:59:59.000Z

90

HEAT TRANSFER FLUIDS  

E-Print Network (OSTI)

The choice of heat transfer fluids has significant effects on the performance, cost, and reliability of solar thermal systems. In this chapter, we evaluate existing heat transfer fluids such as oils and molten salts based ...

Lenert, Andrej

2012-01-01T23:59:59.000Z

91

Fluid force transducer  

DOE Patents (OSTI)

An electrical fluid force transducer for measuring the magnitude and direction of fluid forces caused by lateral fluid flow, includes a movable sleeve which is deflectable in response to the movement of fluid, and a rod fixed to the sleeve to translate forces applied to the sleeve to strain gauges attached to the rod, the strain gauges being connected in a bridge circuit arrangement enabling generation of a signal output indicative of the magnitude and direction of the force applied to the sleeve.

Jendrzejczyk, Joseph A. (Warrenville, IL)

1982-01-01T23:59:59.000Z

92

Selective Catalytic Reduction and Exhaust Gas Recirculation Systems...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Reduction and Exhaust Gas Recirculation Systems Optimization A patented EGR-SCR approach was shown to readily meet the 2010 EPA requirments for NOx and PM emisisons...

93

Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis...

94

Printing 3D Catalytic Devices | The Ames Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Printing 3D Catalytic Devices Ames Laboratory scientist Igor Slowing discusses using 3D printers to create new materials, including catalysts...

95

Catalytic Conversion of Biomass-derived Feedstock (HMF) into...  

NLE Websites -- All DOE Office Websites (Extended Search)

Industrial Technologies Industrial Technologies Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalytic Conversion of Biomass-derived Feedstock...

96

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

97

Single Supported Atoms Participate in Catalytic Processes | ornl...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Materials for Energy Single Supported Atoms Participate in Catalytic Processes December 04, 2014 Pathways for NO oxidation on single Pt atoms supported on the (010)...

98

3D Printing of nanostructured catalytic materials | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

3D Printing of nanostructured catalytic materials Over the last couple of decades, scientists have been able to develop a tremendous control over the synthesis and properties of...

99

The Effects of Trace Contaminants on Catalytic Processing of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

100

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Energy.gov (U.S. Department of Energy (DOE))

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

102

Catalytic bromine recovery from HBr waste  

SciTech Connect

Waste HBr is formed during the bromination of many organic molecules, such as flame retardants, pharmaceuticals, and agricultural chemicals. For over 50 years attempts to recover the bromine from waste HBr by catalytic oxidation have been unsuccessful due to low catalyst activity and stability. The discovery of a new high-activity catalysts with excellent long-term stability and life capable of high HBr conversion below 300{degrees}C has made catalytic oxidation of waste HBr commercially feasible. The oxidation of anhydrous HBr using oxygen is highly exothermic, giving an adiabatic temperature rise of 2000{degrees}C. Use of 48 wt% HBr in the oxidation reduces the adiabatic temperature rise to only 300{degrees}C. A multitubular heat exchanger type of reactor can then be used to manage the heat. A 5,000 kg/yr pilot plant was built to verify the performance of the catalyst, the suitability of the reactor materials of construction, and the multibular reactor concept. The pilot unit has a single full-scale reactor tube 4 m long and 2.54 cm in diameter with a hot oil jacket for heat management. Excellent catalyst stability was observed during a 600 h catalyst-life test. HBr conversion of 99% was maintained throughout the run, and over 360 kg of bromine was produced. The temperature at a localized hot spot near the reactor inlet was only 15-20{degrees}C above the reactor inlet temperature, indicating efficient heat management.

Schubert, P.F.; Beatty, R.D.; Mahajan, S. [Catalytica Inc., Mountain View, CA (United States)

1993-12-31T23:59:59.000Z

103

Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming  

E-Print Network (OSTI)

-gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

Kuncharam, Bhanu Vardhan

2013-11-26T23:59:59.000Z

104

Fiber optic fluid detector  

DOE Patents (OSTI)

Particular gases or liquids are detected with a fiber optic element having a cladding or coating of a material which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses. 10 figs.

Angel, S.M.

1987-02-27T23:59:59.000Z

105

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1984-03-27T23:59:59.000Z

106

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1985-08-20T23:59:59.000Z

107

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1984-01-01T23:59:59.000Z

108

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1985-01-01T23:59:59.000Z

109

Catalytic cartridge SO/sub 3/ decomposer  

DOE Patents (OSTI)

A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

Galloway, T.R.

1980-11-18T23:59:59.000Z

110

Design for Process Integration and Efficient Energy Utilization  

E-Print Network (OSTI)

within a process unit is provided by a Fluid Catalytic Cracker (FCCU) operating at design capacity and 80% of design capacity. The process is energy intensive and cracks hydrocarbons into lighter components, with incidental deposition of carbon onto..., with the energy balance closed by power import or export. To facilitate start-up, a steam turbine is added to the shaft. RfGlNERATDll flUE GAS AlII TO RfGINERATDll BY?PASS ~===:(I MIG EXHAUST Figure 8. FCCU Expander/ Compressor Hot combustion gases...

James, A. J.

1982-01-01T23:59:59.000Z

111

Thermodynamics and Fluids  

Science Journals Connector (OSTI)

... AN important section of the work of modern chemical engineers lies in the application of thermodynamics to problems of fluid systems. This volume, the fourth in the series, is ... properties of physical systems and to the transport properties of fluids. The first section on thermodynamics has been written by Dr. R. Strickland Constable of the Chemical Engineering Department at ...

J. M. COULSON

1958-09-27T23:59:59.000Z

112

Multiphase Equilibrium of Fluids Confined in Fisher-Tropsch Catalytic Systems  

E-Print Network (OSTI)

. Two different scenarios were studied for fixed bed reactor: the first one is the conventional gas phase FTS and the second one is for the supercritical phase FTS (SCF-FTS). In each case, the phase behavior of the mixture of the reactants and products...

Warrag, Samah

2014-04-23T23:59:59.000Z

113

MAX Fluid Dynamics facility  

NLE Websites -- All DOE Office Websites (Extended Search)

MAX Fluid Dynamics facility MAX Fluid Dynamics facility Capabilities Engineering Experimentation Reactor Safety Testing and Analysis Overview Nuclear Reactor Severe Accident Experiments MAX NSTF SNAKE Aerosol Experiments System Components Laser Applications Robots Applications Other Facilities Other Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr MAX Fluid Dynamics facility Providing high resolution data for development of computational tools that model fluid flow and heat transfer within complex systems such as the core of a nuclear reactor. 1 2 3 4 5 Hot and cold air jets are mixed within a glass tank while laser-based anemometers and a high-speed infrared camera characterize fluid flow and heat transfer behavior. Click on image to view larger size image.

114

Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids  

SciTech Connect

The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

2013-01-18T23:59:59.000Z

115

NETL: C&CBTL - Investigation of Coal-Biomass Catalytic Gasification Using  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed and Gasification Coal/Biomass Feed and Gasification Investigation of Coal-Biomass Catalytic Gasification Using Experiments, Reaction Kinetics and Computational Fluid Dynamics Virginia Polytechnic Institute and State University Project Number: FE0005476 Project Description The objectives of the proposed study are to obtain experimental reactor data and develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations, to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure, to build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and to investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.

116

Fluid sampling tool  

DOE Patents (OSTI)

A fluid sampling tool is described for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall. 6 figs.

Garcia, A.R.; Johnston, R.G.; Martinez, R.K.

1999-05-25T23:59:59.000Z

117

IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY |  

Open Energy Info (EERE)

IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAPHY Details Activities (1) Areas (1) Regions (0) Abstract: Fluid Inclusion Stratigraphy (FIS) is a method currently being developed for use in geothermal systems to identify fractures and fluid types. This paper is the third in a series of papers on the development of FIS. Fluid inclusion gas chemistry is analyzed and plotted on well log diagrams. The working hypothesis is that select gaseous species and species ratios indicate areas of groundwater and reservoir fluid flow and reservoir seals. Previously we showed that FIS analyses identify fluid types and

118

Multiphase fluid characterization system  

DOE Patents (OSTI)

A measurement system and method for permitting multiple independent measurements of several physical parameters of multiphase fluids flowing through pipes are described. Multiple acoustic transducers are placed in acoustic communication with or attached to the outside surface of a section of existing spool (metal pipe), typically less than 3 feet in length, for noninvasive measurements. Sound speed, sound attenuation, fluid density, fluid flow, container wall resonance characteristics, and Doppler measurements for gas volume fraction may be measured simultaneously by the system. Temperature measurements are made using a temperature sensor for oil-cut correction.

Sinha, Dipen N.

2014-09-02T23:59:59.000Z

119

CATALYTIC MICROWAVE PYROLYSIS OF BIOMASS FOR RENEWABLE PHENOLS AND FUELS .  

E-Print Network (OSTI)

??Bio-oil is an unstable intermediate and needs to be upgraded before its use. This study focused on improving the selectivity of bio-oilby catalytic pyrolysis of… (more)

[No author

2013-01-01T23:59:59.000Z

120

Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity Thanks to a groundbreaking new method, scientists have created the first 3D super-resolution maps of...

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

In situ XAS Characterization of Catalytic Nano-Materials with...  

NLE Websites -- All DOE Office Websites (Extended Search)

XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying...

122

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents (OSTI)

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

123

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

SciTech Connect

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-10-07T23:59:59.000Z

124

Microchannel Reactor System for Catalytic Hydrogenation  

SciTech Connect

We successfully demonstrated a novel process intensification concept enabled by the development of microchannel reactors, for energy efficient catalytic hydrogenation reactions at moderate temperature, and pressure, and low solvent levels. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for hydrogenation of onitroanisole and a proprietary BMS molecule. In the second phase of the program, as a prelude to full-scale commercialization, we designed and developed a fully-automated skid-mounted multichannel microreactor pilot plant system for multiphase reactions. The system is capable of processing 1 – 10 kg/h of liquid substrate, and an industrially relevant immiscible liquid-liquid was successfully demonstrated on the system. Our microreactor-based pilot plant is one-of-akind. We anticipate that this process intensification concept, if successfully demonstrated, will provide a paradigm-changing basis for replacing existing energy inefficient, cost ineffective, environmentally detrimental slurry semi-batch reactor-based manufacturing practiced in the pharmaceutical and fine chemicals industries.

Adeniyi Lawal; Woo Lee; Ron Besser; Donald Kientzler; Luke Achenie

2010-12-22T23:59:59.000Z

125

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

DOE Patents (OSTI)

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christpher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

126

Catalytic Transformation of Waste Carbon Dioxide into Valuable Products  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Transformation of Waste Catalytic Transformation of Waste Carbon Dioxide into Valuable Products Background Many industrial processes contribute large amounts of carbon dioxide (CO 2 ) to the earth's atmosphere. In an effort to reduce the amount of CO 2 released to the atmosphere, the U.S. Department of Energy (DOE) is funding efforts to develop CO 2 capture and storage technologies. In addition to permanent storage of CO 2 in underground reservoirs, some

127

Northwestern University Facility for Clean Catalytic Process Research  

SciTech Connect

Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

Marks, Tobin Jay [Northwestern University

2013-05-08T23:59:59.000Z

128

Fluid pumping apparatus  

DOE Patents (OSTI)

A method and apparatus suitable for coupling seismic or other downhole sensors to a borehole wall in high temperature and pressure environments. In one embodiment, one or more metal bellows mounted to a sensor module are inflated to clamp the sensor module within the borehole and couple an associated seismic sensor to a borehole wall. Once the sensing operation is complete, the bellows are deflated and the sensor module is unclamped by deflation of the metal bellows. In a further embodiment, a magnetic drive pump in a pump module is used to supply fluid pressure for inflating the metal bellows using borehole fluid or fluid from a reservoir. The pump includes a magnetic drive motor configured with a rotor assembly to be exposed to borehole fluid pressure including a rotatable armature for driving an impeller and an associated coil under control of electronics isolated from borehole pressure.

West, Phillip B. (Idaho Falls, ID)

2006-01-17T23:59:59.000Z

129

Basic fluid system trainer  

DOE Patents (OSTI)

A trainer, mounted and housed within a mobile console, is used to teach and reinforce fluid principles to students. The system trainer has two centrifugal pumps, each driven by a corresponding two-speed electric motor. The motors are controlled by motor controllers for operating the pumps to circulate the fluid stored within a supply tank through a closed system. The pumps may be connected in series or in parallel. A number of valves are also included within the system to effect different flow paths for the fluid. In addition, temperature and pressure sensing instruments are installed throughout the closed system for measuring the characteristics of the fluid, as it passes through the different valves and pumps. These measurements are indicated on a front panel mounted to the console, as a teaching aid, to allow the students to observe the characteristics of the system.

Semans, Joseph P. (Uniontown, PA); Johnson, Peter G. (Pittsburgh, PA); LeBoeuf, Jr., Robert F. (Clairton, PA); Kromka, Joseph A. (Idaho Falls, ID); Goron, Ronald H. (Connellsville, PA); Hay, George D. (Venetia, PA)

1993-01-01T23:59:59.000Z

130

GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID | Open Energy  

Open Energy Info (EERE)

FLUID PROPENE AND PROPANE: INDICATORS OF FLUID FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Details Activities (1) Areas (1) Regions (0) Abstract: The use of fluid inclusion gas analysis propene/propene ratios is investigated. Ratios of these species are affected by geothermal fluid temperature and oxidations state. Our purpose is to determine if analyses of these species in fluid inclusions these species to can be used to interpret fluid type, history, or process. Analyses were performed on drill cuttings at 20ft intervals from four Coso geothermal wells. Two wells are good producers, one has cold-water entrants in the production zone, and the fourth is a non-producer. The ratios show distinct differences between

131

Fluid driven reciprocating apparatus  

DOE Patents (OSTI)

An apparatus is described comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached. 13 figs.

Whitehead, J.C.

1997-04-01T23:59:59.000Z

132

Development of a catalytically assisted combustor for a gas turbine  

Science Journals Connector (OSTI)

A catalytically assisted low \\{NOx\\} combustor has been developed which has the advantage of catalyst durability. This combustor is composed of a burner section and a premixed combustion section behind the burner section. The burner system consists of six catalytic combustor segments and six premixing nozzles, which are arranged alternately and in parallel. Fuel flow rate for the catalysts and the premixing nozzles are controlled independently. The catalytic combustion temperature is maintained under 1000°C, additional premixed gas is injected from the premixing nozzles into the catalytic combustion gas, and lean premixed combustion at 1300°C is carried out in the premixed combustion section. This system was designed to avoid catalytic deactivation at high temperature and thermal or mechanical shock fracture of the honeycomb monolith. In order to maintain the catalyst temperature under 1000°C, the combustion characteristics of catalysts at high pressure were investigated using a bench scale reactor and an improved catalyst was selected for the combustor test. A combustor for a 20 MW class multi-can type gas turbine was designed and tested under high pressure conditions using LNG fuel. Measurements of NOx, CO and unburned hydrocarbon were made and other measurements were made to evaluate combustor performance under various combustion temperatures and pressures. As a result of the tests, it was proved that \\{NOx\\} emission was lower than 10 ppm converted at 16% O2, combustion efficiency was almost 100% at 1300°C of combustor outlet temperature and 13.5 ata of combustor inlet pressure.

Yasushi Ozawa; Tomoharu Fujii; Mikio Sato; Takaaki Kanazawa; Hitoshi Inoue

1999-01-01T23:59:59.000Z

133

Enhanced thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith  

Energy.gov (U.S. Department of Energy (DOE))

Emissions performance comparison of conventional catalytic converter with multi-channel catalytic converter (ceramic fiber insulation layers introduced into ceramic monolith of three-way catalytic converter)

134

View dependent fluid dynamics  

E-Print Network (OSTI)

VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2006 Major Subject: Visualization... Sciences VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Donald...

Barran, Brian Arthur

2006-08-16T23:59:59.000Z

135

Visually simulating realistic fluid motion  

E-Print Network (OSTI)

where 0 stands for obstacle cell, S surface cell, F full cell, I inlet cell, U outlet cell and the cells not marked are empty cells . . . . . . 34 12 Area weighting interpolation scheme for determining local fluid velocity for a marker k [9] . . 35... in the fluid. It is measured as the force on the face of a unit cube, inserted into the fluid. If the pressure varies in the fluid, the fluid will move due to the acceleration generated by the pressure force. The pressure at a point is isotropic in a fluid...

Naithani, Priyanka

2012-06-07T23:59:59.000Z

136

DOE - Office of Legacy Management -- Catalytic Co - PA 40  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Co - PA 40 Catalytic Co - PA 40 FUSRAP Considered Sites Site: Catalytic Co. (PA.40 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Philadelphia , Pennsylvania PA.40-1 Evaluation Year: 1991 PA.40-1 Site Operations: Prime contractor for construction of the Fernald facility. Records indicate one time shipment of a very small quantity (4 lbs) of uranium metal to this site. PA.40-1 Site Disposition: Eliminated - Construction contractor - Potential for residual contamination from the very small quantity of uranium shipped to this site is considered remote PA.40-2 Radioactive Materials Handled: None - as a construction contractor Primary Radioactive Materials Handled: Uranium Metal - Believed to be a Souvenier. PA.40-1

137

Imaging Catalytic Surfaces by Multiplexed Capillary Electrophoresis With Absorption Detection  

SciTech Connect

A new technique for in situ imaging and screening heterogeneous catalysts by using multiplexed capillary electrophoresis with absorption detection was developed. By bundling the inlets of a large number of capillaries, an imaging probe can be created that can be used to sample products formed directly from a catalytic surface with high spatial resolution. In this work, they used surfaces made of platinum, iron or gold wires as model catalytic surfaces for imaging. Various shapes were recorded including squares and triangles. Model catalytic surfaces consisting of both iron and platinum wires in the shape of a cross were also imaged successfully. Each of the two wires produced a different electrochemical product that was separated by capillary electrophoresis. Based on the collected data they were able to distinguish the products from each wire in the reconstructed image.

Michael Christodoulou

2002-08-27T23:59:59.000Z

138

Test results of a catalytic combustor for a gas turbine  

Science Journals Connector (OSTI)

A catalytically assisted low \\{NOx\\} combustor has been developed which has the advantage of catalyst durability. Combustion characteristics of catalysts at high pressure were investigated using a bench scale reactor and an improved catalyst was selected. A combustor for multi-can type gas turbine of 10 MW class was designed and tested at high-pressure conditions using liquefied natural gas (LNG) fuel. This combustor is composed of a burner system and a premixed combustion zone in a ceramic type liner. The burner system consists of catalytic combustor segments and premixing nozzles. Catalyst bed temperature is controlled under 1000°C, premixed gas is injected from the premixing nozzles to catalytic combustion gas and lean premixed combustion is carried out in the premixed combustion zone. As a result of the combustion tests, \\{NOx\\} emission was lower than 5 ppm converted at 16% O2 at a combustor outlet temperature of 1350°C and a combustor inlet pressure of 1.33 MPa.

Y Ozawa; T Fujii; Y Tochihara; T Kanazawa; K Sagimori

1998-01-01T23:59:59.000Z

139

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID...  

Open Energy Info (EERE)

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

140

Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications  

SciTech Connect

Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

Eteman, Shahrokh

2013-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Relativistic viscoelastic fluid mechanics  

SciTech Connect

A detailed study is carried out for the relativistic theory of viscoelasticity which was recently constructed on the basis of Onsager's linear nonequilibrium thermodynamics. After rederiving the theory using a local argument with the entropy current, we show that this theory universally reduces to the standard relativistic Navier-Stokes fluid mechanics in the long time limit. Since effects of elasticity are taken into account, the dynamics at short time scales is modified from that given by the Navier-Stokes equations, so that acausal problems intrinsic to relativistic Navier-Stokes fluids are significantly remedied. We in particular show that the wave equations for the propagation of disturbance around a hydrostatic equilibrium in Minkowski space-time become symmetric hyperbolic for some range of parameters, so that the model is free of acausality problems. This observation suggests that the relativistic viscoelastic model with such parameters can be regarded as a causal completion of relativistic Navier-Stokes fluid mechanics. By adjusting parameters to various values, this theory can treat a wide variety of materials including elastic materials, Maxwell materials, Kelvin-Voigt materials, and (a nonlinearly generalized version of) simplified Israel-Stewart fluids, and thus we expect the theory to be the most universal description of single-component relativistic continuum materials. We also show that the presence of strains and the corresponding change in temperature are naturally unified through the Tolman law in a generally covariant description of continuum mechanics.

Fukuma, Masafumi; Sakatani, Yuho [Department of Physics, Kyoto University, Kyoto 606-8502 (Japan)

2011-08-15T23:59:59.000Z

142

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

143

Magnetically stimulated fluid flow patterns  

ScienceCinema (OSTI)

Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

Martin, Jim; Solis, Kyle

2014-08-06T23:59:59.000Z

144

Fluid Flow Modeling in Fractures  

E-Print Network (OSTI)

In this paper we study fluid flow in fractures using numerical simulation and address the challenging issue of hydraulic property characterization in fractures. The methodology is based on Computational Fluid Dynamics, ...

Sarkar, Sudipta

2004-01-01T23:59:59.000Z

145

Use of Pd membranes in catalytic reactors for steam methane reforming for pure hydrogen production  

Science Journals Connector (OSTI)

This review analyzes publications on experimental studies and mathematical modeling in the field of development of a catalytic reformer (mainly, steam methane conversion) with a fixed catalytic bed. The specif...

A. B. Shigarov; V. D. Meshcheryakov…

2011-10-01T23:59:59.000Z

146

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

147

E-Print Network 3.0 - atpase catalytic domain Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

impressive progress has been made in understanding of the catalytic mechanism of F-type ATP synthase, which is the key enzyme in the energy metabolism of Summary: of the catalytic...

148

Enhanced thermal and gas flow performance in a three-way catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Enhanced thermal and gas flow performance in a three-way catalytic...

149

Utilization and Mitigation of VAM/CMM Emissions by a Catalytic Combustion Gas Turbine  

Science Journals Connector (OSTI)

A system configured with a catalytic combustion gas turbine generator unit is introduced. The system has ... Heavy Industries, Ltd., such as small gas turbines, recuperators and catalytic combustors, and catalyti...

K. Tanaka; Y. Yoshino; H. Kashihara; S. Kajita

2013-01-01T23:59:59.000Z

150

Process analysis of syngas production by non-catalytic POX of oven gas  

Science Journals Connector (OSTI)

A non-catalytic POX of oven gas is proposed to solve the problem of secondary pollution due to solid wastes produced from the great amount of organic sulfur contained in oven gas in the traditional catalytic p...

Fuchen Wang; Xinwen Zhou; Wenyuan Guo…

2009-03-01T23:59:59.000Z

151

High Performance Catalytic Heat Exchanger for SOFC Systems - FuelCell Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Heat Catalytic Heat Exchanger for SOFC Systems-FuelCell Energy Background In a typical solid oxide fuel cell (SOFC) power generation system, hot (~900 Ā°C) effluent gas from a catalytic combustor serves as the heat source within a high-temperature heat exchanger, preheating incoming fresh air for the SOFC's cathode. The catalytic combustor and the cathode air heat exchanger together represent the largest opportunity for cost

152

Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels  

Energy.gov (U.S. Department of Energy (DOE))

Factsheet overview of how project will develop a unique, feul-flexible catalytic combustor for gas turbines

153

The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann  

E-Print Network (OSTI)

The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann WeierstraĆ?-Institut f that the reactant has an infinite local biodiversity or genetic abundance. This contrasts the finite local biodiversity of the equilibrium of classical super-Brownian motion. Another question we address

Klenke, Achim

154

Short Communication Catalytic coal gasification: use of calcium versus potassium*  

E-Print Network (OSTI)

Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

155

Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC)  

E-Print Network (OSTI)

Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC) MUTATIONAL ANALYSIS OF RESIDUES WITHIN THE ACTIVE SITE AND HYDROPHOBIC RIDGE OF PLC 1* (Received for publication, November 20, 1997 Institute, University of Dundee, Dundee DD1 4HN, United Kingdom Structural studies of phospholipase C 1 (PLC

Williams, Roger L.

156

Catalytic gasification of automotive shredder residues with hydrogen generation  

Science Journals Connector (OSTI)

Hydrogen is a clean and new energy carrier to generate power through the Proton exchange membrane fuel cell (PEMFC) system. Hydrogen can be effectively turned out through the catalytic gasification of organic material such as automotive shredder residues (ASR). The main objective of this manuscript is to present an analysis of the catalytic gasification of ASR for the generation of high-purity hydrogen in a lab-scale fixed-bed downdraft gasifier using 15 wt.% NiO/Al2O3 catalysts at 760–900 K. In the catalytic gasification process, reduction of Ni(II) catalyst into Ni(0) has been confirmed through XANES spectra and consequently EXAFS data shows that the central Ni atoms have Ni–O and Ni–Ni bonds with bond distances of 2.03 ± 0.05 and 2.46 ± 0.05 Å, respectively. ASR is partially oxidized and ultimately converts into hydrogen rich syngas (CO and H2) and increases of the reaction temperature are favored the generation of hydrogen with decomposition of the CO. As well, approximately 220 kg h?1 of ASR would be catalytically gasified at 760–900 K and 46.2 atm with the reactor volume 0.27 m3 to obtain approximately 3.42 × 105 kcal h?1 of thermal energy during over 87% syngas generation with the generation of 100 kW electric powers.

Kuen-Song Lin; Sujan Chowdhury; Ze-Ping Wang

2010-01-01T23:59:59.000Z

157

Production of Syngas by Direct Catalytic Oxidation of Methane  

Science Journals Connector (OSTI)

...DESORPTION AT HIGH-TEMPERATURES...of abundant natural gas into liquid...a 50-mI high-pressure Autoclave...atmospheric pressure, and the...with very high CH4 yields...Contact times of gases within the...catalytic combustors and reactors...

D. A. Hickman; L. D. Schmidt

1993-01-15T23:59:59.000Z

158

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

159

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

160

Scaling behavior of optimally structured catalytic microfluidic reactors  

E-Print Network (OSTI)

In this study of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying scaling properties. The scaling is predicted theoretically and verified numerically. Furthermore, we show how to increase the reaction rate significantly by distributing the active porous material within the reactor using a high-level implementation of topology optimization.

Okkels, F; Bruus, Henrik; Okkels, Fridolin

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Nanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties  

E-Print Network (OSTI)

to be a useful technique to generate nanophase transition metals.7,8 Recently, molybdenum and tungsten carbides of metal salts.5,6 Sonochemical decomposition of transition metal carbonyl compounds has also been provenNanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties Taeghwan Hyeon

Suslick, Kenneth S.

162

Oscillating fluid power generator  

SciTech Connect

A system and method for harvesting the kinetic energy of a fluid flow for power generation with a vertically oriented, aerodynamic wing structure comprising one or more airfoil elements pivotably attached to a mast. When activated by the moving fluid stream, the wing structure oscillates back and forth, generating lift first in one direction then in the opposite direction. This oscillating movement is converted to unidirectional rotational movement in order to provide motive power to an electricity generator. Unlike other oscillating devices, this device is designed to harvest the maximum aerodynamic lift forces available for a given oscillation cycle. Because the system is not subjected to the same intense forces and stresses as turbine systems, it can be constructed less expensively, reducing the cost of electricity generation. The system can be grouped in more compact clusters, be less evident in the landscape, and present reduced risk to avian species.

Morris, David C

2014-02-25T23:59:59.000Z

163

Modeling a Catalytic Reactor for Hydrotreating of Straight-Run Gas Oil Blended with Fluid Catalytic Cracking Naphtha and Light Cycle Oil: Influence of Vapor–Liquid Equilibrium  

Science Journals Connector (OSTI)

Model results were validated using the industrial test run data, and very good predictions of overall sulfur conversion and reactor temperature were obtained. ...

Ivana M. Mijatovi?; Sandra B. Glisic; Aleksandar M. Orlovi?

2014-11-17T23:59:59.000Z

164

Chapter 22 - Heterogeneous Catalytic Reduction for Water Purification: Nanoscale Effects on Catalytic Activity, Selectivity, and Sustainability  

Science Journals Connector (OSTI)

Reductive catalysis is a promising water treatment technology that employs heterogeneous metal catalysts (e.g., Pd nanoparticles on a support) to convert dihydrogen to adsorbed atomic hydrogen in order to promote reactions with functional groups in various contaminants. Reductive catalysis has several potential advantages, including high selectivity for a given target, fast rates under mild conditions, and low production of harmful by-products. The technology has been applied mostly for remediation of groundwater contaminated with halogenated hydrocarbons and for treatment of nitrate, but recent studies have expanded the range of target contaminants to include perchlorate and N-nitrosamines. Palladium-based catalysts hold tremendous promise for their ability to selectively destroy several drinking water contaminants, and some compounds that exhibit slow reaction kinetics with Pd alone are rapidly degraded when a second, promoter metal is added to the catalyst. However, there is a lack of information about the long-term sustainability of these catalytic treatment processes, which is a major consideration in their possible adoption for remediation applications. Recent research has focused on the nanoscale characterization of these heterogeneous catalysts in order to develop an improved understanding of their mechanisms of deactivation and the pathways for regeneration. Two examples of studies from the authors’ laboratories, involving (i) hydrodehalogenation of iodinated X-ray contrast media with Ni or Pd catalysts and (ii) selective reduction of nitrate with a regenerable Pd-In/alumina catalyst, are discussed in this chapter.

Timothy J. Strathmann; Charles J. Werth; John R. Shapley

2014-01-01T23:59:59.000Z

165

Downhole Fluid Analyzer Development  

SciTech Connect

A novel fiber optic downhole fluid analyzer has been developed for operation in production wells. This device will allow real-time determination of the oil, gas and water fractions of fluids from different zones in a multizone or multilateral completion environment. The device uses near infrared spectroscopy and induced fluorescence measurement to unambiguously determine the oil, water and gas concentrations at all but the highest water cuts. The only downhole components of the system are the fiber optic cable and windows. All of the active components--light sources, sensors, detection electronics and software--will be located at the surface, and will be able to operate multiple downhole probes. Laboratory testing has demonstrated that the sensor can accurately determine oil, water and gas fractions with a less than 5 percent standard error. Once installed in an intelligent completion, this sensor will give the operating company timely information about the fluids arising from various zones or multilaterals in a complex completion pattern, allowing informed decisions to be made on controlling production. The research and development tasks are discussed along with a market analysis.

Bill Turner

2006-11-28T23:59:59.000Z

166

Energy Efficiency Improvements of U.S. Olefins Crackers  

E-Print Network (OSTI)

-05-18 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 7 Reduced Capital: 2008 - Present ? Highest ROI projects (i.e. ?low-hanging fruit?) already implemented ? Lower energy prices reduce the economic...-24, 2013 2 About Dow Combine the power of science and technology to passionately innovate what is essential to human progress. ? Founded by Herbert H. Dow in Midland, Michigan in 1897 ? Serve customers in ~160 countries ? 5,000+ products...

Benton, J.

2013-01-01T23:59:59.000Z

167

Acoustic concentration of particles in fluid flow  

SciTech Connect

An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

Ward, Michael D. (Los Alamos, NM); Kaduchak, Gregory (Los Alamos, NM)

2010-11-23T23:59:59.000Z

168

Solar reforming of methane in a direct absorption catalytic reactor on a parabolic dish: 2, Modeling and analysis  

SciTech Connect

The CAtalytically Enhanced Solar Absorption Receiver (CAESAR) experiment was conducted to determine the thermal, chemical, and mechanical performance of a commercial-scale, dish-mounted, direct catalytic absorption receiver (DCAR) reactor over a range of steady state and transient (cloud) operating conditions. The focus of the experiment is on global performance such as receiver efficiencies and overall methane conversion; it was not intended to provide data for code validation. A numerical model was previously developed to provide guidance in the design of the absorber. The one-dimensional, planar and steady-state model incorporates, the following energy transfer mechanisms: solar and infrared radiation, heterogeneous chemical reaction, conduction in the solid phase, and convection between the fluid and solid phases. A number of upgrades to the model and improved property values are presented here. Model predictions are shown to bound the experimental axial thermocouple data when experimental uncertainties are included. Global predictions are made using a technique in which the incident solar flux distribution is subdivided into flux contour bands. Model predictions for each band are then spatially integrated to provide global predictions such as reactor efficiencies and methane conversions. Global predictions are shown to compare well with experimental data. Reactor predictions for anticipated operating conditions suggest a further decrease in optical density at the front of the absorber inner disk may be beneficial. The need to conduct code-validation experiments is identified as essential to improve the confidence in the capability to predict large-scale reactor operation.

Skocypec, R.D.; Hogan, R.E. Jr.; Muir, J.F.

1991-01-01T23:59:59.000Z

169

Volatiles in hydrothermal fluids- A mass spectrometric study of fluid  

Open Energy Info (EERE)

Volatiles in hydrothermal fluids- A mass spectrometric study of fluid Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Report: Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Details Activities (4) Areas (4) Regions (0) Abstract: A system for analysis of inclusion gas contents based upon quadrupole mass spectrometry has been designed, assembled and tested during the first 7 months of funding. The system is currently being tested and calibrated using inclusions with known gas contents from active geothermal systems. Analyses are in progress on inclusions from the Salton Sea, Valles Caldera, Geysers, and Coso geothermal systems. Author(s): Mckibben, M. A.

170

Notes 09. Fluid inertia and turbulence in fluid film bearings  

E-Print Network (OSTI)

When fluid inertia effects are important. Bulk-flow model for inertial flows. Turbulence and inertia in short length journal bearings and open end dampers....

San Andres, Luis

2009-01-01T23:59:59.000Z

171

Thermodynamic Model for Fluid-Fluid Interfacial Areas in Porous...  

NLE Websites -- All DOE Office Websites (Extended Search)

areas are important in controlling the rate of mass and energy transfer between fluid phases in porous media. We present a modified thermodynamically based model (TBM) to...

172

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents (OSTI)

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

173

Catalytic production of metal carbonyls from metal oxides  

DOE Patents (OSTI)

This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

1984-01-06T23:59:59.000Z

174

The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides  

SciTech Connect

Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

Kelty,S.; Berhault, G.; Chianelli, R.

2007-01-01T23:59:59.000Z

175

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels  

Science Journals Connector (OSTI)

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels ... Results derived from soybean oil, jatropha oil, and tung oil show that certain biofuel fractions met JP-8 specifications and Navy distillate specifications. ... Therefore, tung-oil-derived CH biofuel will have added value as a blend stock for existing FT jet fuels and emerging biofuels such as those produced from the UOP/ENI EcofiningTM process to meet fuel specifications by increasing density and aromatic content. ...

Lixiong Li; Edward Coppola; Jeffrey Rine; Jonathan L. Miller; Devin Walker

2010-01-13T23:59:59.000Z

176

Micro-Scale Catalytic Reactor for Syngas Production  

Science Journals Connector (OSTI)

Micro-Scale Catalytic Reactor for Syngas Production ... The H2 yield (?H2) was evaluated as moles of H2 produced per mole of CH4 converted in the reforming channel. ... In particular, the maximum temperature moves from a location close to the reactor center (for MCH4-sr/MCH4-co = 2) toward the reactor inlet producing in the case of MCH4-sr/MCH4-co =2.75 decreasing temperature profiles without a maximum. ...

S. Vaccaro; L. Malangone; P. Ciambelli

2010-07-01T23:59:59.000Z

177

Catalytic Graphitization of Carbon Aerogels by Transition Metals  

Science Journals Connector (OSTI)

Catalytic Graphitization of Carbon Aerogels by Transition Metals ... Carbon aerogels and Cr-, Fe-, Co-, and Ni-containing carbon aerogels were obtained by pyrolysis, at temperatures between 500 and 1800 °C, of the corresponding aerogels prepared by the sol?gel method from polymerization of resorcinol with formaldehyde. ... Results obtained show that carbon aerogels are, essentially, macroporous materials that maintain large pore volumes even after pyrolysis at 1800 °C. ...

F. J. Maldonado-Hódar; C. Moreno-Castilla; J. Rivera-Utrilla; Y. Hanzawa; Y. Yamada

2000-03-24T23:59:59.000Z

178

Effects of Current upon Electrochemical Catalytic Reforming of Anisole  

Science Journals Connector (OSTI)

The reforming of anisole (as model compound of bio-oil) was performed over the NiCuZn-Al2O3 catalyst, using a recently-developed electrochemical catalytic reforming (ECR). The influence of the current on the anisole reforming in the ECR process has been investigated. It was observed that anisole reforming was significantly enhanced by the current approached over the catalyst in the electrochemical catalytic process, which was due to the non-uniform temperature distribution in the catalytic bed and the role of the thermal electrons originating from the electrified wire. The maximum hydrogen yield of 88.7% with a carbon conversion of 98.3% was obtained through the ECR reforming of anisole at 700°C and 4 A. X-ray diffraction was employed to characterize catalyst features and their alterations in the anisole reforming. The apparent activation energy for the anisole reforming is calculated as 99.54 kJ/mol, which is higher than ethanol, acetic acid, and light fraction of bio-oil. It should owe to different physical and chemical properties and reforming mechanism for different hydrocarbons.

Jia-xing Xiong; Tao Kan; Xing-long Li; Tong-qi Ye; Quan-xin Li

2010-01-01T23:59:59.000Z

179

Chapter 10 - Regenerative catalytic oxidizer technology for VOC control  

Science Journals Connector (OSTI)

Publisher Summary The regenerative catalytic oxidizer (RCO) technology has evolved significantly as an efficient method to control volatile organic compounds. The RCO technology favors using oxide catalysts because it allows for easy compensation of lower activity by an increase in the catalyst amount or temperature. Heat transfer and accumulation properties of ceramic packing material strongly influence RCO performance. The rate of heat transfer affects the temperature gradients along the bed length that, in turn, determine the volume of material required to preheat the gas to the temperature of catalytic or thermal oxidation. During the catalyst operation, it gradually becomes less active and must be eventually replaced. The factors affecting the catalyst lifetime include high temperature, catalytic poisons, and masking agents. Compounds of halogens and sulfur are the most common catalyst poisons. Temperature control, poison tolerant catalysts, and gas-flow pretreatment are used to reduce the impact of catalyst deactivation. This chapter also presents the behavior of an RCO when the catalyst deactivates, and proposes strategies ensuring the required performance during the entire catalyst lifetime.

V.O. Strots; G.A. Bunimovich; C.R. Roach; Yu.Sh. Matros

2000-01-01T23:59:59.000Z

180

Fracturing Fluid Characterization Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

Documentation Page Documentation Page 1. Report No. DE - FC 21 - 92MC29077 2. 3. Recipient's Accession No. 5. Report Date August 31, 2000 4. Title and Subtitle Fracturing Fluid Characterization Facility 6. 7. Author(s) The University of Oklahoma 8. Performing Organization Rept. No. 10. Project/Task/Work Unit No. 9. Performing Organization Name and Address The University of Oklahoma Sarkeys Energy Center T301 100 E Boyd St Norman, OK 73019 11. Contract (C) or Grant (G) No. DOE:DE FC21 92 MC29077 13. Type of Report & Period Covered Final Report 09 30 92 - 03 31 00 12. Sponsoring Organization Name and Address US Dept of Energy - FETL 3610 Collins Ferry Road Morgantown, WV 26505 14. 15. Supplementary Notes Several technical papers were prepared and presented at various Society of Petroleum Engineers Conferences and US

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Viscosity of Quantum Hall Fluids  

Science Journals Connector (OSTI)

The viscosity of quantum fluids with an energy gap at zero temperature is related to the adiabatic curvature on the space parametrizing flat background metrics. For quantum Hall fluids on two-dimensional tori, the quantum viscosity is computed. It turns out to be isotropic, constant, and proportional to the magnetic field strength.

J. E. Avron; R. Seiler; P. G. Zograf

1995-07-24T23:59:59.000Z

182

Fluid Mechanics and Homeland Security  

E-Print Network (OSTI)

Fluid Mechanics and Homeland Security Gary S. Settles Mechanical and Nuclear Engineering Department and sampling, explosive detection, microfluidics and labs-on-a-chip, chem- ical plume dispersal in urban security combines established fluids topics like plume dispersion with others that are new

Settles, Gary S.

183

LECTURES IN ELEMENTARY FLUID DYNAMICS  

E-Print Network (OSTI)

LECTURES IN ELEMENTARY FLUID DYNAMICS: Physics, Mathematics and Applications J. M. McDonough Departments of Mechanical Engineering and Mathematics University of Kentucky, Lexington, KY 40506-0503 c 1987, 1990, 2002, 2004, 2009 #12;Contents 1 Introduction 1 1.1 Importance of Fluids

McDonough, James M.

184

Effective perfect fluids in cosmology  

SciTech Connect

We describe the cosmological dynamics of perfect fluids within the framework of effective field theories. The effective action is a derivative expansion whose terms are selected by the symmetry requirements on the relevant long-distance degrees of freedom, which are identified with comoving coordinates. The perfect fluid is defined by requiring invariance of the action under internal volume-preserving diffeomorphisms and general covariance. At lowest order in derivatives, the dynamics is encoded in a single function of the entropy density that characterizes the properties of the fluid, such as the equation of state and the speed of sound. This framework allows a neat simultaneous description of fluid and metric perturbations. Longitudinal fluid perturbations are closely related to the adiabatic modes, while the transverse modes mix with vector metric perturbations as a consequence of vorticity conservation. This formalism features a large flexibility which can be of practical use for higher order perturbation theory and cosmological parameter estimation.

Ballesteros, Guillermo [Museo Storico della Fisica e Centro Studi e Ricerche Enrico Fermi, Piazza del Viminale 1, I-00184 Rome (Italy); Bellazzini, Brando, E-mail: guillermo.ballesteros@unige.ch, E-mail: brando.bellazzini@pd.infn.it [Dipartimento di Fisica, Universitą di Padova and INFN, Sezione di Padova, Via Marzolo 8, I-35131 Padova (Italy)

2013-04-01T23:59:59.000Z

185

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents (OSTI)

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

186

oil-emulsion (rotary) drilling fluid  

Science Journals Connector (OSTI)

oil-emulsion (rotary) drilling fluid, oil-emulsion fluid [Used where low fluid-loss, very thin cake, and good lubrication of the drill pipe are of primary importance, such as in directional drilling ...

2014-08-01T23:59:59.000Z

187

oil-base(d) (rotary) drilling fluid  

Science Journals Connector (OSTI)

oil-base(d) (rotary) drilling fluid, oil-base(d) fluid [Used primarily for drilling-in or recomputing wells in formations subject ... with low formation pressures. See remark under “drilling fluid”] ...

2014-08-01T23:59:59.000Z

188

Lattice Boltzmann simulations of complex fluids  

Science Journals Connector (OSTI)

......research-article Articles Lattice Boltzmann simulations of complex fluids...OX1 3NP, UK We discuss how lattice Boltzmann simulations can be used to model...binary and lamellar fluids. lattice Boltzmann|complex fluids|shear flow......

J. M. YEOMANS; ALEXANDER J. WAGNER

2000-10-01T23:59:59.000Z

189

Multipurpose Acoustic Sensor for Downhole Fluid Monitoring  

Energy.gov (U.S. Department of Energy (DOE))

Novel sensor design based on acoustics. Determine in real-timeand in a single sensor packagemultiple parameters: temperature, pressure, fluid flow; and fluid properties, such as density, viscosity, fluid composition.

190

Finite element simulation of electrorheological fluids  

E-Print Network (OSTI)

Electrorheological (ER) fluids change their flow properties dramatically when an electric field is applied. These fluids are usually composed of dispersions of polarizable particles in an insulating base fluid or composed ...

Rhyou, Chanryeol, 1973-

2005-01-01T23:59:59.000Z

191

Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis  

Energy.gov (U.S. Department of Energy (DOE))

In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks.

192

E-Print Network 3.0 - automobile catalytic converters Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: automobile catalytic converters Page: << < 1 2 3 4 5 > >> 1 IEEE International Symposium on...

193

Catalytic ozonation of phenol in water with natural brucite and magnesia  

Science Journals Connector (OSTI)

Natural brucite and magnesia were applied as catalysts in catalytic ozonation of phenol in this work. It was found that both brucite and magnesia had remarkable accelerations on degradation of phenol and removal of COD in water. On this basis, effective and feasible routes for catalytic ozonation of phenol in water were proposed. The influence of initial pH value, radical scavengers and reaction temperature were investigated. The results revealed that there were different ozonation mechanisms in two systems: molecular ozone direct oxidation mechanism was proved in catalytic ozonation with brucite, and hydroxyl radical mechanism was demonstrated to play a main role in catalytic ozonation with magnesia.

Kun He; Yu Ming Dong; Zhen Li; Lin Yin; Ai Min Zhang; Yi Chun Zheng

2008-01-01T23:59:59.000Z

194

Catalytic microwave torrefaction and pyrolysis of Douglas fir pellet to improve biofuel quality .  

E-Print Network (OSTI)

??The aims of this dissertation were to understand the effects of torrefaction as pretreatment on biomass pyrolysis and catalytic pyrolysis for improving biofuel quality, and… (more)

[No author

2012-01-01T23:59:59.000Z

195

E-Print Network 3.0 - apparent catalytic site Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Yeshiva University Collection: Materials Science 11 Chemo-Mechanical Coupling in F1-ATPase Revealed by Catalytic Site Occupancy during Catalysis Summary: Chemo-Mechanical...

196

Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them  

DOE Patents (OSTI)

A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

Schwartz, Michael (Boulder, CO); White, James H. (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

2001-01-01T23:59:59.000Z

197

Atomic Hydrogen in Condensed Form Produced by a Catalytic Process:? A Future Energy-Rich Fuel?  

Science Journals Connector (OSTI)

Atomic Hydrogen in Condensed Form Produced by a Catalytic Process:? A Future Energy-Rich Fuel? ... Energy Fuels, 2005, 19 (6), ...

Shahriar Badiei; Leif Holmlid

2005-10-04T23:59:59.000Z

198

Problems in Catalytic Oxidation of Hydrocarbons and Detailed Simulation of Combustion Processes.  

E-Print Network (OSTI)

??This dissertation research consists of two parts, with Part I on the kinetics of catalytic oxidation of hydrocarbons and Part II on aspects on the… (more)

Xin, Yuxuan

2014-01-01T23:59:59.000Z

199

Production of high-octane gasoline on a semi-industrial catalytic reforming plant  

Science Journals Connector (OSTI)

Experiments have been carried out on the catalytic reforming at a pressure of 20 atm of a wide, straight-run gasoline fraction on an experimental industrial plant.

A. P. Fedorov; G. N. Maslyanskii…

1967-01-01T23:59:59.000Z

200

E-Print Network 3.0 - advanced catalytic materials--1996 Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ecology 44 Surface Science Perspectives The unhappy marriage of transition and noble metal atoms: A new Summary: to enhance catalytic activity? (A perspective on: When adding...

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Measurement of diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol  

Energy.gov (U.S. Department of Energy (DOE))

Evaluation and comparison of the measurements of diesel solid nanoparticle emissions using the European Particle Measurement Programme (PMP) system and catalytic stripper

202

New Tandem Catalytic Cycles take to the Rhod(ium) | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

New Tandem Catalytic Cycles take to the Rhod(ium) Light, combined with a novel rhodium catalyst, enables greener production of chemical feedstocks from biorenewables. A key...

203

Computational fluid dynamic applications  

SciTech Connect

The rapid advancement of computational capability including speed and memory size has prompted the wide use of computational fluid dynamics (CFD) codes to simulate complex flow systems. CFD simulations are used to study the operating problems encountered in system, to evaluate the impacts of operation/design parameters on the performance of a system, and to investigate novel design concepts. CFD codes are generally developed based on the conservation laws of mass, momentum, and energy that govern the characteristics of a flow. The governing equations are simplified and discretized for a selected computational grid system. Numerical methods are selected to simplify and calculate approximate flow properties. For turbulent, reacting, and multiphase flow systems the complex processes relating to these aspects of the flow, i.e., turbulent diffusion, combustion kinetics, interfacial drag and heat and mass transfer, etc., are described in mathematical models, based on a combination of fundamental physics and empirical data, that are incorporated into the code. CFD simulation has been applied to a large variety of practical and industrial scale flow systems.

Chang, S.-L.; Lottes, S. A.; Zhou, C. Q.

2000-04-03T23:59:59.000Z

204

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

1993-11-30T23:59:59.000Z

205

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, Mark D. (1426 Socastee Dr., North Augusta, SC 29841); Sweeney, Chad E. (3600 Westhampton Dr., Martinez, GA 30907-3036); Spangler, Jr., B. Samuel (2715 Margate Dr., Augusta, GA 30909)

1993-01-01T23:59:59.000Z

206

Fluid sampling system  

DOE Patents (OSTI)

An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to be decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank. 4 figs.

Houck, E.D.

1994-10-11T23:59:59.000Z

207

Tracing Geothermal Fluids  

SciTech Connect

Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

Michael C. Adams; Greg Nash

2004-03-01T23:59:59.000Z

208

Catalytic process for converting 2-oxazolidinones to their corresponding alkanolamines  

SciTech Connect

This invention provides a process for recovering alkanolamines, e.g. diisopropanolamine, from their corresponding cyclic reaction products (e.g., oxazolidinones), which products are the result of the reaction of CO/sub 2/ and the alkanolamine, a situation commonly encountered in acid gas removal processes employing the alkanolamines alone or in combination with other liquids such as sulfolane (tetrahydrothiophene-1,1 -dioxide). The process involves hydrolyzing the oxazolidinones in the presence of a small but catalytically effective amount of an amine, preferably from about 2 to 10 weight percent, based on 2-oxazolidinones. Preferably, the amine is the alkanolamine precursor of the corresponding 2-oxazolidinone.

Miller, A. E.

1985-04-30T23:59:59.000Z

209

Plasma-assisted catalytic ionization using porous nickel plate  

SciTech Connect

Hydrogen atomic pair ions, i.e., H{sup +} and H{sup -} ions, are produced by plasma-assisted catalytic ionization using a porous nickel plate. Positive ions in a hydrogen plasma generated by dc arc discharge are irradiated to the porous plate, and pair ions are produced from the back of the irradiation plane. It becomes clear that the production quantity of pair ions mainly depends on the irradiation current of positive ions and the irradiation energy affects the production efficiency of H{sup -} ions.

Oohara, W.; Maeda, T.; Higuchi, T. [Department of Electronic Device Engineering, Yamaguchi University, Ube 755-8611 (Japan)

2011-09-15T23:59:59.000Z

210

Development of a Sustainable Catalytic Ester Amidation Process  

Science Journals Connector (OSTI)

Development of a Sustainable Catalytic Ester Amidation Process ... In this paper, and as part of our ongoing interests in the advancement and uptake of green synthesis in a discovery chemistry setting,(17-19) we report our efforts to develop a significantly more sustainable process and demonstrate its applicability to the synthesis of a range of lead-like substrates. ... Overall, consideration of the isolated yields obtained with this new and sustainable coupling protocol indicates that the current method is an extremely viable alternative compared to the previously developed approach. ...

Nicola Caldwell; Craig Jamieson; Iain Simpson; Allan J. B. Watson

2013-07-30T23:59:59.000Z

211

Recent Advances in Catalytic Conversion of Ethanol to Chemicals  

SciTech Connect

With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

Sun, Junming; Wang, Yong

2014-04-30T23:59:59.000Z

212

Detachment Energies of Spheroidal Particles from Fluid-Fluid Interfaces  

E-Print Network (OSTI)

The energy required to detach a single particle from a fluid-fluid interface is an important parameter for designing certain soft materials, for example, emulsions stabilised by colloidal particles, colloidosomes designed for targeted drug delivery, and bio-sensors composed of magnetic particles adsorbed at interfaces. For a fixed particle volume, prolate and oblate spheroids attach more strongly to interfaces because they have larger particle-interface areas. Calculating the detachment energy of spheroids necessitates the difficult measurement of particle-liquid surface tensions, in contrast with spheres, where the contact angle suffices. We develop a simplified detachment energy model for spheroids which depends only on the particle aspect ratio and the height of the particle centre of mass above the fluid-fluid interface. We use lattice Boltzmann simulations to validate the model and provide quantitative evidence that the approach can be applied to simulate particle-stabilized emulsions, and highlight the experimental implications of this validation.

Gary B. Davies; Timm Krüger; Peter V. Coveney; Jens Harting

2014-07-01T23:59:59.000Z

213

Downhole Fluid Sampling | Open Energy Information  

Open Energy Info (EERE)

Downhole Fluid Sampling Downhole Fluid Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Downhole Fluid Sampling Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Water composition and source of fluids. Gas composition and source of fluids. Thermal: Water temperature. Distinguish magmatic/mantle heat inputs. Can be used to estimate reservoir fluid temperatures. Dictionary.png Downhole Fluid Sampling: Downhole fluid sampling is done to characterize the chemical, thermal, or hydrological properties of a surface or subsurface aqueous system. Downhole

214

Isotopic Analysis- Fluid | Open Energy Information  

Open Energy Info (EERE)

Isotopic Analysis- Fluid Isotopic Analysis- Fluid Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Isotopic Analysis- Fluid Details Activities (61) Areas (32) Regions (6) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Water rock interaction Stratigraphic/Structural: Hydrological: Origin of hydrothermal fluids; Mixing of hydrothermal fluids Thermal: Isotopic ratios can be used to characterize and locate subsurface thermal anomalies. Dictionary.png Isotopic Analysis- Fluid: Isotopes are atoms of the same element that have different numbers of neutrons. An isotopic analysis looks at a particular isotopic element(s) in

215

Gel Evolution in Oil Based Drilling Fluids.  

E-Print Network (OSTI)

?? Drilling fluids make up an essential part of the drilling operation. Successful drilling operations rely on adequate drilling fluid quality. With the development of… (more)

Sandvold, Ida

2012-01-01T23:59:59.000Z

216

Shale Gas Development Challenges: Fracture Fluids | Department...  

Office of Environmental Management (EM)

Fluids Shale Gas Development Challenges: Fracture Fluids More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary FracFocus 2.0 Task Force...

217

Chemically Reactive Working Fluids | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chemically Reactive Working Fluids for the Capture and Transport of Concentrated Solar Thermal Energy for Power Generation Chemically Reactive Working Fluids SunShot CSP...

218

Acoustic Concentration Of Particles In Fluid Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. Available for thumbnail of...

219

Fluid Gravity Engineering Rocket motor flow analysis  

E-Print Network (OSTI)

Fluid Gravity Engineering Capability Ā· Rocket motor flow analysis -Internal (performance) -External young scientists/engineers Fluid Gravity Engineering Ltd #12;

Anand, Mahesh

220

NETL: Releases & Briefs - MFIX: Particle-fluid flow modeling, fast and free  

NLE Websites -- All DOE Office Websites (Extended Search)

MFIX: Particle-fluid Flow Modeling, Fast and Free MFIX: Particle-fluid Flow Modeling, Fast and Free Until recently, full solution of the complex set of equations that describe gas-particle flows was nearly impossible. But an open-source code developed by researchers at the National Energy Technology Laboratory (NETL), and designed to run on inexpensive PC (Beowulf) clusters, makes it relatively simple. Called MFIX (Multi-phase Flow with Interphase eXchange), the code incorporates special numerical techniques that provide an efficient solution to the coupled equations, exceeding the capabilities of commercial software. Originally developed at NETL to model fixed, fluidized and bubbling coal gasification technologies, its power has been used in research ranging from catalytic cracking in oil refineries to volcanology. A free, fully-functional version is available at www.mfix.org

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Fluid Imaging | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit History Facebook icon Twitter icon Ā» Fluid Imaging Jump to: navigation, search Contents 1 Geothermal Lab Call Projects for Fluid Imaging 2 Geothermal ARRA Funded Projects for Fluid Imaging Geothermal Lab Call Projects for Fluid Imaging Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":14,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

222

Bio-inspired fluid locomotion  

E-Print Network (OSTI)

We have developed several novel methods of locomotion at low Reynolds number, for both Newtonian and non-Newtonian fluids: Robosnails 1 and 2, which operate on a lubrication layer, and the three-link swimmer which moves ...

Chan, Brian, 1980-

2009-01-01T23:59:59.000Z

223

Self-similar perfect fluids  

E-Print Network (OSTI)

Space-times admitting an $r$-parameter Lie group of homotheties are studied for $r > 2$ devoting a special attention to those representing perfect fluid solutions to Einstein's field equations.

J. Carot; A. M. Sintes

2000-05-16T23:59:59.000Z

224

Biocatalytic transformations of hydrothermal fluids  

Science Journals Connector (OSTI)

...emission into oxygenated ambient seawater. The large metabolic and physiological...emission into oxygenated ambient seawater. The large metabolic and physiological...DNA (the reproducing genetic storage for each species), individual...where entrained oxygenated seawater mixes with hydrothermal fluid...

1997-01-01T23:59:59.000Z

225

Atomistic methods in fluid simulation  

Science Journals Connector (OSTI)

...easily describable by traditional methods, as ICF involves a complex coupling between fluid instabilities and combustion processes at very small length and times scales. One contribution of 13 to a Theme Issue Turbulent mixing and beyond . Figure...

2010-01-01T23:59:59.000Z

226

Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum  

SciTech Connect

Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

Cho, P.; Law, C.K.

1986-11-01T23:59:59.000Z

227

Catalytic combustor for integrated gasification combined cycle power plant  

DOE Patents (OSTI)

A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

2008-12-16T23:59:59.000Z

228

Coupling of kinetic Monte Carlo simulations of surface reactions to transport in a fluid for heterogeneous catalytic reactor modeling  

SciTech Connect

We have developed a method to couple kinetic Monte Carlo simulations of surface reactions at a molecular scale to transport equations at a macroscopic scale. This method is applicable to steady state reactors. We use a finite difference upwinding scheme and a gap-tooth scheme to efficiently use a limited amount of kinetic Monte Carlo simulations. In general the stochastic kinetic Monte Carlo results do not obey mass conservation so that unphysical accumulation of mass could occur in the reactor. We have developed a method to perform mass balance corrections that is based on a stoichiometry matrix and a least-squares problem that is reduced to a non-singular set of linear equations that is applicable to any surface catalyzed reaction. The implementation of these methods is validated by comparing numerical results of a reactor simulation with a unimolecular reaction to an analytical solution. Furthermore, the method is applied to two reaction mechanisms. The first is the ZGB model for CO oxidation in which inevitable poisoning of the catalyst limits the performance of the reactor. The second is a model for the oxidation of NO on a Pt(111) surface, which becomes active due to lateral interaction at high coverages of oxygen. This reaction model is based on ab initio density functional theory calculations from literature.

Schaefer, C.; Jansen, A. P. J. [Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

2013-02-07T23:59:59.000Z

229

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

230

Production of renewable jet fuel range alkanes and commodity chemicals from integrated catalytic  

E-Print Network (OSTI)

, carbohydrate hydrolysis and dehydration, and catalytic upgrading of platform chemicals. The technology centersProduction of renewable jet fuel range alkanes and commodity chemicals from integrated catalytic and subsequently upgrading these two platforms into a mixture of branched, linear, and cyclic alkanes of molecular

California at Riverside, University of

231

Evolution of Domain Architectures and Catalytic Functions of Enzymes in Metabolic Systems  

E-Print Network (OSTI)

Evolution of Domain Architectures and Catalytic Functions of Enzymes in Metabolic Systems Summit architectures and catalytic functions of enzymes constitute the centerpieces of a metabolic network. These types. In contrast, prokaryotic enzymes become more versatile by catalyzing multiple reactions with similar chemical

Yeang, Chen-Hsiang

232

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1  

E-Print Network (OSTI)

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Ghosh3 , Huei Peng2 Abstract A fuel processor that reforms natural gas to hydrogen-rich mixture to feed of the hydrogen in the fuel processor is based on catalytic partial oxidation of the methane in the natural gas

Peng, Huei

233

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors  

Science Journals Connector (OSTI)

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors ... For safety and environmental protection reasons (to avoid syngas release into the atmosphere), after the analysis section, the reacted gas stream was completely oxidized by forced air in a catalytic honeycomb burner (Figure 2). ...

S. Specchia; L. D. Vella; B. Lorenzut; T. Montini; V. Specchia; P. Fornasiero

2009-07-22T23:59:59.000Z

234

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes  

E-Print Network (OSTI)

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes M Growth of carbon nanotubes during transition-metal particles catalytically-assisted thermal decomposition of various nanotube surface and edge reactions (e.g. adsorption of hydrocarbons and hydrogen onto the surface

Grujicic, Mica

235

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application  

E-Print Network (OSTI)

, the mixture temperature at the combustor inlet is set to 630 o C. Thermal conductivity of the ceramic wall Keywords: Catalytic combustion, Pd/nano-porous alumina, Ceramic tape casting, Thermophotovoltaic Abstract: A micro-scale catalytic combustor using high-precision ceramic tape-casting technology has been developed

Kasagi, Nobuhide

236

Catalytic study of SOFC electrode materials in engine exhaust gas Pauline Briaulta  

E-Print Network (OSTI)

cathode materials, besides LSCF demonstrated a lower catalytic activity towards hydrocarbon partial corresponding to a composition of exhaust gas. A screening of four cathode materials was done, some well selected as the electrolyte material. Chemical stability tests and catalytic activity studies in the gas

Paris-Sud XI, UniversitƩ de

237

Catalytic Conversion of Ethanol to Hydrogen Using Combinatorial Shici Duan and Selim Senkan*  

E-Print Network (OSTI)

the single component catalytic materials explored. Introduction Due to their high energy conversionCatalytic Conversion of Ethanol to Hydrogen Using Combinatorial Methods Shici Duan and Selim Senkan using a feed gas composition of 2% C2H5OH and 12% H2O in a helium carrier gas. This systematic

Senkan, Selim M.

238

Engineering a Unimolecular DNA-Catalytic Probe for Single Lead Ion Monitoring  

E-Print Network (OSTI)

Engineering a Unimolecular DNA-Catalytic Probe for Single Lead Ion Monitoring Hui Wang, Youngmi Kim reactions. These catalytic DNAs, or DNAzymes, can be activated by metal ions. In this paper, we take advantage of DNA molecular engineering to improve the properties of DNAzymes by designing a unimolecular

Tan, Weihong

239

Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik Bruus  

E-Print Network (OSTI)

Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying the reactor using a high-level implementation of topology optimization. DOI: 10.1103/PhysRevE.75.016301 PACS

240

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An...  

NLE Websites -- All DOE Office Websites (Extended Search)

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR Study. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR...

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Transparent fluids for 157-nm immersion lithography  

E-Print Network (OSTI)

- gineers. [DOI: 10.1117/1.1637366] Subject terms: 157-nm lithography; immersion fluid; perfluoropolyether

Rollins, Andrew M.

242

Pitch-catch only ultrasonic fluid densitometer  

DOE Patents (OSTI)

The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

Greenwood, Margaret S. (Richland, WA); Harris, Robert V. (Pasco, WA)

1999-01-01T23:59:59.000Z

243

Pitch-catch only ultrasonic fluid densitometer  

DOE Patents (OSTI)

The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

Greenwood, M.S.; Harris, R.V.

1999-03-23T23:59:59.000Z

244

Fluid Mechanics IB Lecturer: Dr Natalia Berloff  

E-Print Network (OSTI)

-efficient aircraft design, hydroelectric power, chemical processing, jet-driven cutting tools Ā· our fluid environment

245

Microsoft Word - 41891_SWPC_Catalytic Combustor_Factsheet_Rev01_04-24.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC 891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC Facts Sheet: Catalytic Combustor for Fuel Flexible Gas Turbine (DE-FC26-03NT41891) I. PROJECT PARTICIPANTS A. Siemens Westinghouse Power Corporation B. Caterpillar/Solar Turbine C. Penn State University D. Southern Company Services II. PROJECT DESCRIPTION A. Objective: To develop and demonstrate a cost effective, fuel flexible (syngas/natural gas) catalytic combustor that will achieve ultra low NOx emissions (2ppm) at the exit of the gas turbine and without the use of backend cleanup in Integrated Gasification Combined Cycle (IGCC) application. B. Background/Relevancy 1. Background: Catalytic combustion has been shown to achieve lowest emissions in conventional gas turbine application (natural gas only). Available technical data indicate that it can be effective

246

DEVELOPMENT OF NEW DRILLING FLUIDS  

SciTech Connect

The goal of the project has been to develop new types of drill-in fluids (DIFs) and completion fluids (CFs) for use in natural gas reservoirs. Phase 1 of the project was a 24-month study to develop the concept of advanced type of fluids usable in well completions. Phase 1 tested this concept and created a kinetic mathematical model to accurately track the fluid's behavior under downhole conditions. Phase 2 includes tests of the new materials and practices. Work includes the preparation of new materials and the deployment of the new fluids and new practices to the field. The project addresses the special problem of formation damage issues related to the use of CFs and DIFs in open hole horizontal well completions. The concept of a ''removable filtercake'' has, as its basis, a mechanism to initiate or trigger the removal process. Our approach to developing such a mechanism is to identify the components of the filtercake and measure the change in the characteristics of these components when certain cleanup (filtercake removal) techniques are employed.

David B. Burnett

2003-08-01T23:59:59.000Z

247

Coal hydrogenation and deashing in ebullated bed catalytic reactor  

DOE Patents (OSTI)

An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

1983-01-01T23:59:59.000Z

248

Development of a Methane Premixed Catalytic Burner for Household Applications  

Science Journals Connector (OSTI)

The catalytic combustion of methane is currently investigated in a variety of international research programs, thanks to its numerous potential applications (e.g., boilers, process heaters, reciprocating engines, gas-turbine cycles, etc.). ... At low surface heat powers (Q) and excesses of air (Ea), the combustion mostly occurs in a thin layer within the permeable panel (radiant or flameless regime, Figure 1b); the burner outlet surface (burner deck) reaches temperatures varying from 700 to 900 °C, depending on both Q and Ea values, and glows flamelessly. ... The goal is to assemble a boiler capable of coping with variable hot water requests:? from about 2?3 kW (160?240 kW/m2) for apartment heating up to 25 kW (2000 kW/m2) for sanitary purposes, so as to produce hot water with time delays compatible with the users' comfort. ...

Isotta Cerri; Guido Saracco; Francesco Geobaldo; Vito Specchia

2000-01-04T23:59:59.000Z

249

Tantalum pillard montmorillonite: II. Acidic and catalytic properties  

SciTech Connect

The acidic and catalytic properties of a series of Ta-PILCs synthesized with a different initial tantalum content were characterized by adsorption of gaseous probe molecules (TPD of ammonia and FTIR spectra of absorbed pyridine) and by the test reaction of 1-butanol dehydration. A large increase of acidity was noted in Ta-PILCs compared to Na-montmorillonite or tantalum oxide. Cross-linking pillars and silica layers of the clay induce stronger Lewis and new Bronsted sites. The lack of basic sites formation is evidenced by the dehydration of 1-butanol to butene selectivity (100%). The incorporation of the tantalum oxide between the montmorillonite sheets produce, within Ta-PILC, acid centers of the same nature as observed for the silicon-tantalum mixed oxides. 32 refs., 4 figs., 5 tabs.

Guiu, G.; Grange, P. [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)] [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)

1997-06-01T23:59:59.000Z

250

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

251

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

252

Treating isopropyl alcohol by a regenerative catalytic oxidizer  

Science Journals Connector (OSTI)

Regenerative catalytic oxidizer (RCO) can be conveniently used to control emissions of volatile organic compounds (VOCs), because of their thermal recovery efficiency (TRE), low fuel cost and high oxidation. In this work, catalysts with various metal weight loadings were prepared by deposition–precipitation, wet impregnation and incipient impregnation to treat isopropyl alcohol (IPA). We used the excellent catalytic performance in a pilot RCO to test IPA oxidation performance under various conditions. The best catalyst was selected and its TRE, bed temperature variations, pressure drops and selectivity of the catalyst were more widely discussed. The results demonstrate that the optimal catalyst was prepared by wet impregnation with 20 wt.% metal on ceramic honeycomb (CH). 20 wt.% Cu–Co/(CH) catalyst was the best catalyst used in a RCO because it was effective in treating IPA, with a CO2 yield of up to 95% at a heating zone temperature (Tset) = 400 °C under various conditions. It also had the largest tolerance of variations in inlet IPA concentration and gas velocity (Ug). This 20 wt.% Cu–Co/(CH) catalyst in a RCO performed well in terms of TRE, pressure drop and selectivity to CO2. The TRE range in a RCO was from 87.8 to 91.2% under various conditions, and decreased as Ug increased in a fixed Tset. The pressure drop increased with Ug and Tset. The selectivity to CO2 increased to over 95% at 300 °C, and that to propene remained at 2–5% from 200 to 400 °C. Finally, the stability test results indicated that the 20 wt.% Cu–Co/(CH) catalyst was very stable at various CO2 yields and temperatures.

Jie-Chung Lou; Shih-Wei Huang

2008-01-01T23:59:59.000Z

253

Viscosity of a nucleonic fluid  

E-Print Network (OSTI)

The viscosity of nucleonic matter is studied both classically and in a quantum mechanical description. The collisions between particles are modeled as hard sphere scattering as a baseline for comparison and as scattering from an attractive square well potential. Properties associated with the unitary limit are developed which are shown to be approximately realized for a system of neutrons. The issue of near perfect fluid behavior of neutron matter is remarked on. Using some results from hard sphere molecular dynamics studies near perfect fluid behavior is discussed further.

Aram Z. Mekjian

2012-03-21T23:59:59.000Z

254

Compressor bleed cooling fluid feed system  

DOE Patents (OSTI)

A compressor bleed cooling fluid feed system for a turbine engine for directing cooling fluids from a compressor to a turbine airfoil cooling system to supply cooling fluids to one or more airfoils of a rotor assembly is disclosed. The compressor bleed cooling fluid feed system may enable cooling fluids to be exhausted from a compressor exhaust plenum through a downstream compressor bleed collection chamber and into the turbine airfoil cooling system. As such, the suction created in the compressor exhaust plenum mitigates boundary layer growth along the inner surface while providing flow of cooling fluids to the turbine airfoils.

Donahoo, Eric E; Ross, Christopher W

2014-11-25T23:59:59.000Z

255

,"Catalytic Reforming Downstream Processing of Fresh Feed Input"  

U.S. Energy Information Administration (EIA) Indexed Site

Catalytic Reforming Downstream Processing of Fresh Feed Input" Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","9/2013","1/15/2010" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_dwns_a_(na)_ydr_mbblpd_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_dwns_a_(na)_ydr_mbblpd_m.htm" ,"Source:","Energy Information Administration"

256

Bio-Oil Separation and Stabilization by Supercritical Fluid Fractionation – 2014 Final Report  

SciTech Connect

The objective of this project is to use supercritical fluids to separate and fractionate algal-based bio-oils into stable products that can be subsequently upgraded to produce drop-in renewable fuels. To accomplish this objective, algae was grown and thermochemically converted to bio-oils using hydrothermal liquefaction (HTL), pyrolysis, and catalytic pyrolysis. The bio-oils were separated into an extract and a raffinate using near-critical propane or carbon dioxide. The fractions were then subjected to thermal aging studies to determine if the extraction process had stabilized the products. It was found that the propane extract fraction was twice as stable as the parent catalytic pyrolysis bio-oils as measured by the change in viscosity after two weeks of accelerated aging at 80°C. Further, in-situ NMR aging studies found that the propane extract was chemically more stable than the parent bio-oil. Thus the milestone of stabilizing the product was met. A preliminary design of the extraction plant was prepared. The design was based on a depot scale plant processing 20,000,000 gallons per year of bio-oil. It was estimated that the capital costs for such a plant would be $8,700,000 with an operating cost of $3,500,000 per year. On a per gallon of product cost and a 10% annual rate of return, capital costs would represent $0.06 per gallon and operating costs would amount to $0.20 per gallon. Further, it was found that the energy required to run the process represented 6.2% of the energy available in the bio-oil, meeting the milestone of less than 20%. Life cycle analysis and greenhouse gas (GHG) emission analysis found that the energy for running the critical fluid separation process and the GHG emissions were minor compared to all the inputs to the overall well to pump system. For the well to pump system boundary, energetics in biofuel conversion are typically dominated by energy demands in the growth, dewater, and thermochemical process. Bio-oil stabilization by near critical propane extraction had minimal impact in the overall energetics of the process with NER contributions of 0.03. Based on the LCA, the overall conversion pathways were found to be energy intensive with a NER of about 2.3 and 1.2 for catalytic pyrolysis and HTL, respectively. GHG emissions for the catalytic pyrolysis process were greater than that of petroleum diesel at 210 g CO2 eq compared to 18.9 g CO2 eq. Microalgae bio-oil based diesel with thermochemical conversion through HTL meets renewable fuel standards with favorable emission reductions of -10.8 g CO2 eq. The importance of the outcomes is that the critical fluid extraction and stabilization process improved product stability and did so with minimal energy inputs and processing costs. The LCA and GHG emission calculations point toward the HTL pathway as the more favorable thermochemical route towards upgrading algae to bio-fuels. Since the quality of the HTL oil was significantly lower than that of the catalytic pyrolysis bio-oil, the next steps point toward improving the quality of the HTL oils from algae biomass and focusing the critical fluid stabilization on that bio-oil product.

Foster Agblevor; Lucia Petkovic; Edward Bennion; Jason Quinn; John Moses; Deborah Newby; Daniel Ginosar

2014-03-01T23:59:59.000Z

257

Directed flow fluid rinse trough  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs.

Kempka, Steven N. (9504 Lona La., Albuquerque, NM 87111); Walters, Robert N. (11872 LaGrange St., Boise, ID 83709)

1996-01-01T23:59:59.000Z

258

Directed flow fluid rinse trough  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs. 9 figs.

Kempka, S.N.; Walters, R.N.

1996-07-02T23:59:59.000Z

259

Working fluid for Rankine cycle  

SciTech Connect

A Rankine cycle working fluid is disclosed containing a mixture of 2,2,3,3tetrafluoropropanol and water, which is low toxic, incombustible, nonexplosive, noncorrosive and stable, and also has a high critical temperature and forms azeotropic-like composition. It is suited for use in a rankine cycle using heat source of low temperature.

Aomi, H.; Enjo, N.

1980-11-11T23:59:59.000Z

260

Inverse Fluid Convection Problems in Enclosures  

E-Print Network (OSTI)

Efficiency, security, and reliability of industrial and domestic processes essentially depend on the deep understanding of their actual processes of fluid flow and heat transfer. Actual processes of fluid flow control and ...

Zhao, Fu-Yun

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

CRITICALITY CURVES FOR PLUTONIUM HYDRAULIC FLUID MIXTURES  

SciTech Connect

This Calculation Note performs and documents MCNP criticality calculations for plutonium (100% {sup 239}Pu) hydraulic fluid mixtures. Spherical geometry was used for these generalized criticality safety calculations and three geometries of neutron reflection are: {sm_bullet}bare, {sm_bullet}1 inch of hydraulic fluid, or {sm_bullet}12 inches of hydraulic fluid. This document shows the critical volume and critical mass for various concentrations of plutonium in hydraulic fluid. Between 1 and 2 gallons of hydraulic fluid were discovered in the bottom of HA-23S. This HA-23S hydraulic fluid was reported by engineering to be Fyrquel 220. The hydraulic fluid in GLovebox HA-23S is Fyrquel 220 which contains phosphorus. Critical spherical geometry in air is calculated with 0 in., 1 in., or 12 inches hydraulic fluid reflection.

WITTEKIND WD

2007-10-03T23:59:59.000Z

262

Engine with a solid working fluid  

Science Journals Connector (OSTI)

... fluids: the fluid may be steam, petrol vapour/air mixture or air (in the Stirling engine), but all depend on cycles involving simultaneous changes of temperature and pressure. Now ...

Robert W. Cahn

1975-05-22T23:59:59.000Z

263

Fluid sampling system for a nuclear reactor  

DOE Patents (OSTI)

A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

Lau, Louis K. (Monroeville, PA); Alper, Naum I. (Monroeville, PA)

1994-01-01T23:59:59.000Z

264

Specialized Materials and Fluids and Power Plants  

Energy.gov (U.S. Department of Energy (DOE))

Below are the project presentations and respective peer review results for Specialized Materials and Fluids and Power Plants.

265

Supercritical Fluid Attachment of Palladium Nanoparticles on...  

NLE Websites -- All DOE Office Websites (Extended Search)

Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Supercritical Fluid Attachment of Palladium Nanoparticles on Aligned Carbon Nanotubes. Abstract: Nanocomposite...

266

Fluid Interface Reactions, Structures and Transport  

NLE Websites -- All DOE Office Websites (Extended Search)

fluid by local bond relaxation, charge redistribution, dissolution, precipitation, sorption and porosity developmentdestruction. Heretofore, interfaces have been described...

267

Geek-Up[3.18.2011]: Catalytically Active Material and BELLA | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8.2011]: Catalytically Active Material and BELLA 8.2011]: Catalytically Active Material and BELLA Geek-Up[3.18.2011]: Catalytically Active Material and BELLA March 18, 2011 - 3:54pm Addthis PNNL scientists Grant Johnson and Julia Laskin | Photo Courtesy of the Pacific Northwest National Laboratory PNNL scientists Grant Johnson and Julia Laskin | Photo Courtesy of the Pacific Northwest National Laboratory Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What are the key facts? PNL researchers produced catalytically active material that may help advance fuel cell and solar energy storage applications. In just one meter a single BELLA stage -- with a "boosted-frame" method -- will accelerate an electron beam to 10 billion electron volts. Thanks to an innovative approach from Pacific Northwest National Laboratory

268

Catalytic Hydrodeoxygenation of Methyl-Substituted Phenols: Correlations of Kinetic Parameters with Molecular Properties  

E-Print Network (OSTI)

. Introduction As a result of increasing environmental concerns, catalytic hydrotreating has become an important, oil shale, and tar sands would render the hydrotreating of oxygen-containing com- pounds, mostly

Simons, Jack

269

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

NLE Websites -- All DOE Office Websites (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

270

Thermally Coupled Catalytic Reactor for Steam Reforming of Methane and Liquid Hydrocarbons: Experiment and Mathematical Modeling  

Science Journals Connector (OSTI)

An energy-efficient catalytic reactor for producing synthesis gas from methane and liquid hydrocarbons is proposed that is ... on the coupling of an endothermic reaction (steam reforming of methane, hexane, or is...

V. A. Kirillov; N. A. Kuzin; A. V. Kulikov…

2003-05-01T23:59:59.000Z

271

Chemical-Catalytic Approaches to the Production of Furfurals and Levulinates from Biomass  

Science Journals Connector (OSTI)

The synthesis and chemistry of 5-(hydroxymethyl)furfural (HMF), 5-(chloromethyl)furfural (CMF), ... levulinic acid (LA), three carbohydrate-derived platform molecules produced by the chemical-catalytic processing...

Mark Mascal; Saikat Dutta

2014-01-01T23:59:59.000Z

272

Center for Catalytic Science and Technology Recent Highlights from the Center for  

E-Print Network (OSTI)

for Catalytic Science and Technology CCST Research Areas Electrocatalysts and hydrogen processing for PEM fuel cells Selective oxidation and selective hydrogenation Biomass to fuels and chemicals phosphates prepared in ionic liquids A straightforward, cost-effective and scalable synthesis

Firestone, Jeremy

273

Catalytic Conversion of Tars, Carbon Black and Methane from Pyrolysis/Gasification of Biomass  

Science Journals Connector (OSTI)

The use of catalysts in biomass gasification has been suggested for a long time.1 Fung and Graham found that potassium carbonate and calcium oxide have catalytic influences on the gasification rate and the produc...

Clas Ekström; Nils Lindman; Rune Pettersson

1985-01-01T23:59:59.000Z

274

Catalytic Activity of Alkali Metals on the Thermochemical Conversion of Biomass Materials  

Science Journals Connector (OSTI)

The first reaction in the thermal decomposition of cellulose is very sensitive to the existence of mineral impurities such as alkali metals and iron at concentrations as low as 0.5%. The catalytic reaction app...

Mahmood M. Barbooti

1986-01-01T23:59:59.000Z

275

E-Print Network 3.0 - atp catalytic domain Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

domain Search Powered by Explorit Topic List Advanced Search Sample search results for: atp catalytic domain Page: << < 1 2 3 4 5 > >> 1 Encyclopedia of Molecular Biology Thomas E....

276

E-Print Network 3.0 - atp catalytic cycle Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

cycle Search Powered by Explorit Topic List Advanced Search Sample search results for: atp catalytic cycle Page: << < 1 2 3 4 5 > >> 1 Encyclopedia of Molecular Biology Thomas E....

277

CO-CATALYTIC ABSORPTION LAYERS FOR CONTROLLED LASER-INDUCED CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES  

E-Print Network (OSTI)

The concept of co-catalytic layer structures for controlled laser-induced chemical vapor deposition of carbon nanotubes is established, in which a thin Ta support layer chemically aids the initial Fe catalyst reduction. This enables a significant...

Michaelis, F.B.; Weatherup, R.S.; Bayer, B.C.; Bock, M.C.D; Sugime, H.; Caneva, S.; Robertson, J.; Baumberg, J.J.; Hofmann, S.

2014-02-24T23:59:59.000Z

278

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents (OSTI)

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

279

Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural, levulinic acid, and lactic acid  

Science Journals Connector (OSTI)

The catalytic transformation of cellulose into key building-block or platform chemicals such as 5-hydoxymethylfurfural (HMF), levulinic acid, and lactic acid under mild conditions, has attracted much attention...

Weiping Deng; Qinghong Zhang; Ye Wang

2014-12-01T23:59:59.000Z

280

Catalytic converter applications for two stroke, spark-ignited marine engines  

SciTech Connect

When catalytic converters are used for cleansing of exhaust gas from two-stroke marine engines, new issues must be brought up in combination with prior technology. Therefore, a study was made of V6, 2600cc engine having a large volume of hydrocarbon emissions with respect to three issues: (1) To what degree seawater effects catalytic converter performance and possible countermeasures; (2) Effects attained on cleansing level and catalyst temperature; (3) Finding abatement levels for catalyst deterioration and exhaust emission output in the marine mode. It was found that physical adsorption was a significant factor in catalytic degradation resulting from direct contact with seawater. The cleansing levels obtained when a marine engine is equipped with a catalyst converter were found by clarifying the extent of effects of catalyst volume, performance and temperature. The reduction obtained in exhaust emission allowing for a deterioration factor, is shown in a catalytic converter heated to the maximum temperature of 960 C.

Fujimoto, Hiroaki; Isogawa, Atsushi; Matsumoto, Naoto

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

A resource recycling technique of hydrogen production from the catalytic degradation of organics in wastewater  

Science Journals Connector (OSTI)

A resource recycling technique of hydrogen production from the catalytic degradation of organics in wastewater by aqueous phase reforming (APR) has...N,N-dimethylformamide (DMF) and cyclohexanol) in water could b...

XiaoNian Li; LingNiao Kong; YiZhi Xiang; YaoMing Ju…

2008-11-01T23:59:59.000Z

282

Effects of copper catalytic reactions on the development of supersonic hydrogen flames  

SciTech Connect

Copper species are present in hydrogen flames in arc heated supersonic ramjet testing facilities. Homogeneous and heterogeneous copper catalytic reactions may affect the flame development by enhancing the recombination of hydrogen atoms. Computer simulation is used to investigate the effects of the catalytic reactions on the reaction and ignition times of the flames. The simulation uses a modified general chemical kinetics computer program to simulate the development of copper-contaminated hydrogen flames under scramjet testing conditions. Reaction times of hydrogen flames are found to be reduced due to the copper catalytic effects, but ignition times are much less sensitive to such effects. The reduction of reaction time depends on copper concentration, particle size (if copper is in the condensed phase), and Mach number (or initial temperature and pressure). As copper concentration increases or the particle size decreases, reaction time decreases. As Mach number increases (or pressure and temperature decrease), the copper catalytic effects are greater.

Chang, S.L.; Lottes, S.A.; Berry, G.F.

1992-10-01T23:59:59.000Z

283

Catalytic steam gasification of carbon: Final report, 3/1/84-2/28/87  

SciTech Connect

Work for this grant period covers two areas: formation of coke on the platinum surface of reforming catalysts, and the preparation, surface reactivity, and catalytic activity of high specific surface area molybdenum and tungsten carbides.

Boudart, M.

1987-01-01T23:59:59.000Z

284

E-Print Network 3.0 - active catalytic sites Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

interface to the active site andor a macromolecular substrate-binding site.21... (IXegf1)a-TF. The active site is depicted by superimposing the catalytic domains of the nal...

285

E-Print Network 3.0 - acrylamide catalytically inhibits Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

for non-commercial research and Summary: that ADP was not essential suggesting that MgVi-F1 complex inhibited the catalytic activity to the same... :www.elsevier.comcopyright...

286

Comparison of Gas Catalytic and Electric Infrared Performance for Industrial Applications  

E-Print Network (OSTI)

A study was conducted to evaluate the performance of gas catalytic and electric infrared for industrial applications. The project focused on fabric drying, paper drying, metal heating, and plastic forming as target industrial applications. Tests...

Eshraghi, R. R.; Welch, D. E.

287

E-Print Network 3.0 - advanced catalytic science Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

science Search Powered by Explorit Topic List Advanced Search Sample search results for: advanced catalytic science Page: << < 1 2 3 4 5 > >> 1 Synthesis of single-walled carbon...

288

Biomass gasification using a horizontal entrained-flow gasifier and catalytic processing of the product gas.  

E-Print Network (OSTI)

??A novel study on biomass-air gasification using a horizontal entrained-flow gasifier and catalytic processing of the product gas has been conducted. The study was designed… (more)

Legonda, Isack Amos

2012-01-01T23:59:59.000Z

289

Natural catalytic activity in a marine shale for generating natural gas  

Science Journals Connector (OSTI)

...natural catalytic activity in marine shales. Gas is generated at ambient temperatures...differences are in degree. Mowry shale generates gas compositions that are quite different...probably a major source of natural gas. Mowry shale generates gas at thermodynamic...

2010-01-01T23:59:59.000Z

290

Application of a cw quantum cascade laser CO2 analyser to catalytic oxidation reaction monitoring  

Science Journals Connector (OSTI)

Catalytic oxidation reaction monitoring has been performed for the first time with a trace gas carbon dioxide analyser based on a continuous wave (cw), thermoelectrically cooled (TEC), distributed feedback (DFB)

V. L. Kasyutich; D. Poulidi; M. Jalil; I. S. Metcalfe; P. A. Martin

2013-02-01T23:59:59.000Z

291

Regional catalytic economic impacts and noise-damage costs of aviation growth  

E-Print Network (OSTI)

There is growing recognition that transportation or infrastructure improvements can have longer-term catalytic impacts economic productivity, which are in addition to the direct, indirect, or induced household spending ...

Tam, Ryan Aung Min, 1973-

2008-01-01T23:59:59.000Z

292

Activation energy of ignition for catalytic oxidation of ethanol in oscillatory regime  

Science Journals Connector (OSTI)

Activation energies of ignition for the thermokinetic oscillations obtained during the heterogeneous catalytic oxidation of ethanol on Pd/Al2O3...in a dynamic calorimeter were obtained using the minimum values of...

N. I. Ionescu; N. I. Jaeger; P. J. Plath…

2008-02-01T23:59:59.000Z

293

NMR Sensor for Onboard Ship Detection of Catalytic Fines in Marine Fuel Oils  

Science Journals Connector (OSTI)

NMR Sensor for Onboard Ship Detection of Catalytic Fines in Marine Fuel Oils ... Vermeire, M. B. Everything You Need to Know About Marine Fuels; Chevron Global Marine Products: Ghent, Belgium, 2007. ...

Morten K. Sųrensen; Mads S. Vinding; Oleg N. Bakharev; Tomas Nesgaard; Ole Jensen; Niels Chr. Nielsen

2014-07-02T23:59:59.000Z

294

Study of biomass combustion characteristics for the development of a catalytic combustor/gasifier.  

E-Print Network (OSTI)

??The research reported here explored, a "new" approach to biomass energy conversion for small-scale process heat-applications. The conversion process uses close-coupled catalytic. combustion to burn… (more)

Dody, Joseph W.

2012-01-01T23:59:59.000Z

295

Physicochemical and catalytic properties of iron- and indium-containing zeolites  

Science Journals Connector (OSTI)

The influence of the preparation procedure of Fe- and In-containing zeolites on their physicochemical and catalytic properties in methanol conversion to hydrocarbons and the upgrading of the straight-run gasoline

L. M. Velichkina; L. L. Korobitsyna; B. Ulzii; A. V. Vosmerikov…

2013-03-01T23:59:59.000Z

296

Diesel emission control: Catalytic filters for particulate removal  

Science Journals Connector (OSTI)

The European diesel engine industry represents a vital sector across the Continent, with more than 2 million direct work positions and a turnover of over 400 billion Euro. Diesel engines provide large paybacks to society since they are extensively used to transport goods, services and people. In recent years increasing attention has been paid to the emissions from diesel engines which, like gasoline engine emissions, include carbon monoxide (CO), hydrocarbons (HC) and oxides of nitrogen (NOx). Diesel engines also produce significant levels of particulate matter (PM), which consists mostly of carbonaceous soot and a soluble organic fraction (SOF) of hydrocarbons that have condensed on the soot.Meeting the emission levels imposed for NOx and PM by legislation (Euro IV in 2005 and, in the 2008 perspective, Euro V) requires the development of a number of critical technologies to fulfill these very stringent emission limits (e.g. 0.005 g/km for PM). This review is focused on these innovative technologies with special reference to catalytic traps for diesel particulate removal.

Debora Fino

2007-01-01T23:59:59.000Z

297

Effect of severity on catalytic hydroprocessed shale oil jet fuels  

SciTech Connect

Catalytic hydroprocessed shale oil jet fuels in the USA were characterized and compared with petroleum jet fuel to demonstrate their possibility as a conventional jet fuel substitute. The shale oils (Geokinetics, Occidental, Paraho and Tosco II) were hydrotreated in a 0.0508m ID by K1.524m long reactor containing Ni/Mo/Al/sub 2/O/sub 3/ catalyst. The fractionated hydrogenated shale oils at jet fuel ranges (120-300/degree/C) were analyzed for composition and physical properties. The increasing hydroprocessing severity proportionally decreased nitrogen, sulfur, olefins, aromatics and increased hydrogen content. The nitrogen content was considerable higher even at high severity conditions. Sulfur and olefin contents were lower at all severities. The heat of combustion and the physical properties, except the freezing point, were comparable to petroleum jet fuels. The yields of jet fuels increased proportionally to increased severity. The study showed that high severity hydroprocessing gave better performance in processing shale oils to jet fuels.

Mukherjee, N.L.

1987-01-01T23:59:59.000Z

298

Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods  

SciTech Connect

In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

Vicic, David A.

2014-05-01T23:59:59.000Z

299

TEC as electric generator in an automobile catalytic converter  

SciTech Connect

Modern cars use more and more electric power due to more on-board electric systems, e.g., ABS brakes, active suspension systems, electric windows, chair adjustment systems and electronic engine control systems. One possible energy source for electricity generation is to use the waste heat from the car`s engine, which generally is as much as 80% of the total energy from the combustion of the gasoline. Maybe the best location to tap the excess heat is the Catalytic Converter (Cat) in the exhaust system or perhaps at the exhaust pipes close to the engine. The Cat must be kept within a certain temperature interval. Large amounts of heat are dissipated through the wall of the Cat. A Thermionic Energy Converter (TEC) in coaxial form could conveniently be located around the ceramic cartridge of the Cat. Since the TEC is a rather good heat insulator before it reaches its working temperature the Cat will reach working temperature faster, and the final temperature of it can be controlled better when encapsulated in a concentric TEC arrangement. It is also possible to regulate the temperature of the Cat and the TEC by controlling the electrical load of the TEC. The possible working temperatures of present and future Cats appear very suitable for the new low work function collector TEC, which has been demonstrated to work down to 470 K.

Svensson, R. [Chalmers Univ. of Technology, Goeteborg (Sweden); Holmlid, L. [Univ. of Goeteborg (Sweden). Dept. of Physical Chemistry

1996-12-31T23:59:59.000Z

300

Enhancement of catalytic activities of serine proteases by tripeptides compounds  

Science Journals Connector (OSTI)

The tripeptide compounds, Glu-Arg-Pro-amide (ERPm), d-Pro-Thr-Trp-amide (dPTWm) and thioproline-Thr-Trp (tPTW), were obtained by screening of synthetic peptides for growth-inhibitory activity toward cultured transformed cells. The effects of these peptide compounds on proteases were investigated and the results showed that these compounds enhanced the amidolytic activity of serine proteases despite the fact that each reaction was carried out under optimal conditions. \\{ERPm\\} stimulated the activities of trypsin, chymotrypsin, thrombin, plasmin urokinase and elastase. dPTWm also showed similar effects except that toward chymotrypsin. tPTW elevated the activity only of trypsin, chymotrypsin and thrombin. Stimulation of trypsin activity by these compounds was also confirmed by using casein as a substrate. None of these compounds affected the amidolytic activities of metalloproteinases (MMP-1 and MMP-9), cysteine proteinases (m- and ?-calpains, cathepsin B and papain) or an exopeptidase (leucine aminopeptidase). The activation was at least partly due to the stabilization of the catalytic activity of proteases as well as prevention of autolysis.

Takaki Hiwasa; Sachiko Ogawa; Hisashi Kobayashi; Yoshimasa Ike

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

2014 GRADUATE STUDIES ENVIRONMENTAL FLUID MECHANICS  

E-Print Network (OSTI)

for Civil and Environmental Engineers Ā· Stochastic Hydrology Ā· Water Resources Management Ā· Fluid Mechanics2014 GRADUATE STUDIES ENVIRONMENTAL FLUID MECHANICS AND WATER RESOURCES ENGINEERING RESEARCH AREAS SELECTED COURSES FACILITIES The Environmental Fluid Mechanics and Water Resources program at the Georgia

Wang, Yuhang

302

System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines  

SciTech Connect

Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

Shahrokh Etemad; Lance Smith; Kevin Burns

2004-12-01T23:59:59.000Z

303

Effect of support on catalytic behavior of dispersed rhodium for hydrocarbon hydrogenolyses  

E-Print Network (OSTI)

EFFFCT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM POR HYDROCARBON HYDROGENOLYSES A Thesis AMINA ARMED KHAL'lFA Submi I ted to the Graduate College of Texas AKM University in partial full illment of the requirement for the degree... of MASTER OF SCIENCE December 1986 Major Subject: Chemistry EFFECT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM FOR HYDROCARBON HYDROGENOLYSES A Thesis by AMINA AHMED KHALIFA Approved as to style and content by: M. P. osynek (Chairman...

Khalifa, Amina Ahmed

2012-06-07T23:59:59.000Z

304

Facile Catalytic Combustion of Rice Husk and Burning Temperature Dependence of the Ashes  

Science Journals Connector (OSTI)

Facile Catalytic Combustion of Rice Husk and Burning Temperature Dependence of the Ashes ... However, these traditional applications are of low profits, and in many cases, RH is discarded as agricultural waste, which is mostly burned in open heaps (8). ... The utilization of a vibrofluidized bed of catalysts makes it possible to burn RH at decreased temperatures (10), but the millimetric catalyst particles are ill dispersed over the RH pieces, limiting the catalytic effect. ...

Liangming Xiong; Edson H. Sekiya; Shigetaka Wada; Kazuya Saito

2009-10-27T23:59:59.000Z

305

Lean Catalytic Combustion for Ultra-low Emissions at High Temperature in Gas-Turbine Burners  

Science Journals Connector (OSTI)

This illustrates the weak point of current catalytic combustion technology: the unavailability of catalytic systems stable at the temperature of the gas turbine inlet temperature. ... The possible feeds are methane, gaseous fuels, and gasified biomasses. ... In particular, the paper presents current development status and design challenges being addressed by Siemens Westinghouse Power Corp. for large industrial engines (>200 MW) and by Solar Turbines for smaller engines (Turbine Systems (ATS) program. ...

Fabrizio D’Alessandro; Giovanna Pacchiarotta; Alberto Rubino; Mauro Sperandio; Pierluigi Villa; Arturo Manrique Carrera; Reza Fakhrai; Gianluigi Marra; Annalisa Congiu

2010-12-16T23:59:59.000Z

306

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds  

DOE Patents (OSTI)

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

2001-01-01T23:59:59.000Z

307

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

SciTech Connect

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

308

Test results of low NO[sub x] catalytic combustors for gas turbines  

SciTech Connect

Catalytic combustion is an ultralow NO[sub x] combustion method, so it is expected that this method will be applied to a gas turbine combustor, However, it is difficult to develop a catalytic combustor because catalytic reliability at high temperature is still insufficient. To overcome this difficulty, the authors designed a catalytic combustor in which premixed combustion was combined. By this device, it is possible to obtain combustion gas at a combustion temperature of 1,300 C while keeping the catalytic temperature below 1,000 C. After performing preliminary tests using LPG, the authors designed two types of combustor for natural gas with a capacity equivalent to one combustor used in a 20 MW class multican-type gas turbine. Combustion tests were conducted at atmospheric pressure using natural gas. As a result, it was confirmed that a combustor in which catalytic combustor segments were arranged alternately with premixing nozzles could achieve low NO[sub x] and high combustion efficiency in the range from 1,000 C to 1,300 C of the combustor exit gas temperature.

Ozawa, Y.; Hirano, J.; Sato, M. (Central Research Inst. of Electric Power Industry, Kanagawa (Japan)); Saiga, M.; Watanabe, S. (Kansai Electric Power Co., Inc., Hyogo (Japan))

1994-07-01T23:59:59.000Z

309

Fluid dynamics kill Wyoming icicle  

SciTech Connect

Control of a blowout in which a portion of the drill collar string was extending through the rotary table and into the derrick was compounded by ice building up on the derrick and substructure. However, the momentum kill procedure proved successful. Topics considered in this paper include oil wells, natural gas wells, sleeves, rotary drills, drilling rigs, fluid mechanics, occupational safety, blowouts, drill pipes, rotary drilling, ice removal, and freezing.

Grace, R.D.

1987-04-01T23:59:59.000Z

310

Use of Clays as Drilling Fluids and Filters  

Science Journals Connector (OSTI)

In geotechnical engineering, drilling fluid is a fluid used to drill boreholes into the earth. In drilling rigs, drilling fluids help to do drill for exploration of oil and natural gas. Liquid drilling fluid is o...

Swapna Mukherjee

2013-01-01T23:59:59.000Z

311

Fluid Inclusion Analysis | Open Energy Information  

Open Energy Info (EERE)

Fluid Inclusion Analysis Fluid Inclusion Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Fluid Inclusion Analysis Details Activities (20) Areas (11) Regions (1) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Fluid composition at a point in time and space Thermal: The minimum temperature of fluid inclusion formation Cost Information Low-End Estimate (USD): 17.571,757 centUSD 0.0176 kUSD 1.757e-5 MUSD 1.757e-8 TUSD / sample Median Estimate (USD): 17.571,757 centUSD 0.0176 kUSD 1.757e-5 MUSD 1.757e-8 TUSD / sample High-End Estimate (USD): 26.782,678 centUSD

312

Hydrostatic bearings for a turbine fluid flow metering device  

DOE Patents (OSTI)

A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion. 3 figs.

Fincke, J.R.

1982-05-04T23:59:59.000Z

313

Integrating catalytic coal gasifiers with solid oxide fuel cells  

SciTech Connect

A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

2010-01-01T23:59:59.000Z

314

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

315

Multiple source/multiple target fluid transfer apparatus  

DOE Patents (OSTI)

A fluid transfer apparatus includes: (a) a plurality of orifices for connection with fluid sources; (b) a plurality of orifices for connection with fluid targets; (c) a set of fluid source conduits and fluid target conduits associated with the orifices; (d) a pump fluidically interposed between the source and target conduits to transfer fluid there between; (e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; (f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; (g) pump control means for controlling operation of the pump; (h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; (i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and (j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits. 6 figs.

Turner, T.D.

1997-08-26T23:59:59.000Z

316

Metal nanoparticles in catalytic polymer membranes and ion-exchange systems for advanced purification of water from molecular oxygen  

Science Journals Connector (OSTI)

Methods of synthesis of metal nanoparticles and metal/polymer nanocomposites including ion-exchange materials are considered. The effect of the composition and size of nanoparticles on their catalytic activity is analyzed. Attention is focused on the composites used in catalytic processes, namely, catalytic membranes and ion-exchange systems. The problems associated with the removal of dissolved oxygen from water by means of such composites are discussed. The bibliography includes 225 references.

V V Volkov; T A Kravchenko; Vyacheslav I Roldughin

2013-01-01T23:59:59.000Z

317

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

Kronberg, James W. (Aiken, SC)

1995-01-01T23:59:59.000Z

318

Chemical Fixation of Carbon Dioxide Using a Green and Efficient Catalytic System Based on Sugarcane Bagasse—An Agricultural Waste  

Science Journals Connector (OSTI)

Chemical Fixation of Carbon Dioxide Using a Green and Efficient Catalytic System Based on Sugarcane Bagasse—An Agricultural Waste ... § Wisconsin

Wei Chen; Lin-xin Zhong; Xin-wen Peng; Run-cang Sun; Fa-chuang Lu

2014-11-17T23:59:59.000Z

319

Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite  

Science Journals Connector (OSTI)

Natural mineral brucite was used directly in catalytic ozonation of dye wastewater of active brilliant red X-3B. Compared with single ozonation, degradation of X-3B increased from 47% to 89%, and removal rate of COD increased from 9% to 32.5% in catalytic ozonation for 15 min. The catalytic ozonation of X-3B followed a direct oxidization mechanism by ozone molecule, and this was actually a homogeneous catalysis of OH? due to dissolution of Mg(OH)2 from natural brucite. As a natural mineral catalyst, brucite has supplied an economical and feasible choice for catalytic ozonation of X-3B in industrial wastewater.

Yuming Dong; Kun He; Bo Zhao; Ying Yin; Lin Yin; Aimin Zhang

2007-01-01T23:59:59.000Z

320

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, April 1, 1995--June 30, 1995  

SciTech Connect

Efforts continued towards the synthesis of new pillared clay catalysts for the selective catalytic reduction of nitric oxide by ammonia. The possibility of utilizing hydrocarbons was also investigated.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Effect of K and Ca on catalytic activity of Mn-CeO x /Ti-PILC  

Science Journals Connector (OSTI)

Mn-CeO x /Ti-pillared clay (PILC) is an attractive catalyst for selective catalytic... x at low temperature because of its low cost. The poison...

Boxiong Shen; Lidan Deng; Jianhong Chen

2013-08-01T23:59:59.000Z

322

High pressure test results of a catalytically assisted ceramic combustor for a gas turbine  

SciTech Connect

A catalytically assisted ceramic combustor for a gas turbine was designed to achieve low NOx emission under 5 ppm at a combustor outlet temperature over 1300 C. This combustor is composed of a burner system and a ceramic liner behind the burner system. The burner system consist of 6 catalytic combustor segments and 6 premixing nozzles, which are arranged in parallel and alternately. The ceramic liner is made up of the layer of outer metal wall, ceramic fiber, and inner ceramic tiles. Fuel flow rates for the catalysts and the premixing nozzles are controlled independently. Catalytic combustion temperature is controlled under 1000 C, premixed gas is injected from the premixing nozzles to the catalytic combustion gas and lean premixed combustion over 1300 C is carried out in the ceramic liner. This system was designed to avoid catalytic deactivation at high temperature and thermal and mechanical shock fracture of the honeycomb monolith of catalyst. A combustor for a 10 MW class, multican type gas turbine was tested under high pressure conditions using LNG fuel. Measurements of emission, temperature, etc. were made to evaluate combustor performance under various combustion temperatures and pressures. This paper presents the design features and the test results of this combustor.

Ozawa, Y.; Tochihara, Y.; Mori, N.; Yuri, I. [Central Research Inst. of Electric Power Industry, Yokosuka, Kanagawa (Japan); Kanazawa, T.; Sagimori, K. [Kansai Electric Power Co., Inc., Amagasaki, Hyogo (Japan)

1999-07-01T23:59:59.000Z

323

Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction  

DOE Patents (OSTI)

A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

1989-10-17T23:59:59.000Z

324

Analysis of fluid inclusions in halite  

SciTech Connect

A technique has been developed to drill into fluid inclusions in halite, to extract the inclusions fluids, and to determine the concentration of all of the major and some of the minor constituents in these fluids. The minimum diameter of usable fluid inclusions is ca. 250 ..mu..m. After dilution, the fluids are analyzed by ion chromatography and coulometry. Uncertainties in the concentration of the major cations and anions is on the order of 4%. The analytical scheme provides much more precise analyses of inclusion fluids than have been available to date. The analyses are a useful starting point for reconstructing the composition of the sea water from which the evaporite brines evolved.

Lazar, B.; Holland, H.D.

1988-02-01T23:59:59.000Z

325

Apparatus for unloading pressurized fluid  

DOE Patents (OSTI)

An apparatus is described for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device. 2 figures.

Rehberger, K.M.

1994-01-04T23:59:59.000Z

326

System and method for filling a plurality of isolated vehicle fluid circuits through a common fluid fill port  

SciTech Connect

A vehicle having multiple isolated fluid circuits configured to be filled through a common fill port includes a first fluid circuit disposed within the vehicle, the first fluid circuit having a first fill port, a second fluid circuit disposed within the vehicle, and a conduit defining a fluid passageway between the first fluid circuit and second fluid circuit, the conduit including a valve. The valve is configured such that the first and second fluid circuits are fluidly coupled via the passageway when the valve is open, and are fluidly isolated when the valve is closed.

Sullivan, Scott C; Fansler, Douglas

2014-10-14T23:59:59.000Z

327

Studies of complexity in fluid systems  

SciTech Connect

This is the final report of Grant DE-FG02-92ER25119, ''Studies of Complexity in Fluids'', we have investigated turbulence, flow in granular materials, singularities in evolution of fluid surfaces and selective withdrawal fluid flows. We have studied numerical methods for dealing with complex phenomena, and done simulations on the formation of river networks. We have also studied contact-line deposition that occurs in a drying drop.

Nagel, Sidney R.

2000-06-12T23:59:59.000Z

328

Vibratory pumping of a free fluid stream  

DOE Patents (OSTI)

A vibratory fluid pump having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments.

Merrigan, Michael A. (Santa Cruz, NM); Woloshun, Keith A. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

329

Vibratory pumping of a free fluid stream  

DOE Patents (OSTI)

A vibratory fluid pump is described having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments. 3 figs.

Merrigan, M.A.; Woloshun, K.A.

1990-11-13T23:59:59.000Z

330

Hydrostatic bearings for a turbine fluid flow metering device  

DOE Patents (OSTI)

A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

Fincke, J.R.

1980-05-02T23:59:59.000Z

331

Heat Transfer Fluids Containing Nanoparticles | Argonne National...  

NLE Websites -- All DOE Office Websites (Extended Search)

Heat Transfer Fluids Containing Nanoparticles Technology available for licensing: A stable, nonreactive nanofluid that exhibits enhanced heat transfer properties with only a...

332

Sandia National Laboratories: Computational Fluid Dynamics Simulations...  

NLE Websites -- All DOE Office Websites (Extended Search)

Canal, Yakima Washington Sandia Publishes Five Reports on the Environmental Effects of Wave-Energy Converters Computational Fluid Dynamics Simulations Provide Insight for Rotor...

333

DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...  

Open Energy Info (EERE)

This is the fourth paper in a series on developing fluid inclusion stratigraphy (FIS) as a logging tool for geothermal bore holes. Here we address methods of displaying...

334

Fluid casting of particle-based articles  

DOE Patents (OSTI)

A method for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets or hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product.

Menchhofer, Paul (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

335

Particle-fluid heat/mass transfer: Newtonian and non-Newtonian fluids  

Science Journals Connector (OSTI)

A new model based on the boundary layer analysis is developed for particle-fluid heat/mass transfer. The proposed model enables a unified consideration ... results with data for Newtonian and non-Newtonian fluids

Y. Kawase

1992-01-01T23:59:59.000Z

336

Microsoft Word - 41890_PW_Catalytic Combustion_Factsheet_Rev01_12-03.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Deployment of Rich Catalytic Combustion Deployment of Rich Catalytic Combustion DE-FC26-03NT41890 I. PROJECT PARTICIPANTS A. Prime: United Technologies Corporation through its Pratt and Whitney Division B. Sub-award: Precision Combustion, Incorporated II. PROJECT DESCRIPTION A. Objectives: Create an Implementation Plan and Integration Study for rich catalytic combustion as applied to industrial gas turbines fired on both natural gas and coal derived synthesis gas. The overall goal is a combustion system that will be capable of NOx less than 2 ppmvd. at 15% oxygen in an F-class gas turbine without exhaust gas after-treatment. B. Background/relevancy: The objective of the Turbines (HEET) program is to create the necessary technology base leading to Vision 21 (V21) goals. V21

337

Hydrogen Production by Catalytic Steam Reforming of Bio-oil, Naphtha  

Science Journals Connector (OSTI)

Hydrogen production by catalytic steam reforming of the bio-oil, naphtha, and CH4 was investigated over a novel metal-doped catalyst of (Ca24Al28O64)4+4O?/Mg (C12A7-Mg). The catalytic steam reforming was investigated from 250 to 850°C in the fixed-bed continuous flow reactor. For the reforming of bio-oil, the yield of hydrogen of 80% was obtained at 750°C, and the maximum carbon conversion is nearly close to 95% under the optimum steam reforming condition. For the reforming of naphtha and CH4, the hydrogen yield and carbon conversion are lower than that of bio-oil at the same temperature. The characteristics of catalyst were also investigated by XPS. The catalyst deactivation was mainly caused by the deposition of carbon in the catalytic steam reforming process.

Yue Pan; Zhao-xiang Wang; Tao Kan; Xi-feng Zhu; Quan-xin Li

2006-01-01T23:59:59.000Z

338

Laser microfluidics : fluid actuation by light Laser microfluidics: fluid actuation by light  

E-Print Network (OSTI)

Laser microfluidics : fluid actuation by light Laser microfluidics: fluid actuation by light Jean.delville@cpmoh.u-bordeaux1.fr Abstract: The development of microfluidic devices is still hindered by the lack of robust to extend this concept to microfluidic two-phase flows. First, we investigate the destabilization of fluid

Paris-Sud XI, UniversitƩ de

339

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS Int. J. Numer. Meth. Fluids 31: 345358 (1999)  

E-Print Network (OSTI)

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS Int. J. Numer. Meth. Fluids 31: 345Ā­358 (1999 AND S. ROYc,3 a Engineering Science Program, MAES Department, 316A Perkins Hall, Uni6ersity of Tennessee Corporation, Burr Ridge, IL, USA SUMMARY The quest continues for accurate and efficient computational fluid

Roy, Subrata

340

Structural, textural and catalytic properties of Al-, Ti-pillared clays  

SciTech Connect

Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Visualizing a Catalyst at Work during the Ignition of the Catalytic Partial Oxidation of Methane  

Science Journals Connector (OSTI)

Ignitions or light-offs of heterogeneously catalyzed oxidation reactions are a special challenge for operando studies on catalytic reactors, which have gained increasing attention for the identification of active sites of catalysts and optimal reactor design. ... One of these reactions is the catalytic partial oxidation (CPO) of hydrocarbons to carbon monoxide and hydrogen, which is considered an important alternative to presently utilized processes in natural gas and biomass conversion such as steam and autothermal reforming. ... In conclusion, we demonstrate that the ignition of heterogeneously catalyzed chemical reactions can be visualized in a spatiotemporal manner by means of synchrotron radiation based high resolution transmission X-ray absorption imaging combined with IR thermography. ...

Bertram Kimmerle; Jan-Dierk Grunwaldt; Alfons Baiker; Pieter Glatzel; Pit Boye; Sandra Stephan; Christian G. Schroer

2009-01-29T23:59:59.000Z

342

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

Hazen, T.C.; Fliermans, C.B.

1994-01-01T23:59:59.000Z

343

Immersible solar heater for fluids  

DOE Patents (OSTI)

An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater. 11 figs.

Kronberg, J.W.

1995-07-11T23:59:59.000Z

344

Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification  

SciTech Connect

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

2008-07-01T23:59:59.000Z

345

Novel Syngas Production Techniques for GTL-FT Synthesis of Gasoline Using Reverse Flow Catalytic Membrane Reactors  

Science Journals Connector (OSTI)

Novel Syngas Production Techniques for GTL-FT Synthesis of Gasoline Using Reverse Flow Catalytic Membrane Reactors ... Catalytic partial oxidation (CPO, or also CPOX) is different from noncatalytic partial oxidation (POX) in that chemical conversion takes place over a catalyst bed, but it does not use a burner. ...

C. Dillerop; H. van den Berg; A. G. J. van der Ham

2010-11-10T23:59:59.000Z

346

Foam vessel for cryogenic fluid storage  

DOE Patents (OSTI)

Cryogenic storage and separator vessels made of polyolefin foams are disclosed, as are methods of storing and separating cryogenic fluids and fluid mixtures using these vessels. In one embodiment, the polyolefin foams may be cross-linked, closed-cell polyethylene foams with a density of from about 2 pounds per cubic foot to a density of about 4 pounds per cubic foot.

Spear, Jonathan D (San Francisco, CA)

2011-07-05T23:59:59.000Z

347

It's The Fluids SEG Honorary Lecture  

E-Print Network (OSTI)

Coarse Sand w/o THF-Hydrates Coarse Sand w/ THF-Hydrates #12;Guest Molecules Gas Hydrate Crystal information please visit: #12;Ā·WATER and BRINE (BRINE = H2O + Salt) Ā·HYDROCARBONS Oil Gas TYPES of PORE FLUIDS Gas Mixtures Ā·DRILLING MUD Ā·PRODUCTION FLUIDS Miscible Injectants (CO2, Enriched Gas) #12;From Ivar

348

Dense colloidal fluids form denser amorphous sediments  

E-Print Network (OSTI)

Dense colloidal fluids form denser amorphous sediments Shir R. Libera,b , Shai Borohovicha of their randomly packed solid sediments. We demonstrate that the most dilute fluids of colloidal hard spheres form loosely packed sediments, where the volume fraction of the particles approaches in frictional systems

Schofield, Andrew B.

349

Supercritical Fluid Extraction of Wood Pulps  

Science Journals Connector (OSTI)

......capillary column inlet system which was main tained...great concern in this study because (a) their relative...McNally and J.R. Wheeler. J. Chromatogr. 447...Chaplin, and N.R. Foster. J. Supercrit. Fluids...Wells, and N.R. Foster. J. Supercrit. Fluids......

A.J. Sequeira; L.T. Taylor

1992-10-01T23:59:59.000Z

350

Engineering Insights 2006 Complex Fluids Design Consortium  

E-Print Network (OSTI)

Engineering Insights 2006 Complex Fluids Design Consortium (CFDC) www.mrl.ucsb.edu/cfdc Overview;Engineering Insights 2006 Objectives -- continued Ā· Create a world-class center for complex fluid and soft and Research Highlights Glenn Fredrickson October 18, 2006 #12;Engineering Insights 2006 What is the CFDC

California at Santa Barbara, University of

351

Definition: Isotopic Analysis- Fluid | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon Ā» Definition: Isotopic Analysis- Fluid Jump to: navigation, search Dictionary.png Isotopic Analysis- Fluid Isotopes are atoms of the same element that have different numbers of neutrons. An isotopic analysis looks at a particular isotopic element(s) in a given system, while the conditions which increase/decrease the number of neutrons are well understood and measurable. Fluid isotopes are used to characterize a fluids origin, age, and/or interaction with rocks or other fluids based on unique isotopic ratios or concentrations.[1] View on Wikipedia Wikipedia Definition Isotope geochemistry is an aspect of geology based upon study of the relative and absolute concentrations of the elements and their isotopes in

352

Definition: Fluid Lab Analysis | Open Energy Information  

Open Energy Info (EERE)

Fluid Lab Analysis Fluid Lab Analysis Jump to: navigation, search Dictionary.png Fluid Lab Analysis Fluid lab analysis encompasses a broad array of techniques used for the analysis of water and gas samples. These analyses are used in a variety of disciplines to quantify the chemical components and properties of groundwater systems. In geothermal exploration and development, fluid analyses often provide a first look into the characteristics of a hydrothermal system, and are routinely used in ongoing monitoring of geothermal reservoirs.[1] View on Wikipedia Wikipedia Definition Water chemistry analyses are carried out to identify and quantify the chemical components and properties of a certain water. This include pH, major cations and anions, trace elements and isotopes. Water chemistry

353

Definition: Downhole Fluid Sampling | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon Ā» Definition: Downhole Fluid Sampling Jump to: navigation, search Dictionary.png Downhole Fluid Sampling Downhole fluid sampling is done to characterize the chemical, thermal, or hydrological properties of a surface or subsurface aqueous system. Downhole fluid sampling is typically performed to monitor water quality, study recharge and flow in groundwater systems, and evaluate resource potential of geothermal reservoirs. Analysis of both the liquid and gas fractions of the reservoir fluid allows for detailed characterize the chemical, thermal, or hydrological properties of the subsurface hydrothermal system. View on Wikipedia Wikipedia Definition Ret Like Like You like this.Sign Up to see what your friends like.

354

Fluid Lab Analysis | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon Ā» Fluid Lab Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Fluid Lab Analysis Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Lab Analysis Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Results can aid in the determination of fluid source regions and circulation pathways, and assist in determining the degree of mixing between different hydrothermal fluids. Thermal: Certain elements exhibit high spatial correlation with high-temperature geothermal systems; Isotopic ratios can be used to characterize and locate subsurface thermal anomalies.

355

Modelling anisotropic fluid spheres in general relativity  

E-Print Network (OSTI)

We argue that an arbitrary general relativistic anisotropic fluid sphere, (spherically symmetric but with transverse pressure not equal to radial pressure), can nevertheless be successfully modelled by suitable linear combinations of quite ordinary classical matter: an isotropic perfect fluid, a classical electromagnetic field, and a classical (minimally coupled) scalar field. While the most general decomposition is not unique, a preferred minimal decomposition can be constructed that is unique. We show how the classical energy conditions for the anisotropic fluid sphere can be related to energy conditions for the isotropic perfect fluid, electromagnetic field, and scalar field components of the model. Furthermore we show how this decomposition relates to the distribution of electric charge density and scalar charge density throughout the model that is used to mimic the anisotropic fluid sphere. Consequently, we can build physically reasonable matter models for almost any spherically symmetric spacetime.

Boonserm, Petarpa; Visser, Matt

2015-01-01T23:59:59.000Z

356

Euler's fluid equations: Optimal Control vs Optimization  

E-Print Network (OSTI)

An optimization method used in image-processing (metamorphosis) is found to imply Euler's equations for incompressible flow of an inviscid fluid, without requiring that the Lagrangian particle labels exactly follow the flow lines of the Eulerian velocity vector field. Thus, an optimal control problem and an optimization problem for incompressible ideal fluid flow both yield the \\emph {same} Euler fluid equations, although their Lagrangian parcel dynamics are \\emph{different}. This is a result of the \\emph{gauge freedom} in the definition of the fluid pressure for an incompressible flow, in combination with the symmetry of fluid dynamics under relabeling of their Lagrangian coordinates. Similar ideas are also illustrated for SO(N) rigid body motion.

Darryl D. Holm

2009-09-28T23:59:59.000Z

357

Pumping viscoelastic two-fluid media  

E-Print Network (OSTI)

Using a two-fluid model for viscoelastic polymer solutions, we study analytically fluid transport driven by a transverse, small amplitude traveling wave propagation. The pumping flow far from the waving boundary is shown to be strongly wave number and viscosity dependent, in contrast to a viscous Newtonian fluid. We find the two qualitatively different regimes: In one regime relevant to small wave numbers, the fluidic transport is almost the same as the Newtonian case, and uniform viscoelastic constitutive equations provide a good approximation. In the other regime, the pumping is substantially decreased because of the gel-like character. The boundary separating these two regimes is clarified. Our results suggest possible needs of two-fluid descriptions for the transport and locomotion in biological fluids with cilia and flagella.

Hirofumi Wada

2010-04-08T23:59:59.000Z

358

Short residence time coal liquefaction process including catalytic hydrogenation  

DOE Patents (OSTI)

Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm.sup.2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455.degree. and about 500.degree. C. to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425.degree. C. to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C.sub.5 -454.degree. C. is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance.

Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

1982-05-18T23:59:59.000Z

359

Short residence time coal liquefaction process including catalytic hydrogenation  

DOE Patents (OSTI)

Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone, the hydrogen pressure in the preheating-reaction zone being at least 1,500 psig (105 kg/cm[sup 2]), reacting the slurry in the preheating-reaction zone at a temperature in the range of between about 455 and about 500 C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid to substantially immediately reduce the temperature of the reaction effluent to below 425 C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C[sub 5]-454 C is an amount at least equal to that obtainable by performing the process under the same condition except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent and recycled as process solvent. The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. 6 figs.

Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

1982-05-18T23:59:59.000Z

360

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION  

Open Energy Info (EERE)

TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: TRACING FLUID SOURCES IN THE COSO GEOTHERMAL SYSTEM USING FLUID-INCLUSION GAS CHEMISTRY Details Activities (1) Areas (1) Regions (0) Abstract: Vein and alteration assemblages from eight Coso wells have been collected and their fluid-inclusion gases analyzed by quadrupole mass spectrometry. Four major types of alteration were sampled: 1) young calcite-hematite-pyrite veins; 2) wairakite or epidote veins and alteration that are spatially associated with deep reservoirs in the main field and eastern wells; 3) older sericite and pyrite wallrock alteration; and 4) stilbite-calcite veins that are common in cooler or marginal portions of

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Computational fluid dynamics simulation of hydrodynamics and chemical reaction in a CFB downer  

Science Journals Connector (OSTI)

Abstract A computational fluid dynamics (CFD) model for simulating the chemical reaction process in a gas–particle circulating fluidized bed (CFB) downer is introduced by combining the two-fluid model (TFM) for the gas–particle turbulent flows and the c 2 Æ ? ? c model for the turbulent mass transfer. With the proposed model, the species concentration and solid volume fraction as well as the velocity distributions along the CFB downer are able to be predicted. In mathematical expression of the proposed model, the recently developed formulations of c 2 Æ ? ? c is adopted to close the turbulent mass transfer equations so that the turbulent mass diffusivity can be determined without relying on empirical methods. As for the gas–solid two phase turbulent momentum transfer equations, the methodology of kg ? ?g ? kp ? ?p ? ? is used for their closures. To validate the proposed model, simulation is carried out for the catalytic ozone decomposition in a gas–solid CFB downer. The simulation results are compared with the experimental data and satisfactory agreement is found between them in both axial/radial distributions of concentration and solid volume fraction. Furthermore, the simulations reveal that the turbulent mass diffusivity varies along axial and radial directions, and the turbulent Schmidt number is not a constant throughout the CFB downer.

Wenbin Li; Kuotsung Yu; Botan Liu; Xigang Yuan

2015-01-01T23:59:59.000Z

362

Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils  

Science Journals Connector (OSTI)

...hydrogen is from large steam reformers and...amounts of undesired methane are produced, which...such as by the reforming of biomass-derived...aqueous-phase reforming of biomass-derived...Survey of the Economics of Hydrogen Technologies...Hydrogen from catalytic reforming of biomass-derived...

Tushar P. Vispute; Huiyan Zhang; Aimaro Sanna; Rui Xiao; George W. Huber

2010-11-26T23:59:59.000Z

363

Selection and evolution of enzymes from a partially randomized non-catalytic scaffold  

E-Print Network (OSTI)

LETTERS Selection and evolution of enzymes from a partially randomized non-catalytic scaffold Burckhard Seelig1 & Jack W. Szostak1 Enzymes are exceptional catalysts that facilitate a wide variety- and stereoselectiv- ities. There is considerable interest in developing new enzymes for the synthesis of chemicals

Heller, Eric

364

Synthesis of single-walled carbon nanotube (SWNTs) from size-selected catalytic metal particles.  

E-Print Network (OSTI)

Synthesis of single-walled carbon nanotube (SWNTs) from size-selected catalytic metal particles-quality synthesis of single-walled carbon nanotubes (SWNTs) has demonstrated new possibilities of applications and for the controlled synthesis directly on semiconductor materials. In this technique, it is known that material, size

Maruyama, Shigeo

365

Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction  

DOE Patents (OSTI)

A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Westmont, IL); Wang, Xiaoping (Naperville, IL)

2010-08-03T23:59:59.000Z

366

Test results of a catalytically assisted combustor for a gas turbine  

Science Journals Connector (OSTI)

A catalytically assisted ceramic combustor for a gas turbine was designed and tested to achieve low \\{NOx\\} emissions. This combustor is composed of a burner and a ceramic liner. The burner consists of an annular preburner, six catalytic combustor segments and six premixing nozzles, which are arranged in parallel and alternately. In this combustor system, catalytic combustion temperature is controlled under 1000 °C, premixed gas is injected from the premixing nozzles to the catalytic combustion gas and lean premixed combustion over 1300 °C is carried out in the ceramic liner. This system was designed to avoid catalyst deactivation at high temperature and thermal shock fracture of the ceramic honeycomb monolith of the catalyst. A 1 MW class combustor was tested using LNG fuel. Firstly, \\{NOx\\} emissions from the preburner were investigated under various pressure conditions. Secondly, two sets of honeycomb cell density catalysts and one set of thermally pretreated catalysts ware applied to the combustor, and combustion tests were carried out under various pressure conditions. As a result, it was found that the main source of \\{NOx\\} was the preburner, and total \\{NOx\\} emissions from the combustor were approximately 4 ppm (at 16% O2) at an adiabatic combustion temperature of 1350 °C and combustor inlet pressure of 1.33 MPa.

Yasushi Ozawa; Yoshihisa Tochihara; Noriyuki Mori; Isao Yuri; Junichi Sato; Koji Kagawa

2003-01-01T23:59:59.000Z

367

in: Nanotechnology 7(1), pp. 307314, 1996 Emergent Computation by Catalytic Reactions  

E-Print Network (OSTI)

in: Nanotechnology 7(1), pp. 307Ā­314, 1996 Emergent Computation by Catalytic Reactions Wolfgang the idea behind the chemical computational metaphor and outline its relevance for nanotechnology. We set up within this context. The implications of this approach for nanotechnology, parallel computers based on mo

Dittrich, Peter

368

Synthesis, characterization and catalytic activity of Al/Fe2O3 nanothermite  

Science Journals Connector (OSTI)

Nanothermites have attracted much attention owing to their excellent sensitivity and catalytic activity. In this paper, Fe2O3 is used to achieve Al/Fe2O3 nanothermite by mixing nano-Al with Fe2O3 nanopowder. X-ra...

Supriya Singh; Gurdip Singh; Naveen Kulkarni…

2014-09-01T23:59:59.000Z

369

Functionalized Graphene as a Catalytic Counter Electrode in Dye-Sensitized  

E-Print Network (OSTI)

be responsible for the observed catalytic performance of car- bonaceous electrode materials, while the impact graphene sheets (FGSs), a type of defective graphene currently synthesized at the industrial scale25 via to 2630 m2 g 1 ) and contain lat- tice defects and oxygen-containing func- tional groups

Aksay, Ilhan A.

370

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT  

E-Print Network (OSTI)

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

371

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network (OSTI)

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

372

Acidity and catalytic activity of zeolite catalysts bound with silica and alumina  

E-Print Network (OSTI)

. Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking...

Wu, Xianchun

2004-09-30T23:59:59.000Z

373

Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles  

E-Print Network (OSTI)

of this process is a limiting factor in the performance of direct methanol fuel cells, which produce electricityCorrelating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol

Kik, Pieter

374

Optimal control of a time-varying catalytic fixed bed reactor with catalyst deactivation  

Science Journals Connector (OSTI)

The paper deals with the linear-quadratic control problem for a time-varying partial differential equation model of a catalytic fixed-bed reactor. The classical Riccati equation approach, for time-varying infinite-dimensional systems, is extended to ... Keywords: catalyst deactivation, fixed bed reactor, infinite dimensional time-varying system, linear quadratic optimal control

L. Mohammadi; I. Aksikas; J. F. Forbes

2009-06-01T23:59:59.000Z

375

Application of Nanotechnology for Heavy Oil Upgrading: Catalytic Steam Gasification/Cracking of Asphaltenes  

Science Journals Connector (OSTI)

It is well-known that oilsands processing and production faces several challenges that need to be surmounted to make it an environmentally sound and economically feasible industry. ... In this work, we are exploring a novel method for the elimination of asphaltenes, waste hydrocarbons, by adsorption on nanoparticles and, subsequent, catalytic steam gasification of the adsorbed asphaltenes for synthesis gas production. ...

Nashaat N. Nassar; Azfar Hassan; Pedro Pereira-Almao

2011-03-21T23:59:59.000Z

376

Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural with an Immobilized Enzyme and a Solid Acid  

Science Journals Connector (OSTI)

Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural with an Immobilized Enzyme and a Solid Acid ... Conversion of cellulosic biomass to renewable chemicals such as 5-hydroxymethylfurfural (HMF) is of high current interest. ... The materials were studied and compared in the selective dehydration of fructose to 5-hydroxymethylfurfural (HMF). ...

Hua Huang; Carl A. Denard; Ricardo Alamillo; Anthony J. Crisci; Yurun Miao; James. A. Dumesic; Susannah L. Scott; Huimin Zhao

2014-06-03T23:59:59.000Z

377

Structural analysis of Catliq bio-oil produced by catalytic liquid conversion of biomass  

E-Print Network (OSTI)

. The energy contained in biomass can be utilized either directly as in combustion or by converting the biomassStructural analysis of CatliqĀ® bio-oil produced by catalytic liquid conversion of biomass Toor, S The potential offered by biomass for solving some of the world's energy problems is widely recognized

Toor, Saqib

378

Catalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders  

E-Print Network (OSTI)

) that are otherwise difficult to produce (e.g., transition metal/borides, carbides, and nitrides).1,2 Many earlierCatalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders Troy/carbon/tantalum carbide combustion synthesis system has been examined to determine the effects of transport agents

Wooldridge, Margaret S.

379

ADAR Proteins: Structure and Catalytic Rena A. Goodman, Mark R. Macbeth and Peter A. Beal  

E-Print Network (OSTI)

ADAR Proteins: Structure and Catalytic Mechanism Rena A. Goodman, Mark R. Macbeth and Peter A. Beal .................................................. 3 R. A. Goodman Ɓ P. A. Beal (&) Department of Chemistry, University of California, One Shields Ave, Davis, CA 95616, USA e-mail: beal@chem.ucdavis.edu M. R. Macbeth (&) Department of Biological Sciences

Beal, Peter A.

380

Studying rheological behavior of nanoclay as oil well drilling fluid  

Science Journals Connector (OSTI)

Bentonite is commonly used to control the rheology and filtrate loss required for water-based drilling fluids. In this study, the effect ... modification on fluid viscosity and its dispersion in oil-wet fluids we...

M. Mohammadi; M. Kouhi; A. Sarrafi; M. Schaffie

2013-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Thermal Storage and Advanced Heat Transfer Fluids (Fact Sheet)  

SciTech Connect

Fact sheet describing NREL CSP Program capabilities in the area of thermal storage and advanced heat transfer fluids: measuring thermophysical properties, measuring fluid flow and heat transfer, and simulating flow of thermal energy and fluid.

Not Available

2010-08-01T23:59:59.000Z

382

Heat Transfer in Wedge Flow of a Micropolar Fluid  

Science Journals Connector (OSTI)

The theory of fluids with microstructures was first given by Eringen ... , 1965), and they are called micropolar fluids. These fluids exhibit microrotational effects and microrotational inertia. The flow of such

V. M. Soundalgekar; H. S. Takhar

1980-01-01T23:59:59.000Z

383

The incorporation of bubbles into a computer graphics fluid simulation  

E-Print Network (OSTI)

We present methods for incorporating bubbles into a photorealistc fluid simulation. Previous methods of fluid simulation in computer graphics do not include bubbles. Our system automatically creates bubbles, which are simulated on top of the fluid...

Greenwood, Shannon Thomas

2005-08-29T23:59:59.000Z

384

A model of overall regulation of body fluids  

Science Journals Connector (OSTI)

A large-scale model of body fluid regulation was presented for the purpose of studying problems concerning body fluid disturbances and fluid therapy. This model, containing subsystems of circulation, respirati...

Noriaki Ikeda; Fumiaki Marumo; Masuo Shirataka…

1979-01-01T23:59:59.000Z

385

Arterial LDL Transport Incorporating Fluid Solid Interactions, Hyperthermia, and Atherosclerosis  

E-Print Network (OSTI)

of Mechanical Engineers, Fluids Engineering Division (FED, Bio-Medical Fluids Engineering 21, 8. Buckwalter, J.Fluid Solid Interactions, Hyperthermia, and Atherosclerosis by Stephen Chung Doctor of Philosophy, Graduate Program in Mechanical Engineering

Chung, Stephen

2013-01-01T23:59:59.000Z

386

Packing frustration in dense confined fluids  

E-Print Network (OSTI)

Packing frustration for confined fluids, i.e., the incompatibility between the preferred packing of the fluid particles and the packing constraints imposed by the confining surfaces, is studied for a dense hard-sphere fluid confined between planar hard surfaces at short separations. The detailed mechanism for the frustration is investigated via an analysis of the anisotropic pair distributions of the confined fluid, as obtained from integral equation theory for inhomogeneous fluids at pair correlation level within the anisotropic Percus-Yevick approximation. By examining the mean forces that arise from interparticle collisions around the periphery of each particle in the slit, we calculate the principal components of the mean force for the density profile - each component being the sum of collisional forces on a particle's hemisphere facing either surface. The variations of these components with the slit width give rise to rather intricate changes in the layer structure between the surfaces, but, as shown in this paper, the basis of these variations can be easily understood qualitatively and often also semi-quantitatively. It is found that the ordering of the fluid is in essence governed locally by the packing constraints at each single solid-fluid interface. A simple superposition of forces due to the presence of each surface gives surprisingly good estimates of the density profiles, but there remain nontrivial confinement effects that cannot be explained by superposition, most notably the magnitude of the excess adsorption of particles in the slit relative to bulk.

Kim Nygård; Sten Sarman; Roland Kjellander

2014-09-04T23:59:59.000Z

387

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-06-01T23:59:59.000Z

388

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-01-01T23:59:59.000Z

389

High pressure test results of a catalytic combustor for gas turbine  

SciTech Connect

Recently, the use of gas turbine systems, such as combined cycle and cogeneration systems, has gradually increased in the world. But even when a clean fuel such as LNG (liquefied natural gas) is used, thermal NO{sub x} is generated in the high temperature gas turbine combustion process. The NO{sub x} emission from gas turbines is controlled through selective catalytic reduction processes (SCR) in the Japanese electric industry. If catalytic combustion could be applied to the combustor of the gas turbine, it is expected to lower NO{sub x} emission more economically. Under such high temperature and high pressure conditions, as in the gas turbine, however, the durability of the catalyst is still insufficient. So it prevents the realization of a high temperature catalytic combustor. To overcome this difficulty, a catalytic combustor combined with premixed combustion for a 1,300 C class gas turbine was developed. In this method, catalyst temperature is kept below 1,000 C, and a lean premixed gas is injected into the catalytic combustion gas. As a result, the load on the catalyst is reduced and it is possible to prevent the catalyst deactivation. After a preliminary atmospheric test, the design of the combustion was modified and a high pressure combustion test was conducted. As a result, it was confirmed that NO{sub x} emission was below 10 ppm (at 16 percent O{sub 2}) at a combustor outlet gas temperature of 1,300 C and that the combustion efficiency was almost 100%. This paper presents the design features and test results of the combustor.

Fujii, T.; Ozawa, Y.; Kikumoto, S.; Sato, M. [Central Research Inst. of Electric Power Industry, Yokosuka, Kanagawa (Japan); Yuasa, Y.; Inoue, H. [Kansai Electric Power Co., Inc., Amagasaki, Hyogo (Japan)

1998-07-01T23:59:59.000Z

390

Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996  

SciTech Connect

During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

1997-08-01T23:59:59.000Z

391

Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced...

392

Application of Neutron Imaging and Scattering to Fluid Flow and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS Environments Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS...

393

Development of Molten-Salt Heat Trasfer Fluid Technology for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar...

394

Fracture Network and Fluid Flow Imaging for EGS Applications...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fracture Network and Fluid Flow Imaging for EGS Applications from Multi-Dimensional Electrical Resistivity Structure Fracture Network and Fluid Flow Imaging for EGS Applications...

395

FLUID INCLUSION STRATIGRAPHY: NEW METHOD FOR GEOTHERMAL RESERVOIR...  

Open Energy Info (EERE)

RESERVOIR ASSESSMENT PRELIMINARY RESULTS Abstract Fluid Inclusion Stratigraphy (FIS) is a new technique developed for the oil industry in order to map borehole fluids....

396

Working Fluids Low Global Warming Potential Refrigerants - 2013...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Emerging Technologies...

397

FLUID GEOCHEMISTRY AT THE RAFT RIVER GEOTHERMAL FIELD, IDAHO...  

Open Energy Info (EERE)

deep structural controls on fluid pathways in the field, which has compartmentalized the fluids and limited the degree of mixing between them. Authors Ayling, B.; Molling, P.;...

398

Electric Power Generation from Coproduced Fluids from Oil and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Electric Power Generation from Coproduced Fluids from Oil and Gas Wells The primary objective of this...

399

Fluid injection and production apparatus and method  

SciTech Connect

This patent describes an apparatus for transporting fluid. It comprises: a first generally tubular assembly having a first end and a second end, the first assembly having at least one aperture therethrough; a second generally tubular assembly having a first end and a second end and being positioned within the first tubular assembly; a first means for selectively permitting fluid flow between the exterior and the interior of the second assembly; a third generally tubular assembly having a first end and a second end; and a second means for selectively permitting fluid flow between the exterior and the interior of the third assembly.

Deines, T.A.; Ellwood, D.E.

1992-07-28T23:59:59.000Z

400

Apparatus And Method For Fluid Analysis  

DOE Patents (OSTI)

The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

Wilson, Bary W. (Richland, WA); Peters, Timothy J. (Richland, WA); Shepard, Chester L. (West Richland, WA); Reeves, James H. (Richland, WA)

2003-05-13T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Excitations of Bose Fluids in Nanotubes  

Science Journals Connector (OSTI)

We discuss the excitation spectra of Bose fluids in the quasi-one dimensional geometries which can be found in interstitial channels of nanotubes and inside individual nanotubes. We compute the collective excitat...

E. S. Hernįndez; M. W. Cole

2002-01-01T23:59:59.000Z

402

Geothermal Reservoir Evaluation Considering Fluid Adsorption  

E-Print Network (OSTI)

SGP-"R- 68 Geothermal Reservoir Evaluation Considering Fluid Adsorption and Composition Michael J. Economides September, 1983 Financial support was provided through the Stanford Geothermal Program Contract No Geothermal Program Interdisciplinary Research in Engineering and Earth Sciences STANFORD UNIVERSITY Stanford

Stanford University

403

Clay-based geothermal drilling fluids  

SciTech Connect

The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

1982-11-01T23:59:59.000Z

404

Geophysical Fluid Dynamics Laboratory Presented by  

E-Print Network (OSTI)

Dynamics Laboratory Outline: Ā· Introduction Ā· Software Infrastructure Projects: Completed Current consortium for climate-weather community 3 #12;Geophysical Fluid Dynamics Laboratory Software Infrastructure Projects Ā­ Completed: Ā· Flexible Modeling System (FMS) Ā· FMS Model: Hybrid programming model Memory

405

Controllable adhesion using field-activated fluids  

E-Print Network (OSTI)

We demonstrate that field-responsive magnetorheological fluids can be used for variable-strength controllable adhesion. The adhesive performance is measured experimentally in tensile tests (a.k.a. probe-tack experiments) ...

Ewoldt, Randy H.

406

Fluid Imaging of Enhanced Geothermal Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

eere.energy.gov Velocity & Resistivity Imaging Possibility & Potential Fluid Filled Fracture Network? VpVs Ratio Map 500 m below sea level Conductivity Map 500 m below sea level...

407

Modelling suspended sediment in environmental turbulent fluids  

E-Print Network (OSTI)

Modelling sediment transport in environmental turbulent fluids is a challenge. This article develops a sound model of the lateral transport of suspended sediment in environmental fluid flows such as floods and tsunamis. The model is systematically derived from a 3D turbulence model based on the Smagorinski large eddy closure. Embedding the physical dynamics into a family of problems and analysing linear dynamics of the system, centre manifold theory indicates the existence of slow manifold parametrised by macroscale variables. Computer algebra then constructs the slow manifold in terms of fluid depth, depth-averaged lateral velocities, and suspended sediment concentration. The model includes the effects of sediment erosion, advection, dispersion, and also the interactions between the sediment and turbulent fluid flow. Vertical distributions of the velocity and concentration in steady flow agree with the established experimental data. Numerical simulations of the suspended sediment under large waves show that ...

Cao, Meng

2014-01-01T23:59:59.000Z

408

Working Fluids Low Global Warming Potential Refrigerants  

NLE Websites -- All DOE Office Websites (Extended Search)

Working Fluids Low GWP Working Fluids Low GWP Refrigerants - CRADA Ed Vineyard Oak Ridge National Laboratory vineyardea@ornl.gov (865) 574-0576 3 April 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: - High GWP refrigerants increase CO 2 equivalent emissions for HVAC&R equipment - Low GWP alternatives may increase energy consumption, introduce safety risks, require significant modifications to equipment, and have higher costs

409

Working Fluids Low Global Warming Potential Refrigerants  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Working Fluids Low GWP Working Fluids Low GWP Refrigerants - CRADA Ed Vineyard Oak Ridge National Laboratory vineyardea@ornl.gov (865) 574-0576 3 April 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem Statement: - High GWP refrigerants increase CO 2 equivalent emissions for HVAC&R equipment - Low GWP alternatives may increase energy consumption, introduce safety risks, require significant modifications to equipment, and have higher costs

410

Parametric internal waves in a compressible fluid  

E-Print Network (OSTI)

We describe the effect of vibration on a confined volume of fluid which is density stratified due to its compressibility. We show that internal gravity-acoustic waves can be parametrically destabilized by the vibration. The resulting instability is similar to the classic Faraday instability of surface waves, albeit modified by the compressible nature of the fluid. It may be possible to observe experimentally near a gas-liquid critical point.

Kausik S. Das; Stephen W. Morris; A. Bhattacharyay

2007-10-11T23:59:59.000Z

411

Parametric internal waves in a compressible fluid  

E-Print Network (OSTI)

We describe the effect of vibration on a confined volume of fluid which is density stratified due to its compressibility. We show that internal gravity-acoustic waves can be parametrically destabilized by the vibration. The resulting instability is similar to the classic Faraday instability of surface waves, albeit modified by the compressible nature of the fluid. It may be possible to observe experimentally near a gas-liquid critical point.

Das, Kausik S; Bhattacharyay, A

2007-01-01T23:59:59.000Z

412

Nanoparticle enhanced ionic liquid heat transfer fluids  

DOE Patents (OSTI)

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

2014-08-12T23:59:59.000Z

413

Anisotropic surface tension of buckled fluid membrane  

E-Print Network (OSTI)

Solid sheets and fluid membranes exhibit buckling under lateral compression. Here, it is revealed that fluid membranes have anisotropic buckling surface tension contrary to solid sheets. Surprisingly, the surface tension perpendicular to the buckling direction shows stronger dependence than that parallel to it. Our theoretical predictions are supported by numerical simulations of a meshless membrane model. This anisotropic tension can be used to measure the membrane bending rigidity. It is also found phase synchronization occurs between multilayered buckled membranes.

Hiroshi Noguchi

2011-06-01T23:59:59.000Z

414

Fluid driven torsional dipole seismic source  

DOE Patents (OSTI)

A compressible fluid powered oscillating downhole seismic source device capable of periodically generating uncontaminated horizontally-propagated, shear waves is provided. A compressible fluid generated oscillation is created within the device which imparts an oscillation to a housing when the device is installed in a housing such as the cylinder off an existing downhole tool, thereby a torsional seismic source is established. Horizontal waves are transferred to the surrounding bore hole medium through downhole clamping.

Hardee, Harry C. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

415

Control system for fluid heated steam generator  

DOE Patents (OSTI)

A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

Boland, J.F.; Koenig, J.F.

1984-05-29T23:59:59.000Z

416

Stirling engine with air working fluid  

DOE Patents (OSTI)

A Stirling engine capable of utilizing air as a working fluid which includes a compact heat exchange module which includes heating tube units, regenerator and cooler positioned about the combustion chamber. This arrangement has the purpose and effect of allowing the construction of an efficient, high-speed, high power-density engine without the use of difficult to seal light gases as working fluids.

Corey, John A. (North Troy, NY)

1985-01-01T23:59:59.000Z

417

Viscosity of High Energy Nuclear Fluids  

E-Print Network (OSTI)

Relativistic high energy heavy ion collision cross sections have been interpreted in terms of almost ideal liquid droplets of nuclear matter. The experimental low viscosity of these nuclear fluids have been of considerable recent quantum chromodynamic interest. The viscosity is here discussed in terms of the string fragmentation models wherein the temperature dependence of the nuclear fluid viscosity obeys the Vogel-Fulcher-Tammann law.

V. Parihar; A. Widom; D. Drosdoff; Y. N. Srivastava

2007-03-15T23:59:59.000Z

418

High gliding fluid power generation system with fluid component separation and multiple condensers  

DOE Patents (OSTI)

An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

2014-10-14T23:59:59.000Z

419

Selection of fluids for tritium pumping systems  

SciTech Connect

The degradation characteristics of three types of vacuum pump fluids, polyphenyl ethers, perfluoropolyethers and hydrocarbon oils were reviewed. Fluid selection proved to be a critical factor in the long-term performance of tritium pumping systems and subsequent tritium recovery operations. Thermal degradation and tritium radiolysis of pump fluids produce contaminants which can damage equipment and interfere with tritium recovery operations. General characteristics of these fluids are as follows: polyphenyl ether has outstanding radiation resistance, is very stable under normal diffusion pump conditions, but breaks down in the presence of oxygen at anticipated operating temperatures. Perfluoropolyether fluids are very stable and do not react chemically with most gases. Thermal and mechanical degradation products are inert, but the radiolysis products are very corrosive. Most of the degradation products of hydrogen oils are volatile and the principal radiolysis product is methane. Our studies show that polyphenyl ethers and hydrocarbon oils are the preferred fluids for use in tritium pumping systems. No corrosive materials are formed and most of the degradation products can be removed with suitable filter systems.

Chastagner, P

1984-02-01T23:59:59.000Z

420

Monodisperse metal nanoparticle catalysts on silica mesoporous supports: synthesis, characterizations, and catalytic reactions  

SciTech Connect

The design of high performance catalyst achieving near 100% product selectivity at maximum activity is one of the most important goals in the modern catalytic science research. To this end, the preparation of model catalysts whose catalytic performances can be predicted in a systematic and rational manner is of significant importance, which thereby allows understanding of the molecular ingredients affecting the catalytic performances. We have designed novel 3-dimensional (3D) high surface area model catalysts by the integration of colloidal metal nanoparticles and mesoporous silica supports. Monodisperse colloidal metal NPs with controllable size and shape were synthesized using dendrimers, polymers, or surfactants as the surface stabilizers. The size of Pt, and Rh nanoparticles can be varied from sub 1 nm to 15 nm, while the shape of Pt can be controlled to cube, cuboctahedron, and octahedron. The 3D model catalysts were generated by the incorporation of metal nanoparticles into the pores of mesoporous silica supports via two methods: capillary inclusion (CI) and nanoparticle encapsulation (NE). The former method relies on the sonication-induced inclusion of metal nanoparticles into the pores of mesoporous silica, whereas the latter is performed by the encapsulation of metal nanoparticles during the hydrothermal synthesis of mesoporous silica. The 3D model catalysts were comprehensively characterized by a variety of physical and chemical methods. These catalysts were found to show structure sensitivity in hydrocarbon conversion reactions. The Pt NPs supported on mesoporous SBA-15 silica (Pt/SBA-15) displayed significant particle size sensitivity in ethane hydrogenolysis over the size range of 1-7 nm. The Pt/SBA-15 catalysts also exhibited particle size dependent product selectivity in cyclohexene hydrogenation, crotonaldehyde hydrogenation, and pyrrole hydrogenation. The Rh loaded SBA-15 silica catalyst showed structure sensitivity in CO oxidation reaction. In addition, Pt-mesoporous silica core-shell structured NPs (Pt{at}mSiO{sub 2}) were prepared, where the individual Pt NP is encapsulated by the mesoporous silica layer. The Pt{at}mSiO{sub 2} catalysts showed promising catalytic activity in high temperature CO oxidation. The design of catalytic structures with tunable parameters by rational synthetic methods presents a major advance in the field of catalyst synthesis, which would lead to uncover the structure-function relationships in heterogeneous catalytic reactions.

Somorjai, G.A.

2009-09-14T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Lattice Boltzmann Methods for Fluid-Structure Interaction Problems  

E-Print Network (OSTI)

Lattice Boltzmann Methods for Fluid-Structure Interaction Problems Alfonso Caiazzo, Eric Lorenz, Firdaouss M, Lallemand P. Momentum transfer on a Boltzmann lattice fluid with Boundaries, Phys. Fluids 13, 3452-3459, 2002. [2] Caiazzo, A. Asymptotic Analysis of lattice Boltzmann Method for Fluid- Structure

422

Geophysical Fluid Dynamics Laboratory Review May 20 May 22, 2014  

E-Print Network (OSTI)

in modeling fluid dynamics and heat transfer in large facilities is being applied to the analysis of new might use 25% less fuel than a conventional vehicle. Cool Designs for Hot Spaces Computational Fluid Computational Fluid Dynamics model. (Image Right) Image showing the geometry of a typical Computational Fluid

423

New fluids help increase effectiveness of hydraulic fracturing  

SciTech Connect

It is important to choose the most effective fluid for hydraulic fracturing a particular formation. Fracturing fluids are used to initiate formation parting, extend the fracture into the reservoir, and to transport and distribute proppant. This paper discusses the fundamental of fluid types, viscosifiers, and fluid rheology.

Ebinger, C.D.; Hunt, E.

1989-06-05T23:59:59.000Z

424

Fundamentals of Engineering (FE) Exam Fluid Mechanics Review  

E-Print Network (OSTI)

one unit area layer of a substance over another ļæ½ Viscosity (ļæ½): measure of a fluid's resistance Energy, Friction Loss, and Pipe Flow Momentum and Drag #12;Pressure ļæ½ Gage pressure: measured relative Engineering March 22, 2013 #12;Morning (Fluid Mechanics) A. Flow measurement B. Fluid properties C. Fluid

Provancher, William

425

Boston University Department of Mechanical Engineering ME 303 Fluid Mechanics  

E-Print Network (OSTI)

Boston University Department of Mechanical Engineering ME 303 Ā­ Fluid Mechanics Fall 2011 Class: EK301 Engineering Mechanics Course Textbook: Fundamentals of Fluid Mechanics, 6th ed., Munson B. Reference Texts: Fluid Mechanics, Landau and Lifshitz, Vol. 6 Fluid Mechanics, Y. Cengel and J. Cimbala

426

Hydrogen production in Multi-Channel Membrane Reactor via Steam Methane Reforming and Methane Catalytic Combustion  

Science Journals Connector (OSTI)

Abstract A novel Multi-Channel Membrane Reactor (MCMR) was designed and built for the small-scale production of hydrogen via Steam Methane Reforming (SMR). The prototype alternates an SMR gas channel to produce hydrogen catalytically, with a Methane Catalytic Combustion (MCC) gas channel to provide the heat of reaction needed by the endothermic reforming. A palladium–silver membrane inside the reforming gas channel shifts the reaction equilibrium, allowing lower operating temperatures, and producing pure hydrogen in a single vessel. Using an innovative air-spray coating technique, channels were coated with Ru–MgO–La2O3/?-Al2O3 and Pd/?-Al2O3 catalyst particles for the SMR and MCC reactions, respectively. Results for the proof-of-concept MCMR showed that methane conversion in the reformer of 91% and a hydrogen purity in excess of 99.99% were possible with the reformer operating at 570 °C and 15 bar.

Alexandre Vigneault; John R. Grace

2014-01-01T23:59:59.000Z

427

Production of algae-based biodiesel using the continuous catalytic Mcgyan® process  

Science Journals Connector (OSTI)

This study demonstrates the production of algal biodiesel from Dunaliella tertiolecta, Nannochloropsis oculata, wild freshwater microalgae, and macroalgae lipids using a highly efficient continuous catalytic process. The heterogeneous catalytic process uses supercritical methanol and porous titania microspheres in a fixed bed reactor to catalyze the simultaneous transesterification and esterification of triacylglycerides and free fatty acids, respectively, to fatty acid methyl esters (biodiesel). Triacylglycerides and free fatty acids were converted to alkyl esters with up to 85% efficiency as measured by 300 MHz 1H NMR spectroscopy. The lipid composition of the different algae was studied gravimetrically and by gas chromatography. The analysis showed that even though total lipids comprised upwards of 19% of algal dry weight the saponifiable lipids, and resulting biodiesel, comprised only 1% of dry weight. Thus highlighting the need to determine the triacylglyceride and free fatty acid content when considering microalgae for biodiesel production.

Brian J. Krohn; Clayton V. McNeff; Bingwen Yan; Daniel Nowlan

2011-01-01T23:59:59.000Z

428

Synthesis and Characterization of Transition Metal Complexes Useful for the Catalytic Deconstruction of Lignin  

SciTech Connect

Lignin is an earth-abundant biopolymer that is grossly underutilized as a source of fuels and value-added chemicals. However, lignin is an intractable heteropolymer, which makes it difficult to deconstruct and upgrade in many chemically selective biomass conversion routes. The development of new catalytic routes to depolymerize this recalcitrant biopolymer is required to more effectively utilize lignin. To that end, our group aims to synthesize and characterize a collection of inorganic and organometallic catalysts to promote atom-economical catalytic lignin depolymerization. These catalysts have been screened against a continuum of model compounds and biomass-derived lignin for their usefulness in the deconstruction of these substrates. In addition, we have coupled our experimental efforts with quantum mechanical calculations to elucidate the mechanisms of catalysts to identify the mechanisms of lignin depolymerization. Detailed synthetic procedures, as well as spectroscopic and crystallographic characterization and DFT calculations will be presented.

Chmely, S. C.; Kim, S.; Beckham, G. T.

2012-01-01T23:59:59.000Z

429

Integrated Catalytic Process for Biomass Conversion and Upgrading to C12 Furoin and Alkane Fuel  

Science Journals Connector (OSTI)

Integrated Catalytic Process for Biomass Conversion and Upgrading to C12 Furoin and Alkane Fuel ... Accordingly, this work was directed at accomplishing the following three goals: (a) to investigate possible glucose isomerization to fructose by organocatalysis; (b) to establish an efficient, economical, integrated catalytic process for converting inexpensive biomass feedstocks such as fructose (currently at ?$32 per 100 g) to DHMF through generation of the high-purity HMF intermediate; and (c) to identify a bifunctional HDO catalyst system that can convert C12 DHMF to n-C12H26 alkane more selectively for achieving higher atom efficiency. ... Specifically, 2,5-dimethylfuran (derived from lignocellulosic biomass through 5-(hydroxymethyl)furfural) and acrolein (produced from glycerol, a side product of biodiesel production) were converted into the key intermediate p-xylene (a precursor of terephthalic acid). ...

Dajiang (D. J.) Liu; Eugene Y.-X. Chen

2014-03-18T23:59:59.000Z

430

Modeling the kinetics of parallel thermal and catalytic hydrotreating of heavy oil  

Science Journals Connector (OSTI)

Abstract A series of experiments were performed for obtaining the kinetics of the parallel thermal and catalytic hydrotreating reactions. The reactions considered were: hydrodesulfurization, hydrodenitrogenation (basic and non-basic), hydrodemetallization, hydrodeasphaltenization and hydro Conradson carbon removal. Hydrodesulfurization reaction was described by Langmuir–Hinshelwood kinetics while the other reactions were modeled with power-law approach. The tests were carried out in a CSTBR at the following conditions: 380–420 °C, 9.8 MPa, 891 std m3/m3 of hydrogen-to-oil ratio, 0.98–2.56 of g feed/(g cat h), and 200 h of time-on-stream. The developed kinetic model incorporates the effectiveness factor and a time-dependant deactivation function for obtaining the intrinsic kinetic parameters. It was demonstrated that at low severity reaction conditions the reactions occur via catalytic route, while at high severity conditions thermal reactions are more favored.

Jeremķas Martķnez; Jorge Ancheyta

2014-01-01T23:59:59.000Z

431

Numerical simulation of the two-dimensional flow in high pressure catalytic combustor for gas turbine  

Science Journals Connector (OSTI)

The objective of this paper is modeling the mechanism of high pressure and high temperature catalytic oxidation of natural gas, or methane. The model is two-dimensional steady-state, and includes axial and radial convection and diffusion of mass, momentum and energy, as well as homogeneous (gas phase) and heterogeneous (gas surface) single step irreversible chemical reactions within a catalyst channel. Experimental investigations were also made of natural gas, or methane combustion in the presence of Mn-substituted hexaaluminate catalysts. Axial profiles of catalyst wall temperature, and gas temperature and gas composition for a range of gas turbine combustor operating conditions have been obtained for comparison with and development of a computer model of catalytic combustion. Numerical calculation results for atmospheric pressure agree well with experimental data. The calculations have been extended for high pressure (10 atm) operating conditions of gas turbine.

Y. Tsujikawa; S. Fujii; H. Sadamori; S. Ito; S. Katsura

1995-01-01T23:59:59.000Z

432

Selective catalytic reduction used at Scanraff to reduce NO{sub x}, particulate emissions from FCCU  

SciTech Connect

This article describes various studies conducted to identify how the Scanraff Refinery in Sweden could best comply with environmental legislation for NO{sub x} and particulate emissions. Initial work identified flue gas from the catalyst regenerator of the fluidized catalytic cracking unit as the largest single source of NO{sub x} emissions. A more detailed study identified process modifications to reduce emissions, including the addition of a selective catalytic reduction (SCR) unit and a ceramic hot-gas filter. For the SCR unit, subtopics discussed include design option selection, SCR size and performance, selection of catalyst, catalyst configuration and performance, contamination, and modification of the waste heat boiler. The description of the hot-gas filtration system includes a comparison with electrostatic precipitator systems, the Schumacher filter, filtration medium, design temperature, and handling.

Brook, P.; Hagger, B.; Wood, J. [Foster Wheeler Energy Limited, Reading (United Kingdom)

1996-12-31T23:59:59.000Z

433

Catalytic igniters and their use to ignite lean hydrogen-air mixtures  

DOE Patents (OSTI)

A catalytic igniter which can ignite a hydrogen-air mixture as lean as 5.5% hydrogen with induction times ranging from 20 s to 400 s, under conditions which may be present during a loss-of-liquid-coolant accident at a light water nuclear reactor comprises (a) a perforate catalytically active substrate, such as a platinum coated ceramic honeycomb or wire mesh screen, through which heated gases produced by oxidation of the mixture can freely flow and (b) a plurality of thin platinum wires mounted in a thermally conductive manner on the substrate and positioned thereon so as to be able to receive heat from the substrate and the heated gases while also in contact with unoxidized gases.

McLean, William J. (Oakland, CA); Thorne, Lawrence R. (Livermore, CA); Volponi, Joanne V. (Livermore, CA)

1988-01-01T23:59:59.000Z

434

Catalytic and reactive polypeptides and methods for their preparation and use  

DOE Patents (OSTI)

Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the binding site, where the active functionality is capable of catalyzing or chemically participating in the chemical reaction in such a way that the reaction rate is enhanced. Methods for preparing the catalytic peptides include chemical synthesis, site-directed mutagenesis of antibody and enzyme genes, covalent attachment of the functionalities through particular amino acid side chains, and the like. This invention was made with Government support under Grant Contract No. AI-24695, awarded by the Department of health and Human Services, and under Grant Contract No. N 00014-87-K-0256, awarded by the Office of Naval Research. The Government has certain rights in this invention.

Schultz, Peter (Oakland, CA)

1994-01-01T23:59:59.000Z

435

Electro-catalytic oxidation device for removing carbon from a fuel reformate  

DOE Patents (OSTI)

An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

Liu, Di-Jia (Naperville, IL)

2010-02-23T23:59:59.000Z

436

Low density microcellular carbon or catalytically impregnated carbon foams and process for their preparation  

DOE Patents (OSTI)

Machinable and structurally stable, low density microcellular carbon, and catalytically impregnated carbon, foams, and process for their preparation, are provided. Pulverized sodium chloride is classified to improve particle size uniformity, and the classified particles may be further mixed with a catalyst material. The particles are cold pressed into a compact having internal pores, and then sintered. The sintered compact is immersed and then submerged in a phenolic polymer solution to uniformly fill the pores of the compact with phenolic polymer. The compact is then heated to pyrolyze the phenolic polymer into carbon in the form of a foam. Then the sodium chloride of the compact is leached away with water, and the remaining product is freeze dried to provide the carbon, or catalytically impregnated carbon, foam.

Hooper, R.W.; Pekala, R.W.

1987-04-30T23:59:59.000Z

437

A 25 kWe low concentration methane catalytic combustion gas turbine prototype unit  

Science Journals Connector (OSTI)

Abstract Low concentration methane, emitted from various industries e.g. coal mines and landfills into atmosphere, is not only an important greenhouse gas, but also a wasted energy resource if not utilized. In the past decade, we have been developing a novel VAMCAT (ventilation air methane catalytic combustion gas turbine) technology. This turbine technology can be used to mitigate methane emissions for greenhouse gas reduction, and also to utilize the low concentration methane as an energy source. This paper presents our latest research results on the development and demonstration of a 25 kWe lean burn catalytic combustion gas turbine prototype unit. Recent experimental results show that the unit can be operated with 0.8 vol% of methane in air, producing about 19–21 kWe of electricity output.

Shi Su; Xinxiang Yu

2014-01-01T23:59:59.000Z

438

Influence of Activation (Reduction) Conditions on the Catalytic Activity of Copper-Zinc Catalysts of NTK-10 Series  

Science Journals Connector (OSTI)

X-ray phase analysis and the temperature-programmed reduction method were applied to study the activation (reduction) of copper-zinc catalysts of the NTK-10 series. The catalytic activity of catalysts reduced ...

P. D. Androsov; I. A. Mamaeva; E. Z. Golosman

2004-07-01T23:59:59.000Z

439

Relation between the characteristics of the pitches produced on the basis of heavy gas-oil of catalytic cracking  

SciTech Connect

Mesophase pitches are often used to produce carbon fibers. Results of microanalysis and fiber-forming ability of the pitches are described. The pitches were obtained by the catalytic cracking of heavy gas-oil.

Nikolaeva, L.V.; Bulanova, V.V. [Rossiiskaya Akadeiya, Nauk (Russian Federation)

1995-12-31T23:59:59.000Z

440

Catalytic Deoxygenation of Tall Oil Fatty Acids Over a Palladium-Mesoporous Carbon Catalyst: A New Source of Biofuels  

Science Journals Connector (OSTI)

Catalytic deoxygenation of tall oil fatty acids (TOFA) was demonstrated over palladium catalysts supported on mesoporous carbon at 300 °C using dodecane as a solvent. Maximally 95% selectivity to linear C17 hy...

Bartosz Rozmys?owicz; Päivi Mäki-Arvela; Siswati Lestari…

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Porous Clays and Pillared Clays-Based Catalysts. Part 2: A Review of the Catalytic and Molecular Sieve Applications  

Science Journals Connector (OSTI)

Metal oxide pillared clay (PILC) possesses several interesting properties, such as ... /metal oxide pillars. These unique characteristics make PILC an attractive material in catalytic reactions. It...5..., 5 1998...

Z. Ding; J.T. Kloprogge; R.L. Frost; G.Q. Lu; H.Y. Zhu

2001-12-01T23:59:59.000Z

442

Experimental and numerical study of the behavior of three-way catalytic converters under different engine operation conditions  

E-Print Network (OSTI)

The thesis reports the studies on how the three-way catalytic converters behave under different operation conditions. The main focus of the work is in the oxygen storage capacity of the three-way catalyst. Rich-to-lean ...

Zhang, Yuetao

2005-01-01T23:59:59.000Z

443

Catalytic activity in the hydrocarbon conversion of systems containing platinum, nickel, iron, and zinc nanoparticles (communication 2)  

Science Journals Connector (OSTI)

The catalytic activity of metal-containing zeolites modified by nanosized Pt, Ni, Fe, and Zn powders was studied in the process of upgrading the petroleum straight-run gasoline fractions. It was found that the in...

L. M. Velichkina; A. N. Pestryakov; A. V. Vosmerikov…

2008-09-01T23:59:59.000Z

444

"Nanotechnology Enabled Advanced Industrial Heat Transfer Fluids"  

SciTech Connect

ABSTRACT Nanotechnology Enabled Advanced industrial Heat Transfer Fluids” Improving the efficiency of Industrial Heat Exchangers offers a great opportunity to improve overall process efficiencies in diverse industries such as pharmaceutical, materials manufacturing and food processing. The higher efficiencies can come in part from improved heat transfer during both cooling and heating of the material being processed. Additionally, there is great interest in enhancing the performance and reducing the weight of heat exchangers used in automotives in order to increase fuel efficiency. The goal of the Phase I program was to develop nanoparticle containing heat transfer fluids (e.g., antifreeze, water, silicone and hydrocarbon-based oils) that are used in transportation and in the chemical industry for heating, cooling and recovering waste heat. Much work has been done to date at investigating the potential use of nanoparticle-enhanced thermal fluids to improve heat transfer in heat exchangers. In most cases the effect in a commercial heat transfer fluid has been marginal at best. In the Phase I work, we demonstrated that the thermal conductivity, and hence heat transfer, of a fluid containing nanoparticles can be dramatically increased when subjected to an external influence. The increase in thermal conductivity was significantly larger than what is predicted by commonly used thermal models for two-phase materials. Additionally, the surface of the nanoparticles was engineered so as to have a minimal influence on the viscosity of the fluid. As a result, a nanoparticle-laden fluid was successfully developed that can lead to enhanced heat transfer in both industrial and automotive heat exchangers

Dr. Ganesh Skandan; Dr. Amit Singhal; Mr. Kenneth Eberts; Mr. Damian Sobrevilla; Prof. Jerry Shan; Stephen Tse; Toby Rossmann

2008-06-12T23:59:59.000Z

445

Theory, Investigation, and Stability of Cathode Electro-catalytic ActivityĀ„Georgia Institute of Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory, Investigation, and Stability of Theory, Investigation, and Stability of Cathode Electro-catalytic Activity- Georgia Institute of Technology Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide fuel cells (SOFCs) for

446

Informatics guided discovery of surface structure-chemistry relationships in catalytic nanoparticles  

SciTech Connect

A data driven discovery strategy based on statistical learning principles is used to discover new correlations between electronic structure and catalytic activity of metal surfaces. From the quantitative formulations derived from this informatics based model, a high throughput computational framework for predicting binding energy as a function of surface chemistry and adsorption configuration that bypasses the need for repeated electronic structure calculations has been developed.

Andriotis, Antonis N., E-mail: andriot@iesl.forth.gr [Institute of Electronic Structure and Laser, FORTH, P.O. Box 1527, 71110 Heraklio, Crete (Greece); Mpourmpakis, Giannis, E-mail: gmpourmp@pitt.edu [Department of Chemical Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15621 (United States)] [Department of Chemical Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15621 (United States); Broderick, Scott, E-mail: broderick.scott@gmail.com; Rajan, Krishna, E-mail: krajan@iastate.edu [Materials Science and Engineering, Iowa State University, Ames, Iowa 50011 (United States)] [Materials Science and Engineering, Iowa State University, Ames, Iowa 50011 (United States); Datta, Somnath, E-mail: somnath.datta@louisville.edu [Department of Bioinformatics and Biostatistics, University of Louisville, Louisville, Kentucky 40202 (United States)] [Department of Bioinformatics and Biostatistics, University of Louisville, Louisville, Kentucky 40202 (United States); Sunkara, Mahendra, E-mail: mahendra@louisville.edu [Department of Chemical Engineering, University of Louisville, Louisville, Kentucky 40202 (United States)] [Department of Chemical Engineering, University of Louisville, Louisville, Kentucky 40202 (United States); Menon, Madhu, E-mail: super250@uky.edu [Department of Physics and Astronomy and Center for Computational Sciences, University of Kentucky, Lexington, Kentucky 40506 (United States)] [Department of Physics and Astronomy and Center for Computational Sciences, University of Kentucky, Lexington, Kentucky 40506 (United States)

2014-03-07T23:59:59.000Z

447

Effects of boundaries on pattern formation: Catalytic oxidation of CO on platinum  

SciTech Connect

The effect of boundaries on pattern formation was studied for the catalytic oxidation of carbon monoxide on platinum surfaces. Photolithography was used to create microscopic reacting domains on polycrystalline foils and single-crystal platinum (110) surfaces with inert titanium overlayers. Certain domain geometries give rise to patterns that have not been observed on the untreated catalyst and bring to light surface mechanisms that have no analog in homogeneous reaction-diffusion systems.

Graham, M.D. (Univ. of Wisconsin, Madison (United States)); Kevrekidis, I.G. (Princeton Univ., NJ (United States)); Asakura, K.; Lauterbach, J.; Krischer, K.; Rotermund, H.H.; Ertl, G. (Fritz-Haber-Institut de Max-Planck-Gesellschaft, Berlin (Germany))

1994-04-01T23:59:59.000Z

448

Comparative Study on the Electronic Structure of Arc-Discharge and Catalytic Carbon Nanotubes  

Science Journals Connector (OSTI)

Comparative Study on the Electronic Structure of Arc-Discharge and Catalytic Carbon Nanotubes ... A perfect nanotube may be thought of as a cylindrical graphene sheet composed only of hexagons with a few pentagonal rings needed to close the tips.1 The typical carbon nanotubes formed under high temperature conditions, which can be induced by an electric arc for example, are predominantly straight having the largest numbers of topological defects at their ends. ...

L. G. Bulusheva; A. V. Okotrub; I. P. Asanov; A. Fonseca; J. B. Nagy

2001-05-05T23:59:59.000Z

449

The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes  

E-Print Network (OSTI)

THE CATALETIC REDUCTION OF NITRIC OXIDE NITH AMMONIA OVER TETRARPMINECOPPER(11) COMPLEXES A Thesis by Margaret Deron Oates Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1979 Major Subject: Chemistry THE CATALYTIC REDUCTION OF NITRIC OXIDE WITH AMMONIA OVER TETRAAMMINECOPPER(IZ) COMPLEXES A Thesis by Margaret Deron Dates Approved as to style and content by: (Chairman of Committe (Member...

Oates, Margaret Deron

1979-01-01T23:59:59.000Z

450

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

451

Heterogeneous catalytic wet peroxide oxidation of phenol over delaminated Fe–Ti-PILC employing microwave irradiation  

Science Journals Connector (OSTI)

Delaminated Fe-exchanged Ti-pillared interlayered montmorillonite (Fe–Ti-PILC) was prepared and its catalytic performance as heterogeneous catalyst in wet hydrogen peroxide oxidation of phenol employing microwave irradiation was firstly evaluated. The obtained results indicated that the application of the catalyst allows a comparatively high removal of COD and a total elimination of phenol under mild conditions, without obvious leaching of iron species. The introduction of microwave irradiation could greatly shorten the reaction time.

Jian Guo Mei; Shao Ming Yu; Jun Cheng

2004-01-01T23:59:59.000Z

452

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

453

Idle catalytic reformer can be converted to isomerization unit or jet-fuel treater  

SciTech Connect

This article discusses the economic advantages in conversion of catalytic reformers idled by reduced demand or rendered obsolete by replacement with modern technology. An older semi-regenerative reformer can be converted to a modern C4 or C5/C6 isomerization unit or to a kerosene hydrotreater to meet jet fuel specifications. Reactor design parameters operating conditions, and equipment sizing required for the highly endothermic reforming process are discussed.

Cobb, D.D.; Chapel, D.G.

1985-06-03T23:59:59.000Z

454

Catalytic pyrolysis of straight-run gasoline on a promoted vanadium catalyst  

SciTech Connect

Over the years the catalytic pyrolysis has been studied of various hydrocarbon materials - from gaseous (ethane, propane and n-butane) to heavy petroleum fractions with an end boiling point higher than 500/sup 0/C. The process indices for all the raw materials studied were significantly better than those from thermal pyrolysis. Improvement of operational properties for the vanadium catalyst for pyrolysis involved the selecting a better acceptor and the use of promotor additives which inhibit coke formation.

Chernykh, S.P.; Adel'son, S.V.; Rudyk, E.M.; Zhagfarov, F.G.; Motorina, I.A.; Nikonov, V.I.; Mukhina, T.N.; Barabanov, N.L.; Pyatiletov, V.I.

1983-04-01T23:59:59.000Z

455

High-pressure reaction and emissions characteristics of catalytic reactors for gas turbine combustors  

Science Journals Connector (OSTI)

The reaction and emissions characteristics of catalytic reactors comprising noble metal catalysts were investigated using homogeneous mixtures of natural gas and vitiated air at pressures up to 2.9 MPa. The mixture temperatures at inlet ranged from 500 to 700°C and the fuel-air ratio was increased till the exit gas temperature reached about 1200°C. Values of combustion efficiency greater than 99.5% and nitrogen oxides emissions for all catalytic reactors tested were less than 0.2 g NO2/kg fuel (2 ppm (15% 02) ) for all reactors at reactor exit gas temperatures higher than about 1100°C. Combustion efficiency decreased with increasing pressure in the heterogeneous-reaction controlled region, though a pressure increase favored homogeneous, gas phase reactions. Appreciable reactivity deterioration by aging for 1000 h at 1000°C was observed at lower mixture temperatures. A two-stage combustor comprising a conventional flame combustion stage and a catalytic stage was fabricated and its NO,x emissions and performance were evaluated at conditions typical of stationary gas turbine combustor operations. About 80% reduction in NO,x emissions levels compared with flame combustion was attained at 1 \\{MPa\\} pressure and 1180°C exit gas temperature, together with complete hydrocarbon combustion.

S. Hayashi; H. Yamada; K. Shimodaira

1995-01-01T23:59:59.000Z

456

Carbon Dioxide Conversion to Valuable Chemical Products over Composite Catalytic Systems  

SciTech Connect

Presented is an experimental study on catalytic conversion of carbon dioxide into methanol, ethanol and acetic acid. Catalysts having different catalytic functions were synthesized and combined in different ways to enhance selectivity to desired products. The combined catalyst system possessed the following functions: methanol synthesis, Fischer-Tropsch synthesis, water-gas-shift and hydrogenation. Results showed that the methods of integrating these catalytic functions played important role in achieving desired product selectivity. It was speculated that if methanol synthesis sites were located adjacent to the C-C chain growth sites, the formation rate of C2 oxygenates would be enhanced. The advantage of using high temperature methanol catalyst PdZnAl in the combined catalyst system was demonstrated. In the presence of PdZnAl catalyst, the combined catalyst system was stable at temperature of 380oC. It was observed that, at high temperature, kinetics favored oxygenate formation. Results implied that the process can be intensified by operating at high temperature using Pd-based methanol synthesis catalyst. Steam reforming of the byproduct organics was demonstrated as a means to provide supplemental hydrogen. Preliminary process design, simulation, and economic analysis of the proposed CO2 conversion process were carried out. Economic analysis indicates how ethanol production cost was affected by the price of CO2 and hydrogen.

Dagle, Robert A.; Hu, Jianli; Jones, Susanne B.; Wilcox, Wayne A.; Frye, John G.; White, J. F.; Jiang, Juyuan; Wang, Yong

2013-05-01T23:59:59.000Z

457

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange  

Science Journals Connector (OSTI)

selective catalytic reduction; chabazite; SAPO-34; Cu-SAPO-34; diesel engine; emission control; NOx ... NOx storage-reduction (NSR) and selective catalytic reduction (SCR) are leading NOx emission control techniques for such lean-burn diesel engines. ... (8, 47) However, severe intracrystalline mass-transfer limitations for Cu-SSZ-13, due apparently to the small-pore opening structure of Chabazite, complicates such fundamental studies. ...

Feng Gao; Eric D. Walter; Nancy M. Washton; Jįnos Szanyi; Charles H. F. Peden

2013-08-01T23:59:59.000Z

458

Fluid samplers: sampling music keyboards having fluidly continuous action and sound, without being electrophones  

Science Journals Connector (OSTI)

Present-day sampling music keyboards are electronic instruments that fall under the last (5th) category of the Hornbostel Sachs musical instrument classification scheme. Conversely, we first propose an entirely acoustic/mechanical mellotron-like sampling ... Keywords: fluid sampling, fluid user-interfaces, hydraulophones, interactive art, tangible user interfaces, water-based immersive multimedia

Steve Mann; Ryan E. Janzen

2007-09-01T23:59:59.000Z

459

Br-Cl-Na systematics in Illinois basin fluids: Constraints on fluid origin and evolution  

SciTech Connect

The authors present here bromide, chloride, and sodium data for fluids from reservoirs of Ordovician through Pennsylvania age in the Illinois basic which suggest that remnant marine fluids contribute significantly to fluid Cl budgets. Cl/Br and NaBr ratios for Ordovician through Devonian formation fluids are relatively uniform and near those for seawater, despite greater than a factor of ten range in Cl concentration. In contrast, fluids from Mississippian and Pennsylvanian reservoirs, separated from older reservoirs by the New Albany Shale Group, have more variable fluid Cl/Br and Na/Br ratios, most of which are significantly greater then those of seawater. The 1:1 stoichiometry of Cl and Na increases for Mississippian and Pennsylvanian formation fluids is consistent with halite dissolution. Nevertheless, Br systematics and mass-balance considerations indicate that he overall Cl budget of Illinois basin formation fluids appears to be more significantly influenced by the contribution from subaerially evaporated seawater than by halite dissolution.

Walter, L.M.; Huston, T.J. (Washington Univ., St. Louis, Missouri (USA)); Stueber, A.M. (Southern Illinois Univ., Edwardsville (USA))

1990-04-01T23:59:59.000Z

460

Phys. Fluids. Two spheres in a free stream of a second-order fluid  

E-Print Network (OSTI)

Phys. Fluids. Two spheres in a free stream of a second-order fluid A. M. Ardekani1 , R. H. Rangel1 , and D. D. Joseph1,2 1 Department of Mechanical and Aerospace Engineering University of California, Irvine, CA 92697 and 2 Department of Aerospace Engineering and Mechanics University of Minnesota, MN

Joseph, Daniel D.

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Advanced binary cycles: Optimum working fluids  

SciTech Connect

A computer model (Cycle Analysis Simulation Tool, CAST) and a methodology have been developed to perform value analysis for small, low- to moderate-temperature binary geothermal power plants. The value analysis method allows for incremental changes in the levelized electricity cost (LEC) to be determined between a baseline plant and a modified plant. Thermodynamic cycle analyses and component sizing are carried out in the model followed by economic analysis which provides LEC results. The emphasis of the present work is on evaluating the effect of mixed working fluids instead of pure fluids on the LEC of a geothermal binary plant that uses a simple Organic Rankine Cycle. Four resources were studied spanning the range of 265 F to 375 F. A variety of isobutane and propane based mixtures, in addition to pure fluids, were used as working fluids. This study shows that the use of propane mixtures at a 265 F resource can reduce the LEC by 24% when compared to a base case value that utilizes commercial isobutane as its working fluid. The cost savings drop to 6% for a 375 F resource, where an isobutane mixture is favored. Supercritical cycles were found to have the lowest cost at all resources.

Gawlik, K.; Hassani, V. [National Renewable Energy Lab., Golden, CO (United States)

1997-12-31T23:59:59.000Z

462

Electrorheological fluid under elongation, compression, and shearing  

Science Journals Connector (OSTI)

Electrorheological (ER) fluid based on zeolite and silicone oil under elongation, compression, and shearing was investigated at room temperature. Dc electric fields were applied on the ER fluid when elongation and compression were carried out on a self-constructed test system. The shear yield stress, presenting the macroscopic interactions of particles in the ER fluid along the direction of shearing and perpendicular to the direction of the electric field, was also obtained by a HAAKE RV20 rheometer. The tensile yield stress, presenting the macroscopic interactions of particles in the ER fluid along the direction of the electric field, was achieved as the peak value in the elongating curve with an elongating yield strain of 0.15–0.20. A shear yield angle of about 15°–18.5° reasonably connected tensile yield stress with shear yield stress, agreeing with the shear yield angle tested well by other researchers. The compressing tests showed that the ER fluid has a high compressive modulus under a small compressive strain lower than 0.1. The compressive stress has an exponential relationship with the compressive strain when it is higher than 0.1, and it is much higher than shear yield stress.

Y. Tian; Y. Meng; H. Mao; S. Wen

2002-03-06T23:59:59.000Z

463

Ultrasonic fluid flow measurement method and apparatus  

DOE Patents (OSTI)

An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible.

Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

1993-01-01T23:59:59.000Z

464

Ultrasonic fluid flow measurement method and apparatus  

DOE Patents (OSTI)

An apparatus for measuring the flow of a fluid in a pipe using ultrasonic waves. The apparatus comprises an ultrasonic generator, a lens for focusing the sound energy produced by the generator, and means for directing the focused energy into the side of the pipe through an opening and in a direction close to parallel to the long axis of the pipe. A cone carries the sound energy to the lens from the generator. Depending on the choice of materials, there may be a quarter-wave, acoustic impedance matching section between the generator and the cone to reduce the reflections of energy at the cone boundary. The lens material has an acoustic impedance similar to that of the cone material but a different sonic velocity so that the lens can converge the sound waves in the fluid. A transition section between the lens and the fluid helps to couple the energy to the fluid and assures it is directed as close to parallel to the fluid flow direction as possible. 3 figures.

Kronberg, J.W.

1993-10-12T23:59:59.000Z

465

Fluid-bed combustion of solid wastes  

SciTech Connect

For over ten years combustion Power Company has been conducting experimental programs and developing fluid bed systems for agencies of the federal government and for private industry and institutions. Many of these activities have involved systems for the combustion of solid waste materials. Discussed here will be three categories of programs, development of Municipal Solid Waste (MSW) fired fluid beds, development of wood waste fired fluid beds, and industrial installations. Research and development work on wood wastes has led to the design and construction of two large industrial fluid bed combustors. In one of these, a fluid bed is used for the generation of steam with a fuel that was previously suited only for landfill. Rocks and inerts are continuously removed from this combustor using a patented system. The second FBC is designed to use a variety of fuels as the source of energy to dry hog fuel for use in a high performance power boiler. Here the FBC burns green hog fuel, log yard debris, fly ash (char) from the boiler, and dried wood fines to produce a hot gas system for the wood dryer. A significant advantage of the fluidized bed reactor over conventional incinerators is its ability to reduce noxious gas emission and, finally, the fluidized bed is unique in its ability to efficiently consume low quality fuels. The relatively high inerts and moisture content of solid wastes pose no serious problem and require no associated additional devices for their removal.

Vander Molen, R.H.

1980-01-01T23:59:59.000Z

466

A theoretical approach for assessing the role of rock and fluid properties in the development of abnormal fluid pressures  

E-Print Network (OSTI)

and shales. The important parameters determining the extent of fluid pressure preservation are the geothermal gradient, the thermal loading rate, and the hydraulic diffusivity, K/Ss, of the rock . The highest fluid pressure development is expected... Variation of fluid expansivity and fluid compressibility with depth for a 25C/km geothermal gradient Page 14 Pressure response in different rock types and for various boundary conditions under . constant fluid mass 25 Values of or/Bf as a function...

Hastings, Thomas Worcester

2012-06-07T23:59:59.000Z

467

High-Energy-Density Plasmas, Fluids  

NLE Websites -- All DOE Office Websites (Extended Search)

High-Energy-Density Plasmas, Fluids High-Energy-Density Plasmas, Fluids /science-innovation/_assets/images/icon-science.jpg High-Energy-Density Plasmas, Fluids National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. TRIDENT target chamber Sasi Palaniyappan, right, and Rahul Shah left inside a target chamber where the TRIDENT short pulse laser is aimed at a very thin diamond- foil target, a fraction of a micrometer thick. The laser delivers a power on target of 150 Terawatts focused into a 7 micrometer spot, yielding laser brilliance over 100 times more intense than needed to make the target electrons fully relativistic. These experiments test novel methods of producing intense

468

Thermal Fluid Multiphysics Optimization of Spherical Tokamak  

SciTech Connect

An experimental Fusion Nuclear Science Facility (FNSF) is required that will create the environment that simultaneously achieves high energy neutrons and high ion fluence necessary in order to bridge the gaps from ITER to the realization of a fusion nuclear power plant. One concept for achieving this is a high duty cycle spherical torus. This study will focus on thermal modeling of the spherical torus centerpost using computational fluid dynamics to effectively model the thermal transfer of the cooling fluid to the centerpost. The design of the fluid channels is optimized in order to minimize the temperature in the centerpost. Results indicate the feasibility of water cooling for a long-pulse spherical torus FNSF.

Lumsdaine, Arnold [ORNL; Tipton, Joseph B [ORNL; Peng, Yueng Kay Martin [ORNL

2012-01-01T23:59:59.000Z

469

Carbon-bearing fluids at nanoscale interfaces  

SciTech Connect

The behaviour of fluids at mineral surfaces or in confined geometries (pores, fractures) typically differs from their bulk behaviour in many ways due to the effects of large internal surfaces and geometrical confinement. We summarize research performed on C-O-H fluids at nanoscale interfaces in materials of interest to the earth and material sciences (e.g., silica, alumina, zeolites, clays, rocks, etc.), emphasizing those techniques that assess microstructural modification and/or dynamical behaviour such as gravimetric analysis, small-angle (SANS) neutron scattering, and nuclear magnetic resonance (NMR). Molecular dynamics (MD) simulations will be described that provide atomistic characterization of interfacial and confined fluid behaviour as well as aid in the interpretation of the neutron scattering results.

Cole, David [Ohio State University; Ok, Salim [Ohio State University, Columbus; Phan, A [Ohio State University, Columbus; Rother, Gernot [ORNL; Striolo, Alberto [Oklahoma University; Vlcek, Lukas [ORNL

2013-01-01T23:59:59.000Z

470

Detecting low levels of radionuclides in fluids  

DOE Patents (OSTI)

An apparatus and method for detecting low levels of one or more radionuclides in a fluid sample uses a substrate that includes an ion exchange resin or other sorbent material to collect the radionuclides. A collecting apparatus includes a collecting chamber that exposes the substrate to a measured amount of the fluid sample such that radionuclides in the fluid sample are collected by the ion exchange resin. A drying apparatus, which can include a drying chamber, then dries the substrate. A measuring apparatus measures emissions from radionuclides collected on the substrate. The substrate is positioned in a measuring chamber proximate to a detector, which provides a signal in response to emissions from the radionuclides. Other analysis methods can be used to detect non-radioactive analytes, which can be collected with other types of sorbent materials.

Patch, Keith D. (Lexington, MA); Morgan, Dean T. (Sudbury, MA)

2000-01-01T23:59:59.000Z

471

Convective heat transfer in the vertical channel flow of a clear fluid adjacent to a nanofluid layer: a two-fluid model  

Science Journals Connector (OSTI)

A two-fluid vertical channel flow and convective heat transfer model in which one of the two fluids is a nanofluid demonstrates that the nanofluid can modify the fluid velocity at the interface of the two fluids,...

Robert A. Van Gorder; K. V. Prasad; K. Vajravelu

2012-07-01T23:59:59.000Z

472

The Geometric Structure of Complex Fluids  

E-Print Network (OSTI)

This paper develops the theory of affine Euler-Poincar\\'e and affine Lie-Poisson reductions and applies these processes to various examples of complex fluids, including Yang-Mills and Hall magnetohydrodynamics for fluids and superfluids, spin glasses, microfluids, and liquid crystals. As a consequence of the Lagrangian approach, the variational formulation of the equations is determined. On the Hamiltonian side, the associated Poisson brackets are obtained by reduction of a canonical cotangent bundle. A Kelvin-Noether circulation theorem is presented and is applied to these examples.

Franēois Gay-Balmaz; Tudor S. Ratiu

2009-03-25T23:59:59.000Z

473

Geomechanical Simulation of Fluid-Driven Fractures  

SciTech Connect

The project supported graduate students working on experimental and numerical modeling of rock fracture, with the following objectives: (a) perform laboratory testing of fluid-saturated rock; (b) develop predictive models for simulation of fracture; and (c) establish educational frameworks for geologic sequestration issues related to rock fracture. These objectives were achieved through (i) using a novel apparatus to produce faulting in a fluid-saturated rock; (ii) modeling fracture with a boundary element method; and (iii) developing curricula for training geoengineers in experimental mechanics, numerical modeling of fracture, and poroelasticity.

Makhnenko, R.; Nikolskiy, D.; Mogilevskaya, S.; Labuz, J.

2012-11-30T23:59:59.000Z

474

Homothetic perfect fluid space-times  

E-Print Network (OSTI)

A brief summary of results on homotheties in General Relativity is given, including general information about space-times admitting an r-parameter group of homothetic transformations for r>2, as well as some specific results on perfect fluids. Attention is then focussed on inhomogeneous models, in particular on those with a homothetic group $H_4$ (acting multiply transitively) and $H_3$. A classification of all possible Lie algebra structures along with (local) coordinate expressions for the metric and homothetic vectors is then provided (irrespectively of the matter content), and some new perfect fluid solutions are given and briefly discussed.

J. Carot; A. M. Sintes

1996-07-24T23:59:59.000Z

475

Vibration of Nanoparticles in Viscous Fluids  

Science Journals Connector (OSTI)

In this article, we present results of a rigorous finite-element analysis and commensurate scaling theory that enable interpretation and analysis of these experiments, for the extensional vibrational modes of axisymmetric nanoparticles immersed in viscous fluids. ... (51) Vibration of the particle accelerates the fluid, which increases the effective mass of the vibrating particle. ... Using low-frequency Raman scattering, the authors clearly demonstrate that single-domain NCs vibrate differently than their multiply twinned counterparts, through the splitting of the quadrupolar vibrations, which is only obsd. ...

Debadi Chakraborty; Emma van Leeuwen; Matthew Pelton; John E. Sader

2013-03-21T23:59:59.000Z

476

Friction-Induced Fluid Heating in Nanoscale Helium Flows  

SciTech Connect

We investigate the mechanism of friction-induced fluid heating in nanoconfinements. Molecular dynamics simulations are used to study the temperature variations of liquid helium in nanoscale Poiseuille flows. It is found that the fluid heating is dominated by different sources of friction as the external driving force is changed. For small external force, the fluid heating is mainly caused by the internal viscous friction in the fluid. When the external force is large and causes fluid slip at the surfaces of channel walls, the friction at the fluid-solid interface dominates over the internal friction in the fluid and is the major contribution to fluid heating. An asymmetric temperature gradient in the fluid is developed in the case of nonidentical walls and the general temperature gradient may change sign as the dominant heating factor changes from internal to interfacial friction with increasing external force.

Li Zhigang [Department of Mechanical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

2010-05-21T23:59:59.000Z

477

Catalytic Micropumps: Microscopic Convective Fluid Flow and Pattern Timothy R. Kline, Walter F. Paxton, Yang Wang, Darrell Velegol,*, Thomas E. Mallouk,* and  

E-Print Network (OSTI)

or concentration gradients.4 Heterogeneous catalysis offers a new and potentially powerful alternative. Energy from and rings; 1.8 Āµm diameter car- boxylated polystyrene spheres were used as tracers to follow the flow

478

Method and apparatus for chemically altering fluids in continuous flow  

DOE Patents (OSTI)

The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation.

Heath, William O. (Richland, WA); Virden, Jr., Judson W. (Richland, WA); Richardson, R. L. (West Richland, WA); Bergsman, Theresa M. (Richland, WA)

1993-01-01T23:59:59.000Z

479

Method and apparatus for chemically altering fluids in continuous flow  

DOE Patents (OSTI)

The present invention relates to a continuous flow fluid reactor for chemically altering fluids. The reactor operates on standard frequency (50 to 60 Hz) electricity. The fluid reactor contains particles that are energized by the electricity to form a corona throughout the volume of the reactor and subsequently a non-equilibrium plasma that interacts with the fluid. Particles may form a fixed bed or a fluid bed. Electricity may be provided through electrodes or through an inductive coil. Fluids include gases containing exhaust products and organic fuels requiring oxidation. 4 figures.

Heath, W.O.; Virden, J.W. Jr.; Richardson, R.L.; Bergsman, T.M.

1993-10-19T23:59:59.000Z

480

Qualitative and Quantitative On-line Analysis of Thermal Cracker Effluent by GC  

Science Journals Connector (OSTI)

......complete sampling, analysis, and data reduction...components and permits an analysis from hydrogen up to...reproducibility and reliability of results. Selection...location allows for analysis on an absolute basis...the feed section, the reactor section, the analytical......

C.E. Van Camp; P.J. Clymans; P.S. Van Damme; G.F. Froment

1983-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "fluid catalytic cracker" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Accounting for Remaining Injected Fracturing Fluid  

E-Print Network (OSTI)

The technology of multi-stage fracturing of horizontal wells made the development of shale gas reservoirs become greatly successful during the past decades. A large amount of fracturing fluid, usually from 53,000 bbls to 81,400 bbls, is injected...

Zhang, Yannan

2013-12-06T23:59:59.000Z

482

Experimental verification of bifurcation in fluid bearings  

E-Print Network (OSTI)

The thesis presents the results of the experiments that were conducted on short and long fluid film bearings with a simple single disk rotor. The behavior of the journal was analyzed as function of the rotor system parameters such as the load, speed...

Deepak, James Christopher

1997-01-01T23:59:59.000Z

483

Superconducting Topological Fluids in Josephson Junction Arrays  

E-Print Network (OSTI)

We argue that the frustrated Josephson junction arrays may support a topologically ordered superconducting ground state, characterized by a non-trivial ground state degeneracy on the torus. This superconducting quantum fluid provides an explicit example of a system in which superconductivity arises from a topological mechanism rather than from the usual Landau-Ginzburg mechanism.

M. Cristina Diamantini; Pasquale Sodano; Carlo A. Trugenberger

2006-04-21T23:59:59.000Z

484

Paleotemperatures preserved in fluid inclusions in halite  

SciTech Connect

A variety of paleoclimate proxy records allow determination of relative warming or cooling. However, if we are to understand climate change, quantification of past temperature fluctuations is essential. Our research indicates that fluid inclusions in halite can yield homogenization temperatures that record surface brine temperatures at the time of halite precipitation. To avoid problems with stretching, leaking, and initial trapping of air, samples with primary, single-phase (liquid) fluid inclusions are chilled in a freezer to nucleate vapor bubbles. We tested the reliability of this method of obtaining fluid-inclusion homogenization temperatures using modern salts precipitated at Badwater Basin, Death Valley, California. Homogenization temperatures correlate well with measured brine temperatures. The same method is applied to fluid inclusions in Pleistocene halite from a core taken at the same location in Death Valley. Results are at several scales, recording diurnal temperature variations, seasonal temperature fluctuations, and longer-term warming and cooling events that correlate with major changes in the sedimentary environment related to climate. This technique is uniquely instrumental for paleoclimate studies because it offers actual, not just proxy, paleotemperature data. 27 refs., 17 figs.

Roberts, S.M.; Spencer, R.J. [Univ. of Calgary, Alberta (Canada)] [Univ. of Calgary, Alberta (Canada)

1995-10-01T23:59:59.000Z

485

Using Nanotechnology in Viscoelastic Surfactant Stimulation Fluids  

E-Print Network (OSTI)

USING NANOTECHNOLOGY IN VISCOELASTIC SURFACTANT STIMULATION FLUIDS A Thesis by MERVE RABIA GURLUK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... .......................................... 9 1.7 Kinetics of Micellization ......................................................................... 10 1.8 Nanotechnology ....................................................................................... 16...

Gurluk, Merve Rabia 1986-

2012-11-12T23:59:59.000Z

486

Newtonian fluid flow through Microfabricated Hyperbolic Contractions  

E-Print Network (OSTI)

spraying (Barnes et al. 1989). Optimization of these processes requires accurate measurements for measurement of extensional viscosity involves studying the fluid flow through contractions profiled to give extensional viscosity. To remove the effect of shear at the walls of contractions Shaw (1975) proposed the use

487

Supercritical Fluid Extraction- Process Simulation and Design  

E-Print Network (OSTI)

SIMULATION P-1 SFE FEED PUMP SUPERCRITICAL FLUID EXTRACTOR (SFE) 2 T-1 10 7 .r D-2 SFE BOnoMS FLASH 9 222 The extract is decanted and fed to the fractionator to recover solvent carbon dioxide overhead and waterlIPA/carbon dioxide out...

Martin, C. L.; Seibert, A. F.

488

Recent Developments in Geothermal Drilling Fluids  

SciTech Connect

In the past, standard drilling muds have been used to drill most geothermal wells. However, the harsh thermal and chemical environment and the unique geothermal formations have led to such problems as excessive thickening of the fluid, formation damage, and lost circulation. This paper describes three recent development efforts aimed at solving some of these drilling fluid problems. Each of the efforts is at a different stage of development. The Sandia aqueous foam studies are still in the laboratory phase, NL Baroid's polymeric deflocculant is soon to be field tested, and the Mudtech high-temperature mud was field tested several months ago. Low density and the capability to suspend particles at low relative velocities are two factors which make foam an attractive drilling fluid. The stability of these foams and their material properties at high temperatures are presently unknown and this lack of information has precluded their use as a geothermal drilling fluid. The aqueous foam studies being conducted at Sandia are aimed at screening available surfactants for temperature and chemical stability. Approximately 100 surfactants have been tested at temperatures of 260 and 310 C (500 and 590 F), and several of these candidates appear very promising. NL Baroid has developed a polymeric deflocculant for water-based muds which shows promise in retarding thermal degradation effects and associated gelation. Formulations containing this new polymer have shown good rheological properties up to 260 C (500 F) in laboratory testing. A high-temperature mud consisting primarily of sepiolite, bentonite, and brown coal has been developed by Mudtech, Inc. A field test of this mud was conducted in a geothermal well in the Imperial Valley of California in May 1980. The fluid exhibited good hole-cleaning characteristics and good rheological properties throughout the test.

Kelsey, J. R.; Rand, P. B.; Nevins, M. J.; Clements, W. R.; Hilscher, L. W.; Remont, L. J.; Matula, G. W.; Balley, D. N.

1981-01-01T23:59:59.000Z

489

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS Int. J. Numer. Meth. Fluids (2012)  

E-Print Network (OSTI)

are still within reasonable range. Nevertheless, for test case two, which has higher density and viscosity, emulsification, spraying and so on. The kinematics and dynamics of the fluid interfaces play an important role

Frey, Pascal

490

Final Report: Catalytic Hydrocarbon Reactions over Supported Metal Oxides, August 1, 1995 - July 31, 1999  

SciTech Connect

The research program focused on the catalysis of hydrodesulfurization (HDS) over molybdenum-based catalysts and how catalyst composition, redox ability, structure and neighboring sites control the catalytic properties of metal oxides. We sought to understand the catalytic features/sites that control hydrogenation, hydrogenolysis, and isomerization during HDS. Unprompted silica-supported molybdenum oxides and molybdenum sulfides were studied. Model catalyst systems were prepared from organometallic precursors or cluster compounds to generate supported structures that feature Mo(II) and Mo(IV) cations that are isolated or in ensembles and that have either Mo-O or Mo-S bonds. Conventional MOS{sub 2} catalysts, which contain both edge and rim sites, were be studied. Finally, single-layer MOS{sub 2} structures were also prepared from 2H-MoS{sub 2} powder so that the model systems could be compared against a disulfide catalyst that only involves rim sites. Catalytic reactions for thiophene and tetrahydrothione were studied over the various catalysts. Oxidation states were determined using X-ray photoelectron spectroscopy. X-ray crystallography was used to characterize and follow changes in the MOS{sub 2} structures. The program on metal oxides prepared supported oxides that have a specific structure and oxidation state to serve as model templates for the more complex commercial catalysts and then employed these structures in reaction studies. This focus area examined the relationships between structure and cation redox characteristics in oxidation catalysis. Infrared and Raman spectroscopy were used to characterize the cations and reaction intermediates.

Ekerdt, John G.

1999-07-31T23:59:59.000Z

491

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

SciTech Connect

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

492

Aluminosilicates as controlled molecular environments for selective photochemical and catalytic reactions  

SciTech Connect

This dissertation concerns research that involves photochemical, catalytic and spectroscopic studies of clays, pillared clays and zeolites. Incorporation of uranyl ions into hectorite, montmorillonite, bentonite and vermiculite clays was monitored by XRD and luminescence methods. Excitation and emission characteristics were studied in order to understand the behavior of uranyl ions in clays after various thermal treatments. Luminescence lifetime measurements elucidated the number of uranyl sites. Uranyl-exchanged clays were found to absorb light at lower energies (445-455nm) than analogous uranyl-exchanged zeolites (425nm). Each uranyl-exchanged clay was tested as a catalyst for the photoassisted oxidation of isopropyl alcohol. Energy transfer (ET) between uranyl and Eu(III) ions in different zeolite framework systems was examined. The efficiency of ET (eta/sub t/) was found to be affected by the type of framework present. Pillared bentonites were examined in the hydrocracking of decane. A catalytically and spectroscopically active dopant ion, Cr(III), was introduced into the clays in both pillared and unpillared forms depending upon synthetic conditions. EPR and DRS were employed to monitor the environment of Cr(III) for determination of its location - whether in the micropore structure or associated with alumina pillars. Catalytic behavior based upon this variability of location was examined. Incorporation of Cr(III) ions into an alumina pillar was found to increase the stability and activity with respect to an alumina PILC catalyst. The results of these studies suggest that selective, efficient catalysts can be designed around inorganic ions in aluminosilicate supports.

Carrado, K.A.

1986-01-01T23:59:59.000Z

493

Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.  

E-Print Network (OSTI)

2 H 2 CH 3 CH 3 Scheme 2. Ethylene Hydrogenation Reaction. HHydrogenation Reaction. Table 1 Ethylene Hydrogenation RatesCatalytic Activity for Ethylene and Pyrrole Hydrogenation

Huang, Wenyu

2009-01-01T23:59:59.000Z

494

E-Print Network 3.0 - acoustic energy-driven fluid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

search results for: acoustic energy-driven fluid Page: << < 1 2 3 4 5 > >> 1 Acoustic Identification of Unknown Fluids Summary: Acoustic Identification of Unknown Fluids...

495

FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL RESERVOIR | Open Energy  

Open Energy Info (EERE)

FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL RESERVOIR FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL RESERVOIR Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: FLUID STRATIGRAPHY OF THE COSO GEOTHERMAL RESERVOIR Details Activities (1) Areas (1) Regions (0) Abstract: A fluid model for the Coso geothermal reservoir is developed from Fluid Inclusion Stratigraphy (FIS) analyses. Fluid inclusion gas chemistry in well cuttings collected at 20 ft intervals is analyzed and plotted on well log diagrams. The working hypothesis is that select gaseous species and species ratios indicate areas of groundwater and reservoir fluid flow, fluid processes and reservoir seals. Boiling and condensate zones are distinguished. Models are created using cross-sections and fence diagrams. A thick condensate and boiling zone is indicated across the western portion

496

Building Technologies Office: Recovery Act-Funded Working Fluid Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Working Fluid Projects to someone by E-mail Working Fluid Projects to someone by E-mail Share Building Technologies Office: Recovery Act-Funded Working Fluid Projects on Facebook Tweet about Building Technologies Office: Recovery Act-Funded Working Fluid Projects on Twitter Bookmark Building Technologies Office: Recovery Act-Funded Working Fluid Projects on Google Bookmark Building Technologies Office: Recovery Act-Funded Working Fluid Projects on Delicious Rank Building Technologies Office: Recovery Act-Funded Working Fluid Projects on Digg Find More places to share Building Technologies Office: Recovery Act-Funded Working Fluid Projects on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Appliances Research Building Envelope Research Windows, Skylights, & Doors Research Space Heating & Cooling Research

497

Category:Fluid Lab Analysis | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Category Edit History Facebook icon Twitter icon Ā» Category:Fluid Lab Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Fluid Lab Analysis page? For detailed information on exploration techniques, click here. Category:Fluid Lab Analysis Add.png Add a new Fluid Lab Analysis Technique Pages in category "Fluid Lab Analysis" The following 5 pages are in this category, out of 5 total. C Compound and Elemental Analysis F Fluid Inclusion Analysis I Isotopic Analysis- Fluid M Mercury Vapor T Trace Element Analysis Retrieved from "http://en.openei.org/w/index.php?title=Category:Fluid_Lab_Analysis&oldid=689846"

498

Exergy Effectiveness Analysis of Three-Fluid Heat Exchanger  

Science Journals Connector (OSTI)

In this paper, exergy effectiveness is defined to describe the thermodynamic ... ratio of the inlet temperature of fluids on exergy effectiveness of three-fluid heat exchangers. Furthermore, the exergy effectiven...

Deng-Fang Ruan; Xiao-Feng Yuan…

2010-08-01T23:59:59.000Z

499

Oil-Based Drilling Fluids: Are they an Environmental Risk?  

Science Journals Connector (OSTI)

The use of oil-based drilling fluids has been discouraged in hydrocarbon exploration ... and production in the marine environment but these drilling fluids are presently being used to a ... Sea have demonstrated ...

F. Payne Jerry; L. Fancey; J. Kiceniuk…

1987-01-01T23:59:59.000Z

500

Time-lapse seismic monitoring of subsurface fluid flow  

E-Print Network (OSTI)

Time-lapse seismic monitoring repeats 3 D seismic imaging over a reservoir to map fluid movements in a reservoir. During hydrocarbon production, the fluid saturation, pressure, and temperature of a reservoir change, thereby altering the acoustic...

Yuh, Sung H.

2004-09-30T23:59:59.000Z