Sample records for flue gas heat

  1. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  2. The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas

    E-Print Network [OSTI]

    Henderson, W. R.; DeBiase, J. F.

    1983-01-01T23:59:59.000Z

    . During low demand periods, the unit is gas-fired and produces 150 psi steam at high efficiency. In the fall, the heat exchanger is converted to accept flue gas from the large original water tube boilers. The flue gas heats water, which preheats make...

  3. The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas 

    E-Print Network [OSTI]

    Henderson, W. R.; DeBiase, J. F.

    1983-01-01T23:59:59.000Z

    The Beckett Heat Recovery is a series of techniques for recovering low-grade waste heat from flue gas. Until the cost of fossil fuels began rising rapidly, flue gas below 600 F was considered economically unworthy of reclaim. This paper...

  4. Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams

    E-Print Network [OSTI]

    Latcham, Jacob G. (Jacob Greco)

    2009-01-01T23:59:59.000Z

    An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

  5. Recovery of Water from Boiler Flue Gas

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

    2008-09-30T23:59:59.000Z

    This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

  6. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31T23:59:59.000Z

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  7. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; John DuPoint

    2011-03-31T23:59:59.000Z

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

  8. Combined Flue Gas Heat Recovery and Pollution Control Systems

    E-Print Network [OSTI]

    Zbikowski, T.

    1979-01-01T23:59:59.000Z

    in the field of heat recovery now make it possible to recover a portion of the wasted heat and improve the working conditions of the air purification equipment. Proper design and selection of heat recovery and pollution control equipment as a combination...

  9. Evaluation of the Energy Saving Potential from Flue Gas Pressurization 

    E-Print Network [OSTI]

    Stanton, E. H.

    1980-01-01T23:59:59.000Z

    The potential for recovering energy from low pressure furnace flue products is limited when standard heat recovery equipment is utilized. Efficient energy recovery can be accomplished by providing a flue gas side pressure drop across a heat...

  10. Evaluation of the Energy Saving Potential from Flue Gas Pressurization

    E-Print Network [OSTI]

    Stanton, E. H.

    1980-01-01T23:59:59.000Z

    The potential for recovering energy from low pressure furnace flue products is limited when standard heat recovery equipment is utilized. Efficient energy recovery can be accomplished by providing a flue gas side pressure drop across a heat...

  11. E-Print Network 3.0 - advanced flue gas Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flue gas losses and minimized in... generated from flue gas condensation for district heating. Twence is another example, where a high degree... into a reusable ash and that...

  12. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01T23:59:59.000Z

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  13. Mercury sorbent delivery system for flue gas

    SciTech Connect (OSTI)

    Klunder; ,Edgar B. (Bethel Park, PA)

    2009-02-24T23:59:59.000Z

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  14. OpenEI Community - natural gas+ condensing flue gas heat recovery+ water

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff<div/0 en TheResult

  15. Final Flue Gas Cleaning (FFGC)

    E-Print Network [OSTI]

    Stinger, D. H.; Romero, M. H.

    2006-01-01T23:59:59.000Z

    the surrounding area but can also be carried thousands of miles by trade winds before falling to ground level to pollute soil, vegetation and water resources. An obvious question is: why doesn’t industry cool the flue gas; condense out the pollutants... of handling and disposing of these pollutants at the plant site. 2. Oxides of sulfur and nitrogen can condense out as an acid, including carbonic acid that attacks materials of construction. By keeping temperatures elevated, carbon steel construction can...

  16. Final Flue Gas Cleaning (FFGC) 

    E-Print Network [OSTI]

    Stinger, D. H.; Romero, M. H.

    2006-01-01T23:59:59.000Z

    .F., Blythe, OG.M., Carey, T.R., Radian International & Rhudy, R.G., EPRI & Brown, T.D., Federal Energy Technology Center-DOE, ”Enhanced Control of Mercury by Wet FGD Systems, 1999 f Gramite. Evan J. and Pennline, Henry W., “Photochemical Removal of Mercury... from the Texas Commission on Environmental Quality (TCEQ). The pilot plant (FFGC-PP) will be used to test and evaluate removal of air pollution constituents from the flue gas of a power plant to determine the optimum emission reduction system...

  17. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01T23:59:59.000Z

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  18. Construction and testing of a flue-gas corrosion probe

    SciTech Connect (OSTI)

    Federer, J.I.; McEvers, J.A.

    1990-08-01T23:59:59.000Z

    The selection of suitable materials for industrial, waste-heat- recovery systems requires assessment of corrosion of materials in various flue-gas environments. Such assessments involve exposing candidate materials to high-temperature flue gases and analyzing the effects of the exposure conditions. Because corrosion is related to flue-gas chemical composition and temperature, variations in temperature complicate the determination of corrosion rates and corrosion mechanisms. Conversely, a relatively constant temperature allows a more accurate determination of the effects of exposure conditions. For this reason, controlled-temperature flue-gas corrosion probes were constructed and tested for exposure tests of materials. A prototype probe consisted of a silicon carbide tube specimen, supporting hardware, and instrumentation for controlling temperature by internal heating and cooling. An advanced probe included other tubular specimens. Testing of the probes in an industrial-type furnace at a nominal flue-gas temperature of 1200{degree}C revealed that temperature control was inadequate. The cooling mode imposed a substantial axial-temperature gradient on the specimens; while the heating mode imposed a smaller gradient, the heating capacity was very limited. 10 refs., 10 figs., 2 tabs.

  19. Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas

    SciTech Connect (OSTI)

    Dexin Wang

    2012-03-31T23:59:59.000Z

    The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

  20. The Gonzaga desulfurization flue gas process

    SciTech Connect (OSTI)

    Kelleher, R.L.; O'Leary, T.J.; Shirk, I.A.

    1984-01-01T23:59:59.000Z

    The Gonzaga desulfurization flue gas process removes sulfur dioxide from a flue by cold water scrubbing. Sulfur dioxide is significantly more soluable in cold water (35/sup 0/F to 60/sup 0/F) than in warm water (100/sup 0/F). Sulfur dioxide reacts in water similarly as carbon dioxide reacts in water, in that both gasses are released from the water as the temperature of the water increases. The researchers at the Gonzaga University developed this process from the observations and techniques used in studying the acid and aldehyde concentrations in flue gasses with varying of fuel to air ratios. The apparatus was fixed to a stationary engine and a gas/oil fired boiler. The flue gas was cooled to the dew point temperature of the air entering the combustion chamber on the pre-air heater. The system is described in two parts: the energies required for cooling in the scrubbing section and the energies required in the treatment section. The cold flue gas is utilized in cooling the scrubber section.

  1. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  2. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  3. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  4. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18T23:59:59.000Z

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  5. Flue gas cleanup with hydroxyl radical reactions

    SciTech Connect (OSTI)

    Lee, Y.J.; Pennline, H.W.; Markussen, J.M.

    1990-02-01T23:59:59.000Z

    Electric discharge processes have been intensively tested for application to flue gas cleanup. Among the several means of OH- radical generation grouped as electric discharge, E-Beam irradiation is the one that has been most thoroughly studied. Corona glow discharge, especially pulsed corona glow discharge, on the other hand, has attracted attention recently, and several active research projects are being conducted in the United States, Japan, West Germany, and Italy. Other promising approaches for generating OH radicals efficiently are based on thermal or catalytic decomposition of OH-radical precursors. If mixing problems can be overcome to achieve homogeneous distribution of OH radicals in the flue gas stream, these methods may be applicable to flue gas cleanup. Because of their high OH-radical generation rates and potentially low capital costs, the following three approaches are recommended to be tested for their potential capability to remove SO{sub 2}/NO{sub x}: (1) H{sub 2}/O{sub 2} combustion in a hydrogen torch, (2) thermal decomposition of H{sub 2}O{sub 2}, and (3) catalytic decomposition of H{sub 2}O. Ideally, the OH radicals will convert SO{sub 2} and NO{sub x} to sulfuric acid and nitric acid. These acids or acid precursors would easily be removed from the flue gas by conventional technology, such as spray drying and wet limestone scrubbing. 67 refs., 2 tabs.

  6. Activation of flue gas nitrogen oxides by transition metal complexes

    SciTech Connect (OSTI)

    Miller, M.E.; Finseth, D.H.; Pennline, H.W.

    1987-01-01T23:59:59.000Z

    Sulfur and nitrogen oxides are major flue gas pollutants released by coal-fired electric power plants. In the atmosphere these oxides are converted to sulfuric and nitric acids, which contribute to the acid rain problem. Most of the nitrogen oxides present in coal-derived flue gas exist as the relatively inert and water-insoluble nitric oxide (NO), thus presenting a difficult removal problem. We present preliminary studies intended to establish basic homogeneous chemistry of transition metal complexes with nitrogen oxides. The transition metals considered in this work are volatile carbonyl complexes. The metal carbonyls took up nitric oxide homogeneously in the gas phase. Iron required uv light for reaction with NO, but the same result is expected with the application of heat. Metal carbonyls also reacted with nitrogen dioxide but produced polynuclear metal species. Oxygen did not attack the carbonyl or nitrosyl complexes. Results indicate high potential for NO/sub x/ removal from stack gases by sorption onto supported metal carbonyl complexes. The solid form allows ease in separation from the flue gas. Regeneration of the sorbent might be achieved by treating with CO to liberate NO/sub x/ by displacement or by heating to decompose and drive off NO/sub x/.

  7. Fundamental mechanisms in flue-gas conditioning

    SciTech Connect (OSTI)

    Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

    1992-01-09T23:59:59.000Z

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  8. System and method for monitoring wet bulb temperature in a flue gas stream

    SciTech Connect (OSTI)

    Glover, R.L.; Bland, V.V.

    1990-01-02T23:59:59.000Z

    This patent describes in a system for monitoring wet bulb temperature in a flue gas stream means for extracting a sample of the gas from the flue, means for heating the sample to maintain the sample at substantially the same temperature as the gas in the flue, a sensor for measuring the wet bulb temperature of the sample, a reservoir of liquid, a liquid absorbent wick surrounding the sensor and extending into the liquid in the reservoir, and means for maintaining the liquid in the reservoir at a substantially constant level.

  9. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30T23:59:59.000Z

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  10. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Andreas Weber; Raghubir P. Gupta

    2006-01-01T23:59:59.000Z

    This report describes research conducted between October 1, 2005, and December 31, 2005, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from flue gas from coal combustion. A field test was conducted to examine the extent to which RTI's supported sorbent can be regenerated in a heated, hollow screw conveyor. This field test was conducted at the facilities of a screw conveyor manufacturer. The sorbent was essentially completely regenerated during this test, as confirmed by thermal desorption and mass spectroscopy analysis of the regenerated sorbent. Little or no sorbent attrition was observed during 24 passes through the heated screw conveyor system. Three downflow contactor absorption tests were conducted using calcined sodium bicarbonate as the absorbent. Maximum carbon dioxide removals of 57 and 91% from simulated flue gas were observed at near ambient temperatures with water-saturated gas. These tests demonstrated that calcined sodium carbonate is not as effective at removing CO{sub 2} as are supported sorbents containing 10 to 15% sodium carbonate. Delivery of the hollow screw conveyor for the laboratory-scale sorbent regeneration system was delayed; however, construction of other components of this system continued during the quarter.

  11. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir Gupta; Alejandro Lopez-Ortiz

    2001-01-01T23:59:59.000Z

    Four grades of sodium bicarbonate and two grades of trona were characterized in terms of particle size distribution, surface area, pore size distribution, and attrition. Surface area and pore size distribution determinations were conducted after calcination of the materials. The sorbent materials were subjected to thermogravimetric testing to determine comparative rates and extent of calcination (in inert gas) and sorption (in a simulated coal combustion flue gas mixture). Selected materials were exposed to five calcination/sorption cycles and showed no decrease in either sorption capacity or sorption rate. Process simulations were conducted involving different heat recovery schemes. The process is thermodynamically feasible. The sodium-based materials appear to have suitable physical properties for use as regenerable sorbents and, based on thermogravimetric testing, are likely to have sorption and calcination rates that are rapid enough to be of interest in full-scale carbon sequestration processes.

  12. Noble metal catalysts for oxidation of mercury in flue gas

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2008-04-01T23:59:59.000Z

    The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

  13. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Bush, P.V.

    1992-04-27T23:59:59.000Z

    This project is divided into four tasks. The Management Plan was developed in task 1. Task 2, Evaluation of Mechanisms in FGD Sorbent and Ash Interactions, focuses on the characteristics of binary mixtures of these distinct powders. Task 3, Evaluation of Mechanisms in Conditioning Agents and Ash, is designed to examine the effects of various conditioning agents on fine ash particles to determine the mechanisms by which these agents alter the physical properties of the ash. Tasks 2 and 3 began with an extensive literature search and the assembly of existing theories. This phase of the project is now complete. During the past quarter, initial preparations of laboratory equipment for laboratory testing have been made. A plan for initial laboratory tests has been submitted to the Project Manager for review. Laboratory testing will commence once these laboratory plans have been formally approved. The results of the work performed under task 2 and 3 will be included in a Flue Gas Conditioning Model that will be issued under task 4. The Final Report for the project will also be prepared under task 4.

  14. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

    2001-05-01T23:59:59.000Z

    Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

  15. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Doctor, Richard D. (Glen Ellyn, IL); Wingender, Ronald J. (Deerfield, IL)

    1986-01-01T23:59:59.000Z

    A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

  16. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05T23:59:59.000Z

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  17. Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2012-11-06T23:59:59.000Z

    Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

  18. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30T23:59:59.000Z

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  19. Flue gas injection control of silica in cooling towers.

    SciTech Connect (OSTI)

    Brady, Patrick Vane; Anderson, Howard L., Jr.; Altman, Susan Jeanne

    2011-06-01T23:59:59.000Z

    Injection of CO{sub 2}-laden flue gas can decrease the potential for silica and calcite scale formation in cooling tower blowdown by lowering solution pH to decrease equilibrium calcite solubility and kinetic rates of silica polymerization. Flue gas injection might best inhibit scale formation in power plant cooling towers that use impaired makeup waters - for example, groundwaters that contain relatively high levels of calcium, alkalinity, and silica. Groundwaters brought to the surface for cooling will degas CO{sub 2} and increase their pH by 1-2 units, possibly precipitating calcite in the process. Recarbonation with flue gas can lower the pHs of these fluids back to roughly their initial pH. Flue gas carbonation probably cannot lower pHs to much below pH 6 because the pHs of impaired waters, once outgassed at the surface, are likely to be relatively alkaline. Silica polymerization to form scale occurs most rapidly at pH {approx} 8.3 at 25 C; polymerization is slower at higher and lower pH. pH 7 fluids containing {approx}220 ppm SiO{sub 2} require > 180 hours equilibration to begin forming scale whereas at pH 8.3 scale formation is complete within 36 hours. Flue gas injection that lowers pHs to {approx} 7 should allow substantially higher concentration factors. Periodic cycling to lower recoveries - hence lower silica concentrations - might be required though. Higher concentration factors enabled by flue gas injection should decrease concentrate volumes and disposal costs by roughly half.

  20. Biomimetic Membrane for CO2 Capture from Flue Gas

    SciTech Connect (OSTI)

    Michael C. Trachtenberg

    2007-05-31T23:59:59.000Z

    These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer model that supports prediction of heat transfer profiles for larger permeators Tasks 3. 4.1, 4.2--Temperature Range of Enzymes--The goal was to determine if the enzyme operating temperature would limit the range of thermal conditions available to the capture system. We demonstrated the ability of various isozymes (enzyme variants) to operate from 4-85 C. Consequently, the operating characteristics of the enzyme are not a controlling factor. Further, any isozyme whose upper temperature bound is at least 10 C greater than that of the planned inlet temperature will be stable under unanticipated, uncontrolled 'hiccups' in power plant operation. Task 4.4, 4.4--Examination of the Effects of SOx and NOx on Enzyme Activity (Development of Flue Gas Composition Acceptance Standards)--The purpose was to define the inlet gas profile boundaries. We examined the potential adverse effects of flue gas constituents including different acids from to develop an acceptance standard and compared these values to actual PC flue gas composition. Potential issues include changes in pH, accumulation of specific inhibitory anions and cations. A model was developed and validated by test with a SO{sub 2}-laden stream. The predicted and actual data very largely coincided. The model predicted feed stream requirements to allow continuous operation in excess of 2500 hours. We developed operational (physical and chemical) strategies to avoid or ameliorate these effects. Avoidance, the preferred strategy (noted above), is accomplished by more extensive cleanup of the flue gas stream. Task 5--Process Engineering Model--We developed a process-engineering model for two purposes. The first was to predict the physical and chemical status at each test point in the design as a basis for scale-up. The second was to model the capital and operating cost of the apparatus. These were accomplished and used to predict capex, opex and cost of energy. Task 6--Preliminary Commercialization Plan--We carried out analyses of the market and the competition by a variety of parameters. The conclusion was that there is a l

  1. Selecting the right pumps and valves for flue gas desulfurization

    SciTech Connect (OSTI)

    Ellis, D.; Ahluwalia, H. [ITT Engineered Valves, Lancaster, PA (United States)

    2006-07-15T23:59:59.000Z

    Limestone slurry needs to move efficiently through a complex process, meaning that selecting the right pumps and valves is critical. The article discusses factors to consider in selecting pumps and values for flue gas desulfurization process in coal-fired power plants. 2 photos.

  2. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-10-01T23:59:59.000Z

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport reactor systems is planned to demonstrate the feasibility of this process in large scale operations to separate carbon dioxide from flue gas.

  3. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Raghubir P. Gupta

    2006-03-31T23:59:59.000Z

    This report describes research conducted between January 1, 2006, and March 31, 2006, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. An integrated system composed of a downflow co-current contact absorber and two hollow screw conveyors (regenerator and cooler) was assembled, instrumented, debugged, and calibrated. A new batch of supported sorbent containing 15% sodium carbonate was prepared and subjected to surface area and compact bulk density determination.

  4. Dry scrubber reduces SO sub 2 in calciner flue gas

    SciTech Connect (OSTI)

    Brown, G.W. (Refining Consulting Services, Englewood, CO (US)); Roderick, D. (Western Slope Refining Co., Fruita, CO (US)); Nastri, A. (NATEC Resources Inc., Dallas, TX (US))

    1991-02-18T23:59:59.000Z

    This paper discusses the installation of a dry sulfur dioxide scrubber for an existing petroleum coke calciner at its Fruita, Colo., refinery. The dry scrubbing process was developed by the power industry to help cope with the acid rain problem. It is the first application of the process in an oil refinery. The process could also remove SO{sub 2} from the flue gas of a fluid catalytic cracker, fluid coker, or other refinery sources.

  5. The thief process for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Freeman, M.C.; Hargis, R.A.; O'Dowd, W.J.; Pennline, H.W.

    2007-09-01T23:59:59.000Z

    The Thief Process is a cost-effective variation to activated carbon injection (ACI) for removal of mercury from flue gas. In this scheme, partially combusted coal from the furnace of a pulverized coal power generation plant is extracted by a lance and then re-injected into the ductwork downstream of the air preheater. Recent results on a 500-lb/h pilot-scale combustion facility show similar removals of mercury for both the Thief Process and ACI. The tests conducted to date at laboratory, bench, and pilot-scales demonstrate that the Thief sorbents exhibit capacities for mercury from flue gas streams that are comparable to those exhibited by commercially available activated carbons. A patent for the process was issued in February 2003. The Thief sorbents are cheaper than commercially-available activated carbons; exhibit excellent capacities for mercury; and the overall process holds great potential for reducing the cost of mercury removal from flue gas. The Thief Process was licensed to Mobotec USA, Inc. in May of 2005.

  6. Activation of flue gas nitrogen oxides by transition metal complexes

    SciTech Connect (OSTI)

    Miller, M.E.; Finseth, D.H.; Pennline, H.W.

    1987-01-01T23:59:59.000Z

    Sulfur and nitrogen oxides are major flue gas pollutants released by coal-fired electric power plants. In the atmosphere these oxides are converted to sulfuric and nitric acids, which contribute to the acid rain problem. Most of the nitrogen oxides (90%-95%) present in coal-derived flue gas exist as the relatively inert and water-insoluble nitric oxide (NO), thus presenting a difficult removal problem. A practical strategy for nitrogen oxides removal might utilize a solid support that has been impregnated with an active transition metal complex. Some supported transition metals are expected to remove NO/sub x/ by sorption, with regeneration of the sorbent being a necessary property. Others catalyze NO oxidation to the more soluble NO/sub 2/ and N/sub 2/O/sub 5/, which has been demonstrated for certain transition metal species. These activated nitrogen oxides can be more efficiently removed along with SO/sub 2/ in conventional scrubbing or spray-drying processes, in which an aqueous slurry of sorbent, such as hydrated lime, is injected into the hot flue gas. We present here preliminary studies intended to establish basic homogeneous chemistry of transition metal complexes with nitrogen oxides. The transition metals considered in this work are volatile carbonyl complexes. This work is the first step in the development of supported metal species for enhanced nitrogen oxides removal.

  7. Alternative formulations of regenerable flue gas cleanup catalysts

    SciTech Connect (OSTI)

    Mitchell, M.B.; White, M.G.

    1991-01-01T23:59:59.000Z

    The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

  8. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

    2003-02-18T23:59:59.000Z

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  9. Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum

    SciTech Connect (OSTI)

    Hensman, Carl, E., P.h.D; Baker, Trevor

    2008-06-16T23:59:59.000Z

    Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

  10. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31T23:59:59.000Z

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  11. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2005-08-01T23:59:59.000Z

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

  12. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31T23:59:59.000Z

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  13. Supported polyethylenimine adsorbents for CO2 capture from flue gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Gray, M.L.; Pennline, H.W.

    2008-10-01T23:59:59.000Z

    Anthropogenic CO2 emissions produced from fossil fuel combustion are believed to contribute to undesired consequences in global climate. Major contributors towards CO2 emissions are fossil fuel-fired power plants for electricity production. For this reason, CO2 capture from flue gas streams together with permanent sequestration in geologic formations is being considered a viable solution towards mitigation of the major greenhouse gas1. Technologies based on chemical absorption with alkanolamines have been assessed for first generation CO2 post-combustion capture primarily due to its advanced stage of development. However, limitations associated with these chemical solvents (i.e., low CO2 loadings, amine degradation by oxygen, equipment corrosion) manifest themselves in high capital and operating costs with reduced thermal efficiencies. Therefore, necessary design and development of alternative, lower cost approaches for CO2 capture from coal-fired combustion streams are warranted.

  14. Separation of CO2 from flue gas using electrochemical cells

    SciTech Connect (OSTI)

    Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

    2010-06-01T23:59:59.000Z

    ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

  15. Advanced environmental control technology for flue gas cleanup

    SciTech Connect (OSTI)

    Pennline, H.W.; Drummond, C.J.

    1987-01-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) oversees a substantial research and development effort to develop advanced environmental control technology for coal-fired sources. This Flue Gas Cleanup Program is currently divided into five areas: combined SO/sub 2//NO/sub x/ control, SO/sub 2/ control, particulate control, NO/sub x/ control, and small-scale boiler emission control. Projects in these areas range from basic research studies to proof-of-concept-scale evaluations. Projects in the DOE program are conducted by universities, national laboratories, industrial organizations, and in-house research at the Pittsburgh Energy Technology Center. An overview of the program, together with brief descriptions of the status of individual projects are given.

  16. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01T23:59:59.000Z

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  17. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21T23:59:59.000Z

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  18. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

    2007-08-14T23:59:59.000Z

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  19. Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs

    E-Print Network [OSTI]

    Nogueira de Mago, Marjorie Carolina

    2005-11-01T23:59:59.000Z

    sequestration. In this thesis, I report my findings on the effect of flue gas ??impurities?? on the displacement of natural gas during CO2 sequestration, and results on unconfined compressive strength (UCS) tests to carbonate samples. In displacement experiments...

  20. New Developments in Closed Loop Combustion Control Using Flue Gas Analysis 

    E-Print Network [OSTI]

    Nelson, R. L.

    1981-01-01T23:59:59.000Z

    New developments in closed loop combustion control are causing radical changes in the way combustion control systems are implemented. The recent availability of in line flue gas analyzers and microprocessor technology are teaming up to produce...

  1. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers 

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01T23:59:59.000Z

    Chemical technology has been used successfully to solve many of the operational and emissions problems that result from burning coal. This paper describes the use of blended chemical flue gas conditioners to significantly reduce particulate...

  2. Flue gas desulfurization : cost and functional analysis of large-scale and proven plants

    E-Print Network [OSTI]

    Tilly, Jean

    1983-01-01T23:59:59.000Z

    Flue Gas Desulfurization is a method of controlling the emission of sulfurs, which causes the acid rain. The following study is based on 26 utilities which burn coal, have a generating capacity of at least 50 Megawatts ...

  3. Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J

    2008-07-01T23:59:59.000Z

    The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

  4. Analysis of Halogen-Mercury Reactions in Flue Gas

    SciTech Connect (OSTI)

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

    2010-01-01T23:59:59.000Z

    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

  5. Integration of a high efficiency flue gas cleanup process into advanced power systems

    SciTech Connect (OSTI)

    Hoffman, J.S.; Pennline, H.W.; Yeh, J.T.; Ratafia-Brown, J.A.; Gorokhov, V.A.

    1994-12-31T23:59:59.000Z

    The Moving-Bed Copper Oxide Process, a dry, regenerable flue gas cleanup technology, can simultaneously remove sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emissions from the flue gases generated by coal combustion. While this advanced air pollution abatement process technology has only been previously considered for conventional utility system applications, its unique design characteristics make it quite advantageous for use in advanced power systems, such as those pulverized-coal-fired systems defined in the US Department of Energy`s Combustion 2000 Initiative. Integration of this flue gas cleanup process into the advanced power systems is technically and economically assessed and compared with several commercially available flue gas cleanup processes. An update on the status of the Moving-Bed Copper oxide Process development is also presented.

  6. Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-08-31T23:59:59.000Z

    The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

  7. Low Temperature Heat Recovery for Boiler Systems 

    E-Print Network [OSTI]

    Shook, J. R.; Luttenberger, D. B.

    1986-01-01T23:59:59.000Z

    Low temperature corrosion proof heat exchangers designed to reduce boiler flue gas temperatures to 150°F or lower are now being commercially operated on gas, oil and coal fired boilers. These heat exchangers, when applied to boiler flue gas...

  8. Flue-gas carbon capture on carbonaceous sorbents: Toward a low-cost multifunctional Carbon Filter for 'Green' energy producers

    SciTech Connect (OSTI)

    Radosz, M.; Hu, X.D.; Krutkramelis, K.; Shen, Y.Q. [University of Wyoming, Laramie, WY (United States)

    2008-05-15T23:59:59.000Z

    A low-pressure Carbon Filter Process (patent pending) is proposed to capture carbon dioxide (CO{sub 2}) from flue gas. This filter is filled with a low-cost carbonaceous sorbent, such as activated carbon or charcoal, which has a high affinity (and, hence, high capacity) to CO{sub 2} but not to nitrogen (N{sub 2}). This, in turn, leads to a high CO{sub 2}/N{sub 2} selectivity, especially at low pressures. The Carbon Filter Process proposed in this work can recover at least 90% of flue-gas CO{sub 2} of 90%+ purity at a fraction of the cost normally associated with the conventional amine absorption process. The Carbon Filter Process requires neither expensive materials nor flue-gas compression or refrigeration, and it is easy to heat integrate with an existing or grassroots power plant without affecting the cost of the produced electricity too much. An abundant supply of low-cost CO{sub 2} from electricity producers is good news for enhanced oil recovery (EOR) and enhanced coal-bed methane recovery (ECBMR) operators, because it will lead to higher oil and gas recovery rates in an environmentally sensitive manner. A CO{sub 2}-rich mixture that contains some nitrogen is much less expensive to separate from flue-gas than pure CO{sub 2}; therefore, mixed CO{sub 2}/N{sub 2}-EOR and CO{sub 2}/N{sub 2}-ECBMR methods are proposed to maximize the overall carbon capture and utilization efficiency.

  9. In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas

    SciTech Connect (OSTI)

    NONE

    2008-04-01T23:59:59.000Z

    A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

  10. Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”

    SciTech Connect (OSTI)

    Granite, E.J.; Presto, A.A.

    2008-09-01T23:59:59.000Z

    A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

  11. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    SciTech Connect (OSTI)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30T23:59:59.000Z

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

  12. Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

    SciTech Connect (OSTI)

    Lee, S.H.D.; Swift, W.M.; Johnson, I.

    1980-01-01T23:59:59.000Z

    Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

  13. Proof-of concept testing of the advanced NOXSO flue gas cleanup process. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-04-01T23:59:59.000Z

    The NOXSO Process uses a regenerable sorbent that removes SO{sub 2} and NO{sub x} simultaneously from flue gas. The sorbent is a stabilized {gamma}-alumina bed impregnated with sodium carbonate. The process was successfully tested at three different scales, equivalent to 0.017, 0.06 and 0.75 MW of flue gas generated from a coal-fired power plant. The Proof-of-Concept (POC) Test is the last test prior to a full-scale demonstration. A slip stream of flue gas equivalent to a 5 MW coal-fired power plant was used for the POC test. This paper summarizes the NOXSO POC plant and its test results.

  14. Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using flue gas

    E-Print Network [OSTI]

    Subramanian, Venkat

    great potential for converting flue gas to biomass. Microalgae can capture solar energy more efficientlyExperimental analysis and model-based optimization of microalgae growth in photo-bioreactors using flue gas Lian He, Venkat R. Subramanian, Yinjie J. Tang* Department of Energy, Environmental

  15. Effect of connate water on miscible displacement of reservoir oil by flue gas 

    E-Print Network [OSTI]

    Maxwell, H. D.

    1960-01-01T23:59:59.000Z

    EFFECT OF CONNATE WATER ON MISCIBLE DISPLACEMENT OF RESERVOIR OIL BY FLUE GAS A Thesis By H. D. MAXWELL, JR. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE Au gus t, 19 60 Major Subject: PETROLEUM ENGINEERING EFFECT OF CONNATE WATER ON MISCIBLE DISPLACEMENT OF RESERVOIR OIL BY FLUE GAS A Thesis H. D. MAXWELL, JR. Approved as to style and content by: haxrman of ommitte...

  16. Compression stripping of flue gas with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); O'Connor, William K. (Lebanon, OR)

    2005-05-31T23:59:59.000Z

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  17. Compression Stripping of Flue Gas with Energy Recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; O'Connor, William K.

    2005-05-31T23:59:59.000Z

    A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

  18. Synthetic aggregates prepared from flue gas desulfurization by-products using various binder materials

    SciTech Connect (OSTI)

    Bellucci, J.; Graham, U.M.; Hower, J.C.; Robl, T.L. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1994-12-31T23:59:59.000Z

    Flue Gas Desulfurization (FGD) by-products can be converted into environmentally safe and structurally stable aggregates. One type of synthetic aggregate was prepared using an optimum mixture of (FGD) by-products, fly ash, and water. Mineral reactions have been examined using X-ray diffraction and scanning electron microscope.

  19. Separation of Carbon Dioxide from Nitrogen and Water in Flue Gas Streams 

    E-Print Network [OSTI]

    Mera, Hilda 1989-

    2012-04-12T23:59:59.000Z

    are determined by the mean-square displacement method derived by Albert Einstein. The diffusion coefficients of each component in the flue gas are analyzed to examine the effect of temperature in diffusion coefficients and study the motion of the gases in the MOF...

  20. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20T23:59:59.000Z

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  1. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31T23:59:59.000Z

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  2. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 10, February 17--May 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-15T23:59:59.000Z

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). One of the two flue gas ducts leading from the boiler has been retrofitted with the CZD technology. The first existing ESP installed in the station is immediately behind the air preheater. The second ESP, installed about 15 years ago, is about 80 feet away from the first ESP. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2}

  3. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01T23:59:59.000Z

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  4. Microalgae Production from Power Plant Flue Gas: Environmental Implications on a Life Cycle Basis

    SciTech Connect (OSTI)

    Kadam, K. L.

    2001-06-22T23:59:59.000Z

    Power-plant flue gas can serve as a source of CO{sub 2} for microalgae cultivation, and the algae can be cofired with coal. This life cycle assessment (LCA) compared the environmental impacts of electricity production via coal firing versus coal/algae cofiring. The LCA results demonstrated lower net values for the algae cofiring scenario for the following using the direct injection process (in which the flue gas is directly transported to the algae ponds): SOx, NOx, particulates, carbon dioxide, methane, and fossil energy consumption. Carbon monoxide, hydrocarbons emissions were statistically unchanged. Lower values for the algae cofiring scenario, when compared to the burning scenario, were observed for greenhouse potential and air acidification potential. However, impact assessment for depletion of natural resources and eutrophication potential showed much higher values. This LCA gives us an overall picture of impacts across different environmental boundaries, and hence, can help in the decision-making process for implementation of the algae scenario.

  5. Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass

    SciTech Connect (OSTI)

    Anuar, S.H.; Keener, H.M.

    1995-12-31T23:59:59.000Z

    The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

  6. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    SciTech Connect (OSTI)

    Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Yin, Hongxi [Southeast University, Nanjing, China

    2014-11-01T23:59:59.000Z

    Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

  7. Effect of connate water on miscible displacement of reservoir oil by flue gas

    E-Print Network [OSTI]

    Maxwell, H. D.

    1960-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE Au gus t, 19 60 Major Subject: PETROLEUM ENGINEERING EFFECT OF CONNATE WATER ON MISCIBLE DISPLACEMENT OF RESERVOIR OIL BY FLUE GAS A Thesis H. D. MAXWELL, JR. Approved as to style and content by: haxrman of ommitte... of the petroleum industry there has been a continually increasing search for more economical and more efficient methods for increasing the primary recovery from an oil reservoir. Better production practices, including pressure maintenance programs using both...

  8. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01T23:59:59.000Z

    FLUE GAS CONDITIONING TO REDUCE PARTICULATE EMISSIONS IN INDUSTRIAL COAL-FIRED BOILERS Barry Miller and Ed Keon Apollo Technologies, Inc. Whippany, New Jersey ABSTRACT Chemical technology has been used successfully to solve many... inspection of the ESP, careful observation of ESP controls to determine spark rate and voltage drop during sparking, in-situ resistivity mea surements, rapper on-off observations, and a re view of records to investigate the relationship of boiler...

  9. New Developments in Closed Loop Combustion Control Using Flue Gas Analysis

    E-Print Network [OSTI]

    Nelson, R. L.

    1981-01-01T23:59:59.000Z

    NEW DEVELOPMENTS IN CLOSED LOOP COMBUSTION CONTROL USING FLUE GAS ANALYSIS Robert L. Nelson Westinghouse Computer &Instrumentation Div. Orrville, Ohio Introduction New developments in closed loop combustion control are causing radical changes... the Third Industrial Energy Technology Conference Houston, TX, April 26-29, 1981 i The Westinghouse Model 215 analyzer, shown in j Figure 8, has a very short sampling path and has be~n used on many high temperature applications befor~ a high temperature...

  10. Investigation of the moving-bed copper oxide process for flue gas cleanup

    SciTech Connect (OSTI)

    Pennline, H.W.; Hoffman, J.S.; Yeh, J.T. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Resnik, K.P.; Vore, P.A. [Parsons Power Group, Inc., Pittsburgh, PA (United States)

    1996-12-31T23:59:59.000Z

    The Moving-Bed Copper Oxide Process is a dry, regenerable sorbent technique that uses supported copper oxide sorbent to simultaneously remove SO{sub 2} and NO{sub x} emissions from flue gas generated by coal combustion. The process can be integrated into the design of advanced power systems, such as the Low-Emission Boiler System (LEBS) or the High-Performance Power System (HIPPS). This flue gas cleanup technique is currently being evaluated in a life-cycle test system (LCTS) with a moving-bed flue gas contactor at DOE`s Pittsburgh Energy Technology Center. An experimental data base being established will be used to verify reported technical and economic advantages, optimize process conditions, provide scaleup information, and validate absorber and regenerator mathematical models. In this communication, the results from several process parametric test series with the LCTS are discussed. The effects of various absorber and regenerator parameters on sorbent performance (e.g., SO{sub 2} removal) were investigated. Sorbent spheres of 1/8-in diameter were used as compared to 1/16-in sized sorbent of a previous study. Also discussed are modifications to the absorber to improve the operability of the LCTS when fly ash is present during coal combustion.

  11. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01T23:59:59.000Z

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  12. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30T23:59:59.000Z

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  13. Alternative formulations of regenerable flue gas cleanup catalysts. Progress report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Mitchell, M.B.; White, M.G.

    1991-12-31T23:59:59.000Z

    The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

  14. Using Flue Gas Huff 'n Puff Technology and Surfactants to Increase Oil Production from the Antelope Shale Formation of the Railroad Gap Oil Field

    SciTech Connect (OSTI)

    McWilliams, Michael

    2001-12-18T23:59:59.000Z

    This project was designed to test cyclic injection of exhaust flue gas from compressors located in the field to stimulate production from Antelope Shale zone producers. Approximately 17,000 m{sup 3} ({+-}600 MCF) of flue gas was to be injected into each of three wells over a three-week period, followed by close monitoring of production for response. Flue gas injection on one of the wells would be supplemented with a surfactant.

  15. Investigation of mercury transformation by HBr addition in a slipstream facility with real flue gas atmospheres of bituminous coal and Powder River Basin Coal

    SciTech Connect (OSTI)

    Yan Cao; Quanhai Wang; Chien-wei Chen; Bobby Chen; Martin Cohron; Yi-chuan Tseng; Cheng-chung Chiu; Paul Chu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2007-09-15T23:59:59.000Z

    An investigation of speciated mercury transformation with the addition of hydrogen bromide (HBr) at elevated temperatures was conducted in a slipstream reactor with real flue gas atmospheres. Test results indicated that adding HBr into the flue gas at several parts per million strongly impacted the mercury oxidation and adsorption, which were dependent upon temperature ranges. Higher temperatures (in the range of 300-350 C) promoted mercury oxidation by HBr addition but did not promote mercury adsorption. Lower temperatures (in a range of 150-200 C) enhanced mercury adsorption on the fly ash by adding HBr. Test results also verified effects of flue gas atmospheres on the mercury oxidation by the addition of HBr, which included concentrations of chlorine and sulfur in the flue gas. Chlorine species seemed to be involved in the competition with bromine species in the mercury oxidation process. With the addition of HBr at 3 ppm at a temperature of about 330 C, the additional mercury oxidation could be reached by about 55% in a flue gas atmosphere by burning PRB coal in the flue gas and by about 20% in a flue gas by burning bituminous coal. These are both greater than the maximum gaseous HgBr2 percentage in the flue gas (35% for PRB coal and 5% for bituminous coal) by thermodynamic equilibrium analysis predictions under the same conditions. This disagreement may indicate a greater complexity of mercury oxidation mechanisms by the addition of HBr. It is possible that bromine species promote activated chlorine species generation in the flue gas, where the kinetics of elemental mercury oxidation were enhanced. However, SO{sub 2} in the flue gas may involve the consumption of the available activated chlorine species. Thus, the higher mercury oxidation rate by adding bromine under the flue gas by burning PRB coal may be associated with its lower SO{sub 2} concentration in the flue gas. 39 refs., 8 figs., 4 tabs.

  16. An investigation of sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Haddad, G.J.; Hargis, R.A. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center

    1998-12-31T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from a carrier gas. An on-line atomic fluorescence spectrophotometer, used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  17. Catalysts for oxidation of mercury in flue gas

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2010-08-17T23:59:59.000Z

    Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

  18. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31T23:59:59.000Z

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  19. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01T23:59:59.000Z

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  20. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    1999-07-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  1. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    2000-04-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, the capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons as well as novel sorbents were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  2. Developments in flue gas cleanup research at the Federal Energy Technology Center

    SciTech Connect (OSTI)

    Pennline, H.W.; Hargis, R.A.; Hedges, S.W.; Hoffman, J.S.; O`Dowd, W.J.; Warzinski, R.P.; Yeh, J.T.; Scierka, S.J.; Granite, E.J. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center

    1997-12-31T23:59:59.000Z

    A major research effort in the cleanup of flue gas, which is produced by the combustion of fossil fuels, is being conducted by the in-house research program at the Federal Energy Technology Center (FETC) of the US Department of Energy (DOE). Novel technologies being developed can abate sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), hazardous air pollutants (also referred to as air toxics), and carbon dioxide (CO{sub 2}) from flue gas. Laws within the US mandate the control of some of these pollutants and the initial characterization of others, while potential new regulations impact the status of others. Techniques that can control one or more of the targeted pollutants in an environmentally and economically acceptable manner are of prime interest. Past efforts have included low-temperature dry scrubbing SO{sub 2} removal techniques that typically use a calcium or sodium-based disposable sorbent either in a spray drying mode or in a duct injection mode of operation; novel techniques for enhancing sorbent utilization in conventional wet or dry scrubbing processes; and control of emissions produced from small-scale combustors (residential or commercial-size) that burn coal or coal/sorbent briquettes. Recent research at FETC has focused on investigations of air toxics produced by burning various coals, with a particular emphasis on the speciation of mercury and the control of the various mercury species; dry, regenerable sorbent processes that use a metal oxide sorbent to simultaneously remove SO{sub 2} and NO{sub x}; catalysts for selective catalytic reduction (SCR)-type NO{sub x} control; and the utilization and sequestering of CO{sub 2} removed from flue gas produced by fossil fuel combustion. The research projects range from laboratory-scale work to testing with the combustion products of coal at a scale equivalent to about 0.75 megawatt of electric power generation. An overview and status of the in-house flue gas cleanup projects at FETC are reported.

  3. EPA reports advances in scrubber technology at Flue Gas Desulfurization symposium

    SciTech Connect (OSTI)

    Smock, R.

    1982-07-01T23:59:59.000Z

    The overall message of the recent Symposium on Flue Gas Desulfurization was that the technology for sulfur dioxide scrubbing has matured enough for discussions to focus on future improvements rather than whether scrubbers work at all. The Environmental Protection Agency (EPA) regulations will not change in the near future, however, unless there are changes in the Clean air Act to deal with acid rain, despite the improvements in performance data. The symposium covered reports on dual-alkali scrubbing, organic buffer additives, the probability that scrubber wastes will not be classified as hazardous, simultaneous removal of nitrogen oxides and sulfur dioxide, and continuous monitoring programs. 3 figures, 4 tables. (DCK)

  4. Flue Gas Desulfurization Market Research Report 2018 | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489Information Hydro IncEnergy InformationFlue Gas

  5. Advanced separation technology for flue gas cleanup. Quarterly technical report No. 8, [January--March 1994

    SciTech Connect (OSTI)

    Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S. [SRI International, Menlo Park, CA (United States)] [SRI International, Menlo Park, CA (United States); Sirkar, K.K.; Majumdar, S.; Bhaumick, D. [New Jersey Inst. of Tech., Newark, NJ (United States)] [New Jersey Inst. of Tech., Newark, NJ (United States)

    1994-03-01T23:59:59.000Z

    During the first quarter of 1994, we continued work on Tasks 2, 3, 4, 5, and 6. We also began work on Task 7. In Task 2, we incorporated 4.5% O{sub 2} into our simulated flue gas stream during this quarter`s NO{sub x}-absorption experiments. We also ran experiments using Cobalt (II)-phthalocyanine as an absorbing agent We observed higher absorption capacities when using this solution with the simulated flue gas containing O{sub 2}. In Task 3, we synthesized a few EDTA polymer analogs. We also began scaled up synthesis of Co(II)-phthalocyanine for use in Task 5. In Task 4, we performed experiments for measuring distribution coefficients (m{sub i}) Of SO{sub 2} between aqueous and organic phases. This was done using the liquor regenerating apparatus described in Task 6. In Task 5, we began working with Co(II)-phthalocyanine in the 301 fiber hollow fiber contactor. We also calculated mass transfer coefficients (K{sub olm}) for these runs, and we observed that the gas side resistance dominates mass transfer. In Task 6, in the liquor regeneration apparatus, we observed 90% recovery of SO{sub 2} by DMA from water used as the scrubbing solution. We also calculated the distribution of coefficients (m{sub i}). In Task 7, we established and began implementing a methodology for completing this task.

  6. Desulfurization of flue gas by the confined zone dispersion process - Proof-of-concept tests

    SciTech Connect (OSTI)

    Abrams, J.Z.; Blake, J.H.; Pennline, H.W.

    1986-01-01T23:59:59.000Z

    As part of a program to develop more cost-effective approaches to the control of acid rain precursors, the Department of Energy (DOE) is supporting proof-of-concept tests of the Confined Zone Dispersion (CZD) process proposed by Bechtel. This process removes SO/sub 2/ from flue gas by injecting a finely atomized slurry of highly reactive pressure hydrated dolomitic lime into the duct of a utility boiler. A slipstream of flue gas at 300/sup 0/F will be withdrawn from the plant ductwork and will pass through a 130-ft run of 3-ft diameter test duct. A two-fluid atomizer will inject the lime slurry into the upstream end of the test duct. A pilot scale electrostatic precipitator (ESP) will remove reaction products and fly ash before the gas is discharged back into the utility's ESP. An 11-month test program will optimize controllable variables, acquire design data, and demonstrate reliability by a long duration run. Measurements taken will include SO/sub 2/ removal, lime utilization, ESP performance, and characterization of waste solids.

  7. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    SciTech Connect (OSTI)

    Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

    2008-07-02T23:59:59.000Z

    Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

  8. Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

    SciTech Connect (OSTI)

    David A Lesch

    2010-06-30T23:59:59.000Z

    UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

  9. Environ. Scl. Technol. 1994, 28, 277-283 Effects of Salts on Preparation and Use of Calcium Silicates for Flue Gas

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Silicates for Flue Gas Desulfurization Kurt K. Klnd, Phlllp D. Wasserman, and Gary 1.Rochelle' Department is a flue gas desulfurization (FGD) technology developed for existingcoal to remove sulfur dioxide. High surface area calcium silicate hydrates are made by slurrying Ca(0H

  10. Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors in France: Implications for Atmospheric Lead Source Tracing.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors@crpg.cnrs-nancy.fr _______________________________________________________________________________________ Fly ash and flue gas residues from eight municipal solid waste combusters (MSWC) in France (1992 of "industrial Pb" is not an easy task because of its possible extreme heterogeneity. Municipal solid waste

  11. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31T23:59:59.000Z

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  12. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31T23:59:59.000Z

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  13. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01T23:59:59.000Z

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  14. Flue gas cleanup using the Moving-Bed Copper Oxide Process

    SciTech Connect (OSTI)

    Pennline, Henry W.; Hoffman, James S.

    2013-10-01T23:59:59.000Z

    The use of copper oxide on a support had been envisioned as a gas cleanup technique to remove sulfur dioxide (SO{sub 2}) and nitric oxides (NO{sub x}) from flue gas produced by the combustion of coal for electric power generation. In general, dry, regenerable flue gas cleanup techniques that use a sorbent can have various advantages, such as simultaneous removal of pollutants, production of a salable by-product, and low costs when compared to commercially available wet scrubbing technology. Due to the temperature of reaction, the placement of the process into an advanced power system could actually increase the thermal efficiency of the plant. The Moving-Bed Copper Oxide Process is capable of simultaneously removing sulfur oxides and nitric oxides within the reactor system. In this regenerable sorbent technique, the use of the copper oxide sorbent was originally in a fluidized bed, but the more recent effort developed the use of the sorbent in a moving-bed reactor design. A pilot facility or life-cycle test system was constructed so that an integrated testing of the sorbent over absorption/regeneration cycles could be conducted. A parametric study of the total process was then performed where all process steps, including absorption and regeneration, were continuously operated and experimentally evaluated. The parametric effects, including absorption temperature, sorbent and gas residence times, inlet SO{sub 2} and NO{sub x} concentration, and flyash loadings, on removal efficiencies and overall operational performance were determined. Although some of the research results have not been previously published because of previous collaborative restrictions, a summary of these past findings is presented in this communication. Additionally, the potential use of the process for criteria pollutant removal in oxy-firing of fossil fuel for carbon sequestration purposes is discussed.

  15. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

  16. Assessment of the Flue Gas Recycle Strategies on Oxy-Coal Power Plants using an Exergy-based Methodology

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Assessment of the Flue Gas Recycle Strategies on Oxy- Coal Power Plants using an Exergy to be competitive with post-combustion for carbon capture on coal-fired power plants. In order to achieve is produced from coal (IEA 2012b), the development of CO2 capture technology on coal-fired power plants

  17. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    NONE

    1996-04-30T23:59:59.000Z

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  18. Speciation, characterization, and mobility of As, Se, and Hg in flue gas desulphurization residues

    SciTech Connect (OSTI)

    Souhail R. Al-Abed; Gautham Jegadeesan; Kirk G. Scheckel; Thabet Tolaymat [United States Environmental Protection Agency, Cincinnati, OH (United States). National Risk Management Research Laboratory

    2008-03-01T23:59:59.000Z

    Flue gas from coal combustion contains significant amounts of volatile toxic trace elements such as arsenic (As), selenium (Se), and mercury (Hg). The capture of these elements in the flue gas desulphurization (FGD) scrubber unit has resulted in generation of a metal-laden residue. With increasing reuse of the FGD residues in beneficial applications, it is important to determine metal speciation and mobility to understand the environmental impact of its reuse. In this paper, we report the solid phase speciation of As, Se, and Hg in FGD residues using X-ray absorption spectroscopy (XAS), X-ray fluorescence spectroscopy (XRF), and sequential chemical extraction (SCE) techniques. The SCE results combined with XRF data indicated a strong possibility of As association with iron oxides, whereas Se was distributed among all geochemical phases. Hg appeared to be mainly distributed in the strong-complexed phase. XRF images also suggested a strong association of Hg with Fe oxide materials within FGD residues. XAS analysis indicated that As existed in its oxidized state (As(V)), whereas Se and Hg was observed in primarily reduced states as selenite (Se(IV)) and Hg(I), respectively. The results from the SCE and variable pH leaching tests indicated that the labile fractions of As, Se, and Hg were fairly low and thus suggestive of their stability in the FGD residues. However, the presence of a fine fraction enriched in metal content in the FGD residue suggested that size fractionation is important in assessing the environmental risks associated with their reuse. 34 refs., 3 figs., 4 tabs.

  19. SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

  20. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2011-03-01T23:59:59.000Z

    A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

  1. New strategy to decompose nitrogen oxides from regenerable flue gas cleanup processes

    SciTech Connect (OSTI)

    Yeh, J.T.; Ekmann, J.M.; Pennline, H.W.; Drummond, C.J.

    1987-01-01T23:59:59.000Z

    Simulated NO/sub x/ recycle tests were recently conducted at the Pittsburgh Energy Technology Center (PETC), US Department of Energy, with excellent results. However, the NO/sub x/-recycle technique needs improvement if steady-state removal of 90% of the NO/sub x/ produced from the combustor is required. This paper reports experimental results for two new techniques to improve the destruction of externally injected NO/sub x/ into a combustor. The first technique involves doping the NO/sub x/ gas stream to the combustor with methane (other reductants might also be effective). The second technique is injecting the recycled NO/sub x/ stream at the optimum location (with and without methane doping) for maximum reduction. Test data showed 100% reduction of injected NO/sub x/ is possible with this technique. A third approach is proposed using a low-NO/sub x/ burner in combination with the NO/sub x/ recycle technique to achieve a steady-state 90% NO/sub x/ removal in the flue gas. The projected results of the third process scheme are based on material balance computations and reasonable expectations of the performance of each component of the process.

  2. A technique to control mercury from flue gas: The Thief Process

    SciTech Connect (OSTI)

    O'Dowd, W.J.; Pennline, H.W.; Freeman, M.C.; Granite, E.J.; Hargis, R.A.; Lacher, C.J.; Karash, A.

    2006-12-01T23:59:59.000Z

    The Thief Process is a mercury removal process that may be applicable to a broad range of pulverized coal-fired combustion systems. This is one of several sorbent injection technologies under development by the U.S. Department of Energy for capturing mercury from coal-fired electric utility boilers. A unique feature of the Thief Process involves the production of a thermally activated sorbent in situ at the power plant. The sorbent is obtained by inserting a lance, or thief, into the combustor, in or near the flame, and extracting a mixture of partially combusted coal and gas. The partially combusted coal or sorbent has adsorptive properties suitable for the removal of vapor-phase mercury at flue gas temperatures that are typical downstream of a power plant preheater. One proposed scenario, similar to activated carbon injection (ACI), involves injecting the extracted sorbent into the downstream ductwork between the air preheater and the particulate collection device of the power plant. Initial laboratory-scale and pilot-scale testing, using an eastern bituminous coal, focused on the concept validation. Subsequent pilot-scale testing, using a Powder River Basin (PRB) coal, focused on the process development and optimization. The results of the experimental studies, as well as an independent experimental assessment, are detailed. In addition, the results of a preliminary economic analysis that documents the costs and the potential economic advantages of the Thief Process for mercury control are discussed.

  3. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  4. A kinetic approach to the catalytic oxidation of mercury in flue gas

    SciTech Connect (OSTI)

    Albert A. Presto; Evan J. Granite; Andrew Karash; Richard A. Hargis; William J. O'Dowd; Henry W. Pennline [U.S. Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

    2006-10-15T23:59:59.000Z

    Four mercury oxidation catalysts were tested in a packed bed reactor in the presence of flue gas generated by the NETL 500 lb/h coal combustor. The four catalysts tested were Ir, Ir/HCl, Darco FGD activated carbon, and Thief/HCl. The Thief/HCl and Darco converted the highest percentage of the inlet mercury; however, the high conversion in these experiments was aided by larger catalyst loadings than in the Ir and Ir/HCl experiments. We propose a method for analyzing mercury oxidation catalyst results in a kinetic framework using the bulk reaction rate for oxidized mercury formation normalized by either the catalyst mass or surface area. Results reported for fractional mercury oxidation are strongly influenced by the specific experimental conditions and are therefore difficult to translate from experiment to experiment. The catalyst-normalized results allow for more quantitative analysis of mercury oxidation catalyst data and are the first step in creating a predictive model that will allow for efficient scaling up from laboratory-scale to larger-scale studies. 34 refs., 1 fig., 3 tabs.

  5. Fundamental mechanisms in flue gas conditioning. Quarterly report, January 1992--March 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Bush, P.V.

    1992-04-27T23:59:59.000Z

    This project is divided into four tasks. The Management Plan was developed in task 1. Task 2, Evaluation of Mechanisms in FGD Sorbent and Ash Interactions, focuses on the characteristics of binary mixtures of these distinct powders. Task 3, Evaluation of Mechanisms in Conditioning Agents and Ash, is designed to examine the effects of various conditioning agents on fine ash particles to determine the mechanisms by which these agents alter the physical properties of the ash. Tasks 2 and 3 began with an extensive literature search and the assembly of existing theories. This phase of the project is now complete. During the past quarter, initial preparations of laboratory equipment for laboratory testing have been made. A plan for initial laboratory tests has been submitted to the Project Manager for review. Laboratory testing will commence once these laboratory plans have been formally approved. The results of the work performed under task 2 and 3 will be included in a Flue Gas Conditioning Model that will be issued under task 4. The Final Report for the project will also be prepared under task 4.

  6. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect (OSTI)

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R. [University of Cincinnati, Cincinnati, OH (United States). Department of Chemical and Materials Engineering

    2009-08-15T23:59:59.000Z

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  7. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30T23:59:59.000Z

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  8. CO{sub 2} Capture Membrane Process for Power Plant Flue Gas

    SciTech Connect (OSTI)

    Lora Toy; Atish Kataria; Raghubir Gupta

    2011-09-30T23:59:59.000Z

    Because the fleet of coal-fired power plants is of such importance to the nationâ??s energy production while also being the single largest emitter of CO{sub 2}, the development of retrofit, post-combustion CO{sub 2} capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO{sub 2} from plant flue gas with 95% captured CO{sub 2} purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO{sub 2}-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft{sup 2}) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO{sub 2}, NOx, etc.). Specific objectives were: ï?· Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO{sub 2} over N{sub 2} and CO{sub 2} permeance greater than 300 gas permeation units (GPU) targeted; ï?· Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO{sub 2} permeance than current commercial polycarbonate membranes; ï?· Development and fabrication of membrane hollow fibers and modules from candidate polymers; ï?· Development of a CO{sub 2} capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and ï?· Techno-economic evaluation of the "best" integrated CO{sub 2} capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO{sub 2} capture with 95% captured CO{sub 2} purity.

  9. CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents

    SciTech Connect (OSTI)

    Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

    2012-08-31T23:59:59.000Z

    The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

  10. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01T23:59:59.000Z

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of “staining” upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  11. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27T23:59:59.000Z

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  12. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01T23:59:59.000Z

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  13. Field testing of a probe to measure fouling in an industrial flue gas stream

    SciTech Connect (OSTI)

    Sohal, M.S.

    1990-11-01T23:59:59.000Z

    The US Department of Energy, Office of Industrial Technology sponsors work in the area of measuring and mitigating fouling in heat exchangers. This report describes the design and fabrication of a gas-side fouling measuring device, and its testing in an industrial environment. The report gives details of the probe fabrication, material used, controllers, other instrumentation required for various measurements, and computer system needed for recording the data. The calibration constants for measuring the heat flux with the heat fluxmeter were determined. The report also describes the field test location, the tests performed, the data collected, and the data analysis. The conclusions of the tests performed were summarized. Although fouling deposits on the probe were minimal, the tests proved that the probe is capable of measuring the fouling in a harsh industrial environment. 17 refs., 19 figs., 5 tabs.

  14. Design, construction, and operation of a life-cycle test system for the evaluation of flue gas cleanup processes

    SciTech Connect (OSTI)

    Pennline, H.W.; Yeh, James T.; Hoffman, J.S. [USDOE Pittsburgh Energy Technology Center, PA (United States); Longton, E.J.; Vore, P.A.; Resnik, K.P.; Gromicko, F.N. [Gilbert/Commonwealth, Inc., Library, PA (United States)

    1995-12-01T23:59:59.000Z

    The Pittsburgh Energy Technology Center of the US Department of Energy has designed, constructed, and operated a Life-Cycle Test Systems (LCTS) that will be used primarily for the investigation of dry, regenerable sorbent flue gas cleanup processes. Sorbent continuously cycles from an absorber reactor where the pollutants are removed from the flue gas, to a regenerator reactor where the activity of the spent sorbent is restored and a usable by-product stream of gas is produced. The LCTS will initially be used to evaluate the Moving-Bed Copper Oxide Process by determining the effects of various process parameters on SO{sub 2} and NO{sub x} removals. The purpose of this paper is to document the design rationale and details, the reactor/component/instrument installation, and the initial performance of the system. Although the Moving-Bed Copper Oxide Process will be investigated initially, the design of the LCTS evolved to make the system a multipurpose, versatile research facility. Thus, the unit can be used to investigate various other processes for pollution abatement of SO{sub 2}, NO{sub x}, particulates, air toxics, and/or other pollutants.

  15. Indirect Heat Transfer Technology For Waste Heat Recovery Can Save You Money

    E-Print Network [OSTI]

    Beyrau, J. A.; Bogel, N. G.; Seifert, W. F.; Wuelpern, L. E.

    1984-01-01T23:59:59.000Z

    constraints of an existing installation makes the conventional flue gas to air energy recovery technology impractical to employ. A successful alternative is the transfer of waste heat to an intermediate heat transfer fluid (i.e., DOWTHERM Heat Transfer Fluid...

  16. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  17. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  18. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2001-09-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  19. Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03T23:59:59.000Z

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  20. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24T23:59:59.000Z

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  1. Low Temperature Heat Recovery for Boiler Systems

    E-Print Network [OSTI]

    Shook, J. R.; Luttenberger, D. B.

    be economically heated to within 50 0 F of the entering flue gas temperature. Other less common, but practical, uses for energy include driving a low-temperature electric turbine cycle or an absorption chilling cycle. An improvement in boiler efficiency of 3...% to 8% can normally be realized by cooling boiler flue gasses down to llO o F_200 0 F. This recovers a large quantity of the available sensible heat in most boiler flue gas streams. Efficiency can be improv ed by up to 10% if flue gas is cooled down...

  2. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard

    2003-12-01T23:59:59.000Z

    ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

  3. Status of flue-gas treatment technologies for combined SO[sub 2]/NO[sub x] reduction

    SciTech Connect (OSTI)

    Livengood, C.D. (Argonne National Lab., IL (United States). Energy Systems Div.); Markussen, J.M. (USDOE Pittsburgh Energy Technology Center, PA (United States))

    1993-01-01T23:59:59.000Z

    Enactment of the Clean Air Act Amendments and passage of state legislation leading to more stringent nitrogen oxides (NO.) regulations have fueled research and development efforts on the technologies for the combined control of sulfur dioxide (SO[sub 2]) and NO[sub x]. The integrated removal of both SO[sub 2] and NO[sub x] in a single system can offer significant advantages over the use of several separate processes, including such factors as reduced system complexity, better operability, and lower costs. This paper reviews the status of a number of integrated flue-gas-cleanup systems that have reached a significant stage of development, focusing on post-combustion processes that have been tested or are ready for testing at the pilot scale or larger. A brief process description, a summary of the development status and performance achieved to date, pending commercialization issues, and process economics (when available) are given for each technology.

  4. Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants

    SciTech Connect (OSTI)

    M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

    2003-12-31T23:59:59.000Z

    This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

  5. Global evaluation of mass transfer effects: In-duct injection flue gas desulfurization

    SciTech Connect (OSTI)

    Cole, J.A.; Newton, G.H.; Kramlich, J.C.; Payne, R.

    1990-09-30T23:59:59.000Z

    Sorbent injection is a low capital cost, low operating cost approach to SO{sub 2} control targeted primarily at older boilers for which conventional fuel gas desulfurization is not economically viable. Duct injection is one variation of this concept in which the sorbent, either a dry powder or a slurry, is injected into the cooler regions of the boiler, generally downstream of the air heaters. The attractiveness of duct injection is tied to the fact that it avoids much of the boiler heat transfer equipment and thus has minimal impact of boiler performance. Both capital and operating cost are low. This program has as its objectives three performance related issues to address: (1) experimentally identify limits on sorbent performance. (2) identify and test sorbent performance enhancement strategies. (3) develop a compute model of the duct injection process. Two major tasks are described: a laboratory-scale global experiment and development of process model. Both are aimed at understanding and quantifying the rate-limiting processes which control SO{sub 2} capture by lime slurry during boiler duct injection. 29 refs., 35 figs., 4 tabs.

  6. Absorption, electrodialysis and additional regeneration in two flue gas SO/sub 2//NO/sub x/ cleanup processes

    SciTech Connect (OSTI)

    Walker, R.J.; Pennline, H.W.

    1987-01-01T23:59:59.000Z

    Eleven potential adsorbents for use in the two processes were tested in a laboratory-scale bubble column. Best absorbent performance was obtained with iron EDTA in an ammonium sulfite/sulfate solution. Removals of greater than 95% were observed for SO/sub 2/, NO, and NO/sub 2/ from a simulated flue gas containing N/sub 2/, O/sub 2/, CO/sub 2/, SO/sub 2/, NO, and NO/sub 2/. Laboratory-scale electrodialysis tests of fresh scrubbing liquor revealed that iron EDTA tended to permeate through anion-selective membranes and thus deleteriously affected process performance. Screening tests with twelve types of anion-selective membranes showed that three had EDTA permeation rates that were acceptable for process operation. Two methods of regeneration with respect to the NO/sub x/-removal component were investigated. Thermal stripping did not appear successful for producing nitrogen oxides in the off-gas from the stripper. A thermal treatment of the spent liquor at 50/sup 0/C successfully regenerated iron EDTA. The mechanism is being investigated.

  7. Fundamental mechanisms in flue-gas conditioning. Topical report No. 1, Literature review and assembly of theories on the interactions of ash and FGD sorbents

    SciTech Connect (OSTI)

    Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

    1992-01-09T23:59:59.000Z

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  8. Efficient capture of CO{sub 2} from simulated flue gas by formation of TBAB or TBAF semiclathrate hydrates

    SciTech Connect (OSTI)

    Shuanshi Fan; Shifeng Li; Jingqu Wang; Xuemei Lang; Yanhong Wang [South China University of Technology, Guangzhou (China). Key Laboratory of Enhanced Heat Transfer and Energy Conversation

    2009-08-15T23:59:59.000Z

    Capturing CO{sub 2} by forming hydrate is an attractive technology for reducing the greenhouse effect. The most primary challenges are high energy consumption, low hydrate formation rate, and separation efficiency. This work presents efficient capture of CO{sub 2} from simulated flue gas (CO{sub 2} (16.60 mol %)/N{sub 2} binary mixtures) by formation of semiclathrate hydrates at 4.5 and 7.1{sup o}C and feed pressures ranging from 2.19 to 7.31 MPa. The effect of 0.293 mol % tetra-n-butyl ammonium bromide (TBAB) and tetra-n-butyl ammonium fluoride (TBAF) on the hydrate formation rate, reactor space velocity, and CO{sub 2} separation efficiency was studied in a 1 L stirred reactor. The results showed the hydrate formation rate constant increased with increasing feed pressure and reached the maximum at 2.82 x 10{sup -7} mol{sup 2}/(s.J) with TBAB and 8.26 x 10{sup -7} mol{sup 2}/(s.J) with TBAF. The space velocity of the hydrate reactor increased with increasing feed pressure and reached a maximum of 13.46 h{sup -1} with TBAB and 25.96 h{sup -1} with TBAF. CO{sub 2} recovery was about 50%, and the optimum CO{sub 2} separation factor with TBAF was 36.98, which was about 4 times higher than that with TBAB in the range of feed pressure. CO{sub 2} could be enriched to 90.40 mol % from simulated flue gas under low feed pressure by two stages of hydrate separation with TBAF. The results demonstrated that TBAB, especially TBAF, could accelerate hydrate formation. The space velocity of the hydrate reactor with TBAB or TBAF was higher than that with THF. CO{sub 2} could be easily enriched in the hydrate phase by two stages of hydrate separation under gentle conditions. 27 refs., 8 figs., 5 tabs.

  9. Simultaneous SO{sub 2}/NO separation from flue gas using HFCLM. Final report

    SciTech Connect (OSTI)

    Schimmel, K.

    1995-02-01T23:59:59.000Z

    Abatement technologies for oxides of sulfur and nitrogen present in flue and stack gases from coal fired boilers are becoming increasingly important. Scrubbing the gases with an aqueous limestone slurry to remove SO{sub 2} is a widely used treatment process. These scrubbing solutions are, however, not very effective in removing NO. In addition, the process is expensive and produces large volumes of sludge. The liquid membrane from a 0.01 M aqueous solution of Fe{sup 2+}EDTA has been found to have a very high selectivity for NO over N{sub 2}. Thus, SO{sub 2}/NO{sub x} can be removed simultaneously using an aqueous Fe 3{sup 3+}EDTA solution in a hollow fiber contained liquid membrane (HFCLM) permeator with hydrophobic fibers. The HFCLM configuration has addressed previous concerns about liquid membrane stability for an application such as this. In this project, a flow apparatus was constructed that will allow simultaneous SO{sub 2}/NO removal and recovery using two hollow fiber modules in series. Flowing the liquid membrane on the shell-side of the modules it is hypothesized will enhance the performance over that of HFCLMs without loss of stability. From the work completed in this exploratory project, it was concluded that to move the current state-of-the-art for this promising technology toward commercialization will require progress in the following areas: (1) sensitivity of the performance of the system to temperature changes, (2) validation of a mass transfer model to be used in scale-up calculations, (3) data on alternative flow schemes, and (4) overall process economics calculations.

  10. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

    2006-07-01T23:59:59.000Z

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  11. Load Preheating Using Flue Gases from a Fuel-Fired Heating System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil & Gas »ofMarketing | DepartmentComputing CenterLiz Doris

  12. Waste Heat Recovery From Stacks Using Direct-Contact Condensing Heat Exchange

    E-Print Network [OSTI]

    Thorn, W. F.

    is mainly for general interest and to illustrate the analysis methodology. Two key parameters from Table A-I are needed for a heat recovery analysis. First is the weight of water vapor in the flue gas per unit weight of fuel burned and the second... ........_ ...._ ...._ ...._ ...._ ...._ ....--1 200 260 300 360 400 460 600 660 HEAT RECOVERY UNIT INLET FLUE GAS TEMPERATURE, OF FJpre 2. Efficiency Variation With Heat Recovery Unit Inlet Flue Gas Temperature 428 ESL-IE-86-06-69 Proceedings from the Eighth Annual Industrial Energy...

  13. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J. [and others

    1998-12-31T23:59:59.000Z

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  14. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30T23:59:59.000Z

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  15. Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Fogash, Kevin

    2010-09-30T23:59:59.000Z

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  16. Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01T23:59:59.000Z

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  17. Alternative flue gas treatment technologies for integrated SO{sub 2} and NO{sub x} control

    SciTech Connect (OSTI)

    Markussen, J.M. [USDOE Pittsburgh Energy Technology Center, PA (United States); Livengood, D.D. [Argonne National Lab., IL (United States)

    1995-06-01T23:59:59.000Z

    Enactment of the 1990 Clean Air Act Amendments, as well as passage of legislation at the state level has raised the prospect of more stringent nitrogen oxides (NO{sub x}) emission regulations and has fueled research and development efforts on a number technologies for the combined control of sulfur dioxide (SO{sub 2}) and NO{sub x}. The integrated removal of both SO{sub 2} and NO{sub x} in a single system can offer significant advantages over the use of several separate processes, including such factors as reduced system complexity, better operability, and lower costs. This paper reviews the status of a number of integrated flue gas cleanup systems that have reached a significant stage of development, focusing on post-combustion processes that have been tested or are ready for testing at the pilot scale or larger. A brief process description, a summary of the development status and performance achieved to date, pending commercialization issues, and process economics (when available) are given for each technology.

  18. DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2005-01-30T23:59:59.000Z

    For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

  19. The use of wet limestone systems for combined removal of SO sub 2 and NO sub x from flue gas

    SciTech Connect (OSTI)

    Lee, G.C. (Bechtel Corp., San Francisco, CA (USA)); Shen, D.X.; Littlejohn, D.; Chang, S.G. (Lawrence Berkeley Lab., CA (USA))

    1990-03-01T23:59:59.000Z

    A new approach by utilizing yellow phosphorus in conventional wet limestone systems for high efficiency control of SO{sub 2} and NO{sub x} emissions from power plants has been developed. The addition of yellow phosphorus in the system induces the production of O{sub 3} which subsequently oxidizes NO to NO{sub 2}. The resulting NO{sub 2} dissolves readily and can be reduced to form ammonium ions by dissolved SO{sub 2} under appropriate conditions. Yellow phosphorus is oxidized to yield P{sub 2}O{sub 5} which picks up water to form H{sub 3}PO{sub 4} mists and can be collected as a valuable product. Proof of concept experiments have been performed using a 20 acfm bench-scale system. The results show that better than 90% of SO{sub 2} and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained. This ratio depends on operating conditions as well as the process configuration. A conceptual process flow diagram has been proposed. A preliminary cost evaluation of this approach appears to indicate great economic potential. 22 refs., 8 figs., 1 tab.

  20. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07T23:59:59.000Z

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  1. natural gas+ condensing flue gas heat recovery+ water creation+ CO2

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlinPapersWindey Wind Home Rmckeel'slinked openreduction+ cool exhaust

  2. Inorganic hazardous air pollutants before and after a limestone flue gas desulfurization system as a function of <10 micrometer particle sizes and unit load

    SciTech Connect (OSTI)

    Maxwell, D.P.; Williams, W.A.; Flora, H.B. II [Radian Corp., Austin, TX (United States)

    1995-12-31T23:59:59.000Z

    Radian Corporation collected size-fractionated particulate samples from stack gas at a unit burning high sulfur coal with a venturi scrubber FGD system. Independent sample fractions were collected under high-load and low-load operating conditions and subjected to various techniques designed to measure the total composition and surface-extractable concentrations of selected trace elements. The relationships between unit load, particle-size distribution, total composition, and surface-extractable inorganic species are reported and compared to show the availability of trace elements relevant to potential health risks from flue gas particulate emissions.

  3. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01T23:59:59.000Z

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  4. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05T23:59:59.000Z

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  5. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-11-01T23:59:59.000Z

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  6. Refinery gas waste heat energy conversion optimization in gas turbines

    SciTech Connect (OSTI)

    Rao, A.D.; Francuz, D.J.; West, E.W. [Fluor Daniel, Inc., Irvine, CA (United States)

    1996-12-31T23:59:59.000Z

    Utilization of refinery fuel gas in gas turbines poses special challenges due to the combustion characteristics of the fuel gas which contains significant concentrations of hydrogen. Proper modifications to the combustion system of the existing gas turbines are required in order to combust such fuel gas streams in gas turbines while minimizing the NO{sub x} emissions. A novel approach to the utilization of this hydrogen bearing fuel gas in gas turbines consists of humidifying the fuel gas with water vapor by direct contact with hot water in a counter-current column, the feed water to the humidifier being first circulated through the refinery to recover waste heat. The refinery waste heat produces additional motive fluid with a result that the waste heat is converted to power in the gas turbine. Furthermore, the water vapor introduced into the fuel gas reduces the NO{sub x} formation and increases the gas turbine output, while the hydrogen present in the fuel gas provides the flame stability required when combusting a fuel gas containing a large concentration of water vapor.

  7. Residential gas-fired sorption heat Test and technology evaluation

    E-Print Network [OSTI]

    Residential gas-fired sorption heat pumps Test and technology evaluation Energiforskningsprogram EFP05 Journal nr: 33031-0054 December 2008 #12;Residential gas-fired sorption heat pumps Test.............................................................................................................................................5 1 Residential gas-fired thermally driven heat pumps

  8. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, January--March 1995

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S. [and others

    1995-04-01T23:59:59.000Z

    On September 30, 1993, the U.S. Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC 30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, as well as the management plan and the test plan for the overall program, and a discussion of these will not be repeated here. Rather, this report, will set forth the technical progress made during the period January 1 through March 31, 1995. The demonstration of the SEEC, Inc. technology for the transporting of coal combustion residues was completed with the unloading and final disposition of the three Collapsible Intermodal Containers (CIC). The loading and transport by rail of the three CIC`s was quire successful; however some difficulties were encountered in the unloading of the containers. A full topical report on the entire SEEC demonstration is being prepared. As a result of the demonstration some modifications of the SEEC concept may be undertaken. Also during the quarter the location of the injection wells at the Peabody No. 10 mine demonstration site were selected. Peabody Coal Company has developed the specifications for the wells and sought bids for the actual drilling. It is expected that the wells will be drilled early in May.

  9. Scrubber strategy: the how and why of flue gas desulfurization. [Analysis of 20 US scrubbing systems in 1980

    SciTech Connect (OSTI)

    Baviello, M.A.

    1982-01-01T23:59:59.000Z

    In this report, INFORM provides facts that will help the non-technical decisionmakers in the US understand a technology that can significantly reduce the polluting effects of burning coal. Those decisionmakers include legislators, regulators and utility executives, public interest groups, concerned community organizations and environmentalists who have been involved in the debate over the broader use of our most abundant fossil fuel - coal. The use of this resource, especially in large industrial and utility plants, has created widespread and intense public controversy. For the past four years INFORM has turned its research capabilities to defining cleaner and more economical ways of using US coal supplies. We have focused on finding out what cleaning coal and using flue gas desulfurization systems (called scrubbers) can contribute to reducing the polluting effects of burning coal in utility plants. All in all, both scrubbers and coal cleaning offer exciting and important possibilities for putting more coal to work in generating power in this country more economically and still meeting critical air quality standards that have been set to protect public health. The need for accurate and clear information concerning these technologies is evident: 80% of the sulfur dioxide emissions in the US now come from utility power plant operations, and over 140 existing oil-fired power plants are candidates for conversion to coal use. We hope that this documentation of the technologies of scrubber systems along with INFORM's companion study of coal cleaning, may help government and business planners and concerned citizens chart intelligent future courses and set realistic goals for meeting our energy needs in an environmentally sound manner.

  10. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenter (LMI-EFRC)MaRIETechnologiesMesdiCenter for Gas

  11. Experimental investigation of a molecular gate membrane for separation of carbon dioxide from flue gas

    SciTech Connect (OSTI)

    Kazama, S. (RITE, Kyoto, Japan); Kai, T. (RITE, Kyoto, Japan); Kouketsu, T. (RITE, Kyoto, Japan); Matsui, S. (RITE, Kyoto, Japan); Yamada, K. (RITE, Kyoto, Japan); Hoffman, J.S.; Pennline, H.W.

    2006-09-01T23:59:59.000Z

    Commercial-sized modules of the PAMAM dendrimer composite membrane with high CO2/N2 selectivity and CO2 permeance were developed according to the In-situ Modification (IM) method. This method utilizes the interfacial precipitation of membrane materials on the surface of porous, commercially available polysulfone (PSF) ultrafiltration hollow fiber membrane substrates. A thin layer of amphiphilic chitosan, which has a potential affinity for both hydrophobic PSF substrates and hydrophilic PAMAM dendrimers, was employed as a gutter layer directly beneath the inner surface of the substrate by the IM method. PAMAM dendrimers were then impregnated into the chitosan gutter layer to form a hybrid active layer for CO2 separation. Permeation experiments of the PAMAM dendrimer composite membrane were carried out using a humidified mixed CO2 / N2 feed gas at a pressure difference up to 97 kPa at ambient temperature. When conducted with CO2 (5%) / N2 (95%) feed gas at a pressure difference of 97 kPa, the PAMAM composite membrane exhibited an excellent CO2/N2 selectivity of 150 and a CO2 permeance of 1.7×10-7 m3(STP) m-2 s-1 kPa-1. The impact of various process parameters on the permeability and selectivity was also examined.

  12. Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Heat to Power Using Thermoelectric Engines Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Discusses a novel TEG which utilizes a proprietary stack...

  13. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Presents successful incorporation of one of the most...

  14. Heat Hyperbolic Diffusion in Planck Gas

    E-Print Network [OSTI]

    Miroslaw Kozlowski; Janina Marciak-Kozlowska

    2006-07-06T23:59:59.000Z

    In this paper we investigate the diffusion of the thermal pulse in Planck Gas. We show that the Fourier diffusion equation gives the speed of diffusion, v > c and breaks the causality of the thermal processes in Planck gas .For hyperbolic heat transport v

  15. Heat conductivity of a pion gas

    E-Print Network [OSTI]

    Antonio Dobado Gonzalez; Felipe J. Llanes-Estrada; Juan M. Torres Rincon

    2007-02-13T23:59:59.000Z

    We evaluate the heat conductivity of a dilute pion gas employing the Uehling-Uehlenbeck equation and experimental phase-shifts parameterized by means of the SU(2) Inverse Amplitude Method. Our results are consistent with previous evaluations. For comparison we also give results for an (unphysical) hard sphere gas.

  16. Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 15, September 1, 1994--November 30, 1994

    SciTech Connect (OSTI)

    NONE

    1997-01-01T23:59:59.000Z

    The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

  17. Ecological and Economical efficient Heating and Cooling by innovative Gas Motor Heat Pump Systems and Solutions

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    #12;Ecological and Economical efficient Heating and Cooling by innovative Gas Motor Heat Pump use of buildings Gas Heat Pump Solution #12;Gas Heat Pump - deserves special attention due to its source in addition to the outside air ·A further essential component of Gas Heat Pump air conditioning

  18. Protecting the Investment in Heat Recovery with Boiler Economizers 

    E-Print Network [OSTI]

    Roethe, L. A.

    1985-01-01T23:59:59.000Z

    Many people consider energy to be a crisis in remission -- even with continuing high fuel costs. Some voice concern over the long term security of an investment in flue gas heat recovery equipment. The concern generally involves the ability...

  19. Install Waste Heat Recovery Systems for Fuel-Fired Furnaces (English/Chinese) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01T23:59:59.000Z

    Chinese translation of ITP fact sheet about installing Waste Heat Recovery Systems for Fuel-Fired Furnaces. For most fuel-fired heating equipment, a large amount of the heat supplied is wasted as exhaust or flue gases. In furnaces, air and fuel are mixed and burned to generate heat, some of which is transferred to the heating device and its load. When the heat transfer reaches its practical limit, the spent combustion gases are removed from the furnace via a flue or stack. At this point, these gases still hold considerable thermal energy. In many systems, this is the greatest single heat loss. The energy efficiency can often be increased by using waste heat gas recovery systems to capture and use some of the energy in the flue gas. For natural gas-based systems, the amount of heat contained in the flue gases as a percentage of the heat input in a heating system can be estimated by using Figure 1. Exhaust gas loss or waste heat depends on flue gas temperature and its mass flow, or in practical terms, excess air resulting from combustion air supply and air leakage into the furnace. The excess air can be estimated by measuring oxygen percentage in the flue gases.

  20. Gas heat transfer in a heated vertical channel under deteriorated turbulent heat transfer regime

    E-Print Network [OSTI]

    Lee, Jeongik

    2007-01-01T23:59:59.000Z

    Passive cooling via natural circulation of gas after a loss of coolant (LOCA) accident is one of the major goals of the Gas-cooled Fast Reactor (GFR). Due to its high surface heat flux and low coolant velocities under ...

  1. Gas Heat Transfer in a Heated Vertical Channel under Deteriorated Turbulent Heat Transfer Regime

    E-Print Network [OSTI]

    Lee, Jeongik

    Passive cooling via natural circulation of gas after a loss of coolant (LOCA) accident is one of the major goals of the Gas-cooled Fast Reactor (GFR). Due to its high surface heat flux and low coolant velocities under ...

  2. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01T23:59:59.000Z

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  3. CenterPoint Energy- Residential Gas Heating Rebates

    Broader source: Energy.gov [DOE]

    CenterPoint Energy offers gas heating and water heating equipment rebates to its residential customers. Eligible equipment includes furnaces, back-up furnace systems, hydronic heaters, storage...

  4. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2007-06-30T23:59:59.000Z

    In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

  5. Heat transfer in gas tungsten arc welding

    SciTech Connect (OSTI)

    Smartt, H.B.; Stewart, J.A.; Einerson, C.J.

    1986-05-01T23:59:59.000Z

    The heat transferred from an electrode negative, argon gas tungsten arc to an anode has been measured for a wide range of conditions suitable for mechanized welding applications. The results are given as (1) the arc efficiency; and (2) the anode heat and current input distribution functional shapes and radii for various anode materials and groove shapes over a wide range of current and voltage, using different electrode geometries, as well as both He and Ar-He shielding gases. The nominal arc is Gaussian with a diameter of about 4 mm and a heat transfer efficiency to the anode of about 75%. Variations from these values are discussed in terms of current knowledge of the electrical and thermal energy transport mechanisms. A new method of measuring the heat transferred from the arc to the anode, using a boiling liquid nitrogen calorimeter, has been developed which gives rapid, accurate values.

  6. Industrial Waste Heat Recovery

    E-Print Network [OSTI]

    Ward, M. E.; Solomon, N. G.; Tabb, E. S.

    1980-01-01T23:59:59.000Z

    INDUSTRIAL WASTE HEAT RECOVREY M. E. Ward and N. G. Solomon E. S. Tabb Solar Turbines International and Gas Research Institute San Diego, California Chicago, Illinois ABSTRACT i I One hundred fifty reports were reviewed along with interviews... tests, promising low temperature heat exchanger tube alloys and coated surfaces were identified. 1INTROUCTION of advanced technology heat recovery techniques 1_ Recovering waste heat from the flue gases of the pr~ary objective. Specific objectives...

  7. FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS

    SciTech Connect (OSTI)

    Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

    2004-01-29T23:59:59.000Z

    With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

  8. Method and apparatus for fuel gas moisturization and heating

    DOE Patents [OSTI]

    Ranasinghe, Jatila (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    Fuel gas is saturated with water heated with a heat recovery steam generator heat source. The heat source is preferably a water heating section downstream of the lower pressure evaporator to provide better temperature matching between the hot and cold heat exchange streams in that portion of the heat recovery steam generator. The increased gas mass flow due to the addition of moisture results in increased power output from the gas and steam turbines. Fuel gas saturation is followed by superheating the fuel, preferably with bottom cycle heat sources, resulting in a larger thermal efficiency gain compared to current fuel heating methods. There is a gain in power output compared to no fuel heating, even when heating the fuel to above the LP steam temperature.

  9. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-12-31T23:59:59.000Z

    This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

  10. DEVELOPMENT OF THFEGENERAL ELECTRIC STIRLING ENGINE GAS HEAT PUMP

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DEVELOPMENT OF THFEGENERAL ELECTRIC STIRLING ENGINE GAS HEAT PUMP R. C. Meier, Program Manager, Gas for the market- place of the 1980's. 1 7//AA -'6 1 #12;DEVELOPMENT OF THE GENERAL ELECTRIC STIRLING ENGINE GAS Heat Pump Program General Electric Company P. 0. Box 8555 Philadelphia, Pennsylvania 19101 FILE COPY DO

  11. Working on new gas turbine cycle for heat pump drive

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Working on new gas turbine cycle for heat pump drive FILE COPY TAP By Irwin Stambler, Field Editor DO NOT 16 0 REMOVE 16 Small recuperated gas turbine engine, design rated at 13 hp and 27% efficiency of the cycle- as a heat pump drive for commercial installations. Company is testing prototype gas turbine

  12. Residential Multi-Function Gas Heat Pump: Efficient Engine-Driven...

    Office of Environmental Management (EM)

    Residential Multi-Function Gas Heat Pump: Efficient Engine-Driven Heat Pump for the Residential Sector - Fact Sheet, 2013 Residential Multi-Function Gas Heat Pump: Efficient...

  13. High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines - Phase I: Laboratory investigations. Quarterly report, October 1993--December 1993

    SciTech Connect (OSTI)

    Not Available

    1994-03-01T23:59:59.000Z

    This project proposes to use pneumatically or hydraulically emplaced dry-flue gas desulfurization (FGD) by-products to backfill the adits left by highwall mining. Backfilling highwall mine adits with dry-FGD materials is technically attractive. The use of an active highwall mine would allow the dry-FGD material to be brought in using the same transportation network used to move the coal out, eliminating the need to recreated the transportation infrastructure, thereby saving costs. Activities during the period included the negotiations leading to the final cooperative agreement for the project and the implementation of the necessary instruments at the University of Kentucky to administer the project. Early in the negotiations, a final agreement on a task structure was reached and a milestone plan was filed. A review was initiated of the original laboratory plan as presented in the proposal, and tentative modifications were developed. Selection of a mine site was made early; the Pleasant Valley mine in Greenup County was chosen. Several visits were made to the mine site to begin work on the hydrologic monitoring plan. The investigation of the types of permits needed to conduct the project was initiated. Considerations concerning the acceptance and implementation of technologies led to the choice of circulating fluidized bed ash as the primary material for the study. Finally, the membership of a Technical Advisory Committee for the study was assembled.

  14. Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction

    SciTech Connect (OSTI)

    Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-01-15T23:59:59.000Z

    Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

  15. Increasing interest in the gas engine heat pump

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    Increasing primary-energy prices and the availability of untapped heat sources have sparked interest in using a high-efficiency natural gas-driven engine as the power source in a heatpump system. This approach is being studied using a 37-kW Waukesha gas engine; one recently completed installation at Schiedam, Netherlands, extracts heat from a nearby waterway and utilizes the gas engine's waste heat as well.

  16. A Gas-Fired Heat Pipe Zone Heater 

    E-Print Network [OSTI]

    Winn, C. B.; Burns, P.; Guire, J.

    1984-01-01T23:59:59.000Z

    A gas-fired vented zone heater has recently been developed by the Altar Corporation for Colorado State University (CSU) under a Gas Research Institute (GRI) contract. The unit war developed for auxiliary heating applications in passive solar...

  17. A Gas-Fired Heat Pipe Zone Heater

    E-Print Network [OSTI]

    Winn, C. B.; Burns, P.; Guire, J.

    1984-01-01T23:59:59.000Z

    A gas-fired vented zone heater has recently been developed by the Altar Corporation for Colorado State University (CSU) under a Gas Research Institute (GRI) contract. The unit war developed for auxiliary heating applications in passive solar...

  18. Southwest Gas Corporation- Combined Heat and Power Program

    Broader source: Energy.gov [DOE]

    Southwest Gas Corporation (SWG) offers incentives to qualifying commercial and industrial facilities who install efficient Combined Heat and Power systems (CHP). CHP systems produce localized, on...

  19. ,"New Mexico Heat Content of Natural Gas Consumed"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Heat Content of Natural Gas Consumed",1,"Monthly","12015","1152013"...

  20. Combustion Exhaust Gas Heat to Power usingThermoelectric Engines...

    Broader source: Energy.gov (indexed) [DOE]

    Solutions Combustion Exhaust Gas Heat to Power using Thermoelectric Engines John LaGrandeur October 5, 2011 Advanced Thermoelectric Solutions - 1 - Market motivation based on CO 2...

  1. Condensing Heat Exchangers Optimize Steam Boilers

    E-Print Network [OSTI]

    Sullivan, B.; Sullivan, P. A.

    1983-01-01T23:59:59.000Z

    the flue gas from the p~oducts of combustion faom natural gas from 300 to the dew point of 129 results in an efficiency increase of 3%. Further cooling, resulting in condensa tion of water vapor, increases the rate of heat recovery dramatically and a...

  2. COLLISIONLESS ELECTRON HEATING IN RF GAS DISCHARGES: I. QUASILINEAR THEORY

    E-Print Network [OSTI]

    Kaganovich, Igor

    COLLISIONLESS ELECTRON HEATING IN RF GAS DISCHARGES: I. QUASILINEAR THEORY Yu.M. Aliev1 , I an interest in mechanisms of electron heating and power deposition in the plasma main- tained by radio{frequency (rf) electric elds. A modern trend in plasma technology aims at decreasing the gas pressures down

  3. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01T23:59:59.000Z

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  4. FlueGen Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489Information Hydro IncEnergy InformationFlue GasFlueGen Inc

  5. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01T23:59:59.000Z

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  6. Energy Recovery By Direct Contact Gas-Liquid Heat Exchange

    E-Print Network [OSTI]

    Fair, J. R.; Bravo, J. L.

    ENERGY RECOVERY BY DIRECf CONTACf GAS-LIQUID HEAT EXCHANGE James R. Fair and Jose L. Bravo Separations Research Program The University o/Texas at Austin Austin, Texas ABSIRACf Energy from hot gas discharge streams can be recovered... by transfer directly to a coolant liquid in one of several available gas-liquid contacting devices. The design of the device is central to the theme of this paper, and experimental work has verified that the analogy between heat transfer and mass transfer...

  7. Dynamic Allocation of a Domestic Heating Task to Gas-Based and Heatpump-Based Heating Agents

    E-Print Network [OSTI]

    Treur, Jan

    Dynamic Allocation of a Domestic Heating Task to Gas-Based and Heatpump-Based Heating Agents Jan for a domestic heating task is introduced and analysed. The model includes two alternative heating agents (for gas-based heating and for heatpump-based heating), and a third allocation agent which determines

  8. Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (Oakland, CA); Griffiths, Elizabeth A. (Neston, GB2); Littlejohn, David (Oakland, CA)

    1988-01-01T23:59:59.000Z

    The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

  9. Forming liquid sprays in compressed-gas energy storage systems for effective heat exchange

    DOE Patents [OSTI]

    McBride, Troy O; Bell, Alexander; Bollinger, Benjamin R; Shang, Andrew; Chmiel, David; Richter, Horst; Magari, Patrick; Cameron, Benjamin

    2013-07-02T23:59:59.000Z

    In various embodiments, efficiency of energy storage and recovery systems compressing and expanding gas is improved via heat exchange between the gas and a heat-transfer fluid.

  10. Forming liquid sprays in compressed-gas energy storage systems for effective heat exchange

    DOE Patents [OSTI]

    McBride, Troy O.; Bell, Alexander; Bollinger, Benjamin R.

    2012-08-07T23:59:59.000Z

    In various embodiments, efficiency of energy storage and recovery systems compressing and expanding gas is improved via heat exchange between the gas and a heat-transfer fluid.

  11. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31T23:59:59.000Z

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

  12. Cascade heat recovery with coproduct gas production

    DOE Patents [OSTI]

    Brown, William R. (Zionsville, PA); Cassano, Anthony A. (Allentown, PA); Dunbobbin, Brian R. (Allentown, PA); Rao, Pradip (Allentown, PA); Erickson, Donald C. (Annapolis, MD)

    1986-01-01T23:59:59.000Z

    A process for the integration of a chemical absorption separation of oxygen and nitrogen from air with a combustion process is set forth wherein excess temperature availability from the combustion process is more effectively utilized to desorb oxygen product from the absorbent and then the sensible heat and absorption reaction heat is further utilized to produce a high temperature process stream. The oxygen may be utilized to enrich the combustion process wherein the high temperature heat for desorption is conducted in a heat exchange preferably performed with a pressure differential of less than 10 atmospheres which provides considerable flexibility in the heat exchange.

  13. Cascade heat recovery with coproduct gas production

    DOE Patents [OSTI]

    Brown, W.R.; Cassano, A.A.; Dunbobbin, B.R.; Rao, P.; Erickson, D.C.

    1986-10-14T23:59:59.000Z

    A process for the integration of a chemical absorption separation of oxygen and nitrogen from air with a combustion process is set forth wherein excess temperature availability from the combustion process is more effectively utilized to desorb oxygen product from the absorbent and then the sensible heat and absorption reaction heat is further utilized to produce a high temperature process stream. The oxygen may be utilized to enrich the combustion process wherein the high temperature heat for desorption is conducted in a heat exchange preferably performed with a pressure differential of less than 10 atmospheres which provides considerable flexibility in the heat exchange. 4 figs.

  14. PECO Energy (Gas) – Heating Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    The PECO Smart Gas Efficiency Upgrade Program offers rebates and incentives to commercial or residential customers that install an ENERGY STAR qualified high-efficiency natural gas furnace or...

  15. Southwest Gas Corporation- Smarter Greener Better Solar Water Heating Program

    Broader source: Energy.gov [DOE]

    Southwest Gas is offering rebates to Nevada customers for solar water heating systems installed in private residential, small business, public and other properties. Rebates are based on the amount...

  16. Questar Gas- Residential Solar Assisted Water Heating Rebate Program

    Broader source: Energy.gov [DOE]

    Questar gas provides incentives for residential customers to purchase and install solar water heating systems on their homes. Rebates of $750 per system are provided to customers of Questar who...

  17. Questar Gas- Residential Solar Assisted Water Heating Rebate Program (Idaho)

    Broader source: Energy.gov [DOE]

    Questar gas provides incentives for residential customers to purchase and install solar water heating systems on their homes. Rebates of $750 per system are provided to customers of Questar who...

  18. Questar Gas- Residential Solar Assisted Water Heating Rebate Program

    Broader source: Energy.gov [DOE]

    Questar Gas provides incentives for residential customers to purchase and install solar water heating systems on their homes. Rebates of $750 per system are provided to customers of Questar who...

  19. Table 26. Natural gas home customer-weighted heating degree...

    Gasoline and Diesel Fuel Update (EIA)

    92 Created on: 3262015 1:21:33 PM Table 26. Natural gas home customer-weighted heating degree days New England Middle Atlantic East North Central West North Central South...

  20. Separation of flue-gas scrubber sludge into marketable products. Second quarterly technical progress report, December 1, 1993--February 28, 1994 (Quarter No. 2)

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1994-03-01T23:59:59.000Z

    To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. It consists of calcium sulfite (CaSO{sub 3}{lg_bullet}0.5H{sub 2}0), gypsum (CaSO{sub 4}{lg_bullet}2H{sub 2}0), and unreacted limestone (CaCO{sub 3}) or lime (Ca(OH){sub 2}), with miscellaneous objectionable impurities such as iron oxides; silica; and magnesium, sodium, and potassium oxides or salts. Currently, the only market for scrubber sludge is for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. This project is developing a process that can produce a high-quality calcium sulfite or gypsum product while keeping process costs low enough that the material produced will be competitive with that from other, more conventional sources. This purification will consist of minimal-reagent froth flotation, using the surface properties of the particles of unreacted limestone to remove them and their associated impurities from the material, leaving a purified gypsum or calcium sulfite product. The separated limestone will be a useful by-product, as it can be recycled to the scrubber, thus boosting the limestone utilization and improving process efficiency. Calcium sulfite will then be oxidized to gypsum, or separated as a salable product in its own right from sludges where it is present in sufficient quantity. The main product of the process will be either gypsum or calcium sulfite, depending on the characteristics of the sludge being processed. These products will be sufficiently pure to be easily marketed, rather that being landfilled.

  1. Novel technologies for SO{sub x}/NO{sub x} removal from flue gas. Technical report, March 1, 1994--May 31, 1994

    SciTech Connect (OSTI)

    Kung, H.; Kung, M.; Yang, B.; Spivey, J.J.; Jang, B.W.

    1994-09-01T23:59:59.000Z

    The goal of this project is to develop a cost-effective low temperature deNO{sub x} catalyst to be used in the Research Triangle Institute-Waterloo SO{sub 2}/NO{sub x} process for boiler retrofit applications. The performance goal of the catalyst is to convert over 80% of the NO in the flue gas at a temperature as low as 150{degrees}C in the presence of 4% O{sub 2}, and 10% water. Based on the results obtained in the previous quarter, which showed a La-Cu-ZrO{sub 2} catalyst to be a promising low temperature catalyst in the presence of 2% H{sub 2}O in the reduction of NO to N{sub 2} with isobutanol, research was conducted to investigate the variations in feed conditions on the performance of the catalyst. Specifically, the effect of increased H{sub 2}O concentration and the effect of NO{sub 2} in the feed were investigated. Although the activity of the catalyst declined when the H{sub 2}O concentration was increased from 2 to 10%, the decline was relatively mild compared with that when the water content was changed from 0 to 2%. The effect of NO{sub 2} was investigated because oxidation of NO to NO{sub 2}, a thermodynamically favorable process, proceeds at a finite rate even in the absence of a catalyst. It was found that, under the low temperature reaction conditions, replacement of NO{sub 2} with NO did not affect the catalytic performance of the La-Cu-ZrO{sub 2} catalyst. Besides studying the La-Cu-ZrO{sub 2} catalyst, effort has continued in screening other potential catalysts. A promising 5%Cu-2%Ag catalyst supported on active carbon was found that catalyzes NO reduction by acetone. At 150{degrees}C, 35% NO conversion was obtained in the presence of 4% O{sub 2} and 8% H{sub 2}O at a space velocity of 3000 h{sup {minus}1} after 5 h on stream.

  2. Residential gas heat pump assessment: A market-based approach

    SciTech Connect (OSTI)

    Hughes, P.J.

    1995-09-01T23:59:59.000Z

    There has been considerable activity in recent years to develop technologies that could reduce or levelize residential and light-commercial building space cooling electrical use and heating/cooling energy use. For example, variable or multi-speed electric heat pumps, electric ground-source heat pumps, dual-fuel heat pumps, multi-function heat pumps, and electric cool storage concepts have been developed; and several types of gas heat pumps are emerging. A residential gas heat pump (GHP) benefits assessment is performed to assist gas utility and equipment manufacturer decision making on level of commitment to this technology. The methodology and generic types of results that can be generated are described. National market share is estimated using a market segmentation approach. The assessment design requires dividing the 334 Metropolitan Statistical Areas (MSAS) of the US into 42 market segments of relatively homogeneous weather and gas/electric rates (14 climate groupings by 3 rate groupings). Gas and electric rates for each MSA are evaluated to arrive at population-weighted rates for the market segments. GHPs are competed against 14 conventional equipment options in each homogeneous segment.

  3. Measurement and analysis of gas turbine blade endwall heat transfer

    E-Print Network [OSTI]

    Lee, Joon Ho

    2001-01-01T23:59:59.000Z

    the aerodynamic flow and external heat transfer distribution around the airfoils and end-wall surfaces. A stationary 5 vane linear cascade is designed and developed to investigate gas turbine blade endwall heat transfer and flow. The test cascade is instrumented...

  4. Fluidized-Bed Waste-Heat Recovery System development. Semiannual report, 1 August 1982-31 January 1983

    SciTech Connect (OSTI)

    Cole, W.E.; DeSaro, R.; Joshi, C.

    1983-02-01T23:59:59.000Z

    The Fluidized-Bed Waste-Heat Recovery (FBWHR) System is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, a recirculating medium is heated by the flue gas in a fluidized bed. The hot medium is then removed from the bed and placed in a second fluidized bed where it is fluidized by the combustion air. Through this process, the combustion air is heated. The cooled medium is then returned to the first bed. Initial development of this concept is for the aluminum smelting industry.

  5. Method of coverning the working gas temperature of a solar heated hot gas engine

    SciTech Connect (OSTI)

    Almstrom, S.-H.; Nelving, H.G.

    1984-07-03T23:59:59.000Z

    A closed-cycle hot gas engine heated by solar radiation is provided with a governing system varying the working gas pressure so as to vary the power output at a constant high temperature level of the working gas and-at least partly-at a constant engine speed.

  6. Method of governing the working gas temperature of a solar heated hot gas engine

    SciTech Connect (OSTI)

    Almstrom, S.H.; Nelving, H.G.

    1984-07-03T23:59:59.000Z

    A closed-cycle hot gas engine heated by solar radiation is provided with a governing system varying the working gas pressure so as to vary the power output at a constant high temperature level of the working gas and-at least partly-at a constant engine speed.

  7. Heat Exchanger Fouling- Prediction, Measurement and Mitigation

    E-Print Network [OSTI]

    Peterson, G. R.

    wall. The fouling probe has been successfully tested in the laboratory at flue gas temperatures up to 2200°F and a local heat flux up to 41,000 BTU/hr-ft2. The probe has been field tested at a coal-fired boiler plant. Future tests at a municipal waste...

  8. Method for controlling exhaust gas heat recovery systems in vehicles

    DOE Patents [OSTI]

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11T23:59:59.000Z

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  9. Transient fission gas release during direct electrical heating experiments

    SciTech Connect (OSTI)

    Fenske, G.R.; Emerson, J.E.; Savoie, F.E.

    1983-12-01T23:59:59.000Z

    The gas release behavior of irradiated EBR-II fuel was observed to be dependent on several factors: the presence of cladding, the retained gas content, and the energy absorbed. Fuel that retained in excess of 16 to 17 ..mu..moles/g of fission gas underwent spallation as the cladding melted and released 22 to 45% of its retained gas, while fuel with retained gas levels below approx. 15 to 16 ..mu..moles/g released less than approx. 9% of its gas as the cladding melted. During subsequent direct electrical heating ramps, fuel that did not spall released an additional quantity of gas (up to 4 ..mu..moles/g), depending on the energy absorbed.

  10. Indriect Measurement Of Nitrogen In A Mult-Component Natural Gas By Heating The Gas

    DOE Patents [OSTI]

    Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

    2004-06-22T23:59:59.000Z

    Methods of indirectly measuring the nitrogen concentration in a natural gas by heating the gas. In two embodiments, the heating energy is correlated to the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. Regression analysis is used to calculate the constant values, which can then be substituted into the model equation. If the diluent concentrations other than nitrogen (typically carbon dioxide) are known, the model equation can be solved for the nitrogen concentration.

  11. Industrial Heat Recovery with Organic Rankine Cycles

    E-Print Network [OSTI]

    Hnat, J. G.; Patten, J. S.; Cutting, J. C.; Bartone, L. M.

    1982-01-01T23:59:59.000Z

    to examine a specific application of the use of an ORC heat recovery system and compare it to a stear), Rankine cycle heat recovery system. The particular application ~ssumed is heat recovery from diesel engine exhaust gas at a temPErature of 700F. Figure...,vaporized and superheated ina flue gas heat recovery su bsystem. he super heated fluid is expanded through a turbine for power p oduction, condensed in a water cooled condenser and return d to the vaporizer via feed pu mps. In the steam cycle, a port n of the Figure 1...

  12. Low-pressure-ratio regenerative exhaust-heated gas turbine

    SciTech Connect (OSTI)

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01T23:59:59.000Z

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  13. Sour gas injection for use with in situ heat treatment

    DOE Patents [OSTI]

    Fowler, Thomas David (Houston, TX)

    2009-11-03T23:59:59.000Z

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for providing acidic gas to a subsurface formation is described herein. The method may include providing heat from one or more heaters to a portion of a subsurface formation; producing fluids that include one or more acidic gases from the formation using a heat treatment process. At least a portion of one of the acidic gases may be introduced into the formation, or into another formation, through one or more wellbores at a pressure below a lithostatic pressure of the formation in which the acidic gas is introduced.

  14. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  15. Performance of Gas-Engine Driven Heat Pump Unit

    SciTech Connect (OSTI)

    Abdi Zaltash; Randy Linkous; Randall Wetherington; Patrick Geoghegan; Ed Vineyard; Isaac Mahderekal; Robert Gaylord

    2008-09-30T23:59:59.000Z

    Air-conditioning (cooling) for buildings is the single largest use of electricity in the United States (U.S.). This drives summer peak electric demand in much of the U.S. Improved air-conditioning technology thus has the greatest potential impact on the electric grid compared to other technologies that use electricity. Thermally-activated technologies (TAT), such as natural gas engine-driven heat pumps (GHP), can provide overall peak load reduction and electric grid relief for summer peak demand. GHP offers an attractive opportunity for commercial building owners to reduce electric demand charges and operating expenses. Engine-driven systems have several potential advantages over conventional single-speed or single-capacity electric motor-driven units. Among them are variable speed operation, high part load efficiency, high temperature waste heat recovery from the engine, and reduced annual operating costs (SCGC 1998). Although gas engine-driven systems have been in use since the 1960s, current research is resulting in better performance, lower maintenance requirements, and longer operating lifetimes. Gas engine-driven systems are typically more expensive to purchase than comparable electric motor-driven systems, but they typically cost less to operate, especially for commercial building applications. Operating cost savings for commercial applications are primarily driven by electric demand charges. GHP operating costs are dominated by fuel costs, but also include maintenance costs. The reliability of gas cooling equipment has improved in the last few years and maintenance requirements have decreased (SCGC 1998, Yahagi et al. 2006). Another advantage of the GHP over electric motor-driven is the ability to use the heat rejected from the engine during heating operation. The recovered heat can be used to supplement the vapor compression cycle during heating or to supply other process loads, such as water heating. The use of the engine waste heat results in greater operating efficiency compared to conventional electric motor-driven units (SCGC 1998). In Japan, many hundreds of thousands of natural gas-driven heat pumps have been sold (typically 40,000 systems annually) (Yahagi et al. 2006). The goal of this program is to develop dependable and energy efficient GHPs suitable for U.S. commercial rooftop applications (the single largest commercial product segment). This study describes the laboratory performance evaluation of an integrated 10-ton GHP rooftop unit (a 900cc Daihatsu-Aisin natural gas engine) which uses R410A as the refrigerant (GEDAC No.23). ORNL Thermally-Activated Heat Pump (TAHP) Environmental Chambers were used to evaluate this unit in a controlled laboratory environment.

  16. Florida Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.Gas ProvedCommercial

  17. Florida Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.Gas ProvedCommercialNov-14 Dec-14 Jan-15 Feb-15

  18. Georgia Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYear JanPrice Data59.2 58.987.193.52009 2010

  19. Georgia Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYear JanPrice Data59.2 58.987.193.52009

  20. Hawaii Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOW TO OBTAIN EIACubic Feet)2009

  1. Hawaii Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOW TO OBTAIN EIACubic

  2. Idaho Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOWYear-Month Week2009 2010 2011 2012

  3. Idaho Heat Content of Natural Gas Consumed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOWYear-Month Week2009 2010 2011

  4. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Final report

    SciTech Connect (OSTI)

    Sublette, K.L.

    1994-03-01T23:59:59.000Z

    The main objective of this research was to investigate microorganisms capable of fossil fuel flue gas desulfurization and denitrification. The study used municipal sewage sludge as a carbon and energy source for SO{sub 2}-reducing cultures. The individual tasks developed a consortium of sulfate-reducing bacteria, investigated the design parameters for a continuous process, preformed a cost analysis, and screened sulfate-reducing bacteria. In the investigation of microbial reduction of NO{sub x} to nitrogen, tasks included screening denitrifying bacteria for NO and NO{sub 2} activity, developing optimum NO-reducing cultures, and investigating design parameters for a continuous system. This final report reviews the work previous to the current project, describes project objectives and the specific work plan, and reports results from the work completed during the previous reporting periods.

  5. CenterPoint Energy (Gas)- Residential Heating and Hot Water Rebates

    Broader source: Energy.gov [DOE]

    CenterPoint Energy offers gas heating and water heating equipment rebates to its residential customers. Eligible equipment includes furnaces, back-up furnace systems, hydronic heaters, storage...

  6. Condensing Heat Exchanger for Optimization of Energy Efficiency 

    E-Print Network [OSTI]

    Carrigan, J. F.; Johnson, D. W.; DiVitto, J. G.; Schulze, K. H.

    1995-01-01T23:59:59.000Z

    Historically, boiler efficiency has been limited due to the minimum temperature allowed at the stack. Heat lost up the stack was in exchange for keeping the flue gas temperature above the water vapor dew point. If water vapor was allowed to condense...

  7. Condensing Heat Exchanger for Optimization of Energy Efficiency

    E-Print Network [OSTI]

    Carrigan, J. F.; Johnson, D. W.; DiVitto, J. G.; Schulze, K. H.

    Historically, boiler efficiency has been limited due to the minimum temperature allowed at the stack. Heat lost up the stack was in exchange for keeping the flue gas temperature above the water vapor dew point. If water vapor was allowed to condense...

  8. Heat and mass transfer in the gas tungsten and gas metal arc welding processes

    SciTech Connect (OSTI)

    Watkins, A.D; Smartt, H.B.; Einerson, C.J.; Watkins, J.A.

    1990-01-01T23:59:59.000Z

    The heat transferred from an electrode negative, argon gas tungsten arc to an anode was measured for a wide range of conditions suitable for mechanized welding. The results are given as (1) the arc efficiency and (2) the anode heat and current input distributions for various anode materials over a range of current and voltage. The nominal arc is Gaussian, {approximately}4 mm in diameter, with {approximately}75{percent}heat transfer efficiency. Variations from these values are discussed in terms of the electrical and thermal energy transport mechanisms. Heat transferred to the workpiece (cathode) during direct current, electrode positive gas metal arc welding (GMAW) was measured for various parameters applicable to machine welding. The results are presented as a function of electrode speed for changing voltages and contact tip to workpiece distances. The total heat transfer efficiency was nominally 85{percent} for a 0.89 mm diameter steel electrode using an argon-2{percent} oxygen shielding gas; the nominal heat transfer efficiency of the droplet component was 40{percent}. The average droplet temperatures ranged from 2400 to 3100 K, depending on the process parameters. A new method of measuring the heat transferred from the arc to the workpiece, using a boiling liquid nitrogen calorimeter, has been developed that gives rapid, accurate values. 20 refs., 8 figs., 2 tabs.

  9. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  10. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  11. Comparative evaluation of the impacts of domestic gas and electric heat pump heating on air pollution in California. Final report

    SciTech Connect (OSTI)

    Ganji, A. [San Francisco State Univ., CA (United States). Div. of Engineering

    1992-07-01T23:59:59.000Z

    Residential space and water heating accounts for approximately 12% of California`s and 15% of the United States, energy consumption. most Of the residential heating is by direct use of natural gas. combustion of natural gas is a contributor to the overall air pollution,, especially CO and NO{sub x} in the urban areas. Another efficient method for domestic water and space heating is use of electric heat pumps, the most popular category of which uses air as its heat source. Electric heat pumps do not emit air pollutants at the point of use, but use electric power, which is a major contributor to air pollution at its point of generation from fossil fuels. It is the specific objective of this report to evaluate and compare the energy efficiency and source air pollutants of natural gas heaters and electric heat pumps used for domestic heating. Effect of replacing natural gas heaters with electric heat pumps on air pollutant emissions due to domestic heating in two urban areas and in California as a whole has also been evaluated. The analysis shows that with the present state of technology, electric heat pumps have higher heating efficiencies than natural gas heaters. Considering the current electricity generation mix in the US, electric heat pumps produce two to four times more NO{sub x}, much less CO, and comparable amount of CO{sub 2} per unit of useful heating energy compared to natural gas heaters. With California mix, electric heat pumps produce comparable NO{sub x} and much less CO and approximately 30% less CO{sub 2} per unit heat output. Replacement of natural gas heaters with electric heat pumps will slightly increase the overall NO{sub x}, and reduce CO and CO{sub 2} emissions in California. The effect of advanced technology power generation and heat pump heating has also been analyzed.

  12. Comparative evaluation of the impacts of domestic gas and electric heat pump heating on air pollution in California

    SciTech Connect (OSTI)

    Ganji, A. (San Francisco State Univ., CA (United States). Div. of Engineering)

    1992-07-01T23:59:59.000Z

    Residential space and water heating accounts for approximately 12% of California's and 15% of the United States, energy consumption. most Of the residential heating is by direct use of natural gas. combustion of natural gas is a contributor to the overall air pollution,, especially CO and NO{sub x} in the urban areas. Another efficient method for domestic water and space heating is use of electric heat pumps, the most popular category of which uses air as its heat source. Electric heat pumps do not emit air pollutants at the point of use, but use electric power, which is a major contributor to air pollution at its point of generation from fossil fuels. It is the specific objective of this report to evaluate and compare the energy efficiency and source air pollutants of natural gas heaters and electric heat pumps used for domestic heating. Effect of replacing natural gas heaters with electric heat pumps on air pollutant emissions due to domestic heating in two urban areas and in California as a whole has also been evaluated. The analysis shows that with the present state of technology, electric heat pumps have higher heating efficiencies than natural gas heaters. Considering the current electricity generation mix in the US, electric heat pumps produce two to four times more NO{sub x}, much less CO, and comparable amount of CO{sub 2} per unit of useful heating energy compared to natural gas heaters. With California mix, electric heat pumps produce comparable NO{sub x} and much less CO and approximately 30% less CO{sub 2} per unit heat output. Replacement of natural gas heaters with electric heat pumps will slightly increase the overall NO{sub x}, and reduce CO and CO{sub 2} emissions in California. The effect of advanced technology power generation and heat pump heating has also been analyzed.

  13. A Heating Model for the Millennium Gas Run

    E-Print Network [OSTI]

    L. Gazzola; F. R. Pearce

    2006-11-22T23:59:59.000Z

    The comparison between observations of galaxy clusters thermo-dynamical properties and theoretical predictions suggests that non-gravitational heating needs to be added into the models. We implement an internally self-consistent heating scheme into GADGET-2 for the third (and fourth) run of the Millennium gas project (Pearce et al. in preparation), a set of four hydrodynamical cosmological simulations with N=2(5x10^8) particles and with the same volume (L=500 h-1 Mpc) and structures as the the N-body Millennium Simulation (Springel et al. 2005). Our aim is to reproduce the observed thermo-dynamical properties of galaxy clusters.

  14. Fluidized-bed waste-heat recovery system development: Final report

    SciTech Connect (OSTI)

    Patch, K.D.; Cole, W.E.

    1988-06-01T23:59:59.000Z

    A major energy loss in industry is the heat content of the flue gases from industrial process heaters. One effective way to utilize the energy, which is applicable to all processes, is to preheat the combustion air for the process heater. Although recuperators are available to preheat this air when the flue gases are clean, recuperators to recover the heat from dirty and corrosive flue gases do not exist. The Fluidized-Bed Waste-Heat Recovery (FBWHR) system is designed to preheat this combustion air using the heat available in dirty flue gas streams. In this system, recirculating alumina particles are heated by the flue gas in a raining bed. The hot particles are then removed from the bed and placed in a fluidized bed where they are fluidized by the combustion air. Through this process, the combustion air is preheated. The cooled particles are then returned to the raining bed. Initial development of this concept is for the aluminum smelting industry. In this final report, the design, development, fabrication, and installation of a full-scale FBWHR system is detailed.

  15. Study of the Heating Load of a Manufactured Space with a Gas-fired Radiant Heating System

    E-Print Network [OSTI]

    Zheng, X.; Dong, Z.

    2006-01-01T23:59:59.000Z

    A thermal balance mathematics model of a manufactured space with a gas-fired radiant heating system is established to calculate the heating load. Computer programs are used to solve the model. Envelope internal surface temperatures under different...

  16. A comparison of ground source heat pumps and micro-combined heat and power as residential greenhouse gas reduction strategies

    E-Print Network [OSTI]

    Guyer, Brittany (Brittany Leigh)

    2009-01-01T23:59:59.000Z

    Both ground source heat pumps operating on electricity and micro-combined heat and power systems operating on fossil fuels offer potential for the reduction of green house gas emissions in comparison to the conventional ...

  17. Study of the Heating Load of a Manufactured Space with a Gas-fired Radiant Heating System 

    E-Print Network [OSTI]

    Zheng, X.; Dong, Z.

    2006-01-01T23:59:59.000Z

    A thermal balance mathematics model of a manufactured space with a gas-fired radiant heating system is established to calculate the heating load. Computer programs are used to solve the model. Envelope internal surface temperatures under different...

  18. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  19. Heating and cooling gas-gun targets: nuts and bolts

    SciTech Connect (OSTI)

    Gustavsen, Richard L [Los Alamos National Laboratory; Bartram, Brian D [Los Alamos National Laboratory; Gehr, Russell J [HONEYWEL FM& T; Bucholtz, Scott M [HINEYWELL FM& T

    2009-01-01T23:59:59.000Z

    The nuts and bolts of a system used to heat and cool gas-gun targets is described. We have now used the system for more than 35 experiments, all of which have used electromagnetic gauging. Features of the system include a cover which is removed (remotely) just prior to projectile impact and the widespread use of metal/polymer insulations. Both the cover and insulation were required to obtain uniform temperatures in samples with low thermal conductivity. The use of inexpensive video cameras to make remote observations of the cover removal was found to be very useful. A brief catalog of useful glue, adhesive tape, insulation, and seal materials is given.

  20. Ex Parte Communication Gas Heat SPVU Question | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan Departmentof1-SCORECARD-09-21-11 Page5-03Department ofEnergyGas Heat

  1. Int. Symp. on Heat Transfer in Gas Turbine Systems 9 14 August, 2009, Antalya, Turkey

    E-Print Network [OSTI]

    Camci, Cengiz

    for turbine aero heat transfer work performed under rotational conditions. A flow coefficient and a loading candidates to generate very realistic gas turbine heat transfer data, the initial investment made generate an accurately measurable amount of heat transfer from the gas side to turbine blades in a linear

  2. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect (OSTI)

    Sublette, K.L.

    1992-12-31T23:59:59.000Z

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  3. Energy recovery during expansion of compressed gas using power plant low-quality heat sources

    DOE Patents [OSTI]

    Ochs, Thomas L. (Albany, OR); O'Connor, William K. (Lebanon, OR)

    2006-03-07T23:59:59.000Z

    A method of recovering energy from a cool compressed gas, compressed liquid, vapor, or supercritical fluid is disclosed which includes incrementally expanding the compressed gas, compressed liquid, vapor, or supercritical fluid through a plurality of expansion engines and heating the gas, vapor, compressed liquid, or supercritical fluid entering at least one of the expansion engines with a low quality heat source. Expansion engines such as turbines and multiple expansions with heating are disclosed.

  4. Optimization of Combustion Efficiency for Supplementally Fired Gas Turbine Cogenerator Exhaust Heat Receptors

    E-Print Network [OSTI]

    Waterland, A. F.

    1984-01-01T23:59:59.000Z

    A broad range of unique cogeneration schemes are being installed or considered for application in the process industries involving gas turbines with heat recovery from the exhaust gas. Depending on the turbine design, exhaust gases will range from...

  5. Gas Turbine/Solar Parabolic Trough Hybrid Design Using Molten Salt Heat Transfer Fluid: Preprint

    SciTech Connect (OSTI)

    Turchi, C. S.; Ma, Z.

    2011-08-01T23:59:59.000Z

    Parabolic trough power plants can provide reliable power by incorporating either thermal energy storage (TES) or backup heat from fossil fuels. This paper describes a gas turbine / parabolic trough hybrid design that combines a solar contribution greater than 50% with gas heat rates that rival those of natural gas combined-cycle plants. Previous work illustrated benefits of integrating gas turbines with conventional oil heat-transfer-fluid (HTF) troughs running at 390?C. This work extends that analysis to examine the integration of gas turbines with salt-HTF troughs running at 450 degrees C and including TES. Using gas turbine waste heat to supplement the TES system provides greater operating flexibility while enhancing the efficiency of gas utilization. The analysis indicates that the hybrid plant design produces solar-derived electricity and gas-derived electricity at lower cost than either system operating alone.

  6. Optimization of Combustion Efficiency for Supplementally Fired Gas Turbine Cogenerator Exhaust Heat Receptors 

    E-Print Network [OSTI]

    Waterland, A. F.

    1984-01-01T23:59:59.000Z

    A broad range of unique cogeneration schemes are being installed or considered for application in the process industries involving gas turbines with heat recovery from the exhaust gas. Depending on the turbine design, exhaust gases will range from...

  7. Gas, Heat, Water, Sewerage Collection and Disposal, and Street Railway Companies (South Carolina)

    Broader source: Energy.gov [DOE]

    This legislation applies to public utilities and entities furnishing natural gas, heat, water, sewerage, and street railway services to the public. The legislation addresses rates and services,...

  8. Electric, Gas, Water, Heating, Refrigeration, and Street Railways Facilities and Service (South Dakota)

    Broader source: Energy.gov [DOE]

    This legislation contains provisions for facilities and service related to electricity, natural gas, water, heating, refrigeration, and street railways. The chapter addresses the construction and...

  9. Superconductor fiber elongation with a heated injected gas

    DOE Patents [OSTI]

    Zeigler, Douglas D. (Atwater, OH); Conrad, Barry L. (Alliance, OH); Gleixner, Richard A. (North Canton, OH)

    2001-01-16T23:59:59.000Z

    An improved method and apparatus for producing flexible fibers (30) of superconducting material includes a crucible (12) for containing a charge of the superconducting material. The material is melted in the crucible (12) and falls in a stream (18) through a bottom hole (16) in the crucible (12). The stream (18) falls through a protecting collar (22) which maintains the stream (18) at high temperatures. The stream (18) is then supplied through a downwardly directed nozzle (26) where it is subjected to a high velocity of a heated gas (36') which breaks the melted superconducting material into ligaments which solidify into the flexible fibers (30). The fibers (30) are collected by directing them against a collection filter (32).

  10. System Modeling and Building Energy Simulations of Gas Engine Driven Heat Pump

    SciTech Connect (OSTI)

    Mahderekal, Isaac [Oak Ridge National Laboratory (ORNL); Vineyard, Edward [Oak Ridge National Laboratory (ORNL)

    2013-01-01T23:59:59.000Z

    To improve the system performance of a gas engine driven heat pump (GHP) system, an analytical modeling and experimental study has been made by using desiccant system in cooling operation (particularly in high humidity operations) and suction line waste heat recovery to augment heating capacity and efficiency. The performance of overall GHP system has been simulated with a detailed vapor compression heat pump system design model. The modeling includes: (1) GHP cycle without any performance improvements (suction liquid heat exchange and heat recovery) as a baseline (both in cooling and heating mode), (2) the GHP cycle in cooling mode with desiccant system regenerated by waste heat from engine incorporated, (3) GHP cycle in heating mode with heat recovery (recovered heat from engine). According to the system modeling results, by using the desiccant system the sensible heat ratio (SHR- sensible heat ratio) can be lowered to 40%. The waste heat of the gas engine can boost the space heating efficiency by 25% at rated operating conditions. In addtion,using EnergyPlus, building energy simulations have been conducted to assess annual energy consumptions of GHP in sixteen US cities, and the performances are compared to a baseline unit, which has a electrically-driven air conditioner with the seasonal COP of 4.1 for space cooling and a gas funace with 90% fuel efficiency for space heating.

  11. Gas-Cooled Fast Reactor (GFR) Decay Heat Removal Concepts

    SciTech Connect (OSTI)

    K. D. Weaver; L-Y. Cheng; H. Ludewig; J. Jo

    2005-09-01T23:59:59.000Z

    Current research and development on the Gas-Cooled Fast Reactor (GFR) has focused on the design of safety systems that will remove the decay heat during accident conditions, ion irradiations of candidate ceramic materials, joining studies of oxide dispersion strengthened alloys; and within the Advanced Fuel Cycle Initiative (AFCI) the fabrication of carbide fuels and ceramic fuel matrix materials, development of non-halide precursor low density and high density ceramic coatings, and neutron irradiation of candidate ceramic fuel matrix and metallic materials. The vast majority of this work has focused on the reference design for the GFR: a helium-cooled, direct power conversion system that will operate with an outlet temperature of 850ºC at 7 MPa. In addition to the work being performed in the United States, seven international partners under the Generation IV International Forum (GIF) have identified their interest in participating in research related to the development of the GFR. These are Euratom (European Commission), France, Japan, South Africa, South Korea, Switzerland, and the United Kingdom. Of these, Euratom (including the United Kingdom), France, and Japan have active research activities with respect to the GFR. The research includes GFR design and safety, and fuels/in-core materials/fuel cycle projects. This report is a compilation of work performed on decay heat removal systems for a 2400 MWt GFR during this fiscal year (FY05).

  12. Analysis of Heating Systems and Scale of Natural Gas-Condensing Water Boilers in Northern Zones

    E-Print Network [OSTI]

    Wu, Y.; Wang, S.; Pan, S.; Shi, Y.

    2006-01-01T23:59:59.000Z

    In this paper, various heating systems and scale of the natural gas-condensing water boiler in northern zones are discussed, based on a technical-economic analysis of the heating systems of natural gas condensing water boilers in northern zones...

  13. Analysis of Heating Systems and Scale of Natural Gas-Condensing Water Boilers in Northern Zones 

    E-Print Network [OSTI]

    Wu, Y.; Wang, S.; Pan, S.; Shi, Y.

    2006-01-01T23:59:59.000Z

    In this paper, various heating systems and scale of the natural gas-condensing water boiler in northern zones are discussed, based on a technical-economic analysis of the heating systems of natural gas condensing water boilers in northern zones...

  14. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  15. High volume - high value usage of Flue Gas Desulfurization (FGD) by-products in underground mines. Quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The amount of dry FGD materials produced in the U.S. has not been increasing at the high rate originally anticipated. This has been due to a number of economic factors affecting the utility industry. Technologies for the disposal of large amounts of materials are not going to be implemented in the near term. In light of this development the target application for this project is being changed from highwall adit filling to the filling of auger holes to allow for highwall mining. This application focuses on using the dry FGD material to recover coal isolated by excessive augering. It produces 10 or more times the amount of coal per ton of dry FGD utilized than the originally proposed methodology. It also does not require extensive equipment development and, if applied to abandoned mine lands, may have substantially more significant environmental benefit. We also propose to use a spray dryer material for the demonstration instead of the fluidized bed material originally proposed. The spray dryer material is already slacked eliminating problems associated with heat generation at the mine site. Auger hole grouting with FGD material is also best performed by hydraulic emplacement methods.

  16. HEAT TRANSFER ON A HYPERSONIC SPHERE WITH DIFFUSE RAREFIED-GAS INJECTION

    E-Print Network [OSTI]

    Riabov, Vladimir V.

    HEAT TRANSFER ON A HYPERSONIC SPHERE WITH DIFFUSE RAREFIED-GAS INJECTION Vladimir V. Riabov* Rivier numbers Re0,R.3-7 Mass injection can be considered as an effective way of the reduction of heat transfer in the case of small Reynolds numbers. Moss12 found that mass injection dramatically reduces heat transfer

  17. Heat Transfer on a Hypersonic Sphere with Gas Injection Vladimir V. Riabov

    E-Print Network [OSTI]

    Riabov, Vladimir V.

    Heat Transfer on a Hypersonic Sphere with Gas Injection Vladimir V. Riabov Department be considered as an effective way of the reduction of heat transfer to the surface in this area [1 the viscous layer is blown completely off the surface, and heat transfer is zero. The effect of injecting

  18. Ameren Illinois (Gas)- Cooking and Heating Business Efficiency Incentives

    Broader source: Energy.gov [DOE]

    Ameren Illinois offers several incentive programs that include efficient natural gas technologies. The programs are available only to non-residential customers that receive natural gas service from...

  19. Direct Gas Fired Air Heating For 40 to 50% Fuel Savings

    E-Print Network [OSTI]

    Searcy, J. A.

    1979-01-01T23:59:59.000Z

    between direct and indirect gas fired unit heaters show why there is a minimum of 40% fuel savings. The application of direct gas-fired make-up heaters for industrial space heating as well as the safety of the direct gas fired systems, a simple...

  20. Coil said to up heat reclaimer efficiency 3-5%

    SciTech Connect (OSTI)

    Not Available

    1984-08-06T23:59:59.000Z

    The Elton Corp. will introduce a new heat reclaimer coil that can be used with its flue gas heat claimer to produce high-temperature hot water. The new coil, which can bring water from 125 to 165 degrees for users that require hotter water, can increase fuel savings by 3 to 5 percent over the standard unit. At prices starting at $32,000 to generate 20 gallons per minute, the heat reclaimer can pay for itself in as little as four months. Both the heat reclaimer and coil are custom built at Eldon's Louisiana plant.

  1. Simulation of Strongly Heated Internal Gas Flows Using a Near-Wall Two-Equation Heat Flux Model

    SciTech Connect (OSTI)

    Richards, Adam H.; Spall, Robert E. [Utah State University, 1400 Old Main Hill Logan, Utah 84322-1400 (United States)

    2006-07-01T23:59:59.000Z

    A two-equation k-{omega} model is used to model a strongly heated, low-Mach number gas flowing upward in a vertical tube. Heating causes significant property variation and thickening of the viscous sublayer, consequently a fully developed flow does not evolve. Two-equation turbulence models generally perform poorly under such conditions. Consequently, in the present work, a near-wall two-equation heat transfer model is utilized in conjunction with the k-{omega} model to improve heat transfer predictions. (authors)

  2. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

    1995-12-31T23:59:59.000Z

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  3. Fluid Bed Waste Heat Boiler Operating Experience in Dirty Gas Streams

    E-Print Network [OSTI]

    Kreeger, A. H.

    FLUID BED WASTE HEAT BOILER OPERATING EXPERIENCE IN DIRTY GAS STREAMS Alan H. Kreeger. Aerojet Energy Conversion Company. Sacramento. California ABSTRACT The first industrial fluid bed waste heat boiler in the U. S. is operating... on an aluminium melting furnace at the ALCOA Massena Integrated Aluminum Works in upstate New York. Waste heat from an aluminum melting furnace is captured for general plant use for the first time in this plant. It is accomplished with advanced fluid bed heat...

  4. CORQUENCH: A model for gas sparging-enhanced, melt-water, film-boiling heat transfer

    SciTech Connect (OSTI)

    Farmer, M.T.; Sienicki, J.J.; Spencer, B.W.

    1990-01-01T23:59:59.000Z

    In evaluation of severe-accident sequences for water-cooled nuclear reactors, molten core materials may be postulated to be released into the containment and accumulate on concrete. The heatup and decomposition of concrete is accompanied by the release of water vapor and carbon dioxide gases. Gases flowing through the melt upper surface can influence the rates of heat transfer to water overlying the melt. In particular, the gas flow through the interface can be envisioned to enhance the heat removal from the melt. A mechanistic model (CORQUENCH) has been developed to describe film-boiling heat transfer between a molten pool and an overlying coolant layer in the presence of sparging gas. The model favorably predicts the lead-Feron 11 data of Greene and Greene et al. for which the calculations indicate that area enhancement in the conduction heat transfer across the film is the predominant mechanism leading to augmentation in the heat flux as the gas velocity increases. Predictions for oxidic corium indicate a rapid increase in film-boiling heat flux as the gas velocity rises. The predominant mode of heat transfer for this case is radiation, and the increase in heat flux with gas velocity is primarily a result of interfacial area enhancement of the radiation component of the overall heat transfer coefficient. The CORQUENCH model has been incorporated into the MELTSPREAD-1 computer code{sup 6} for the analysis of transient spreading in containments.

  5. Supervision and control prototyping for an engine exhaust gas heat recovery system based on a steam Rankine cycle

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Supervision and control prototyping for an engine exhaust gas heat recovery system based on a steam of a practical supervi- sion and control system for a pilot Rankine steam process for exhaust gas heat recovery Rankine steam process for exhaust gas heat recovery from a spark-ignition (SI) engine, from a prototyping

  6. Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)

    E-Print Network [OSTI]

    Demirel, Melik C.

    Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB) to cool process syngas. The gas enters satisfies all 3 design criteria. · Correlations relating our experimental results to a waste heat boiler

  7. Protecting the Investment in Heat Recovery with Boiler Economizers

    E-Print Network [OSTI]

    Roethe, L. A.

    bearing fuels. How ever, the exact reactions have been under study in continuing research. Cause of Cold-end Corrosion - the sulphur com pounds in the fuel are oxidized to sulphur dioxide (S02) during combustion. A small portion of the S02 is further... voice concern over the long term security of an investment in flue gas heat recovery equipment. The concern generally involves the ability of an economizer or air heater to continue to perform efficiently without corrosion. The recognized economic...

  8. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO[sub 2] and NO[sub x] Reduction - Preliminary confirmation of 50% SO[sub 2] reduction has been achieved, but the NO[sub x] reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO[sub 2] reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO[sub 2] Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel's original cost estimates (capital and operating) were prepared. Therefore, SO[sub 2] removal costs are still expected to be in the range of $300/ton or less.

  9. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Bush, P.V.

    1993-01-20T23:59:59.000Z

    We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test the samples. Plans are under way to condition selected samples with (NH[sub 4])[sub 2]SO[sub 4], NH[sub 4]HSO[sub 4], CaCl[sub 2], organosiloxane, and SO[sub 3]. Pending approval, we will begin these conditioning experiments, and subsequent analyses of the conditioned samples.

  10. Fundamental mechanisms in flue gas conditioning

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.

    1992-07-27T23:59:59.000Z

    SEM pictures of the three mixtures of sorbent and ash from the DITF and the base line ESP hopper ash from Muskingum are shown in Figures 1 through 4. The effects of sorbent addition on particle morphology are evident in Figures 2 through 4 by the presence of irregularly shaped particles and deposits on the surfaces of the spherical fly ash particles. In contrast, the base Ene ash particles have the characteristic relatively smooth, spherical morphology normally associated with pulverized-coal (PC) fly ashes. Resistivity determinations made on these four ashes in ascending and descending temperature modes. These data are shown in Figures 5 and 6. Sorbent injection processes performed at the DITF lowered the duct temperature to around 165{degrees}F from about 350{degrees}F for base line operation. Consequently, during collection in the ESP, the particulate matter from the sorbent injection processes had a significantly lower resitivity (approximately 4 {times} 10{sup 7} {Omega}-cm) than the base line ash (approximately 3 {times} 10{sup 11} {Omega}-cm at 350{degrees}F). Specific surface areas and true particle densities have been measured for the four samples obtained from the DOE/PETC Duct Injection Test Facility. These data are summarized in Table 4. The primary difference indicated by these initial analyses of these four samples is the significant increase in specific surface area due to sorbent addition. The specific surface areas of the three sorbent and ash mixtures from the DITF are quite similar.

  11. Two-tank working gas storage system for heat engine

    DOE Patents [OSTI]

    Hindes, Clyde J. (Troy, NY)

    1987-01-01T23:59:59.000Z

    A two-tank working gas supply and pump-down system is coupled to a hot gas engine, such as a Stirling engine. The system has a power control valve for admitting the working gas to the engine when increased power is needed, and for releasing the working gas from the engine when engine power is to be decreased. A compressor pumps the working gas that is released from the engine. Two storage vessels or tanks are provided, one for storing the working gas at a modest pressure (i.e., half maximum pressure), and another for storing the working gas at a higher pressure (i.e., about full engine pressure). Solenoid valves are associated with the gas line to each of the storage vessels, and are selectively actuated to couple the vessels one at a time to the compressor during pumpdown to fill the high-pressure vessel with working gas at high pressure and then to fill the low-pressure vessel with the gas at low pressure. When more power is needed, the solenoid valves first supply the low-pressure gas from the low-pressure vessel to the engine and then supply the high-pressure gas from the high-pressure vessel. The solenoid valves each act as a check-valve when unactuated, and as an open valve when actuated.

  12. Design and Development of a Plastic Film Heat Exchanger

    E-Print Network [OSTI]

    Guyer, E. C.; Gollin, M. K.; Brownell, D. L.

    be liquid, gas, or a condensing vapor. The low thermal conductivity of the plastic is off set by the use of thin films so that overall heat transfer rates are achieved which are comparable 'to conventional units. Potential.uses for such? a unit are low... grade heat recovery, flu?e gas condensing, and liquid dessicant dehumidification systems. This paper discusses the range of plastic films available and compares their individual properties with those desirable in materials to be used in a PFHX...

  13. International Lige Colloquium on Ocean Dynamics, GAS TRANSFER AT WATER SURFACES, May 2 -6 2005 Estimation of air-sea gas and heat fluxes from infrared imagery and

    E-Print Network [OSTI]

    Jaehne, Bernd

    2005 Estimation of air-sea gas and heat fluxes from infrared imagery and surface wave measurements and much higher heat fluxes. In addition, the infrared imagery analysis reveals potentially significant the infrared images. It is also shown that the difference in the surface boundary conditions for heat and gas

  14. Grid-region heat transfer in a gas solid fluidized bed

    SciTech Connect (OSTI)

    Wang, R.C.

    1986-01-01T23:59:59.000Z

    The grid region heat transfer to a horizontal tube in a gas-solid fluidized bed was studied experimentally and theoretically. A preliminary experimental study was first conducted to investigate semi-quantitatively the heat transfer characteristics in the grid region as well as in the bubbling region of the gas-solid fluidized bed using a simple hot water circulation system. Experimental parameters included particle size, static bed height, superficial gas velocity, distributor open area, distributor hole sizes, distributor hole numbers, and vertical locations of the heating tube. An additional experimental study was then carried out to study quantitatively the heat transfer coefficient in each grid region phase, i.e., jet phase, emulsion phase and dead phase using an artificial jet and an electrically heated tube. The observed heat transfer coefficients for each phase were correlated as a function of experimental parameters. The observed results are also compared with results estimated from a heat transfer model, which is based on plausible heat transfer mechanisms in the grid region of a gas-solid fluidized bed.

  15. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect (OSTI)

    Duignan, M.R.; Greene, G.A. [Brookhaven National Lab., Upton, NY (United States); Irvine, T.F., Jr. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Mechanical Engineering

    1992-04-01T23:59:59.000Z

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus_minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured [0 to 8.5 cm/s], the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  16. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect (OSTI)

    Duignan, M.R.; Greene, G.A. (Brookhaven National Lab., Upton, NY (United States)); Irvine, T.F., Jr. (State Univ. of New York, Stony Brook, NY (United States). Dept. of Mechanical Engineering)

    1992-04-01T23:59:59.000Z

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured (0 to 8.5 cm/s), the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  17. Laclede Gas Company- Residential High Efficiency Heating Rebate Program

    Broader source: Energy.gov [DOE]

    Laclede Gas Company offers various rebates to residential customers for investing in energy efficient equipment and appliances. Residential customers can qualify for rebates on boilers, furnaces,...

  18. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    governments are considering a diverse energy mix that includes a growing proportion of renewable energy sources and natural gas. Proponents of this approach suggest that methane...

  19. Compact Ceramic Heat Exchangers for Corrosive Waste Gas Applications

    E-Print Network [OSTI]

    Laws, W. R.; Reed, G. R.

    1982-01-01T23:59:59.000Z

    developed for low temperature corrosive gas situations and have been applied to the pottery industry and are being developed for coal fired air heaters for the food industry....

  20. Elevated freestream turbulence effects on heat transfer for a gas turbine vane

    E-Print Network [OSTI]

    Thole, Karen A.

    turbine airfoil, particularly for the first stage nozzle guide vane. For this study, augmentations. To incorporate all of the variables affecting boundary layer development on gas turbine airfoils, studies needElevated freestream turbulence effects on heat transfer for a gas turbine vane K.A. Thole a,*, R

  1. Heat and Metal Transfer in Gas Metal Arc Welding Using Argon and Helium

    E-Print Network [OSTI]

    Eagar, Thomas W.

    Heat and Metal Transfer in Gas Metal Arc Welding Using Argon and Helium P.G. JONSSON, T.W. EAGAR transfer in gas metal arc welding (GMAW) of mild steel using argon and helium shielding gases. Major dif properties. Various findings from the study include that an arc cannot be stru~k in a pure helium atmosphere

  2. Conjugate Heat Transfer with Large Eddy Simulation for Gas Turbine Components.

    E-Print Network [OSTI]

    Nicoud, Franck

    Conjugate Heat Transfer with Large Eddy Simulation for Gas Turbine Components. Florent Duchaine constraint for GT (gas turbines). Most existing CHT tools are developped for chained, steady phenomena. A film-cooled turbine vane is then studied. Thermal conduction in the blade implies lower wall

  3. Development and Validation of a Gas-Fired Residential Heat Pump Water Heater - Final Report

    SciTech Connect (OSTI)

    Michael Garrabrant; Roger Stout; Paul Glanville; Janice Fitzgerald; Chris Keinath

    2013-01-21T23:59:59.000Z

    For gas-fired residential water heating, the U.S. and Canada is predominantly supplied by minimum efficiency storage water heaters with Energy Factors (EF) in the range of 0.59 to 0.62. Higher efficiency and higher cost ($700 - $2,000) options serve about 15% of the market, but still have EFs below 1.0, ranging from 0.65 to 0.95. To develop a new class of water heating products that exceeds the traditional limit of thermal efficiency, the project team designed and demonstrated a packaged water heater driven by a gas-fired ammonia-water absorption heat pump. This gas-fired heat pump water heater can achieve EFs of 1.3 or higher, at a consumer cost of $2,000 or less. Led by Stone Mountain Technologies Inc. (SMTI), with support from A.O. Smith, the Gas Technology Institute (GTI), and Georgia Tech, the cross-functional team completed research and development tasks including cycle modeling, breadboard evaluation of two cycles and two heat exchanger classes, heat pump/storage tank integration, compact solution pump development, combustion system specification, and evaluation of packaged prototype GHPWHs. The heat pump system extracts low grade heat from the ambient air and produces high grade heat suitable for heating water in a storage tank for domestic use. Product features that include conventional installation practices, standard footprint and reasonable economic payback, position the technology to gain significant market penetration, resulting in a large reduction of energy use and greenhouse gas emissions from domestic hot water production.

  4. THE INTEGRATION OF PROCESS HEAT APPLICATIONS TO HIGH TEMPERATURE GAS REACTORS

    SciTech Connect (OSTI)

    Michael G. McKellar

    2011-11-01T23:59:59.000Z

    A high temperature gas reactor, HTGR, can produce industrial process steam, high-temperature heat-transfer gases, and/or electricity. In conventional industrial processes, these products are generated by the combustion of fossil fuels such as coal and natural gas, resulting in significant emissions of greenhouse gases such as carbon dioxide. Heat or electricity produced in an HTGR could be used to supply process heat or electricity to conventional processes without generating any greenhouse gases. Process heat from a reactor needs to be transported by a gas to the industrial process. Two such gases were considered in this study: helium and steam. For this analysis, it was assumed that steam was delivered at 17 MPa and 540 C and helium was delivered at 7 MPa and at a variety of temperatures. The temperature of the gas returning from the industrial process and going to the HTGR must be within certain temperature ranges to maintain the correct reactor inlet temperature for a particular reactor outlet temperature. The returning gas may be below the reactor inlet temperature, ROT, but not above. The optimal return temperature produces the maximum process heat gas flow rate. For steam, the delivered pressure sets an optimal reactor outlet temperature based on the condensation temperature of the steam. ROTs greater than 769.7 C produce no additional advantage for the production of steam.

  5. International Journal of Machine Tools & Manufacture 40 (2000) 10231038 Nano-second laser pulse heating and assisting gas jet

    E-Print Network [OSTI]

    Budair, Mohammed Omar

    2000-01-01T23:59:59.000Z

    International Journal of Machine Tools & Manufacture 40 (2000) 1023­1038 Nano-second laser pulse-second laser pulse gas assisting processing method offers considerable advantages in the heat treatment process. In the present study gas assisted nano-second pulse laser heating of a stationary surface is considered. The gas

  6. Texas Gas Service- Residential Solar Water Heating Rebate Program (Texas)

    Broader source: Energy.gov [DOE]

    Texas Gas Service offers a flat rebate of $750 for its residential customers within the Austin and Sunset Valley city limits for the installation and purchase of a new solar water heater with...

  7. The origin of the hot metal-poor gas in NGC1291: Testing the hypothesis of gas dynamics as the cause of the gas heating

    E-Print Network [OSTI]

    I. Perez; K. Freeman

    2006-04-18T23:59:59.000Z

    In this paper we test the idea that the low-metallicity hot gas in the centre of NGC 1291 is heated via a dynamical process. In this scenario, the gas from the outer gas-rich ring loses energy through bar-driven shocks and falls to the centre. Heating of the gas to X-ray temperatures comes from the high velocity that it reaches ($\\approx$ 700 \\kms) as it falls to the bottom of the potential well. This would explain why the stellar metallicity in the bulge region is around solar while the hot gas metallicity is around 0.1 solar. We carried out an observational test to check this hypothesis by measuring the metallicity of HII regions in the outer ring to check whether they matched the hot gas metallicity. For this purpose we obtained medium resolution long slit spectroscopy with FORS1 on the ESO VLT at Paranal and obtained the metallicities using emission line ratio diagnostics. The obtained metallicities are compatible with the bulge stellar metallicities but very different from the hot-gas metallicity. However, when comparing the different time-scales, the gas in the ring had time enough to get enriched through stellar processes, therefore we cannot rule out the dynamical mechanism as the heating process of the gas. However, the blue colours of the outer ring and the dust structures in the bar region could suggest that the origin of the X-ray hot gas is due to the infall of material from further out.

  8. Fluid and heat flow in gas-rich geothermal reservoirs

    SciTech Connect (OSTI)

    O'Sullivan, M.J.; Bodvarsson, G.S.; Pruess, K.; Blakeley, M.R.

    1983-07-01T23:59:59.000Z

    Numerical-simulation techniques are used to study the effects of noncondensible gases (CO/sub 2/) on geothermal reservoir behavior in the natural state and during exploitation. It is shown that the presence of CO/sub 2/ has large effects on the thermodynamic conditions of a reservoir in the natural state, especially on temperature distributions and phase compositions. The gas will expand two-phase zones and increase gas saturations to enable flow of CO/sub 2/ through the system. During exploitation, the early pressure drop is primarily due to degassing of the system. This process can cause a very rapid initial pressure drop, on the order of tens of bars, depending upon the initial partial pressure of CO/sub 2/. The following gas content from wells can provide information on in-place gas saturations and relative permeability curves that apply at a given geothermal resource. Site-specific studies are made for the gas-rich two-phase reservoir at the Ohaki geothermal field in New Zealand. A simple lumped-parameter model and a vertical column model are applied to the field data. The results obtained agree well with the natural thermodynamic state of the Ohaki field (pressure and temperature profiles) and a partial pressure of 15 to 25 bars is calculated in the primary reservoirs. The models also agree reasonably well with field data obtained during exploitation of the field. The treatment of thermophysical properties of H/sub 2/O-CO/sub 2/ mixtures for different phase compositions is summarized.

  9. Low-pressure-ratio regenerative exhaust-heated gas turbine. Final report

    SciTech Connect (OSTI)

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01T23:59:59.000Z

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  10. Massively-Parallel Direct Numerical Simulation of Gas Turbine Endwall Film-Cooling Conjugate Heat Transfer

    E-Print Network [OSTI]

    Meador, Charles Michael

    2011-02-22T23:59:59.000Z

    MASSIVELY-PARALLEL DIRECT NUMERICAL SIMULATION OF GAS TURBINE ENDWALL FILM-COOLING CONJUGATE HEAT TRANSFER A Thesis by CHARLES MICHAEL MEADOR Submitted to the O ce of Graduate Studies of Texas A&M University in partial ful llment of the requirements... for the degree of MASTER OF SCIENCE December 2010 Major Subject: Mechanical Engineering MASSIVELY-PARALLEL DIRECT NUMERICAL SIMULATION OF GAS TURBINE ENDWALL FILM-COOLING CONJUGATE HEAT TRANSFER A Thesis by CHARLES MICHAEL MEADOR Submitted to the O ce of Graduate...

  11. Heat pipes and use of heat pipes in furnace exhaust

    DOE Patents [OSTI]

    Polcyn, Adam D. (Pittsburgh, PA)

    2010-12-28T23:59:59.000Z

    An array of a plurality of heat pipe are mounted in spaced relationship to one another with the hot end of the heat pipes in a heated environment, e.g. the exhaust flue of a furnace, and the cold end outside the furnace. Heat conversion equipment is connected to the cold end of the heat pipes.

  12. Modelling of the dynamics of a low-speed gas-liquid heat engine

    SciTech Connect (OSTI)

    Cunha, C.M.P.; Parise, J.A.R. (Pontificia Univ. Catolica do Rio de Janeiro (Brazil))

    1992-01-01T23:59:59.000Z

    This paper deals with the simulation model of a gas-liquid heat engine which is characterized by very low speeds (1-3 rpm) and relatively high torque. The engine operates according to the Minto Thermal Wheel' principle. It is based on the conversion of thermal energy from the heat source, through gas expansion, into mechanical work, by means of the fall of a mass of liquid. A prototype has already been constructed showing great ability to operate at very low temperature differences between the heat source and heat sink. This makes the engine quite suitable to the utilization of low temperature heat sources such as solar energy and waste heat. On the other hand, the number of moving parts is kept to a minimum, since the piston of traditional positive displacement engines (PDE) is now replaced simply by a mass of liquid. The mathematical model consists of applying the energy equation, in it time-derivative form, to representative engine control volumes, resulting in a set of linear ordinary differential equations. Their integration provides the time variation of pressure and temperature of the working fluid. The engine performance can thus be predicted as a function of engine operating conditions and geometric characteristics. In this paper, the engine dynamics (i.e., variable angular speed) have been taken into account, as well as heat losses in the engine structure. Results and further design considerations are discussed.

  13. Tips: Natural Gas and Oil Heating Systems | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you sure you want toworldPower 2010 1 TNews & SolarLaundry Tips:Natural Gas

  14. Heat Recovery Considerations for Process Heaters and Boilers

    E-Print Network [OSTI]

    Kumar, A.

    I/ton of product; and the estimated average potential energy HVings falla in 20-30% range. ;0, .666 ESL-IE-86-06-108 Proceedings from the Eighth Annual Industrial Energy Technology Conference, Houston, TX, June 17-19, 1986 'i. Improving mainrenallce. tll... fuels . The unit consists 0i metallic oi:!lt:ments that are alternately heated ..lI1d ..:oolt:'d, Elements are contained in a subdivided cylinder that rotates illside a casing. Hot flue gas flows through one side of this cylinder and heats...

  15. Field monitoring and evaluation of a residential gas-engine-driven heat pump: Volume 2, Heating season

    SciTech Connect (OSTI)

    Miller, J.D.

    1995-11-01T23:59:59.000Z

    The Federal Government is the largest single energy consumer in the United States; consumption approaches 1.5 quads/year of energy (1 quad = 10{sup 15} Btu) at a cost valued at nearly $10 billion annually. The US Department of Energy (DOE) Federal Energy Management Program (FEMP) supports efforts to reduce energy use and associated expenses in the Federal sector. One such effort, the New Technology Demonstration Program (NTDP), seeks to evaluate new energy-saving US technologies and secure their more timely adoption by the US Government. Pacific Northwest Laboratory (PNL) is one of four DOE national multiprogram laboratories that participate in the NTDP by providing technical expertise and equipment to evaluate new, energy-saving technologies being studied and evaluated under that program. This two-volume report describes a field evaluation that PNL conducted for DOE/FEMP and the US Department of Defense (DoD) Strategic Environmental Research and Development Program (SERDP) to examine the performance of a candidate energy-saving technology -- a gas-engine-driven heat pump. The unit was installed at a single residence at Fort Sam Houston, a US Army base in San Antonio, Texas, and the performance was monitored under the NTDP. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) were York International, the heat pump manufacturer; Gas Research Institute (GRI), the technology developer; City Public Service of San Antonio, the local utility; American Gas Cooling Center (AGCC); Fort Sam Houston; and PNL.

  16. Couette flow regimes with heat transfer in rarefied gas

    SciTech Connect (OSTI)

    Abramov, A. A., E-mail: alabr54@mail.ru; Butkovskii, A. V., E-mail: albutkov@mail.ru [Zhukovski Central Aerohydrodynamics Institute (Russian Federation)

    2013-06-15T23:59:59.000Z

    Based on numerical solution of the Boltzmann equation by direct statistic simulation, the Couette flow with heat transfer is studied in a broad range of ratios of plate temperatures and Mach numbers of a moving plate. Flow regime classification by the form of the dependences of the energy flux and friction stress on the Knudsen number Kn is proposed. These dependences can be simultaneously monotonic and nonmonotonic and have maxima. Situations are possible in which the dependence of the energy flux transferred to a plate on Kn has a minimum, while the dependence of the friction stress is monotonic or even has a maximum. Also, regimes exist in which the dependence of the energy flux on Kn has a maximum, while the dependence of the friction stress is monotonic, and vice versa.

  17. Crude Distillation Unit Heat Recovery Study

    E-Print Network [OSTI]

    John, P.

    1979-01-01T23:59:59.000Z

    to 426?F. There is no preheat of tower bottoms. All heat beyond the prefractionator comes from fired furnaces. But there is steam generation at 25 pounds pressure from hot oil and an approved project to generate ISO-pound steam from flue gas. Pipe Still... Sinks Sources Difference Disposition Sinks 110 (110) (213) Furnace Duty 400/690 430/720 255 152 (103) l50-Pound Steam Production 365/400 395/430 25 44 19 50-Pound Steam Production 300/365 330/395 47 80 33 29 25-Pound Steam...

  18. Low-Cost Gas Heat Pump For Building Space Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil & Gas »ofMarketing |Prepare for| DepartmentRyan Paul,Low-Cost Gas

  19. Multiple pollutant removal using the condensing heat exchanger: Phase 1 final report, October 1995--July 1997

    SciTech Connect (OSTI)

    Bailey, R.T.; Jankura, B.J.; Kudlac, G.A.

    1998-06-01T23:59:59.000Z

    The Integrated Flue Gas Treatment (IFGT) system is a new concept whereby a Teflon{reg_sign} covered condensing heat exchanger is adapted to remove certain flue gas constitutents, both particulate and gaseous, while recovering low level heat. Phase 1 includes two experimental tasks. One task dealt principally with the pollutant removal capabilities of the IFGT at a scale of about 1.2MW{sub t}. The other task studied the durability of the Teflon{reg_sign} covering to withstand the rigors of abrasive wear by fly ash emitted as a result of coal combustion. The pollutant removal characteristics of the IFGT system were measured over a wide range of operating conditions. The coals tested included high, medium and low-sulfur coals. The flue gas pollutants studied included ammonia, hydrogen chloride, hydrogen fluoride, particulate, sulfur dioxide, gas phase and particle phase mercury and gas phase and particle phase trace elements. The particulate removal efficiency and size distribution was investigated. These test results demonstrated that the IFGT system is an effective device for both acid gas absorption and fine particulate collection. The durability of the Teflon{reg_sign} covered heat exchanger tubes was studied on a pilot-scale single-stage condensing heat exchanger (CHX{reg_sign}). Data from the test indicate that virtually no decrease in Teflon{reg_sign} thickness was observed for the coating on the first two rows of heat exchanger tubes, even at high inlet particulate loadings. Evidence of wear was present only at the microscopic level, and even then was very minor in severity.

  20. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott [ORNL; Theiss, Timothy J [ORNL; Bunce, Michael [ORNL

    2012-01-01T23:59:59.000Z

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  1. Final report to US Department of Energy: Cyclotron autoresonance accelerator for electron beam dry scrubbing of flue gases

    SciTech Connect (OSTI)

    Hirshfield, J.L.

    2001-05-25T23:59:59.000Z

    Several designs have been built and operated of microwave cyclotron autoresonance accelerators (CARA's) with electron beam parameters suitable for remediation of pollutants in flue gas emissions from coal-burning power plants. CARA designs have also been developed with a TW-level 10.6 micron laser driver for electron acceleration from 50 to 100 MeV, and with UHF drivers for proton acceleration to over 500 MeV. Dose requirements for reducing SO2, NOx, and particulates in flue gas emissions to acceptable levels have been surveyed, and used to optimize the design of an electron beam source to deliver this dose.

  2. Application of advanced Stirling engine technology to a commercial size gas-fired heat pump

    SciTech Connect (OSTI)

    Johansson, L.; Agno, J.; Wurm, J.

    1985-08-01T23:59:59.000Z

    The Gas Research Institute sponsored work on the kinematic Stirling engine-driven heat pump, which offers practical improvements in the use of natural gas. Results from the first phase of the program led to the selection of a method of introducing low pressure natural gas into the V160 engine's combustor and testing of the ejector system. Further engine modifications will be needed as well as demonstrations of the performance and reliability of the units. The first phase found all developmental needs to be achievable, making the concept technically feasible. Computer projections based on the system performance of components indicate the gas-fired pump will work better than electric models and be economically feasible as well. 5 figures, 1 table.

  3. A convective-radiative heat transfer model for gas core reactors

    SciTech Connect (OSTI)

    Chen, G.; Anghaie, S. [Univ. of Florida, Gainesville, FL (United States)

    1995-12-31T23:59:59.000Z

    A convective-radiative heat transfer model is developed and used to predict the temperature distribution in gaseous fuel nuclear reactor cores. The axisymmetric, thin layer Navier-Stokes equations with diffusive radiation source term are the basis for this modeling approach. An algebraic turbulence model is used to calculate the eddy viscosity. The Rosseland diffusion approximation is used to model the radiative heat transfer. A hybrid implicit-explicit numerical scheme with Gauss-Seidel iterative process and a highly stretched grid system near wall is employed to solve the governing equations. Several cases with different internal heat generation rates are modeled and analyzed. Results of the temperature distribution, wall heat flux and the associated Nusselt number are presented. The influence of the internal heat generation rate and the wall temperature on the radiative and convective wall heat fluxes are discussed. At gas and wall temperatures close to 3,500 K and 1,600 K, respectively, the radiative and convective heat transfer rates have similar values.

  4. Adding Environmental Gas Physics to the Semi-Analytic Method for Galaxy Formation: Gravitational Heating

    E-Print Network [OSTI]

    S. Khochfar; J. P. Ostriker

    2008-02-12T23:59:59.000Z

    We present results of an attempt to include more detailed gas physics motivated from hydrodynamical simulations within semi-analytic models (SAM) of galaxy formation, focusing on the role that environmental effects play. The main difference to previous SAMs is that we include 'gravitational' heating of the intra-cluster medium (ICM) by the net surplus of gravitational potential energy released from gas that has been stripped from infalling satellites. Gravitational heating appears to be an efficient heating source able to prevent cooling in environments corresponding to dark matter halos more massive than $\\sim 10^{13} $M$_{\\odot}$. The energy release by gravitational heating can match that by AGN-feedback in massive galaxies and can exceed it in the most massive ones. However, there is a fundamental difference in the way the two processes operate. Gravitational heating becomes important at late times, when the peak activity of AGNs is already over, and it is very mass dependent. This mass dependency and time behaviour gives the right trend to recover down-sizing in the star-formation rate of massive galaxies. Abridged...

  5. Condensing Heating and Water Heating Equipment Workshop Location: Washington Gas Light Appliance Training Facility

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T, Inc.'sEnergyTexas1.Space DataEnergyCompressedOil, and Gas Sectors

  6. CORQUENCH: A model for gas sparging-enhanced melt-water, film boiling heat transfer

    SciTech Connect (OSTI)

    Farmer, M.T.; Sienicki, J.J.; Spencer, B.W.

    1990-01-01T23:59:59.000Z

    A phenomenological model (CORQUENCH) has been developed to describe the gas-sparging enhanced film boiling heat transfer between a molten pool of corium and an overlying water layer. The model accounts for thermal radiation across the vapor film, bulk liquid subcooling, interfacial area enhancement due to sparging gas, and melt entrainment into the overlying water layer. In this paper, the modeling approach is described, and a comparison with the lead-Freon 11 and lead-water film boiling experiment data of Greene is made. Predictions are then made for the case of film boiling over corium in the presence of sparging concrete decomposition gases. 15 refs., 3 figs.

  7. AN EXPERIMENTAL INVESTIGATION OF THE HEAT TRANSFER FROM A BUOYANT GAS PLUME TO A

    E-Print Network [OSTI]

    Winfree, Erik

    Temperature E. Heat Transfer Model 1. Determining the Ceiling Heat Transfer 2. Ceiling Heat Transfer

  8. Decay Heat Removal in GEN IV Gas-Cooled Fast Reactors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Lap-Yan; Wei, Thomas Y. C.

    2009-01-01T23:59:59.000Z

    The safety goal of the current designs of advanced high-temperature thermal gas-cooled reactors (HTRs) is that no core meltdown would occur in a depressurization event with a combination of concurrent safety system failures. This study focused on the analysis of passive decay heat removal (DHR) in a GEN IV direct-cycle gas-cooled fast reactor (GFR) which is based on the technology developments of the HTRs. Given the different criteria and design characteristics of the GFR, an approach different from that taken for the HTRs for passive DHR would have to be explored. Different design options based on maintaining core flow weremore »evaluated by performing transient analysis of a depressurization accident using the system code RELAP5-3D. The study also reviewed the conceptual design of autonomous systems for shutdown decay heat removal and recommends that future work in this area should be focused on the potential for Brayton cycle DHRs.« less

  9. Solar heating, cooling and domestic hot water system installed at Columbia Gas System Service Corp. , Columbus, Ohio. Final report

    SciTech Connect (OSTI)

    None

    1980-11-01T23:59:59.000Z

    The Solar Energy System located at the Columbia Gas Corporation, Columbus, Ohio, has 2978 ft/sup 2/ of Honeywell single axis tracking, concentrating collectors and provides solar energy for space heating, space cooling and domestic hot water. A 1,200,000 Btu/h Bryan water-tube gas boiler provides hot water for space heating. Space cooling is provided by a 100 ton Arkla hot water fired absorption chiller. Domestic hot water heating is provided by a 50 gallon natural gas domestic storage water heater. Extracts are included from the site files, specification references, drawings, installation, operation and maintenance instructions.

  10. Comparison of thermoelectric and permeation dryers for sulfur dioxide removal during sample conditioning of wet gas streams

    SciTech Connect (OSTI)

    Dunder, T.A. [Entropy, Inc., Research Triangle Park, NC (United States). Research Div.; Leighty, D.A. [Perma Pure, Inc., Toms River, NJ (United States)

    1997-12-31T23:59:59.000Z

    Flue gas conditioning for moisture removal is commonly performed for criteria pollutant measurements, in particular for extractive CEM systems at combustion sources. An implicit assumption is that conditioning systems specifically remove moisture without affecting pollutant and diluent concentrations. Gas conditioning is usually performed by passing the flue gas through a cold trap (Peltier or thermoelectric dryer) to remove moisture by condensation, which is subsequently extracted by a peristaltic pump. Many air pollutants are water-soluble and potentially susceptible to removal in a condensation dryer from gas interaction with liquid water. An alternative technology for gas conditioning is the permeation dryer, where the flue gas passes through a selectively permeable membrane for moisture removal. In this case water is transferred through the membrane while other pollutants are excluded, and the gas does not contact condensed liquid. Laboratory experiments were performed to measure the relative removal of a water-soluble pollutant (sulfur dioxide, SO{sub 2}) by the two conditioning techniques. A wet gas generating system was used to create hot, wet gas streams of known composition (15% and 30% moisture, balance nitrogen) and flow rate. Pre-heated SO{sub 2} was dynamically spiked into the wet stream using mass flow meters to achieve concentrations of 20, 50, and 100 ppm. The spiked gas was directed through a heated sample line to either a thermoelectric or a permeation conditioning system. Two gas analyzers (Western Research UV gas monitor, KVB/Analect FTIR spectrometer) were used to measure the SO{sub 2} concentration after conditioning. Both analytic methods demonstrated that SO{sub 2} is removed to a significantly greater extent by the thermoelectric dryer. These results have important implications for SO{sub 2} monitoring and emissions trading.

  11. Heat-pipe gas-combustion system endurance test for Stirling engine. Final report, May 1990-September 1990

    SciTech Connect (OSTI)

    Mahrle, P.

    1990-12-01T23:59:59.000Z

    Stirling Thermal Motors, Inc., (STM) has been developing a general purpose Heat Pipe Gas Combustion System (HPGC) suitable for use with the STM4-120 Stirling engine. The HPGC consists of a parallel plate recuperative preheater, a finned heat pipe evaporator and a film cooled gas combustor. A principal component of the HPGC is the heat pipe evaporator which collects and distributes the liquid sodium over the heat transfer surfaces. The liquid sodium evaporates and flows to the condensers where it delivers its latent heat. The report presents test results of endurance tests run on a Gas-Fired Stirling Engine (GFSE). Tests on a dynamometer test stand yielded 67 hours of engine operation at power levels over 10 kW (13.5 hp) with 26 hours at power levels above 15 kW (20 hp). Total testing of the engine, including both motoring tests and engine operation, yielded 245 hours of engine run time.

  12. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, Chang Y. (3807 Reynolds St., Laramie, WY 82070)

    1993-01-01T23:59:59.000Z

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.

  13. The Gas-Cooled Fast Reactor: Report on Safety System Design for Decay Heat Removal

    SciTech Connect (OSTI)

    K. D. Weaver; T. Marshall; T. Y. C. Wei; E. E. Feldman; M. J. Driscoll; H. Ludewig

    2003-09-01T23:59:59.000Z

    The gas-cooled fast reactor (GFR) was chosen as one of the Generation IV nuclear reactor systems to be developed based on its excellent potential for sustainability through reduction of the volume and radiotoxicity of both its own fuel and other spent nuclear fuel, and for extending/utilizing uranium resources orders of magnitude beyond what the current open fuel cycle can realize. In addition, energy conversion at high thermal efficiency is possible with the current designs being considered, thus increasing the economic benefit of the GFR. However, research and development challenges include the ability to use passive decay heat removal systems during accident conditions, survivability of fuels and in-core materials under extreme temperatures and radiation, and economical and efficient fuel cycle processes. This report addresses/discusses the decay heat removal options available to the GFR, and the current solutions. While it is possible to design a GFR with complete passive safety (i.e., reliance solely on conductive and radiative heat transfer for decay heat removal), it has been shown that the low power density results in unacceptable fuel cycle costs for the GFR. However, increasing power density results in higher decay heat rates, and the attendant temperature increase in the fuel and core. Use of active movers, or blowers/fans, is possible during accident conditions, which only requires 3% of nominal flow to remove the decay heat. Unfortunately, this requires reliance on active systems. In order to incorporate passive systems, innovative designs have been studied, and a mix of passive and active systems appears to meet the requirements for decay heat removal during accident conditions.

  14. HEAT TRANSFER DURING THE SHOCK-INDUCED IGNITION OF AN EXPOLSIVE GAS

    E-Print Network [OSTI]

    Heperkan, H.

    2013-01-01T23:59:59.000Z

    Proceedings of the 1963 Heat Transfer and Fluid Mechanicsto the Journal of Heat Transfer HEAT TRANSFER DURING THETechniques for Heat Transfer and Force Measurements in a

  15. Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.

    SciTech Connect (OSTI)

    Parkinson, W. J. (William Jerry),

    2003-01-01T23:59:59.000Z

    In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

  16. Preliminary Estimates of Combined Heat and Power Greenhouse GasAbatement Potential for California in 2020

    SciTech Connect (OSTI)

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare,Kristina

    2007-07-31T23:59:59.000Z

    The objective of this scoping project is to help the California Energy Commission's (CEC) Public Interest Energy Research (PIER) Program determine where it should make investments in research to support combined heat and power (CHP) deployment. Specifically, this project will: {sm_bullet} Determine what impact CHP might have in reducing greenhouse gas (GHG) emissions, {sm_bullet} Determine which CHP strategies might encourage the most attractive early adoption, {sm_bullet} Identify the regulatory and technological barriers to the most attractive CHP strategies, and {sm_bullet} Make recommendations to the PIER program as to research that is needed to support the most attractive CHP strategies.

  17. Heating the bubbly gas of galaxy clusters with weak shocks and sound waves

    E-Print Network [OSTI]

    S. Heinz; E. Churazov

    2005-09-26T23:59:59.000Z

    Using hydrodynamic simulations and a technique to extract the rotational component of the velocity field, we show how bubbles of relativistic gas inflated by AGN jets in galaxy clusters act as a catalyst, transforming the energy carried by sound and shock waves to heat. The energy is stored in a vortex field around the bubbles which can subsequently be dissipated. The efficiency of this process is set mainly by the fraction of the cluster volume filled by (sub-)kpc scale filaments and bubbles of relativistic plasma.

  18. KEY DESIGN REQUIREMENTS FOR THE HIGH TEMPERATURE GAS-COOLED REACTOR NUCLEAR HEAT SUPPLY SYSTEM

    SciTech Connect (OSTI)

    L.E. Demick

    2010-09-01T23:59:59.000Z

    Key requirements that affect the design of the high temperature gas-cooled reactor nuclear heat supply system (HTGR-NHSS) as the NGNP Project progresses through the design, licensing, construction and testing of the first of a kind HTGR based plant are summarized. These requirements derive from pre-conceptual design development completed to-date by HTGR Suppliers, collaboration with potential end users of the HTGR technology to identify energy needs, evaluation of integration of the HTGR technology with industrial processes and recommendations of the NGNP Project Senior Advisory Group.

  19. Heating and cooling of a two-dimensional electron gas by terahertz radiation

    SciTech Connect (OSTI)

    Budkin, G. V.; Tarasenko, S. A., E-mail: tarasenko@coherent.ioffe.ru [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)

    2011-04-15T23:59:59.000Z

    The absorption of terahertz radiation by free charge carriers in n-type semiconductor quantum wells accompanied by the interaction of electrons with acoustic and optical phonons is studied. It is shown that intrasubband optical transitions can cause both heating and cooling of the electron gas. The cooling of charge carriers occurs in a certain temperature and radiation frequency region where light is most efficiently absorbed due to intrasubband transitions with emission of optical phonons. In GaAs quantum wells, the optical cooling of electrons occurs most efficiently at liquid nitrogen temperatures, while cooling is possible even at room temperature in GaN heterostructures.

  20. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    MW Reciprocating Engine 3 MW Gas Turbine 1 MW ReciprocatingEngine 5 MW Gas Turbine 3MW Gas Turbine 40 MW Gas Turbine 1 MW Reciprocating Engine

  1. Method and apparatus for enhanced heat recovery from steam generators and water heaters

    DOE Patents [OSTI]

    Knight, Richard A.; Rabovitser, Iosif K.; Wang, Dexin

    2006-06-27T23:59:59.000Z

    A heating system having a steam generator or water heater, at least one economizer, at least one condenser and at least one oxidant heater arranged in a manner so as to reduce the temperature and humidity of the exhaust gas (flue gas) stream and recover a major portion of the associated sensible and latent heat. The recovered heat is returned to the steam generator or water heater so as to increase the quantity of steam generated or water heated per quantity of fuel consumed. In addition, a portion of the water vapor produced by combustion of fuel is reclaimed for use as feed water, thereby reducing the make-up water requirement for the system.

  2. Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

    E-Print Network [OSTI]

    1994-01-01T23:59:59.000Z

    Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

  3. Corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, Scott L. (Annandale, VA)

    1989-01-01T23:59:59.000Z

    A corrosive and errosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is conveyed through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium.

  4. Ionization heating in rare-gas clusters under intense XUV laser pulses

    SciTech Connect (OSTI)

    Arbeiter, Mathias; Fennel, Thomas [Institute of Physics, University of Rostock, D-18051 Rostock (Germany)

    2010-07-15T23:59:59.000Z

    The interaction of intense extreme ultraviolet (XUV) laser pulses ({lambda}=32 nm, I=10{sup 11}-10{sup 14} W/cm{sup 2}) with small rare-gas clusters (Ar{sub 147}) is studied by quasiclassical molecular dynamics simulations. Our analysis supports a very general picture of the charging and heating dynamics in finite samples under short-wavelength radiation that is of relevance for several applications of free-electron lasers. First, up to a certain photon flux, ionization proceeds as a series of direct photoemission events producing a jellium-like cluster potential and a characteristic plateau in the photoelectron spectrum as observed in Bostedt et al. [Phys. Rev. Lett. 100, 133401 (2008)]. Second, beyond the onset of photoelectron trapping, nanoplasma formation leads to evaporative electron emission with a characteristic thermal tail in the electron spectrum. A detailed analysis of this transition is presented. Third, in contrast to the behavior in the infrared or low vacuum ultraviolet range, the nanoplasma energy capture proceeds via ionization heating, i.e., inner photoionization of localized electrons, whereas collisional heating of conduction electrons is negligible up to high laser intensities. A direct consequence of the latter is a surprising evolution of the mean energy of emitted electrons as function of laser intensity.

  5. A Gas-Cooled-Reactor Closed-Brayton-Cycle Demonstration with Nuclear Heating

    SciTech Connect (OSTI)

    Lipinski, Ronald J.; Wright, Steven A.; Dorsey, Daniel J.; Williamson, Joshua [Advanced Nuclear Concepts Department, Sandia National Laboratories, P.O Box 5800, Albuquerque, NM 87185 (United States); Peters, Curtis D.; Brown, Nicholas [Advanced Nuclear Concepts Department, Sandia National Laboratories, P.O Box 5800, Albuquerque, NM 87185 (United States); Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, NM 87108 (United States); Jablonski, Jennifer [Advanced Nuclear Concepts Department, Sandia National Laboratories, P.O Box 5800, Albuquerque, NM 87185 (United States); Department of Education, University of New Mexico, Albuquerque, NM 87108 (United States)

    2005-02-06T23:59:59.000Z

    A gas-cooled reactor may be coupled directly to turbomachinery to form a closed-Brayton-cycle (CBC) system in which the CBC working fluid serves as the reactor coolant. Such a system has the potential to be a very simple and robust space-reactor power system. Gas-cooled reactors have been built and operated in the past, but very few have been coupled directly to the turbomachinery in this fashion. In this paper we describe the option for testing such a system with a small reactor and turbomachinery at Sandia National Laboratories. Sandia currently operates the Annular Core Research Reactor (ACRR) at steady-state powers up to 4 MW and has an adjacent facility with heavy shielding in which another reactor recently operated. Sandia also has a closed-Brayton-Cycle test bed with a converted commercial turbomachinery unit that is rated for up to 30 kWe of power. It is proposed to construct a small experimental gas-cooled reactor core and attach this via ducting to the CBC turbomachinery for cooling and electricity production. Calculations suggest that such a unit could produce about 20 kWe, which would be a good power level for initial surface power units on the Moon or Mars. The intent of this experiment is to demonstrate the stable start-up and operation of such a system. Of particular interest is the effect of a negative temperature power coefficient as the initially cold Brayton gas passes through the core during startup or power changes. Sandia's dynamic model for such a system would be compared with the performance data. This paper describes the neutronics, heat transfer, and cycle dynamics of this proposed system. Safety and radiation issues are presented. The views expressed in this document are those of the author and do not necessarily reflect agreement by the government.

  6. A gas-cooled-reactor closed-Brayton-cycle demonstration with nuclear heating.

    SciTech Connect (OSTI)

    Jablonski, Jennifer A.; Williamson, Joshua J.; Wright, Steven Alan; Dorsey, Daniel John; Brown, Nicholas; Peters, Curtis D.; Lipinski, Ronald J.

    2004-09-01T23:59:59.000Z

    A gas-cooled reactor may be coupled directly to turbomachinery to form a closed-Brayton-cycle (CBC) system in which the CBC working fluid serves as the reactor coolant. Such a system has the potential to be a very simple and robust space-reactor power system. Gas-cooled reactors have been built and operated in the past, but very few have been coupled directly to the turbomachinery in this fashion. In this paper we describe the option for testing such a system with a small reactor and turbomachinery at Sandia National Laboratories. Sandia currently operates the Annular Core Research Reactor (ACRR) at steady-state powers up to 4 MW and has an adjacent facility with heavy shielding in which another reactor recently operated. Sandia also has a closed-Brayton-Cycle test bed with a converted commercial turbomachinery unit that is rated for up to 30 kWe of power. It is proposed to construct a small experimental gas-cooled reactor core and attach this via ducting to the CBC turbomachinery for cooling and electricity production. Calculations suggest that such a unit could produce about 20 kWe, which would be a good power level for initial surface power units on the Moon or Mars. The intent of this experiment is to demonstrate the stable start-up and operation of such a system. Of particular interest is the effect of a negative temperature power coefficient as the initially cold Brayton gas passes through the core during startup or power changes. Sandia's dynamic model for such a system would be compared with the performance data. This paper describes the neutronics, heat transfer, and cycle dynamics of this proposed system. Safety and radiation issues are presented. The views expressed in this document are those of the author and do not necessarily reflect agreement by the government.

  7. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01T23:59:59.000Z

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  8. Modified heat transfer coefficient in the presence of noncondensible gas for RELAP5/MOD2 computer code 

    E-Print Network [OSTI]

    Grant, Sharon Elizabeth

    1990-01-01T23:59:59.000Z

    for other noncondensible gases (such as argon, helium, hydrogen, etc. . . ) which the user can specify in the RELAP5/MOD2 computer code. 38 REFERENCES 1. M. T. Leonard, The effects of a noncodensable gas on pressurizer insurge transients, MS Thesis...MODIFIED HEAT TRANSFER COEFFICIENT IN THE PRESENCE OF NONCONDENSIBLE GAS FOR RELAP5/MOD2 COMPUTER CODE A Thesis by SHARON ELIZABETH GRANT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  9. Evaluation of Gas, Oil and Wood Pellet Fueled Residential Heating System Emissions Characteristics

    SciTech Connect (OSTI)

    McDonald, R.

    2009-12-01T23:59:59.000Z

    This study has measured the emissions from a wide range of heating equipment burning different fuels including several liquid fuel options, utility supplied natural gas and wood pellet resources. The major effort was placed on generating a database for the mass emission rate of fine particulates (PM 2.5) for the various fuel types studied. The fine particulates or PM 2.5 (less than 2.5 microns in size) were measured using a dilution tunnel technique following the method described in US EPA CTM-039. The PM 2.5 emission results are expressed in several units for the benefit of scientists, engineers and administrators. The measurements of gaseous emissions of O{sub 2}, CO{sub 2}, CO, NO{sub x} and SO{sub 2} were made using a combustion analyzer based on electrochemical cells These measurements are presented for each of the residential heating systems tested. This analyzer also provides a steady state efficiency based on stack gas and temperature measurements and these values are included in the report. The gaseous results are within the ranges expected from prior emission studies with the enhancement of expanding these measurements to fuels not available to earlier researchers. Based on measured excess air levels and ultimate analysis of the fuel's chemical composition the gaseous emission results are as expected and fall within the range provided for emission factors contained in the US-EPA AP 42, Emission Factors Volume I, Fifth Edition. Since there were no unexpected findings in these gaseous measurements, the bulk of the report is centered on the emissions of fine particulates, or PM 2.5. The fine particulate (PM 2.5) results for the liquid fuel fired heating systems indicate a very strong linear relationship between the fine particulate emissions and the sulfur content of the liquid fuels being studied. This is illustrated by the plot contained in the first figure on the next page which clearly illustrates the linear relationship between the measured mass of fine particulate per unit of energy, expressed as milligrams per Mega-Joule (mg/MJ) versus the different sulfur contents of four different heating fuels. These were tested in a conventional cast iron boiler equipped with a flame retention head burner. The fuels included a typical ASTM No. 2 fuel oil with sulfur below 0.5 percent (1520 average ppm S), an ASTM No. 2 fuel oil with very high sulfur content (5780 ppm S), low sulfur heating oil (322 ppm S) and an ultra low sulfur diesel fuel (11 ppm S). Three additional oil-fired heating system types were also tested with normal heating fuel, low sulfur and ultralow sulfur fuel. They included an oil-fired warm air furnace of conventional design, a high efficiency condensing warm air furnace, a condensing hydronic boiler and the conventional hydronic boiler as discussed above. The linearity in the results was observed with all of the different oil-fired equipment types (as shown in the second figure on the next page). A linear regression of the data resulted in an Rsquared value of 0.99 indicating that a very good linear relationship exits. This means that as sulfur decreases the PM 2.5 emissions are reduced in a linear manner within the sulfur content range tested. At the ultra low sulfur level (15 ppm S) the amount of PM 2.5 had been reduced dramatically to an average of 0.043 mg/MJ. Three different gas-fired heating systems were tested. These included a conventional in-shot induced draft warm air furnace, an atmospheric fired hydronic boiler and a high efficiency hydronic boiler. The particulate (PM 2.5) measured ranged from 0.011 to 0.036 mg/MJ. depending on the raw material source used in their manufacture. All three stoves tested were fueled with premium (low ash) wood pellets obtained in a single batch to provide for uniformity in the test fuel. Unlike the oil and gas fired systems, the wood pellet stoves had measurable amounts of particulates sized above the 2.5-micron size that defines fine particulates (less than 2.5 microns). The fine particulate emissions rates ranged from 22 to 30 mg/ MJ with an average value

  10. Brayton-cycle heat recovery-system characterization program. Subatmospheric-system test report

    SciTech Connect (OSTI)

    Burgmeier, L.; Leung, S.

    1981-07-31T23:59:59.000Z

    The turbine tests and results for the Brayton cycle subatmospheric system (SAS) are summarized. A scaled model turbine was operated in the same environment as that which a full-scale SAS machine would experience from the hot effluent flue gas from a glass container furnace. The objective of the testing was to evaluate the effects of a simulated furnace flue gas stream on the turbine nozzles and blades. The following specific areas were evaluated: erosion of the turbine nozzles and blades from the dust in the flue gas, hot corrosion from alkali metal salts in the dust and acid vapor (sulfur trioxide and hydrogen chloride) in the flue gas, and fouling and flow blockage due to deposition and/or condensation from the flue gas constituents.

  11. Rheology and Convective Heat Transfer of Colloidal Gas Aphrons in Horizontal Minichannels

    E-Print Network [OSTI]

    Tseng, H.; Pilon, L.; Warrier, G.

    2006-01-01T23:59:59.000Z

    volumetric flow rates and heat input of 2.68×10 -6 m 3 /s attime for different heat input but identical pump setting.per channel, m 3 /s total heat input in the five channels, W

  12. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    that during this forecast period, natural gas will be the7. 2020 forecasts of California electricity and natural gasEnergy Prices Forecasts of 2020 natural gas prices are taken

  13. Bubble columns for condensation at high concentrations of noncondensable gas: Heat-transfer model and experiments

    E-Print Network [OSTI]

    Narayan, G. Prakash

    Carrier gas based thermodynamic cycles are common in water desalination applications. These cycles often require condensation of water vapor out of the carrier gas stream. As the carrier gas is most likely a noncondensable ...

  14. Field comparison of conventional HVAC systems with a residential gas-engine-driven heat pump

    SciTech Connect (OSTI)

    Miller, J.D.

    1994-08-01T23:59:59.000Z

    Through its Office of Federal Energy Management Program (FEMP), the US Department of Energy (DOE) provides technical and administrative support to federal agency programs directed at reducing energy consumption and cost in federal buildings and facilities. One such program is the New Technology Demonstration Program (NTDP). In this context, NTDP is a demonstration of a US energy-related technology at a federal site. Through a partnership with a federal site, the utility serving the site, a manufacturer of an energy-related technology, and other organizations associated with these interests, DOE can evaluate new technologies. The partnership of these interests is secured through a Cooperative Research and Development Agreement (CRADA). The Fort Sam Houston (San Antonio, Texas) NTDP is a field evaluation of a 3-ton gas-engine-driven residential heat pump. Details of the technical approach used in the evaluation, including instrumentation and methodology, are presented. Dynamic performance maps, based on field data, are developed for the existing residential furnaces and air conditioners at Fort Sam Houston. These maps are the basis for comparisons between the candidate and current equipment. The approach offers advantages over pre/post-measure evaluations by decoupling the measured equipment performance from the effects of different envelope characteristics, occupant behavior, and weather.

  15. Comparative Performance Analysis of IADR Operating in Natural Gas-Fired and Waste-Heat CHP Modes

    SciTech Connect (OSTI)

    Petrov, Andrei Y [ORNL; Sand, James R [ORNL; Zaltash, Abdolreza [ORNL

    2006-01-01T23:59:59.000Z

    Fuel utilization can be dramatically improved through effective recycle of 'waste' heat produced as a by-product of on-site or near-site power generation technologies. Development of modular compact cooling, heating, and power (CHP) systems for end-use applications in commercial and institutional buildings is a key part of the Department of Energy's (DOE) energy policy. To effectively use the thermal energy from a wide variety of sources which is normally discarded to the ambient, many components such as heat exchangers, boilers, absorption chillers, and desiccant dehumidification systems must be further developed. Recently a compact, cost-effective, and energy-efficient integrated active-desiccant vapor-compression hybrid rooftop (IADR) unit has been introduced in the market. It combines the advantages of an advanced direct-expansion cooling system with the dehumidification capability of an active desiccant wheel. The aim of this study is to compare the efficiency of the IADR operation in baseline mode, when desiccant wheel regeneration is driven by a natural gas burner, and in CHP mode, when the waste heat recovered from microturbine exhaust gas is used for desiccant regeneration. Comparative analysis shows an excellent potential for more efficient use of the desiccant dehumidification as part of a CHP system and the importance of proper sizing of the CHP components. The most crucial factor in exploiting the efficiency of this application is the maximum use of thermal energy recovered for heating of regeneration air.

  16. Duplex Stirling gas-fired heat pump. Phase 2. Breadboard demonstration. Final report, May 1981-November 1982

    SciTech Connect (OSTI)

    Gedeon, D.; Penswick, B.; Beale, W.

    1982-11-01T23:59:59.000Z

    This program represents the first attempt to design, fabricate, and test a breadboard gas-fired duplex Stirling heat pump in a heating only mode. The system was designed to obtain a COP of 1.5 at an ambient temperature of 17F and have an output sufficient for an average residential home. The design methodology, detailed system description and test results for sub components and the entire system are discussed. Technical problems encountered in the program, and recommendations for further efforts are detailed.

  17. Negative heat capacity in the critical region of nuclear fragmentation: an experimental evidence of the liquid-gas phase transition

    E-Print Network [OSTI]

    M. D'Agostino; F. Gulminelli; Ph. Chomaz; M. Bruno; F. Cannata; R. Bougault; N. Colonna; F. Gramegna; I. Iori; N. Le Neindre; G. V. Margagliotti; P. F. Mastinu; P. M. Milazzo; A. Moroni; G. Vannini

    1999-06-07T23:59:59.000Z

    An experimental indication of negative heat capacity in excited nuclear systems is inferred from the event by event study of energy fluctuations in $Au$ quasi-projectile sources formed in $Au+Au$ collisions at 35 A.MeV. The excited source configuration is reconstructed through a calorimetric analysis of its de-excitation products. Fragment partitions show signs of a critical behavior at about 5 A.MeV excitation energy. In the same energy range the heat capacity shows a negative branch providing a direct evidence of a first order liquid gas phase transition.

  18. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    generation: 50% of electricity from central grid natural gas plantsgeneration: 100% of electricity from central grid natural gas plantselectricity comes from central station natural-gas- fired combined cycle generation, and the other half comes from natural-gas-fired single cycle plants. •

  19. Quantity, quality, and availability of waste heat from United States thermal power generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gingerich, Daniel B; Mauter, Meagan S

    2015-06-10T23:59:59.000Z

    Secondary application of unconverted heat produced during electric power generation has the potential to improve the life-cycle fuel efficiency of the electric power industry and the sectors it serves. This work quantifies the residual heat (also known as waste heat) generated by U.S. thermal power plants and assesses the intermittency and transport issues that must be considered when planning to utilize this heat. Combining Energy Information Administration plant-level data with literature-reported process efficiency data, we develop estimates of the unconverted heat flux from individual U.S. thermal power plants in 2012. Together these power plants discharged an estimated 18.9 billion GJthmore »of residual heat in 2012, 4% of which was discharged at temperatures greater than 90 °C. We also characterize the temperature, spatial distribution, and temporal availability of this residual heat at the plant level and model the implications for the technical and economic feasibility of its end use. Increased implementation of flue gas desulfurization technologies at coal-fired facilities and the higher quality heat generated in the exhaust of natural gas fuel cycles are expected to increase the availability of residual heat generated by 10.6% in 2040.« less

  20. Quantity, quality, and availability of waste heat from United States thermal power generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gingerich, Daniel B [Carnegie Mellon Univ., Pittsburgh, PA (United States); Mauter, Meagan S [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2015-06-10T23:59:59.000Z

    Secondary application of unconverted heat produced during electric power generation has the potential to improve the life-cycle fuel efficiency of the electric power industry and the sectors it serves. This work quantifies the residual heat (also known as waste heat) generated by U.S. thermal power plants and assesses the intermittency and transport issues that must be considered when planning to utilize this heat. Combining Energy Information Administration plant-level data with literature-reported process efficiency data, we develop estimates of the unconverted heat flux from individual U.S. thermal power plants in 2012. Together these power plants discharged an estimated 18.9 billion GJth of residual heat in 2012, 4% of which was discharged at temperatures greater than 90 °C. We also characterize the temperature, spatial distribution, and temporal availability of this residual heat at the plant level and model the implications for the technical and economic feasibility of its end use. Increased implementation of flue gas desulfurization technologies at coal-fired facilities and the higher quality heat generated in the exhaust of natural gas fuel cycles are expected to increase the availability of residual heat generated by 10.6% in 2040.

  1. Design of compact intermediate heat exchangers for gas cooled fast reactors

    E-Print Network [OSTI]

    Gezelius, Knut, 1978-

    2004-01-01T23:59:59.000Z

    Two aspects of an intermediate heat exchanger (IHX) for GFR service have been investigated: (1) the intrinsic characteristics of the proposed compact printed circuit heat exchanger (PCHE); and (2) a specific design optimizing ...

  2. Anisotropic Heat and Water Transport in a PEFC Cathode Gas Diffusion Layer

    E-Print Network [OSTI]

    reaction ORR in the cathode CL to recombine with oxygen and producing water and waste heat. Despite amount of waste heat as it does electric power output. Furthermore, PEFCs tolerate only a small

  3. Ceramic heat-exchanger applications study

    SciTech Connect (OSTI)

    McFarlin, D.J.; Sgamboti, C.T.; Lessard, R.D.

    1982-10-01T23:59:59.000Z

    To put the potential benefits of ceramic heat exchangers (CHX) applications into quantitative perspective, several industrial cogeneration and electric utiity power generation systems were surveyed and evaluated. This study was focused on coal-based fuel fired applications, for which system performance and economic assessments were made. Seven CHX applications in the industrial cogeneration sector were selected for evaluation. These include (1) Gasified Coal-Fired Gas Turbine, (2) Pressurized Fluidized Bed Combustor (PFBC)-Gas Turbine, (3) Atmospheric Fluidized Bed Combustor (AFBC)-Gas Turbine, (4 and 5) AFBC Combined Cycle with and without reheat and (6 and 7) Indirect Coal-Fired Gas Turbine and Combined Cycle. The performance and economics of these cogeneration systems were evaluated and compared with other competing systems (both advanced and State-of-the-Art). For the electric utility power generation sector five applications utilizing a CHX were selected and evaluated; their performance and cost factors were compared to those of a reference pulverized coal-fired steam plant with flue gas desulfurization. These five applications included (1) PFBC-Combined Cycle, (2) AFBC-Combined Cycle, (3) Industrial Coal Gasifier-Combined Cycle, (4) Indirect Coal-Fired Combined Cycle, and (5) Indirect Coal-Fired Simple Cycle. Of the five CHX applications evaluated in the power generation sector, only the AFBC system showed a clear gain over the reference pulverized coal system.

  4. Feasibility of an alpha particle gas densimeter for stack sampling applications 

    E-Print Network [OSTI]

    Johnson, Randall Mark

    1983-01-01T23:59:59.000Z

    , for conceivable ranges of flue gas composition, the maximum error in density due to the uncertainty in gas composition is less than 2%. ACKNOWLEDGEMENTS I wish to express my appreciation to Dr. R. A. Fjeld and Dr. A. R. McFarland for their patience... LISTING APPENDIX C TABULATED RESULTS 58 60 72 VI TA 84 Vi LIST OF TABLES TABLE P age I Typical Flue Gas Compositions II Model Flue Gas Compositions 35 Coeff icients for Alpha particle Stopping Power Functions 59 Computed and Experimental...

  5. Gas-phase and catalytic combustion in heat-recirculating burners Jeongmin Ahn, Craig Eastwood, Lars Sitzki* and Paul D. Ronney

    E-Print Network [OSTI]

    1 Gas-phase and catalytic combustion in heat-recirculating burners Jeongmin Ahn, Craig Eastwood title: Extinction limits in excess enthalpy burners To be published in Proceedings of the Combustion-phase and catalytic combustion in heat-recirculating burners Jeongmin Ahn, Craig Eastwood, Lars Sitzki* and Paul D

  6. Combined heat and power has the potential to significantly increase energy production efficiency and thus reduce greenhouse gas emissions, however current market penetration

    E-Print Network [OSTI]

    Kammen, Daniel M.

    1 Combined heat and power has the potential to significantly increase energy production efficiency and thus reduce greenhouse gas emissions, however current market penetration analyses suggest that California will not reach the targets for combined heat and power set for it by the Air Resources Board (ARB

  7. Insights into gas heating and cooling in the disc of NGC 891 from Herschel far-infrared spectroscopy

    E-Print Network [OSTI]

    Hughes, T M; Schirm, M R P; Parkin, T J; De Looze, I; Wilson, C D; Bendo, G J; Baes, M; Fritz, J; Boselli, A; Cooray, A; Cormier, D; Karczewski, O ?; Lebouteiller, V; Lu, N; Madden, S C; Spinoglio, L; Viaene, S

    2014-01-01T23:59:59.000Z

    We present Herschel PACS and SPIRE spectroscopy of the most important far-infrared cooling lines in the nearby edge-on spiral galaxy, NGC 891: [CII] 158 $\\mu$m, [NII] 122, 205 $\\mu$m, [OI] 63, 145 $\\mu$m, and [OIII] 88 $\\mu$m. We find that the photoelectric heating efficiency of the gas, traced via the ([CII]+[OII]63)/$F_{\\mathrm{TIR}}$ ratio, varies from a mean of 3.5$\\times$10$^{-3}$ in the centre up to 8$\\times$10$^{-3}$ at increasing radial and vertical distances in the disc. A decrease in ([CII]+[OII]63)/$F_{\\mathrm{TIR}}$ but constant ([CII]+[OI]63)/$F_{\\mathrm{PAH}}$ with increasing FIR colour suggests that polycyclic aromatic hydrocarbons (PAHs) may become important for gas heating in the central regions. We compare the observed flux of the FIR cooling lines and total IR emission with the predicted flux from a PDR model to determine the gas density, surface temperature and the strength of the incident far-ultraviolet (FUV) radiation field, $G_{0}$. Resolving details on physical scales of ~0.6 kpc, a p...

  8. Field monitoring and evaluation of a residential gas-engine-driven heat pump: Volume 1, Cooling season

    SciTech Connect (OSTI)

    Miller, J.D.

    1995-09-01T23:59:59.000Z

    The Federal government is the largest single energy consumer in the United States; consumption approaches 1.5 quads/year of energy (1 quad = 10{sup 15} Btu) at a cost valued at nearly $10 billion annually. The US Department of Energy (DOE) Federal Energy Management Program (FEMP) supports efforts to reduce energy use and associated expenses in the Federal sector. One such effort, the New Technology Demonstration Program (NTDP), seeks to evaluate new energy-saving US technologies and secure their more timely adoption by the US government. Pacific Northwest Laboratory (PNL)is one of four DOE national multiprogram laboratories that participate in the NTDP by providing technical expertise and equipment to evaluate new, energy-saving technologies being studied and evaluated under that program. This two-volume report describes a field evaluation that PNL conducted for DOE/FEMP and the US Department of Defense (DoD) Strategic Environmental Research and Development Program (SERDP) to examine the performance of a candidate energy-saving technology -- a gas-engine-driven heat pump. The unit was installed at a single residence at Fort Sam Houston, a US Army base in San Antonio, Texas, and the performance was monitored under the NTDP. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) were York International, the heat pump manufacturer, Gas Research Institute (GRI), the technology developer; City Public Service of San Antonio, the local utility; American Gas Cooling Center (AGCC); Fort Sam Houston; and PNL.

  9. Fluid Bed Waste Heat Boiler Operating Experience in Dirty Gas Streams 

    E-Print Network [OSTI]

    Kreeger, A. H.

    1986-01-01T23:59:59.000Z

    The first industrial fluid bed waste heat boiler in the U. S. is operating on an aluminium melting furnace at the ALCOA Massena Integrated Aluminum Works in upstate New York. Waste heat from an aluminum melting furnace is captured for general plant...

  10. Gas injection to inhibit migration during an in situ heat treatment process

    DOE Patents [OSTI]

    Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

    2010-11-30T23:59:59.000Z

    Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

  11. High freestream turbulence levels have been shown to greatly augment the heat transfer along a gas turbine airfoil, particularly for the first stage

    E-Print Network [OSTI]

    Thole, Karen A.

    along a gas turbine airfoil, particularly for the first stage nozzle guide vane. For this study of the variables affecting boundary layer development on gas turbine airfoils, studies need to be performed, augmentations in convective heat transfer have been measured for a first stage turbine vane in the stagna- tion

  12. Flue-Cured Tobacco Curing Efficiency Research Tour

    E-Print Network [OSTI]

    Buehrer, R. Michael

    Flue-Cured Tobacco Curing Efficiency Research Tour Wednesday, October 23, 2013 Topics to be discussed: Tobacco curing efficiency New barn evaluations New curing barn technology Evaluation of single-barn hot water boiler systems Remedial barn pad insulation Utilization of solar energy

  13. INTERNAL FORCED iquid or gas flow through pipes or ducts is commonly used in heating and

    E-Print Network [OSTI]

    Ghajar, Afshin J.

    to flow by a fan or pump through a flow section that is sufficiently long to accomplish the desired heat. Then the logarithmic mean temperature difference and the rate of heat loss from the air become Tln 15.2°C Q · hAs Tln (13.5 W/m2 °C)(6.4 m2 )( 15.2°C) 1313 W Therefore, air will lose heat at a rate of 1313 W as it flows

  14. Phase I-B development of kinematic Stirling/Rankine commercial gas-fired heat-pump system. Final report, September 1983-December 1985

    SciTech Connect (OSTI)

    Monahan, R.E.

    1986-07-01T23:59:59.000Z

    The Kinematic Stirling/Rankine gas heat pump concept is based on the application of a Stirling engine that has been under development for over a decade. The engine has been converted to natural gas and is characterized with many thousand hours of operating experience. The goal of the project is to develop a commercial-size Stirling engine-driven gas heat pump with a cooling capacity of 10-ton, and a COP (heating) of 1.8 and COP (cooling) of 1.1. The project is a multi-phase development with commercialization planned for 1989. In this phase, an HVAC systems manufacturer (Borg-Warner) is working with SPS to develop a prototype gas-heat-pump system. To date, a piston-type open-shaft refrigeration compressor was selected as the best match for the engine. Both the engine and compressor have been tested and characterized by performance maps, and the experimental heat-pump systems designed, built, and preliminary testing performed. Close agreement with computer model output has been achieved. SPS has continued to focus on improving the Stirling-engine performance and reliability for the gas-heat-pump application.

  15. A novel high-heat transfer low-NO{sub x} natural gas combustion system. Phase 1 final report

    SciTech Connect (OSTI)

    Rue, D.M. [Institute of Gas Technology, Des Plaines, IL (United States); Fridman, A. [Univ. of Illinois, Chicago (United States); Viskanta, R. [Purdue Univ. (United States); Neff, D. [Cumbustion Tec, Inc. (United States)

    1997-11-01T23:59:59.000Z

    Phase I of the project focused on acquiring the market needs, modeling, design, and test plan information for a novel high-heat transfer low-NO{sub x} natural gas combustion system. All goals and objectives were achieved. The key component of the system is an innovative burner technology which combines high temperature natural gas preheating with soot formation and subsequent soot burnout in the flame, increases the system`s energy efficiency and furnace throughput, while minimizing the furnace air emissions, all without external parasitic systems. Work has included identifying industry`s needs and constraints, modeling the high luminosity burner system, designing the prototype burner for initial laboratory-scale testing, defining the test plan, adapting the burner technology to meet the industry`s needs and constraints, and outlining the Industrial Adoption Plan.

  16. Orthogonal Decomposition Methods for Turbulent Heat Transfer Analysis with Application to Gas Turbines

    E-Print Network [OSTI]

    Schwaenen, Markus

    2012-07-16T23:59:59.000Z

    . . . . . . . . . . . . . . . . . 46 C. Computational procedure . . . . . . . . . . . . . . . . . . . 48 1. Solver settings and grid for URANS study . . . . . . . 48 2. LES study . . . . . . . . . . . . . . . . . . . . . . . . 52 D. Results... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 1. Orthogonal decomposition URANS . . . . . . . . . . . 59 2. Orthogonal decomposition LES . . . . . . . . . . . . . 62 E. Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 V OPTIMIZING TURBULENT HEAT TRANSFER USING...

  17. Rigorous modeling of the acid gas heat of absorption in alkanolamine solutions

    SciTech Connect (OSTI)

    Emilie Blanchon le Bouhelec; Pascal Mougin; Alain Barreau; Roland Solimando [Institut Francais du Petrole, Rueil-Malmaison (France). Departement Thermodynamique et Modelisation Moleculaire

    2007-08-15T23:59:59.000Z

    In this work, we are interested in the estimation of CO{sub 2} and H{sub 2}S heats of absorption in aqueous solutions of alkanolamine: monoethanolamine (MEA), diethanolamine (DEA), and methyldiethanolamine (MDEA). Two methods can be used to calculate the heat release during the absorption phenomenon. The easier which consists of applying the integration of the Gibbs-Helmholtz expression remains inaccurate. The second one, more rigorous, evaluates the heat transfer through an internal energy balance for an open system. The balance expression contains partial molar enthalpies of species in the liquid phase which are calculated from the electrolyte nonrandom-two-liquid (NRTL) excess Gibbs energy model. The calculations carried out in this method can be considered as predictive regarding the NRTL model because its interaction parameters were previously and solely fitted on vapor-liquid equilibrium (VLE) data and not on experimental heat of absorption data. The comparison between both methods and experimental data for the three alkanolamines shows the contribution of this rigorous calculation to better estimate both properties (i.e., solubility and heat) and its usefulness to improve processes. Heats of absorption calculated with the second method can be used in addition to VLE data to fit NRTL parameters. This procedure leads to less-correlated parameters and allows extrapolating the model with more confidence. 63 refs., 10 figs., 6 tabs.

  18. A Novel High-Heat Transfer Low-NO{sub x} Natural Gas Combustion System. Final Technical Report

    SciTech Connect (OSTI)

    Abbasi, H.

    2004-01-01T23:59:59.000Z

    A novel high-heat transfer low NO(sub x) natural gas combustion system. The objectives of this program are to research, develop, test, and commercialize a novel high-heat transfer low-NO{sub x} natural gas combustion system for oxygen-, oxygen-enriched air, and air-fired furnaces. This technology will improve the process efficiency (productivity and product quality) and the energy efficiency of high-temperature industrial furnaces by at least 20%. GTI's high-heat transfer burner has applications in high-temperature air, oxygen-enriched air, and oxygen furnaces used in the glass, metals, cement, and other industries. Development work in this program is focused on using this burner to improve the energy efficiency and productivity of glass melting furnaces that are major industrial energy consumers. The following specific project objectives are defined to provide a means of achieving the overall project objectives. (1) Identify topics to be covered, problems requiring attention, equipment to be used in the program, and test plans to be followed in Phase II and Phase III. (2) Use existing codes to develop models of gas combustion and soot nucleation and growth as well as a thermodynamic and parametric description of furnace heat transfer issues. (3) Conduct a parametric study to confirm the increase in process and energy efficiency. (4) Design and fabricate a high-heat transfer low-NOx natural gas burners for laboratory, pilot- and demonstration-scale tests. (5) Test the high-heat transfer burner in one of GTI's laboratory-scale high-temperature furnaces. (6) Design and demonstrate the high-heat transfer burner on GTI's unique pilot-scale glass tank simulator. (7) Complete one long term demonstration test of this burner technology on an Owens Corning full-scale industrial glass melting furnace. (8) Prepare an Industrial Adoption Plan. This Plan will be updated in each program Phase as additional information becomes available. The Plan will include technical and economic analyses, energy savings and waste reduction predictions, evaluation of environmental effects, and outline issues concerning manufacturing, marketing, and financing. Combustion Tec, Owens Corning, and GTI will all take active roles in defining this Plan. During Phase I, the first three objectives were addressed and completed along with the design component of the fourth objective. In Phase II, the fabrication component of the fourth objective was completed along with objectives five and six. Results of the Phase I work were reported in the Phase I Final Report and are summarized in this Final Technical Report. Work for Phase II was divided in four specific Tasks. Results of the Phase II work were reported in the Phase II Final Report and are also summarized in this Final Technical Report. No Phase III Final Report was prepared, so this Final Technical Report presents the results of Phase III commercial demonstration efforts. A description of each Task in Phases I, II, and III is presented in this report.

  19. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D.; Bourcier, William L.

    2014-08-19T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  20. Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

    2010-11-09T23:59:59.000Z

    A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

  1. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    for out-of-state coal generation, then clearly the GHGElectricity Generation (TWh/a) Natural Gas Coal Natural Gascoal becomes the marginal fuel. Note that the marginal generation

  2. Film Cooling, Heat Transfer and Aerodynamic Measurements in a Three Stage Research Gas Turbine 

    E-Print Network [OSTI]

    Suryanarayanan, Arun

    2010-07-14T23:59:59.000Z

    The existing 3-stage turbine research facility at the Turbomachinery Performance and Flow Research Laboratory (TPFL), Texas A and M University, is re-designed and newly installed to enable coolant gas injection on the first ...

  3. Film Cooling, Heat Transfer and Aerodynamic Measurements in a Three Stage Research Gas Turbine

    E-Print Network [OSTI]

    Suryanarayanan, Arun

    2010-07-14T23:59:59.000Z

    The existing 3-stage turbine research facility at the Turbomachinery Performance and Flow Research Laboratory (TPFL), Texas A and M University, is re-designed and newly installed to enable coolant gas injection on the first stage rotor platform...

  4. Southwest Gas Corporation- Smarter Greener Better Solar Water Heating Program (Arizona)

    Broader source: Energy.gov [DOE]

    '''''Note: Effective July 15, 2013, Southwest Gas is no longer accepting applications for the current program year. Systems installed during the current program year will not be eligible for a...

  5. Local heat transfer and film effectiveness of a film cooled gas turbine blade tip

    E-Print Network [OSTI]

    Adewusi, Adedapo Oluyomi

    1999-01-01T23:59:59.000Z

    Gas turbine engines due to high operating temperatures undergo severe thermal stress and fatigue during operation. Cooling of these components is a very important issue during the lifetime of the engine. Cooling is achieved through the use...

  6. Advanced Energy and Water Recovery Technology from Low Grade Waste Heat

    SciTech Connect (OSTI)

    Dexin Wang

    2011-12-19T23:59:59.000Z

    The project has developed a nanoporous membrane based water vapor separation technology that can be used for recovering energy and water from low-temperature industrial waste gas streams with high moisture contents. This kind of exhaust stream is widely present in many industrial processes including the forest products and paper industry, food industry, chemical industry, cement industry, metal industry, and petroleum industry. The technology can recover not only the sensible heat but also high-purity water along with its considerable latent heat. Waste heats from such streams are considered very difficult to recover by conventional technology because of poor heat transfer performance of heat-exchanger type equipment at low temperature and moisture-related corrosion issues. During the one-year Concept Definition stage of the project, the goal was to prove the concept and technology in the laboratory and identify any issues that need to be addressed in future development of this technology. In this project, computational modeling and simulation have been conducted to investigate the performance of a nanoporous material based technology, transport membrane condenser (TMC), for waste heat and water recovery from low grade industrial flue gases. A series of theoretical and computational analyses have provided insight and support in advanced TMC design and experiments. Experimental study revealed condensation and convection through the porous membrane bundle was greatly improved over an impermeable tube bundle, because of the membrane capillary condensation mechanism and the continuous evacuation of the condensate film or droplets through the membrane pores. Convection Nusselt number in flue gas side for the porous membrane tube bundle is 50% to 80% higher than those for the impermeable stainless steel tube bundle. The condensation rates for the porous membrane tube bundle also increase 60% to 80%. Parametric study for the porous membrane tube bundle heat transfer performance was also done, which shows this heat transfer enhancement approach works well in a wide parameters range for typical flue gas conditions. Better understanding of condensing heat transfer mechanism for porous membrane heat transfer surfaces, shows higher condensation and heat transfer rates than non-permeable tubes, due to existence of the porous membrane walls. Laboratory testing has documented increased TMC performance with increased exhaust gas moisture content levels, which has exponentially increased potential markets for the product. The TMC technology can uniquely enhance waste heat recovery in tandem with water vapor recovery for many other industrial processes such as drying, wet and dry scrubber exhaust gases, dewatering, and water chilling. A new metallic substrate membrane tube development and molded TMC part fabrication method, provides an economical way to expand this technology for scaled up applications with less than 3 year payback expectation. A detailed market study shows a broad application area for this advanced waste heat and water recovery technology. A commercialization partner has been lined up to expand this technology to this big market. This research work led to new findings on the TMC working mechanism to improve its performance, better scale up design approaches, and economical part fabrication methods. Field evaluation work needs to be done to verify the TMC real world performance, and get acceptance from the industry, and pave the way for our commercial partner to put it into a much larger waste heat and waste water recovery market. This project is addressing the priority areas specified for DOE Industrial Technologies Program's (ITP's): Energy Intensive Processes (EIP) Portfolio - Waste Heat Minimization and Recovery platform.

  7. Heat Flow and Gas Hydrates on the Continental Margin of India: Building on Results from NGHP Expedition 01

    SciTech Connect (OSTI)

    Anne Trehu; Peter Kannberg

    2011-06-30T23:59:59.000Z

    The Indian National Gas Hydrate Program (NGHP) Expedition 01 presented the unique opportunity to constrain regional heat flow derived from seismic observations by using drilling data in three regions on the continental margin of India. The seismic bottom simulating reflection (BSR) is a well-documented feature in hydrate bearing sediments, and can serve as a proxy for apparent heat flow if data are available to estimate acoustic velocity and density in water and sediments, thermal conductivity, and seafloor temperature. Direct observations of temperature at depth and physical properties of the sediment obtained from drilling can be used to calibrate the seismic observations, decreasing the uncertainty of the seismically-derived estimates. Anomalies in apparent heat flow can result from a variety of sources, including sedimentation, erosion, topographic refraction and fluid flow. We constructed apparent heat flow maps for portions of the Krishna-Godavari (K-G) basin, the Mahanadi basin, and the Andaman basin and modeled anomalies using 1-D conductive thermal models. Apparent heat flow values in the Krishna-Godavari (K-G) basin and Mahanadi basin are generally 0.035 to 0.055 watts per square meter (W/m{sup 2}). The borehole data show an increase in apparent heat flow as water depth increases from 900 to 1500 m. In the SW part of the seismic grid, 1D modeling of the effect of sedimentation on heat flow shows that {approx}50% of the observed increase in apparent heat flow with increasing water depth can be attributed to trapping of sediments behind a 'toe-thrust' ridge that is forming along the seaward edge of a thick, rapidly accumulating deltaic sediment pile. The remainder of the anomaly can be explained either by a decrease in thermal conductivity of the sediments filling the slope basin or by lateral advection of heat through fluid flow along stratigraphic horizons within the basin and through flexural faults in the crest of the anticline. Such flow probably plays a role in bringing methane into the ridge formed by the toe-thrust. Because of the small anomaly due to this process and the uncertainty in thermal conductivity, we did not model this process explicitly. In the NE part of the K-G basin seismic grid, a number of local heat flow lows and highs are observed, which can be attributed to topographic refraction and to local fluid flow along faults, respectively. No regional anomaly can be resolved. Because of lack of continuity between the K-G basin sites within the seismic grid and those {approx}70 km to the NE in water depths of 1200 to 1500 m, we do not speculate on the reason for higher heat flow at these depths. The Mahanadi basin results, while limited in geographic extent, are similar to those for the K-G basin. The Andaman basin exhibits much lower apparent heat flow values, ranging from 0.015 to 0.025 W/m{sup 2}. Heat flow here also appears to increase with increasing water depth. The very low heat flow here is among the lowest heat flow observed anywhere and gives rise to a very thick hydrate stability zone in the sediments. Through 1D models of sedimentation (with extremely high sedimentation rates as a proxy for tectonic thickening), we concluded that the very low heat flow can probably be attributed to the combined effects of high sedimentation rate, low thermal conductivity, tectonic thickening of sediments and the cooling effect of a subducting plate in a subduction zone forearc. Like for the K-G basin, much of the local variability can be attributed to topography. The regional increase in heat flow with water depth remains unexplained because the seismic grid available to us did not extend far enough to define the local tectonic setting of the slope basin controlling this observational pattern. The results are compared to results from other margins, both active and passive. While an increase in apparent heat flow with increasing water depth is widely observed, it is likely a result of different processes in different places. The very low heat flow due to sedimentation and tectonics in the Andaman basi

  8. Heat Flow and Gas Hydrates on the Continental Margin of India: Building on Results from NGHP Expedition 01

    SciTech Connect (OSTI)

    Trehu, Anne; Kannberg, Peter

    2011-06-30T23:59:59.000Z

    The Indian National Gas Hydrate Program (NGHP) Expedition 01 presented the unique opportunity to constrain regional heat flow derived from seismic observations by using drilling data in three regions on the continental margin of India. The seismic bottom simulating reflection (BSR) is a well-documented feature in hydrate bearing sediments, and can serve as a proxy for apparent heat flow if data are available to estimate acoustic velocity and density in water and sediments, thermal conductivity, and seafloor temperature. Direct observations of temperature at depth and physical properties of the sediment obtained from drilling can be used to calibrate the seismic observations, decreasing the uncertainty of the seismically-derived estimates. Anomalies in apparent heat flow can result from a variety of sources, including sedimentation, erosion, topographic refraction and fluid flow. We constructed apparent heat flow maps for portions of the Krishna-Godavari (K-G) basin, the Mahanadi basin, and the Andaman basin and modeled anomalies using 1-D conductive thermal models. Apparent heat flow values in the Krishna-Godavari (K-G) basin and Mahanadi basin are generally 0.035 to 0.055 watts per square meter (W/m2). The borehole data show an increase in apparent heat flow as water depth increases from 900 to 1500 m. In the SW part of the seismic grid, 1D modeling of the effect of sedimentation on heat flow shows that ~50% of the observed increase in apparent heat flow with increasing water depth can be attributed to trapping of sediments behind a "toe-thrust" ridge that is forming along the seaward edge of a thick, rapidly accumulating deltaic sediment pile. The remainder of the anomaly can be explained either by a decrease in thermal conductivity of the sediments filling the slope basin or by lateral advection of heat through fluid flow along stratigraphic horizons within the basin and through flexural faults in the crest of the anticline. Such flow probably plays a role in bringing methane into the ridge formed by the toe-thrust. Because of the small anomaly due to this process and the uncertainty in thermal conductivity, we did not model this process explicitly. In the NE part of the K-G basin seismic grid, a number of local heat flow lows and highs are observed, which can be attributed to topographic refraction and to local fluid flow along faults, respectively. No regional anomaly can be resolved. Because of lack of continuity between the K-G basin sites within the seismic grid and those ~70 km to the NE in water depths of 1200 to 1500 m, we do not speculate on the reason for higher heat flow at these depths. The Mahanadi basin results, while limited in geographic extent, are similar to those for the KG basin. The Andaman basin exhibits much lower apparent heat flow values, ranging from 0.015 to 0.025 W/m2. Heat flow here also appears to increase with increasing water depth. The very low heat flow here is among the lowest heat flow observed anywhere and gives rise to a very thick hydrate stability zone in the sediments. Through 1D models of sedimentation (with extremely high sedimentation rates as a proxy for tectonic thickening), we concluded that the very low heat flow can probably be attributed to the combined effects of high sedimentation rate, low thermal conductivity, tectonic thickening of sediments and the cooling effect of a subducting plate in a subduction zone forearc. Like for the K-G basin, much of the local variability can be attributed to topography. The regional increase in heat flow with water depth remains unexplained because the seismic grid available to us did not extend far enough to define the local tectonic setting of the slope basin controlling this observational pattern. The results are compared to results from other margins, both active and passive. While an increase in apparent heat flow with increasing water depth is widely observed, it is likely a result of different processes in different places. The very low heat flow due to sedimentation and tectonics in the Andaman basin is at the low end of glob

  9. Single Channel Testing for Characterization of the Direct Gas Cooled Reactor and the SAFE-100 Heat Exchanger

    SciTech Connect (OSTI)

    Bragg-Sitton, S.M. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, MI 48109 (United States); Propulsion Research Center, NASA Marshall Space Flight Center, Huntsville, AL 35812 (United States); Kapernick, R. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Godfroy, T.J. [Propulsion Research Center, NASA Marshall Space Flight Center, Huntsville, AL 35812 (United States)

    2004-02-04T23:59:59.000Z

    Experiments have been designed to characterize the coolant gas flow in two space reactor concepts that are currently under investigation by NASA Marshall Space Flight Center and Los Alamos National Laboratory: the direct-drive gas-cooled reactor (DDG) and the SAFE-100 heatpipe-cooled reactor (HPR). For the DDG concept, initial tests have been completed to measure pressure drop versus flow rate for a prototypic core flow channel, with gas exiting to atmospheric pressure conditions. The experimental results of the completed DDG tests presented in this paper validate the predicted results to within a reasonable margin of error. These tests have resulted in a re-design of the flow annulus to reduce the pressure drop. Subsequent tests will be conducted with the re-designed flow channel and with the outlet pressure held at 150 psi (1 MPa). Design of a similar test for a nominal flow channel in the HPR heat exchanger (HPR-HX) has been completed and hardware is currently being assembled for testing this channel at 150 psi. When completed, these test programs will provide the data necessary to validate calculated flow performance for these reactor concepts (pressure drop and film temperature rise)

  10. Experimental Study of Gas Turbine Blade Film Cooling and Heat Transfer

    E-Print Network [OSTI]

    Narzary, Diganta P.

    2010-10-12T23:59:59.000Z

    thermal and mechanical stresses. This heat-up can be reduced by: (i) applying thermal barrier coating (TBC) on the surface, and (ii) providing coolant to the surface by injecting secondary air discharged from the compressor. However, as the bleeding off...

  11. Sinterable ceramic powders from laser heated gas phase reactions and rapidly solidified ceramic materials : annual report.

    E-Print Network [OSTI]

    Haggerty, John Scarseth

    1984-01-01T23:59:59.000Z

    CO[subscript 2] lasers have been employed to heat reactant gases to synthesize Si, Si[subscript 3] N[subscript 4] and SiC powders. The powders are small, uniform in size, nonagglomerated, highly pure and of controlled ...

  12. Effect of heat input on the microstructure and mechanical properties of tungsten inert gas arc butt-welded AZ61 magnesium alloy plates

    SciTech Connect (OSTI)

    Min Dong [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China); Shen Jun, E-mail: shenjun2626@163.com [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China); Lai Shiqiang; Chen Jie [College of Material Science and Engineering, Chongqing University, Chongqing 400044 (China)

    2009-12-15T23:59:59.000Z

    In this paper, the effects of heat input on the microstructures and mechanical properties of tungsten inert gas arc butt-welded AZ61 magnesium alloy plates were investigated by microstructural observations, microhardness tests and tensile tests. The results show that with an increase of the heat input, the grains both in the fusion zone and the heat-affected zone coarsen and the width of the heat-affected zone increased. Moreover, an increase of the heat input resulted in a decrease of the continuous {beta}-Mg{sub 17}Al{sub 12} phase and an increase of the granular {beta}-Mg{sub 17}Al{sub 12} phase in both the fusion zone and the heat-affected zone. The ultimate tensile strength of the welded joint increased with an increase of the heat input, while, too high a heat input resulted in a decrease of the ultimate tensile strength of the welded joint. In addition, the average microhardness of the heat-affected zone and fusion zone decreased sharply with an increase of the heat input and then decreased slowly at a relatively high heat input.

  13. Theoretical study of gas heated in a porous material subjected to a concentrated solar radiation (*)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . An experimental reactor was constructed for the verification of the model; it was designed to be used with 6.5 k velocity in the axial direction ; Vo = fluid velocity in the empty column, Vo = 03B6v. (*) Presented), physics (drying, distillation), thermo- dynamics (thermo-helio-electric power plants), etc. The gas being

  14. Measurement and analysis of heating of paper with gas-fired infrared burner

    E-Print Network [OSTI]

    Husain, Abdullah Nadir

    2000-01-01T23:59:59.000Z

    . Gas-fired IR heaters produce combustion on the burner surface by ignition of a pre-mixed air and fuel streams. The combustion raises the surface temperature to ranges of 800-1,100°C to emit radiation, mainly in the medium IR range, which has a...

  15. Improving Gas-Fired Heat Pump Capacity and Performance by Adding a Desiccant Dehumidification Subsystem

    E-Print Network [OSTI]

    Parsons, B. K.; Pesaran, A. A.; Bharathan, D.; Shelpuk, B. C.

    1990-01-01T23:59:59.000Z

    of absorption and desiccant solar cooling systems." Berkeley, CA: Lawrence Berkeley La- boratory. Kinast, J. A,; Wurm. J.; Zawacki, T. S.: and . Macriss, R. A. 1982. SOLAR-MEC~ development program report. COO-4495-53. Chicago, IL: Institute of Gas...

  16. COMBINED ACTIVE/PASSIVE DECAY HEAT REMOVAL APPROACH FOR THE 24 MWt GAS-COOLED FAST REACTOR

    SciTech Connect (OSTI)

    CHENG,L.Y.; LUDEWIG, H.

    2007-06-01T23:59:59.000Z

    Decay heat removal at depressurized shutdown conditions has been regarded as one of the key areas where significant improvement in passive response was targeted for the GEN IV GFR over the GCFR designs of thirty years ago. It has been recognized that the poor heat transfer characteristics of gas coolant at lower pressures needed to be accommodated in the GEN IV design. The design envelope has therefore been extended to include a station blackout sequence simultaneous with a small break/leak. After an exploratory phase of scoping analysis in this project, together with CEA of France, it was decided that natural convection would be selected as the passive decay heat removal approach of preference. Furthermore, a double vessel/containment option, similar to the double vessel/guard vessel approach of the SFR, was selected as the means of design implementation to reduce the PRA risks of the depressurization accident. However additional calculations in conjunction with CEA showed that there was an economic penalty in terms of decay heat removal system heat exchanger size, elevation heights for thermal centers, and most of all in guard containment back pressure for complete reliance on natural convection only. The back pressure ranges complicated the design requirements for the guard containment. Recognizing that the definition of a loss-of-coolant-accident in the GFR is a misnomer, since gas coolant will always be present, and the availability of some driven blower would reduce fuel temperature transients significantly; it was decided instead to aim for a hybrid active/passive combination approach to the selected BDBA. Complete natural convection only would still be relied on for decay heat removal but only after the first twenty four hours after the initiation of the accident. During the first twenty four hour period an actively powered blower would be relied on to provide the emergency decay power removal. However the power requirements of the active blower/circulators would be kept low by maintaining a pressurized system coolant back pressure of {approx}7-8 bars through the design of the guard containment for such a design pressure. This approach is termed the medium pressure approach by both CEA and the US. Such a containment design pressure is in the range of the LWR experience, both PWRs and BWRs. Both metal containments and concrete guard containments are possible in this pressure range. This approach is then a time-at-risk approach as the power requirements should be low enough that battery/fuel cell banks without diesel generator start-up failure rate issues should be capable of providing the necessary power. Compressed gas sources are another possibility. A companion PRA study is being conducted to survey the reliability of such systems.

  17. The use of combined heat and power (CHP) to reduce greenhouse gas emissions

    SciTech Connect (OSTI)

    Asrael, J.; Milmoe, P.H.; Haydel, J.

    1999-07-01T23:59:59.000Z

    Cogeneration or Combined Heat and Power (CHP) is the sequential production of electric power and thermal energy. It is a more efficient way of providing electricity and process heat than producing them independently. Average overall efficiencies can range from 70% to more than 80%. CHP decisions often present an opportunity to switch to a cleaner fuel. CHP systems are an attractive opportunity to save money, increase overall efficiency, reduce net emissions, and improve environmental performance. Climate Wise, a US Environmental Protection Agency (US EPA) program helping industrial Partners turn energy efficiency and pollution prevention into a corporate asset, has increased awareness of CHP by providing implementation and savings information, providing peer exchange opportunities for its Partners, and recognizing the achievements of Partners that have implemented CHP at their facilities. This paper profiles Climate Wise Partners that have invested in CHP systems, including describing how CHP is used in their facilities and the resulting cost and emission reductions.

  18. Advanced Fluidized Bed Waste Heat Recovery Systems

    E-Print Network [OSTI]

    Peterson, G. R.

    ADVANCED FLUIDIZED BED WASTE HEAT RECOVERY SYSTEMS G. R. PETERSON Project Manager U.S. Department of Energy, Idaho Operations Office Idaho Falls, Idaho ABSTRACT The U.S. Department of Energy, Office of Industri al Programs, has sponsored... the development of a Fluidized Bed Waste Heat Recovery System (FBWHRS) and a higher temperature variant, the Ceramic Tubular Distributor Plate (CTOP) Fluidized Bed Heat Exchanger (FBHX) system. Both systems recover energy from high-temperature flue gases...

  19. Phase 1-supplemental development of a kinematic Stirling/Rankine commercial gas-fired heat-pump system. Final report, January 1989-June 1989

    SciTech Connect (OSTI)

    Monahan, R.

    1989-06-01T23:59:59.000Z

    The kinematic Stirling/Rankine gas heat pump concept is based on the application of a Stirling engine that has been under development for over a decade. The engine has been converted to natural gas and is characterized with many thousand hours of operating experience. The goal of the project is to develop a commercial size Stirling engine-driven gas heat pump with a cooling capacity of 10 tons, a COP (heating) of 1.8 and a COP (cooling) of 1.1. The project is a multi-phase development with commercialization planned for the mid-1990's. In previous phases, an HVAC-systems manufacturer (York International) had been working with SPS to develop a prototype gas-heat-pump system. To date, two generations of prototype GHP systems have been built and tested and have demonstrated significant operating cost savings over the conventional electric heat pump. Under the program, a number of design and manufacturing process changes were made to the engine to reduce costs and improve endurance and shaft efficiency and are described. The adaptation and operation of a computer optimization code was accomplished under the program and is reported herein.

  20. Wafer heating mechanisms in a molecular gas, inductively coupled plasma: in situ, real time wafer surface measurements and three-dimensional thermal modeling

    SciTech Connect (OSTI)

    Titus, M. J.; Graves, D. B. [Department of Chemical Engineering, University of California, Berkeley, California 94720 (United States)

    2008-09-15T23:59:59.000Z

    The authors report measurements and modeling of wafer heating mechanisms in an Ar/O{sub 2} inductively coupled plasma (ICP). The authors employed a commercially available on-wafer sensor system (PlasmaTemp developed by KLA-Tencor) consisting of an on-board electronics module housing battery power and data storage with 30 temperature sensors embedded onto the wafer at different radial positions. This system allows for real time, in situ wafer temperature measurements. Wafer heating mechanisms were investigated by combining temperature measurements from the PlasmaTemp sensor wafer with a three-dimensional heat transfer model of the wafer and a model of the ICP. Comparisons between pure Ar and Ar/O{sub 2} discharges demonstrated that two additional wafer heating mechanisms can be important in molecular gas plasmas compared to atomic gas discharges. The two mechanisms are heating from the gas phase and O-atom surface recombination. These mechanisms were shown to contribute as much as 60% to wafer heating under conditions of low bias power. This study demonstrated how the 'on-wafer' temperature sensor not only yields a temperature profile distribution across the wafer, but can be used to help determine plasma characteristics, such as ion flux profiles or plasma processing temperatures.

  1. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  2. Cement kiln flue dust as a source of lime and potassium in four East Texas soils

    E-Print Network [OSTI]

    Poole, Warren David

    1975-01-01T23:59:59.000Z

    design on both sites. Yield, soil pH, plant and soil concentrations of K, Ca, and Mg were determined. Soil pH and extractable Ca increased with increasing rate of flue dust or calcite. Under field conditions, flue dust compared favorably with calcite... was similar to plant uptake from corresponding calcite + KC1 treatments. Soil pH and extractable soil K, Ca, and Mg increased with increased rate of flue dust treatment equally as well as from the corresponding calcite treatments. The flue dust was equal...

  3. Economics of residential gas furnaces and water heaters in United States new construction market

    E-Print Network [OSTI]

    Lekov, Alex B.

    2010-01-01T23:59:59.000Z

    gas space heating and water heating technologies. 3.Heating and Gas Water Heating Technology Characterizationspace and water heating technologies. It also shows that

  4. Heat transfer in sound propagation and attenuation through gas-liquid polyhedral foams

    E-Print Network [OSTI]

    Yuri M. Shtemler; Isaac R. Shreiber

    2007-05-20T23:59:59.000Z

    A cell method is developed, which takes into account the bubble geometry of polyhedral foams, and provides for the generalized Rayleigh-Plesset equation that contains the non-local in time term corresponding to heat relaxation. The Rayleigh-Plesset equation together with the equations of mass and momentum balances for an effective single-phase inviscid fluid yield a model for foam acoustics. The present calculations reconcile observed sound velocity and attenuation with those predicted using the assumption that thermal dissipation is the dominant damping mechanism in a range of foam expansions and sound excitation frequencies.

  5. Managing Your Energy: An ENERGY STAR(R) Guide for Identifying Energy Savings in Manufacturing Plants

    E-Print Network [OSTI]

    Worrell, Ernst

    2010-01-01T23:59:59.000Z

    recovery of exhaust gas waste heat—should be considered.It is common to use waste heat from furnace flue gases toa process heater. Recovering waste heat from the flue will

  6. New Mexico Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office(Billion Cubic Feet) Gas, WetReservesCubic

  7. Washington Heat Content of Natural Gas Deliveries to Consumers (BTU per

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are nowTotal" (Percent) Type: Sulfur Content4,367,470 4,364,790 4,363,909 4,363,143 4,363,967 4,363,549 1973-2015 Alaska 14,197 14,197Cubic Feet) Gas, WetCubic Foot)

  8. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, C.Y.

    1993-09-21T23:59:59.000Z

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

  9. Heat-pump-centered Integrated Community Energy Systems: systems development, Consolidated Natural Gas Service Company. Final report

    SciTech Connect (OSTI)

    Baker, N.R.; Donakowski, T.D.; Foster, R.B.; Sala, D.L.; Tison, R.R.; Whaley, T.P.; Yudow, B.D.; Swenson, P.F.

    1980-01-01T23:59:59.000Z

    The Heat-Actuated Heat Pump Centered Integrated Community Energy System (HAHP-ICES) utilizes a gas-fired, engine-driven, heat pump and commercial buildings, and offers several advantages over the more conventional equipment it is intended to supplant. The general non-site-specific application assumes a hypothetical community of one 59,000 ft/sup 2/ office building and five 24-unit, low-rise apartment buildings located in a region with a climate similar to Chicago. This community serves as a starting point - the base case - upon which various sensitivity analyses are performed and through which the performance characteristics of the HAHP are explored. The results of these analyses provided the selection criteria for the site-specific application of the HAHP-ICES concept to a real-world community. The site-specific community consists of 42 townhouses; five 120-unit, low-rise apartment buildings; five 104-unit high-rise apartment buildings; one 124,000 ft/sup 2/ office building; and a single 135,000 ft/sup 2/ retail building located in Monroeville, Pa. The base-case analyses confirmed that the HAHP-ICES has significant potentials for reducing the primary energy consumption and pollutant emissions associated with space conditioning when compared with a conventional system. Primary energy consumption was reduced by 30%, while emission reductions ranged from 39 to 77%. The results of the site-specific analysis indicate that reductions in energy consumption of between 15 and 22% are possible when a HAHP-ICES is selected as opposed to conventional HVAC equipment.

  10. Transitional regimes of natural convection in a differentially heated cubical cavity under the effects of wall and molecular gas radiation

    SciTech Connect (OSTI)

    Soucasse, L.; Rivière, Ph.; Soufiani, A., E-mail: anouar.soufiani@ecp.fr [CNRS, UPR 288, Laboratoire EM2C, 92290 Châtenay-Malabry (France); École Centrale Paris, 92290 Châtenay-Malabry (France)] [France; Xin, S. [CNRS/INSA-Lyon, UMR 5008, CETHIL, 69621 Villeurbanne (France)] [CNRS/INSA-Lyon, UMR 5008, CETHIL, 69621 Villeurbanne (France); Le Quéré, P. [CNRS, UPR 3251, LIMSI, 91403 Orsay Cedex (France)] [CNRS, UPR 3251, LIMSI, 91403 Orsay Cedex (France)

    2014-02-15T23:59:59.000Z

    The transition to unsteadiness and the dynamics of weakly turbulent natural convection, coupled to wall or gas radiation in a differentially heated cubical cavity with adiabatic lateral walls, are studied numerically. The working fluid is air with small contents of water vapor and carbon dioxide whose infrared spectral radiative properties are modelled by the absorption distribution function model. A pseudo spectral Chebyshev collocation method is used to solve the flow field equations and is coupled to a direct ray tracing method for radiation transport. Flow structures are identified by means of either the proper orthogonal decomposition or the dynamic mode decomposition methods. We first retrieve the classical mechanism of transition to unsteadiness without radiation, characterized by counter-rotating streamwise-oriented vortices generated at the exit of the vertical boundary layers. Wall radiation through a transparent medium leads to a homogenization of lateral wall temperatures and the resulting transition mechanism is similar to that obtained with perfectly conducting lateral walls. The transition is due to an unstable stratification upstream the vertical boundary layers and is characterized by periodically oscillating transverse rolls of axis perpendicular to the main flow. When molecular gas radiation is accounted for, no periodic solution is found and the transition to unsteadiness displays complex structures with chimneys-like rolls whose axes are again parallel to the main flow. The origin of this instability is probably due to centrifugal forces, as suggested previously for the case without radiation. Above the transition to unsteadiness, at Ra = 3 × 10{sup 8}, it is shown that both wall and gas radiation significantly intensify turbulent fluctuations, decrease the thermal stratification in the core of the cavity, and increase the global circulation.

  11. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25T23:59:59.000Z

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  12. Recovering "Waste" from "WTEs"? Heat Attaching devices to flues and exhaust pipes could harvest waste heat-

    E-Print Network [OSTI]

    Columbia University

    saving that would be especially relevant in hybrid petrol/electric devices where the battery is recharged

  13. Solar heat receiver

    DOE Patents [OSTI]

    Hunt, Arlon J. (Oakland, CA); Hansen, Leif J. (Berkeley, CA); Evans, David B. (Orinda, CA)

    1985-01-01T23:59:59.000Z

    A receiver for converting solar energy to heat a gas to temperatures from 700.degree.-900.degree. C. The receiver is formed to minimize impingement of radiation on the walls and to provide maximum heating at and near the entry of the gas exit. Also, the receiver is formed to provide controlled movement of the gas to be heated to minimize wall temperatures. The receiver is designed for use with gas containing fine heat absorbing particles, such as carbon particles.

  14. Solar heat receiver

    DOE Patents [OSTI]

    Hunt, A.J.; Hansen, L.J.; Evans, D.B.

    1982-09-29T23:59:59.000Z

    A receiver is described for converting solar energy to heat a gas to temperatures from 700 to 900/sup 0/C. The receiver is formed to minimize impingement of radiation on the walls and to provide maximum heating at and near the entry of the gas exit. Also, the receiver is formed to provide controlled movement of the gas to be heated to minimize wall temperatures. The receiver is designed for use with gas containing fine heat absorbing particles, such as carbon particles.

  15. A corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, S.L.

    1987-08-10T23:59:59.000Z

    A corrosive and erosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is pumped through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium. 3 figs., 3 tabs.

  16. anion-exchange resin-based desulfurization: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flue Gas Desulfurization GT Gas Turbine HHV Higher Heating Values HCN Hydrogen Cyanide HRSG Heat Recovery Steam Generation... ? Nuclear Power Plants ? Solar Power Plants ? Wind...

  17. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    None

    1998-09-01T23:59:59.000Z

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, especially NOX. The project involved operating gas reburning technology combined with low NO, burner technology (GR-LNB) on a coal-fired utility boiler. Low NOX burners are designed to create less NOX than conventional burners. However, the NO, control achieved is in the range of 30-60-40, and typically 50%. At the higher NO, reduction levels, CO emissions tend to be higher than acceptable standards. Gas Reburning (GR) is designed to reduce the level of NO. in the flue gas by staged fuel combustion. When combined, GR and LNBs work in harmony to both minimize NOX emissions and maintain an acceptable level of CO emissions. The demonstration was performed at Public Service Company of Colorado's (PSCO) Cherokee Unit 3, located in Denver, Colorado. This unit is a 172 MW. wall-fired boiler that uses Colorado bituminous, low-sulfur coal and had a pre GR-LNB baseline NOX emission of 0.73 lb/1 Oe Btu. The target for the project was a reduction of 70 percent in NOX emissions. Project sponsors included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation (EER). EER conducted a comprehensive test demonstration program over a wide range of boiler conditions. Over 4,000 hours of operation were achieved. Intensive measurements were taken to quantify the reductions in NOX emissions, the impact on boiler equipment and operability, and all factors influencing costs. The results showed that GR-LNB technology achieved excellent emission reductions. Although the performance of the low NOX burners (supplied by others) was somewhat less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 180A. The performance goal of 70% reduction was met on many test runs, but at higher gas heat inputs. The impact on boiler equipment was determined to be very minimal. Toward the end of the testing, the flue gas recirculation (used to enhance gas penetration into the furnace) system was removed and new high pressure gas injectors were installed. Further, the low NOX burners were modified and gave better NO. reduction performance. These modifications resulted in a similar NO, reduction performance (64%) at a reduced level of gas heat input (-13Yo). In addition, the OFA injectors were re-designed to provide for better control of CO emissions. Although not a part of this project, the use of natural gas as the primary fuel with gas reburning was also tested. The gas/gas reburning tests demonstrated a reduction in NOX emissions of 43% (0.30 lb/1 OG Btu reduced to 0.17 lb/1 OG Btu) using 7% gas heat input. Economics are a key issue affecting technology development. Application of GR-LNB requires modifications to existing power plant equipment and as a result, the capital and operating costs depend largely on site-specific factors such as: gas availability at the site, gas to coal delivered price differential, sulfur dioxide removal requirements, windbox pressure, existing burner throat diameters, and reburn zone residence time available. Based on the results of this CCT project, EER expects that most GR-LNB installations will achieve at least 60% NOX control when firing 10-15% gas. The capital cost estimate for installing a GR-LNB system on a 300 MW, unit is approximately $25/kW. plus the cost of a gas pipeline (if required). Operating costs are almost entirely related to the differential cost of the natural gas compared to coal.

  18. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    None

    1998-07-01T23:59:59.000Z

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

  19. Demonstration Results From Greenhouse Heating with Liquified Wood

    SciTech Connect (OSTI)

    Steele, Philip; Parish, Don; Cooper, Jerome

    2011-07-01T23:59:59.000Z

    A boiler fuel known as Lignocellulosic Boiler Fuel (LBF) was developed at the Department of Forest Products, Mississippi State University for potential application for heating agricultural buildings. LBF was field tested to heat green houses in cooperation with Natchez Trace Greenhouses (NTG) located in Kosciusko, Mississippi. MSU modified an idled natural gas boiler located at NTG to combust the LBF. Thirty gallons of bio-oil were produced at the MSU Bio-oil Research Laboratory. The bio-oil was produced from the fast-pyrolysis of southern pine (15 gal) and white oak (15 gal) feedstocks and subsequently upgraded by a proprietary process. Preliminary field testing was conducted at (NTG). The LBF was produced from each wood species was tested separately and co-fed with diesel fuel to yield three fuel formulations: (1) 100% diesel; (2) 87.5% LBF from southern pine bio-oil co-fed with 12.5% diesel and (3) 87.5% LBF from white oak co-fed with 12.5% diesel fuel formulations. Each fuel formulation was combusted in a retrofit NTG boiler. Fuel consumption and water temperature were measured periodically. Flue gas from the boiler was analyzed by gas chromatograph. The 100% diesel fuel increased water temperature at a rate of 4 ���°F per min. for 35 min. to achieve the target 140 ���°F water temperature increase. The 87.5% pine LBF fuel cofed with 12.5%) diesel attained the 140 ���°F water temperature increase in 62 min. at a rate of 2.3 ���°F per min. The 87.5% white oak LBF fuel co-fed with 12.5% diesel reached the 140 ���°F water temperature increase in 85 min. at a rate of 1.6 ���°F per min. Fuel that contained 87.5% pine LBF co-fed with 12.5% diesel yielded nitrogen and oxygen at a ratio of 5.3 and carbon dioxide and carbon monoxide at a ratio of 22.2. Fuel formulations that contained 87.5% white oak LBF co-fed with 12.5% diesel yielded nitrogen and oxygen at a ratio of 4.9 and carbon dioxide and carbon monoxide at a ratio of 16.4. Neither the pine LBF nor the white oak LBF fuel showed any measureable methane emissions from the NTG boiler flue gas. These results indicate a viable potential for mildly upgraded bio-oil to become an alternative fuel source for greenhouse operations.

  20. Gas-Cooled Fast Breeder Reactor Preliminary Safety Information Document, Amendment 10. GCFR residual heat removal system criteria, design, and performance

    SciTech Connect (OSTI)

    Not Available

    1980-09-01T23:59:59.000Z

    This report presents a comprehensive set of safety design bases to support the conceptual design of the gas-cooled fast breeder reactor (GCFR) residual heat removal (RHR) systems. The report is structured to enable the Nuclear Regulatory Commission (NRC) to review and comment in the licensability of these design bases. This report also presents information concerning a specific plant design and its performance as an auxiliary part to assist the NRC in evaluating the safety design bases.

  1. CO.sub.2 separation from low-temperature flue gases

    DOE Patents [OSTI]

    Dilmore, Robert (Irwin, PA); Allen, Douglas (Salem, MA); Soong, Yee (Monroeville, PA); Hedges, Sheila (Bethel Park, PA)

    2010-11-30T23:59:59.000Z

    Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

  2. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    None

    1998-07-01T23:59:59.000Z

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

  3. Water treatment capacity of forward osmosis systems utilizing power plant waste heat

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Xingshi; Gingerich, Daniel B.; Mauter, Meagan S.

    2015-06-11T23:59:59.000Z

    Forward osmosis (FO) has the potential to improve the energy efficiency of membrane-based water treatment by leveraging waste heat from steam electric power generation as the primary driving force for separation. In this study, we develop a comprehensive FO process model, consisting of membrane separation, heat recovery, and draw solute regeneration (DSR) models. We quantitatively characterize three alternative processes for DSR: distillation, steam stripping, and air stripping. We then construct a mathematical model of the distillation process for DSR that incorporates hydrodynamics, mass and heat transport resistances, and reaction kinetics, and we integrate this into a model for the fullmore »FO process. Finally, we utilize this FO process model to derive a first-order approximation of the water production capacity given the rejected heat quantity and quality available at U.S. electric power facilities. We find that the upper bound of FO water treatment capacity using low-grade heat sources at electric power facilities exceeds process water treatment demand for boiler water make-up and flue gas desulfurization wastewater systems.« less

  4. Water treatment capacity of forward osmosis systems utilizing power plant waste heat

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Xingshi [Carnegie Mellon Univ., Pittsburgh, PA (United States); Gingerich, Daniel B. [Carnegie Mellon Univ., Pittsburgh, PA (United States); Mauter, Meagan S. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2015-06-11T23:59:59.000Z

    Forward osmosis (FO) has the potential to improve the energy efficiency of membrane-based water treatment by leveraging waste heat from steam electric power generation as the primary driving force for separation. In this study, we develop a comprehensive FO process model, consisting of membrane separation, heat recovery, and draw solute regeneration (DSR) models. We quantitatively characterize three alternative processes for DSR: distillation, steam stripping, and air stripping. We then construct a mathematical model of the distillation process for DSR that incorporates hydrodynamics, mass and heat transport resistances, and reaction kinetics, and we integrate this into a model for the full FO process. Finally, we utilize this FO process model to derive a first-order approximation of the water production capacity given the rejected heat quantity and quality available at U.S. electric power facilities. We find that the upper bound of FO water treatment capacity using low-grade heat sources at electric power facilities exceeds process water treatment demand for boiler water make-up and flue gas desulfurization wastewater systems.

  5. Economics of residential gas furnaces and water heaters in US new construction market

    E-Print Network [OSTI]

    Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

    2010-01-01T23:59:59.000Z

    gas space heating and water-heating technologies. USheating and gas water-heating technology characterizationspace and water-heating technologies. It also shows that

  6. Condensing Heating and Water Heating Equipment Workshop Location...

    Energy Savers [EERE]

    Condensing Heating and Water Heating Equipment Workshop Location: Washington Gas Light Appliance Training Facility 6801 Industrial Road Springfield, VA Date: October 9, 2014 Time:...

  7. Heating of the molecular gas in the massive outflow of the local ultraluminous-infrared and radio-loud galaxy 4C12.50

    E-Print Network [OSTI]

    Dasyra, K M; Novak, G S; Bremer, M; Spinoglio, L; Santaella, M Pereira; Salome, P; Falgarone, E

    2014-01-01T23:59:59.000Z

    We present a comparison of the molecular gas properties in the outflow vs. in the ambient medium of the local prototype radio-loud and ultraluminous-infrared galaxy 4C12.50 (IRAS13451+1232), using new data from the IRAM Plateau de Bure interferometer and 30m telescope, and the Herschel space telescope. Previous H_2 (0-0) S(1) and S(2) observations with the Spitzer space telescope had indicated that the warm (~400K) molecular gas in 4C12.50 is made up of a 1.4(+-0.2)x10^8 M_sun ambient reservoir and a 5.2(+-1.7)x10^7 M_sun outflow. The new CO(1-0) data cube indicates that the corresponding cold (25K) H_2 gas mass is 1.0(+-0.1)x10^10 M_sun for the ambient medium and = 30 times higher in the outflow than in the ambient medium, indicating that a non-negligible fraction of the accelerated gas is heated to temperatures at which star formation is inefficient. This conclusion is robust against the use of different alpha factor values, and/or different warm gas tracers (H_2 vs. H_2 plus CO): with the CO-probed gas mas...

  8. High potential recovery -- Gas repressurization

    SciTech Connect (OSTI)

    Madden, M.P.

    1998-05-01T23:59:59.000Z

    The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

  9. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation 

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30T23:59:59.000Z

    The Gas-to-liquids (GTL) processes produce a large fraction of by-products whose disposal or handling ordinarily becomes a cost rather than benefit. As an alternative strategy to market stranded gas reserves, GTL...

  10. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    E-Print Network [OSTI]

    Carerras-Sospedra, Marc

    2012-01-01T23:59:59.000Z

    Gas Industrial Natural Gas Combustion (Unspecified) COlb/MMcf Commercial Natural Gas Combustion - WaterHeating Commercial Natural Gas Combustion - Space Heating NO

  11. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    E-Print Network [OSTI]

    Carerras-Sospedra, Marc

    2012-01-01T23:59:59.000Z

    Gas Industrial Natural Gas Combustion (Unspecified) CO lb/MMcf Commercial Natural Gas Combustion - Water HeatingCommercial Natural Gas Combustion - Space Heating NO X CO

  12. Evaluating energy dissipation during expansion in a refrigeration cycle using flue pipe acoustic resonators

    E-Print Network [OSTI]

    Luckyanova, Maria N. (Maria Nickolayevna)

    2008-01-01T23:59:59.000Z

    This research evaluates the feasibility of using a flue pipe acoustic resonator to dissipate energy from a refrigerant stream in order to achieve greater cooling power from a cryorefrigeration cycle. Two models of the ...

  13. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    Flue Flue Fuel oil Natural gas Natural gas Gas turbine Gasturbine Gas turbine Coal IGCC Flue Flue Flue Flue Fuel IEA,oil, natural gas, and gas turbine power plants. As shown,

  14. The CO2 Reduction Potential of Combined Heat and Power in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    chillers that use waste heat for cooling (see also Stadlerfired natural gas chillers, waste heat or solar heat; •with HX can utilize waste heat for heating or cooling

  15. NSTAR (Gas)- Commercial Energy Efficiency Programs

    Broader source: Energy.gov [DOE]

    NSTAR Gas offers incentives for their commercial customers to save energy in existing facilities. Rebates are for high efficiency gas space heating equipment, water heating equipment, infrared...

  16. GAS INJECTION/WELL STIMULATION PROJECT

    SciTech Connect (OSTI)

    John K. Godwin

    2005-12-01T23:59:59.000Z

    Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

  17. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Zevenhoven, Ron

    and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste

  18. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect (OSTI)

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01T23:59:59.000Z

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  19. Waste Heat Recovery by Organic Fluid Rankine Cycle

    E-Print Network [OSTI]

    Verneau, A.

    1979-01-01T23:59:59.000Z

    powers of a few megawatts and medium temperatures, about 500 C/600 C, for flue gas. The very simple technology of turbines is shown. Three examples are presented. The first one is a test loop of 300 thermal kW built in BERTIN & Cie laboratory...

  20. Prediction of convective heat transfer coefficients and their effects on distortion and mechanical properties of cylinder steel bodies quenched by gas cooling

    SciTech Connect (OSTI)

    Thuvander, A.; Melander, A.; Lind, M.; Lior, N.; Bark, F.H.

    1999-07-01T23:59:59.000Z

    The primary objectives of this study are to model the nature of the complex high-turbulence quenching cooling-gas flow, and to examine its effects on the resulting distortions and mechanical properties of the quenched piece, here bearing steel tubes and solid cylinders. A {kappa}-{epsilon} turbulent flow and heat transfer model adopted was found to predict the convective heat transfer coefficient (h) distribution reasonably well for Reynolds number up to about (0.3)10{sup 6}. At higher Reynolds number (to 10{sup 6}) it still predicts the nature of the flow well, but overpredicts h by up to 100% in the transition zone. The distributions of h around the body surface were used as the boundary condition for computing the temperature distribution history, phase transformations, distortions and mechanical properties of the quenched bodies. Increasing variation in h was found to increase the probability of large out-of-roundness, and nonuniformity in the properties.

  1. Phases I-C, I-D and I-E development of Kinematic Stirling/Rankine commercial gas-fired heat pump system. Final report, January 1986-September 1988

    SciTech Connect (OSTI)

    Monahan, R.E.

    1988-10-01T23:59:59.000Z

    The Kinematic Stirling/Rankine gas-heat-pump concept is based on the application of a Stirling engine under development for over a decade. The engine was converted to natural gas and is characterized with many thousand hours of operating experience. The goal of the project is to develop a commercial-size Stirling engine-driven gas heat pump with a cooling capacity of 10-tons, a COP (heating) of 1.8 and a COP (cooling) of 1.1. The project is a multi-phase development with commercialization planned for 1990. In these phases, an HVAC systems manufacturer (York International) has been working with SPS to develop a prototype gas-heat-pump system. To date, two generations of prototype GHP systems have been built and tested and have demonstrated significant operating cost savings over the conventional electric heat pump. Data are presented for environmental laboratory testing of both prototype gas heat pumps as well as durability, reliability, performance, and emission testing of the V160 Stirling engine. A number of design and manufacturing process changes were made to the engine to reduce costs and improve endurance and shaft efficiency and are described.

  2. Fluid Circulation and Heat Extraction from Engineered Geothermal Reservoirs

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489Information Hydro IncEnergy InformationFlue GasFlueGen

  3. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  4. Design of an experimental loop for post-LOCA heat transfer regimes in a Gas-cooled Fast Reactor

    E-Print Network [OSTI]

    Cochran, Peter A. (Peter Andrew)

    2005-01-01T23:59:59.000Z

    The goal of this thesis is to design an experimental thermal-hydraulic loop capable of generating accurate, reliable data in various convection heat transfer regimes for use in the formulation of a comprehensive convection ...

  5. Acoustically enhanced heat exchange and drying apparatus

    DOE Patents [OSTI]

    Bramlette, T.T.; Keller, J.O.

    1987-07-10T23:59:59.000Z

    A heat transfer drying apparatus includes an acoustically augmented heat transfer chamber for receiving material to be dried. The chamber includes a first heat transfer gas inlet, a second heat transfer gas inlet, a material inlet, and a gas outlet which also serves as a dried material and gas outlet. A non-pulsing first heat transfer gas source provides a first drying gas to the acoustically augmented heat transfer chamber through the first heat transfer gas inlet. A valveless, continuous second heat transfer gas source provides a second drying gas to the acoustically augmented heat transfer chamber through the second heat transfer gas inlet. The second drying gas also generates acoustic waves which bring about acoustical coupling with the gases in the acoustically augmented heat transfer chamber. The second drying gas itself oscillates at an acoustic frequency of approximately 180 Hz due to fluid mechanical motion in the gas. The oscillations of the second heat transfer gas coupled to the first heat transfer gas in the acoustically augmented heat transfer chamber enhance heat and mass transfer by convection within the chamber. 3 figs.

  6. Economics of residential gas furnaces and water heaters in United States new construction market

    E-Print Network [OSTI]

    Lekov, Alex B.

    2010-01-01T23:59:59.000Z

    around 25% of the gas water heating market by 2015. DOE alsoSpace Heating and Water Heating Market Characterization Thespace heating and water heating market differs significantly

  7. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 450 operational projects in 43 states. These projects convert a large source of greenhouse gases into a fuel that...

  8. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  9. Predictions of flow and heat transfer in sharp 180-deg turns of gas turbine coolant channels with and without turning vanes

    SciTech Connect (OSTI)

    Bonhoff, B.; Leusch, J.; Johnson, B.V.

    1999-07-01T23:59:59.000Z

    A numerical study was conducted to determine the effects of turning vanes on the flow characteristics, the pressure drop and the heat transfer distribution in the turn region of two-legged, coolant passages for application to cooling gas turbine blades. The channels consisted of two straight, square-sectioned legs connected by a 180-deg. turn, with an inner radius of 0.15 hydraulic diameters. The ribs were square-sectioned with a height of 0.1 D{sub h}, staggered between leading and trailing side and at an angle of 45-deg. to the flow. Three different configurations of the coolant channel were investigated: with smooth walls, with ribs on two walls and no vane and with ribs on two walls and a 180-deg guide vane in the turn. For all calculations, the Reynolds number at the inlet was Re{sub D} = 100,000, the fluid was water and buoyancy effects were neglected. The simulations were made for rotation numbers, Ro = 0.0 and 0.15. The flow and heat transfer simulations were made with the FLUENT structured code. Based on the results of several previous studies, the differential-Reynolds-Stress turbulence model with wall functions was used. The highest heat transfer in the turn was obtained for both the rotating and non-rotating cases with the ribbed channel without the guide vane. The pressure loss was also higher without the vane. Due to the staggering of the ribs, secondary flow and heat transfer in the turn was higher on the side of the channel where the last rib at the entrance reaches further into the turn. With increasing rotation number, the secondary flow and heat transfer increased on the leading side of the turn. For the configuration with a 180-deg. vane, the mass flux at the outer side of the vane increased with increasing rotation number.

  10. Laboratory Evaluation of Gas-Fired Tankless and Storage Water Heater Approaches to Combination Water and Space Heating

    SciTech Connect (OSTI)

    Kingston, T.; Scott, S.

    2013-03-01T23:59:59.000Z

    Homebuilders are exploring more cost effective combined space and water heating systems (combo systems) with major water heater manufacturers that are offering pre-engineered forced air space heating combo systems. In this project, unlike standardized tests, laboratory tests were conducted that subjected condensing tankless and storage water heater based combo systems to realistic, coincidental space and domestic hot water loads with the following key findings: 1) The tankless combo system maintained more stable DHW and space heating temperatures than the storage combo system. 2) The tankless combo system consistently achieved better daily efficiencies (i.e. 84%-93%) than the storage combo system (i.e. 81%- 91%) when the air handler was sized adequately and adjusted properly to achieve significant condensing operation. When condensing operation was not achieved, both systems performed with lower (i.e. 75%-88%), but similar efficiencies. 3) Air handlers currently packaged with combo systems are not designed to optimize condensing operation. More research is needed to develop air handlers specifically designed for condensing water heaters. 4) System efficiencies greater than 90% were achieved only on days where continual and steady space heating loads were required with significant condensing operation. For days where heating was more intermittent, the system efficiencies fell below 90%.

  11. Develop Thermoelectric Technology for Automotive Waste Heat Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

  12. Acoustically enhanced heat exchange and drying apparatus

    DOE Patents [OSTI]

    Bramlette, T. Tazwell (Livermore, CA); Keller, Jay O. (Oakland, CA)

    1989-01-01T23:59:59.000Z

    A heat transfer apparatus includes a first chamber having a first heat transfer gas inlet, a second heat transfer gas inlet, and an outlet. A first heat transfer gas source provides a first gas flow to the first chamber through the first heat transfer gas inlet. A second gas flow through a second chamber connected to the side of the first chamber, generates acoustic waves which bring about acoustical coupling of the first and second gases in the acoustically augmented first chamber. The first chamber may also include a material inlet for receiving material to be dried, in which case the gas outlet serves as a dried material and gas outlet.

  13. Heat Transfer in Rectangular Channels (AR=2:1) of the Gas Turbine Blade at High Rotation Numbers

    E-Print Network [OSTI]

    Lei, Jiang 1980-

    2011-08-03T23:59:59.000Z

    , the flow direction is radial inward. The hydraulic diameter (Dh) of the channel is 16.9 mm. Parallel square ribs with an attack angle (alpha) of 45 degrees are used on leading and trailing surfaces to enhance the heat transfer. The rib height...

  14. Effect of film hole location on heat transfer coefficient and film effectiveness of a gas turbine blade

    E-Print Network [OSTI]

    Jiang, Huan Wanda

    1994-01-01T23:59:59.000Z

    Experiments were performed to study the effect of film hole location on local heat transfer coefficient and film effectiveness distributions of a turbine blade model with air (D.R. = 1.0) and C02 (D.R. = 1.52) film injection. Tests were performed...

  15. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01T23:59:59.000Z

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  16. Zevenhoven & Kilpinen FLUE GASES and FUEL GASES 19.6.2001 2-1 Chapter 2 Flue gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    .1 Introduction Combustion processes for heat and power generation and the incineration of household waste are actually unwanted by-products from a power plant or a waste incinerator, since the first has the objective to convert hydrocarbon fuels (CxHy) into CO2, H2O plus heat and power, whilst the second aims at reducing

  17. First university owned district heating system using biomass heat

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Highlights · First university owned district heating system using biomass heat · Capacity: 15 MMBtu Main Campus District Heating Performance · Avoided: 3500 tonnes of CO2 · Particulate: less than 10 mg District Heating Goals To displace 85% of natural gas used for core campus heating. Fuel Bunker Sawmill

  18. A cement kiln flue-dust evaluated as a soil liming material

    E-Print Network [OSTI]

    Stacha, Raimund

    1973-01-01T23:59:59.000Z

    A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

  19. Heat transfer in leading and trailing edge cooling channels of the gas turbine blade under high rotation numbers

    E-Print Network [OSTI]

    Liu, Yao-Hsien

    2009-05-15T23:59:59.000Z

    The gas turbine blade/vane internal cooling is achieved by circulating the compressed air through the cooling passages inside the turbine blade. Leading edge and trailing edge of the turbine blade are two critical regions which need to be properly...

  20. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  1. Sauget Plant Flare Gas Reduction Project

    E-Print Network [OSTI]

    Ratkowski, D. P.

    2007-01-01T23:59:59.000Z

    Empirical analysis of stack gas heating value allowed the Afton Chemical Corporation Sauget Plant to reduce natural gas flow to its process flares by about 50% while maintaining the EPA-required minimum heating value of the gas streams....

  2. Enhancing the use of coals by gas reburning-sorbent injection. Volume 3, Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x}, and SO{sub 2} from a wall fired unit. A GR-SI system was designed for Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The unit is rated at 117 MW(e) (net) and is front wall fired with a pulverized bituminous coal blend. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the ``as found`` baseline of 0.98 lb/MBtu (420 mg/MJ), and to reduce emissions of S0{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an S0{sub 2} limit Of 1.8 lb/MBtu (770 mg/MJ), the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. The design natural gas input corresponds to 18% of the total heat input. Burnout (overfire) air is injected at a higher elevation to burn out fuel combustible matter at a normal excess air level of 18%. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with S0{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  3. Sulfur Dioxide Treatment from Flue Gases Using a Biotrickling

    E-Print Network [OSTI]

    ), and several episodes in London (1). All fuels used by humans such as coal, oil, natural gas, peat, wood of absorbing sulfur dioxide either in water or in aqueous slurries

  4. Pilot-scale study of the effect of selective catalytic reduction catalyst on mercury speciation in Illinois and Powder River Basin coal combustion flue gases

    SciTech Connect (OSTI)

    Lee, C.W.; Srivastava, R.K.; Ghorishi, S.B.; Karwowski, J.; Hastings, T.H.; Hirschi, J.C. [US Environmental Protection Agency, Triangle Park, NC (United States)

    2006-05-15T23:59:59.000Z

    A study was conducted to investigate the effect of selective catalytic reduction (SCR) catalyst on mercury (Hg) speciation in bituminous and subbituminous coal combustion flue gases. Three different Illinois Basin bituminous coals (from high to low sulfur (S) and chlorine (Cl)) and one Powder River Basin (PRB) subbituminous coal with very low S and very low Cl were tested in a pilot-scale combustor equipped with an SCR reactor for controlling nitrogen oxides (NO{sub x}) emissions. The SCR catalyst induced high oxidation of elemental Hg (Hg{sup 0}), decreasing the percentage of Hg{sup 0} at the outlet of the SCR to values <12% for the three Illinois coal tests. The PRB coal test indicated a low oxidation of Hg{sup 0} by the SCR catalyst, with the percentage of Hg{sup 0} decreasing from {approximately} 96% at the inlet of the reactor to {approximately} 80% at the outlet. The low Cl content of the PRB coal and corresponding low level of available flue gas Cl species were believed to be responsible for low SCR Hg oxidation for this coal type. The test results indicated a strong effect of coal type on the extent of Hg oxidation. 16 refs., 4 figs., 3 tabs.

  5. Combined Heat and Power Plant Steam Turbine

    E-Print Network [OSTI]

    Rose, Michael R.

    Combined Heat and Power Plant Steam Turbine Steam Turbine Chiller Campus Heat Load Steam (recovered waste heat) Gas Turbine University Substation High Pressure Natural Gas Campus Electric Load Southern Generator Heat Recovery Alternative Uses: 1. Campus heating load 2. Steam turbine chiller to campus cooling

  6. Heat treatment furnace

    DOE Patents [OSTI]

    Seals, Roland D; Parrott, Jeffrey G; DeMint, Paul D; Finney, Kevin R; Blue, Charles T

    2014-10-21T23:59:59.000Z

    A furnace heats through both infrared radiation and convective air utilizing an infrared/purge gas design that enables improved temperature control to enable more uniform treatment of workpieces. The furnace utilizes lamps, the electrical end connections of which are located in an enclosure outside the furnace chamber, with the lamps extending into the furnace chamber through openings in the wall of the chamber. The enclosure is purged with gas, which gas flows from the enclosure into the furnace chamber via the openings in the wall of the chamber so that the gas flows above and around the lamps and is heated to form a convective mechanism in heating parts.

  7. Automotive Fuel Efficiency Improvement via Exhaust Gas Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Efficiency Improvement via Exhaust Gas Waste Heat Conversion to Electricity Automotive Fuel Efficiency Improvement via Exhaust Gas Waste Heat Conversion to Electricity Working...

  8. REGIONAL VARIATIONS IN THE DENSE GAS HEATING AND COOLING IN M51 FROM HERSCHEL FAR-INFRARED SPECTROSCOPY

    SciTech Connect (OSTI)

    Parkin, T. J.; Wilson, C. D.; Schirm, M. R. P.; Foyle, K. [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8S 4M1 (Canada); Baes, M.; De Looze, I. [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281 S9, B-9000 Gent (Belgium); Boquien, M.; Boselli, A. [Laboratoire d'Astrophysique de Marseille-LAM, Université d'Aix-Marseille and CNRS, UMR7326, 38 rue F. Joliot-Curie, F-13388 Marseille Cedex 13 (France); Cooray, A. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Cormier, D. [Institut für Theoretische Astrophysik, Zentrum für Astronomie der Universität Heidelberg, Albert-Ueberle Str. 2, D-69120 Heidelberg (Germany); Karczewski, O. ?. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Lebouteiller, V.; Madden, S. C.; Sauvage, M. [CEA, Laboratoire AIM, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Roussel, H. [Institut d'Astrophysique de Paris, UMR7095 CNRS, Université Pierre and Marie Curie, 98 bis Boulevard Arago, F-75014 Paris (France); Spinoglio, L., E-mail: parkintj@mcmaster.ca [Istituto di Astrofisica e Planetologia Spaziali, INAF-IAPS, Via Fosso del Cavaliere 100, I-00133 Roma (Italy)

    2013-10-20T23:59:59.000Z

    We present Herschel PACS and SPIRE spectroscopy of the most important far-infrared cooling lines in M51, [C II](158 ?m), [N II](122 and 205 ?m), [O I](63 and 145 ?m), and [O III](88 ?m). We compare the observed flux of these lines with the predicted flux from a photon-dominated region model to determine characteristics of the cold gas such as density, temperature, and the far-ultraviolet (FUV) radiation field, G{sub 0}, resolving details on physical scales of roughly 600 pc. We find an average [C II]/F{sub TIR} of 4 × 10{sup –3}, in agreement with previous studies of other galaxies. A pixel-by-pixel analysis of four distinct regions of M51 shows a radially decreasing trend in both the FUV radiation field, G{sub 0}, and the hydrogen density, n, peaking in the nucleus of the galaxy, and then falling off out to the arm and interarm regions. We see for the first time that the FUV flux and gas density are similar in the differing environments of the arm and interarm regions, suggesting that the inherent physical properties of the molecular clouds in both regions are essentially the same.

  9. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    all fuels including electricity and syngas will be used forGas Electricity Biomass Syngas Space Heating Coal Oil Gas

  10. MATERIALS AND MOLECULAR RESEARCH DIVISION. ANNUAL REPORT 1980

    E-Print Network [OSTI]

    Searcy, Alan W.

    2010-01-01T23:59:59.000Z

    the reaction in flue gas desulphurization processes. TIEimportance in flue gas desulphurization proc­ esses carried

  11. Water Heating Requirements – Overview Page 5-1 5. Water Heating Requirements 5.1 Overview 5

    E-Print Network [OSTI]

    unknown authors

    . Electric heat pump water heaters, however, are closer to the efficiency of typical gas systems, because

  12. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06T23:59:59.000Z

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  13. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Brent Constantz; Randy Seeker; Martin Devenney

    2010-06-30T23:59:59.000Z

    Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

  14. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  15. QUANTIFICATION OF MERCURY IN FLUE GAS EMISSION USING BORON-DOPED DIAMOND ELECTROCHEMISTRY

    SciTech Connect (OSTI)

    A. Manivannan; M.S. Seehra

    2003-08-19T23:59:59.000Z

    In this project, we have attempted to develop a new technique utilizing Boron-doped diamond (BDD) films to electrochemically detect mercury dissolved in solution via the initial deposition of metallic mercury, followed by anodic linear sweep voltammetry in the range from 10-10{sup -10} M to 10{sup -5} M. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques were employed. The extremely low background current for BDD electrodes compared to glassy carbon (GC) provides a strong advantage in trace metal detection. CV peak currents showed good linearity in the micromolar range. A detection level of 6.8 x 10{sup -10} M was achieved with DPV in 0.1 M KNO{sub 3} (pH = 1) for a deposition time of 20 minutes. Reproducible stripping peaks were obtained, even for the low concentration range. A comparison with GC shows that BDD is superior. Linear behavior was also obtained in the mercury concentration range from 10{sup -10} M to 10{sup -9} M.

  16. Performance history over 10 years of super duplex stainless steel in flue gas desulfurization

    SciTech Connect (OSTI)

    Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

    1996-08-01T23:59:59.000Z

    25 Cr duplex (austenitic/ferritic) stainless steel containing copper and nitrogen offers a cost effective solution to material selection for pollution control equipment. The properties of duplex stainless steel which make it suitable for this type of application are discussed and long term performance histories presented. It is concluded that high alloy duplex steel has an important role to play in the production of low maintenance reliable equipment for FGD and other pollution control systems.

  17. Fundamental mechanisms in flue gas conditioning. Quarterly report, April 1992--June 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.

    1992-07-27T23:59:59.000Z

    SEM pictures of the three mixtures of sorbent and ash from the DITF and the base line ESP hopper ash from Muskingum are shown in Figures 1 through 4. The effects of sorbent addition on particle morphology are evident in Figures 2 through 4 by the presence of irregularly shaped particles and deposits on the surfaces of the spherical fly ash particles. In contrast, the base Ene ash particles have the characteristic relatively smooth, spherical morphology normally associated with pulverized-coal (PC) fly ashes. Resistivity determinations made on these four ashes in ascending and descending temperature modes. These data are shown in Figures 5 and 6. Sorbent injection processes performed at the DITF lowered the duct temperature to around 165{degrees}F from about 350{degrees}F for base line operation. Consequently, during collection in the ESP, the particulate matter from the sorbent injection processes had a significantly lower resitivity (approximately 4 {times} 10{sup 7} {Omega}-cm) than the base line ash (approximately 3 {times} 10{sup 11} {Omega}-cm at 350{degrees}F). Specific surface areas and true particle densities have been measured for the four samples obtained from the DOE/PETC Duct Injection Test Facility. These data are summarized in Table 4. The primary difference indicated by these initial analyses of these four samples is the significant increase in specific surface area due to sorbent addition. The specific surface areas of the three sorbent and ash mixtures from the DITF are quite similar.

  18. Fundamental mechanisms in flue gas conditioning. Quarterly report, October 1992--December 1992

    SciTech Connect (OSTI)

    Snyder, T.R.; Bush, P.V.

    1993-01-20T23:59:59.000Z

    We performed a wide variety of laboratory analyses during the past quarter. As with most of the work we performed during the previous quarter, our recent efforts were primarily directed toward the determination of the effects of adsorbed water on the cohesivity and tensile strength of powders. We also continued our analyses of dust cake ashes that have had the soluble compounds leached from their particle surfaces by repeated washings with water. Our analyses of leached and unleached dust cake ashes continued to provide some interesting insights into effects that compounds adsorbed on surfaces of ash particles can have on bulk ash behavior. As suggested by our literature review, our data indicate that water adsorption depends on particle morphology and on surface chemistry. Our measurements of tensile strength show, that for many of the samples we have analyzed a relative minimum in tensile strength exists for samples conditioned and tested at about 30% relative humidity. In our examinations of the effects of water conditioning on sample cohesivity, we determined that in the absence of absorption of water into the interior of the particles, cohesivity usually increases sharply when environments having relative humidities above 75% are used to condition and test the samples. Plans are under way to condition selected samples with (NH{sub 4}){sub 2}SO{sub 4}, NH{sub 4}HSO{sub 4}, CaCl{sub 2}, organosiloxane, and SO{sub 3}. Pending approval, we will begin these conditioning experiments, and subsequent analyses of the conditioned samples.

  19. SOx-NOx-Rox Box Flue Gas Cleanup Demonstration: A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2000-12-15T23:59:59.000Z

    The SNRB{trademark} test program demonstrated the feasibility of controlling multiple emissions from a coal-fired boiler in a single processing unit. The degree of emissions removals for SO{sub 2}, NO{sub x}, and particulates all exceeded the project goals. A high degree of removal for HAPs was also achieved. The SNRB system offers low space requirements, control of multiple pollutants, and operating flexibility. The pneumatic SO{sub 2} sorbent and ammonia injection systems are expected to have high reliability because of their mechanical simplicity. Despite these advantages, the SNRB process may not be an economic choice for applications involving SO{sub 2} removals above about 85%. For lower levels of SO{sub 2} removal, the projected economics for SNRB appear to be more favorable than those of existing processes which involve separate units for the same degree of control for SO{sub 2}, NO{sub x} , and particulates. Specific findings are summarized as follows: (1) SO{sub 2} removal of 85-90% was achieved at a calcium utilization of 40-45%, representing a significant improvement in performance over other dry lime injection processes. (2) When firing 3-4% sulfur coal, compliance with the 1990 CAAA Phase I SO{sub 2} emissions limit of 2.5 lb/10{sup 6} Btu was achieved with a Ca/S molar ratio of less than 1.0. For the Phase II SO{sub 2} emissions limit of 1.2 lb/10{sup 6} Btu, compliance was achieved with a Ca/S molar ratio as low as 1.5. Phase II compliance is the more relevant emissions limit. (3) When using NaHCO{sub 3} as the sorbent, the Phase II SO{sub 2} emissions limit was achieved at a Na{sub 2}/S molar ratio of less than 2.0 (NSR < 1.0). (4) Compliance with the Phase I NO{sub x} emissions limit of 0.45 lb/10{sup 6} Btu for Group 1 boilers was achieved at an NH{sub 3}/NO{sub x} ratio of 0.85, with an ammonia slip of 5 ppm or less. (5) Particulate collection efficiency averaged 99.9%, corresponding to an average emissions rate of 0.018 lb/10{sup 6} Btu. This is significantly lower than the NSPS value of 0.03 lb/10{sup 6} Btu. The high-temperature baghouse design incorporating an SCR catalyst for NO{sub x} reduction was demonstrated successfully. The technology is ready for commercial application. The key feature of the technology is control of SO{sub 2}, NO{sub x}, and particulates in a single process unit. However, this limits its commercial market to applications requiring control of all three components. Also, although the testing demonstrated greater than 90% SO{sub 2} capture, this was achieved at high sorbent/sulfur ratios. For applications requiring a high percentage of sulfur removal, a modern conventional FGD unit with LNBs for NO{sub x} control may be the preferred option.

  20. The utilization of flue gas desulfurization waste by-products in construction brick 

    E-Print Network [OSTI]

    Berryman, Charles Wayne

    1992-01-01T23:59:59.000Z

    Unconfined Compressive Strength and Density Comparisons of Gypsum Hemihydrate with Various Inductions of Fly Ash 16 Unconfined Compressive Strength and Density Comparisons Using Various Types of Bottom Ashes 18 Optimum Temperature to Calcine Dihydrate... Gypsum to Hemihydrate Gypsum 21 Optimum Time to Calcine Dihydrate to Hemihydrate 22 Unconfined Compressive Strength and Density Comparisons for Hemihydrate Subjected to Various Size Sieves 25 Temperature of Hemihydrate during Hydration versus Time...

  1. The utilization of flue gas desulfurization waste by-products in construction brick

    E-Print Network [OSTI]

    Berryman, Charles Wayne

    1992-01-01T23:59:59.000Z

    APPENDIX D. TEST PROCEDURES APPENDIX E. CONVERSION TABLES VITA 85 90 93 96 99 LIST OF FIGURES Figure Page Model for FGD Waste By-Product Research Unconfined Compressive Strength for Fly Ash Mixed with Various Inductions of Portland Cement 15... properties such as weight, durability, strength, density, etc. Varying mixes of bottom ash, fly ash, portland cement, and sand will be tested for possible enhancement of the hemihydrate. Also, a mix design that best utilizes all the waste by...

  2. pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, ,Development of NovelHigh( ( ( ( ( ( ( ( ( ( ( ( (

  3. DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 Clean Energy5655994DP-1513 . Di

  4. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 CleanFOR IMMEDIATE RELEASENovel CO 2

  5. Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C lKieling ,Catalysis ScienceTheAdvanced

  6. Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Become agovEducationWelcome to StudyFuel

  7. Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries BatteriesCAESMissionMetal-Organic Framework

  8. Heat-Of-Reaction Chemical Heat Pumps--Possible Configurations

    E-Print Network [OSTI]

    Kirol, L. D.

    for water and gas connections, and temperature variations. Recent work on heat pump cycles using complex compound reactions includes development of energy storage systems at laboratories in Europe (11) and the United States (12), and residential...ABSTRACT Chemical heat pumps utilize working fluids which undergo reversible chemical changes. Mechanically driven reactive heat pump cycles or, alternatively, hl~a: driven heat pumps in which either heat engine or heat pump working fluid...

  9. Thulium-170 heat source

    DOE Patents [OSTI]

    Walter, Carl E. (Pleasanton, CA); Van Konynenburg, Richard (Livermore, CA); VanSant, James H. (Tracy, CA)

    1992-01-01T23:59:59.000Z

    An isotopic heat source is formed using stacks of thin individual layers of a refractory isotopic fuel, preferably thulium oxide, alternating with layers of a low atomic weight diluent, preferably graphite. The graphite serves several functions: to act as a moderator during neutron irradiation, to minimize bremsstrahlung radiation, and to facilitate heat transfer. The fuel stacks are inserted into a heat block, which is encased in a sealed, insulated and shielded structural container. Heat pipes are inserted in the heat block and contain a working fluid. The heat pipe working fluid transfers heat from the heat block to a heat exchanger for power conversion. Single phase gas pressure controls the flow of the working fluid for maximum heat exchange and to provide passive cooling.

  10. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    E-Print Network [OSTI]

    Akbari, Hashem

    2011-01-01T23:59:59.000Z

    49 Figure 26. Comparison of roof heat flux for East and West49 Figure 27. Roof heat flux vs. outside air temperature for8-19. 50 Figure 28. Roof heat flux vs. outside air

  11. Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Bai, T.; Yeboah, Y.D.; Sampath, R.

    1995-10-01T23:59:59.000Z

    The objective of this investigation is to characterize the operation of fan powered infrared burner (PIR) at various gas compositions and ambient conditions and develop design guidelines for appliances in containing PIR burners for satisfactory performance. During this period, experimental setup with optical and electronic instrumentation that is necessary for measuring the radiant heat output and the emission gas output of the burner has been established. The radiation measurement instrument, an FTIR, has been purchased and installed in the porous burner experimental system. The radiation measurement capability of the FTIR was tested and found to be satisfactory. A standard blackbody source, made by Graseby Infrared, was employed to calibrate the FTIR. A collection duct for emission gas measurement was fabricated and connected to the existing Horiba gas analyzer. Test runs are being conducted for flue gas analysis. A number of published research papers on modeling of porous burners were reviewed. The physical mechanism and theoretical analysis of the combustion process of the PIR burner was formulated. The numerical modeling, and implementation of a PIR burner code at CAU`s computing facility is in progress.

  12. High-accuracy P-p-T measurements of pure gas and natural gas like mixtures using a compact magnetic suspension densimeter

    E-Print Network [OSTI]

    Ejaz, Saquib

    2007-09-17T23:59:59.000Z

    into syngas, i.e. carbon monoxide and hydrogen. The syngas, after cleaned of particles, mercury and sulfur, is combusted and the resulting hot, pressurized flue gas expands through a gas turbine thus producing power in an open gas turbine (Brayton) cycle...). The indirect route involves the production of syngas. Syngas can be produced by steam reforming or partial oxidative reaction of methane, which finally is converted to higher hydrocarbons by a Fischer- Tropsch (FT) process. The need for air separation...

  13. PERFORMANCE OF A STIRLING ENGINE POWERED HEAT ACTIVATED HEAT PUMP

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    PERFORMANCE OF A STIRLING ENGINE POWERED HEAT ACTIVATED HEAT PUMP W. D. C. Richards and W. L. Auxer) which employs a natural gas fired Stirling engine to drive a Rankine cycle vapor compressor is presently by the heat pump effect. The Stirling engine/Rankine cycle refrigeration loop heat pump being developed would

  14. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    fired natural gas chillers, waste heat or solar heat; • hot-with HX can utilize waste heat for heating or coolingto utilize all the waste heat just reduces overall energy

  15. Solar Water Heating Incentive Program

    Broader source: Energy.gov [DOE]

    Beginning in the fall of 2003, Energy Trust of Oregon's Solar Water Heating (SWH) Incentive Program offers incentives to customers of Pacific Power, PGE, NW Natural Gas and Cascade Natural Gas who...

  16. Carbon dioxide capture from power or process plant gases

    SciTech Connect (OSTI)

    Bearden, Mark D; Humble, Paul H

    2014-06-10T23:59:59.000Z

    The present invention are methods for removing preselected substances from a mixed flue gas stream characterized by cooling said mixed flue gas by direct contact with a quench liquid to condense at least one preselected substance and form a cooled flue gas without substantial ice formation on a heat exchanger. After cooling additional process methods utilizing a cryogenic approach and physical concentration and separation or pressurization and sorbent capture may be utilized to selectively remove these materials from the mixed flue gas resulting in a clean flue gas.

  17. acute nitrogen dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas,...

  18. Key Technology Poster Number Performer Project Title Presenter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multi-Phase Turbo-Expander Vitali Lissianski 24 Gas Technology Institute Simultaneous Waste Heat and Water Recovery from Power Plant Flue Gases for Advanced Energy System Dexin...

  19. Advanced fuel gas desulfurization (AFGD) demonstration project. Technical progress report No. 19, July 1, 1994--September 30, 1994

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    The {open_quotes}Advanced Flue Gas Desulfurization (AFGD) Demonstration Project{close_quotes} is a $150.5 million cooperative effort between the U.S. Department of Energy and Pure Air, a general partnership of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc. The AFGD process is one of several alternatives to conventional flue gas desulfurization (FGD) being demonstrated under the Department of Energy`s Clean Coal Technology Demonstration Program. The AFGD demonstration project is located at the Northern Indiana Public Service Company`s Bailly Generating Station, about 12 miles northeast of Gary, Indiana.

  20. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    SciTech Connect (OSTI)

    Akbari, Hashem; Xu, Tengfang; Taha, Haider; Wray, Craig; Sathaye, Jayant; Garg, Vishal; Tetali, Surekha; Babu, M. Hari; Reddy, K. Niranjan

    2011-05-25T23:59:59.000Z

    Cool roofs, cool pavements, and urban vegetation reduce energy use in buildings, lower local air pollutant concentrations, and decrease greenhouse gas emissions from urban areas. This report summarizes the results of a detailed monitoring project in India and related simulations of meteorology and air quality in three developing countries. The field results quantified direct energy savings from installation of cool roofs on individual commercial buildings. The measured annual energy savings potential from roof-whitening of previously black roofs ranged from 20-22 kWh/m2 of roof area, corresponding to an air-conditioning energy use reduction of 14-26% in commercial buildings. The study estimated that typical annual savings of 13-14 kWh/m2 of roof area could be achieved by applying white coating to uncoated concrete roofs on commercial buildings in the Metropolitan Hyderabad region, corresponding to cooling energy savings of 10-19%. With the assumption of an annual increase of 100,000 square meters of new roof construction for the next 10 years in the Metropolitan Hyderabad region, the annual cooling energy savings due to whitening concrete roof would be 13-14 GWh of electricity in year ten alone, with cumulative 10-year cooling energy savings of 73-79 GWh for the region. The estimated savings for the entire country would be at least 10 times the savings in Hyderabad, i.e., more than 730-790 GWh. We estimated that annual direct CO2 reduction associated with reduced energy use would be 11-12 kg CO2/m2 of flat concrete roof area whitened, and the cumulative 10-year CO2 reduction would be approximately 0.60-0.65 million tons in India. With the price of electricity estimated at seven Rupees per kWh, the annual electricity savings on air-conditioning would be approximately 93-101 Rupees per m2 of roof. This would translate into annual national savings of approximately one billion Rupees in year ten, and cumulative 10-year savings of over five billion Rupees for cooling energy in India. Meteorological simulations in this study indicated that a reduction of 2C in air temperature in the Hyderabad area would be likely if a combination of increased surface albedo and vegetative cover are used as urban heat-island control strategies. In addition, air-temperature reductions on the order of 2.5-3.5C could be achieved if moderate and aggressive heat-island mitigation measures are adopted, respectively. A large-scale deployment of mitigation measures can bring additional indirect benefit to the urban area. For example, cooling outside air can improve the efficiency of cooling systems, reduce smog and greenhouse gas (GHG) emissions, and indirectly reduce pollution from power plants - all improving environmental health quality. This study has demonstrated the effectiveness of cool-roof technology as one of the urban heat-island control strategies for the Indian industrial and scientific communities and has provided an estimate of the national energy savings potential of cool roofs in India. These outcomes can be used for developing cool-roof building standards and related policies in India. Additional field studies, built upon the successes and lessons learned from this project, may be helpful to further confirm the scale of potential energy savings from the application of cooler roofs in various regions of India. In the future, a more rigorous meteorological simulation using urbanized (meso-urban) meteorological models should be conducted, which may produce a more accurate estimate of the air-temperature reductions for the entire urban area.