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Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
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1

Fundamental mechanisms in flue-gas conditioning  

SciTech Connect (OSTI)

The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

1992-01-09T23:59:59.000Z

2

Flue gas conditioning for improved particle collection in electrostatic precipitators  

SciTech Connect (OSTI)

The purpose of this research program is to identify and evaluate a variety of additives capable of increasing particle cohesion which could be used for improving collection efficiency in an ESP. A three-phase screening process will be used to provide the, evaluation of many additives in a logical and cost-effective manner. The three step approach involves the following experimental setups: 1. Provide a preliminary screening in the laboratory by measuring the effects of various conditioning agents on reentrainment of flyash particles in an electric field operating at simulated flue gas conditions. 2. Evaluate the successful additives using a 100 acfm bench-scale ESP operating on actual flue gas. 3. Obtain the data required for scaling up the technology by testing the two or three most promising conditioning agents at the pilot scale.

Durham, M.D.

1992-04-27T23:59:59.000Z

3

Flue gas conditioning for improved particle collection in electrostatic precipitators. Quarterly technical report  

SciTech Connect (OSTI)

The purpose of this research program is to identify and evaluate a variety of additives capable of increasing particle cohesion which could be used for improving collection efficiency in an ESP. A three-phase screening process will be used to provide the, evaluation of many additives in a logical and cost-effective manner. The three step approach involves the following experimental setups: 1. Provide a preliminary screening in the laboratory by measuring the effects of various conditioning agents on reentrainment of flyash particles in an electric field operating at simulated flue gas conditions. 2. Evaluate the successful additives using a 100 acfm bench-scale ESP operating on actual flue gas. 3. Obtain the data required for scaling up the technology by testing the two or three most promising conditioning agents at the pilot scale.

Durham, M.D.

1992-04-27T23:59:59.000Z

4

Recovery of Water from Boiler Flue Gas  

SciTech Connect (OSTI)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

2008-09-30T23:59:59.000Z

5

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

Kenneth E. Baldrey

2003-01-01T23:59:59.000Z

6

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-05-01T23:59:59.000Z

7

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was completed at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. The product was effective as a flue gas conditioner. However, ongoing problems with in-duct deposition resulting from the flue gas conditioning were not entirely resolved. Primarily these problems were the result of difficulties encountered with retrofit of an existing spray humidification system. Eventually it proved necessary to replace all of the original injection lances and to manually bypass the PLC-based air/liquid feed control. This yielded substantial improvement in spray atomization and system reliability. However, the plant opted not to install a permanent system. Also in this quarter, preparations continued for a test of the cohesivity additives at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-07-01T23:59:59.000Z

8

Integrated flue gas processing method  

SciTech Connect (OSTI)

A system and process for flue gas processing to remove both gaseous contaminants such as sulfur dioxide and particulate matter such as flyash integrates spray scrubbing apparatus and wet electrostatic precipitation apparatus and provides for the advantageous extraction and utilization of heat present in the flue gas which is being processed. The integrated system and process utilizes a spray scrubbing tower into which the flue gas is introduced and into which aqueous alkali slurry is introduced as spray for sulfur dioxide removal therein. The flue gas leaves the tower moisture laden and enters a wet electrostatic precipitator which includes a heat exchanger where flyash and entrained droplets in the flue gas are removed by electrostatic precipitation and heat is removed from the flue gas. The cleaned flue gas exits from the precipitator and discharges into a stack. The heat removed from the flue gas finds use in the system or otherwise in the steam generation plant. The wet electrostatic precipitator of the integrated system and process includes a portion constructed as a cross flow heat exchanger with flue gas saturated with water vapor moving vertically upwards inside tubes arranged in a staggered pattern and ambient air being pulled horizontally across the outside of those tubes to cool the tube walls and thereby remove heat from the flue gas and cause condensation of water vapor on the inside wall surfaces. The condensate washes the electrostatically collected flyash particles down from the inside tube walls. The heat that is extracted from the saturated flue gas in the wet electrostatic precipitator heat exchanger may be utilized in several different ways, including: (1) for flue gas reheat after the wet electrostatic precipitator; (2) for preheating of combustion air to the steam generator boiler; and, (3) for heating of buildings.

Bakke, E.; Willett, H.P.

1982-12-21T23:59:59.000Z

9

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

Kenneth E. Baldrey

2002-01-01T23:59:59.000Z

10

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

Kenneth E. Baldrey

2003-07-30T23:59:59.000Z

11

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, two cohesivity-specific additive formulations, ADA-44C and ADA-51, were evaluated in a full-scale trial at the American Electric Power Conesville plant. Ammonia conditioning was also evaluated for comparison. ADA-51 and ammonia conditioning significantly reduced rapping and non-rapped particulate re-entrainment based on stack opacity monitor data. Based on the successful tests to date, ADA-51 will be evaluated in a long-term test.

Kenneth E. Baldrey

2003-02-01T23:59:59.000Z

12

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

Kenneth E. Baldrey

2001-09-01T23:59:59.000Z

13

Mercury sorbent delivery system for flue gas  

DOE Patents [OSTI]

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Klunder; ,Edgar B. (Bethel Park, PA)

2009-02-24T23:59:59.000Z

14

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

C. Jean Bustard

2003-12-01T23:59:59.000Z

15

Flue gas desulfurization  

DOE Patents [OSTI]

A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

Im, Kwan H. (Lisle, IL); Ahluwalia, Rajesh K. (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

16

Flue gas desulfurization  

DOE Patents [OSTI]

The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

Im, K.H.; Ahluwalia, R.K.

1984-05-01T23:59:59.000Z

17

Final Flue Gas Cleaning (FFGC)  

E-Print Network [OSTI]

the surrounding area but can also be carried thousands of miles by trade winds before falling to ground level to pollute soil, vegetation and water resources. An obvious question is: why doesn’t industry cool the flue gas; condense out the pollutants... of handling and disposing of these pollutants at the plant site. 2. Oxides of sulfur and nitrogen can condense out as an acid, including carbonic acid that attacks materials of construction. By keeping temperatures elevated, carbon steel construction can...

Stinger, D. H.; Romero, M. H.

2006-01-01T23:59:59.000Z

18

Fundamental mechanisms in flue-gas conditioning. Topical report No. 1, Literature review and assembly of theories on the interactions of ash and FGD sorbents  

SciTech Connect (OSTI)

The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

1992-01-09T23:59:59.000Z

19

natural gas+ condensing flue gas heat recovery+ water creation...  

Open Energy Info (EERE)

natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

20

Flue gas conditioning for improved particle collection in electrostatic precipitators. Quarterly technical report, October 1--December 31, 1993  

SciTech Connect (OSTI)

The initial pilot-scale testing of two additives was completed at CONSOL`s research coal combustor. The results and conclusions from this test series and subsequent analysis of the data are presented in this report. Table 1 summarizes the conditions tested. During the tests, the research combustor was firing a medium-sulfur coal. The combustor had recently been retrofitted with low-NOx burners for a DOE Clean Coal test program. Operation of the low-NOx burners required a reduced flow rate in the combustor, resulting in lower flow and velocity in the ESP. A comprehensive baseline condition was tested, followed by initial screening runs for several additives. It was discovered that the flyash exhibited properties characteristic of a high-resistivity ash. In-situ measurements at the ESP inlet confirmed that the resistivity was in the 10{sup 10} -- 10{sup 12} ohm-cm range. In addition, the ESP plate rappers were not able to remove ash buildup on the first section during normal operation. Power off rapping was periodically required to fully clean the plates; this is a clear indication of high-resistivity conditions. Since the major benefit of ESP additives will be to reduce reentrainment at low to midrange resistivity, this operating condition was undesirable for performance testing. It was decided to continue the program with SO{sub 3} conditioning of the flue gas to reduce particle resistivity. It was also decided to operate with two rather than three electrical fields energized. By reducing the ESP collection area, it was hoped that it would be easier to measure changes in ESP performance and to see an immediate indication of the effectiveness Of SO{sub 3} conditioning. The ESP was reconfigured with two electrical sections energized and SO{sub 3} conditioning at a rate of approximately 20 ppM. An additional baseline was run, followed by extended tests with two additives referred to in this report as Additive ``C`` and Additive ``D.``

Durham, M.D.; Baldrey, K.E.

1994-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Construction and testing of a flue-gas corrosion probe  

SciTech Connect (OSTI)

The selection of suitable materials for industrial, waste-heat- recovery systems requires assessment of corrosion of materials in various flue-gas environments. Such assessments involve exposing candidate materials to high-temperature flue gases and analyzing the effects of the exposure conditions. Because corrosion is related to flue-gas chemical composition and temperature, variations in temperature complicate the determination of corrosion rates and corrosion mechanisms. Conversely, a relatively constant temperature allows a more accurate determination of the effects of exposure conditions. For this reason, controlled-temperature flue-gas corrosion probes were constructed and tested for exposure tests of materials. A prototype probe consisted of a silicon carbide tube specimen, supporting hardware, and instrumentation for controlling temperature by internal heating and cooling. An advanced probe included other tubular specimens. Testing of the probes in an industrial-type furnace at a nominal flue-gas temperature of 1200{degree}C revealed that temperature control was inadequate. The cooling mode imposed a substantial axial-temperature gradient on the specimens; while the heating mode imposed a smaller gradient, the heating capacity was very limited. 10 refs., 10 figs., 2 tabs.

Federer, J.I.; McEvers, J.A.

1990-08-01T23:59:59.000Z

22

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-09-29T23:59:59.000Z

23

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-08-18T23:59:59.000Z

24

Control of scale in flue gas scrubbers  

SciTech Connect (OSTI)

This patent describes a flue gas desulfurization system in which sulfur dioxide-containing flue gas is passed in countercurrent flow with an aqueous calcium-bearing scrubbing liquor whereby the sulfur dioxide is removed from the flue gas by being absorbed by the scrubbing liquor and converted to calcium sulfite and/or calcium sulfate. The improvement of minimizing the formation of calcium scale on the surfaces of the system comprises maintaining in the scrubbing liquor about 0.1-25 ppm of a 1:1 diisobutylene-maleic anhydride copolymer having an average molecular weight of 11000. The copolymer is incorporated in the scrubbing liquor as a 10-15% aqueous dispersion.

Thomas, P.A.; Dewitt-Dick, D.B.

1987-06-02T23:59:59.000Z

25

Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas  

SciTech Connect (OSTI)

The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

Dexin Wang

2012-03-31T23:59:59.000Z

26

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

Under the Cooperative Agreement with DOE, Bechtel and Pennsylvania Electric Company (Penelec) will jointly demonstrate Bechtel's confined zone dispersion (CZD) process for removing both sulfur and nitrogen pollutants from the flue gases leaving a coal-fired boiler. Demonstration testing of the CZD process will be conducted on the 147 MWe coal-fired generating Seward Station Unit 15 of Penelec. The test will utilize one-half of the existing flue gas capacity, and will be designed to demonstrate the viability of the process and its operability at a total cost of less than $300/ton of SO{sub 2} removed. The CZD process involves injecting a finely atomized slurry of reactive lime into the duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. 2 figs.

Not Available

1991-02-22T23:59:59.000Z

27

Cement Kiln Flue Gas Recovery Scrubber Project  

SciTech Connect (OSTI)

The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

National Energy Technology Laboratory

2001-11-30T23:59:59.000Z

28

Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction  

SciTech Connect (OSTI)

Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

2009-01-15T23:59:59.000Z

29

Noble metal catalysts for oxidation of mercury in flue gas  

SciTech Connect (OSTI)

The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

Presto, A.A.; Granite, E.J.

2008-04-01T23:59:59.000Z

30

Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs  

E-Print Network [OSTI]

, corefloods were conducted at 1,500 psig and 70??C, in which flue gas was injected into an Austin chalk core containing initially methane. Two types of flue gases were injected: dehydrated flue gas with 13.574 mole% CO2 (Gas A), and treated flue gas (N2, O2...

Nogueira de Mago, Marjorie Carolina

2005-11-01T23:59:59.000Z

31

Flue gas desulfurization/denitrification using metal-chelate additives  

DOE Patents [OSTI]

A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

1985-08-05T23:59:59.000Z

32

Flue gas injection control of silica in cooling towers.  

SciTech Connect (OSTI)

Injection of CO{sub 2}-laden flue gas can decrease the potential for silica and calcite scale formation in cooling tower blowdown by lowering solution pH to decrease equilibrium calcite solubility and kinetic rates of silica polymerization. Flue gas injection might best inhibit scale formation in power plant cooling towers that use impaired makeup waters - for example, groundwaters that contain relatively high levels of calcium, alkalinity, and silica. Groundwaters brought to the surface for cooling will degas CO{sub 2} and increase their pH by 1-2 units, possibly precipitating calcite in the process. Recarbonation with flue gas can lower the pHs of these fluids back to roughly their initial pH. Flue gas carbonation probably cannot lower pHs to much below pH 6 because the pHs of impaired waters, once outgassed at the surface, are likely to be relatively alkaline. Silica polymerization to form scale occurs most rapidly at pH {approx} 8.3 at 25 C; polymerization is slower at higher and lower pH. pH 7 fluids containing {approx}220 ppm SiO{sub 2} require > 180 hours equilibration to begin forming scale whereas at pH 8.3 scale formation is complete within 36 hours. Flue gas injection that lowers pHs to {approx} 7 should allow substantially higher concentration factors. Periodic cycling to lower recoveries - hence lower silica concentrations - might be required though. Higher concentration factors enabled by flue gas injection should decrease concentrate volumes and disposal costs by roughly half.

Brady, Patrick Vane; Anderson, Howard L., Jr.; Altman, Susan Jeanne

2011-06-01T23:59:59.000Z

33

Evaluation of the Energy Saving Potential from Flue Gas Pressurization  

E-Print Network [OSTI]

details the impact of providing a can be recovered at .1 inch wc. The work of com 500 r----------------------, FLUE GAS TEMPERATURES 200 COUNTER FLOW 100 50 _~,,_ CO-FLOW RECUPERATORS 20 10 SPECIFIC ENERGY, Btu/IbM AIR rl'-h~A:--WORK OF 5... consideration for a convective heat flue gas is entrained, the two are mixed in a exchanger is l600?F for the convective portion of the mixing section, and pressure is then recovered in recuperation equipment. It is significant that for a a diffuser...

Stanton, E. H.

1980-01-01T23:59:59.000Z

34

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

2005-07-01T23:59:59.000Z

35

Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents  

SciTech Connect (OSTI)

Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

2007-06-30T23:59:59.000Z

36

Direct fired absorption machine flue gas recuperator  

DOE Patents [OSTI]

A recuperator which recovers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine. The recuperator includes a housing with liquid flowing therethrough, the liquid being in direct contact with the combustion gas for increasing the effectiveness of the heat transfer between the gas and the liquid.

Reimann, Robert C. (Lafayette, NY); Root, Richard A. (Spokane, WA)

1985-01-01T23:59:59.000Z

37

Biomimetic Membrane for CO2 Capture from Flue Gas  

SciTech Connect (OSTI)

These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer model that supports prediction of heat transfer profiles for larger permeators Tasks 3. 4.1, 4.2--Temperature Range of Enzymes--The goal was to determine if the enzyme operating temperature would limit the range of thermal conditions available to the capture system. We demonstrated the ability of various isozymes (enzyme variants) to operate from 4-85 C. Consequently, the operating characteristics of the enzyme are not a controlling factor. Further, any isozyme whose upper temperature bound is at least 10 C greater than that of the planned inlet temperature will be stable under unanticipated, uncontrolled 'hiccups' in power plant operation. Task 4.4, 4.4--Examination of the Effects of SOx and NOx on Enzyme Activity (Development of Flue Gas Composition Acceptance Standards)--The purpose was to define the inlet gas profile boundaries. We examined the potential adverse effects of flue gas constituents including different acids from to develop an acceptance standard and compared these values to actual PC flue gas composition. Potential issues include changes in pH, accumulation of specific inhibitory anions and cations. A model was developed and validated by test with a SO{sub 2}-laden stream. The predicted and actual data very largely coincided. The model predicted feed stream requirements to allow continuous operation in excess of 2500 hours. We developed operational (physical and chemical) strategies to avoid or ameliorate these effects. Avoidance, the preferred strategy (noted above), is accomplished by more extensive cleanup of the flue gas stream. Task 5--Process Engineering Model--We developed a process-engineering model for two purposes. The first was to predict the physical and chemical status at each test point in the design as a basis for scale-up. The second was to model the capital and operating cost of the apparatus. These were accomplished and used to predict capex, opex and cost of energy. Task 6--Preliminary Commercialization Plan--We carried out analyses of the market and the competition by a variety of parameters. The conclusion was that there is a l

Michael C. Trachtenberg

2007-05-31T23:59:59.000Z

38

Analysis of Halogen-Mercury Reactions in Flue Gas  

SciTech Connect (OSTI)

Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

2010-01-01T23:59:59.000Z

39

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

2006-09-30T23:59:59.000Z

40

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport reactor systems is planned to demonstrate the feasibility of this process in large scale operations to separate carbon dioxide from flue gas.

David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

2001-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between January 1, 2006, and March 31, 2006, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. An integrated system composed of a downflow co-current contact absorber and two hollow screw conveyors (regenerator and cooler) was assembled, instrumented, debugged, and calibrated. A new batch of supported sorbent containing 15% sodium carbonate was prepared and subjected to surface area and compact bulk density determination.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Raghubir P. Gupta

2006-03-31T23:59:59.000Z

42

Alternative formulations of regenerable flue gas cleanup catalysts  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-01-01T23:59:59.000Z

43

Thief process for the removal of mercury from flue gas  

DOE Patents [OSTI]

A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

2003-02-18T23:59:59.000Z

44

Water Extraction from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

2006-06-30T23:59:59.000Z

45

E-Print Network 3.0 - advanced flue gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(WTERT) Collection: Renewable Energy 5 INNOVATIVE TECHNOLOGY FOR THE CONTROL OF AIR POLLUTION AT WASTE-TO-ENERGY Summary: -Beam process is applied to flue gas compositions...

46

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

47

MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS  

SciTech Connect (OSTI)

The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

2009-03-31T23:59:59.000Z

48

Fundamentals of Mercury Oxidation in Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

2005-08-01T23:59:59.000Z

49

Flue gas desulfurization gypsum and fly ash  

SciTech Connect (OSTI)

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

Not Available

1992-05-01T23:59:59.000Z

50

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between October 1, 2005, and December 31, 2005, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from flue gas from coal combustion. A field test was conducted to examine the extent to which RTI's supported sorbent can be regenerated in a heated, hollow screw conveyor. This field test was conducted at the facilities of a screw conveyor manufacturer. The sorbent was essentially completely regenerated during this test, as confirmed by thermal desorption and mass spectroscopy analysis of the regenerated sorbent. Little or no sorbent attrition was observed during 24 passes through the heated screw conveyor system. Three downflow contactor absorption tests were conducted using calcined sodium bicarbonate as the absorbent. Maximum carbon dioxide removals of 57 and 91% from simulated flue gas were observed at near ambient temperatures with water-saturated gas. These tests demonstrated that calcined sodium carbonate is not as effective at removing CO{sub 2} as are supported sorbents containing 10 to 15% sodium carbonate. Delivery of the hollow screw conveyor for the laboratory-scale sorbent regeneration system was delayed; however, construction of other components of this system continued during the quarter.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Andreas Weber; Raghubir P. Gupta

2006-01-01T23:59:59.000Z

51

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO[sub 2] and NO[sub x] Reduction - Preliminary confirmation of 50% SO[sub 2] reduction has been achieved, but the NO[sub x] reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO[sub 2] reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO[sub 2] Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel's original cost estimates (capital and operating) were prepared. Therefore, SO[sub 2] removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

52

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers  

SciTech Connect (OSTI)

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

Edward Levy; Harun Bilirgen; John DuPoint

2011-03-31T23:59:59.000Z

53

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers  

SciTech Connect (OSTI)

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

Levy, Edward; Bilirgen, Harun; DuPont, John

2011-03-31T23:59:59.000Z

54

Characterization of flue gas residues from municipal solid waste combustors  

SciTech Connect (OSTI)

Solid residues recovered from treatment of flue gas resulting from the combustion of municipal solid waste (MSW) are of particular concern because of ever-increasing worldwide production rates and their concentrations of potentially hazardous transition elements and heavy metals. Three main residue types have been studied in this study: electrostatic precipitator ashes, wet filter cakes, and semidry scrubber residues. Using a large number of residues from two French MSW combustion (MSWC) facilities, the aim of this work is to determine their chemistry and mineralogy in order to shed light on their potential toxicity. The authors find that pollutant concentrations are dependent not only on the composition of MSW but also on the size of particles and flue gas treatment process. Using a procedure based on leaching, grain-size, density, and magnetic separations, the authors present a detailed description of the mineralogy of MSWC solid residues. These residues consist of a very heterogeneous assemblage of glasses, metals, and other crystals in which polluting elements are distributed. The results of this characterization will therefore help to contribute to the development of adequate waste management strategies.

Forestier, L.L. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [ENSG, Vandoeuvre-les-Nancy (France); Libourel, G. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [Univ. H. Poincare, Vandoeuvre-les-Nancy (France)

1998-08-01T23:59:59.000Z

55

Dry flue gas desulfurization process for various coals  

SciTech Connect (OSTI)

Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coal-fired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone. Calcium-based wet systems have, in general, satisfied SO/sub 2/ removal requirements; however, reliability of the early systems was affected by some operational problems. Additionally, sludge dewatering and disposal equipment results in overall system complexity. A dry FGD process which minimizes these problems was developed in late 1970's. It incorporates a spray drying concept for removal of SO/sub 2/ by reaction with lime slurry or soda ash solution. The spray dryer absorber is followed by an electrostatic precipitator or a fabric filter where particulates are collected. The waste product, which is a mixture of FGD reaction products, unreacted reagent and fly ash, is dry thus eliminating the need for dewatering equipment.

Widico, M.J.; Dhargalkar, P.H.

1985-01-01T23:59:59.000Z

56

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

Four grades of sodium bicarbonate and two grades of trona were characterized in terms of particle size distribution, surface area, pore size distribution, and attrition. Surface area and pore size distribution determinations were conducted after calcination of the materials. The sorbent materials were subjected to thermogravimetric testing to determine comparative rates and extent of calcination (in inert gas) and sorption (in a simulated coal combustion flue gas mixture). Selected materials were exposed to five calcination/sorption cycles and showed no decrease in either sorption capacity or sorption rate. Process simulations were conducted involving different heat recovery schemes. The process is thermodynamically feasible. The sodium-based materials appear to have suitable physical properties for use as regenerable sorbents and, based on thermogravimetric testing, are likely to have sorption and calcination rates that are rapid enough to be of interest in full-scale carbon sequestration processes.

David A. Green; Brian S. Turk; Raghubir Gupta; Alejandro Lopez-Ortiz

2001-01-01T23:59:59.000Z

57

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

58

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

2001-05-01T23:59:59.000Z

59

Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps  

DOE Patents [OSTI]

A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

2012-08-21T23:59:59.000Z

60

Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas  

SciTech Connect (OSTI)

An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Desulfurization of flue gas by the confined zone dispersion process  

SciTech Connect (OSTI)

This Confined Zone Dispersion (CZD) process involves injecting a finely atomized slurry of reactive lime into the ductwork of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. The purpose of this project was to prove the CZD process concept by testing it on a limited scale, and then demonstrating the process on a large scale. The scope of work included projecting the cost of commercial implementation. The test facility for the proof-of-concept tests was on a scale equivalent to a 7 MWe generating plant. The large-scale demonstration was made on a scale of 70 MWe. This report describes how data from the two test sites were correlated, and presents conceptual designs for two full-scale retrofit installations. The rationale and data supporting the conclusions are also given in Part 4.

Not Available

1989-10-01T23:59:59.000Z

62

Multi-component removal in flue gas by aqua ammonia  

DOE Patents [OSTI]

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

2007-08-14T23:59:59.000Z

63

Flue gas desulfurization : cost and functional analysis of large-scale and proven plants  

E-Print Network [OSTI]

Flue Gas Desulfurization is a method of controlling the emission of sulfurs, which causes the acid rain. The following study is based on 26 utilities which burn coal, have a generating capacity of at least 50 Megawatts ...

Tilly, Jean

1983-01-01T23:59:59.000Z

64

Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams  

E-Print Network [OSTI]

An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

Latcham, Jacob G. (Jacob Greco)

2009-01-01T23:59:59.000Z

65

New Developments in Closed Loop Combustion Control Using Flue Gas Analysis  

E-Print Network [OSTI]

New developments in closed loop combustion control are causing radical changes in the way combustion control systems are implemented. The recent availability of in line flue gas analyzers and microprocessor technology are teaming up to produce...

Nelson, R. L.

1981-01-01T23:59:59.000Z

66

Profitability of CCS with flue gas bypass and solvent storage Supplementary Information  

E-Print Network [OSTI]

1 Profitability of CCS with flue gas bypass and solvent storage #12; 2 Perfect information model formulation Sets t T Time, in hours, from K Capital cost to oversize turbine if solvent storage or bypass are used

Jaramillo, Paulina

67

Separation of flue-gas scrubber sludge into marketable products  

SciTech Connect (OSTI)

A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium sulfite/sulfate material can be oxidized into a synthetic gypsum that can be used in several markets which include: wallboard manufacturing, plaster, portland cement, and as a soil conditioner. Single stage water-only cycloning removed nearly 50% of the limestone by weight from the scrubber sludge and maintained a weight recovery of 76%. Froth flotation produced a calcium sulfite/sulfate that contained 4.30% limestone by weight with a 71% weight recovery. These methods were successful in removing some of the limestone impurity, but were not able to meet the specifications needed. However, the combination of water-only cycloning and froth flotation provided a clean, useful calcium sulfite/sulfate material with a limestone grade of 1.70% by weight and a total weight recovery of nearly 66%.

Kawatra, S.K.; Eisele, T.C.

1997-08-31T23:59:59.000Z

68

Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations  

SciTech Connect (OSTI)

The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

Presto, A.A.; Granite, E.J

2008-07-01T23:59:59.000Z

69

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

SciTech Connect (OSTI)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

National Energy Technology Laboratory

2001-08-31T23:59:59.000Z

70

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2013-08-01T23:59:59.000Z

71

Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development  

SciTech Connect (OSTI)

The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

Radisav Vidic; Joseph Flora; Eric Borguet

2008-12-31T23:59:59.000Z

72

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks  

SciTech Connect (OSTI)

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

David A Lesch

2010-06-30T23:59:59.000Z

73

Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”  

SciTech Connect (OSTI)

A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

Granite, E.J.; Presto, A.A.

2008-09-01T23:59:59.000Z

74

In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas  

SciTech Connect (OSTI)

A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

NONE

2008-04-01T23:59:59.000Z

75

Near-Zero Emissions Oxy-Combustion Flue Gas Purification  

SciTech Connect (OSTI)

The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

2012-06-30T23:59:59.000Z

76

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas  

SciTech Connect (OSTI)

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01T23:59:59.000Z

77

Proof-of concept testing of the advanced NOXSO flue gas cleanup process. Final report  

SciTech Connect (OSTI)

The NOXSO Process uses a regenerable sorbent that removes SO{sub 2} and NO{sub x} simultaneously from flue gas. The sorbent is a stabilized {gamma}-alumina bed impregnated with sodium carbonate. The process was successfully tested at three different scales, equivalent to 0.017, 0.06 and 0.75 MW of flue gas generated from a coal-fired power plant. The Proof-of-Concept (POC) Test is the last test prior to a full-scale demonstration. A slip stream of flue gas equivalent to a 5 MW coal-fired power plant was used for the POC test. This paper summarizes the NOXSO POC plant and its test results.

Not Available

1993-04-01T23:59:59.000Z

78

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

79

Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using flue gas  

E-Print Network [OSTI]

Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using]. Besides physical and chemical methods for sequestration of CO2 from flue gas [2], microalgae culture holds great potential for converting flue gas to biomass. Microalgae can capture solar energy more efficiently

Subramanian, Venkat

80

JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas  

SciTech Connect (OSTI)

This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

Ye Zhuang; Christopher Martin; John Pavlish

2009-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas  

DOE Patents [OSTI]

Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

2012-11-06T23:59:59.000Z

82

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc)  

E-Print Network [OSTI]

, stationary sources like coal-fired power plants, carbon capture and sequestration (CCS) has been proposed.4Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine- Appended Metal-Organic Framework viable absorbents for carbon capture under the aforementioned conditions, and they are presently used

83

High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents  

SciTech Connect (OSTI)

The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

2002-09-20T23:59:59.000Z

84

The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas  

E-Print Network [OSTI]

THE BECKETT SYSTEM RECOVERY AND UTILIZATION OF LOW GRADE WASTE HEAT FROM FLUE GAS Wilfred R. Henderson Blenkhorn & Sawle Ltd. St. Catharines, Ontario Joseph F. DeBiase John Deere WeIland I%rks WeIland, Ontario ABSTRACT The Beckett Heat Recovery...

Henderson, W. R.; DeBiase, J. F.

1983-01-01T23:59:59.000Z

85

Synthetic aggregates prepared from flue gas desulfurization by-products using various binder materials  

SciTech Connect (OSTI)

Flue Gas Desulfurization (FGD) by-products can be converted into environmentally safe and structurally stable aggregates. One type of synthetic aggregate was prepared using an optimum mixture of (FGD) by-products, fly ash, and water. Mineral reactions have been examined using X-ray diffraction and scanning electron microscope.

Bellucci, J.; Graham, U.M.; Hower, J.C.; Robl, T.L. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1994-12-31T23:59:59.000Z

86

Fuel gas conditioning process  

DOE Patents [OSTI]

A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

Lokhandwala, Kaaeid A. (Union City, CA)

2000-01-01T23:59:59.000Z

87

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 10, February 17--May 31, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). One of the two flue gas ducts leading from the boiler has been retrofitted with the CZD technology. The first existing ESP installed in the station is immediately behind the air preheater. The second ESP, installed about 15 years ago, is about 80 feet away from the first ESP. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2}

Not Available

1993-11-15T23:59:59.000Z

88

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2014-06-01T23:59:59.000Z

89

Microalgae Production from Power Plant Flue Gas: Environmental Implications on a Life Cycle Basis  

SciTech Connect (OSTI)

Power-plant flue gas can serve as a source of CO{sub 2} for microalgae cultivation, and the algae can be cofired with coal. This life cycle assessment (LCA) compared the environmental impacts of electricity production via coal firing versus coal/algae cofiring. The LCA results demonstrated lower net values for the algae cofiring scenario for the following using the direct injection process (in which the flue gas is directly transported to the algae ponds): SOx, NOx, particulates, carbon dioxide, methane, and fossil energy consumption. Carbon monoxide, hydrocarbons emissions were statistically unchanged. Lower values for the algae cofiring scenario, when compared to the burning scenario, were observed for greenhouse potential and air acidification potential. However, impact assessment for depletion of natural resources and eutrophication potential showed much higher values. This LCA gives us an overall picture of impacts across different environmental boundaries, and hence, can help in the decision-making process for implementation of the algae scenario.

Kadam, K. L.

2001-06-22T23:59:59.000Z

90

Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass  

SciTech Connect (OSTI)

The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

Anuar, S.H.; Keener, H.M.

1995-12-31T23:59:59.000Z

91

Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal  

SciTech Connect (OSTI)

This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

Eric P. Robertson

2007-09-01T23:59:59.000Z

92

Alternative formulations of regenerable flue gas cleanup catalysts. Progress report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-12-31T23:59:59.000Z

93

Cleaning of municipal-waste incinerator flue gas in Europe  

SciTech Connect (OSTI)

This paper gives an overview of a substantial ongoing air-pollution-control program in West Germany, as it relates to emission of acid gases and other pollutants from municipal-refuse incineration. It details emission regulations, control means used, and technical advancements accomplished and foreseen. It gives results and the approximate effectiveness of various controls in reducing acid gas, trace organic, trace heavy metal, and particulate-matter emissions. Available data indicate that lime spray dryer/electrostatic precipitator (ESP) and spray-dryer/fabric-filter systems can attain 70-90% acid-gas removal and 97% or more control of dioxins and furans, while limiting mercury emissions to about 0.01-0.07 mg/N-cu m (dry). In comparison, some wet-scrubber systems can attain 90-plus % acid-gas removal with substantial removal of NOx and comparable control of dioxins and furans, while possibly providing consistently lower mercury emissions.

Brna, T.G.; Ellison, W.; Jorgensen, C.

1988-01-01T23:59:59.000Z

94

Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study  

SciTech Connect (OSTI)

It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

2012-05-03T23:59:59.000Z

95

Catalysts for oxidation of mercury in flue gas  

DOE Patents [OSTI]

Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2010-08-17T23:59:59.000Z

96

Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

2012-03-31T23:59:59.000Z

97

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 7, May 1, 1992--August 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The features that distinguish the CZD process from other similar injection processes are: (1) Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. (2) Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. (3) Low residence time, made possible by the high effective surface area of the Type S lime. (4) Localized dispersion of the reagent. (5) Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash.

Not Available

1993-02-01T23:59:59.000Z

98

Combined Flue Gas Heat Recovery and Pollution Control Systems  

E-Print Network [OSTI]

in the field of heat recovery now make it possible to recover a portion of the wasted heat and improve the working conditions of the air purification equipment. Proper design and selection of heat recovery and pollution control equipment as a combination...

Zbikowski, T.

1979-01-01T23:59:59.000Z

99

Compression stripping of flue gas with energy recovery  

DOE Patents [OSTI]

A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

Ochs, Thomas L. (Albany, OR); O'Connor, William K. (Lebanon, OR)

2005-05-31T23:59:59.000Z

100

Compression Stripping of Flue Gas with Energy Recovery  

DOE Patents [OSTI]

A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

Ochs, Thomas L.; O'Connor, William K.

2005-05-31T23:59:59.000Z

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101

Advanced separation technology for flue gas cleanup. Quarterly technical report No. 8, [January--March 1994  

SciTech Connect (OSTI)

During the first quarter of 1994, we continued work on Tasks 2, 3, 4, 5, and 6. We also began work on Task 7. In Task 2, we incorporated 4.5% O{sub 2} into our simulated flue gas stream during this quarter`s NO{sub x}-absorption experiments. We also ran experiments using Cobalt (II)-phthalocyanine as an absorbing agent We observed higher absorption capacities when using this solution with the simulated flue gas containing O{sub 2}. In Task 3, we synthesized a few EDTA polymer analogs. We also began scaled up synthesis of Co(II)-phthalocyanine for use in Task 5. In Task 4, we performed experiments for measuring distribution coefficients (m{sub i}) Of SO{sub 2} between aqueous and organic phases. This was done using the liquor regenerating apparatus described in Task 6. In Task 5, we began working with Co(II)-phthalocyanine in the 301 fiber hollow fiber contactor. We also calculated mass transfer coefficients (K{sub olm}) for these runs, and we observed that the gas side resistance dominates mass transfer. In Task 6, in the liquor regeneration apparatus, we observed 90% recovery of SO{sub 2} by DMA from water used as the scrubbing solution. We also calculated the distribution of coefficients (m{sub i}). In Task 7, we established and began implementing a methodology for completing this task.

Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S. [SRI International, Menlo Park, CA (United States)] [SRI International, Menlo Park, CA (United States); Sirkar, K.K.; Majumdar, S.; Bhaumick, D. [New Jersey Inst. of Tech., Newark, NJ (United States)] [New Jersey Inst. of Tech., Newark, NJ (United States)

1994-03-01T23:59:59.000Z

102

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

103

Environ. Scl. Technol. 1994, 28, 277-283 Effects of Salts on Preparation and Use of Calcium Silicates for Flue Gas  

E-Print Network [OSTI]

Silicates for Flue Gas Desulfurization Kurt K. Klnd, Phlllp D. Wasserman, and Gary 1.Rochelle' Department is a flue gas desulfurization (FGD) technology developed for existingcoal to remove sulfur dioxide. High surface area calcium silicate hydrates are made by slurrying Ca(0H

Rochelle, Gary T.

104

Flue gas cleaning with ammonia reduces SO{sub 2} emission  

SciTech Connect (OSTI)

This paper describes the technical and commercial development and basis for application in North America for wet flue gas desulfurization (FGD) of the AMASOX{reg_sign} (i.e. Ammonia Absorbs Sulfur Oxides) Process of Krupp Uhde (Germany) employing ammonia reagent. This process technology has been emerging slowly and stepwise over a twenty-year period in reaching the present stage of commercial applicability. The discussion herein considers the need for accommodating to and advantageously addressing the increasing number of applications with high and ultra-high flue-gas concentrations of SO{sub 2} at the boiler outlet accompanied by significant levels of other pollutants. Key measures in accomplishing this include use of important process innovations. This, as well, calls for the effective use, when applicable, of wet electrostatic precipitator mist-elimination means to gain low/minimum-opacity stack plume trailoff in wet scrubber use together with reduction of air toxics to low concentrations. With cost-effectiveness in electric utility service, detailed herein, superior to FGD processes commonly used to date in high-sulfur service, utilization of this technology is expanding. Important, potentially trend-setting types of powerplant applications of ammonia FGD are reviewed to identify foreseen market sectors and procurement trends that will at the same time serve to substantially broaden lowest-cost coal utilization.

Emish, G.J. [Krupp Wilputte Corp., Bridgeville, PA (United States); Schulte, W. [Krupp Uhde GmbH, Dortmund (Germany); Ellison, W. [Ellison Consultants, Monrovia, MD (United States)

1997-12-31T23:59:59.000Z

105

Land application uses for dry flue gas desulfurization by-products: Phase 3  

SciTech Connect (OSTI)

New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

1999-01-31T23:59:59.000Z

106

Hydrodynamics and flue gas desulfurization characteristics of a three-phase, gas-continuous, cocurrent semifluidized bed  

SciTech Connect (OSTI)

The hydrodynamic characteristics of a gas-liquid-solid, gas-continuous, cocurrent semifluidized bed were defined. Five different particle types were used to characterize the hydrodynamics. Air and water were used as the gas and liquid streams, respectively. Six flow regimes were observed in the constrained gas-continuous, three-phase bed. These regimes are described in terms of the solids properties and the gas and liquid superficial velocities. The heights of the packed and fluidized beds and the solids holdup in the fluidized section of the semifluidized bed are discussed in terms of the superficial gas and liquid velocities, the solids density and diameter and the initial quantity of particles in the bed. The desulfurization characteristics of the gas-liquid-solid semifluidized bed were determined using a calcium carbonate slurry. Gas side mass transfer coefficients and the ratio of liquid side to gas side mass transfer coefficients were measured and correlated in terms of gas flow rate, liquid flow rate, bed height, calcium carbonate concentration and sulfur dioxide pressure for both the fluidized and packed sections of the semifluidized bed. The hydrodynamic and mass transfer characteristics were used to construct a mathematical model that predicted overall removal of sulfur dioxide from the simulated flue gas.

Beaver, L.E.

1983-01-01T23:59:59.000Z

107

Monticello Unit 3 recovery project: The rebuild of a first generation wet flue gas desulfurization system  

SciTech Connect (OSTI)

Since November 1993, TU Electric and Sargent & Lundy have been engaged in the repair or replacement of equipment that was damaged by the collapse of the Monticello Unit 3 chimney. In addition to the replacement of the chimney, electrostatic precipitator, and various balance-of-plant systems, the scope of the project includes the demolition, engineering and design, procurement, and construction activities to rebuild major equipment within the wet limestone flue gas desulfurization (FGD) system. This paper reviews and discusses various aspects of the design, procurement and schedule associated with the rebuild of the FGD system. The paper reviews the design selections in the areas of process technology, the absorber island, and technical enhancements to improve the operability of this 1970s-vintage system. Finally, the challenges and solutions in implementing a 17-month schedule for the design, construction, and startup of an FGD system will be discussed.

Guletsky, P.W.; Katzberger, S.M. [Sargent & Lundy, Chicago, IL (United States); Jeanes, R.L. [TU Electric, Dallas, TX (United States)

1995-06-01T23:59:59.000Z

108

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

NONE

1995-09-01T23:59:59.000Z

109

The desulfurization of flue gas at the Mae Moh Power Plant Units 12 and 13  

SciTech Connect (OSTI)

As pollution of air, water and ground increasingly raises worldwide concern, the responsible national and international authorities establish and issue stringent regulations in order to maintain an acceptable air quality in the environment. In Thailand, the Electricity Generating Authority of Thailand (EGAT) takes full responsibility in environmental protection matters as well as in generating the electricity needed to supply the country`s very rapid power demand growth. Due to the rapidly increasing electricity demand of the country, EGAT had decided to install two further lignite-fired units of 300 MW each (Units 12 and 13) at the Mae Moh power generation station and they are now under construction. The arrangement and the capacity of all the power plant units are as shown. In 1989, EGAT started the work on the flue gas desulfurization system of Mae Moh power plant units 12 and 13 as planned. A study has been conducted to select the most suitable and most economical process for flue gas desulfurization. The wet scrubbing limestone process was finally selected for the two new units. Local limestone will be utilized in the process, producing a by-product of gypsum. Unfortunately, natural gypsum is found in abundance in Thailand, so the produced gypsum will be treated as landfill by mixing it with ash from the boilers of the power plants and then carrying it to the ash dumping area. The water from the waste ash water lake is utilized in the process as much as possible to minimize the requirement of service water, which is a limited resource. The Mae Moh power generation station is situated in the northern region of Thailand, 600 km north of Bangkok and about 30 km east of the town of Lampang, close to the Mae Moh lignite mine. Three lignite-fired units (Units 1-3) of 75 MW each, four units (Units 4-7) of 150 MW each and four units (Units 8-11) of 300 MW each are in operation.

Haemapun, C.

1993-12-31T23:59:59.000Z

110

Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report  

SciTech Connect (OSTI)

The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

NONE

1996-04-30T23:59:59.000Z

111

Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance  

SciTech Connect (OSTI)

A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

Andrew Seltzer; Zhen Fan

2011-03-01T23:59:59.000Z

112

Start up results from a specialized flue gas cleaning facility in a power station using refinery residues  

SciTech Connect (OSTI)

In eastern Germany STEAG--the biggest German IPP--has erected a power plant consisting of three combustion lines burning oil distillation residues from the new Mider refinery to provide the refinery with power, steam, water and compressed air. Each of the three flue gas cleaning lines consists of a high dust SCR-system, quench, wet electrostatic precipitator, scrubber, steam reheater and ID-fan. Common systems are the storage and handling of the absorbent, the gypsum dewatering and the waste water treatment. The installed high dust SCR system attains the expected NO{sub x}-reduction efficiency and an excellent NO{sub x} outlet distribution and low ammonia slip. After commissioning problems occurred with the wet ESP in all three lines due to improper function of the upstream quenches. Modifications of the quench system have been made which assure a temperature of the flue gas after quench near saturation temperature and correct functioning of the quench and wet ESP. To reduce pressure loss of the absorber concurrent spray nozzles were installed. Strong vibrations of the absorber tower, the connected pipes and the steel structure along with an insufficient SO{sub x} removal efficiency at high inlet concentration were observed. After changing the concurrent operation of the spray nozzles to counter current operation the vibrations of the absorber tower became smaller and the removal efficiency achieved the guaranteed value. Problems arose in the waste water treatment plant caused by the high solid concentration of up to 1,000 g/l in the thickener. By diluting the settled sludge with overflow water from the thickener the problems in the waste water treatment plant could be minimized to an acceptable degree. Despite these problems the flue gas cleaning system is in continuous operation and the emission values of flue gas and waste water meet the required standards.

Beiers, H.G.; Gilgen, R.; Weiler, H.

1998-07-01T23:59:59.000Z

113

Separation of the components of flue-gas scrubber sludge by froth flotation  

SciTech Connect (OSTI)

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. Currently, the major markets for scrubber sludge are for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. Other markets, such as paper manufacture and plastics fillers, have even more stringent quality requirements and will not accept raw sludge at all. In the work described in this paper, several reagents have been examined to determine their ability to selectively improve the flotation of the unreacted limestone contaminant away from the desirable products (calcium sulfite and gypsum). The most success has been achieved using a cationic collector, which shows a higher selectivity between calcium sulfite and calcium carbonate than do the anionic collectors that were studied.

Kawatra, S.K.; Eisele, T.C. [Michigan Technological Univ., Houghton, MI (United States). Dept. of Metallurgical and Materials Engineering

1995-12-31T23:59:59.000Z

114

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

115

Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams .  

E-Print Network [OSTI]

??An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue… (more)

Latcham, Jacob G. (Jacob Greco)

2009-01-01T23:59:59.000Z

116

CO{sub 2} Capture Membrane Process for Power Plant Flue Gas  

SciTech Connect (OSTI)

Because the fleet of coal-fired power plants is of such importance to the nationâ??s energy production while also being the single largest emitter of CO{sub 2}, the development of retrofit, post-combustion CO{sub 2} capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO{sub 2} from plant flue gas with 95% captured CO{sub 2} purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO{sub 2}-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft{sup 2}) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO{sub 2}, NOx, etc.). Specific objectives were: ï?· Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO{sub 2} over N{sub 2} and CO{sub 2} permeance greater than 300 gas permeation units (GPU) targeted; ï?· Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO{sub 2} permeance than current commercial polycarbonate membranes; ï?· Development and fabrication of membrane hollow fibers and modules from candidate polymers; ï?· Development of a CO{sub 2} capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and ï?· Techno-economic evaluation of the "best" integrated CO{sub 2} capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO{sub 2} capture with 95% captured CO{sub 2} purity.

Lora Toy; Atish Kataria; Raghubir Gupta

2011-09-30T23:59:59.000Z

117

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

118

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

Not Available

1993-09-27T23:59:59.000Z

119

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 9, November 17, 1992--February 16, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically on electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). Progress is described for the ninth quarter.

Not Available

1993-10-01T23:59:59.000Z

120

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system  

SciTech Connect (OSTI)

Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

1991-01-01T23:59:59.000Z

122

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

123

Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture  

SciTech Connect (OSTI)

An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

2012-04-24T23:59:59.000Z

124

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

125

Flue gas desulfurization sludge: establishment of vegetation on ponded and soil-applied waste. Final report January 1977-September 1981  

SciTech Connect (OSTI)

The report gives results of research to identify and evaluate forms of vegetation and methods of their establishment for reclaiming retired flue gas desulfurization sludge ponds. Also studied were the soil liming value of limestone scrubber sludge (LSS) and plant uptake and percolation losses of some chemical nutrients in the sludge. Several vegetation schemes were evaluated between 1977 and 1982 for covering and stabilizing LSS at Colbert Steam Plant, Cherokee, AL, and Shawnee Steam Plant, Paducah, KY. Eleven tree and 10 grass or legume species were tested for adaptability and survival when planted directly in LSS or in LSS amended with soil, municipal sewage sludge, or standard potting mix. Other studies indicated that LSS apparently has sufficient unreacted limestone to be a satisfactory soil liming agent.

Giordano, P.M.; Mays, D.A.; Soileau, J.M.

1984-01-01T23:59:59.000Z

126

Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants  

SciTech Connect (OSTI)

This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

2003-12-31T23:59:59.000Z

127

Comparison of thermoelectric and permeation dryers for sulfur dioxide removal during sample conditioning of wet gas streams  

SciTech Connect (OSTI)

Flue gas conditioning for moisture removal is commonly performed for criteria pollutant measurements, in particular for extractive CEM systems at combustion sources. An implicit assumption is that conditioning systems specifically remove moisture without affecting pollutant and diluent concentrations. Gas conditioning is usually performed by passing the flue gas through a cold trap (Peltier or thermoelectric dryer) to remove moisture by condensation, which is subsequently extracted by a peristaltic pump. Many air pollutants are water-soluble and potentially susceptible to removal in a condensation dryer from gas interaction with liquid water. An alternative technology for gas conditioning is the permeation dryer, where the flue gas passes through a selectively permeable membrane for moisture removal. In this case water is transferred through the membrane while other pollutants are excluded, and the gas does not contact condensed liquid. Laboratory experiments were performed to measure the relative removal of a water-soluble pollutant (sulfur dioxide, SO{sub 2}) by the two conditioning techniques. A wet gas generating system was used to create hot, wet gas streams of known composition (15% and 30% moisture, balance nitrogen) and flow rate. Pre-heated SO{sub 2} was dynamically spiked into the wet stream using mass flow meters to achieve concentrations of 20, 50, and 100 ppm. The spiked gas was directed through a heated sample line to either a thermoelectric or a permeation conditioning system. Two gas analyzers (Western Research UV gas monitor, KVB/Analect FTIR spectrometer) were used to measure the SO{sub 2} concentration after conditioning. Both analytic methods demonstrated that SO{sub 2} is removed to a significantly greater extent by the thermoelectric dryer. These results have important implications for SO{sub 2} monitoring and emissions trading.

Dunder, T.A. [Entropy, Inc., Research Triangle Park, NC (United States). Research Div.; Leighty, D.A. [Perma Pure, Inc., Toms River, NJ (United States)

1997-12-31T23:59:59.000Z

128

Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator  

SciTech Connect (OSTI)

This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

2006-07-01T23:59:59.000Z

129

Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I  

SciTech Connect (OSTI)

This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

1981-09-01T23:59:59.000Z

130

Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997  

SciTech Connect (OSTI)

This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

Chugh, Y.P.; Brackebusch, F.; Carpenter, J. [and others

1998-12-31T23:59:59.000Z

131

DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION  

SciTech Connect (OSTI)

For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

Panagiotis G. Smirniotis

2005-01-30T23:59:59.000Z

132

Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Fogash, Kevin

2010-09-30T23:59:59.000Z

133

Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Kevin Fogash

2010-09-30T23:59:59.000Z

134

Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas  

DOE Patents [OSTI]

The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

2014-10-07T23:59:59.000Z

135

Effect of connate water on miscible displacement of reservoir oil by flue gas  

E-Print Network [OSTI]

gas and water injection, have allowed the industry to greatly increase primary oil recovery. But the common weakness of gas and water as pressure maintenance and secondary recovery agents is im- miscibility with the reservoir fluid to be displaced... to using a hydrocarbon slug, Saxon, et al was one of the earliest investigators of carbon dioxide as a possible flooding 14 agent. Gatlin and Slobod reported on laboratory investigations of another possible miscible flooding agent, methyl alcohol. Each...

Maxwell, H. D.

1960-01-01T23:59:59.000Z

136

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

137

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

1997-01-01T23:59:59.000Z

138

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

Yang, W.C.; Newby, R.A.; Lippert, T.E.

1997-08-05T23:59:59.000Z

139

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993  

SciTech Connect (OSTI)

There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

Sublette, K.L.

1993-11-01T23:59:59.000Z

140

Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |  

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141

Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas  

SciTech Connect (OSTI)

This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

C. Jean Bustard; Charles Lindsey; Paul Brignac

2006-05-01T23:59:59.000Z

142

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 15, September 1, 1994--November 30, 1994  

SciTech Connect (OSTI)

The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

NONE

1997-01-01T23:59:59.000Z

143

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report, No. 14, June 1, 1994--August 31, 1994  

SciTech Connect (OSTI)

The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

NONE

1997-01-01T23:59:59.000Z

144

Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion  

SciTech Connect (OSTI)

In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

Panagiotis G. Smirniotis

2007-06-30T23:59:59.000Z

145

Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers  

E-Print Network [OSTI]

....'::::;::::::: Il-~:!=;~:o:oo:t(.~ _.;:::::=:;:::::.":':::"':'::':":::":::.lIoo:...:...:_:?.:""'.:::::::::::::::::::;::~ . ??:.:?????????????::: Precipitator :.- .......?......... ~ ........ . ... :.:.:.:. ..:.:.:.:.:.:.:.:.:.:.. ? ? ? ? ......w.;."w,1o&.I1.&r...

Miller, B.; Keon, E.

1980-01-01T23:59:59.000Z

146

FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

2004-01-29T23:59:59.000Z

147

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 13, March 1, 1994--May 31, 1994  

SciTech Connect (OSTI)

The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from the flue gas of a coal-fired utility boiler. In the process, the SO{sub 2} is converted to a sulfur by-product and the NO{sub x} is converted to nitrogen and oxygen. It is predicted that the process can economically remove 90% of the acid rain precursor gases from the flue gas stream in a retrofit or new facility. The objective of the NOXSO Demonstration Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process. The effectiveness of the process will be demonstrated by achieving significant reductions in emissions of sulfur and nitrogen oxides. In addition, sufficient operating data will be obtained to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is presently in the project definition and preliminary design phase. Data obtained during pilot plant testing which was completed on July 30, 1993 is being incorporated in the design of the commercial size plant. A suitable host site to demonstrate the NOXSO process on a commercial scale is presently being sought. Preliminary engineering activities involved evaluating various design options for the major process vessels with the principal focus being on the sorbent heater vessel, which is operated at the highest temperature. Additionally, the impact of the NOXSO system on power plant particulate emissions and opacity was estimated. It is predicted that particulate emissions will decrease slightly while opacity will increase slightly. Neither change will be significant enough to have an impact on emissions compliance. Advertised performance of the proposed adsorber separator is being verified by laboratory testing. Process studies activities included POC equipment inspection and materials evaluations.

NONE

1994-12-31T23:59:59.000Z

148

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993  

SciTech Connect (OSTI)

This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

Sublette, K.L.

1993-12-31T23:59:59.000Z

149

High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines - Phase I: Laboratory investigations. Quarterly report, October 1993--December 1993  

SciTech Connect (OSTI)

This project proposes to use pneumatically or hydraulically emplaced dry-flue gas desulfurization (FGD) by-products to backfill the adits left by highwall mining. Backfilling highwall mine adits with dry-FGD materials is technically attractive. The use of an active highwall mine would allow the dry-FGD material to be brought in using the same transportation network used to move the coal out, eliminating the need to recreated the transportation infrastructure, thereby saving costs. Activities during the period included the negotiations leading to the final cooperative agreement for the project and the implementation of the necessary instruments at the University of Kentucky to administer the project. Early in the negotiations, a final agreement on a task structure was reached and a milestone plan was filed. A review was initiated of the original laboratory plan as presented in the proposal, and tentative modifications were developed. Selection of a mine site was made early; the Pleasant Valley mine in Greenup County was chosen. Several visits were made to the mine site to begin work on the hydrologic monitoring plan. The investigation of the types of permits needed to conduct the project was initiated. Considerations concerning the acceptance and implementation of technologies led to the choice of circulating fluidized bed ash as the primary material for the study. Finally, the membership of a Technical Advisory Committee for the study was assembled.

Not Available

1994-03-01T23:59:59.000Z

150

Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use  

SciTech Connect (OSTI)

field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

2012-07-31T23:59:59.000Z

151

Improved high efficiency third stage separator cyclones for separation of fines from fluid catalytic cracking flue gas  

SciTech Connect (OSTI)

Stairmand type small diameter (0.254 m) multicyclones were cold flow tested for fluid catalytic cracking third stage separator application. The gas discharge from the cyclone dust outlet into the common collection hopper was found to far exceed the hopper bleed rate (underflow). The excess gas reentrained dust from the hopper back into cyclones, which lowered collection efficiencies. Vortex {open_quotes}stabilization{close_quotes} using apex cones was unsuccessful whereas a Mobil proprietary cyclone modification was successful in minimizing excess gas discharge and dust reentrainment at the cyclone-hopper boundary. In tests at 700 {degrees}C, the modified cyclones captured all particles above 4 {mu}m. Mobil-Kellogg incorporated the modified cyclones in a new third stage separator design which is targeted for achieving lowest opacity and <50 mg/Nm{sup 3} emissions at the stack. The first such unit will be commercialized in Mobil`s newest catalytic cracker (M.W. Kellogg design) under construction in Altona, Australia in late 1996. 5 refs., 4 figs., 2 tabs.

Chitnis, G.K.; Schatz, K.W. [Mobil Technology Co., Paulsboro, NJ (United States); Bussey, B.K. [M.W. Kellogg Co., Houston, TX (United States)

1996-12-31T23:59:59.000Z

152

Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets  

E-Print Network [OSTI]

of a flue gas condenser with a steam boiler. ? Improvedsteam dryers by gas ? Dryers and filtration equipment ? Applied CHP ? Purchased flue gas condensers ?

Price, Lynn

2010-01-01T23:59:59.000Z

153

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 16, December 1, 1994--February 28, 1995  

SciTech Connect (OSTI)

The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from flue gas. In the process, the SO{sub 2} is converted to a sulfur by- product (elemental sulfur, sulfuric acid, or liquid SO{sub 2}) and the NO{sub x} is converted to nitrogen and oxygen. The objective of the NOXSO Clean Coal Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process at Alcoa Generating Corporation`s (AGC) Warrick Power Plant. The NOXSO plant is being designed to remove 98% of the SO{sub 2} and 75% of the NO{sub x} from the flue gas from the 150-MW equivalent, unit 2 boiler. The by-product to be generated by the project is liquid SO{sub 2}. Sufficient construction cost and operating data will be obtained during the project to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is in the Front End Engineering/Environmental Evaluation Phase. Engineering activities are approximately 20% complete and activities to update the project estimate based on completed engineering and equipment bids have been initiated. Process study activities include laboratory fluid-bed adsorber studies, regenerator computer model development and studies, fluid-flow modelling in fluid-bed vessels, and evaluations of SO{sub 2} production processes. The laboratory- scale, fluid-bed adsorber studies are being conducted to improve the accuracy of the removal efficiency predictions and study the impact of adding a third adsorber stage. The construction of the steel, multi-stage reactor is currently underway. The regenerator computer model was revised and is being used to study design options for improving the regenerator performance. Fluid-flow modelling has been conducted to study the effect of grid supports on the gas flow inside the fluid bed vessels.

NONE

1995-12-31T23:59:59.000Z

154

Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas  

DOE Patents [OSTI]

The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (Oakland, CA); Griffiths, Elizabeth A. (Neston, GB2); Littlejohn, David (Oakland, CA)

1988-01-01T23:59:59.000Z

155

Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 5, November 1, 1991--January 31, 1992  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO{sub 2} and NO{sub x} Reduction - Preliminary confirmation of 50% SO{sub 2} reduction has been achieved, but the NO{sub x} reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO{sub 2} reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO{sub 2} Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel`s original cost estimates (capital and operating) were prepared. Therefore, SO{sub 2} removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

156

Separation of flue-gas scrubber sludge into marketable products. Second quarterly technical progress report, December 1, 1993--February 28, 1994 (Quarter No. 2)  

SciTech Connect (OSTI)

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. It consists of calcium sulfite (CaSO{sub 3}{lg_bullet}0.5H{sub 2}0), gypsum (CaSO{sub 4}{lg_bullet}2H{sub 2}0), and unreacted limestone (CaCO{sub 3}) or lime (Ca(OH){sub 2}), with miscellaneous objectionable impurities such as iron oxides; silica; and magnesium, sodium, and potassium oxides or salts. Currently, the only market for scrubber sludge is for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. This project is developing a process that can produce a high-quality calcium sulfite or gypsum product while keeping process costs low enough that the material produced will be competitive with that from other, more conventional sources. This purification will consist of minimal-reagent froth flotation, using the surface properties of the particles of unreacted limestone to remove them and their associated impurities from the material, leaving a purified gypsum or calcium sulfite product. The separated limestone will be a useful by-product, as it can be recycled to the scrubber, thus boosting the limestone utilization and improving process efficiency. Calcium sulfite will then be oxidized to gypsum, or separated as a salable product in its own right from sludges where it is present in sufficient quantity. The main product of the process will be either gypsum or calcium sulfite, depending on the characteristics of the sludge being processed. These products will be sufficiently pure to be easily marketed, rather that being landfilled.

Kawatra, S.K.; Eisele, T.C.

1994-03-01T23:59:59.000Z

157

Optimization of well rates under gas coning conditions  

E-Print Network [OSTI]

production rates under gas caning conditions. This new method applies to an oil reservoir overlain by a large gas cap containing multiple wells. The cases consider have a limit on the maximum field production rate for both oil and gas. It was found... that the optimal p~ion rates are achieved when Eq. 1 is satisfied for any pair of wells i and j: ) I = constant i = 1, . . . , n dqo This condition minimizes the f ield gas production rate when the maximum field production rate for oil is met, and maximizes...

Urbanczyk, Christopher Henry

1989-01-01T23:59:59.000Z

158

Gas Powered Air Conditioning Absorption vs. Engine-Drive  

E-Print Network [OSTI]

It used to be that the only alternative to costly electric air conditioning was the double-effect gas-fired absorption chiller/heaters. Beginning in the 1980's, they were the "star" equipment promoted by gas companies throughout the nation. Although...

Phillips, J. N.

1996-01-01T23:59:59.000Z

159

NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

SciTech Connect (OSTI)

Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the individual gas cleaning stages, and the probable operating conditions of the gas cleaning stages to conceptually satisfy the gas cleaning requirements; (2) Estimate process material & energy balances for the major plant sections and for each gas cleaning stage; (3) Conceptually size and specify the major gas cleaning process equipment; (4) Determine the resulting overall performance of the application; and (5) Estimate the investment cost and operating cost for each application. Analogous evaluation steps were applied for each application using conventional gas cleaning technology, and comparison was made to extract the potential benefits, issues, and development needs of the Filter-Reactor Novel Gas Cleaning technology. The gas cleaning process and related gas conditioning steps were also required to meet specifications that address plant environmental emissions, the protection of the gas turbine and other Power Island components, and the protection of the methanol synthesis reactor. Detailed material & energy balances for the gas cleaning applications, coupled with preliminary thermodynamic modeling and laboratory testing of candidate sorbents, identified the probable sorbent types that should be used, their needed operating conditions in each stage, and their required levels of performance. The study showed that Filter-Reactor Novel Gas Cleaning technology can be configured to address and conceptually meet all of the gas cleaning requirements for IGCC, and that it can potentially overcome several of the conventional IGCC power plant availability issues, resulting in improved power plant thermal efficiency and cost. For IGCC application, Filter-Reactor Novel Gas Cleaning yields 6% greater generating capacity and 2.3 percentage-points greater efficiency under the Current Standards case, and more than 9% generating capacity increase and 3.6 percentage-points higher efficiency in the Future Standards case. While the conceptual equipment costs are estimated to be only slightly lower for the Filter-Reactor Novel Gas Cleaning processes than for the conventional processes, the improved power plant capacity results in the potentia

Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

2005-12-01T23:59:59.000Z

160

Process for removing sulfur dioxide from flue gases  

SciTech Connect (OSTI)

This patent describes an improvement in a dry process for the removal of sulfur dioxide from flue gases by the addition thereto of hydrated lime containing sugar in a coal combustion unit, wherein the flue gases result from the combustion of a coal in a combustion chamber, and the flue gases are treated in an electrostatic precipitator prior to discharge to the atmosphere the improvement comprising: passing the flue gases, after the addition of the hydrated lime is of fine particles of a specific surface of 7 to 25 square meters per gram, through a conduit towards the electrostatic precipitator; and adding an aqueous media to the flue gases in the conduit in an amount to increase the water content of the flue gases and cool the same by evaporative cooling to a temperature no lower than 20{sup 0}F. about the dew point of the gas, so as to avoid forming water droplets in the gas, so as to prevent condensation of water therefrom.

Robinson, M.W. Jr.

1989-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Final report  

SciTech Connect (OSTI)

The main objective of this research was to investigate microorganisms capable of fossil fuel flue gas desulfurization and denitrification. The study used municipal sewage sludge as a carbon and energy source for SO{sub 2}-reducing cultures. The individual tasks developed a consortium of sulfate-reducing bacteria, investigated the design parameters for a continuous process, preformed a cost analysis, and screened sulfate-reducing bacteria. In the investigation of microbial reduction of NO{sub x} to nitrogen, tasks included screening denitrifying bacteria for NO and NO{sub 2} activity, developing optimum NO-reducing cultures, and investigating design parameters for a continuous system. This final report reviews the work previous to the current project, describes project objectives and the specific work plan, and reports results from the work completed during the previous reporting periods.

Sublette, K.L.

1994-03-01T23:59:59.000Z

162

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

2003-01-01T23:59:59.000Z

163

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

2006-05-02T23:59:59.000Z

164

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

Infrared burner is a surface combustor that elevates the temperature of the burner head to a radiant condition. Applications of radiant burners includes boilers, air heaters, deep fat fryers, process heaters, and immersion heaters. On reason for the present interest in this type of burner is its low NO{sub x} emissions, which is attributed to the fact that a large proportion of the combustion heat is given out as radiation from the burner surface, which results in relatively low gas temperature in the combustion zone compared to that of a conventional free-flame burner. As a consequence, such burners produce less NO{sub x}, mainly by the so-called prompt-NO mechanism. A porous radiant burner testing facility was built, consisting of spectral radiance as well as flue gas composition measurements. Measurement capabilities were tested using methane; results were consistent with literature.

Bai, Tiejun; Yeboah, Y.D.; Sampath, R.

1996-01-01T23:59:59.000Z

165

Cement kiln flue dust as a source of lime and potassium in four East Texas soils  

E-Print Network [OSTI]

design on both sites. Yield, soil pH, plant and soil concentrations of K, Ca, and Mg were determined. Soil pH and extractable Ca increased with increasing rate of flue dust or calcite. Under field conditions, flue dust compared favorably with calcite... was similar to plant uptake from corresponding calcite + KC1 treatments. Soil pH and extractable soil K, Ca, and Mg increased with increased rate of flue dust treatment equally as well as from the corresponding calcite treatments. The flue dust was equal...

Poole, Warren David

1975-01-01T23:59:59.000Z

166

Reducing the cost of CO{sub 2} capture from flue gases using membrane technology  

SciTech Connect (OSTI)

Studies of CO{sub 2} capture using membrane technology from coal-fired power-plant flue gas typically assume compression of the feed to achieve a driving force across the membrane. The high CO{sub 2} capture cost of these systems reflects the need to compress the low-pressure feed gas (1 bar) and the low CO{sub 2} purity of the product stream. This article investigates how costs for CO{sub 2} capture using membranes can be reduced by operating under vacuum conditions. The flue gas is pressurized to 1.5 bar, whereas the permeate stream is at 0.08 bar. Under these operating conditions, the capture cost is U.S. $54/tonne CO{sub 2} avoided compared to U.S. $82/tonne CO{sub 2} avoided using membrane processes with a pressurized feed. This is a. reduction of 35%. The article also investigates the effect on the capture cost of improvements in CO{sub 2} permeability and selectivity. The results show that the capture cost can be reduced to less than U.S. $25/tonne CO{sub 2} avoided when the CO{sub 2} permeability is 300 bar, CO{sub 2}/N{sub 2} selectivity is 250, and the membrane cost is U.S. $10/m{sup 2}.

Ho, M.T.; Allinson, G.W.; Wiley, D.E. [University of New South Wales, Kensington, NSW (Australia)

2008-03-15T23:59:59.000Z

167

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992  

SciTech Connect (OSTI)

With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

Sublette, K.L.

1992-12-31T23:59:59.000Z

168

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, July 1--September 30, 1995  

SciTech Connect (OSTI)

The objective of this investigation is to characterize the operation of fan powered infrared burner (PIR) at various gas compositions and ambient conditions and develop design guidelines for appliances in containing PIR burners for satisfactory performance. During this period, experimental setup with optical and electronic instrumentation that is necessary for measuring the radiant heat output and the emission gas output of the burner has been established. The radiation measurement instrument, an FTIR, has been purchased and installed in the porous burner experimental system. The radiation measurement capability of the FTIR was tested and found to be satisfactory. A standard blackbody source, made by Graseby Infrared, was employed to calibrate the FTIR. A collection duct for emission gas measurement was fabricated and connected to the existing Horiba gas analyzer. Test runs are being conducted for flue gas analysis. A number of published research papers on modeling of porous burners were reviewed. The physical mechanism and theoretical analysis of the combustion process of the PIR burner was formulated. The numerical modeling, and implementation of a PIR burner code at CAU`s computing facility is in progress.

Bai, T.; Yeboah, Y.D.; Sampath, R.

1995-10-01T23:59:59.000Z

169

High Btu gas from peat. Existing social and economic conditions  

SciTech Connect (OSTI)

In 1980, the Minnesota Gas Company (Minnegasco) submitted a proposal to the US Department of Energy entitled, A Feasibility Study - High Btu Gas from Peat. The proposed study was designed to assess the overall viability of the design, construction and operation of a commercial facility for the production of high-Btu substitute natural gas (SNG) from Minnesota peat. On September 30, 1980, Minnegasco was awarded a grant by the Department of Energy to perform the proposed study. In order to complete the study, Minnegasco assembled an experienced project team with the wide range of expertise required. In addition, the State of Minnesota agreed to participate in an advisory capacity. The items to be investigated by the project team during the feasibility study include peat harvesting, dewatering, gasification process design, economic and risk assessment, site evaluation, environmental and socioeconomic impact assessment. Ertec (The Earth Technology Corporation) was selected to conduct the site evaluation and environmental assessment portions of the feasibility study. The site evaluation was completed in March of 1981 with the submittal of the first of several reports to Minnegasco. This report describes the existing social and economic conditions of the proposed project area in northern Minnesota. The baseline data presented will be used to assess the significance of potential project impacts in subsequent phases of the feasibility study. Wherever possible, the data base was established using 1980 Bureau of Census statistics. However, where the 1980 data were not yet available, the most recent information is presented. 11 figures, 46 tables.

Not Available

1981-08-01T23:59:59.000Z

170

GAS INJECTION/WELL STIMULATION PROJECT  

SciTech Connect (OSTI)

Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

John K. Godwin

2005-12-01T23:59:59.000Z

171

Water-saving liquid-gas conditioning system  

DOE Patents [OSTI]

A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

Martin, Christopher; Zhuang, Ye

2014-01-14T23:59:59.000Z

172

Regeneration analysis under different exhaust gas thermal conditions  

SciTech Connect (OSTI)

A refinement of the honeycomb trap model developed by the authors of this paper for analyzing the temperature history of the trap channels during the regeneration period is presented. The first results obtained, shown in previous papers, encouraged the authors to improve the model in order to account for the heat transfer not only along the channel length, but also in the radial direction. In order to achieve this objective, a control volume approach was used to simulate the soot regeneration in all contiguous channels along the axial and radial directions of the monolith, and to determine the wall temperature and soot oxidation as a function of time. Different thermodynamic conditions of the exhaust gas at the trap inlet were considered in order to examine the effects of cold regeneration. For the same soot amount accumulated in the trap, the soot burnup time and temperature history depend on the inlet temperature.

Bella, G.; Rocco, Y. (Dept. di Ingegneria Meccanica, II Univ. di Roma Tor Vergata, Rome (IT))

1990-07-01T23:59:59.000Z

173

Laboratory Investigations of a Low-Swirl Injector with H2 and CH4 at Gas Turbine Conditions  

E-Print Network [OSTI]

to verify this model at gas turbine conditions so that itmodel is consistent with the trends observed at gas turbine

Cheng, R. K.

2009-01-01T23:59:59.000Z

174

Gas-surface interaction and boundary conditions for the Boltzmann equation  

E-Print Network [OSTI]

Gas-surface interaction and boundary conditions for the Boltzmann equation St´ephane Brull, Pierre Equation. The interaction between the wall atoms and the gas molecules within a thin surface layer of the gas in the bulk flow. Boundary conditions are formally derived from this model by using classical

Mieussens, Luc

175

Condition Based Monitoring of Gas Turbine Combustion Components  

SciTech Connect (OSTI)

The objective of this program is to develop sensors that allow condition based monitoring of critical combustion parts of gas turbines. Siemens teamed with innovative, small companies that were developing sensor concepts that could monitor wearing and cracking of hot turbine parts. A magnetic crack monitoring sensor concept developed by JENTEK Sensors, Inc. was evaluated in laboratory tests. Designs for engine application were evaluated. The inability to develop a robust lead wire to transmit the signal long distances resulted in a discontinuation of this concept. An optical wear sensor concept proposed by K Sciences GP, LLC was tested in proof-of concept testing. The sensor concept depended, however, on optical fiber tips wearing with the loaded part. The fiber tip wear resulted in too much optical input variability; the sensor could not provide adequate stability for measurement. Siemens developed an alternative optical wear sensor approach that used a commercial PHILTEC, Inc. optical gap sensor with an optical spacer to remove fibers from the wearing surface. The gap sensor measured the length of the wearing spacer to follow loaded part wear. This optical wear sensor was developed to a Technology Readiness Level (TRL) of 5. It was validated in lab tests and installed on a floating transition seal in an F-Class gas turbine. Laboratory tests indicate that the concept can measure wear on loaded parts at temperatures up to 800{degrees}C with uncertainty of < 0.3 mm. Testing in an F-Class engine installation showed that the optical spacer wore with the wearing part. The electro-optics box located outside the engine enclosure survived the engine enclosure environment. The fiber optic cable and the optical spacer, however, both degraded after about 100 operating hours, impacting the signal analysis.

Ulerich, Nancy; Kidane, Getnet; Spiegelberg, Christine; Tevs, Nikolai

2012-09-30T23:59:59.000Z

176

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly report, April 1, 1996 - June 30, 1996  

SciTech Connect (OSTI)

A porous radiant burner testing facility consisting of a commercial deep-fat fryer, an FTIR based spectral radiance measurement system, a set of flue gas analysis components, and a fuel gas mixing station was constructed. The measurement capabilities of the system were tested using methane and the test results were found to be consistent with the literature. Following the validation of the measurement system, various gas mixtures were tested to study the effect of gas compositions have on burner performance. Results indicated that the emissions vary with fuel gas composition and air/fuel ratio. The maximum radiant efficiency of the burner was obtained close to air/fuel ratio of 1.

Bai, T.; Yeboah, Y.D.; Sampath, R.

1996-07-01T23:59:59.000Z

177

New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement  

SciTech Connect (OSTI)

Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Yin, Hongxi [Southeast University, Nanjing, China

2014-01-01T23:59:59.000Z

178

Integrated Simulations for Multi-Component Analysis of Gas Turbines : RANS Boundary Conditions  

E-Print Network [OSTI]

More recently the coupling method has also been applied to a Pratt & Whitney gas turbine.7 The RANSIntegrated Simulations for Multi-Component Analysis of Gas Turbines : RANS Boundary Conditions 94305, U.S.A The aero-thermal computation of the flow path of an entire gas turbine engine can

Kim, Sangho

179

NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE  

SciTech Connect (OSTI)

The objective of this program is to develop and evaluate novel sorbents for the Siemens Westinghouse Power Company's (SWPC's) ''Ultra-Clean Gas Cleaning Process'' for reducing to near-zero levels the sulfur- and chlorine-containing gas emissions and fine particulate matter (PM2.5) caused by fuel bound constituents found in carbonaceous materials, which are processed in Integrated Gasification Combined Cycle (IGCC) technologies.

Javad Abbasian

2001-07-01T23:59:59.000Z

180

A mathematical model for the estimation of flue temperature in a coke oven  

SciTech Connect (OSTI)

The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Effects of gaseous NH{sub 3} and SO{sub 2} on the concentration profiles of PCDD/F in flyash under post-combustion zone conditions  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Influence of NH{sub 3} and SO{sub 2} on 2378-PCDD/F in flyash and flue gases was investigated. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 34-75% in the flyash. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 21-40% from the flue gases. Black-Right-Pointing-Pointer SO{sub 2} led to 99% PCDD and 93% PCDF reductions in the flyash. Black-Right-Pointing-Pointer SO{sub 2} led to 89% PCDD and 76% PCDF reductions in the flue gases. - Abstract: The influence of gaseous ammonia and sulphur dioxide on the formation of 2378-substituted PCDD/F on a reference flyash from a municipal waste incinerator has been investigated using a laboratory scale fixed-bed reactor. The reference flyash samples (BCR-490) was reacted under a simulated flue gas stream at temperatures of 225 and 375 Degree-Sign C for 96 h. The experiments were carried out in two series: first with simulated flue gas alone, and then with injection of NH{sub 3} or SO{sub 2} gas into the flue gas just before the reactor inlet. It was found that the injection of gaseous ammonia into the flue gas could decrease the concentration of both PCDD and PCDF by 34-75% from the solid phase and by 21-40% from the gas phase. Converting the results to I-TEQ values, it could reduce the total I-TEQ values of PCDD and PCDF in the sum of the flyash and exhaust flue gas by 42-75% and 24-57% respectively. The application of SO{sub 2} led to 99% and 93% reductions in the PCDD and PCDF average congener concentrations, respectively in the solid phase. In the gas phase, the total reductions were 89% and 76% for PCDD and PCDF, respectively. Moreover, addition of SO{sub 2} reduced the total I-TEQ value of PCDD and PCDF in the flyash and exhaust flue gas together by 60-86% and 72-82% respectively. Sulphur dioxide was more effective than ammonia in suppressing PCDD/F formation in flyash under the conditions investigated.

Hajizadeh, Yaghoub; Onwudili, Jude A. [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom); Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom)

2012-07-15T23:59:59.000Z

182

Final report to US Department of Energy: Cyclotron autoresonance accelerator for electron beam dry scrubbing of flue gases  

SciTech Connect (OSTI)

Several designs have been built and operated of microwave cyclotron autoresonance accelerators (CARA's) with electron beam parameters suitable for remediation of pollutants in flue gas emissions from coal-burning power plants. CARA designs have also been developed with a TW-level 10.6 micron laser driver for electron acceleration from 50 to 100 MeV, and with UHF drivers for proton acceleration to over 500 MeV. Dose requirements for reducing SO2, NOx, and particulates in flue gas emissions to acceptable levels have been surveyed, and used to optimize the design of an electron beam source to deliver this dose.

Hirshfield, J.L.

2001-05-25T23:59:59.000Z

183

Predictive Modeling of Mercury Speciation in Combustion Flue Gases Using GMDH-Based Abductive Networks  

E-Print Network [OSTI]

to develop. The use of modern data-based machine learning techniques has been recently introduced, including and boiler operating conditions. Prediction performance compares favourably with neural network models for future work to further improve performance. Index Terms: Mercury speciation, Flue gases, Boiler emissions

Abdel-Aal, Radwan E.

184

Evaluation of Wall Boundary Condition Parameters for Gas-Solids Fluidized Bed Simulations  

SciTech Connect (OSTI)

Wall boundary conditions for the solids phase have significant effects on numerical predictions of various gas-solids fluidized beds. Several models for the granular flow wall boundary condition are available in the open literature for numerical modeling of gas-solids flow. In this study, a model for specularity coefficient used in Johnson and Jackson boundary conditions by Li and Benyahia (AIChE Journal, 2012, 58, 2058-2068) is implemented in the open-source CFD code-MFIX. The variable specularity coefficient model provides a physical way to calculate the specularity coefficient needed by the partial-slip boundary conditions for the solids phase. Through a series of 2-D numerical simulations of bubbling fluidized bed and circulating fluidized bed riser, the model predicts qualitatively consistent trends to the previous studies. Furthermore, a quantitative comparison is conducted between numerical results of variable and constant specularity coefficients to investigate the effect of spatial and temporal variations in specularity coefficient.

Li, Tingwen; Benyahia, Sofiane

2013-10-01T23:59:59.000Z

185

Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report  

SciTech Connect (OSTI)

Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

Gillow, J.B.; Francis, A.

2011-07-01T23:59:59.000Z

186

Numerical Analysis of Metal Transfer in Gas Metal Arc Welding under Modified Pulsed Current Conditions  

E-Print Network [OSTI]

causes a thermal load too high to apply to thin sectioned or heat-sensitive materials. In an effort was assumed as the boundary condition for the calculation of the electromagnetic force. The calculations were agreement between calculation and experimental results. I. INTRODUCTION IN gas metal arc welding (GMAW

Zhang, YuMing

187

Separation of carbon dioxide from flue emissions using Endex principles  

E-Print Network [OSTI]

In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

Ball, R

2009-01-01T23:59:59.000Z

188

Testing of a Hydrogen Diffusion Flame Array Injector at Gas Turbine Conditions  

SciTech Connect (OSTI)

High-hydrogen gas turbines enable integration of carbon sequestration into coal-gasifying power plants, though NO{sub x} emissions are often high. This work explores nitrogen dilution of hydrogen diffusion flames to reduce thermal NO{sub x} emissions and avoid problems with premixing hydrogen at gas turbine pressures and temperatures. The burner design includes an array of high-velocity coaxial fuel and air injectors, which balances stability and ignition performance, combustor pressure drop, and flame residence time. Testing of this array injector at representative gas turbine conditions (16 atm and 1750 K firing temperature) yields 4.4 ppmv NO{sub x} at 15% O{sub 2} equivalent. NO{sub x} emissions are proportional to flame residence times, though these deviate from expected scaling due to active combustor cooling and merged flame behavior. The results demonstrate that nitrogen dilution in combination with high velocities can provide low NO{sub x} hydrogen combustion at gas turbine conditions, with significant potential for further NO{sub x} reductions via suggested design changes.

Weiland, Nathan T.; Sidwell, Todd G.; Strakey, Peter A.

2013-07-03T23:59:59.000Z

189

Assessment of existing H2/O2 chemical reaction mechanisms at reheat gas turbine conditions  

E-Print Network [OSTI]

This paper provides detailed comparisons of chemical reaction mechanisms of H2 applicable at high preheat temperatures and pressures relevant to gas turbine and particularly Alstom's reheat gas turbine conditions. It is shown that the available reaction mechanisms exhibit large differences in several important elementary reaction coefficients. The reaction mechanisms are assessed by comparing ignition delay and laminar flame speed results obtained from CHEMKIN with available data, however, the amount of data at these conditions is scarce and a recommended candidate among the mechanisms can presently not be selected. Generally, the results with the GRI-Mech and Leeds mechanisms deviate from the Davis, Li, O'Conaire, Konnov and San Diego mechanisms, but there are also significant deviations between the latter five mechanisms that altogether are better adapted to hydrogen. The differences in ignition delay times between the dedicated hydrogen mechanisms (O'Conaire, Li and Konnov) range from approximately a maxim...

Weydahl, Torleif; Seljeskog, Morten; Haugen, Nils Erland L

2011-01-01T23:59:59.000Z

190

Hybrid particle traps and conditioning procedure for gas insulated transmission lines  

DOE Patents [OSTI]

A gas insulated transmission line includes an outer sheath, an inner condor within the outer sheath, insulating supports supporting the inner conductor within the outer sheath, and an insulating gas electrically insulating the inner conductor from the outer sheath. An apertured particle trapping ring is disposed within the outer sheath, and the trapping ring has a pair of dielectric members secured at each longitudinal end thereof, with the dielectric members extending outwardly from the trapping ring along an arc. A support sheet having an adhesive coating thereon is secured to the trapping ring and disposed on the outer sheath within the low field region formed between the trapping ring and the outer sheath. A conditioning method used to condition the transmission line prior to activation in service comprises applying an AC voltage to the inner conductor in a plurality of voltage-time steps, with the voltage-time steps increasing in voltage magnitude while decreasing in time duration.

Dale, Steinar J. (Monroeville, PA); Cookson, Alan H. (Churchill, PA)

1982-01-01T23:59:59.000Z

191

Strategies for gas production from hydrate accumulations under various geologic conditions  

E-Print Network [OSTI]

JNOC/GSC Mallik 2L- 38 Gas Hydrate Research Well, Mackenziedeposits. INTRODUCTION Gas hydrates are solid crystallinequantity of hydrocarbon gas hydrates range between 10 15 to

Moridis, G.; Collett, T.

2003-01-01T23:59:59.000Z

192

WATER-GAS SHIFT KINETICS OVER IRON OXIDE CATALYSTS AT MEMBRANE REACTOR CONDITIONS  

SciTech Connect (OSTI)

This report covers the second year of a project investigating water-gas shift catalysts for use in membrane reactors. It has been established that a simple iron high temperature shift catalyst becomes ineffective in a membrane reactor because the reaction rate is severely inhibited by the build-up of the product CO{sub 2}. During the past year, an improved microkinetic model for water-gas shift over iron oxide was developed. Its principal advantage over prior models is that it displays the correct asymptotic behavior at all temperatures and pressures as the composition approaches equilibrium. This model has been used to explore whether it might be possible to improve the performance of iron high temperature shift catalysts under conditions of high CO{sub 2} partial pressure. The model predicts that weakening the surface oxygen bond strength by less than 5% should lead to higher catalytic activity as well as resistance to rate inhibition at higher CO{sub 2} partial pressures. Two promoted iron high temperature shift catalysts were studied. Ceria and copper were each studied as promoters since there were indications in the literature that they might weaken the surface oxygen bond strength. Ceria was found to be ineffective as a promoter, but preliminary results with copper promoted FeCr high temperature shift catalyst show it to be much more resistant to rate inhibition by high levels of CO{sub 2}. Finally, the performance of sulfided CoMo/Al{sub 2}O{sub 3} catalysts under conditions of high CO{sub 2} partial pressure was simulated using an available microkinetic model for water-gas shift over this catalyst. The model suggests that this catalyst might be quite effective in a medium temperature water-gas shift membrane reactor, provided that the membrane was resistant to the H{sub 2}S that is required in the feed.

Carl R.F. Lund

2001-08-10T23:59:59.000Z

193

Solution of the Kramers' problem about isothermal sliding of moderately dense gas with accomodation boundary conditions  

E-Print Network [OSTI]

Half-space boundary Kramers' problem about isothermal sliding of moderate dense gas with accomodation boundary conditions along a flat firm surface is solving. The new method of the solution of boundary problems of the kinetic theory is applied (see JVMMF, 2012, 52:3, 539-552). The method allows to receive the solution with arbitrary degree of accuracy. The idea of representation of boundary condition on distribution function in the form of source in the kinetic equation serves as the basis for the method mentioned above. By means of Fourier integrals the kinetic equation with a source comes to the Fredholm integral equation of the second kind. The solution has been received in the form of Neumann's number.

A. V. Latyshev; A. D. Kurilov

2014-12-30T23:59:59.000Z

194

WATER-GAS SHIFT KINETICS OVER IRON OXIDE CATALYSTS AT MEMBRANE REACTOR CONDITIONS  

SciTech Connect (OSTI)

The kinetics of water-gas shift were studied over ferrochrome catalysts under conditions with high carbon dioxide partial pressures, such as would be expected in a membrane reactor. The catalyst activity is inhibited by increasing carbon dioxide partial pressure. A microkinetic model of the reaction kinetics was developed. The model indicated that catalyst performance could be improved by decreasing the strength of surface oxygen bonds. Literature data indicated that adding either ceria or copper to the catalyst as a promoter might impart this desired effect. Ceria-promoted ferrochrome catalysts did not perform any better than unpromoted catalyst at the conditions tested, but copper-promoted ferrochrome catalysts did offer an improvement over the base ferrochrome material. A different class of water-gas shift catalyst, sulfided CoMo/Al{sub 2}O{sub 3} is not affected by carbon dioxide and may be a good alternative to the ferrochrome system, provided other constraints, notably the requisite sulfur level and maximum temperature, are not too limiting. A model was developed for an adiabatic, high-temperature water-gas shift membrane reactor. Simulation results indicate that an excess of steam in the feed (three moles of water per mole of CO) is beneficial even in a membrane reactor as it reduces the rate of adiabatic temperature rise. The simulations also indicate that much greater improvement can be attained by improving the catalyst as opposed to improving the membrane. Further, eliminating the inhibition by carbon dioxide will have a greater impact than will increasing the catalyst activity (assuming inhibition is still operative). Follow-up research into the use of sulfide catalysts with continued kinetic and reactor modeling is suggested.

Carl R.F. Lund

2002-08-02T23:59:59.000Z

195

Cyclic carbonation calcination studies of limestone and dolomite for CO{sub 2} separation from combustion flue gases - article no. 011801  

SciTech Connect (OSTI)

Naturally occurring limestone and dolomite samples, originating from different geographical locations, were tested as potential sorbents for carbonation/calcination based CO{sub 2} capture from combustion flue gases. Samples have been studied in a thermogravimetric analyzer under simulated flue gas conditions at three calcination temperatures, viz., 750{sup o}C, 875{sup o}C, and 930{sup o}C for four carbonation calcination reaction (CCR) cycles. The dolomite sample exhibited the highest rate of carbonation than the tested limestones. At the third cycle, its CO{sub 2} capture capacity per kilogram of the sample was nearly equal to that of Gotland, the highest reacting limestone tested. At the fourth cycle it surpassed Gotland, despite the fact that the CaCO{sub 3} content of the Sibbo dolomite was only 2/3 of that of the Gotland. Decay coefficients were calculated by a curve fitting exercise and its value is lowest for the Sibbo dolomite. That means, most probably its capture capacity per kilogram of the sample would remain higher well beyond the fourth cycle. There was a strong correlation between the calcination temperature, the specific surface area of the calcined samples, and the degree of carbonation. It was observed that the higher the calcination temperature, the lower the sorbent reactivity. For a given limestone/dolomite sample, sorbents CO{sub 2} capture capacity depended on the number of CCR cycles and the calcination temperature. According to the equilibrium thermodynamics, the CO{sub 2} partial pressure in the calciner should be lowered to lower the calcination temperature. This can be achieved by additional steam supply into the calciner. Steam could then be condensed in an external condenser to single out the CO{sub 2} stream from the exit gas mixture of the calciner. A calciner design based on this concept is illustrated.

Senthoorselvan, S.; Gleis, S.; Hartmut, S.; Yrjas, P.; Hupa, M. [TUM, Garching (Germany)

2009-01-15T23:59:59.000Z

196

Influence of EGR (Exhaust Gas Recirculation) on Engine Components Durability & Lubricating Oil Condition  

E-Print Network [OSTI]

Abstract––Diesel engines are extensively used in automotive systems due to their low fuel consumption and very low CO emissions. Despite of these advantages, diesel engines suffer from environmental and health drawbacks such as high levels of NOx and particulate matter. Exhaust Gas Recirculation ( EGR) is an effective technique which is being used widely to control the NOx emissions from diesel engines. However, the use of EGR leads to rise in soot emission and it causes the problems inside the engine like degradation of lubricating oil, enhanced engine component wear etc. Therefore, it requires a study of influence of EGR on engine components and lubricating oil. This can be achieved only with different experimental investigation. In the present work, Engine test and Tribology test with lubricants ( Without EGR and With EGR) have been carried out to evaluate the effect of EGR on tribo- characteristics of engine components and lubricating oil condition. Influencing parameters like load, speed, temperature were selected as per the engine components operating condition. Friction and wear characteristics were measured and compared with the actual engine wear results to validate the test parameters. I.

Mrs Rita; S. Pimpalkar

197

Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions  

SciTech Connect (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device, Pt/SiO{sub 2}/SiC that can detect hydrogen-containing species in chemically reactive, high temperature (600 C) environments. We demonstrate that the device can be used as a hydrogen monitor in syngas applications of common interferants as well as sulfur and water vapor. These measurements were made in the Catalyst Screening Unit at NETL, Morgantown under atmospheric conditions. The sensor response to hydrogen gas at 350 C is 240 mV/decade, this is significantly higher than the device response to room temperature gas or that predicted from vacuum chamber studies. The enhanced catalytic activity of the platinum sensing film under energy plant operating conditions was investigated via AFM, x-ray diffraction, TEM and x-ray photoelectron spectroscopy. Our characterization indicated that exposure to high temperature gases significantly modifies the morphology of the Pt catalytic film and the Pt/SiO{sub 2} interfacial region, which we tentatively attribute to the enhanced hydrogen sensitivity of the sensing film. A model for the hydrogen/oxygen response of the SiC device under atmospheric conditions was developed. It is based on two independent phenomena: a chemically induced shift in the metal-semiconductor work function difference and the passivation/creation of charged states at the SiO{sub 2}-SiC interface. The optimum operating set point for the SiC sensor with respect to response time and long term reliability was determined to be close to mid-gap. Ultrahigh vacuum (UHV) techniques were used to investigate the effects of sulfur contamination on the Pt gate. Exposure to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20-600 times greater than the H2S level, rapidly coated the gate with a monolayer of sulfur. Although hydrogen exposure could not remove the adsorbed sulfur, oxygen was effective at removing sulfur with no evidence of irreversible changes in device behavior. The role of oxygen in the functioning of the SiC sensors was also investigated. All of the results are consistent with oxygen acting through its surface reactions with hydrogen, including the need for oxygen to reset the device to a fully hydrogen-depleted state and competition between hydrogen oxidation and hydrogen diffusion to metal/oxide interface sites. A strong sensor response to the unsaturated linear hydrocarbon propene (C{sub 3}H{sub 6}) was observed.

Ruby Ghosh; Reza Loloee; Roger Tobin

2008-09-30T23:59:59.000Z

198

Study of the Effects of Ambient Conditions Upon the Performance of Fan Powered, Infrared Natural Gas Burners  

SciTech Connect (OSTI)

The objective of this investigation was to characterize the operation of a fan-powered, infrared burner (IR burner) at various gas compositions and ambient conditions, develop numerical model to simulate the burner performances, and provide design guidelines for appliances containing PIR burners for satisfactory performance.

Clark Atlanta University

2002-12-02T23:59:59.000Z

199

An Electrochemically-mediated Gas Separation Process for Carbon Abatement  

E-Print Network [OSTI]

This work describes a promising alternative to conventional thermal processes for absorber/desorber processing of for removal of CO[subscript 2] from flue gas streams at fossil fuel fired power plants. Our electrochemica ...

Stern, Michael C.

200

Published in `AI Communications 9 journal', pp1-17. Published by IOS Press (1996) TIGERTM: Knowledge Based Gas Turbine Condition Monitoring  

E-Print Network [OSTI]

: Knowledge Based Gas Turbine Condition Monitoring Dr. Robert Milne and Dr. Charlie Nicol Intelligent, 11 Colon, Barcelona, 08222 Terrassa. Spain 1. INTRODUCTION Given the critical nature of gas turbines and increasing the availability of the gas turbine. Routine preventative maintenance techniques have been used

Travé-Massuyès, Louise

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Prediction of gas-hydrate formation conditions in production and surface facilities  

E-Print Network [OSTI]

such as methane, ethane, propane, carbon dioxide and hydrogen sulfide to binary, ternary, and natural gas mixtures. I used the Statistical Analysis Software (SAS) to find the best correlations among variables such as specific gravity and pseudoreduced pressure...

Ameripour, Sharareh

2006-10-30T23:59:59.000Z

202

Laboratory Investigations of a Low-Swirl Injector with H2 and CH4 at Gas Turbine Conditions  

SciTech Connect (OSTI)

Laboratory experiments were conducted at gas turbine and atmospheric conditions (0.101 < P{sub 0} < 0.810 MPa, 298 < T{sub 0} < 580K, 18 < U{sub 0} < 60 m/s) to characterize the overall behaviors and emissions of the turbulent premixed flames produced by a low-swirl injector (LSI) for gas turbines. The objective was to investigate the effects of hydrogen on the combustion processes for the adaptation to gas turbines in an IGCC power plant. The experiments at high pressures and temperatures showed that the LSI can operate with 100% H{sub 2} at up to {phi} = 0.5 and has a slightly higher flashback tolerance than an idealized high-swirl design. With increasing H{sub 2} fuel concentration, the lifted LSI flame begins to shift closer to the exit and eventually attaches to the nozzle rim and assumes a different shape at 100% H{sub 2}. The STP experiments show the same phenomena. The analysis of velocity data from PIV shows that the stabilization mechanism of the LSI remains unchanged up to 60% H{sub 2}. The change in the flame position with increasing H{sub 2} concentration is attributed to the increase in the turbulent flame speed. The NO{sub x} emissions show a log linear dependency on the adiabatic flame temperature and the concentrations are similar to those obtained previously in a LSI prototype developed for natural gas. These results show that the LSI exhibits the same overall behaviors at STP and at gas turbine conditions. Such insight will be useful for scaling the LSI to operate at IGCC conditions.

Cheng, R. K.; Littlejohn, D.; Strakey, P.A.; Sidwell, T.

2008-03-05T23:59:59.000Z

203

Gas-solid carbonation of Ca(OH)2 and CaO particles under non-isothermal and isothermal conditions by using a thermogravimetric analyzer  

E-Print Network [OSTI]

1 Gas-solid carbonation of Ca(OH)2 and CaO particles under non-isothermal and isothermal conditions Gas Control 11, 3 (2012) 172-180" DOI : 10.1016/j.ijggc.2012.08.009 #12;2 Abstract The gas, quantify the gas-solid carbonation extent and the carbonation kinetics of Ca(OH)2 and CaO; and secondly

Boyer, Edmond

204

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

2010-11-09T23:59:59.000Z

205

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D.; Bourcier, William L.

2014-08-19T23:59:59.000Z

206

In situ x-ray photoelectron spectroscopy studies of gas/solidinterfaces at near-ambient conditions  

SciTech Connect (OSTI)

X-ray photoelectron spectroscopy (XPS) is a quantitative, chemically specific technique with a probing depth of a few angstroms to a few nanometers. It is therefore ideally suited to investigate the chemical nature of the surfaces of catalysts. Because of the scattering of electrons by gas molecules, XPS is generally performed under vacuum conditions. However, for thermodynamic and/or kinetic reasons, the catalyst's chemical state observed under vacuum reaction conditions is not necessarily the same as that of a catalyst under realistic operating pressures. Therefore, investigations of catalysts should ideally be performed under reaction conditions, i.e., in the presence of a gas or gas mixtures. Using differentially pumped chambers separated by small apertures, XPS can operate at pressures of up to 1 Torr, and with a recently developed differentially pumped lens system, the pressure limit has been raised to about 10 Torr. Here, we describe the technical aspects of high-pressure XPS and discuss recent applications of this technique to oxidation and heterogeneous catalytic reactions on metal surfaces.

Bluhm, Hendrik; Havecker, Michael; Knop-Gericke, Axel; Kiskinova,Maya; Schlogl, Robert; Salmeron, Miquel

2007-12-03T23:59:59.000Z

207

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . . 3-5 3.4 Emission

Zevenhoven, Ron

208

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

Laughlin, Robert B.

209

Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions  

SciTech Connect (OSTI)

A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high pH and temperatures.

Lee, Joo-Youp

2013-09-30T23:59:59.000Z

210

The Effects of Oxy-firing Conditions on Gas-phase Mercury Oxidation by Chlorine and Bromine  

SciTech Connect (OSTI)

Bench-scale experiments were conducted in a quartz-lined, natural gas-fired reactor with the combustion air replaced with a blend of 27 mole percent oxygen, with the balance carbon dioxide. Quench rates of 210 and 440 K/s were tested. In the absence of sulfur dioxide, the oxy-firing environment caused a remarkable increase in oxidation of mercury by chlorine. At 400 ppm chlorine (as HCl equivalent), air-firing results in roughly 5 percent oxidation. At the same conditions with oxy-firing, oxidation levels are roughly 80 percent. Oxidation levels with bromine at 25 and 50 ppm (as HBr equivalent) ranged from 80 to 95 percent and were roughly the same for oxy- and air-firing conditions. Kinetic calculations of levels of oxidation at air- and oxy-conditions captured the essential features of the experimental results but have not revealed a mechanistic basis for the oxidative benefits of oxy-firing conditions. Mixtures of 25 ppm bromine and 100 and 400 ppm chlorine gave more than 90 percent oxidation. At all conditions, the effects of quench rate were not significant. The presence of 500 ppm SO2 caused a dramatic decline in the levels of oxidation at all oxy-fired conditions examined. This effect suggests that SO2 may be preventing oxidation in the gas phase or preventing oxidation in the wetconditioning system that was used in quantifying oxidized and elemental mercury concentrations. Similar effects of SO2 have been noted with air-firing. The addition of sodium thiosulfate to the hydroxide impingers that are part of wet conditioning systems may prevent liquid-phase oxidation from occurring.

Buitrago, Paula; Silcox, Geoffrey

2010-06-30T23:59:59.000Z

211

Systems and methods of monitoring acoustic pressure to detect a flame condition in a gas turbine  

DOE Patents [OSTI]

A method may detect a flashback condition in a fuel nozzle of a combustor. The method may include obtaining a current acoustic pressure signal from the combustor, analyzing the current acoustic pressure signal to determine current operating frequency information for the combustor, and indicating that the flashback condition exists based at least in part on the current operating frequency information.

Ziminsky, Willy Steve (Simpsonville, SC); Krull, Anthony Wayne (Anderson, SC); Healy, Timothy Andrew (Simpsonville, SC), Yilmaz, Ertan (Glenville, NY)

2011-05-17T23:59:59.000Z

212

Silicon Carbide Micro-devices for Combustion Gas Sensing under Harsh Conditions  

SciTech Connect (OSTI)

A sensor based on the wide bandgap semiconductor, silicon carbide (SiC), has been developed for the detection of combustion products in power plant environments. The sensor is a catalytic gate field effect device that can detect hydrogen-containing species in chemically reactive, high temperature environments. For fast and stable sensor response measurements, a gate activation process is required. Activation of all sensors took place by switching back and forth between oxidizing (1.0% oxygen in nitrogen) and reducing (10% hydrogen in nitrogen) gases for several hours at a sensor temperature {ge}620 C. All 52 devices on the sensor chip were activated simultaneously by flooding the entire chip with gas. The effects of activation on surface morphology and structure of Pt gates before and after activation were investigated. The optical images obtained from Pt gates demonstrated a clear transition from a smooth and shiny surface to a grainy and cloudy surface morphology. XRD scans collected from Pt gates suggest the presence of an amorphous layer and species other than Pt (111) after activation. The reliability of the gate insulator of our metal-oxide-SiC sensors for long-term device operation at 630 C was studied. We find that the dielectric is stable against breakdown due to electron injection from the substrate with gate leakage current densities as low at 5nA/cm{sup 2} at 630 C. We also designed and constructed a new nano-reactor capable of high gas flow rates at elevated pressure. Our reactor, which is a miniature version of an industrial reactor, is designed to heat the flowing gas up to 700 C. Measurements in ultrahigh vacuum demonstrated that hydrogen sulfide readily deposits sulfur on the gate surface, even at the very high hydrogen/hydrogen sulfide ratios (10{sup 3}-10{sup 5}) expected in applications. Once deposited, the sulfur adversely affects sensor response, and could not be removed by exposure to hydrogen at the temperatures and pressures accessible in the ultrahigh vacuum experiments. Oxygen exposures, however, were very effective at removing sulfur, and the device performance after sulfur removal was indistinguishable from performance before exposure to H{sub 2}S.

Ruby N. Ghosh; Reza Loloee; Roger G. Tobin; Yung Ho Kahng

2006-04-01T23:59:59.000Z

213

Performance and evaluation of gas engine driven rooftop air conditioning equipment at the Willow Grove (PA) Naval Air Station  

SciTech Connect (OSTI)

In a field evaluation conducted for the US Department of Energy (DOE) Office of Federal Energy Management Program (FEMP), the Pacific Northwest Laboratory (PNL) examined the performance of a new US energy-related technology under the FEMP Test Bed Demonstration Program. The technology was a 15-ton natural gas engine driven roof top air conditioning unit. Two such units were installed on a naval retail building to provide space conditioning to the building. Under the Test Bed Demonstration Program, private and public sector interests are focused to support the installation and evaluation of new US technologies in the federal sector. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) with DOE were the American Gas Cooling Center, Philadelphia Electric Company, Thermo King Corporation, and the US Naval Air Station at Willow Grove, Pennsylvania. Equipment operating and service data as well as building interior and exterior conditions were secured for the 1992 cooling season. Based on a computer assessment of the building using standard weather data, a comparison was made with the energy and operating costs associated with the previous space conditioning system. Based on performance during the 1992 cooling season and adjusted to a normal weather year, the technology will save the site $6,000/yr in purchased energy costs. An additional $9,000 in savings due to electricity demand ratchet charge reductions will also be realized. Detailed information on the technology, the installation, and the results of the technology test are provided to illustrate the advantages to the federal sector of using this technology. A history of the CRADA development process is also reported.

Armstrong, P.R.; Conover, D.R.

1993-05-01T23:59:59.000Z

214

Process for selected gas oxide removal by radiofrequency catalysts  

DOE Patents [OSTI]

This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

Cha, C.Y.

1993-09-21T23:59:59.000Z

215

Study of the effects of ambient conditions upon the performance of fam powered, infrared, natural gas burners  

SciTech Connect (OSTI)

The objective of this investigation is to characterize the operation of a fan powered infrared burner (PIR burner) at various gas compositions and ambient conditions and develop design guidelines for appliances containing PIR burners for satisfactory performance. The fan powered infrared burner is a technology introduced more recently in the residential and commercial markets. It is a surface combustor that elevates the temperature of the burner head to a radiant condition. A variety of metallic and ceramic materials are used for the burner heads. It has been demonstrated that infrared burners produce low CO and NO{sub x} emissions in a controlled geometric space. This project consists of both experimental research and numerical analysis. To conduct the experiments, an experimental setup has been developed and installed in the Combustion Laboratory at Clerk Atlanta University (CAU). This setup consists of a commercial deep fat fryer that has been modified to allow in-situ radiation measurements on the surface of the infrared burner via a view port installed on the side wall of the oil vat. Proper instrumentation including fuel/air flow rate measurement, exhaust gas emission measurement, and radiation measurement has been developed. The project is progressing well. The scheduled tasks for this period of time were conducted smoothly. Specifically: 1. Baseline experimental study at CAU has been completed. The data are now under detailed analysis and will be reported in next quarterly report. 2. Theoretical formulation and analysis of the PIR burner performance model are continuing. Preliminary results have been obtained.

Bai, Tiejun

1996-10-01T23:59:59.000Z

216

Method for high temperature mercury capture from gas streams  

DOE Patents [OSTI]

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

217

Laboratory Investigations of a Low-Swirl Injector with H2 and CH4 at Gas Turbine Conditions  

E-Print Network [OSTI]

Journal of Engineering for Gas Turbines and Power, 130 C. K.Journal of Engineering for Gas Turbines and Power, 130 (2) (of Engineering for Gas Turbines and Power-Transactions of

Cheng, R. K.

2009-01-01T23:59:59.000Z

218

Reducing the cost of CO{sub 2} capture from flue gases using pressure swing adsorption  

SciTech Connect (OSTI)

Pressure swing adsorption (PSA) processes have been used extensively for gas separation, especially in the separation of hydrogen from CO{sub 2}, and in air purification. The objective of this paper is to examine the economic feasibility of pressure swing adsorption (PSA) for recovering CO{sub 2} from postcombustion power plant flue gas. The analysis considers both high-pressure feed and vacuum desorption using commercial adsorbent 13X, which has a working capacity of 2.2 mol/kg and CO{sub 2}/N{sub 2} selectivity of 54. The results show that using vacuum desorption reduces the capture cost from US$57 to US$51 per ton of CO{sub 2} avoided and is comparable in cost to CO{sub 2} capture using conventional MEA absorption of US$49 per ton of CO{sub 2} avoided. In this paper, a sensitivity analysis is also presented showing the effect on the capture cost with changes in process cycle; feed pressure and evacuation pressure; improvements the adsorbent characteristics; and selectivity and working capacity. The results show that a hypothetical adsorbent with a working capacity of 4.3 mol/kg and a CO{sub 2}/N{sub 2} selectivity of 150 can reduce the capture cost to US$30 per ton of CO{sub 2} avoided.

Ho, M.T.; Allinson, G.W.; Wiley, D.E. [University of New South Wales, Sydney, NSW (Australia)

2008-07-15T23:59:59.000Z

219

Improving the performance of stainless-steel DC high voltage photoelectron gun cathode electrodes via gas conditioning with helium or krypton  

SciTech Connect (OSTI)

Gas conditioning was shown to eliminate field emission from cathode electrodes used inside DC high voltage photoelectron guns, thus providing a reliable means to operate photoguns at higher voltages and field strengths. Measurements and simulation results indicate that gas conditioning eliminates field emission from cathode electrodes via two mechanisms: sputtering and implantation, with the benefits of implantation reversed by heating the electrode. We have studied five stainless steel electrodes (304L and 316LN) that were polished to approximately 20 nm surface roughness using diamond grit, and evaluated inside a high voltage apparatus to determine the onset of field emission as a function of voltage and field strength. The field emission characteristics of each electrode varied significantly upon the initial application of voltage but improved to nearly the same level after gas conditioning using either helium or krypton, exhibiting less than 10 pA field emission at ?225 kV bias voltage with a 50 mm cathode/anode gap, corresponding to a field strength of ~13 MV/m. Field emission could be reduced with either gas, but there were conditions related to gas choice, voltage and field strength that were more favorable than others.

Bastaninejad, Mahzad [ODU; Elmustafa, Abdelmageed [ODU; Forman, Eric I. [JLAB; Clark, James [JLAB; Covert, Steven R. [JLAB; Grames, Joseph M. [JLAB; Hansknecht, John C. [JLAB; Hernandez-Garcia, Carlos [JLAB; Poelker, Bernard [JLAB; Suleiman, Riad S. [JLAB

2014-10-01T23:59:59.000Z

220

natural gas+ condensing flue gas heat recovery+ water creation+ CO2  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectric Coop,SaveWhiskey Flatshydro Home Water Powerlaunchmulticolorreduction+

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

OpenEI Community - natural gas+ condensing flue gas heat recovery+ water  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth'sOklahoma/Geothermal < Oklahomast, 2012CoastfredResult Formats

222

High potential recovery -- Gas repressurization  

SciTech Connect (OSTI)

The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

Madden, M.P.

1998-05-01T23:59:59.000Z

223

Effect of Synthesis Condition and Annealing on the Sensitivity and Stability of Gas Sensors Made of Zn-Doped y-Fe2O3 Particles  

E-Print Network [OSTI]

In this study, the effect of synthesis conditions and annealing process on the sensitivity and stability of gas sensors made of flame-synthesized Zn-doped ?-Fe2O3 particles was investigated. Zn-doped ?-Fe2O3 particles were synthesized by flame...

Kim, Taeyang

2010-10-12T23:59:59.000Z

224

A study of diesel combustion process under the condition of EGR and high-pressure fuel injection with gas sampling method  

SciTech Connect (OSTI)

It is well known that a high-pressure fuel injection is effective for the reduction in particulates and smoke emissions. Exhaust gas recirculation (EGR) is effective for the reduction in NO{sub x} emission. In this study an experiment aiming to understand more comprehensive combustion under the condition of EGR and high-pressure fuel injection was carried out by using gas sampling method for the purpose of understanding what occurred inside the spray before and after combustion. The number of combustion cycles in this engine can be controlled in order to change EGR conditions by adjusting the residual gas concentration in the cylinder. Main results were: (1) close to the nozzle tip, the sampling gas data showed little reaction which implies that combustion never occurs in this area during the injection period; (2) in the case of high-pressure fuel injection O{sub 2} concentration decreased faster and air dilution was more active and earlier, this may cause the decrease of smoke emissions due to accelerated soot oxidation; (3) in the case of EGR, combustion was poor since oxygen concentration was insufficient, thus, inactivity of oxidation reaction caused reduction in NO{sub x} emission; (4) in the case of increasing the amounts of N{sub 2} gas while keeping the O{sub 2} content constant (same amount as without EGR), NO{sub x} emission decreased without deterioration of smoke emission and Pmi.

Shimazaki, Naoki; Hatanaka, Hirokazu; Yokota, Katsuhiko; Nakahira, Toshio

1996-09-01T23:59:59.000Z

225

Evaluating energy dissipation during expansion in a refrigeration cycle using flue pipe acoustic resonators  

E-Print Network [OSTI]

This research evaluates the feasibility of using a flue pipe acoustic resonator to dissipate energy from a refrigerant stream in order to achieve greater cooling power from a cryorefrigeration cycle. Two models of the ...

Luckyanova, Maria N. (Maria Nickolayevna)

2008-01-01T23:59:59.000Z

226

Numerical analysis of hypersonic continuum and rarefied gas flows near blunt probes is presented under conditions of intensive gas blowing from the surface.  

E-Print Network [OSTI]

1 Abstract Numerical analysis of hypersonic continuum and rarefied gas flows near blunt probes injection, hydrogen combustion, hypersonic flow, exponential box-scheme, direct-simulation Monte-Carlo method. 1 Introduction Numerical and experimental studies [1, 2] of aerothermodynamics of hypersonic

Riabov, Vladimir V.

227

Performance and evaluation of gas-engine-driven rooftop air conditioning equipment at the Willow Grove Naval Air Station. Final report (revised October 21, 1996)  

SciTech Connect (OSTI)

The performance was evaluated of a new US cooling technology that has been installed for the first time at a federal facility. The technology is a 15-ton natural gas-engine-driven rooftop air conditioning unit made by Thermo King. Two units were installed to serve the Navy Exchange at Willow Grove. The savings potential at Willow Grove is described and that in the federal sector estimated. Conditions for implementation are discussed. In summary, the new technology is generally cost-effective at sites where marginal electricity cost (per MBtu at the meter) is more than 4 times the marginal gas cost (per MBtu at the meter) and annual full-load-equivalent cooling hours exceed 2,000.

Armstrong, P.R.; Katipamula, S.

1996-10-01T23:59:59.000Z

228

Comparisons of diffusive and advective fluxes of gas phase volatile organic compounds (VOCs) in unsaturated zones under natural conditions  

E-Print Network [OSTI]

) in unsaturated zones under natural conditions Kehua You a , Hongbin Zhan a,b, a Department of Geology

Zhan, Hongbin

229

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy  

SciTech Connect (OSTI)

Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad; Baiker, Alfons, E-mail: baiker@chem.ethz.ch [Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Switzerland)

2014-08-15T23:59:59.000Z

230

Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler  

SciTech Connect (OSTI)

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

None

1998-07-01T23:59:59.000Z

231

A cement kiln flue-dust evaluated as a soil liming material  

E-Print Network [OSTI]

A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

Stacha, Raimund

1973-01-01T23:59:59.000Z

232

CHARACTERIZATION OF CONDITIONS OF NATURAL GAS STORAGE RESERVOIRS AND DESIGN AND DEMONSTRATION OF REMEDIAL TECHNIQUES FOR DAMAGE MECHANISMS FOUND THEREIN  

SciTech Connect (OSTI)

The underground gas storage (UGS) industry uses over 400 reservoirs and 17,000 wells to store and withdrawal gas. As such, it is a significant contributor to gas supply in the United States. It has been demonstrated that many UGS wells show a loss of deliverability each year due to numerous damage mechanisms. Previous studies estimate that up to one hundred million dollars are spent each year to recover or replace a deliverability loss of approximately 3.2 Bscf/D per year in the storage industry. Clearly, there is a great potential for developing technology to prevent, mitigate, or eliminate the damage causing deliverability losses in UGS wells. Prior studies have also identified the presence of several potential damage mechanisms in storage wells, developed damage diagnostic procedures, and discussed, in general terms, the possible reactions that need to occur to create the damage. However, few studies address how to prevent or mitigate specific damage types, and/or how to eliminate the damage from occurring in the future. This study seeks to increase our understanding of two specific damage mechanisms, inorganic precipitates (specifically siderite), and non-darcy damage, and thus serves to expand prior efforts as well as complement ongoing gas storage projects. Specifically, this study has resulted in: (1) An effective lab protocol designed to assess the extent of damage due to inorganic precipitates; (2) An increased understanding of how inorganic precipitates (specifically siderite) develop; (3) Identification of potential sources of chemical components necessary for siderite formation; (4) A remediation technique that has successfully restored deliverability to storage wells damaged by the inorganic precipitate siderite (one well had nearly a tenfold increase in deliverability); (5) Identification of the types of treatments that have historically been successful at reducing the amount of non-darcy pressure drop in a well, and (6) Development of a tool that can be used by operators to guide treatment selection in wells with significant non-darcy damage component. In addition, the effectiveness of the remediation treatment designed to reduce damage caused by the inorganic precipitate siderite was measured, and the benefits of this work are extrapolated to the entire U.S. storage industry. Similarly the potential benefits realized from more effective identification and treatment of wells with significant nondarcy damage component are also presented, and these benefits are also extrapolated to the entire U.S. storage industry.

J.H. Frantz Jr; K.G. Brown; W.K. Sawyer; P.A. Zyglowicz; P.M. Halleck; J.P. Spivey

2004-12-01T23:59:59.000Z

233

Energy Savings and Economics of Advanced Control Strategies for Packaged Air-Conditioning Units with Gas Heat  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) with funding from the U.S. Department of Energy's Building Technologies Program (BTP) evaluated a number of control strategies that can be implemented in a controller, to improve the operational efficiency of the packaged air conditioning units. The two primary objectives of this research project are: (1) determine the magnitude of energy savings achievable by retrofitting existing packaged air conditioning units with advanced control strategies not ordinarily used for packaged units and (2) estimating what the installed cost of a replacement control with the desired features should be in various regions of the U.S. This document reports results of the study.

Wang, Weimin; Katipamula, Srinivas; Huang, Yunzhi; Brambley, Michael R.

2011-12-31T23:59:59.000Z

234

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, October 1, 1996--December 31, 1996  

SciTech Connect (OSTI)

This quarterly technical progress report describes work performed under DOE Grant No. DE-FG22-94MT94011 during the period September 1, 1996 to December 31, 1996 which covers the nineth quarter of the project. The objective of this investigation is to characterize the operation of a fan powered infrared burner (IR burner) at various gas compositions and ambient conditions and develop design guidelines for appliances containing PIR burners for satisfactory performance. The fan powered infrared burner is a technology introduced more recently in the residential and commercial markets. It is a surface combustor that elevates the temperature of the burner head to a radiant condition. A variety of metallic and ceramic materials are used for the burner heads. It has been demonstrated that infrared burners produce low CO and NO{sub x} emissions in a controlled geometric space. As the environmental regulations become more stringent, infrared burners are receiving increasing interests.

Bai, T.

1997-01-01T23:59:59.000Z

235

Proceedings: EPRI Workshop on Condition and Remaining Life Assessment of Hot Gas Path Components of Combustion Turbines  

SciTech Connect (OSTI)

The severity of modern combustion turbine operation is a reflection of industry competition to achieve higher thermal efficiency. This competitive stance has resulted in new turbine designs and material systems that have at times outpaced condition and remaining life assessment (CARLA) technology. These proceedings summarize a two-day workshop on CARLA technology for hot section components of large combustion turbines.

None

2000-05-01T23:59:59.000Z

236

Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler  

SciTech Connect (OSTI)

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, especially NOX. The project involved operating gas reburning technology combined with low NO, burner technology (GR-LNB) on a coal-fired utility boiler. Low NOX burners are designed to create less NOX than conventional burners. However, the NO, control achieved is in the range of 30-60-40, and typically 50%. At the higher NO, reduction levels, CO emissions tend to be higher than acceptable standards. Gas Reburning (GR) is designed to reduce the level of NO. in the flue gas by staged fuel combustion. When combined, GR and LNBs work in harmony to both minimize NOX emissions and maintain an acceptable level of CO emissions. The demonstration was performed at Public Service Company of Colorado's (PSCO) Cherokee Unit 3, located in Denver, Colorado. This unit is a 172 MW. wall-fired boiler that uses Colorado bituminous, low-sulfur coal and had a pre GR-LNB baseline NOX emission of 0.73 lb/1 Oe Btu. The target for the project was a reduction of 70 percent in NOX emissions. Project sponsors included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation (EER). EER conducted a comprehensive test demonstration program over a wide range of boiler conditions. Over 4,000 hours of operation were achieved. Intensive measurements were taken to quantify the reductions in NOX emissions, the impact on boiler equipment and operability, and all factors influencing costs. The results showed that GR-LNB technology achieved excellent emission reductions. Although the performance of the low NOX burners (supplied by others) was somewhat less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 180A. The performance goal of 70% reduction was met on many test runs, but at higher gas heat inputs. The impact on boiler equipment was determined to be very minimal. Toward the end of the testing, the flue gas recirculation (used to enhance gas penetration into the furnace) system was removed and new high pressure gas injectors were installed. Further, the low NOX burners were modified and gave better NO. reduction performance. These modifications resulted in a similar NO, reduction performance (64%) at a reduced level of gas heat input (-13Yo). In addition, the OFA injectors were re-designed to provide for better control of CO emissions. Although not a part of this project, the use of natural gas as the primary fuel with gas reburning was also tested. The gas/gas reburning tests demonstrated a reduction in NOX emissions of 43% (0.30 lb/1 OG Btu reduced to 0.17 lb/1 OG Btu) using 7% gas heat input. Economics are a key issue affecting technology development. Application of GR-LNB requires modifications to existing power plant equipment and as a result, the capital and operating costs depend largely on site-specific factors such as: gas availability at the site, gas to coal delivered price differential, sulfur dioxide removal requirements, windbox pressure, existing burner throat diameters, and reburn zone residence time available. Based on the results of this CCT project, EER expects that most GR-LNB installations will achieve at least 60% NOX control when firing 10-15% gas. The capital cost estimate for installing a GR-LNB system on a 300 MW, unit is approximately $25/kW. plus the cost of a gas pipeline (if required). Operating costs are almost entirely related to the differential cost of the natural gas compared to coal.

None

1998-09-01T23:59:59.000Z

237

Performance and evaluation of gas engine driven rooftop air conditioning equipment at the Willow Grove (PA) Naval Air Station. Interim report, 1992 cooling season  

SciTech Connect (OSTI)

In a field evaluation conducted for the US Department of Energy (DOE) Office of Federal Energy Management Program (FEMP), the Pacific Northwest Laboratory (PNL) examined the performance of a new US energy-related technology under the FEMP Test Bed Demonstration Program. The technology was a 15-ton natural gas engine driven roof top air conditioning unit. Two such units were installed on a naval retail building to provide space conditioning to the building. Under the Test Bed Demonstration Program, private and public sector interests are focused to support the installation and evaluation of new US technologies in the federal sector. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) with DOE were the American Gas Cooling Center, Philadelphia Electric Company, Thermo King Corporation, and the US Naval Air Station at Willow Grove, Pennsylvania. Equipment operating and service data as well as building interior and exterior conditions were secured for the 1992 cooling season. Based on a computer assessment of the building using standard weather data, a comparison was made with the energy and operating costs associated with the previous space conditioning system. Based on performance during the 1992 cooling season and adjusted to a normal weather year, the technology will save the site $6,000/yr in purchased energy costs. An additional $9,000 in savings due to electricity demand ratchet charge reductions will also be realized. Detailed information on the technology, the installation, and the results of the technology test are provided to illustrate the advantages to the federal sector of using this technology. A history of the CRADA development process is also reported.

Armstrong, P.R.; Conover, D.R.

1993-05-01T23:59:59.000Z

238

Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado  

SciTech Connect (OSTI)

Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

None

1998-07-01T23:59:59.000Z

239

Recovering "Waste" from "WTEs"? Heat Attaching devices to flues and exhaust pipes could harvest waste heat-  

E-Print Network [OSTI]

Kanatzidis argues that wherever heat is generated as part of power generation, thermoelectric devices couldRecovering "Waste" from "WTEs"? Heat Attaching devices to flues and exhaust pipes could harvest waste heat- Mar 16th 2006 | From The Economist print edition HERE is a thought: approximately 60

Columbia University

240

Application of holographic neural networks for flue gas emissions prediction in the Burnaby incinerator  

SciTech Connect (OSTI)

This article describes the development of a parametric prediction system (PPS) for various emission species at the Burnaby incinerator. The continuous emissions monitoring system at the Burnaby incinerator is shared between three boilers and therefore actual results are only available 5 minutes out of every 15 minutes. The PPS was developed to fill in data for the 10 minutes when the Continuous Emission Monitor (CEM) is measuring the other boilers. It bases its prediction on the last few actual readings taken and parametrically predicts CO, SO2 and NOx. The Burnaby Incinerator is located in the commercial/industrial area of South Burnaby, British Columbia. It consists of three separate lines, each burning ten tonnes of garbage per hour and producing about three tonnes of steam for every tonne of garbage burned. The air pollution control system first cools the combustion products with water injection and then scrubs them with very fine hydrated lime. Carbon is added to the lime to enhance the scrubbing of the combustion products. The CEM monitors the levels of oxygen, carbon monoxide, nitrogen oxides, sulphur dioxide and opacity. In 1996, an expert system was installed on one of boilers at the Burnaby Incinerator plant to determine if it could improve the plant=s operations and reduce overall emission. As part of the expert system, the PPS was developed. Holographic Neural Technology (HNeT), developed by AND Corporation of Toronto, Ontario, is a novel neural network technology using complex numbers in its architecture. Compared to the traditional neural networks, HNeT has some significant advantage. It is more resilient against converging on local minima; is faster training and executing; less prone to over fitting; and, in most cases, has significantly lower error. Selection of independent variabs, training set preparation, testing neural nets and other related issue will be discussed.

Zheng, L.; Dockrill, P.; Clements, B. [Natural Resources Canada, Nepean, Ontario (Canada). CANMET Energy Technology Centre

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

Brent Constantz; Randy Seeker; Martin Devenney

2010-06-30T23:59:59.000Z

242

Performance history over 10 years of super duplex stainless steel in flue gas desulfurization  

SciTech Connect (OSTI)

25 Cr duplex (austenitic/ferritic) stainless steel containing copper and nitrogen offers a cost effective solution to material selection for pollution control equipment. The properties of duplex stainless steel which make it suitable for this type of application are discussed and long term performance histories presented. It is concluded that high alloy duplex steel has an important role to play in the production of low maintenance reliable equipment for FGD and other pollution control systems.

Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

1996-08-01T23:59:59.000Z

243

SOx-NOx-Rox Box Flue Gas Cleanup Demonstration: A DOE Assessment  

SciTech Connect (OSTI)

The SNRB{trademark} test program demonstrated the feasibility of controlling multiple emissions from a coal-fired boiler in a single processing unit. The degree of emissions removals for SO{sub 2}, NO{sub x}, and particulates all exceeded the project goals. A high degree of removal for HAPs was also achieved. The SNRB system offers low space requirements, control of multiple pollutants, and operating flexibility. The pneumatic SO{sub 2} sorbent and ammonia injection systems are expected to have high reliability because of their mechanical simplicity. Despite these advantages, the SNRB process may not be an economic choice for applications involving SO{sub 2} removals above about 85%. For lower levels of SO{sub 2} removal, the projected economics for SNRB appear to be more favorable than those of existing processes which involve separate units for the same degree of control for SO{sub 2}, NO{sub x} , and particulates. Specific findings are summarized as follows: (1) SO{sub 2} removal of 85-90% was achieved at a calcium utilization of 40-45%, representing a significant improvement in performance over other dry lime injection processes. (2) When firing 3-4% sulfur coal, compliance with the 1990 CAAA Phase I SO{sub 2} emissions limit of 2.5 lb/10{sup 6} Btu was achieved with a Ca/S molar ratio of less than 1.0. For the Phase II SO{sub 2} emissions limit of 1.2 lb/10{sup 6} Btu, compliance was achieved with a Ca/S molar ratio as low as 1.5. Phase II compliance is the more relevant emissions limit. (3) When using NaHCO{sub 3} as the sorbent, the Phase II SO{sub 2} emissions limit was achieved at a Na{sub 2}/S molar ratio of less than 2.0 (NSR < 1.0). (4) Compliance with the Phase I NO{sub x} emissions limit of 0.45 lb/10{sup 6} Btu for Group 1 boilers was achieved at an NH{sub 3}/NO{sub x} ratio of 0.85, with an ammonia slip of 5 ppm or less. (5) Particulate collection efficiency averaged 99.9%, corresponding to an average emissions rate of 0.018 lb/10{sup 6} Btu. This is significantly lower than the NSPS value of 0.03 lb/10{sup 6} Btu. The high-temperature baghouse design incorporating an SCR catalyst for NO{sub x} reduction was demonstrated successfully. The technology is ready for commercial application. The key feature of the technology is control of SO{sub 2}, NO{sub x}, and particulates in a single process unit. However, this limits its commercial market to applications requiring control of all three components. Also, although the testing demonstrated greater than 90% SO{sub 2} capture, this was achieved at high sorbent/sulfur ratios. For applications requiring a high percentage of sulfur removal, a modern conventional FGD unit with LNBs for NO{sub x} control may be the preferred option.

National Energy Technology Laboratory

2000-12-15T23:59:59.000Z

244

The utilization of flue gas desulfurization waste by-products in construction brick  

E-Print Network [OSTI]

APPENDIX D. TEST PROCEDURES APPENDIX E. CONVERSION TABLES VITA 85 90 93 96 99 LIST OF FIGURES Figure Page Model for FGD Waste By-Product Research Unconfined Compressive Strength for Fly Ash Mixed with Various Inductions of Portland Cement 15... properties such as weight, durability, strength, density, etc. Varying mixes of bottom ash, fly ash, portland cement, and sand will be tested for possible enhancement of the hemihydrate. Also, a mix design that best utilizes all the waste by...

Berryman, Charles Wayne

1992-01-01T23:59:59.000Z

245

Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Health Services| Advanced PhotonAdvanced

246

Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch Highlights MediaFuel Production ASU is a placeJoin the|

247

DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganizationElectronic Reading2Q)382 THE HUMANlviA,'{i

248

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearchCASL Symposium: CelebratingMissionat CornellMetal-Organic

249

pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 Industrial Carbon CaptureFY08 Joint JOULE J.nbarbeeLargeNHMFL-PFF at51( ( ( ( ( (

250

Resilience of gas-phase anharmonicity in the vibrational response of adsorbed carbon monoxide and breakdown under electrical conditions  

E-Print Network [OSTI]

In surface catalysis, the adsorption of carbon monoxide on transition-metal electrodes represents the prototype of strong chemisorption. Notwithstanding significant changes in the molecular orbitals of adsorbed CO, spectroscopic experiments highlight a close correlation between the adsorbate stretching frequency and equilibrium bond length for a wide range of adsorption geometries and substrate compositions. In this work, we study the origins of this correlation, commonly known as Badger's rule, by deconvoluting and examining contributions from the adsorption environment to the intramolecular potential using first-principles calculations. Noting that intramolecular anharmonicity is preserved upon CO chemisorption, we show that Badger's rule for adsorbed CO can be expressed solely in terms of the tabulated Herzberg spectroscopic constants of isolated CO. Moreover, although it had been previously established using finite-cluster models that Badger's rule is not affected by electrical conditions, we find here th...

Dabo, Ismaila

2012-01-01T23:59:59.000Z

251

The dynamics of the early universe and the initial conditions for inflation in a model with radiation and a Chaplygin gas  

E-Print Network [OSTI]

The modeling of the early universe is done through the quantization of a Friedmann-Robertson-Walker model with positive curvature. The material content consists of two fluids: radiation and Chaplygin gas. The quantization of these models is made by following the Wheeler and DeWitt's prescriptions. Using the Schutz formalism, the time notion is recovered and the Wheeler-DeWitt equation transforms into a time dependent Schr\\"{o}dinger equation, which rules the dynamics of the early universe, under the action of an effective potential $V_{ef}$. Using a finite differences method and the Crank-Nicholson scheme, in a code implemented in the program OCTAVE, we solve the corresponding time dependent Schr\\"{o}dinger equation and obtain the time evolution of a initial wave packet. This wave packet satisfies appropriate boundary conditions. The calculation of the tunneling probabilities shows that the universe may emerge from the Planck era to an inflationary phase. It also shows that, the tunneling probability is a function of the mean energy of the initial wave packet and of two parameters related to the Chaplygin gas. We also show a comparison between these results and those obtained by the WKB approximation.

G. A. Monerat; G. Oliveira-Neto; E. V. Corrêa Silva; L. G. Ferreira Filho; P. Romildo Jr.; J. C. Fabris; R. Fracalossi; F. G. Alvarenga; S. V. B. Gonçalves

2007-04-19T23:59:59.000Z

252

A versatile elevated-pressure reactor combined with an ultrahigh vacuum surface setup for efficient testing of model and powder catalysts under clean gas-phase conditions  

SciTech Connect (OSTI)

A small-volume reaction cell for catalytic or photocatalytic testing of solid materials at pressures up to 1000 Torr has been coupled to a surface-science setup used for standard sample preparation and characterization under ultrahigh vacuum (UHV). The reactor and sample holder designs allow easy sample transfer from/to the UHV chamber, and investigation of both planar and small amounts of powder catalysts under the same conditions. The sample is heated with an infrared laser beam and its temperature is measured with a compact pyrometer. Combined in a regulation loop, this system ensures fast and accurate temperature control as well as clean heating. The reaction products are automatically sampled and analyzed by mass spectrometry and/or gas chromatography (GC). Unlike previous systems, our GC apparatus does not use a recirculation loop and allows working in clean conditions at pressures as low as 1 Torr while detecting partial pressures smaller than 10{sup ?4} Torr. The efficiency and versatility of the reactor are demonstrated in the study of two catalytic systems: butadiene hydrogenation on Pd(100) and CO oxidation over an AuRh/TiO{sub 2} powder catalyst.

Morfin, Franck; Piccolo, Laurent [Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), UMR 5256 CNRS and Université Lyon 1, 2 avenue Albert Einstein, F-69626 Villeurbanne (France)] [Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), UMR 5256 CNRS and Université Lyon 1, 2 avenue Albert Einstein, F-69626 Villeurbanne (France)

2013-09-15T23:59:59.000Z

253

Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)  

SciTech Connect (OSTI)

The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

Rothgeb, S.; Brand, L.

2013-11-01T23:59:59.000Z

254

The production of activated silica with carbon dioxide gas  

E-Print Network [OSTI]

Ional to the per cent of carbon dioxi. de 1n the flue gas for a constant total gas flow rate. REFE REN CES l. Andrews, R. V, , Hanford Works Eocument (1952), 2. Andrews, R. V. & J. A. W. W. A, , ~46 82 (1954). 3. Andrews, R. V, , Personal Communication 4... of the reciuire . ents for the dedree of iliASTER OF SCIENCE Janus', 1956 Major Subject: Chemi. cal Engineering TH PRODUCTION OP ACTIVATED SILICA 7iIITH CARBON DIOXIDE GAS A Thesis William Bell Hayes III Approved as to style and content by: Chairmen...

Hayes, William Bell

1956-01-01T23:59:59.000Z

255

Gas Separations using Ceramic Membranes  

SciTech Connect (OSTI)

This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

Paul KT Liu

2005-01-13T23:59:59.000Z

256

Environmental Conditions Environmental Conditions  

E-Print Network [OSTI]

Environmental Conditions Environmental Conditions Appendix II The unique geology, hydrology and instream habitat. This chapter examines how environmental conditions in the Deschutes watershed affect, the discussion characterizes the environmental conditions within three watershed areas: the Lower Deschutes

257

Cesium and heavy metal removal from flue dusts and other matrices  

SciTech Connect (OSTI)

A problem exists in the steel industry because of the generation of radioactive waste that is caused by the accidental destruction of nuclear detection instruments. The flue dust from electric Arc Furnaces (EAF) becomes contaminated with the radionuclide used. Typically the radionuclide is cesium 137. The problem is a concern to the industry since the contamination results in the generation of a mixed waste which is costly to dispose of properly. In the interest of providing a viable solution to the problem, Lockheed Environmental Systems and Technologies has developed a process for removal of cesium from flue dust. While removing the cesium from the treatment residue, the process also isolates the other major elements of concern and renders them innocuous, saleable, or readily disposable. However, several innovative techniques have been applied which make the process far more economical, and in addition, the changes simplify the operation and render it controllable. The process involves the dissolution of the various metallic and non-metallic constituents through the use of a mild mineral acid leach. This treatment solubilizes the majority of the constituents including the cesium.

Soderstrom, D.J.; May, R.; Spaulding, S. [Lockheed Environmental Systems and Technologies Co., Las Vegas, NV (United States). Technology Applications Div.

1994-12-31T23:59:59.000Z

258

JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course  

SciTech Connect (OSTI)

The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

Dennis Laudal

2008-09-30T23:59:59.000Z

259

Application of convolution and average pressure approximation for solving non-linear flow problems. constant pressure inner boundary condition for gas flow  

E-Print Network [OSTI]

character of the solution), each of the existing approximate solutions does have disadvantages. The purpose of this work is to provide a solution mechanism for the case of timedependent real gas flow which contains as few "limitations" as possible...

Zhakupov, Mansur

2006-08-16T23:59:59.000Z

260

47 Natural Gas Market Trends NATURAL GAS MARKET TRENDS  

E-Print Network [OSTI]

47 Natural Gas Market Trends Chapter 5 NATURAL GAS MARKET TRENDS INTRODUCTION Natural gas discusses current natural gas market conditions in California and the rest of North America, followed on the outlook for demand, supply, and price of natural gas for the forecasted 20-year horizon. It also addresses

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261

Energy Department Conditionally Authorizes Oregon LNG to Export...  

Energy Savers [EERE]

Energy Department Conditionally Authorizes Oregon LNG to Export Liquefied Natural Gas Energy Department Conditionally Authorizes Oregon LNG to Export Liquefied Natural Gas July 31,...

262

Energy Department Conditionally Authorizes Cameron LNG to Export...  

Broader source: Energy.gov (indexed) [DOE]

Conditionally Authorizes Cameron LNG to Export Liquefied Natural Gas Energy Department Conditionally Authorizes Cameron LNG to Export Liquefied Natural Gas February 11, 2014 -...

263

Ice Formation in Gas-Diffusion Layers  

E-Print Network [OSTI]

the University of California. Ice Formation in Gas-Diffusionsub-freezing conditions, ice forms in the gas-diffusionstrategies exist to prevent ice formation, there is little

Dursch, Thomas

2013-01-01T23:59:59.000Z

264

Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems  

SciTech Connect (OSTI)

The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

Not Available

1990-12-01T23:59:59.000Z

265

Pilot-Scale Demonstration of hZVI Process for Treating Flue Gas Desulfurization Wastewater at Plant Wansley, Carrollton, GA  

E-Print Network [OSTI]

), Chromium (VI), Cadmium (II), Lead (II) and Copper (II) from ppm level to ppb level in a very short reaction time. The chemical consumption was estimated to be approximately 0.2-0.4 kg of ZVI per 1 m^3 of FGD water treated, which suggested the process...

Peddi, Phani 1987-

2011-12-06T23:59:59.000Z

266

Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1993--September 1994  

SciTech Connect (OSTI)

Preliminary environmental risk assessment on the FGD by-products to be placed underground is virtually complete. The initial mixes for pneumatic and hydraulic placement have been selected and are being subject to TCLP, ASTM, and modified SLP shake tests as well as ASTM column leaching. Results of these analyses show that the individual coal combustion residues, and the residues mixes, are non-hazardous in character. Based on available information, including well logs obtained from Peabody Coal Company, a detailed study of the geology of the placement site was completed. The study shows that the disposal site in the abandoned underground mine workings at depths of between 325 and 375 feet are well below potable groundwater resources. This, coupled with the benign nature of the residues and residues mixtures, should alleviate any concern that the underground placement will have adverse effects on groundwater resources. Seven convergence stations were installed in the proposed underground placement area of the Peabody Coal Company No. 10 mine. Several sets of convergence data were obtained from the stations. A study of materials handling and transportation of coal combustion residues from the electric power plant to the injection site has been made. The study evaluated the economics of the transportation of coal combustion residues by pneumatic trucks, by pressure differential rail cars, and by SEEC, Inc. collapsible intermodal containers (CICs) for different annual handling rates and transport distances. The preliminary physico-chemical characteristics and engineering properties of various FBC fly ash-spent bed mixes have been determined, and long-term studies of these properties are continuing.

Chugh, Y.P.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

1994-10-01T23:59:59.000Z

267

Assessment of the Flue Gas Recycle Strategies on Oxy-Coal Power Plants using an Exergy-based Methodology  

E-Print Network [OSTI]

to the highest net plant efficiency. This option not only allows the minimal exergy losses in the boiler but also and solvents formulation. Thus, significant efficiency improvement is needed for the oxy- combustion route minimizes the flowrate going through the downstream depollution devices. The net plant efficiency obtained

Paris-Sud XI, Université de

268

Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997  

SciTech Connect (OSTI)

The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

Chugh, Y.P.

1997-12-31T23:59:59.000Z

269

Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility  

SciTech Connect (OSTI)

With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

Metz, Paul; Bolz, Patricia

2013-03-25T23:59:59.000Z

270

CO.sub.2 separation from low-temperature flue gases  

DOE Patents [OSTI]

Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

Dilmore, Robert (Irwin, PA); Allen, Douglas (Salem, MA); Soong, Yee (Monroeville, PA); Hedges, Sheila (Bethel Park, PA)

2010-11-30T23:59:59.000Z

271

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect (OSTI)

The objective of this investigation is to characterize the operation of fan powered infrared (PIR) burner at various barometric pressures (operating altitude) and gas compositions and develop design guidelines for appliances containing PIR burners for satisfactory performance. In this program, the theoretical basis for the behavior of PIR burners will be established through analysis of the combustion, heat and mass transfer, and other related processes that determine the performance of PIR burners. Based on the results of this study, a burner performance model for radiant output will be developed. The model will be applied to predict the performance of the selected burner and will also be modified and improved through comparison with experimental results. During this period, laboratory facilities that are necessary for conducting this research are completed. The student research assistants have started working in the laboratory. The selection of the test burner has completed. The preparation and instrumentation of this test burner is underway. The theoretical analysis and modeling of the fundamental combustion process of the PIR burner is progressing well. A study of the existing models are being conducted, which will yield specific direction and recommendations for the new model to be developed.

Bai, Tiejun

1995-04-01T23:59:59.000Z

272

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly technical progress report, September 1--September 30, 1994  

SciTech Connect (OSTI)

The objective of this investigation is to characterize the operation of fan powered infrared(PIR) burner at various barometric pressures (operating altitude) and gas compositions and develop design guidelines for appliances containing PIR burners for satisfactory performance. In this program, the theoretical basis for the behavior of PIR burners will be established through analysis of the combustion, heat and mass transfer, and other related processes which determine the performance of PIR burners. Based on the results of this study, a first order model of the performance of the burner, including radiant output will be developed. The model will be applied to predict the performance of the selected burner and modified through comparison with test results. Concurrently, an experimental setup will be devised and built. This experimental rig will be a modified appliance, capable of measuring the heat and combustion product output, as well as providing a means by which the radiant heat output can be measured. The burner will be selected from an existing commercial appliance, a commercial deep fat fryer, and will be of a scale that will be compatible with the laboratory facilities in the Combustion Laboratory at Clark Atlanta University. Theoretical analysis and formulation of the PIR burner performance model has been started and the development of the test facilities and experimental setup has also been initiated. These are described.

Bai, T.

1994-10-01T23:59:59.000Z

273

Enhanced membrane gas separations  

SciTech Connect (OSTI)

An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

Prasad, R.

1993-07-13T23:59:59.000Z

274

Thermodynamics of Chaplygin gas  

E-Print Network [OSTI]

We clarify thermodynamics of the Chaplygin gas by introducing the integrability condition. All thermal quantities are derived as functions of either volume or temperature. Importantly, we find a new general equation of state, describing the Chaplygin gas completely. We confirm that the Chaplygin gas could show a unified picture of dark matter and energy which cools down through the universe expansion without any critical point (phase transition).

Yun Soo Myung

2011-05-11T23:59:59.000Z

275

Detection of gas hydrates by the measurement of instantaneous temperature  

E-Print Network [OSTI]

Natural gas hydrates are icelike crystalline substances formed by gas molecules trapped in a water lattice. Suitable thermodynamic conditions and the presence of gas are required for the formation of natural gas hydrates in ocean sediments. Several...

Dinakaran, Srikanth

1994-01-01T23:59:59.000Z

276

Behavior of carbonate-rich fuels in ACFBC and PFBC conditions  

SciTech Connect (OSTI)

Estonian oil shale is known as one of richest in carbonate fuels. High mineral matter content (60--75% in dry mass), moderate moisture (9--12%) and carbonate carbon dioxide content (17--19%), and low heating value (LHV 8--10 MJ/kg as received) are characteristic for Estonian oil shale. Approximately half of the mineral matter is in the carbonate form, mainly as calcium carbonate. The sulfur content of dry mass is 1.5--1.7% and Ca/S molar ratio is 8--10. Due to limestone present in oil shale, the additional sorbent for sulfur retention during combustion is not needed. The behavior of carbonates as well as the formation of ash at fluidized bed combustion (FBC) was the main topics to study. At Thermal Engineering Department (TED) of Tallinn Technical University a laboratory pressurized combustion facility was used for investigation the decomposition of soil shale carbonates in atmospheric and pressurized burning conditions. The experiments with oil shale were performed at pressures 0.1 MPa and 1.2 MPa and at the temperature 850 C. Based on the carbonate decomposition rate (CDR) 0.3--0.4 established experimentally at pressurized combustion, it may be concluded that the heating value of oil shale increases approximately by 5.5--8% and the carbon dioxide concentration in flue gas decreases by 13--20% compared with the conditions of the complete decomposition of carbonate. Combustion of oil shale was tested in 0.15--1.0 MW{sub th} test facilities. The tests confirmed the suitability of both ACFBC and PFBC technologies to utilize oil shale. The tests showed a nearly complete binding of sulfur by oil shale ash and a limited formation of NO{sub x} at combustion. Oil shale FBC is characterized by the formation of large amounts (40--85% from total) of fine-grained fly ash.

Ots, A.; Arro, H.; Pihu, T.; Prikk, A.

1999-07-01T23:59:59.000Z

277

Superfund Record of Decision (EPA Region 8): Anaconda Smelter site, (Operable Unit 11 - Flue Dust), Deer Lodge County, Anaconda, MT. (Second remedial action), September 1991  

SciTech Connect (OSTI)

The 6,000-acre Anaconda Smelter site is a former copper and ore processing facility in Deer Lodge County, Montana. Land use in the area is predominantly residential. The site is bounded on the north and east, respectively, by the Warm Springs Creek and Mill Creek, both of which are potential sources of drinking water. From 1884 until 1980 when activities ceased, the site was used for ore processing and smelting operations. In 1988, EPA conducted an investigation to determine the nature and extent of the flue dust contamination. A 1988 ROD addressed the Mill Creek Operable Unit (OU15) and documented the relocation of residents from the community surrounding the smelter site as the selected remedial action. The Record of Decision (ROD) addresses the Flue Dust Operable Unit (OU11). The primary contaminants of concern affecting this site from the flue dust materials are metals including arsenic, cadmium, and lead. The selected remedial action for the site is included.

Not Available

1991-09-23T23:59:59.000Z

278

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. The Ontario Hydro method was used to determine the total amount of Hg passing through the filter as well as the percentages of elemental and oxidized Hg collected. Results indicated that substantial amounts of Hg oxidation did not occur with either fly ash, regardless of the temperature used for testing. When oxidation was observed, the magnitude of the oxidation was comparable between the two fly ashes. These results suggest that the gas matrix may be more important than the ash components with respect to the distribution of Hg species observed in gaseous effluents at coal-fired power plants.

Glenn A. Norton

1999-10-01T23:59:59.000Z

279

Gas intrusion into SPR caverns  

SciTech Connect (OSTI)

The conditions and occurrence of gas in crude oil stored in Strategic Petroleum Reserve, SPR, caverns is characterized in this report. Many caverns in the SPR show that gas has intruded into the oil from the surrounding salt dome. Historical evidence and the analyses presented here suggest that gas will continue to intrude into many SPR caverns in the future. In considering why only some caverns contain gas, it is concluded that the naturally occurring spatial variability in salt permeability can explain the range of gas content measured in SPR caverns. Further, it is not possible to make a one-to-one correlation between specific geologic phenomena and the occurrence of gas in salt caverns. However, gas is concluded to be petrogenic in origin. Consequently, attempts have been made to associate the occurrence of gas with salt inhomogeneities including anomalies and other structural features. Two scenarios for actual gas intrusion into caverns were investigated for consistency with existing information. These scenarios are gas release during leaching and gas permeation through salt. Of these mechanisms, the greater consistency comes from the belief that gas permeates to caverns through the salt. A review of historical operating data for five Bryan Mound caverns loosely supports the hypothesis that higher operating pressures reduce gas intrusion into caverns. This conclusion supports a permeability intrusion mechanism. Further, it provides justification for operating the caverns near maximum operating pressure to minimize gas intrusion. Historical gas intrusion rates and estimates of future gas intrusion are given for all caverns.

Hinkebein, T.E.; Bauer, S.J.; Ehgartner, B.L.; Linn, J.K.; Neal, J.T.; Todd, J.L.; Kuhlman, P.S.; Gniady, C.T. [Sandia National Labs., Albuquerque, NM (United States). Underground Storage Technology Dept.; Giles, H.N. [Dept. of Energy, Washington, DC (United States). Strategic Petroleum Reserve

1995-12-01T23:59:59.000Z

280

The Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigerati...  

Open Energy Info (EERE)

Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigeration and Air Conditioning Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol...

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Oil and Gas on Public Lands (Texas)  

Broader source: Energy.gov [DOE]

The School Land Board may choose to lease lands for the production of oil and natural gas, on the condition that oil and gas resources are leased together and separate from other minerals. Lands...

282

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

Nsakala ya Nsakala; Gregory N. Liljedahl

2003-05-15T23:59:59.000Z

283

Effect of Coal Properties and Operation Conditions on Flow Behavior of Coal Slag in Entrained Flow Gasifiers: A Brief Review  

SciTech Connect (OSTI)

Integrated gasification combined cycle (IGCC) is a potentially promising clean technology with an inherent advantage of low emissions, since the process removes contaminants before combustion instead of from flue gas after combustion, as in a conventional coal steam plant. In addition, IGCC has potential for cost-effective carbon dioxide capture. Availability and high capital costs are the main challenges to making IGCC technology more competitive and fully commercial. Experiences from demonstrated IGCC plants show that, in the gasification system, low availability is largely due to slag buildup in the gasifier and fouling in the syngas cooler downstream of the gasification system. In the entrained flow gasifiers used in IGCC plants, the majority of mineral matter transforms to liquid slag on the wall of the gasifier and flows out the bottom. However, a small fraction of the mineral matter (as fly ash) is entrained with the raw syngas out of the gasifier to downstream processing. This molten/sticky fly ash could cause fouling of the syngas cooler. Therefore, it is preferable to minimize the quantity of fly ash and maximize slag. In addition, the hot raw syngas is cooled to convert any entrained molten fly slag to hardened solid fly ash prior to entering the syngas cooler. To improve gasification availability through better design and operation of the gasification process, better understanding of slag behavior and characteristics of the slagging process are needed. Slagging behavior is affected by char/ash properties, gas compositions in the gasifier, the gasifier wall structure, fluid dynamics, and plant operating conditions (mainly temperature and oxygen/carbon ratio). The viscosity of the slag is used to characterize the behavior of the slag flow and is the dominating factor to determine the probability that ash particles will stick. Slag viscosity strongly depends on the temperature and chemical composition of the slag. Because coal has varying ash content and composition, different operating conditions are required to maintain the slag flow and limit problems downstream. This report briefly introduces the IGCC process, the gasification process, and the main types and operating conditions of entrained flow gasifiers used in IGCC plants. This report also discusses the effects of coal ash and slag properties on slag flow and its qualities required for the entrained flow gasifier. Finally this report will identify the key operating conditions affecting slag flow behaviors, including temperature, oxygen/coal ratio, and flux agents.

Wang,Ping; Massoudi, Mehrdad

2011-01-01T23:59:59.000Z

284

Evaluation of gas-reburning and low NO{sub x} burners on a wall fired boiler. Progress report, January 1--March 31, 1996  

SciTech Connect (OSTI)

The primary objective of this Clean Coal Technology project is to evaluate the use of Gas Reburning and Low NO{sub x} Burners (GR-LNB) for NO{sub x} emission control from a wall fired boiler. This project is being conducted in three phases at the host site, a 172 MW{sub e} wall fired boiler of Public Service Company of Colorado, Cherokee Unit 3 in Denver, Colorado: Phase I, design and permitting has been completed on June 30, 1992; Phase II, construction and start-up has been completed on September 1991; and Phase III, operation, data collection, reporting and disposition. Phase III activities during this reporting period involved the following: compilation, analysis and assembly of the final report and initiation of restoration activities; restoration of the gas reburning system involving removal of the flue gas recirculation system (permanent Second Generation Gas Reburning); and participants meeting and reburning workshop. Long term testing of the equipment demonstrated an average NO{sub x} reduction of 65% using 18% gas heat input. After removing the flue gas recirculation system, (Second Generation GR), an average NO{sub x} of 64% was achieved using 13% gas heat input. The project goal of 70% reduction was achieved, but no on an average basis due to the load requirements of the utility.

NONE

1996-04-15T23:59:59.000Z

285

Wet-gas compression in twin-screw multiphase pumps  

E-Print Network [OSTI]

encountered when operating under conditions with high gas volume fractions (GVF). Twin-screw multiphase pumps experience a severe decrease in efficiency when operating under wet-gas conditions, GVF over 95%. Field operations have revealed severe vibration...

Chan, Evan

2009-05-15T23:59:59.000Z

286

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE  

SciTech Connect (OSTI)

Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

2004-10-27T23:59:59.000Z

287

Evolution of simple configurations of gravitating gas  

E-Print Network [OSTI]

We considered the dynamics of gravitating gas - a continuous media with peculiar properties. The exact solutions of its Euler equations for simple initial conditions is obtained.

G. P. Pronko

2011-04-23T23:59:59.000Z

288

Analysis of the Development of Messoyakha Gas Field: A Commercial Gas Hydrate Reservoir  

E-Print Network [OSTI]

the presence of gas hydrates in the Messoyakha field was not a certainty, this current study determined the undeniable presence of gas hydrates in the reservoir. This study uses four models of the Messoyakha field structure and reservoir conditions...

Omelchenko, Roman 1987-

2012-12-11T23:59:59.000Z

289

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using fly ash from the electrostatic precipitators of two full-scale utility boilers. One fly ash was from a Powder River Basin (PRB) coal, while the other was from Blacksville coal. Elemental Hg was injected upstream from samples of fly ash loaded onto filters housed in an oven at 120 or 180 C. Concentrations of oxidized and elemental Hg downstream from the filters were determined using the Ontario Hydro method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables affecting Hg oxidation. The presence of HCl, NO, NO{sub 2}, and SO{sub 2} were all important with respect to Hg oxidation, with NO{sub 2} and HCl being the most important. The presence of NO suppressed Hg oxidation in these tests. Although the two fly ashes were chemically and mineralogically diverse, there were generally no large differences in catalytic potential (for oxidizing Hg) between them. Similarly, no ash fraction appeared to be highly catalytic relative to other ash fractions. This includes fractions enriched in unburned carbon and fractions enriched in iron oxides. Although some differences of lesser magnitude were observed in the amount of oxidized Hg formed, levels of oxidized Hg generally tracked well with the surface areas of the different ashes and ash fractions. Therefore, although the Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, this could be due to the relatively high surface area of that ash. Similarly, for Blacksville fly ash, using nonmagnetic ash resulted in more Hg oxidation than using magnetic ash, but this again tracked well with the relative surface areas of the two ash fractions. Test results suggest that the gas matrix may be more important in Hg oxidation chemistry than the fly ash composition. Combustion tests were performed in which Blacksville and PRB fly ashes were injected into filtered (via a baghouse with Teflon bags) flue gas obtained while firing PRB coal in a 35 kW combustor. The Ontario Hydro method was used to determine the Hg speciation after fly ash injection. Wall effects in the combustor complicated interpretation of testing data, although a number of observations could still be made. The amount of Hg collected in the Ontario Hydro impingers was lower than anticipated, and is probably due to sorption of Hg by the fly ash. While firing PRB coal without any ash injection, the percent oxidized Hg in the gas stream was fairly high (average of 63%). The high levels of vapor phase oxidized Hg in these base line tests may be due to catalytic effects from the refractory materials in the combustor. When PRB fly ash was injected into a filtered PRB flue gas stream, the percentage of oxidized Hg in the gas stream decreased dramatically. Decreases in the percentage of oxidized Hg were also observed while injecting Blacksville fly ash, but to a lesser extent. Injecting whole Blacksville fly ash into the filtered PRB flue gas appeared to result in greater concentrations of oxidized Hg relative to the tests where whole PRB fly ash was injected. However, because the Blacksville fly ash has a relatively high surface area, this may be only a surface area effect.

Glenn A. Norton; Hongqun Yang; Robert C. Brown; Dennis L. Laudal; Grant E. Dunham; John Erjavec; Joseph M. Okoh

2002-01-31T23:59:59.000Z

290

North American Natural Gas Markets  

SciTech Connect (OSTI)

This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group's findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

Not Available

1989-02-01T23:59:59.000Z

291

North American Natural Gas Markets  

SciTech Connect (OSTI)

This report sunnnarizes the research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group's findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

Not Available

1988-12-01T23:59:59.000Z

292

Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals  

SciTech Connect (OSTI)

This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

Sun, Xiaolei; Rink, Nancy

2011-04-30T23:59:59.000Z

293

Security Conditions  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Notice ensures that DOE uniformly meets the requirements of the Homeland Security Advisory System outlined in Homeland Security Presidential Directive-3, Threat Conditions and Associated Protective Measures, dated 3-11-02, and provides responses specified in Presidential Decision Directive 39, U.S. Policy on Counterterrorism (U), dated 6-21-95. It cancels DOE N 473.8, Security Conditions, dated 8-7-02. Extended until 7-7-06 by DOE N 251.64, dated 7-7-05 Cancels DOE N 473.8

2004-07-08T23:59:59.000Z

294

Rapid gas hydrate formation process  

DOE Patents [OSTI]

The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

2013-01-15T23:59:59.000Z

295

U-GAS process  

SciTech Connect (OSTI)

The Institute of Gas Technology (IGT) has developed an advanced coal gasification process. The U-GAS process has been extensively tested in a pilot plant to firmly establish process feasibility and provide a large data base for scale-up and design of the first commercial plant. The U-GAS process is considered to be one of the more flexible, efficient, and economical coal gasification technologies developed in the US during the last decade. The U-GAS technology is presently available for licensing from GDC, Inc., a wholly-owned subsidiary of IGT. The U-GAS process accomplishes four important functions in a single-stage, fluidized-bed gasifier: It decakes coal, devolatilizes coal, gasifies coal, and agglomerates and separates ash from char. Simultaneously with coal gasification, the ash is agglomerated into spherical particles and separated from the bed. Part of the fluidizing gas enters the gasifier through a sloping grid. The remaining gas flows upward at a high velocity through the ash agglomerating device and forms a hot zone within the fluidized bed. High-ash-content particles agglomerate under these conditions and grow into larger and heavier particles. Agglomerates grow in size until they can be selectively separated and discharged from the bed into water-filled ash hoppers where they are withdrawn as a slurry. In this manner, the fluidized bed achieves the same low level of carbon losses in the discharge ash generally associated with the ash-slagging type of gasifier. Coal fines elutriated from the fluidized bed are collected in two external cyclones. Fines from the first cyclone are returned to the bed and fines from the second cyclone are returned to the ash agglomerating zone, where they are gasified, and the ash agglomerated with bed ash. The raw product gas is virtually free of tar and oils, thus simplifying ensuing heat recovery and purification steps.

Schora, F.C.; Patel, J.G.

1982-01-01T23:59:59.000Z

296

Gas reburning in tangentially-fired, wall-fired and cyclone-fired boilers  

SciTech Connect (OSTI)

Gas Reburning has been successfully demonstrated for over 4,428 hours on three coal fired utility boilers as of March 31, 1994. Typically, NO{sub x} reductions have been above 60% in long-term, load-following operation. The thermal performance of the boilers has been virtually unaffected by Gas Reburning. At Illinois Power`s Hennepin Station, Gas Reburning in a 71 MWe tangentially-fired boiler achieved an average NO{sub x} reduction of 67% from the original baseline NO{sub x} level of 0.75 lb NO{sub x}/10{sup 6} Btu over a one year period. The nominal natural gas input was 18% of total heat input. Even at 10% gas heat input, NO{sub x} reduction of 55% was achieved. At Public Service Company of Colorado`s Cherokee Station, a Gas Reburning-Low NO{sub x} Burner system on a 172 MWe wall-fired boiler has achieved overall NO{sub x} reductions of 60--73% in parametric and long-term testing, based on the original baseline NO{sub x} level of 0.73 lb/10{sup 6} Btu. NO{sub x} reduction is as high as 60--65% even at relatively low natural gas usage (5--10% of total heat input). The NO{sub x} reduction by Low NO{sub x} Burners alone is typically 30--40%. NO{sub x} reduction has been found to be insensitive to changes in recirculated flue gas (2--7% of total flue gas) injected with natural gas. At City Water, Light and Power Company`s Lakeside Station in Springfield, Illinois, Gas Reburning in a 33 MWe cyclone-fired boiler has achieved an average NO{sub x} reduction of 66% (range 52--77%) at gas heat inputs of 20--26% in long-term testing, based on a baseline NO{sub x} level of 1.0 lb/10{sup 6} Btu (430 mg/MJ). This paper presents a summary of the operating experience at each site and discusses the long term impacts of applying this technology to units with tangential, cyclone and wall-fired (with Low NO{sub x} Burner) configurations.

May, T.J. [Illinois Power Co., Decatur, IL (United States); Rindahl, E.G. [Public Service Co. of Colorado, Denver, CO (United States); Booker, T. [City Water Light and Power, Springfield, IL (United States)] [and others

1994-12-31T23:59:59.000Z

297

Gas separation process  

SciTech Connect (OSTI)

The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

1988-03-22T23:59:59.000Z

298

Passive gas separator and accumulator device  

DOE Patents [OSTI]

A separation device employing a gas separation filter and swirler vanes for separating gas from a gas-liquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use. 3 figs.

Choe, H.; Fallas, T.T.

1994-08-02T23:59:59.000Z

299

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network [OSTI]

pressure, the hot combustion gases would be cooled andphase include post-combustion flue gas treatment methods.Combustion Staged Combustion Flue Gas Recirculation Water

Ferrell, G.C.

2010-01-01T23:59:59.000Z

300

Dampers for Natural Draft Heaters: Technical Report  

E-Print Network [OSTI]

Storage Water Heater.draft gas-fired storage water heater. The flue damper waswater heater, gas-fired storage water heater, flue damper,

Lutz, James D.

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

High volume - high value usage of Flue Gas Desulfurization (FGD) by-products in underground mines. Quarterly report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

The amount of dry FGD materials produced in the U.S. has not been increasing at the high rate originally anticipated. This has been due to a number of economic factors affecting the utility industry. Technologies for the disposal of large amounts of materials are not going to be implemented in the near term. In light of this development the target application for this project is being changed from highwall adit filling to the filling of auger holes to allow for highwall mining. This application focuses on using the dry FGD material to recover coal isolated by excessive augering. It produces 10 or more times the amount of coal per ton of dry FGD utilized than the originally proposed methodology. It also does not require extensive equipment development and, if applied to abandoned mine lands, may have substantially more significant environmental benefit. We also propose to use a spray dryer material for the demonstration instead of the fluidized bed material originally proposed. The spray dryer material is already slacked eliminating problems associated with heat generation at the mine site. Auger hole grouting with FGD material is also best performed by hydraulic emplacement methods.

NONE

1997-05-01T23:59:59.000Z

302

Solid-Fueled Pressurized Chemical Looping with Flue-Gas Turbine Combined Cycle for Improved Plant Efficiency and CO{sub 2} Capture  

SciTech Connect (OSTI)

The purpose of this document is to report the final result of techno-economic analysis for the proposed 550MWe integrated pressurized chemical looping combustion combined cycle process. An Aspen Plus based model is delivered in this report along with the results from three sensitivity scenarios including the operating pressure, excess air ratio and oxygen carrier performance. A process flow diagram and detailed stream table for the base case are also provided with the overall plant energy balance, carbon balance, sulfur balance and water balance. The approach to the process and key component simulation are explained. The economic analysis (OPEX and CAPX) on four study cases via DOE NETL Reference Case 12 are presented and explained.

Liu, Kunlei; Chen, Liangyong; Zhang, Yi; Richburg, Lisa; Simpson, James; White, Jay; Rossi, Gianalfredo

2013-12-31T23:59:59.000Z

303

Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors in France: Implications for Atmospheric Lead Source Tracing.  

E-Print Network [OSTI]

types contain hundreds to thousands of micrograms of metals per gram. Leaching experiments showed that metals are present in condensed phases, probably as sulfates and chlorides, and suggest that Cd, Pb and Zn are highly fractionated from one another during volatilization/condensation processes occurring

Paris-Sud XI, Université de

304

Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery  

DOE Patents [OSTI]

A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

Ochs, Thomas L. (Albany, OR); Summers, Cathy A. (Albany, OR); Gerdemann, Steve (Albany, OR); Oryshchyn, Danylo B. (Philomath, OR); Turner, Paul (Independence, OR); Patrick, Brian R. (Chicago, IL)

2011-10-18T23:59:59.000Z

305

Hot conditioning equipment conceptual design report  

SciTech Connect (OSTI)

This report documents the conceptual design of the Hot Conditioning System Equipment. The Hot conditioning System will consist of two separate designs: the Hot Conditioning System Equipment; and the Hot Conditioning System Annex. The Hot Conditioning System Equipment Design includes the equipment such as ovens, vacuum pumps, inert gas delivery systems, etc.necessary to condition spent nuclear fuel currently in storage in the K Basins of the Hanford Site. The Hot Conditioning System Annex consists of the facility of house the Hot Conditioning System. The Hot Conditioning System will be housed in an annex to the Canister Storage Building. The Hot Conditioning System will consist of pits in the floor which contain ovens in which the spent nuclear will be conditioned prior to interim storage.

Bradshaw, F.W., Westinghouse Hanford

1996-08-06T23:59:59.000Z

306

DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS  

SciTech Connect (OSTI)

The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

2012-09-30T23:59:59.000Z

307

Passive gas separator and accumulator device  

DOE Patents [OSTI]

A separation device employing a gas separation filter and swirler vanes for separating gas from a gasliquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use.

Choe, Hwang (Saratoga, CA); Fallas, Thomas T. (Berkeley, CA)

1994-01-01T23:59:59.000Z

308

Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

2007-03-31T23:59:59.000Z

309

Gas sensor  

DOE Patents [OSTI]

A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

2014-09-09T23:59:59.000Z

310

Experimental Investigation on High-pressure, High-temperature Viscosity of Gas Mixtures  

E-Print Network [OSTI]

Modeling the performance of high-pressure, high-temperature (HPHT) natural gas reservoirs requires the understanding of gas behavior at such conditions. In particular, gas viscosity is an important fluid property that directly affects fluid flow...

Davani, Ehsan

2012-02-14T23:59:59.000Z

311

NATURAL GAS MARKET ASSESSMENT  

E-Print Network [OSTI]

CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

312

Georgia Tech Dangerous Gas  

E-Print Network [OSTI]

1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

Sherrill, David

313

Coal beneficiation by gas agglomeration  

DOE Patents [OSTI]

Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

Wheelock, Thomas D.; Meiyu, Shen

2003-10-14T23:59:59.000Z

314

Method for detecting gas turbine engine flashback  

DOE Patents [OSTI]

A method for monitoring and controlling a gas turbine, comprises predicting frequencies of combustion dynamics in a combustor using operating conditions of a gas turbine, receiving a signal from a sensor that is indicative of combustion dynamics in the combustor, and detecting a flashback if a frequency of the received signal does not correspond to the predicted frequencies.

Singh, Kapil Kumar; Varatharajan, Balachandar; Kraemer, Gilbert Otto; Yilmaz, Ertan; Lacy, Benjamin Paul

2012-09-04T23:59:59.000Z

315

Underground Gas Storage Reservoirs (West Virginia)  

Broader source: Energy.gov [DOE]

Lays out guidelines for the conditions under which coal mining operations must notify state authorities of intentions to mine where underground gas is stored as well as map and data requirements,...

316

Conservation of Oil and Gas (Texas)  

Broader source: Energy.gov [DOE]

This legislation prohibits the production, storage, or transportation of oil or gas in a manner, in an amount, or under conditions that constitute waste. Actions which may lead to the waste of oil...

317

EFFECTS OF FLY ASH ON MERCURY OXIDATION DURING POST COMBUSTION CONDITIONS  

SciTech Connect (OSTI)

Tests were performed in simulated flue gas streams using two fly ash samples from the electrostatic precipitators of two full-scale utility boilers. One fly ash was derived from a Powder River Basin (PRB) coal, while the other was derived from Blacksville coal (Pittsburgh No. 8 seam). The tests were performed at temperatures of 120 and 180 C under different gas compositions using whole fly ash samples as well as magnetic and nonmagnetic concentrates from sized fly ash. Only the Blacksville ash contained magnetic phases. The whole and fractionated fly ash samples were analyzed for morphology, chemical composition, mineralogical composition, total organic carbon, porosity, and surface area. Mineralogically, the Blacksville ash was composed predominantly of magnetite, hematite, quartz, and mullite, while the PRB ash contained mostly quartz with lesser amounts of lime, periclase, and calcium aluminum oxide. The iron oxides in the Blacksville ash were concentrated almost entirely in the largest size fraction. As anticipated, there was not a clean separation of magnetic (Fe-rich) and nonmagnetic (aluminosilicate-rich) phases for the Blacksville ash. The Blacksville ash had a significantly higher surface area and a much higher unburned carbon content than the PRB ash. Elemental mercury (Hg) streams were injected into the simulated flue gas and passed over filters (housed in a convection oven) loaded with fly ash. Concentrations of total, oxidized, and elemental Hg downstream from the ash samples were determined by the Ontario Hydro Method. The gas stream composition and whether or not ash was present in the gas stream were the two most important variables. Based on the statistical analyses, the presence of HCl, NO, NO{sub 2}, and SO{sub 2} and all two-way gas interactions were significant. In addition, it appears that even four-factor interactions between those gases are significant. The HCl, NO{sub 2}, and SO{sub 2} were critical gases resulting in Hg oxidation, while the presence of NO appeared to suppress oxidation. The Blacksville fly ash tended to show slightly more catalytic activity than the PRB fly ash, but this could be largely due to the higher surface area of the Blacksville ash. Temperature was not a statistically important factor. The magnetic (Fe-rich) phases did not appear to be more catalytically active than the nonmagnetic phases, and unburned carbon did not appear to play a critical role in oxidation chemistry.

Unknown

2000-10-01T23:59:59.000Z

318

Gas Network Optimization: A comparison of Piecewise Linear Models  

E-Print Network [OSTI]

Oct 4, 2014 ... ... and advanced MILP formulations for the gas network optimization in dynamic or in steady-state conditions. ... Search, Browse the Repository.

CARLOS M. CORREA-POSADA

2014-10-04T23:59:59.000Z

319

Louisville Gas and Electric- Residential Energy Efficiency Rebate Program (Kentucky)  

Broader source: Energy.gov [DOE]

Louisville Gas and Electric's Home Energy Rebate program provides incentives for residential customers to upgrade to energy efficiency home appliances and heat and air conditioning equipment. ...

320

Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect (OSTI)

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

None

1998-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect (OSTI)

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

None

1998-06-01T23:59:59.000Z

322

Assessment of coal bed gas prospects  

SciTech Connect (OSTI)

Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

1996-12-31T23:59:59.000Z

323

SLE($?,?$)and Boundary Coulomb Gas  

E-Print Network [OSTI]

We consider the coulomb gas model on the upper half plane with different boundary conditions, namely Drichlet, Neuman and mixed. We related this model to SLE($\\kappa,\\rho$) theories. We derive a set of conditions connecting the total charge of the coulomb gas, the boundary charges, the parameters $\\kappa$ and $\\rho$. Also we study a free fermion theory in presence of a boundary and show with the same methods that it would lead to logarithmic boundary changing operators.

S. Moghimi-Araghi; M. A. Rajabpour; S. Rouhani

2005-08-07T23:59:59.000Z

324

Method and apparatus for manufacturing gas tags  

DOE Patents [OSTI]

For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases.

Gross, Kenny C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

325

Method and apparatus for manufacturing gas tags  

DOE Patents [OSTI]

For use in the manufacture of gas tags employed in a gas tagging failure detection system for a nuclear reactor, a plurality of commercial feed gases each having a respective noble gas isotopic composition are blended under computer control to provide various tag gas mixtures having selected isotopic ratios which are optimized for specified defined conditions such as cost. Using a new approach employing a discrete variable structure rather than the known continuous-variable optimization problem, the computer controlled gas tag manufacturing process employs an analytical formalism from condensed matter physics known as stochastic relaxation, which is a special case of simulated annealing, for input feed gas selection. For a tag blending process involving M tag isotopes with N distinct feed gas mixtures commercially available from an enriched gas supplier, the manufacturing process calculates the cost difference between multiple combinations and specifies gas mixtures which approach the optimum defined conditions. The manufacturing process is then used to control tag blending apparatus incorporating tag gas canisters connected by stainless-steel tubing with computer controlled valves, with the canisters automatically filled with metered quantities of the required feed gases. 4 figs.

Gross, K.C.; Laug, M.T.

1996-12-17T23:59:59.000Z

326

Gas stream cleanup  

SciTech Connect (OSTI)

This report describes the current status and recent accomplishments of gas stream cleanup (GSCU) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Gas Stream Cleanup Program is to develop contaminant control strategies that meet environmental regulations and protect equipment in advanced coal conversion systems. Contaminant control systems are being developed for integration into seven advanced coal conversion processes: Pressurized fludized-bed combustion (PFBC), Direct coal-fueled turbine (DCFT), Intergrated gasification combined-cycle (IGCC), Gasification/molten carbonate fuel cell (MCFC), Gasification/solid oxide fuel cell (SOFC), Coal-fueled diesel (CFD), and Mild gasification (MG). These advanced coal conversion systems present a significant challenge for development of contaminant control systems because they generate multi-contaminant gas streams at high-pressures and high temperatures. Each of the seven advanced coal conversion systems incorporates distinct contaminant control strategies because each has different contaminant tolerance limits and operating conditions. 59 refs., 17 figs., 5 tabs.

Bossart, S.J.; Cicero, D.C.; Zeh, C.M.; Bedick, R.C.

1990-08-01T23:59:59.000Z

327

Pulsed plasma treatment of polluted gas using wet-/low-temperature corona reactors  

SciTech Connect (OSTI)

Application of pulsed plasma for gas cleaning is gaining prominence in recent years, mainly from the energy consideration point of view. Normally, the gas treatment is carried out at or above room temperature by the conventional dry-type corona reactor. However, this treatment is still inadequate for the removal of certain stable gases present in the exhaust/flue gas mixture. The authors report here some interesting results of treatment of such stable gases like N{sub 2}O with pulsed plasma at subambient temperature. Also reported in this paper are improvements in DeNO/DeNO{sub x} efficiency using unconventional wet-type reactors, designed and fabricated by us, and operating at different subambient temperatures. DeNO/DeNO{sub x} by the pulsed-plasma process is mainly due to oxidation, but reduction takes place at the same time. When the wet-type reactor was used, the NO{sub 2} product was absorbed by water film and higher DeNO{sub x} efficiency could be achieved. Apart from laboratory tests on simulated gas mixtures, field tests were also carried out on the exhaust gas of an 8-kW diesel engine. A comparative analysis of the various tests are presented, together with a note on the energy consideration.

Shimizu, Kazuo; Kinoshita, Katsuhiro; Yanagihara, Kenya; Rajanikanth, B.S.; Katsura, Shinji; Mizuno, Akira [Toyohashi Univ. of Technology, Aichi (Japan). Dept. of Ecological Engineering] [Toyohashi Univ. of Technology, Aichi (Japan). Dept. of Ecological Engineering

1997-09-01T23:59:59.000Z

328

North American Natural Gas Markets. Volume 1  

SciTech Connect (OSTI)

This report sunnnarizes the research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group`s findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

Not Available

1988-12-01T23:59:59.000Z

329

North American Natural Gas Markets. Volume 2  

SciTech Connect (OSTI)

This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group`s findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

Not Available

1989-02-01T23:59:59.000Z

330

Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report  

SciTech Connect (OSTI)

The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

Hsu, F.E.

1995-08-01T23:59:59.000Z

331

Rekuperativ katalytisk udstdsreaktor til stationre gasmotorer  

E-Print Network [OSTI]

at fairly low flue gas temperatures in the exhaust to regenerative incineration plants that increase

332

Pennsylvania's Natural Gas Future  

E-Print Network [OSTI]

1 Pennsylvania's Natural Gas Future Penn State Natural Gas Utilization Workshop Bradley Hall sales to commercial and industrial customers ­ Natural gas, power, oil · Power generation ­ FossilMMBtuEquivalent Wellhead Gas Price, $/MMBtu Monthly US Spot Oil Price, $/MMBtu* U.S. Crude Oil vs. Natural Gas Prices, 2005

Lee, Dongwon

333

OGEL (Oil, Gas & Energy Law Intelligence): Focussing on recent developments in the area of oil-gas-energy law,  

E-Print Network [OSTI]

About OGEL OGEL (Oil, Gas & Energy Law Intelligence): Focussing on recent developments in the area of oil-gas-energy law, regulation, treaties, judicial and arbitral cases, voluntary guidelines, tax and contracting, including the oil-gas- energy geopolitics. For full Terms & Conditions and subscription rates

Dixon, Juan

334

Altering Wettability in Gas Condensate Sandstone Reservoirs for Gas Mobillity Improvement  

E-Print Network [OSTI]

study on Berea sandstone rocks treated with a fluorinated polymer. Various concentrations of the polymer are investigated to obtain the optimum alteration in wettability to intermediate gas-wet. This wetting condition is achieved with an 8% polymer...

Fernandez Martinez, Ruth Gabriela

2012-07-16T23:59:59.000Z

335

Fuel-cell engine stream conditioning system  

DOE Patents [OSTI]

A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

DuBose, Ronald Arthur (Marietta, GA)

2002-01-01T23:59:59.000Z

336

Gas Storage Act (Illinois)  

Broader source: Energy.gov [DOE]

Any corporation which is engaged in or desires to engage in, the distribution, transportation or storage of natural gas or manufactured gas, which gas, in whole or in part, is intended for ultimate...

337

Gas Utilities (New York)  

Broader source: Energy.gov [DOE]

This chapter regulates natural gas utilities in the State of New York, and describes standards and procedures for gas meters and accessories, gas quality, line and main extensions, transmission and...

338

Industrial Gas Turbines  

Broader source: Energy.gov [DOE]

A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

339

Gas Utilities (Maine)  

Broader source: Energy.gov [DOE]

Rules regarding the production, sale, and transfer of manufactured gas will also apply to natural gas. This section regulates natural gas utilities that serve ten or more customers, more than one...

340

Coke oven gas injection to blast furnaces  

SciTech Connect (OSTI)

U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Effective Lone Star program reduces unaccounted-for gas  

SciTech Connect (OSTI)

Lone Star's program for holding down its gas losses implements individual remedies for each of six broad categories of unaccounted-for gas: measurement at other than base conditions, meter inaccuracy, meter-reading errors, accounting mistakes, unmetered or unrecorded gas use, and leakage. Even though some of these remedies will not be fully effective for 2 more years, the program's first year of operation has reduced unaccounted-for gas volumes by 9.2%.

Wallace, J.E.

1982-04-01T23:59:59.000Z

342

Gas Production Tax (Texas)  

Broader source: Energy.gov [DOE]

A tax of 7.5 percent of the market value of natural gas produced in the state of Texas is imposed on every producer of gas.

343

Natural gas dehydration apparatus  

DOE Patents [OSTI]

A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

2006-11-07T23:59:59.000Z

344

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

345

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

346

Historical Natural Gas Annual  

U.S. Energy Information Administration (EIA) Indexed Site

7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

347

CO2-Binding Organic Liquids Gas Capture with Polarity-Swing-Assisted Regeneration Full Technology Feasibility Study B1 - Solvent-based Systems  

SciTech Connect (OSTI)

PNNL, Fluor Corporation and Queens University (Kingston, ON) successfully completed a three year comprehensive study of the CO2BOL water-lean solvent platform with Polarity Swing Assisted Regeneration (PSAR). This study encompassed solvent synthesis, characterization, environmental toxicology, physical, thermodynamic and kinetic property measurements, Aspen Plus™ modeling and bench-scale testing of a candidate CO2BOL solvent molecule. Key Program Findings The key program findings are summarized as follows: • PSAR favorably reduced stripper duties and reboiler temperatures with little/no impact to absorption column • >90% CO2 capture was achievable at reasonable liquid-gas ratios in the absorber • High rich solvent viscosities (up to 600 cP) were successfully demonstrated in the bench-scale system. However, the projected impacts of high viscosity to capital cost and operational limits compromised the other levelized cost of electricity benefits. • Low thermal conductivity of organics significantly increased the required cross exchanger surface area, and potentially other heat exchange surfaces. • CO2BOL had low evaporative losses during bench-scale testing • There was no evidence of foaming during bench scale testing • Current CO2BOL formulation costs project to be $35/kg • Ecotoxicity (Water Daphnia) was comparable between CO2BOL and MEA (169.47 versus 103.63 mg/L) • Full dehydration of the flue gas was determined to not be economically feasible. However, modest refrigeration (13 MW for the 550 MW reference system) was determined to be potentially economically feasible, and still produce a water-lean condition for the CO2BOLs (5 wt% steady-state water loading). • CO2BOLs testing with 5 wt% water loading did not compromise anhydrous performance behavior, and showed actual enhancement of CO2 capture performance. • Mass transfer of CO2BOLs was not greatly impeded by viscosity • Facile separation of antisolvent from lean CO2BOL was demonstrated on the bench cart • No measurable solvent degradation was observed over 4 months of testing – even with 5 wt% water present

Heldebrant, David J

2014-08-31T23:59:59.000Z

348

Assessment of API Thread Connections Under Tight Gas Well Conditions  

E-Print Network [OSTI]

enginering in the form of hydraulic fracturing, efective wel-spacing and optimum wel placement for economic development. Wolhart et al (200) discused how Pemex Exploration and Production (PEMEX) utilized the services of Pinacle Technologies (tiltmeter...

Bourne, Dwayne

2010-01-14T23:59:59.000Z

349

Condition Monitoring of Electrical Power Plant Components During Operational  

E-Print Network [OSTI]

the condition monitoring of a gas turbine during start-up transients. * Corresponding author. E-mail: piero reconstruction, AAKR, Haar transform, Gas turbine, Start-up transients LIST OF SYMBOLS AND ACRONYMS AAKR Auto of a component is typically based on an empirical model that estimates the values of some measurable variables

Paris-Sud XI, Université de

350

Compressed gas manifold  

DOE Patents [OSTI]

A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

2001-01-01T23:59:59.000Z

351

OIL & GAS INSTITUTE Introduction  

E-Print Network [OSTI]

OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

Mottram, Nigel

352

Noble gas magnetic resonator  

DOE Patents [OSTI]

Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

2014-04-15T23:59:59.000Z

353

Transportation and Greenhouse Gas Mitigation  

E-Print Network [OSTI]

fuels (eg diesel, compressed natural gas). Electricity (infossil fuels, such as compressed natural gas and liquefied

Lutsey, Nicholas P.; Sperling, Dan

2008-01-01T23:59:59.000Z

354

Ecological and Economical efficient Heating and Cooling by innovative Gas Motor Heat Pump Systems and Solutions  

E-Print Network [OSTI]

#12;Ecological and Economical efficient Heating and Cooling by innovative Gas Motor Heat Pump use of buildings Gas Heat Pump Solution #12;Gas Heat Pump - deserves special attention due to its source in addition to the outside air ·A further essential component of Gas Heat Pump air conditioning

Oak Ridge National Laboratory

355

Backward Raman amplification in a partially ionized gas A. A. Balakin,1  

E-Print Network [OSTI]

was accessed 10,11 . The experimental success was achieved using a gas jet of propane, subse- quently ionized that would be most desired. Using the pro- pane gas jet, as opposed to pure hydrogen, eased conditions on the gas jet nozzle, since a lower gas pressure could pro- duce a higher density target. However, the use

356

Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report  

SciTech Connect (OSTI)

A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

NONE

1996-03-01T23:59:59.000Z

357

Natural gas monthly  

SciTech Connect (OSTI)

The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.

NONE

1998-01-01T23:59:59.000Z

358

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents [OSTI]

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

359

Multicomponent Gas Diffusion in Porous Electrodes  

E-Print Network [OSTI]

Multicomponent gas transport is investigated with unprecedented precision by AC impedance analysis of porous YSZ anode-supported solid oxide fuel cells. A fuel gas mixture of H2-H2O-N2 is fed to the anode, and impedance data are measured across the range of hydrogen partial pressure (10-100%) for open circuit conditions at three temperatures (800C, 850C and 900C) and for 300mA applied current at 800C. For the first time, analytical formulae for the diffusion resistance (Rb) of three standard models of multicomponent gas transport (Fick, Stefan-Maxwell, and Dusty Gas) are derived and tested against the impedance data. The tortuosity is the only fitting parameter since all the diffusion coefficients are known. Only the Dusty Gas model leads to a remarkable data collapse for over twenty experimental conditions, using a constant tortuosity consistent with permeability measurements and the Bruggeman relation. These results establish the accuracy of the Dusty Gas model for multicomponent gas diffusion in porous med...

Fu, Yeqing; Dutta, Abhijit; Mohanram, Aravind; Pietras, John D; Bazant, Martin Z

2014-01-01T23:59:59.000Z

360

Fission gas release restrictor for breached fuel rod  

DOE Patents [OSTI]

In the event of a breach in the cladding of a rod in an operating liquid metal fast breeder reactor, the rapid release of high-pressure gas from the fission gas plenum may result in a gas blanketing of the breached rod and rods adjacent thereto which impairs the heat transfer to the liquid metal coolant. In order to control the release rate of fission gas in the event of a breached rod, the substantial portion of the conventional fission gas plenum is formed as a gas bottle means which includes a gas pervious means in a small portion thereof. During normal reactor operation, as the fission gas pressure gradually increases, the gas pressure interiorly of and exteriorly of the gas bottle means equalizes. In the event of a breach in the cladding, the gas pervious means in the gas bottle means constitutes a sufficient restriction to the rapid flow of gas therethrough that under maximum design pressure differential conditions, the fission gas flow through the breach will not significantly reduce the heat transfer from the affected rod and adjacent rods to the liquid metal heat transfer fluid flowing therebetween.

Kadambi, N. Prasad (Gaithersburg, MD); Tilbrook, Roger W. (Monroeville, PA); Spencer, Daniel R. (Unity Twp., PA); Schwallie, Ambrose L. (Greensburg, PA)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Gas-cooled nuclear reactor  

DOE Patents [OSTI]

A gas-cooled nuclear reactor includes a central core located in the lower portion of a prestressed concrete reactor vessel. Primary coolant gas flows upward through the core and into four overlying heat-exchangers wherein stream is generated. During normal operation, the return flow of coolant is between the core and the vessel sidewall to a pair of motor-driven circulators located at about the bottom of the concrete pressure vessel. The circulators repressurize the gas coolant and return it back to the core through passageways in the underlying core structure. If during emergency conditions the primary circulators are no longer functioning, the decay heat is effectively removed from the core by means of natural convection circulation. The hot gas rising through the core exits the top of the shroud of the heat-exchangers and flows radially outward to the sidewall of the concrete pressure vessel. A metal liner covers the entire inside concrete surfaces of the concrete pressure vessel, and cooling tubes are welded to the exterior or concrete side of the metal liner. The gas coolant is in direct contact with the interior surface of the metal liner and transfers its heat through the metal liner to the liquid coolant flowing through the cooling tubes. The cooler gas is more dense and creates a downward convection flow in the region between the core and the sidewall until it reaches the bottom of the concrete pressure vessel when it flows radially inward and up into the core for another pass. Water is forced to flow through the cooling tubes to absorb heat from the core at a sufficient rate to remove enough of the decay heat created in the core to prevent overheating of the core or the vessel.

Peinado, Charles O. (La Jolla, CA); Koutz, Stanley L. (San Diego, CA)

1985-01-01T23:59:59.000Z

362

CONDITIONS FOR SUPERNOVAE-DRIVEN GALACTIC WINDS  

SciTech Connect (OSTI)

We point out that the commonly assumed condition for galactic outflows, that supernovae (SNe) heating is efficient in the central regions of starburst galaxies, suffers from invalid assumptions. We show that a large filling factor of hot (?10{sup 6} K) gas is difficult to achieve through SNe heating, irrespective of the SN's initial gas temperature and density, its uniformity, or its clumpiness. We instead suggest that correlated supernovae from OB associations in molecular clouds in the central region can drive powerful outflows if the molecular surface density is >10{sup 3} M {sub ?} pc{sup –2}.

Nath, Biman B. [Raman Research Institute, Sadashiva Nagar, Bangalore 560080 (India)] [Raman Research Institute, Sadashiva Nagar, Bangalore 560080 (India); Shchekinov, Yuri, E-mail: biman@rri.res.in, E-mail: yus@sfedu.ru [Department of Physics, Southern Federal University, Rostov on Don, 344090 (Russian Federation)] [Department of Physics, Southern Federal University, Rostov on Don, 344090 (Russian Federation)

2013-11-01T23:59:59.000Z

363

E-Print Network 3.0 - advanced coal-fired gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CHLORINE LINK IN COMMERCIAL SCALE SYSTEM FLUE GASES? Summary: that Battelle measured dioxins in coal fired utility boiler stack emissions in the United States and by ETSU... in...

364

Hybrid gas bearings with controlled supply pressure to eliminate rotor vibrations while crossing system critical speeds  

E-Print Network [OSTI]

Micro-turbomachinery (MTM) implements gas bearings in compact units of enhanced mechanical reliability. Gas bearings, however, have little damping and are prone to wear during frequent rotor start-up and shut down conditions. Externally pressurized...

Ryu, Keun

2009-05-15T23:59:59.000Z

365

Stochastic Programming Approaches for the Placement of Gas Detectors in Process Facilities  

E-Print Network [OSTI]

of these detectors is required in order to have a well-functioning gas detection system. However, the uncertainty in leak locations, gas composition, process and weather conditions, and process geometries must all be considered when attempting to determine...

Legg, Sean W

2013-05-21T23:59:59.000Z

366

Development of an electrical resistivity cone for the detection of gas hydrates in marine sediments  

E-Print Network [OSTI]

Natural gas hydrates are formed when, under certain pressure and temperature conditions, gas molecules become encaged by hydrogenbonded oxygen atoms, forming a solid, ice-like crystalline substance. They have been found all over the world in both...

McClelland, Martha Ann

1994-01-01T23:59:59.000Z

367

Restricted Natural Gas Supply Case (released in AEO2005)  

Reports and Publications (EIA)

The restricted natural gas supply case provides an analysis of the energy-economic implications of a scenario in which future gas supply is significantly more constrained than assumed in the reference case. Future natural gas supply conditions could be constrained because of problems with the construction and operation of large new energy projects, and because the future rate of technological progress could be significantly lower than the historical rate. Although the restricted natural gas supply case represents a plausible set of constraints on future natural gas supply, it is not intended to represent what is likely to happen in the future.

2005-01-01T23:59:59.000Z

368

Natural gas imports and exports: First quarter report 1995  

SciTech Connect (OSTI)

The Office of Fuels Programs prepares quarterly reports summarizing the data provided by companies authorized to import or export natural gas. Companies are required, as a condition of their authorizations, to file quarterly reports with the OFP. This quarter`s focus is market penetration of gas imports into New England. Attachments show the following: % takes to maximum firm contract levels and weighted average per unit price for the long-term importers, volumes and prices of gas purchased by long-term importers and exporters, volumes and prices for gas imported on short-term or spot market basis, and gas exported short-term to Canada and Mexico.

NONE

1995-07-01T23:59:59.000Z

369

Cost of Gas Adjustment for Gas Utilities (Maine)  

Broader source: Energy.gov [DOE]

This rule, applicable to gas utilities, establishes rules for calculation of gas cost adjustments, procedures to be followed in establishing gas cost adjustments and refunds, and describes reports...

370

Physical Properties of Gas Hydrates: A Review  

SciTech Connect (OSTI)

Methane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 1016?m3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detected by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed.

Gabitto, Jorge [Prairie View A& M University; Tsouris, Costas [ORNL

2010-01-01T23:59:59.000Z

371

Gas Hydrates Research Programs: An International Review  

SciTech Connect (OSTI)

Gas hydrates sediments have the potential of providing a huge amount of natural gas for human use. Hydrate sediments have been found in many different regions where the required temperature and pressure conditions have been satisfied. Resource exploitation is related to the safe dissociation of the gas hydrate sediments. Basic depressurization techniques and thermal stimulation processes have been tried in pilot efforts to exploit the resource. There is a growing interest in gas hydrates all over the world due to the inevitable decline of oil and gas reserves. Many different countries are interested in this valuable resource. Unsurprisingly, developed countries with limited energy resources have taken the lead in worldwide gas hydrates research and exploration. The goal of this research project is to collect information in order to record and evaluate the relative strengths and goals of the different gas hydrates programs throughout the world. A thorough literature search about gas hydrates research activities has been conducted. The main participants in the research effort have been identified and summaries of their past and present activities reported. An evaluation section discussing present and future research activities has also been included.

Jorge Gabitto; Maria Barrufet

2009-12-09T23:59:59.000Z

372

Natural Gas & Local Governments  

E-Print Network [OSTI]

-trailers New business ventures Frac services Water hauling Brine water remediation Pipeline Group #12;2. Sublette County, Wyoming Largest gas-producing county in Wyoming (44% of states gas

Boyer, Elizabeth W.

373

Microminiature gas chromatograph  

DOE Patents [OSTI]

A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

Yu, Conrad M. (Antioch, CA)

1996-01-01T23:59:59.000Z

374

Microminiature gas chromatograph  

DOE Patents [OSTI]

A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

Yu, C.M.

1996-12-10T23:59:59.000Z

375

Recirculating rotary gas compressor  

DOE Patents [OSTI]

A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

Weinbrecht, J.F.

1992-02-25T23:59:59.000Z

376

Recirculating rotary gas compressor  

DOE Patents [OSTI]

A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

1992-01-01T23:59:59.000Z

377

Oil and Gas Exploration  

E-Print Network [OSTI]

Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

Tingley, Joseph V.

378

Gas and Oil (Maryland)  

Broader source: Energy.gov [DOE]

The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

379

Natural gas annual 1996  

SciTech Connect (OSTI)

This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

NONE

1997-09-01T23:59:59.000Z

380

Purchased Gas Adjustment Rules (Tennessee)  

Broader source: Energy.gov [DOE]

The Purchased Gas Adjustment Rules are implemented by the Tennessee Regulatory Authority (Authority). Purchased Gas Adjustment (PGA) Rules are intended to permit the company/LDC (local gas...

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

COMPUTATIONAL OPTIMIZATION OF GAS COMPRESSOR ...  

E-Print Network [OSTI]

Feb 26, 2015 ... When considering cost-optimal operation of gas transport net- works ..... The four most frequently used drive types are gas turbines, gas driven.

2015-02-26T23:59:59.000Z

382

Determination of leakage and unaccounted-for gas distribution  

SciTech Connect (OSTI)

All gas systems leak. Gas escapes every system in one way or another. This is true because gas is permeable to every system. For instance, with PE2306 pipe, the volume of methane lost through permeation in one mile of two-inch pipe operated at 60 psi is about 0.26 cubic feet per day. So, if every system leaks, then how much do we lose? Hence, we have unaccounted-for gas. Unaccounted-for gas is truly accounted-for gas--but it is missing! It is the difference between the amount of gas accounted into a system and the amount of gas accounted out. Many factors cause unaccounted-for gas. Each should be examined before the missing gas is all attributed to leakage--a single cause of unaccounted-for gas. Factors I would suggest evaluating are the following: (1) Measured conditions; (2) Accounting methods; (3) Meter errors; (4) Gas used for construction and operations; (5) Major damage and relief valve trips; (6) Meter reading errors, stolen gas, etc.; and (7) Leakage.

Spriggs, C.M. [Oklahoma Natural Gas Co., Tulsa, OK (United States)

1995-12-01T23:59:59.000Z

383

Evaluation of Gas Reburning and Low-NOx Burners on a Wall-Fired Boiler; a DOE Assessment  

SciTech Connect (OSTI)

The results from the GR-LNB technology demonstrated by EER at Cherokee Station approached, but did not meet, the CCT project's performance objectives. Acceptable unit operability was achieved with both the GR and the LNB components. The gas reburning component of the process appears to be broadly applicable for retrofit NO{sub x} control to most utility boilers and, in particular, to wet-bottom cyclone boilers, which are high NO{sub x} emitters and are difficult to control (LNB technology is not applicable to cyclone boilers). GR-LNB can reduce NO{sub x} to mandated emissions levels under Title IV of the CAAA without significant, adverse boiler impacts. The GR-LNB process may be applicable to boilers significantly larger than the demonstration unit, provided there is adequate dispersion and mixing of injected natural gas. Major results of the demonstration project are summarized as follows: NO{sub x}-emissions reductions averaging 64% were achieved with 12.5% gas heat input in long-term tests on a 158-MWe (net) wall-fired unit. The target reduction level of 70% was achieved only on a short-term basis with higher gas consumption. The thermal performance of coal-fired boilers is not significantly affected by GR-LNB. Convective section steam temperatures can be controlled within acceptable limits. Thermal efficiency is decreased by a small amount (about 0.8%), because of increased dry gas loss and higher moisture in the flue gas as a result of the GR process. Furnace slagging and convective section fouling can be adequately controlled. Because of the higher hydrogen/carbon (H/C) ratio of natural gas compared with coal, use of the GR process results in a modest reduction in CO{sub 2} emissions. SO{sub 2} and particulate emissions are reduced in direct proportion to the fraction of heat supplied by natural gas.

National Energy Technology Laboratory

2001-02-28T23:59:59.000Z

384

Residual gas analysis device  

DOE Patents [OSTI]

A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

Thornberg, Steven M. (Peralta, NM)

2012-07-31T23:59:59.000Z

385

Natural gas annual 1994  

SciTech Connect (OSTI)

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

NONE

1995-11-17T23:59:59.000Z

386

Natural gas annual 1995  

SciTech Connect (OSTI)

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

NONE

1996-11-01T23:59:59.000Z

387

Gas Cylinders: Proper Management  

E-Print Network [OSTI]

Compressed Gas Cylinders: Proper Management And Use Published by the Office of Environment, Health;1 Introduction University of California, Berkeley (UC Berkeley) departments that use compressed gas cylinders (MSDS) and your department's Job Safety Analyses (JSAs). Talk to your gas supplier about hands

Boyer, Elizabeth W.

388

Gas Chromatography -Mass Spectrometry  

E-Print Network [OSTI]

GCMS - 1 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS OF ETHANOL AND BENZENE IN GASOLINE Last updated: June 17, 2014 #12;GCMS - 2 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS). The goal of this experiment is to separate the components in a sample of gasoline using Gas Chromatography

Nizkorodov, Sergey

389

Static gas expansion cooler  

DOE Patents [OSTI]

Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

Guzek, J.C.; Lujan, R.A.

1984-01-01T23:59:59.000Z

390

Valve for gas centrifuges  

DOE Patents [OSTI]

The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

Hahs, C.A.; Rurbage, C.H.

1982-03-17T23:59:59.000Z

391

Advanced Coal-Fueled Gas Turbine Program  

SciTech Connect (OSTI)

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

392

Nuclear liquid-gas phase transition within the lattice gas model  

E-Print Network [OSTI]

We study the nuclear liquid-gas phase transition on the basis of a two-component lattice gas model. A Metropolis type of sampling method is used to generate microscopic states in the canonical ensemble. The effective equation of state and fragment mass distributions are evaluated in a wide range of temperatures and densities. A definition of the phase coexistence region appropriate for mesoscopic systems is proposed. The caloric curve resulting from different types of freeze-out conditions are presented.

J. Borg; I. N. Mishustin; J. P. Bondorf

1998-09-25T23:59:59.000Z

393

Microfluidics: The no-slip boundary condition  

E-Print Network [OSTI]

The no-slip boundary condition at a solid-liquid interface is at the center of our understanding of fluid mechanics. However, this condition is an assumption that cannot be derived from first principles and could, in theory, be violated. We present a review of recent experimental, numerical and theoretical investigations on the subject. The physical picture that emerges is that of a complex behavior at a liquid/solid interface, involving an interplay of many physico-chemical parameters, including wetting, shear rate, pressure, surface charge, surface roughness, impurities and dissolved gas.

Eric Lauga; Michael P. Brenner; Howard A. Stone

2005-09-28T23:59:59.000Z

394

Welcome FUPWG- Natural Gas Overview  

Broader source: Energy.gov [DOE]

Presentation—given at the Federal Utility Partnership Working Group (FUPWG) Fall 2008 meeting—provides an overview of natural gas, including emissions, compressed natural gas (CNG) vehicles, and landfill gas supplement for natural gas system.

395

Natural gas leak mapper  

DOE Patents [OSTI]

A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

2008-05-20T23:59:59.000Z

396

Gas Hydrate Storage of Natural Gas  

SciTech Connect (OSTI)

Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

Rudy Rogers; John Etheridge

2006-03-31T23:59:59.000Z

397

Natural gas imports and exports. Second quarter report  

SciTech Connect (OSTI)

The Office of Natural Gas and Petroleum Import and Export Activities prepares quarterly reports summarizing the data provided by companies authorized to import or export natural gas. Companies are required, as a condition of their authorizations, to file quarterly reports. This report is for the second quarter of 1997 (April through June).

NONE

1997-12-31T23:59:59.000Z

398

Parametric Study of Gas Turbine Film-Cooling  

E-Print Network [OSTI]

In this study, the film-cooling effectiveness in different regions of gas turbine blades was investigated with various film hole/slot configurations and mainstream flow conditions. The study consisted of three parts: 1) turbine blade span film...

Liu, Kevin

2012-10-19T23:59:59.000Z

399

An investigation of real gas effects in supercritical CO? compressors  

E-Print Network [OSTI]

This thesis presents a comprehensive assessment of real gas effects on the performance and matching of centrifugal compressors operating with CO2 at supercritical conditions. The analytical framework combines first principles ...

Baltadjiev, Nikola D. (Nikola Dimitrov)

2012-01-01T23:59:59.000Z

400

Comparison of Palladium and Platinum Water Gas Shift Kinetics Using Density Functional Theory Models.  

E-Print Network [OSTI]

??The Water Gas Shift (WGS) reaction can be either thermodynamically or kinetically limited, depending on process conditions. Improved catalysts are of particular interest at low… (more)

Clay, John

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas conditioning" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Comparison of palladium and platinum Water Gas Shift reaction kinetics using density functional theory models.  

E-Print Network [OSTI]

?? The Water Gas Shift (WGS) reaction can be either thermodynamically or kinetically limited, depending on process conditions. Improved catalysts are of particular interest at… (more)

Clay, John P.

2014-01-01T23:59:59.000Z

402

Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage  

E-Print Network [OSTI]

gas reservoirs for carbon sequestration and enhanced gasproduction and carbon sequestration, Society of Petroleumfeasibiilty of carbon sequestration with enhanced gas

Oldenburg, Curtis M.

2003-01-01T23:59:59.000Z

403

Terms and Conditions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Testbed Results Current Testbed Research Proposal Process Terms and Conditions Dark Fiber Testbed Performance (perfSONAR) Software & Tools Development Partnerships...

404

Turbulent Compressibilty of Protogalactic Gas  

E-Print Network [OSTI]

The star formation rate in galaxies should be related to the fraction of gas that can attain densities large enough for gravitational collapse. In galaxies with a turbulent interstellar medium, this fraction is controlled by the effective barotropic index $gamma = dlog P/dlog (rho)$ which measures the turbulent compressibility. When the cooling timescale is smaller than the dynamical timescale, gamma can be evaluated from the derivatives of cooling and heating functions, using the condition of thermal equilibrium. We present calculations of gamma for protogalaxies in which the metal abundance is so small that H_2 and HD cooling dominates. For a heating rate independent of temperature and proportional to the first power of density, the turbulent gas is relatively "hard", with $gamma >= 1$, at large densities, but moderately "soft", $gamma <= 0.8$, at densities below around $10^4 cm^(-3)$. At low temperatures the density probability distribution should fall ra pidly for densities larger than this value, which corresponds physically to the critical density at which collisional and radiative deexcitation rate s of HD are equal. The densities attained in turbulent protogalaxies thus depend on the relatively large deuterium abundance in our universe. We expect the same physical effect to occur in higher metallicity gas with different coolants. The case in which adiabatic (compressional) heating due to cloud collapse dominates is also discussed, and suggests a criterion for the maximum mass of Population III stars.

John Scalo; Anirban Biswas

2001-11-09T23:59:59.000Z

405

Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems  

DOE Patents [OSTI]

A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

1983-08-26T23:59:59.000Z

406

When Does Aid Conditionality Work?  

E-Print Network [OSTI]

institutions may tailor conditions for success because theytailor their conditions for success, and they are especially

Montinola, Gabriella R.

2010-01-01T23:59:59.000Z

407

Gas shielding apparatus  

DOE Patents [OSTI]

An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

Brandt, D.

1984-06-05T23:59:59.000Z

408

Air- and Oxy-Fired Fireside Corrosion  

SciTech Connect (OSTI)

The primary goal of this work was to examine the corrosion effects from flue gas composition changes arising from oxy?combustion. At 700°C, increased SO{sub X}, CO{sub 2}, and H{sub 2}O contents in the gas phase arising from various oxy?combustion flue gas recirculation scenarios, while maintaining constant ash deposit chemistry, do not increase corrosion in superheater or reheater tubing. At 400°C, for both oxidative and reducing conditions, the corrosion rates were lower than at 700°C.

Holcomb, G. R.; Tylczak, J.; Carney, C.; Laughlin, D.; Zhu, J.; Wise, A.

2014-03-04T23:59:59.000Z

409

Valve for gas centrifuges  

DOE Patents [OSTI]

The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

Hahs, Charles A. (Oak Ridge, TN); Burbage, Charles H. (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

410

Ammonia synthesis gas purification  

SciTech Connect (OSTI)

This patent describes the purification of a reformed gas mixture following water gas shift conversion to produce a purified ammonia synthesis gas stream. The improved processing sequence consisting essentially of: (A) Selectively catalytically oxidizing the residual carbon monoxide content of the gas mixture to carbon dioxide so as to reduce the carbon monoxide content of the gas mixture to less than about 20 ppm, the selective catalytic oxidation being carried out with an excess of air, with the excess oxygen being catalytically reacted with a small amount of hydrogen so that the residual oxygen level is reduced to less than about 3 ppm; (B) removing the bulk of the carbon dioxide content of the gas mixture by liquid absorption; (C) Removing residual amounts of carbon monoxide, carbon dioxide and water by selective adsorption on the fixed beds of a thermal swing adsorption system, a dry, purified ammonia ammonia synthesis gas stream containing less than a total of 10 ppm of carbon monoxide and carbon dioxide being recovered from the thermal swing adsorption system; (D) Passing the resulting dry, purified ammonia synthesis gas stream having a low content of methane to an ammonia production operation without intermediate passage of the ammonia synthesis gas stream to a methanation unit or to a cryogenic unit for removal of carbon monoxide and carbon dioxide therefrom; whereby the efficiency of the overall purification operation and the effective utilization of hydrogen are enhanced.

Fuderer, A.

1986-02-25T23:59:59.000Z

411

Liquefied Natural Gas (Iowa)  

Broader source: Energy.gov [DOE]

This document adopts the standards promulgated by the National Fire Protection Association as rules for the transportation, storage, handling, and use of liquefied natural gas. The NFPA standards...

412

Reversible Acid Gas Capture  

ScienceCinema (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2012-12-31T23:59:59.000Z

413

Natural Gas Rules (Louisiana)  

Broader source: Energy.gov [DOE]

The Louisiana Department of Natural Resources administers the rules that govern natural gas exploration and extraction in the state. DNR works with the Louisiana Department of Environmental...

414

String Gas Baryogenesis  

E-Print Network [OSTI]

We describe a possible realization of the spontaneous baryogenesis mechanism in the context of extra-dimensional string cosmology and specifically in the string gas scenario.

G. L. Alberghi

2010-02-19T23:59:59.000Z

415

Polyport atmospheric gas sampler  

DOE Patents [OSTI]

An atmospheric gas sampler with a multi-port valve which allows for multi, sequential sampling of air through a plurality of gas sampling tubes mounted in corresponding gas inlet ports. The gas sampler comprises a flow-through housing which defines a sampling chamber and includes a gas outlet port to accommodate a flow of gases through the housing. An apertured sample support plate defining the inlet ports extends across and encloses the sampling chamber and supports gas sampling tubes which depend into the sampling chamber and are secured across each of the inlet ports of the sample support plate in a flow-through relation to the flow of gases through the housing during sampling operations. A normally closed stopper means mounted on the sample support plate and operatively associated with each of the inlet ports blocks the flow of gases through the respective gas sampling tubes. A camming mechanism mounted on the sample support plate is adapted to rotate under and selectively lift open the stopper spring to accommodate a predetermined flow of gas through the respective gas sampling tubes when air is drawn from the housing through the outlet port.

Guggenheim, S. Frederic (Teaneck, NJ)

1995-01-01T23:59:59.000Z

416

,"Colorado Natural Gas Prices"  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Natural Gas Prices",8,"Monthly","112014","1151989" ,"Release Date:","1302015"...

417

Oil and Gas (Indiana)  

Broader source: Energy.gov [DOE]

This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

418

Oil and Gas Outlook  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Outlook For Independent Petroleum Association of America November 13, 2014 | Palm Beach, FL By Adam Sieminski, Administrator U.S. Energy Information Administration Recent...

419

Natural gas annual 1997  

SciTech Connect (OSTI)

The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

NONE

1998-10-01T23:59:59.000Z

420

Gas venting system  

DOE Patents [OSTI]

A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stre