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1

Alternative formulations of regenerable flue gas cleanup catalysts  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-01-01T23:59:59.000Z

2

Alternative formulations of regenerable flue gas cleanup catalysts. Progress report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

The major source of man-made SO{sub 2} in the atmosphere is the burning of coal for electric power generation. Coal-fired utility plants are also large sources of NO{sub x} pollution. Regenerable flue gas desulfurization/NO{sub x} abatement catalysts provide one mechanism of simultaneously removing SO{sub 2} and NO{sub x} species from flue gases released into the atmosphere. The purpose of this project is to examine routes of optimizing the adsorption efficiency, the adsorption capacity, and the ease of regeneration of regenerable flue gas cleanup catalysts. We are investigating two different mechanisms for accomplishing this goal. The first involves the use of different alkali and alkaline earth metals as promoters for the alumina sorbents to increase the surface basicity of the sorbent and thus adjust the number and distribution of adsorption sites. The second involves investigation of non-aqueous impregnation, as opposed to aqueous impregnation, as a method to obtain an evenly dispersed monolayer of the promoter on the surface.

Mitchell, M.B.; White, M.G.

1991-12-31T23:59:59.000Z

3

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

The SNRB{trademark} Flue Gas Cleanup Demonstration Project was cooperatively funded by the U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B&W, the Electric Power Research Institute (EPRI), Ohio Edison, Norton Chemical Process Products Company and the 3M Company. The SNRB{trademark} technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. Development of the SNRB{trademark} process at B&W began with pilot testing of high-temperature dry sorbent injection for SO{sub 2} removal in the 1960`s. Integration of NO{sub x} reduction was evaluated in the 1970`s. Pilot work in the 1980`s focused on evaluation of various NO{sub x} reduction catalysts, SO{sub 2} sorbents and integration of the catalyst with the baghouse. This early development work led to the issuance of two US process patents to B&W - No. 4,309,386 and No. 4,793,981. An additional patent application for improvements to the process is pending. The OCDO was instrumental in working with B&W to develop the process to the point where a larger scale demonstration of the technology was feasible. This report represents the completion of Milestone M14 as specified in the Work Plan. B&W tested the SNRB{trademark} pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R. E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B&W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB{trademark} process. The SNRB{trademark} facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993.

NONE

1995-09-01T23:59:59.000Z

4

Proof-of concept testing of the advanced NOXSO flue gas cleanup process. Final report  

SciTech Connect (OSTI)

The NOXSO Process uses a regenerable sorbent that removes SO{sub 2} and NO{sub x} simultaneously from flue gas. The sorbent is a stabilized {gamma}-alumina bed impregnated with sodium carbonate. The process was successfully tested at three different scales, equivalent to 0.017, 0.06 and 0.75 MW of flue gas generated from a coal-fired power plant. The Proof-of-Concept (POC) Test is the last test prior to a full-scale demonstration. A slip stream of flue gas equivalent to a 5 MW coal-fired power plant was used for the POC test. This paper summarizes the NOXSO POC plant and its test results.

Not Available

1993-04-01T23:59:59.000Z

5

Advanced separation technology for flue gas cleanup. Quarterly technical report No. 8, [January--March 1994  

SciTech Connect (OSTI)

During the first quarter of 1994, we continued work on Tasks 2, 3, 4, 5, and 6. We also began work on Task 7. In Task 2, we incorporated 4.5% O{sub 2} into our simulated flue gas stream during this quarter`s NO{sub x}-absorption experiments. We also ran experiments using Cobalt (II)-phthalocyanine as an absorbing agent We observed higher absorption capacities when using this solution with the simulated flue gas containing O{sub 2}. In Task 3, we synthesized a few EDTA polymer analogs. We also began scaled up synthesis of Co(II)-phthalocyanine for use in Task 5. In Task 4, we performed experiments for measuring distribution coefficients (m{sub i}) Of SO{sub 2} between aqueous and organic phases. This was done using the liquor regenerating apparatus described in Task 6. In Task 5, we began working with Co(II)-phthalocyanine in the 301 fiber hollow fiber contactor. We also calculated mass transfer coefficients (K{sub olm}) for these runs, and we observed that the gas side resistance dominates mass transfer. In Task 6, in the liquor regeneration apparatus, we observed 90% recovery of SO{sub 2} by DMA from water used as the scrubbing solution. We also calculated the distribution of coefficients (m{sub i}). In Task 7, we established and began implementing a methodology for completing this task.

Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S. [SRI International, Menlo Park, CA (United States)] [SRI International, Menlo Park, CA (United States); Sirkar, K.K.; Majumdar, S.; Bhaumick, D. [New Jersey Inst. of Tech., Newark, NJ (United States)] [New Jersey Inst. of Tech., Newark, NJ (United States)

1994-03-01T23:59:59.000Z

6

SOx-NOx-Rox Box{trademark} flue gas clean-up demonstration. Final report  

SciTech Connect (OSTI)

Babcock and Wilcox`s (B and W) SOx-NOx-Rox Box{trademark} process effectively removes SOx, NOx and particulate (Rox) from flue gas generated from coal-fired boilers in a single unit operation, a high temperature baghouse. The SNRB technology utilizes dry sorbent injection upstream of the baghouse for removal of SOx and ammonia injection upstream of a zeolitic selective catalytic reduction (SCR) catalyst incorporated in the baghouse to reduce NOx emissions. Because the SOx and NOx removal processes require operation at elevated gas temperatures (800--900 F) for high removal efficiency, high-temperature fabric filter bags are used in the baghouse. The SNRB technology evolved from the bench and laboratory pilot scale to be successfully demonstrated at the 5-MWe field scale. This report represents the completion of Milestone M14 as specified in the Work Plan. B and W tested the SNRB pollution control system at a 5-MWe demonstration facility at Ohio Edison`s R.E. Burger Plant located near Shadyside, Ohio. The design and operation were influenced by the results from laboratory pilot testing at B and W`s Alliance Research Center. The intent was to demonstrate the commercial feasibility of the SNRB process. The SNRB facility treated a 30,000 ACFM flue gas slipstream from Boiler No. 8. Operation of the facility began in May 1992 and was completed in May 1993. About 2,300 hours of high-temperature operation were achieved. The main emissions control performance goals of: greater than 70% SO{sub 2} removal using a calcium-based sorbent; greater than 90% NOx removal with minimal ammonia slip; and particulate emissions in compliance with the New Source Performance Standards (NSPS) of 0.03 lb/million Btu were exceeded simultaneously in the demonstration program when the facility was operated at optimal conditions. Testing also showed significant reductions in emissions of some hazardous air pollutants.

NONE

1995-09-01T23:59:59.000Z

7

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 15, September 1, 1994--November 30, 1994  

SciTech Connect (OSTI)

The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

NONE

1997-01-01T23:59:59.000Z

8

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report, No. 14, June 1, 1994--August 31, 1994  

SciTech Connect (OSTI)

The objective of the NOXSO Demonstration Project (NDP), with cost-shared funding support from DOE, is to design, construct, and operate a commercial-scale flue gas cleanup system utilizing the NOXSO process. The NDP consists of the NOXSO plant and sulfur recovery unit, designed to remove SO{sub 2} and NO{sub x} from flue gas and produce elemental sulfur by-product, and the liquid SO{sub 2} plant and air separation unit, designed to process the elemental sulfur into liquid SO{sub 2}. The NOXSO plant and sulfur recovery unit will be constructed at ALCOA Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana, and will treat all of the flue gas from the 150-MW Unit 2 boiler. The elemental sulfur produced will be shipped to the Olin Charleston Plant in Charleston, Tennessee, for conversion into liquid SO{sub 2}.

NONE

1997-01-01T23:59:59.000Z

9

Integrated flue gas processing method  

SciTech Connect (OSTI)

A system and process for flue gas processing to remove both gaseous contaminants such as sulfur dioxide and particulate matter such as flyash integrates spray scrubbing apparatus and wet electrostatic precipitation apparatus and provides for the advantageous extraction and utilization of heat present in the flue gas which is being processed. The integrated system and process utilizes a spray scrubbing tower into which the flue gas is introduced and into which aqueous alkali slurry is introduced as spray for sulfur dioxide removal therein. The flue gas leaves the tower moisture laden and enters a wet electrostatic precipitator which includes a heat exchanger where flyash and entrained droplets in the flue gas are removed by electrostatic precipitation and heat is removed from the flue gas. The cleaned flue gas exits from the precipitator and discharges into a stack. The heat removed from the flue gas finds use in the system or otherwise in the steam generation plant. The wet electrostatic precipitator of the integrated system and process includes a portion constructed as a cross flow heat exchanger with flue gas saturated with water vapor moving vertically upwards inside tubes arranged in a staggered pattern and ambient air being pulled horizontally across the outside of those tubes to cool the tube walls and thereby remove heat from the flue gas and cause condensation of water vapor on the inside wall surfaces. The condensate washes the electrostatically collected flyash particles down from the inside tube walls. The heat that is extracted from the saturated flue gas in the wet electrostatic precipitator heat exchanger may be utilized in several different ways, including: (1) for flue gas reheat after the wet electrostatic precipitator; (2) for preheating of combustion air to the steam generator boiler; and, (3) for heating of buildings.

Bakke, E.; Willett, H.P.

1982-12-21T23:59:59.000Z

10

Gas stream cleanup  

SciTech Connect (OSTI)

This report describes the current status and recent accomplishments of gas stream cleanup (GSCU) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Gas Stream Cleanup Program is to develop contaminant control strategies that meet environmental regulations and protect equipment in advanced coal conversion systems. Contaminant control systems are being developed for integration into seven advanced coal conversion processes: Pressurized fludized-bed combustion (PFBC), Direct coal-fueled turbine (DCFT), Intergrated gasification combined-cycle (IGCC), Gasification/molten carbonate fuel cell (MCFC), Gasification/solid oxide fuel cell (SOFC), Coal-fueled diesel (CFD), and Mild gasification (MG). These advanced coal conversion systems present a significant challenge for development of contaminant control systems because they generate multi-contaminant gas streams at high-pressures and high temperatures. Each of the seven advanced coal conversion systems incorporates distinct contaminant control strategies because each has different contaminant tolerance limits and operating conditions. 59 refs., 17 figs., 5 tabs.

Bossart, S.J.; Cicero, D.C.; Zeh, C.M.; Bedick, R.C.

1990-08-01T23:59:59.000Z

11

Mercury sorbent delivery system for flue gas  

DOE Patents [OSTI]

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Klunder; ,Edgar B. (Bethel Park, PA)

2009-02-24T23:59:59.000Z

12

Recovery of Water from Boiler Flue Gas  

SciTech Connect (OSTI)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature regions of the heat transfer apparatus, while hydrochloric and nitric acid vapors condensed with the water vapor in the low temperature region. Measurements made of flue gas mercury concentrations upstream and downstream of the heat exchangers showed a significant reduction in flue gas mercury concentration within the heat exchangers. A theoretical heat and mass transfer model was developed for predicting rates of heat transfer and water vapor condensation and comparisons were made with pilot scale measurements. Analyses were also carried out to estimate how much flue gas moisture it would be practical to recover from boiler flue gas and the magnitude of the heat rate improvements which could be made by recovering sensible and latent heat from flue gas.

Edward Levy; Harun Bilirgen; Kwangkook Jeong; Michael Kessen; Christopher Samuelson; Christopher Whitcombe

2008-09-30T23:59:59.000Z

13

Flue gas desulfurization  

DOE Patents [OSTI]

A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

Im, Kwan H. (Lisle, IL); Ahluwalia, Rajesh K. (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

14

Flue gas desulfurization  

DOE Patents [OSTI]

The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

Im, K.H.; Ahluwalia, R.K.

1984-05-01T23:59:59.000Z

15

Final Flue Gas Cleaning (FFGC)  

E-Print Network [OSTI]

the surrounding area but can also be carried thousands of miles by trade winds before falling to ground level to pollute soil, vegetation and water resources. An obvious question is: why doesn’t industry cool the flue gas; condense out the pollutants... of handling and disposing of these pollutants at the plant site. 2. Oxides of sulfur and nitrogen can condense out as an acid, including carbonic acid that attacks materials of construction. By keeping temperatures elevated, carbon steel construction can...

Stinger, D. H.; Romero, M. H.

2006-01-01T23:59:59.000Z

16

natural gas+ condensing flue gas heat recovery+ water creation...  

Open Energy Info (EERE)

natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

17

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 13, March 1, 1994--May 31, 1994  

SciTech Connect (OSTI)

The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from the flue gas of a coal-fired utility boiler. In the process, the SO{sub 2} is converted to a sulfur by-product and the NO{sub x} is converted to nitrogen and oxygen. It is predicted that the process can economically remove 90% of the acid rain precursor gases from the flue gas stream in a retrofit or new facility. The objective of the NOXSO Demonstration Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process. The effectiveness of the process will be demonstrated by achieving significant reductions in emissions of sulfur and nitrogen oxides. In addition, sufficient operating data will be obtained to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is presently in the project definition and preliminary design phase. Data obtained during pilot plant testing which was completed on July 30, 1993 is being incorporated in the design of the commercial size plant. A suitable host site to demonstrate the NOXSO process on a commercial scale is presently being sought. Preliminary engineering activities involved evaluating various design options for the major process vessels with the principal focus being on the sorbent heater vessel, which is operated at the highest temperature. Additionally, the impact of the NOXSO system on power plant particulate emissions and opacity was estimated. It is predicted that particulate emissions will decrease slightly while opacity will increase slightly. Neither change will be significant enough to have an impact on emissions compliance. Advertised performance of the proposed adsorber separator is being verified by laboratory testing. Process studies activities included POC equipment inspection and materials evaluations.

NONE

1994-12-31T23:59:59.000Z

18

Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems  

SciTech Connect (OSTI)

The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

Not Available

1990-12-01T23:59:59.000Z

19

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-09-29T23:59:59.000Z

20

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-08-18T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Control of scale in flue gas scrubbers  

SciTech Connect (OSTI)

This patent describes a flue gas desulfurization system in which sulfur dioxide-containing flue gas is passed in countercurrent flow with an aqueous calcium-bearing scrubbing liquor whereby the sulfur dioxide is removed from the flue gas by being absorbed by the scrubbing liquor and converted to calcium sulfite and/or calcium sulfate. The improvement of minimizing the formation of calcium scale on the surfaces of the system comprises maintaining in the scrubbing liquor about 0.1-25 ppm of a 1:1 diisobutylene-maleic anhydride copolymer having an average molecular weight of 11000. The copolymer is incorporated in the scrubbing liquor as a 10-15% aqueous dispersion.

Thomas, P.A.; Dewitt-Dick, D.B.

1987-06-02T23:59:59.000Z

22

Commercial demonstration of the NOXSO SO{sub 2}/NO{sub x} removal flue gas cleanup system. Quarterly technical progress report No. 16, December 1, 1994--February 28, 1995  

SciTech Connect (OSTI)

The NOXSO process is a dry, post-combustion flue gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from flue gas. In the process, the SO{sub 2} is converted to a sulfur by- product (elemental sulfur, sulfuric acid, or liquid SO{sub 2}) and the NO{sub x} is converted to nitrogen and oxygen. The objective of the NOXSO Clean Coal Project is to design, construct, and operate a flue gas treatment system utilizing the NOXSO process at Alcoa Generating Corporation`s (AGC) Warrick Power Plant. The NOXSO plant is being designed to remove 98% of the SO{sub 2} and 75% of the NO{sub x} from the flue gas from the 150-MW equivalent, unit 2 boiler. The by-product to be generated by the project is liquid SO{sub 2}. Sufficient construction cost and operating data will be obtained during the project to confirm the process economics and provide a basis to guarantee performance on a commercial scale. The project is in the Front End Engineering/Environmental Evaluation Phase. Engineering activities are approximately 20% complete and activities to update the project estimate based on completed engineering and equipment bids have been initiated. Process study activities include laboratory fluid-bed adsorber studies, regenerator computer model development and studies, fluid-flow modelling in fluid-bed vessels, and evaluations of SO{sub 2} production processes. The laboratory- scale, fluid-bed adsorber studies are being conducted to improve the accuracy of the removal efficiency predictions and study the impact of adding a third adsorber stage. The construction of the steel, multi-stage reactor is currently underway. The regenerator computer model was revised and is being used to study design options for improving the regenerator performance. Fluid-flow modelling has been conducted to study the effect of grid supports on the gas flow inside the fluid bed vessels.

NONE

1995-12-31T23:59:59.000Z

23

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

Under the Cooperative Agreement with DOE, Bechtel and Pennsylvania Electric Company (Penelec) will jointly demonstrate Bechtel's confined zone dispersion (CZD) process for removing both sulfur and nitrogen pollutants from the flue gases leaving a coal-fired boiler. Demonstration testing of the CZD process will be conducted on the 147 MWe coal-fired generating Seward Station Unit 15 of Penelec. The test will utilize one-half of the existing flue gas capacity, and will be designed to demonstrate the viability of the process and its operability at a total cost of less than $300/ton of SO{sub 2} removed. The CZD process involves injecting a finely atomized slurry of reactive lime into the duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. 2 figs.

Not Available

1991-02-22T23:59:59.000Z

24

Fundamental mechanisms in flue-gas conditioning  

SciTech Connect (OSTI)

The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

1992-01-09T23:59:59.000Z

25

Cement Kiln Flue Gas Recovery Scrubber Project  

SciTech Connect (OSTI)

The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

National Energy Technology Laboratory

2001-11-30T23:59:59.000Z

26

Biomimetic Membrane for CO2 Capture from Flue Gas  

SciTech Connect (OSTI)

These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer model that supports prediction of heat transfer profiles for larger permeators Tasks 3. 4.1, 4.2--Temperature Range of Enzymes--The goal was to determine if the enzyme operating temperature would limit the range of thermal conditions available to the capture system. We demonstrated the ability of various isozymes (enzyme variants) to operate from 4-85 C. Consequently, the operating characteristics of the enzyme are not a controlling factor. Further, any isozyme whose upper temperature bound is at least 10 C greater than that of the planned inlet temperature will be stable under unanticipated, uncontrolled 'hiccups' in power plant operation. Task 4.4, 4.4--Examination of the Effects of SOx and NOx on Enzyme Activity (Development of Flue Gas Composition Acceptance Standards)--The purpose was to define the inlet gas profile boundaries. We examined the potential adverse effects of flue gas constituents including different acids from to develop an acceptance standard and compared these values to actual PC flue gas composition. Potential issues include changes in pH, accumulation of specific inhibitory anions and cations. A model was developed and validated by test with a SO{sub 2}-laden stream. The predicted and actual data very largely coincided. The model predicted feed stream requirements to allow continuous operation in excess of 2500 hours. We developed operational (physical and chemical) strategies to avoid or ameliorate these effects. Avoidance, the preferred strategy (noted above), is accomplished by more extensive cleanup of the flue gas stream. Task 5--Process Engineering Model--We developed a process-engineering model for two purposes. The first was to predict the physical and chemical status at each test point in the design as a basis for scale-up. The second was to model the capital and operating cost of the apparatus. These were accomplished and used to predict capex, opex and cost of energy. Task 6--Preliminary Commercialization Plan--We carried out analyses of the market and the competition by a variety of parameters. The conclusion was that there is a l

Michael C. Trachtenberg

2007-05-31T23:59:59.000Z

27

Noble metal catalysts for oxidation of mercury in flue gas  

SciTech Connect (OSTI)

The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

Presto, A.A.; Granite, E.J.

2008-04-01T23:59:59.000Z

28

Particulate hot gas stream cleanup technical issues  

SciTech Connect (OSTI)

The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

Pontius, D.H.; Snyder, T.R.

1999-09-30T23:59:59.000Z

29

Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs  

E-Print Network [OSTI]

, corefloods were conducted at 1,500 psig and 70??C, in which flue gas was injected into an Austin chalk core containing initially methane. Two types of flue gases were injected: dehydrated flue gas with 13.574 mole% CO2 (Gas A), and treated flue gas (N2, O2...

Nogueira de Mago, Marjorie Carolina

2005-11-01T23:59:59.000Z

30

Flue gas desulfurization/denitrification using metal-chelate additives  

DOE Patents [OSTI]

A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

1985-08-05T23:59:59.000Z

31

Construction and testing of a flue-gas corrosion probe  

SciTech Connect (OSTI)

The selection of suitable materials for industrial, waste-heat- recovery systems requires assessment of corrosion of materials in various flue-gas environments. Such assessments involve exposing candidate materials to high-temperature flue gases and analyzing the effects of the exposure conditions. Because corrosion is related to flue-gas chemical composition and temperature, variations in temperature complicate the determination of corrosion rates and corrosion mechanisms. Conversely, a relatively constant temperature allows a more accurate determination of the effects of exposure conditions. For this reason, controlled-temperature flue-gas corrosion probes were constructed and tested for exposure tests of materials. A prototype probe consisted of a silicon carbide tube specimen, supporting hardware, and instrumentation for controlling temperature by internal heating and cooling. An advanced probe included other tubular specimens. Testing of the probes in an industrial-type furnace at a nominal flue-gas temperature of 1200{degree}C revealed that temperature control was inadequate. The cooling mode imposed a substantial axial-temperature gradient on the specimens; while the heating mode imposed a smaller gradient, the heating capacity was very limited. 10 refs., 10 figs., 2 tabs.

Federer, J.I.; McEvers, J.A.

1990-08-01T23:59:59.000Z

32

Flue gas injection control of silica in cooling towers.  

SciTech Connect (OSTI)

Injection of CO{sub 2}-laden flue gas can decrease the potential for silica and calcite scale formation in cooling tower blowdown by lowering solution pH to decrease equilibrium calcite solubility and kinetic rates of silica polymerization. Flue gas injection might best inhibit scale formation in power plant cooling towers that use impaired makeup waters - for example, groundwaters that contain relatively high levels of calcium, alkalinity, and silica. Groundwaters brought to the surface for cooling will degas CO{sub 2} and increase their pH by 1-2 units, possibly precipitating calcite in the process. Recarbonation with flue gas can lower the pHs of these fluids back to roughly their initial pH. Flue gas carbonation probably cannot lower pHs to much below pH 6 because the pHs of impaired waters, once outgassed at the surface, are likely to be relatively alkaline. Silica polymerization to form scale occurs most rapidly at pH {approx} 8.3 at 25 C; polymerization is slower at higher and lower pH. pH 7 fluids containing {approx}220 ppm SiO{sub 2} require > 180 hours equilibration to begin forming scale whereas at pH 8.3 scale formation is complete within 36 hours. Flue gas injection that lowers pHs to {approx} 7 should allow substantially higher concentration factors. Periodic cycling to lower recoveries - hence lower silica concentrations - might be required though. Higher concentration factors enabled by flue gas injection should decrease concentrate volumes and disposal costs by roughly half.

Brady, Patrick Vane; Anderson, Howard L., Jr.; Altman, Susan Jeanne

2011-06-01T23:59:59.000Z

33

Evaluation of the Energy Saving Potential from Flue Gas Pressurization  

E-Print Network [OSTI]

details the impact of providing a can be recovered at .1 inch wc. The work of com 500 r----------------------, FLUE GAS TEMPERATURES 200 COUNTER FLOW 100 50 _~,,_ CO-FLOW RECUPERATORS 20 10 SPECIFIC ENERGY, Btu/IbM AIR rl'-h~A:--WORK OF 5... consideration for a convective heat flue gas is entrained, the two are mixed in a exchanger is l600?F for the convective portion of the mixing section, and pressure is then recovered in recuperation equipment. It is significant that for a a diffuser...

Stanton, E. H.

1980-01-01T23:59:59.000Z

34

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

This report describes research conducted between April 1, 2005 and June 30, 2005 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas from coal combustion and synthesis gas from coal gasification. Supported sodium carbonate sorbents removed up to 76% of the carbon dioxide from simulated flue gas in a downflow cocurrent flow reactor system, with an approximate 15 second gas-solid contact time. This reaction proceeds at temperatures as low as 25 C. Lithium silicate sorbents remove carbon dioxide from high temperature simulated flue gas and simulated synthesis gas. Both sorbent types can be thermally regenerated and reused. The lithium silicate sorbent was tested in a thermogravimetric analyzer and in a 1-in quartz reactor at atmospheric pressure; tests were also conducted at elevated pressure in a 2-in diameter high temperature high pressure reactor system. The lithium sorbent reacts rapidly with carbon dioxide in flue gas at 350-500 C to absorb about 10% of the sorbent weight, then continues to react at a lower rate. The sorbent can be essentially completely regenerated at temperatures above 600 C and reused. In atmospheric pressure tests with synthesis gas of 10% initial carbon dioxide content, the sorbent removed over 90% of the carbon dioxide. An economic analysis of a downflow absorption process for removal of carbon dioxide from flue gas with a supported sodium carbonate sorbent suggests that a 90% efficient carbon dioxide capture system installed at a 500 MW{sub e} generating plant would have an incremental capital cost of $35 million ($91/kWe, assuming 20 percent for contingencies) and an operating cost of $0.0046/kWh. Assuming capital costs of $1,000/kW for a 500 MWe plant the capital cost of the down flow absorption process represents a less than 10% increase, thus meeting DOE goals as set forth in its Carbon Sequestration Technology Roadmap and Program Plan.

David A. Green; Thomas Nelson; Brian S. Turk; Paul Box; Weijiong Li; Raghubir P. Gupta

2005-07-01T23:59:59.000Z

35

Direct fired absorption machine flue gas recuperator  

DOE Patents [OSTI]

A recuperator which recovers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine. The recuperator includes a housing with liquid flowing therethrough, the liquid being in direct contact with the combustion gas for increasing the effectiveness of the heat transfer between the gas and the liquid.

Reimann, Robert C. (Lafayette, NY); Root, Richard A. (Spokane, WA)

1985-01-01T23:59:59.000Z

36

Flue gas conditioning for improved particle collection in electrostatic precipitators  

SciTech Connect (OSTI)

The purpose of this research program is to identify and evaluate a variety of additives capable of increasing particle cohesion which could be used for improving collection efficiency in an ESP. A three-phase screening process will be used to provide the, evaluation of many additives in a logical and cost-effective manner. The three step approach involves the following experimental setups: 1. Provide a preliminary screening in the laboratory by measuring the effects of various conditioning agents on reentrainment of flyash particles in an electric field operating at simulated flue gas conditions. 2. Evaluate the successful additives using a 100 acfm bench-scale ESP operating on actual flue gas. 3. Obtain the data required for scaling up the technology by testing the two or three most promising conditioning agents at the pilot scale.

Durham, M.D.

1992-04-27T23:59:59.000Z

37

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

2006-09-30T23:59:59.000Z

38

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between January 1, 2006, and March 31, 2006, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. An integrated system composed of a downflow co-current contact absorber and two hollow screw conveyors (regenerator and cooler) was assembled, instrumented, debugged, and calibrated. A new batch of supported sorbent containing 15% sodium carbonate was prepared and subjected to surface area and compact bulk density determination.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Raghubir P. Gupta

2006-03-31T23:59:59.000Z

39

Thief process for the removal of mercury from flue gas  

DOE Patents [OSTI]

A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

2003-02-18T23:59:59.000Z

40

Water Extraction from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

2006-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

E-Print Network 3.0 - advanced flue gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(WTERT) Collection: Renewable Energy 5 INNOVATIVE TECHNOLOGY FOR THE CONTROL OF AIR POLLUTION AT WASTE-TO-ENERGY Summary: -Beam process is applied to flue gas compositions...

42

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

43

Transport Membrane Condenser for Water and Energy Recovery from Power Plant Flue Gas  

SciTech Connect (OSTI)

The new waste heat and water recovery technology based on a nanoporous ceramic membrane vapor separation mechanism has been developed for power plant flue gas application. The recovered water vapor and its latent heat from the flue gas can increase the power plant boiler efficiency and reduce water consumption. This report describes the development of the Transport Membrane Condenser (TMC) technology in details for power plant flue gas application. The two-stage TMC design can achieve maximum heat and water recovery based on practical power plant flue gas and cooling water stream conditions. And the report includes: Two-stage TMC water and heat recovery system design based on potential host power plant coal fired flue gas conditions; Membrane performance optimization process based on the flue gas conditions, heat sink conditions, and water and heat transport rate requirement; Pilot-Scale Unit design, fabrication and performance validation test results. Laboratory test results showed the TMC system can exact significant amount of vapor and heat from the flue gases. The recovered water has been tested and proved of good quality, and the impact of SO{sub 2} in the flue gas on the membrane has been evaluated. The TMC pilot-scale system has been field tested with a slip stream of flue gas in a power plant to prove its long term real world operation performance. A TMC scale-up design approach has been investigated and an economic analysis of applying the technology has been performed.

Dexin Wang

2012-03-31T23:59:59.000Z

44

Fundamentals of Mercury Oxidation in Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.

JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar

2005-08-01T23:59:59.000Z

45

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between October 1, 2005, and December 31, 2005, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from flue gas from coal combustion. A field test was conducted to examine the extent to which RTI's supported sorbent can be regenerated in a heated, hollow screw conveyor. This field test was conducted at the facilities of a screw conveyor manufacturer. The sorbent was essentially completely regenerated during this test, as confirmed by thermal desorption and mass spectroscopy analysis of the regenerated sorbent. Little or no sorbent attrition was observed during 24 passes through the heated screw conveyor system. Three downflow contactor absorption tests were conducted using calcined sodium bicarbonate as the absorbent. Maximum carbon dioxide removals of 57 and 91% from simulated flue gas were observed at near ambient temperatures with water-saturated gas. These tests demonstrated that calcined sodium carbonate is not as effective at removing CO{sub 2} as are supported sorbents containing 10 to 15% sodium carbonate. Delivery of the hollow screw conveyor for the laboratory-scale sorbent regeneration system was delayed; however, construction of other components of this system continued during the quarter.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Andreas Weber; Raghubir P. Gupta

2006-01-01T23:59:59.000Z

46

Characterization of flue gas residues from municipal solid waste combustors  

SciTech Connect (OSTI)

Solid residues recovered from treatment of flue gas resulting from the combustion of municipal solid waste (MSW) are of particular concern because of ever-increasing worldwide production rates and their concentrations of potentially hazardous transition elements and heavy metals. Three main residue types have been studied in this study: electrostatic precipitator ashes, wet filter cakes, and semidry scrubber residues. Using a large number of residues from two French MSW combustion (MSWC) facilities, the aim of this work is to determine their chemistry and mineralogy in order to shed light on their potential toxicity. The authors find that pollutant concentrations are dependent not only on the composition of MSW but also on the size of particles and flue gas treatment process. Using a procedure based on leaching, grain-size, density, and magnetic separations, the authors present a detailed description of the mineralogy of MSWC solid residues. These residues consist of a very heterogeneous assemblage of glasses, metals, and other crystals in which polluting elements are distributed. The results of this characterization will therefore help to contribute to the development of adequate waste management strategies.

Forestier, L.L. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [ENSG, Vandoeuvre-les-Nancy (France); Libourel, G. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [Univ. H. Poincare, Vandoeuvre-les-Nancy (France)

1998-08-01T23:59:59.000Z

47

Dry flue gas desulfurization process for various coals  

SciTech Connect (OSTI)

Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coal-fired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone. Calcium-based wet systems have, in general, satisfied SO/sub 2/ removal requirements; however, reliability of the early systems was affected by some operational problems. Additionally, sludge dewatering and disposal equipment results in overall system complexity. A dry FGD process which minimizes these problems was developed in late 1970's. It incorporates a spray drying concept for removal of SO/sub 2/ by reaction with lime slurry or soda ash solution. The spray dryer absorber is followed by an electrostatic precipitator or a fabric filter where particulates are collected. The waste product, which is a mixture of FGD reaction products, unreacted reagent and fly ash, is dry thus eliminating the need for dewatering equipment.

Widico, M.J.; Dhargalkar, P.H.

1985-01-01T23:59:59.000Z

48

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

Four grades of sodium bicarbonate and two grades of trona were characterized in terms of particle size distribution, surface area, pore size distribution, and attrition. Surface area and pore size distribution determinations were conducted after calcination of the materials. The sorbent materials were subjected to thermogravimetric testing to determine comparative rates and extent of calcination (in inert gas) and sorption (in a simulated coal combustion flue gas mixture). Selected materials were exposed to five calcination/sorption cycles and showed no decrease in either sorption capacity or sorption rate. Process simulations were conducted involving different heat recovery schemes. The process is thermodynamically feasible. The sodium-based materials appear to have suitable physical properties for use as regenerable sorbents and, based on thermogravimetric testing, are likely to have sorption and calcination rates that are rapid enough to be of interest in full-scale carbon sequestration processes.

David A. Green; Brian S. Turk; Raghubir Gupta; Alejandro Lopez-Ortiz

2001-01-01T23:59:59.000Z

49

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

50

Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents  

SciTech Connect (OSTI)

Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

2007-06-30T23:59:59.000Z

51

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

2001-05-01T23:59:59.000Z

52

Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps  

DOE Patents [OSTI]

A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

2012-08-21T23:59:59.000Z

53

Biomass Gas Cleanup Using a Therminator  

SciTech Connect (OSTI)

The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a �¢����Therminator�¢��� to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. We will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700���°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very active cracking catalysts that lose activity due to coking within the order of several seconds.

David C. Dayton; Atish Kataria; Rabhubir Gupta

2012-03-06T23:59:59.000Z

54

Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas  

SciTech Connect (OSTI)

An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

2004-01-01T23:59:59.000Z

55

Desulfurization of flue gas by the confined zone dispersion process  

SciTech Connect (OSTI)

This Confined Zone Dispersion (CZD) process involves injecting a finely atomized slurry of reactive lime into the ductwork of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. The purpose of this project was to prove the CZD process concept by testing it on a limited scale, and then demonstrating the process on a large scale. The scope of work included projecting the cost of commercial implementation. The test facility for the proof-of-concept tests was on a scale equivalent to a 7 MWe generating plant. The large-scale demonstration was made on a scale of 70 MWe. This report describes how data from the two test sites were correlated, and presents conceptual designs for two full-scale retrofit installations. The rationale and data supporting the conclusions are also given in Part 4.

Not Available

1989-10-01T23:59:59.000Z

56

Multi-component removal in flue gas by aqua ammonia  

DOE Patents [OSTI]

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

2007-08-14T23:59:59.000Z

57

Flue gas desulfurization : cost and functional analysis of large-scale and proven plants  

E-Print Network [OSTI]

Flue Gas Desulfurization is a method of controlling the emission of sulfurs, which causes the acid rain. The following study is based on 26 utilities which burn coal, have a generating capacity of at least 50 Megawatts ...

Tilly, Jean

1983-01-01T23:59:59.000Z

58

Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams  

E-Print Network [OSTI]

An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

Latcham, Jacob G. (Jacob Greco)

2009-01-01T23:59:59.000Z

59

New Developments in Closed Loop Combustion Control Using Flue Gas Analysis  

E-Print Network [OSTI]

New developments in closed loop combustion control are causing radical changes in the way combustion control systems are implemented. The recent availability of in line flue gas analyzers and microprocessor technology are teaming up to produce...

Nelson, R. L.

1981-01-01T23:59:59.000Z

60

Profitability of CCS with flue gas bypass and solvent storage Supplementary Information  

E-Print Network [OSTI]

1 Profitability of CCS with flue gas bypass and solvent storage #12; 2 Perfect information model formulation Sets t T Time, in hours, from K Capital cost to oversize turbine if solvent storage or bypass are used

Jaramillo, Paulina

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Separation of flue-gas scrubber sludge into marketable products  

SciTech Connect (OSTI)

A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium sulfite/sulfate material can be oxidized into a synthetic gypsum that can be used in several markets which include: wallboard manufacturing, plaster, portland cement, and as a soil conditioner. Single stage water-only cycloning removed nearly 50% of the limestone by weight from the scrubber sludge and maintained a weight recovery of 76%. Froth flotation produced a calcium sulfite/sulfate that contained 4.30% limestone by weight with a 71% weight recovery. These methods were successful in removing some of the limestone impurity, but were not able to meet the specifications needed. However, the combination of water-only cycloning and froth flotation provided a clean, useful calcium sulfite/sulfate material with a limestone grade of 1.70% by weight and a total weight recovery of nearly 66%.

Kawatra, S.K.; Eisele, T.C.

1997-08-31T23:59:59.000Z

62

Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations  

SciTech Connect (OSTI)

The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

Presto, A.A.; Granite, E.J

2008-07-01T23:59:59.000Z

63

CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS  

SciTech Connect (OSTI)

The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport reactor systems is planned to demonstrate the feasibility of this process in large scale operations to separate carbon dioxide from flue gas.

David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

2001-10-01T23:59:59.000Z

64

Analysis of Halogen-Mercury Reactions in Flue Gas  

SciTech Connect (OSTI)

Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

2010-01-01T23:59:59.000Z

65

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

SciTech Connect (OSTI)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

National Energy Technology Laboratory

2001-08-31T23:59:59.000Z

66

Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”  

SciTech Connect (OSTI)

A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

Granite, E.J.; Presto, A.A.

2008-09-01T23:59:59.000Z

67

In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas  

SciTech Connect (OSTI)

A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

NONE

2008-04-01T23:59:59.000Z

68

Near-Zero Emissions Oxy-Combustion Flue Gas Purification  

SciTech Connect (OSTI)

The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

2012-06-30T23:59:59.000Z

69

High-level waste vitrification off-gas cleanup technology  

SciTech Connect (OSTI)

This brief overview is intended to be a basis for discussion of needs and problems existing in the off-gas clean-up technology. A variety of types of waste form and processes are being developed in the United States and abroad. A description of many of the processes can be found in the Technical Alternative Documents (TAD). Concurrently, off-gas processing systems are being developed with most of the processes. An extensive review of methodology as well as decontamination factors can be found in the literature. Since it is generally agreed that the most advanced solidification process is vitrification, discussion here centers about the off-gas problems related to vitrification. With a number of waste soldification facilities around the world in operation, it can be shown that present technology can satisfy the present requirement for off-gas control. However, a number of areas within the technology base show potential for improvement. Fundamental as well as verification studies are needed to obtain the improvements.

Hanson, M.S.

1980-01-01T23:59:59.000Z

70

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas  

SciTech Connect (OSTI)

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01T23:59:59.000Z

71

Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using flue gas  

E-Print Network [OSTI]

Experimental analysis and model-based optimization of microalgae growth in photo-bioreactors using]. Besides physical and chemical methods for sequestration of CO2 from flue gas [2], microalgae culture holds great potential for converting flue gas to biomass. Microalgae can capture solar energy more efficiently

Subramanian, Venkat

72

Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas  

DOE Patents [OSTI]

Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

2012-11-06T23:59:59.000Z

73

High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents  

SciTech Connect (OSTI)

The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

2002-09-20T23:59:59.000Z

74

The Beckett System Recovery and Utilization of Low Grade Waste Heat From Flue Gas  

E-Print Network [OSTI]

THE BECKETT SYSTEM RECOVERY AND UTILIZATION OF LOW GRADE WASTE HEAT FROM FLUE GAS Wilfred R. Henderson Blenkhorn & Sawle Ltd. St. Catharines, Ontario Joseph F. DeBiase John Deere WeIland I%rks WeIland, Ontario ABSTRACT The Beckett Heat Recovery...

Henderson, W. R.; DeBiase, J. F.

1983-01-01T23:59:59.000Z

75

Synthetic aggregates prepared from flue gas desulfurization by-products using various binder materials  

SciTech Connect (OSTI)

Flue Gas Desulfurization (FGD) by-products can be converted into environmentally safe and structurally stable aggregates. One type of synthetic aggregate was prepared using an optimum mixture of (FGD) by-products, fly ash, and water. Mineral reactions have been examined using X-ray diffraction and scanning electron microscope.

Bellucci, J.; Graham, U.M.; Hower, J.C.; Robl, T.L. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1994-12-31T23:59:59.000Z

76

Hot-gas cleanup system model development. Volume I. Final report  

SciTech Connect (OSTI)

This two-volume report summarizes the state of the art in performance modeling of advanced high-temperature, high-pressure (HTHP) gas cleanup devices. Volume I contains the culmination of the research effort carried over the past 12 months and is a summary of research achievements. Volume II is the user's manual for the computer programs developed under the present research project. In this volume, Section 2 presents background information on pressurized, fluidized-bed combustion concepts, a description of the role of the advanced gas cleanup systems, and a list of advanced gas cleanup systems that are currently in development under DOE sponsorship. Section 3 describes the methodology for the software architecture that forms the basis of the well-disciplined and structured computer programs developed under the present project. Section 4 reviews the fundamental theories that are important in analyzing the cleanup performance of HTHP gas filters. Section 5 discusses the effect of alkali agents in HTHP gas cleanup. Section 6 evaluates the advanced HTHP gas cleanup models based on their mathematical integrity, availability of supporting data, and the likelihood of commercialization. As a result of the evaluation procedure detailed in Section 6, five performance models were chosen to be incorporated into the overall system simulation code, ASPEN. These five models (the electrocyclone, ceramic bag filter, moving granular bed filter, electrostatic granular bed filter, and electrostatic precipitator) are described in Section 7. The method of cost projection for these five models is discussed in Section 8. The supporting data and validation of the computer codes are presented in Section 9, and finally the conclusions and recommendations for the HTHP gas cleanup system model development are given in Section 10. 72 references, 19 figures, 25 tables.

Ushimaru, K.; Bennett, A.; Bekowies, P.J.

1982-11-01T23:59:59.000Z

77

MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS  

SciTech Connect (OSTI)

The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

2009-03-31T23:59:59.000Z

78

ENGINEERING A NEW MATERIAL FOR HOT GAS CLEANUP  

SciTech Connect (OSTI)

The overall purpose of this project was to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas with the sorbent being in the form of small pellets made with a layered structure such that each pellet consists of a highly reactive lime core enclosed within a porous protective shell of strong but relatively inert material. The sorbent can be very useful for hot gas cleanup in advanced power generation systems where problems have been encountered with presently available materials. An economical method of preparing the desired material was demonstrated with a laboratory-scale revolving drum pelletizer. Core-in-shell pellets were produced by first pelletizing powdered limestone or other calcium-bearing material to make the pellet cores, and then the cores were coated with a mixture of powdered alumina and limestone to make the shells. The core-in-shell pellets were subsequently calcined at 1373 K (1100 C) to sinter the shell material and convert CaCO{sub 3} to CaO. The resulting product was shown to be highly reactive and a very good sorbent for H{sub 2}S at temperatures in the range of 1113 to 1193 K (840 to 920 C) which corresponds well with the outlet temperatures of some coal gasifiers. The product was also shown to be both strong and attrition resistant, and that it can be regenerated by a cyclic oxidation and reduction process. A preliminary evaluation of the material showed that while it was capable of withstanding repeated sulfidation and regeneration, the reactivity of the sorbent tended to decline with usage due to CaO sintering. Also it was found that the compressive strength of the shell material depends on the relative proportions of alumina and limestone as well as their particle size distributions. Therefore, an extensive study of formulation and preparation conditions was conducted to improve the performance of both the core and shell materials. It was subsequently determined that MgO tends to stabilize the high-temperature reactivity of CaO. Therefore, a sorbent prepared from dolomite withstands the effects of repeated sulfidation and regeneration better than one prepared from limestone. It was also determined that both the compressive strength and attrition resistance of core-in-shell pellets depend on shell thickness and that the compressive strength can be improved by reducing both the particle size and amount of limestone in the shell preparation mixture. A semiempirical model was also found which seems to adequately represent the absorption process. This model can be used for analyzing and predicting sorbent performance, and, therefore, it can provide guidance for any additional development which may be required. In conclusion, the overall objective of developing an economical, reusable, and practical material was largely achieved. The material appears suitable for removing CO{sub 2} from fuel combustion products as well as for desulfurizing hot coal gas.

T.D. Wheelock; L.K. Doraiswamy; K.P. Constant

2003-09-01T23:59:59.000Z

79

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers  

SciTech Connect (OSTI)

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

Edward Levy; Harun Bilirgen; John DuPoint

2011-03-31T23:59:59.000Z

80

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers  

SciTech Connect (OSTI)

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

Levy, Edward; Bilirgen, Harun; DuPont, John

2011-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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81

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 10, February 17--May 31, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). One of the two flue gas ducts leading from the boiler has been retrofitted with the CZD technology. The first existing ESP installed in the station is immediately behind the air preheater. The second ESP, installed about 15 years ago, is about 80 feet away from the first ESP. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2}

Not Available

1993-11-15T23:59:59.000Z

82

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2014-06-01T23:59:59.000Z

83

Flue gas conditioning for improved particle collection in electrostatic precipitators. Quarterly technical report  

SciTech Connect (OSTI)

The purpose of this research program is to identify and evaluate a variety of additives capable of increasing particle cohesion which could be used for improving collection efficiency in an ESP. A three-phase screening process will be used to provide the, evaluation of many additives in a logical and cost-effective manner. The three step approach involves the following experimental setups: 1. Provide a preliminary screening in the laboratory by measuring the effects of various conditioning agents on reentrainment of flyash particles in an electric field operating at simulated flue gas conditions. 2. Evaluate the successful additives using a 100 acfm bench-scale ESP operating on actual flue gas. 3. Obtain the data required for scaling up the technology by testing the two or three most promising conditioning agents at the pilot scale.

Durham, M.D.

1992-04-27T23:59:59.000Z

84

Microalgae Production from Power Plant Flue Gas: Environmental Implications on a Life Cycle Basis  

SciTech Connect (OSTI)

Power-plant flue gas can serve as a source of CO{sub 2} for microalgae cultivation, and the algae can be cofired with coal. This life cycle assessment (LCA) compared the environmental impacts of electricity production via coal firing versus coal/algae cofiring. The LCA results demonstrated lower net values for the algae cofiring scenario for the following using the direct injection process (in which the flue gas is directly transported to the algae ponds): SOx, NOx, particulates, carbon dioxide, methane, and fossil energy consumption. Carbon monoxide, hydrocarbons emissions were statistically unchanged. Lower values for the algae cofiring scenario, when compared to the burning scenario, were observed for greenhouse potential and air acidification potential. However, impact assessment for depletion of natural resources and eutrophication potential showed much higher values. This LCA gives us an overall picture of impacts across different environmental boundaries, and hence, can help in the decision-making process for implementation of the algae scenario.

Kadam, K. L.

2001-06-22T23:59:59.000Z

85

Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass  

SciTech Connect (OSTI)

The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

Anuar, S.H.; Keener, H.M.

1995-12-31T23:59:59.000Z

86

Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal  

SciTech Connect (OSTI)

This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

Eric P. Robertson

2007-09-01T23:59:59.000Z

87

Cleaning of municipal-waste incinerator flue gas in Europe  

SciTech Connect (OSTI)

This paper gives an overview of a substantial ongoing air-pollution-control program in West Germany, as it relates to emission of acid gases and other pollutants from municipal-refuse incineration. It details emission regulations, control means used, and technical advancements accomplished and foreseen. It gives results and the approximate effectiveness of various controls in reducing acid gas, trace organic, trace heavy metal, and particulate-matter emissions. Available data indicate that lime spray dryer/electrostatic precipitator (ESP) and spray-dryer/fabric-filter systems can attain 70-90% acid-gas removal and 97% or more control of dioxins and furans, while limiting mercury emissions to about 0.01-0.07 mg/N-cu m (dry). In comparison, some wet-scrubber systems can attain 90-plus % acid-gas removal with substantial removal of NOx and comparable control of dioxins and furans, while possibly providing consistently lower mercury emissions.

Brna, T.G.; Ellison, W.; Jorgensen, C.

1988-01-01T23:59:59.000Z

88

Catalysts for oxidation of mercury in flue gas  

DOE Patents [OSTI]

Two new classes of catalysts for the removal of heavy metal contaminants, especially mercury (Hg) from effluent gases. Both of these classes of catalysts are excellent absorbers of HCl and Cl.sub.2 present in effluent gases. This adsorption of oxidizing agents aids in the oxidation of heavy metal contaminants. The catalysts remove mercury by oxidizing the Hg into mercury (II) moieties. For one class of catalysts, the active component is selected from the group consisting of iridium (Ir) and iridum-platinum (Ir/Pt) alloys. The Ir and Ir/Pt alloy catalysts are especially corrosion resistant. For the other class of catalyst, the active component is partially combusted coal or "Thief" carbon impregnated with Cl.sub.2. Untreated Thief carbon catalyst can be self-activating in the presence of effluent gas streams. The Thief carbon catalyst is disposable by means of capture from the effluent gas stream in a particulate collection device (PCD).

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2010-08-17T23:59:59.000Z

89

Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

2012-03-31T23:59:59.000Z

90

SOx-NOx-Rox Box Flue Gas Cleanup Demonstration: A DOE Assessment  

SciTech Connect (OSTI)

The SNRB{trademark} test program demonstrated the feasibility of controlling multiple emissions from a coal-fired boiler in a single processing unit. The degree of emissions removals for SO{sub 2}, NO{sub x}, and particulates all exceeded the project goals. A high degree of removal for HAPs was also achieved. The SNRB system offers low space requirements, control of multiple pollutants, and operating flexibility. The pneumatic SO{sub 2} sorbent and ammonia injection systems are expected to have high reliability because of their mechanical simplicity. Despite these advantages, the SNRB process may not be an economic choice for applications involving SO{sub 2} removals above about 85%. For lower levels of SO{sub 2} removal, the projected economics for SNRB appear to be more favorable than those of existing processes which involve separate units for the same degree of control for SO{sub 2}, NO{sub x} , and particulates. Specific findings are summarized as follows: (1) SO{sub 2} removal of 85-90% was achieved at a calcium utilization of 40-45%, representing a significant improvement in performance over other dry lime injection processes. (2) When firing 3-4% sulfur coal, compliance with the 1990 CAAA Phase I SO{sub 2} emissions limit of 2.5 lb/10{sup 6} Btu was achieved with a Ca/S molar ratio of less than 1.0. For the Phase II SO{sub 2} emissions limit of 1.2 lb/10{sup 6} Btu, compliance was achieved with a Ca/S molar ratio as low as 1.5. Phase II compliance is the more relevant emissions limit. (3) When using NaHCO{sub 3} as the sorbent, the Phase II SO{sub 2} emissions limit was achieved at a Na{sub 2}/S molar ratio of less than 2.0 (NSR < 1.0). (4) Compliance with the Phase I NO{sub x} emissions limit of 0.45 lb/10{sup 6} Btu for Group 1 boilers was achieved at an NH{sub 3}/NO{sub x} ratio of 0.85, with an ammonia slip of 5 ppm or less. (5) Particulate collection efficiency averaged 99.9%, corresponding to an average emissions rate of 0.018 lb/10{sup 6} Btu. This is significantly lower than the NSPS value of 0.03 lb/10{sup 6} Btu. The high-temperature baghouse design incorporating an SCR catalyst for NO{sub x} reduction was demonstrated successfully. The technology is ready for commercial application. The key feature of the technology is control of SO{sub 2}, NO{sub x}, and particulates in a single process unit. However, this limits its commercial market to applications requiring control of all three components. Also, although the testing demonstrated greater than 90% SO{sub 2} capture, this was achieved at high sorbent/sulfur ratios. For applications requiring a high percentage of sulfur removal, a modern conventional FGD unit with LNBs for NO{sub x} control may be the preferred option.

National Energy Technology Laboratory

2000-12-15T23:59:59.000Z

91

Compression stripping of flue gas with energy recovery  

DOE Patents [OSTI]

A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SO.sub.X and NO.sub.X and CO.sub.2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO.sub.2, SO.sub.2, and H.sub.2 O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

Ochs, Thomas L. (Albany, OR); O'Connor, William K. (Lebanon, OR)

2005-05-31T23:59:59.000Z

92

Compression Stripping of Flue Gas with Energy Recovery  

DOE Patents [OSTI]

A method of remediating and recovering energy from combustion products from a fossil fuel power plant having at least one fossil fuel combustion chamber, at least one compressor, at least one turbine, at least one heat exchanger and a source of oxygen. Combustion products including non-condensable gases such as oxygen and nitrogen and condensable vapors such as water vapor and acid gases such as SOX and NOX and CO2 and pollutants are produced and energy is recovered during the remediation which recycles combustion products and adds oxygen to support combustion. The temperature and/or pressure of the combustion products are changed by cooling through heat exchange with thermodynamic working fluids in the power generation cycle and/or compressing and/or heating and/or expanding the combustion products to a temperature/pressure combination below the dew point of at least some of the condensable vapors to condense liquid having some acid gases dissolved and/or entrained and/or directly condense acid gas vapors from the combustion products and to entrain and/or dissolve some of the pollutants while recovering sensible and/or latent heat from the combustion products through heat exchange between the combustion products and thermodynamic working fluids and/or cooling fluids used in the power generating cycle. Then the CO2, SO2, and H2O poor and oxygen enriched remediation stream is sent to an exhaust and/or an air separation unit and/or a turbine.

Ochs, Thomas L.; O'Connor, William K.

2005-05-31T23:59:59.000Z

93

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

94

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Wood Feedstock  

SciTech Connect (OSTI)

As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for treatment of wood-derived syngas for use in the synthesis of liquid fuels. Two different 2,000 metric tonne per day gasification schemes, a low-pressure, indirect system using the gasifier, and a high-pressure, direct system using gasification technology were evaluated. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

Nexant Inc.

2006-05-01T23:59:59.000Z

95

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

Kenneth E. Baldrey

2003-01-01T23:59:59.000Z

96

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly report, April--June 1995  

SciTech Connect (OSTI)

This quarterly technical progress report summarizes the work completed during the first quarter, April 1 through June 30, 1995. The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasificafion and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel continued at a good pace during the quarter.

NONE

1995-08-01T23:59:59.000Z

97

Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly report, October--December 1994  

SciTech Connect (OSTI)

The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs. Substantial progress in underground construction activities was achieved during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. MWK equipment at the grade level and the first tier are being set in the structure.

NONE

1995-02-01T23:59:59.000Z

98

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks  

SciTech Connect (OSTI)

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

David A Lesch

2010-06-30T23:59:59.000Z

99

Environ. Scl. Technol. 1994, 28, 277-283 Effects of Salts on Preparation and Use of Calcium Silicates for Flue Gas  

E-Print Network [OSTI]

Silicates for Flue Gas Desulfurization Kurt K. Klnd, Phlllp D. Wasserman, and Gary 1.Rochelle' Department is a flue gas desulfurization (FGD) technology developed for existingcoal to remove sulfur dioxide. High surface area calcium silicate hydrates are made by slurrying Ca(0H

Rochelle, Gary T.

100

Flue gas cleaning with ammonia reduces SO{sub 2} emission  

SciTech Connect (OSTI)

This paper describes the technical and commercial development and basis for application in North America for wet flue gas desulfurization (FGD) of the AMASOX{reg_sign} (i.e. Ammonia Absorbs Sulfur Oxides) Process of Krupp Uhde (Germany) employing ammonia reagent. This process technology has been emerging slowly and stepwise over a twenty-year period in reaching the present stage of commercial applicability. The discussion herein considers the need for accommodating to and advantageously addressing the increasing number of applications with high and ultra-high flue-gas concentrations of SO{sub 2} at the boiler outlet accompanied by significant levels of other pollutants. Key measures in accomplishing this include use of important process innovations. This, as well, calls for the effective use, when applicable, of wet electrostatic precipitator mist-elimination means to gain low/minimum-opacity stack plume trailoff in wet scrubber use together with reduction of air toxics to low concentrations. With cost-effectiveness in electric utility service, detailed herein, superior to FGD processes commonly used to date in high-sulfur service, utilization of this technology is expanding. Important, potentially trend-setting types of powerplant applications of ammonia FGD are reviewed to identify foreseen market sectors and procurement trends that will at the same time serve to substantially broaden lowest-cost coal utilization.

Emish, G.J. [Krupp Wilputte Corp., Bridgeville, PA (United States); Schulte, W. [Krupp Uhde GmbH, Dortmund (Germany); Ellison, W. [Ellison Consultants, Monrovia, MD (United States)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2013-08-01T23:59:59.000Z

102

Land application uses for dry flue gas desulfurization by-products: Phase 3  

SciTech Connect (OSTI)

New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

1999-01-31T23:59:59.000Z

103

Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development  

SciTech Connect (OSTI)

The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

Radisav Vidic; Joseph Flora; Eric Borguet

2008-12-31T23:59:59.000Z

104

Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 1  

SciTech Connect (OSTI)

On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster displays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume I covers information presented at sessions 1 through 4 on systems for the production of Co-products and industrial fuel gas, environmental projects, and components and materials. Individual papers have been processed for the Energy Data Base.

Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J. (eds.)

1987-08-01T23:59:59.000Z

105

Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 2  

SciTech Connect (OSTI)

On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster dsplays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume II covers papers presented at sessions 5 and 6 on system for the production of synthesis gas, and on system for the production of power. All papers have been processed for inclusion in the Energy Data Base.

Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J. (eds.)

1987-08-01T23:59:59.000Z

106

Performance and gas cleanup criterion for a cotton gin waste fluidized-bed gasifier  

E-Print Network [OSTI]

Biodegradation Combustion Pyrolysis Gasification . Gas Clean-Up . Fluidized-Bed Gasification DESIGN OF THE GASIFICATION SYSTEM Fluidized-Bed Reactor Particle Size Distributor Plate Insulation Preheaters . Cyclone Feed Injection System Gasifier..., The greatest thermal efficiency appeared to occur near 760'C, well below the expected ash fusion temperature. The gasification reaction was operated with no supplemental heat for most of the experiments. The most prominent problem with the gasifier...

Craig, Joe David

1980-01-01T23:59:59.000Z

107

Hydrodynamics and flue gas desulfurization characteristics of a three-phase, gas-continuous, cocurrent semifluidized bed  

SciTech Connect (OSTI)

The hydrodynamic characteristics of a gas-liquid-solid, gas-continuous, cocurrent semifluidized bed were defined. Five different particle types were used to characterize the hydrodynamics. Air and water were used as the gas and liquid streams, respectively. Six flow regimes were observed in the constrained gas-continuous, three-phase bed. These regimes are described in terms of the solids properties and the gas and liquid superficial velocities. The heights of the packed and fluidized beds and the solids holdup in the fluidized section of the semifluidized bed are discussed in terms of the superficial gas and liquid velocities, the solids density and diameter and the initial quantity of particles in the bed. The desulfurization characteristics of the gas-liquid-solid semifluidized bed were determined using a calcium carbonate slurry. Gas side mass transfer coefficients and the ratio of liquid side to gas side mass transfer coefficients were measured and correlated in terms of gas flow rate, liquid flow rate, bed height, calcium carbonate concentration and sulfur dioxide pressure for both the fluidized and packed sections of the semifluidized bed. The hydrodynamic and mass transfer characteristics were used to construct a mathematical model that predicted overall removal of sulfur dioxide from the simulated flue gas.

Beaver, L.E.

1983-01-01T23:59:59.000Z

108

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-05-01T23:59:59.000Z

109

ENGINEERING A NEW MATERIAL FOR HOT GAS CLEANUP  

SciTech Connect (OSTI)

The overall objective of this project is the engineering development of a reusable calcium-based sorbent for desulfurizing hot coal gas. A two-step pelletization method has been employed to produce relatively strong, ''core-in-shell,'' spherical pellets. Each pellet consists of a highly reactive core surrounded by a strong, inert, porous shell. A suitable core is composed largely of CaO which reacts with H{sub 2}S to form CaS. Pellet cores have been prepared by pelletizing either pulverized limestone or plaster of Paris, and shells have been made of various materials. The most suitable shell material has been formed from a mixture of alumina and limestone particles. The core-in-shell pellets require treatment at high temperature to convert the core material to CaO and to partially sinter the shell material. Pellet cores derived from plaster of Paris have proved superior to those derived from limestone because they react more rapidly with H{sub 2}S and their reactivity does not seem to decline with repeated loading and regeneration. The rate of reaction of H{sub 2}S with CaO derived from either material is directly proportional to H{sub 2}S concentration. The rate of reaction does not appear to be affected significantly by temperature in the range of 1113 K (840 C) to 1193 K (920 C) but decreases markedly at 1233 K (960 C). The rate is not affected by shell thickness within the range tested, which also provides adequate compressive strength.

T.D. Wheelock; L.K. Doraiswamy; K. Constant

2001-06-30T23:59:59.000Z

110

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was completed at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. The product was effective as a flue gas conditioner. However, ongoing problems with in-duct deposition resulting from the flue gas conditioning were not entirely resolved. Primarily these problems were the result of difficulties encountered with retrofit of an existing spray humidification system. Eventually it proved necessary to replace all of the original injection lances and to manually bypass the PLC-based air/liquid feed control. This yielded substantial improvement in spray atomization and system reliability. However, the plant opted not to install a permanent system. Also in this quarter, preparations continued for a test of the cohesivity additives at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-07-01T23:59:59.000Z

111

Monticello Unit 3 recovery project: The rebuild of a first generation wet flue gas desulfurization system  

SciTech Connect (OSTI)

Since November 1993, TU Electric and Sargent & Lundy have been engaged in the repair or replacement of equipment that was damaged by the collapse of the Monticello Unit 3 chimney. In addition to the replacement of the chimney, electrostatic precipitator, and various balance-of-plant systems, the scope of the project includes the demolition, engineering and design, procurement, and construction activities to rebuild major equipment within the wet limestone flue gas desulfurization (FGD) system. This paper reviews and discusses various aspects of the design, procurement and schedule associated with the rebuild of the FGD system. The paper reviews the design selections in the areas of process technology, the absorber island, and technical enhancements to improve the operability of this 1970s-vintage system. Finally, the challenges and solutions in implementing a 17-month schedule for the design, construction, and startup of an FGD system will be discussed.

Guletsky, P.W.; Katzberger, S.M. [Sargent & Lundy, Chicago, IL (United States); Jeanes, R.L. [TU Electric, Dallas, TX (United States)

1995-06-01T23:59:59.000Z

112

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification  

SciTech Connect (OSTI)

As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

Nexant Inc.

2006-05-01T23:59:59.000Z

113

The desulfurization of flue gas at the Mae Moh Power Plant Units 12 and 13  

SciTech Connect (OSTI)

As pollution of air, water and ground increasingly raises worldwide concern, the responsible national and international authorities establish and issue stringent regulations in order to maintain an acceptable air quality in the environment. In Thailand, the Electricity Generating Authority of Thailand (EGAT) takes full responsibility in environmental protection matters as well as in generating the electricity needed to supply the country`s very rapid power demand growth. Due to the rapidly increasing electricity demand of the country, EGAT had decided to install two further lignite-fired units of 300 MW each (Units 12 and 13) at the Mae Moh power generation station and they are now under construction. The arrangement and the capacity of all the power plant units are as shown. In 1989, EGAT started the work on the flue gas desulfurization system of Mae Moh power plant units 12 and 13 as planned. A study has been conducted to select the most suitable and most economical process for flue gas desulfurization. The wet scrubbing limestone process was finally selected for the two new units. Local limestone will be utilized in the process, producing a by-product of gypsum. Unfortunately, natural gypsum is found in abundance in Thailand, so the produced gypsum will be treated as landfill by mixing it with ash from the boilers of the power plants and then carrying it to the ash dumping area. The water from the waste ash water lake is utilized in the process as much as possible to minimize the requirement of service water, which is a limited resource. The Mae Moh power generation station is situated in the northern region of Thailand, 600 km north of Bangkok and about 30 km east of the town of Lampang, close to the Mae Moh lignite mine. Three lignite-fired units (Units 1-3) of 75 MW each, four units (Units 4-7) of 150 MW each and four units (Units 8-11) of 300 MW each are in operation.

Haemapun, C.

1993-12-31T23:59:59.000Z

114

Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report  

SciTech Connect (OSTI)

The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

NONE

1996-04-30T23:59:59.000Z

115

Hot gas cleanup test facility for gasification and pressurized combustion project. Quarterly report, October--December 1995  

SciTech Connect (OSTI)

The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDs) into the structural and process designs. Substantial progress in construction activities was achieved during this quarter.

NONE

1996-02-01T23:59:59.000Z

116

Landfill gas cleanup for carbonate fuel cell power generation. Final report  

SciTech Connect (OSTI)

Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

Steinfield, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

117

Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance  

SciTech Connect (OSTI)

A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ÂşF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

Andrew Seltzer; Zhen Fan

2011-03-01T23:59:59.000Z

118

[Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion]. Quarterly technical progress report, October 1--December 31, 1993  

SciTech Connect (OSTI)

This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, October 1 through December 31, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: (1) Carbonizer/pressurized circulating fluidized bed gas source; (2) hot gas cleanup units to mate to all gas streams; (3) combustion gas turbine; (4) fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

Not Available

1993-12-31T23:59:59.000Z

119

Start up results from a specialized flue gas cleaning facility in a power station using refinery residues  

SciTech Connect (OSTI)

In eastern Germany STEAG--the biggest German IPP--has erected a power plant consisting of three combustion lines burning oil distillation residues from the new Mider refinery to provide the refinery with power, steam, water and compressed air. Each of the three flue gas cleaning lines consists of a high dust SCR-system, quench, wet electrostatic precipitator, scrubber, steam reheater and ID-fan. Common systems are the storage and handling of the absorbent, the gypsum dewatering and the waste water treatment. The installed high dust SCR system attains the expected NO{sub x}-reduction efficiency and an excellent NO{sub x} outlet distribution and low ammonia slip. After commissioning problems occurred with the wet ESP in all three lines due to improper function of the upstream quenches. Modifications of the quench system have been made which assure a temperature of the flue gas after quench near saturation temperature and correct functioning of the quench and wet ESP. To reduce pressure loss of the absorber concurrent spray nozzles were installed. Strong vibrations of the absorber tower, the connected pipes and the steel structure along with an insufficient SO{sub x} removal efficiency at high inlet concentration were observed. After changing the concurrent operation of the spray nozzles to counter current operation the vibrations of the absorber tower became smaller and the removal efficiency achieved the guaranteed value. Problems arose in the waste water treatment plant caused by the high solid concentration of up to 1,000 g/l in the thickener. By diluting the settled sludge with overflow water from the thickener the problems in the waste water treatment plant could be minimized to an acceptable degree. Despite these problems the flue gas cleaning system is in continuous operation and the emission values of flue gas and waste water meet the required standards.

Beiers, H.G.; Gilgen, R.; Weiler, H.

1998-07-01T23:59:59.000Z

120

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

Kenneth E. Baldrey

2002-01-01T23:59:59.000Z

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121

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

Kenneth E. Baldrey

2003-07-30T23:59:59.000Z

122

JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas  

SciTech Connect (OSTI)

This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

Ye Zhuang; Christopher Martin; John Pavlish

2009-03-31T23:59:59.000Z

123

Separation of the components of flue-gas scrubber sludge by froth flotation  

SciTech Connect (OSTI)

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. Currently, the major markets for scrubber sludge are for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. Other markets, such as paper manufacture and plastics fillers, have even more stringent quality requirements and will not accept raw sludge at all. In the work described in this paper, several reagents have been examined to determine their ability to selectively improve the flotation of the unreacted limestone contaminant away from the desirable products (calcium sulfite and gypsum). The most success has been achieved using a cationic collector, which shows a higher selectivity between calcium sulfite and calcium carbonate than do the anionic collectors that were studied.

Kawatra, S.K.; Eisele, T.C. [Michigan Technological Univ., Houghton, MI (United States). Dept. of Metallurgical and Materials Engineering

1995-12-31T23:59:59.000Z

124

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

125

Method of and apparatus for preheating pressurized fluidized bed combustor and clean-up subsystem of a gas turbine power plant  

DOE Patents [OSTI]

In a gas turbine power plant having a pressurized fluidized bed combustor, gas turbine-air compressor subsystem and a gas clean-up subsystem interconnected for fluid flow therethrough, a pipe communicating the outlet of the compressor of the gas turbine-air compressor subsystem with the interior of the pressurized fluidized bed combustor and the gas clean-up subsystem to provide for flow of compressed air, heated by the heat of compression, therethrough. The pressurized fluidized bed combustor and gas clean-up subsystem are vented to atmosphere so that the heated compressed air flows therethrough and loses heat to the interior of those components before passing to the atmosphere.

Cole, Rossa W. (E. Rutherford, NJ); Zoll, August H. (Cedar Grove, NJ)

1982-01-01T23:59:59.000Z

126

Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams .  

E-Print Network [OSTI]

??An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue… (more)

Latcham, Jacob G. (Jacob Greco)

2009-01-01T23:59:59.000Z

127

CO{sub 2} Capture Membrane Process for Power Plant Flue Gas  

SciTech Connect (OSTI)

Because the fleet of coal-fired power plants is of such importance to the nationâ??s energy production while also being the single largest emitter of CO{sub 2}, the development of retrofit, post-combustion CO{sub 2} capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO{sub 2} from plant flue gas with 95% captured CO{sub 2} purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO{sub 2}-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft{sup 2}) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO{sub 2}, NOx, etc.). Specific objectives were: ď?· Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO{sub 2} over N{sub 2} and CO{sub 2} permeance greater than 300 gas permeation units (GPU) targeted; ď?· Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO{sub 2} permeance than current commercial polycarbonate membranes; ď?· Development and fabrication of membrane hollow fibers and modules from candidate polymers; ď?· Development of a CO{sub 2} capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and ď?· Techno-economic evaluation of the "best" integrated CO{sub 2} capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO{sub 2} capture with 95% captured CO{sub 2} purity.

Lora Toy; Atish Kataria; Raghubir Gupta

2011-09-30T23:59:59.000Z

128

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

129

Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion Project. Quarterly report, April--June 1996  

SciTech Connect (OSTI)

The objective of this project is to evaluate hot gas particle control technologies using coal-derived as streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed Include the integration of the particulate control devices into coal utilization systems, on-line cleaning, techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing, Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: 1 . Carbonizer/Pressurized Circulating, Fluidized Bed Gas Source; 2. Hot Gas Cleanup Units to mate to all gas streams; 3. Combustion Gas Turbine; 4. Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during, this reporting period was continuing, the detailed design of the FW portion of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is complete and the construction of steel for the coal preparation structure is complete.

NONE

1996-12-31T23:59:59.000Z

130

Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems  

DOE Patents [OSTI]

A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

1983-08-26T23:59:59.000Z

131

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

Not Available

1993-09-27T23:59:59.000Z

132

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 9, November 17, 1992--February 16, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically on electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). Progress is described for the ninth quarter.

Not Available

1993-10-01T23:59:59.000Z

133

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

134

Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system  

SciTech Connect (OSTI)

Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

1991-01-01T23:59:59.000Z

135

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2.3: Sulfur Primer  

SciTech Connect (OSTI)

This deliverable is Subtask 2.3 of Task 2, Gas Cleanup Design and Cost Estimates, of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 2.3 builds upon the sulfur removal information first presented in Subtask 2.1, Gas Cleanup Technologies for Biomass Gasification by adding additional information on the commercial applications, manufacturers, environmental footprint, and technical specifications for sulfur removal technologies. The data was obtained from Nexant's experience, input from GTI and other vendors, past and current facility data, and existing literature.

Nexant Inc.

2006-05-01T23:59:59.000Z

136

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

Kenneth E. Baldrey

2001-09-01T23:59:59.000Z

137

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, two cohesivity-specific additive formulations, ADA-44C and ADA-51, were evaluated in a full-scale trial at the American Electric Power Conesville plant. Ammonia conditioning was also evaluated for comparison. ADA-51 and ammonia conditioning significantly reduced rapping and non-rapped particulate re-entrainment based on stack opacity monitor data. Based on the successful tests to date, ADA-51 will be evaluated in a long-term test.

Kenneth E. Baldrey

2003-02-01T23:59:59.000Z

138

Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study  

SciTech Connect (OSTI)

It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

2012-05-03T23:59:59.000Z

139

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 7, May 1, 1992--August 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The features that distinguish the CZD process from other similar injection processes are: (1) Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. (2) Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. (3) Low residence time, made possible by the high effective surface area of the Type S lime. (4) Localized dispersion of the reagent. (5) Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash.

Not Available

1993-02-01T23:59:59.000Z

140

Development of a Calicum-Based Sorbent for Hot Gas Cleanup.  

SciTech Connect (OSTI)

Further review of the technical literature has provided additional information which will support the development of a superior calcium-based sorbent for hot gas cleanup in IGCC systems. Two general methods of sorbent preparation are being investigated. One method involves impregnating a porous refractory substrate with calcium while another method involves pelletizing lime or other calcium containing materials with a suitable binder. Several potential substrates, which are made of alumina and are commercially available, have been characterized by various methods. The surface area and apparent density of the materials have been measured, and it has been shown that some of the high surface area materials (i.e., 200-400 m{sub 2}/g) undergo a large decrease in surface area when heated to higher temperatures. Some of the lower surface area materials (i.e., 1-30 m{sub 2}/g) have been successfully impregnated with calcium by soaking them in a calcium nitrate solution and then heat treating them to decompose the nitrate. Potentially useful sorbents have also been prepared by pelletizing type I Portland cement and mixtures of cement and lime.

Wheelock, T.W.; Constant, K.; Doraiswamy, L.K.; Akiti, T.; Zhu, J.; Amanda, A.; Roe, R.

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc)  

E-Print Network [OSTI]

, stationary sources like coal-fired power plants, carbon capture and sequestration (CCS) has been proposed.4Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine- Appended Metal-Organic Framework viable absorbents for carbon capture under the aforementioned conditions, and they are presently used

142

Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, January 1--March 31, 1992  

SciTech Connect (OSTI)

This quarterly technical progress report summarizes work completed during the Sixth Quarter of the First Budget Period, January 1 through March 31, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. The major emphasis during this reporting period was expanding the test facility to address system integration issues of hot particulate removal in advanced power generation systems. The conceptual design of the facility was extended to include additional modules for the expansion of the test facility, which is referred to as the Power Systems Development Facility (PSOF). A letter agreement was negotiated between Southern Company Services (SCS) and Foster Wheeler (FW) for the conceptual design of the Advanced Pressurized Fluid-Bed Combustion (APFBC)/Topping Combustor/Gas Turbine System to be added to the facility. The expanded conceptual design also included modifications to the existing conceptual design for the Hot Gas Cleanup Test Facility (HGCTF), facility layout and balance of plant design for the PSOF. Southern Research Institute (SRI) began investigating the sampling requirements for the expanded facility and assisted SCS in contacting Particulate Control Device (PCD) vendors for additional information. SCS also contacted the Electric Power Research Institute (EPRI) and two molten carbonate fuel cell vendors for input on the fuel cell module for the PSDF.

Not Available

1992-12-01T23:59:59.000Z

143

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

144

Flue gas desulfurization sludge: establishment of vegetation on ponded and soil-applied waste. Final report January 1977-September 1981  

SciTech Connect (OSTI)

The report gives results of research to identify and evaluate forms of vegetation and methods of their establishment for reclaiming retired flue gas desulfurization sludge ponds. Also studied were the soil liming value of limestone scrubber sludge (LSS) and plant uptake and percolation losses of some chemical nutrients in the sludge. Several vegetation schemes were evaluated between 1977 and 1982 for covering and stabilizing LSS at Colbert Steam Plant, Cherokee, AL, and Shawnee Steam Plant, Paducah, KY. Eleven tree and 10 grass or legume species were tested for adaptability and survival when planted directly in LSS or in LSS amended with soil, municipal sewage sludge, or standard potting mix. Other studies indicated that LSS apparently has sufficient unreacted limestone to be a satisfactory soil liming agent.

Giordano, P.M.; Mays, D.A.; Soileau, J.M.

1984-01-01T23:59:59.000Z

145

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

C. Jean Bustard

2003-12-01T23:59:59.000Z

146

Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants  

SciTech Connect (OSTI)

This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

2003-12-31T23:59:59.000Z

147

Fundamental mechanisms in flue-gas conditioning. Topical report No. 1, Literature review and assembly of theories on the interactions of ash and FGD sorbents  

SciTech Connect (OSTI)

The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

1992-01-09T23:59:59.000Z

148

Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator  

SciTech Connect (OSTI)

This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

2006-07-01T23:59:59.000Z

149

Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I  

SciTech Connect (OSTI)

This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

1981-09-01T23:59:59.000Z

150

Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997  

SciTech Connect (OSTI)

This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

Chugh, Y.P.; Brackebusch, F.; Carpenter, J. [and others

1998-12-31T23:59:59.000Z

151

DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION  

SciTech Connect (OSTI)

For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

Panagiotis G. Smirniotis

2005-01-30T23:59:59.000Z

152

Flue Gas Purification Utilizing SOx/NOx Reactions During Compression of CO{sub 2} Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO{sub 2} stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO{sub 2} derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Fogash, Kevin

2010-09-30T23:59:59.000Z

153

Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion  

SciTech Connect (OSTI)

The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

Kevin Fogash

2010-09-30T23:59:59.000Z

154

Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas  

DOE Patents [OSTI]

The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

2014-10-07T23:59:59.000Z

155

Effect of connate water on miscible displacement of reservoir oil by flue gas  

E-Print Network [OSTI]

gas and water injection, have allowed the industry to greatly increase primary oil recovery. But the common weakness of gas and water as pressure maintenance and secondary recovery agents is im- miscibility with the reservoir fluid to be displaced... to using a hydrocarbon slug, Saxon, et al was one of the earliest investigators of carbon dioxide as a possible flooding 14 agent. Gatlin and Slobod reported on laboratory investigations of another possible miscible flooding agent, methyl alcohol. Each...

Maxwell, H. D.

1960-01-01T23:59:59.000Z

156

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

157

Improved heat recovery and high-temperature clean-up for coal-gas fired combustion turbines  

SciTech Connect (OSTI)

This study investigates the performance of an Improved Heat Recovery Method (IHRM) applied to a coal-gas fired power-generating system using a high-temperature clean-up. This heat recovery process has been described by Higdon and Lynn (1990). The IHRM is an integrated heat-recovery network that significantly increases the thermal efficiency of a gas turbine in the generation of electric power. Its main feature is to recover both low- and high-temperature heat reclaimed from various gas streams by means of evaporating heated water into combustion air in an air saturation unit. This unit is a packed column where compressed air flows countercurrently to the heated water prior to being sent to the combustor, where it is mixed with coal-gas and burned. The high water content of the air stream thus obtained reduces the amount of excess air required to control the firing temperature of the combustor, which in turn lowers the total work of compression and results in a high thermal efficiency. Three designs of the IHRM were developed to accommodate three different gasifying process. The performances of those designs were evaluated and compared using computer simulations. The efficiencies obtained with the IHRM are substantially higher those yielded by other heat-recovery technologies using the same gasifying processes. The study also revealed that the IHRM compares advantageously to most advanced power-generation technologies currently available or tested commercially. 13 refs., 34 figs., 10 tabs.

Barthelemy, N.M.; Lynn, S.

1991-07-01T23:59:59.000Z

158

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

1997-01-01T23:59:59.000Z

159

Separation of particulate from flue gas of fossil fuel combustion and gasification  

DOE Patents [OSTI]

The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

Yang, W.C.; Newby, R.A.; Lippert, T.E.

1997-08-05T23:59:59.000Z

160

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993  

SciTech Connect (OSTI)

There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

Sublette, K.L.

1993-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Preliminary evaluation of a concept using microwave energy to improve an adsorption-based, natural gas clean-up process  

SciTech Connect (OSTI)

This report describes the results of a preliminary evaluation performed to: (1) determine if microwave energy could be used to regenerate a zeolite adsorbent and (2) to evaluate the feasibility of using microwave energy to improve the desorption phase of a pressure swing adsorption process applied to upgrading natural gas (methane) contaminated with nitrogen. Microwave regeneration was evaluated by comparing the adsorption characteristics of a zeolite preconditioned by heating under vacuum to the characteristics of the same zeolite after various lengths of exposure to microwave energy. The applicability of microwave regeneration to natural gas cleanup was evaluated by measuring the rise in adsorbent temperature resulting from the microwave exposure. Microwave energy consumed by heating the adsorbent is not productive and must therefore be minimal for a process to be economically viable. Exposure of the methane-saturated chabazite for 2 minutes to microwave energy effectively regenerated the adsorbent, but resulted in a 75{degrees}F (42{degrees}C) rise in adsorbent temperature. This temperature rise indicates that the concept is unacceptable for natural gas processing due to excessive energy consumption.

Grimes, R.W.

1992-12-01T23:59:59.000Z

162

Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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163

Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes  

SciTech Connect (OSTI)

This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

1982-01-01T23:59:59.000Z

164

Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report  

SciTech Connect (OSTI)

The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

165

Flue gas conditioning for improved particle collection in electrostatic precipitators. Quarterly technical report, October 1--December 31, 1993  

SciTech Connect (OSTI)

The initial pilot-scale testing of two additives was completed at CONSOL`s research coal combustor. The results and conclusions from this test series and subsequent analysis of the data are presented in this report. Table 1 summarizes the conditions tested. During the tests, the research combustor was firing a medium-sulfur coal. The combustor had recently been retrofitted with low-NOx burners for a DOE Clean Coal test program. Operation of the low-NOx burners required a reduced flow rate in the combustor, resulting in lower flow and velocity in the ESP. A comprehensive baseline condition was tested, followed by initial screening runs for several additives. It was discovered that the flyash exhibited properties characteristic of a high-resistivity ash. In-situ measurements at the ESP inlet confirmed that the resistivity was in the 10{sup 10} -- 10{sup 12} ohm-cm range. In addition, the ESP plate rappers were not able to remove ash buildup on the first section during normal operation. Power off rapping was periodically required to fully clean the plates; this is a clear indication of high-resistivity conditions. Since the major benefit of ESP additives will be to reduce reentrainment at low to midrange resistivity, this operating condition was undesirable for performance testing. It was decided to continue the program with SO{sub 3} conditioning of the flue gas to reduce particle resistivity. It was also decided to operate with two rather than three electrical fields energized. By reducing the ESP collection area, it was hoped that it would be easier to measure changes in ESP performance and to see an immediate indication of the effectiveness Of SO{sub 3} conditioning. The ESP was reconfigured with two electrical sections energized and SO{sub 3} conditioning at a rate of approximately 20 ppM. An additional baseline was run, followed by extended tests with two additives referred to in this report as Additive ``C`` and Additive ``D.``

Durham, M.D.; Baldrey, K.E.

1994-01-12T23:59:59.000Z

166

Gas stream clean-up filter and method for forming same  

DOE Patents [OSTI]

A gas cleaning filter is formed in-situ within a vessel containing a fluidizable bed of granular material of a relatively large size fraction. A filter membrane provided by a porous metal or ceramic body or such a body supported a perforated screen on one side thereof is coated in-situ with a layer of the granular material from the fluidized bed by serially passing a bed-fluidizing gas stream through the bed of granular material and the membrane. The layer of granular material provides the filtering medium for the combined membrane-granular layer filter. The filter is not blinded by the granular material and provides for the removal of virtually all of the particulates from a process gas stream. The granular material can be at least partially provided by a material capable of chemically reacting with and removing sulfur compounds from the process gas stream. Low level radioactive waste containing organic material may be incinerated in a fluidized bed in communication with the described filter for removing particulates from the gaseous combustion products.

Mei, Joseph S. (Morgantown, WV); DeVault, James (Fairmont, WV); Halow, John S. (Waynesburg, PA)

1993-01-01T23:59:59.000Z

167

Development of novel copper-based sorbents for hot-gas cleanup. Technical report, March 1, 1992--May 31, 1992  

SciTech Connect (OSTI)

The objective of this investigation is to evaluate several novel copper-based binary oxides for their suitability as regenerable sorbents for hot gas cleanup application in the temperature range of 650{degrees} to 850{degrees}C. During this quarter cyclic sulfidation/regeneration tests of the sorbents Cu{sub 2}Cr-O and Cu-Ce-0 were conducted using different compositions of the feed gases to investigate the effects of H{sub 2}0, H{sub 2} and CO. These tests were conducted in a packed-bed microreactor at 850{degrees}C. The results of these tests showed that H{sub 2} and CO (along with C02) had a significant effect on the H{sub 2}S pre-breakthrough levels, whereas H{sub 2}0 did not have an effect. The physical properties of the fresh and reacted samples of the Cu-2Cr-O and Cu-Ce-0 sorbents prepared in this program and used in the cyclic sulfidation/regeneration tests were also measured. In addition, sulfidation/regeneration tests were conducted using two commercial copper chromite sorbents (G-13 and G-89, United Catalyst, Inc.) and a zinc titanate sorbent (L-3014) in a one-inch fluidized-bed reactor at 650{degrees}C. The G-13 sorbent appears to have a much higher sulfur capacity than the G-89 sorbent.

Abbasian, J.; Hill, A.H.; Wangerow, J.R. [Institute of Gas Technology, Chicago, IL (United States); Flytzani-Stephanopoulos, M.; Bo, L.; Patel, C. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

1992-10-01T23:59:59.000Z

168

Initial test results from the Department of Energy`s pressurized fluidized bed combustion Hot Gas Cleanup Program  

SciTech Connect (OSTI)

In August 1989 a cooperative agreement was signed between Ohio Power Company, through its agent the American Electric Power Service Corporation, and the United States Department of Energy to assess the readiness and economic viability of high-temperature and high-pressure (HTHP) particulate filter systems for pressurized fluidized bed combustion (PFBC) applications. In this agreement, known as the PFBC Hot Gas Cleanup (HGCU) Program, two HTHP particulate filtration systems are to be tested with one seventh of the flow from the Tidd 70-MWe PFBC Clean Coal Demonstration Plant. This paper describes the initial results from the first PFBC HGCU test and an additional proof-of-concept, pilot-scale test used to validate a ceramic candle filter element, which may be used in the second test of the PFBC HGCU Program. The first test consisted of a three-cluster filter system, incorporating 384, 1.5-meter long silicon carbide candle filters. This system utilized a one-seventh flow slipstream, approximately 7360 actual cubic feet per minute, from the Tidd 70-MWe PFBC. The proof-of-concept test is being used to qualify mullite candle filters as a potential candidate for the second test at the Tidd 70-MWe PFBC. Both filter systems were designed and fabricated by the Westinghouse Science and Technology Center.

Dennis, R.A. [USDOE Morgantown Energy Technology Center, WV (United States); Lippert, T.E.; Bruck, G.J.; Alvin, M.A. [Westinghouse Electric Corp., Pittsburgh, PA (United States). Science and Technology Center; Mudd, M.J. [Ohio Power Co., Columbus, OH (United States)]|[American Electric Power Service Corp., Columbus, OH (United States)

1993-06-01T23:59:59.000Z

169

Rapid pressure swing absorption cleanup of post-shift reactor synthesis gas  

SciTech Connect (OSTI)

This investigation is concerned with the separation of gas mixtures using a novel concept of rapid pressure swing absorption (RAPSAB) of gas in a stationary absorbent liquid through gas-liquid interfaces immobilized in the pore mouths of hydrophobic microporous membranes. The process is implemented in a module well-packed with hydrophobic microporous hollow fiber membranes. Before we proceed to RAPSAB studies with reactive absorbents, it is necessary to make an effort to compare experimental results with those predicted by the models. The only model developed so far involved a type of RAPSAB cycle (Mode 3) for which limited data were acquired earlier. A number of experiments have, therefore, been conducted in this mode to characterize the absorption part of the cycle. A new and more compact module (Module No. 5) was made using 840 fibers and a teflon casing inside the stainless steel shell to exactly define the fiber packing density. This allows an exact calculation of Happel's free surface radius. Experiments were carried out using a CO[sub 2]-N[sub 2] mixture of around 10% CO[sub 2] and balanced N[sub 2] using both modules 4 and 5 over a wide range of absorption times.

Sirkar, K.K.; Majumdar, S.; Bhaumik, S.

1992-09-24T23:59:59.000Z

170

Renewable Natural Gas Clean-up Challenges and Applications | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartmentnews-flashesEnergy by Brian Weeks, Gas Technology

171

Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +  

E-Print Network [OSTI]

pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system scrubber (pH ~ 6) 60 - 70 7 Re-heater 350 - 400 8 SCR DeNOx 300 - 400 9 Active coke bed 100 - 150 Figure 10

Zevenhoven, Ron

172

The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification  

E-Print Network [OSTI]

for biomas-derived syngas. National Renewable EnergyM. Lesemann. RTI/Eastman warm syngas clean-up technology:v the composition of syngas from steam hydrogasification

Luo, Qian

2012-01-01T23:59:59.000Z

173

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

174

Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion  

SciTech Connect (OSTI)

In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

Panagiotis G. Smirniotis

2007-06-30T23:59:59.000Z

175

Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture  

SciTech Connect (OSTI)

An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

2012-04-24T23:59:59.000Z

176

Paducah Cleanup Milestones  

Broader source: Energy.gov [DOE]

The Paducah Site Management Plan sets forth enforceable milestones for cleanup activities. These activities include a series of prioritized cleanup actions, ongoing analysis to support future cleanup decisions, and eventual D&D of the gaseous diffusion plant.

177

FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

2004-01-29T23:59:59.000Z

178

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993  

SciTech Connect (OSTI)

This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

Sublette, K.L.

1993-12-31T23:59:59.000Z

179

Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction  

SciTech Connect (OSTI)

Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

2009-01-15T23:59:59.000Z

180

High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines - Phase I: Laboratory investigations. Quarterly report, October 1993--December 1993  

SciTech Connect (OSTI)

This project proposes to use pneumatically or hydraulically emplaced dry-flue gas desulfurization (FGD) by-products to backfill the adits left by highwall mining. Backfilling highwall mine adits with dry-FGD materials is technically attractive. The use of an active highwall mine would allow the dry-FGD material to be brought in using the same transportation network used to move the coal out, eliminating the need to recreated the transportation infrastructure, thereby saving costs. Activities during the period included the negotiations leading to the final cooperative agreement for the project and the implementation of the necessary instruments at the University of Kentucky to administer the project. Early in the negotiations, a final agreement on a task structure was reached and a milestone plan was filed. A review was initiated of the original laboratory plan as presented in the proposal, and tentative modifications were developed. Selection of a mine site was made early; the Pleasant Valley mine in Greenup County was chosen. Several visits were made to the mine site to begin work on the hydrologic monitoring plan. The investigation of the types of permits needed to conduct the project was initiated. Considerations concerning the acceptance and implementation of technologies led to the choice of circulating fluidized bed ash as the primary material for the study. Finally, the membership of a Technical Advisory Committee for the study was assembled.

Not Available

1994-03-01T23:59:59.000Z

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181

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 1: Cost Estimates of Small Modular Systems  

SciTech Connect (OSTI)

This deliverable is the Final Report for Task 1, Cost Estimates of Small Modular Systems, as part of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 1.1 looked into processes and technologies that have been commercially built at both large and small scales, with three technologies, Fluidized Catalytic Cracking (FCC) of refinery gas oil, Steam Methane Reforming (SMR) of Natural Gas, and Natural Gas Liquids (NGL) Expanders, chosen for further investigation. These technologies were chosen due to their applicability relative to other technologies being considered by NREL for future commercial applications, such as indirect gasification and fluidized bed tar cracking. Research in this subject is driven by an interest in the impact that scaling has on the cost and major process unit designs for commercial technologies. Conclusions from the evaluations performed could be applied to other technologies being considered for modular or skid-mounted applications.

Nexant Inc.

2006-05-01T23:59:59.000Z

182

DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development...  

Energy Savers [EERE]

of Energy (DOE), a demonstration-scale application of RTI International's warm synthesis gas (syngas) cleanup process technology has achieved a key operational milestone at Tampa...

183

Improved high efficiency third stage separator cyclones for separation of fines from fluid catalytic cracking flue gas  

SciTech Connect (OSTI)

Stairmand type small diameter (0.254 m) multicyclones were cold flow tested for fluid catalytic cracking third stage separator application. The gas discharge from the cyclone dust outlet into the common collection hopper was found to far exceed the hopper bleed rate (underflow). The excess gas reentrained dust from the hopper back into cyclones, which lowered collection efficiencies. Vortex {open_quotes}stabilization{close_quotes} using apex cones was unsuccessful whereas a Mobil proprietary cyclone modification was successful in minimizing excess gas discharge and dust reentrainment at the cyclone-hopper boundary. In tests at 700 {degrees}C, the modified cyclones captured all particles above 4 {mu}m. Mobil-Kellogg incorporated the modified cyclones in a new third stage separator design which is targeted for achieving lowest opacity and <50 mg/Nm{sup 3} emissions at the stack. The first such unit will be commercialized in Mobil`s newest catalytic cracker (M.W. Kellogg design) under construction in Altona, Australia in late 1996. 5 refs., 4 figs., 2 tabs.

Chitnis, G.K.; Schatz, K.W. [Mobil Technology Co., Paulsboro, NJ (United States); Bussey, B.K. [M.W. Kellogg Co., Houston, TX (United States)

1996-12-31T23:59:59.000Z

184

Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas  

SciTech Connect (OSTI)

This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

C. Jean Bustard; Charles Lindsey; Paul Brignac

2006-05-01T23:59:59.000Z

185

Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets  

E-Print Network [OSTI]

of a flue gas condenser with a steam boiler. ? Improvedsteam dryers by gas ? Dryers and filtration equipment ? Applied CHP ? Purchased flue gas condensers ?

Price, Lynn

2010-01-01T23:59:59.000Z

186

Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas  

DOE Patents [OSTI]

The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (Oakland, CA); Griffiths, Elizabeth A. (Neston, GB2); Littlejohn, David (Oakland, CA)

1988-01-01T23:59:59.000Z

187

Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use  

SciTech Connect (OSTI)

field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

2012-07-31T23:59:59.000Z

188

Simulation of fracture fluid cleanup and its effect on long-term recovery in tight gas reservoirs  

E-Print Network [OSTI]

technologies, such as large volume fracture treatments, are required before a reasonable profit can be made. Hydraulic fracturing is one of the best methods to stimulate a tight gas well. Most fracture treatments result in 3-6 fold increases in the productivity...

Wang, Yilin

2009-05-15T23:59:59.000Z

189

The effects of fracture fluid cleanup upon the analysis of pressure buildup tests in tight gas reservoirs  

E-Print Network [OSTI]

in the Mast A-1 are interpreted as being longitudinal- and transverse-bar deposits and channel ARCO OIL AND GAS ~ I PHILLIPS SMITH CO ? ? I I CLAYTON WILUAMS Ja ~ G I SAM IAIGHES I L HARRISON CO Z I GREGG CO. T' PANOLA CO. RUSK CO. SHELBY CO...

Johansen, Atle Thomas

1988-01-01T23:59:59.000Z

190

Separation of flue-gas scrubber sludge into marketable products. Second quarterly technical progress report, December 1, 1993--February 28, 1994 (Quarter No. 2)  

SciTech Connect (OSTI)

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. It consists of calcium sulfite (CaSO{sub 3}{lg_bullet}0.5H{sub 2}0), gypsum (CaSO{sub 4}{lg_bullet}2H{sub 2}0), and unreacted limestone (CaCO{sub 3}) or lime (Ca(OH){sub 2}), with miscellaneous objectionable impurities such as iron oxides; silica; and magnesium, sodium, and potassium oxides or salts. Currently, the only market for scrubber sludge is for manufacture of gypsum products, such as wallboard and plaster, and for cement. However, the quality of the raw sludge is often not high enough or consistent enough to satisfy manufacturers, and so the material is difficult to sell. This project is developing a process that can produce a high-quality calcium sulfite or gypsum product while keeping process costs low enough that the material produced will be competitive with that from other, more conventional sources. This purification will consist of minimal-reagent froth flotation, using the surface properties of the particles of unreacted limestone to remove them and their associated impurities from the material, leaving a purified gypsum or calcium sulfite product. The separated limestone will be a useful by-product, as it can be recycled to the scrubber, thus boosting the limestone utilization and improving process efficiency. Calcium sulfite will then be oxidized to gypsum, or separated as a salable product in its own right from sludges where it is present in sufficient quantity. The main product of the process will be either gypsum or calcium sulfite, depending on the characteristics of the sludge being processed. These products will be sufficiently pure to be easily marketed, rather that being landfilled.

Kawatra, S.K.; Eisele, T.C.

1994-03-01T23:59:59.000Z

191

PFB coal fired combined cycle development program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation  

SciTech Connect (OSTI)

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. This finding suggests that large cyclones with natural or augmented electrostatic forces employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. This is of special importance since the use of many small cyclones in parallel, or multicyclones, commonly suffers from fouling and this approach is not recommended in the CFCC application. The original objective of this investigation was to assess the relative merits of the Aerodyne cyclone separator. It was found from both the cold flow and the hot flow tests that its separative efficiencies are disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones.

Not Available

1980-11-01T23:59:59.000Z

192

PFB Coal Fired Combined Cycle Development Program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume A. Aerodyne cyclone evaluation  

SciTech Connect (OSTI)

This report summarizes the results of testing of a rotary flow cyclone, manufactured by Aerodyne Development Corporation under license by Siemens Kraftwerk Union. This cyclone was selected for evaluation due to the unusually high separative efficiencies claimed by the manufacturer (based on developer data), and relative lack of open literature data. The most significant finding of this work was the observation that electrostatic forces could enhance or, in fact, dominate the separation process. Separative efficiencies, with electrostatic forces present, were found to be substantially independent of flow rate and, by inference, could be independent of unit size. Hence this finding offers a major hope that large cyclones employed in the hot gas cleanup train of the CFCC system may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. The separative efficiencies of the Aerodyne cyclone separator were found from both the cold flow and the hot flow tests to be disappointingly poorer than expectations (in agreement with Westinghouse results), and even poorer than conventional cyclones. (LTN)

Not Available

1980-02-01T23:59:59.000Z

193

Factors that affect fracture fluid clean-up and pressure buildup test results in tight gas reservoirs  

E-Print Network [OSTI]

engineering effort with a complete formation evaluation prior to the stimulation treatment can one understand a well containing a vertical hydraulic fracture. If the reservoir produces substantial volumes of either fracture fluid or formation water, along... and Water Permeability . . . 21 Fracture Relative Gas and Water Permeability . . . . . . 24 Created and Propped Fracture Lengths as a Function of Treatment Volume Based on FRACDIM ZI One Quarter of a Square Pattern with Wellbore Centered in Middle...

Montgomery, Kevin Todd

1990-01-01T23:59:59.000Z

194

Development of hollow fiber catalytic membrane reactors for high temperature gas cleanup. Final report, September 1989--March 1994  

SciTech Connect (OSTI)

The objective of this project was to develop economically and technically viable catalytic membrane reactors for high temperature, high pressure gaseous contaminant control in Integrated Gasification Combined Cycle (IGCC) systems. These catalytic membrane reactors decompose H{sub 2}S and separate the reaction products. The reactors were designed to operate in the hostile process environment of the IGCC systems, and at temperatures ranging from 500 to 1000{degrees}C. Severe conditions encountered in the IGCC process (e.g., 900{degrees}C, containing of H{sub 2}S, CO{sub 2} and H{sub 2}O) make it impossible to use polymeric membranes in the process. A list of inorganic membranes that can be employed in the membrane reactor includes Pd metallic membranes, molecular-sieve glass membranes (PPG Industries), porous Vycor glass membranes and porous sol-gel derived membranes such as alumina, zirconia. Alumina and zirconia membranes, however, cannot withstand for a long time at high temperatures in the presence of water vapors. Palladium membranes are a very promising class of inorganic membranes for gas separations that is currently under development. In this project two different types of membranes were used in the design of the membrane reactor -- molecular-sieve glass membrane and Vycor glass porous membrane.

Ma, Yi Hua; Moser, W.R.; Pien, S.; Shelekhin, A.B.

1994-07-01T23:59:59.000Z

195

Process for removing sulfur dioxide from flue gases  

SciTech Connect (OSTI)

This patent describes an improvement in a dry process for the removal of sulfur dioxide from flue gases by the addition thereto of hydrated lime containing sugar in a coal combustion unit, wherein the flue gases result from the combustion of a coal in a combustion chamber, and the flue gases are treated in an electrostatic precipitator prior to discharge to the atmosphere the improvement comprising: passing the flue gases, after the addition of the hydrated lime is of fine particles of a specific surface of 7 to 25 square meters per gram, through a conduit towards the electrostatic precipitator; and adding an aqueous media to the flue gases in the conduit in an amount to increase the water content of the flue gases and cool the same by evaporative cooling to a temperature no lower than 20{sup 0}F. about the dew point of the gas, so as to avoid forming water droplets in the gas, so as to prevent condensation of water therefrom.

Robinson, M.W. Jr.

1989-08-29T23:59:59.000Z

196

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Final report  

SciTech Connect (OSTI)

The main objective of this research was to investigate microorganisms capable of fossil fuel flue gas desulfurization and denitrification. The study used municipal sewage sludge as a carbon and energy source for SO{sub 2}-reducing cultures. The individual tasks developed a consortium of sulfate-reducing bacteria, investigated the design parameters for a continuous process, preformed a cost analysis, and screened sulfate-reducing bacteria. In the investigation of microbial reduction of NO{sub x} to nitrogen, tasks included screening denitrifying bacteria for NO and NO{sub 2} activity, developing optimum NO-reducing cultures, and investigating design parameters for a continuous system. This final report reviews the work previous to the current project, describes project objectives and the specific work plan, and reports results from the work completed during the previous reporting periods.

Sublette, K.L.

1994-03-01T23:59:59.000Z

197

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents [OSTI]

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

198

Idaho Cleanup Project Congressional Nuclear Cleanup Caucus  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4InFindingIR-2003-TransmissionDepartmentIanCleanup

199

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

2003-01-01T23:59:59.000Z

200

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

2006-05-02T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Reactor water cleanup system  

DOE Patents [OSTI]

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

Gluntz, D.M.; Taft, W.E.

1994-12-20T23:59:59.000Z

202

Reactor water cleanup system  

DOE Patents [OSTI]

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

Gluntz, Douglas M. (San Jose, CA); Taft, William E. (Los Gatos, CA)

1994-01-01T23:59:59.000Z

203

Debate over waste imperils 3-Mile cleanup  

SciTech Connect (OSTI)

The cleanup is a task of extraordinary proportions. Every step in the cleanup must be taken in a highly sensitive political and regulatory environment. A demineralizer or ion exchange filtration unit was installed in order that the fission products could be removed from the water spilled in the auxiliary and fuel handling buildings. GPU later vented krypton gas. Twice now engineers have made cautions entries into the containment building as part of the effort to size up the job. Cleanup will be costly, requiring many workers. Some wastes will require special packaging in hundreds of containers with shielded overpacks, plus bulky items of hardware and equipment that cannot be easily packaged. There will be the damaged fuel assemblies from the reactor core. Removing the fuel from the reactor may be difficult. A troublesome waste disposal question has to do with the material to be generated in cleaning up the containment building's sump water. GPU's man in charge of clean-up strategy is to collect the wastes in a form that permits maximum flexibility with respect to their stage, packaging, transport, and ultimate disposal. If plans for disposal of all the wastes from the cleanup are to be completed, an early commitment by Pennsylvania and other northeastern states to establish a burial ground for low level waste generated within the region is needed. Also a speedy commitment by NRC, DOE, and Congress to a plan for disposal of the first-stage zeolites is needed. Should there be a failure to cope with the wastes that Three Mile Island cleanup generates, the whole nuclear enterprise may suffer.

Carter, L.J.

1980-10-10T23:59:59.000Z

204

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992  

SciTech Connect (OSTI)

With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

Sublette, K.L.

1992-12-31T23:59:59.000Z

205

New Contract Helps Portsmouth GDP Cleanup  

Broader source: Energy.gov [DOE]

To accelerate the Portsmouth GDP cleanup efforts left over from the Cold War, the Department of Energy made a huge step forward in our nuclear environmental cleanup efforts.

206

Superfund Cleanups and Infant Health  

E-Print Network [OSTI]

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989 and 2003 ...

Currie, Janet

2011-02-23T23:59:59.000Z

207

Environmental Management (EM) Cleanup Projects  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The guide supports DOE O 413.3A, Program and Project Management for the Acquisition of Capital Assets, and provides guidance on environmental management cleanup projects. Canceled by DOE N 251.105.

2008-09-24T23:59:59.000Z

208

Cleanup Sites | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehiclesTankless orAChief Medical Officerof EnergyCleanup Sites Cleanup

209

Natural gas cleanup: Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures  

SciTech Connect (OSTI)

This report describes the results of a preliminary evaluation to determine the technical feasibility of using a molecular sieve carbon manufactured by the Takeda Chemical Company of Japan in a pressure owing adsorption cycle for upgrading natural gas (methane) contaminated with nitrogen. Adsorption tests were conducted using this adsorbent in two, four, and five-step adsorption cycles. Separation performance was evaluated in terms of product purity, product recovery, and sorbent productivity for all tests. The tests were conducted in a small, single-column adsorption apparatus that held 120 grams of the adsorbent. Test variables included adsorption pressure, pressurization rate, purge rate and volume, feed rate, and flow direction in the steps from which the product was collected. Sorbent regeneration was accomplished by purging the column with the feed gas mixture for all but one test series where a pure methane purge was used. The ratio between the volumes of the pressurization gas and the purge gas streams was found to be an important factor in determining separation performance. Flow rates in the various cycle steps had no significant effect. Countercurrent flow in the blow-down and purge steps improved separation performance. Separation performance appears to improve with increasing adsorption pressure, but because there are a number of interrelated variables that are also effected by pressure, further testing will be needed to verify this. The work demonstrates that a molecular sieve carbon can be used to separate a mixture of methane and nitrogen when used in a pressure swing cycle with regeneration by purge. Further work is needed to increase product purity and product recovery.

Grimes, R.W.

1994-06-01T23:59:59.000Z

210

Rapid pressure swing absorption cleanup of post-shift reactor synthesis gas. Technical progress report, April 1, 1992--July 31, 1992  

SciTech Connect (OSTI)

This investigation is concerned with the separation of gas mixtures using a novel concept of rapid pressure swing absorption (RAPSAB) of gas in a stationary absorbent liquid through gas-liquid interfaces immobilized in the pore mouths of hydrophobic microporous membranes. The process is implemented in a module well-packed with hydrophobic microporous hollow fiber membranes. Before we proceed to RAPSAB studies with reactive absorbents, it is necessary to make an effort to compare experimental results with those predicted by the models. The only model developed so far involved a type of RAPSAB cycle (Mode 3) for which limited data were acquired earlier. A number of experiments have, therefore, been conducted in this mode to characterize the absorption part of the cycle. A new and more compact module (Module No. 5) was made using 840 fibers and a teflon casing inside the stainless steel shell to exactly define the fiber packing density. This allows an exact calculation of Happel`s free surface radius. Experiments were carried out using a CO{sub 2}-N{sub 2} mixture of around 10% CO{sub 2} and balanced N{sub 2} using both modules 4 and 5 over a wide range of absorption times.

Sirkar, K.K.; Majumdar, S.; Bhaumik, S.

1992-09-24T23:59:59.000Z

211

Flue gas desulfurization gypsum and fly ash  

SciTech Connect (OSTI)

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

Not Available

1992-05-01T23:59:59.000Z

212

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO[sub 2] and NO[sub x] Reduction - Preliminary confirmation of 50% SO[sub 2] reduction has been achieved, but the NO[sub x] reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO[sub 2] reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO[sub 2] Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel's original cost estimates (capital and operating) were prepared. Therefore, SO[sub 2] removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

213

Accelerating cleanup: Paths to closure  

SciTech Connect (OSTI)

This report describes the status of Environmental Management`s (EM`s) cleanup program and a direction forward to complete achievement of the 2006 vision. Achieving the 2006 vision results in significant benefits related to accomplishing EM program objectives. As DOE sites accelerate cleanup activities, risks to public health, the environment, and worker safety and health are all reduced. Finding more efficient ways to conduct work can result in making compliance with applicable environmental requirements easier to achieve. Finally, as cleanup activities at sites are completed, the EM program can focus attention and resources on the small number of sites with more complex cleanup challenges. Chapter 1 describes the process by which this report has been developed and what it hopes to accomplish, its relationship to the EM decision-making process, and a general background of the EM mission and program. Chapter 2 describes how the site-by-site projections were constructed, and summarizes, for each of DOE`s 11 Operations/Field Offices, the projected costs and schedules for completing the cleanup mission. Chapter 3 presents summaries of the detailed cleanup projections from three of the 11 Operations/Field Offices: Rocky Flats (Colorado), Richland (Washington), and Savannah River (South Carolina). The remaining eight Operations/Field Office summaries are in Appendix E. Chapter 4 reviews the cost drivers, budgetary constraints, and performance enhancements underlying the detailed analysis of the 353 projects that comprise EM`s accelerated cleanup and closure effort. Chapter 5 describes a management system to support the EM program. Chapter 6 provides responses to the general comments received on the February draft of this document.

NONE

1998-06-01T23:59:59.000Z

214

Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned...  

Energy Savers [EERE]

Soil and Groundwater Cleanup - In-Situ Grouting, Lessons Learned (Post CD-4), Environmental Management Cleanup, May 2011 Soil and Groundwater Cleanup - In-Situ Grouting, Lessons...

215

DOE outlines complex cleanup options  

SciTech Connect (OSTI)

The Energy Department said last week it will consider four different strategies for cleanup of its nuclear weapons complex in a draft programmatic environmental impact statement due for release this summer. In an implementation plan released for public comment February 17, DOE also said the EIS would look at centralized, decentralized and regional approaches to management of six types of radioactive and hazardous wastes. Other issues to be addressed in the EIS are development of innovative cleanup technology, budgeting and prioritization, job cutbacks and worker retraining, waste minimization and community involvement in cleanup decisions. However, DOE said it had decided not to address spent nuclear fuel storage in the EIS, as had been previously planned. Instead, spent fuel storage options will be reviewed in another environmental study being done under court order for DOE's Idaho National Engineering Laboratory. Findings from the INEL study will be incorporated in the department-wide EIS for environmental restoration and waste management.

Lobsenz, G.

1994-02-25T23:59:59.000Z

216

A mathematical model for the estimation of flue temperature in a coke oven  

SciTech Connect (OSTI)

The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

1997-12-31T23:59:59.000Z

217

Richland Operations Office Cleanup Strategy, Scope  

Energy Savers [EERE]

Cleanup Work * Deactivate and Demolish facilities * Move buried waste, contaminated soil away from Columbia River * Treat contaminated groundwater * Isolate contamination...

218

Superfund Cleanups and Infant Health  

E-Print Network [OSTI]

We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989-2003 in ...

Currie, Janet

219

Environmental Cleanup and Remediation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area. TheEPSCI Home It isGas Environmental Management

220

The Morgantown Energy Technology Center`s particulate cleanup program  

SciTech Connect (OSTI)

The development of integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC) power systems has made it possible to use coal while still protecting the environment. Such power systems significantly reduce the pollutants associated with coal-fired plants built before the 1970s. This superior environmental performance and related high system efficiency is possible, in part, because particulate gas-stream cleanup is conducted at high-temperature and high-pressure process conditions. A main objective of the Particulate Cleanup Program at the Morgantown Energy Technology Center (METC) is to ensure the success of the CCT demonstration projects. METC`s Particulate Cleanup Program supports research, development, and demonstration in three areas: (1) filter-system development, (2) barrier-filter component development, and (3) ash and char characterization. The support is through contracted research, cooperative agreements, Cooperative Research And Development Agreements (CRADAs), and METC`s own in-house research. This paper describes METC`s Particulate Cleanup Program.

Dennis, R.A.

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

HANFORD SITE CENTRAL PLATEAU CLEANUP COMPLETION STRATEGY  

SciTech Connect (OSTI)

Cleanup of the Hanford Site is a complex and challenging undertaking. The U.S. Department of Energy (DOE) has developed a comprehensive vision for completing Hanford's cleanup mission including transition to post-cleanup activities. This vision includes 3 principle components of cleanup: the {approx}200 square miles ofland adjacent to the Columbia River, known as the River Corridor; the 75 square miles of land in the center of the Hanford Site, where the majority of the reprocessing and waste management activities have occurred, known as the Central Plateau; and the stored reprocessing wastes in the Central Plateau, the Tank Wastes. Cleanup of the River Corridor is well underway and is progressing towards completion of most cleanup actions by 2015. Tank waste cleanup is progressing on a longer schedule due to the complexity of the mission, with construction of the largest nuclear construction project in the United States, the Waste Treatment Plant, over 50% complete. With the progress on the River Corridor and Tank Waste, it is time to place increased emphasis on moving forward with cleanup of the Central Plateau. Cleanup of the Hanford Site has been proceeding under a framework defmed in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In early 2009, the DOE, the State of Washington Department of Ecology, and the U.S. Environmental Protection Agency signed an Agreement in Principle in which the parties recognized the need to develop a more comprehensive strategy for cleanup of the Central Plateau. DOE agreed to develop a Central Plateau Cleanup Completion Strategy as a starting point for discussions. This DOE Strategy was the basis for negotiations between the Parties, discussions with the State of Oregon, the Hanford Advisory Board, and other Stakeholder groups (including open public meetings), and consultation with the Tribal Nations. The change packages to incorporate the Central Plateau Cleanup Completion Strategy were signed by the Parties on October 26,2010, and are now in the process of being implemented.

BERGMAN TB

2011-01-14T23:59:59.000Z

222

German engineers study UMTRA cleanup programs  

SciTech Connect (OSTI)

Two environmental engineers from Germany's WISMUT, the organization responsible for uranium tailings cleanup in that country, recently completed extensive training as part of a technology transfer program at the US DOE. For six weeks the two engineers studied the practices employed in the cleanup of the DOE's UMTRA (Uranium Mill Tailings Remedial Action) sites, hoping to gain insight into how Germany's own cleanup program should proceed.

Not Available

1994-01-01T23:59:59.000Z

223

Lab completes record year for environmental cleanup  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Buckman Direct Diversion Board to monitor, sample, and protect the community's future water supply. Cleanup of legacy waste at Los Alamos is a partnership between the Department...

224

Independent Oversight Assessment, Idaho Cleanup Project Sodium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Bearing Waste Treatment Project - November 2012 November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project This...

225

Site Cleanup | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas |DOE FormerEnergy Data Access SilverSiouxCleanup

226

Final report to US Department of Energy: Cyclotron autoresonance accelerator for electron beam dry scrubbing of flue gases  

SciTech Connect (OSTI)

Several designs have been built and operated of microwave cyclotron autoresonance accelerators (CARA's) with electron beam parameters suitable for remediation of pollutants in flue gas emissions from coal-burning power plants. CARA designs have also been developed with a TW-level 10.6 micron laser driver for electron acceleration from 50 to 100 MeV, and with UHF drivers for proton acceleration to over 500 MeV. Dose requirements for reducing SO2, NOx, and particulates in flue gas emissions to acceptable levels have been surveyed, and used to optimize the design of an electron beam source to deliver this dose.

Hirshfield, J.L.

2001-05-25T23:59:59.000Z

227

Development of EPA radiation site cleanup regulations  

SciTech Connect (OSTI)

This paper summarizes the EPA program to develop radiation site cleanup and identifies many of the issues related to that effort. The material is drawn from portions of the Agency`s Issues Paper on Radiation Site Cleanup Regulations (EPA 402-R-93-084). The site cleanup regulations will be designed to protect human health and the environment and to facilitate the cleanup of sites. EPA believes that developing specific cleanup standards for radionuclides will ensure consistent, protective, and cost-effective site remediation. They will apply to all Federal facilities such as those operated by the US Department of Energy (DOE), the US Department of Defense (DoD), and sites licensed by the US Nuclear Regulatory Commission (NRC) and its Agreement States.

Burnett, J.

1994-12-31T23:59:59.000Z

228

Exemplary Hurricane Damage Cleanup Earns Petroleum Reserve Coveted...  

Broader source: Energy.gov (indexed) [DOE]

Exemplary Hurricane Damage Cleanup Earns Petroleum Reserve Coveted Environmental Award Exemplary Hurricane Damage Cleanup Earns Petroleum Reserve Coveted Environmental Award April...

229

HANFORD SITE RIVER CORRIDOR CLEANUP  

SciTech Connect (OSTI)

In 2005, the US Department of Energy (DOE) launched the third generation of closure contracts, including the River Corridor Closure (RCC) Contract at Hanford. Over the past decade, significant progress has been made on cleaning up the river shore that bordes Hanford. However, the most important cleanup challenges lie ahead. In March 2005, DOE awarded the Hanford River Corridor Closure Contract to Washington Closure Hanford (WCH), a limited liability company owned by Washington Group International, Bechtel National and CH2M HILL. It is a single-purpose company whose goal is to safely and efficiently accelerate cleanup in the 544 km{sup 2} Hanford river corridor and reduce or eliminate future obligations to DOE for maintaining long-term stewardship over the site. The RCC Contract is a cost-plus-incentive-fee closure contract, which incentivizes the contractor to reduce cost and accelerate the schedule. At $1.9 billion and seven years, WCH has accelerated cleaning up Hanford's river corridor significantly compared to the $3.2 billion and 10 years originally estimated by the US Army Corps of Engineers. Predictable funding is one of the key features of the new contract, with funding set by contract at $183 million in fiscal year (FY) 2006 and peaking at $387 million in FY2012. Another feature of the contract allows for Washington Closure to perform up to 40% of the value of the contract and subcontract the balance. One of the major challenges in the next few years will be to identify and qualify sufficient subcontractors to meet the goal.

BAZZELL, K.D.

2006-02-01T23:59:59.000Z

230

Separation of carbon dioxide from flue emissions using Endex principles  

E-Print Network [OSTI]

In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

Ball, R

2009-01-01T23:59:59.000Z

231

Assessment of hot gas contaminant control  

SciTech Connect (OSTI)

The objective of this work is to gather data and information to assist DOE in responding to the NRC recommendation on hot gas cleanup by performing a comprehensive assessment of hot gas cleanup systems for advanced coal-based Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) including the status of development of the components of the hot gas cleanup systems, and the probable cost and performance impacts. The scope and time frame of information gathering is generally responsive to the boundaries set by the National Research council (NRC), but includes a broad range of interests and programs which cover hot gas cleanup through the year 2010. As the status of hot gas cleanup is continually changing, additional current data and information are being obtained for this effort from this 1996 METC Contractors` Review Meeting as well as from the 1996 Pittsburgh Coal Conference, and the University of Karlsruhe Symposium. The technical approach to completing this work consists of: (1) Determination of the status of hot gas cleanup technologies-- particulate collection systems, hot gas desulfurization systems, and trace contaminant removal systems; (2) Determination of hot gas cleanup systems cost and performance sensitivities. Analysis of conceptual IGCC and PFBC plant designs with hot gas cleanup have been performed. The impact of variations in hot gas cleanup technologies on cost and performance was evaluated using parametric analysis of the baseline plant designs and performance sensitivity.

Rutkowski, M.D.; Klett, M.G.; Zaharchuk, R.

1996-12-31T23:59:59.000Z

232

bectcom-roxbox | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Mar 1989) Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Program: SOx-NOx-Rox Box(tm) Flue Gas Cleanup Demonstration Project...

233

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

cost, followed by power island and gas cleanup. The totalgas from coal-fired power plants, gas turbine exhaust gas,Gas C1-C4 22.Ash Power 20.Flue gas Gas Turbine 23.Expanded

Lu, Xiaoming

2012-01-01T23:59:59.000Z

234

Money crunch looms for Federal cleanup effort  

SciTech Connect (OSTI)

In an unprecedented acknowledgement that federal facility cleanup activities face a money crunch, a federal-state advisory panel is preparing a new strategy to avert enforcement showdowns when funding cuts prevent federal agencies from meeting legally required cleanup schedules set by states. In a draft report the panel said states must recognize that some cleanup [open quotes]milestones[close quotes] will have to be delayed due to budget pressures - a concession that will be politically difficult in some states. At the same time, the panel said federal agencies must be more forthcoming in working with states and local groups to determine how increasingly scarce resources will be distributed. As a general rule, the report recommended that federal agencies and state environmental officials agree on a [open quotes]fair share[close quotes] allocation method under which the pain of a budget cutback would be spread equally among all cleanup sites within an affected federal agency. That fair share approach would be altered only if the federal agency reached agreement with states that a funding cutback could be absorbed at selected sites without affecting any cleanup milestone.

Lobsenz, G.

1992-12-03T23:59:59.000Z

235

Upton bill offers clean-up incentives  

SciTech Connect (OSTI)

Like castor oil, the Superfund law can be difficult medicine to swallow, and no one wants to volunteer for a dose. Indeed, the law`s harsh and unbending liability scheme sometimes hinders the cleanup of contaminated property. Confronted with the choice of redeveloping an old {open_quotes}brownfield{close_quotes} urban industrial site or building at a pristine new {open_quotes}greenfield{close_quotes} location, most companies opt for the latter. The brownfield problem is especially troubling because the law often prevents voluntary cleanups at relatively low priority sites that usually don`t get caught up in the Superfund program. This paper describes the Upton Bill which would require the US EPA to establish cleanup standards for hazrdous substances, allow for public comment on a proposed response plan, and require a voluntary party to submit detailed annual reports and maintain records.

Black, B. [Weinberg & Green, Baltimore, MD (United States)

1994-07-01T23:59:59.000Z

236

Issues paper on radiation site cleanup regulations  

SciTech Connect (OSTI)

EPA prepared the document to present issues, approaches, and preliminary analyses related to its development of radiation site cleanup regulations. It focuses exclusively on issues and approaches related to developing cleanup regulations; it does not address issues specific to waste management regulations, which will be addressed in a separate document. The first three chapters discuss Significant Issues, Regulatory Approaches, and Summary and Next Steps. Appendix A presents background information on radioactive waste and provides additional details of EPA coordination of its rulemaking effort. Appendix B discusses statutory authorities upon which EPA may base its cleanup regulations. Appendix C is a copy of the EPA/NRC MOU. Appendix D discusses the issues raised in NRC's Enhanced Participatory Rulemaking on Radiological Criteria for Decommissioning, in which EPA participated. Appendix E is a list of acronyms, and Appendix F is a glossary of terms used throughout the document.

Not Available

1993-09-01T23:59:59.000Z

237

GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

Nsakala ya Nsakala; Gregory N. Liljedahl

2003-05-15T23:59:59.000Z

238

Recovery Act funds advance cleanup efforts at Cold War site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cleanup efforts at Cold War site Recovery Act funds advance cleanup efforts at Cold War site A local small business, ARSEC Environmental, LLC, of White Rock, NM, won a 2 million...

239

Voluntary Protection Program Onsite Review, Idaho Cleanup Project- October 2010  

Broader source: Energy.gov [DOE]

Evaluation to determine whether Idaho Cleanup Project is continuing to perform at a level deserving DOE-VPP Star recognition.

240

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)  

SciTech Connect (OSTI)

The objective of this contract was to investigate the removal of SO[sub x] and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO[sub x] removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800[degrees] and 2500[degrees]F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

Quimby, J.M.; Kumar, K.S.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network [OSTI]

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

242

Natural Gas Utilities Options Analysis for the Hydrogen  

E-Print Network [OSTI]

Natural Gas Gas Hydrates Kent Perry Executive Director Exploration & Production Technology Distributed Hydrogen Fuel Processing Low-Temperature Fuel Cells High-Temperature Fuel Cells Vehicle Fuel Infrastructure Gerry Runte Executive Director Hydrogen Energy Systems Gasification & Hot Gas Cleanup Process

243

Reducing the cost of CO{sub 2} capture from flue gases using membrane technology  

SciTech Connect (OSTI)

Studies of CO{sub 2} capture using membrane technology from coal-fired power-plant flue gas typically assume compression of the feed to achieve a driving force across the membrane. The high CO{sub 2} capture cost of these systems reflects the need to compress the low-pressure feed gas (1 bar) and the low CO{sub 2} purity of the product stream. This article investigates how costs for CO{sub 2} capture using membranes can be reduced by operating under vacuum conditions. The flue gas is pressurized to 1.5 bar, whereas the permeate stream is at 0.08 bar. Under these operating conditions, the capture cost is U.S. $54/tonne CO{sub 2} avoided compared to U.S. $82/tonne CO{sub 2} avoided using membrane processes with a pressurized feed. This is a. reduction of 35%. The article also investigates the effect on the capture cost of improvements in CO{sub 2} permeability and selectivity. The results show that the capture cost can be reduced to less than U.S. $25/tonne CO{sub 2} avoided when the CO{sub 2} permeability is 300 bar, CO{sub 2}/N{sub 2} selectivity is 250, and the membrane cost is U.S. $10/m{sup 2}.

Ho, M.T.; Allinson, G.W.; Wiley, D.E. [University of New South Wales, Kensington, NSW (Australia)

2008-03-15T23:59:59.000Z

244

2014 House Nuclear Cleanup Caucus Oak Ridge  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3 Beryllium-Associated Worker2014 House Nuclear Cleanup Caucus Oak Ridge August 16,

245

Sandia National Laboratories: radioactive waste solution cleanup  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine bladelifetimepower-to-gasproduceradiation waste cleanup ECIS

246

Combined Flue Gas Heat Recovery and Pollution Control Systems  

E-Print Network [OSTI]

in the field of heat recovery now make it possible to recover a portion of the wasted heat and improve the working conditions of the air purification equipment. Proper design and selection of heat recovery and pollution control equipment as a combination...

Zbikowski, T.

1979-01-01T23:59:59.000Z

247

Cleanup of Nuclear Licensed Facility 57  

SciTech Connect (OSTI)

This summary describes the operations to clean up the equipment of the Nuclear Licensed Facility 57 (NLF 57). Due to the diversity of the research and development work carried out on the reprocessing of spent fuel in it, this installation is emblematic of many of the technical and organizational issues liable to be encountered in the final closure of nuclear facilities. The French atomic energy commission's center at Fontenay aux Roses (CEA-FAR) was created in 1946 to house pile ZOE. Laboratories for fuel cycle research were installed in existing buildings at the site. Work was later concentrated on spent fuel reprocessing, in a pilot workshop referred to as the 'Usine Pu'. In the early sixties, after the dismantling of these first generation facilities, a radiochemistry laboratory dedicated to research and development work on reprocessing was constructed, designated Building 18. During the same decade, more buildings were added: Building 54, storehouses and offices, Building 91, a hall and laboratories for chemical engineering research on natural and depleted uranium. Together, these three building constitute NLF 57. Building 18 architecture featured four similar modules. Each module had three levels: a sub-level consisting of technical galleries and rooms for the liquid effluent tanks, a ground floor and roof space in which the ventilation was installed. Offices, change rooms, four laboratories and a hall were situated on the ground floor. The shielded lines were installed in the laboratories and the halls. Construction of the building took place between 1959 and 1962, and its commissioning began in 1961. The research and development programs performed in NLF 57 related to studies of the reprocessing of spent fuel, including dry methods and the Purex process, techniques for the treatment of waste (vitrification, alpha waste decontamination, etc.) as well as studies and production of transuranic elements for industry and research. In addition to this work, the necessary methods of analysis for monitoring it were also developed. The research and development program finally ended on 30 June 1995. The NLF 57 cleanup program was intended to reduce the nuclear and conventional hazards and minimize the quantities of HLW and MLW during the subsequent dismantling work. To facilitate the organization of the cleanup work, it was divided into categories by type: - treatment and removal of nuclear material, - removal of radioactive sources, - treatment and removal of aqueous liquid waste, - treatment and removal of organic effluents, - treatment and removal of solid waste, - pumping out of the PETRUS tank, - flushing and decontamination of the tanks, - cleanup of Buildings 18 and 91/54. To estimate the cost of the operations and to monitor the progress of the work, an indicator system was put in place based on work units representative of the operation. The values of the work units were periodically updated on the basis of experience feedback. The cleanup progress is now 92% complete (06/12/31): - treatment and removal of nuclear material: 100%, - removal of radioactive sources: 100%, - treatment and removal of aqueous liquid waste: 64%, - treatment and removal of organic effluents: 87%, - treatment and removal of solid waste: 99%, - pumping out of the PETRUS tank: 69%, - flushing and decontamination of tank: 75%, - section cleaning of Buildings 18 and 91/: 90%. The DRSN/SAFAR is the delegated Project Owner for cleanup and dismantling operations. It is also the prime contractor for the cleanup and dismantling operations. SAFAR itself is responsible for operations relating to the CEA activity and those with technical risks (Removal of nuclear materials, Removal of radioactive sources, Pumping out plutonium and transuranic contaminated solvent and Flushing and decontamination of tanks and pipes). All other operations are sub-contracted to specialist companies. The NLF57 cleanup program as executed is capable of attaining activity levels compatible with a future dismantling operation using known and mastered techniques and producing a

Jeanjacques, Michel; Bremond, Marie Pierre; Marchand, Carole; Poyau, Cecile; Viallefont, Cecile; Gautier, Laurent; Masure, Frederic [Commissariat a l'Energie Atomique, Direction de l'Energie Nucleaire, Direction deleguee des Activites Nucleaires de Saclay, Departement des Reacteurs et des Services Nucleaires, Service d'Assainissement de Fontenay Aux Roses: 18, route du Panorama, BP6, 92265 Fontenay aux Roses Cedex (France)

2008-01-15T23:59:59.000Z

248

Progress toward Biomass and Coal-Derived Syngas Warm Cleanup...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal Progress toward Biomass and Coal-Derived Syngas...

249

Site Transition Process upon Completion of the Cleanup Mission...  

Office of Environmental Management (EM)

218: Develop a Fact Sheet on Site Transition at On-going Mission Sites Site Transition Summary: Cleanup Completion to Long-Term Stewardship at Department of Energy...

250

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup...  

Office of Environmental Management (EM)

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley...

251

Oversight Reports - Idaho Cleanup Project | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Project Sodium Bearing Waste Treatment Project - November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project...

252

ORNL research reveals new challenges for mercury cleanup | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Jennifer Brouner Communications 865.241.0709 ORNL research reveals new challenges for mercury cleanup ORNL researchers are learning more about the microbial processes that convert...

253

Promising Science for Plutonium Cleanup | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for Plutonium Cleanup Promising Science for

254

Portsmouth Cleanup Progress | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006PhotovoltaicSeptember 22, 2014 In reply refer to: PE-1Cleanup

255

Portsmouth Environmental Cleanup | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006PhotovoltaicSeptember 22, 2014 In reply refer to:SiteCleanup

256

Sandia National Laboratories: radiation waste cleanup  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine bladelifetimepower-to-gasproduceradiation waste cleanup ECIS and

257

An Electrochemically-mediated Gas Separation Process for Carbon Abatement  

E-Print Network [OSTI]

This work describes a promising alternative to conventional thermal processes for absorber/desorber processing of for removal of CO[subscript 2] from flue gas streams at fossil fuel fired power plants. Our electrochemica ...

Stern, Michael C.

258

IDAHO OPERATIONS OFFICE NAMES NEW IDAHO CLEANUP PROJECT MANAGER  

Broader source: Energy.gov [DOE]

Idaho Falls, ID – The Department of Energy Idaho Operations Office today announced that James Cooper has been named deputy manager of its highly-successful Idaho Cleanup Project, which oversees the environmental cleanup and waste management mission at DOE’s Idaho site.

259

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Draft final technical report  

SciTech Connect (OSTI)

The objective of this contract was to investigate the removal of SO{sub x} and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO{sub x} removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800{degrees} and 2500{degrees}F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

Quimby, J.M.; Kumar, K.S.

1992-12-31T23:59:59.000Z

260

Risk management: Reducing brownfield cleanup costs  

SciTech Connect (OSTI)

Balancing environmental protection with economic vitality is crucial to maintaining competitiveness in world markets. One key initiative that has been identified as important to both environmental protection and the economy is the redevelopment of brownfields. Brownfield redevelopment can stimulate local economies that have been devastated by lost jobs and can recycle industrial land use, thereby preserving undeveloped lands. Many existing brownfield sites appear on the US Environmental Protection Agency`s (EPA) National Priority List (NPL), which designates over 1200 sites and is expected to grow to more than 2000 by the end of the decade. EPA estimates the cost of remediating the sites on the current list will approach $30 billion, with the average cost of remediating a site close to $25 million. Thousands of additional brownfield sites that do not appear on the NPL are listed under state cleanup programs.

Graves, N.

1997-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

2010-11-09T23:59:59.000Z

262

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D.; Bourcier, William L.

2014-08-19T23:59:59.000Z

263

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . . 3-5 3.4 Emission

Zevenhoven, Ron

264

Control of pollutants in flue gases and fuel gases  

E-Print Network [OSTI]

and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

Laughlin, Robert B.

265

Update of lessons learned from cleanup projects at Oak Ridge  

SciTech Connect (OSTI)

The Oak Ridge Operations (ORO) of the US Department of Energy (DOE) has been actively pursuing environmental cleanup of chemically and radioactively contaminated sites for about 7 years. These cleanup projects are carried out under the regulatory requirements of the US Environmental Protection Agency and the various states in which the remedial sites are located. This paper updates and re-examines some of the successes and failures of Oak Ridge cleanup activities, with the intent of encouraging improvements in the areas of safety, project planning, quality assurance, training, and regulatory interactions in future remedial projects.

Sleeman, R.C. [USDOE Oak Ridge Operations, TN (United States)

1993-12-31T23:59:59.000Z

266

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems  

SciTech Connect (OSTI)

The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

1991-02-01T23:59:59.000Z

267

Central Plateau Cleanup at DOE's Hanford Site - 12504  

SciTech Connect (OSTI)

The discussion of Hanford's Central Plateau includes significant work in and around the center of the Hanford Site - located about 7 miles from the Columbia River. The Central Plateau is the area to which operations will be shrunk in 2015 when River Corridor cleanup is complete. This work includes retrieval and disposal of buried waste from miles of trenches; the cleanup and closure of massive processing canyons; the clean-out and demolition to 'slab on grade' of the high-hazard Plutonium Finishing Plant; installation of key groundwater treatment facilities to contain and shrink plumes of contaminated groundwater; demolition of all other unneeded facilities; and the completion of decisions about remaining Central Plateau waste sites. A stated goal of EM has been to shrink the footprint of active cleanup to less than 10 square miles by 2020. By the end of FY2011, Hanford will have reduced the active footprint of cleanup by 64 percent exceeding the goal of 49 percent. By 2015, Hanford will reduce the active footprint of cleanup by more than 90 percent. The remaining footprint reduction will occur between 2015 and 2020. The Central Plateau is a 75-square-mile region near the center of the Hanford Site including the area designated in the Hanford Comprehensive Land Use Plan Environmental Impact Statement (DOE 1999) and Record of Decision (64 FR 61615) as the Industrial-Exclusive Area, a rectangular area of about 20 square miles in the center of the Central Plateau. The Industrial-Exclusive Area contains the 200 East and 200 West Areas that have been used primarily for Hanford's nuclear fuel processing and waste management and disposal activities. The Central Plateau also encompasses the 200 Area CERCLA National Priorities List site. The Central Plateau has a large physical inventory of chemical processing and support facilities, tank systems, liquid and solid waste disposal and storage facilities, utility systems, administrative facilities, and groundwater monitoring wells. As a companion to the Hanford Site Cleanup Completion Framework document, DOE issued its draft Central Plateau Cleanup Completion Strategy in September 2009 to provide an outline of DOE's vision for completion of cleanup activities across the Central Plateau. As major elements of the Hanford cleanup along the Columbia River Corridor near completion, DOE believed it appropriate to articulate the agency vision for the remainder of the cleanup mission. The Central Plateau Cleanup Completion Strategy and the Hanford Site Cleanup Completion Framework were provided to the regulatory community, the Tribal Nations, political leaders, the public, and Hanford stakeholders to promote dialogue on Hanford's future. The Central Plateau Cleanup Completion Strategy describes DOE's vision for completion of Central Plateau cleanup and outlines the decisions needed to achieve the vision. The Central Plateau strategy involves steps to: (1) contain and remediate contaminated groundwater, (2) implement a geographic cleanup approach that guides remedy selection from a plateau-wide perspective, (3) evaluate and deploy viable treatment methods for deep vadose contamination to provide long-term protection of the groundwater, and (4) conduct essential waste management operations in coordination with cleanup actions. The strategy will also help optimize Central Plateau readiness to use funding when it is available upon completion of River Corridor cleanup projects. One aspect of the Central Plateau strategy is to put in place the process to identify the final footprint for permanent waste management and containment of residual contamination within the 20-square-mile Industrial-Exclusive Area. The final footprint identified for permanent waste management and containment of residual contamination should be as small as practical and remain under federal ownership and control for as long as a potential hazard exists. Outside the final footprint, the remainder of the Central Plateau will be available for other uses consistent with the Hanford Comprehensive Land-Use Plan (DOE 1999), while

Dowell, Jonathan [US DOE (United States)

2012-07-01T23:59:59.000Z

268

PPPL's Earth Week features Colloquium on NYC green plan, cleanup...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PPPL's Earth Week features Colloquium on NYC green plan, cleanup and awards By Jeanne Jackson DeVoe April 28, 2014 Tweet Widget Google Plus One Share on Facebook Volunteers clean...

269

EM SSAB Contributes Community Views to Clean-up Decisions  

Broader source: Energy.gov [DOE]

EM has made public participation a fundamental component of its cleanup mission and has found that the EM SSAB, which draws upon diverse community viewpoints to provide advice and recommendations,...

270

Idaho Site Advances Recovery Act Cleanup after Inventing Effective Treatment  

Broader source: Energy.gov [DOE]

For the first time in history, workers at the Idaho site achieved success in the initial cleanup of potentially dangerous sodium in a decommissioned nuclear reactor using an innovative treatment...

271

Radiation site cleanup regulation: An interim progress report  

SciTech Connect (OSTI)

On October 18 and 19, 1993, the 13 members of the National Advisory Council on Environmental Policy and Technology (NACEPT) Subcommittee on Radiation Site Cleanup Regulations met in Washington D.C. at the invitation of EPA. The Subcommittee discussed a variety of topics relevant to the cleanup of sites contaminated with radiation, and to the regulations which EPA will promulgate to establish cleanup levels for radioactive sites. This Interim Progress Report: condenses and summarizes the major themes, issues, and concerns brought up during the NACEPT Subcommittee meeting in October; Provides a brief description of current Agency thinking regarding each of the major topic areas discussed by the NACEPT Subcommittee; and Serves as a discussion guide for NACEPT Subcommittee members. Four major topics were discussed by the NACEPT Subcommittee members during their first meeting in October 1993: Common Themes; Risk (or Cleanup Levels and Risk Levels); Future Land Use and Local Statutes; and Site-Specific Public Involvement.

Not Available

1994-02-01T23:59:59.000Z

272

Process for selected gas oxide removal by radiofrequency catalysts  

DOE Patents [OSTI]

This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

Cha, C.Y.

1993-09-21T23:59:59.000Z

273

Method for high temperature mercury capture from gas streams  

DOE Patents [OSTI]

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

274

Cement kiln flue dust as a source of lime and potassium in four East Texas soils  

E-Print Network [OSTI]

design on both sites. Yield, soil pH, plant and soil concentrations of K, Ca, and Mg were determined. Soil pH and extractable Ca increased with increasing rate of flue dust or calcite. Under field conditions, flue dust compared favorably with calcite... was similar to plant uptake from corresponding calcite + KC1 treatments. Soil pH and extractable soil K, Ca, and Mg increased with increased rate of flue dust treatment equally as well as from the corresponding calcite treatments. The flue dust was equal...

Poole, Warren David

1975-01-01T23:59:59.000Z

275

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 1, Final report  

SciTech Connect (OSTI)

The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

1991-02-01T23:59:59.000Z

276

Implications of the KONVERGENCE Model for Difficult Cleanup Decisions  

SciTech Connect (OSTI)

Abstract—Some cleanup decisions, such as cleanup of intractable contaminated sites or disposal of spent nuclear fuel, have proven difficult to make. Such decisions face high resistance to agreement from stakeholders possibly because they do not trust the decision makers, view the consequences of being wrong as too high, etc. Our project’s goal is to improve sciencebased cleanup decision-making. This includes diagnosing intractable situations, as a step to identifying a path toward sustainable solutions. Companion papers describe the underlying philosophy of the KONVERGENCE Model for Sustainable Decisions,1 and the overall framework and process steps.2 Where knowledge, values, and resources converge (the K, V, and R in KONVERGENCE), you will find a sustainable decision – a decision that works over time. For intractable cases, serious consideration of the adaptable class of alternatives is warranted – if properly implemented and packaged.

Piet, Steven James; Dakins, Maxine Ellen; Gibson, Patrick Lavern; Joe, Jeffrey Clark; Kerr, Thomas A; Nitschke, Robert Leon

2002-08-04T23:59:59.000Z

277

Needs for Risk Informing Environmental Cleanup Decision Making - 13613  

SciTech Connect (OSTI)

This paper discusses the needs for risk informing decision making by the U.S. Department of Energy (DOE) Office of Environmental Management (EM). The mission of the DOE EM is to complete the safe cleanup of the environmental legacy brought about from the nation's five decades of nuclear weapons development and production and nuclear energy research. This work represents some of the most technically challenging and complex cleanup efforts in the world and is projected to require the investment of billions of dollars and several decades to complete. Quantitative assessments of health and environmental risks play an important role in work prioritization and cleanup decisions of these challenging environmental cleanup and closure projects. The risk assessments often involve evaluation of performance of integrated engineered barriers and natural systems over a period of hundreds to thousands of years, when subject to complex geo-environmental transformation processes resulting from remediation and disposal actions. The requirement of resource investments for the cleanup efforts and the associated technical challenges have subjected the EM program to continuous scrutiny by oversight entities. Recent DOE reviews recommended application of a risk-informed approach throughout the EM complex for improved targeting of resources. The idea behind this recommendation is that by using risk-informed approaches to prioritize work scope, the available resources can be best utilized to reduce environmental and health risks across the EM complex, while maintaining the momentum of the overall EM cleanup program at a sustainable level. In response to these recommendations, EM is re-examining its work portfolio and key decision making with risk insights for the major sites. This paper summarizes the review findings and recommendations from the DOE internal reviews, discusses the needs for risk informing the EM portfolio and makes an attempt to identify topics for R and D in integrated risk assessment that could assist in the EM prioritization efforts. (authors)

Zhu, Ming; Moorer, Richard [U.S. Department of Energy, Washington, DC 20585 (United States)] [U.S. Department of Energy, Washington, DC 20585 (United States)

2013-07-01T23:59:59.000Z

278

Clean-up standards and pathways analysis methods  

SciTech Connect (OSTI)

Remediation of a radioactively contaminated site requires that certain regulatory criteria be met before the site can be released for unrestricted future use. Since the ultimate objective of remediation is to protect the public health and safety, residual radioactivity levels remaining at a site after cleanup must be below certain preset limits or meet acceptable dose or risk criteria. This paper discusses cleanup standards for radioactively contaminated soils and describes the use of pathways analysis methods for deriving site-specific residual radioactivity guidelines. An example is provided in which a pathways analysis code (RESRAD) was used to establish such guidelines.

Devgun, J.S. [Argonne National Lab., IL (United States). Office of Waste Management Programs

1993-12-31T23:59:59.000Z

279

Reducing the cost of CO{sub 2} capture from flue gases using pressure swing adsorption  

SciTech Connect (OSTI)

Pressure swing adsorption (PSA) processes have been used extensively for gas separation, especially in the separation of hydrogen from CO{sub 2}, and in air purification. The objective of this paper is to examine the economic feasibility of pressure swing adsorption (PSA) for recovering CO{sub 2} from postcombustion power plant flue gas. The analysis considers both high-pressure feed and vacuum desorption using commercial adsorbent 13X, which has a working capacity of 2.2 mol/kg and CO{sub 2}/N{sub 2} selectivity of 54. The results show that using vacuum desorption reduces the capture cost from US$57 to US$51 per ton of CO{sub 2} avoided and is comparable in cost to CO{sub 2} capture using conventional MEA absorption of US$49 per ton of CO{sub 2} avoided. In this paper, a sensitivity analysis is also presented showing the effect on the capture cost with changes in process cycle; feed pressure and evacuation pressure; improvements the adsorbent characteristics; and selectivity and working capacity. The results show that a hypothetical adsorbent with a working capacity of 4.3 mol/kg and a CO{sub 2}/N{sub 2} selectivity of 150 can reduce the capture cost to US$30 per ton of CO{sub 2} avoided.

Ho, M.T.; Allinson, G.W.; Wiley, D.E. [University of New South Wales, Sydney, NSW (Australia)

2008-07-15T23:59:59.000Z

280

Microsoft Word - DOE News Release-DOE Completes Cleanup at New...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DOE Completes Cleanup at New York, California Sites Recovery Act funds accelerate cleanup; support job creation and footprint reduction WASHINGTON, D.C. - Last month, the U.S....

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Technical papers presented at a DOE meeting on criteria for cleanup of transuranium elements in soil  

SciTech Connect (OSTI)

Transuranium element soil contamination cleanup experience gained from nuclear weapons accidents and cleanup at Eniwetok Atoll was reviewed. Presentations have been individually abstracted for inclusion in the data base. (ACR)

Not Available

1984-09-01T23:59:59.000Z

282

Radiation site cleanup regulations: Technical support document for the development of radionuclide cleanup levels for soil. Review draft  

SciTech Connect (OSTI)

This report presents EPA`s approach to assessing some of the beneficial and adverse radiation health effects associated with various possible values for an annual dose limit. In particular, it discusses the method developed to determine how the choice of cleanup criterion affects (1) the time-integrated numbers of non-fatal and fatal radiogenic cancers averted among future populations, (2) the occurrence of radiogenic cancers among remediation workers and the public caused by the cleanup process itself, and (3) the volume of contaminated soil that may require remediation.

Wolbarst, A.B.; Mauro, J.; Anigstein, R.; Back, D.; Bartlett, J.W.

1994-09-24T23:59:59.000Z

283

Cleanup Verification Package for the 118-F-6 Burial Ground  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 118-F-6 Burial Ground located in the 100-FR-2 Operable Unit of the 100-F Area on the Hanford Site. The trenches received waste from the 100-F Experimental Animal Farm, including animal manure, animal carcasses, laboratory waste, plastic, cardboard, metal, and concrete debris as well as a railroad tank car.

H. M. Sulloway

2008-10-02T23:59:59.000Z

284

Cleanup at Los Alamos National Laboratory - the challenges - 9493  

SciTech Connect (OSTI)

This paper provides an overview of environmental cleanup at the Los Alamos National Laboratory (LANL) and some of the unique aspects and challenges. Cleanup of the 65-year old Department of Energy Laboratory is being conducted under a RCRA Consent Order with the State of New Mexico. This agreement is one of the most recent cleanup agreements signed in the DOE complex and was based on lessons learned at other DOE sites. A number of attributes create unique challenges for LANL cleanup -- the proximity to the community and pueblos, the site's topography and geology, and the nature of LANL's on-going missions. This overview paper will set the stage for other papers in this session, including papers that present: Plans to retrieve buried waste at Material Disposal Area B, across the street from oen of Los Alamos' commercial districts and the local newspaper; Progress to date and joint plans with WIPP for disposal of the remaining inventory of legacy transuranic waste; Reviews of both groundwater and surface water contamination and the factors complicating both characterization and remediation; Optimizing the disposal of low-level radioactive waste from ongoing LANL missions; A stakeholder environmental data transparency project (RACER), with full public access to all available information on contamination at LANL, and A description of the approach to waste processing cost recovery from the programs that generate hazardous and radioactive waste at LANL.

Stiger, Susan G [Los Alamos National Laboratory; Hargis, Kenneth M [Los Alamos National Laboratory; Graham, Michael J [Los Alamos National Laboratory; Rael, George J [NNSL/LASO

2008-01-01T23:59:59.000Z

285

natural gas+ condensing flue gas heat recovery+ water creation+ CO2  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectric Coop,SaveWhiskey Flatshydro Home Water Powerlaunchmulticolorreduction+

286

OpenEI Community - natural gas+ condensing flue gas heat recovery+ water  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth'sOklahoma/Geothermal < Oklahomast, 2012CoastfredResult Formats

287

High potential recovery -- Gas repressurization  

SciTech Connect (OSTI)

The objective of this project was to demonstrate that small independent oil producers can use existing gas injection technologies, scaled to their operations, to repressurize petroleum reservoirs and increase their economic oil production. This report gives background information for gas repressurization technologies, the results of workshops held to inform small independent producers about gas repressurization, and the results of four gas repressurization field demonstration projects. Much of the material in this report is based on annual reports (BDM-Oklahoma 1995, BDM-Oklahoma 1996, BDM-Oklahoma 1997), a report describing the results of the workshops (Olsen 1995), and the four final reports for the field demonstration projects which are reproduced in the Appendix. This project was designed to demonstrate that repressurization of reservoirs with gas (natural gas, enriched gas, nitrogen, flue gas, or air) can be used by small independent operators in selected reservoirs to increase production and/or decrease premature abandonment of the resource. The project excluded carbon dioxide because of other DOE-sponsored projects that address carbon dioxide processes directly. Two of the demonstration projects, one using flue gas and the other involving natural gas from a deeper coal zone, were both technical and economic successes. The two major lessons learned from the projects are the importance of (1) adequate infrastructure (piping, wells, compressors, etc.) and (2) adequate planning including testing compatibility between injected gases and fluids, and reservoir gases, fluids, and rocks.

Madden, M.P.

1998-05-01T23:59:59.000Z

288

PETC Review, Issue 2, September 1990  

SciTech Connect (OSTI)

This issue of PETC Review provides short discussion on research programs in (1) combustion technology, (2) flue gas cleanup technology, (3) coal science and chemistry. An overview of the PETC New Fuels Evaluation Facility is given, the US Clean Coal Technology Program's activities in Poland are discussed, and the NOXSO flue gas cleanup process is outlined. Supplemental sections on events, special focuses, publication listings, etc. are also included.

Blaustein, B.; Reiss, J.; Riehle, B.; Brown, J.; Hammer, D. (eds.)

1990-09-01T23:59:59.000Z

289

PETC Review, Issue 2, September 1990  

SciTech Connect (OSTI)

This issue of PETC Review provides short discussion on research programs in (1) combustion technology, (2) flue gas cleanup technology, (3) coal science and chemistry. An overview of the PETC New Fuels Evaluation Facility is given, the US Clean Coal Technology Program`s activities in Poland are discussed, and the NOXSO flue gas cleanup process is outlined. Supplemental sections on events, special focuses, publication listings, etc. are also included.

Blaustein, B.; Reiss, J.; Riehle, B.; Brown, J.; Hammer, D. [eds.

1990-09-01T23:59:59.000Z

290

Proceedings: EPRI Manufactured Gas Plants 2003 Forum  

SciTech Connect (OSTI)

The EPRI Manufactured Gas Plants 2003 Forum covered a range of topics related to remediation and management of former manufactured gas plant (MGP) sites, with emphasis on technological advances and current issues associated with site cleanup. In specific, the forum covered MGP coal-tar delineation, soil and groundwater remediation technologies, improvements in air monitoring, and ecological risk characterization/risk management tools.

None

2004-02-01T23:59:59.000Z

291

Site Cleanup Report for Sites PBF-33 and PBF-34  

SciTech Connect (OSTI)

This document summaries the actions taken to remove asbestos-reinforced-concrete (transite) pipe and miscellaneous debris from Power Purst Facility (PBF)-33 and PBF-34 sites. Removal of pipe and debris were performed in November 2006 in accordance with the requirements discussed in notice of soil disturbance NSD-PBF-07-01. Debris at these two sites were classified as industrial waste that could be disposed at the Central Facilities Area (CFA) landfill at the Idaho National Laboratory. Asbestos removal was performed as Class IV asbestos cleanup work. All transite pipe was double bagged and dispositioned in the INL Landfill Complex at CFA. The remaining miscellaneous debris was loaded into dump trucks and taken to the INL Landfill Complex at CFA for final disposition. Cleanup actions are complete for both sites, and no debris or hazardous constituents remain. Therefore, both sites will be classified as No action sites.

W. L. Jolley

2007-01-16T23:59:59.000Z

292

Cleanup Verification Package for the 618-8 Burial Ground  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 618-8 Burial Ground, also referred to as the Solid Waste Burial Ground No. 8, 318-8, and the Early Solid Waste Burial Ground. During its period of operation, the 618-8 site is speculated to have been used to bury uranium-contaminated waste derived from fuel manufacturing, and construction debris from the remodeling of the 313 Building.

M. J. Appel

2006-08-10T23:59:59.000Z

293

"Hanford: A Conversation About Nuclear Waste and Cleanup"  

SciTech Connect (OSTI)

In ''Hanford: A Conversation about Nuclear Waste and Cleanup'', Roy Gephart takes us on a journey through a world of facts, values, conflicts, and choices facing the most complex environmental cleanup project in the United States, the U.S. Department of Energy's Hanford Site. Starting with the top-secret Manhattan Project, Hanford was used to create tons of plutonium for nuclear weapons. Hundreds of tons of waste remain. In an easy-to-read, illustrated text, Gephart crafts the story of Hanford becoming the world's first nuclear weapons site to release large amounts of contaminants into the environment. This was at a time when radiation biology was in its infancy, industry practiced unbridled waste dumping, and the public trusted what it was told. The plutonium market stalled with the end of the Cold War. Public accountability and environmental compliance ushered in a new cleanup mission. Today, Hanford is driven by remediation choices whose outcomes remain uncertain. It's a story whose epilogue will be written by future generations. This book is an information resource, written for the general reader as well as the technically trained person wanting an overview of Hanford and cleanup issues facing the nuclear weapons complex. Each chapter is a topical mini-series. It's an idea guide that encourages readers to be informed consumers of Hanford news, to recognize that knowledge, high ethical standards, and social values are at the heart of coping with Hanford's past and charting its future. Hanford history is a window into many environmental conflicts facing our nation; it's about building upon success and learning from failure. And therein lies a key lesson, when powerful interests are involved, no generation is above pretense. Roy E. Gephart is a geohydrologist and senior program manager at the Pacific Northwest National Laboratory, Richland, Washington. He has 30 years experience in environmental studies and the nuclear waste industry.

Gephart, Roy E.

2003-05-10T23:59:59.000Z

294

GAS INJECTION/WELL STIMULATION PROJECT  

SciTech Connect (OSTI)

Driver Production proposes to conduct a gas repressurization/well stimulation project on a six well, 80-acre portion of the Dutcher Sand of the East Edna Field, Okmulgee County, Oklahoma. The site has been location of previous successful flue gas injection demonstration but due to changing economic and sales conditions, finds new opportunities to use associated natural gas that is currently being vented to the atmosphere to repressurize the reservoir to produce additional oil. The established infrastructure and known geological conditions should allow quick startup and much lower operating costs than flue gas. Lessons learned from the previous project, the lessons learned form cyclical oil prices and from other operators in the area will be applied. Technology transfer of the lessons learned from both projects could be applied by other small independent operators.

John K. Godwin

2005-12-01T23:59:59.000Z

295

Rocky Flats Cleanup Agreement implementation successes and challenges  

SciTech Connect (OSTI)

On July 19, 1996 the US Department of Energy (DOE), State of Colorado (CDPHE), and US Environmental Protection Agency (EPA) entered into an agreement called the Rocky Flats Cleanup Agreement (RFCA) for the cleanup and closure of the Rocky Flats Environmental Technology Site (RFETS or Rocky Flats). Major elements of the agreement include: an Integrated Site-Wide Baseline; up to twelve significant enforceable milestones per year; agreed upon soil and water action levels and standards for cleanup; open space as the likely foreseeable land use; the plutonium and TRU waste removed by 2015; streamlined regulatory process; agreement with the Defense Nuclear Facilities Safety Board (DNFSB) to coordinate activities; and a risk reduction focus. Successful implementation of RFCA requires a substantial effort by the parties to change their way of thinking about RFETS and meet the deliverables and commitments. Substantial progress toward Site closure through the implementation of RFCA has been accomplished in the short time since the signing, yet much remains to be done. Much can be learned from the Rocky Flats experience by other facilities in similar situations.

Shelton, D.C.

1997-02-01T23:59:59.000Z

296

Clean-up of Nuclear Licensed Facility 57  

SciTech Connect (OSTI)

Available in abstract form only. Full text of publication follows: In the early sixties a radiochemistry laboratory dedicated to Research and Development was built at the French Atomic Energy Commission's centre at Fontenay aux Roses (CEA-FAR); it was named Building 18. More buildings were added during the decade: Building 54, storehouses and offices and Building 91, a hall and laboratories for chemical engineering research into natural and depleted uranium. These three buildings together constitute NLF57. Construction work took place between 1959 and 1962 and the buildings entered operation in 1961. The research and development programs performed in NLF57 involved spent fuel reprocessing studies, waste treatment processes and studies and production of transuranic elements with the related analytical methods development. The research and development program ended on 30 June 1995. The NLF57 clean-up program was launched to reduce the nuclear and conventional hazards and minimise HLW and MLW production during the dismantling work. The clean-up work was divided into categories by type to facilitate its organisation: treatment and removal of nuclear material, removal of radioactive sources, treatment and removal of organic and aqueous effluents, treatment and removal of solid waste, pumping out of the PETRUS tank, flushing and decontamination of the tanks and clean-up of buildings. (authors)

Jeanjacques, Michel; Bremond, Marie Pierre; Marchand, Carole; Poyau, Cecile; Viallefont, Cecile; Gautier, Laurent; Masure, Frederic [CEA, DANS-DRSN-SAFAR (France)

2007-07-01T23:59:59.000Z

297

Evaluating energy dissipation during expansion in a refrigeration cycle using flue pipe acoustic resonators  

E-Print Network [OSTI]

This research evaluates the feasibility of using a flue pipe acoustic resonator to dissipate energy from a refrigerant stream in order to achieve greater cooling power from a cryorefrigeration cycle. Two models of the ...

Luckyanova, Maria N. (Maria Nickolayevna)

2008-01-01T23:59:59.000Z

298

Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems: Greenfield assessment  

SciTech Connect (OSTI)

Both the KRW fluidized-bed gasifier and the transport gasifier case studies were used for this assessment. The transport technology is a high-velocity circulating fluidized-bed reactor currently under development by The M.W. Kellogg Company. In the earlier assessment, seven design concepts or cases were identified; a process design was developed; major equipment items were identified; estimates of capital cost, operation and maintenance cost, and cost of electricity were developed; reliability was predicted; and development issues were identified for six studies. Three of the most probable cases were further evaluated for a Greenfield assessment in this report to adequately determine all costs independent of facilities at Plant Wansley.

Not Available

1991-12-01T23:59:59.000Z

299

E-Print Network 3.0 - accelerated cleanup risk Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of having cleanup activities guided by ... Source: Flury, Markus - Department of Crop and Soil Sciences, Washington State University Collection: Environmental Management and...

300

Richland Operations Office Completes Cleanup in Hanford’s 300 Area North Section  

Broader source: Energy.gov [DOE]

RICHLAND, Wash. – EM met a Tri-Party Agreement milestone by completing cleanup of the north portion of Hanford’s 300 Area.

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

River Corridor Cleanup Contract Fiscal Year 2006 Detailed Work Plan: DWP Summary, Volume 1  

SciTech Connect (OSTI)

This detailed work plan provides the scope, cost, and schedule for the Fiscal Year 2006 activities required to support River Corridor cleanup objectives within the directed guidance.

Project Integration

2005-09-26T23:59:59.000Z

302

Recovery Cleanup Project at Y-12 Leaves Alpha 5 with an Empty...  

National Nuclear Security Administration (NNSA)

Cleanup Project at Y-12 Leaves Alpha 5 with an Empty Feeling | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

303

LANL selects local small business for post-Recovery Act cleanup...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

up where the Recovery Act leaves off," said Michael Graham, LANL's associate director for Environmental Programs. "The Recovery Act was a huge boost to our cleanup efforts, and...

304

Petroleum cleanup in the United States: A historical review and comparison of state programs.  

E-Print Network [OSTI]

??Cleanup of leaking underground storage tank (LUST) sites has been a priority for the United States of America (USA) for more than 20 years due… (more)

Terwilliger, Timothy A

2006-01-01T23:59:59.000Z

305

Recovery Act Helps Y-12 Exceed Cleanup Goal at Manhattan Project...  

National Nuclear Security Administration (NNSA)

Helps Y-12 Exceed Cleanup Goal at Manhattan Project-Era Building | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the...

306

Voluntary Protection Program Onsite Review, CH2M WG LLC, Idaho Cleanup Project – March 2014  

Broader source: Energy.gov [DOE]

Evaluation to determine whether CH2M WG LLC, Idaho Cleanup Project is performing at a level deserving DOE-VPP Star recognition.

307

Environmental Cleanup of the Idaho National Laboratory Status Report  

SciTech Connect (OSTI)

This paper describes the status of the cleanup of the U.S. Department of Energy's Idaho National Laboratory site (INL). On May 1, 2005 CH2M.WG Idaho, LLC (CWI) began its 7-year, $2.4 billion cleanup of the INL. When the work is completed, 3,406,871 liters (900,000 gallons) of sodium-bearing waste will have been treated; 15 high-level waste tanks will have been grouted and Resource Conservation and Recovery Act (RCRA)- closed; more than 200 facilities will have been demolished or disposed of, including three reactors, several spent fuel basins, and hot cells; thousands of containers of buried transuranic waste will have been retrieved; more than 8,000 cubic meters (10,464 cubic yards) of contact-handled transuranic waste and more than 500 cubic meters (654 cubic yards) of remote-handled transuranic waste will have been characterized, packaged, and shipped offsite; almost 200 release sites and voluntary consent order tank systems will have been remediated; and 3,178 units of spent fuel will have been moved from wet to dry storage. In 2007, CWI began the construction of the Integrated Waste Treatment Unit that will treat the sodium-bearing waste for eventual disposal; removed and disposed the 112-ton Engineering Test Reactor vessel; demolished all significant radiological facilities at Test Area North; continued the exhumation of buried transuranic wastes from the Subsurface Disposal Area at the Radioactive Waste Management Complex; shipped the first of hundreds of containers of remote-handled transuranic waste to the Waste Isolation Pilot Plant; disposed of thousands of cubic meters of low-level and low-level mixed radioactive wastes both onsite and offsite while meeting all regulatory cleanup objectives. (author)

Schubert, A.L. [CH2M.WG Idaho, LLC, Idaho Falls, Idaho (United States)

2008-07-01T23:59:59.000Z

308

Thyroid nodularity and cancer among Chernobyl cleanup workers from Estonia  

SciTech Connect (OSTI)

Thyroid examinations, including palpation, ultrasound and, selectively, fine-needle aspiration biopsy, were conducted on nearly 2,000 Chernobyl cleanup workers from Estonia to evaluate the occurrence of thyroid cancer and nodular thyroid disease among men with protracted exposure to ionizing radiation. The examinations were conducted in four cities in Estonia during March-April 1995, 9 years after the reactor accident. The study population was selected from a predefined cohort of 4,833 cleanup workers from Estonia under surveillance for cancer incidence. These men had been sent to Chernobyl between 1986 and 1991 to entomb the damaged reactor, remove radioactive debris and perform related cleanup activities. A total of 2,997 men were invited for thyroid screening and 1,984 (66%) were examined. Estimates of radiation dose from external sources were obtained from military or other institutional records, and details about service dates and types of work performed while at Chernobyl were obtained from a self-administered questionnaire. Blood samples were collected for assay of chromosomal translocations in circulating lymphocytes and loss of expression of the glycophorin A (GPA) gene in erythrocytes. The primary outcome measure was the presence or absence of thyroid nodules as determined by the ultrasound examination. Of the screened workers, 1,247 (63%) were sent to Chernobyl in 1986, including 603 (30%) sent in April or May, soon after the accident. Workers served at Chernobyl for an average of 3 months. The average age was 32 years at the time of arrival at Chernobyl and 40 years at the time of thyroid examination. The mean documented radiation dose from external sources was 10.8 cGy. Biological indicators of exposure showed low correlations with documented dose, but did not indicate that the mean dose for the population was higher than the average documented dose. 47 refs., 1 fig., 9 tabs.

Inskip, P.D.; Boice, J.D. Jr. [National Cancer Inst., Rockville, MD (United States); Tekkel, M. [Univ. of New Mexico, Albuquerque, NM (United States)] [and others

1997-02-01T23:59:59.000Z

309

FUSRAP - 45 DOE cleanup projects across the country  

SciTech Connect (OSTI)

The Formerly Utilized Sites Remedial Action Program (FUSRAP) is a U.S. Department of Energy (DOE) program designed to address radiological contamination exceeding acceptable cleanup standards at 45 sites throughout the United States. The DOE and its predecessor agencies, the Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC), used many of these sites for processing and storing uranium and thorium ores as part of the nation`s early nuclear production activities. While some of the sites are owned by the federal government, most of the sites were, and are, privately owned.

Price, L.K. [Dept. of Energy, Oak Ridge, TN (United States); Harbert, R.R.; Palau, G.L.

1994-12-31T23:59:59.000Z

310

Cleanup Verification Package for the 118-F-1 Burial Ground  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 118-F-1 Burial Ground on the Hanford Site. This burial ground is a combination of two locations formerly called Minor Construction Burial Ground No. 2 and Solid Waste Burial Ground No. 2. This waste site received radioactive equipment and other miscellaneous waste from 105-F Reactor operations, including dummy elements and irradiated process tubing; gun barrel tips, steel sleeves, and metal chips removed from the reactor; filter boxes containing reactor graphite chips; and miscellaneous construction solid waste.

E. J. Farris and H. M. Sulloway

2008-01-10T23:59:59.000Z

311

Cleanup Verification Package for the 116-K-2 Effluent Trench  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 116-K-2 effluent trench, also referred to as the 116-K-2 mile-long trench and the 116-K-2 site. During its period of operation, the 116-K-2 site was used to dispose of cooling water effluent from the 105-KE and 105-KW Reactors by percolation into the soil. This site also received mixed liquid wastes from the 105-KW and 105-KE fuel storage basins, reactor floor drains, and miscellaneous decontamination activities.

J. M. Capron

2006-04-04T23:59:59.000Z

312

Groundwater Cleanup Progresses at Paducah Site | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecemberGlossary ofGroundwater Cleanup Progresses at Paducah

313

Recovery Act funds advance cleanup efforts at Cold War site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising ScienceRecent SREL ReprintsHeaviestRecovery Act »Cleanup

314

Secretary Chu Highlights Recovery Act Cleanup Progress | Department of  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September2-SCORECARD-01-24-13Discovers Transformers inEnergy Cleanup

315

Mercury cleanup efforts intensify | Y-12 National Security Complex  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubeyChallenge MelroseMentorMercury cleanup

316

FY14 Guidelines for Brownfields Cleanup Grants | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplainsEnvironmental Assessments andCleanup Grants

317

Effects of fracturing fluid recovery upon well performance and ultimate recovery of hydraulically fractured gas wells  

E-Print Network [OSTI]

on Clean-Up Mobile Water Phase 84 17 Effects of Hystexesis on Clean-Up immobile Water Phase 84 18 Effects of Initial Flow Conditions on Gas Production Initial Resexvor Pressure = 11, 700 psi ? Single Phase . . . 95 Table 19 21 22 23 24 25... Effects of Initial How Conditions on Gas Pmduction Initial Reservor Pressure = 7, 800 psi - Single Phase Effects of Initial Flow Conditions on Productivity With No Water Injection Initial Reservoir Pressure = 11, 700 psi ? Initial Cr = 10 Effects...

Berthelot, Jan Marie

1990-01-01T23:59:59.000Z

318

Remediation cleanup options for the Hoe Creek UCG site  

SciTech Connect (OSTI)

The US Department of Energy must restore groundwater quality at the Hoe Creek, Wyoming, underground coal gasification site using the best proven practicable technology. Six alternative remediation methods are evaluated in this project: (1) excavation, (2) three variations of groundwater plume containment, (3) in situ vacuum extraction, (4) pump and treat using a defined pattern of pumping wells to obtain an effective matrix sweep, (5) in situ flushing using a surfactant, and (6) in situ bioremediation. Available site characterization data is insufficient to accurately project the cost of remediation. Several alternative hypothetical examples and associated costs are described in the text and in the appendices. However, not enough information is available to use these examples as a basis for comparison purposes. Before a cleanup method is selected, core borings should be taken to define the areal extent and depth of contaminated matrix material. Segments of these core borings should be analyzed for organic contaminants in the soil (e.g., benzene) and their relationship to the groundwater contamination. These analyses and subsequent treatability studies will show whether or not the contaminants can be effectively removed by surface on in situ volatilization, leached from the matrix using washing solutions, or removed by bioremediation. After this information is obtained, each technology should be evaluated with respect to cost and probability of success. A decision tree for implementing remediation cleanup at the Hoe Creek site is presented in this report. 26 refs., 11 figs., 3 tabs.

Nordin, J.; Griffin, W.; Chatwin, T.; Lindblom, S.; Crader, S.

1990-03-01T23:59:59.000Z

319

Micellar/Polymer PhysicalProperty Models for Contaminant Cleanup Problems and  

E-Print Network [OSTI]

/polymer phase behavior have been highly successful in simulating enhanced oil recovery processes using for contaminant cleanup [26] and for enhanced oil recovery [14]. Surfactants can be injected as dilute aqueousMicellar/Polymer Physical­Property Models for Contaminant Cleanup Problems and Enhanced Oil

Trangenstein, John A.

320

Development of a risk-based approach to Hanford Site cleanup  

SciTech Connect (OSTI)

In response to a request from Mr. Thomas Grumbly, Assistant Secretary of Energy for Environmental Management, the Hanford Site contractors developed a conceptual set of risk-based cleanup strategies that (1) protect the public, workers, and environment from unacceptable risks; (2) are executable technically; and (3) fit within an expected annual funding profile of 1.05 billion dollars. These strategies were developed because (1) the US Department of Energy and Hanford Site budgets are being reduced, (2) stakeholders are dissatisfied with the perceived rate of cleanup, (3) the US Congress and the US Department of Energy are increasingly focusing on risk and riskreduction activities, (4) the present strategy is not integrated across the Site and is inconsistent in its treatment of similar hazards, (5) the present cleanup strategy is not cost-effective from a risk-reduction or future land use perspective, and (6) the milestones and activities in the Tri-Party Agreement cannot be achieved with an anticipated funding of 1.05 billion dollars annually. The risk-based strategies described herein were developed through a systems analysis approach that (1) analyzed the cleanup mission; (2) identified cleanup objectives, including risk reduction, land use, and mortgage reduction; (3) analyzed the existing baseline cleanup strategy from a cost and risk perspective; (4) developed alternatives for accomplishing the cleanup mission; (5) compared those alternatives against cleanup objectives; and (6) produced conclusions and recommendations regarding the current strategy and potential risk-based strategies.

Hesser, W.A.; Daling, P.M. [Pacific Northwest Lab., Richland, WA (United States); Baynes, P.A. [Westinghouse Hanford Co., Richland, WA (United States)] [and others

1995-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement  

SciTech Connect (OSTI)

Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60 C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.

Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Yin, Hongxi [Southeast University, Nanjing, China

2014-01-01T23:59:59.000Z

322

A cement kiln flue-dust evaluated as a soil liming material  

E-Print Network [OSTI]

A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

Stacha, Raimund

1973-01-01T23:59:59.000Z

323

Predictive Modeling of Mercury Speciation in Combustion Flue Gases Using GMDH-Based Abductive Networks  

E-Print Network [OSTI]

to develop. The use of modern data-based machine learning techniques has been recently introduced, including and boiler operating conditions. Prediction performance compares favourably with neural network models for future work to further improve performance. Index Terms: Mercury speciation, Flue gases, Boiler emissions

Abdel-Aal, Radwan E.

324

Recovering "Waste" from "WTEs"? Heat Attaching devices to flues and exhaust pipes could harvest waste heat-  

E-Print Network [OSTI]

Kanatzidis argues that wherever heat is generated as part of power generation, thermoelectric devices couldRecovering "Waste" from "WTEs"? Heat Attaching devices to flues and exhaust pipes could harvest waste heat- Mar 16th 2006 | From The Economist print edition HERE is a thought: approximately 60

Columbia University

325

Advanced cleanup device performance design report (Task 4. 3). Volume A. Cyclone theory and data correlation  

SciTech Connect (OSTI)

The 100-year-old cyclone is perhaps the best known and least expensive method of gas particulate cleaning. The theory and practice of cyclone operation has been extensively documented. The body of experience indicates that small cyclones operated at high swirl velocity give better separative efficiency although consideration must also be given to coarse particle bouncing and limitations associated with system pressure losses and cyclone erosion. Hence, multicyclones (i.e., many small cyclones operating in parallel), and staging have been employed in situations where unusually clean gas is mandated. Despite the extensive body of literature on the subject, predicting the performance of cyclones in actual service remains an art. The inadequacies in the existing cyclone theories quickly became evident in the course of several experimental programs at GE using various cyclone designs. The most significant finding of this work has been the observation that electrostatic forces could enhance, or, in fact, dominate the separation process. Cyclone separative efficiencies, with natural electrostatic effects present, were found to be independent of flowrate or even to improve at low flowrates, completely contrary to any of the existing cyclone literature. By implication, it is also possible that such electrostatic forces could influence cyclone scaling so that large cyclones employed in the cleanup train may not suffer the performance degradation compared to small cyclones, as projected from conventional inertial theory. Much of the GE work has therefore been oriented toward understanding and augmenting these electrostatic effects. This report is a collection of the most significant papers and memos on cyclone performance generated during the past three years by General Electric under the CFCC program.

Not Available

1981-01-01T23:59:59.000Z

326

Application of holographic neural networks for flue gas emissions prediction in the Burnaby incinerator  

SciTech Connect (OSTI)

This article describes the development of a parametric prediction system (PPS) for various emission species at the Burnaby incinerator. The continuous emissions monitoring system at the Burnaby incinerator is shared between three boilers and therefore actual results are only available 5 minutes out of every 15 minutes. The PPS was developed to fill in data for the 10 minutes when the Continuous Emission Monitor (CEM) is measuring the other boilers. It bases its prediction on the last few actual readings taken and parametrically predicts CO, SO2 and NOx. The Burnaby Incinerator is located in the commercial/industrial area of South Burnaby, British Columbia. It consists of three separate lines, each burning ten tonnes of garbage per hour and producing about three tonnes of steam for every tonne of garbage burned. The air pollution control system first cools the combustion products with water injection and then scrubs them with very fine hydrated lime. Carbon is added to the lime to enhance the scrubbing of the combustion products. The CEM monitors the levels of oxygen, carbon monoxide, nitrogen oxides, sulphur dioxide and opacity. In 1996, an expert system was installed on one of boilers at the Burnaby Incinerator plant to determine if it could improve the plant=s operations and reduce overall emission. As part of the expert system, the PPS was developed. Holographic Neural Technology (HNeT), developed by AND Corporation of Toronto, Ontario, is a novel neural network technology using complex numbers in its architecture. Compared to the traditional neural networks, HNeT has some significant advantage. It is more resilient against converging on local minima; is faster training and executing; less prone to over fitting; and, in most cases, has significantly lower error. Selection of independent variabs, training set preparation, testing neural nets and other related issue will be discussed.

Zheng, L.; Dockrill, P.; Clements, B. [Natural Resources Canada, Nepean, Ontario (Canada). CANMET Energy Technology Centre

1997-12-31T23:59:59.000Z

327

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the reactive carbonate material. The presence of carboaluminate phases as a result of the interaction of the reactive carbonate materials with ordinary portland cement was also confirmed. A Life Cycle Assessment was completed for several cases based on different Calera process configurations and compared against the life cycle of ordinary portland cement. In addition to the materials development efforts, the Calera technology for the production of product using an innovative building materials demonstration plant was developed beyond conceptual engineering to a detailed design with a construction schedule and cost estimate.

Brent Constantz; Randy Seeker; Martin Devenney

2010-06-30T23:59:59.000Z

328

Performance history over 10 years of super duplex stainless steel in flue gas desulfurization  

SciTech Connect (OSTI)

25 Cr duplex (austenitic/ferritic) stainless steel containing copper and nitrogen offers a cost effective solution to material selection for pollution control equipment. The properties of duplex stainless steel which make it suitable for this type of application are discussed and long term performance histories presented. It is concluded that high alloy duplex steel has an important role to play in the production of low maintenance reliable equipment for FGD and other pollution control systems.

Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

1996-08-01T23:59:59.000Z

329

Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers  

E-Print Network [OSTI]

....'::::;::::::: Il-~:!=;~:o:oo:t(.~ _.;:::::=:;:::::.":':::"':'::':":::":::.lIoo:...:...:_:?.:""'.:::::::::::::::::::;::~ . ??:.:?????????????::: Precipitator :.- .......?......... ~ ........ . ... :.:.:.:. ..:.:.:.:.:.:.:.:.:.:.. ? ? ? ? ......w.;."w,1o&.I1.&r...

Miller, B.; Keon, E.

1980-01-01T23:59:59.000Z

330

The utilization of flue gas desulfurization waste by-products in construction brick  

E-Print Network [OSTI]

APPENDIX D. TEST PROCEDURES APPENDIX E. CONVERSION TABLES VITA 85 90 93 96 99 LIST OF FIGURES Figure Page Model for FGD Waste By-Product Research Unconfined Compressive Strength for Fly Ash Mixed with Various Inductions of Portland Cement 15... properties such as weight, durability, strength, density, etc. Varying mixes of bottom ash, fly ash, portland cement, and sand will be tested for possible enhancement of the hemihydrate. Also, a mix design that best utilizes all the waste by...

Berryman, Charles Wayne

1992-01-01T23:59:59.000Z

331

Catalysts for Oxidation of Mercury in Flue Gas - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Health Services| Advanced PhotonAdvanced

332

Ab Initio Rational Design of New MOFs for Separations and Flue Gas Capture  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch Highlights MediaFuel Production ASU is a placeJoin the|

333

DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganizationElectronic Reading2Q)382 THE HUMANlviA,'{i

334

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearchCASL Symposium: CelebratingMissionat CornellMetal-Organic

335

pH Adjustment of Power Plant Cooling Water with Flue Gas/ Fly Ash - Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 Industrial Carbon CaptureFY08 Joint JOULE J.nbarbeeLargeNHMFL-PFF at51( ( ( ( ( (

336

From Cleanup to Stewardship. A companion report to Accelerating Cleanup: Paths to Closure and background information to support the scoping process required for the 1998 PEIS Settlement Study  

SciTech Connect (OSTI)

Long-term stewardship is expected to be needed at more than 100 DOE sites after DOE's Environmental Management program completes disposal, stabilization, and restoration operations to address waste and contamination resulting from nuclear research and nuclear weapons production conducted over the past 50 years. From Cleanup to stewardship provides background information on the Department of Energy (DOE) long-term stewardship obligations and activities. This document begins to examine the transition from cleanup to long-term stewardship, and it fulfills the Secretary's commitment to the President in the 1999 Performance Agreement to provide a companion report to the Department's Accelerating Cleanup: Paths to Closure report. It also provides background information to support the scoping process required for a study on long-term stewardship required by a 1998 Settlement Agreement.

None

1999-10-01T23:59:59.000Z

337

Options for improving hazardous waste cleanups using risk-based criteria  

SciTech Connect (OSTI)

This paper explores how risk- and technology-based criteria are currently used in the RCRA and CERCLA cleanup programs. It identifies ways in which risk could be further incorporated into RCRA and CERCLA cleanup requirements and the implications of risk-based approaches. The more universal use of risk assessment as embodied in the risk communication and risk improvement bills before Congress is not addressed. Incorporating risk into the laws and regulations governing hazardous waste cleanup, will allow the use of the best scientific information available to further the goal of environmental protection in the United States while containing costs. and may help set an example for other countries that may be developing cleanup programs, thereby contributing to enhanced global environmental management.

Elcock, D.

1995-06-01T23:59:59.000Z

338

EM’s December Newsletter Recaps Cold War Cleanup Accomplishments in 2013  

Broader source: Energy.gov [DOE]

On Dec. 19, EM completed demolition of the 4.8 million-square-foot Building K-25 at Oak Ridge, a milestone that capped a busy and successful 2013 for the Cold War cleanup program.

339

E-Print Network 3.0 - accident clean-up workers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 UNIVERSITY OF SOUTH CAROLINA CHEMICAL SPILL CLEAN-UP PROCEDURES Summary: workers are neither expected, nor allowed, to clean up chemical spills...

340

EA-1345: Cleanup and Closure of the Energy Technology Engineering Center  

Broader source: Energy.gov [DOE]

DOE prepared an EA and finding of no significant impact (FONSI) for cleanup and closure of DOE’s Energy Technology Engineering Center at the Santa Susana Field Laboratory in 2003. However, DOE’s...

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
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341

E-Print Network 3.0 - alternate soil clean-up Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3... . The coatings could also be used in clean-up procedures for .ion- radioactive pollutants. 5. Acknowledgments... T>*0>JOOo3>2> Riso M-2912 M The Characterization and Removal...

342

Time series study of urban rainfall suppression during clean-up periods  

E-Print Network [OSTI]

The effect on urban rainfall of pollution aerosols is studied both by data analysis and computational simulation. Our study examines data for urban areas undergoing decadal clean-up. We compare the annual precipitation between polluted sites...

Geng, Jun

2009-05-15T23:59:59.000Z

343

Time series study of urban rainfall suppression during clean-up periods  

E-Print Network [OSTI]

The effect on urban rainfall of pollution aerosols is studied both by data analysis and computational simulation. Our study examines data for urban areas undergoing decadal clean-up. We compare the annual precipitation between polluted sites...

Geng, Jun

2008-10-10T23:59:59.000Z

344

Active-to-Passive Environmental Cleanup Transition Strategies - 13220  

SciTech Connect (OSTI)

The Savannah River Site uses a graded approach to environmental cleanup. The selection of groundwater and vadose zone remediation technologies for a specific contamination area is based on the size, contaminant type, contaminant concentration, and configuration of the plume. These attributes are the result of the nature and mass of the source of contamination and the subsurface characteristics in the area of the plume. Many large plumes consist of several zones that are most efficiently addressed with separate complementary corrective action/remedial technologies. The highest concentrations of contaminants are found in the source zone. The most robust, high mass removal technologies are often best suited for remediation of the source zone. In the primary plume zone, active remedies, such as pump-and-treat, may be necessary to remove contaminants and exert hydraulic control of the plume. In the dilute fringe zone, contaminants are generally lower in concentration and can often be treated with passive techniques. A key determination in achieving an acceptable and cost-effective end state for a given waste unit is when to transition from an active treatment system to a more passive or natural approach (e.g., monitored natural attenuation or enhanced attenuation). This paper will discuss the considerations for such a transition as well as provide examples of successful transitions at the Savannah River Site. (authors)

Gaughan, Thomas F. [Savannah River Nuclear Solutions, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River Nuclear Solutions, Savannah River Site, Aiken, SC 29808 (United States); Aylward, Robert S.; Denham, Miles E.; Looney, Brian B. [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States); Whitaker, Wade C. [Department of Energy - Savannah River, Savannah River Site, Aiken, SC 29808 (United States)] [Department of Energy - Savannah River, Savannah River Site, Aiken, SC 29808 (United States); Mills, Gary L. [Savannah River Ecology Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River Ecology Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

345

Cyclic carbonation calcination studies of limestone and dolomite for CO{sub 2} separation from combustion flue gases - article no. 011801  

SciTech Connect (OSTI)

Naturally occurring limestone and dolomite samples, originating from different geographical locations, were tested as potential sorbents for carbonation/calcination based CO{sub 2} capture from combustion flue gases. Samples have been studied in a thermogravimetric analyzer under simulated flue gas conditions at three calcination temperatures, viz., 750{sup o}C, 875{sup o}C, and 930{sup o}C for four carbonation calcination reaction (CCR) cycles. The dolomite sample exhibited the highest rate of carbonation than the tested limestones. At the third cycle, its CO{sub 2} capture capacity per kilogram of the sample was nearly equal to that of Gotland, the highest reacting limestone tested. At the fourth cycle it surpassed Gotland, despite the fact that the CaCO{sub 3} content of the Sibbo dolomite was only 2/3 of that of the Gotland. Decay coefficients were calculated by a curve fitting exercise and its value is lowest for the Sibbo dolomite. That means, most probably its capture capacity per kilogram of the sample would remain higher well beyond the fourth cycle. There was a strong correlation between the calcination temperature, the specific surface area of the calcined samples, and the degree of carbonation. It was observed that the higher the calcination temperature, the lower the sorbent reactivity. For a given limestone/dolomite sample, sorbents CO{sub 2} capture capacity depended on the number of CCR cycles and the calcination temperature. According to the equilibrium thermodynamics, the CO{sub 2} partial pressure in the calciner should be lowered to lower the calcination temperature. This can be achieved by additional steam supply into the calciner. Steam could then be condensed in an external condenser to single out the CO{sub 2} stream from the exit gas mixture of the calciner. A calciner design based on this concept is illustrated.

Senthoorselvan, S.; Gleis, S.; Hartmut, S.; Yrjas, P.; Hupa, M. [TUM, Garching (Germany)

2009-01-15T23:59:59.000Z

346

PROGRESS & CHALLENGES IN CLEANUP OF HANFORDS TANK WASTES  

SciTech Connect (OSTI)

The River Protection Project (RPP), which is managed by the Department of Energy (DOE) Office of River Protection (ORP), is highly complex from technical, regulatory, legal, political, and logistical perspectives and is the largest ongoing environmental cleanup project in the world. Over the past three years, ORP has made significant advances in its planning and execution of the cleanup of the Hartford tank wastes. The 149 single-shell tanks (SSTs), 28 double-shell tanks (DSTs), and 60 miscellaneous underground storage tanks (MUSTs) at Hanford contain approximately 200,000 m{sup 3} (53 million gallons) of mixed radioactive wastes, some of which dates back to the first days of the Manhattan Project. The plan for treating and disposing of the waste stored in large underground tanks is to: (1) retrieve the waste, (2) treat the waste to separate it into high-level (sludge) and low-activity (supernatant) fractions, (3) remove key radionuclides (e.g., Cs-137, Sr-90, actinides) from the low-activity fraction to the maximum extent technically and economically practical, (4) immobilize both the high-level and low-activity waste fractions by vitrification, (5) interim store the high-level waste fraction for ultimate disposal off-site at the federal HLW repository, (6) dispose the low-activity fraction on-site in the Integrated Disposal Facility (IDF), and (7) close the waste management areas consisting of tanks, ancillary equipment, soils, and facilities. Design and construction of the Waste Treatment and Immobilization Plant (WTP), the cornerstone of the RPP, has progressed substantially despite challenges arising from new seismic information for the WTP site. We have looked closely at the waste and aligned our treatment and disposal approaches with the waste characteristics. For example, approximately 11,000 m{sup 3} (2-3 million gallons) of metal sludges in twenty tanks were not created during spent nuclear fuel reprocessing and have low fission product concentrations. We plan to treat these wastes as transuranic waste (TRU) for disposal at the Waste Isolation Pilot Plant (WIPP), which will reduce the WTP system processing time by three years. We are also developing and testing bulk vitrification as a technology to supplement the WTP LAW vitrification facility for immobilizing the massive volume of LAW. We will conduct a full-scale demonstration of the Demonstration Bulk Vitrification System by immobilizing up to 1,100 m{sup 3} (300,000 gallons) of tank S-109 low-curie soluble waste from which Cs-137 had previously been removed. This past year has been marked by both progress and new challenges. The focus of our tank farm work has been retrieving waste from the old single-shell tanks (SSTs). We have completed waste retrieval from three SSTs and are conducting retrieval operations on an additional three SSTs. While most waste retrievals have gone about as expected, we have faced challenges with some recalcitrant tank heel wastes that required enhanced approaches. Those enhanced approaches ranged from oxalic acid additions to deploying a remote high-pressure water lance. As with all large, long-term projects that employ first of a kind technologies, we continue to be challenged to control costs and maintain schedule. However, it is most important to work safely and to provide facilities that will do the job they are intended to do.

HEWITT, W.M.; SCHEPENS, R.

2006-01-23T23:59:59.000Z

347

Cleanup under Airlock of an Old Uranium Foundry - 13273  

SciTech Connect (OSTI)

Since 2004, AREVA's subsidiary SICN has been conducting the cleanup and dismantling of an old uranium foundry located in the town of Annecy (France). The first operations consisted in the removal of the foundry's production equipment, producing more than 300 metric tons (MT) of waste. The second step consisted in performing the radiological characterization of the 1,600 m{sup 2} (17,200 ft{sup 2}) building, including underground trenches and galleries. The building was precisely inventoried, based on operations records and direct measurements. All sub-surfaces, which needed to be cleaned up were characterized, and a determination of the contamination migration was established, in particular with trenches and galleries. The wall thicknesses to be treated were empirically justified, knowing that the maximal migration depth inside concrete is 5 mm for a liquid transfer vector. All singularities such as cracks, anchoring points, etc. were spotted for a complete and systematic treatment. Building structures not laying directly on the soil, such as floor slabs, were not cleaned up but directly deconstructed and disposed of as waste. The facility was located within the town of Annecy. Therefore, in order to avoid the risk of dusts dispersion and public exposure during the building deconstruction and the soil treatment, a third of the building's surface was confined in a sliding airlock built from a metal structure capable of resisting to wind and snow, which are frequent in this area. This particular structure provided a static confinement over the half of the building which was covered and a dynamic confinement using a ventilation and high efficiency air filtration system, sized to provide 2.5 air changes per hour. The enclosure and its metallic structure is 33 m long (108 feet), 25 m wide (82 feet), and 13 m high (42 feet), for a volume of 10,000 m{sup 3} (353,000 ft{sup 3}). It was made up of a double skin envelope, allowing the recycling of its structure and outside envelope. After cleaning up and dismantling the first portion of the building, the enclosure was repositioned on the second and the last third of the building, by sliding it on support pads. Almost 7,000 m{sup 2} of concrete surface has been treated with no dust dispersion outside the enclosure. After treatment, all the remaining surfaces were controlled by an independent entity to verify their acceptability with regards to residual contamination (less than 0.4 Bq/cm{sup 2} (24 DPM) for alpha contamination and less than 1 Bq/g of total uranium). Approximately 1,900 MT of equipment and waste were generated in batches of 1m{sup 3}, in order to be staged on site, and then characterized and packaged in 20 foot containers for shipment to the final ANDRA repository. The package certification included the verification of the physical and chemical characteristics and the radiological characteristics (mass activity, dose rate, and residual outside surface contamination). Finally, after cleanup and dismantling of the foundry, a concrete slab was poured on the free surface as a clean base for implementation of new activities. (authors)

Thuillier, Daniel; Houee, Jean-Marie [AREVA D and D BU, Paris La Defense (France)] [AREVA D and D BU, Paris La Defense (France); Chambon, Frederic [AREVA FEDERAL SERVICES, Columbia MD (United States)] [AREVA FEDERAL SERVICES, Columbia MD (United States)

2013-07-01T23:59:59.000Z

348

North Slope (Wahluke Slope) expedited response action cleanup plan  

SciTech Connect (OSTI)

The purpose of this action is to mitigate any threat to public health and the environment from hazards on the North Slope and meet the expedited response action (ERA) objective of cleanup to a degree requiring no further action. The ERA may be the final remediation of the 100-I-3 Operable Unit. A No Action record of decision (ROD) may be issued after remediation completion. The US Department of Energy (DOE) currently owns or administers approximately 140 mi{sup 2} (about 90,000 acres) of land north and east of the Columbia River (referred to as the North Slope) that is part of the Hanford Site. The North Slope, also commonly known as the Wahluke Slope, was not used for plutonium production or support facilities; it was used for military air defense of the Hanford Site and vicinity. The North Slope contained seven antiaircraft gun emplacements and three Nike-Ajax missile positions. These military positions were vacated in 1960--1961 as the defense requirements at Hanford changed. They were demolished in 1974. Prior to government control in 1943, the North Slope was homesteaded. Since the initiation of this ERA in the summer of 1992, DOE signed the modified Hanford Federal Agreement and Consent Order (Tri-Party Agreement) with the Washington Department of Ecology (Ecology) and the US Environmental Protection Agency (EPA), in which a milestone was set to complete remediation activities and a draft closeout report by October 1994. Remediation activities will make the North Slope area available for future non-DOE uses. Thirty-nine sites have undergone limited characterization to determine if significant environmental hazards exist. This plan documents the results of that characterization and evaluates the potential remediation alternatives.

Not Available

1994-02-01T23:59:59.000Z

349

Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions  

SciTech Connect (OSTI)

A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high pH and temperatures.

Lee, Joo-Youp

2013-09-30T23:59:59.000Z

350

An Act Relative to Environmental Cleanup and Promoting the Redevelopment of Contaminated Property- The “Brownfields” Act (Massachusetts)  

Broader source: Energy.gov [DOE]

The Commonwealth of Massachusetts provides liability relief and financial incentives aimed to encourage cleanup and redevelopment of contaminated sites. Financial incentives include encouraging...

351

Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures  

E-Print Network [OSTI]

Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

Couling, David Joseph

2012-01-01T23:59:59.000Z

352

Short Communications FID gas chromatogram from LC-GC clean-up and analysis of the  

E-Print Network [OSTI]

) as a result of entry of air into the ion source through the leaking press-fit connection Such problems were of the glued press-fit connection.:` was tested by use of an HPLC pump delivering pentane as mobile phase. A short piece (ca 0.5m) of 0.25mm i.d.fused silica tubing was glued into a press-fit connector which had

Zare, Richard N.

353

Development of ceramic membrane reactors for high temperature gas cleanup. Final report  

SciTech Connect (OSTI)

The objective of this project was to develop high temperature, high pressure catalytic ceramic membrane reactors and to demonstrate the feasibility of using these membrane reactors to control gaseous contaminants (hydrogen sulfide and ammonia) in integrated gasification combined cycle (IGCC) systems. Our strategy was to first develop catalysts and membranes suitable for the IGCC application and then combine these two components as a complete membrane reactor system. We also developed a computer model of the membrane reactor and used it, along with experimental data, to perform an economic analysis of the IGCC application. Our results have demonstrated the concept of using a membrane reactor to remove trace contaminants from an IGCC process. Experiments showed that NH{sub 3} decomposition efficiencies of 95% can be achieved. Our economic evaluation predicts ammonia decomposition costs of less than 1% of the total cost of electricity; improved membranes would give even higher conversions and lower costs.

Roberts, D.L.; Abraham, I.C.; Blum, Y.; Gottschlich, D.E.; Hirschon, A.; Way, J.D.; Collins, J.

1993-06-01T23:59:59.000Z

354

DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants |  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomentheATLANTA, GA - U.S. Departmentto DevelopMark Duff (LATA KY),

355

Preferential oxidation of methanol and carbon monoxide for gas cleanup during methanol fuel processing  

SciTech Connect (OSTI)

Methanol fuel processing generates hydrogen for low-temperature, PEM fuel cell systems now being considered for transportation and other applications. Although liquid methanol fuel is convenient for this application, existing fuel processing techniques generate contaminants that degrade fuel cell performance. Through mathematical models and laboratory experiments chemical processing is described that removes CO and other contaminants from the anode feed stream.

Birdsell, S.A.; Vanderborgh, N.E.; Inbody, M.A. [Los Alamos National Lab., NM (United States)

1993-07-01T23:59:59.000Z

356

Renewable Natural Gas Clean-up Challenges and Applications | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartmentnews-flashes

357

Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup  

E-Print Network [OSTI]

hydrocarbons mixture such as EPE (74.8% methane, 8% ethane, 8% ethylene, 2.1% propane and 1.1% Propene). Non-thermal plasmas, due to their unique non-equilibrium characteristics, offer advantages as method of reforming at lower temperature (100-150 ş...

Ming, Pingjia

2014-06-05T23:59:59.000Z

358

Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site. Final [report  

SciTech Connect (OSTI)

Surface and subsurface soil cleanup protocols for the Gunnison, Colorado, processing sits are summarized as follows: In accordance with EPA-promulgated land cleanup standards (40 CFR 192), in situ Ra-226 is to be cleaned up based on bulk concentrations not exceeding 5 and 15 pCi/g in 15-cm surface and subsurface depth increments, averaged over 100-m{sup 2} grid blocks, where the parent Ra-226 concentrations are greater than, or in secular equilibrium with, the Th-230 parent. A bulk interpretation of these EPA standards has been accepted by the Nuclear Regulatory Commission (NRC), and while the concentration of the finer-sized soil fraction less than a No. 4 mesh sieve contains the higher concentration of radioactivity, the bulk approach in effect integrates the total sample radioactivity over the entire sample mass. In locations where Th-230 has differentially migrated in subsoil relative to Ra-226, a Th-230 cleanup protocol has been developed in accordance with Supplemental Standard provisions of 40 CFR 192 for NRC/Colorado Department of Health (CDH) approval for timely implementation. Detailed elements of the protocol are contained in Appendix A, Generic Protocol from Thorium-230 Cleanup/Verification at UMTRA Project Processing Sites. The cleanup of other radionuclides or nonradiological hazards that pose a significant threat to the public and the environment will be determined and implemented in accordance with pathway analysis to assess impacts and the implications of ALARA specified in 40 CFR 192 relative to supplemental standards.

Not Available

1993-09-01T23:59:59.000Z

359

Sectored Clean-up Work Plan for Housekeeping Category Waste Sites  

SciTech Connect (OSTI)

The Sectored Clean-up Work Plan (SCWP) replaces the Housekeeping Category Corrective Action Unit Work Plan and provides a strategy to be used for conducting housekeeping activities using a sectored clean-up approach. This work plan provides a process by which one or more existing housekeeping category Corrective Action Sites (CASS) from the Federal Facility Agreement and Consent Order and/or non-FFACO designated waste site(s) are grouped into a sector for simultaneous remediation and cleanup. This increases effectiveness and efficiencies in labor, materials, equipment, cost, and time. This plan is an effort by the U.S. Department of Energy to expedite work in a more organized and efficient approach. The objectives of this plan are to: Group housekeeping FFACO CASS and non-FFACO housekeeping sites into sectors and remediate during the same field visit; Provide consistent documentation on FFACO CAS and non-FFACO clean-up activities; Perform similar activities under one approved document; Remediate areas inside the Deactivation and Decommissioning facilities and compounds in a campaign-style remediation; and Increase efficiencies and cost-effectiveness, accelerate cleanups, reduce mobilization, demobilization, and remediation costs.

S. J. Nacht

2000-02-01T23:59:59.000Z

360

2020 Vision for Tank Waste Cleanup (One System Integration) - 12506  

SciTech Connect (OSTI)

The mission of the Department of Energy's Office of River Protection (ORP) is to safely retrieve and treat the 56 million gallons of Hanford's tank waste and close the Tank Farms to protect the Columbia River. The millions of gallons of waste are a by-product of decades of plutonium production. After irradiated fuel rods were taken from the nuclear reactors to the processing facilities at Hanford they were exposed to a series of chemicals designed to dissolve away the rod, which enabled workers to retrieve the plutonium. Once those chemicals were exposed to the fuel rods they became radioactive and extremely hot. They also couldn't be used in this process more than once. Because the chemicals are caustic and extremely hazardous to humans and the environment, underground storage tanks were built to hold these chemicals until a more permanent solution could be found. The Cleanup of Hanford's 56 million gallons of radioactive and chemical waste stored in 177 large underground tanks represents the Department's largest and most complex environmental remediation project. Sixty percent by volume of the nation's high-level radioactive waste is stored in the underground tanks grouped into 18 'tank farms' on Hanford's central plateau. Hanford's mission to safely remove, treat and dispose of this waste includes the construction of a first-of-its-kind Waste Treatment Plant (WTP), ongoing retrieval of waste from single-shell tanks, and building or upgrading the waste feed delivery infrastructure that will deliver the waste to and support operations of the WTP beginning in 2019. Our discussion of the 2020 Vision for Hanford tank waste cleanup will address the significant progress made to date and ongoing activities to manage the operations of the tank farms and WTP as a single system capable of retrieving, delivering, treating and disposing Hanford's tank waste. The initiation of hot operations and subsequent full operations of the WTP are not only dependent upon the successful design and construction of the WTP, but also on appropriately preparing the tank farms and waste feed delivery infrastructure to reliably and consistently deliver waste feed to the WTP for many decades. The key components of the 2020 vision are: all WTP facilities are commissioned, turned-over and operational, achieving the earliest possible hot operations of completed WTP facilities, and supplying low-activity waste (LAW) feed directly to the LAW Facility using in-tank/near tank supplemental treatment technologies. A One System Integrated Project Team (IPT) was recently formed to focus on developing and executing the programs that will be critical to successful waste feed delivery and WTP startup. The team is comprised of members from Bechtel National, Inc. (BNI), Washington River Protection Solutions LLC (WRPS), and DOE-ORP and DOE-WTP. The IPT will combine WTP and WRPS capabilities in a mission-focused model that is clearly defined, empowered and cost efficient. The genesis for this new team and much of the 2020 vision is based on the work of an earlier team that was tasked with identifying the optimum approach to startup, commissioning, and turnover of WTP facilities for operations. This team worked backwards from 2020 - a date when the project will be completed and steady-state operations will be underway - and identified success criteria to achieving safe and efficient operations of the WTP. The team was not constrained by any existing contract work scope, labor, or funding parameters. Several essential strategies were identified to effectively realize the one-system model of integrated feed stream delivery, WTP operations, and product delivery, and to accomplish the team's vision of hot operations beginning in 2016: - Use a phased startup and turnover approach that will allow WTP facilities to be transitioned to an operational state on as short a timeline as credible. - Align Tank Farm (TF) and WTP objectives such that feed can be supplied to the WTP when it is required for hot operations. - Ensure immobilized waste and waste recycle streams can be recei

Harp, Benton; Charboneau, Stacy; Olds, Erik [US DOE (United States)

2012-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Studies of Plutonium Aerosol Resuspension at the Time of the Maralinga Cleanup  

SciTech Connect (OSTI)

At the former nuclear test site at Maralinga, South Australia, soil cleanup began in October 1996 with the objective to remove the potential for residual plutonium (Pu) exposures to the public. In this case the cleanup was to restore access to the closed test site. The proposed long-term land use was primarily to be a hunting area for Pitjantjatjara (Aboriginal) people, but also presumably to be available to the public who might have an interest in the history of the site. The long-term management objective for the site was to allow casual use, but to prohibit habitation. The goal of this study is to provide an evaluation of the Maralinga soil cleanup in terms of potential long-term public inhalation exposures to particulate Pu, and in terms of a contribution to planning and conducting any such soil Pu-cleanup. Such cleanups might be carried out for example, on the Nevada Test Site in the United States. For Pu that has been deposited on the soil by atmospheric sources of finely divided particles, the dominant exposure pathway to humans is by inhalation. Other exposure pathways are less important because the Pu particles become oxidized into a nearly insoluble form, do not easily enter into the food chain, nor are they significantly transferred through the intestine to the bloodstream should Pu become ingested. The purpose of this report is to provide results of the Pu resuspension measurements made before, during, and after the Pu cleanup at Maralinga, to compare these against similar measurements made elsewhere, and to interpret the results as they relate to potential long-term public exposures. (Exposures to Pu in dust plumes produced by mechanical disturbance during cleanup are considered short-term, unlikely to be significant for purposes of this report, and are not included). A considerable amount of research had been conducted at Maralinga by the Australian Radiation Laboratory, now the Australian Radiation Protection and Nuclear Safety Agency (ARPANSA), prior to the cleanup (Johnston et al, 1992, Williams 1993, Johnston et al 1993, Burns et al 1994, Burns et al 1995). ARPANSA staff made major contributions to delineate the areas with Pu in the soil, to determine the degree of secondary soil contamination by fission products from nuclear testing, to measure Pu resuspension by wind erosion of the undisturbed soil, and to prepare assessments of the human health risk from residual soil Pu. In addition, ARPANSA supported the Maralinga cleanup to assure compliance with criteria set by an independent technical advisory committee. During the cleanup ARPANSA monitored the residual Pu in the soil and certified that the cleanup was complete according to the criteria. It was not the reduction in potential inhalation exposure that usually was the main driver of the cleanup, but the requirement to also remove individual hot particles and fragments. It is the residual microscopic particles of Pu in the soil, however, that have the potential for long-term human exposure. The resuspension of respirable-size Pu particles has been studied with specialized equipment at the Nevada Test Site (Gilbert et al 1988a, Gilbert et al 1988b, Shinn et al 1989, and Shinn 1992), and at Bikini and Enewetak in the Marshall Islands (Shinn et al 1997). These efforts were in large part contributed by the Health and Ecological Assessment Division, University of California, Lawrence Livermore National Laboratory (LLNL). The study reported here is a collaboration between ARPANSA and LLNL, and was jointly supported by the United States Department of Energy, and the Commonwealth of Australia Department of Primary Industry and Energy.

Shinn, J

2003-08-01T23:59:59.000Z

362

Hanford Site Cleanup Challenges and Opportunities for Science and Technology--A Strategic Assessment  

SciTech Connect (OSTI)

The sheer expanse of the Hanford Site, the inherent hazards associated with the significant inventory of nuclear materials and wastes, the large number of aging contaminated facilities, the diverse nature and extent of environmental contamination, and the proximity to the Columbia River make Hanford perhaps the world's largest and most complex environmental cleanup project. It is not possible to address the more complex elements of this enormous challenge in a cost-effective manner without strategic investments in science and technology. Success requires vigorous and sustained efforts to enhance the science and technology basis, develop and deploy innovative solutions, and provide firm scientific bases to support site cleanup and closure decisions at Hanford.

Wood, Thomas W.; Johnson, Wayne L.; Kreid, Dennis K.; Walton, Terry L.

2001-02-01T23:59:59.000Z

363

``How clean is clean`` in the United States federal and Washington State cleanup regulations  

SciTech Connect (OSTI)

The enactment of legislation and promulgation of implementing regulations generally involves the resolution of conflicting goals. Defining ``How Clean is Clean?`` in federal and state cleanup laws, regulations, and policies is no exception. Answering the ``How Clean is Clean?`` question has resulted in the identification of some important and sometimes conflicting goals. Continuing resolution of the following conflicting goals is the key to effect cleanup of hazardous waste sites: Expediency vs. Fairness; Flexibility vs. Consistency; Risk Reduction vs. Risk Causation; and Permanence vs. Cost Effectiveness.

Landau, H.G. [Landau Associates, Inc., Edmonds, WA (United States)

1993-12-31T23:59:59.000Z

364

The production of activated silica with carbon dioxide gas  

E-Print Network [OSTI]

Ional to the per cent of carbon dioxi. de 1n the flue gas for a constant total gas flow rate. REFE REN CES l. Andrews, R. V, , Hanford Works Eocument (1952), 2. Andrews, R. V. & J. A. W. W. A, , ~46 82 (1954). 3. Andrews, R. V, , Personal Communication 4... of the reciuire . ents for the dedree of iliASTER OF SCIENCE Janus', 1956 Major Subject: Chemi. cal Engineering TH PRODUCTION OP ACTIVATED SILICA 7iIITH CARBON DIOXIDE GAS A Thesis William Bell Hayes III Approved as to style and content by: Chairmen...

Hayes, William Bell

1956-01-01T23:59:59.000Z

365

DECOMMISSIONING AND ENVRIONMENTAL CLEANUP OF SMALL ARMS TRAINING FACILITY  

SciTech Connect (OSTI)

USDOE performed a (CERCLA) non-time critical removal (NTCR) action at the Small Arms Training Area (SATA) Site Evaluation Area (SEA) located at the Savannah River Site (SRS), in Aiken, South Carolina. From 1951 to May 2010, the SATA was used as a small weapons practice and qualifying firing range. The SATA consisted of 870.1 ha (2,150 ac) of woodlands and open field, of which approximately 2.9 ha (7.3 ac) were used as a firing range. The SATA facility was comprised of three small arms ranges (one static and two interactive), storage buildings for supplies, a weapons cleaning building, and a control building. Additionally, a 113- m (370-ft) long earthen berm was used as a target backstop during live-fire exercises. The berm soils accumulated a large amount of spent lead bullets in the berm face during the facilities 59- years of operation. The accumulation of lead was such that soil concentrations exceeded the U.S. Environmental Protection Agency (USEPA) residential and industrial worker regional screening levels (RSLs). The RSL threshold values are based on standardized exposure scenarios that estimate contaminant concentrations in soil that the USEPA considers protective of humans over a lifetime. For the SATA facility, lead was present in soil at concentrations that exceed both the current residential (400 mg/kg) and industrial (800 mg/kg) RSLs. In addition, the concentration of lead in the soil exceeded the Toxicity Characteristic Leaching Procedure (TCLP) (40 Code of Federal Regulations [CFR] 261.24) regulatory limit. The TCLP analysis simulates landfill conditions and is designed to determine the mobility of contaminants in waste. In addition, a principal threat source material (PTSM) evaluation, human health risk assessment (HHRA), and contaminant migration (CM) analysis were conducted to evaluate soil contamination at the SATA SEA. This evaluation determined that there were no contaminants present that constitute PTSM and the CM analysis revealed that no constituents posed a migration risk to groundwater. The NTCR action involved removal of approximately 12,092 m3 (15,816 yd3) of spent bullets and lead-impacted soil and off-site disposal. The removal action included soils from the berm area, a fill area that received scraped soils from the berm, and soil from a drainage ditch located on the edge of the berm area. Also included in the removal action was a mixture of soil, concrete, and asphalt from the other three range areas. Under this action, 11,796 m3 (15,429 yd3) of hazardous waste and impacted soil were removed from the SATA and transported to a permitted hazardous waste disposal facility (Lone Mountain Facility in Oklahoma) and 296 m3 (387 yd3) of nonhazardous waste (primarily concrete debris) were removed and transported to a local solid waste landfill for disposal. During the excavation process, the extent was continuously assessed through the use of a hand-held, field-portable X-ray fluorescence unit with results verified using confirmation sampling with certified laboratory analysis. Following the completion of the excavation and confirmation sampling, final contouring, grading, and establishment of vegetative cover was performed to stabilize the affected areas. The NTCR action began on August 17, 2010, and mechanical completion was achieved on April 27, 2011. The selected removal action met the removal action objectives (RAOs), is protective of human health and the environment both in the short- and long-term, was successful in removing potential ecological risks, and is protective of surface water and groundwater. Furthermore, the selected NTCR action met residential cleanup goals and resulted in the release of the SEA from restricted use contributing to the overall footprint reduction at SRS.

Kmetz, T.

2012-12-04T23:59:59.000Z

366

Gas Separations using Ceramic Membranes  

SciTech Connect (OSTI)

This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

Paul KT Liu

2005-01-13T23:59:59.000Z

367

Guardian Unlimited | The Guardian | Scientists see big role for uranium clean-up bug Sign in Register  

E-Print Network [OSTI]

Guardian Unlimited | The Guardian | Scientists see big role for uranium clean-up bug Sign big role for uranium clean-up bug Alok Jha, science correspondent Friday December 12, 2003 The Guardian Scientists have sequenced the DNA of a bacterium which can help to remove uranium from

Lovley, Derek

368

Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems: Greenfield assessment. Final report  

SciTech Connect (OSTI)

Both the KRW fluidized-bed gasifier and the transport gasifier case studies were used for this assessment. The transport technology is a high-velocity circulating fluidized-bed reactor currently under development by The M.W. Kellogg Company. In the earlier assessment, seven design concepts or cases were identified; a process design was developed; major equipment items were identified; estimates of capital cost, operation and maintenance cost, and cost of electricity were developed; reliability was predicted; and development issues were identified for six studies. Three of the most probable cases were further evaluated for a Greenfield assessment in this report to adequately determine all costs independent of facilities at Plant Wansley.

Not Available

1991-12-01T23:59:59.000Z

369

US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems  

SciTech Connect (OSTI)

The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

Dennis, R.A.

1997-05-01T23:59:59.000Z

370

Cleanup Verification Package for the 100-F-20, Pacific Northwest Laboratory Parallel Pits  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 100-F-20, Pacific Northwest Laboratory Parallel Pits waste site. This waste site consisted of two earthen trenches thought to have received both radioactive and nonradioactive material related to the 100-F Experimental Animal Farm.

M. J. Appel

2007-01-22T23:59:59.000Z

371

CHEAP CLEAN-UP PROTOCOL To clean BigDye reactions  

E-Print Network [OSTI]

CHEAP CLEAN-UP PROTOCOL To clean BigDye reactions: 1. Combine and mix MgCl2/ethanol cocktail. 2. Air dry on a Kimwipe or pulse spin upside down. MgCl2/ethanol 1 µL 0.5M MgCl2 1000 µL 70% ethanol

Russell, Amy L.

372

Idaho Site’s Cold War Cleanup Takes Center Stage in Publication  

Broader source: Energy.gov [DOE]

IDAHO FALLS, Idaho – An association with more than 29,000 members featured an in-depth article on EM’s extensive Cold War legacy cleanup at the Idaho site in the current issue of its publication, The Military Engineer.

373

EA-1867: Scale-up of High-Temperature Syngas Cleanup Technology, Polk County, Florida  

Broader source: Energy.gov [DOE]

This EA evaluates the environmental impacts of a proposal to provide cost-shared funding to RTI International (RTI) for its proposed project to demonstrate the precommercial scale-up of RTI’s high-temperature syngas cleanup and carbon capture and sequestration technologies.

374

Roundtable on Long-Term Management In The Cleanup of Contaminated Sites  

SciTech Connect (OSTI)

The Center for Public Environmental Oversight (CPEO) convened a roundtable in Washington, DC on June 28, 2002 to discuss innovative approaches to long-term management in the cleanup of contaminated property. Twenty participants attended the meeting, including representatives of federal agencies, local government, state regulatory agencies, environmental organizations, and thinking tanks, as well as private consultants with experience in site remediation and redevelopment.

Aimee Houghton

2002-06-28T23:59:59.000Z

375

Radiation protection and decision-making on cleanup of contaminated urban environments  

E-Print Network [OSTI]

--4000 Roskilde,4000 Roskilde, DenmarkDenmark NKS Conference on Radioactive Contamination in Urban Areas-making NKS Conference on Radioactive Contamination in Urban Areas, Risø National Laboratory, 7 - 9 May 2003Justification of cleanup NKS Conference on Radioactive Contamination in Urban Areas, Risø National Laboratory, 7 - 9 May

376

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M Sulloway

2007-10-31T23:59:59.000Z

377

Cleanup Verification Package for the 126-F-1, 184-F Powerhouse Ash Pit  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 126-F-1, 184-F Powerhouse Ash Pit. This waste site received coal ash from the 100-F Area coal-fired steam plant. Leakage of process effluent from the 116-F-14 , 107-F Retention Basins flowed south into the ash pit, contaminating the northern portion.

S. W. Clark and H. M. Sulloway

2007-09-26T23:59:59.000Z

378

Cleanup Verification Package for the 118-C-1, 105-C Solid Waste Burial Ground  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action for the 118-C-1, 105-C Solid Waste Burial Ground. This waste site was the primary burial ground for general wastes from the operation of the 105-C Reactor and received process tubes, aluminum fuel spacers, control rods, reactor hardware, spent nuclear fuel and soft wastes.

M. J. Appel and J. M. Capron

2007-07-25T23:59:59.000Z

379

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Course contentCourse content  

E-Print Network [OSTI]

- firedPulverised coal- fired power plantpower plant #12;HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Pulverised coal combustion and gas clean-upPulverised coal combustion and gas clean-up #12;HELSINKIHELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 ·· Course contentCourse content ·· Flue gases and fuel

Zevenhoven, Ron

380

Cesium and heavy metal removal from flue dusts and other matrices  

SciTech Connect (OSTI)

A problem exists in the steel industry because of the generation of radioactive waste that is caused by the accidental destruction of nuclear detection instruments. The flue dust from electric Arc Furnaces (EAF) becomes contaminated with the radionuclide used. Typically the radionuclide is cesium 137. The problem is a concern to the industry since the contamination results in the generation of a mixed waste which is costly to dispose of properly. In the interest of providing a viable solution to the problem, Lockheed Environmental Systems and Technologies has developed a process for removal of cesium from flue dust. While removing the cesium from the treatment residue, the process also isolates the other major elements of concern and renders them innocuous, saleable, or readily disposable. However, several innovative techniques have been applied which make the process far more economical, and in addition, the changes simplify the operation and render it controllable. The process involves the dissolution of the various metallic and non-metallic constituents through the use of a mild mineral acid leach. This treatment solubilizes the majority of the constituents including the cesium.

Soderstrom, D.J.; May, R.; Spaulding, S. [Lockheed Environmental Systems and Technologies Co., Las Vegas, NV (United States). Technology Applications Div.

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course  

SciTech Connect (OSTI)

The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

Dennis Laudal

2008-09-30T23:59:59.000Z

382

On-line microdialysis sample cleanup for electrospray ionization mass spectrometry of nucleic acid samples  

SciTech Connect (OSTI)

A major limitation of electrospray ionization mass spectrometry (ESI-MS) for oligonucleotide analysis arises due to sodium adduction, a problem that increases with molecular weight. Sodium adduction can preclude useful measurements when limited sample sizes prevent off-line cleanup. A novel and generally useful on-line microdialysis technique is described for the rapid (nearly 1-5 min) DNA sample cleanup for ESI-MS. Mass spectra of oligonucleotides of different size and sequence showing no significant sodium adduct peaks were obtained using the on-line microdialysis system with sodium chloride concentrations as high as 250 mM. Signal-to-noise ratios were also greatly enhanced compared to direct infusion of the original samples. By using ammonium acetate as the dialysis buffer, it was also found that the noncovalent association of double-stranded oligonucleotides could be preserved during the microdialysis process, allowing analysis by ESI-MS. 33 refs., 6 figs.

Liu, C.; Wu, Q.; Harms, A.C.; Smith, R.D. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States)

1996-09-15T23:59:59.000Z

383

The Use of the Hanford Onsite Packaging and Transportation Safety Program to Meet Cleanup Milestones Under the Hanford Site Cleanup 2015 Vision and the American Recovery and Reinvestment Act of 2009 - 12403  

SciTech Connect (OSTI)

The Hanford Site presents unique challenges in meeting the U.S. Department of Energy Richland Operations Office (DOE-RL) 2015 Cleanup Vision. CH2M Hill Plateau Remediation Company (CHPRC), its subcontractors, and DOE-RL were challenged to retrieve, transport and remediate a wide range of waste materials. Through a collaborative effort by all Hanford Onsite Central Plateau Cleanup Team Members, disposition pathways for diverse and seemingly impossible to ship wastes were developed under a DOE Order 460.1C-compliant Hanford Onsite Transportation Safety Program. The team determined an effective method for transporting oversized compliant waste payloads to processing and disposition facilities. The use of the onsite TSD packaging authorizations proved to be vital to safely transporting these materials for processing and eventual final disposition. The American Recovery and Reinvestment Act of 2009 (ARRA) provided additional resources to expedite planning and execution of these important cleanup milestones. Through the innovative and creative use of the TSD, the Hanford Onsite Central Plateau Cleanup Team Members have developed and are executing an integrated project plan that enables the safe and compliant transport of a wide variety of difficult-to-transport waste items, accelerating previous cleanup schedules to meet cleanup milestones. (authors)

Lavender, John C. [CH2M HILL Plateau Remediation Company, Richland, WA 99354 (United States); Edwards, W. Scott [Areva Federal Services, Richland, WA 99354 (United States); Macbeth, Paul J.; Self, Richard J. [U.S. Department of Energy Richland Operations Office, Richland, WA 99352 (United States); West, Lori D. [Materials and Energy Corporation, Richland, WA 99354 (United States)

2012-07-01T23:59:59.000Z

384

Impacts of Motor Vehicle Operation on Water Quality in the United States - Clean-up Costs and Policies  

E-Print Network [OSTI]

and Squillace, P. J. (2005). MTBE and gasoline hydrocarbonsP. J. (2004). The risk of MTBE relative to other VOCs inEPA to Settle Santa Monica MTBE Cleanup Costs, Press release

Nixon, Hilary; Saphores, Jean-Daniel

2007-01-01T23:59:59.000Z

385

Cleanup Verification Package for the 118-B-1, 105-B Solid Waste Burial Ground  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action, sampling activities, and compliance criteria for the 118-B-1, 105-B Solid Waste Burial Ground. This waste site was the primary burial ground for general wastes from the operation of the 105-B Reactor and P-10 Tritium Separation Project and also received waste from the 105-N Reactor. The burial ground received reactor hardware, process piping and tubing, fuel spacers, glassware, electrical components, tritium process wastes, soft wastes and other miscellaneous debris.

J. M. Capron

2008-01-21T23:59:59.000Z

386

Systems engineering product description report for the Hanford Cleanup Mission: First issue  

SciTech Connect (OSTI)

This document describes the upper level physical and administrative (nonphysical) products that, when delivered, complete the Hanford Cleanup Mission. Development of product descriptions is a continuation of the Sitewide Systems Engineering work described in the Sitewide functional analysis, the architecture synthesis, and is consistent with guidance contained in the mission plan. This document provides a bridge between all three documents and the products required to complete the mission of cleaning up the Hanford Site.

Holmes, J.J.; Bailey, K.B. [Westinghouse Hanford Co., Richland, WA (United States); Collings, J.L.; Hubbard, A.B.; Niepke, T.M. [Science Applications International Corp. (United States)

1994-06-01T23:59:59.000Z

387

Cleanup Verification Package for the 118-F-8:4 Fuel Storage Basin West Side Adjacent and Side Slope Soils  

SciTech Connect (OSTI)

This cleanup verification package documents completion of remedial action, sampling activities, and compliance with cleanup criteria for the 118-F-8:4 Fuel Storage Basin West Side Adjacent and Side Slope Soils. The rectangular-shaped concrete basin on the south side of the 105-F Reactor building served as an underwater collection, storage, and transfer facility for irradiated fuel elements discharged from the reactor.

L. D. Habel

2008-03-18T23:59:59.000Z

388

Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site: Final. Revision 2  

SciTech Connect (OSTI)

Thorium 230 (Th-230) at the Gunnison, Colorado processing site will require remediation, however, a seasonally fluctuating groundwater table at the site significantly complicates conventional remedial action with respect to cleanup. Therefore, to effectively remediate the site with respect to Radium 226 (Ra-226) and Th-230, the following supplemental standard is proposed: In situ Ra-26 will be remediated to the EPA soil cleanup standards independent of groundwater considerations. In situ Th-230 concentrations will be remediated in the region above the encountered water table so the 1000-year projected Ra-226 concentration complies with the EPA soil cleanup concentration limits. If elevated Th-230 persists to the water table, an additional foot of excavation will be performed and the grid will be backfilled. Excavated grids will be backfilled to the final remedial action grade with clean cobbly soil. Final grid verification that is required below the water table will be performed by extracting and analyzing a single bulk soil sample with the bucket of a backhoe. Modeled surface radon flux values will be estimated and documented. A recommendation will be made that land records should be annotated to identify the presence of residual Th-230.

Not Available

1994-01-01T23:59:59.000Z

389

Improved gas tagging and cover gas combination for nuclear reactor  

DOE Patents [OSTI]

The invention discloses the use of stable isotopes of neon and argon, sealed as tags in different cladding nuclear fuel elements to be used in a liquid metal fast breeder reactor. Cladding failure allows fission gases and these tag isotopes to escape and to combine with the cover gas. The isotopes are Ne/sup 20/, Ne/sup 21/ and Ne/sup 22/ and Ar/sup 36/, Ar/sup 38/ and Ar/sup 40/, and the cover gas is He. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between 0 and -25/sup 0/C to remove the fission gases from the cover gas and tags, and the second or tag recovery system bed between -170 and -185/sup 0/C to isolate the tags from the cover gas. Spectrometric analysis is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be determined.

Gross, K.C.; Laug, M.T.

1983-09-26T23:59:59.000Z

390

Gas tagging and cover gas combination for nuclear reactor  

DOE Patents [OSTI]

The invention discloses the use of stable isotopes of neon and argon, that are grouped in preselected different ratios one to the other and are then sealed as tags in different cladded nuclear fuel elements to be used in a liquid metal fast breeder reactor. Failure of the cladding of any fuel element allows fission gases generated in the reaction and these tag isotopes to escape and to combine with the cover gas held in the reactor over the fuel elements. The isotopes specifically are Ne.sup.20, Ne.sup.21 and Ne.sup.22 of neon and Ar.sup.36, Ar.sup.38 and Ar.sup.40 of argon, and the cover gas is helium. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between approximately 0.degree. and -25.degree. C. operable to remove the fission gases from the cover gas and tags and the second or tag recovery system bed is held between approximately -170.degree. and -185.degree. C. operable to isolate the tags from the cover gas. Spectrometric analysis further is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be specifically determined.

Gross, Kenny C. (Lemont, IL); Laug, Matthew T. (Idaho Falls, ID)

1985-01-01T23:59:59.000Z

391

Engineering analysis of biomass gasifier product gas cleaning technology  

SciTech Connect (OSTI)

For biomass gasification to make a significant contribution to the energy picture in the next decade, emphasis must be placed on the generation of clean, pollutant-free gas products. This reports attempts to quantify levels of particulated, tars, oils, and various other pollutants generated by biomass gasifiers of all types. End uses for biomass gases and appropriate gas cleaning technologies are examined. Complete systems analysis is used to predit the performance of various gasifier/gas cleanup/end use combinations. Further research needs are identified. 128 refs., 20 figs., 19 tabs.

Baker, E.G.; Brown, M.D.; Moore, R.H.; Mudge, L.K.; Elliott, D.C.

1986-08-01T23:59:59.000Z

392

Methods developed for detecting hazardous elements in produced gas  

SciTech Connect (OSTI)

The Institute of Gas Technology, Des Plaines, Ill. has been developing sampling and analytical methods to detect in natural gas various trace constituents that may pose health, safety, or operational risks. The constituents of interest include paraffinic and aromatic hydrocarbons, H[sub 2]S, organic sulfur compounds, arsenic, mercury, radon, and others. Better sampling and analytical techniques for produced natural gas, similar to those developed by IGT for processed gas, will enhance producers and processors' abilities to monitor undesirable constituents in raw gas streams and improve their clean-up processes. The methods developed at IGT were modifications of air sampling and analytical methods that are commonly used for air toxic substances. These monitoring methods, when applied to natural gas, present special challenges because gas has a much more complex matrix than the air. Methods for the analysis of the following are discussed: arsenic, mercury, radon, sulfur compounds, hydrocarbons, and aromatics including BTEX and PAHs.

Chao, S.; Attari, A. (Inst. of Gas Technology, Des Plaines, IL (United States))

1995-01-16T23:59:59.000Z

393

Comparison of thermoelectric and permeation dryers for sulfur dioxide removal during sample conditioning of wet gas streams  

SciTech Connect (OSTI)

Flue gas conditioning for moisture removal is commonly performed for criteria pollutant measurements, in particular for extractive CEM systems at combustion sources. An implicit assumption is that conditioning systems specifically remove moisture without affecting pollutant and diluent concentrations. Gas conditioning is usually performed by passing the flue gas through a cold trap (Peltier or thermoelectric dryer) to remove moisture by condensation, which is subsequently extracted by a peristaltic pump. Many air pollutants are water-soluble and potentially susceptible to removal in a condensation dryer from gas interaction with liquid water. An alternative technology for gas conditioning is the permeation dryer, where the flue gas passes through a selectively permeable membrane for moisture removal. In this case water is transferred through the membrane while other pollutants are excluded, and the gas does not contact condensed liquid. Laboratory experiments were performed to measure the relative removal of a water-soluble pollutant (sulfur dioxide, SO{sub 2}) by the two conditioning techniques. A wet gas generating system was used to create hot, wet gas streams of known composition (15% and 30% moisture, balance nitrogen) and flow rate. Pre-heated SO{sub 2} was dynamically spiked into the wet stream using mass flow meters to achieve concentrations of 20, 50, and 100 ppm. The spiked gas was directed through a heated sample line to either a thermoelectric or a permeation conditioning system. Two gas analyzers (Western Research UV gas monitor, KVB/Analect FTIR spectrometer) were used to measure the SO{sub 2} concentration after conditioning. Both analytic methods demonstrated that SO{sub 2} is removed to a significantly greater extent by the thermoelectric dryer. These results have important implications for SO{sub 2} monitoring and emissions trading.

Dunder, T.A. [Entropy, Inc., Research Triangle Park, NC (United States). Research Div.; Leighty, D.A. [Perma Pure, Inc., Toms River, NJ (United States)

1997-12-31T23:59:59.000Z

394

The Estonian study of Chernobyl cleanup workers: I. Design and questionnaire data  

SciTech Connect (OSTI)

Nearly 2% of the male population of Estonia aged 20-39 years were sent to Chernobyl to assist in the cleanup activities after the reactor accident. A cohort of 4,833 cleanup workers was assembled based on multiple and independent sources of information. Information obtained from 3,704 responses to a detailed questionnaire indicated that 63% of the workers were sent to Chernobyl in 1986; 54% were of Estonian and 35% of Russian ethnicity; 72% were married, and 1,164 of their 5,392 children were conceived after the Chernobyl disaster. The workers were less educated than their counterparts than their counterparts in the general population of Estonia, and only 8.5% had attended university. Based on doses entered in workers records, the mean dose was 11 cGy, with only 1.4% over 25 cGy. Nearly 85% of the workers were sent as part of military training activities, and more than half spent in excess of 3 months in the Chernobyl area. Thirty-six percent of the workers reported having worked within the immediate vicinity of the accident site; 11.5% worked on the roofs near the damaged reactor, clearing the highly radioactive debris. The most commonly performed task was the removal and burial of topsoil (55% of the workers). Potassium iodide was given to over 18% of the men. The study design also incorporates biological indicators of exposure based on the glycophorin A mutational assay of red blood cells and chromosome translocation analyses of lymphocytes; record linkage with national cancer registry and mortality registry files to determine cancer incidence and cause-specific mortality; thyroid screening examinations with ultrasound and fine-needle biopsy; and cryopreserved white blood cells and plasma for future molecular studies. Comprehensive studies of Chernobyl cleanup workers have potential to provide a new information about cancer risks due to protracted exposures to ionizing radiation. 21 refs., 1 fig., 11 tabs.

Tekkel, M.; Rahu, M.; Veidebaum, T. [Institute of Experimental and Clinical Medicine, Tallinn (Estonia)] [and others

1997-05-01T23:59:59.000Z

395

Study of the effects of ambient conditions upon the performance of fan powered, infrared, natural gas burners. Quarterly report, April 1, 1996 - June 30, 1996  

SciTech Connect (OSTI)

A porous radiant burner testing facility consisting of a commercial deep-fat fryer, an FTIR based spectral radiance measurement system, a set of flue gas analysis components, and a fuel gas mixing station was constructed. The measurement capabilities of the system were tested using methane and the test results were found to be consistent with the literature. Following the validation of the measurement system, various gas mixtures were tested to study the effect of gas compositions have on burner performance. Results indicated that the emissions vary with fuel gas composition and air/fuel ratio. The maximum radiant efficiency of the burner was obtained close to air/fuel ratio of 1.

Bai, T.; Yeboah, Y.D.; Sampath, R.

1996-07-01T23:59:59.000Z

396

Action Memorandum for the Engineering Test Reactor under the Idaho Cleanup Project  

SciTech Connect (OSTI)

This Action Memorandum documents the selected alternative for decommissioning of the Engineering Test Reactor at the Idaho National Laboratory under the Idaho Cleanup Project. Since the missions of the Engineering Test Reactor Complex have been completed, an engineering evaluation/cost analysis that evaluated alternatives to accomplish the decommissioning of the Engineering Test Reactor Complex was prepared adn released for public comment. The scope of this Action Memorandum is to encompass the final end state of the Complex and disposal of the Engineering Test Reactor vessol. The selected removal action includes removing and disposing of the vessel at the Idaho CERCLA Disposal Facility and demolishing the reactor building to ground surface.

A. B. Culp

2007-01-26T23:59:59.000Z

397

Action Memorandum for General Decommissioning Activities under the Idaho Cleanup Project  

SciTech Connect (OSTI)

This Action Memorandum documents the selected alternative to perform general decommissioning activities at the Idaho National Laboratory (INL) under the Idaho Cleanup Project (ICP). Preparation of this Action Memorandum has been performed in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), as amended by the "Superfund Amendments and Reauthorization Act of 1986", and in accordance with the "National Oil and Hazardous Substances Pollution Contingency Plan". An engineering evaluation/cost analysis (EE/CA) was prepared and released for public comment and evaluated alternatives to accomplish the decommissioning of excess buildings and structures whose missions havve been completed.

S. L. Reno

2006-10-26T23:59:59.000Z

398

FLUOR HANFORD (FH) MAKES CLEANUP A REALITY IN NEARLY 11 YEARS AT HANFORD  

SciTech Connect (OSTI)

For nearly 11 years, Fluor Hanford has been busy cleaning up the legacy of nuclear weapons production at one of the Department of Energy's (DOE'S) major sites in the United States. As prime nuclear waste cleanup contractor at the vast Hanford Site in southeastern Washington state, Fluor Hanford has changed the face of cleanup. Fluor beginning on October 1, 1996, Hanford Site cleanup was primarily a ''paper exercise.'' The Tri-Party Agreement, officially called the Hanford Federal Facility Agreement and Consent Order - the edict governing cleanup among the DOE, U.S. Environmental Protection Agency (EPA) and Washington state - was just seven years old. Milestones mandated in the agreement up until then had required mainly waste characterization, reporting, and planning, with actual waste remediation activities off in the future. Real work, accessing waste ''in the field'' - or more literally in huge underground tanks, decaying spent fuel POO{approx}{approx}S, groundwater, hundreds of contaminated facilities, solid waste burial grounds, and liquid waste disposal sites -began in earnest under Fluor Hanford. The fruits of labors initiated, completed and/or underway by Fluor Hanford can today be seen across the site. Spent nuclear fuel is buttoned up in secure, dry containers stored away from regional water resources, reactive plutonium scraps are packaged in approved containers, transuranic (TRU) solid waste is being retrieved from burial trenches and shipped offsite for permanent disposal, contaminated facilities are being demolished, contaminated groundwater is being pumped out of aquifers at record rates, and many other inventive solutions are being applied to Hanford's most intransigent nuclear wastes. (TRU) waste contains more than 100 nanocuries per gram, and contains isotopes higher than uranium on the Periodic Table of the Elements. (A nanocurie is one-billionth of a curie.) At the same time, Fluor Hanford has dramatically improved safety records, and cost effectively maintained and streamlined infrastructure and equipment that is impossibly old and in many cases ''extinct'' in terms of spare parts and vendor support. The story of Fluor's achievements at the Hanford Site - the oldest and most productive plutonium site in the world - is both inspiring and instructive.

GERBER, M.S.

2007-05-24T23:59:59.000Z

399

Continuing Clean-up at Oak Ridge, Portsmouth and Paducah-Successes and Near-Term Plans  

SciTech Connect (OSTI)

This paper describes the complexities and challenges associated with the Oak Ridge Environmental Management (EM) cleanup program and the steps that DOE and Bechtel Jacobs Company LLC (the Oak Ridge EM team) have collaboratively taken to make significant physical progress and get the job done. Maintaining significant environmental cleanup progress is a daunting challenge for the Oak Ridge EM Team. The scale and span of the Oak Ridge Operations (ORO) cleanup is immense-five major half-century-old installations in three states (three installations are complete gaseous diffusion plants), with concurrent cleanup at the fully operational Oak Ridge National Laboratory and Y-12 National Security Complex, and with regulatory oversight from three states and two United States (US) Environmental Protection Agency (EPA) Regions. Potential distractions arising from funding fluctuations and color-of-money constraints, regulatory negotiations, stakeholder issues, or any one of a number of other potential delay phenomena can not reduce the focus on safely achieving project objectives to maintain cleanup momentum.

Fritz, L. L.; Houser, S. M.; Starling, D. A.

2002-02-26T23:59:59.000Z

400

Pilot-Scale Demonstration of hZVI Process for Treating Flue Gas Desulfurization Wastewater at Plant Wansley, Carrollton, GA  

E-Print Network [OSTI]

), Chromium (VI), Cadmium (II), Lead (II) and Copper (II) from ppm level to ppb level in a very short reaction time. The chemical consumption was estimated to be approximately 0.2-0.4 kg of ZVI per 1 m^3 of FGD water treated, which suggested the process...

Peddi, Phani 1987-

2011-12-06T23:59:59.000Z

Note: This page contains sample records for the topic "flue gas cleanup" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1993--September 1994  

SciTech Connect (OSTI)

Preliminary environmental risk assessment on the FGD by-products to be placed underground is virtually complete. The initial mixes for pneumatic and hydraulic placement have been selected and are being subject to TCLP, ASTM, and modified SLP shake tests as well as ASTM column leaching. Results of these analyses show that the individual coal combustion residues, and the residues mixes, are non-hazardous in character. Based on available information, including well logs obtained from Peabody Coal Company, a detailed study of the geology of the placement site was completed. The study shows that the disposal site in the abandoned underground mine workings at depths of between 325 and 375 feet are well below potable groundwater resources. This, coupled with the benign nature of the residues and residues mixtures, should alleviate any concern that the underground placement will have adverse effects on groundwater resources. Seven convergence stations were installed in the proposed underground placement area of the Peabody Coal Company No. 10 mine. Several sets of convergence data were obtained from the stations. A study of materials handling and transportation of coal combustion residues from the electric power plant to the injection site has been made. The study evaluated the economics of the transportation of coal combustion residues by pneumatic trucks, by pressure differential rail cars, and by SEEC, Inc. collapsible intermodal containers (CICs) for different annual handling rates and transport distances. The preliminary physico-chemical characteristics and engineering properties of various FBC fly ash-spent bed mixes have been determined, and long-term studies of these properties are continuing.

Chugh, Y.P.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

1994-10-01T23:59:59.000Z

402

Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 5, November 1, 1991--January 31, 1992  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO{sub 2} and NO{sub x} Reduction - Preliminary confirmation of 50% SO{sub 2} reduction has been achieved, but the NO{sub x} reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO{sub 2} reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO{sub 2} Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel`s original cost estimates (capital and operating) were prepared. Therefore, SO{sub 2} removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

403

Assessment of the Flue Gas Recycle Strategies on Oxy-Coal Power Plants using an Exergy-based Methodology  

E-Print Network [OSTI]

to the highest net plant efficiency. This option not only allows the minimal exergy losses in the boiler but also and solvents formulation. Thus, significant efficiency improvement is needed for the oxy- combustion route minimizes the flowrate going through the downstream depollution devices. The net plant efficiency obtained

Paris-Sud XI, Université de

404

Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997  

SciTech Connect (OSTI)

The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

Chugh, Y.P.

1997-12-31T23:59:59.000Z

405

Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility  

SciTech Connect (OSTI)

With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

Metz, Paul; Bolz, Patricia

2013-03-25T23:59:59.000Z

406

Environmental Cleanup  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia NanoparticlesSmartAffects

407

CO.sub.2 separation from low-temperature flue gases  

DOE Patents [OSTI]

Two methods are provide for the separation of carbon dioxide from the flue gases. The first method utilizes a phase-separating moiety dissolved in an aqueous solution of a basic moiety to capture carbon dioxide. The second method utilizes a phase-separating moiety as a suspended solid in an aqueous solution of a basic moiety to capture carbon dioxide. The first method takes advantage of the surface-independent nature of the CO.sub.2 absorption reactions in a homogeneous aqueous system. The second method also provides permanent sequestration of the carbon dioxide. Both methods incorporate the kinetic rate enhancements of amine-based scrubbing while eliminating the need to heat the entire amine solution (80% water) in order to regenerate and release CO.sub.2. Both methods also take advantage of the low-regeneration temperatures of CO.sub.2-bearing mineral systems such as Na.sub.2CO.sub.3/NaHCO.sub.3 and K.sub.2CO.sub.3/KHCO.sub.3.

Dilmore, Robert (Irwin, PA); Allen, Douglas (Salem, MA); Soong, Yee (Monroeville, PA); Hedges, Sheila (Bethel Park, PA)

2010-11-30T23:59:59.000Z

408

Surface and subsurface cleanup protocol for radionuclides, Gunnison, Colorado, UMTRA project processing site. Final report: Revision 1  

SciTech Connect (OSTI)

Surface and subsurface soil cleanup protocols for the Gunnison, Colorado, processing site are summarized as follows: In accordance with EPA-promulgated land cleanup standards, in situ Ra-226 is to be cleaned up based on bulk concentrations not exceeding 5 and 15 pCi/g in 15-cm surface and subsurface depth increments, averaged over 100m{sup 2} grid blocks, where the parent Ra-226 concentrations are greater than, or in secular equilibrium with, the Th-230 parent. In locations where Th-230 has differentially migrated in subsoil relative to Ra-226, a Th-230 clean up protocol has been developed. The cleanup of other radionuclides or nonradiological hazards that pose a significant threat to the public and the environment will be determined and implemented in accordance with pathway analysis to assess impacts and the implications of ALARA specified in 40 CFR Part 192 relative to supplemental standards.

Gonzales, D.

1993-12-01T23:59:59.000Z

409

Effect of radon dose on cleanup criteria and using RESRAD for chemical risk assessment  

SciTech Connect (OSTI)

The US Department of Energy has used RESRAD, a pathway analysis program developed at Argonne National Laboratory, in conjunction with the as low as reasonably achievable (ALARA) principle to develop site-specific residual radioactive material guidelines (cleanup criteria) for many sites. This study examines the effects of the radon pathway, recently added to the RESRAD program, on the calculation of uranium, radium, and thorium cleanup criteria. The results show that the derived uranium guidelines will not be affected by the radon ingrowth considerations. The effect of radon on radium and thorium generic guidelines is more significant, but the model does indicate that at the generic soil limits used for radium and thorium the indoor radon decay product concentrations would be below the 0.02 working level standard. This study also examines the feasibility of applying RESRAD to chemical risk assessment. The results show that RESRAD can perform risk assessment of toxic chemicals after simple modifications. Expansion of the RESRAD database to include chemical compounds will increase its capability to handle chemical risk assessments. 11 refs., 3 tabs.

Yu, C.; Cheng, J.-J. (Argonne National Lab., IL (United States)); Wallo, A. III (USDOE, Washington, DC (United States))

1991-01-01T23:59:59.000Z

410

Phase 1 of the North Site cleanup: Definition of product streams. Volume 1  

SciTech Connect (OSTI)

Various materials and equipment have accumulated at the Western Research Institute (WRI) North Site Facility since its commissioning in 1968. This facility was built by the US Bureau of Mines, transferred to the US Energy Research Development Administration (ERDA) in 1976, and transferred once again to the US Department of Energy (DOE) shortly thereafter. In 1983, the North Site Facility became part of WRI. The materials that have accumulated over the years at the site have been stored in drums, tanks, and open piles. They vary from oil shale, tar sand, and coal feedstocks to products and materials associated with in situ simulation and surface process developments associated with these feedstocks. The majority of these materials have been associated with DOE North Site activities and work performed at the North Site under DOE-WRI cooperative agreement contracts. In phase I of the North Site Facility cleanup project, these materials were sampled and evaluated to determine their chemical characteristics for proper disposal or use in accordance with current local, state, and federal regulations. Phase I of the North Site Facility cleanup project involved dividing the stored materials into product streams and dividing each product stream into composite groups. Composite groups contain materials known to be similar in composition, source, and process exposure. For each composite group, materials, which are representative of the composite, were selected for sampling, compositing, and analysis.

Sorini, S.; Merriam, N.

1994-03-01T23:59:59.000Z

411

Plutonium-aerosol emission rates and potential inhalation exposure during cleanup and treatment test at Area 11, Nevada Test Site  

SciTech Connect (OSTI)

A Cleanup and Treatment (CAT) test was conducted in 1981 at Area 11, Nevada Test Site. Its purpose was to evaluate the effectiveness of using a large truck-mounted vacuum cleaner similar to those used to clean paved streets for cleaning radiological contamination from the surface of desert soils. We found that four passes with the vehicle removed 97% of the alpha contamination and reduced resuspension by 99.3 to 99.7%. Potential exposure to cleanup workers was slight when compared to natural background exposure. 7 refs., 1 fig., 2 tabs.

Shinn, J.H.; Homan, D.N.

1985-08-13T23:59:59.000Z

412

Bugs boost Cold War clean-up: Bacteria could scrub uranium from sites contaminated decades ago. updated at midnight GMTtoday is friday, november 14  

E-Print Network [OSTI]

2003 · Fungus catches radioactive fallout 8 May 2002 · Depleted uranium soils battlefields 12 MarchBugs boost Cold War clean-up: Bacteria could scrub uranium from sites contaminated decades ago boost Cold War clean-up Bacteria could scrub uranium from sites contaminated decades ago. 13 October

Lovley, Derek

413

Superfund Record of Decision (EPA Region 8): Anaconda Smelter site, (Operable Unit 11 - Flue Dust), Deer Lodge County, Anaconda, MT. (Second remedial action), September 1991  

SciTech Connect (OSTI)

The 6,000-acre Anaconda Smelter site is a former copper and ore processing facility in Deer Lodge County, Montana. Land use in the area is predominantly residential. The site is bounded on the north and east, respectively, by the Warm Springs Creek and Mill Creek, both of which are potential sources of drinking water. From 1884 until 1980 when activities ceased, the site was used for ore processing and smelting operations. In 1988, EPA conducted an investigation to determine the nature and extent of the flue dust contamination. A 1988 ROD addressed the Mill Creek Operable Unit (OU15) and documented the relocation of residents from the community surrounding the smelter site as the selected remedial action. The Record of Decision (ROD) addresses the Flue Dust Operable Unit (OU11). The primary contaminants of concern affecting this site from the flue dust materials are metals including arsenic, cadmium, and lead. The selected remedial action for the site is included.

Not Available

1991-09-23T23:59:59.000Z

414

Z .The Science of the Total Environment 260 2000 1 9 Assessing water quality impacts and cleanup  

E-Print Network [OSTI]

Z .The Science of the Total Environment 260 2000 1 9 Assessing water quality impacts and cleanup a California Regional Water Quality Control Board, 1515 Clay St., Suite 1400, Oakland, CA 94612, USA b of the Total En¨ironment 260 2000 1 92 quality trends can be more accurately measured by changes

Kirchner, James W.

415

Commercial Environmental Cleanup -- The products and services directory. Treatment, characterization and extraction/delivery/materials handling technologies  

SciTech Connect (OSTI)

This directory is patterned after the telephone Yellow Pages and is designed as a reference tool to those who may seek commercial remedies for their environmental cleanup problems. It offers the user the opportunity to survey 325 environmental cleanup businesses that currently market their products and services through 1,134 applications of commercially available technologies. Like the Yellow Pages, the Directory furnishes the user with points-of-contact to investigate the capabilities of the listed companies to perform within acceptable standards, practices, and costs and to meet a user`s specific needs. The three major sections of the Directory are organized under the broad headings of Treatment, Characterization, and Extraction/Delivery/Materials Handling. Within each section, information is grouped according to the applicable contaminant medium and companies are listed alphabetically under each medium heading. Not all vendors in the environmental cleanup business are included in this first edition of the Directory. Future editions will more completely reflect the status of the industry. The database of the commercial cleanup products and services Directory will be offered on the Internet in the future and will be available on the Homepage www.doe.gjpo.com.

NONE

1995-11-01T23:59:59.000Z

416

Answers to frequently asked questions about cleanup activities at Three Mile Island, Unit 2. Public information report  

SciTech Connect (OSTI)

The document presents answers to frequently asked questions about plans for cleanup and decontamination activities at Three Mile Island, Unit 2. Answers to the questions asked are based on information in the NRC 'Draft Programmatic Environmental Impact Statement related to decontamination and disposal of radioactive wastes resulting from March 28, 1979, accident, Three Mile Island Nuclear Station, Unit 2,' NUREG-0683.

Not Available

1980-09-01T23:59:59.000Z

417

Environmental cleanup privatization, products and services directory, January 1997. Second edition  

SciTech Connect (OSTI)

The US Department of Energy has undertaken an ambitious ``Ten Year Plan`` for the Weapons Complex, an initiative to complete cleanup at most nuclear sites within a decade. This Second Edition of the Directory is designed to facilitate privatization which is key to the success of the Plan. The Directory is patterned after the telephone Yellow Pages. Like the Yellow Pages, it provides the user with points of contact for inquiring further into the capabilities of the listed companies. This edition retains the original format of three major sections under the broad headings: Treatment, Characterization, and Extraction/Deliver/Materials Handling. Within each section, companies are listed alphabetically. Also, ``company name`` and ``process type`` indices are provided at the beginning of each section to allow the user quick access to listings of particular interest.

NONE

1997-01-01T23:59:59.000Z

418

From Pushing Paper to Pushing Dirt - Canada's Largest LLRW Cleanup Gets Underway - 13111  

SciTech Connect (OSTI)

The Port Hope Project is the larger of the two projects in the Port Hope Area Initiative (PHAI), Canada's largest low level radioactive waste (LLRW) cleanup. With a budget of approximately $1 billion, the Port Hope Project includes a broad and complex range of remedial elements from a state of the art water treatment plant, an engineered waste management facility, municipal solid waste removal, remediation of 18 major sites within the Municipality of Port Hope (MPH), sediment dredging and dewatering, an investigation of 4,800 properties (many of these homes) to identify LLRW and remediation of approximately 450 of these properties. This paper discusses the status of the Port Hope Project in terms of designs completed and regulatory approvals received, and sets out the scope and schedule for the remaining studies, engineering designs and remediation contracts. (authors)

Veen, Walter van [Atomic Energy of Canada Limited, Port Hope, Ontario (Canada)] [Atomic Energy of Canada Limited, Port Hope, Ontario (Canada); Lawrence, Dave [Public Works and Government Services Canada, Port Hope, Ontario (Canada)] [Public Works and Government Services Canada, Port Hope, Ontario (Canada)

2013-07-01T23:59:59.000Z

419

Building organizational technical capabilities: a new approach to address the office of environmental management cleanup challenges in the 21. century  

SciTech Connect (OSTI)

The United States Department of Energy (DOE), Office of Environmental Management (EM) is responsible for the nations nuclear weapons program legacy wastes cleanup. The EM cleanup efforts continue to progress, however the cleanup continues to be technologically complex, heavily regulated, long-term, and a high life cycle cost estimate (LCCE) effort. Over the past few years, the EM program has undergone several changes to accelerate its cleanup efforts with varying degrees of success. Several cleanup projects continued to experience schedule delays and cost growth. The schedule delays and cost growth have been attributed to several factors such as changes in technical scope, regulatory and safety considerations, inadequacy of acquisition approach and project management. This article will briefly review the background and schools of thought on strategic management and organizational change practiced in the United States over the last few decades to improve an organisation's competitive edge and cost performance. The article will briefly review examples such as the change at General Electric, and the recent experience obtained from the nuclear industry, namely the long-term response to the 1986 Chernobyl accident. The long-term response to Chernobyl, though not a case of organizational change, could provide some insight in the strategic management approaches used to address people issues. The article will discuss briefly EM attempts to accelerate cleanup over the past few years, and the subsequent paradigm shift. The paradigm shift targets enhancing and/or creating organizational capabilities to achieve cost savings. To improve its ability to address the 21. century environmental cleanup challenges and achieve cost savings, EM has initiated new corporate changes to develop new and enhance existing capabilities. These new and enhanced organizational capabilities include a renewed emphasis on basics, especially technical capabilities including safety, project management, acquisition management and people. The new enhanced organizational capabilities coupled with more effective communications; oversight and decision-making processes are expected to help EM meet the 21. century challenges. This article will focus on some of the initiatives to develop and enhance organizational technical capabilities. Some of these development initiatives are a part of DOE corporate actions to respond to the Defense Nuclear Facilities Safety Board (DNFSB) recommendations 93-3 and 2004-1. Other development initiatives have been tailored to meet EM specific needs for organizational capabilities such as case studies analysis and cost estimating. (authors)

Fiore, J.J.; Rizkalla, E.I. [Office of Environmental Management, The United States Dept. of Energy, Washington, D.C. (United States)

2007-07-01T23:59:59.000Z

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