National Library of Energy BETA

Sample records for flared na na

  1. 20Na

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na β+-Decay Evaluated Data Measurements 1951SH38: 20Na; measured T1/2. 1953HO01: 20Na; measured T1/2. 1964MA44, 1969MAZT: 20Na; measured T1/2, α-spectrum; deduced β-branching. 20Ne deduced levels α-width. 1967SU05: 20Na; measured T1/2; deduced nuclear properties. 1970OA01: 20Na; measured T1/2, βα-coin, βα(θ). 1971GO18: 20Na; measured T1/2; deduced mass excess. 1971MA09: 20Na; measured β-delayed α-spectra; deduced βν anisotropy coefficients. 1971WI07: 20Na; measured T1/2; deduced ft

  2. 18Na

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na Ground-State Decay Evaluated Data Measured Ground-State Γcm(T1/2) for 18Na Adopted value: < 200 keV (2012MU05) Measured Mass Excess for 18Na Adopted value: 25040 ± 110 keV (2012WA38) Measurements 2004ZE05: 9Be(20Mg, 18NaX), E = 43 MeV/nucleon; measured particle spectra, angular correlations, invariant mass following fragment proton decay. 18Na; deduced excited states proton decay features. 2011AS07: 1H(17Ne, 17Ne), 1H(17Ne, X)18Na, E = 4 MeV/nucleon; measured reaction products, proton

  3. 19Na

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    features. 2006ACZY: 1H(18Ne, p), E 66 MeV; measured Ep following elastic and inelastic scattering. 19Na deduced excited states. 2006DEZU: 1H(18Ne, p), Ecm 800 - 6000...

  4. Natural Gas Vented and Flared

    Gasoline and Diesel Fuel Update (EIA)

    6-2015 Colorado NA NA NA NA NA NA 1996-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2015 Kansas NA NA NA NA NA NA 1996-2015 Louisiana NA NA NA NA NA NA 1991-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1996-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 Oklahoma NA NA NA NA NA NA 1996-2015 Pennsylvania NA NA NA NA NA NA 1991-2015 Texas NA NA NA NA NA NA 1991-2015 Utah NA NA NA NA NA NA 1994-2015 West Virginia NA NA NA NA NA

  5. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1991-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1996-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 ...

  6. Na onal Security Site?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mul ple Choice (circle the correct answer) 1. How many diff erent animal species can be found at the Nevada Na onal Security Site? a. Less than 500 b. Exactly 1,325 c. More than 1,500 d. Exactly 2,303 2. Nuclear research, development and tes ng caused radioac ve contamina on of: a. Buildings b. Clothes and tools c. Soil and water d. All of the above 3. One method used to check soil for the presence of radioac ve contamina on is: a. Use a black light to see if the soil glows b. Send soil samples

  7. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    SciTech Connect (OSTI)

    Guo, Ya; Yu, Xiqian; You, Ya; Yin, Yaxia; Nam, Kyung -Wan

    2015-01-01

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

  8. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    You, Ya; Yu, Xi -Qian; Yin, Ya -Xia; Nam, Kyung -Wan; Guo, Yu -Guo

    2014-10-27

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmospheremore » during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. As a result, the Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.« less

  9. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    SciTech Connect (OSTI)

    You, Ya; Yu, Xi -Qian; Yin, Ya -Xia; Nam, Kyung -Wan; Guo, Yu -Guo

    2014-10-27

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. As a result, the Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

  10. NaWoTec | Open Energy Information

    Open Energy Info (EERE)

    NaWoTec Jump to: navigation, search Name: NaWoTec Place: Rossdorf, Germany Zip: 64380 Product: Germany-based company developing 3-dimensional additive lithography using...

  11. Threshold electron excitation of Na

    SciTech Connect (OSTI)

    Marinkovic, B.; Wang, P.; Gallagher, A. )

    1992-09-01

    Electron collisional excitation of the 4{ital D}, 5{ital D}, 4{ital P}, and 6{ital S} states of Na has been measured with about 30-meV energy resolution. Very rapid, unresolved threshold onsets are seen for all but the 4{ital P} state, and a near-threshold resonance is suggested by the 5{ital D} data. However, only weak undulations in the cross sections are observed above threshold.

  12. A=14Na (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) 14Ne, 14Na and 14Mg have not been observed. See (1983ANZQ

  13. A=14Na (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    91AJ01) (Not illustrated) 14Ne, 14Na and 14Mg have not been observed. See (1986AN07

  14. A=20Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    72AJ02) (See Energy Level Diagrams for 20Na) GENERAL: See Table 20.35 Table of Energy Levels (in PDF or PS). Mass of 20Na: From the threshold energy of the 20Ne(p, n)20Na...

  15. Document: NA Actionee: Dorothy Riehie

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SI T op Document: NA Actionee: Dorothy Riehie - 04 2 Document Date: 11/01/2012 Due Date: NO ACTION Author: JOHNSON M Addressee: RIEHLE D ~71ES (), Title: Re: Freedom Of Information Act Request DIR DIV NAME DIR DIV NAME MGR AMRP DEP AMRP CPD AMB AMRP RCD AMB BUD AMISE AMB FIN AMISE EMD AMB HRM AMISE OOD AMIB PRO AMISE SED AMMIS 0CC AMMIS SES OCE Riehle, Dorothy (Actionee) AMIMS ISI ORP AMMS PlC PNSO AMMS SSD RLCI Comments: Original to D. Riehle. Records Schedule Information: ADM-1.28.1 Scan?: Yes

  16. A=19Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    72AJ02) (See the Isobar Diagram for 19Na) A study of the reaction 24Mg(p, 6He)19Na at Ep = 54.7 MeV reveals a group of 6He particles corresponding to a state in 19Na with M - A = 12.974 ± 0.070 MeV. It is presumed to be the ground state of 19Na, although the close proximity of the second T = 3/2 state in 19O from the first (96 keV), does not permit a definite assignment. If it is assumed that 19Na(0) has M - A = 12.974 ± 0.070 MeV, then 19Na is unbound with respect to decay into 18Ne + p by

  17. New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers...

    Open Energy Info (EERE)

    Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier Detection And Rejection Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  18. A=18Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    72AJ02) (Not illustrated) A calculation using an isobaric mass formula predicts that the mass excess of 18Na is 25.4 ± 0.4 MeV (KE66C): 18Na is then unbound with respect to proton emission by 1.6 MeV. See also (JA65C

  19. A=20Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    87AJ02) (See Energy Level Diagrams for 20Na) GENERAL: See (1983AJ01) and Table 20.27 [Table of Energy Levels] (in PDF or PS). (1981WA1Q, 1983ANZQ, 1983BR29, 1985AN28, 1985HA1N, 1985RO1N, 1986AN07, 1986GA1I). 1. 20Na(β+)20Ne Qm = 13.887 20Na decays by positron emission to 20Ne*(1.63) and to a number of other excited states of 20Ne: see Table 20.26 (in PDF or PS) and reaction 53 in 20Ne. The half-life of 20Na is 447.9 ± 2.3 msec [weighted mean of values quoted in (1978AJ03) and in (1983CL01)];

  20. A=20Na (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    98TI06) (See Energy Level Diagrams for 20Na) GENERAL: See Table Prev. Table 20.32 preview 20.32 [General Table] (in PDF or PS) and Table Prev. Table 20.33 preview 20.33 [Table of Energy Levels] (in PDF or PS) here. μ = 0.3694 ± 0.0002 nm (1975SC20, 1989RA17) 1. 20Na(β+)20Ne Qm = 13.887 20Na decays by positron emission to 20Ne*(1.63) and to a number of other excited states of 20Ne: see Table Prev. Table 20.31 preview 20.31 (in PDF or PS) and reaction 59 in 20Ne. The half-life of 20Na is 447.9

  1. FEiNA SCP | Open Energy Information

    Open Energy Info (EERE)

    Place: Sant Marta de Torruella, Spain Product: Manufacturer of tracking systems for PV plants, and looking for STEG partners. References: FEiNA SCP1 This article is a stub. You...

  2. NA 80 - Associate Administrator for Counterterrorism andCounterprolif...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 80 - Associate Administrator for Counterterrorism ... NA 80 - Associate...

  3. NA 70 - Associate Administrator for Defense Nuclear Security...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 70 - Associate Administrator for Defense ... NA 70 - Associate Administrator...

  4. NA 50 - Associate Administrator for Safety, Infrastructure and...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 50 - Associate Administrator for Safety, ... NA 50 - Associate Administrator...

  5. NA 1 - Immediate Office of the Administrator | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 1 - Immediate Office of the Administrator NA 1 - Immediate Office of the...

  6. NA 30 - Deputy Administrator for Naval Reactors | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 30 - Deputy Administrator for Naval Reactors NA 30 - Deputy Administrator for...

  7. NA EA - Associate Administrator for External Affairs | National...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA EA - Associate Administrator for External Affairs NA EA - Associate...

  8. NA 20 - Deputy Administrator for Defense Nuclear Nonproliferation...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 20 - Deputy Administrator for Defense ... NA 20 - Deputy Administrator for...

  9. NA 15 - Assistant Deputy Administrator for Secure Transportation...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 15 - Assistant Deputy Administrator for ... NA 15 - Assistant Deputy...

  10. NA 10 - Deputy Administrator for Defense Programs | National...

    National Nuclear Security Administration (NNSA)

    Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA 10 - Deputy Administrator for Defense Programs NA 10 - Deputy Administrator for...

  11. NA GC - Office of General Counsel | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    Blog Home About Us Our Operations Management and Budget Office of Civil Rights Workforce Statistics NA GC - Office of General Counsel NA GC - Office of General Counsel...

  12. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Virginia Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 0 0 0 0 0 0 1980's 0 0 0 0 27 0 0 297 258 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 NA NA NA 2010's NA NA 0 NA NA - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  13. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Virginia Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 0 0 0 0 0 0 1980's 0 0 0 0 27 0 0 297 258 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 NA NA NA 2010's NA NA 0 NA NA - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  14. A=18Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    78AJ03) (Not illustrated) 18Na has not been observed: its atomic mass excess has been estimated to be 25.32 MeV: it is then unbound with respect to proton emission by 1.55 MeV (1977WA08). See also (1976JA23, 1976WA1E

  15. A=18Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3AJ01) (Not illustrated) 18Na has not been observed: its atomic mass excess has been estimated to be 25.32 MeV: it is then unbound with respect to proton emission by 1.55 MeV (1977WA08). See also (1978GU10

  16. A=18Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7AJ02) (Not observed) 18Na has not been observed; its atomic mass excess has been estimated to be 25.32 MeV; it is then unbound with respect to proton emission by 1.6 MeV: see (1978AJ03). See also (1986AN07) and (1983ANZQ

  17. A=18Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    95TI07) (Not observed) 18Na has not been observed; its atomic mass excess has been estimated to be 25.32 MeV (1993AU05); it is then unbound with respect to proton emission by 1.6 MeV: see (1978AJ03). See also (1986AN07) and (1983ANZQ

  18. A=20Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    20Na) GENERAL: See also (1978AJ03) and Table 20.36 Table of Energy Levels (in PDF or PS). (1977SI1D, 1978WO1E, 1979BE1H, 1980OK01, 1981AY01). J 2 (1975SC20); 0.3694 ...

  19. A=20Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    78AJ03) (See Energy Level Diagrams for 20Na) GENERAL: See also (1972AJ02) and Table 20.39 Table of Energy Levels (in PDF or PS). (1973HA77, 1973SU1B, 1974HA17, 1976CH1T,...

  20. A=19Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mass excess of 12.928 0.012 MeV for 19Na; it is then unstable with respect to breakup into 18Ne + p by 320 13 keV. An excited state at Ex 120 10 keV is also...

  1. A=19Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assuming the atomic mass excess listed above, 19Na(0) is unstable with respect to breakup into 18Ne + p by 320 13 keV. See also (1972CE1A, 1976BE1L, 1976JA23), (1975BE31,...

  2. A=19Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mass excess of 12.929 0.012 MeV for 19Na; it is then unstable with respect to breakup into 18Ne + p by 321 13 keV. An excited state at Ex 120 10 keV is also...

  3. A=19Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mass excess of 12.929 0.012 MeV for 19Na; it is then unstable with respect to breakup into 18Ne + p by 321 13 keV. An excited state at Ex 120 10 keV is also...

  4. U.S. Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 12,000 10,000 10,000 10,000 11,000 9,000 9,000 10,000 12,000 10,000 10,000 11,000 1981 10,000 10,000 9,000 8,000 7,000 8,000 9,000 10,000 7,000 7,000 6,000

  5. OR I GI NA L S I GNE D B Y OR I GI NA L S I GNE D B Y

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NA L S I GNE D B Y OR I GI NA L S I GNE D B Y

  6. NNSA reorganizes Office of Emergency Operations (NA-40), Office...

    National Nuclear Security Administration (NNSA)

    ... NA-40 will continue to be led by Associate Administrator Deborah Wilber, and NA-80 will continue to be led by Associate Administrator Steven Aoki. Frank Klotz and Madelyn Creedon ...

  7. na-00 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    na-00 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home /

  8. NNSA reorganizes Office of Emergency Operations (NA-40), Office of

    National Nuclear Security Administration (NNSA)

    Counterterrorism and Counterproliferation (NA-80) | National Nuclear Security Administration reorganizes Office of Emergency Operations (NA-40), Office of Counterterrorism and Counterproliferation (NA-80) | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are

  9. Analysis of NaOH releases for Hanford tank farms

    SciTech Connect (OSTI)

    Ryan, G.W., Westinghouse Hanford

    1996-09-12

    The information contained in the canceled document is now located in the document: Consequence Analysis of a NaOH Solution Spray Release During Addition to Waste Tank, WHC-SD-WM-CN-065.

  10. NaIrO3A Pentavalent Post-perovskite

    SciTech Connect (OSTI)

    M Bremholm; S Dutton; P Stephens; R Cava

    2011-12-31

    Sodium iridium (V) oxide, NaIrO{sub 3}, was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides.

  11. Office of Nuclear Material Integration (ONMI), NA-73

    National Nuclear Security Administration (NNSA)

    Office of Nuclear Material Integration (ONMI), NA-73 Over 420 Government & Commercial Nuclear Entities currently report to NMMSS Mission U.S. Government's Official Database to Track Transactions, Movements and Inventories of Nuclear Materials throughout the U.S. as well as Imports and Exports Jointly funded by the NRC & NNSA - Managed by NA-73 Fuel Cycle Facilities  Conversion  Enrichment  Fuel Fabrication  Power Reactors, etc. DOE/NNSA  Defense Programs  Naval

  12. Magnetism in Na-filled Fe-based skutterudites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xing, Guangzong; Fan, Xiaofeng; Zheng, Weitao; Ma, Yanming; Shi, Hongliang; Singh, David J.

    2015-06-01

    The interplay of superconductivity and magnetism is a subject of ongoing interest, stimulated most recently by the discovery of Fe-based superconductivity and the recognition that spin-fluctuations near a magnetic quantum critical point may provide an explanation for the superconductivity and the order parameter. We investigate magnetism in the Na filled Fe-based skutterudites using first principles calculations. NaFe4Sb12 is a known ferromagnet near a quantum critical point. We find a ferromagnetic metallic state for this compound driven by a Stoner type instability, consistent with prior work. In accord with prior work, the magnetization is overestimated, as expected for a material nearmore » an itinerant ferromagnetic quantum critical point. NaFe4P12 also shows a ferromagnetic instability at the density functional level, but this instability is much weaker than that of NaFe4Sb12, possibly placing it on the paramagnetic side of the quantum critical point. NaFe4As12 shows intermediate behavior. We also present results for skutterudite FeSb3, which is a metastable phase that has been reported in thin film form.« less

  13. Two-frequency lidar technique for mesospheric Na temperature measurements

    SciTech Connect (OSTI)

    She, C.Y.; Latifi, H.; Yu, J.R.; Alvarez, R.J. II ); Bills, R.E.; Gardner, C.S. )

    1990-06-01

    The authors describe a new two-frequency lidar for measuring Na temperature profiles that uses a stabilized cw single-mode dye laser oscillator (rms frequency jitter < 1 MHz) followed by a pulsed-dye power amplifier (140 MHz FWHM linewidth) which is pumped by an injection-locked Nd:YAG laser. The laser oscillator is tuned to the two operating frequencies by observing the Doppler-free structure of the Na D{sub 2} fluorescence spectrum in a vapor cells. The lidar technique and the initial observations of the temperature profile between 82 and 102 km at Ft. Collins, CO (40.6{degree}N,105{degree}W) are described. Absolute temperature accuracies at the Na layer peak of better than {plus minus}3 K with a vertical resolution of 1 km and an integration period of approximately 5 min were achieved.

  14. A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

    SciTech Connect (OSTI)

    Jian, ZL; Sun, Y; Ji, XL

    2015-01-01

    A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

  15. DOE-NA-STD-3016-2006 | Department of Energy

    Energy Savers [EERE]

    NA-STD-3016-2006 DOE-NA-STD-3016-2006 May 19, 2006 Hazard Analysis Reports for Nuclear Explosive Operations The purpose of this technical standard is to clarify DOE/NNSA expectations and to provide guidance for preparing HARs for NEOs. The general requirements for operation-specific HARs are those contained in Chapters 2-5 of DOE-STD-3009-94, Change Notice 2, "Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Documented Safety Analysis", or superseding

  16. Nevada Na onal Security Site U.S. Department of Energy, Na onal Nuclear Security Administra on Nevada Field Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wells Sampled On and Near the Nevada Na onal Security Site U.S. Department of Energy, Na onal Nuclear Security Administra on Nevada Field Office Stages of an Underground Nuclear Test An underground nuclear explosion vaporizes the surrounding rock resul ng in a cavity. As the remaining rock cools, melt glass forms and se les to the bo om of the cavity. This may lead to a collapse of the cavity which forms a depression on the surface, or a subsidence crater. Explosion Explosion Cavity Cavity Forms

  17. Analysis of a graphite foam-NaCl latent heat storage system for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of a graphite foam-NaCl latent heat storage system for supercritical CO2 power cycles for concentrated solar power Title Analysis of a graphite foam-NaCl latent heat...

  18. Europium (Z=63) n=3-3 lines in the extreme ultraviolet: Na- through...

    Office of Scientific and Technical Information (OSTI)

    ultraviolet: Na- through Si-like ions Citation Details In-Document Search Title: Europium (Z63) n3-3 lines in the extreme ultraviolet: Na- through Si-like ions Authors: ...

  19. Electronic structure and magnetic properties of NaOsO3 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Electronic structure and magnetic properties of NaOsO3 Prev Next Title: Electronic structure and magnetic properties of NaOsO3 Authors: Du, Yongping ; Wan, Xiangang ; Sheng, ...

  20. Electronic structure and magnetic properties of NaOsO3 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Electronic structure and magnetic properties of NaOsO3 Citation Details In-Document Search Title: Electronic structure and magnetic properties of NaOsO3 Authors: Du, Yongping ; ...

  1. Impact of Biodiesel-based Na on the Selective Catalytic Reduction...

    Office of Scientific and Technical Information (OSTI)

    of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the ...

  2. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  3. APPENDIXN DE-NA0000622 LIST OF APPLICABLE DIRECTIVES

    National Nuclear Security Administration (NNSA)

    .I APPENDIXN DE-NA0000622 LIST OF APPLICABLE DIRECTIVES 09/17/2014 Directive Directive Title 10 CFR 824, Current Rule Procedural Rules for the Assessment of Civil Penalties for Classified Information Security Violations 1 O CFR 830 - Current Rule Nuclear Safety Management 1 O CFR 851 - Current Rule Worker Safety and Health Program ANSI B30.11 Monorails and Underhung Hoists ANSI N323A Radiation Protection Instrumentation Test and Calibration Portable Survey Instrumentation, 1997 ANSI N43.2

  4. Characterization of H, Na-Y using amine desorption

    SciTech Connect (OSTI)

    Biaglow, A.I.; Parrillo, D.J.; Gorte, R.J. )

    1993-11-01

    The authors have examined series of partially ion-exchanged H, Na-Y zeolites using temperature programmed desorption (TPD) and thermogravimetric analysis (TGA) of isopropylamine and n-propylamine in order to examine the acid sites in H-Y zeolites as a function of Na poisoning. Both amines desorbed from Na-Y, unreacted, below 500 K; however, samples containing protonic sites exhibited two additional desorption features. First, unreacted amine molecules were observed leaving the samples between [approximately] 500 and 600 K. Second, reaction features appeared which were observed as the simultaneous desorption of propene and ammonia between 575 and 650 K for isopropylamine and between 625 and 700 K for n-propylamine. For a given sample, the number of both isopropylene and n-propylamine molecules which desorbed in both features was identical. Furthermore, the number of molecules desorbing from the two high-temperature features was found to be equal to the number of protonic sites for the entire series, which indicates that both desorption features are associated with protonic sites. This finding was confirmed by infrared spectroscopy, which also demonstrated that the unreacting desorption feature was associated with the low-frequency, hydroxyl stretch at 3540 cm[sup [minus]1] and that the reacting amine molecules was adsorbed at the high-frequency, hydroxyl stretch near 3640 cm[sup [minus]1]. The implications of these results for understanding the use of TPD-TGA of amines for the characterization of acidity is discussed. 30 refs., 9 figs., 2 tabs.

  5. THERMAL CONDUCTIVITY OF AQUEOUS NaCl SOLUTIONS

    Office of Scientific and Technical Information (OSTI)

    9086 THERMAL CONDUCTIVITY OF AQUEOUS NaCl SOLUTIONS FROM 20°C TO 330°C Huseyin Ozbek and Sidney L. P h i l l i p s Lawrence Berkeley Laboratory University o f California Berkeley, CA 94720 _ _ NOTICE sponsored by the United Stater Government. Neither the United Stater nor chc Umtcd Stater Department of Energy, nor any of their employees. nor any o f the11 c o n t r a ~ t ~ r i . subcontractors. or their cmploycer, makes any warranty, express or implied, or assumes any legal Itability or

  6. Standard Model Tests at the NA62 CERN Experiment

    SciTech Connect (OSTI)

    Bifani, Simone

    2010-02-10

    The physics program of the NA62 experiment aims to search for phenomena beyond the Standard Model by measuring the ratio R{sub K} (GammaK->ev{sub e}(gamma))/GAMMA(K->muv{sub mu}{sub (gamma)}) and studying the ultra rare decay K{sup +}->pi{sup +}vv-bar. The status of the R{sub K} analysis based on approx40% of the data collected during 2007 and 2008 is summarized and the proposed detector layout to measure the branching ratio of the K{sup +}->pi{sup +}vv-bar decay is described.

  7. NA-ASC-100R-04-Vol.1-Rev.0

    National Nuclear Security Administration (NNSA)

    100R-04-Vol.1-Rev.0 August 2004 SAND 2004-3740P Issued by Sandia National Laboratories for NNSA's Office of Advanced Simulation & Computing, NA-114. For more information, contact Dr. Dimitri Kusnezov at dimitri.kusnezov@nnsa.doe.gov ON THE COVER: These experimental images show the evolution of three gaseous cylinders (seeded with a tracer gas) that have been accelerated by a planar shock wave. The flow fields are dominated by vortices created by the shock acceleration, so the swirling red

  8. MINOS Calibration and NA49 Hadronic Production Studies

    SciTech Connect (OSTI)

    Morse, Robert James

    2003-08-01

    An overview of the current status of the Main Injector Neutrino Oscillation Search (MINOS) is presented. MINOS is a long-baseline experiment with two detectors situated in North America. The near detector is based at the emission point of the NuMI beam at Fermilab, Chicago, the far detector is 735 km downstream in a disused iron mine in Soudan, Minnesota. A third detector, the calibration detector, is used to cross-calibrate these detectors by sampling different particle beams at CERN. A detailed description of the design and construction of the light-injection calibration system is included. Also presented are experimental investigations into proton-carbon collisions at 158 GeV/c carried out with the NA49 experiment at CERN. The NA49 experiment is a Time Projection Chamber (TPC) based experiment situated at CERN's North Area. It is a well established experiment with well known characteristics. The data gained from this investigation are to be used to parameterize various hadronic production processes in accelerator and atmospheric neutrino production. These hadronic production parameters will be used to improve the neutrino generation models used in calculating the neutrino oscillation parameters in MINOS.

  9. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    165,360 165,928 209,439 212,848 260,394 288,743 1936-2014 Alaska 6,481 10,173 10,966 11,769 7,219 6,554 1967-2014 Alaska Onshore 5,271 8,034 9,276 9,244 5,670 5,779 1992-2014 Alaska State Offshore 1,210 2,139 1,690 2,525 1,549 776 1992-2014 Arkansas 141 425 494 0 NA NA 1967-2014 California 2,501 2,790 2,424 0 NA NA 1967-2014 California Onshore 2,501 2,790 2,424 NA NA NA 1992-2014 California State Offshore 0 0 0 NA NA NA 2003-2014 Federal Offshore California NA NA 2003-2014 Colorado 1,411 1,242

  10. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    165,360 165,928 209,439 212,848 260,394 288,743 1936-2014 Alaska 6,481 10,173 10,966 11,769 7,219 6,554 1967-2014 Alaska Onshore 5,271 8,034 9,276 9,244 5,670 5,779 1992-2014 Alaska State Offshore 1,210 2,139 1,690 2,525 1,549 776 1992-2014 Arkansas 141 425 494 0 NA NA 1967-2014 California 2,501 2,790 2,424 0 NA NA 1967-2014 California Onshore 2,501 2,790 2,424 NA NA NA 1992-2014 California State Offshore 0 0 0 NA NA NA 2003-2014 Federal Offshore California NA NA 2003-2014 Colorado 1,411 1,242

  11. Formation of titanate nanostructures under different NaOH concentration and their application in wastewater treatment

    SciTech Connect (OSTI)

    Huang Jiquan; Cao Yongge; Deng Zhonghua; Tong Hao

    2011-03-15

    The effects of the concentration of NaOH on the formation and transformation of various titanate nanostructures were studied. With increasing NaOH concentration, three different formation mechanisms were proposed. Nanotubes can only be obtained under moderate NaOH conditions, and should transform into nanowires with prolonged hydrothermal treatment, and their formation rate is accelerated by increasing NaOH concentration. Low concentration of NaOH results in the direct formation of nanowires, while extra high concentration of NaOH leads to the formation of amorphous nanoparticles. Adsorption and photocatalysis studies show that titanate nanowires and nanotubes might be potential adsorbents for the removal of both heavy metal ions and dyes and photocatalysts for the removal of dyes from wastewater. -- Graphical abstract: The morphologies of the titanates depend deeply on the concentration of NaOH. With increasing NaOH concentration, three different formation mechanisms were proposed. The application of these titanate nanostructures in the wastewater treatment was studied. Display Omitted Research highlights: {yields} Effect of NaOH concentration on the structures of various titanates was reported. {yields} Three different formation mechanisms were presented with increasing NaOH concentration. {yields} Various titanates were used as adsorbents/photocatalysts in wastewater treatment.

  12. Photoemission study of the electronic structure and charge density waves of Na?Ti?Sb?O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, S. Y.; Jiang, J.; Ye, Z. R.; Niu, X. H.; Song, Y.; Zhang, C. L.; Dai, P. C.; Xie, B. P.; Lai, X. C.; Feng, D. L.

    2015-04-30

    The electronic structure of Na?Ti?Sb?O single crystal is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The obtained band structure and Fermi surface agree well with the band structure calculation of Na?Ti?Sb?O in the non-magnetic state, which indicates that there is no magnetic order in Na?Ti?Sb?O and the electronic correlation is weak. Polarization dependent ARPES results suggest the multi-band and multi-orbital nature of Na?Ti?Sb?O. Photon energy dependent ARPES results suggest that the electronic structure of Na?Ti?Sb?O is rather two-dimensional. Moreover, we find a density wave energy gap forms below the transition temperature and reaches 65 meV atmore7 K, indicating that Na?Ti?Sb?O is likely a weakly correlated CDW material in the strong electron-phonon interaction regime. (author)less

  13. Photoemission study of the electronic structure and charge density waves of Na?Ti?Sb?O

    SciTech Connect (OSTI)

    Tan, S. Y.; Jiang, J.; Ye, Z. R.; Niu, X. H.; Song, Y.; Zhang, C. L.; Dai, P. C.; Xie, B. P.; Lai, X. C.; Feng, D. L.

    2015-04-30

    The electronic structure of Na?Ti?Sb?O single crystal is studied by photon energy and polarization dependent angle-resolved photoemission spectroscopy (ARPES). The obtained band structure and Fermi surface agree well with the band structure calculation of Na?Ti?Sb?O in the non-magnetic state, which indicates that there is no magnetic order in Na?Ti?Sb?O and the electronic correlation is weak. Polarization dependent ARPES results suggest the multi-band and multi-orbital nature of Na?Ti?Sb?O. Photon energy dependent ARPES results suggest that the electronic structure of Na?Ti?Sb?O is rather two-dimensional. Moreover, we find a density wave energy gap forms below the transition temperature and reaches 65 meV at 7 K, indicating that Na?Ti?Sb?O is likely a weakly correlated CDW material in the strong electron-phonon interaction regime. (author)

  14. Influence of NaA Zeolite Crystal Expansion/Contraction on Zeolite Membrane Separations

    SciTech Connect (OSTI)

    Sorenson, Stephanie G; Payzant, E Andrew; Gibbons, Will T; Soydas, Belma; Kita, Hidetoshi; Noble, Richard D; Falconer, John L.

    2011-01-01

    In-situ powder XRD measurements showed that the NaA zeolite unit cell contracts and expands upon adsorption, and these changes in zeolite crystal size correlate with permeation changes through NaA zeolite membranes. These membranes had high pervaporation selectivities, even though gas permeation was mainly through defects, as indicated by Knudsen selectivities for gases. At 300 K and a thermodynamic activity of 0.03, water contracted the NaA crystals by 0.22 vol%, and this contraction increased the helium flux through two NaA membranes by approximately 80%. Crystal contraction also increased the fluxes of i-butane during vapor permeation and i-propanol (IPA) during pervaporation (~ 0.03 wt% water). At activities above 0.07, water expanded NaA crystals and correspondingly decreased the membrane fluxes of helium, i-butane, and IPA. Similarly, methanol contracted NaA crystals by 0.05 vol% at an activity of 0.02, and this contraction slightly increased the helium and i-butane fluxes through a NaA membrane. Above an activity of 0.06, methanol expanded the crystals, and the fluxes of helium and i-butane through a NaA membrane decreased. The adsorbate-induced changes explain some pervaporation behavior reported by others, and they indicate that crystal expansion and contraction may increase or decrease zeolite NaA membrane selectivity by changing the defect sizes.

  15. High Energy Density Na-S/NiCl2 Hybrid Battery

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Lemmon, John P.; Kim, Jin Yong; Sprenkle, Vincent L.; Yang, Zhenguo

    2013-02-15

    High temperature (250-350C) sodium-beta alumina batteries (NBBs) are attractive energy storage devices for renewable energy integration and other grid related applications. Currently, two technologies are commercially available in NBBs, e.g., sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries. In this study, we investigated the combination of these two chemistries with a mixed cathode. In particular, the cathode of the cell consisted of molten NaAlCl4 as a catholyte and a mixture of Ni, NaCl and Na2S as active materials. During cycling, two reversible plateaus were observed in cell voltage profiles, which matched electrochemical reactions for Na-S and Na-NiCl2 redox couples. An irreversible reaction between sulfur species and Ni was identified during initial charge at 280C, which caused a decrease in cell capacity. The final products on discharge included Na2Sn with 1< n < 3, which differed from Na2S3 found in traditional Na-S battery. Reduction of sulfur in the mixed cathode led to an increase in overall energy density over ZEBRA batteries. Despite of the initial drop in cell capacity, the mixed cathode demonstrated relatively stable cycling with more than 95% of capacity retained over 60 cycles under 10mA/cm2. Optimization of the cathode may lead to further improvements in battery performance.

  16. 2011 Annual Planning Summary for NNSA, Infrastructure and Environment (NA-50)

    Broader source: Energy.gov [DOE]

    The ongoing and projected Environmental Assessments and Environmental Impact Statements for 2011 and 2012 within NNSA, Infrastructure and Environment (NA-50).

  17. EA-372 GDF Suez Energy Marketing NA, Inc. | Department of Energy

    Energy Savers [EERE]

    2 GDF Suez Energy Marketing NA, Inc. EA-372 GDF Suez Energy Marketing NA, Inc. Order authorizing GDF Suez Energy Marketing NA, Inc. to export electric energy to Canada PDF icon EA-372 GDF Suez Energy Marketing NA, Inc. More Documents & Publications EA-386 IPR-GDF Suez Energy Marketing North America, Inc. (GSEMNA) Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF Suez Energy Marketing (Gsemna) Application to Export Electric Energy OE Docket No. EA-386 IPR-GDF SUEZ Energy

  18. Effects of Point Defects and Impurities on Kinetics in NaAlH4 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Point Defects and Impurities on Kinetics in NaAlH4 Effects of Point Defects and Impurities on Kinetics in NaAlH4 A presentation showing that point defects play an important role in the kinetics of NaAlH4 including vacancies and interstitials consistent with observed effects of Ti. PDF icon effects_of_point_defects.pdf More Documents & Publications Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 FTA - SunLine Transit Agency - Final Report Proceedings of the 1998 U.S. DOE

  19. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 A presentation about how hydrogen can be reversibly absorbed and desorbed from NaAlH4 under moderate conditions by the addition of catalysts. PDF icon catalytic_effect_of_ti.pdf More Documents & Publications Final Report for the DOE Metal Hydride Center of Excellence Effects of Point Defects and Impurities on Kinetics in NaAlH4 Prediction of New Hydrogen Storage Compounds

  20. NaRec New and Renewable Energy Centre | Open Energy Information

    Open Energy Info (EERE)

    New and Renewable Energy Centre Jump to: navigation, search Name: NaRec New and Renewable Energy Centre Region: United Kingdom Sector: Marine and Hydrokinetic Website: http: This...

  1. The (111) Surface of NaAu2. Structure, Composition, and Stability

    SciTech Connect (OSTI)

    Kwolek, Emma J.; Widmer, Roland; Grning, Oliver; Deniz, Okan; Walen, Holly; Yuen, Chad D.; Huang, Wenyu; Schlagel, Deborah L.; Wallingford, Mark; Thiel, Patricia A.

    2014-12-17

    The (111) surface of single-crystal NaAu2 is a model for catalytically active, powdered NaAu2. We prepare and characterize this surface with a broad suite of techniques. Preparation in ultrahigh vacuum consists of the traditional approach of ion bombardment (to remove impurities) and thermal annealing (to restore surface order). Both of these steps cause loss of sodium (Na), and repeated treatments eventually trigger conversion of the surface and near-surface regions to crystalline gold. The bulk has a limited ability to repopulate the surface Na. Under conditions where Na depletion is minimized, electron diffraction patterns are consistent with the bulk-terminated structure, and scanning tunneling microscopy reveals mesa-like features with lateral dimensions of a few tens of nanometers. The tops of the mesas do not possess fine structure characteristic of a periodic lattice, suggesting that the surface layer is disordered under the conditions of these experiments.

  2. Missouri Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 NA NA 2010's NA NA NA 0 0

  3. Missouri Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 0 NA NA 2010's NA NA NA 0 0

  4. NaIrO{sub 3}-A pentavalent post-perovskite

    SciTech Connect (OSTI)

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-03-15

    Sodium iridium (V) oxide, NaIrO{sub 3,} was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO{sub 3}, synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO{sub 3} post-perovskite. Research highlights: {yields} NaIrO{sub 3} post-perovskite stabilized by pressure. {yields} First example of a pentavalent oxide post-perovskite. {yields} Non-metallic and non-magnetic behavior of NaIrO{sub 3}.

  5. Recent results from NA44 and a review of HBT

    SciTech Connect (OSTI)

    Jacak, B.V.

    1995-04-01

    High energy heavy ion collisions provide the opportunity to create hadronic matter at high energy density and study its properties. In order to do this, one must characterize the collisions, ascertain the size and density of the hot system in the central region of the nucleus-nucleus system, and determine the energy density achieved. Furthermore, one needs to determine whether or not the system approaches equilibrium so thermodynamic descriptions may be used. One of the experimental tools available is the study of two-particle correlations to map the space-time extent of the system when the hadrons decouple. Other observables include the flow of energy and charged particles transverse to the beam and the rapidity distribution of protons to indicate the amount of stopping and randomization of the incoming energy. The transverse mass distributions of hadrons reflect the temperature of the system at freezeout and effects of radial expansion. The production ratios of different particles are related to the extent of chemical equilibrium reached in the collision and subsequent evolution of the hadron gas. The NA44 Experiment at CERN can address all of these observables, though here the author focus mainly on correlation measurements. Kaons and pions are emitted rather late in the evolution of a heavy ion collision, at the time of {open_quotes}freezeout{close_quotes} when the hadrons cease to interact. Their correlations reflect the space-time evolution of the later part of the collision. In addition to characterizing the collision, correlations can signal a phase transition as they measure the duration of hadronization and particle emission, which should be long in both a first- or second-order phase transition. Furthermore, correlation measurements offer an important tool to help disentangle effects of expansion from the freezeout temperature reflected in the single particle spectra.

  6. Nebraska Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA 1991

  7. Kentucky Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA 1991

  8. Virginia Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA

  9. Oregon Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1996-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1996-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1996-2015 Vented and Flared NA NA NA NA NA NA 1996-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production NA NA NA NA NA NA

  10. Investigation of the Effects of Biodiesel-based Na on Emissions Control Components

    SciTech Connect (OSTI)

    Brookshear, D. William; Nguyen, Ke; Toops, Todd J; Bunting, Bruce G; Howe, Janet E

    2012-01-01

    A single-cylinder diesel engine was used to investigate the impact of biodiesel-based Na on emissions control components using specially blended 20% biodiesel fuel (B20). The emissions control components investigated were a diesel oxidation catalyst (DOC), a Cu-zeolite-based NH{sub 3}-SCR (selective catalytic reduction) catalyst, and a diesel particulate filter (DPF). Both light-duty vehicle, DOC-SCR-DPF, and heavy-duty vehicle, DOC-DPF-SCR, emissions control configurations were employed. The accelerated Na aging is achieved by introducing elevated Na levels in the fuel, to represent full useful life exposure, and periodically increasing the exhaust temperature to replicate DPF regeneration. To assess the validity of the implemented accelerated Na aging protocol, engine-aged lean NO{sub x} traps (LNTs), DOCs and DPFs are also evaluated. To fully characterize the impact on the catalytic activity the LNT, DOC and SCR catalysts were evaluated using a bench flow reactor. The evaluation of the aged DOC samples and LNT show little to no deactivation as a result of Na contamination. However, the SCR in the light-duty configuration (DOC-SCR-DPF) was severely affected by Na contamination, especially when NO was the only fed NO{sub x} source. In the heavy-duty configuration (DOC-DPF-SCR), no impact is observed in the SCR NO{sub x} reduction activity. Electron probe micro-analysis (EPMA) reveals that Na contamination on the LNT, DOC, and SCR samples is present throughout the length of the catalysts with a higher concentration on the washcoat surface. In both the long-term engine-aged DPF and the accelerated Na-aged DPFs, there is significant Na ash present in the upstream channels; however, in the engine-aged sample lube oil-based ash is the predominant constituent.

  11. Is Tritium over-regulated by DOE? Should the TFG support NA-1 SD G 1027

    Office of Environmental Management (EM)

    tritium values? | Department of Energy over-regulated by DOE? Should the TFG support NA-1 SD G 1027 tritium values? Is Tritium over-regulated by DOE? Should the TFG support NA-1 SD G 1027 tritium values? Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013. PDF icon Is Tritium over-regulated by DOE? Should the TFG support NA-1 SD G 1027 tritium values? More Documents & Publications Is Tritium Over-Regulated, Part 2 Should The TFG

  12. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Using Cu-zeolite | Department of Energy Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst PDF icon deer11_toops.pdf More Documents & Publications Impacts of Biodiesel on Emission Control

  13. The NA62 RICH Detector (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The NA62 RICH Detector Citation Details In-Document Search Title: The NA62 RICH Detector The goal of the CERN NA62 experiment is to measure the ultra-rare (Branching Ratio, BR {approx}10{sup -10}) charged kaon decay K{sup +}{yields}{pi}{sup +}vv-bar with an accuracy of 10%. The main background, the K{sup +}{yields}{mu}{sup +}v decay (BR {approx}63%), must be suppressed by a rejection factor of 4x10{sup -13}. This can be accomplished using a combination of several methods and detectors. The RICH

  14. MHK Projects/University of Manchester Phase 1 and 2 NaREC | Open...

    Open Energy Info (EERE)

    University of Manchester Phase 1 and 2 NaREC < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map... "minzoom":false,"mappingservice":"goo...

  15. Thermoelectric Enhancement in PbTe with K or Na codoping from...

    Office of Scientific and Technical Information (OSTI)

    We combined high-temperature Hall-effect, electrical conductivity, and thermal conductivity measurements to show that K-Na codoping do not form resonance states but can control the ...

  16. New and Renewable Energy Centre NaREC | Open Energy Information

    Open Energy Info (EERE)

    NE24 3AG Product: NaREC is a Centre of Excellence, fast-tracking concept evaluation, feasibility studies and prototype evaluation and testing through to early commercialisation....

  17. " East North Central",9.3,"NA",10.1,10.7,11.6,11.85822

    U.S. Energy Information Administration (EIA) Indexed Site

    (Thousands) " ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",9.4,9.9,10.2,10.6,11.4,12 "Household Characteristics" "Census Region and Division" " Northeast",9.5,"NA",10.3...

  18. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Krukowski, Elizabeth G; Goodman, Angela; Rother, Gernot; Ilton, Eugene; Guthrie, George; Bodnar, Robert

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate formore » CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.« less

  19. Phase transitions and compressibility of NaMgF[subscript 3] (Neighborite)

    Office of Scientific and Technical Information (OSTI)

    in perovskite- and post perovskite-related structures (Journal Article) | SciTech Connect Phase transitions and compressibility of NaMgF[subscript 3] (Neighborite) in perovskite- and post perovskite-related structures Citation Details In-Document Search Title: Phase transitions and compressibility of NaMgF[subscript 3] (Neighborite) in perovskite- and post perovskite-related structures Authors: Martin, C. David ; Crichton, Wilson A. ; Liu, Haozhe ; Prakapenka, Vitali ; Chen, Jiuhua ; Parise,

  20. Antiferromagnetism in the spin-gap system NaV2O5: Muon spin rotation

    Office of Scientific and Technical Information (OSTI)

    measurements (Journal Article) | SciTech Connect Journal Article: Antiferromagnetism in the spin-gap system NaV2O5: Muon spin rotation measurements Citation Details In-Document Search Title: Antiferromagnetism in the spin-gap system NaV2O5: Muon spin rotation measurements Authors: Storchak, Vyacheslav G. ; Parfenov, Oleg E. ; Eshchenko, Dmitry G. ; Lichti, Roger L. ; Mengyan, Patrick W. ; Isobe, Masahiko ; Ueda, Yutaka Publication Date: 2012-03-05 OSTI Identifier: 1099289 Type: Publisher's

  1. NNSA Supplemental Guidance: NA-1 SD G 1027 | Department of Energy

    Energy Savers [EERE]

    Supplemental Guidance: NA-1 SD G 1027 NNSA Supplemental Guidance: NA-1 SD G 1027 Guidance on using Release Fraction and Modern Dosimetric information consistently with DOE STD 1027-92, Hazard Categorization and Accident Analysis Techniques for Compliance with DOE Order 5480.23, Nuclear Safety Analysis Reports, Change Notice No. 1. This supplemental guidance was inspired by a desire within NNSA to update the radionuclide threshold values tabulated in DOE STD 1027-92 CN1. NNSA personnel

  2. Technical Qualification Program Self-Assessment Report - NA-SH - 2013 |

    Energy Savers [EERE]

    Department of Energy NA-SH - 2013 Technical Qualification Program Self-Assessment Report - NA-SH - 2013 DOE Federal Technical Capability Panel provides the requirements for the recruitment, deployment, development, and retention of federal personnel with demonstrated technical capability to safely accomplish the Department's missions and responsibilities. This Program applies to the National Nuclear Security Administration (NNSA) Headquarters (HQ) and Field organizations that have safety

  3. Band gap engineering for graphene by using Na{sup +} ions

    SciTech Connect (OSTI)

    Sung, S. J.; Lee, P. R.; Kim, J. G.; Ryu, M. T.; Park, H. M.; Chung, J. W.

    2014-08-25

    Despite the noble electronic properties of graphene, its industrial application has been hindered mainly by the absence of a stable means of producing a band gap at the Dirac point (DP). We report a new route to open a band gap (E{sub g}) at DP in a controlled way by depositing positively charged Na{sup +} ions on single layer graphene formed on 6H-SiC(0001) surface. The doping of low energy Na{sup +} ions is found to deplete the ?* band of graphene above the DP, and simultaneously shift the DP downward away from Fermi energy indicating the opening of E{sub g}. The band gap increases with increasing Na{sup +} coverage with a maximum E{sub g}?0.70?eV. Our core-level data, C 1s, Na 2p, and Si 2p, consistently suggest that Na{sup +} ions do not intercalate through graphene, but produce a significant charge asymmetry among the carbon atoms of graphene to cause the opening of a band gap. We thus provide a reliable way of producing and tuning the band gap of graphene by using Na{sup +} ions, which may play a vital role in utilizing graphene in future nano-electronic devices.

  4. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 98 96 99 75 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring

  5. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Tennessee Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 408 180 165 376 585 339 156 117 126 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  6. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Kentucky Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 6 15 0 1970's 0 0 0 0 0 0 0 0 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  7. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Ohio Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 0 0 0 330 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages:

  8. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Vented and Flared (Million Cubic Feet) Oklahoma Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 126,629 129,408 130,766 1970's 129,629 39,799 38,797 36,411 34,199 31,802 30,197 29,186 27,489 26,605 1980's 25,555 2000's 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release

  9. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Arizona Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 347 367 277 26 47 32 101 1980's 143 106 162 108 182 124 122 125 123 95 1990's 22 56 23 21 8 0 0 1 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  10. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Florida Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 355 284 837 607 1980's 677 428 435 198 34 13 54 30 166 450 1990's 286 482 245 205 220 28 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  11. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Ohio Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 0 0 0 330 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages:

  12. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Oklahoma Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 126,629 129,408 130,766 1970's 129,629 39,799 38,797 36,411 34,199 31,802 30,197 29,186 27,489 26,605 1980's 25,555 2000's 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release

  13. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 98 96 99 75 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring

  14. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Tennessee Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 408 180 165 376 585 339 156 117 126 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  15. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Florida Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 355 284 837 607 1980's 677 428 435 198 34 13 54 30 166 450 1990's 286 482 245 205 220 28 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  16. Illinois Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Illinois Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 126 102 93 1970's 122 3,997 1,806 0 0 0 0 0 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  17. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Kentucky Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 6 15 0 1970's 0 0 0 0 0 0 0 0 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  18. Assessing out-of-band flare effects at the wafer level for EUV lithography

    SciTech Connect (OSTI)

    George, Simi; Naulleau, Patrick; Kemp, Charles; Denham, Paul; Rekawa, Senajith

    2010-01-25

    To accurately estimate the flare contribution from the out-of-band (OOB), the integration of a DUV source into the SEMATECH Berkeley 0.3-NA Micro-field Exposure tool is proposed, enabling precisely controlled exposures along with the EUV patterning of resists in vacuum. First measurements evaluating the impact of bandwidth selected exposures with a table-top set-up and subsequent EUV patterning show significant impact on line-edge roughness and process performance. We outline a simulation-based method for computing the effective flare from resist sensitive wavelengths as a function of mask pattern types and sizes. This simulation method is benchmarked against measured OOB flare measurements and the results obtained are in agreement.

  19. Ordered and disordered polymorphs of Na(Ni2/3Sb1/3)O₂: Honeycomb-ordered cathodes for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ma, Jeffrey; Wu, Lijun; Bo, Shou -Hang; Khalifah, Peter G.; Grey, Clare P.; Zhu, Yimei

    2015-04-14

    Na-ion batteries are appealing alternatives to Li-ion battery systems for large-scale energy storage applications in which elemental cost and abundance are important. Although it is difficult to find Na-ion batteries which achieve substantial specific capacities at voltages above 3 V (vs Na⁺/Na), the honeycomb-layered compound Na(Ni2/3Sb1/3)O₂ can deliver up to 130 mAh/g of capacity at voltages above 3 V with this capacity concentrated in plateaus at 3.27 and 3.64 V. Comprehensive crystallographic studies have been carried out in order to understand the role of disorder in this system which can be prepared in both “disordered” and “ordered” forms, depending onmore » the synthesis conditions. The average structure of Na(Ni2/3Sb1/3)O₂ is always found to adopt an O3-type stacking sequence, though different structures for the disordered (R3¯m, #166, a = b = 3.06253(3) Å and c = 16.05192(7) Å) and ordered variants (C2/m, #12, a = 5.30458(1) Å, b = 9.18432(1) Å, c = 5.62742(1) Å and β = 108.2797(2)°) are demonstrated through the combined Rietveld refinement of synchrotron X-ray and time-of-flight neutron powder diffraction data. However, pair distribution function studies find that the local structure of disordered Na(Ni2/3Sb1/3)O₂ is more correctly described using the honeycomb-ordered structural model, and solid state NMR studies confirm that the well-developed honeycomb ordering of Ni and Sb cations within the transition metal layers is indistinguishable from that of the ordered phase. The disorder is instead found to mainly occur perpendicular to the honeycomb layers with an observed coherence length of not much more than 1 nm seen in electron diffraction studies. When the Na environment is probed through ²³Na solid state NMR, no evidence is found for prismatic Na environments, and a bulk diffraction analysis finds no evidence of conventional stacking faults. The lack of long range coherence is instead attributed to disorder among the three possible choices for distributing Ni and Sb cations into a honeycomb lattice in each transition metal layer. It is observed that the full theoretical discharge capacity expected for a Ni³⁺/²⁺ redox couple (133 mAh/g) can be achieved for the ordered variant but not for the disordered variant (~110 mAh/g). The first 3.27 V plateau during charging is found to be associated with a two-phase O3 ↔ P3 structural transition, with the P3 stacking sequence persisting throughout all further stages of desodiation.« less

  20. The (111) Surface of NaAu2. Structure, Composition, and Stability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kwolek, Emma J.; Widmer, Roland; Gröning, Oliver; Deniz, Okan; Walen, Holly; Yuen, Chad D.; Huang, Wenyu; Schlagel, Deborah L.; Wallingford, Mark; Thiel, Patricia A.

    2014-12-17

    The (111) surface of single-crystal NaAu2 is a model for catalytically active, powdered NaAu2. We prepare and characterize this surface with a broad suite of techniques. Preparation in ultrahigh vacuum consists of the traditional approach of ion bombardment (to remove impurities) and thermal annealing (to restore surface order). Both of these steps cause loss of sodium (Na), and repeated treatments eventually trigger conversion of the surface and near-surface regions to crystalline gold. The bulk has a limited ability to repopulate the surface Na. Under conditions where Na depletion is minimized, electron diffraction patterns are consistent with the bulk-terminated structure, andmore » scanning tunneling microscopy reveals mesa-like features with lateral dimensions of a few tens of nanometers. The tops of the mesas do not possess fine structure characteristic of a periodic lattice, suggesting that the surface layer is disordered under the conditions of these experiments.« less

  1. Mississippi Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    2-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1996-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA 1989-2015 Dry Production 2006

  2. Missouri Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    7-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA 1991-2015 Dry Production 2007

  3. Maryland Natural Gas Gross Withdrawals and Production

    Gasoline and Diesel Fuel Update (EIA)

    6-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production NA NA NA NA NA NA 1991

  4. New tetragonal derivatives of cubic NaZn{sub 13}-type structure: RNi{sub

    Office of Scientific and Technical Information (OSTI)

    6}Si{sub 6} compounds, crystal structure and magnetic ordering (R=Y, La, Ce, Sm, Gd-Yb) (Journal Article) | SciTech Connect New tetragonal derivatives of cubic NaZn{sub 13}-type structure: RNi{sub 6}Si{sub 6} compounds, crystal structure and magnetic ordering (R=Y, La, Ce, Sm, Gd-Yb) Citation Details In-Document Search Title: New tetragonal derivatives of cubic NaZn{sub 13}-type structure: RNi{sub 6}Si{sub 6} compounds, crystal structure and magnetic ordering (R=Y, La, Ce, Sm, Gd-Yb) Novel

  5. Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by

    Office of Scientific and Technical Information (OSTI)

    NH3 Over Cu-zeolite Catalysts (Journal Article) | SciTech Connect Journal Article: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Authors: Brookshear, D. William [1] ; Nguyen, Ke [1] ; Toops, Todd J [2] ; Bunting, Bruce G [2] ; Rohr, William F [2] + Show Author Affiliations University of

  6. Erratum: Coulomb excitation of the proton-dripline nucleus {sup 20}Na

    Office of Scientific and Technical Information (OSTI)

    [Phys. Rev. C 80, 044325 (2009)] (Journal Article) | SciTech Connect Erratum: Coulomb excitation of the proton-dripline nucleus {sup 20}Na [Phys. Rev. C 80, 044325 (2009)] Citation Details In-Document Search Title: Erratum: Coulomb excitation of the proton-dripline nucleus {sup 20}Na [Phys. Rev. C 80, 044325 (2009)] No abstract prepared. Authors: Schumaker, M. A. ; Cline, D. ; Hackman, G. ; Pearson, C. J. ; Svensson, C. E. ; Wu, C. Y. ; Andreyev, A. ; Austin, R. A. E. ; Ball, G. C. ;

  7. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect FT-IR Study of CO2 Interaction with Na-rich Montmorillonite Citation Details In-Document Search Title: FT-IR Study of CO2 Interaction with Na-rich Montmorillonite Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature

  8. NaI (Tl) Calorimeter Calibration and Simulation for Coulomb Sum Rule

    Office of Scientific and Technical Information (OSTI)

    Experiment in Hall-A at Jefferson Lab (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: NaI (Tl) Calorimeter Calibration and Simulation for Coulomb Sum Rule Experiment in Hall-A at Jefferson Lab Citation Details In-Document Search Title: NaI (Tl) Calorimeter Calibration and Simulation for Coulomb Sum Rule Experiment in Hall-A at Jefferson Lab A precision measurement of inclusive electron scattering cross sections was carried out at Jefferson Lab in the

  9. POST-OPERATIONAL TREATMENT OF RESIDUAL NA COOLLANT IN EBR-2 USING CARBONATION

    SciTech Connect (OSTI)

    Sherman, S.; Knight, C.

    2011-03-08

    At the end of 2002, the Experimental Breeder Reactor Two (EBR-II) facility became a U.S. Resource Conservation and Recovery Act (RCRA) permitted site, and the RCRA permit1 compelled further treatment of the residual sodium in order to convert it into a less reactive chemical form and remove the by-products from the facility, so that a state of RCRA 'closure' for the facility may be achieved (42 U.S.C. 6901-6992k, 2002). In response to this regulatory driver, and in recognition of project budgetary and safety constraints, it was decided to treat the residual sodium in the EBR-II primary and secondary sodium systems using a process known as 'carbonation.' In early EBR-II post-operation documentation, this process is also called 'passivation.' In the carbonation process (Sherman and Henslee, 2005), the system containing residual sodium is flushed with humidified carbon dioxide (CO{sub 2}). The water vapor in the flush gas reacts with residual sodium to form sodium hydroxide (NaOH), and the CO{sub 2} in the flush gas reacts with the newly formed NaOH to make sodium bicarbonate (NaHCO{sub 3}). Hydrogen gas (H{sub 2}) is produced as a by-product. The chemical reactions occur at the exposed surface of the residual sodium. The NaHCO{sub 3} layer that forms is porous, and humidified carbon dioxide can penetrate the NaHCO{sub 3} layer to continue reacting residual sodium underneath. The rate of reaction is controlled by the thickness of the NaHCO{sub 3} surface layer, the moisture input rate, and the residual sodium exposed surface area. At the end of carbonation, approximately 780 liters of residual sodium in the EBR-II primary tank ({approx}70% of original inventory), and just under 190 liters of residual sodium in the EBR-II secondary sodium system ({approx}50% of original inventory), were converted into NaHCO{sub 3}. No bare surfaces of residual sodium remained after treatment, and all remaining residual sodium deposits are covered by a layer of NaHCO{sub 3}. From a safety standpoint, the inventory of residual sodium in these systems was greatly reduced by using the carbonation process. From a regulatory standpoint, the process was not able to achieve deactivation of all residual sodium, and other more aggressive measures will be needed if the remaining residual sodium must also be deactivated to meet the requirements of the existing environmental permit. This chapter provides a project history and technical summary of the carbonation of EBR-II residual sodium. Options for future treatment are also discussed.

  10. Study of the nanobubble phase of aqueous NaCl solutions by dynamic light scattering

    SciTech Connect (OSTI)

    Bunkin, N F; Shkirin, A V [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Burkhanov, I S; Chaikov, L L [P N Lebedev Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Lomkova, A K [N.E. Bauman Moscow State Technical University, Moscow (Russian Federation)

    2014-11-30

    Aqueous NaCl solutions with different concentrations have been investigated by dynamic scattering of laser radiation. It is experimentally shown that these solutions contain scattering particles with a wide size distribution in a range of ?10 100 nm. The experimental results indirectly confirm the existence of quasi-stable gas nanobubbles in the bulk of aqueous ionic solutions. (light scattering)

  11. LANL surveillance requirements management and surveillance requirements from NA-12 tasking memo

    SciTech Connect (OSTI)

    Hills, Charles R

    2011-01-25

    Surveillance briefing to NNSA to support a tasking memo from NA-12 on Surveillance requirements. This talk presents the process for developing surveillance requirements, discusses the LANL requirements that were issued as part of that tasking memo, and presents recommendations on Component Evaluation and Planning Committee activities for FY11.

  12. Consequence analysis of an unmitigated NaOH solution spray release during addition to waste tank

    SciTech Connect (OSTI)

    Himes, D.A., Westinghouse Hanford

    1996-08-21

    Toxicological consequences were calculated for a postulated maximum caustic soda (NaOH) solution spray leak during addition to a waste tank to adjust tank pH. Although onsite risk guidelines were exceeded for the unmitigated release, site boundary consequences were below the level of concern. Means of mitigating the release so as to greatly reduce the onsite consequences were recommended.

  13. Consequence analysis of a postulated NaOH release from the 2727-W sodium storage facility

    SciTech Connect (OSTI)

    Himes, D.A.

    1996-09-27

    Toxicological and radiological consequences were calculated for a maximum sodium fire in the 2727-W Sodium Storage Facility. The sodium is solid and cannot leak out of the tanks. The maximum fire therefore corresponded to the maximum cross-sectional area of one tank. It was shown that release of the entire facility inventory of 22 Na is insufficient to produce an appreciable effect.

  14. Ion-conduction mechanisms in NaSICON-type membranes for energy storage and utilization

    SciTech Connect (OSTI)

    McDaniel, Anthony H.; Ihlefeld, Jon F.; Bartelt, Norman Charles

    2015-10-01

    Next generation metal-ion conducting membranes are key to developing energy storage and utilization technologies like batteries and fuel ce lls. Sodium super-ionic conductors (aka NaSICON) are a class of compounds with AM 1 M 2 (PO 4 ) 3 stoichiometry where the choice of "A" and "M" cation varies widely. This report, which de scribes substitutional derivatives of NZP (NaZr 2 P 3 O 12 ), summarizes the accomplishments of a Laboratory D irected Research and Development (LDRD) project to analyze transport mec hanisms using a combination of in situ studies of structure, composition, and bonding, com bined with first principles theory and modeling. We developed an experimental platform and applied methods, such as synchrotron- based X-ray spectroscopies, to probe the electronic structure of compositionally well-controlled NaSICON films while in operation ( i.e ., conducting Na ions exposed to oxygen or water va por atmospheres). First principles theory and modeling were used to interpret the experimental observations and develop an enhanced understanding of atomistic processes that give rise to, and affect, ion conduction.

  15. K{sub 2}NaOsO{sub 5.5} and K{sub 3}NaOs{sub 2}O{sub 9}: The first osmium perovskites containing alkali cations at the 'A' site

    SciTech Connect (OSTI)

    Mogare, Kailash M.; Klein, Wilhelm; Jansen, Martin

    2012-07-15

    K{sub 2}NaOsO{sub 5.5} and K{sub 3}NaOs{sub 2}O{sub 9} were obtained from solid-state reactions of potassium superoxide, sodium peroxide and osmium metal at elevated oxygen pressures. K{sub 2}NaOsO{sub 5.5} crystallizes as an oxygen-deficient cubic double perovskite in space group Fm3{sup Macron }m with a=8.4184(5) A and contains isolated OsO{sub 6} octahedra. K{sub 3}NaOs{sub 2}O{sub 9} crystallizes hexagonally in P6{sub 3}/mmc with a=5.9998(4) A and c=14.3053(14) A. K{sub 3}NaOs{sub 2}O{sub 9} consists of face sharing Os{sub 2}O{sub 9} pairs of octahedra. According to magnetic measurements K{sub 2}NaOsO{sub 5.5} is diamagnetic, whereas K{sub 3}NaOs{sub 2}O{sub 9} displays strong antiferromagnetic coupling (T{sub N}=140 K), indicating enhanced magnetic interactions within the octahedral pair. - Graphical abstract: High oxidation states of Os, obtained by high oxygen pressure synthesis, are accommodated in double and triple perovskite matrices. K{sub 3}NaOs{sub 2}O{sub 9} displays enhanced magnetic interactions. Highlights: Black-Right-Pointing-Pointer New osmates containing highly oxidized Os were obtained by high O{sub 2} pressure synthesis. Black-Right-Pointing-Pointer High oxidation states of Os are accommodated in double and triple perovskite matrices. Black-Right-Pointing-Pointer Both compounds represent the first Os perovskites with an alkali metal at the A site. Black-Right-Pointing-Pointer K{sub 3}NaOs{sub 2}O{sub 9} displays enhanced magnetic interactions within the octahedral pair.

  16. 20Na

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  17. Photoresponsive Release from Azobenzene-Modified Single Cubic Crystal NaCl/Silica Particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Xingmao; Liu, Nanguo; Assink, Roger A.; Jiang, Yingbing; Brinker, C. Jeffrey

    2011-01-01

    Azobenzene ligands were uniformly anchored to the pore surfaces of nanoporous silica particles with single crystal NaCl using 4-(3-triethoxysilylpropylureido)azobenzene (TSUA). The functionalization delayed the release of NaCl significantly. The modified particles demonstrated a photocontrolled release by trans/cis isomerization of azobenzene moieties. The addition of amphiphilic solvents, propylene glycol (PG), propylene glycol propyl ether (PGPE), and dipropylene glycol propyl ether (DPGPE) delayed the release in water, although the wetting behavior was improved and the delay is the most for the block molecules with the longest carbon chain. The speedup by UV irradiation suggests a strong dependence of diffusion on the switchablemore » pore size. TGA, XRD, FTIR, and NMR techniques were used to characterize the structures.« less

  18. Groundwater quality assessment plan for the 1324-N/NA Site: Phase 1 (first determination)

    SciTech Connect (OSTI)

    Hartman, M.J.

    1998-05-01

    The 1324-N Surface Impoundment and 1324-NA Percolation Pond (1324-N/NA Site) are treatment/storage/disposal sites regulated under the Resource Conservation and Recovery Act of 1976 (RCRA). They are located in the 100-N Area of the Hanford Site, and were used to treat and dispose of corrosive waste from a water treatment plant. Groundwater monitoring under an interim-status detection program compared indicator parameters from downgradient wells to background values established from an upgradient well. One of the indicator parameters, total organic carbon (TOC), exceeded its background value in one downgradient well, triggering an upgrade from a detection program to an assessment program. This plan presents the first phase of the assessment program.

  19. Consequence analysis of a postulated NaOH release from the 2727-W sodium storage facility

    SciTech Connect (OSTI)

    Himes, D.A., Westinghouse Hanford

    1996-08-02

    Toxicological and radiological consequences were calculated for a maximum sodium fire in the 2727-W Sodium Storage Facility. The sodium is solid and cannot leak out of the tanks. The maximum fire therefore corresponded to the maximum cross-sectional area of one tank. It was shown that release of the entire facility inventory of {sup 22}Na is insufficient to produce an appreciable effect.

  20. by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

    Broader source: Energy.gov (indexed) [DOE]

    work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. Richard A. Rankin Director, Industrial Partnerships Office and Interim Director Economic Development Office 22 May 2015 LLNL-PRES-670964 Lawrence Livermore National Laboratory LLNL-PRES-670964 From a mission-focus perspective, there are four areas where the nature of the security mission means interacting with private sector owners, and operators: *

  1. 3.04 DOE.NA-0014 Stockpile Stewardship Plan.pdf

    National Nuclear Security Administration (NNSA)

    OVERVIEW DOE/NA-0014 November 13, 2006 STOCKPILE STEWARDSHIP PLAN STOCKPILE STEWARDSHIP PLAN United States Department of Energy National Nuclear Security Administration 1000 Independence Avenue, SW Washington, D.C. 20585 FISCAL YEAR 2007 - 2011 FISCAL YEAR 2007 - 2011 OVERVIEW Warhead W76 W88 Weapon System D5 Missile, Trident Submarine D5 Missile, Trident Submarine Laboratories Los Alamos/ Sandia Los Alamos/ Sandia Mission Underwater to Surface Underwater to Surface Military Service Navy Navy

  2. Computational observation of enhanced solvation of the hydroxyl radical with increased NaCl concentration

    SciTech Connect (OSTI)

    Wick, Collin D.; Dang, Liem X.

    2006-05-11

    Classical molecular dynamics simulations with many-body potentials were carried out to quantitatively determine the effect of NaCl salt concentration on the aqueous solvation and surface concentration of hydroxyl radicals. The potential of mean force technique was used to track the incremental free energy of the hydroxyl radical from the vapor, crossing the air-water interface into the aqueous bulk. Results showed increased NaCl salt concentration significantly enhanced hydroxyl radical solvation, which should significantly increase its accommodation on water droplets. This has been experimentally observed for ozone aqueous accommodation with increased NaI concentration, but to our knowledge, no experimental study has probed this for hydroxyl radicals. The origin for this effect was found to be very favorable hydroxyl radical-chloride ion interactions, being stronger than for water-chloride. This work was performed at Pacific Northwest National Laboratory (PNNL) under the auspices of the Division of Chemical Sciences, Office of Basic Energy Sciences, U.S. Department of Energy. Battelle operates PNNL for the Department of Energy.

  3. Effects of dilute aqueous NaCl solution on caffeine aggregation

    SciTech Connect (OSTI)

    Sharma, Bhanita; Paul, Sandip

    2013-11-21

    The effect of salt concentration on association properties of caffeine molecule was investigated by employing molecular dynamics simulations in isothermal-isobaric ensemble of eight caffeine molecules in pure water and three different salt (NaCl) concentrations, at 300 K temperature and 1 atm pressure. The concentration of caffeine was taken almost at the solubility limit. With increasing salt concentration, we observe enhancement of first peak height and appearance of a second peak in the caffeine-caffeine distribution function. Furthermore, our calculated solvent accessible area values and cluster structure analyses suggest formation of higher order caffeine cluster on addition of salt. The calculated hydrogen bond properties reveal that there is a modest decrease in the average number of water-caffeine hydrogen bonds on addition of NaCl salt. Also observed are: (i) decrease in probability of salt contact ion pair as well as decrease in the solvent separated ion pair formation with increasing salt concentration, (ii) a modest second shell collapse in the water structure, and (iii) dehydration of hydrophobic atomic sites of caffeine on addition of NaCl.

  4. Synthesis and crystal structure of NaNb{sub 2}AsO{sub 8}

    SciTech Connect (OSTI)

    Harrison, W.T.A.; Liang, C.S.; Stucky, G.D.; Nenoff, T.M.

    1994-12-01

    The high-temperature/high-pressure hydrothermal synthesis and X-ray single crystal structure of NaNb{sub 2}AsO{sub 8} are reported. The title compound contains a three-dimensional network of NbO{sub 6}, NbO{sub 5}, and AsO{sub 4} groups, enclosing one-dimensional channels containing seven-coordinate guest sodium cations. UV/visible measurements on NaNb{sub 2}AsO{sub 8} indicate two distinct absorption features at {approximately}285 and {approximately} 360 nm. Crystal data for NaNb{sub 2}AsO{sub 8}:M{sub r} = 410.79, monoclinic, P2{sub 1}/n(No.14), a = 4.8970(6) {angstrom}, b = 8.516(2) {angstrom}, c = 15.075(3) {angstrom}, {beta} = 98.971(6){degrees}, V = 620.98 {angstrom}{sup 3}, Z = 4, R = 5.31%, R{sub w} = 5.15%, 2121 observed reflections (I > 3{sigma}(I)).

  5. Europium (Z=63) n=3-3 lines in the extreme ultraviolet: Na- through Si-like

    Office of Scientific and Technical Information (OSTI)

    ions (Journal Article) | SciTech Connect Europium (Z=63) n=3-3 lines in the extreme ultraviolet: Na- through Si-like ions Citation Details In-Document Search Title: Europium (Z=63) n=3-3 lines in the extreme ultraviolet: Na- through Si-like ions Authors: Trabert, E ; Beiersdorfer, P ; Hell, N ; Brown, G V Publication Date: 2014-08-22 OSTI Identifier: 1228017 Report Number(s): LLNL-JRNL-659246 DOE Contract Number: AC52-07NA27344 Resource Type: Journal Article Resource Relation: Journal Name:

  6. Synthesis and crystal structure of the palladium oxides NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Panin, Rodion V. Khasanova, Nellie R.; Abakumov, Artem M.; Antipov, Evgeny V.; Tendeloo, Gustaaf van; Schnelle, Walter

    2007-05-15

    NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4} have been prepared by solid-state reaction of Na{sub 2}O{sub 2} or KO{sub 2} and PdO in sealed silica tubes. Crystal structures of the synthesized phases were refined by the Rietveld method from X-ray powder diffraction data. NaPd{sub 3}O{sub 4} (space group Pm3-barn, a=5.64979(6) A, Z=2) is isostructural to NaPt{sub 3}O{sub 4}. It consists of NaO{sub 8} cubes and PdO{sub 4} squares, corner linked into a three-dimensional framework where the planes of neighboring PdO{sub 4} squares are perpendicular to each other. Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2){sup o}, Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations alternate with Na{sub 3} layers along the c-axis. Na{sub 2}PdO{sub 3} exhibits a stacking disorder, detected by electron diffraction and Rietveld refinement. K{sub 3}Pd{sub 2}O{sub 4}, prepared for the first time, crystallizes in the orthorhombic space group Cmcm (a=6.1751(6) A, b=9.1772(12) A, c=11.3402(12) A, Z=4). Its structure is composed of planar PdO{sub 4} units connected via common edges to form parallel staggered PdO{sub 2} strips, where potassium atoms are located between them. Magnetic susceptibility measurements of K{sub 3}Pd{sub 2}O{sub 4} reveal a Curie-Weiss behavior in the temperature range above 80 K. - Graphical abstract: Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2), Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations (NaPd{sub 2}O{sub 6} slabs) alternate with Na{sub 3} layers along the c-axis.

  7. FY14 Annual Report for NA-22 Project LA14-FY14-027-PD2Jb "Developing...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: FY14 Annual Report for NA-22 Project LA14-FY14-027-PD2Jb "Developing Accurate Simulations of Correlated Data in Fission Events" Citation Details In-Document...

  8. Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}

    SciTech Connect (OSTI)

    Giot, Maud; Chapon, Laurent C.; Radaelli, Paolo G.; Androulakis, John; Lappas, Alexandros; Green, Mark A.

    2007-12-14

    The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

  9. Document: NA Actionee: Dorothy Riehie Document Date: 03/09/2011 Due Date: NO ACTION

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SN~T op Document: NA Actionee: Dorothy Riehie Document Date: 03/09/2011 Due Date: NO ACTION I Author: ALDRIDGE M Addressee: RIEHLE DC 7PES 01 Title: Re: Prime Contract # DE-AC06-08RL14788 Drilling Project Contract #41293-l:ARRA 300-FF-5 RJ/FS Installation of 11I Extract/Inj. Wells DIR DIV NAME DIR DIV NAME MGR AMRC ______ __ DEP AMSE _______ ___ AMA ___EMD____ FMD QOD HRM SED PRO 0CC ______________ AMCP _________OE Riehie, Dorothy (Actionee) AMMS ORP ______________ 15 _____________ PNSO PIC RLCI

  10. Document: NA Document Date: 12/12/20 11 Actionee: Dorothy Riehie

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document: NA Document Date: 12/12/20 11 Actionee: Dorothy Riehie QMACDONALD Due Date: NO ACTION ~ti)Author: HOAGUE & BAYLESS ~TES o1 Addressee: RIEHLE D Title: FREEDOM OF INFORMATION ACT REQUEST DIR DIV NAME DIR DIV NAME MGR AMMS DEP AMMS ISI AMA AMMS PLC AMA FMD AMMS SES AMA HRM AMMS SSD AMA PRO AMRC AMCP AMSE AMSE EMD AMSE OOD AMSE SED 0CC OCE Riehle, Dorothy (Actionee) ORP PNSO RLCI Comments: ORIGINAL TO RIEHLE. Records Schedule Information: ADM-1.28.1 Scan?: Yes Sensitive?: Yes Sensitive

  11. NA-ASC-500-13 Issue 26 ASC eNews Quarterly Newsletter

    National Nuclear Security Administration (NNSA)

    NA-ASC-500-13 Issue 26 ASC eNews Quarterly Newsletter December 2013 2 shutdown. But the two-year budget agreement is not an appropriation, so we must await final appropriations for both FY14 and FY15. The President also signed the National Defense Authorization Act into law, which directs NNSA to develop and carry out a plan to incorporate exascale computing in the Stockpile Stewardship Program. This is not an exascale program, but recognition that stockpile stewardship requires exascale

  12. Los Alamos National Security, LLC Contract No. DE-AC52-06NA25396

    National Nuclear Security Administration (NNSA)

    Los Alamos National Security, LLC Contract No. DE-AC52-06NA25396 Attachment to Modification No. 150 PART III - SECTION J APPENDIX G October 5, 2010 [Modified by Modification No. A009, A015, A018, A019, A021, A027, M033, M041, M042, M046, M056, M062, M069, M078, M103, M133, 150] LIST OF APPLICABLE DIRECTIVES In addition to the list of applicable directives listed below, the Contractor shall also comply with supplementary directives, (e.g., manuals) which are invoked by a Contractor Requirements

  13. OFFICE OF CIVIL RIGHTS NA-1.2 VIDEO LIBRARY Item Title

    National Nuclear Security Administration (NNSA)

    OFFICE OF CIVIL RIGHTS NA-1.2 VIDEO LIBRARY Item # Title # of copies DVD / CD Length Year Publisher 1 A Clear Picture - Harassment in the Public Sector- Una Imagen Clara Acosoen el Sector Publico 1 DVD 2008 Coastal Training Technologies Corp. A Dupont Company 2 Harassment Hurts: It's Personal 1 DVD 16 min 2009 ATS Media 3 Harassment Is .. (government version) 1 DVD 21 min 2005 Coastal Training Technologies Corp. A Dupont Company 4 Harassment Made Simple 1 DVD 6 min 2011 TrainingABC 5 Harassment

  14. Honeywell FM&T, LLC Contract No. DE-NA0000622

    National Nuclear Security Administration (NNSA)

    FM&T, LLC Contract No. DE-NA0000622 Modification No. 016 Page 2 of 10 1. Part II - Contract Clauses. The following Section I clause is revised and replaced in its entirety as follows: I-11 52.204-4 PRINTED OR COPIED DOUBLE-SIDED ON POSTCONSUMER FIBER CONTENT PAPER (MAY 2011) (a) Definitions. As used in this clause- "Postconsumer fiber" means- (1) Paper, paperboard, and fibrous materials from retail stores, office buildings, homes, and so forth, after they have passed through their

  15. Missouri Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA 9 9 1967-2014 From Gas Wells NA NA NA NA 8 8 1967-2014 From Oil Wells NA NA NA NA 1 * 2007-2014 From Shale Gas Wells NA NA NA NA 0 0 2007-2014 From Coalbed Wells NA NA NA NA 0 0 2007-2014 Repressuring NA NA NA NA 0 0 2007-2014 Vented and Flared NA NA NA NA 0 0 2007-2014 Nonhydrocarbon Gases Removed NA NA NA NA 0 0 2007-2014 Marketed Production NA NA NA NA 9 9 1967-2014 Dry Production NA NA NA NA 9 9

  16. Development of high-performance Na/NiCl{sub 2} cell

    SciTech Connect (OSTI)

    Redey, L.: Prakash, J.; Vissers, D.R.; Myles, K.M.

    1992-07-01

    The performance of the Ni/NiCl{sub 2} positive electrode for the Na/NiCl{sub 2} battery has been significantly improved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even below 200{degrees}C and can be recharged within one hour. The performance of this new electrode was measured by a conventional galvanostatic method and by a newly developed ``powerdynamic`` method. These measurements were used to project the performance of 40 to 60-kWh batteries built with this new electrode combined with already highly developed sodium/{beta} -- alumina negative electrode. These calculated results yielded a specific power of 150--400 W/kg and a specific energy of 110--200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the NA/NiCl{sub 2} battery attractive for electric vehicle applications.

  17. Development of high-performance Na/NiCl sub 2 cell

    SciTech Connect (OSTI)

    Redey, L.: Prakash, J.; Vissers, D.R.; Myles, K.M.

    1992-01-01

    The performance of the Ni/NiCl{sub 2} positive electrode for the Na/NiCl{sub 2} battery has been significantly improved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even below 200{degrees}C and can be recharged within one hour. The performance of this new electrode was measured by a conventional galvanostatic method and by a newly developed powerdynamic'' method. These measurements were used to project the performance of 40 to 60-kWh batteries built with this new electrode combined with already highly developed sodium/{beta} -- alumina negative electrode. These calculated results yielded a specific power of 150--400 W/kg and a specific energy of 110--200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the NA/NiCl{sub 2} battery attractive for electric vehicle applications.

  18. Characterization of Na+- beta-Zeolite Supported Pd and Pd Ag Bimetallic Catalysts using EXAFS, TEM and Flow Reactor

    SciTech Connect (OSTI)

    Huang,W.; Lobo, R.; Chen, J.

    2008-01-01

    Flow reactor studies of the selective hydrogenation of acetylene in the presence of ethylene have been performed on Na+ exchanged {beta}-zeolite supported Pd, Ag and PdAg catalysts, as an extension of our previous batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. Results from flow reactor studies show that the PdAg/Na+-{beta}-zeolite bimetallic catalyst has lower activity than Pd/Na+-{beta}-zeolite monometallic catalyst, while Ag/Na+-{beta}-zeolite does not show any activity for acetylene hydrogenation. However, the selectivity for the PdAg bimetallic catalyst is much higher than that for either the Pd catalyst or Ag catalyst. The selectivity to byproduct (ethane) is greatly inhibited on the PdAg bimetallic catalyst as well. The results from the current flow reactor studies confirmed the pervious results from batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. In addition, we used transmission electron microscope (TEM), extended X-ray absorption fine structure (EXAFS), and FTIR of CO adsorption to confirm the formation of Pd-Ag bimetallic alloy in the PdAg/Na+-{beta}-zeolite catalyst.

  19. Structural investigation and luminescence of nanocrystalline lanthanide doped NaNbO{sub 3} and Na{sub 0.5}K{sub 0.5}NbO{sub 3}

    SciTech Connect (OSTI)

    Pin, Sonia; Piccinelli, Fabio; Upendra Kumar, Kagola; Enzo, Stefano; Ghigna, Paolo; Cannas, Carla; Musinu, Anna; Mariotto, Gino; Bettinelli, Marco; Speghini, Adolfo

    2012-12-15

    Nd{sup 3+} and Eu{sup 3+} doped NaNbO{sub 3} and Na{sub 0.5}K{sub 0.5}NbO{sub 3} nanostructured multiferroics (nanoparticles or nanorods) were prepared by a sol-gel route. X-Ray powder diffraction results evidence that the sodium and mixed sodium-potassium niobates show orthorhombic (Pmc2{sub 1} space group), and monoclinic structure (Pm space group), respectively, confirmed by the Raman spectra. The local structure around the trivalent lanthanides was investigated with Extended X-ray Absorption Fine Structure spectroscopy at the Ln-K edge and luminescence spectroscopy. The Ln{sup 3+} ions enter the structure by substituting the alkali metals, with a 12-fold oxygen coordination, and inducing a large amount of static disorder. The visible emission bands of the Eu{sup 3+} ions indicate that multiple sites exist for the lanthanide ions, in agreement with the EXAFS results showing the largest amount of static disorder in these samples. A possible indication of clustering of oxygen vacancies around the Ln{sub Na} Double-Prime defect is obtained by VBS calculations. - Graphical Abstract: Ln{sup 3+} doped NaNbO{sub 3} and Na{sub 0.5}K{sub 0.5}NbO{sub 3} nanoparticles or nanorods can be prepared by a simple sol-gel procedure. The synergy of X-ray diffraction, EXAFS and luminescence spectroscopy gives important information on the Ln{sup 3+} local environment. Highlights: Black-Right-Pointing-Pointer Nd{sup 3+} and Eu{sup 3+} doped NaNbO{sub 3} and Na{sub 0.5}K{sub 0.5}NbO{sub 3} nanoparticles or nanorods are prepared by sol-gel. Black-Right-Pointing-Pointer EXAFS indicates that the Ln{sup 3+} ions substitutes the Na{sup +} and K{sup +} ions, inducing a large amount of static disorder. Black-Right-Pointing-Pointer The visible emission bands of the Eu{sup 3+} ions confirm that multiple sites exist for the lanthanide ions.

  20. Simulation of energy absorption spectrum in NaI crystal detector for multiple gamma energy using Monte Carlo method

    SciTech Connect (OSTI)

    Wirawan, Rahadi; Waris, Abdul; Djamal, Mitra; Handayani, Gunawan

    2015-04-16

    The spectrum of gamma energy absorption in the NaI crystal (scintillation detector) is the interaction result of gamma photon with NaI crystal, and it’s associated with the photon gamma energy incoming to the detector. Through a simulation approach, we can perform an early observation of gamma energy absorption spectrum in a scintillator crystal detector (NaI) before the experiment conducted. In this paper, we present a simulation model result of gamma energy absorption spectrum for energy 100-700 keV (i.e. 297 keV, 400 keV and 662 keV). This simulation developed based on the concept of photon beam point source distribution and photon cross section interaction with the Monte Carlo method. Our computational code has been successfully predicting the multiple energy peaks absorption spectrum, which derived from multiple photon energy sources.

  1. Mean ionic activity coefficients in aqueous NaCl solutions from molecular dynamics simulations

    SciTech Connect (OSTI)

    Mester, Zoltan; Panagiotopoulos, Athanassios Z.

    2015-01-28

    The mean ionic activity coefficients of aqueous NaCl solutions of varying concentrations at 298.15 K and 1 bar have been obtained from molecular dynamics simulations by gradually turning on the interactions of an ion pair inserted into the solution. Several common non-polarizable water and ion models have been used in the simulations. Gibbs-Duhem equation calculations of the thermodynamic activity of water are used to confirm the thermodynamic consistency of the mean ionic activity coefficients. While the majority of model combinations predict the correct trends in mean ionic activity coefficients, they overestimate their values at high salt concentrations. The solubility predictions also suffer from inaccuracies, with all models underpredicting the experimental values, some by large factors. These results point to the need for further ion and water model development.

  2. Nanocheckerboard modulations in (NaNd)(MgW)O[subscript 6

    SciTech Connect (OSTI)

    Licurse, Mark W.; Davies, Peter K.

    2010-10-22

    Data is presented for a complex structural and compositional modulation in the perovskite (NaNd)(MgW)O{sub 6}. This modulation creates a large 14a{sub p} x 14a{sub p} x 2a{sub p} supercell (a{sub p} {approx} 3.9 {angstrom} is the lattice parameter of the cubic perovskite aristotype) containing ordered regions with doubled (110) d-spacings in the a-b plane separated by two-dimensional periodic antiphase boundaries and accompanied by a nanocheckerboard pattern. Faint periodic modulations in Z-contrast images suggest an associated periodic variation in composition. The presence of a sodium rich impurity implies the composition of the stable perovskite is nonstoichiometric.

  3. Magnetically Driven Metal-Insulator Transition in NaOsO3

    SciTech Connect (OSTI)

    Calder, Stuart A [ORNL; Christianson, Andrew D [ORNL; Lumsden, Mark D [ORNL; Lang, Jonathan [Argonne National Laboratory (ANL); Stone, Matthew B [ORNL; McMorrow, D. F. [University College, London; Garlea, Vasile O [ORNL; Kim, Jong-Woo [Argonne National Laboratory (ANL); Schlueter, J. A. [Argonne National Laboratory (ANL); Shi, Y. G. [Chinese Academy of Sciences; Yamaura, K. [National Institute for Materials Science, Tsukuba, Japan; Sun, Y. S. [MANA; Tsujimoto, Y. [Kyoto University, Japan

    2012-01-01

    The metal-insulator transition (MIT) is one of the most dramatic manifestations of electron correlations in materials. Various mechanisms producing MITs have been extensively considered, including the Mott (electron localization via Coulomb repulsion), Anderson (localization via disorder), and Peierls (local- ization via distortion of a periodic one-dimensional lattice) mechanisms. One additional route to a MIT proposed by Slater, in which long-range magnetic order in a three dimensional system drives the MIT, has received relatively little attention. Using neutron and x-ray scattering we show that the MIT in NaOsO3 is coincident with the onset of long-range commensurate three dimensional magnetic order. While candidate materials have been suggested, our experimental methodology allows the first definitive demonstration of the long predicted Slater MIT.

  4. Total reflection infrared spectroscopy of water-ice and frozen aqueous NaCl solutions

    SciTech Connect (OSTI)

    Walker, Rachel L.; Searles, Keith; Willard, Jesse A.; Michelsen, Rebecca R. H., E-mail: RMichelsen@rmc.edu [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)] [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)

    2013-12-28

    Liquid-like and liquid water at and near the surface of water-ice and frozen aqueous sodium chloride films were observed using attenuated total reflection infrared spectroscopy (ATR-IR). The concentration of NaCl ranged from 0.0001 to 0.01 M and the temperature varied from the melting point of water down to 256 K. The amount of liquid brine at the interface of the frozen films with the germanium ATR crystal increased with salt concentration and temperature. Experimental spectra are compared to reflection spectra calculated for a simplified morphology of a uniform liquid layer between the germanium crystal and the frozen film. This morphology allows for the amount of liquid observed in an experimental spectrum to be converted to the thickness of a homogenous layer with an equivalent amount of liquid. These equivalent thickness ranges from a nanometer for water-ice at 260 K to 170 nm for 0.01 M NaCl close to the melting point. The amounts of brine observed are over an order of magnitude less than the total liquid predicted by equilibrium thermodynamic models, implying that the vast majority of the liquid fraction of frozen solutions may be found in internal inclusions, grain boundaries, and the like. Thus, the amount of liquid and the solutes dissolved in them that are available to react with atmospheric gases on the surfaces of snow and ice are not well described by thermodynamic equilibrium models which assume the liquid phase is located entirely at the surface.

  5. FY14 Annual Report for NA-22 Project LA14-FY14-027-PD2Jb "Developing

    Office of Scientific and Technical Information (OSTI)

    Accurate Simulations of Correlated Data in Fission Events" (Technical Report) | SciTech Connect Technical Report: FY14 Annual Report for NA-22 Project LA14-FY14-027-PD2Jb "Developing Accurate Simulations of Correlated Data in Fission Events" Citation Details In-Document Search Title: FY14 Annual Report for NA-22 Project LA14-FY14-027-PD2Jb "Developing Accurate Simulations of Correlated Data in Fission Events" Authors: Talou, Patrick [1] ; Vogt, Ramona [2] + Show

  6. Materials Data on Na3H5(CO2)4 (SG:2) by Materials Project (Dataset) | Data

    Office of Scientific and Technical Information (OSTI)

    Explorer Na3H5(CO2)4 (SG:2) by Materials Project Title: Materials Data on Na3H5(CO2)4 (SG:2) by Materials Project Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations Authors: Kristin Persson Publication Date: 2014-11-02 OSTI Identifier: 1183905 Report Number(s): mp-555083 DOE

  7. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  8. Microstructural and compositional change of NaOH-activated high calcium fly ash by incorporating Na-aluminate and co-existence of geopolymeric gel and C-S-H(I)

    SciTech Connect (OSTI)

    Oh, Jae Eun; Moon, Juhyuk; Oh, Sang-Gyun; Clark, Simon M.; Monteiro, Paulo J.M.

    2012-05-15

    This study explores the reaction products of alkali-activated Class C fly ash-based aluminosilicate samples by means of high-resolution synchrotron X-ray diffraction (HSXRD), scanning electron microscope (SEM), and compressive strength tests to investigate how the readily available aluminum affects the reaction. Class C fly ash-based aluminosilicate raw materials were prepared by incorporating Na-aluminate into the original fly ashes, then alkali-activated by 10 M NaOH solution. Incorporating Na-aluminate reduced the compressive strength of samples, with the reduction magnitude relatively constant regardless of length of curing period. The HSXRD provides evidence of the co-existence of C-S-H with geopolymeric gels and strongly suggests that the C-S-H formed in the current system is C-S-H(I). The back-scattered electron images suggest that the C-S-H(I) phase exists as small grains in a finely intermixed form with geopolymeric gels. Despite providing extra source of aluminum, adding Na-aluminate to the mixes did not decrease the Si/Al ratio of the geopolymeric gel.

  9. Ordered and disordered polymorphs of Na(Ni2/3Sb1/3)O?: Honeycomb-ordered cathodes for Na-ion batteries

    SciTech Connect (OSTI)

    Ma, Jeffrey; Wu, Lijun; Bo, Shou -Hang; Khalifah, Peter G.; Grey, Clare P.; Zhu, Yimei

    2015-04-14

    Na-ion batteries are appealing alternatives to Li-ion battery systems for large-scale energy storage applications in which elemental cost and abundance are important. Although it is difficult to find Na-ion batteries which achieve substantial specific capacities at voltages above 3 V (vs Na?/Na), the honeycomb-layered compound Na(Ni2/3Sb1/3)O? can deliver up to 130 mAh/g of capacity at voltages above 3 V with this capacity concentrated in plateaus at 3.27 and 3.64 V. Comprehensive crystallographic studies have been carried out in order to understand the role of disorder in this system which can be prepared in both disordered and ordered forms, depending on the synthesis conditions. The average structure of Na(Ni2/3Sb1/3)O? is always found to adopt an O3-type stacking sequence, though different structures for the disordered (R3m, #166, a = b = 3.06253(3) and c = 16.05192(7) ) and ordered variants (C2/m, #12, a = 5.30458(1) , b = 9.18432(1) , c = 5.62742(1) and ? = 108.2797(2)) are demonstrated through the combined Rietveld refinement of synchrotron X-ray and time-of-flight neutron powder diffraction data. However, pair distribution function studies find that the local structure of disordered Na(Ni2/3Sb1/3)O? is more correctly described using the honeycomb-ordered structural model, and solid state NMR studies confirm that the well-developed honeycomb ordering of Ni and Sb cations within the transition metal layers is indistinguishable from that of the ordered phase. The disorder is instead found to mainly occur perpendicular to the honeycomb layers with an observed coherence length of not much more than 1 nm seen in electron diffraction studies. When the Na environment is probed through Na solid state NMR, no evidence is found for prismatic Na environments, and a bulk diffraction analysis finds no evidence of conventional stacking faults. The lack of long range coherence is instead attributed to disorder among the three possible choices for distributing Ni and Sb cations into a honeycomb lattice in each transition metal layer. It is observed that the full theoretical discharge capacity expected for a Ni?/? redox couple (133 mAh/g) can be achieved for the ordered variant but not for the disordered variant (~110 mAh/g). The first 3.27 V plateau during charging is found to be associated with a two-phase O3 ? P3 structural transition, with the P3 stacking sequence persisting throughout all further stages of desodiation.

  10. Hard carbon nanoparticles as high-capacity, high-stability anodic materials for Na-ion batteries

    SciTech Connect (OSTI)

    Xiao, Lifen; Cao, Yuliang; Henderson, Wesley A.; Sushko, Maria L.; Shao, Yuyan; Xiao, Jie; Wang, Wei; Engelhard, Mark H.; Nie, Zimin; Liu, Jun

    2016-01-01

    Hard carbon nanoparticles (HCNP) were synthesized by the pyrolysis of a polyaniline precursor. The measured Na+ cation diffusion coefficient (10-13-10-15cm2s-1) in the HCNP obtained at 1150 C is two orders of magnitude lower than that of Li+ in graphite (10-10-13-15cm2s-1), indicating that reducing the carbon particle size is very important for improving electrochemical performance. These measurements also enable a clear visualization of the stepwise reaction phases and rate changes which occur throughout the insertion/extraction processes in HCNP, The electrochemical measurements also show that the nano-sized HCNP obtained at 1150 C exhibited higher practical capacity at voltages lower than 1.2 V (vs. Na/Na?), as well as a prolonged cycling stability, which is attributed to an optimum spacing of 0.366 nm between the graphitic layers and the nano particular size resulting in a low-barrier Na+ cation insertion. These results suggest that HCNP is a very promising high-capacity/stability anode for low cost sodium-ion batteries (SIBs).

  11. Post-Closure Groundwater Monitoring Plan for the 1324-N Surface Impoundment and 1324-NA Percolation Pond

    SciTech Connect (OSTI)

    Hartman, Mary J.

    2004-04-02

    The 1324-N Surface Impoundment and the 1324-NA Percolation Pond, located in the 100-N Area of the Hanford Site, are regulated under the Resource Consevation and Recovery Act (RCRA). Surface and underground features of the facilities have been removed and laboratory analyses showed that soil met the closure performance standards. These sites have been backfilled and revegetated.

  12. A new low-voltage plateau of Na₃V₂(PO₄)₃ as an anode for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jian, Zelang; Sun, Yang; Ji, Xiulei

    2015-04-04

    A low-voltage plateau at ~0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, turning it into a promising anode for Na-ion batteries.

  13. Quadruple-layered perovskite (CuCl)Ca{sub 2}NaNb{sub 4}O{sub 13}

    SciTech Connect (OSTI)

    Kitada, A.; Tsujimoto, Y.; Yamamoto, T. [Department of Energy and Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Nishikyo, Kyoto 615-8510 (Japan); Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502 (Japan); Kobayashi, Y. [Department of Energy and Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Nishikyo, Kyoto 615-8510 (Japan); Narumi, Y. [Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581 (Japan); Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577 (Japan); Kindo, K. [Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581 (Japan); Aczel, A.A.; Luke, G.M. [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8S 4M1 (Canada); Uemura, Y.J. [Department of Physics, Columbia University, New York, NY 10027 (United States); Kiuchi, Y.; Ueda, Y. [Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581 (Japan); Yoshimura, K. [Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502 (Japan); Ajiro, Y. [Department of Energy and Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Nishikyo, Kyoto 615-8510 (Japan); Kageyama, H., E-mail: kage@scl.kyoto-u.ac.jp [Department of Energy and Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Nishikyo, Kyoto 615-8510 (Japan); Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502 (Japan); Institute for Integrated Cell-Material Sciences, Kyoto University, Sakyo, Kyoto 606-8501 (Japan); CREST, Japan Science and Technology Agency, Kawaguchi 332-0012 (Japan)

    2012-01-15

    We will present the synthesis, structure and magnetic properties of a new quadruple-layered perovskite (CuCl)Ca{sub 2}NaNb{sub 4}O{sub 13}. Through a topotactic ion-exchange reaction with CuCl{sub 2}, the precursor RbCa{sub 2}NaNb{sub 4}O{sub 13} presumably having an incoherent octahederal tliting changes into (CuCl)Ca{sub 2}NaNb{sub 4}O{sub 13} with a 2a{sub p} Multiplication-Sign 2a{sub p} Multiplication-Sign 2c{sub p} superstructure (tetragonal; a=7.73232(5) A, c=39.2156(4) A). The well-defined superstructure for the ion-exchanged product should be stabilized by the inserted CuCl{sub 4}O{sub 2} octahedral layers that firmly connect with neighboring perovskite layers. Magnetic studies show the absence of long-range magnetic ordering down to 2 K despite strong in-plane interactions. Aleksandrov Prime s group theory and Rietveld refinement of synchrotron X-ray diffraction data suggest the structure to be of I4/mmm space group with in-phase tilting along the a and b axes, a two-tilt system (++0). - Graphical Abstract: We present a quadruple-layered copper oxyhalide (CuCl)Ca{sub 2}NaNb{sub 4}O{sub 13} synthesized through a topotactic ion-exchange reaction of RbCa{sub 2}NaNb{sub 4}O{sub 13} with CuCl{sub 2}. The compound has a well-defined superstructure. Magnetic studies suggest the absence of magnetic order even at 2 K. Highlights: Black-Right-Pointing-Pointer (CuCl)Ca{sub 2}NaNb{sub 4}O{sub 13} was prepared by ion-exchange reaction of RbCa{sub 2}NaNb{sub 4}O{sub 13} with CuCl{sub 2}. Black-Right-Pointing-Pointer Compound has a 2a{sub p} Multiplication-Sign 2a{sub p} Multiplication-Sign 2c{sub p} superstructure (tetragonal; a=7.73 A, c=39.21 A). Black-Right-Pointing-Pointer Such a well-defined superstructure was not observed in the precursor compound. Black-Right-Pointing-Pointer Aleksandrov Prime s theory and Rietveld study suggest a (++0) octahedral tilting (I4/mmm). Black-Right-Pointing-Pointer Magnetic studies revealed the absence of magnetic order down to 2 K.

  14. Spin-lozenge thermodynamics and magnetic excitations in Na3RuO4

    SciTech Connect (OSTI)

    Haraldsen, Jason T; Stone, Matthew B; Lumsden, Mark D; Barnes, Ted {F E }; Jin, Rongying; Taylor, J. W.; Fernandez-Alonso, F

    2009-01-01

    We report inelastic and elastic neutron scattering, magnetic susceptibility, and heat capacity measurements of polycrystalline sodium ruthenate (Na3RuO4). Previous work suggests this material consists of isolated tetramers of S = 3/2 Ru5+ ions in a so-called lozenge configuration. Using a Heisenberg antiferromagnet Hamiltonian, we analytically determine the energy eigenstates for general spin S. From this model, the neutron scattering cross-sections for excitations associated with spin-3/2 tetramer configurations is determined. Comparison of magnetic susceptibility and inelastic neutron scattering results shows that the proposed lozenge model is not distinctly supported, but provides evidence that the system may be better described as a pair of non-interacting inequivalent dimers, i.e double dimers. However, the existence of long-range magnetic order below Tc ≈ 28 K immediately questions such a description. Although no evidence of the lozenge model is observed, future studies on single crystals may further clarify the appropriate magnetic Hamiltonian.

  15. Na9K16TI~25: A New Phase Containing Naked Icosahedral Cluster Fragments Ti99-

    SciTech Connect (OSTI)

    Li, Bin; Corbett, John D.

    2007-12-05

    The phase Na{sub 9}K{sub 16}Tl{sub 25.25(2)} was synthesized by fusion of the elements in sealed Ta containers followed by quenching and annealing at 250 C. The structure established by single crystal X-ray diffraction means (P6{sub 3}/m, Z = 2, a = 19.376(3) {angstrom}, c = 11.480(2) {angstrom}) features Tl{sub 9}{sup 9-} clusters. These are well separated by cations that bridge between, faces, edges, and vertices of the clusters; sodium appears to be essential in this role. This is the third compound known to contain Tl{sub 9} clusters, but here two of nine sites are partially occupied, which can be interpreted as a 70:30 mixture of Tl{sub 9} and Tl{sub 7} units in the same cavity. This Tl{sub 9} example also displays lower symmetry (C{sub s}) but requires the same 2n skeletal electrons. EHTB electronic structure calculations indicate that the Fermi level intersects a finite densities-of-states (DOS), and only some bonds are optimized at E{sub F}, giving some insight regarding the site of Tl deficiency. Direct geometric relationships are found among Tl{sub 13}, Tl{sub 9}, Tl{sub 7} and Tl{sub 5} clusters through systematic removal of vertices.

  16. Preparation and photocatalytic activity for water splitting of Pt-Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays

    SciTech Connect (OSTI)

    Liu, Jing; Liu, Jiawen; Li, Zhonghua

    2013-02-15

    Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays were prepared by hydrothermal method from Ta{sub 2}O{sub 5} nanotube arrays, obtained by anodization of Ta foils, in Na{sub 2}CO{sub 3} solution at 150 Degree-Sign C. The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-vis diffuse reflectance spectra (UV-DRS) and X-ray photoelectron spectroscopy (XPS). Analysis results show that pyrochlore structure Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays have been successfully fabricated. The diameters and lengths of Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are 50 nm and 4 {mu}m, respectively. The photocatalytic hydrogen production activities of the as-synthesized Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are highly dependent on the hydrothermal reaction time and Na{sub 2}CO{sub 3} concentration, optimized reaction parameters are obtained. To further improve the photocatalytic activity for hydrogen evolution, Pt loaded Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are prepared by photochemical reduction method. The Pt loaded samples exhibit much higher activity for hydrogen evolution than pure Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays. Moreover, the photocatalytic hydrogen properties are rather stable. - Graphical abstract: Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays were synthesized by hydrothermal method using Ta{sub 2}O{sub 5} nanotube arrays as a precursor. The loaded Pt enhances the photocatalytic activity for water splitting of Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays. Highlights: Black-Right-Pointing-Pointer Novel Na{sub 2}Ta{sub 2}O{sub 6} nanotube array films with pyrochlore structure were synthesized. Black-Right-Pointing-Pointer Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are active for H{sub 2} evolution from aqueous CH{sub 3}OH solution. Black-Right-Pointing-Pointer The effect of hydrothermal conditions on photocatalytic activity was investigated. Black-Right-Pointing-Pointer Pt loading can improve the photocatalytic activities of Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays. Black-Right-Pointing-Pointer Photocatalytic mechanism is proposed based on the experimental results.

  17. Gamma-ray burst flares: X-ray flaring. II

    SciTech Connect (OSTI)

    Swenson, C. A.; Roming, P. W. A., E-mail: cswenson@astro.psu.edu [Pennsylvania State University, 525 Davey Lab, University Park, PA 16802 (United States)

    2014-06-10

    We present a catalog of 498 flaring periods found in gamma-ray burst (GRB) light curves taken from the online Swift X-Ray Telescope GRB Catalogue. We analyzed 680 individual light curves using a flare detection method developed and used on our UV/optical GRB Flare Catalog. This method makes use of the Bayesian Information Criterion to analyze the residuals of fitted GRB light curves and statistically determines the optimal fit to the light curve residuals in an attempt to identify any additional features. These features, which we classify as flares, are identified by iteratively adding additional 'breaks' to the light curve. We find evidence of flaring in 326 of the analyzed light curves. For those light curves with flares, we find an average number of ?1.5 flares per GRB. As with the UV/optical, flaring in our sample is generally confined to the first 1000 s of the afterglow, but can be detected to beyond 10{sup 5} s. Only ?50% of the detected flares follow the 'classical' definition of ?t/t ? 0.5, with many of the largest flares exceeding this value.

  18. The influence of field-free orientation on the predissociation dynamics of the NaI molecule

    SciTech Connect (OSTI)

    Zhao, Ze-Yu; Han, Yong-Chang, E-mail: ychan@dlut.edu.cn; Yu, Jie; Cong, Shu-Lin [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-01-28

    The orientation and predissociation dynamics of the NaI molecule are studied by using a time-dependent wavepacket method. The NaI molecule is first pre-oriented by a single-cycle pulse (SCP) in terahertz (THz) region and then predissociated by a femtosecond pump pulse. The influence of the molecular field-free orientation on the predissociation dynamics is studied in detail. We calculate the radial and angular distributions, the molecular orientation degrees, and the time-dependent populations for both the ground and excited electronic states. It is found that the pre-orientation affects the angular distributions significantly, and that it has weak influence on the radial distributions. By varying the delay time between the THz SCP and the pump pulse, the angular distribution of the fragments from the predissociation can be manipulated.

  19. Measurement of the tradeoff between intrinsic emittance and quantum efficiency from a NaKSb photocathode near threshold

    SciTech Connect (OSTI)

    Maxson, Jared Cultrera, Luca; Gulliford, Colwyn; Bazarov, Ivan

    2015-06-08

    We measure the tradeoff between the quantum efficiency and intrinsic emittance from a NaKSb photocathode at three increasing wavelengths (635, 650, and 690 nm) at or below the energy of the bandgap plus the electron affinity, hν≤E{sub g}+E{sub a}. These measurements were performed using a high voltage dc gun for varied photocathode surface fields of 1.4−4.4 MV/m. Measurements of intrinsic emittance are performed using two different methods and were found to agree. At the longest wavelength available, 690 nm, the intrinsic emittance was 0.26 μm/mm-rms with a quantum efficiency of ∼10{sup −4}. The suitability of NaKSb emitting at threshold for various low emittance applications is discussed.

  20. Treatment of EBR-I NaK mixed waste at Argonne National Laboratory and subsequent land disposal at the Idaho National Engineering and Environmental Laboratory.

    SciTech Connect (OSTI)

    Herrmann, S. D.; Buzzell, J. A.; Holzemer, M. J.

    1998-02-03

    Sodium/potassium (NaK) liquid metal coolant, contaminated with fission products from the core meltdown of Experimental Breeder Reactor I (EBR-I) and classified as a mixed waste, has been deactivated and converted to a contact-handled, low-level waste at Argonne's Sodium Component Maintenance Shop and land disposed at the Radioactive Waste Management Complex. Treatment of the EBR-I NaK involved converting the sodium and potassium to its respective hydroxide via reaction with air and water, followed by conversion to its respective carbonate via reaction with carbon dioxide. The resultant aqueous carbonate solution was solidified in 55-gallon drums. Challenges in the NaK treatment involved processing a mixed waste which was incompletely characterized and difficult to handle. The NaK was highly radioactive, i.e. up to 4.5 R/hr on contact with the mixed waste drums. In addition, the potential existed for plutonium and toxic characteristic metals to be present in the NaK, resultant from the location of the partial core meltdown of EBR-I in 1955. Moreover, the NaK was susceptible to degradation after more than 40 years of storage in unmonitored conditions. Such degradation raised the possibility of energetic exothermic reactions between the liquid NaK and its crust, which could have consisted of potassium superoxide as well as hydrated sodium/potassium hydroxides.

  1. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification

    Office of Environmental Management (EM)

    Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3 Incentive and Objectives FBSR sodium-aluminosilicate (NAS) waste form has been identified as a promising supplemental treatment technology for Hanford LAW Objectives: Reduce the risk associated with implementing the FBSR NAS waste form as a supplemental treatment technology for Hanford LAW Conduct test with actual tank

  2. Development of Na/sup +/-dependent hexose transport in cultured renal epithelial cells (LLC-PK/sub 1/)

    SciTech Connect (OSTI)

    Weiss, E.R.; Amsler, K.; Dawson, W.D.; Cook, J.S.

    1984-01-01

    A number of factors were explored to analyze how they interact to yield the increasing transport capacity in differentiating cell populations. These factors include the number of functional transporters in the population, the distribution of these transporters among the individual cells, the Na/sup +/ chemical gradient, the transmembrane potential, the pathways and activities of these pathways for efflux of glucoside, and cell-cell coupling between accumulating and non-accumulating cells. 35 references, 9 figures, 2 tables. (ACR)

  3. NNSA Corporate CPEP Process NNSA Honeywell FM&T PER NNSA/NA-00.2

    National Nuclear Security Administration (NNSA)

    NNSA Honeywell FM&T PER NNSA/NA-00.2 National Nuclear Security Administration FY 2013 PEP Honeywell FM&T Performance Evaluation Report Kansas City Field Office Kansas City Plant Performance Period: October 2012 - September 2013 December 20, 2013 Executive Summary Honeywell Federal Manufacturing & Technologies (FM&T) exceeded almost all FY13 performance targets during a year of significant organizational challenges including; transitioning to a new facility while simultaneously

  4. Modeling the Interaction between Integrin-Binding Peptide (RGD) and Rutile Surface: The Effect of Na+ on Peptide Adsorption

    SciTech Connect (OSTI)

    Wu, Chunya; Skelton, Adam; Chen, Mingjun; Vlcek, Lukas; Cummings, Peter T

    2011-01-01

    The dynamics of a single tripeptide Arg-Gly-Asp (RGD) adsorbing onto negatively charged hydroxylated rutile (110) surface in aqueous solution was studied using molecular dynamics (MD) simulations. The results indicate that the adsorbed Na{sup +} ions play an important role in determining the binding geometry of RGD. With an initial 'horseshoe' configuration, the charged side groups (COO{sup -} and NH{sub 2}) of the peptide are able to interact with the surface through direct hydrogen bonds (H bonds) in the very early stage of adsorption. The Na{sup +} ions approach the positively charged Arg side chain, competing with the Arg side chain for adsorption to the negatively charged hydroxyl oxygen. In coordination with the structural adjustment of the peptide, the Arg residue is driven to detach from the rutile surface. In contrast, the Na+ ions in close proximity to the negatively charged Asp side chain contribute to the binding of the COO{sup -} group on the surface, helping the carboxyl oxygen not involved in COO{sup -}-surface H bonds to orientate toward the hydroxyl hydrogens. Once both carboxyl oxygens form enough H bonds with the hydroxyl hydrogens, the redundant ions move toward a more favorable adsorption site.

  5. Materials corrosion in molten LiF-NaF-KF eutectic salt under different reduction-oxidation conditions

    SciTech Connect (OSTI)

    Sellers, R. S.; Cheng, W. J.; Anderson, M. H.; Sridharan, K.; Wang, C. J.; Allen, T. R.

    2012-07-01

    Molten fluoride salts such as FLiNaK (LiF-NaF-KF: 46.5-11.5-42 mol %) have been proposed for use as secondary reactor coolants, media for transfer of high temperature process heat from nuclear reactors to chemical plants, and for concentrated solar power thermal energy storage. In molten fluoride salts, passive oxide films are chemically unstable, and corrosion is driven largely by the thermodynamically driven dissolution of alloying elements into the molten salt environment. Two alloys, Hastelloy{sup R} N and 316L stainless steel were exposed to molten FLiNaK salt in a 316L stainless steel crucible under argon cover gas for 1000 hours at 850 deg. C. Graphite was present in some of the crucibles with the goal of studying corrosion behavior of relevant reactor material combinations. In addition, a technique to reduce alloy corrosion through modification of the reduction-oxidation state was tested by the inclusion of zirconium to the system. Corrosion of 316L stainless steel was noted to occur primarily through surface depletion of chromium, an effect that was enhanced by the presence of graphite. Hastelloy{sup R} N experienced weight gain through electrochemical plating of corrosion products derived from the 316L stainless steel crucible. In the presence of zirconium, both alloys gained weight through plating of zirconium and as a result formed intermetallic layers. (authors)

  6. NaREC Offshore and Drivetrain Test Facility Collaboration: Cooperative Research and Development Final Report, CRADA Number CRD-04-140

    SciTech Connect (OSTI)

    Musial, W.

    2014-08-01

    The National Renewable Energy Laboratory (NREL) and the National Renewable Energy Centre (NaREC) in the United Kingdom (UK) have a mutual interest in collaborating in the development of full-scale offshore wind energy and drivetrain testing facilities. NREL and NaREC will work together to share resources and experiences in the development of future wind energy test facilities. This Cooperative Research and Development Agreement (CRADA) includes sharing of test protocols, infrastructure cost data, test plans, pro forma contracting instruments, and safe operating strategies. Furthermore, NREL and NaREC will exchange staff for training and development purposes.

  7. Low-temperature hydrothermal synthesis of the three-layered sodium cobaltite P3-Na{sub x}CoO{sub 2} (x ? 0.60)

    SciTech Connect (OSTI)

    Miclau, M.; Bokinala, K.; Miclau, N.

    2014-06-01

    Highlights: We report direct synthesis of the high temperature stable phase, P3-Na{sub 0.6}CoO{sub 2}. The hydrothermal synthesis of P3-Na{sub 0.6}CoO{sub 2} involves one step and low temperature. The yield diagram for NaCoH{sub 2}O system has been builded up to 250 C. We propose a formation mechanism of P3-Na{sub 0.6}CoO{sub 2} phase using the unit cell theory. The thermal stability of P3-Na{sub 0.6}CoO{sub 2} has been investigated by means of HT-XRD. - Abstract: In order to obtain the layered sodium cobalt oxide materials by hydrothermal synthesis, the yield diagram for NaCoH{sub 2}O system has been built and studied. In the same time, the well-known data of CoH{sub 2}O system have been extended at 250 C in basic solution. We had first synthesized directly the high temperature stable phase, P3-Na{sub 0.6}CoO{sub 2} by a one-step low-temperature hydrothermal method. The rhombohedral structure of P3-Na{sub 0.6}CoO{sub 2} has been determined by X-ray diffraction (XRD) and the purity of phases has been confirmed by XPS. The thermal stability of P3-Na{sub 0.6}CoO{sub 2} has been investigated by means of high temperature X-ray diffraction in 298873 K range and when the temperature has reached 723 K, the completely transformation of P3-Na{sub 0.6}CoO{sub 2} in the rhombohedral stable phase ?-NaCoO{sub 2} (space group R-3m) was observed. Also, a formation mechanism of P3-Na{sub 0.6}CoO{sub 2} phase using the unit cell theory in the hydrothermal process was proposed.

  8. Management and Operating Contract for the Los Alamos National Laboratory, NNSA contract No. DE-AC52-06NA25396

    National Nuclear Security Administration (NNSA)

    MANAGEMENT AND OPERATING CONTRACT FOR THE LOS ALAMOS NATIONAL LABORATORY NATIONAL NUCLEAR SECURITY ADMINISTRATION CONTRACT No. DE-AC52-06NA25396 DECEMBER 21, 2005 1943 Today Blank Page Blank Page Request for Proposal No. DE-RP52-05NA25396 LANS Contract DE-AC52-06NA25396.doc Section B - H, Page 2 Part I - The Schedule Sections B through H TABLE OF CONTENTS STANDARD FORM 33 SOLICITATION, OFFER AND AWARD....................................... 1 Section B - SUPPLIES OR SERVICES AND PRICES/COSTS

  9. PRECURSOR FLARES IN OJ 287

    SciTech Connect (OSTI)

    Pihajoki, P.; Berdyugin, A.; Lindfors, E.; Reinthal, R.; Sillanpaeae, A.; Takalo, L.; Valtonen, M.; Nilsson, K.; Zola, S.; Koziel-Wierzbowska, D.; Liakos, A.; Drozdz, M.; Winiarski, M.; Ogloza, W.; Provencal, J.; Santangelo, M. M. M.; Salo, H.; Chandra, S.; Ganesh, S.; Baliyan, K. S.; and others

    2013-02-10

    We have studied three most recent precursor flares in the light curve of the blazar OJ 287 while invoking the presence of a precessing binary black hole in the system to explain the nature of these flares. Precursor flare timings from the historical light curves are compared with theoretical predictions from our model that incorporate effects of an accretion disk and post-Newtonian description for the binary black hole orbit. We find that the precursor flares coincide with the secondary black hole descending toward the accretion disk of the primary black hole from the observed side, with a mean z-component of approximately z{sub c} = 4000 AU. We use this model of precursor flares to predict that precursor flare of similar nature should happen around 2020.96 before the next major outburst in 2022.

  10. Charging Properties of Cassiterite (alpha-SnO2) surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite (alpha-SnO2) surfaces at 10-50 degrees C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH2 group is more acidic than the bridging Sn2OH group, with protonation constants (log KH) of 3.60 and 5.13 at 25 degrees C, respectively. This is contrary to the situation on the isostructural alpha-TiO2 (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na+ and Rb+, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na+ between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb+ is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na+/Rb+ was formulated. According to the SCM, the deprotonated terminal group (SnOH(-0.40)) and the protonated bridging group (Sn2OH+0.36) dominate the surface speciation over the entire pH range of this study (2.7-10). The complexation of medium cations increases significantly with increasing negative surface charge, and at pH 10, roughly 40% of the terminal sites are predicted to form cation complexes, whereas anion complexation is minor throughout the studied pH range.

  11. Charging Properties of Cassiterite (alpha-SnO2) Surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite ({alpha}-SnO{sub 2}) surfaces at 10-50 C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH{sub 2} group is more acidic than the bridging Sn{sub 2}OH group, with protonation constants (log K{sub H}) of 3.60 and 5.13 at 25 C, respectively. This is contrary to the situation on the isostructural {alpha}-TiO{sub 2} (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na{sup +} and Rb{sup +}, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na{sup +} between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb{sup +} is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na{sup +}/Rb{sup +} was formulated. According to the SCM, the deprotonated terminal group (SnOH{sup -0.40}) and the protonated bridging group (Sn{sub 2}OH{sup +0.36}) dominate the surface speciation over the entire pH range of this study (2.7-10). The complexation of medium cations increases significantly with increasing negative surface charge, and at pH 10, roughly 40% of the terminal sites are predicted to form cation complexes, whereas anion complexation is minor throughout the studied pH range.

  12. High-pressure stability relations, crystal structures, and physical properties of perovskite and post-perovskite of NaNiF{sub 3}

    SciTech Connect (OSTI)

    Shirako, Y.; Shi, Y.G.; Aimi, A.; Mori, D.; Kojitani, H.; Yamaura, K.; Inaguma, Y.; Akaogi, M.

    2012-07-15

    NaNiF{sub 3} perovskite was found to transform to post-perovskite at 16-18 GPa and 1273-1473 K. The equilibrium transition boundary is expressed as P (GPa)=-2.0+0.014 Multiplication-Sign T (K). Structure refinements indicated that NaNiF{sub 3} perovskite and post-perovskite have almost regular NiF{sub 6} octahedra consistent with absence of the first-order Jahn-Teller active ions. Both NaNiF{sub 3} perovskite and post-perovskite are insulators. The perovskite underwent a canted antiferromagnetic transition at 156 K, and the post-perovskite antiferromagnetic transition at 22 K. Magnetic exchange interaction of NaNiF{sub 3} post-perovskite is smaller than that of perovskite, reflecting larger distortion of Ni-F-Ni network and lower dimension of octahedral arrangement in post-perovskite than those in perovskite. - Graphical abstract: Perovskite-post-perovskite transition in NaNiF{sub 3} at high pressure Highlights: Black-Right-Pointing-Pointer NaNiF{sub 3} perovskite (Pv) transforms to post-perovskite (pPv) at 16 GPa and 1300 K. Black-Right-Pointing-Pointer The equilibrium transition boundary is expressed as P (GPa)=-2.0+0.014 T (K). Black-Right-Pointing-Pointer Antiferromagnetic transition occurs at 156 K in Pv and 22 K in pPv.

  13. Structure of 2 molar NaOH in aqueous solution from neutron diffraction and empirical potential structure refinement

    SciTech Connect (OSTI)

    McLain, Sylvia E.; Imberti, Silvia; Soper, Alan K.; Botti, Alberto; Bruni, Fabio; Ricci, Maria Antonietta

    2006-09-01

    Neutron diffraction with isotopic substitution has been used to investigate aqueous solutions of 2M NaOH in the liquid state. The data were modeled using empirical potential structure refinement which allows for the extraction of the ion-water and water-water correlations. The data show that the ion-water radial distribution functions are in accordance with those found by previous studies on NaOH solutions and follow a trend which is dependent on the concentration of the solute. In particular, the shape of the hydroxide hydration shell is found to be concentration independent, but the number of water molecules occupying this shell increases with dilution. Additionally, the water-water correlations show that there is still a measurable effect on water structure with the addition of ions at this concentration, as the second shell in the water oxygen radial distribution function is compressed relative to the first shell. The data are also used to discuss the recent claims that the published radial distribution functions of water are unreliable, showing that data taken at different neutron sources, with different diffraction geometry and systematic errors lead to the same structural information when analyzed via a realistic modeling regime.

  14. Synthesis and photoluminescence properties of NaLaMgWO{sub 6}:RE{sup 3+} (RE = Eu, Sm, Tb) phosphor for white LED application

    SciTech Connect (OSTI)

    Hou, Jingshan; CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050; College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 ; Yin, Xin; College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 ; Huang, Fuqiang; College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 ; Jiang, Weizhong

    2012-06-15

    Highlights: ► NaLa{sub 1−x}MgWO{sub 6}:xRE{sup 3+} phosphors were synthesized by solid-state reaction method. ► Compared with Y{sub 2}O{sub 3}:Eu{sup 3+}, NaLaMgWO{sub 6}:Eu{sup 3+} performed better luminescence properties. ► The results demonstrated NaLaMgWO{sub 6} as a suitable host for RE{sup 3+}-doping. -- Abstract: Single phase of NaLa{sub 1−x}MgWO{sub 6}:xRE{sup 3+} (0 < x ≤1) (RE = Eu, Sm, Tb) phosphors were prepared by solid-state reaction method. X-ray diffraction, scanning electron microscopy, the morphology energy-dispersive X-ray spectroscopy, UV–vis diffuse reflectance spectra and photoluminescence were used to characterize the samples. Under the light excitation, NaLaMgWO{sub 6}:Eu{sup 3+}, NaLaMgWO{sub 6}:Sm{sup 3+} and NaLaMgWO{sub 6}:Tb{sup 3+}, phosphors showed the characteristic emissions of Eu{sup 3+} ({sup 5}D{sub 0} → {sup 7}F{sub 4,3,2,1}), Sm{sup 3+} ({sup 4}G{sub 5/2} → {sup 6}H{sub 5/2,7/2,9/2}), and Tb{sup 3+} ({sup 5}D{sub 4} → {sup 7}F{sub 6,5,4,3}), respectively. The intensity of the red emission for Na(La{sub 0.6}Eu{sub 0.4})MgWO{sub 6} is 2.5 times higher than that of (Y{sub 0.95}Eu{sub 0.05}){sub 2}O{sub 3} under blue light irradiation. The quantum efficiencies of the entitled phosphors excited under 394 nm and 464 nm are also investigated and compared with commercial phosphors Y{sub 2}O{sub 3}:Eu{sup 3+}, Sr{sub 2}Si{sub 5}N{sub 8}:Eu{sup 2+} and Y{sub 3}A{sub 5}G{sub 12}:Ce{sup 3+}. The results demonstrated NaLaMgWO{sub 6}:RE{sup 3+} phosphors as potential candidates for white light emitting diode pumped by UV or blue chip.

  15. Thermal stability, acidity, catalytic properties, and deactivation behaviour of SAPO-5 catalysts: Effect of silicon content, acid treatment, and Na exchange

    SciTech Connect (OSTI)

    Akolekar, D.B.

    1994-09-01

    Crystalline microporous SAPO-5 molecular sieves with different silicon content, acid-treated SAPO-5 and Na-exchanged SAPO-5 were investigated for their thermal stability, and acidic and catalytic properties. SAPO-5 materials with increasing SI framework content exhibited lower thermal stability. The effects of the thermal treatment and Na exchange on the N{sub 2}-sorption capacity (at 78 K) of these materials were studied. In situ IR spectroscopic investigations of pyridine chemisorbed on the aluminophosphate catalysts revealed that the concentration of Broensted and Lewis acid sites are strongly affected by the Si content in the AlPO{sub 4} framework, acid treatment, and Na exchange. The results of temperature programmed desorption (TPD) and stepwise thermal desorption of pyridine suggest that there exists a broad site energy distribution over the aluminophosphate catalysts increases with the increasing Si content in the AlPO{sub 4} framework. The acid treatment and Na exchange showed a decrease in the number of strong acid sites on SAPO-5. The TPD of pyridine over SAPO-5, acid-treated SAPO-5, and Na-exchanged SAPO-5 indicated the presence of two types of acid sites. Correlation between the number of strong acid sites (measured in terms of the chemisorption of pyridine at 673 K) and framework charge on the aluminophosphate catalysts has also been obtained. The catalytic activities of SAPO-5 catalysts in the ethanol, n-hexane, isooctane, toluene, and o-xylene conversion reactions were studied. 22 refs., 11 figs., 5 tabs.

  16. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; et al

    2015-03-25

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accuratelymore » identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.« less

  17. Room temperature magnetocaloric effect, critical behavior, and magnetoresistance in Na-deficient manganite La{sub 0.8}Na{sub 0.1}MnO{sub 3}

    SciTech Connect (OSTI)

    Khlifi, M. Dhahri, E.; Hlil, E. K.

    2014-05-21

    The La{sub 0.8}Na{sub 0.1}MnO{sub 3} oxide was prepared by the solid-state reaction and annealed in air. The X-ray diffraction data reveal that the sample is crystallized in a rhombohedral structure with R3{sup ¯}c space group. Magnetic study shows a second-order magnetic phase transition from ferromagnetic to paramagnetic state at the Curie temperature T{sub C} = 295 K. In addition, the magnetizations as a function of temperature and the magnetic field is used to evaluate the magnetic entropy change ΔS{sub M}. Then, we have deduced that the La{sub 0.8}Na{sub 0.1}MnO{sub 3} oxide has a large magnetocaloric effect at room temperature. Such effect is given by the maximum of the magnetic entropy change ΔS{sub Mmax} = 5.56, and by the Relative cooling power (RCP) factor which is equal to 235 under a magnetic field of 5 T. Moreover, the magnetic field dependence of the magnetic entropy change is used to determine the critical exponents β, γ, and δ which are found to be β = 0.495, γ = 1.083, and δ = 3.18. These values are consistent with the prediction of the mean field theory (β = 0.5, γ = 1, and δ = 3). Above all, the temperature dependence of electrical resistivity shows a metal–insulator transition at T{sub ρ}. The electrical resistivity decrease when we apply a magnetic field giving a magnetoresistance effect in the order of 60% at room temperature.

  18. Exotic magnetism on the quasi-FCC lattices of the d3 double perovskites La2NaB'O6 (B' = Ru, Os)

    SciTech Connect (OSTI)

    Aczel, Adam A; Baker, Peter J.; Bugaris, Dan; Yeon, Jeongho; Zur Loye, Hans-Conrad; Guidi, T.; Adroja, D. T.

    2014-01-01

    We find evidence for long-range and short-range ($\\zeta$~$=$~70~\\AA~at 4~K) incommensurate magnetic order on the quasi-face-centered-cubic (FCC) lattices of the monoclinic double perovskites La$_2$NaRuO$_6$ and La$_2$NaOsO$_6$ respectively. Incommensurate magnetic order on the FCC lattice has not been predicted by mean field theory, but may arise via a delicate balance of inequivalent nearest neighbour and next nearest neighbour exchange interactions. In the Ru system with long-range order, inelastic neutron scattering also reveals a spin gap $\\Delta$~$\\sim$~2.75~meV. Magnetic anisotropy is generally minimized in the more familiar octahedrally-coordinated $3d^3$ systems, so the large gap observed for La$_2$NaRuO$_6$ may result from the significantly enhanced value of spin-orbit coupling in this $4d^3$ material.

  19. Evolution of structure in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3} single crystals

    Office of Scientific and Technical Information (OSTI)

    with BaTiO{sub 3} (Journal Article) | SciTech Connect Evolution of structure in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3} single crystals with BaTiO{sub 3} Citation Details In-Document Search Title: Evolution of structure in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3} single crystals with BaTiO{sub 3} The structural, dielectric, and piezoelectric properties of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-x mol. %BaTiO{sub 3} (NBT-x%BT) crystals have been investigated. The dielectric and piezoelectric properties of NBT-x%BT

  20. Structure and ferroelectricity of nonstoichiometric (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3}

    SciTech Connect (OSTI)

    Carter, Jared; Aksel, Elena; Iamsasri, Thanakorn; Forrester, Jennifer S.; Jones, Jacob L.; Chen, Jun

    2014-03-17

    Stoichiometric (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3} (NBT) adopts the ABO{sub 3} perovskite structure with the A-site equally occupied by Na{sup +} and Bi{sup 3+} ions. However, non-stoichiometric compositions can be synthesized intentionally or unintentionally. To determine the effect of A-site nonstoichiometry on the crystal structure and ferroelectricity of NBT, the composition of (Na{sub 0.5?x}Bi{sub 0.5+x})TiO{sub 3+x} was varied using x?=??0.01, ?0.005, 0, 0.005, and 0.01. High resolution synchrotron x-ray diffraction and Rietveld refinement revealed that a shift in either direction from x = 0 results in a decrease in the spontaneous ferroelastic strain. Ferroelectric hysteresis and piezoelectric coefficients were found to be optimum in the stoichiometric composition.

  1. Coordinated role of voltage-gated sodium channels and the Na{sup +}/H{sup +} exchanger in sustaining microglial activation during inflammation

    SciTech Connect (OSTI)

    Hossain, Muhammad M.; Sonsalla, Patricia K.; Richardson, Jason R.

    2013-12-01

    Persistent neuroinflammation and microglial activation play an integral role in the pathogenesis of many neurological disorders. We investigated the role of voltage-gated sodium channels (VGSC) and Na{sup +}/H{sup +} exchangers (NHE) in the activation of immortalized microglial cells (BV-2) after lipopolysaccharide (LPS) exposure. LPS (10 and 100 ng/ml) caused a dose- and time-dependent accumulation of intracellular sodium [(Na{sup +}){sub i}] in BV-2 cells. Pre-treatment of cells with the VGSC antagonist tetrodotoxin (TTX, 1 ?M) abolished short-term Na{sup +} influx, but was unable to prevent the accumulation of (Na{sup +}){sub i} observed at 6 and 24 h after LPS exposure. The NHE inhibitor cariporide (1 ?M) significantly reduced accumulation of (Na{sup +}){sub i} 6 and 24 h after LPS exposure. Furthermore, LPS increased the mRNA expression and protein level of NHE-1 in a dose- and time-dependent manner, which was significantly reduced after co-treatment with TTX and/or cariporide. LPS increased production of TNF-?, ROS, and H{sub 2}O{sub 2} and expression of gp91{sup phox}, an active subunit of NADPH oxidase, in a dose- and time-dependent manner, which was significantly reduced by TTX or TTX + cariporide. Collectively, these data demonstrate a closely-linked temporal relationship between VGSC and NHE-1 in regulating function in activated microglia, which may provide avenues for therapeutic interventions aimed at reducing neuroinflammation. - Highlights: LPS causes immediate increase in sodium through VGSC and subsequently through the NHE-1. Inhibition of VGSC reduces increases in NHE-1 and gp91{sup phox}. Inhibition of VGSC and NHE-1 reduces NADPH oxidase-mediated Tnf-?, ROS, and H{sub 2}O{sub 2} production. NHE-1 and Na{sub v}1.6 may be viable targets for therapeutic interventions to reduce neuroinflammation in neurodegenerative disease.

  2. Hot-stage transmission electron microscopy study of (Na, K)NbO{sub 3} based lead-free piezoceramics

    SciTech Connect (OSTI)

    Lu, Shengbo; Xu, Zhengkui; Kwok, K. W.; Chan, Helen L. W.

    2014-07-28

    Hierarchical nanodomains assembled into micron-sized stripe domains, which is believed to be associated with outstanding piezoelectric properties, were observed at room temperature in a typical lead free piezoceramics, (Na{sub 0.52}K{sub 0.48?x})(Nb{sub 0.95?x}Ta{sub 0.05})-xLiSbO{sub 3}, with finely tuned polymorphic phase boundaries (x?=?0.0465) by transmission electron microscopy. The evolution of domain morphology and crystal structure under heating and cooling cycles in the ceramic was investigated by in-situ hot stage study. It is found that the nanodomains are irreversibly transformed into micron-sized rectangular domains during heating and cooling cycles, which lead to the thermal instability of piezoelectric properties of the materials.

  3. Viscosity of NaCl and other solutions up to 350{sup 0}C and 50 MPa pressures

    SciTech Connect (OSTI)

    Phillips, S.L.; Ozbek, H.; Igbene, A.; Litton, G.

    1980-11-01

    Experimental values for the viscosity of sodium chloride solutions are critically reviewed for application to geothermal energy. Data published recently by Kestin, Los, Pepinov, and Semenyuk as well as earlier data are included. A theoretically based equation for calculating relative viscosity was developed, and used to generate tables of smoothed values over the ranges 20{sup 0}C to 350{sup 0}C, 0 to 5 m and pressures up to 50 MPa. The equation reproduces selected data to an average of better than 2 percent over the entire range of temperatures and pressures. Selected tables of data are included for KCl up to 150{sup 0}C, CaCl{sub 2} solutions up to 100{sup 0}C, and for mixtures of NaCl with KCl and CaCl{sub 2}. Recommendations are given for additional data needs.

  4. Low-surface-area hard carbon anode for Na-ion batteries via graphene oxide as a dehydration agent

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Wei; Bommier, Clement; Jian, Zelang; Li, Xin; Carter, Rich; Vail, Sean; Lu, Yuhao; Lee, Jong -Jan; Ji, Xiulei

    2015-02-04

    Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In this study, we discover that doping graphene oxide into sucrose, the precursor for hard carbon, can effectively reduce the specific surface area of hard carbon to as low as 5.4 m²/g. We further reveal that such doping can effectively prevent foaming during caramelization of sucrose and extend the pyrolysis burn-offmore » of sucrose caramel over a wider temperature range. Thus, the obtained low-surface-area hard carbon greatly improves the first-cycle Coulombic efficiency from 74% to 83% and delivers a very stable cyclic life with 95% of capacity retention after 200 cycles.« less

  5. Low-surface-area hard carbon anode for Na-ion batteries via graphene oxide as a dehydration agent

    SciTech Connect (OSTI)

    Luo, Wei; Bommier, Clement; Jian, Zelang; Li, Xin; Carter, Rich; Vail, Sean; Lu, Yuhao; Lee, Jong -Jan; Ji, Xiulei

    2015-02-04

    Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In this study, we discover that doping graphene oxide into sucrose, the precursor for hard carbon, can effectively reduce the specific surface area of hard carbon to as low as 5.4 m/g. We further reveal that such doping can effectively prevent foaming during caramelization of sucrose and extend the pyrolysis burn-off of sucrose caramel over a wider temperature range. Thus, the obtained low-surface-area hard carbon greatly improves the first-cycle Coulombic efficiency from 74% to 83% and delivers a very stable cyclic life with 95% of capacity retention after 200 cycles.

  6. Enhancement of second harmonic generation in NaNO{sub 2}-infiltrated opal photonic crystal using structural light focusing

    SciTech Connect (OSTI)

    Zaytsev, Kirill I. Yurchenko, Stanislav O.

    2014-08-04

    Experimental and numerical results for second harmonic generation (SHG) in photonic crystal (PC) based on NaNO{sub 2}-infiltrated opal matrix are presented. SHG is performed in reflection mode; thus, the direction of the SHG maximum is equal to the angle of mirror reflection. The PC was pumped with femtosecond optical pulses at different angles of incidence, allowing the dependence of the SHG efficiency on the location of the fundamental wavelength toward the PC band gap (BG) to be examined. The most efficient SHG was observed when pumping the BG of the PC. To interpret the experimental results, finite-difference time-domain numerical simulations of the light interaction with the PC were conducted. The observed effect of highly efficient SHG is associated with structural light focusing, and, as a consequence, with strong optical field localization within certain near-surface PC regions. Thus, SHG enhancement based on structural light focusing in PC was demonstrated.

  7. Evidence for the onset of deconfinement and quest for the critical point by NA49 at the CERN SPS

    SciTech Connect (OSTI)

    Melkumov, G. L.; Anticic, T.; Baatar, B.; Barna, D.; Bartke, J.; Beck, H.; Betev, L.; Bialkowska, H.; Blume, C.; Bogusz, M.; Boimska, B.; Book, J.; Botje, M.; Buncic, P.; Cetner, T.; Christakoglou, P.; Chung, P.; Chvala, O.; Cramer, J. G.; Eckardt, V.; and others

    2012-05-15

    The NA49 results on hadron production obtained in PbPb collisions at SPS energies from 20 to 158 A GeV are shown and discussed as evidence for the onset of deconfinement. The primary measures are the pion yield, the kaon-to-pion ratio and the slope parameter of transverse mass distributions. The possible indication of the QCD critical point signatures was investigated in the event-by-event fluctuations of various observables such as the mean transverse momentum, particle multiplicity and azimuthal angle distributions as well as in the particle ratio fluctuations. The energy dependence of these observables was measured in central PbPb collisions in the full SPS energy range while for analysis of the system size dependence data from pp, CC, SiSi, and PbPb collisions at the top SPS energy were used.

  8. ..&rrbt, Chief, Industrial Hy&na Branch, HerlthbrSas8byLaboratoly

    Office of Legacy Management (LM)

    tf..@ ..&rrbt, Chief, Industrial Hy&na Branch, HerlthbrSas8byLaboratoly ;,.; , ' 1 ' @@w-w 3, 1954 P. B. Klevin, Indurtrial Hygiexn J5rantah, Barrlei &'afelky Lab0raM~ : . .A , 3 t :;p,: . NATIONAL LEiD OF OHIO ROLLINO OFERATIONS AT SIHONr>s SAW 6 STEEL- Amm', +I& y9, <: '.. SmBoLt HSHtPBK ' -: - St. Louis Area Office at the Simnds Saw and Steel Co., k&port, NJ., on tha &boVe clrtm, I oblruloed tb Mat;Lonal Uad umu&m and thorium roll- ing operations which were

  9. The Role of FeS in Initial Activation and Performance Degradation of Na-NiCl2 Batteries

    SciTech Connect (OSTI)

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; Engelhard, Mark H.; Lemmon, John P.; Sprenkle, Vincent L.

    2014-12-25

    The role of iron sulfide (FeS) in initial cell activation and degradation in the Na-NiCl2 battery was investigated in this work. The research focused on identifying the effects of the FeS level on the electrochemical performance and morphological changes in the cathode. The x-ray photoelectron spectroscopy study along with battery tests revealed that FeS plays a critical role in initial battery activation by removing passivation layers on Ni particles. It was also found that the optimum level of FeS in the cathode resulted in minimum Ni particle growth and improved battery cycling performance. The results of electrochemical characterization indicated that sulfur species generated in situ during initial charging, such as polysulfide and sulfur, are responsible for removing the passivation layer. Consequently, the cells containing elemental sulfur in the cathode exhibited similar electrochemical behavior during initial charging compared to that of the cells containing FeS.

  10. Influence of cadmium on ketamine-induced anesthesia and brain microsomal Na[sup +], K[sup +]-ATPase in mice

    SciTech Connect (OSTI)

    Shen, Y.; Sangiah, S. )

    1994-10-01

    Cadmium is a rare metallic element, present in almost all types of food. Shellfish, wheat and rice accumulate very high amounts. Occupational and environmental pollutants are the main sources of cadmium exposure. Cadmium has a very long biologic half-life. Exposure to Cadmium causes anemia, hypertension, hepatic, renal, pulmonary and cardiovascular disorders as well as being a possible mutagen, teratogen and carcinogen. Acute cadmium treatment increased the hexobarbital sleeping time and inhibited hepatic microsomal drug metabolism due to a decrease in cytochrome P[sub 450] content. Cadmium potentiated ethanol-induced sleep in a dose-dependent manner. Cadmium has been shown to inhibit brain microsomal Na[sup +], K[sup +]-ATPase activity in vitro and in vivo. Cadmium and ethanol additively inhibited brain Na[sup +], K[sup +]-ATPase. This might be a direct interaction between cadmium and ethanol in the central nervous system. Ketamine is an intravenous anesthetic agent. It acts on central nervous system and produces [open quotes]dissociative anaesthesia.[close quotes] Ketamine provides adequate surgical anesthesia and is used alone in humans and/or combination with xylazine, an [alpha][sub 2]-adrenergic agonist in animals. It produces CNS depression, analgesia, amnesia, immobility and a feeling of dissociation from the environment. Ketamine is a non-competitive antagonist of the NMDA subset of the glutamate receptor. This perhaps results in an increase in neuronal activity leading to disorganization of normal neurotransmission and produces dissociative anesthetic state. Because it is different from most other anesthetics, ketamine may be expected to have a unique effect on brain biochemical parameters and enzymes. The purpose of this study was to examine the interactions between cadmium and ketamine on the central nervous system and ATPase, in an attempt to further understand the mechanism of action. 12 refs., 3 figs.

  11. The reaction mechanism of SnSb and Sb thin film anodes for Na-ion batteries studied by X-ray diffraction, 119Sn and 121Sb M ssbauer spectroscopies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Baggetto, Loic; Hah, Hien-Yoong; Jumas, Dr. Jean-Claude; Johnson, Prof. Dr. Charles E.; Johnson, Jackie A.; Keum, Jong Kahk; Bridges, Craig A; Veith, Gabriel M

    2014-01-01

    The electrochemical reaction of Sb and SnSb anode materials with Na results in the formation of amorphous materials. To understand the resulting phases and electrochemical capacities we studied the reaction products local order using 119Sn and 121Sb M ssbauer spectroscopies in conjunction with measurements performed on model powder compounds of Na-Sn and Na-Sb to further clarify the reactions steps. For pure Sb the discharge (sodiation) starts with the formation of an amorphous phase composed of atomic environments similar to those found in NaSb, and proceeds further by the formation of environments similar to that present in Na3Sb. The reversible reactionmore » takes place during a large portion of the charge process. At full charge the anode material still contains a substantial fraction of Na, which explains the lack of recrystallization into crystalline Sb. The reaction of SnSb yields Na3Sb crystalline phase at full discharge at higher temperatures (65 and 95 C) while the room temperature reaction yields amorphous compounds. The electrochemically-driven, solid-state amorphization reaction occurring at room temperature is governed by the simultaneous formation of Na-coordinated Sn and Sb environments, as monitored by the decrease (increase) of the 119Sn (121Sb) M ssbauer isomer shifts. Overall, the monitoring of the hyperfine parameters enables to correlate the changes in Na content to the individual Sn and Sb local chemical environments.« less

  12. Luminescent properties of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} and its potential application in white light emitting diodes

    SciTech Connect (OSTI)

    Wang, Zhijun; Li, Panlai; Li, Ting; Zhang, Xing; Li, Qingxuan; Yang, Zhiping; Guo, Qinglin

    2013-06-01

    Graphical abstract: Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} phosphor can be effectively excited by an ultraviolet and near-ultraviolet light, and produce a bright blue emission centered at 436 nm. The CIE chromaticity coordinations (x, y) of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+}(NSCE)/Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}(LSSE) vary with the molar ratio of the two constituents. When NSCE/LSSE is 1:3, the CIE chromaticity coordination is (0.332, 0.346), which is close to that of the natural sunlight (0.33, 0.33). The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a promising blue phosphor for UV chip-based multi-phosphor converted white light emitting diodes. Highlights: ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} shows the blue emission with a peak at 436 nm and broad excitation band in the UV/n-UV range. ? White light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor with the Li{sub 2}SrSiO{sub 4}:Eu{sup 2+} yellow phosphor. ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} would be a promising blue phosphor candidate for UV chip-based multi-phosphor converted white LEDs. - Abstract: A novel blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is synthesized by a high temperature solid-state reaction, and its luminescent properties are systematically studied. Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} can be effectively excited by the 354 nm radiation, and create blue emission (436 nm). The emission intensity of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is influenced by the Eu{sup 2+} doping content, and the optimal doping content is 1.5%, and the concentration quenching mechanism of Eu{sup 2+} in Na{sub 2}CaSiO{sub 4} can be attributed to the multipolar interaction. The white light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} with the yellow phosphor Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}. The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a potential blue emitting phosphor for UV chip-based multi-phosphor converted white light emitting diodes.

  13. Natural Gas Wellhead Price

    Gasoline and Diesel Fuel Update (EIA)

    NA NA NA NA NA NA 1973

  14. STELLAR CORONAE, SOLAR FLARES: A DETAILED COMPARISON OF {sigma} GEM, HR 1099, AND THE SUN IN HIGH-RESOLUTION X-RAYS

    SciTech Connect (OSTI)

    Huenemoerder, David P.; Phillips, Kenneth J. H.; Sylwester, Janusz; Sylwester, Barbara E-mail: kennethjhphillips@yahoo.com E-mail: bs@cbk.pan.wroc.pl

    2013-05-10

    The Chandra High Energy Transmission Grating Spectrometer (HETG) spectra of the coronally active binary stars {sigma} Gem and HR 1099 are among the highest fluence observations for such systems taken at high spectral resolution in X-rays with this instrument. This allows us to compare their properties in detail to solar flare spectra obtained with the Russian CORONAS-F spacecraft's RESIK instrument at similar resolution in an overlapping bandpass. Here we emphasize the detailed comparisons of the 3.3-6.1 A region (including emission from highly ionized S, Si, Ar, and K) from solar flare spectra to the corresponding {sigma} Gem and HR 1099 spectra. We also model the larger wavelength range of the HETG, from 1.7 to 25 A - having emission lines from Fe, Ca, Ar, Si, Al, Mg, Ne, O, and N-to determine coronal temperatures and abundances. {sigma} Gem is a single-lined coronally active long-period binary which has a very hot corona. HR 1099 is a similar, but shorter period, double-lined system. With very deep HETG exposures we can even study emission from some of the weaker species, such as K, Na, and Al, which are important since they have the lowest first ionization potentials, a parameter well known to be correlated with elemental fractionation in the solar corona. The solar flare temperatures reach Almost-Equal-To 20 MK, comparable to the {sigma} Gem and HR 1099 coronae. During the Chandra exposures, {sigma} Gem was slowly decaying from a flare and its spectrum is well characterized by a collisional ionization equilibrium plasma with a broad temperature distribution ranging from 2 to 60 MK, peaking near 25 MK, but with substantial emission from 50 MK plasma. We have detected K XVIII and Na XI emission which allow us to set limits on their abundances. HR 1099 was also quite variable in X-rays, also in a flare state, but had no detectable K XVIII. These measurements provide new comparisons of solar and stellar coronal abundances, especially at the lowest first ionization potential (FIP) values. The low FIP elements do not show enhancement in the stellar coronae as they do in the Sun, except perhaps for K in {sigma} Gem. While {sigma} Gem and HR 1099 differ in their emission measure distributions, they have very similar elemental abundances.

  15. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe?(MoO?)?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe?(MoO?)? electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na? and Li?, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe?(MoO?)? and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmorepartially sodiated Fe?(MoO?)? are obtained during the discharge processes of Li/Fe?(MoO?)? and Na/Fe?(MoO?)? cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.less

  16. Synthesis, structural and electrical properties of a new cobalt arsenate NaCo{sub 2}As{sub 3}O{sub 10}

    SciTech Connect (OSTI)

    Ben Smida, Y.; Marzouki, R.; Guesmi, A.; Georges, S.; Zid, M.F.

    2015-01-15

    The title compound sodium dicobalt triarsenate NaCo{sub 2}As{sub 3}O{sub 10} has been synthesized by solid state reaction. Crystal structure and electrical properties were studied by X-ray diffraction and complex impedance spectroscopy, respectively. The obtained structural model is supported by charge-distribution (CHARDI) analysis and bond-valence-sum (BVS) validations tools. The structure (triclinic, P?1, a=6.800 (8) , b=7.816 (9) , c=8.718 (3) , ?=108.03 (2), ?=108.48 (3), ?=100.11 (2)) can be described as a three-dimensional framework resulted from corner-connection between cobalt metallic chains running along [?110] and As{sub 3}O{sub 10} groups; the negative charge is balanced by Na{sup +} ions which house the two tunnels parallel to a and b axes. Ball milling was used as mechanical means to reduce the particles sizes of the synthesized powder. At the optimal sintering temperature of 650 C, 85% of the relative density was obtained. The conductivity measurements show that NaCo{sub 2}As{sub 3}O{sub 10} is a cationic conductor with an activation energy of 0.48 eV and a conductivity of ?=1.210{sup ?5} S cm{sup ?1} at 310 C. The BVS model is extended to simulate the ionic migration pathways of alkali cations in the anionic framework. - Graphical abstract: 1D pathways link Na atoms along the a-axis with bond valence mismatch |?V(Na)|=0.64 v.u. - Highlights: A new single crystal NaCo{sub 2}As{sub 3}O{sub 10} was grown by solid state reaction and its structure determined by single-crystal X-ray diffraction. The purity of the powder sample was verified by Rietveld refinement. The CIS measurements were optimized and the obtained spectra were fitted by electrical equivalent circuits. The conduction pathways for Na{sup +} cations are simulated by means of the bond valence sum model.

  17. Federal Offshore Gulf of Mexico Natural Gas Gross Withdrawals and

    Gasoline and Diesel Fuel Update (EIA)

    Production 121,847 124,795 122,038 116,075 103,357 109,286 1997-2015 From Gas Wells NA NA NA NA NA NA 1997-2015 From Oil Wells NA NA NA NA NA NA 1997-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1997-2015 Vented and Flared NA NA NA NA NA NA 1997-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1997-2015 Marketed Production 120,019 122,924 120,208 114,334 101,806 107,646 1997-2015 Dry Production

  18. Texas Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    752,341 754,086 731,049 739,603 714,788 720,593 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production 675,828 677,396 656,702 664,386 642,094 647,308

  19. New Mexico Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    109,430 112,061 109,134 112,013 107,721 102,253 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1996-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production 105,797 108,340 105,510 108,294 104,145 98,858

  20. North Dakota Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    51,167 50,537 47,895 50,958 49,559 51,065 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1996-2015 Vented and Flared NA NA NA NA NA NA 1996-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production 40,494 39,995 37,904 40,328 39,221 40,413

  1. Ohio Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    88,406 87,904 89,371 104,127 104,572 113,096 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production 88,406 87,904 89,371 104,127 104,572 113,096 1991

  2. Oklahoma Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    217,883 213,529 204,298 209,342 200,704 206,487 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1996-2015 Vented and Flared NA NA NA NA NA NA 1996-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production 217,883 213,529 204,298 209,342 200,704 206,487 1989

  3. Other States Total Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    52,422 52,053 51,181 51,756 49,472 48,285 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production 50,729 50,372 49,527 50,084 47,874 46,725 1989-2015 Dry Production 2006-2

  4. Pennsylvania Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    398,737 408,325 396,931 404,431 403,683 429,251 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production 398,737 408,325 396,931 404,431 403,683 429,251

  5. Wyoming Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    68,548 167,539 162,880 167,555 163,345 165,658 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production 150,260 149,361 145,208 149,375 145,622 147,684 1989

  6. Utah Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    35,984 33,029 30,933 31,404 30,891 34,204 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1994-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1996-2015 Marketed Production 35,984 33,029 30,933 31,404 30,891 34,204

  7. West Virginia Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    15,055 114,871 111,932 108,711 96,802 105,945 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and Flared NA NA NA NA NA NA 1991-2015 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 1991-2015 Marketed Production 115,055 114,871 111,932 108,711 96,802 105,945 1991

  8. {gamma}-Radiolysis of NaCl Brine in the Presence of UO{sub 2}(s): Effects of Hydrogen and Bromide

    SciTech Connect (OSTI)

    Metz, Volker; Bohnert, Elke; Kelm, Manfred; Schild, Dieter; Kienzler, Bernhard

    2007-07-01

    A concentrated NaCl solution was {gamma}-irradiated in autoclaves under a pressure of 25 MPa. A set of experiments were conducted in 6 mol (kg H{sub 2}O){sup -1} NaCl solution in the presence of UO{sub 2}(s) pellets; in a second set of experiments, {gamma}-radiolysis of the NaCl brine was studied without UO{sub 2}(s). Hydrogen, oxygen and chlorate were formed as long-lived radiolysis products. Due to the high external pressure, all radiolysis products remained dissolved. H{sub 2} and O{sub 2} reached steady state concentrations in the range of 5.10{sup -3} to 6.10{sup -2} mol (kg H{sub 2}O){sup -1} corresponding to a partial gas pressure of {approx}2 to {approx}20 MPa. Radiolytic formation of hydrogen and oxygen increased with the concentration of bromide added to solution. Both, in the presence of bromide, resulting in a relatively high radiolytic yield, and in the absence of bromide surfaces of the UO{sub 2}(s) samples were oxidized, and concentration of dissolved uranium reached the solubility limit of the schoepite / NaUO{sub 2}O(OH)(cr) transition. At the end of the experiments, the pellets were covered by a surface layer of a secondary solid phase having a composition close to Na{sub 2}U{sub 2}O{sub 7}. The experimental results demonstrate that bromide counteracts an H{sub 2} inhibition effect on radiolysis gas production, even at a concentration ratio of [H{sub 2}] / [Br{sup -}] > 100. The present observations are related to the competitive reactions of OH radicals with H{sub 2}, Br{sup -} and Cl{sup -}. A similar competition of hydrogen and bromide, controlling the yield of {gamma}-radiolysis products, is expected for solutions of lower Cl{sup -} concentration. (authors)

  9. Boron uptake in tumors, cerebrum and blood from [10B]NA4B24H22S2

    DOE Patents [OSTI]

    Slatkin, Daniel N.; Micca, Peggy L.; Fairchild, Ralph G.

    1988-01-01

    A stable boronated (.sup.10 B-labeled) compound, sodium mercaptoundecahydrododecaborate is infused in the form of the disulfide dimer, [.sup.10 B]Na.sub.4 B.sub.24 H.sub.22 S.sub.2, at a dose of about 200 .mu.g .sup.10 B per gm body weight. The infusion is performed into the blood or peritoneal cavity of the patient slowly over a period of many days, perhaps one week or more, at the rate of roughly 1 .mu.g .sup.10 B per gm body weight per hour. Use of this particular boronated dimer in the manner or similarly to the manner so described permits radiotherapeutically effective amounts of boron to accumulate in tumors to be treated by boron neutron capture radiation therapy and also permits sufficient retention of boron in tumor after the cessation of the slow infusion, so as to allow the blood concentration of .sup.10 B to drop or to be reduced artificially to a radiotherapeutically effective level, less than one-half of the concentration of .sup.10 B in the tumor.

  10. Using GC-FID to Quantify the Removal of 4-sec-Butylphenol from NGS Solvent by NaOH

    SciTech Connect (OSTI)

    Sloop, Jr., Frederick V.; Moyer, Bruce A.

    2014-12-01

    A caustic wash of the solvent used in the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process was found to remove the modifier breakdown product 4-sec-butylphenol (SBP) with varying efficiency depending on the aqueous NaOH concentration. Recent efforts at ORNL have aimed at characterizing the flowsheet chemistry and reducing the technical uncertainties of the NG-CSSX process. One technical uncertainty has been the efficacy of caustic washing of the solvent for the removal of lipophilic anions, in particular, the efficient removal of SBP, an important degradation product of the solvent modifier, Cs-7SB. In order to make this determination, it was necessary to develop a sensitive and reliable analytical technique for the detection and quantitation of SBP. This report recounts the development of a GC-FID-based (Gas Chromatography Flame Ionization Detection) technique for analyzing SBP and the utilization of the technique to subsequently confirm the ability of the caustic wash to efficiently remove SBP from the Next Generation Solvent (NGS) used in NG-CSSX. In particular, the developed technique was used to monitor the amount of SBP removed from a simple solvent and the full NGS by contact with sodium hydroxide wash solutions over a range of concentrations. The results show that caustic washing removes SBP with effectively the same efficiency as it did in the original Caustic-Side Solvent Extraction (CSSX) process.

  11. Laboratory Test Report for Fujitsu 12RLS and Mitsubishi FE12NA Mini-Split Heat Pumps

    SciTech Connect (OSTI)

    Winkler, J.

    2011-09-01

    Mini-split heat pumps are being proposed as a new retrofit option to replace resistance heating in the Pacific Northwest. NREL has previously developed a field test protocol for mini-split systems to ensure consistent results from field tests. This report focuses on the development of detailed system performance maps for mini-split heat pumps so that the potential benefits of mini-split systems can be accurately analyzed for different climate regions and housing types. This report presents laboratory test results for two mini-split heat pumps. Steady-state heating and cooling performance for the Fujitsu 12RLS and Mitsubishi FE12NA was tested under a wide range of outdoor and indoor temperatures at various compressor and fan speeds. Cycling performance for each unit was also tested under both modes of operation. Both systems performed quite well under low loads and the experimental test data aligned with manufacturer reported values. Adequate datasets were attained to promote performance modeling of these two systems in the future.

  12. Preparation, catalysis, and characterization of highly dispersed molybdenum sulfide catalysts supported on a NaY zeolite

    SciTech Connect (OSTI)

    Okamoto, Yasuaki; Katsuyama, Hiromoto [Osaka Univ., Toyonaka, Osaka (Japan)] [Osaka Univ., Toyonaka, Osaka (Japan)

    1996-06-01

    The structure and dispersion of the molybdenum sulfides supported on a NaY zeolite were studied using XAFS techniques. It was found that molybdenum sulfide species prepared by sulfiding vapor deposited Mo(CO){sub 6} or by sulfiding molybdenum oxide dimer species encaged in the zeolite are highly dispersed and thermally stabilized against sintering or restructuring. These molybdenum species are formed via molybdenum sulfide dimer species as an intermediate. On the other hand, with the molybdenum sulfide catalysts prepared by an impregnation method, the sulfidation of molybdenum oxides was incomplete. The molybdenum oxide species are suggested to be mainly located in the zeolite cavities after calcination, forming isolated molybdenum oxides in tetrahedral configurations. The molybdenum sulfide species prepared from Mo(CO){sub 6} showed much higher catalytic activities for thiophene hydrodesulfurization and butadiene hydrogenation than the molybdenum sulfides prepared by the impregnation, in conformity with a higher dispersion and higher fraction of the molybdenum sulfide species. It is demonstrated that in combination with metal carbonyl techniques, zeolite supports are very suitable for the preparation of highly dispersed molybdenum sulfides at a high Mo loading.

  13. Study the performance of photogalvanic cells for solar energy conversion and storage: Rose Bengal-D-Xylose-NaLS system

    SciTech Connect (OSTI)

    Gangotri, K.M.; Bhimwal, Mahesh Kumar

    2010-07-15

    The Rose Bengal is used as photosensitizer with D-Xylose as reductant and sodium lauryl sulphate (NaLS) as surfactant for the enhancement of the conversion efficiency and storage capacity of photogalvanic cell for its commercial viability. The observed value of the photogeneration of photopotential was 885.0 mV and photocurrent was 460.0 {mu}A whereas maximum power of the cell was 407.10 {mu}W. The observed power at power point was 158.72 {mu}W and the conversion efficiency was 1.52%. The fill factor 0.3151 was experimentally determined at the power point of the cell. The rate of initial generation of photocurrent was 63.88 {mu}A min{sup -1}. The photogalvanic cell so developed can work for 145.0 min in dark on irradiation for 165.0 min, i.e. the storage capacity of the photogalvanic cell is 87.87%. A simple mechanism for the photogeneration of photocurrent has also been proposed. (author)

  14. U.S. Natural Gas Citygate Price (Dollars per Thousand Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 NA NA NA NA NA NA NA NA NA NA NA NA 1981 NA NA NA NA NA NA NA NA NA NA NA NA 1982 NA NA NA NA NA NA NA NA NA NA NA NA 1983 NA NA NA NA NA NA NA NA NA 3.97

  15. DOE/NA-0038

    National Nuclear Security Administration (NNSA)

    ... The wide optical window of diamonds allows us to probe (in situ) the effect of high P-T on ... implemented at the SNL Z-Machine, the entropy in the shock state of iron was determined. ...

  16. 20Na.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  17. 20Na_78.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  18. DOE/NA-0027

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 2015 Stewardship Science Academic Programs Annual  Stewardship Science Academic Alliances  High Energy Density Laboratory Plasmas  National Laser Users' Facility  Predictive Science Academic Alliance Program II On the Cover High energy density plasma deflagrations from a coaxial gun form highly concentrated dense plasma jets used to study first-wall fusion reactor science. - Photo courtesy of Dr. Mark Cappelli, Stanford University (see page 18). This report was prepared as an

  19. NA Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy ,' ~Washington, DC 20585 August 22, 2008 Ms. Susan Leckband, Chair I lantord Advisory Board Environissues Hanford Project Office 713 Jadwin Avenue, Suite 4 Richland, Washington 99352 Dear Ms. Leckband: This letter is in response to Hanford AdvisorylBoard (I [ll) consensus advice fi 199, Costs and Baseline Schedules, and to your letter of February 8, 2008. requesting that the Office of Environmental Management share validated and certified H anford cleanup baselines with the

  20. DOE/NA-0038

    National Nuclear Security Administration (NNSA)

    38 2016 Stewardship Science Academic Programs Annual  Stewardship Science Academic Alliances  High Energy Density Laboratory Plasmas  National Laser Users' Facility  Predictive Science Academic Alliance Program II On the Cover This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors or their employees,

  1. (Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C.; Han, W.; Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J.; Ning, F. L.; Munsie, T. J. S.; Medina, T.; Luke, G. M.; Carlo, J. P.; Munevar, J.; Zhang, G. M.; Jin, C. Q.

    2014-10-28

    Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?

  2. Effect of acute treatment with cadmium on ethanol anesthesia, body termperature, and synaptosomal Na/sup +/-K/sup +/-ATPase of rat brain

    SciTech Connect (OSTI)

    Magour, S.; Kristof, V.; Baumann, M.; Assmann, G.

    1981-12-01

    The effect of a single intraperitoneal dose of 0.56, 1.12, and 1.68 mg cadmium/kg on the duration of ethanol-induced sleep was investigated in male rats. Cadmium potentiated ethanol sleeping time in a dose dependent manner up to 300% over controls. No significant difference in the elimination rate of ethanol from blood and brain and observed between control and cadmium-pretreated rats. Cadmium slightly inhibited the hepatic alcohol dehydrogenase in vivo and also potentiated ethanol hypothermia but these changes did not play a significant role in the observed prolongation of ethanol sleeping time. However, cadmium and ethanol additively inhibited brain synaptosomal Na/sup +/-K/sup +/-ATPase in a noncompetitive manner. The results so far indicate that cadmium may increase brain responsiveness toward ethanol partly through inhibition of snaptosomal Na/sup +/-K/sup +/-ATPase.

  3. Preparation of NaGdS{sub 2} via thermolysis of Gd[S{sub 2}CN(C{sub 4}H{sub 8})]{sub 3}-phen complexes and sodium diethyldithiocarbamate mixtures

    SciTech Connect (OSTI)

    Luo, Xixian, E-mail: Luoxixiandl@126.com [Physics Department, Dalian Maritime University, Dalian, Liaoning 116026 (China); Ma, Lubin; Xing, Mingming; Fu, Yao; Zhou, Xiaolin; Sun, Min [Physics Department, Dalian Maritime University, Dalian, Liaoning 116026 (China)

    2013-05-15

    Highlights: ? We adopt a new and simple thermolysis method to synthesise NaGdS{sub 2} compounds. ? The obtained NaGdS{sub 2} presents a microrod morphology with a length diameter ratio of 2.1. ? NaGdS{sub 2} has excellent transmission over a very wide range of wavelengths (>430 nm). ? The route may be used for the synthesis of other AREX{sub 2}-based materials or nanocrystals. - Abstract: A novel, simple thermolysis method is adopted to prepare alkali metal rare earth ternary sulphide NaGdS{sub 2} using Gd(S{sub 2}CNEt{sub 2}){sub 3-}phen complexes and NaS{sub 2}CNEt{sub 2}3H{sub 2}O mixtures as precursors in a nitrogen atmosphere at 6001000 C. The obtained NaGdS{sub 2} presents a microrod morphology with an average diameter of 112 nm, average length of 236 nm, and length diameter ratio of 2.1. Furthermore, the as-prepared NaGdS{sub 2} has excellent transmission over a very wide range of wavelengths (>430 nm) and may be an ideal IR window material.

  4. Helium (3) Rich Solar Flares

    DOE R&D Accomplishments [OSTI]

    Colgate, S. A.; Audouze, J.; Fowler, W. A.

    1977-05-03

    The extreme enrichment of {sup 3} He {sup 4} He greater than or equal to 1 in some solar flares as due to spallation and the subsequent confinement of the products in a high temperature, kT approx. = 200 keV, high density, n{sub e} approx. = 3 x 10{sup 15} cm {sup -3} plasma associated with the magnetic instability producing the flare is interpreted. The pinch or filament is a current of high energy protons that creates the spallation and maintains the temperature that produces the high energy x-ray spectrum and depletes other isotopes D, Li, Be, and B as observed. Finally the high temperature plasma is a uniquely efficient spallation target that is powered by the interaction of stellar convection and self generated magnetic field.

  5. Scintillation properties and electronic structure of the intrinsic and extrinsic mixed elpasolites Cs2 Na REBr3I3 (R = La, Y)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Hua; Du, Mao -Hua; Stand, Luis; Zhao, Zhao; Zhuravleva, Mariya; Melcher, Charles L.; Shi, Hongliang

    2016-02-19

    Scintillators attract wide research interest for their distinct applications in radiation detection. Elpasolite halides are among the most promising scintillators due to their high structural symmetry and good scintillation performance. A better understanding of their underlying scintillation mechanism opens up possibilities in scintillator development. In this work, we employ a variety of experimental techniques to study the two mixed-anion elpasolites Cs2 Na REBr3I3 (R = La, Y). The emission of intrinsic Cs2Na RBr3I3 with a light yield ranging from 20 000 to 40 000 ph / MeV is dominant by self-trapped exciton emission. Partial substitution of R with Ce introducesmore » a competing emission, the Ce3+ 5d-to-4f radiative transition. Ab initio calculations are performed to investigate the electronic structures as well as the binding energies of polarons in Cs2 Na RBr6. The calculated large self-trapped exciton binding energies are consistent with the observed high light yield due to self-trapped exciton (STE) emission. The unique electronic structure of halide elpasolites as calculated enhances the STE stability and the STE emission. The highly tunable scintillation properties of mixed-anion elpasolites underscore the role of their complex scintillation mechanism. Furthermore, our study provides guidance for the design of elpasolite scintillators with exceptional energy resolution and light yield desirable for applications.« less

  6. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Hui; Yu, Xiqian; Bai, Ying; Wu, Feng; Wu, Chuan; Liu, Liang-Yu; Yang, Xiao-Qing

    2015-01-01

    Na3V2-xMgx(PO4)3/C composites with different Mg2+ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg2+ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na3V2-xMgx(PO4)3/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na3V1.95Mg0.05(PO4)3/C. For example, when the current density increased from 1 C to 30 C, the specific capacitymore » only decreased from 112.5 mAh g-1 to 94.2 mAh g-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh g-1 to 86.2 mAh g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.« less

  7. Immobilization of sodium-bearing high-level radioactive waste in synroc containing (Na{sub 0.5}Nd{sub 0.5})TiO{sub 3}-type perovskite

    SciTech Connect (OSTI)

    Li, L.; Luo, S.; Tang, B.; Wang, D.

    1997-01-01

    This study on the immobilization of high-sodium-bearing HLW in synroc indicates that (Na{sub 0.5}Nd{sub 0.5})TiO{sub 3}-type perovskite can be used to incorporate a high content of sodium in synroc. Synroc samples containing 13.0 wt% waste oxide and 5.7 wt% Na{sub 2}O show very well chemical durability and physical properties. The standard Synroc-C formulation can incorporate only 2 wt% Na{sub 2}O, so this study greatly improved the immobilization ability of sodium in Synroc-related material.

  8. Staff Research Physicist (Experimental Research, FLARE) | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental Research, FLARE) Department: Research Staff: RM 02 Requisition Number: 1500503 The Princeton Plasma Physics Laboratory seeks to fill a staff research physicist...

  9. U.S. Price of Natural Gas Sold to Commercial Consumers (Dollars per

    Gasoline and Diesel Fuel Update (EIA)

    Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 NA NA NA NA NA NA NA NA NA NA NA NA 1981 NA NA NA NA NA NA NA NA NA NA NA NA 1982 NA NA NA NA NA NA NA NA NA NA NA NA 1983 NA NA

  10. NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite: A highly efficient visible-light-driven photocatalyst utilizing upconversion

    SciTech Connect (OSTI)

    Sun, Yuanyuan; Wang, Wenzhong Sun, Songmei; Zhang, Ling

    2014-04-01

    Highlights: Design and synthesis of NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} based on upconversion. NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite was prepared for the first time. Coreshell structure benefits the properties. Upconversion contributed to the enhanced photocatalytic activity. Helps to understand the functionality of new type photocatalysts. - Abstract: NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite was designed and prepared for the first time based on upconversion. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution TEM (HRTEM), energy dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectra (DRS). The results revealed that the as-synthesized NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} consisted of spheres with a core diameter of about 26 nm and a shell diameter of around 6 nm. The core was upconversion illuminant NaYF{sub 4}:Er,Yb and the shell was Bi{sub 2}MoO{sub 6} around the core, which was confirmed by EDS. The NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} exhibited higher photocatalytic activity for the photodecomposition of Rhodamine B (RhB) under the irradiation of Xe lamp and green light emitting diode (g-LED). The mechanism of the high photocatalytic activity was discussed by photoluminescence spectra (PL), which is mainly attributed to upconversion of NaYF{sub 4}:Er,Yb in the NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite and the coreshell structure.

  11. Hierarchical Na-doped cubic ZrO{sub 2} synthesis by a simple hydrothermal route and its application in biodiesel production

    SciTech Connect (OSTI)

    Lara-Garca, Hugo A.; Romero-Ibarra, Issis C.; Pfeiffer, Heriberto

    2014-10-15

    Hierarchical growth of cubic ZrO{sub 2} phase was successfully synthesized via a simple hydrothermal process in the presence of different surfactants (cationic, non-ionic and anionic) and sodium hydroxide. The structural and microstructural characterizations of different ZrO{sub 2} powders were performed using various techniques, such as X-ray diffraction, transmission electron microscopy, N{sub 2} adsorptiondesorption, scanning electron microscopy and infrared. Results indicated that sodium addition stabilized the cubic ZrO{sub 2} phase by a Na-doping process, independently of the surfactant used. In contrast, microstructural characteristics varied as a function of the surfactant and sodium presence. In addition, water vapor (H{sub 2}O) and carbon dioxide (CO{sub 2}) sorption properties were evaluated on ZrO{sub 2} samples. Results evidenced that sample surface reactivity changed as a function of the sodium content. Finally, this surface reactivity was evaluated on the biodiesel transesterification reaction using the different synthesized samples, obtaining yields of 93%. - Graphical abstract: Hierarchical growth of cubic Na-ZrO{sub 2} phase was synthesized by hydrothermal processes in the presence of surfactants and sodium. Sodium addition stabilized the cubic phase by a Na-doping process, while the microstructural characteristics varied with surfactants. Finally, this surface reactivity was evaluated on the biodiesel transesterification reaction. - Highlights: Cubic-ZrO{sub 2} phase was synthesized via a simple hydrothermal process. ZrO{sub 2} structure and microstructures changed as a function of the surfactant. Cubic-ZrO{sub 2} phase was evaluated on the biodiesel transesterification reaction.

  12. Surface Complexation of Neodymium at the Rutile-Water Interface: A Potentiometric and Modeling Study in NaCl Media to 250C

    SciTech Connect (OSTI)

    Ridley, Mora K.; Machesky, Michael L.; Wesolowski, David J; Palmer, Donald

    2005-01-01

    The adsorption of Nd{sup 3+} onto rutile surfaces was examined by potentiometric titration from 25 to 250 C, in 0.03 and 0.30m NaCl background electrolyte. Experimental results show that Nd{sup 3+} sorbs strongly, even at low temperature, with adsorption commencing below the pHznpc of rutile. In addition, there is a systematic increase in Nd{sup 3+} adsorption with increasing temperature. The experimental results were rationalized and described using surface oxygen proton affinities computed from the MUlti SIte Complexation or MUSIC model, coupled with a Stern-based three-layer description of the oxide/water interface. Moreover, molecular-scale information was incorporated successfully into the surface complexation model, providing a unique geometry for the adsorption of Nd{sup 3+} on rutile. The primary mode of Nd{sup 3+} adsorption was assumed to be the tetradentate configuration found for Y{sup 3+} adsorption on the rutile (110) surface from previously described in situ X-ray standing wave experiments, wherein the sorbing cations bond directly with two adjacent ''terminal'' and two adjacent ''bridging'' surface oxygen atoms. Similarly, the adsorption of Na{sup +} counterions was also assumed to be tetradentate, as supported by MD simulations of Na{sup +} interactions with the rutile (110) surface, and by analogous X-ray standing wave results for Rb{sup +} adsorption on rutile. Fitting parameters for Nd{sup 3+} adsorption included binding constants for the tetradentate adsorption complex and capacitance values for the inner-sphere binding plane. In addition, hydrolysis of the tetradentate adsorption complex was permitted and resulted in significantly improved model fits at higher temperature and pH values. The modeling results indicate that the Stern-based MUSIC surface-complexation model adequately accommodates molecular-scale information to uniquely rationalize and describe multivalent ion adsorption systematically into the hydrothermal regime.

  13. In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution

    SciTech Connect (OSTI)

    Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

    2010-03-31

    A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

  14. NaLaF{sub 4}:Pr{sup 3+},Yb{sup 3+}, an efficient blue to near infra-red quantum cutter

    SciTech Connect (OSTI)

    Guille, A.; Pereira, A.; Moine, B.

    2013-12-01

    In order to reduce the thermalization losses in solar cells, down-conversion of blue photons into near infra-red photons is a promising solution. In the present paper, we analyse the energy transfer processes between Pr{sup 3+} and Yb{sup 3+} in NaLaF{sub 4} and we show that an efficient quantum-cutting process occurs. Nevertheless, we also show that a back transfer from Yb{sup 3+} toward the {sup 1}G{sub 4} level of Pr{sup 3+} ion leading to emission beyond 1??m reduces the potentiality of this material as a quantum cutter for Si solar cells.

  15. Improvement of the piezoelectric properties in (K,Na)NbO{sub 3}-based lead-free piezoelectric ceramic with two-phase co-existing state

    SciTech Connect (OSTI)

    Yamada, H. Matsuoka, T.; Kozuka, H.; Yamazaki, M.; Ohbayashi, K.; Ida, T.

    2015-06-07

    Two phases of (K,Na)NbO{sub 3} (KNN) co-exist in a KNN-based composite lead-free piezoelectric ceramic 0.910(K{sub 1?x}Na{sub x}){sub 0.86}Ca{sub 0.04}Li{sub 0.02}Nb{sub 0.85}O{sub 3??}0.042K{sub 0.85}Ti{sub 0.85}Nb{sub 1.15}O{sub 5} 0.036BaZrO{sub 3}0.0016Co{sub 3}O{sub 4} 0.0025Fe{sub 2}O{sub 3}0.0069ZnO system, over a wide range of Na fractions, where 0.56???x???0.75. The crystal systems of the two KNN phases are identified to tetragonal and orthorhombic by analyzing the synchrotron powder X-ray diffraction (XRD) data, high-resolution transmission electron microscopy (HR-TEM), and selected-area electron diffraction (SAD). In the range 0.33???x???0.50, the main component of the composite system is found to be single-phase KNN with a tetragonal structure. Granular nanodomains of the orthorhombic phase dispersed in the tetragonal matrix have been identified by HR-TEM and SAD for 0.56???x???0.75. Only a trace amount of the orthorhombic phase has been found in the SAD patterns at the composition x?=?0.56. However, the number of orthorhombic nanodomains gradually increases with increasing Na content up to x?

  16. The solubility of zinc oxide in 0.03 m NaTr as a function of temperature, with in situ pH measurement

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-01

    The solubility of zincite (ZnO) has been measured in noncomplexing solutions over a wide range of pH{sub m} (4--11), and temperature (75--200 C) at 0.03 mol/kg ionic strength in NaTr media (sodium trifluoromethanesulfonate, a noncomplexing 1:1 electrolyte), in a hydrogen electrode concentration cell (HECC), which provided continuous in situ measurement of hydrogen ion molality. Total zinc content was analyzed by atomic absorption using graphite furnace, flame, and inductively coupled plasma (ICP) spectrometers. The direction of approach to the equilibrium saturation state was varied to demonstrate that the system was reversible thermodynamically. Separate experiments were performed in alkaline solutions (0.03 mol/kg NaOH) at 25 and 50 C in polypropylene syringes, and between 50 and 290 C in a Teflon-lined pressure vessel. The aim of these experiments was to reach higher pH{sub m} (>8 depending on the temperature) to determine the thermodynamic properties of the negatively charged species, Zn(OH){sub 3}{sup {minus}}. A least-squares regression of the results obtained at this ionic strength was used to determine the molal solubility products (Q{sub sn}) of zincite. The solubility products (Q{sub sn}) were extrapolated to infinite dilution (K{sub sn}), permitting calculation of the thermodynamic properties of aqueous species of zinc for comparison with previous work.

  17. Report on the GC-MBS method for correcting NaI spectra for transmission loss in hand-held instruments

    SciTech Connect (OSTI)

    Rawool-Sullivan, M.

    1997-10-08

    The goals of this project were (1) to develop a capability to study the scattered components in the NaI spectra of attenuated sources and (2) to evaluate the effectiveness of the gross count material basis set (GC-MBS) method in quantifying transmission losses from the shapes of measured NaI spectra. These goals are related, as the GC-MBS method involves a linear log-spectrum decomposition into MBS component spectra, and scattered gamma rays represent a significant nonlinear interference. Eventually, the authors hope to understand the effect of the scattered components on the MBS decomposition and to develop ways to correct for inaccuracies. As of this writing the authors have not reached that long-term objective, so the two halves of this project are treated here as separate topics, with a separate section for each. They have substantially achieved both of the project goals and are collecting additional data for two publications at the upcoming IEEE conference in Albuquerque, NM--one paper about their work on scattering and another on the GC-MBS method. This project report will contain preliminary portions of those two papers.

  18. g-C{sub 3}N{sub 4}/NaTaO{sub 3} organicinorganic hybrid nanocomposite: High-performance and recyclable visible light driven photocatalyst

    SciTech Connect (OSTI)

    Kumar, Santosh; Kumar, Bharat; Surendar, T.; Shanker, Vishnu

    2014-01-01

    Graphical abstract: High-performance and recyclable visible-light driven g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposite photocatalysts have been prepared by a facile ultrasonic dispersion method. The hybrid nanocomposite photocatalyst can be promising photocatalytic material for practical application in water splitting and environmental remediation. - Highlights: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites as a high performance and recyclable photocatalysts. These catalysts exhibited significantly enhanced photocatalytic activity under UVvisible light irradiation. More attractively, dramatic activity is generated under visible light irradiation due to the g-C{sub 3}N{sub 4} loaded. Interestingly, the as-prepared hybrid nanocomposites possess high reusability. - Abstract: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposites have been prepared by a facile ultrasonic dispersion method. Our results clearly show the formation of interface between NaTaO{sub 3} and g-C{sub 3}N{sub 4} and further loading of g-C{sub 3}N{sub 4} did not affect the crystal structure and morphology of NaTaO{sub 3}. The g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites exhibited enhanced photocatalytic performance for the degradation of Rhodamine B under UVvisible and visible light irradiation compared to pure NaTaO{sub 3} and Degussa P25. Interestingly, the visible light photocatalytic activity is generated due to the loading of g-C{sub 3}N{sub 4}. A mechanism is proposed to discuss the enhanced photocatalytic activity based on trapping experiments of photoinduced radicals and holes. Under visible light irradiation, electron excited from the valance band (VB) to conduction band (CB) of g-C{sub 3}N{sub 4} could directly inject into the CB of NaTaO{sub 3}, making g-C{sub 3}N{sub 4}/NaTaO{sub 3} visible light driven photocatalyst. Since the as-prepared hybrid nanocomposites possess high reusability therefore it can be promising photocatalyst for environmental applications.

  19. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    SciTech Connect (OSTI)

    Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; Kang, Kisuk; Li, Hong; Yang, Xiao-Qing; Chen, Liquan; Huang, Xuejie

    2015-03-25

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.

  20. ON THE DURATION OF BLAZAR SYNCHROTRON FLARES

    SciTech Connect (OSTI)

    Eichmann, B.; Schlickeiser, R.; Rhode, W.

    2012-01-10

    A semi-analytical model is presented that describes the temporal development of a blazar synchrotron flare for the case of a broadband synchrotron power spectrum. We examine three different injection scenarios and present its influence on the synchrotron flare. An accurate approximation of the half-life of a synchrotron flare is analytically computed and we give some illustrative examples of the time evolution of the emergent synchrotron intensity by using a numerical integration method. The synchrotron flare starts at all photon energies right after the injection of ultrarelativistic electrons into the spherical emission volume of radius R and its duration exceeds the light travel time 2R/c in the low energy regime. Furthermore, the flare duration extends by the period of injection of relativistic electrons into the emission knot. However, the energetic and spatial distribution of these injected electrons has no significant influence on the flare duration. We obtain a temporal behavior that agrees most favorably with the observations of PKS 2155-304 on 2006 July 29-30 and it differs considerably from the results that were recently achieved by using a monochromatic approximation of the synchrotron power.

  1. Crystal structure and magnetic properties of NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl

    SciTech Connect (OSTI)

    Jin Tengteng; Liu Wei; Chen Shuang; Prots, Yurii; Schnelle, Walter; Zhao Jingtai; Kniep, Ruediger; Hoffmann, Stefan

    2012-08-15

    A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Single-crystal X-ray diffraction data show that the title compound crystallizes in the monoclinic system, space group P2{sub 1}/c (No. 14), with lattice parameters a=8.392(2) A, b=6.3960(10) A, c=16.670(2) A, {beta}=109.470(10) Degree-Sign , V=843.6(3) A{sup 3}, Z=4. The crystal structure is characterized by a complex chain of copper-centered polyhedra running along [0 1 0] which are connected by phosphate tetrahedra. The resulting three-dimensional polyhedra framework exhibits channels filled by additional copper and sodium atoms. Field and temperature dependent measurements of the specific heat and the magnetic susceptibility reveal low-dimensional magnetic behavior. The compound starts to decompose at 700 K under release of oxygen and evaporation of Cu{sup I}Cl as shown by simultaneous thermogravimetry and mass spectrometry. - Graphical abstract: The crystal structure of the new copper(II) phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], exhibits linear chains of copper tetrahedra which show low-dimensional magnetic behavior proven by specific heat and magnetic susceptibility measurements. Highlights: Black-Right-Pointing-Pointer A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Black-Right-Pointing-Pointer The crystal structure comprises chains of Cu{sub 4}O tetrahedra. Black-Right-Pointing-Pointer Low-dimensional behavior has been proven by magnetic and specific heat measurements. Black-Right-Pointing-Pointer On heating, Cu{sup I}Cl and oxygen are released shown by simultaneous thermogravimetry and mass spectrometry.

  2. Enclosed ground-flare incinerator

    DOE Patents [OSTI]

    Wiseman, Thomas R. (Calgary, CA)

    2000-01-01

    An improved ground flare is provided comprising a stack, two or more burner assemblies, and a servicing port so that some of the burner assemblies can be serviced while others remain in operation. The burner assemblies comprise a burner conduit and nozzles which are individually fitted to the stack's burner chamber and are each removably supported in the chamber. Each burner conduit is sealed to and sandwiched between a waste gas inlet port and a matching a closure port on the other side of the stack. The closure port can be opened for physically releasing the burner conduit and supplying sufficient axial movement room for extracting the conduit from the socket, thereby releasing the conduit for hand removal through a servicing port. Preferably, the lower end of the stack is formed of one or more axially displaced lower tubular shells which are concentrically spaced for forming annular inlets for admitting combustion air. An upper tubular exhaust stack, similarly formed, admits additional combustion air for increasing the efficiency of combustion, increasing the flow of exhausted for improved atmospheric dispersion and for cooling the upper stack.

  3. Fundamental limitation to the magnitude of piezoelectric response of (001)pc textured K0.5Na0.5NbO3 ceramic

    SciTech Connect (OSTI)

    Gupta, Shashaank; Belianinov, Alex; Okatan, Mahmut B; Jesse, Stephen; Kalinin, Sergei V; Priya, Shashaank

    2014-01-01

    (001)pc textured K0.5Na0.5NbO3 (KNN) ceramic was found to exhibit a 65% improvement in the longitudinal piezoelectric response as compared to its random counterpart. Piezoresponse force microscopy study revealed the existence of larger 180 and non-180 domains for textured ceramic as compared to that of the random ceramic. Improvement in piezoresponse by the development of (001)pc texture is discussed in terms of the crystallographic nature of KNN and domain morphology. A comparative analysis performed with a rhombohedral composition suggested that the improvement in longitudinal piezoresponse of polycrystalline ceramics by the development of (001)pc texture is limited by the crystal structure.

  4. {sup 25}Na and {sup 25}Mg fragmentation on {sup 12}C at 9.23 MeV per nucleon at TRIUMF

    SciTech Connect (OSTI)

    St-Onge, Patrick; Boisjoli, Mark; Fregeau, Marc-Olivier; Gauthier, Jerome; Wallace, Barton; Roy, Rene

    2012-10-20

    HERACLES is a multidetector that is used to study heavy-ion collisions, with ion beams with an energy range between 8 to 15 MeV per nucleon. It has 78 detectors axially distributed around the beam axis in 6 rings allowing detection of multiple charged fragments from nuclear reactions. HERACLES has 4 different types of detectors, BC408/BaF{sub 2} phoswich, Si/CsI(Tl) telescope, BC408/BC444 phoswich and CsI(Tl) detectors. The multidetector has been run with a radioactive {sup 25}Na beam and a stable {sup 25}Mg beam at 9.23 MeV per nucleon on a carbon target.

  5. Differential effects of five 'classical' scorpion {beta}-toxins on rNa{sub v}1.2a and DmNav1 provide clues on species-selectivity

    SciTech Connect (OSTI)

    Bosmans, Frank; Martin-Eauclaire, Marie-France; Tytgat, Jan . E-mail: Jan.Tytgat@pharm.kuleuven.be

    2007-01-01

    In general, scorpion {beta}-toxins have been well examined. However, few in-depth studies have been devoted to species selectivity and affinity comparisons on the different voltage-activated Na{sup +} channels since they have become available as cloned channels that can be studied in heterologous expression systems. As a result, their classification is largely historical and dates from early in vivo experiments on mice and cockroach and fly larvae. In this study, we aimed to provide an updated overview of selectivity and affinity of scorpion {beta}-toxins towards voltage-activated Na{sup +} channels of vertebrates or invertebrates. As pharmacological tools, we used the classic {beta}-toxins AaHIT, Css II, Css IV, Css VI and Ts VII and tested them on the neuronal vertebrate voltage-activated Na{sup +} channel, rNa{sub v}1.2a. For comparison, its invertebrate counterpart, DmNav1, was also tested. Both these channels were expressed in Xenopus laevis oocytes and the currents measured with the two-electrode voltage-clamp technique. We supplemented this data with several binding displacement studies on rat brain synaptosomes. The results lead us to propose a general classification and a novel nomenclature of scorpion {beta}-toxins based on pharmacological activity.

  6. MEASUREMENTS OF ABSOLUTE ABUNDANCES IN SOLAR FLARES

    SciTech Connect (OSTI)

    Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States)

    2014-05-01

    We present measurements of elemental abundances in solar flares with the EUV Variability Experiment (EVE) on the Solar Dynamics Observatory. EVE observes both high temperature Fe emission lines (Fe XV-Fe XXIV) and continuum emission from thermal bremsstrahlung that is proportional to the abundance of H. By comparing the relative intensities of line and continuum emission it is possible to determine the enrichment of the flare plasma relative to the composition of the photosphere. This is the first ionization potential or FIP bias (f). Since thermal bremsstrahlung at EUV wavelengths is relatively insensitive to the electron temperature, it is important to account for the distribution of electron temperatures in the emitting plasma. We accomplish this by using the observed spectra to infer the differential emission measure distribution and FIP bias simultaneously. In each of the 21 flares that we analyze we find that the observed composition is close to photospheric. The mean FIP bias in our sample is f = 1.17 0.22. This analysis suggests that the bulk of the plasma evaporated during a flare comes from deep in the chromosphere, below the region where elemental fractionation occurs.

  7. Compensation of flare-induced CD changes EUVL

    DOE Patents [OSTI]

    Bjorkholm, John E. (Pleasanton, CA); Stearns, Daniel G. (Los Altos, CA); Gullikson, Eric M. (Oakland, CA); Tichenor, Daniel A. (Castro Valley, CA); Hector, Scott D. (Oakland, CA)

    2004-11-09

    A method for compensating for flare-induced critical dimensions (CD) changes in photolithography. Changes in the flare level results in undesirable CD changes. The method when used in extreme ultraviolet (EUV) lithography essentially eliminates the unwanted CD changes. The method is based on the recognition that the intrinsic level of flare for an EUV camera (the flare level for an isolated sub-resolution opaque dot in a bright field mask) is essentially constant over the image field. The method involves calculating the flare and its variation over the area of a patterned mask that will be imaged and then using mask biasing to largely eliminate the CD variations that the flare and its variations would otherwise cause. This method would be difficult to apply to optical or DUV lithography since the intrinsic flare for those lithographies is not constant over the image field.

  8. Boron uptake in tumors, cerebrum and blood from (/sup 10/B)Na/sub 4/B/sub 24/H/sub 22/S/sub 2/

    DOE Patents [OSTI]

    Slatkin, D.N.; Micca, P.L.; Fairchild, R.G.

    1986-03-11

    A stable boronated (/sup 10/B-labeled) compound, sodium mercaptoundecahydrododecaborate is infused in the form of the disulfide dimer, (/sup 10/B)Na/sub 4/B/sub 24/H/sub 22/S/sub 2/, at a dose of about 200 ..mu..g /sup 10/B per gm body weight. The infusion is preformed into the blood or peritoneal cavity of the patient slowly over a period of many days, perhaps one week or more, at the rate of roughly 1 ..mu..g /sup 10/B per gm body weight per hour. Use of this particular boronated dimer in the manner or similarly to the manner so described permits radiotherapeutically effective amounts of boron to accumulate in tumors to be treated by boron neutron capture radiation therapy and also permits sufficient retention of boron in tumor after the cessation of the slow infusion, so as to allow the blood concentration of /sup 10/B to drop or to be reduced artificially to a radiotherapeutically effective level, less than one-half of the concentration of /sup 10/B in the tumor. 1 tab.

  9. Molecular dynamics simulations of the electrical double layer on smectite surfaces contacting concentrated mixed electrolyte (NaCl-CaCl?) solutions

    SciTech Connect (OSTI)

    Bourg, Ian C.; Sposito, Garrison

    2011-01-01

    We report new molecular dynamics results elucidating the structure of the electrical double layer (EDL) on smectite surfaces contacting mixed NaClCaCl2 electrolyte solutions in the range of concentrations relevant to pore waters in geologic repositories for CO2 or high-level radioactive waste (0.341.83 molc dm-3). Our results confirm the existence of three distinct ion adsorption planes (0-, ?-, and d-planes), often assumed in EDL models, but with two important qualifications: (1) the location of the ?- and d-planes are independent of ionic strength or ion type and (2) indifferent electrolyte ions can occupy all three planes. Charge inversion occurred in the diffuse ion swarm because of the affinity of the clay surface for CaCl+ ion pairs. Therefore, at concentrations {>=0.34 molc dm-3}, properties arising from long-range electrostatics at interfaces (electrophoresis, electro-osmosis, co-ion exclusion, colloidal aggregation) will not be correctly predicted by most EDL models. Co-ion exclusion, typically neglected by surface speciation models, balanced a large part of the clay mineral structural charge in the more concentrated solutions. Water molecules and ions diffused relatively rapidly even in the first statistical water monolayer, contradicting reports of rigid ice-like structures for water on clay mineral surfaces.

  10. High Schottky barrier at grain boundaries observed in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics

    SciTech Connect (OSTI)

    Somphan, Weeraya; Thongbai, Prasit; Yamwong, Teerapon; Maensiri, Santi

    2013-10-15

    Graphical abstract: - Highlights: NSCTO exhibits a high ?? of 7.08.4 10{sup 3} and low tan ? of 0.0300.041. NSCTO exhibits a high E{sub b} of ?2208 V cm{sup ?1} and large ? of 15.6. Giant ?? response is attributed to the electrically heterogeneous microstructure. High ?{sub b} values at grain boundaries are found to be 0.9250.964 eV. Formation of a potential barrier at grain boundaries is caused by Schottky effect. - Abstract: The dielectric properties and nonlinear currentvoltage characteristics of Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics prepared by a conventional solid state reaction method were investigated. Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics exhibited a high dielectric permittivity of 7.08.4 10{sup 3} and low loss tangent (tan ??0.0300.041). Non-Ohmic properties with a high breakdown voltage of ?2208 V cm{sup ?1} and large nonlinear coefficient of 15.6 were observed in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics. Using complex impedance analysis, Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics were shown to be electrically heterogeneous consisting of semiconducting grains and insulating grain boundaries. Giant dielectric properties were described based on the electrically heterogeneous microstructure. X-ray photoelectron spectroscopy analysis suggested that the semiconductive nature of grains may be related to the presence of Cu{sup +} and Ti{sup 3+}. The formation of an electrostatic potential barrier at the grain boundaries of Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics was suggested to be caused by the Schottky effect. Interestingly, high electrostatic potential barriers at grain boundaries in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics were calculated and found to be 0.9250.964 eV.

  11. NA SD 452.2

    National Nuclear Security Administration (NNSA)

    NNSA SD 452.2 Approved: 11-17-14 Nuclear Explosive Safety Evaluation Processes NATIONAL NUCLEAR SECURITY ADMINISTRATION Office of Safety and Health CONTROLLED DOCUMENT OFFICE OF PRIMARY INTEREST (OPI): AVAILABLE ONLINE AT: Office of Safety and Health http://nnsa.energy.gov printed copies are uncontrolled THIS PAGE INTENTIONALLY LEFT BLANK NNSA SD 452.2 i 11-17-14 Nuclear Explosive Safety Evaluation Processes 1. PURPOSE. This Supplemental Directive (SD) provides supplemental details to support

  12. The U.S./IAEA Workshop on Software Sustainability for Safeguards Instrumentation: Report to the NNSA DOE Office of International Nuclear Safeguards (NA-241)

    SciTech Connect (OSTI)

    Pepper, Susan E.; Pickett, Chris A.; Queirolo, Al; Bachner, Katherine M.; Worrall, Louise G.

    2015-04-07

    The U.S Department of Energy (DOE) National Nuclear Security Administration (NNSA) Next Generation Safeguards Initiative (NGSI) and the International Atomic Energy Agency (IAEA) convened a workshop on Software Sustainability for Safeguards Instrumentation in Vienna, Austria, May 6-8, 2014. Safeguards instrumentation software must be sustained in a changing environment to ensure existing instruments can continue to perform as designed, with improved security. The approaches to the development and maintenance of instrument software used in the past may not be the best model for the future and, therefore, the organizers’ goal was to investigate these past approaches and to determine an optimal path forward. The purpose of this report is to provide input for the DOE NNSA Office of International Nuclear Safeguards (NA-241) and other stakeholders that can be utilized when making decisions related to the development and maintenance of software used in the implementation of international nuclear safeguards. For example, this guidance can be used when determining whether to fund the development, upgrade, or replacement of a particular software product. The report identifies the challenges related to sustaining software, and makes recommendations for addressing these challenges, supported by summaries and detailed notes from the workshop discussions. In addition the authors provide a set of recommendations for institutionalizing software sustainability practices in the safeguards community. The term “software sustainability” was defined for this workshop as ensuring that safeguards instrument software and algorithm functionality can be maintained efficiently throughout the instrument lifecycle, without interruption and providing the ability to continue to improve that software as needs arise.

  13. Isothermal evaporation process simulation using the Pitzer model for the Quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Lingzong; Gruszkiewicz, Miroslaw S.; Deng, Tianlong; Guo, Yafei; Li, Dan

    2015-08-05

    In this study, the Pitzer thermodynamic model for solid-liquid equilibria in the quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K was constructed by selecting the proper parameters for the subsystems in the literature. The solubility data of the systems NaCl–SrCl2–H2O, KCl–SrCl2–H2O, LiCl–SrCl2–H2O, and NaCl–KCl–SrCl2–H2O were used to evaluate the model. Good agreement between the experimental and calculated solubilities shows that the model is reliable. The Pitzer model for the quinary system at 298.15 K was then used to calculate the component solubilities and conduct computer simulation of isothermal evaporation of the mother liquor for the oilfield brine from Nanyishan district in themore » Qaidam Basin. The evaporation-crystallization path and sequence of salt precipitation, change in concentration and precipitation of lithium, sodium, potassium, and strontium, and water activities during the evaporation process were demonstrated. The salts precipitated from the brine in the order : KCl, NaCl, SrCl2∙6H2O, SrCl2∙2H2O, and LiCl∙H2O. The entire evaporation process may be divided into six stages. In each stage the variation trends for the relationships between ion concentrations or water activities and the evaporation ratio are different. This result of the simulation of brines can be used as a theoretical reference for comprehensive exploitation and utilization of this type of brine resources.« less

  14. Investigation of the hydrothermal crystallisation of the perovskite solid solution NaCe{sub 1?x}La{sub x}Ti{sub 2}O{sub 6} and its defect chemistry

    SciTech Connect (OSTI)

    Harunsani, Mohammad H.; Woodward, David I.; Peel, Martin D.; Ashbrook, Sharon E.; Walton, Richard I.

    2013-11-15

    Perovskites of nominal composition NaCe{sub 1?x}La{sub x}Ti{sub 2}O{sub 6} (0?x?1) crystallise directly under hydrothermal conditions at 240 C. Raman spectroscopy shows distortion from the ideal cubic structure and Rietveld analysis of powder X-ray and neutron diffraction reveals that the materials represent a continuous series in rhombohedral space group R3-bar c. Ce L{sub III}-edge X-ray absorption near edge structure spectroscopy shows that while the majority of cerium is present as Ce{sup 3+} there is evidence for Ce{sup 4+}. The paramagnetic Ce{sup 3+} affects the chemical shift and line width of {sup 23}Na MAS NMR spectra, which also show with no evidence for A-site ordering. {sup 2}H MAS NMR of samples prepared in D{sub 2}O shows the inclusion of deuterium, which IR spectroscopy shows is most likely to be as D{sub 2}O. The deuterium content is highest for the cerium-rich materials, consistent with oxidation of some cerium to Ce{sup 4+} to provide charge balance of A-site water. - Graphical abstract: A multi-element A-site perovskite crystallises directly from aqueous, basic solutions at 240 C; while the paramagnetic effect of Ce{sup 3+} on the {sup 23}Na NMR shows a homogeneous solid-solution, the incorporation of A-site water is also found from {sup 2}H NMR and IR, with oxidation of some cerium to charge balance proved by XANES spectroscopy. Display Omitted - Highlights: Direct hydrothermal synthesis allows crystallisation of a perovskite solid-solution. XANES spectroscopy shows some oxidation of Ce{sup 3+} to Ce{sup 4+}. The paramagnetism of Ce{sup 3+} shifts and broadens the {sup 23}Na solid-state NMR. The perovskite materials incorporate water as an A-site defect.

  15. Effect of tungsten doping in bismuth-layered Na{sub 0.5}Bi{sub 2.5}Nb{sub 2}O{sub 9} high temperature piezoceramics

    SciTech Connect (OSTI)

    Zhou, Zhiyong Li, Yuchen; Hui, Shipeng; Dong, Xianlin

    2014-01-06

    The effects of W{sup 6+} doping for B site on the structural and electrical properties of Na{sub 0.5}Bi{sub 2.5}Nb{sub 2}O{sub 9}-based ceramics were studied. It shows a trend of preferable orientation growth along c-axis and the Curie point (T{sub c}) decreases slightly from 792 to 761?C with the increasing W{sup 6+} amount. The electrical resistivity of Na{sub 0.5}Bi{sub 2.5}Nb{sub 2}O{sub 9}-based ceramics increases as much as about two orders of magnitude and the piezoelectric constant d{sub 33} is significantly improved from 10.5 to 21.8 pC/N by W{sup 6+} modification. The composition of Na{sub 0.5}Bi{sub 2.5}Nb{sub 1.99}W{sub 0.01}O{sub 9} with a high T{sub c} (792?C), very good temperature stability up to ?0.96T{sub c}, a large d{sub 33} of 17.9 pC/N and sufficient high resistivity, is an excellent candidate for high temperature piezoelectric applications.

  16. Characterisation of Ba(OH){sub 2}Na{sub 2}SO{sub 4}blast furnace slag cement-like composites for the immobilisation of sulfate bearing nuclear wastes

    SciTech Connect (OSTI)

    Mobasher, Neda; Bernal, Susan A.; Hussain, Oday H.; Apperley, David C.; Kinoshita, Hajime; Provis, John L.

    2014-12-15

    Soluble sulfate ions in nuclear waste can have detrimental effects on cementitious wasteforms and disposal facilities based on Portland cement. As an alternative, Ba(OH){sub 2}Na{sub 2}SO{sub 4}blast furnace slag composites are studied for immobilisation of sulfate-bearing nuclear wastes. Calcium aluminosilicate hydrate (CASH) with some barium substitution is the main binder phase, with barium also present in the low solubility salts BaSO{sub 4} and BaCO{sub 3}, along with Ba-substituted calcium sulfoaluminate hydrates, and a hydrotalcite-type layered double hydroxide. This reaction product assemblage indicates that Ba(OH){sub 2} and Na{sub 2}SO{sub 4} act as alkaline activators and control the reaction of the slag in addition to forming insoluble BaSO{sub 4}, and this restricts sulfate availability for further reaction as long as sufficient Ba(OH){sub 2} is added. An increased content of Ba(OH){sub 2} promotes a higher degree of reaction, and the formation of a highly cross-linked CASH gel. These Ba(OH){sub 2}Na{sub 2}SO{sub 4}blast furnace slag composite binders could be effective in the immobilisation of sulfate-bearing nuclear wastes.

  17. A proposal for positive cooperativity in anion-cation binding in yttrium and lutetium complexes based on o-amino-substituted phenolate ligands. On the way to coordination polymers by self-assembly. Molecular structures of [ClLu(OAr){sub 3}Na] (X-ray) and [ClY(OAr{prime}){sub 3}Y(OAr{prime}){sub 3}Na] (X-ray and {sup 89}Y-NMR)

    SciTech Connect (OSTI)

    Hogerheide, M.P.; Ringelberg, S.N.; Grove, D.M.

    1996-02-28

    The authors prepared the hetero(poly)metallic complexes [ClM(OAr){sub 3}Na] (M = Lu (3a), Y (3b)) and [ClY(OAr`){sub 3}Y(OAR`){sub 3}Na] (4) (OAr = OC{sub 6}H{sub 2}(CH{sub 2}NMe{sub 2}){sub 2}-2,6,Me-4; OAr` = OC{sub 6}H{sub 4}(CH{sub 2}NMe{sub 2})-2). Structural analysis was afforded by NMR spectroscopy and X-ray diffraction. The structures show evidence for anion-cation cooperativity in bonding and are discussed in detail for the compounds in both the solid state and in solution.

  18. Spin orientations of the spin-half Ir4+ ions in Sr3NiIrO6, Sr2IrO4 and Na2IrO3: Density functional, perturbation theory and Madelung potential analyses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gordon, Elijah E.; Xiang, Hongjun; Koehler, Jurgen; Whangbo, Myung -Hwan

    2016-03-01

    The spins of the low-spin Ir4+ (S = 1/2, d5) ions at the octahedral sites of the oxides Sr3NiIrO6, Sr2IrO4 and Na2IrO3 exhibit preferred orientations with respect to their IrO6 octahedra. We evaluated the magnetic anisotropies of these S = 1/2 ions on the basis of DFT calculations including spin-orbit coupling (SOC), and probed their origin by performing perturbation theory analyses with SOC as perturbation within the LS coupling scheme. The observed spin orientations of Sr3NiIrO6 and Sr2IrO4 are correctly predicted by DFT calculations, and are accounted for by the perturbation theory analysis. As for the spin orientation of Na2IrO3,more » both experimental studies and DFT calculations have not been unequivocal. Our analysis reveals that the Ir4+ spin orientation of Na2IrO3 should have nonzero components along the c- and a-axes directions. The spin orientations determined by DFT calculations are sensitive to the accuracy of the crystal structures employed, which is explained by perturbation theory analyses when interactions between adjacent Ir4+ ions are taken into consideration. There are indications implying that the 5d electrons of Na2IrO3 are less strongly localized compared with those of Sr3NiIrO6 and Sr2IrO4. This implication was confirmed by showing that the Madelung potentials of the Ir4+ ions are less negative in Na2IrO3 than in Sr3NiIrO6, Sr2IrO4. Most transition-metal S = 1/2 ions do have magnetic anisotropies because the SOC induces interactions among their crystal-field split d-states, and the associated mixing of the states modifies only the orbital parts of the states. This finding cannot be mimicked by a spin Hamiltonian because this model Hamiltonian lacks the orbital degree of freedom, thereby leading to the spin-half syndrome. As a result, the spin-orbital entanglement for the 5d spin-half ions Ir4+ is not as strong as has been assumed lately.« less

  19. U.S. Sales for Resale, Total Refiner Motor Gasoline Sales Volumes

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    NA NA NA NA NA NA 1983-2014 by Grade Regular NA NA NA NA NA NA 1983-2014 Midgrade NA NA NA NA NA NA 1989-2014 Premium NA NA NA NA NA NA 1983-2014 by Formulation Conventional NA NA NA NA NA NA 1994-2014 Oxygenated - - - - - - 1994-2014 Reformulated NA NA NA NA NA NA

  20. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

    SciTech Connect (OSTI)

    Li, Hui; Yu, Xiqian; Bai, Ying; Wu, Feng; Wu, Chuan; Liu, Liang-Yu; Yang, Xiao-Qing

    2015-01-01

    Na3V2-xMgx(PO4)3/C composites with different Mg2+ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg2+ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na3V2-xMgx(PO4)3/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na3V1.95Mg0.05(PO4)3/C. For example, when the current density increased from 1 C to 30 C, the specific capacity only decreased from 112.5 mAh g-1 to 94.2 mAh g-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh g-1 to 86.2 mAh g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.

  1. A sodium gadolinium phosphate with two different types of tunnel structure: Synthesis, crystal structure, and optical properties of Na{sub 3}GdP{sub 2}O{sub 8}

    SciTech Connect (OSTI)

    Fang, M.; Cheng, W.-D. Zhang, H.; Zhao, D.; Zhang, W.-L.; Yang, S.-L.

    2008-09-15

    A sodium gadolinium phosphate crystal, Na{sub 3}GdP{sub 2}O{sub 8}, has been synthesized by a high-temperature solution reaction, and it exhibits a new structural family of the alkali-metal-rare-earth phosphate system. Although many compounds with formula M{sub 3}LnP{sub 2}O{sub 8} have been reported, but they were shown to be orthorhombic [R. Salmon, C. Parent, M. Vlasse, G. LeFlem, Mater. Res. Bull. 13 (1978) 439] rather than monoclinic as shown in this paper. Single-crystal X-ray diffraction analysis shows the structure to be monoclinic with space group C2/c and the cell parameters: a=27.55 (25), b=5.312 (4), c=13.935(11) A, {beta}=91.30(1){sup o}, and V=2038.80 A{sup 3}, Z=4. Its structure features a three-dimensional GdP{sub 2}O{sub 8}{sup 3-} anionic framework with two different types of interesting tunnels at where Na atoms are located by different manners. The framework is constructed by Gd polyhedra and isolated PO{sub 4} tetrahedra. It is different from the structure of K{sub 3}NdP{sub 2}O{sub 8} [R. Salmon, C. Parent, M. Vlasse, G. LeFlem, Mater. Res. Bull. 13 (1978) 439] with space group P2{sub 1}/m that shows only one type of tunnel. The emission spectrum and the absorption spectrum of the compound have been investigated. Additionally, the calculations of band structure, density of states, dielectric constants, and refractive indexes have been also performed with the density functional theory method. The obtained results tend to support the experimental data. - Graphical abstract: Projection of the structure of Na{sub 3}GdP{sub 2}O{sub 8} with a unit cell edge along the b-axis. The Na-O bonds are omitted for clarity.

  2. In-beam Mssbauer spectroscopy of {sup 57}Fe/{sup 57}Mn in MgO and NaF at Heavy-Ion Medical Accelerator in Chiba

    SciTech Connect (OSTI)

    Kubo, M. K.; Kobayashi, Y.; Yamada, Y.; Mihara, M.; Nagatomo, T.; Sato, W.; Miyazaki, J.; Sato, S.; Kitagawa, A.

    2014-02-15

    Development of efficient ion supply of {sup 58}Fe from {sup 58}Fe(C{sub 5}H{sub 5}){sub 2}, and quick switching between therapy and material science at the Heavy-Ion Medical Accelerator in Chiba realized a new {sup 57}Mn in-beam emission Mssbauer spectroscopy measurement system. Application to simple binary chemical compounds, MgO and NaF, proved the usefulness of the system to probe chemical and physical behaviors of trace impurities in solids. Annealing of lattice defects produced by the implantation and ?-decay of {sup 57}Mn and/or ?-ray emission recoil was observed by a local probe.

  3. OBSERVATIONS OF THERMAL FLARE PLASMA WITH THE EUV VARIABILITY EXPERIMENT

    SciTech Connect (OSTI)

    Warren, Harry P.; Doschek, George A. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States); Mariska, John T. [School of Physics, Astronomy, and Computational Sciences, George Mason University, 4400 University Drive, Fairfax, VA 22030 (United States)

    2013-06-20

    One of the defining characteristics of a solar flare is the impulsive formation of very high temperature plasma. The properties of the thermal emission are not well understood, however, and the analysis of solar flare observations is often predicated on the assumption that the flare plasma is isothermal. The EUV Variability Experiment (EVE) on the Solar Dynamics Observatory provides spectrally resolved observations of emission lines that span a wide range of temperatures (e.g., Fe XV-Fe XXIV) and allow for thermal flare plasma to be studied in detail. In this paper we describe a method for computing the differential emission measure distribution in a flare using EVE observations and apply it to several representative events. We find that in all phases of the flare the differential emission measure distribution is broad. Comparisons of EVE spectra with calculations based on parameters derived from the Geostationary Operational Environmental Satellites soft X-ray fluxes indicate that the isothermal approximation is generally a poor representation of the thermal structure of a flare.

  4. An X-ray flare from 47 Cas

    SciTech Connect (OSTI)

    Pandey, Jeewan C.; Karmakar, Subhajeet

    2015-02-01

    Using XMM-Newton observations, we investigate properties of a flare from the very active but poorly known stellar system 47 Cas. The luminosity at the peak of the flare is found to be 3.54 10{sup 30} erg s{sup ?1}, which is ?2 times higher than that at a quiescent state. The quiescent state corona of 47 Cas can be represented by two temperature plasma: 3.7 and 11.0 MK. The time-resolved X-ray spectroscopy of the flare show the variable nature of the temperature, the emission measure, and the abundance. The maximum temperature during the flare is derived as 72.8 MK. We infer the length of a flaring loop to be 3.3 10{sup 10} cm using a hydrodynamic loop model. Using the RGS spectra, the density during the flare is estimated as 4.0 10{sup 10} cm{sup ?3}. The loop scaling laws are also applied when deriving physical parameters of the flaring plasma.

  5. CONSTRAINING SOLAR FLARE DIFFERENTIAL EMISSION MEASURES WITH EVE AND RHESSI

    SciTech Connect (OSTI)

    Caspi, Amir [Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO 80303 (United States); McTiernan, James M. [Space Sciences Laboratory University of California, Berkeley, CA 94720 (United States); Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States)

    2014-06-20

    Deriving a well-constrained differential emission measure (DEM) distribution for solar flares has historically been difficult, primarily because no single instrument is sensitive to the full range of coronal temperatures observed in flares, from ?2 to ?50MK. We present a new technique, combining extreme ultraviolet (EUV) spectra from the EUV Variability Experiment (EVE) onboard the Solar Dynamics Observatory with X-ray spectra from the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI), to derive, for the first time, a self-consistent, well-constrained DEM for jointly observed solar flares. EVE is sensitive to ?2-25MK thermal plasma emission, and RHESSI to ?10MK; together, the two instruments cover the full range of flare coronal plasma temperatures. We have validated the new technique on artificial test data, and apply it to two X-class flares from solar cycle 24 to determine the flare DEM and its temporal evolution; the constraints on the thermal emission derived from the EVE data also constrain the low energy cutoff of the non-thermal electrons, a crucial parameter for flare energetics. The DEM analysis can also be used to predict the soft X-ray flux in the poorly observed ?0.4-5nm range, with important applications for geospace science.

  6. Enhanced tolerance to NaCl and LiCl stresses by over-expressing Caragana korshinskii sodium/proton exchanger 1 (CkNHX1) and the hydrophilic C terminus is required for the activity of CkNHX1 in Atsos3-1 mutant and yeast

    SciTech Connect (OSTI)

    Yang, Da-Hai; Department of Plant Physiology, Institute of General Botany and Plant Physiology, Friedrich-Schiller-University, Dornburger Strasse 159, 07743 Jena ; Song, Li-Ying; Hu, Jun; Yin, Wei-Bo; Li, Zhi-Guo; Chen, Yu-Hong; Su, Xiao-Hua; Wang, Richard R.-C.; Hu, Zan-Min

    2012-01-13

    Highlights: Black-Right-Pointing-Pointer CkNHX1 was isolated from Caragana korshinskii. Black-Right-Pointing-Pointer CkNHX1 was expressed mainly in roots, and significantly induced by NaCl in stems. Black-Right-Pointing-Pointer Expression of CkNHX1 enhanced the resistance to NaCl and LiCl in yeast and Atsos3-1. Black-Right-Pointing-Pointer Expression of CkNHX1-{Delta}C had little effect on NaCl/LiCl tolerance in Atsos3-1. Black-Right-Pointing-Pointer C-terminal region of CkNHX1 is required for its Na{sup +} and Li{sup +} transporting activity. -- Abstract: Sodium/proton exchangers (NHX antiporters) play important roles in plant responses to salt stress. Previous research showed that hydrophilic C-terminal region of Arabidopsis AtNHX1 negatively regulates the Na{sup +}/H{sup +} transporting activity. In this study, CkNHX1 were isolated from Caragana korshinskii, a pea shrub with high tolerance to salt, drought, and cold stresses. Transcripts of CkNHX1 were detected predominantly in roots, and were significantly induced by NaCl stress in stems. Transgenic yeast and Arabidopsisthalianasos3-1 (Atsos3-1) mutant over-expressing CkNHX1 and its hydrophilic C terminus-truncated derivative, CkNHX1-{Delta}C, were generated and subjected to NaCl and LiCl stresses. Expression of CkNHX1 significantly enhanced the resistance to NaCl and LiCl stresses in yeast and Atsos3-1 mutant. Whereas, compared with expression of CkNHX1, the expression of CkNHX1-{Delta}C had much less effect on NaCl tolerance in Atsos3-1 and LiCl tolerance in yeast and Atsos3-1. All together, these results suggest that the predominant expression of CkNHX1 in roots might contribute to keep C. korshinskii adapting to the high salt condition in this plant's living environment; CkNHX1 could recover the phenotype of Atsos3-1 mutant; and the hydrophilic C-terminal region of CkNHX1 should be required for Na{sup +}/H{sup +} and Li{sup +}/H{sup +} exchanging activity of CkNHX1.

  7. O3-type layered transition metal oxide Na(NiCoFeTi)1/4O2 as a high rate and long cycle life cathode material for sodium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji -Li; Yang, Xiao -Qing; Zhou, Yong -Ning; Yu, Xiqian; Bak, Seong -Min; Fu, Zheng -Wen

    2015-10-09

    High rate capability and long cycle life are challenging goals for the development of room temperature sodium-ion batteries. Here we report a new single phase quaternary O3-type layer-structured transition metal oxide Na(NiCoFeTi)1/4O2 synthesized by a simple solid-state reaction as a new cathode material for sodium-ion batteries. It can deliver a reversible capacity of 90.6 mA h g–1 at a rate as high as 20C. At 5C, 75.0% of the initial specific capacity can be retained after 400 cycles with a capacity-decay rate of 0.07% per cycle, demonstrating a superior long-term cyclability at high current density. X-ray diffraction and absorption characterizationmore » revealed reversible phase transformations and electronic structural changes during the Na+ deintercalation/intercalation process. Ni, Co and Fe ions contribute to charge compensation during charge and discharge. Although Ti ions do not contribute to the charge transfer, they play a very important role in stabilizing the structure during charge and discharge by suppressing the Fe migration. Additionally, Ti substitution can also smooth the charge–discharge plateaus effectively, which provides a potential advantage for the commercialization of this material for room temperature sodium-ion batteries.« less

  8. O3-type layered transition metal oxide Na(NiCoFeTi)1/4O2 as a high rate and long cycle life cathode material for sodium ion batteries

    SciTech Connect (OSTI)

    Yue, Ji -Li; Yang, Xiao -Qing; Zhou, Yong -Ning; Yu, Xiqian; Bak, Seong -Min; Fu, Zheng -Wen

    2015-10-09

    High rate capability and long cycle life are challenging goals for the development of room temperature sodium-ion batteries. Here we report a new single phase quaternary O3-type layer-structured transition metal oxide Na(NiCoFeTi)1/4O2 synthesized by a simple solid-state reaction as a new cathode material for sodium-ion batteries. It can deliver a reversible capacity of 90.6 mA h g1 at a rate as high as 20C. At 5C, 75.0% of the initial specific capacity can be retained after 400 cycles with a capacity-decay rate of 0.07% per cycle, demonstrating a superior long-term cyclability at high current density. X-ray diffraction and absorption characterization revealed reversible phase transformations and electronic structural changes during the Na+ deintercalation/intercalation process. Ni, Co and Fe ions contribute to charge compensation during charge and discharge. Although Ti ions do not contribute to the charge transfer, they play a very important role in stabilizing the structure during charge and discharge by suppressing the Fe migration. Additionally, Ti substitution can also smooth the chargedischarge plateaus effectively, which provides a potential advantage for the commercialization of this material for room temperature sodium-ion batteries.

  9. Dual-enhancement of ferro-/piezoelectric and photoluminescent performance in Pr{sup 3+} doped (K{sub 0.5}Na{sub 0.5})NbO{sub 3} lead-free ceramics

    SciTech Connect (OSTI)

    Wei, Yongbin; Jia, Yanmin E-mail: ymjia@zjnu.edu.cn; Wu, Jiang; Shen, Yichao; Wu, Zheng E-mail: ymjia@zjnu.edu.cn; Luo, Haosu

    2014-07-28

    A mutual enhancement action between the ferro-/piezoelectric polarization and the photoluminescent performance of rare earth Pr{sup 3+} doped (K{sub 0.5}Na{sub 0.5})NbO{sub 3} (KNN) lead-free ceramics is reported. After Pr{sup 3+} doping, the KNN ceramics exhibit the maximum enhancement of ?1.2 times in the ferroelectric remanent polarization strength and ?1.25 times in the piezoelectric coefficient d{sub 33}, respectively. Furthermore, after undergoing a ferro-/piezoelectric polarization treatment, the maximum enhancement of ?1.3 times in photoluminescence (PL) was observed in the poled 0.3% Pr{sup 3+} doped sample. After the trivalent Pr{sup 3+} unequivalently substituting the univalent (K{sub 0.5}Na{sub 0.5}){sup +}, A-sites ionic vacancies will occur to maintain charge neutrality, which may reduce the inner stress and ease the domain wall motions, yielding to the enhancement in ferro-/piezoelectric performance. The polarization-induced enhancement in PL is attributed to the decrease of crystal symmetry abound the Pr{sup 3+} ions after polarization. The dual-enhancement of the ferro-/piezoelectric and photoluminescent performance makes the Pr{sup 3+} doped KNN ceramic hopeful for piezoelectric/luminescent multifunctional devices.

  10. Interferometric at-wavelength flare characterization of EUV optical systems

    DOE Patents [OSTI]

    Naulleau, Patrick P. (Oakland, CA); Goldberg, Kenneth Alan (Berkeley, CA)

    2001-01-01

    The extreme ultraviolet (EUV) phase-shifting point diffraction interferometer (PS/PDI) provides the high-accuracy wavefront characterization critical to the development of EUV lithography systems. Enhancing the implementation of the PS/PDI can significantly extend its spatial-frequency measurement bandwidth. The enhanced PS/PDI is capable of simultaneously characterizing both wavefront and flare. The enhanced technique employs a hybrid spatial/temporal-domain point diffraction interferometer (referred to as the dual-domain PS/PDI) that is capable of suppressing the scattered-reference-light noise that hinders the conventional PS/PDI. Using the dual-domain technique in combination with a flare-measurement-optimized mask and an iterative calculation process for removing flare contribution caused by higher order grating diffraction terms, the enhanced PS/PDI can be used to simultaneously measure both figure and flare in optical systems.

  11. Missouri Dry Natural Gas Production (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 NA NA NA NA NA NA NA NA NA NA NA NA 2009 NA NA NA NA NA NA NA NA NA NA NA NA 2010 NA NA NA NA NA NA NA NA NA NA NA NA 2011 NA NA NA NA NA NA NA NA NA NA NA NA 2012 NA NA NA NA NA NA NA NA NA NA NA NA 2013 1 1 1 1 1 1 1 1 0 1 0 0

  12. Missouri Dry Natural Gas Production (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 NA NA NA NA NA NA NA NA NA NA NA NA 2009 NA NA NA NA NA NA NA NA NA NA NA NA 2010 NA NA NA NA NA NA NA NA NA NA NA NA 2011 NA NA NA NA NA NA NA NA NA NA NA NA 2012 NA NA NA NA NA NA NA NA NA NA NA NA 2013 1 1 1 1 1 1 1 1 0 1 0 0

  13. Solar Flare Activity Closely Monitored | Department of Energy

    Energy Savers [EERE]

    Solar Flare Activity Closely Monitored Solar Flare Activity Closely Monitored September 11, 2014 - 5:30pm Addthis Dr. Ken Friedman Senior Policy Advisor in the Office of Electricity Delivery and Energy Reliability The National Oceanic and Atmospheric Administration's (NOAA) Space Weather Prediction Center, which provides important resources to describe the space environment, including geomagnetic storms, solar radiation storms and radio blackouts, is forecasting the possibility of

  14. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the strength of natural gas. The cost of producing oil is to a large extent the cost of electric power used to extract and deliver the oil. Researchers have identified stranded and flared gas in California that could generate 400 megawatts of power, and believe that there is at least an additional 2,000 megawatts that have not been identified. Since California accounts for about 14.5% of the total domestic oil production, it is reasonable to assume that about 16,500 megawatts could be generated throughout the United States. This power could restore the cost-effectiveness of thousands of oil wells, increasing oil production by millions of barrels a year, while reducing emissions and greenhouse gas emissions by burning the gas in clean distributed generators rather than flaring or venting the stranded gases. Most turbines and engines are designed for standardized, high-quality gas. However, emerging technologies such as microturbines have increased the options for a broader range of fuels. By demonstrating practical means to consume the four gas streams, the project showed that any gases whose properties are between the extreme conditions also could be utilized. The economics of doing so depends on factors such as the value of additional oil recovered, the price of electricity produced, and the alternate costs to dispose of stranded gas.

  15. U.S. Natural Gas Repressuring (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 110,000 105,000 114,000 110,000 118,000 114,000 114,000 114,000 115,000 118,000 112,000 122,000 1981 108,000 101,000 109,000 108,000 115,000 109,000

  16. Missouri Natural Gas Gross Withdrawals from Coalbed Wells (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 NA NA NA NA NA NA NA NA NA NA NA NA 2009 NA NA NA NA NA NA NA NA NA NA NA NA 2010 NA NA NA NA NA NA NA NA NA NA NA NA 2011 NA NA NA NA NA NA NA NA NA NA NA NA 2012 NA NA NA NA NA NA NA NA NA NA NA NA 2013 0 0 0 0 0 0 0 0 0 0 0 0 2014 NA NA NA NA NA NA NA NA NA NA NA NA 2015 NA NA NA NA NA NA NA NA NA NA NA NA

  17. Missouri Natural Gas Gross Withdrawals from Shale Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 NA NA NA NA NA NA NA NA NA NA NA NA 2009 NA NA NA NA NA NA NA NA NA NA NA NA 2010 NA NA NA NA NA NA NA NA NA NA NA NA 2011 NA NA NA NA NA NA NA NA NA NA NA NA 2012 NA NA NA NA NA NA NA NA NA NA NA NA 2013 0 0 0 0 0 0 0 0 0 0 0 0 2014 NA NA NA NA NA NA NA NA NA NA NA NA 2015 NA NA NA NA NA NA NA NA NA NA NA NA

  18. U.S. Supplemental Gaseous Fuels (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 17 16 16 12 11 10 10 10 10 12 14 16 1981 20 17 17 14 13 12 12 12 12 14 15 19 1982 19 16 15 12 9 9 9 9 9 11 13 14 1983 16 12 12 10 8 8 8 10 10 10 13 16 1984

  19. On the crystal energy and structure of A{sub 2}Ti{sub n}O{sub 2n+1} (A=Li, Na, K) titanates by DFT calculations and neutron diffraction

    SciTech Connect (OSTI)

    Catti, Michele; Pinus, Ilya; Scherillo, Antonella

    2013-09-15

    First-principles quantum-mechanical calculations (CRYSTAL09 code, B3LYP functional) were performed on alkali titanates A{sub 2}Ti{sub n}O{sub 2n+1} with layered structure (n=3,4,6). Monoclinic structural types with unshifted (P2{sub 1}/m) and with shifted (C2/m) layers were considered. Crystal energies and full structural details were obtained for all Li, Na, and K phases. Neutron diffraction data were collected on powder samples of P2{sub 1}/m-Li{sub 2}Ti{sub 3}O{sub 7} (a=9.3146(3), b=3.7522(1), c=7.5447(3) Å, β=97.611(4)°) and C2/m-K{sub 2}Ti{sub 4}O{sub 9} (a=18.2578(8), b=3.79160(9), c=12.0242(4) Å, β=106.459(4)°) and their structures were Rietveld-refined. Computed energies show the P2{sub 1}/m arrangement as favoured over the C2/m one for n=3, and the opposite holds for n=6. In the n=4 case the P2{sub 1}/m configuration is predicted to be more stable for Li and Na, and the C2/m one for K titanates. Analysis of Li–O and K–O crystal-chemical environments from experiment and theory shows that the alkali atom bonding is stabilized/destabilized in the different phases consistently with the energy trend. - Graphical abstract: Display Omitted - Highlights: • The P2{sub 1}/m structure-type is found to be more stable for A{sub 2}Ti{sub 3}O{sub 7} layer titanates. • The C2/m structure-type is found to be more stable for A{sub 2}Ti{sub 6}O{sub 13} layer titanates. • Tetratitanates are predicted to prefer the P2{sub 1}/m (Li and Na) or C2/m (K) structure. • Li–O and K–O bond distances follow a trend consistent with computed phase energies.

  20. Product transfer service chosen over LPG flaring

    SciTech Connect (OSTI)

    Horn, J.; Powers, M.

    1994-07-01

    Seadrift Pipeline Corp. recently decommissioned its Ella Pipeline, an 108-mile, 8-in. line between the King Ranch and a Union Carbide plant at Seadrift, Texas. The pipeline company opted for the product transfer services of pipeline Dehydrators Inc. to evacuate the ethane-rich LPG mixture from the pipeline instead of flaring the LPG or displacing it with nitrogen at operating pressures into another pipeline. The product transfer system of Pipeline Dehydrators incorporates the use of highly specialized portable compressors, heat exchangers and interconnected piping. The product transfer process of evacuating a pipeline is an economically viable method that safely recovers a very high percentage of the product while maintaining product purity. Using positive-displacement compressors, PLD transferred the LPG from the idled 8-in. Ella line into an adjacent 12-in. ethane pipeline that remained in service at approximately 800 psig. Approximately 4.3 million lb of LPG (97% ethane, 2.7% methane and 0.3% propane) were transferred into the ethane pipeline, lowering the pressure on the Ella Pipeline from 800 psig to 65 psig.

  1. An unorthodox X-Class Long-Duration Confined Flare

    SciTech Connect (OSTI)

    Liu, Rui; Gou, Tingyu; Wang, Yuming; Liu, Kai; Titov, Viacheslav S.; Wang, Haimin

    2014-07-20

    We report the observation of an X-class long-duration flare which is clearly confined. It appears as a compact-loop flare in the traditional EUV passbands (171 and 195 ), but in the passbands sensitive to flare plasmas (94 and 131 ), it exhibits a cusp-shaped structure above an arcade of loops like other long-duration events. Inspecting images in a running difference approach, we find that the seemingly diffuse, quasi-static cusp-shaped structure consists of multiple nested loops that repeatedly rise upward and disappear approaching the cusp edge. Over the gradual phase, we detect numerous episodes of loop rising, each lasting minutes. A differential emission measure analysis reveals that the temperature is highest at the top of the arcade and becomes cooler at higher altitudes within the cusp-shaped structure, contrary to typical long-duration flares. With a nonlinear force-free model, our analysis shows that the event mainly involves two adjacent sheared arcades separated by a T-type hyperbolic flux tube (HFT). One of the arcades harbors a magnetic flux rope, which is identified with a filament that survives the flare owing to the strong confining field. We conclude that a new emergence of magnetic flux in the other arcade triggers the flare, while the preexisting HFT and flux rope dictate the structure and dynamics of the flare loops and ribbons during the long-lasting decay phase, and that a quasi-separatrix layer high above the HFT could account for the cusp-shaped structure.

  2. First principles DFT study of ferromagnetism in SnO{sub 2} induced by doped group 1A and 2A non-magnetic elements X (X=Li, Na, K, Be, Mg, Ca)

    SciTech Connect (OSTI)

    Chakraborty, Brahmananda Ramaniah, Lavanya M.

    2014-04-24

    Transition metal - free - ferromagnetism in diluted magnetic semiconductors (DMS) is of much current interest in the search for more efficient DMS materials for spintronic applications. Here, we report the results of our first principles density functional theory (DFT) study on impurity - induced ferromagnetism in non-magnetic SnO{sub 2} by a non-magnetic impurity. The impurities considered are sp-type of group 1A and 2A elements X (X = Li, Na, K, Be, Mg, Ca). Even a single atom of the group 1A elements makes the system magnetic, whereas for the group 2A elements Ca and Mg, a higher doping is required to induce ferromagnetism. For all the elements studied, the magnetic moment appears to increase with the doping concentration, at least at certain impurity separations, which is a positive indicator for practical applications.

  3. Fine tunable red-green upconversion luminescence from glass ceramic containing 5%Er{sup 3+}:NaYF{sub 4} nanocrystals under excitation of two near infrared femtosecond lasers

    SciTech Connect (OSTI)

    Shang, Xiaoying; Cheng, Wenjing; Zhou, Kan; Ma, Jing; Feng, Donghai; Zhang, Shian; Sun, Zhenrong; Jia, Tianqing; Chen, Ping; Qiu, Jianrong

    2014-08-14

    In this paper, we report fine tunable red-green upconversion luminescence of glass ceramic containing 5%Er{sup 3+}: NaYF{sub 4} nanocrystals excited simultaneously by two near infrared femtosecond lasers. When the glass ceramic was irradiated by 800?nm femtosecond laser, weak red emission centered at 670?nm was detected. Bright red light was observed when the fs laser wavelength was tuned to 1490?nm. However, when excited by the two fs lasers simultaneously, the sample emitted bright green light centered at 550?nm, while the red light kept the same intensity. The dependences of the red and the green light intensities on the two pump lasers are much different, which enables us to manipulate the color emission by adjusting the two pump laser intensities, respectively. We present a theoretical model of Er{sup 3+} ions interacting with two fs laser fields, and explain well the experimental results.

  4. Alternating and direct current field effects on the structure-property relationships in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-x%BaTiO{sub 3} textured ceramics

    SciTech Connect (OSTI)

    Ge, Wenwei; Li, Jiefang; Viehland, D.; Maurya, Deepam; Priya, Shashank

    2013-06-03

    The influence of alternating (ac) and direct current (dc) fields on the structural and dielectric properties of [001]{sub PC} textured Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) ceramics has been investigated. X-ray diffraction measurements revealed that the depolarization at temperature T{sub d} in poled samples resulted from a tetragonal {yields} pseudo-cubic transition on heating. Moderate ac drive and dc bias had opposite influences on T{sub d}: ac drive decreased the T{sub d}, whereas dc bias increased it. These investigations suggested an effective method to expand the working temperature range of NBT-x%BT textured ceramics to a high temperature.

  5. Aging in the relaxor and ferroelectric state of Fe-doped (1-x)(Bi{sub 1/2}Na{sub 1/2})TiO?-xBaTiO? piezoelectric ceramics

    SciTech Connect (OSTI)

    Sapper, Eva; Dittmer, Robert; Rdel, Jrgen; Damjanovic, Dragan; Erdem, Emre; Keeble, David J.; Jo, Wook; Granzow, Torsten

    2014-09-14

    Aging of piezoelectric properties was investigated in lead-free (1x)(Bi{sub 1/2}Na{sub 1/2})TiO?-xBaTiO? doped with 1at.% Fe. The relaxor character of the un-poled material prevents macroscopic aging effects, while in the field-induced ferroelectric phase aging phenomena are similar to those found in lead zirconate titanate or barium titanate. Most prominent aging effects are the development of an internal bias field and the decrease of switchable polarization. These effects are temperature activated, and can be explained in the framework of defect complex reorientation. This picture is further supported by electron paramagnetic resonance spectra indicating the existence of (Fe{sub Ti}-V{sub O}{sup }){sup } defect complexes in the Fe-doped material.

  6. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K???Bi???TiO?-BaTiO?-Na???Bi???TiO? piezoelectric materials

    SciTech Connect (OSTI)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K???Bi???TiO?-BaTiO?-xNa???Bi???TiO? (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d?? ~ 190pC/N) and high temperature stability (~160C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180 domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectric materials.

  7. Study of electrical conduction behavior of the system La[sub 1[minus]x]Na[sub x]Co[sub 1[minus]x]Nb[sub x]O[sub 3] (x [gt] 0. 05)

    SciTech Connect (OSTI)

    Parkash, O. . School of Materials Science and Technology); Tewari, H.S.; Tare, V.B. . Dept. of Metallurgical Engineering); Kumar, D. ); Pandey, L. )

    1992-11-01

    This paper reports on electrical behavior of a few compositions with x [ge] 0.50 in the system La[sub 1 [minus] x]Na[sub x]Co[sub 1 [minus] x]Nb[sub x]O[sub 3] that has been studied by complex-plane-impedance analysis in the temperature range 300-525 K. Three depressed semicircular arcs have been observed in the complex impedance plot of the composition with x = 0.50. These arcs represent the contributions of bulk, grain boundaries, and electrode polarization to the total observed resistance. Two semicircular arcs have been observed in the complex-impedance plot of the compositions with x = 0.70 and 0.80. They represent the bulk and the grain boundaries contribution to the total observed resistance. The values of the resistance for the bulk and grain boundaries in each sample indicate the formation of barrier layers in these mathese materials.

  8. OPTICAL DISCOVERY OF PROBABLE STELLAR TIDAL DISRUPTION FLARES

    SciTech Connect (OSTI)

    Van Velzen, Sjoert; Farrar, Glennys R.; Gezari, Suvi; Morrell, Nidia; Zaritsky, Dennis; Oestman, Linda; Smith, Mathew; Gelfand, Joseph; Drake, Andrew J.

    2011-11-10

    Using archival Sloan Digital Sky Survey (SDSS) multi-epoch imaging data (Stripe 82), we have searched for the tidal disruption of stars by supermassive black holes in non-active galaxies. Two candidate tidal disruption events (TDEs) are identified. The TDE flares have optical blackbody temperatures of 2 Multiplication-Sign 10{sup 4} K and observed peak luminosities of M{sub g} = -18.3 and -20.4 ({nu}L{sub {nu}} = 5 Multiplication-Sign 10{sup 42}, 4 Multiplication-Sign 10{sup 43} erg s{sup -1}, in the rest frame); their cooling rates are very low, qualitatively consistent with expectations for tidal disruption flares. The properties of the TDE candidates are examined using (1) SDSS imaging to compare them to other flares observed in the search, (2) UV emission measured by GALEX, and (3) spectra of the hosts and of one of the flares. Our pipeline excludes optically identifiable AGN hosts, and our variability monitoring over nine years provides strong evidence that these are not flares in hidden AGNs. The spectra and color evolution of the flares are unlike any SN observed to date, their strong late-time UV emission is particularly distinctive, and they are nuclear at high resolution arguing against these being first cases of a previously unobserved class of SNe or more extreme examples of known SN types. Taken together, the observed properties are difficult to reconcile with an SN or an AGN-flare explanation, although an entirely new process specific to the inner few hundred parsecs of non-active galaxies cannot be excluded. Based on our observed rate, we infer that hundreds or thousands of TDEs will be present in current and next-generation optical synoptic surveys. Using the approach outlined here, a TDE candidate sample with O(1) purity can be selected using geometric resolution and host and flare color alone, demonstrating that a campaign to create a large sample of TDEs, with immediate and detailed multi-wavelength follow-up, is feasible. A by-product of this work is quantification of the power spectrum of extreme flares in AGNs.

  9. Electrical properties of (1?x)(Bi{sub 0.5}Na{sub 0.5})TiO{sub 3}xKNbO{sub 3} lead-free ceramics

    SciTech Connect (OSTI)

    Jiang, Xijie; Wang, Baoyin; Luo, Laihui; Li, Weiping; Zhou, Jun; Chen, Hongbing

    2014-05-01

    In this investigation, a simple compound (1?x)(Bi{sub 0.5}Na{sub 0.5})TiO{sub 3}xKNbO{sub 3} (BNTxKN, x=00.08) lead-free ceramics were synthesized successfully by conventional solid state reaction method. The piezoelectric, dielectric and ferroelectric characteristics of the ceramics were investigated and discussed. The results shows that moderate KN addition can enhance the piezoelectric response without an obvious decline of ferroelectric properties. The largest piezoelectric response is obtained in BNT0.05KN, whereas largest electric-field-induced strain is obtained in BNT0.06KN. An effective d{sub 33}{sup eff} of ?400 pC/N calculated from electric-field-induced strain is obtained in BNT0.06KN. The present investigation demonstrates that addition KN effectively reduces the depolarization temperature of the BNTxKN ceramics. The electrical properties of the ceramics are tightly related to their depolarization temperature. - Graphical abstract: Unipolar electric-field-induced strain for the BNTxKN ceramics. A maximum strain of 0.28% is achieved with a low field in BNT0.06KN. - Highlights: Moderate KNbO{sub 3} addition enhances the piezoelectric properties of the ceramics. A maximum strain of 0.28% is achieved with a low field. A large piezoelectric response is achieved in 0.95(Bi{sub 0.5}Na{sub 0.5})TiO{sub 3}0.05KNbO{sub 3}. The electrical properties are tightly related to the depolarization temperature T{sub d}.

  10. Statistical properties of super-hot solar flares

    SciTech Connect (OSTI)

    Caspi, Amir; Krucker, Sm; Lin, R. P.

    2014-01-20

    We use Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) high-resolution imaging and spectroscopy observations from ?6 to 100 keV to determine the statistical relationships between measured parameters (temperature, emission measure, etc.) of hot, thermal plasma in 37 intense (GOES M- and X-class) solar flares. The RHESSI data, most sensitive to the hottest flare plasmas, reveal a strong correlation between the maximum achieved temperature and the flare GOES class, such that 'super-hot' temperatures >30 MK are achieved almost exclusively by X-class events; the observed correlation differs significantly from that of GOES-derived temperatures, and from previous studies. A nearly ubiquitous association with high emission measures, electron densities, and instantaneous thermal energies suggests that super-hot plasmas are physically distinct from cooler, ?10-20 MK GOES plasmas, and that they require substantially greater energy input during the flare. High thermal energy densities suggest that super-hot flares require strong coronal magnetic fields, exceeding ?100 G, and that both the plasma ? and volume filling factor f cannot be much less than unity in the super-hot region.

  11. Well-observed dynamics of flaring and peripheral coronal magnetic loops during an M-class limb flare

    SciTech Connect (OSTI)

    Shen, Jinhua; Zhou, Tuanhui; Ji, Haisheng; Feng, Li; Wiegelmann, Thomas; Inhester, Bernd

    2014-08-20

    In this paper, we present a variety of well-observed dynamic behaviors for the flaring and peripheral magnetic loops of the M6.6 class extreme limb flare that occurred on 2011 February 24 (SOL2011-02-24T07:20) from EUV observations by the Atmospheric Imaging Assembly on the Solar Dynamics Observatory and X-ray observations by RHESSI. The flaring loop motion confirms the earlier contraction-expansion picture. We find that the U-shaped trajectory delineated by the X-ray corona source of the flare roughly follows the direction of a filament eruption associated with the flare. Different temperature structures of the coronal source during the contraction and expansion phases strongly suggest different kinds of magnetic reconnection processes. For some peripheral loops, we discover that their dynamics are closely correlated with the filament eruption. During the slow rising to abrupt, fast rising of the filament, overlying peripheral magnetic loops display different responses. Two magnetic loops on the elbow of the active region had a slow descending motion followed by an abrupt successive fast contraction, while magnetic loops on the top of the filament were pushed outward, slowly being inflated for a while and then erupting as a moving front. We show that the filament activation and eruption play a dominant role in determining the dynamics of the overlying peripheral coronal magnetic loops.

  12. Other States Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Other States Natural Gas Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 408 1992 501 530 501 1993 501 522 515 533 536 531 583 546 1994 533 616 623 620 629 654 1995 667 594 663 634 643 626 643 663 603 553 567 578 1996 549 538 625 620 693 703 709 715 676 708 682 690 1997 133 124 135 142 147 142 149 177 160 150 159 161 1998 147 134 150 148 132 117 126 132 124 121 121 123 1999 754 406 686 588 693 611 708 340 590

  13. TIDAL DISRUPTION FLARES: THE ACCRETION DISK PHASE

    SciTech Connect (OSTI)

    Montesinos Armijo, Matias; De Freitas Pacheco, Jose A. [Observatoire de la Cote d'Azur, Laboratoire Cassiopee, Universite de Nice Sophia-Antipolis Bd de l'Observatoire, BP 4229, 06304 Nice Cedex 4 (France)

    2011-08-01

    The evolution of an accretion disk, formed as a consequence of the disruption of a star by a black hole, is followed by solving numerically hydrodynamic equations. The present investigation aims to study the dependence of resulting light curves on dynamical and physical properties of such a transient disk during its existence. One of the main results derived from our simulations is that blackbody fits of X-ray data tend to overestimate the true mean disk temperature. In fact, the temperature derived from blackbody fits should be identified with the color X-ray temperature rather than the average value derived from the true temperature distribution along the disk. The time interval between the beginning of the circularization of the bound debris and the beginning of the accretion process by the black hole is determined by the viscous (or accretion) timescale, which also fixes the rising part of the resulting light curve. The luminosity peak coincides with the beginning of matter accretion by the black hole and the late evolution of the light curve depends on the evolution of the debris fallback rate. Peak bolometric luminosities are in the range 10{sup 45}-10{sup 46} erg s{sup -1}, whereas peak luminosities in soft X-rays (0.2-2.0 keV) are typically one order of magnitude lower. The typical timescale derived from our preferred models for the flare luminosity to decay by two orders of magnitude is about 3-4 yr. Predicted soft X-ray light curves reproduce quite well data on galaxies in which a variable X-ray emission possibly related to a tidal event was detected. In the cases of NGC 3599 and IC 3599, data are reproduced well by models defined by a black hole with mass {approx}10{sup 7} M{sub sun} and a disrupted star of about 1 solar mass. The X-ray variation observed in XMMSL1 is consistent with a model defined by a black hole with mass {approx}3 x 10{sup 6} M{sub sun} and a disrupted star of 1 solar mass, while that observed in the galaxy situated in the cluster A1689 is consistent with a model including a black hole of {approx}10{sup 7} M{sub sun} and a disrupted star of {approx}0.5 M{sub sun}.

  14. Strategy for stabilization of the antiferroelectric phase (Pbma) over the metastable ferroelectric phase (P2{sub 1}ma) to establish double loop hysteresis in lead-free (1−x)NaNbO{sub 3}-xSrZrO{sub 3} solid solution

    SciTech Connect (OSTI)

    Guo, Hanzheng Randall, Clive A.; Shimizu, Hiroyuki; Mizuno, Youichi

    2015-06-07

    A new lead-free antiferroelectric solid solution system, (1−x)NaNbO{sub 3}-xSrZrO{sub 3}, was rationalized through noting the crystal chemistry trend, of decreasing the tolerance factor and an increase in the average electronegativity of the system. The SrZrO{sub 3} doping was found to effectively stabilize the antiferroelectric (P) phase in NaNbO{sub 3} without changing its crystal symmetry. Preliminary electron diffraction and polarization measurements were presented which verified the enhanced antiferroelectricity. In view of our recent report of another lead-free antiferroelectric system (1−x)NaNbO{sub 3}-xCaZrO{sub 3} [H. Shimizu et al. “Lead-free antiferroelectric: xCaZrO{sub 3} - (1−x)NaNbO{sub 3} system (0 ≤ x ≤ 0.10),” Dalton Trans. (published online)], the present results point to a general strategy of utilizing tolerance factor to develop a broad family of new lead-free antiferroelectrics with double polarization hysteresis loops. We also speculate on a broad family of possible solid solutions that could be identified and tested for this important type of dielectric.

  15. Solar flare impulsive phase emission observed with SDO/EVE

    SciTech Connect (OSTI)

    Kennedy, Michael B.; Milligan, Ryan O.; Mathioudakis, Mihalis; Keenan, Francis P., E-mail: mkennedy29@qub.ac.uk [Astrophysics Research Centre, School of Mathematics and Physics, Queen's University Belfast, University Road, Belfast BT7 1NN (United Kingdom)

    2013-12-10

    Differential emission measures (DEMs) during the impulsive phase of solar flares were constructed using observations from the EUV Variability Experiment (EVE) and the Markov-Chain Monte Carlo method. Emission lines from ions formed over the temperature range log T{sub e} = 5.8-7.2 allow the evolution of the DEM to be studied over a wide temperature range at 10 s cadence. The technique was applied to several M- and X-class flares, where impulsive phase EUV emission is observable in the disk-integrated EVE spectra from emission lines formed up to 3-4 MK and we use spatially unresolved EVE observations to infer the thermal structure of the emitting region. For the nine events studied, the DEMs exhibited a two-component distribution during the impulsive phase, a low-temperature component with peak temperature of 1-2 MK, and a broad high-temperature component from 7 to 30 MK. A bimodal high-temperature component is also found for several events, with peaks at 8 and 25 MK during the impulsive phase. The origin of the emission was verified using Atmospheric Imaging Assembly images to be the flare ribbons and footpoints, indicating that the constructed DEMs represent the spatially average thermal structure of the chromospheric flare emission during the impulsive phase.

  16. Natural Gas Used for Repressuring

    Gasoline and Diesel Fuel Update (EIA)

    1-2015 Colorado NA NA NA NA NA NA 1991-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2015 Kansas NA NA NA NA NA NA 1996-2015 Louisiana NA NA NA NA NA NA 1991-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1991-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 Oklahoma NA NA NA NA NA NA 1996-2015 Pennsylvania NA NA NA NA NA NA 1991-2015 Texas NA NA NA NA NA NA 1991-2015 Utah NA NA NA NA NA NA 1991-2015 West Virginia NA NA NA NA NA

  17. Nonhydrocarbon Gases Removed from Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2015 Arkansas NA NA NA NA NA NA 1991-2015 California NA NA NA NA NA NA 1996-2015 Colorado NA NA NA NA NA NA 1996-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2015 Kansas NA NA NA NA NA NA 1996-2015 Louisiana NA NA NA NA NA NA 1996-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1996-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 Oklahoma NA NA NA NA NA NA 1996-2015 Pennsylvania NA NA NA NA NA NA 1991-2015 Texas NA NA NA NA NA

  18. Nonhydrocarbon Gases Removed from Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2015 Arkansas NA NA NA NA NA NA 1991-2015 California NA NA NA NA NA NA 1996-2015 Colorado NA NA NA NA NA NA 1996-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2015 Kansas NA NA NA NA NA NA 1996-2015 Louisiana NA NA NA NA NA NA 1996-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1996-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 Oklahoma NA NA NA NA NA NA 1996-2015 Pennsylvania NA NA NA NA NA NA 1991-2015 Texas NA NA NA NA NA

  19. Natural Gas Gross Withdrawals from Oil Wells

    U.S. Energy Information Administration (EIA) Indexed Site

    1-2015 Illinois NA NA NA NA NA NA 1991-2015 Indiana NA NA NA NA NA NA 1991-2015 Kentucky NA NA NA NA NA NA 1991-2015 Maryland NA NA NA NA NA NA 1991-2015 Michigan NA NA NA NA NA NA ...

  20. Natural Gas Gross Withdrawals from Gas Wells

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2015 Illinois NA NA NA NA NA NA 1991-2015 Indiana NA NA NA NA NA NA 1991-2015 Kentucky NA NA NA NA NA NA 1991-2015 Maryland NA NA NA NA NA NA 1991-2015 Michigan NA NA NA NA NA NA ...

  1. Natural Gas Gross Withdrawals from Gas Wells

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2015 Illinois NA NA NA NA NA NA 1991-2015 Indiana NA NA NA NA NA NA 1991-2015 Kentucky NA NA NA NA NA NA 1991-2015 Maryland NA NA NA NA NA NA 1991-2015 Michigan NA NA NA NA NA NA...

  2. Natural Gas Gross Withdrawals from Oil Wells

    Gasoline and Diesel Fuel Update (EIA)

    1-2015 Illinois NA NA NA NA NA NA 1991-2015 Indiana NA NA NA NA NA NA 1991-2015 Kentucky NA NA NA NA NA NA 1991-2015 Maryland NA NA NA NA NA NA 1991-2015 Michigan NA NA NA NA NA NA...

  3. Natural Gas Gross Withdrawals from Shale Gas Wells

    Gasoline and Diesel Fuel Update (EIA)

    2007-2015 Arkansas NA NA NA NA NA NA 2007-2015 California NA NA NA NA NA NA 2007-2015 Colorado NA NA NA NA NA NA 2007-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 2007-2015 Kansas NA NA NA NA NA NA 2007-2015 Louisiana NA NA NA NA NA NA 2007-2015 Montana NA NA NA NA NA NA 2007-2015 New Mexico NA NA NA NA NA NA 2007-2015 North Dakota NA NA NA NA NA NA 2007-2015 Ohio NA NA NA NA NA NA 2007-2015 Oklahoma NA NA NA NA NA NA 2007-2015 Pennsylvania NA NA NA NA NA NA 2007-2015 Texas NA NA NA NA

  4. Natural Gas Gross Withdrawals from Shale Gas Wells

    Gasoline and Diesel Fuel Update (EIA)

    2007-2015 Arkansas NA NA NA NA NA NA 2007-2015 California NA NA NA NA NA NA 2007-2015 Colorado NA NA NA NA NA NA 2007-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 2007-2015 Kansas NA NA NA NA NA NA 2007-2015 Louisiana NA NA NA NA NA NA 2007-2015 Montana NA NA NA NA NA NA 2007-2015 New Mexico NA NA NA NA NA NA 2007-2015 North Dakota NA NA NA NA NA NA 2007-2015 Ohio NA NA NA NA NA NA 2007-2015 Oklahoma NA NA NA NA NA NA 2007-2015 Pennsylvania NA NA NA NA NA NA 2007-2015 Texas NA NA NA NA

  5. High-energy gamma-ray emission from solar flares: Summary of Fermi large area telescope detections and analysis of two M-class flares

    SciTech Connect (OSTI)

    Ackermann, M.; Ajello, M.; Albert, A.; Allafort, A.; Bechtol, K.; Bottacini, E.; Buehler, R.; Baldini, L.; Barbiellini, G.; Bastieri, D.; Buson, S.; Bellazzini, R.; Bregeon, J.; Bissaldi, E.; Bonamente, E.; Bouvier, A.; Brandt, T. J.; Brigida, M.; Bruel, P.; and others

    2014-05-20

    We present the detections of 18 solar flares detected in high-energy ?-rays (above 100 MeV) with the Fermi Large Area Telescope (LAT) during its first 4 yr of operation. This work suggests that particle acceleration up to very high energies in solar flares is more common than previously thought, occurring even in modest flares, and for longer durations. Interestingly, all these flares are associated with fairly fast coronal mass ejections (CMEs). We then describe the detailed temporal, spatial, and spectral characteristics of the first two long-lasting events: the 2011 March 7 flare, a moderate (M3.7) impulsive flare followed by slowly varying ?-ray emission over 13 hr, and the 2011 June 7 M2.5 flare, which was followed by ?-ray emission lasting for 2 hr. We compare the Fermi LAT data with X-ray and proton data measurements from GOES and RHESSI. We argue that the ?-rays are more likely produced through pion decay than electron bremsstrahlung, and we find that the energy spectrum of the proton distribution softens during the extended emission of the 2011 March 7 flare. This would disfavor a trapping scenario for particles accelerated during the impulsive phase of the flare and point to a continuous acceleration process at play for the duration of the flares. CME shocks are known for accelerating the solar energetic particles (SEPs) observed in situ on similar timescales, but it might be challenging to explain the production of ?-rays at the surface of the Sun while the CME is halfway to the Earth. A stochastic turbulence acceleration process occurring in the solar corona is another likely scenario. Detailed comparison of characteristics of SEPs and ?-ray-emitting particles for several flares will be helpful to distinguish between these two possibilities.

  6. Dielectric spectroscopy of Dy{sub 2}O{sub 3} doped (K{sub 0.5}Na{sub 0.5})NbO{sub 3} piezoelectric ceramics

    SciTech Connect (OSTI)

    Mahesh, P. Subhash, T. Pamu, D.

    2014-04-24

    We report the dielectric properties of (K{sub 0.5}Na{sub 0.5})NbO{sub 3} ceramics doped with x wt% of Dy{sub 2}O{sub 3} (x= 0.0-1.5 wt%) using the broadband dielectric spectroscopy. The X-ray diffraction studies showed the formation of perovskite structure signifying that Dy{sub 2}O{sub 3} diffuse into the KNN lattice. Samples doped with x > 0.5 wt% exhibit smaller grain size and lower relative densities. The dielectric properties of KNN ceramics doped with Dy{sub 2}O{sub 3} are enhanced by increasing the Dy{sup 3+} content; among the compositions studied, x = 0.5 wt% exhibited the highest dielectric constant and lowest loss at 1MHz over the temperature range of 30C to 400C. All the samples exhibit maximum dielectric constant at the Curie temperature (? 326C) and a small peak in the dielectric constant at around 165C is due to a structural phase transition.

  7. Natural Gas Gross Withdrawals from Coalbed Wells

    Gasoline and Diesel Fuel Update (EIA)

    2002-2015 Alaska NA NA NA NA NA NA 2002-2015 Arkansas NA NA NA NA NA NA 2006-2015 California NA NA NA NA NA NA 2002-2015 Colorado NA NA NA NA NA NA 2002-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 2002-2015 Kansas NA NA NA NA NA NA 2002-2015 Louisiana NA NA NA NA NA NA 2002-2015 Montana NA NA NA NA NA NA 2002-2015 New Mexico NA NA NA NA NA NA 2002-2015 North Dakota NA NA NA NA NA NA 2002-2015 Ohio NA NA NA NA NA NA 2006-2015 Oklahoma NA NA NA NA NA NA 2002-2015 Pennsylvania NA NA NA

  8. High-Energy Aspects of Solar Flares: Observations and Models

    SciTech Connect (OSTI)

    Liu, Wei; Guo, Fan

    2015-07-21

    The paper begins by describing the structure of the Sun, with emphasis on the corona. The Sun is a unique plasma laboratory, which can be probed by Sun-grazing comets, and is the driver of space weather. Energization and particle acceleration mechanisms in solar flares is presented; magnetic reconnection is key is understanding stochastic acceleration mechanisms. Then coupling between kinetic and fluid aspects is taken up; the next step is feedback of atmospheric response to the acceleration process – rapid quenching of acceleration. Future challenges include applications of stochastic acceleration to solar energetic particles (SEPs), Fermi γ-rays observations, fast-mode magnetosonic wave trains in a funnel-shaped wave guide associated with flare pulsations, and the new SMEX mission IRIS (Interface Region Imaging Spectrograph),

  9. DISCOVERY OF 6.035 GHz HYDROXYL MASER FLARES IN IRAS 18566+0408

    SciTech Connect (OSTI)

    Al-Marzouk, A. A.; Araya, E. D.; Hofner, P.; Kurtz, S.; Linz, H.; Olmi, L.

    2012-05-10

    We report the discovery of 6.035 GHz hydroxyl (OH) maser flares toward the massive star-forming region IRAS 18566+0408 (G37.55+0.20), which is the only region known to show periodic formaldehyde (4.8 GHz H{sub 2}CO) and methanol (6.7 GHz CH{sub 3}OH) maser flares. The observations were conducted between 2008 October and 2010 January with the 305 m Arecibo Telescope in Puerto Rico. We detected two flare events, one in 2009 March and one in 2009 September to November. The OH maser flares are not simultaneous with the H{sub 2}CO flares, but may be correlated with CH{sub 3}OH flares from a component at corresponding velocities. A possible correlated variability of OH and CH{sub 3}OH masers in IRAS 18566+0408 is consistent with a common excitation mechanism (IR pumping) as predicted by theory.

  10. SOFE Romanelli_na1.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Roadmap to the realization of fusion energy Francesco Romanelli European Fusion Development Agreement EFDA Leader and JET Leader SOFE 11 June 2013 Acknoledgments: P. Barabaschi,D. Borba, G. Federici, L. Horton, R. Neu, D. Stork, H. Zohm A Roadmap to the realization of fusion energy Francesco Romanelli European Fusion Development Agreement EFDA Leader and JET Leader SOFE 11 June 2013 Acknoledgments: P. Barabaschi,D. Borba, G. Federici, L. Horton, R. Neu, D. Stork, H. Zohm Download at www.efda.org

  11. A=13Na (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) These nuclei have not been observed: see (1983ANZQ

  12. A=13Na (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    91AJ01) (Not illustrated) These nuclei have not been observed. See (1986AN07

  13. A=16Na (1986AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ04) (Not observed) See (1983ANZQ; theor.

  14. A=16Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    93TI07) (Not observed) See (1986AN07

  15. A=17Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    excess is predicted to be 35.61 MeV by (1966KE16). It is then unbound with respect to breakup into 16Ne + p by 4.3 MeV and with respect to breakup into 14O + 3p by 5.7 MeV. See...

  16. A=17Na (1986AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    excess is predicted to be 35.61 MeV by (1966KE16). It is then unbound with respect to breakup into 16Ne + p by 4.3 MeV and with respect to breakup into 14O + 3p by 5.7 MeV. See...

  17. A=17Na (71AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its mass excess is predicted to be 35.61 MeV by (KE66C). It is then unbound with respect to breakup into 16Ne + p by 3.2 MeV and with respect to breakup into 14O + 3p by 5.8 MeV...

  18. A=17Na (1977AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    excess is predicted to be 35.61 MeV by (1966KE16). It is then unbound with respect to breakup into 16Ne + p by 3.2 MeV and with respect to breakup into 14O + 3p by 5.8 MeV. See...

  19. A=17Na (1982AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its mass excess is predicted to be 35.61 MeV by (1966KE16). It is then unbound with respect to breakup into 16Ne + p by 4.3 MeV and with respect to breakup into 14O + 3p by 5.7 MeV...

  20. Document: NA (FOIA) Actionee: Dorothy Riehie

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    well as our newsletters, and often reported in the news media. In addition, we publish special reports and meet with public officials, workers, and the public at large to educate...

  1. Contract No. DE-NA0001942

    National Nuclear Security Administration (NNSA)

    1942 Section B - H, Page i PART I - THE SCHEDULE TABLE OF CONTENTS SECTION B ................................................................................................................................... 1 SUPPLIES OR SERVICES AND PRICES/COSTS ................................................................... 1 CLIN 0001 MANAGEMENT AND OPERATION (M&O) OF Y12/PX .................................. 1 CLIN 0001A CONTRACT TRANSITION: COST REIMBURSEMENT, NO FEE ................ 1 CLIN 0001B

  2. Contract No. DE-NA0002839

    National Nuclear Security Administration (NNSA)

    2839 Section B - H, Page i PART I - THE SCHEDULE TABLE OF CONTENTS SECTION B: SUPPLIES OR SERVICES AND PRICES/COSTS ......................................................................... 1 B-1 SERVICES BEING ACQUIRED ........................................................................................................ 1 CLIN 0001 MANAGEMENT AND OPERATION OF THE NATIONAL SECURITY CAMPUS ..................... 1 CLIN 0001A TRANSITION TERM

  3. NA 80 - Associate Administrator for Counterterrorism and

    National Nuclear Security Administration (NNSA)

    Counterproliferation | National Nuclear Security Administration 80 - Associate Administrator for Counterterrorism and Counterproliferation | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios

  4. NA-40 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    40 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home /

  5. NA-80 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    80 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home /

  6. Global energetics of solar flares. I. Magnetic energies

    SciTech Connect (OSTI)

    Aschwanden, Markus J.; Xu, Yan; Jing, Ju E-mail: yan.xu@njit.edu

    2014-12-10

    We present the first part of a project on the global energetics of solar flares and coronal mass ejections that includes about 400 M- and X-class flares observed with Atmospheric Imaging Assembly (AIA) and Helioseismic and Magnetic Imager (HMI) on board the Solar Dynamics Observatory (SDO). We calculate the potential (E{sub p} ), the nonpotential (E {sub np}) or free energies (E {sub free} = E {sub np} – E{sub p} ), and the flare-dissipated magnetic energies (E {sub diss}). We calculate these magnetic parameters using two different NLFFF codes: the COR-NLFFF code uses the line-of-sight magnetic field component B{sub z} from HMI to define the potential field, and the two-dimensional (2D) coordinates of automatically detected coronal loops in six coronal wavelengths from AIA to measure the helical twist of coronal loops caused by vertical currents, while the PHOT-NLFFF code extrapolates the photospheric three-dimensional (3D) vector fields. We find agreement between the two codes in the measurement of free energies and dissipated energies within a factor of ≲ 3. The size distributions of magnetic parameters exhibit powerlaw slopes that are approximately consistent with the fractal-diffusive self-organized criticality model. The magnetic parameters exhibit scaling laws for the nonpotential energy, E{sub np}∝E{sub p}{sup 1.02}, for the free energy, E{sub free}∝E{sub p}{sup 1.7} and E{sub free}∝B{sub φ}{sup 1.0}L{sup 1.5}, for the dissipated energy, E{sub diss}∝E{sub p}{sup 1.6} and E{sub diss}∝E{sub free}{sup 0.9}, and the energy dissipation volume, V∝E{sub diss}{sup 1.2}. The potential energies vary in the range of E{sub p} = 1 × 10{sup 31}-4 × 10{sup 33} erg, while the free energy has a ratio of E {sub free}/E{sub p} ≈ 1%-25%. The Poynting flux amounts to F {sub flare} ≈ 5 × 10{sup 8}-10{sup 10} erg cm{sup –2} s{sup –1} during flares, which averages to F {sub AR} ≈ 6 × 10{sup 6} erg cm{sup –2} s{sup –1} during the entire observation period and is comparable with the coronal heating rate requirement in active regions.

  7. Gamma-Ray Observations of a Giant Flare From the Magnetar Sgr...

    Office of Scientific and Technical Information (OSTI)

    than the only two previous events, making this flare a once in a century event. This colossal energy release likely occurred during a catastrophic reconfiguration of the...

  8. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-04-01

    ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

  9. Natural Gas Used for Repressuring

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1991-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2015 Kansas NA NA NA NA NA NA 1996-2015 Louisiana NA NA NA NA NA NA 1991-2015 Montana NA NA NA NA ...

  10. QUASI-PERIODIC PULSATIONS IN SOLAR AND STELLAR FLARES: RE-EVALUATING THEIR NATURE IN THE CONTEXT OF POWER-LAW FLARE FOURIER SPECTRA

    SciTech Connect (OSTI)

    Inglis, A. R.; Ireland, J.; Dominique, M.

    2015-01-10

    The nature of quasi-periodic pulsations (QPPs) in solar and stellar flares remains debated. Recent work has shown that power-law-like Fourier power spectra are an intrinsic property of solar and stellar flare signals, a property that many previous studies of this phenomenon have not accounted for. Hence a re-evaluation of the existing interpretations and assumptions regarding QPPs is needed. We adopt a Bayesian method for investigating this phenomenon, fully considering the Fourier power-law properties of flare signals. Using data from the PROBA2/Large Yield Radiometer, Fermi/Gamma-ray Burst Monitor, Nobeyama Radioheliograph, and Yohkoh/HXT instruments, we study a selection of flares from the literature identified as QPP events. Additionally, we examine optical data from a recent stellar flare that appears to exhibit oscillatory properties. We find that, for all but one event tested, an explicit oscillation is not required to explain the observations. Instead, the flare signals are adequately described as a manifestation of a power law in the Fourier power spectrum. However, for the flare of 1998 May 8, strong evidence for an explicit oscillation with P ? 14-16 s is found in the 17GHz radio data and the 13-23 keV Yohkoh/HXT data. We conclude that, most likely, many previously analyzed events in the literature may be similarly described by power laws in the flare Fourier power spectrum, without invoking a narrowband, oscillatory component. Hence the prevalence of oscillatory signatures in solar and stellar flares may be less than previously believed. The physical mechanism behind the appearance of the observed power laws is discussed.

  11. No. 2 Diesel Fuel Sales to End Users Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1994-2015 East Coast (PADD 1) NA NA NA NA NA NA 1994-2015 New England (PADD 1A) NA NA NA NA NA NA 1994-2015 Connecticut NA NA NA NA NA NA 1994-2015 Maine NA NA NA...

  12. Brightest Fermi-LAT flares of PKS 1222+216: implications on emission and acceleration processes

    SciTech Connect (OSTI)

    Kushwaha, Pankaj; Singh, K. P.; Sahayanathan, Sunder

    2014-11-20

    We present a high time resolution study of the two brightest ?-ray outbursts from a blazar PKS 1222+216 observed by the Fermi Large Area Telescope (LAT) in 2010. The ?-ray light curves obtained in four different energy bands, 0.1-3, 0.1-0.3, 0.3-1, and 1-3 GeV, with time bins of six hours, show asymmetric profiles with similar rise times in all the bands but a rapid decline during the April flare and a gradual one during the June flare. The light curves during the April flare show an ?2 day long plateau in 0.1-0.3 GeV emission, erratic variations in 0.3-1 GeV emission, and a daily recurring feature in 1-3 GeV emission until the rapid rise and decline within a day. The June flare shows a monotonic rise until the peak, followed by a gradual decline powered mainly by the multi-peak 0.1-0.3 GeV emission. The peak fluxes during both the flares are similar except in the 1-3 GeV band in April, which is twice the corresponding flux during the June flare. Hardness ratios during the April flare indicate spectral hardening in the rising phase followed by softening during the decay. We attribute this behavior to the development of a shock associated with an increase in acceleration efficiency followed by its decay leading to spectral softening. The June flare suggests hardening during the rise followed by a complicated energy dependent behavior during the decay. Observed features during the June flare favor multiple emission regions while the overall flaring episode can be related to jet dynamics.

  13. RAPID TeV GAMMA-RAY FLARING OF BL LACERTAE

    SciTech Connect (OSTI)

    Arlen, T.; Aune, T.; Bouvier, A.; Beilicke, M.; Buckley, J. H.; Bugaev, V.; Dickherber, R.; Benbow, W.; Cesarini, A.; Connolly, M. P.; Ciupik, L.; Cui, W.; Feng, Q.; Finley, J. P.; Dumm, J.; Fortson, L.; Errando, M.; Falcone, A.; Federici, S.; Finnegan, G. E-mail: cui@purdue.edu; Collaboration: VERITAS Collaboration; and others

    2013-01-10

    We report on the detection of a very rapid TeV gamma-ray flare from BL Lacertae on 2011 June 28 with the Very Energetic Radiation Imaging Telescope Array System (VERITAS). The flaring activity was observed during a 34.6 minute exposure, when the integral flux above 200 GeV reached (3.4 {+-} 0.6) Multiplication-Sign 10{sup -6} photons m{sup -2} s{sup -1}, roughly 125% of the Crab Nebula flux measured by VERITAS. The light curve indicates that the observations missed the rising phase of the flare but covered a significant portion of the decaying phase. The exponential decay time was determined to be 13 {+-} 4 minutes, making it one of the most rapid gamma-ray flares seen from a TeV blazar. The gamma-ray spectrum of BL Lacertae during the flare was soft, with a photon index of 3.6 {+-} 0.4, which is in agreement with the measurement made previously by MAGIC in a lower flaring state. Contemporaneous radio observations of the source with the Very Long Baseline Array revealed the emergence of a new, superluminal component from the core around the time of the TeV gamma-ray flare, accompanied by changes in the optical polarization angle. Changes in flux also appear to have occurred at optical, UV, and GeV gamma-ray wavelengths at the time of the flare, although they are difficult to quantify precisely due to sparse coverage. A strong flare was seen at radio wavelengths roughly four months later, which might be related to the gamma-ray flaring activities. We discuss the implications of these multiwavelength results.

  14. New waste-heat refrigeration unit cuts flaring, reduces pollution

    SciTech Connect (OSTI)

    Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

    1998-05-18

    Planetec Utility Services Co. Inc. and Energy Concepts Co. (ECC), with the help of the US Department of Energy (DOE), developed and commissioned a unique waste-heat powered LPG recovery plant in August 1997 at the 30,000 b/d Denver refinery, operated by Ultramar Diamond Shamrock (UDS). This new environmentally friendly technology reduces flare emissions and the loss of salable liquid-petroleum products to the fuel-gas system. The waste heat ammonia absorption refrigeration plant (Whaarp) is the first technology of its kind to use low-temperature waste heat (295 F) to achieve sub-zero refrigeration temperatures ({minus}40 F) with the capability of dual temperature loads in a refinery setting. The ammonia absorption refrigeration is applied to the refinery`s fuel-gas makeup streams to condense over 180 b/d of salable liquid hydrocarbon products. The recovered liquid, about 64,000 bbl/year of LPG and gasoline, increases annual refinery profits by nearly $1 million, while substantially reducing air pollution emissions from the refinery`s flare.

  15. Biogas, once flared, fuels cogen plant serving two hosts

    SciTech Connect (OSTI)

    Johnson, J.K.; McRae, C.L.

    1995-04-01

    This article reports that digester gas from a wastewater treatment plant meets up to 40% of the fuel needs of this cogenerator. Steam is exported for heating the treatment plant`s digesters and for ice production by a second steam host. The Carson Ice-Gen Project promises to enhance the reliability of electric service to the Sacramento Regional Waste water Treatment Plant (SRWTP), to prevent effluent discharges to nearby water ways during power disruptions, and to reduce air emissions associated with flaring of digester gas. The project comprises a 95-MW combined-cycle cogeneration powerplant and a 300-ton/day ice-production plant. The powerplant features twin LM 6000 gas turbines (GTs). One, used as a 53-MW base-load unit, is paired with a heat-recovery steam generator (HRSG) feeding an extraction/condensing steam turbine/generator (STG). The other GT is used as a 42-MW, simple-cycle peaking unit. Primary fuel is natural gas, which is supplemented by digester gas that is currently being flared at the wastewater treatment plant. Export steam extracted from the STG is used to heat the digesters and to drive ammonia compressors at the ice plant. Steam is also used on-site to chill water in absorption chillers that cool the GT inlet air for power augmentation.

  16. UNIVERSAL BEHAVIOR OF X-RAY FLARES FROM BLACK HOLE SYSTEMS

    SciTech Connect (OSTI)

    Wang, F. Y.; Dai, Z. G.; Yi, S. X.; Xi, S. Q. E-mail: dzg@nju.edu.cn

    2015-01-01

    X-ray flares have been discovered in black hole systems such as gamma-ray bursts, the tidal disruption event Swift J1644+57, the supermassive black hole Sagittarius A* at the center of our Galaxy, and some active galactic nuclei. Occurrences of X-ray flares are always accompanied by relativistic jets. However, it is still unknown whether or not there is a physical analogy among such X-ray flares produced in black hole systems spanning nine orders of magnitude in mass. Here, we report observed data of X-ray flares and show that they have three statistical properties similar to solar flares, including power-law distributions of their energies, durations, and waiting times, which can be explained by a fractal-diffusive, self-organized criticality model. These statistical similarities, together with the fact that solar flares are triggered by a magnetic reconnection process, suggest that all of the X-ray flares are consistent with magnetic reconnection events, implying that their concomitant relativistic jets may be magnetically dominated.

  17. Measurements and modeling of total solar irradiance in X-class solar flares

    SciTech Connect (OSTI)

    Moore, Christopher Samuel; Chamberlin, Phillip Clyde; Hock, Rachel

    2014-05-20

    The Total Irradiance Monitor (TIM) from NASA's SOlar Radiation and Climate Experiment can detect changes in the total solar irradiance (TSI) to a precision of 2 ppm, allowing observations of variations due to the largest X-class solar flares for the first time. Presented here is a robust algorithm for determining the radiative output in the TIM TSI measurements, in both the impulsive and gradual phases, for the four solar flares presented in Woods et al., as well as an additional flare measured on 2006 December 6. The radiative outputs for both phases of these five flares are then compared to the vacuum ultraviolet (VUV) irradiance output from the Flare Irradiance Spectral Model (FISM) in order to derive an empirical relationship between the FISM VUV model and the TIM TSI data output to estimate the TSI radiative output for eight other X-class flares. This model provides the basis for the bolometric energy estimates for the solar flares analyzed in the Emslie et al. study.

  18. STUDY OF TWO SUCCESSIVE THREE-RIBBON SOLAR FLARES ON 2012 JULY 6

    SciTech Connect (OSTI)

    Wang, Haimin; Liu, Chang; Deng, Na; Xu, Yan; Jing, Ju; Zeng, Zhicheng; Cao, Wenda

    2014-01-20

    This Letter reports two rarely observed three-ribbon flares (M1.9 and C9.2) on 2012 July 6 in NOAA AR 11515, which we found using H? observations of 0.''1 resolution from the New Solar Telescope and Ca II H images from Hinode. The flaring site is characterized by an intriguing ''fish-bone-like'' morphology evidenced by both H? images and a nonlinear force-free field (NLFFF) extrapolation, where two semi-parallel rows of low-lying, sheared loops connect an elongated, parasitic negative field with the sandwiching positive fields. The NLFFF model also shows that the two rows of loops are asymmetric in height and have opposite twists, and are enveloped by large-scale field lines including open fields. The two flares occurred in succession within half an hour and are located at the two ends of the flaring region. The three ribbons of each flare run parallel to the magnetic polarity inversion line, with the outer two lying in the positive field and the central one in the negative field. Both flares show surge-like flows in H? apparently toward the remote region, while the C9.2 flare is also accompanied by EUV jets possibly along the open field lines. Interestingly, the 12-25keV hard X-ray sources of the C9.2 flare first line up with the central ribbon then shift to concentrate on the top of the higher branch of loops. These results are discussed in favor of reconnection along the coronal null line, producing the three flare ribbons and the associated ejections.

  19. Urinary Symptom Flare in 712 {sup 125}I Prostate Brachytherapy Patients: Long-Term Follow-Up

    SciTech Connect (OSTI)

    Keyes, Mira; Miller, Stacy; Moravan, Veronika; Pickles, Tom; Liu, Mitchell; Spadinger, Ingrid; Lapointe, Vincent; Morris, W. James

    2009-11-01

    Purpose: To describe the late transient worsening of urinary symptoms ('urinary symptom flare') in 712 consecutive prostate brachytherapy patients, associated predictive factors, association with rectal and urinary toxicity, and the development of erectile dysfunction. Methods and Materials: Patients underwent implantation between 1998 and 2003 (median follow-up, 57 months). International Prostate Symptom Score (IPSS), Radiation Therapy Oncology Group (RTOG) toxicity, and erectile function data were prospectively collected. Flare was defined as an increase in IPSS of >=5 and of >=8 points greater than the post-treatment nadir. The relationships between the occurrence of flare and the patient, tumor, and treatment characteristics were examined. The Cox proportional hazards method was used to test individual variables and the multivariate models. Results: The incidence of flare was 52% and 30% using the flare definition of an IPSS of >=5 and >=8 points greater than the postimplant nadir, respectively. Of the patients with symptoms, 65% had resolution of their symptoms within 6 months and 91% within 1 year. Flares most commonly occurred 16-24 months after implantation. On multivariate analysis, a greater baseline IPSS and greater maximal postimplant IPSS were the predictors of flare, regardless of the flare definition used. Androgen suppression was a predictor for fewer flares (IPSS >=5). Diabetes and prostate edema predicted for more frequent flares (IPSS >=8). Patients with flare had a greater incidence of RTOG Grade 3 urinary toxicity and RTOG Grade 2 or greater rectal toxicity. No association was found between erectile dysfunction and the occurrence of flare. Conclusion: Urinary symptom flare is a common, transient phenomenon after prostate brachytherapy. A greater baseline IPSS and maximal postimplant IPSS were the strongest predictive factors. Flare was associated with a greater incidence of late RTOG Grade 3 urinary toxicity and greater rate of late RTOG Grade 2 or greater rectal toxicity.

  20. A NEW CORRELATION BETWEEN GRB X-RAY FLARES AND THE PROMPT EMISSION

    SciTech Connect (OSTI)

    Sonbas, E. [Department of Physics, University of Adiyaman, 02040 Adiyaman (Turkey); MacLachlan, G. A.; Shenoy, A.; Dhuga, K. S.; Parke, W. C., E-mail: edasonbas@yahoo.com [Department of Physics, George Washington University, Washington, DC 20052 (United States)

    2013-04-20

    From a sample of gamma-ray bursts (GRBs) detected by the Fermi and Swift missions, we have extracted the minimum variability timescales for temporal structures in the light curves associated with the prompt emission and X-ray flares. A comparison of this variability timescale with pulse parameters such as rise times, determined via pulse-fitting procedures, and spectral lags, extracted via the cross-correlation function, indicates a tight correlation between these temporal features for both the X-ray flares and the prompt emission. These correlations suggest a common origin for the production of X-ray flares and the prompt emission in GRBs.

  1. Statistical study of free magnetic energy and flare productivity of solar active regions

    SciTech Connect (OSTI)

    Su, J. T.; Jing, J.; Wang, S.; Wang, H. M. [Space Weather Research Laboratory, New Jersey Institute of Technology, University Heights, Newark, NJ 07102-1982 (United States); Wiegelmann, T., E-mail: sjt@bao.ac.cn [Max-Planck-Institut fur Sonnensystemforschung, Max-Planck-Strasse 2, D-37191 Katlenburg-Lindau (Germany)

    2014-06-20

    Photospheric vector magnetograms from the Helioseismic and Magnetic Imager on board the Solar Dynamic Observatory are utilized as the boundary conditions to extrapolate both nonlinear force-free and potential magnetic fields in solar corona. Based on the extrapolations, we are able to determine the free magnetic energy (FME) stored in active regions (ARs). Over 3000 vector magnetograms in 61 ARs were analyzed. We compare FME with the ARs' flare index (FI) and find that there is a weak correlation (<60%) between FME and FI. FME shows slightly improved flare predictability relative to the total unsigned magnetic flux of ARs in the following two aspects: (1) the flare productivity predicted by FME is higher than that predicted by magnetic flux and (2) the correlation between FI and FME is higher than that between FI and magnetic flux. However, this improvement is not significant enough to make a substantial difference in time-accumulated FI, rather than individual flare, predictions.

  2. Underground muons from the direction of Cygnus X-3 during the January 1991 radio flare

    SciTech Connect (OSTI)

    The Soudan 2 Collaboration

    1991-08-01

    Muons recorded in the Soudan 2 underground nucleon decay detector from January 1989 to February 1991 have been examined for any correlation with the radio flares of Cyguns X-3 observed during this period. On two nearby days during the radio flare of January 1991 a total of 32 muons within 2.0{degrees} of the Cyguns X-3 direction were observed when 11.4 were expected.

  3. PLASMOID EJECTIONS AND LOOP CONTRACTIONS IN AN ERUPTIVE M7.7 SOLAR FLARE:

    Office of Scientific and Technical Information (OSTI)

    EVIDENCE OF PARTICLE ACCELERATION AND HEATING IN MAGNETIC RECONNECTION OUTFLOWS (Journal Article) | SciTech Connect PLASMOID EJECTIONS AND LOOP CONTRACTIONS IN AN ERUPTIVE M7.7 SOLAR FLARE: EVIDENCE OF PARTICLE ACCELERATION AND HEATING IN MAGNETIC RECONNECTION OUTFLOWS Citation Details In-Document Search Title: PLASMOID EJECTIONS AND LOOP CONTRACTIONS IN AN ERUPTIVE M7.7 SOLAR FLARE: EVIDENCE OF PARTICLE ACCELERATION AND HEATING IN MAGNETIC RECONNECTION OUTFLOWS Where particle acceleration

  4. DOE/EA-1745 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE CAPTURE PROJECT AT THE ARCELORMITTAL USA, INC. INDIANA HARBOR STEEL MILL, EAST CHICAGO, INDIANA U.S. Department of Energy National Energy Technology Laboratory August 2010 DOE/EA-1745 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE CAPTURE PROJECT AT THE ARCELORMITTAL USA, INC. INDIANA HARBOR STEEL MILL, EAST CHICAGO, INDIANA U.S. Department of Energy National Energy Technology Laboratory August 2010 DOE/EA-1745 iii

  5. DOE/EA-1745 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    45 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE CAPTURE PROJECT AT THE ARCELORMITTAL USA, INC. INDIANA HARBOR STEEL MILL, EAST CHICAGO, INDIANA U.S. Department of Energy National Energy Technology Laboratory August 2010 DOE/EA-1745 FINAL ENVIRONMENTAL ASSESSMENT FOR THE BLAST FURNACE GAS FLARE CAPTURE PROJECT AT THE ARCELORMITTAL USA, INC. INDIANA HARBOR STEEL MILL, EAST CHICAGO, INDIANA U.S. Department of Energy National Energy Technology Laboratory August 2010 DOE/EA-1745 iii

  6. Structural, ferroelectric and magnetic study of lead free (Na{sub 0.5}Bi{sub 0.5}){sub 1-x}La{sub x}Ti{sub 0.988}Fe{sub 0.012}O{sub 3} (x=0,0.01,0.03,0.05) ceramic

    SciTech Connect (OSTI)

    Parmar, Kusum Sharma, Anshu; Sharma, Hakikat; Negi, N. S.

    2015-05-15

    Lead free (Na{sub 0.5}Bi{sub 0.5}){sub 1-x}La{sub x}Ti{sub 0.988}Fe{sub 0.012}O{sub 3} ceramic having compositions (x=0, 0.01, 0.03, 0.05) has been prepared by sol gel method using citric acid. Structural analysis has been done by X-ray diffraction and FTIR measurements. XRD patterns have been confirmed perovskite structure for all samples. FTIR absorption band at around ?630?cm{sup ?1} is observed for all samples which confirm perovskite phase formation in samples. With increasing La concentration, shifting in XRD peaks and FTIR absorption bands is observed which suggests incorporation of La on A-site in prepared (Na{sub 0.5}Bi{sub 0.5}){sub 1-x}La{sub x}Ti{sub 0.988}Fe{sub 0.012}O{sub 3} samples. Effect of La substitution on Ferroelectric (Polarization vs. Electric field) and Magnetic (Magnetization vs. Magnetic field) properties have been studied at room temperature. All samples exhibit weak ferromagnetic order and also possess ferroelectric behavior which provides new insight to lead free single phase multiferroic materials.

  7. A very small and super strong zebra pattern burst at the beginning of a solar flare

    SciTech Connect (OSTI)

    Tan, Baolin; Tan, Chengming; Zhang, Yin; Huang, Jing; Yan, Yihua; Mszrosov, Hana; Karlick, Marian

    2014-08-01

    Microwave emission with spectral zebra pattern structures (ZPs) is frequently observed in solar flares and the Crab pulsar. The previous observations show that ZP is a structure only overlapped on the underlying broadband continuum with slight increments and decrements. This work reports an unusually strong ZP burst occurring at the beginning of a solar flare observed simultaneously by two radio telescopes located in China and the Czech Republic and by the EUV telescope on board NASA's satellite Solar Dynamics Observatory on 2013 April 11. It is a very short and super strong explosion whose intensity exceeds several times that of the underlying flaring broadband continuum emission, lasting for just 18 s. EUV images show that the flare starts from several small flare bursting points (FBPs). There is a sudden EUV flash with extra enhancement in one of these FBPs during the ZP burst. Analysis indicates that the ZP burst accompanying an EUV flash is an unusual explosion revealing a strong coherent process with rapid particle acceleration, violent energy release, and fast plasma heating simultaneously in a small region with a short duration just at the beginning of the flare.

  8. TIME EVOLUTION OF FLARES IN GRB 130925A: JET PRECESSION IN A BLACK HOLE ACCRETION SYSTEM

    SciTech Connect (OSTI)

    Hou, Shu-Jin; Liu, Tong; Gu, Wei-Min; Sun, Mou-Yuan; Lu, Ju-Fu [Department of Astronomy and Institute of Theoretical Physics and Astrophysics, Xiamen University, Xiamen, Fujian 361005 (China); Lin, Da-Bin [Department of Physics and GXU-NAOC Center for Astrophysics and Space Sciences, Guangxi University, Nanning, Guangxi 530004 (China); Wu, Xue-Feng, E-mail: tongliu@xmu.edu.cn [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China)

    2014-01-20

    GRB 130925A, composed of three gamma-ray emission episodes and a series of orderly flares, has been detected by Swift, Fermi, Konus-Wind, and INTEGRAL. If the third weakest gamma-ray episode can be considered a giant flare, we find that after the second gamma-ray episode observed by INTEGRAL located at about 2000s, a positive relation exists between the time intervals of the adjacent flares and the time since the episode. We suggest that the second gamma-ray episode and its flares originate from the resumption of the accretion process due to the fragments from the collapsar falling back; such a relation may be related to a hyperaccretion disk around a precessed black hole (BH). We propose that the origin and time evolution of the flares, and the approximately symmetrical temporal structure and spectral evolution of the single flare can be explained well by a jet precession model. In addition, the mass and spin of the BH can be constrained, which indicates a stellar-mass, fast-rotating BH located in the center of GRB 130925A.

  9. SUCCESSIVE SOLAR FLARES AND CORONAL MASS EJECTIONS ON 2005 SEPTEMBER 13 FROM NOAA AR 10808

    SciTech Connect (OSTI)

    Liu Chang; Wang Haimin; Lee, Jeongwoo; Karlicky, Marian; Choudhary, Debi Prasad; Deng Na E-mail: haimin@flare.njit.ed E-mail: karlicky@asu.cas.c E-mail: na.deng@csun.ed

    2009-09-20

    We present a multiwavelength study of the 2005 September 13 eruption from NOAA AR 10808 that produced total four flares and two fast coronal mass ejections (CMEs) within {approx}1.5 hr. Our primary attention is paid to the fact that these eruptions occurred in close succession in time, and that all of them were located along an S-shaped magnetic polarity inversion line (PIL) of the active region. In our analysis, (1) the disturbance created by the first flare propagated southward along the PIL to cause a major filament eruption that led to the first CME and the associated second flare underneath. (2) The first CME partially removed the overlying magnetic fields over the northern delta spot to allow the third flare and the second CME. (3) The ribbon separation during the fourth flare would indicate reclosing of the overlying field lines opened by the second CME. It is thus concluded that these series of flares and CMEs are interrelated to each other via magnetic reconnections between the expanding magnetic structure and the nearby magnetic fields. These results complement previous works made on this event with the suggested causal relationship among the successive eruptions.

  10. Measurement of the rate of stellar tidal disruption flares

    SciTech Connect (OSTI)

    Van Velzen, Sjoert

    2014-09-01

    We report an observational estimate of the rate of stellar tidal disruption flares (TDFs) in inactive galaxies based on a successful search for these events among transients in galaxies using archival Sloan Digital Sky Survey (SDSS) multi-epoch imaging data (Stripe 82). This search yielded 186 nuclear flares in galaxies, 2 of which are excellent TDF candidates. Because of the systematic nature of the search, the very large number of galaxies, the long time of observation, and the fact that non-TDFs were excluded without resorting to assumptions about TDF characteristics, this study provides an unparalleled opportunity to measure the TDF rate. To compute the rate of optical stellar tidal disruption events, we simulate our entire pipeline to obtain the efficiency of detection. The rate depends on the light curves of TDFs, which are presently still poorly constrained. Using only the observed part of the SDSS light curves gives a model-independent upper limit to the optical TDF rate, N-dot <210{sup ?4} yr{sup ?1} galaxy{sup ?1} (90% CL), under the assumption that the SDSS TDFs are representative examples. We develop three empirical models of the light curves based on the two SDSS light curves and two more recent and better-sampled Pan-STARRS TDF light curves, leading to our best estimate of the rate: N-dot {sub TDF}=(1.5--2.0){sub ?1.3}{sup +2.7}10{sup ?5} yr{sup ?1} galaxy{sup ?1}. We explore the modeling uncertainties by considering two theoretically motivated light curve models, as well as two different relationships between black hole mass and galaxy luminosity, and two different treatments of the cutoff in the visibility of TDFs at large M {sub BH}. From this we conclude that these sources of uncertainty are not significantly larger than the statistical ones. Our results are applicable for galaxies hosting black holes with mass in the range of a few 10{sup 6}-10{sup 8} M {sub ?}, and translates to a volumetric TDF rate of (4-8) 10{sup 80.4} yr{sup 1} Mpc{sup 3}, with the statistical uncertainty in the exponent.

  11. U.S. Price of Natural Gas Delivered to Residential Consumers (Dollars per

    Gasoline and Diesel Fuel Update (EIA)

    Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 NA NA NA NA NA NA NA NA NA NA NA NA 1981 3.94 3.99 4.06 4.11 4.29 4.30 4.32 4.30 4.47 4.50 4.53 4.55 1982 4.65 4.69 4.78 4.86 5.17

  12. Michigan Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed ...

  13. Arizona Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1996-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed ...

  14. Florida Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2002-2015 Repressuring NA NA NA NA NA NA ...

  15. U.S. Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA ...

  16. Illinois Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 From Coalbed Wells NA NA NA NA NA NA 2006-2015 Repressuring NA NA NA NA NA NA 1991-2015 Vented and ...

  17. Natural Gas Gross Withdrawals from Shale Gas Wells (Summary)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2007-2015 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 2007-2015 Alabama NA NA NA NA NA NA 2007-2015 Arizona NA NA NA NA NA NA 2007-2015 Arkansas NA NA NA NA NA NA 2007-2015...

  18. Natural Gas Gross Withdrawals from Coalbed Wells

    Gasoline and Diesel Fuel Update (EIA)

    2002-2015 Alaska NA NA NA NA NA NA 2002-2015 Arkansas NA NA NA NA NA NA 2006-2015 California NA NA NA NA NA NA 2002-2015 Colorado NA NA NA NA NA NA 2002-2015 Federal Offshore Gulf...

  19. Onset of electron acceleration in a flare loop

    SciTech Connect (OSTI)

    Sharykin, Ivan; Liu, Siming [Key Laboratory of Dark Matter and Space Astronomy, Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing, 210008 (China); Fletcher, Lyndsay, E-mail: liusm@pmo.ac.cn [School of Physics and Astronomy, SUPA, University of Glasgow, Glasgow, G12 8QQ (United Kingdom)

    2014-09-20

    We carried out a detailed analysis of X-ray and radio observations of a simple flare loop that occurred on 2002 August 12, with the impulsive hard X-ray (HXR) light curves dominated by a single pulse. The emission spectra of the early impulsive phase are consistent with an isothermal model in the coronal loop with a temperature reaching several keV. A power-law high-energy spectral tail is evident near the HXR peak time, in accordance with the appearance of footpoints at high energies, and is well correlated with the radio emission. The energy content of the thermal component keeps increasing gradually after the disappearance of this nonthermal component. These results suggest that electron acceleration only covers the central period of a longer and more gradual energy dissipation process and that the electron transport within the loop plays a crucial role in the formation of the inferred power-law electron distribution. The spectral index of power-law photons shows a very gradual evolution, indicating that the electron accelerator is in a quasi-steady state, which is confirmed by radio observations. These results are consistent with the theory of stochastic electron acceleration from a thermal background. Advanced modeling with coupled electron acceleration and spatial transport processes is needed to explain these observations more quantitatively, which may reveal the dependence of the electron acceleration on the spatial structure of the acceleration region.

  20. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0

  1. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  2. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0

  3. Illinois Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  4. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  5. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  6. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0

  7. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  8. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  9. Exploring the blazar zone in high-energy flares of FSRQs

    SciTech Connect (OSTI)

    Pacciani, L.; Donnarumma, I.; Tavecchio, F.; Stamerra, A.; Carrasco, L.; Recillas, E.; Porras, A.; Uemura, M.

    2014-07-20

    The gamma-ray emission offers a powerful diagnostic tool to probe jets and their surroundings in flat-spectrum radio quasars (FSRQs). In particular, sources emitting at high energies (>10 GeV) give us the strongest constraints. This motivates us to start a systematic study of flares with bright emission above 10 GeV, examining archival data of the Fermi-LAT gamma-ray telescope. At the same time, we began to trigger Target of Opportunity observations to the Swift observatory at the occurrence of high-energy flares, obtaining a wide coverage of the spectral energy distributions (SEDs) for several FSRQs during flares. Among others, we investigate the SED of a peculiar flare of 3C 454.3, showing a remarkably hard gamma-ray spectrum, quite different from the brightest flares of this source, and a bright flare of CTA 102. We modeled the SED in the framework of the one-zone leptonic model, using also archival optical spectroscopic data to derive the luminosity of the broad lines and thus estimate the disk luminosity, from which the structural parameters of the FSRQ nucleus can be inferred. The model allowed us to evaluate the magnetic field intensity in the blazar zone and to locate the emitting region of gamma-rays in the particular case in which gamma-ray spectra show neither absorption from the broad-line region (BLR) nor the Klein-Nishina curvature expected in leptonic models assuming the BLR as the source of seed photons for the External Compton scenario. For FSRQs bright above 10 GeV, we were able to identify short periods lasting less than one day characterized by a high rate of high-energy gamma-rays and hard gamma-ray spectra. We discussed the observed spectra and variability timescales in terms of injection and cooling of energetic particles, arguing that these flares could be triggered by magnetic reconnection events or turbulence in the flow.

  10. RADIOACTIVE POSITRON EMITTER PRODUCTION BY ENERGETIC ALPHA PARTICLES IN SOLAR FLARES

    SciTech Connect (OSTI)

    Murphy, R. J. [Code 7650, Naval Research Laboratory, Washington, DC 20375 (United States); Kozlovsky, B. [Tel Aviv University, Tel Aviv (Israel); Share, G. H., E-mail: murphy@ssd5.nrl.navy.mil, E-mail: benz@wise.tau.ac.il, E-mail: share@astro.umd.edu [University of Maryland, College Park, MD 20742 (United States)

    2015-01-01

    Measurements of the 0.511 MeV positron-annihilation line from solar flares are used to explore the flare process in general and ion acceleration in particular. In flares, positrons are produced primarily by the decay of radioactive positron-emitting isotopes resulting from nuclear interactions of flare-accelerated ions with ambient solar material. Kozlovsky et al. provided ion-energy-dependent production cross sections for 67 positron emitters evaluated from their threshold energies (some <1 MeV nucleon{sup 1}) to a GeV nucleon{sup 1}, incorporating them into a computer code for calculating positron-emitter production. Adequate cross-section measurements were available for proton reactions, but not for ?-particle reactions where only crude estimates were possible. Here we re-evaluate the ?-particle cross sections using new measurements and nuclear reaction codes. In typical large gamma-ray line flares, proton reactions dominate positron production, but ?-particle reactions will dominate for steeper accelerated-ion spectra because of their relatively low threshold energies. With the accelerated-{sup 3}He reactions added previously, the code is now reliable for calculating positron production from any distribution of accelerated-ion energies, not just those of typical flares. We have made the code available in the online version of the Journal. We investigate which reactions, projectiles, and ion energies contribute to positron production. We calculate ratios of the annihilation-line fluence to fluences of other gamma-ray lines. Such ratios can be used in interpreting flare data and in determining which nuclear radiation is most sensitive for revealing acceleration of low-energy ions at the Sun.

  11. TEMPERATURE AND ELECTRON DENSITY DIAGNOSTICS OF A CANDLE-FLAME-SHAPED FLARE

    SciTech Connect (OSTI)

    Guidoni, S. E.; Plowman, J. E.

    2015-02-10

    Candle-flame-shaped flares are archetypical structures that provide indirect evidence of magnetic reconnection. A flare resembling Tsuneta's famous 1992 candle-flame flare occurred on 2011 January 28; we present its temperature and electron density diagnostics. This flare was observed with Solar Dynamics Observatory/Atmospheric Imaging Assembly (SDO/AIA), Hinode/X-Ray Telescope (XRT), and Solar Terrestrial Relations Observatory Ahead (STEREO-A)/Extreme Ultraviolet Imager, resulting in high-resolution, broad temperature coverage, and stereoscopic views of this iconic structure. The high-temperature images reveal a brightening that grows in size to form a tower-like structure at the top of the posteruption flare arcade, a feature that has been observed in other long-duration events. Despite the extensive work on the standard reconnection scenario, there is no complete agreement among models regarding the nature of this high-intensity elongated structure. Electron density maps reveal that reconnected loops that are successively connected at their tops to the tower develop a density asymmetry of about a factor of two between the two legs, giving the appearance of ''half-loops''. We calculate average temperatures with a new fast differential emission measure (DEM) method that uses SDO/AIA data and analyze the heating and cooling of salient features of the flare. Using STEREO observations, we show that the tower and the half-loop brightenings are not a line-of-sight projection effect of the type studied by Forbes and Acton. This conclusion opens the door for physics-based explanations of these puzzling, recurrent solar flare features, previously attributed to projection effects. We corroborate the results of our DEM analysis by comparing them with temperature analyses from Hinode/XRT.

  12. OPTICAL SPECTRAL OBSERVATIONS OF A FLICKERING WHITE-LIGHT KERNEL IN A C1 SOLAR FLARE

    SciTech Connect (OSTI)

    Kowalski, Adam F.; Cauzzi, Gianna; Fletcher, Lyndsay

    2015-01-10

    We analyze optical spectra of a two-ribbon, long-duration C1.1 flare that occurred on 2011 August 18 within AR 11271 (SOL2011-08-18T15:15). The impulsive phase of the flare was observed with a comprehensive set of space-borne and ground-based instruments, which provide a range of unique diagnostics of the lower flaring atmosphere. Here we report the detection of enhanced continuum emission, observed in low-resolution spectra from 3600 to 4550 acquired with the Horizontal Spectrograph at the Dunn Solar Telescope. A small, ?0.''5 (10{sup 15}cm{sup 2}) penumbral/umbral kernel brightens repeatedly in the optical continuum and chromospheric emission lines, similar to the temporal characteristics of the hard X-ray variation as detected by the Gamma-ray Burst Monitor on the Fermi spacecraft. Radiative-hydrodynamic flare models that employ a nonthermal electron beam energy flux high enough to produce the optical contrast in our flare spectra would predict a large Balmer jump in emission, indicative of hydrogen recombination radiation from the upper flare chromosphere. However, we find no evidence of such a Balmer jump in the bluemost spectral region of the continuum excess. Just redward of the expected Balmer jump, we find evidence of a ''blue continuum bump'' in the excess emission which may be indicative of the merging of the higher order Balmer lines. The large number of observational constraints provides a springboard for modeling the blue/optical emission for this particular flare with radiative-hydrodynamic codes, which are necessary to understand the opacity effects for the continuum and emission line radiation at these wavelengths.

  13. CONTINUUM CONTRIBUTIONS TO THE SDO/AIA PASSBANDS DURING SOLAR FLARES

    SciTech Connect (OSTI)

    Milligan, Ryan O.; McElroy, Sarah A.

    2013-11-01

    Data from the Multiple EUV Grating Spectrograph component of the Extreme-ultraviolet Variability Experiment (EVE) on board the Solar Dynamics Observatory (SDO) were used to quantify the contribution of continuum emission to each of the extreme ultraviolet (EUV) channels of the Atmospheric Imaging Assembly (AIA), also on SDO, during an X-class solar flare that occurred on 2011 February 15. Both the pre-flare-subtracted EVE spectra and fits to the associated free-free continuum were convolved with the AIA response functions of the seven EUV passbands at 10 s cadence throughout the course of the flare. It was found that 10%-25% of the total emission in the 94 , 131 , 193 , and 335 passbands throughout the main phase of the flare was due to free-free emission. Reliable measurements could not be made for the 171 channel, while the continuum contribution to the 304 channel was negligible due to the presence of the strong He II emission line. Up to 50% of the emission in the 211 channel was found to be due to free-free emission around the peak of the flare, while an additional 20% was due to the recombination continuum of He II. The analysis was extended to a number of M- and X-class flares and it was found that the level of free-free emission contributing to both the 171 and 211 passbands increased with increasing GOES class. These results suggest that the amount of continuum emission that contributes to AIA observations during flares is more significant than stated in previous studies which used synthetic, rather than observed, spectra. These findings highlight the importance of spectroscopic observations carried out in conjunction with those from imaging instruments so that the data are interpreted correctly.

  14. Alabama State Offshore Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    From Gas Wells 109,214 101,487 84,270 87,398 75,660 70,827 1987-2014 From Shale Gas Wells 0 0 2012-2014 From Coalbed Wells 0 0 2012-2014 Repressuring 0 NA NA NA 2011-2014 Vented and Flared 523 531 478 NA NA NA 1992-2014 Nonhydrocarbon Gases Removed 7,419 6,218 5,142 NA NA NA 1992-2014 Marketed Production 101,272 94,738 78,649 87,398 75,660 70,827 1992-2014 Dry Production 83,420 67,106 2012

  15. OBSERVATION OF HEATING BY FLARE-ACCELERATED ELECTRONS IN A SOLAR CORONAL MASS EJECTION

    SciTech Connect (OSTI)

    Glesener, Lindsay; Bain, Hazel M.; Krucker, Sm; Lin, Robert P.

    2013-12-20

    We report a Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) observation of flare-accelerated electrons in the core of a coronal mass ejection (CME) and examine their role in heating the CME. Previous CME observations have revealed remarkably high thermal energies that can far surpass the CME's kinetic energy. A joint observation by RHESSI and the Atmospheric Imaging Assembly of a partly occulted flare on 2010 November 3 allows us to test the hypothesis that this excess energy is collisionally deposited by flare-accelerated electrons. Extreme ultraviolet (EUV) images show an ejection forming the CME core and sheath, with isothermal multifilter analysis revealing temperatures of ?11MK in the core. RHESSI images reveal a large (?100 50 arcsec{sup 2}) hard X-ray (HXR) source matching the location, shape, and evolution of the EUV plasma, indicating that the emerging CME is filled with flare-accelerated electrons. The time derivative of the EUV emission matches the HXR light curve (similar to the Neupert effect observed in soft and HXR time profiles), directly linking the CME temperature increase with the nonthermal electron energy loss, while HXR spectroscopy demonstrates that the nonthermal electrons contain enough energy to heat the CME. This is the most direct observation to date of flare-accelerated electrons heating a CME, emphasizing the close relationship of the two in solar eruptive events.

  16. MAGNETIC NONPOTENTIALITY IN PHOTOSPHERIC ACTIVE REGIONS AS A PREDICTOR OF SOLAR FLARES

    SciTech Connect (OSTI)

    Yang Xiao; Lin Ganghua; Zhang Hongqi; Mao Xinjie

    2013-09-10

    Based on several magnetic nonpotentiality parameters obtained from the vector photospheric active region magnetograms obtained with the Solar Magnetic Field Telescope at the Huairou Solar Observing Station over two solar cycles, a machine learning model has been constructed to predict the occurrence of flares in the corresponding active region within a certain time window. The Support Vector Classifier, a widely used general classifier, is applied to build and test the prediction models. Several classical verification measures are adopted to assess the quality of the predictions. We investigate different flare levels within various time windows, and thus it is possible to estimate the rough classes and erupting times of flares for particular active regions. Several combinations of predictors have been tested in the experiments. The True Skill Statistics are higher than 0.36 in 97% of cases and the Heidke Skill Scores range from 0.23 to 0.48. The predictors derived from longitudinal magnetic fields do perform well, however, they are less sensitive in predicting large flares. Employing the nonpotentiality predictors from vector fields improves the performance of predicting large flares of magnitude {>=}M5.0 and {>=}X1.0.

  17. Sulfur dioxide gas detection with Na/sub 2/SO/sub 4/-Li/sub 2/SO/sub 4/-Y/sub 2/(SO/sub 4/)/sub 3/-SiO/sub 2/ solid electrolyte by a solid reference electrode method

    SciTech Connect (OSTI)

    Imanaka, N.; Yamaguchi, Y.; Adachi, G.; Shiokawa, J.

    1987-03-01

    The electromotive force (EMF) measurement for a Na/sub 2/SO/sub 4/Li/sub 2/SO/sub 4/-Y/sub 2/(SO/sub 4/)/sub 3/-SiO/sub 2/ solid electrolyte was performed both with NiSO/sub 4/-NiO and CoSO/sub 4/-Co/sub 3/O/sub 4/ solid reference SO/sub 2/ electrodes. The measured EMF coincided well with the calculated EMF for a sulfur dioxide gas concentration from 30 ppm to 1% at 973 K. Good agreement between the measured and calculated EMF was also obtained for the SO/sub 2/ gas content from 100 ppm to 1%, at 923 K with the NiSO/sub 4/-NiO electrode.

  18. Enhanced ferroelectric properties and thermal stability of nonstoichiometric 0.92(Na{sub 0.5}Bi{sub 0.5})TiO{sub 3}-0.08(K{sub 0.5}Bi{sub 0.5})TiO{sub 3} single crystals

    SciTech Connect (OSTI)

    Zhang, Haiwu E-mail: hsluo@mail.sic.ac.cn; Chen, Chao; Deng, Hao; Li, Long; Graduate University of Chinese Academy of Sciences, Beijing 100049 ; Zhao, Xiangyong; Lin, Di; Li, Xiaobing; Ren, Bo; Luo, Haosu E-mail: hsluo@mail.sic.ac.cn; Yan, Jun

    2013-11-18

    Bi deficient, Mn doped 0.92(Na{sub 0.5}Bi{sub 0.5})TiO{sub 3}-0.08(K{sub 0.5}Bi{sub 0.5})TiO{sub 3} single crystals were grown by carefully controlled top-seeded solution growth method. Local structures were investigated by transmission electron microscopy. The site occupation and valence state of manganese were characterized by electron paramagnetic resonance spectrum. The leakage current density in the as-grown single crystals is effectively depressed. The introduced defect complexes suppress the temperature induced phase transformation, increasing the depolarization temperature (165?C) and thermal stability of ferroelectric properties.

  19. Large piezoelectricity in Pb-free 0.96(K{sub 0.5}Na{sub 0.5}){sub 0.95}Li{sub 0.05}Nb{sub 0.93}Sb{sub 0.07}O{sub 3}?0.04BaZrO{sub 3} ceramic: A perspective from microstructure

    SciTech Connect (OSTI)

    Gao, Jinghui Li, Huiying; Zhong, Lisheng; Li, Shengtao; Hao, Yanshuang; Ren, Shuai Fang, Minxia; Ren, Xiaobing; Kimoto, Takayoshi; Wang, Yu

    2015-02-28

    We employ transmission electron microscopy to explore the reason for large piezoelectricity (d{sub 33}?400pC/N) in a Pb-free 0.96(K{sub 0.5}Na{sub 0.5}){sub 0.95}Li{sub 0.05}Nb{sub 0.93}Sb{sub 0.07}O{sub 3} ?0.04BaZrO{sub 3} ceramic from microstructure. The result shows that the high piezoelectricity corresponds to a miniaturized nanodomain configuration in a domain hierarchy. The nanodomains disappear on heating accompanied by a reduction in d{sub 33} value. Further convergent beam electron diffraction study reveals a coexistence of tetragonal and orthorhombic phase, which indicates that large piezoelectricity of KNLNS{sub 0.07}-BZ may stem from easy polarization rotation due to low polarization anisotropy on the tetragonal-orthorhombic phase boundary.

  20. Alkali-metal/alkaline-earth-metal fluorine beryllium borate NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} with large nonlinear optical properties in the deep-ultraviolet region

    SciTech Connect (OSTI)

    Reshak, A. H.; Huang, Hongwei; Kamarudin, H.; Auluck, S.

    2015-02-28

    The linear optical response and second harmonic generation (SHG) in alkali-metal/alkaline-earth-metal fluorine beryllium borate NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} are investigated by means of density functional theory. Calculations are performed using four types of exchange correlations: Ceperley-Alder local density approximation, Perdew Burke and Ernzerhof general gradient approximation, Engel-Vosko generalized gradient approximation, and the recently modified Becke-Johnson potential (mBJ). The mBJ approach brings the calculated band gap (7.20?eV) in excellent agreement with the experimental one (7.28?eV). The calculated values of the uniaxial anisotropy ??=?0.076 and the birefringence ?n(0)=0.052 indicate considerable anisotropy in the linear optical properties, which makes it favorable for the second harmonic generation. The dominant component of the second harmonic generation is ?{sub 111}{sup (2)}(?). The value of |?{sub 111}{sup (2)}(?)| is about 1.2?pm/V at ??=?1064?nm in agreement with previous calculations. To analyze the origin of the high SHG of NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} single crystals, we have correlated the features of |?{sub 111}{sup (2)}(?)| spectra with the features of ?{sub 2}(?) spectra as a function of ?/2 and ?. From the calculated dominant component |?{sub 111}{sup (2)}(?)|, we find that the microscopic first hyperpolarizability, ?{sub 111}, the vector components along the dipole moment direction is 0.5??10{sup ?30} esu at static limit and 0.6??10{sup ?30} esu at ??=?1064?nm.

  1. CLUSTERS OF SMALL ERUPTIVE FLARES PRODUCED BY MAGNETIC RECONNECTION IN THE SUN

    SciTech Connect (OSTI)

    Archontis, V.; Hansteen, V.

    2014-06-10

    We report on the formation of small solar flares produced by patchy magnetic reconnection between interacting magnetic loops. A three-dimensional (3D) magnetohydrodynamic (MHD) numerical experiment was performed, where a uniform magnetic flux sheet was injected into a fully developed convective layer. The gradual emergence of the field into the solar atmosphere results in a network of magnetic loops, which interact dynamically forming current layers at their interfaces. The formation and ejection of plasmoids out of the current layers leads to patchy reconnection and the spontaneous formation of several small (size ?1-2 Mm) flares. We find that these flares are short-lived (30 s3 minutes) bursts of energy in the range O(10{sup 25}-10{sup 27}) erg, which is basically the nanoflare-microflare range. Their persistent formation and co-operative action and evolution leads to recurrent emission of fast EUV/X-ray jets and considerable plasma heating in the active corona.

  2. Gamma-ray flares in the Crab Nebula: A case of relativistic reconnection?

    SciTech Connect (OSTI)

    Cerutti, B.; Werner, G. R. Uzdensky, D. A.; Begelman, M. C.

    2014-05-15

    The Crab Nebula was formed after the collapse of a massive star about a thousand years ago, leaving behind a pulsar that inflates a bubble of ultra-relativistic electron-positron pairs permeated with magnetic field. The observation of brief but bright flares of energetic gamma rays suggests that pairs are accelerated to PeV energies within a few days; such rapid acceleration cannot be driven by shocks. Here, it is argued that the flares may be the smoking gun of magnetic dissipation in the Nebula. Using 2D and 3D particle-in-cell simulations, it is shown that the observations are consistent with relativistic magnetic reconnection, where pairs are subject to strong radiative cooling. The Crab flares may highlight the importance of relativistic magnetic reconnection in astrophysical sources.

  3. MAGNETIC ENERGY PARTITION BETWEEN THE CORONAL MASS EJECTION AND FLARE FROM AR 11283

    SciTech Connect (OSTI)

    Feng, L.; Li, Y. P.; Gan, W. Q.; Wiegelmann, T.; Inhester, B.; Su, Y.; Sun, X. D.

    2013-03-01

    On 2011 September 6, an X-class flare and a halo coronal mass ejection (CME) were observed from Earth erupting from the same active region AR 11283. The magnetic energy partition between them has been investigated. SDO/HMI vector magnetograms were used to obtain the coronal magnetic field using the nonlinear force-free field (NLFFF) extrapolation method. The free magnetic energies before and after the flare were calculated to estimate the released energy available to power the flare and the CME. For the flare energetics, thermal and nonthermal energies were derived using the RHESSI and GOES data. To obtain the radiative output, SDO/EVE data in the 0.1-37 nm waveband were utilized. We have reconstructed the three-dimensional (3D) periphery of the CME from the coronagraph images observed by STEREO-A, B, and SOHO. The mass calculations were then based on a more precise Thomson-scattering geometry. The subsequent estimate of the kinetic and potential energies of the CME took advantage of the more accurate mass, and the height and speed in a 3D frame. The released free magnetic energy resulting from the NLFFF model is about 6.4 Multiplication-Sign 10{sup 31} erg, which has a possible upper limit of 1.8 Multiplication-Sign 10{sup 32} erg. The thermal and nonthermal energies are lower than the radiative output of 2.2 Multiplication-Sign 10{sup 31} erg from SDO/EVE for this event. The total radiation covering the whole solar spectrum is probably a few times larger. The sum of the kinetic and potential energy of the CME could go up to 6.5 Multiplication-Sign 10{sup 31} erg. Therefore, the free energy is able to power the flare and the CME in AR 11283. Within the uncertainty, the flare and the CME may consume a similar amount of free energy.

  4. THE TIDAL DISRUPTION OF GIANT STARS AND THEIR CONTRIBUTION TO THE FLARING SUPERMASSIVE BLACK HOLE POPULATION

    SciTech Connect (OSTI)

    MacLeod, Morgan; Guillochon, James; Ramirez-Ruiz, Enrico E-mail: jfg@ucolick.org

    2012-10-01

    Sun-like stars are thought to be regularly disrupted by supermassive black holes (SMBHs) within galactic nuclei. Yet, as stars evolve off the main sequence their vulnerability to tidal disruption increases drastically as they develop a bifurcated structure consisting of a dense core and a tenuous envelope. Here we present the first hydrodynamic simulations of the tidal disruption of giant stars and show that the core has a substantial influence on the star's ability to survive the encounter. Stars with more massive cores retain large fractions of their envelope mass, even in deep encounters. Accretion flares resulting from the disruption of giant stars should last for tens to hundreds of years. Their characteristic signature in transient searches would not be the t {sup -5/3} decay typically associated with tidal disruption events, but a correlated rise over many orders of magnitude in brightness on timescales of months to years. We calculate the relative disruption rates of stars of varying evolutionary stages in typical galactic centers, then use our results to produce Monte Carlo realizations of the expected flaring event populations. We find that the demographics of tidal disruption flares are strongly dependent on both stellar and black hole mass, especially near the limiting SMBH mass scale of {approx}10{sup 8} M{sub Sun }. At this black hole mass, we predict a sharp transition in the SMBH flaring diet beyond which all observable disruptions arise from evolved stars, accompanied by a dramatic cutoff in the overall tidal disruption flaring rate. Black holes less massive than this limiting mass scale will show observable flares from both main-sequence and evolved stars, with giants contributing up to 10% of the event rate. The relative fractions of stars disrupted at different evolutionary states can constrain the properties and distributions of stars in galactic nuclei other than our own.

  5. RHESSI AND TRACE OBSERVATIONS OF MULTIPLE FLARE ACTIVITY IN AR 10656 AND ASSOCIATED FILAMENT ERUPTION

    SciTech Connect (OSTI)

    Joshi, Bhuwan; Kushwaha, Upendra; Cho, K.-S.; Veronig, Astrid M.

    2013-07-01

    We present Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) and Transition Region and Coronal Explorer (TRACE) observations of multiple flare activity that occurred in the NOAA active region 10656 over a period of 2 hr on 2004 August 18. Out of four successive flares, three were class C events, and the final event was a major X1.8 solar eruptive flare. The activities during the pre-eruption phase, i.e., before the X1.8 flare, are characterized by three localized episodes of energy release occurring in the vicinity of a filament that produces intense heating along with non-thermal emission. A few minutes before the eruption, the filament undergoes an activation phase during which it slowly rises with a speed of {approx}12 km s{sup -1}. The filament eruption is accompanied by an X1.8 flare, during which multiple hard X-ray (HXR) bursts are observed up to 100-300 keV energies. We observe a bright and elongated coronal structure simultaneously in E(UV) and 50-100 keV HXR images underneath the expanding filament during the period of HXR bursts, which provides strong evidence for ongoing magnetic reconnection. This phase is accompanied by very high plasma temperatures of {approx}31 MK, followed by the detachment of the prominence from the solar source region. From the location, timing, strength, and spectrum of HXR emission, we conclude that the prominence eruption is driven by the distinct events of magnetic reconnection occurring in the current sheet below the erupting prominence. These multi-wavelength observations also suggest that the localized magnetic reconnections associated with different evolutionary stages of the filament in the pre-eruption phase play an important role in destabilizing the active-region filament through the tether-cutting process, leading to large-scale eruption and X-class flare.

  6. THE 2014 MARCH 29 X-FLARE: SUBARCSECOND RESOLUTION OBSERVATIONS OF Fe XXI ?1354.1

    SciTech Connect (OSTI)

    Young, Peter R.; Tian, Hui; Jaeggli, Sarah

    2015-02-01

    The Interface Region Imaging Spectrometer (IRIS) is the first solar instrument to observe ?10 MK plasma at subarcsecond spatial resolution through imaging spectroscopy of the Fe XXI ?1354.1 forbidden line. IRIS observations of the X1 class flare that occurred on 2014 March 29 at 17:48 UT reveal Fe XXI emission from both the flare ribbons and the post-flare loop arcade. Fe XXI appears at all of the chromospheric ribbon sites, although typically with a delay of one raster (75s) and sometimes offset by up to 1''. 100-200 km s{sup 1} blue-shifts are found at the brightest ribbons, suggesting hot plasma upflow into the corona. The Fe XXI ribbon emission is compact with a spatial extent of <2'', and can extend beyond the chromospheric ribbon locations. Examples are found of both decreasing and increasing blue-shift in the direction away from the ribbon locations, and blue-shifts were present for at least sixminutes after the flare peak. The post-flare loop arcade, seen in Atmospheric Imaging Assembly 131 filtergram images that are dominated by Fe XXI, exhibited bright loop-tops with an asymmetric intensity distribution. The sizes of the loop-tops are resolved by IRIS at ?1'', and line widths in the loop-tops are not broader than in the loop-legs suggesting the loop-tops are not sites of enhanced turbulence. Line-of-sight speeds in the loop arcade are typically <10 km s{sup 1}, and mean non-thermal motions fall from 43 km s{sup 1} at the flare peak to 26 km s{sup 1} six minutes later. If the average velocity in the loop arcade is assumed to be at rest, then it implies a new reference wavelength for the Fe XXI line of 1354.106 0.023 .

  7. Gamma-Ray Observations of a Giant Flare From the Magnetar Sgr 1806-20

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Gamma-Ray Observations of a Giant Flare From the Magnetar Sgr 1806-20 Citation Details In-Document Search Title: Gamma-Ray Observations of a Giant Flare From the Magnetar Sgr 1806-20 Magnetars comprise two classes of rotating neutron stars (Soft Gamma Repeaters (SGRs) and Anomalous X-ray Pulsars), whose X-ray emission is powered by an ultrastrong magnetic field, B {approx} 10{sup 15} G. Occasionally SGRs enter into active episodes producing many short

  8. 1 Hz FLARING IN SAX J1808.4-3658: FLOW INSTABILITIES NEAR THE PROPELLER STAGE

    SciTech Connect (OSTI)

    Patruno, Alessandro; Watts, Anna; Klein Wolt, Marc; Wijnands, Rudy; Van der Klis, Michiel

    2009-12-20

    We present a simultaneous periodic and aperiodic timing study of the accreting millisecond X-ray pulsar SAX J1808.4-3658. We analyze five outbursts of the source and for the first time provide a full and systematic investigation of the enigmatic phenomenon of the 1 Hz flares observed during the final stages of some of the outbursts. We show that links between pulsations and 1 Hz flares might exist, and suggest that they are related with hydrodynamic disk instabilities that are triggered close to the disk-magnetosphere boundary layer when the system is entering the propeller regime.

  9. Federal Acquisition Regulation Clause Usage Guide

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    Development Contracts. NA NA NA NA NA NA NA NA NA NA NA NA NA 52.232-3 Payments under Personal Service Contracts. NA NA A A NA NA A NA NA NA NA NA A 52.232-4 Payments under...

  10. THE 5 GHz ARECIBO SEARCH FOR RADIO FLARES FROM ULTRACOOL DWARFS

    SciTech Connect (OSTI)

    Route, Matthew; Wolszczan, Alexander E-mail: alex@astro.psu.edu

    2013-08-10

    We present the results of a 4.75 GHz survey of 33 brown dwarfs and one young exoplanetary system for flaring radio emission, conducted with the 305 m Arecibo radio telescope. The goal of this program was to detect and characterize the magnetic fields of objects cooler than spectral type L3.5, the coolest brown dwarf detected prior to our survey. We have also attempted to detect flaring radio emission from the HR 8799 planetary system, guided by theoretical work indicating that hot, massive exoplanets may have strong magnetic fields capable of generating radio emission at GHz frequencies. We have detected and confirmed radio flares from the T6.5 dwarf 2MASS J10475385+2124234. This detection dramatically extends the temperature range over which brown dwarfs appear to be at least sporadic radio-emitters, from 1900 K (L3.5) down to 900 K (T6.5). It also demonstrates that the utility of radio detection as a unique tool to study the magnetic fields of substellar objects extends to the coolest dwarfs, and, plausibly to hot, massive exoplanets. We have also identified a single, 3.6{sigma} flare from the L1 dwarf, 2MASS J1439284+192915. This detection is tentative and requires confirmation by additional monitoring observations.

  11. NO FLARES FROM GAMMA-RAY BURST AFTERGLOW BLAST WAVES ENCOUNTERING SUDDEN CIRCUMBURST DENSITY CHANGE

    SciTech Connect (OSTI)

    Gat, Ilana; Van Eerten, Hendrik; MacFadyen, Andrew [Center for Cosmology and Particle Physics, Physics Department, New York University, New York, NY 10003 (United States)

    2013-08-10

    Afterglows of gamma-ray bursts are observed to produce light curves with the flux following power-law evolution in time. However, recent observations reveal bright flares at times on the order of minutes to days. One proposed explanation for these flares is the interaction of a relativistic blast wave with a circumburst density transition. In this paper, we model this type of interaction computationally in one and two dimensions, using a relativistic hydrodynamics code with adaptive mesh refinement called RAM, and analytically in one dimension. We simulate a blast wave traveling in a stellar wind environment that encounters a sudden change in density, followed by a homogeneous medium, and compute the observed radiation using a synchrotron model. We show that flares are not observable for an encounter with a sudden density increase, such as a wind termination shock, nor for an encounter with a sudden density decrease. Furthermore, by extending our analysis to two dimensions, we are able to resolve the spreading, collimation, and edge effects of the blast wave as it encounters the change in circumburst medium. In all cases considered in this paper, we find that a flare will not be observed for any of the density changes studied.

  12. IMPULSIVE ACCELERATION OF CORONAL MASS EJECTIONS. II. RELATION TO SOFT X-RAY FLARES AND FILAMENT ERUPTIONS

    SciTech Connect (OSTI)

    Bein, B. M.; Berkebile-Stoiser, S.; Veronig, A. M.; Temmer, M.; Vrsnak, B.

    2012-08-10

    Using high time cadence images from the STEREO EUVI, COR1, and COR2 instruments, we derived detailed kinematics of the main acceleration stage for a sample of 95 coronal mass ejections (CMEs) in comparison with associated flares and filament eruptions. We found that CMEs associated with flares reveal on average significantly higher peak accelerations and lower acceleration phase durations, initiation heights, and heights, at which they reach their peak velocities and peak accelerations. This means that CMEs that are associated with flares are characterized by higher and more impulsive accelerations and originate from lower in the corona where the magnetic field is stronger. For CMEs that are associated with filament eruptions we found only for the CME peak acceleration significantly lower values than for events that were not associated with filament eruptions. The flare rise time was found to be positively correlated with the CME acceleration duration and negatively correlated with the CME peak acceleration. For the majority of the events the CME acceleration starts before the flare onset (for 75% of the events) and the CME acceleration ends after the soft X-ray (SXR) peak time (for 77% of the events). In {approx}60% of the events, the time difference between the peak time of the flare SXR flux derivative and the peak time of the CME acceleration is smaller than {+-}5 minutes, which hints at a feedback relationship between the CME acceleration and the energy release in the associated flare due to magnetic reconnection.

  13. SOLAR FLARE PREDICTION USING SDO/HMI VECTOR MAGNETIC FIELD DATA WITH A MACHINE-LEARNING ALGORITHM

    SciTech Connect (OSTI)

    Bobra, M. G.; Couvidat, S.

    2015-01-10

    We attempt to forecast M- and X-class solar flares using a machine-learning algorithm, called support vector machine (SVM), and four years of data from the Solar Dynamics Observatory's Helioseismic and Magnetic Imager, the first instrument to continuously map the full-disk photospheric vector magnetic field from space. Most flare forecasting efforts described in the literature use either line-of-sight magnetograms or a relatively small number of ground-based vector magnetograms. This is the first time a large data set of vector magnetograms has been used to forecast solar flares. We build a catalog of flaring and non-flaring active regions sampled from a database of 2071 active regions, comprised of 1.5 million active region patches of vector magnetic field data, and characterize each active region by 25 parameters. We then train and test the machine-learning algorithm and we estimate its performances using forecast verification metrics with an emphasis on the true skill statistic (TSS). We obtain relatively high TSS scores and overall predictive abilities. We surmise that this is partly due to fine-tuning the SVM for this purpose and also to an advantageous set of features that can only be calculated from vector magnetic field data. We also apply a feature selection algorithm to determine which of our 25 features are useful for discriminating between flaring and non-flaring active regions and conclude that only a handful are needed for good predictive abilities.

  14. THE MECHANISMS FOR THE ONSET AND EXPLOSIVE ERUPTION OF CORONAL MASS EJECTIONS AND ERUPTIVE FLARES

    SciTech Connect (OSTI)

    Karpen, J. T.; Antiochos, S. K.; DeVore, C. R.

    2012-11-20

    We have investigated the onset and acceleration of coronal mass ejections (CMEs) and eruptive flares. To isolate the eruption physics, our study uses the breakout model, which is insensitive to the energy buildup process leading to the eruption. We performed 2.5D simulations with adaptive mesh refinement that achieved the highest overall spatial resolution to date in a CME/eruptive flare simulation. The ultra-high resolution allows us to separate clearly the timing of the various phases of the eruption. Using new computational tools, we have determined the number and evolution of all X- and O-type nulls in the system, thereby tracking both the progress and the products of reconnection throughout the computational domain. Our results show definitively that CME onset is due to the start of fast reconnection at the breakout current sheet. Once this reconnection begins, eruption is inevitable; if this is the only reconnection in the system, however, the eruption will be slow. The explosive CME acceleration is triggered by fast reconnection at the flare current sheet. Our results indicate that the explosive eruption is caused by a resistive instability, not an ideal process. Moreover, both breakout and flare reconnections begin first as a form of weak tearing characterized by slowly evolving plasmoids, but eventually transition to a fast form with well-defined Alfvenic reconnection jets and rapid flux transfer. This transition to fast reconnection is required for both CME onset and explosive acceleration. We discuss the key implications of our results for CME/flare observations and for theories of magnetic reconnection.

  15. IMPULSIVE PHASE CORONAL HARD X-RAY SOURCES IN AN X3.9 CLASS SOLAR FLARE

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect IMPULSIVE PHASE CORONAL HARD X-RAY SOURCES IN AN X3.9 CLASS SOLAR FLARE Citation Details In-Document Search Title: IMPULSIVE PHASE CORONAL HARD X-RAY SOURCES IN AN X3.9 CLASS SOLAR FLARE We present the analysis of a pair of unusually energetic coronal hard X-ray (HXR) sources detected by the Reuven Ramaty High Energy Solar Spectroscopic Imager during the impulsive phase of an X3.9 class solar flare on 2003 November 3, which simultaneously shows two intense

  16. C:\ANNUAL\Vol2chps.v8\ANNUAL2.VP

    Gasoline and Diesel Fuel Update (EIA)

    2 1. Quantity and Average Price of Natural Gas Production in the United States, 1930-2000 (Volumes in Million Cubic Feet, Prices in Dollars per Thousand Cubic Feet) Table Year Gross Withdrawals Used for Repressuring Nonhydro- carbon Gases Removed Vented and Flared Marketed Production Extraction Loss Dry Production Average Wellhead Price of Marketed Production 1930 ...................... NA NA NA NA 1,978,911 75,140 1,903,771 0.08 1931 ...................... NA NA NA NA 1,721,902 62,288 1,659,614

  17. U.S. Natural Gas Gross Withdrawals (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 1,960,000 1,840,000 1,971,000 1,806,000 1,840,000 1,725,000 1,756,000 1,716,000 1,723,000 1,790,000 1,790,000 1,949,000 1981 1,890,000 1,702,000 1,871,000

  18. U.S. Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 18,000 16,000 17,000 16,000 17,000 16,000 17,000 17,000 17,000 15,000 17,000 18,000 1981 20,000 18,000 18,000 18,000 18,000 19,000 20,000 18,000 18,000

  19. U.S. Natural Gas Gross Withdrawals (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1973 NA NA NA NA NA NA NA NA NA NA NA NA 1974 NA NA NA NA NA NA NA NA NA NA NA NA 1975 NA NA NA NA NA NA NA NA NA NA NA NA 1976 NA NA NA NA NA NA NA NA NA NA NA NA 1977 NA NA NA NA NA NA NA NA NA NA NA NA 1978 NA NA NA NA NA NA NA NA NA NA NA NA 1979 NA NA NA NA NA NA NA NA NA NA NA NA 1980 1,960 1,840 1,971 1,806 1,840 1,725 1,756 1,716 1,723 1,790 1,790 1,949 1981 1,890 1,702 1,871 1,808 1,838 1,770 1,797 1,841 1,716 1,781 1,714 1,860 1982

  20. Department of Energy Federal Acquisition Regulation Clause Usage...

    Broader source: Energy.gov (indexed) [DOE]

    Development Contracts. NA NA A NA NA NA NA NA NA NA NA NA NA 52.232-3 Payments under Personal Service Contracts. NA NA A A NA NA A NA NA NA NA NA A 52.232-4 Payments under...

  1. A novel organicinorganic hybrid with Anderson type polyanions as building blocks: (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]6H{sub 2}O

    SciTech Connect (OSTI)

    Thabet, Safa; Ayed, Brahim; Haddad, Amor

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of a novel inorganicorganic hybrid compound based on Anderson polyoxomolybdates. ? Characterization by X-ray diffraction, IR and UVVis spectroscopies of the new compound. ? Potential applications in catalysis, biochemical analysis and electrical conductivity of the organicinorganic compound. -- Abstract: A new organicinorganic hybrid compound based on Anderson polyoxomolybdates, (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]6H{sub 2}O (1) have been isolated by the conventional solution method and characterized by single-crystal X-ray diffraction, infrared, ultraviolet spectroscopy and Thermogravimetric Analysis (TGA). This compound crystallized in the triclinic system, space group P?1, with a = 94.635(1) ?, b = 10.958(1) ?, c = 11.602(1) ?, ? = 67.525(1), ? = 71.049(1), ? = 70.124(1) and Z = 1. The crystal structures of the compounds exhibit three-dimensional supramolecular assembly based on the extensive hydrogen bonding interactions between organic cations, sodium cations, water molecules and Anderson polyoxoanions. The infrared spectrum fully confirms the X-ray crystal structure and the UV spectrum of the title compound exhibits an absorption peak at 210 nm.

  2. An analysis of lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic for efficient refrigeration and thermal energy harvesting

    SciTech Connect (OSTI)

    Vats, Gaurav; Vaish, Rahul; Bowen, Chris R.

    2014-01-07

    This article demonstrates the colossal energy harvesting capability of a lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic using the Olsen cycle. The maximum harvestable energy density estimated for this system is found to be 1523 J/L (1523 kJ/m{sup 3}) where the results are presented for extreme ambient conditions of 20–160 °C and electric fields of 0.1–4 MV/m. This estimated energy density is 1.7 times higher than the maximum reported to date for the lanthanum-doped lead zirconate titanate (thin film) system. Moreover, this study introduces a generalized and effective solid state refrigeration cycle in contrast to the ferroelectric Ericson refrigeration cycle. The cycle is based on a temperature induced polarization change on application of an unipolar electric field to ferroelectric ceramics.

  3. Effect of composition on electrical properties of lead-free Bi{sub 0.5}(Na{sub 0.80}K{sub 0.20}){sub 0.5}TiO{sub 3}-(Ba{sub 0.98}Nd{sub 0.02})TiO{sub 3} piezoelectric ceramics

    SciTech Connect (OSTI)

    Jaita, Pharatree; Watcharapasorn, Anucha; Jiansirisomboon, Sukanda

    2013-07-14

    Lead-free piezoelectric ceramics with the composition of (1-x)Bi{sub 0.5}(Na{sub 0.80}K{sub 0.20}){sub 0.5}TiO{sub 3}-x(Ba{sub 0.98}Nd{sub 0.02})TiO{sub 3} or (1-x) BNKT-xBNdT (with x = 0-0.20 mol fraction) have been synthesized by a conventional mixed-oxide method. The compositional dependence of phase structure and electrical properties of the ceramics were systemically studied. The optimum sintering temperature of all BNKT-BNdT ceramics was found to be 1125 Degree-Sign C. X-ray diffraction pattern suggested that BNdT effectively diffused into BNKT lattice during sintering to form a solid solution with a perovskite structure. Scanning electron micrographs showed a slight reduction of grain size when BNdT was added. It was found that BNKT-0.10BNdT ceramic exhibited optimum electrical properties ({epsilon}{sub r} = 1716, tan{delta} = 0.0701, T{sub c} = 327 Degree-Sign C, and d{sub 33} = 211 pC/N), suggesting that this composition has a potential to be one of a promising lead-free piezoelectric candidate for dielectric and piezoelectric applications.

  4. SUDDEN PHOTOSPHERIC MOTION AND SUNSPOT ROTATION ASSOCIATED WITH THE X2.2 FLARE ON 2011 FEBRUARY 15

    SciTech Connect (OSTI)

    Wang, Shuo; Liu, Chang; Deng, Na; Wang, Haimin

    2014-02-20

    The Helioseismic and Magnetic Imager provides 45s cadence intensity images and 720s cadence vector magnetograms. These unprecedented high-cadence and high-resolution data give us a unique opportunity to study the change of photospheric flows and sunspot rotations associated with flares. By using the differential affine velocity estimator method and the Fourier local correlation tracking method separately, we calculate velocity and vorticity of photospheric flows in the flaring NOAA AR 11158, and investigate their temporal evolution around the X2.2 flare on 2011 February 15. It is found that the shear flow around the flaring magnetic polarity inversion line exhibits a sudden decrease, and both of the two main sunspots undergo a sudden change in rotational motion during the impulsive phase of the flare. These results are discussed in the context of the Lorentz-force change that was proposed by Hudson etal. and Fisher etal. This mechanism can explain the connections between the rapid and irreversible photospheric vector magnetic field change and the observed short-term motions associated with the flare. In particular, the torque provided by the horizontal Lorentz force change agrees with what is required for the measured angular acceleration.

  5. MODELING OF GYROSYNCHROTRON RADIO EMISSION PULSATIONS PRODUCED BY MAGNETOHYDRODYNAMIC LOOP OSCILLATIONS IN SOLAR FLARES

    SciTech Connect (OSTI)

    Mossessian, George; Fleishman, Gregory D. [Center For Solar-Terrestrial Research, New Jersey Institute of Technology, Newark, NJ 07102 (United States)

    2012-04-01

    A quantitative study of the observable radio signatures of the sausage, kink, and torsional magnetohydrodynamic (MHD) oscillation modes in flaring coronal loops is performed. Considering first non-zero order effect of these various MHD oscillation modes on the radio source parameters such as magnetic field, line of sight, plasma density and temperature, electron distribution function, and the source dimensions, we compute time-dependent radio emission (spectra and light curves). The radio light curves (of both flux density and degree of polarization) at all considered radio frequencies are then quantified in both time domain (via computation of the full modulation amplitude as a function of frequency) and in Fourier domain (oscillation spectra, phases, and partial modulation amplitude) to form the signatures specific to a particular oscillation mode and/or source parameter regime. We found that the parameter regime and the involved MHD mode can indeed be distinguished using the quantitative measures derived in the modeling. We apply the developed approach to analyze radio burst recorded by Owens Valley Solar Array and report possible detection of the sausage mode oscillation in one (partly occulted) flare and kink or torsional oscillations in another flare.

  6. Energetic electron propagation in the decay phase of non-thermal flare emission

    SciTech Connect (OSTI)

    Huang, Jing; Yan, Yihua; Tsap, Yuri T.

    2014-06-01

    On the basis of the trap-plus-precipitation model, the peculiarities of non-thermal emission in the decay phase of solar flares have been considered. The calculation formulas for the escape rate of trapped electrons into the loss cone in terms of time profiles of hard X-ray (HXR) and microwave (MW) emission have been obtained. It has been found that the evolution of the spectral indices of non-thermal emission depend on the regimes of the pitch angle diffusion of trapped particles into the loss cone. The properties of non-thermal electrons related to the HXR and MW emission of the solar flare on 2004 November 3 are studied with Nobeyama Radioheliograph, Nobeyama Radio Polarimeters, RHESSI, and Geostationary Operational Environmental Satellite observations. The spectral indices of non-thermal electrons related to MW and HXR emission remained constant or decreased, while the MW escape rate as distinguished from that of the HXRs increased. This may be associated with different diffusion regimes of trapped electrons into the loss cone. New arguments in favor of an important role of the superstrong diffusion for high-energy electrons in flare coronal loops have been obtained.

  7. An Experiment to Locate the Site of TeV Flaring in M87

    SciTech Connect (OSTI)

    Harris, D.E.; /Harvard-Smithsonian Ctr. Astrophys.; Massaro, F.; /Harvard-Smithsonian Ctr. Astrophys. /KIPAC, Menlo Park /SLAC; Cheung, C.C.; /Natl. Acad. Sci. /Naval Research Lab, Wash., D.C.; Horns, D.; Raue, M.; /Hamburg U.; Stawarz, L.; /JAXA, Sagamihara /Jagiellonian U., Astron. Observ.; Wagner, S.; /Heidelberg Observ.; Colin, P.; /Munich, Max Planck Inst.; Mazin, D.; /Barcelona, IFAE; Wagner, R.; /Munich, Max Planck Inst.; Beilicke, M.; /McDonnell Ctr. Space Sci.; LeBohec, S.; Hui, M.; /Utah U.; Mukherjee, R.; /Barnard Coll.

    2012-05-18

    We describe a Chandra X-ray target-of-opportunity project designed to isolate the site of TeV flaring in the radio galaxy M87. To date, we have triggered the Chandra observations only once (2010 April) and by the time of the first of our nine observations, the TeV flare had ended. However, we found that the X-ray intensity of the unresolved nucleus was at an elevated level for our first observation. Of the more than 60 Chandra observations we have made of the M87 jet covering nine years, the nucleus was measured at a comparably high level only three times. Two of these occasions can be associated with TeV flaring, and at the time of the third event, there were no TeV monitoring activities. From the rapidity of the intensity drop of the nucleus, we infer that the size of the emitting region is of order a few light days x the unknown beaming factor; comparable to the same sort of estimate for the TeV emitting region. We also find evidence of spectral evolution in the X-ray band which seems consistent with radiative losses affecting the non-thermal population of the emitting electrons within the unresolved nucleus.

  8. MAGNETAR GIANT FLARES AND THEIR PRECURSORS-FLUX ROPE ERUPTIONS WITH CURRENT SHEETS

    SciTech Connect (OSTI)

    Yu Cong

    2013-07-10

    We propose a catastrophic magnetospheric model for magnetar precursors and their successive giant flares. Axisymmetric models of the magnetosphere, which contain both a helically twisted flux rope and a current sheet, are established based on force-free field configurations. In this model, the helically twisted flux rope would lose its equilibrium and erupt abruptly in response to the slow and quasi-static variations at the ultra-strongly magnetized neutron star's surface. In a previous model without current sheets, only one critical point exists in the flux rope equilibrium curve. New features show up in the equilibrium curves for the flux rope when current sheets appear in the magnetosphere. The causal connection between the precursor and the giant flare, as well as the temporary re-entry of the quiescent state between the precursor and the giant flare, can be naturally explained. Magnetic energy would be released during the catastrophic state transitions. The detailed energetics of the model are also discussed. The current sheet created by the catastrophic loss of equilibrium of the flux rope provides an ideal place for magnetic reconnection. We point out the importance of magnetic reconnection for further enhancement of the energy release during eruptions.

  9. A simple model of chromospheric evaporation and condensation driven conductively in a solar flare

    SciTech Connect (OSTI)

    Longcope, D. W.

    2014-11-01

    Magnetic energy released in the corona by solar flares reaches the chromosphere where it drives characteristic upflows and downflows known as evaporation and condensation. These flows are studied here for the case where energy is transported to the chromosphere by thermal conduction. An analytic model is used to develop relations by which the density and velocity of each flow can be predicted from coronal parameters including the flare's energy flux F. These relations are explored and refined using a series of numerical investigations in which the transition region (TR) is represented by a simplified density jump. The maximum evaporation velocity, for example, is well approximated by v{sub e} ? 0.38(F/?{sub co,} {sub 0}){sup 1/3}, where ?{sub co,} {sub 0} is the mass density of the pre-flare corona. This and the other relations are found to fit simulations using more realistic models of the TR both performed in this work, and taken from a variety of previously published investigations. These relations offer a novel and efficient means of simulating coronal reconnection without neglecting entirely the effects of evaporation.

  10. ON THE FLARE-INDUCED SEISMICITY IN THE ACTIVE REGION NOAA 10930 AND RELATED ENHANCEMENT OF GLOBAL WAVES IN THE SUN

    SciTech Connect (OSTI)

    Kumar, Brajesh; Venkatakrishnan, P.; Mathur, Savita; Tiwari, Sanjiv Kumar; Garcia, R. A. E-mail: pvk@prl.res.in E-mail: tiwari@mps.mpg.de

    2011-12-10

    A major flare (of class X3.4) occurred on 2006 December 13 in the active region NOAA 10930. This flare event has remained interesting to solar researchers for studies related to particle acceleration during the flare process and the reconfiguration of magnetic fields as well as fine-scale features in the active region. The energy released during flares is also known to induce acoustic oscillations in the Sun. Here, we analyze the line-of-sight velocity patterns in this active region during the X3.4 flare using the Dopplergrams obtained by the Global Oscillation Network Group (GONG) instrument. We have also analyzed the disk-integrated velocity observations of the Sun obtained by the Global Oscillation at Low Frequency (GOLF) instrument on board the Solar and Heliospheric Observatory spacecraft as well as full-disk collapsed velocity signals from GONG observations during this flare to study any possible connection between the flare-related changes seen in the local and global velocity oscillations in the Sun. We apply wavelet transform to the time series of the localized velocity oscillations as well as the global velocity oscillations in the Sun spanning the flare event. The line-of-sight velocity shows significant enhancement in some localized regions of the penumbra of this active region during the flare. The affected region is seen to be away from the locations of the flare ribbons and the hard X-ray footpoints. The sudden enhancement of this velocity seems to be caused by the Lorentz force driven by the 'magnetic jerk' in the localized penumbral region. Application of wavelet analysis to these flare-induced localized seismic signals shows significant enhancement in the high-frequency domain (5 <{nu} < 8 mHz) and a feeble enhancement in the p-mode oscillations (2 <{nu} < 5 mHz) during the flare. On the other hand, the wavelet analysis of GOLF velocity data and the full-disk collapsed GONG velocity data spanning the flare event indicates significant post-flare enhancements in the high-frequency global velocity oscillations in the Sun, as evident from the wavelet power spectrum and the corresponding scale-average variance. The present observations of the flare-induced seismic signals in the active region in context of the driving force are different as compared to previous reports on such cases. We also find indications of a connection between flare-induced localized seismic signals and the excitation of global high-frequency oscillations in the Sun.

  11. Louisiana State Offshore Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    8-2014 From Gas Wells 72,278 63,222 64,448 67,801 70,015 54,501 1978-2014 From Oil Wells 4,108 6,614 6,778 5,443 7,735 7,161 1978-2014 Repressuring 285 116 120 NA NA NA 1992-2014 Vented and Flared 215 146 149 NA NA NA 1999-2014 Nonhydrocarbon Gases Removed NA NA NA NA NA NA 2003-2014 Marketed Production 75,885 69,574 70,957 73,244 77,750 61,662 1992-2014 Dry Production 68,145 58,077 2012

  12. Photosphere emission in the X-ray flares of swift gamma-ray bursts and implications for the fireball properties

    SciTech Connect (OSTI)

    Peng, Fang-Kun; Liang, En-Wei; Xi, Shao-Qiang; Lu, Rui-Jing; Zhang, Bing [Guangxi Key Laboratory for Relativistic Astrophysics, the Department of Physics, Guangxi University, Nanning 530004 (China); Wang, Xiang-Yu [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Hou, Shu-Jin [Institute of Physics and Electronic Engineering, Nanyang Normal College, Nanyang 473061 (China); Zhang, Jin, E-mail: lew@gxu.edu.cn, E-mail: xywang@nju.edu.cn, E-mail: zhang@physics.unlv.edu [National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2014-11-10

    X-ray flares of gamma-ray bursts (GRBs) are usually observed in the soft X-ray range and the spectral coverage is limited. In this paper, we present an analysis of 32 GRB X-ray flares that are simultaneously observed by both Burst Alert Telescope and X-Ray Telescope on board the Swift mission, so that a joint spectral analysis with a wider spectral coverage is possible. Our results show that the joint spectra of 19 flares are fitted with the absorbed single power law or the Band function models. More interestingly, the joint spectra of the other 13 X-ray flares are fitted with the absorbed single power-law model plus a blackbody component. Phenomenally, the observed spectra of these 13 flares are analogous to several GRBs with a thermal component, but only with a much lower temperature of kT = 1 ? 3 keV. Assuming that the thermal emission is the photosphere emission of the GRB fireball, we derive the fireball properties of the 13 flares that have redshift measurements, such as the bulk Lorentz factor ?{sub ph} of the outflow. The derived ?{sub ph} range from 50 to 150 and a relation of ?{sub ph} to the thermal emission luminosity is found. It is consistent with the ?{sub 0} L {sub iso} relations that are derived for the prompt gamma-ray emission. We discuss the physical implications of these results within the content of jet composition and the radiation mechanism of GRBs and X-ray flares.

  13. NA 40 - Associate Administrator for Emergency Operations | National...

    National Nuclear Security Administration (NNSA)

    People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About...

  14. THERMAL CONDUCTIVITY OF AQUEOUS NaCl SOLUTIONS

    Office of Scientific and Technical Information (OSTI)

    and uti1 ization of geothermal energy, petroleum recovery, desalination of sea water, and other energy systems involving water containing dissolved salts. brines contain a...

  15. Analysis of NaOH releases for Hanford tank farms

    SciTech Connect (OSTI)

    Ryan, G.W., Westinghouse Hanford

    1996-07-25

    This document supports the development and presentation of the following accident scenario in the TWRS Final Safety Analysis Report: Caustic Spray Leak. The calculations needed to quantify the risk associated with this accident scenario are included within.

  16. Document: NA (ATTORNEY) Actionee: Dorothy Riehie -e77 Document...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    USDOE'S Hanford Site DIR DIV NAME DIR DIV NAME MGR AMRC DEP AMISE AMA EMD FMD QOD HRM SED PRO 0CC AMCP OCE Riehie, Dorothy (Actionee) AMMS ORP ISI PNSO PIC RLCI SES...

  17. News Release - Pantex repackaging final NA-01-08.PDF

    National Nuclear Security Administration (NNSA)

    NEWS MEDIA CONTACT: FOR IMMEDIATE RELEASE Lisa Cutler, 202/586-7371 Wednesday, August 29, 2001 Pantex Plant Achieves Key Safety Milestone Ahead of Schedule Washington, D.C. - The nuclear weapons dismantlement process at the Pantex Plant in Amarillo, Texas, has achieved a major safety accomplishment, the U.S. Department of Energy's National Nuclear Security Administration (NNSA) announced today. NNSA administrator John Gordon said the Pantex Plant has achieved and sustained a plutonium

  18. Office of Nuclear Material Integration (ONMI), NA-73

    National Nuclear Security Administration (NNSA)

    Energy Agency (IAEA) under International Safeguards Agreements Nuclear Materials Financial M anagement (Asset Tracking for CFO) Critical Support of Regulatory Functions ...

  19. APPENDIXN DE-NA0000622 LIST OF APPLICABLE DIRECTIVES

    National Nuclear Security Administration (NNSA)

    17 Transportation (revised 11305) 21 Financial Close-out (revised 71707) DOE Annual ... Accounting Handbook, Albuquerque Financial Service Handbook, October 2001 Center, ...

  20. DE-RP52-05NA26986

    National Nuclear Security Administration (NNSA)

    Core level testing for NSDD Core installations DE-SOL-0008449 Attachment L-2b [Submit in Volume II, TAB 1] Instructions Attachment L-2b: Note: Attachment L-2b is limited to one (1) 8 ½ x 11 page. Experiences provided must be relevant to the work that the team member will be performing under this contract. The Offeror shall explain how the work performed by the experience is relevant to the indicator. Relevance is defined by Indicator as follows: A. Relevance to indicator A. is defined as

  1. DE-RP52-05NA26986

    National Nuclear Security Administration (NNSA)

    Indicator Summary Matrix Indicator Experience 1 Experience 2 Experience 3 Experience 4 Experience 5 A. Owned and operated by third parties x x A. Integrating multiple public and private entities x x A. Remote sites that lack infrastructure x x A. Accommodating ongoing site operations x x A. Changing requirements x x A. Cultural and language-related barriers x B. Soliciting and managing foreign subcontracts for construction ensuring quality, safe work is carried out within schedule and budgetary

  2. NA 1 - Immediate Office of the Administrator | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration - Immediate Office of the Administrator | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs

  3. NA 10 - Deputy Administrator for Defense Programs | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration 0 - Deputy Administrator for Defense Programs | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo

  4. NA 15 - Assistant Deputy Administrator for Secure Transportation | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration 5 - Assistant Deputy Administrator for Secure Transportation | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters

  5. NA 20 - Deputy Administrator for Defense Nuclear Nonproliferation |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration 20 - Deputy Administrator for Defense Nuclear Nonproliferation | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets

  6. NA 30 - Deputy Administrator for Naval Reactors | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration 30 - Deputy Administrator for Naval Reactors | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery

  7. NA 40 - Associate Administrator for Emergency Operations | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration 40 - Associate Administrator for Emergency Operations | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases

  8. NA 50 - Associate Administrator for Safety, Infrastructure and Operations

    National Nuclear Security Administration (NNSA)

    | National Nuclear Security Administration 50 - Associate Administrator for Safety, Infrastructure and Operations | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony

  9. NA 70 - Associate Administrator for Defense Nuclear Security | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration 70 - Associate Administrator for Defense Nuclear Security | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters

  10. NA APM - Associate Administrator for Acquisition & Project Management |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration APM - Associate Administrator for Acquisition & Project Management | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact

  11. NA EA - Associate Administrator for External Affairs | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration EA - Associate Administrator for External Affairs | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases

  12. NA GC - Office of General Counsel | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration GC - Office of General Counsel | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for

  13. NA IM- Associate Administrator for Information Management & Chief

    National Nuclear Security Administration (NNSA)

    Information Officer | National Nuclear Security Administration IM- Associate Administrator for Information Management & Chief Information Officer | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations

  14. NA MB - Associate Administrator for Management & Budget | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration MB - Associate Administrator for Management & Budget | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press

  15. NA APM - Associate Administrator for Acquisition & Project Management...

    National Nuclear Security Administration (NNSA)

    APM - Associate Administrator for Acquisition & Project Management | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the...

  16. NA MB - Associate Administrator for Management & Budget | National...

    National Nuclear Security Administration (NNSA)

    MB - Associate Administrator for Management & Budget | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing...

  17. NA IM- Associate Administrator for Information Management & Chief...

    National Nuclear Security Administration (NNSA)

    IM- Associate Administrator for Information Management & Chief Information Officer | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission...

  18. A new Bi{sub 0.5}Na{sub 0.5}TiO{sub 3} based lead-free piezoelectric system with calculated end-member Bi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3}

    SciTech Connect (OSTI)

    Liu, Feng; Wahyudi, Olivia; Li, Yongxiang

    2014-03-21

    The phase structure, dielectric and piezoelectric properties of a new lead-free piezoelectric system (1???x)Bi{sub 0.5}Na{sub 0.5}TiO{sub 3}xBi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3} [(1???x)BNTxBZH, x?=?0, 0.01, 0.02, 0.03, and 0.04] were investigated. The structure of Bi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3} was calculated using first-principles method and (1???x)BNTxBZH ceramics were fabricated by conventional solid-state process. At room temperature, a morphotropic phase boundary (MPB) from rhombohedral to pseudocubic is identified near x?=?0.02 by the analysis of X-ray diffraction patterns. The ceramics with MPB near room temperature exhibit excellent electrical properties: the Curie temperature, maximum polarization, remnant polarization, and coercive field are 340?C, 56.3??C/cm{sup 2}, 43.5??C/cm{sup 2}, and 5.4?kV/mm, respectively, while the maximum positive bipolar strain and piezoelectric coefficient are 0.09% and 92 pC/N, respectively. In addition, a linear relationship between the MPB phase boundary composition and the calculated tetragonality of non-BNT end-member was demonstrated. Thus, this study not only shows a new BNT-based lead-free piezoelectric system but also suggest a new way to predict the composition at MPB a priori when designing new lead-free piezoelectric system.

  19. PRODUCTION OF {sup 9}Be THROUGH THE {alpha}-FUSION REACTION OF METAL-POOR COSMIC RAYS AND STELLAR FLARES

    SciTech Connect (OSTI)

    Kusakabe, Motohiko; Kawasaki, Masahiro E-mail: kawasaki@icrr.u-tokyo.ac.jp

    2013-04-10

    Spectroscopic observations of metal-poor stars have indicated possible {sup 6}Li abundances that are much larger than the primordial abundance predicted in the standard big bang nucleosynthesis model. Possible mechanisms of {sup 6}Li production in metal-poor stars include pregalactic and cosmological cosmic-ray (CR) nucleosynthesis and nucleosynthesis by flare-accelerated nuclides. We study {sup 9}Be production via two-step {alpha}-fusion reactions of CR or flare-accelerated {sup 3,4}He through {sup 6}He and {sup 6,7}Li, in pregalactic structure, intergalactic medium, and stellar surfaces. We solve transfer equations of CR or flare particles and calculate nuclear yields of {sup 6}He, {sup 6,7}Li, and {sup 9}Be taking account of probabilities of processing {sup 6}He and {sup 6,7}Li into {sup 9}Be via fusions with {alpha} particles. Yield ratios, i.e., {sup 9}Be/{sup 6}Li, are then calculated for the CR and flare nucleosynthesis models. We suggest that the future observations of {sup 9}Be in metal-poor stars may find enhanced abundances originating from metal-poor CR or flare activities.

  20. Protonation of Different Goethite Surfaces - Unified Models for NaNO3 and NaCl Media.

    SciTech Connect (OSTI)

    Lutzenkirchen, Johannes; Boily, Jean F.; Gunneriusson, Lars; Lovgren, L.; Sjojberg, S.

    2008-01-01

    Acid-base titration data for two goethites samples in sodium nitrate and sodium chloride media are discussed. The data are modelled based on various surface complexation models in the framework of the MUlti SIte Complexation (MUSIC) model. Various assumptions with respect to the goethite morphology are considered in determining the site density of the surface functional groups. The results from the various model applications are not statistically significant in terms of goodness of fit. More importantly, various published assumptions with respect to the goethite morphology (i.e. the contributions of different crystal planes and their repercussions on the overall site densities of the various surface functional groups) do not significantly affect the final model parameters. The simultaneous fit of the chloride and nitrate data results in electrolyte binding constants, which are applicable over a wide range of electrolyte concentrations including mixtures of chloride and nitrate. Model parameters for the high surface area goethite sample are in excellent agreement with parameters that were independently obtained by another group on different goethite titration data sets.

  1. A flare observed in coronal, transition region, and helium I 10830 emissions

    SciTech Connect (OSTI)

    Zeng, Zhicheng; Cao, Wenda; Qiu, Jiong; Judge, Philip G.

    2014-10-01

    On 2012 June 17, we observed the evolution of a C-class flare associated with the eruption of a filament near a large sunspot in the active region NOAA 11504. We obtained high spatial resolution filtergrams using the 1.6 m New Solar Telescope at the Big Bear Solar Observatory in broadband TiO at 706 nm (bandpass: 10 ) and He I 10830 narrow band (bandpass: 0.5 , centered 0.25 to the blue). We analyze the spatio-temporal behavior of the He I 10830 data, which were obtained over a 90''90'' field of view with a cadence of 10 s. We also analyze simultaneous data from the Atmospheric Imaging Assembly and Extreme Ultraviolet Variability Experiment instruments on board the Solar Dynamics Observatory spacecraft, and data from the Reuven Ramaty High Energy Solar Spectroscopic Imager and GOES spacecrafts. Non-thermal effects are ignored in this analysis. Several quantitative aspects of the data, as well as models derived using the '0D' enthalpy-based thermal evolution of loops model code, indicate that the triplet states of the 10830 multiplet are populated by photoionization of chromospheric plasma followed by radiative recombination. Surprisingly, the He II 304 line is reasonably well matched by standard emission measure calculations, along with the C IV emission which dominates the Atmosphere Imaging Assembly 1600 channel during flares. This work lends support to some of our previous work combining X-ray, EUV, and UV data of flares to build models of energy transport from corona to chromosphere.

  2. OFF-SITE RADIOLOGICAL SAFETY PROGRAM FOR PROJECT RULISON FLARING, PHASE I11

    Office of Legacy Management (LM)

    RADIOLOGICAL SAFETY PROGRAM FOR PROJECT RULISON FLARING, PHASE I11 F i.EMSL-LV-539-8 c by Monitoring Operations D i v i s i o n Environmental M o n i t o r i n g and Support Laboratory U. S. ENVIRONMENTAL PROTECTION AGENCY Las Vegas, Nevada Published November 1976 T h i s s u r v e i 1 lance performed under a Memorandum o f Understanding No. AT( 26-1 )-539 f o r t h e U. S. ENERGY RESEARCH AND DEVELOPMENT ADMINISTRATION , I 1 DISCLAIMER T h i s report was prepared a s a n account of work

  3. C:\ANNUAL\Vol2chps.v8\ANNUAL2.VP

    Gasoline and Diesel Fuel Update (EIA)

    Energy Information Administration / Historical Natural Gas Annual 1930 Through 2000 2 1. Quantity and Average Price of Natural Gas Production in the United States, 1930-2000 (Volumes in Million Cubic Feet, Prices in Dollars per Thousand Cubic Feet) Table Year Gross Withdrawals Used for Repressuring Nonhydro- carbon Gases Removed Vented and Flared Marketed Production Extraction Loss Dry Production Average Wellhead Price of Marketed Production 1930 ...................... NA NA NA NA 1,978,911

  4. Bright reddish-orange emission and good piezoelectric properties of Sm{sub 2}O{sub 3}-modified (K{sub 0.5}Na{sub 0.5})NbO{sub 3}-based lead-free piezoelectric ceramics

    SciTech Connect (OSTI)

    Hao, Jigong; Xu, Zhijun Chu, Ruiqing; Li, Wei; Du, Juan

    2015-05-21

    Reddish orange-emitting 0.948(K{sub 0.5}Na{sub 0.5})NbO{sub 3}-0.052LiSbO{sub 3}-xmol%Sm{sub 2}O{sub 3} (KNN-5.2LS-xSm{sub 2}O{sub 3}) lead-free piezoelectric ceramics with good piezoelectric properties were fabricated in this study, and the photoluminescence and electrical properties of the ceramics were systematically studied. Results showed that Sm{sub 2}O{sub 3} substitution into KNN-5.2LS induces a phase transition from the coexistence of orthorhombic and tetragonal phases to a pseudocubic phase and shifts the polymorphic phase transition (PPT) to below room temperature. The temperature stability and fatigue resistance of the modified ceramics were significantly improved by Sm{sub 2}O{sub 3} substitution. The KNN-5.2LS ceramic with 0.4?mol. % Sm{sub 2}O{sub 3} exhibited temperature-independent properties (25150?C), fatigue-free behavior (up to 10{sup 6} cycles), and good piezoelectric properties (d{sub 33}{sup *?}=?230?pm/V, d{sub 33}?=?176 pC/N, k{sub p}?=?35%). Studies on the photoluminescence properties of the samples showed strong reddish-orange emission upon blue light excitation; these emission intensities were strongly dependent on the doping concentration and sintering temperature. The 0.4?mol. % Sm{sub 2}O{sub 3}-modified sample exhibited temperature responses over a wide temperature range of 10443?K. The maximum sensing sensitivity of the sample was 7.5??10{sup ?4} K at 293?K, at which point PPT occurred. A relatively long decay lifetime ? of 1.271.40?ms and a large quantum yield ? of 0.170.19 were obtained from the Sm-modified samples. These results suggest that the KNN-5.2LS-xSm{sub 2}O{sub 3} system presents multifunctional properties and significant technological potential in novel multifunctional devices.

  5. Tennessee Underground Natural Gas Storage Capacity

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 2002-2015 Total Number of Existing Fields 1 1 1 1 1 1

  6. Plasma dynamics above solar flare soft x-ray loop tops

    SciTech Connect (OSTI)

    Doschek, G. A.; Warren, H. P.; McKenzie, D. E.

    2014-06-10

    We measure non-thermal motions in flare loop tops and above the loop tops using profiles of highly ionized spectral lines of Fe XXIV and Fe XXIII formed at multimillion-degree temperatures. Non-thermal motions that may be due to turbulence or multiple flow regions along the line of sight are extracted from the line profiles. The non-thermal motions are measured for four flares seen at or close to the solar limb. The profile data are obtained using the Extreme-ultraviolet Imaging Spectrometer on the Hinode spacecraft. The multimillion-degree non-thermal motions are between 20 and 60 km s{sup 1} and appear to increase with height above the loop tops. Motions determined from coronal lines (i.e., lines formed at about 1.5 MK) tend to be smaller. The multimillion-degree temperatures in the loop tops and above range from about 11 MK to 15 MK and also tend to increase with height above the bright X-ray-emitting loop tops. The non-thermal motions measured along the line of sight, as well as their apparent increase with height, are supported by Solar Dynamics Observatory Atmospheric Imaging Assembly measurements of turbulent velocities in the plane of the sky.

  7. Federal Offshore--Gulf of Mexico Natural Gas Vented and Flared (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Vented and Flared (Million Cubic Feet) Federal Offshore--Gulf of Mexico Natural Gas Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 1,994 1,804 1,837 1,504 1,798 1,541 1,890 1,954 1,742 2,018 1,823 1,711 2002 1,661 1,512 1,693 1,728 1,794 1,738 1,809 1,820 1,523 1,433 1,667 1,714 2003 1,728 1,590 1,801 1,753 1,774

  8. Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

    SciTech Connect (OSTI)

    Seaman, John

    2013-01-14

    The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittals Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

  9. THE EFFECTS OF WAVE ESCAPE ON FAST MAGNETOSONIC WAVE TURBULENCE IN SOLAR FLARES

    SciTech Connect (OSTI)

    Pongkitiwanichakul, Peera; Chandran, Benjamin D. G.; Karpen, Judith T.; DeVore, C. Richard E-mail: benjamin.chandran@unh.edu E-mail: devore@nrl.navy.mil

    2012-09-20

    One of the leading models for electron acceleration in solar flares is stochastic acceleration by weakly turbulent fast magnetosonic waves ({sup f}ast waves{sup )}. In this model, large-scale flows triggered by magnetic reconnection excite large-wavelength fast waves, and fast-wave energy then cascades from large wavelengths to small wavelengths. Electron acceleration by large-wavelength fast waves is weak, and so the model relies on the small-wavelength waves produced by the turbulent cascade. In order for the model to work, the energy cascade time for large-wavelength fast waves must be shorter than the time required for the waves to propagate out of the solar-flare acceleration region. To investigate the effects of wave escape, we solve the wave kinetic equation for fast waves in weak turbulence theory, supplemented with a homogeneous wave-loss term. We find that the amplitude of large-wavelength fast waves must exceed a minimum threshold in order for a significant fraction of the wave energy to cascade to small wavelengths before the waves leave the acceleration region. We evaluate this threshold as a function of the dominant wavelength of the fast waves that are initially excited by reconnection outflows.

  10. PROPAGATION OF ALFVENIC WAVES FROM CORONA TO CHROMOSPHERE AND CONSEQUENCES FOR SOLAR FLARES

    SciTech Connect (OSTI)

    Russell, A. J. B.; Fletcher, L.

    2013-03-10

    How do magnetohydrodynamic waves travel from the fully ionized corona, into and through the underlying partially ionized chromosphere, and what are the consequences for solar flares? To address these questions, we have developed a two-fluid model (of plasma and neutrals) and used it to perform one-dimensional simulations of Alfven waves in a solar atmosphere with realistic density and temperature structure. Studies of a range of solar features (faculae, plage, penumbra, and umbra) show that energy transmission from corona to chromosphere can exceed 20% of incident energy for wave periods of 1 s or less. Damping of waves in the chromosphere depends strongly on wave frequency: waves with periods 10 s or longer pass through the chromosphere with relatively little damping, however, for periods of 1 s or less, a substantial fraction (37%-100%) of wave energy entering the chromosphere is damped by ion-neutral friction in the mid- and upper chromosphere, with electron resistivity playing some role in the lower chromosphere and in umbras. We therefore conclude that Alfvenic waves with periods of a few seconds or less are capable of heating the chromosphere during solar flares, and speculate that they could also contribute to electron acceleration or exciting sunquakes.

  11. Alabama Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  12. Indiana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  13. South Dakota Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  14. Kansas Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    24,842 24,864 23,819 23,559 22,371 22,744 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA ...

  15. Maryland Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  16. Nevada Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  17. Virginia Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  18. Montana Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    4,941 4,756 4,573 4,827 4,568 4,681 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA 2007-2015 ...

  19. California Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    9,225 19,655 18,928 18,868 18,266 18,868 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA NA ...

  20. Illinois Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  1. New York Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  2. Kentucky Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  3. Missouri Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  4. Tennessee Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  5. Multi-wavelength study of flaring activity in BL Lac object S5 0716+714 during the 2015 outburst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chandra, Sunil; Zhang, Haocheng; Kushwaha, Pankaj; Singh, K. P.; Bottcher, M.; Kaur, Navpreet; Baliyan, K. S.

    2015-08-17

    We present a detailed investigation of the flaring activity observed from a BL Lac object, S5 0716+714 , during its brightest ever optical state in the second half of 2015 January. Observed almost simultaneously in the optical, X-rays, and γ-rays, a significant change in the degree of optical polarization (PD) and a swing in the position angle (PA) of polarization were recorded. A TeV (VHE) detection was also reported by the MAGIC consortium during this flaring episode. Two prominent sub-flares, peaking about five days apart, were seen in almost all of the energy bands. The multi-wavelength light curves, spectral energymore » distribution, and polarization are modeled using the time-dependent code developed by Zhang et al. This model assumes a straight jet threaded by large-scale helical magnetic fields taking into account the light travel time effects, incorporating synchrotron flux and polarization in 3D geometry. Furthermore, the rapid variation in PD and rotation in PA are most likely due to reconnections happening in the emission region in the jet, as suggested by the change in the ratio of toroidal to poloidal components of the magnetic field during the quiescent and flaring states.« less

  6. Magnetohydrodynamic simulation of the x2.2 solar flare on 2011 February 15. I. Comparison with the observations

    SciTech Connect (OSTI)

    Inoue, S.; Magara, T.; Choe, G. S.; Hayashi, K.; Park, Y. D.

    2014-06-20

    We performed a magnetohydrodynamic (MHD) simulation using a nonlinear force-free field (NLFFF) in solar active region 11158 to clarify the dynamics of an X2.2-class solar flare. We found that the NLFFF never shows the dramatic dynamics seen in observations, i.e., it is in a stable state against the perturbations. On the other hand, the MHD simulation shows that when the strongly twisted lines are formed at close to the neutral line, which are produced via tether-cutting reconnection in the twisted lines of the NLFFF, they consequently erupt away from the solar surface via the complicated reconnection. This result supports the argument that the strongly twisted lines formed in NLFFF via tether-cutting reconnection are responsible for breaking the force balance condition of the magnetic fields in the lower solar corona. In addition to this, the dynamical evolution of these field lines reveals that at the initial stage the spatial pattern of the footpoints caused by the reconnection of the twisted lines appropriately maps the distribution of the observed two-ribbon flares. Interestingly, after the flare, the reconnected field lines convert into a structure like the post-flare loops, which is analogous to the extreme ultraviolet image taken by the Solar Dynamics Observatory. Eventually, we found that the twisted lines exceed a critical height at which the flux tube becomes unstable to the torus instability. These results illustrate the reliability of our simulation and also provide an important relationship between flare and coronal mass ejection dynamics.

  7. LowerColoradoRiver_Comments_FutureComms.pdf

    Energy Savers [EERE]

    Remote Meter Reading (based on hourly reads) n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a Direct Load Control n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a Real time pricing n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a At the customer premises n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a At charging stations n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a

  8. SIMULATION OF DESCENDING MULTIPLE SUPRA-ARCADE RECONNECTION OUTFLOWS IN SOLAR FLARES

    SciTech Connect (OSTI)

    Cecere, M.; Schneiter, M.; Costa, A.; Elaskar, S.; Maglione, S.

    2012-11-10

    After recent Atmospheric Imaging Assembly observations by Savage, McKenzie, and Reeves, we revisit the scenario proposed by us in previous papers. We have shown that sunward, generally dark plasma features that originated above posteruption flare arcades are consistent with a scenario where plasma voids (which we identify as supra-arcade reconnection outflows, SAROs) generate the bouncing and interfering of shocks and expansion waves upstream of an initial localized deposition of energy that is collimated in the magnetic field direction. In this paper, we analyze the multiple production and interaction of SAROs and their individual structures that make them relatively stable features while moving. We compare our results with observations and with the scenarios proposed by other authors.

  9. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  10. ON THE CAUSE OF SUPRA-ARCADE DOWNFLOWS IN SOLAR FLARES

    SciTech Connect (OSTI)

    Cassak, P. A.; Shepherd, L. S.; Drake, J. F.; Gosling, J. T.; Phan, T.-D.; Shay, M. A. E-mail: lshephe1@mix.wvu.edu E-mail: Jack.Gosling@lasp.colorado.edu E-mail: shay@udel.edu

    2013-09-20

    A model of supra-arcade downflows (SADs), dark low density regions also known as tadpoles that propagate sunward during solar flares, is presented. It is argued that the regions of low density are flow channels carved by sunward-directed outflow jets from reconnection. The solar corona is stratified, so the flare site is populated by a lower density plasma than that in the underlying arcade. As the jets penetrate the arcade, they carve out regions of depleted plasma density which appear as SADs. The present interpretation differs from previous models in that reconnection is localized in space but not in time. Reconnection is continuous in time to explain why SADs are not filled in from behind as they would if they were caused by isolated descending flux tubes or the wakes behind them due to temporally bursty reconnection. Reconnection is localized in space because outflow jets in standard two-dimensional reconnection models expand in the normal (inflow) direction with distance from the reconnection site, which would not produce thin SADs as seen in observations. On the contrary, outflow jets in spatially localized three-dimensional reconnection with an out-of-plane (guide) magnetic field expand primarily in the out-of-plane direction and remain collimated in the normal direction, which is consistent with observed SADs being thin. Two-dimensional proof-of-principle simulations of reconnection with an out-of-plane (guide) magnetic field confirm the creation of SAD-like depletion regions and the necessity of density stratification. Three-dimensional simulations confirm that localized reconnection remains collimated.

  11. Word Pro - Untitled1

    Gasoline and Diesel Fuel Update (EIA)

    1 Table 6.2 Natural Gas Production, Selected Years, 1949-2011 (Billion Cubic Feet) Year Natural Gas Gross Withdrawals Repressuring Nonhydrocarbon Gases Removed Vented and Flared Marketed Production Extraction Loss 1 Dry Gas Production Natural Gas Wells Crude Oil Wells Coalbed Wells Shale Gas Wells Total 1949 4,986 2,561 NA NA 7,547 1,273 NA 854 5,420 224 5,195 1950 5,603 2,876 NA NA 8,480 1,397 NA 801 6,282 260 6,022 1955 7,842 3,878 NA NA 11,720 1,541 NA 774 9,405 377 9,029 1960 10,853 4,234 NA

  12. Louisiana Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    159,456 166,570 164,270 166,973 161,280 163,799 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA ...

  13. Colorado Natural Gas Gross Withdrawals and Production

    U.S. Energy Information Administration (EIA) Indexed Site

    39,822 143,397 138,325 144,845 139,698 141,947 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas Wells NA NA NA NA NA ...

  14. Word Pro - Untitled1

    Gasoline and Diesel Fuel Update (EIA)

    3 Table 10.2b Renewable Energy Consumption: Industrial and Transportation Sectors, Selected Years, 1949-2011 (Trillion Btu) Year Industrial Sector 1 Transportation Sector Hydro- electric Power 2 Geo- thermal 3 Solar/PV 4 Wind 5 Biomass Total Biomass Wood 6 Waste 7 Fuel Ethanol 8 Losses and Co-products 9 Total Fuel Ethanol 10 Biodiesel Total 1949 76 NA NA NA 468 NA NA NA 468 544 NA NA NA 1950 69 NA NA NA 532 NA NA NA 532 602 NA NA NA 1955 38 NA NA NA 631 NA NA NA 631 669 NA NA NA 1960 39 NA NA NA

  15. NEUTRINO-COOLED ACCRETION MODEL WITH MAGNETIC COUPLING FOR X-RAY FLARES IN GAMMA-RAY BURSTS

    SciTech Connect (OSTI)

    Luo Yang; Gu Weimin; Liu Tong; Lu Jufu, E-mail: guwm@xmu.edu.cn [Department of Astronomy and Institute of Theoretical Physics and Astrophysics, Xiamen University, Xiamen, Fujian 361005 (China)

    2013-08-20

    The neutrino-cooled accretion disk, which was proposed to work as the central engine of gamma-ray bursts, encounters difficulty in interpreting the X-ray flares after the prompt gamma-ray emission. In this paper, the magnetic coupling (MC) between the inner disk and the central black hole (BH) is taken into consideration. For mass accretion rates around 0.001 {approx} 0.1 M{sub Sun} s{sup -1}, our results show that the luminosity of neutrino annihilation can be significantly enhanced due to the coupling effects. As a consequence, after the gamma-ray emission, a remnant disk with mass M{sub disk} {approx}< 0.5 M{sub Sun} may power most of the observed X-ray flares with the rest frame duration less than 100 s. In addition, a comparison between the MC process and the Blandford-Znajek mechanism is shown on the extraction of BH rotational energy.

  16. A SEARCH FOR ENHANCED VERY HIGH ENERGY GAMMA-RAY EMISSION FROM THE 2013 MARCH CRAB NEBULA FLARE

    SciTech Connect (OSTI)

    Aliu, E.; Errando, M.; Archambault, S.; Aune, T.; Benbow, W.; Cerruti, M.; Berger, K.; Bird, R.; Bouvier, A.; Buckley, J. H.; Bugaev, V.; Byrum, K.; Chen, X.; Ciupik, L.; Connolly, M. P.; Cui, W.; Feng, Q.; Dumm, J.; Falcone, A.; Federici, S. E-mail: gtrichards@gatech.edu; and others

    2014-01-20

    In 2013 March, a flaring episode from the Crab Nebula lasting ?2 weeks was detected by Fermi-LAT (Large Area Telescope on board the Fermi Gamma-ray Space Telescope). The Very Energetic Radiation Imaging Telescope Array System (VERITAS) provides simultaneous observations throughout this period. During the flare, Fermi-LAT detected a 20 fold increase in flux above the average synchrotron flux >100MeV seen from the Crab Nebula. Simultaneous measurements with VERITAS are consistent with the non-variable long-term average Crab Nebula flux at TeV energies. Assuming a linear correlation between the very high energy flux change >1TeV and the flux change seen in the Fermi-LAT band >100MeV during the period of simultaneous observations, the linear correlation factor can be constrained to be at most 8.6 10{sup 3} with 95% confidence.

  17. UNDERSTANDING THE IMPACT OF RETURN-CURRENT LOSSES ON THE X-RAY EMISSION FROM SOLAR FLARES

    SciTech Connect (OSTI)

    Holman, Gordon D., E-mail: Gordon.D.Holman@nasa.gov [NASA Goddard Space Flight Center, Code 671, Greenbelt, MD 20771 (United States)

    2012-01-20

    I obtain and examine the implications of one-dimensional analytic solutions for return-current losses on an initially power-law distribution of energetic electrons with a sharp low-energy cutoff in flare plasma with classical (collisional) resistivity. These solutions show, for example, that return-current losses are not sensitive to plasma density, but are sensitive to plasma temperature and the low-energy cutoff of the injected nonthermal electron distribution. A characteristic distance from the electron injection site, x{sub rc}, is derived. At distances less than x{sub rc} the electron flux density is not reduced by return-current losses, but plasma heating can be substantial in this region, in the upper, coronal part of the flare loop. Before the electrons reach the collisional thick-target region of the flare loop, an injected power-law electron distribution with a low-energy cutoff maintains that structure, but with a flat energy distribution below the cutoff energy, which is now determined by the total potential drop experienced by the electrons. Modifications due to the presence of collisional losses are discussed. I compare these results with earlier analytical results and with more recent numerical simulations. Emslie's conjecture that there is a maximum integrated X-ray source brightness on the order of 10{sup -15} photons cm{sup -2} s{sup -1} cm{sup -2} is examined. I find that this is not actually the maximum brightness and its value is parameter dependent, but it is nevertheless a valuable benchmark for identifying return-current losses in hard X-ray spectra. I discuss an observational approach to identifying return-current losses in flare data, including identification of a return-current 'bump' in X-ray light curves at low photon energies.

  18. THE IMPACT OF BOUND STELLAR ORBITS AND GENERAL RELATIVITY ON THE TEMPORAL BEHAVIOR OF TIDAL DISRUPTION FLARES

    SciTech Connect (OSTI)

    Dai, Lixin; Escala, Andres; Coppi, Paolo

    2013-09-20

    We have carried out general relativistic particle simulations of stars tidally disrupted by massive black holes. When a star is disrupted in a bound orbit with moderate eccentricity instead of a parabolic orbit, the temporal behavior of the resulting stellar debris changes qualitatively. The debris is initially all bound, returning to pericenter in a short time about the original stellar orbital timescale. The resulting fallback rate can thus be much higher than the Eddington rate. Furthermore, if the star is disrupted close to the hole, in a regime where general relativity is important, the stellar and debris orbits display general relativistic precession. Apsidal precession can make the debris stream cross itself after several orbits, likely leading to fast debris energy dissipation. If the star is disrupted in an inclined orbit around a spinning hole, nodal precession reduces the probability of self-intersection, and circularization may take many dynamical timescales, delaying the onset of flare activity. An examination of the particle dynamics suggests that quasi-periodic flares with short durations, produced when the center of the tidal stream passes pericenter, may occur in the early-time light curve. The late-time light curve may still show power-law behavior which is generic to disk accretion processes. The detection triggers for future surveys should be extended to capture such 'non-standard' short-term flaring activity before the event enters the asymptotic decay phase, as this activity is likely to be more sensitive to physical parameters such as the black hole spin.

  19. On the variation of solar flare coronal X-ray source sizes with energy

    SciTech Connect (OSTI)

    Jeffrey, Natasha L. S.; Kontar, Eduard P.; Bian, Nicolas H. [School of Physics and Astronomy, University of Glasgow, G12 8QQ Glasgow (United Kingdom); Emslie, A. Gordon, E-mail: n.jeffrey@physics.gla.ac.uk [Department of Physics and Astronomy, Western Kentucky University, Bowling Green, KY 42101 (United States)

    2014-05-20

    Observations with RHESSI have enabled the detailed study of the structure of dense hard X-ray coronal sources in solar flares. The variation of source extent with electron energy has been discussed in the context of streaming of non-thermal particles in a one-dimensional cold target model and the results used to constrain both the physical extent of, and density within, the electron acceleration region. Here, we extend this investigation to a more physically realistic model of electron transport that takes into account the finite temperature of the ambient plasma, the initial pitch angle distribution of the accelerated electrons, and the effects of collisional pitch angle scattering. The finite temperature results in the thermal diffusion of electrons, which leads to the observationally inferred value of the acceleration region volume being an overestimate of its true value. The different directions of the electron trajectories, a consequence of both the non-zero injection pitch angle and scattering within the target, cause the projected propagation distance parallel to the guiding magnetic field to be reduced, so that a one-dimensional interpretation can overestimate the actual density by a factor of up to ?6. The implications of these results for the determination of acceleration region properties (specific acceleration rate, filling factor, etc.) are discussed.

  20. KAPPA DISTRIBUTION MODEL FOR HARD X-RAY CORONAL SOURCES OF SOLAR FLARES

    SciTech Connect (OSTI)

    Oka, M.; Ishikawa, S.; Saint-Hilaire, P.; Krucker, S.; Lin, R. P. [Space Sciences Laboratory, University of California Berkeley (United States)] [Space Sciences Laboratory, University of California Berkeley (United States)

    2013-02-10

    Solar flares produce hard X-ray emission, the photon spectrum of which is often represented by a combination of thermal and power-law distributions. However, the estimates of the number and total energy of non-thermal electrons are sensitive to the determination of the power-law cutoff energy. Here, we revisit an 'above-the-loop' coronal source observed by RHESSI on 2007 December 31 and show that a kappa distribution model can also be used to fit its spectrum. Because the kappa distribution has a Maxwellian-like core in addition to a high-energy power-law tail, the emission measure and temperature of the instantaneous electrons can be derived without assuming the cutoff energy. Moreover, the non-thermal fractions of electron number/energy densities can be uniquely estimated because they are functions of only the power-law index. With the kappa distribution model, we estimated that the total electron density of the coronal source region was {approx}2.4 Multiplication-Sign 10{sup 10} cm{sup -3}. We also estimated without assuming the source volume that a moderate fraction ({approx}20%) of electrons in the source region was non-thermal and carried {approx}52% of the total electron energy. The temperature was 28 MK, and the power-law index {delta} of the electron density distribution was -4.3. These results are compared to the conventional power-law models with and without a thermal core component.