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1

Emissions from Trucks using Fischer-Tropsch Diesel Fuel  

SciTech Connect (OSTI)

The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California B- diesel fuel if produced in large volumes. overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel. Vehicle emissions tests were performed using West Virginia University's unique transportable chassis dynamometer. The trucks were found to perform adequately on neat F-T diesel fuel. Compared to a California diesel fuel baseline, neat F-T diesel fuel emitted about 12% lower oxides of nitrogen (NOx) and 24% lower particulate matter over a five-mile driving cycle.

Paul Norton; Keith Vertin; Brent Bailey; Nigel N. Clark; Donald W. Lyons; Stephen Goguen; James Eberhardt

1998-10-19T23:59:59.000Z

2

Development of Detailed Kinetic Models for Fischer-Tropsch Fuels  

SciTech Connect (OSTI)

Fischer-Tropsch (FT) fuels can be synthesized from a syngas stream generated by the gasification of biomass. As such they have the potential to be a renewable hydrocarbon fuel with many desirable properties. However, both the chemical and physical properties are somewhat different from the petroleum-based hydrocarbons that they might replace, and it is important to account for such differences when considering using them as replacements for conventional fuels in devices such as diesel engines and gas turbines. FT fuels generally contain iso-alkanes with one or two substituted methyl groups to meet the pour-point specifications. Although models have been developed for smaller branched alkanes such as isooctane, additional efforts are required to properly capture the kinetics of the larger branched alkanes. Recently, Westbrook et al. developed a chemical kinetic model that can be used to represent the entire series of n-alkanes from C{sub 1} to C{sub 16} (Figure 1). In the current work, the model is extended to treat 2,2,4,4,6,8,8-heptamethylnonane (HMN), a large iso-alkane. The same reaction rate rules used in the iso-octane mechanism were incorporated in the HMN mechanism. Both high and low temperature chemistry was included so that the chemical kinetic model would be applicable to advanced internal combustion engines using low temperature combustion strategies. The chemical kinetic model consists of 1114 species and 4468 reactions. Concurrently with this effort, work is underway to improve the details of specific reaction classes in the mechanism, guided by high-level electronic structure calculations. Attention is focused upon development of accurate rate rules for abstraction of the tertiary hydrogens present in branched alkanes and properly accounting for the pressure dependence of the ?-scission, isomerization, and R + O{sub 2} reactions.

Westbrook, C K; Pitz, W J; Carstensen, H; Dean, A M

2008-10-28T23:59:59.000Z

3

FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

This project has two primary purposes: (1) Build a small-footprint (SFP) fuel production plant to prove the feasibility of this relatively transportable technology on an intermediate scale (i.e. between laboratory-bench and commercial capacity) and produce as much as 150,000 gallons of hydrogen-saturated Fischer-Tropsch (FT) diesel fuel; and (2) Use the virtually sulfur-free fuel produced to demonstrate (over a period of at least six months) that it can not only be used in existing diesel engines, but that it also can enable significantly increased effectiveness and life of the next-generation exhaust-after-treatment emission control systems that are currently under development and that will be required for future diesel engines. Furthermore, a well-to-wheels economic analysis will be performed to characterize the overall costs and benefits that would be associated with the actual commercial production, distribution and use of such FT diesel fuel made by the process under consideration, from the currently underutilized (or entirely un-used) energy resources targeted, primarily natural gas that is stranded, sub-quality, off-shore, etc. During the first year of the project, which is the subject of this report, there have been two significant areas of progress: (1) Most of the preparatory work required to build the SFP fuel-production plant has been completed, and (2) Relationships have been established, and necessary project coordination has been started, with the half dozen project-partner organizations that will have a role in the fuel demonstration and evaluation phase of the project. Additional project tasks directly related to the State of Alaska have also been added to the project. These include: A study of underutilized potential Alaska energy resources that could contribute to domestic diesel and distillate fuel production by providing input energy for future commercial-size SFP fuel production plants; Demonstration of the use of the product fuel in a heavy-duty diesel vehicle during the Alaska winter; a comparative study of the cold-starting characteristics of FT and conventional diesel fuel; and demonstration of the use of the fuel to generate electricity for rural Alaskan villages using both a diesel generator set, and a reformer-equipped fuel cell.

Stephen P. Bergin

2003-04-23T23:59:59.000Z

4

Development and Demonstration of Fischer-Tropsch Fueled Heavy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

(F-T) Fuels in the U.S. -- An Overview APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update Coal-Derived Liquids to Enable HCCI Technology...

5

Subtask 3.4 - Fischer - Tropsch Fuels Development  

SciTech Connect (OSTI)

Under Subtask 3.4, the Energy & Environmental Research Center (EERC) examined the opportunities and challenges facing Fischerâ??Tropsch (FT) technology in the United States today. Work was completed in two distinct budget periods (BPs). In BP1, the EERC examined the technical feasibility of using modern warm-gas cleanup techniques for FT synthesis. FT synthesis is typically done using more expensive and complex cold-gas sweetening. Warm-gas cleanup could greatly reduce capital and operating costs, making FT synthesis more attractive for domestic fuel production. Syngas was generated from a variety of coal and biomass types; cleaned of sulfur, moisture, and condensables; and then passed over a pilot-scale FT catalyst bed. Laboratory and modeling work done in support of the pilot-scale effort suggested that the catalyst was performing suboptimally with warm-gas cleanup. Long-term trends showed that the catalyst was also quickly deactivating. In BP3, the EERC compared FT catalyst results using warm-gas cleanup to results using cold-gas sweetening. A gas-sweetening absorption system (GSAS) was designed, modeled, and constructed to sweeten syngas between the gasifier and the pilot-scale FT reactor. Results verified that the catalyst performed much better with gas sweetening than it had with warm-gas cleanup. The catalyst also showed no signs of rapid deactivation when the GSAS was running. Laboratory tests in support of this effort verified that the catalyst had deactivated quickly in BP1 because of exposure to syngas, not because of any design flaw with the pilot-scale FT reactor itself. Based on these results, the EERC concludes that the two biggest issues with using syngas treated with warm-gas cleanup for FT synthesis are high concentrations of CO{sub 2} and volatile organic matter. Other catalysts tested by the EERC may be more tolerant of CO{sub 2}, but volatile matter removal is critical to ensuring long-term FT catalyst operation. This subtask was funded through the EERCâ??U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding for BP1 was provided by the North Dakota Industrial Commissionâ??s (NDIC) Renewable Energy Council.

Joshua Strege; Anthony Snyder; Jason Laumb; Joshua Stanislowski; Michael Swanson

2012-05-01T23:59:59.000Z

6

ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The Syntroleum plant is mechanically complete and currently undergoing start-up. The fuel production and demonstration plan is near completion. The study on the impact of small footprint plant (SFP) fuel on engine performance is about half-completed. Cold start testing has been completed. Preparations have been completed for testing the fuel in diesel electric generators in Alaska. Preparations are in progress for testing the fuel in bus fleets at Denali National Park and the Washington Metropolitan Transit Authority. The experiments and analyses conducted during this project show that Fischer-Tropsch (FT) gas-to-liquid diesel fuel can easily be used in a diesel engine with little to no modifications. Additionally, based on the results and discussion presented, further improvements in performance and emissions can be realized by configuring the engine to take advantage of FT diesel fuel's properties. The FT fuel also shows excellent cold start properties and enabled the engine tested to start at more the ten degrees than traditional fuels would allow. This plant produced through this project will produce large amounts of FT fuel. This will allow the fuel to be tested extensively, in current, prototype, and advanced diesel engines. The fuel may also contribute to the nation's energy security. The military has expressed interest in testing the fuel in aircraft and ground vehicles.

Steve Bergin

2003-10-17T23:59:59.000Z

7

Catalyst structure and method of Fischer-Tropsch synthesis  

DOE Patents [OSTI]

The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.

Wang, Yong; Vanderwiel, David P.; Tonkovich, Anna Lee; Gao, Yufei; Baker, Eddie G.

2004-06-15T23:59:59.000Z

8

Catalyst structure and method of fischer-tropsch synthesis  

DOE Patents [OSTI]

The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.

Wang, Yong [Richland, WA; Vanderwiel, David P [Richland, WA; Tonkovich, Anna Lee Y [Pasco, WA; Gao, Yufei [Kennewick, WA; Baker, Eddie G [Pasco, WA

2002-12-10T23:59:59.000Z

9

Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project  

SciTech Connect (OSTI)

The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer lab evaluation; cold-start test-cell evaluations; overall feasibility, economics, and efficiency of SFP fuel production; and an economic analysis. Two unexpected issues that arose during the project were further studied and resolved: variations in NOx emissions were accounted for and fuel-injection nozzle fouling issues were traced to the non-combustible (ash) content of the engine oil, not the F-T fuel. The F-T fuel domestically produced and evaluated in this effort appears to be a good replacement candidate for petroleum-based transportation fuels. However, in order for domestic F-T fuels to become a viable cost-comparable alternative to petroleum fuels, the F-T fuels will need to be produced from abundant U.S. domestic resources such as coal and biomass, rather than stranded natural gas.

Stephen P. Bergin

2006-06-30T23:59:59.000Z

10

Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel  

SciTech Connect (OSTI)

Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

2009-01-01T23:59:59.000Z

11

Analysis of Nitro-Polycyclic Aromatic Hydrocarbons in Conventional Diesel and Fischer--Tropsch Diesel Fuel Emissions Using Electron Monochromator-Mass Spectrometry  

SciTech Connect (OSTI)

The presence of nitro-polycyclic aromatic hydrocarbons (NPAHs) in diesel fuel emissions has been studied for a number of years predominantly because of their contribution to the overall health and environmental risks associated with these emissions. Electron monochromator-mass spectrometry (EM-MS) is a highly selective and sensitive method for detection of NPAHs in complex matrixes, such as diesel emissions. Here, EM-MS was used to compare the levels of NPAHs in fuel emissions from conventional (petroleum) diesel, ultra-low sulfur/low-aromatic content diesel, Fischer-Tropsch synthetic diesel, and conventional diesel/synthetic diesel blend. The largest quantities of NPAHs were detected in the conventional diesel fuel emissions, while the ultra-low sulfur diesel and synthetic diesel fuel demonstrated a more than 50% reduction of NPAH quantities when compared to the conventional diesel fuel emissions. The emissions from the blend of conventional diesel with 30% synthetic diesel fuel also demonstrated a more than 30% reduction of the NPAH content when compared to the conventional diesel fuel emissions. In addition, a correlation was made between the aromatic content of the different fuel types and NPAH quantities and between the nitrogen oxides emissions from the different fuel types and NPAH quantities. The EM-MS system demonstrated high selectivity and sensitivity for detection of the NPAHs in the emissions with minimal sample cleanup required.

Havey, C. D.; McCormick, R. L.; Hayes, R. R.; Dane, A. J.; Voorhees, K. J.

2006-01-01T23:59:59.000Z

12

Fischer-Tropsch process  

DOE Patents [OSTI]

A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

1987-01-01T23:59:59.000Z

13

Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process  

SciTech Connect (OSTI)

Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

Oguejiofor, G.C. [Nnamdi Azikiwe University, Awka (Nigeria). Dept. of Chemical Engineering

2008-07-01T23:59:59.000Z

14

Novel Attrition-Resistant Fischer Tropsch Catalyst  

SciTech Connect (OSTI)

There is a strong national interest in the Fischer-Tropsch synthesis process because it offers the possibility of making liquid hydrocarbon fuels from reformed natural gas or coal and biomass gasification products. This project explored a new approach that had been developed to produce active, attrition-resistant Fischer-Tropsch catalysts that are based on glass-ceramic materials and technology. This novel approach represented a promising solution to the problem of reducing or eliminating catalyst attrition and maximizing catalytic activity, thus reducing costs. The technical objective of the Phase I work was to demonstrate that glass-ceramic based catalytic materials for Fischer-Tropsch synthesis have resistance to catalytic deactivation and reduction of particle size superior to traditional supported Fischer-Tropsch catalyst materials. Additionally, these novel glass-ceramic-based materials were expected to exhibit catalytic activity similar to the traditional materials. If successfully developed, the attrition-resistant Fischer-Tropsch catalyst materials would be expected to result in significant technical, economic, and social benefits for both producers and public consumers of Fischer-Tropsch products such as liquid fuels from coal or biomass gasification. This program demonstrated the anticipated high attrition resistance of the glass-ceramic materials. However, the observed catalytic activity of the materials was not sufficient to justify further development at this time. Additional testing documented that a lack of pore volume in the glass-ceramic materials limited the amount of surface area available for catalysis and consequently limited catalytic activity. However, previous work on glass-ceramic catalysts to promote other reactions demonstrated that commercial levels of activity can be achieved, at least for those reactions. Therefore, we recommend that glass-ceramic materials be considered again as potential Fischer-Tropsch catalysts if it can be demonstrated that materials with adequate pore volume can be produced. During the attrition resistance tests, it was learned that the glass-ceramic materials are very abrasive. Attention should be paid in any further developmental efforts to the potential for these hard, abrasive materials to damage reactors.

Weast, Logan, E.; Staats, William, R.

2009-05-01T23:59:59.000Z

15

Development and Demonstration of Fischer-Tropsch Fueled Heavy-Duty Vehicles  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Companya new high capacity anodewith Control

16

Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLCDiesel Enginesthe U.S. -- An Overview | Department of

17

Innovative Gasification to Produce Fischer-Tropsch Jet and Diesel Fuel  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S.Indiana CollegeManagerInnovative Gasification to Produce

18

HEFA and Fischer-Tropsch Jet Fuel Cost Analyses | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many autoThis road map is a summary of- -

19

ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: SFP Construction and Fuel Production, Impact of SFP Fuel on Engine Performance, Fleet Testing at WMATA and Denali National Park, Demonstration of Clean Diesel Fuels in Diesel Electric Generators in Alaska, and Economic Analysis. ICRC provided overall project organization and budget management for the project. ICRC held meetings with various project participants. ICRC presented at the Department of Energy's annual project review meeting. The plant began producing fuel in October 2004. The first delivery of finished fuel was made in March of 2004 after the initial start-up period.

Steve Bergin

2004-10-18T23:59:59.000Z

20

Ultra-Clean Fischer-Tropsch Fuels Production and Demonstration Project  

SciTech Connect (OSTI)

The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: Dynamometer Durability Testing, the Denali Bus Fleet Demonstration, Bus Fleet Demonstrations Emissions Analysis, Impact of SFP Fuel on Engine Performance, Emissions Analysis, Feasibility Study of SFPs for Rural Alaska, and Cold Weather Testing of Ultra Clean Fuel.

Steve Bergin

2005-10-14T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY  

Broader source: Energy.gov [DOE]

This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

22

Process for upgrading wax from Fischer-Tropsch synthesis  

DOE Patents [OSTI]

The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel. 2 figs.

Derr, W.R. Jr.; Garwood, W.E.; Kuo, J.C.; Leib, T.M.; Nace, D.M.; Tabak, S.A.

1987-08-04T23:59:59.000Z

23

Process for upgrading wax from Fischer-Tropsch synthesis  

DOE Patents [OSTI]

The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.

Derr, Jr., W. Rodman (Vincentown, NJ); Garwood, William E. (Haddonfield, NJ); Kuo, James C. (Cherry Hill, NJ); Leib, Tiberiu M. (Voorhees, NJ); Nace, Donald M. (Woodbury, NJ); Tabak, Samuel A. (Wenonah, NJ)

1987-01-01T23:59:59.000Z

24

Fischer-Tropsch wax characterization and upgrading: Final report  

SciTech Connect (OSTI)

The characterization and upgrading of Fischer-Tropsch wax was studied. The focus of the program was to maximize the yield of marketable transportation fuels from the Fischer-Tropsch process. The wax was characterized using gel permeation chromatography (GPC), high resolution mass spectrometry (HRMS), infrared spectroscopy (IR), gas chromatography (GC), nuclear magnetic resonance (NMR) and various other physical analyses. Hydrocracking studies conducted in a pilot plant indicate that Fischer-Tropsch wax is an excellent feedstock. A high yield of excellent quality diesel fuel was produced with satisfactory catalyst performance at relatively mild operating conditions. Correlations for predicting key diesel fuel properties were developed and checked against actual laboratory blend data. The blending study was incorporated into an economic evaluation. Finally, it is possible to take advantage of the high quality of the Fischer-Tropsch derived distillate by blending a lower value light cycle oil (produced from a refinery FCC unit) representing a high aromatic and low cetane number. The blended stream meets diesel pool specifications (up to 60 wt % LCO addition). The value added to this blending stream further enhances the upgrading complex return. 22 refs., 39 figs., 48 tabs.

Shah, P.P.; Sturtevant, G.C.; Gregor, J.H.; Humbach, M.J.; Padrta, F.G.; Steigleder, K.Z.

1988-06-06T23:59:59.000Z

25

Moderated ruthenium fischer-tropsch synthesis catalyst  

DOE Patents [OSTI]

The subject Fischer-Tropsch catalyst comprises moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.

Abrevaya, Hayim (Wilmette, IL)

1991-01-01T23:59:59.000Z

26

On-Road Use of Fischer-Tropsch Diesel Blends  

SciTech Connect (OSTI)

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California No.2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NO{sub x}) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state No.2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without. The CBD cycle was employed as the test schedule, with a test weight of 33,050 lb. For those buses with catalytic converters and rebuilt engines, NO x was reduced by 8% and PM was reduced by 31% on average, while for those buses without, NO x was reduced by 5% and PM was reduced by 20% on average. It is concluded that advanced compression ignition fuels from non-petroleum sources can offer environmental advantages in typical line haul and city transit applications.

Nigel Clark; Mridul Gautam; Donald Lyons; Chris Atkinson; Wenwei Xie; Paul Norton; Keith Vertin; Stephen Goguen; James Eberhardt

1999-04-26T23:59:59.000Z

27

Fischer-Tropsch Wastewater Utilization  

DOE Patents [OSTI]

The present invention is generally directed to handling the wastewater, or condensate, from a hydrocarbon synthesis reactor. More particularly, the present invention provides a process wherein the wastewater of a hydrocarbon synthesis reactor, such as a Fischer-Tropsch reactor, is sent to a gasifier and subsequently reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas. The wastewater may also be recycled back to a slurry preparation stage, where solid combustible organic materials are pulverized and mixed with process water and the wastewater to form a slurry, after which the slurry fed to a gasifier where it is reacted with steam and oxygen at high temperatures and pressures so as to produce synthesis gas.

Shah, Lalit S. (Sugar Land, TX)

2003-03-18T23:59:59.000Z

28

Emissions and in-cylinder combustion characteristics of Fischer-Tropsch and conventional diesel fuels in a modern CI engine  

E-Print Network [OSTI]

Increasingly stringent emissions regulations, rising oil prices, and an increased focus on environmental awareness are driving the search for clean, alternative fuels. Derived from natural gas, coal, and even biomass ...

Sappok, Alexander G. (Alexander Georg)

2006-01-01T23:59:59.000Z

29

The limiting mutual diffusion coefficients of Fischer-Tropsch synthesis products in near-critical hydrocarbons  

E-Print Network [OSTI]

The Fischer-Tropsch synthesis (FTS) is used to convert synthesis gas into petroleum products such as gasoline and diesel fuel. It was developed in Germany during WW 11 as an alternative fuel source during the fuel embargo and is still used as a...

Noel, James Michael

1994-01-01T23:59:59.000Z

30

Effect of engine operating parameters and fuel characteristics on diesel engine emissions  

E-Print Network [OSTI]

To examine the effects of using synthetic Fischer-Tropsch (FT) diesel fuel in a modern compression ignition engine, experiments were conducted on a MY 2002 Cummins 5.9 L diesel engine outfitted with high pressure, common ...

Acar, Joseph, 1977-

2005-01-01T23:59:59.000Z

31

Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.  

SciTech Connect (OSTI)

This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

Xie, X.; Wang, M.; Han, J. (Energy Systems)

2011-04-01T23:59:59.000Z

32

Cobalt Fischer-Tropsch catalysts having improved selectivity  

DOE Patents [OSTI]

A cobalt Fischer-Tropsch catalyst having an improved steam treated, acid extracted LZ-210 support is taught. The new catalyst system demonstrates improved product selectivity at Fischer-Tropsch reaction conditions evidenced by lower methane production, higher C.sub.5.sup.+ yield and increased olefin production.

Miller, James G. (Pearl River, NY); Rabo, Jule A. (Armonk, NY)

1989-01-01T23:59:59.000Z

33

Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions  

DOE Patents [OSTI]

A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

Huffman, Gerald P.

2012-11-13T23:59:59.000Z

34

E-Print Network 3.0 - advanced fischer-tropsch technology Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactors (F-T) has... The Fischer Tropsch (F-T) synthesis was originally devel- oped in Germany in the 1920s by Franz Fischer... into syngas and, then, Fischer-Tropsch synthesis...

35

Romania program targets methanol and Fischer-Tropsch research  

SciTech Connect (OSTI)

Currently, the chemical organic industry, the petrochemical and engine fuels industry in Romania are entirely based on hydrocarbons from oil. To reduce the oil dependence of this sector and to ensure the stipulated growth rate of 8-9%, research and development programs have been set up with a view to the diversification of raw materials. In research on hydrocarbons from alcohol conversion, three process variants are known, i.e. olefins from methanol, gasolines from methanol and a combined gasolines and aromatic hydrocarbons from methanol. The Romanian process of methanol conversion to hydrocarbons is very flexible, with all the variants mentioned being carried out in the same plant by modifying the catalysts. In research on hydrocarbons from synthesis gas a modern process is being developed for gasification of brown coal in a fluidized bed, under pressure, in the presence of oxygen and water vapors. In the field of carbon oxide hydrogenation, studies have been carried out on selective Fischer-Tropsch processes in which the reaction products are high value hydrocarbon fractions.

Not Available

1987-03-01T23:59:59.000Z

36

ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

Fischer-Tropsch (FT) synthesis to convert syngas (CO + H{sub 2}) derived from natural gas or coal to liquid fuels and wax is a well-established technology. For low H{sub 2} to CO ratio syngas produced from CO{sub 2} reforming of natural gas or from gasification of coal, the use of Fe catalysts is attractive because of their high water gas shift activity in addition to their high FT activity. Fe catalysts are also attractive due to their low cost and low methane selectivity. Because of the highly exothermic nature of the FT reaction, there has been a recent move away from fixed-bed reactors toward the development of slurry bubble column reactors (SBCRs) that employ 30 to 90 {micro}m catalyst particles suspended in a waxy liquid for efficient heat removal. However, the use of FeFT catalysts in an SBCR has been problematic due to severe catalyst attrition resulting in fines that plug the filter employed to separate the catalyst from the waxy product. Fe catalysts can undergo attrition in SBCRs not only due to vigorous movement and collisions but also due to phase changes that occur during activation and reaction.

K. Jothimurugesan; James G. Goodwin, Jr.; Santosh K. Gangwal

1999-10-01T23:59:59.000Z

37

Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst  

DOE Patents [OSTI]

A Fischer-Tropsch type process produces hydrocarbons from carbon monoxide and hydrogen using a novel catalyst comprising moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation.

Abrevaya, Hayim (Wilmette, IL)

1990-01-01T23:59:59.000Z

38

Cobalt Fischer-Tropsch catalysts having improved selectivity  

DOE Patents [OSTI]

The promoter(s) Mn oxide or Mn oxide and Zr oxide are added to a cobalt Fischer-Tropsch catalyst combined with the molecular sieve TC-103 or TC-123 such that the resultant catalyst demonstrates improved product selectivity, stability and catalyst life. The improved selectivity is evidenced by lower methane production, higher C5+ yield and increased olefin production.

Miller, James G. (Pearl River, NY); Rabo, Jule A. (Armonk, NY)

1989-01-01T23:59:59.000Z

39

Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst  

DOE Patents [OSTI]

A Fischer-Tropsch type process produces hydrocarbons from carbon monoxide and hydrogen using a novel catalyst comprising moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation. 1 fig.

Abrevaya, H.

1990-07-31T23:59:59.000Z

40

BASELINE DESIGN/ECONOMICS FOR ADVANCED FISCHER-TROPSCH TECHNOLOGY  

SciTech Connect (OSTI)

Bechtel, along with Amoco as the main subcontractor, developed a Baseline design, two alternative designs, and computer process simulation models for indirect coal liquefaction based on advanced Fischer-Tropsch (F-T) technology for the U. S. Department of Energy's (DOE's) Federal Energy Technology Center (FETC).

None

1998-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology  

E-Print Network [OSTI]

M. ,   et   al. ,   Gasoline  conversion:  reactivity  al. ,   Methanol   to   gasoline   over   zeolite   H-­?of a Fischer-Tropsch Gasoline Process for the Steam

Li, Yang

2013-01-01T23:59:59.000Z

42

Separation of catalyst from Fischer-Tropsch slurry  

DOE Patents [OSTI]

In a catalytic process for converting synthesis gas including hydrogen and carbon monoxide to hydrocarbons and oxygenates by a slurry Fischer-Tropsch synthesis, the wax product along with dispersed catalyst is removed from the slurry and purified by removing substantially all of the catalyst prior to upgrading the wax and returning a portion to the Fischer-Tropsch reaction. Separation of the catalyst particles from the wax product is accomplished by dense gas and/or liquid extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic in nature. The purified catalyst free wax product can be subsequently upgraded by various methods such as hydrogenation, isomerization, hydrocracking, conversion to gasoline and other products over ZSM-5 aluminosilicate zeolite, etc. The catalyst particles are returned to the Fischer-Tropsch Reactor by slurring them with a wax fraction of appropriate molecular weight, boiling point and viscosity to avoid reactor gelation.

White, Curt M. (Pittsburgh, PA); Quiring, Michael S. (Katy, TX); Jensen, Karen L. (Pittsburgh, PA); Hickey, Richard F. (Bethel Park, PA); Gillham, Larry D. (Bartlesville, OK)

1998-10-27T23:59:59.000Z

43

Separation of catalyst from Fischer-Tropsch slurry  

DOE Patents [OSTI]

In a catalytic process for converting synthesis gas including hydrogen and carbon monoxide to hydrocarbons and oxygenates by a slurry Fischer-Tropsch synthesis, the wax product along with dispersed catalyst is removed from the slurry and purified by removing substantially all of the catalyst prior to upgrading the wax and returning a portion to the Fischer-Tropsch reaction. Separation of the catalyst particles from the wax product is accomplished by dense gas and/or liquid extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic in nature. The purified catalyst-free wax product can be subsequently upgraded by various methods such as hydrogenation, isomerization, hydrocracking, conversion to gasoline and other products over ZSM-5 aluminosilicate zeolite, etc. The catalyst particles are returned to the Fischer-Tropsch Reactor by mixing them with a wax fraction of appropriate molecular weight, boiling point and viscosity to avoid reactor gelation. 2 figs.

White, C.M.; Quiring, M.S.; Jensen, K.L.; Hickey, R.F.; Gillham, L.D.

1998-10-27T23:59:59.000Z

44

Development and process evaluation of improved Fischer-Tropsch slurry catalysts. Final report  

SciTech Connect (OSTI)

This report describes results of a study aimed at developing and evaluating improved catalysts for a slurry Fischer-Tropsch (FT) process for converting synthesis gas to high quality transportation fuels (gasoline and distillate). The improvements in catalyst performance were sought by studying effects of pretreatment conditions, promoters and binders/supports. A total of 20 different, iron based, catalysts were evaluated in 58 fixed bed reactor tests and 10 slurry reactor tests. The major accomplishments and conclusions are summarized below. The pretreatment conditions (temperature, duration and the nature of reducing gas) have significant effect on catalyst performance (activity, selectivity and stability) during Fischer-Tropsch synthesis. One of precipitated unsupported catalysts had hydrocarbon selectivity similar to Mobil`s I-B catalyst in high wax mode operation, and had not experienced any loss in activity during 460 hours of testing under variable process conditions in a slurry reactor. The effect of promoters (copper and potassium) on catalyst performance during FT synthesis has been studied in a systematic way. It was found that potassium promotion increases activities of the FT and water-gas-shift (WGS) reactions, the average molecular weight of hydrocarbon products, and suppresses the olefin hydrogenation and isomerization reactions. The addition of binders/supports (silica or alumina) to precipitated Fe/Cu/K catalysts, decreased their activity but improved their stability and hydrocarbon selectivity. The performance of catalysts of this type was very promising and additional studies are recommended to evaluate their potential for use in commercial slurry reactors.

Bukur, D.B.; Mukesh, D.; Patel, S.A.; Zimmerman, W.H.; Rosynek, M.P. [Texas A& M Univ., College Station, TX (United States); Kellogg, L.J. [Air Products and Chemicals, Inc., Allentown, PA (United States)

1990-04-01T23:59:59.000Z

45

ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work  

E-Print Network [OSTI]

IX.1-Draft ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work During the 1980s, Air Products & Chemicals worked on several aspects of the Fischer-Tropsch synthesis. These included, exhibited similar activity and product selectivity, showing that the preparative method was reproducible

Kentucky, University of

46

Fischer-Tropsch synthesis over iron-rhodium alloy catalysts  

SciTech Connect (OSTI)

To investigate the nature of iron-rhodium alloy catalysts during the Fischer-Tropsch synthesis, a combination of experimental techniques were applied. Infrared spectroscopy was mainly used to extract direct information on the surface of catalysts under the reaction conditions. In addition, Mossbauer spectroscopy was employed to study the iron alloy catalysts. Further characterization of the catalysts was performed by chemisorption measurements. Hydrocarbon products of the CO + H/sub 2/ synthesis reaction were analyzed by gas chromatography. The working surface of a silica-supported rhodium catalyst was found to be saturated with molecular carbon monoxide. The intensity of the linear carbonyl absorption band remained constant compared to that for room temperature CO adsorption, while that of the bridge-bonded carbonyl absorption band was drastically reduced during the Fischer-Tropsch synthesis. The bridge-bonded adsorption sites are assumed to be the active sites for dissociating carbon monoxide. The hydrogenation rate of the linearly adsorbed carbon monoxide was much slower than the steady state reaction rate. The alloy catalyst did not form a bulk carbide, but the presence of surface carbon was suggested by the large shift of the linear carbonyl absorption band. On the other hand, infrared spectra on an iron catalyst showed only weak bands, indicating a high degree of CO dissociation. On a silica-supported iron-rhodium alloy catalyst, surface analysis by infrared spectroscopy presents evidence of well-mixed alloy formation. Three models of carbon monoxide adsorption were identified.

Choi, S.

1983-01-01T23:59:59.000Z

47

Platinum-Modulated Cobalt Nanocatalysts for Low-Temperature Aqueous-Phase Fischer Tropsch Synthesis  

SciTech Connect (OSTI)

Fischer Tropsch synthesis (FTS) is an important catalytic process for liquid fuel generation, which converts coal/shale gas/biomass-derived syngas (a mixture of CO and H2) to oil. While FTS is thermodynamically favored at low temperature, it is desirable to develop a new catalytic system that could allow working at a relatively low reaction temperature. In this article, we present a one-step hydrogenation reduction route for the synthesis of Pt Co nanoparticles (NPs) which were found to be excellent catalysts for aqueous-phase FTS at 433 K. Coupling with atomic-resolution scanning transmission electron microscopy (STEM) and theoretical calculations, the outstanding activity is rationalized by the formation of Co overlayer structures on Pt NPs or Pt Co alloy NPs. The improved energetics and kinetics from the change of the transition states imposed by the lattice mismatch between the two metals are concluded to be the key factors responsible for the dramatically improved FTS performance.

Wang, Hang [Peking University; Zhou, Wu [ORNL; Liu, JinXun [Dalian Institute of Chemical Physics; Si, Rui [Brookhaven National Laboratory (BNL); Sun, Geng [Peking University; Zhong, Mengqi [Peking University; Su, Haiyan [Peking University; Zhao, Huabo [Peking University; Rodrigues, Jose [Brookhaven National Laboratory (BNL); Pennycook, Stephen J [ORNL; Idrobo Tapia, Juan C [ORNL; Li, Weixue [Dalian Institute of Chemical Physics; Kou, Yuan [Peking University; Ma, Ding [Peking University

2013-01-01T23:59:59.000Z

48

Supported fischer-tropsch catalyst and method of making the catalyst  

SciTech Connect (OSTI)

A Fischer-Tropsch catalyst and a method of making the catalyst for a Fischer-Tropsch process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas, is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Orefield, PA); Withers, Howard P. (Douglassville, PA)

1987-01-01T23:59:59.000Z

49

Spray drying and attrition behavior of iron catalysts for slurry phase Fischer-Tropsch synthesis  

E-Print Network [OSTI]

This thesis describes results of a study aimed at developing and evaluating attrition resistant iron catalysts prepared by spray drying technique. These catalysts are intended for Fischer-Tropsch (F-T) synthesis in a slurry bubble column reactor...

Carreto Vazquez, Victor Hugo

2004-11-15T23:59:59.000Z

50

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1998-07-22T23:59:59.000Z

51

Iron on mixed zirconia-titania substrate Fischer-Tropsch catalyst and method of making same  

DOE Patents [OSTI]

A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.

Dyer, Paul N. (Allentown, PA); Nordquist, Andrew F. (Whitehall, PA); Pierantozzi, Ronald (Macungie, PA)

1986-01-01T23:59:59.000Z

52

Chemical Kinetic Modeling of Fuels  

Broader source: Energy.gov (indexed) [DOE]

petroleum based fuels * Non-petroleum based fuels: - Biodiesel and new generation biofuels - Fischer-Tropsch (F-T) fuels - Oil sand derived fuels Reduce mechanisms for...

53

Effect of surface modification by chelating agents on Fischer-Tropsch performance of Co/SiO2 catalysts  

SciTech Connect (OSTI)

The silica support of a Co-based catalyst for Fischer?Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts shows reduced crystallite sizes, a better-dispersed Co3O4 phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates, and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions. 1. INTRODUCTION Fischer?Tropsch (FT) synthesis has been recognized as one of the most promising technologies for the conversion of coal, natural gas, and biomass-derived syngas into liquid fuels and chemicals.1 Limited oil reserves, energy supply security concerns, carbon credits,1 pollution abatement laws, and, most notably, uncertainty about fuel prices have increased the prospect of commercializing the FT process. Catalysts that are typically used for FT synthesis include supported Co or Fe. Cobased catalysts have the advantage of higher syngas conversion, more high-

Bambal, Ashish S. [WVU; Kyugler, Edwin L. [WVU; Gardner, Todd H. [U.S. DOE; Dadyburjor, Dady B. [WVU

2013-01-01T23:59:59.000Z

54

Gas-to-liquids synthetic fuels for use in fuel cells : reformability, energy density, and infrastructure compatibility.  

SciTech Connect (OSTI)

The fuel cell has many potential applications, from power sources for electric hybrid vehicles to small power plants for commercial buildings. The choice of fuel will be critical to the pace of its commercialization. This paper reviews the various liquid fuels being considered as an alternative to direct hydrogen gas for the fuel cell application, presents calculations of the hydrogen and carbon dioxide yields from autothermal reforming of candidate liquid fuels, and reports the product gas composition measured from the autothermal reforming of a synthetic fuel in a micro-reactor. The hydrogen yield for a synthetic paraffin fuel produced by a cobalt-based Fischer-Tropsch process was found to be similar to that of retail gasoline. The advantages of the synthetic fuel are that it contains no contaminants that would poison the fuel cell catalyst, is relatively benign to the environment, and could be transported in the existing fuel distribution system.

Ahmed, S.; Kopasz, J. P.; Russell, B. J.; Tomlinson, H. L.

1999-09-08T23:59:59.000Z

55

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the first year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sup 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we have completed one STSR test with precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany). This catalyst was initially in commercial fixed bed reactors at Sasol in South Africa. The catalyst was tested at 13 different sets of process conditions, and had experienced a moderate deactivation during the first 500 h of testing (decrease in conversion from 56% to 50% at baseline process conditions). The second STSR test has been initiated and after 270 h on stream, the catalyst was tested at 6 different sets of process conditions.

Dragomir B. Bukur; Gilbert F. Froment; Lech Nowicki; Jiang Wang; Wen-Ping Ma

2003-09-29T23:59:59.000Z

56

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the second year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the second year of the project we completed the STSR test SB-26203 (275-343 h on stream), which was initiated during the first year of the project, and another STSR test (SB-28603 lasting 341 h). Since the inception of the project we completed 3 STSR tests, and evaluated catalyst under 25 different sets of process conditions. A precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany) was used in all tests. This catalyst was used initially in commercial fixed bed reactors at Sasol in South Africa. Also, during the second year we performed a qualitative analysis of experimental data from all three STSR tests. Effects of process conditions (reaction temperature, pressure, feed composition and gas space velocity) on water-gas-shift (WGS) activity and hydrocarbon product distribution have been determined.

Dragomir B. Bukur

2004-09-29T23:59:59.000Z

57

Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions  

DOE Patents [OSTI]

A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

Huffman, Gerald P

2012-09-18T23:59:59.000Z

58

Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis  

SciTech Connect (OSTI)

The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO{sub 2} emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO{sub 2} sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana.

Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu; Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States)

2009-09-15T23:59:59.000Z

59

Attrition resistant catalysts for slurry-phase Fischer-Tropsch process  

SciTech Connect (OSTI)

The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T because they are relatively inexpensive and possess reasonable activity for F-T synthesis (FTS). Their most advantages trait is their high water-gas shift (WGS) activity compared to their competitor, namely cobalt. This enables Fe F-T catalysts to process low H{sub 2}/CO ratio synthesis gas without an external shift reaction step. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, make the separation of catalyst from the oil/wax product very difficult if not impossible, an d result in a steady loss of catalyst from the reactor. The objectives of this research were to develop a better understanding of the parameters affecting attrition of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance.

K. Jothimurugesan

1999-11-01T23:59:59.000Z

60

Technology Development for Iron and Cobalt Fischer-Tropsch Catalysts Quarterly Report  

E-Print Network [OSTI]

, selectivity and water-gas shift activity were studied over a wide range of syngas conversion. Three catalyst water gas shift reaction rates and CO2 2 #12;3 selectivity during Fischer-Tropsch synthesis on Fe are higher than that on Co/SiO (21%). A multi-o 2 compartment kinetic model of catalytic surfaces is being

Kentucky, University of

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas  

E-Print Network [OSTI]

Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas f in out in n n n = - 100 n contraction (%) #12;Syngas ratio (H2:CO): sr H in CO in n n = 2 _ _ n: (mols per hour) sr: Syngas ratio Rates active metal (g) r: Rate (mols / hr / g metal) #12;Rate Syngas: syngas H COr r r= +2 r syngas: Syngas

Kentucky, University of

62

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the fourth year of a research project conducted under the University Coal Research Program. The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (water, carbon dioxide, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the fourth year of the project, an analysis of experimental data collected during the second year of this project was performed. Kinetic parameters were estimated utilizing product distributions from 27 mass balances. During the reporting period two kinetic models were employed: a comprehensive kinetic model of Dr. Li and co-workers (Yang et al., 2003) and a hydrocarbon selectivity model of Van der Laan and Beenackers (1998, 1999) The kinetic model of Yang et al. (2003) has 24 parameters (20 parameters for hydrocarbon formation, and 4 parameters for the water-gas-shift (WGS) reaction). Kinetic parameters for the WGS reaction and FTS synthesis were estimated first separately, and then simultaneously. The estimation of these kinetic parameters employed the Levenberg-Marquardt (LM) method and the trust-region reflective Newton large-scale (LS) method. A genetic algorithm (GA) was incorporated into estimation of parameters for FTS reaction to provide initial estimates of model parameters. All reaction rate constants and activation energies were found to be positive, but at the 95% confidence level the intervals were large. Agreement between predicted and experimental reaction rates has been fair to good. Light hydrocarbons are predicted fairly accurately, whereas the model underpredicts values of higher molecular weight hydrocarbons. Van der Laan and Beenackers hydrocarbon selectivity model provides a very good fit of the experimental data for hydrocarbons up to about C{sub 20}. However, the experimental data shows higher paraffin formation rates in C{sub 12}-C{sub 25} region which is likely due to hydrocracking or other secondary reactions. The model accurately captures the observed experimental trends of decreasing olefin to paraffin ratio and increasing {alpha} (chain growth length) with increase in chain length.

Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

2006-09-29T23:59:59.000Z

63

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYSTHESIS  

SciTech Connect (OSTI)

This report covers the third year of this research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis (FTS) on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we utilized experimental data from the STSR, that were obtained during the first two years of the project, to perform vapor-liquid equilibrium (VLE) calculations and estimate kinetic parameters. We used a modified Peng-Robinson (PR) equation of state (EOS) with estimated values of binary interaction coefficients for the VLE calculations. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Occasional discrepancies (for some of the experimental data) between calculated and experimental values of the liquid phase composition were ascribed to experimental errors. The VLE calculations show that the vapor and the liquid are in thermodynamic equilibrium under reaction conditions. Also, we have successfully applied the Levenberg-Marquardt method (Marquardt, 1963) to estimate parameters of a kinetic model proposed earlier by Lox and Froment (1993b) for FTS on an iron catalyst. This kinetic model is well suited for initial studies where the main goal is to learn techniques for parameter estimation and statistical analysis of estimated values of model parameters. It predicts that the chain growth parameter ({alpha}) and olefin to paraffin ratio are independent of carbon number, whereas our experimental data show that they vary with the carbon number. Predicted molar flow rates of inorganic species, n-paraffins and total olefins were generally not in good agreement with the corresponding experimental values. In the future we'll use kinetic models based on non-constant value of {alpha}.

Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

2005-09-29T23:59:59.000Z

64

Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels  

SciTech Connect (OSTI)

A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fuIly synthetic jet fuel in the place of petroleum-derived fueL

Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

2008-01-01T23:59:59.000Z

65

Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels  

SciTech Connect (OSTI)

A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fully synthetic jet fuel in the place of petroleum-derived fuel.

Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

2009-01-01T23:59:59.000Z

66

Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst  

SciTech Connect (OSTI)

This report details experiments performed on three different copper-based catalysts: Cu/Cr[sub 2]O[sub 3], Cu/MnO/Cr[sub 2]O[sub 3] and Cu/ZnO/Al[sub 2]O[sub 3]. Of these three catalysts, the Cu/ZnO/Al[sub 2]O[sub 3] exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H[sub 2]/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

Yates, I.C.; Satterfield, C.N.

1988-01-01T23:59:59.000Z

67

Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor  

DOE Patents [OSTI]

Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided.

Singleton, Alan H. (Marshall Township, Allegheny County, PA); Oukaci, Rachid (Allison Park, PA); Goodwin, James G. (Cranberry Township, PA)

1999-01-01T23:59:59.000Z

68

Processes and catalysts for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor  

DOE Patents [OSTI]

Processes and catalysts are disclosed for conducting Fischer-Tropsch synthesis in a slurry bubble column reactor (SBCR). One aspect of the invention involves the use of cobalt catalysts without noble metal promotion in an SBCR. Another aspect involves using palladium promoted cobalt catalysts in an SBCR. Methods for preparing noble metal promoted catalysts via totally aqueous impregnation and procedures for producing attrition resistant catalysts are also provided. 1 fig.

Singleton, A.H.; Oukaci, R.; Goodwin, J.G.

1999-08-17T23:59:59.000Z

69

A study of Fischer-Tropsch model compounds reacting over ZSM-5  

E-Print Network [OSTI]

. Anthony The decomposition of three Fischer-Tropsch model compounds, 1-decanol. decanal, and n-heptane, over ZSM-5 catalysts ion exchanged with nickel, zinc, and hydrogen was studied. The mechanisms of decomposition and the reaction kinetics... LITERATURE CITED 49 APPENDIX A CATALYST PREPARATION Nickel Exchange Hydrogen Exchange 51 51 51 Zinc Exchange X-ray Diffraction Pattern 52 53 Table of Contents (Continued) Page APPENDIX B RUN CONDITIONS AND PRODUCT DISTRIBUTIONS 54 APPENDIX C...

Riley, Mark Garner

1984-01-01T23:59:59.000Z

70

Simulation of Fischer-Tropsch Fixed-Bed Reactor in Different Reaction Media  

E-Print Network [OSTI]

-phase FTS in fixed-bed reactor as the liquid phase provides an optimum medium for the highly exothermic reaction due to its heat capacity and density [4]. Besides its excellent temperature control, this medium facilitates the in-situ extraction of heavy...] ( ) Co/MgO/SiO2 [20] ( ) Co/kieselguhr [21] ( ) Co/Al2O3 [22] 1.2.2 Commercial Scale Fischer-Tropsch Reactors FTS is an extremely exothermic process, which...

Bani Nasser, Laial Ahmad

2013-11-04T23:59:59.000Z

71

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: addition of i-butylene during the formation of methanol and/or higher alcohols directly from CO and H[sub 2] during slurry-phase Fischer-Tropsch; addition of i-butylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and addition of methanol to slurry phase FT synthesis making iso-olefins. During the seventh quarter we continued the shake down experiments for the SBCR and conducted an initial aborted run. We have also re-started experiments on Scheme 1, i.e., the addition of iso-butylene during CO hydrogenation. Using a dual bed arrangement, we have demonstrated the synthesis of MTBE from syngas and iso-butylene.

Marcelin, G.

1992-09-24T23:59:59.000Z

72

Calculation of Vapor-Liquid-Liquid Equilibria for the Fischer-Tropsch Reactor Effluents using Modified Peng-Robinson  

E-Print Network [OSTI]

Calculation of Vapor-Liquid-Liquid Equilibria for the Fischer- Tropsch Reactor Effluents using ignored the non-ideal phase equilibrium problem of a FT reactor. The rigorous calculation method is based A modified Peng­Robinson equation of state is used to develop the methods for calculating the thermodynamic

Skogestad, Sigurd

73

IMPROVED IRON CATALYSTS FOR SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

PureVision Technology, Inc. (PureVision) of Fort Lupton, Colorado is developing a process for the conversion of lignocellulosic biomass into fuel-grade ethanol and specialty chemicals in order to enhance national energy security, rural economies, and environmental quality. Lignocellulosic-containing plants are those types of biomass that include wood, agricultural residues, and paper wastes. Lignocellulose is composed of the biopolymers cellulose, hemicellulose, and lignin. Cellulose, a polymer of glucose, is the component in lignocellulose that has potential for the production of fuel-grade ethanol by direct fermentation of the glucose. However, enzymatic hydrolysis of lignocellulose and raw cellulose into glucose is hindered by the presence of lignin. The cellulase enzyme, which hydrolyzes cellulose to glucose, becomes irreversibly bound to lignin. This requires using the enzyme in reagent quantities rather than in catalytic concentration. The extensive use of this enzyme is expensive and adversely affects the economics of ethanol production. PureVision has approached this problem by developing a biomass fractionator to pretreat the lignocellulose to yield a highly pure cellulose fraction. The biomass fractionator is based on sequentially treating the biomass with hot water, hot alkaline solutions, and polishing the cellulose fraction with a wet alkaline oxidation step. In September 2001 PureVision and Western Research Institute (WRI) initiated a jointly sponsored research project with the U.S. Department of Energy (DOE) to evaluate their pretreatment technology, develop an understanding of the chemistry, and provide the data required to design and fabricate a one- to two-ton/day pilot-scale unit. The efforts during the first year of this program completed the design, fabrication, and shakedown of a bench-scale reactor system and evaluated the fractionation of corn stover. The results from the evaluation of corn stover have shown that water hydrolysis prior to alkaline hydrolysis may be beneficial in removing hemicellulose and lignin from the feedstock. In addition, alkaline hydrolysis has been shown to remove a significant portion of the hemicellulose and lignin. The resulting cellulose can be exposed to a finishing step with wet alkaline oxidation to remove the remaining lignin. The final product is a highly pure cellulose fraction containing less than 1% of the native lignin with an overall yield in excess of 85% of the native cellulose. This report summarizes the results from the first year's effort to move the technology to commercialization.

Dr. Dragomir B. Bukur; Dr. Lech Nowicki; Victor Carreto-Vazquez; Dr. Wen-Ping Ma

2001-11-28T23:59:59.000Z

74

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

2010-09-30T23:59:59.000Z

75

Fischer-Tropsch Synthesis: Characterization and Reaction Testing of Cobalt Carbide  

SciTech Connect (OSTI)

Hydrogenation of carbon monoxide was investigated for cobalt carbide synthesized from Co{sub 3}O{sub 4} by CO carburization in a fixed-bed reactor. The cobalt carbide synthesized was characterized by BET surface area, X-ray diffraction, scanning electron microscopy, X-ray absorption near edge spectroscopy, and extended X-ray absorption fine structure spectroscopy. The catalysts were tested in the slurry phase using a continuously stirred tank reactor at P = 2.0 MPa, H{sub 2}/CO = 2:1 in the temperature range of 493-523 K, and with space velocities varying from 1 to 3 Nl h{sup -1} g{sub cat}{sup -1}. The results strongly suggest that a fraction of cobalt converts to a form with greater metallic character under the conditions employed. This was more pronounced on a Fischer-Tropsch synthesis run conducted at a higher temperature (523 versus 493 K).

Khalid S.; Mohandas J.C.; Gnanamani M.K.; Jacobs G.; Ma W.; Ji Y.; Davis B.H.

2011-08-15T23:59:59.000Z

76

CALIFORNIA ALTERNATIVE FUELS MARKET ASSESSMENT  

E-Print Network [OSTI]

, Contract Manager Ray Tuvell, Manager EMERGING FUELS & TECHNOLOGY OFFICE Rosella Shapiro, Deputy Director gas, propane, ethanol, electricity, alternative diesel fuels such as biodiesel and Fischer Tropsch, natural gas vehicles, propane vehicles, electric vehicles, ethanol fuel, E-85, biodiesel, Fischer

77

Kinetic studies for elucidation of the promoter effect of alkali in Fischer-Tropsch iron catalysts  

SciTech Connect (OSTI)

The kinetics of the formation of hydrocarbons in Fischer-Tropsch synthesis and of consecutive reactions, i.e., hydrogenation and double bond isomerization of primarily formed 1-alkenes, were studied in a slurry-phase reactor using alkalized and nonalkalized precipitated iron catalysts. Both consecutive reactions have an order of about -2 with respect to carbon monoxide and an order of about 1 with respect to 1-alkenes. The order with respect to hydrogen is 1 for the hydrocarbon formation and also 1 for the consecutive hydrogenation, but 0 for the consecutive isomerization. The reaction orders are not changed by addition of K{sub 2}CO{sub 3} to the catalyst. The kinetics of consecutive reactions can be interpreted by competitive adsorption of 1-alkene and carbon monoxide. Alkali addition causes an increase in the strength of carbon monoxide adsorption and consequently a decrease in 1-alkene adsorption so that the rates of the consecutive reactions are reduced. This hypothesis could be proved by studies of 1-hexene hydrogenation in the presence and absence of carbon monoxide for alkalized and nonalkalized iron catalysts. The kinetics were studied in the ranges 1.3 < P{sub CO}(10{sup 5} Pa) < 7, 1.6 < P{sub H{sub 2}}(10{sup 5} Pa) < 9, and 490 K < T < 530 K.

Herzog, K.; Gaube, J. (Institut fuer Chemische Technologie der Technischen Hochschule Darmstadt, Darmstadt (West Germany))

1989-02-01T23:59:59.000Z

78

Baseline design/economics for advanced Fischer-Tropsch technology. Quarterly report, January--March 1992  

SciTech Connect (OSTI)

The objectives of the study are to: Develop a baseline design for indirect liquefaction using advanced Fischer-Tropsch (F-T) technology. Prepare the capital and operating costs for the baseline design. Develop a process flow sheet simulation (PFS) model. This report summarizes the activities completed during the period December 23, 1992 through March 15, 1992. In Task 1, Baseline Design and Alternates, the following activities related to the tradeoff studies were completed: approach and basis; oxygen purity; F-T reactor pressure; wax yield; autothermal reformer; hydrocarbons (C{sub 3}/C{sub 4}s) recovery; and hydrogenrecovery. In Task 3, Engineering Design Criteria, activities were initiated to support the process tradeoff studies in Task I and to develop the environmental strategy for the Illinois site. The work completed to date consists of the development of the F-T reactor yield correlation from the Mobil dam and a brief review of the environmental strategy prepared for the same site in the direct liquefaction baseline study.Some work has also been done in establishing site-related criteria, in establishing the maximum vessel diameter for train sizing and in coping with the low H{sub 2}/CO ratio from the Shell gasifier. In Task 7, Project Management and Administration, the following activities were completed: the subcontract agreement between Amoco and Bechtel was negotiated; a first technical progress meeting was held at the Bechtel office in February; and the final Project Management Plan was approved by PETC and issued in March 1992.

Not Available

1992-09-01T23:59:59.000Z

79

DEVELOPMENT OF A COMPUTATIONAL MULTIPHASE FLOW MODEL FOR FISCHER TROPSCH SYNTHESIS IN A SLURRY BUBBLE COLUMN REACTOR  

SciTech Connect (OSTI)

The Hybrid Energy Systems Testing (HYTEST) Laboratory is being established at the Idaho National Laboratory to develop and test hybrid energy systems with the principal objective to safeguard U.S. Energy Security by reducing dependence on foreign petroleum. A central component of the HYTEST is the slurry bubble column reactor (SBCR) in which the gas-to-liquid reactions will be performed to synthesize transportation fuels using the Fischer Tropsch (FT) process. SBCRs are cylindrical vessels in which gaseous reactants (for example, synthesis gas or syngas) is sparged into a slurry of liquid reaction products and finely dispersed catalyst particles. The catalyst particles are suspended in the slurry by the rising gas bubbles and serve to promote the chemical reaction that converts syngas to a spectrum of longer chain hydrocarbon products, which can be upgraded to gasoline, diesel or jet fuel. These SBCRs operate in the churn-turbulent flow regime which is characterized by complex hydrodynamics, coupled with reacting flow chemistry and heat transfer, that effect reactor performance. The purpose of this work is to develop a computational multiphase fluid dynamic (CMFD) model to aid in understanding the physico-chemical processes occurring in the SBCR. Our team is developing a robust methodology to couple reaction kinetics and mass transfer into a four-field model (consisting of the bulk liquid, small bubbles, large bubbles and solid catalyst particles) that includes twelve species: (1) CO reactant, (2) H2 reactant, (3) hydrocarbon product, and (4) H2O product in small bubbles, large bubbles, and the bulk fluid. Properties of the hydrocarbon product were specified by vapor liquid equilibrium calculations. The absorption and kinetic models, specifically changes in species concentrations, have been incorporated into the mass continuity equation. The reaction rate is determined based on the macrokinetic model for a cobalt catalyst developed by Yates and Satterfield [1]. The model includes heat generation due to the exothermic chemical reaction, as well as heat removal from a constant temperature heat exchanger. Results of the CMFD simulations (similar to those shown in Figure 1) will be presented.

Donna Post Guillen; Tami Grimmett; Anastasia M. Gribik; Steven P. Antal

2010-09-01T23:59:59.000Z

80

Synthesis of octane enhancer during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 4, July 1, 1991--September 30, 1991  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1991-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


81

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 5, October 1, 1991--December 31, 1991  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1992-06-10T23:59:59.000Z

82

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 3, April 1, 1991--June 30, 1991  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butytl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch; (2) addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and, (3) addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1991-10-15T23:59:59.000Z

83

SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES  

SciTech Connect (OSTI)

In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. In this reporting period, a series of crossflow filtration experiments were initiated to study the effect of olefins and oxygenates on the filtration flux and membrane performance. Iron-based FTS reactor waxes contain a significant amount of oxygenates, depending on the catalyst formulation and operating conditions. Mono-olefins and aliphatic alcohols were doped into an activated iron catalyst slurry (with Polywax) to test their influence on filtration properties. The olefins were varied from 5 to 25 wt% and oxygenates from 6 to 17 wt% to simulate a range of reactor slurries reported in the literature. The addition of an alcohol (1-dodecanol) was found to decrease the permeation rate while the olefin added (1-hexadecene) had no effect on the permeation rate. A passive flux maintenance technique was tested that can temporarily increase the permeate rate for 24 hours.

James K. Neathery; Gary Jacobs; Burtron H. Davis

2005-03-31T23:59:59.000Z

84

SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES  

SciTech Connect (OSTI)

In this reporting period, a fundamental filtration study was continued to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The shakedown phase of the pilot-scale filtration platform was completed at the end of the last reporting period. A study of various molecular weight waxes was initiated to determine the effect of wax physical properties on the permeation rate without catalyst present. As expected, the permeation flux was inversely proportional to the nominal average molecular weight of the polyethylene wax. Even without catalyst particles present in the filtrate, the filtration membranes experience fouling during an induction period on the order of days on-line. Another long-term filtration test was initiated using a batch of iron catalyst that was previously activated with CO to form iron carbide in a separate continuous stirred tank reactor (CSTR) system. The permeation flux stabilized more rapidly than that experienced with unactivated catalyst tests.

James K. Neathery; Gary Jacobs; Burtron H. Davis

2004-09-30T23:59:59.000Z

85

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles  

SciTech Connect (OSTI)

In this reporting period, a study of ultra-fine iron catalyst filtration was initiated to study the behavior of ultra-fine particles during the separation of Fischer-Tropsch Synthesis (FTS) liquids filtration. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The change of particle size during the slurry-phase FTS has monitored by withdrawing catalyst sample at different TOS. The measurement of dimension of the HRTEM images of samples showed a tremendous growth of the particles. Carbon rims of thickness 3-6 nm around the particles were observed. This growth in particle size was not due to carbon deposition on the catalyst. A conceptual design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. The system will utilize a primary inertial hydroclone followed by a Pall Accusep cross-flow membrane. Provisions for cleaned permeate back-pulsing will be included to as a flux maintenance measure.

James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

2005-09-30T23:59:59.000Z

86

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

87

Synthetic Fuel  

ScienceCinema (OSTI)

Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

2010-01-08T23:59:59.000Z

88

Effect of Surface Modification by Chelating Agents on Fischer- Tropsch Performance of Co/SiO{sub 2} Catalysts  

SciTech Connect (OSTI)

The silica support of a Co-based catalyst for Fischer-Tropsch (FT) synthesis was modified by the chelating agents (CAs) nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA). After the modification, characterization of the fresh and spent catalysts show reduced crystallite sizes, a better-dispersed Co{sub 3}O{sub 4} phase on the calcined samples, and increased metal dispersions for the reduced samples. The CA-modified catalysts display higher CO conversions, product yields, reaction rates and rate constants. The improved FT performance of CA-modified catalysts is attributed to the formation of stable complexes with Co. The superior performance of the EDTA-modified catalyst in comparison to the NTA-modified catalyst is due to the higher affinity of the former for complex formation with Co ions.

Bambal, Ashish S.; Kugler, Edwin L.; Gardner, Todd H.; Dadyburjor, Dady B.

2013-11-27T23:59:59.000Z

89

Potential for Coal-to-Liquids Conversion in the United States--FischerTropsch Synthesis  

E-Print Network [OSTI]

Potential for Coal-to-Liquids Conversion in the United States--Fischer­Tropsch Synthesis Tad W-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create that coal into a synthetic liquid fuel, or synfuel. The plan is con- troversial, but Gov. Schweitzer ­ half

Patzek, Tadeusz W.

90

Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst. [Quarterly] report, June 30, 1988--September 30, 1988  

SciTech Connect (OSTI)

This report details experiments performed on three different copper-based catalysts: Cu/Cr{sub 2}O{sub 3}, Cu/MnO/Cr{sub 2}O{sub 3} and Cu/ZnO/Al{sub 2}O{sub 3}. Of these three catalysts, the Cu/ZnO/Al{sub 2}O{sub 3} exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H{sub 2}/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.

Yates, I.C.; Satterfield, C.N.

1988-12-31T23:59:59.000Z

91

Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts  

SciTech Connect (OSTI)

Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

2010-12-31T23:59:59.000Z

92

Fischer-Tropsch slurry phase process variations to understand wax formations: Quarterly report for period October 1, 1987 to December 31, 1987  

SciTech Connect (OSTI)

Effects of high syngas conversion on the secondary reactions of olefins formed by Fischer-Tropsch synthesis on a reduced fused magnetite catalyst were simulated by studies of olefins in the presence of hydrogen and low concentrations of CO, or none at all. kinetic models were developed for the effect of CO partial pressure on hydrogenation rates at 232)degree)C and 0.30 to 0.79 MPa. In the absence of carbon monoxide, olefin hydrogenation was more rapid than in its presence. A model indicated that a hydrogenated carbon monoxide species on the catalyst may be responsible for the inhibition of olefin hydrogenation, and that olefin adsorption is rate-limiting. The formation of secondary olefins appeared to follow similar trends with carbon monoxide partial pressure. Olefin incorporation was not observed in the small amount of Fischer-Tropsch products obtained in these experiments. The chain growth probability, alpha, appeared to correlate with the H/sub 2/CO feed ratio. 14 refs., 13 figs., 1 tab.

Satterfield, C.N.

1987-01-01T23:59:59.000Z

93

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 6, January 1, 1992--March 31, 1992  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

94

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 7, April 1, 1992--June 30, 1992  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: addition of i-butylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch; addition of i-butylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst; and addition of methanol to slurry phase FT synthesis making iso-olefins. During the seventh quarter we continued the shake down experiments for the SBCR and conducted an initial aborted run. We have also re-started experiments on Scheme 1, i.e., the addition of iso-butylene during CO hydrogenation. Using a dual bed arrangement, we have demonstrated the synthesis of MTBE from syngas and iso-butylene.

Marcelin, G.

1992-09-24T23:59:59.000Z

95

The upgrading of Fischer-Tropsch liquids over ZSM-5 using model compounds  

E-Print Network [OSTI]

. Using the synthetic oxygenate mixture the selectivity of aromatics and LPG increasec with temperature at the expense of lower olerins and C5+ oils. The methane selectivity was very low. At a temperature of 573 K the aromatic yield was 5. s weight.... 1 percent LPG. The remainder was ethylene, propylene, and a small amount of 23 methane. The 1-butane however yielcea 30. 1 precent aromatics, 27. 3 percent oils ana 32. 3 percent LPG. The increase in aromatic yiela from 1-butene when compared...

Smith, David Duane

1982-01-01T23:59:59.000Z

96

Platinum-Modulated Cobalt Nanocatalysts for Low-Temperature Aqueous-Phase Fischer-Tropsch Synthesis  

E-Print Network [OSTI]

catalytic process for liquid fuel generation, which converts coal/shale gas/biomass-derived syngas (a century. Since it is now possible to use diverse resources, such as coal, biomass, and shale gas Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academic of Sciences, Dalian, 116023

Li, Weixue

97

KINETIC MODELING OF A FISCHER-TROPSCH REACTION OVER A COBALT CATALYST IN A SLURRY BUBBLE COLUMN REACTOR FOR INCORPORATION INTO A COMPUTATIONAL MULTIPHASE FLUID DYNAMICS MODEL  

SciTech Connect (OSTI)

Currently multi-tubular fixed bed reactors, fluidized bed reactors, and slurry bubble column reactors (SBCRs) are used in commercial Fischer Tropsch (FT) synthesis. There are a number of advantages of the SBCR compared to fixed and fluidized bed reactors. The main advantage of the SBCR is that temperature control and heat recovery are more easily achieved. The SBCR is a multiphase chemical reactor where a synthesis gas, comprised mainly of H2 and CO, is bubbled through a liquid hydrocarbon wax containing solid catalyst particles to produce specialty chemicals, lubricants, or fuels. The FT synthesis reaction is the polymerization of methylene groups [-(CH2)-] forming mainly linear alkanes and alkenes, ranging from methane to high molecular weight waxes. The Idaho National Laboratory is developing a computational multiphase fluid dynamics (CMFD) model of the FT process in a SBCR. This paper discusses the incorporation of absorption and reaction kinetics into the current hydrodynamic model. A phased approach for incorporation of the reaction kinetics into a CMFD model is presented here. Initially, a simple kinetic model is coupled to the hydrodynamic model, with increasing levels of complexity added in stages. The first phase of the model includes incorporation of the absorption of gas species from both large and small bubbles into the bulk liquid phase. The driving force for the gas across the gas liquid interface into the bulk liquid is dependent upon the interfacial gas concentration in both small and large bubbles. However, because it is difficult to measure the concentration at the gas-liquid interface, coefficients for convective mass transfer have been developed for the overall driving force between the bulk concentrations in the gas and liquid phases. It is assumed that there are no temperature effects from mass transfer of the gas phases to the bulk liquid phase, since there are only small amounts of dissolved gas in the liquid phase. The product from the incorporation of absorption is the steady state concentration profile of the absorbed gas species in the bulk liquid phase. The second phase of the model incorporates a simplified macrokinetic model to the mass balance equation in the CMFD code. Initially, the model assumes that the catalyst particles are sufficiently small such that external and internal mass and heat transfer are not rate limiting. The model is developed utilizing the macrokinetic rate expression developed by Yates and Satterfield (1991). Initially, the model assumes that the only species formed other than water in the FT reaction is C27H56. Change in moles of the reacting species and the resulting temperature of the catalyst and fluid phases is solved simultaneously. The macrokinetic model is solved in conjunction with the species transport equations in a separate module which is incorporated into the CMFD code.

Anastasia Gribik; Doona Guillen, PhD; Daniel Ginosar, PhD

2008-09-01T23:59:59.000Z

98

Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts  

SciTech Connect (OSTI)

Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120�, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230�, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky Center for Applied Energy Research (UK-CAER) led by Dr. Burt Davis. We first conducted a detailed thermodynamic analysis. The three primary mechanisms whereby the contaminants may deactivate the catalyst are condensation, deposition, and reaction. AsH{sub 3}, PH{sub 3}, H{sub 2}S, HCl, NH{sub 3} and HCN were found to have a major impact on the Fe-FT catalyst by producing reaction products, while NaCl, KCl and PH{sub 3} produce trace amounts of deposition products. The impact of the contaminants on the activity, selectivity, and deactivation rates (lifetime) of the catalysts was determined in bench-scale tests. Most of the contaminants appeared to adsorb onto (or react with) the HT- and LT-WGS catalysts were they were co-fed with the syngas: � 4.5 ppmv AsH{sub 3} or 1 ppmv PH{sub 3} in the syngas impacted the selectivity and CO conversion of both catalysts; � H{sub 2}S slowly degraded both WGS catalysts; - A binary mixture of H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv) impacted the activity of the LT-WGS catalyst, but not the HT-WGS catalyst � Moderate levels of NH{sub 3} (100 ppmv) or HCN (10 ppmv) had no impact � NaCl or KCl had essentially no effect on the HT-WGS catalyst, but the activity of the LT-WGS catalyst decreased very slowly Long-term experiments on the Co-FT catalyst at 260 and 270 °C showed that all of the contaminants impacted it to some extent with the exception of NaCl and HF. Irrespective of its source (e.g., NH{sub 3}, KNO{sub 3}, or HNO{sub 3}), ammonia suppressed the activity of the Co-FT catalyst to a moderate degree. There was essentially no impact the Fe-FT catalyst when up to 100 ppmw halide compounds (NaCl and KCl), or up to 40 ppmw alkali bicarbonates (NaHCO{sub 3} and KHCO{sub 3}). After testing, BET analysis showed that the surface areas, and pore volumes and diameters of both WGS catalysts decreased during both single and binary H2S and NH3 tests, which was attributed to sintering and pore filling by the impurities. The HT-WGS catalyst was evaluated with XRD after testing in syngas that contained 1 ppmv PH{sub 3}, or 2 ppmv H{sub 2}S, or both H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv). The peaks became sharper during testing, which was indicative of crystal growth and sintering, but no new phases were detected. After LT-WGS tests (3-33 ppmv NH{sub 3} and/or 0-88 ppmv H{sub 2}S) there were a few new phases that appeared, including sulfides. The fresh Fe-FT catalyst was nanocrystalline and amorphous. ICP-AA spectroscopy and other methods (e.g., chromatography) were used to analyze for

Gokhan Alptekin

2012-09-30T23:59:59.000Z

99

Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potential and Policies  

E-Print Network [OSTI]

to create a synthetic bio- based fuel that is chemicallyBoeing/NASA Synthetic bio-based fuels, Fischer-Tropsch (FT)ICAO 2009b). Synthetic bio-based fuels include bio-based jet

McCollum, David L; Gould, Gregory; Greene, David L

2010-01-01T23:59:59.000Z

100

Six-flow operations for catalyst development in Fischer-Tropsch synthesis: Bridging the gap between high-throughput experimentation and extensive product evaluation  

SciTech Connect (OSTI)

Design and operation of a “six-flow fixed-bed microreactor” setup for Fischer-Tropsch synthesis (FTS) is described. The unit consists of feed and mixing, flow division, reaction, separation, and analysis sections. The reactor system is made of five heating blocks with individual temperature controllers, assuring an identical isothermal zone of at least 10 cm along six fixed-bed microreactor inserts (4?mm inner diameter). Such a lab-scale setup allows running six experiments in parallel, under equal feed composition, reaction temperature, and conditions of separation and analysis equipment. It permits separate collection of wax and liquid samples (from each flow line), allowing operation with high productivities of C5+ hydrocarbons. The latter is crucial for a complete understanding of FTS product compositions and will represent an advantage over high-throughput setups with more than ten flows where such instrumental considerations lead to elevated equipment volume, cost, and operation complexity. The identical performance (of the six flows) under similar reaction conditions was assured by testing a same catalyst batch, loaded in all microreactors.

Sartipi, Sina, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Jansma, Harrie; Bosma, Duco; Boshuizen, Bart; Makkee, Michiel; Gascon, Jorge, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Kapteijn, Freek [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)] [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)

2013-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. Spectroscopic studies of zeolites  

SciTech Connect (OSTI)

Two recent developments in zeolite synthesis and modification were successfully combined to demonstrate a new approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for use as catalysts in Fischer-Tropsch conversions. The steps are: (1) synthesis of an aluminoferrisilicate zeolite having the ZSM-5-type structure; (2) removal of the organic base template incorporated in the channel system during synthesis; (3) formation of a polycyano inclusion compound in the AFS zeolite; and (4) reduction of the inclusion compound by hydrogen at approx. 400/sup 0/C. PAS and EPR spectroscopy have been used to establish that the as-synthesized AFS zeolite contains Fe/sup 3 +/ ions in both framework and non-framework sites. FMR spectroscopy has been used to confirm the formation of the metallic (Fe) and bimetallic (Fe/Ru and Fe/Co) particles as products of the reduction of the inclusion compounds by hydrogen. The application of other spectroscopic techniques in recent studies of cations, complexes, and metal particles in zeolites is reviewed: high-resolution solid-state NMR, nuclear-spin-relaxation studies, FMR, EXAFS, and XANES.

Iton, L.E.; Beal, R.B.; Hodul, D.T.

1983-01-01T23:59:59.000Z

102

Fischer-Tropsch Fuels from Coal and Biomass Thomas G. Kreutz, Eric D. Larson, Guangjian Liu, Robert H. Williams  

E-Print Network [OSTI]

...................................................................................................................................8 2.2.2 Biomass as feedstock

103

Comparative Analysis of the Production Costs and Life-Cycle GHG Emissions of FT-Liquid Fuels from Coal and  

E-Print Network [OSTI]

Coal and Natural Gas Figure S1 shows a graphical description of the life cycle of coal-to-liquids (CTL) and gas-to-liquids (GTL). Figure S1: Life Cycle of Coal-Based and Natural Gas-Based Fischer-Tropsch LiquidComparative Analysis of the Production Costs and Life- Cycle GHG Emissions of FT-Liquid Fuels from

Jaramillo, Paulina

104

Economical utilization of natural gas to produce synthetic petroleum liquids  

SciTech Connect (OSTI)

A new process for converting pipeline quality or subquality natural gas into liquid fuels and other petroleum products is described. The technology, developed by Syntroleum Corporation, utilizes autothermal reforming with air to produce a nitrogen-diluted synthesis gas having a near ideal ratio for converting into synthetic hydrocarbons via Fischer-Tropsch (F-T) synthesis. A proprietary F-T catalyst system, designed to operate in a nitrogen-diluted atmosphere, achieves conversion rates comparable to conventional F-T processes without the need for recycle and the associated recompression equipment. This results in potential plant capital costs low enough to make conversion of remote and or subquality gas into synthetic fuels economical, based on current oil prices. The process is energy self-sufficient and compact enough to be constructed in 5,000 to 10,000 b/d plants on floating or platform facilities to utilize offshore gas reserves. The liquid fuels produced by the process are free of sulfur and aromatics. The process has been demonstrated at pilot-scale. Numerous engineering studies and cost estimates have been conducted to provide the information needed for economic evaluation and confident scale-up. This paper also outlines improvements to the process currently under development and how the process presents new opportunities for gas processors.

Agee, K.L.; Agee, M.A. [Syntroleum Corp., Tulsa, OK (United States); Willingham, F.Y.; Trepper, E.L. [Bateman Engineering, Inc., Denver, CO (United States)

1996-12-31T23:59:59.000Z

105

Future Prospects of Synthetic Fuels  

E-Print Network [OSTI]

It is important for the future of this nation to reach the goal of demonstrated definition and quantification of the parameters which influence the ability to use this country's vast resources of coal and oil shale for production of synthetic fuels...

Fryback, M. G.

1982-01-01T23:59:59.000Z

106

Effect of carbon coating on scuffing performance in diesel fuels  

SciTech Connect (OSTI)

Low-sulfur and low-aromatic diesel fuels are being introduced in order to reduce various types of emissions in diesel engines to levels in compliance with current and impending US federal regulations. The low lubricity of these fuels, however, poses major reliability and durability problems for fuel injection components that depend on diesel fuel for their lubrication. In the present study, the authors evaluated the scuff resistance of surfaces in regular diesel fuel containing 500 ppm sulfur and in Fischer-Tropsch synthetic diesel fuel containing no sulfur or aromatics. Tests were conducted with the high frequency reciprocating test rig (HFRR) using 52100 steel balls and H-13 tool-steel flats with and without Argonne's special carbon coatings. Test results showed that the sulfur-containing fuels provide about 20% higher scuffing resistance than does fuel without sulfur. Use of the carbon coating on the flat increased scuffing resistance in both regular and synthetic fuels by about ten times, as measured by the contact severity index at scuffing. Scuffing failure in tests conducted with coated surfaces did not occur until the coating had been removed by the two distinct mechanisms of spalling and wear.

Ajayi, O. O.; Alzoubi, M. F.; Erdemir, A.; Fenske, G. R.

2000-06-29T23:59:59.000Z

107

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

2011-09-30T23:59:59.000Z

108

Synthetic carbonaceous fuels and feedstocks  

DOE Patents [OSTI]

This invention relates to the use of a three compartment electrolytic cell in the production of synthetic carbonaceous fuels and chemical feedstocks such as gasoline, methane and methanol by electrolyzing an aqueous sodium carbonate/bicarbonate solution, obtained from scrubbing atmospheric carbon dioxide with an aqueous sodium hydroxide solution, whereby the hydrogen generated at the cathode and the carbon dioxide liberated in the center compartment are combined thermocatalytically into methanol and gasoline blends. The oxygen generated at the anode is preferably vented into the atmosphere, and the regenerated sodium hydroxide produced at the cathode is reused for scrubbing the CO.sub.2 from the atmosphere.

Steinberg, Meyer (Huntington Station, NY)

1980-01-01T23:59:59.000Z

109

Enhanced catalyst for conversion of syngas to liquid motor fuels  

DOE Patents [OSTI]

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

1985-01-01T23:59:59.000Z

110

Enhanced conversion of syngas to liquid motor fuels  

DOE Patents [OSTI]

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

1986-01-01T23:59:59.000Z

111

Enhanced catalyst for conversion of syngas to liquid motor fuels  

DOE Patents [OSTI]

Synthesis gas comprising carbon monoxide and hydrogen is converted to C[sub 5][sup +] hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising a SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, P.K.; Rabo, J.A.

1985-12-03T23:59:59.000Z

112

Shape-selective catalysts for Fischer-Tropsch chemistry : iron-containing particulate catalysts. Activity report : January 1, 2001 - December 31, 2004.  

SciTech Connect (OSTI)

Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry--specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. It is desired that selectivity be directed toward producing diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. The goal is to produce shape-selective catalysts that have the potential to limit the formation of longchain products and yet retain the active metal sites in a protected 'cage'. This cage also restricts their loss by attrition during use in slurry-bed reactors. The first stage of this program was to prepare and evaluate iron-containing particulate catalysts. This activity report centers upon this first stage of experimentation with particulate FT catalysts. (For reference, a second experimental stage is under way to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes.) To date, experimentation has centered upon the evaluation of a sample of iron-based, spray-dried catalyst prepared by B.H. Davis of the Center of Applied Energy Research (CAER) and samples of his catalyst onto which inorganic 'shells' were deposited. The reference CAER catalyst contained a high level of dispersed fine particles, a portion of which was removed by differential settling. Reaction conditions have been established using a FT laboratory unit such that reasonable levels of CO conversion can be achieved, where therefore a valid catalyst comparison can be made. A wide range of catalytic activities was observed with SiO{sub 2}-coated FT catalysts. Two techniques were used for SiO{sub 2}coating. The first involved a caustic precipitation of SiO{sub 2} from an organo-silicate onto the CAER catalyst. The second was the acidic precipitation of an organo-silicate with aging to form fractal particles that were then deposited onto the CAER catalyst. Several resulting FT catalysts were as active as the coarse catalyst on which they were prepared. The most active ones were those with the least amount of coating, namely about 2.2 wt% SiO{sub 2}. In the case of the latter acid technique, the use of HCl and HNO{sub 3} was much more effective than that of H{sub 2}SO{sub 4}. Scanning electron microscopy (SEM) was used to observe and analyze as-received and treated FT catalysts. It was observed that (1) spherical particles of CAER FT catalyst were made up of agglomerates of particles that were, in turn, also agglomerates; (2) the spray drying process of CAER apparently concentrated the Si precursor at the surface during drying; (3) while SEM pointed out broad differences in the appearance of the prepared catalyst particles, there was little indication that the catalysts were being uniformly coated with a cage-like protective surface, with perhaps the exception of HNO{sub 3}-precipitated catalyst; and (4) there was only a limited penetration of carbon (i.e., CO) into the FT catalyst during the conditioning and FT reaction steps.

Cronauer, D.; Chemical Engineering

2006-05-12T23:59:59.000Z

113

Shape-selective catalysts for Fischer-Tropsch chemistry : atomic layer deposition of active catalytic metals. Activity report : January 1, 2005 - September 30, 2005.  

SciTech Connect (OSTI)

Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry - specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. The broad goal is to produce diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. Originally the goal was to prepare shape-selective catalysts that would limit the formation of long-chain products and yet retain the active metal sites in a protected 'cage.' Such catalysts were prepared with silica-containing fractal cages. The activity was essentially the same as that of catalysts without the cages. We are currently awaiting follow-up experiments to determine the attrition strength of these catalysts. A second experimental stage was undertaken to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes and particulate supports. The concept was that of depositing active metals (i.e. ruthenium, iron or cobalt) upon membranes with well defined flow channels of small diameter and length such that the catalytic activity and product molecular weight distribution could be controlled. In order to rapidly evaluate the catalytic membranes, the ALD coating processes were performed in an 'exploratory mode' in which ALD procedures from the literature appropriate for coating flat surfaces were applied to the high surface area membranes. Consequently, the Fe and Ru loadings in the membranes were likely to be smaller than those expected for complete monolayer coverage. In addition, there was likely to be significant variation in the Fe and Ru loading among the membranes due to difficulties in nucleating these materials on the aluminum oxide surfaces. The first series of experiments using coated membranes demonstrated that the technology needed further improvement. Specifically, observed catalytic FT activity was low. This low activity appeared to be due to: (1) low available surface area, (2) atomic deposition techniques that needed improvements, and (3) insufficient preconditioning of the catalyst surface prior to FT testing. Therefore, experimentation was expanded to the use of particulate silica supports having defined channels and reasonably high surface area. This later experimentation will be discussed in the next progress report. Subsequently, we plan to evaluate membranes after the ALD techniques are improved with a careful study to control and quantify the Fe and Ru loadings. The preconditioning of these surfaces will also be further developed. (A number of improvements have been made with particulate supports; they will be discussed in the subsequent report.) In support of the above, there was an opportunity to undertake a short study of cobalt/promoter/support interaction using the Advanced Photon Source (APS) of Argonne. Five catalysts and a reference cobalt oxide were characterized during a temperature programmed EXAFS/XANES experimental study with the combined effort of Argonne and the Center for Applied Energy Research (CAER) of the University of Kentucky. This project was completed, and it resulted in an extensive understanding of the preconditioning step of reducing Co-containing FT catalysts. A copy of the resulting manuscript has been submitted and accepted for publication. A similar project was undertaken with iron-containing FT catalysts; the data is currently being studied.

Cronauer, D. C. (Chemical Sciences and Engineering Division)

2011-04-15T23:59:59.000Z

114

Catalyst for converting synthesis gas to liquid motor fuels  

DOE Patents [OSTI]

The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

Coughlin, Peter K. (Yorktown Heights, NY)

1986-01-01T23:59:59.000Z

115

Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report  

SciTech Connect (OSTI)

Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested. Task 3: Chemical Synthesis: Promising process routes will be identified for synthesis of selected chemicals from biomass-derived syngas. A project milestone was to select promising mixed alcohol catalysts and screen productivity and performance in a fixed bed micro-reactor using bottled syngas. This milestone was successfully completed in collaboration withour catalyst development partner. Task 4: Modeling, Engineering Evaluation, and Commercial Assessment: Mass and energy balances of conceptual commercial embodiment for FT and chemical synthesis were completed.

David C. Dayton

2010-03-24T23:59:59.000Z

116

Catalyst and process for converting synthesis gas to liquid motor fuels  

DOE Patents [OSTI]

The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

Coughlin, Peter K. (Yorktown Heights, NY)

1987-01-01T23:59:59.000Z

117

Synthetic fuel production by indirect coal liquefaction  

E-Print Network [OSTI]

Synthetic fuel production by indirect coal liquefaction Eric D. Larson Princeton Environmental@princeton.edu Ren Tingjin Department of Thermal Engineering, Tsinghua University, 100084 Beijing, China This paper reports detailed process designs and cost assessments for production of clean liquid fuels (methanol

118

SWRI notes synthetic fuels capabilities  

SciTech Connect (OSTI)

A report is given of the test facilities developed by the Southwest Research Institute of San Antonio, Texas. Briefly described are a combustion bomb system for the study of the ignition quality of fuels for diesel engines; a variable compression ratio, direct injection, small cylinder engine allowing photography and monitoring of fuel combustion; a mathematical model which predicts cetane number from NMR measurements; another model for blending alcohols and gasoline to specified fuel properties; and a single cylinder, four stroke diesel engine representative of railroad and marine engines, the only engine of this size and speed range available for research in the US.

Not Available

1987-03-01T23:59:59.000Z

119

ULTRACLEAN FUELS PRODUCTION AND UTILIZATION FOR THE TWENTY-FIRST CENTURY: ADVANCES TOWARDS SUSTAINABLE TRANSPORTATION FUELS  

SciTech Connect (OSTI)

Ultraclean fuels production has become increasingly important as a method to help decrease emissions and allow the introduction of alternative feed stocks for transportation fuels. Established methods, such as Fischer-Tropsch, have seen a resurgence of interest as natural gas prices drop and existing petroleum resources require more intensive clean-up and purification to meet stringent environmental standards. This review covers some of the advances in deep desulfurization, synthesis gas conversion into fuels and feed stocks that were presented at the 245th American Chemical Society Spring Annual Meeting in New Orleans, LA in the Division of Energy and Fuels symposium on "Ultraclean Fuels Production and Utilization".

Fox, E.

2013-06-17T23:59:59.000Z

120

Production of synthetic hydrocarbon fuels from peat  

SciTech Connect (OSTI)

A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.

Bodle, W.W.; Punwani, D.; Weil, S.A.

1982-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals  

SciTech Connect (OSTI)

This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for feedstocks consisting of synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch Synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based FT catalysts with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During the fifth reporting period, we studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influenced the performance of these materials in the Fischer-Tropsch synthesis. We also continued our studies of the kinetic behavior of these materials. Specifically, the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch Synthesis reactions led us to propose a new sequence of elementary steps on Fe and Co Fischer-Tropsch catalysts. More specifically, we were focused on the roles of hydrogen-assisted and alkali-assisted dissociation of CO in determining rates and CO{sub 2} selectivities. During this sixth reporting period, we have studied the validity of the mechanism that we propose by analyzing the H{sub 2}/D{sub 2} kinetic isotope effect (r{sub H}/r{sub D}) over a conventional iron-based Fischer-Tropsch catalyst Fe-Zn-K-Cu. We have observed experimentally that the use of D{sub 2} instead of H{sub 2} leads to higher hydrocarbons formation rates (inverse kinetic isotopic effect). On the contrary, primary carbon dioxide formation is not influenced. These experimental observations can be explained by the two CO activation pathways we propose. During this reporting period, the experimental kinetic study has been also complemented with periodic, self-consistent, DFT-GGA investigations in a parallel collaboration with the group of Manos Mavrikakis at the University of Wisconsin-Madison. These DFT calculations suggest minimal energy paths for proposed elementary steps on Fe(110) and Co(0001) surfaces. These calculations support our novel conclusions about the preferential dissociation of CO dissociation via H-assisted pathways on Fe-based catalysts. Unassisted CO dissociation also occurs and lead to the formation of CO{sub 2} as a primary oxygen scavenging mechanism after CO dissociation on Fe-based catalysts. Simulations and our experimental data show also that unassisted CO dissociation route is much less likely on Co surfaces and that hydrocarbons form exclusively via H-assisted pathways with the formation of H{sub 2}O as the sole oxygen rejection product. We have also started a study of the use of colloidal precipitation methods for the synthesis of small Fe and Co clusters using recently developed methods to explore possible further improvements in Fischer-Tropsch synthesis rates and selectivities. We have found that colloidal synthesis makes possible the preparation of small cobalt particles, although large amount of cobalt silicate species, which are difficult to reduce, are formed. The nature of the cobalt precursor and the modification of the support seem to be critical parameters in order to obtain highly dispersed and reducible Co nanoparticles.

Akio; Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

2006-09-30T23:59:59.000Z

122

Fusion: an energy source for synthetic fuels  

SciTech Connect (OSTI)

The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and supplement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Depending on design, electric generation efficiencies of approx. 40 to 60% and hydrogen production efficiencies by high temperature electrolysis of approx. 50 to 70% are projected for fusion reactors using high temperature blankets. Fusion/coal symbiotic systems appear economically promising for the first generation of commercial fusion synfuels plants. Coal production requirements and the environmental effects of large-scale coal usage would be greatly reduced by a fusion/coal system. In the long term, there could be a gradual transition to an inexhaustible energy system based solely on fusion.

Fillo, J A; Powell, J; Steinberg, M

1980-01-01T23:59:59.000Z

123

Methods, systems, and devices for deep desulfurization of fuel gases  

DOE Patents [OSTI]

A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

2012-04-17T23:59:59.000Z

124

Multi-stage Fischer-Tropsch process  

SciTech Connect (OSTI)

A process is described for producing paraffinic hydrocarbons from carbon monoxide and hydrogen comprising: (a) introducing carbon monoxide and hydrogen into a reaction zone wherein the carbon monoxide and hydrogen contact in a first bed a first catalyst having a high olefin selectivity selected from the group consisting of Fe/Ce/Zn/K, Fe/Mn/K and Fe/Co/K; and (b) contacting the resulting olefin in a second bed with a second catalyst having a high selectivity for converting olefins to heavier paraffinic hydrocarbons selected from the group consisting of Ru/TiO/sub 2/, Ru/SiO/sub 2/ and Ru/Al/sub 2/O/sub 3/.

Kim, C.J.; Fiato, R.A.

1986-11-25T23:59:59.000Z

125

Catalysts for conversion of syngas to liquid motor fuels  

DOE Patents [OSTI]

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

Rabo, Jule A. (Armonk, NY); Coughlin, Peter K. (Yorktown Heights, NY)

1987-01-01T23:59:59.000Z

126

Alternatives to diesel fuel in California - fuel cycle energy and emission effects of possible replacements due to the TAC diesel particulate decision.  

SciTech Connect (OSTI)

Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible mid-course strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression-ignition by spark-ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21% above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7% above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case the authors estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOX emissions, though all scenarios bring about PM{sub 10} reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

Saricks, C. L.; Rote, D. M.; Stodolsky, F.; Eberhardt, J. J.

1999-12-03T23:59:59.000Z

127

Alternatives to Diesel Fuel in California - Fuel Cycle Energy and Emission Effects of Possible Replacements Due to the TAC Diesel Particulate Decision  

SciTech Connect (OSTI)

Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression ignition by spark ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7 percent above projected (total) consumption level. In the second case, ressionignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOx emissions, though all scenarios bring about PM10 reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

Christopher L. Saraicks; Donald M. Rote; Frank Stodolsky; James J. Eberhardt

2000-05-01T23:59:59.000Z

128

Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass  

SciTech Connect (OSTI)

This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

Huffman, Gerald

2012-12-31T23:59:59.000Z

129

EIS-0357- Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA  

Broader source: Energy.gov [DOE]

This Environmental Impact Statement (EIS) assesses the potential environmental impacts that would result from a proposed Department of Energy (DOE) action to provide cost-shared funding for construction and operation of facilities near Gilberton, Pennsylvania, which have been proposed by WMPI PTY, LLC, for producing electricity, steam, and liquid fuels from anthracite coal waste (culm). The project was selected by DOE under the Clean Coal Power Initiative (CCPI) to demonstrate the integration of coal waste gasification and Fischer-Tropsch (F-T) synthesis of liquid hydrocarbon fuels at commercial scale.

130

Naphthenic acid corrosion in synthetic fuels production  

SciTech Connect (OSTI)

Serious corrosion damage to carbon steel piping in a fractionation unit associated with synthetic fuels production has been ascribed to the presence of naphthenic acids. Investigation of the problem revealed total acids numbers (TAN) ranging from 8--12mg KOH/g in the feed to the unit. Damage typically occurred in the temperature range 180--240 C and manifested as localized pitting, preferential weld corrosion, general wall thinning and end-grain attack. Filming amine corrosion inhibitors designed for refinery overhead systems have been proven ineffective and high temperature phosphate-based inhibitors could not be used due to potential catalyst poisoning in downstream refinery units. Coupon exposures indicated corrosion rates in the order of 2 mm/y on carbon steel in a reboiler line as well as pitting to austenitic stainless steel type UNS S30403. Line replacement in austenitic stainless steel UNS S31603 has been proven effective. The performance of this alloy is mainly ascribed to its molybdenum content. The absence of sulfur in the feed to the unit is also contributing to the alloy performance despite the extremely high total acid numbers.

Bruyn, H.I. de [Mossgas Ltd., Mossel Bay (South Africa)

1998-12-31T23:59:59.000Z

131

Synthetic fuels handbook: properties, process and performance  

SciTech Connect (OSTI)

The handbook is a comprehensive guide to the benefits and trade-offs of numerous alternative fuels, presenting expert analyses of the different properties, processes, and performance characteristics of each fuel. It discusses the concept systems and technology involved in the production of fuels on both industrial and individual scales. Chapters 5 and 7 are of special interest to the coal industry. Contents: Chapter 1. Fuel Sources - Conventional and Non-conventional; Chapter 2. Natural Gas; Chapter 3. Fuels From Petroleum and Heavy Oil; Chapter 4. Fuels From Tar Sand Bitumen; Chapter 5. Fuels From Coal; Chapter 6. Fuels From Oil Shale; Chapter 7. Fuels From Synthesis Gas; Chapter 8. Fuels From Biomass; Chapter 9. Fuels From Crops; Chapter 10. Fuels From Wood; Chapter 11. Fuels From Domestic and Industrial Waste; Chapter 12. Landfill Gas. 3 apps.

Speight, J. [University of Utah, UT (United States)

2008-07-01T23:59:59.000Z

132

Synthetic fuel concept to steal CO2 from air  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout »LabSustainabilitySynthetic fuel concept Synthetic

133

Defossiling Fuel: How Synthetic Biology Can Transform Biofuel Production  

E-Print Network [OSTI]

Defossiling Fuel: How Synthetic Biology Can Transform Biofuel Production David F. Savage , Jeffrey production is pre- dicted to peak soon, it is reason- able to assume that unconventional fossil fuel sources and economic energy volatility, and smoothing the transition from fossil fuels in the distant future

134

Exergy Analysis of a GTL Process Based on Low-Temperature Slurry F-T Reactor Technology with a Cobalt Catalyst  

E-Print Network [OSTI]

and Hans Tropsch; their aim was to use a mixture of CO and H2 (referred to as synthesis gas, syngas) to produce hydrocarbons, chemicals, and liquid fuels. The production of syngas was achieved by coal into syngas and, then, Fischer-Tropsch synthesis of syngas into synthetic liquid fuels. A first plant

Kjelstrup, Signe

135

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents [OSTI]

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2011-01-18T23:59:59.000Z

136

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents [OSTI]

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D.; Dumesic, James A.

2013-04-02T23:59:59.000Z

137

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents [OSTI]

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2012-04-10T23:59:59.000Z

138

1 Copyright 2013 by ASME Proceedings of the ASME Fluids Engineering Summer Meeting  

E-Print Network [OSTI]

, USA T.J. O'Hern Engineering Sciences Center Sandia National Laboratories Albuquerque, New Mexico, USA of coal slurry to produce synthetic fuels during the Fischer-Tropsch process. Vertical vibration of larger amplitudes. Therefore, a new experimental set up was designed, built, verified by comparison

Ghajar, Afshin J.

139

Near-frictionless carbon coatings for use in fuel injectors and pump systems operating with low-sulfur diesel fuels  

SciTech Connect (OSTI)

While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO{sub 2} emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. This research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems. The lubricity of various diesel fuels (i.e., high-sulfur, 500 ppm; low sulfur, 140 ppm; ultra-clean, 3 ppm; and synthetic diesel or Fischer-Tropsch, zero sulfur) were tested by using both uncoated and NFC-coated 52100 steel specimens in a ball-on-three-disks and a high-frequency reciprocating wear-test rig. The test program was expanded to include some gasoline fuels as well (i.e., regular gasoline and indolene) to further substantiate the usefulness of the NFC coatings in low-sulfur gasoline environments. The results showed that the NFC coating was extremely effective in reducing wear and providing lubricity in low-sulfur or sulfur-free diesel and gasoline fuels. Specifically, depending on the wear test rig, test pair, and test media, the NFC films were able to reduce wear rates of balls and flats by factors of 8 to 83. These remarkable reductions in wear rates raise the prospect for using the ultra slick carbon coatings to alleviate problems that will be caused by the use of low sulfur diesel and gasoline fuels. Surfaces of the wear scars and tracks were characterized by optical and scanning electron microscopy, and by Raman spectroscopy.

Erdemir, A.; Ozturk, O.; Alzoubi, M.; Woodford, J.; Ajayi, L.; Fenske, G.

2000-01-19T23:59:59.000Z

140

Design, Synthesis and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals  

SciTech Connect (OSTI)

This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch Synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based materials with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During the fifth and sixth reporting period, we studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influenced the performance of these materials in the Fischer-Tropsch synthesis. We also continued our studies of the kinetic behavior of these materials during the sixth reporting period. Specifically, the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch Synthesis reactions led us to propose a new sequence of elementary steps on Fe and Co Fischer-Tropsch catalysts. Finally, we also started a study of the use of colloidal precipitation methods for the synthesis small Co clusters using recently developed methods to explore possible further improvements in FTS rates and selectivities. We found that colloidal synthesis makes possible the preparation of small cobalt particles, although large amount of cobalt silicate species, which are difficult to reduce, were formed. During this seventh reporting period, we have explored several methods to modify the silanol groups on SiO{sub 2} by using either a homogeneous deposition-precipitation method or surface titration of Si-OH on SiO{sub 2} with zirconium (IV) ethoxide to prevent the formation of unreducible and unreactive CoO{sub x} species during synthesis and FTS catalysis. We have synthesized monometallic Co/ZrO{sub 2}/SiO{sub 2} catalysts with different Co loadings (11-20 wt%) by incipient wetness impregnation methods and characterized the prepared Co supported catalysts by H{sub 2} temperature-programmed reduction (H{sub 2}-TPR) and H{sub 2}-chemisorption. We have measured the catalytic performance in FTS reactions and shown that although the hydroxyl groups on the SiO{sub 2} surface are difficult to be fully titrated by ZrO{sub 2}, modification of ZrO{sub 2} on SiO{sub 2} surface can improve the Co clusters dispersion and lead to a larger number of exposed Co surface atoms after reduction and during FTS reactions. During this seventh reporting period, we have also advanced our development of the reaction mechanism proposed in the previous reporting period. Specifically, we have shown that our novel proposal for the pathways involved in CO activation on Fe and Co catalysts is consistent with state-of-the-art theoretical calculations carried out in collaboration with Prof. Manos Mavrikakis (University of Wisconsin-Madison). Finally, we have also worked on the preparation of several manuscripts describing our findings about the preparation, activation and mechanism of the FTS with Fe-based catalysts and we have started redacting the final report for this project.

Akio Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

2007-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Biomass gasification for liquid fuel production  

SciTech Connect (OSTI)

In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they do?t compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

Najser, Jan, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz; Peer, Václav, E-mail: jan.najser@vsb.cz, E-mail: vaclav.peer@vsb.cz [VSB - Technical university of Ostrava, Energy Research Center, 17. listopadu 15/2172, 708 33 Ostrava-Poruba (Czech Republic); Vantuch, Martin [University of Zilina, Faculty of Mechanical Engineering, Department of Power Engineering, Univerzitna 1, 010 26 Zilina (Slovakia)

2014-08-06T23:59:59.000Z

142

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

SciTech Connect (OSTI)

The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

Gerald P. Huffman

2004-09-30T23:59:59.000Z

143

Synthetic fuels from peat: state-of-the-art review  

SciTech Connect (OSTI)

The world has significant resources of peat. Total energy contained in these resources is estimated to be equivalent to over 1800 billion barrels of oil. Peat has been used extensively in Europe and Russia for years as a source of energy. In the United States, where peat resources are estimated at equivalent to 240 billion barrels of oil, peat is not used commercially as a source of energy. In 1974, the Institute of Gas Technology (IGT) initiated peat gasification research under the sponsorship of the Minnesota Gas Company (Minnegasco). The results of that work, continued at IGT under the sponsorship of the US Department of Energy (DOE) and Minnegasco, show that on the basis of chemistry and kinetics, peat is a better raw material for making synthetic fuels than coal. This paper reviews the state-of-the-art of the total system of taking peat from the ground and converting it to synthetic fuels. This system incorporates subsystems on harvesting, dewatering, and conversion processes. The world peat resources and environmental effects on large-scale peat utilization are also reviewed.

Punwani, D.V.

1980-01-01T23:59:59.000Z

144

LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS  

SciTech Connect (OSTI)

Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

G. L. Hawkes; J. E. O'Brien; M. G. McKellar

2011-11-01T23:59:59.000Z

145

California's Energy Future - The View to 2050  

E-Print Network [OSTI]

the biomass and coal to “syngas” (a mixture of hydrogen andfor making fuels from syngas, known as Fischer-Tropsch, is

2011-01-01T23:59:59.000Z

146

California’s Energy Future: The View to 2050 - Summary Report  

E-Print Network [OSTI]

the biomass and coal to “syngas” (a mixture of hydrogen andfor making fuels from syngas, known as Fischer-Tropsch, is

Yang, Christopher

2011-01-01T23:59:59.000Z

147

June 3, 2014 Webinar - Features, Events, and Processes: Practical...  

Broader source: Energy.gov (indexed) [DOE]

& Publications HEFA and Fischer-Tropsch Jet Fuel Cost Analyses Proceedings of 3rd USGerman Workshop on Salt Repository Research, Design, and Operation Eastern Wind Integration...

148

Biofuel Boundaries: Estimating the Medium-Term Supply Potential of Domestic Biofuels  

E-Print Network [OSTI]

pathways, such as gasification. However, the current studysuch as MSW, the gasification to Fischer- Tropsch fuelof research on biomass gasification to FT-fuels compared to

Jones, Andrew; O'Hare, Michael; Farrell, Alexander

2007-01-01T23:59:59.000Z

149

Otimização da produção de hidrogênio pela reforma a vapor do metano em reator com membrana laboratorial.  

E-Print Network [OSTI]

??Hydrogen is used as fuel and as a feedstock in important processes such as ammonia and methanol production and Fischer-Tropsch synthesis, besides the increasing use… (more)

Leandro Cardoso Silva

2008-01-01T23:59:59.000Z

150

A Path to the Formulation of New Generations of Synthetic Jet Fuel Derived from Natural Gas  

E-Print Network [OSTI]

with industry and academia to study synthetic jet fuels derived from natural gas. These studies are being implemented at its Fuel Characterization Lab where the most advanced testing equipment is used and strict Quality Management and safety systems are followed...

Al-Nuaimi, Ibrahim Awni Omar Hassan

2013-05-20T23:59:59.000Z

151

Cobalt-ruthenium catalysts for Fischer-Tropsch synthesis  

SciTech Connect (OSTI)

A hydrocarbon synthesis process is described which comprises reacting hydrogen and carbon monoxide in the presence of a catalyst comprised of cobalt and ruthenium on titania, at reaction conditions suitable for the formation of higher hydrocarbons. The catalyst is prepared by impregnating titania with solutions of cobalt and ruthenium salts, drying the impregnated support, reducing the cobalt and ruthenium, treating the reduced metals with an oxygen containing stream at conditions sufficient to form oxides of cobalt and oxides of ruthenium and reducing the cobalt and ruthenium oxides.

Iglesia, E.; Soled, S.L.; Fiato, R.A.

1989-04-18T23:59:59.000Z

152

Nel (2004), “Clean Coal Conversion Options using Fischer-Tropsch  

E-Print Network [OSTI]

facilities producing these products individually. There may be good strategic reasons to use clean coal

Andre ? P. Steynberg; Herman G. Nel

153

Opportunities for the Early Production of Fischer-Tropsch (F...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Presentation: U.S. Department of Energy 2002deershen.pdf More Documents & Publications Coal-Derived Liquids to Enable HCCI Technology WA99018TEXACOENERGYSYSTEMSWaiverofD...

154

Activation studies with promoted precipitated iron Fischer-Tropsch catalysts  

E-Print Network [OSTI]

the Ruhrchemie catalyst, the catalyst activity and stability changed markedly with reduction procedure. Hs reduction at 220'C was repeated since it gave very loiv activity. The reproducibility of this test ivas good. Hs reduction at 250 gave higher catalyst...

Manne, Rama Krishna

1991-01-01T23:59:59.000Z

155

ADDENDUM -EXXON FISCHER-TROPSCH WORK Fischer Synthesis Process  

E-Print Network [OSTI]

-loaded catalyst is determined by relating the rate of diffusion of CO and H2 to a rate of reaction in the porousCCO/d?] = De,H [dCH/d?] [A.1] where the flux is expressed as a product of the effective diffusivity, De's Law constant. The other boundary condition can be defined for two cases as: inert core dCCO/d ? = 0

Kentucky, University of

156

Synthetic fuels from peat by the IGT PEATGAS Process  

SciTech Connect (OSTI)

Peat gasification research at the Institute of Gas Technology (IGT) began in 1974 under the sponsorship of the Minnesota Gas company (Minnegasco). The preliminary evaluation conducted under that program showed encouraging results and led to an expanded program under the joint sponsorship of the US Department of Energy (DOE) and Minnegasco. The current program is also funded by the Gas Research Institute (GRI) and the Northern Natural Gas Company (NNGC). Since 1976 IGT has completed tests with peats from Minnesota, North Carolina, and Maine in laboratory-scale equipment and process development units (PDU's). Tests in the hydrogasification PDU (which represents a scale-up of 250 times the laboratory-scale equipment) confirm the laboratory results. Preparations are being made for pilot-plant scale gasification tests in a modified coal gasification pilot plant (HYGAS) in Chicago. Based on the experimental results obtained in the laboratory-scale tests, IGT conceived a two-stage gasifier (named PEATGAS) for converting peat to synthetic fuels. The PEATGAS Process can be used for making medium- or high-Btu gas as well as liquid fuels. A complete process design and cost estimates have been prepared for a plant producing 250 million cubic feet of SNG per day from Minnesota peat containing 50% moisture. These estimates show that the conversion of peat (containing 50% moisture) is competitive with other alternative methods of SNG production. This paper discusses the important and significant gasification characteristics of the peats evaluated. The paper also describes the use of the PEATGAS Process for production of medium-Btu gas, methanol, and gasoline.

Punwani, D.V.; Rader, A.M.; Kopstein, M.J.

1980-01-01T23:59:59.000Z

157

Procedure for matching synfuel users with potential suppliers. Appendix B. Proposed and ongoing synthetic fuel production projects  

SciTech Connect (OSTI)

To assist the Department of Energy, Office of Fuels Conversion (OFC), in implementing the synthetic fuel exemption under the Powerplant and Industrial Fuel Use Act (FUA) of 1978, Resource Consulting Group, Inc. (RCG), has developed a procedure for matching prospective users and producers of synthetic fuel. The matching procedure, which involves a hierarchical screening process, is designed to assist OFC in: locating a supplier for a firm that wishes to obtain a synthetic fuel exemption; determining whether the fuel supplier proposed by a petitioner is technically and economically capable of meeting the petitioner's needs; and assisting the Synthetic Fuels Corporation or a synthetic fuel supplier in evaluating potential markets for synthetic fuel production. A data base is provided in this appendix on proposed and ongoing synthetic fuel production projects to be used in applying the screening procedure. The data base encompasses a total of 212 projects in the seven production technologies.

None

1981-08-07T23:59:59.000Z

158

Improving low temperature properties of synthetic diesel fuels derived from oil shale. Alternative fuels utilization program  

SciTech Connect (OSTI)

The ability of additives to improve the cold flow properties of shale oil derived fuels boiling in the diesel fuel range was evaluated. Because a commercial shale oil industry did not exist to provide actual samples of finished fuels, a representative range of hydroprocessed shale oil fractions was prepared for use in the additive testing work. Crude oil shale from Occidental Shale Company was fractionated to give three liquids in the diesel fuel boiling range. The initial boiling point in each case was 325/sup 0/F (163/sup 0/C). The final boiling points were 640/sup 0/F (338/sup 0/C), 670/sup 0/F (354/sup 0/C) and 700/sup 0/F (371/sup 0/F). Each fraction was hydrotreated to three different severities (800, 1200 and 1500 psi total pressure) over a Shell 324 nickel molybdate on alumina catalyst at 710 to 750/sup 0/F to afford 9 different model fuels. A variety of commercial and experimental additives were evaluated as cold flow improvers in the model fuels at treat levels of 0.04 to 0.4 wt %. Both the standard pour point test (ASTM D97) and a more severe low temperature flow test (LTFT) were employed. Reductions in pour points of up to 70/sup 0/F and improvements in LTFT temperatures up to 16/sup 0/F were achieved. It is concluded that flow improver additives can play an important role in improving the cold flow properties of future synthetic fuels of the diesel type derived from oil shale.

Frankenfeld, J.W.; Taylor, W.F.

1980-11-01T23:59:59.000Z

159

Application of Synthetic Diesel Fuels | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South42.2 (April 2012)Tie Ltd | Department of Energy Ltd

160

Synthetic and Jet Fuels Pyrolysis for Cooling and Combustion Applications.  

E-Print Network [OSTI]

phenomenon (heat and mass transfers, pyrolysis, combustion) in a cooling channel surrounding a SCRamjet regeneratively cooled SCRamjet is provided to get a large vision of the fuel nature impact on the system of supersonic combustion ramjet (SCRamjet) [1]. For such high velocity, the total temperature of external air

Boyer, Edmond

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels  

SciTech Connect (OSTI)

This collaborative joint research project is in the area of advanced gasification and conversion, within the Chinese Academy of Sciences (CAS)-National Energy Technology Laboratory (NETL)-Pacific Northwest National Laboratory (PNNL) Memorandum of Understanding. The goal for this subtask is the development of advanced syngas conversion technologies. Two areas of investigation were evaluated: Sorption-Enhanced Synthetic Natural Gas Production from Syngas The conversion of synthetic gas (syngas) to synthetic natural gas (SNG) is typically catalyzed by nickel catalysts performed at moderate temperatures (275 to 325°C). The reaction is highly exothermic and substantial heat is liberated, which can lead to process thermal imbalance and destruction of the catalyst. As a result, conversion per pass is typically limited, and substantial syngas recycle is employed. Commercial methanation catalysts and processes have been developed by Haldor Topsoe, and in some reports, they have indicated that there is a need and opportunity for thermally more robust methanation catalysts to allow for higher per-pass conversion in methanation units. SNG process requires the syngas feed with a higher H2/CO ratio than typically produced from gasification processes. Therefore, the water-gas shift reaction (WGS) will be required to tailor the H2/CO ratio. Integration with CO2 separation could potentially eliminate the need for a separate WGS unit, thereby integrating WGS, methanation, and CO2 capture into one single unit operation and, consequently, leading to improved process efficiency. The SNG process also has the benefit of producing a product stream with high CO2 concentrations, which makes CO2 separation more readily achievable. The use of either adsorbents or membranes that selectively separate the CO2 from the H2 and CO would shift the methanation reaction (by driving WGS for hydrogen production) and greatly improve the overall efficiency and economics of the process. The scope of this activity was to develop methods and enabling materials for syngas conversion to SNG with readily CO2 separation. Suitable methanation catalyst and CO2 sorbent materials were developed. Successful proof-of-concept for the combined reaction-sorption process was demonstrated, which culminated in a research publication. With successful demonstration, a decision was made to switch focus to an area of fuels research of more interest to all three research institutions (CAS-NETL-PNNL). Syngas-to-Hydrocarbon Fuels through Higher Alcohol Intermediates There are two types of processes in syngas conversion to fuels that are attracting R&D interest: 1) syngas conversion to mixed alcohols; and 2) syngas conversion to gasoline via the methanol-to-gasoline process developed by Exxon-Mobil in the 1970s. The focus of this task was to develop a one-step conversion technology by effectively incorporating both processes, which is expected to reduce the capital and operational cost associated with the conversion of coal-derived syngas to liquid fuels. It should be noted that this work did not further study the classic Fischer-Tropsch reaction pathway. Rather, we focused on the studies for unique catalyst pathways that involve the direct liquid fuel synthesis enabled by oxygenated intermediates. Recent advances made in the area of higher alcohol synthesis including the novel catalytic composite materials recently developed by CAS using base metal catalysts were used.

Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

2014-03-31T23:59:59.000Z

162

An investigation of synthetic fuel production via chemical looping  

SciTech Connect (OSTI)

Producing liquid hydrocarbon fuels with a reduced greenhouse gas emissions profile would ease the transition to a carbon-neutral energy sector with the transportation industry being the immediate beneficiary followed by the power industry. Revolutionary solutions in transportation, such as electricity and hydrogen, depend on the deployment of carbon capture and storage technologies and/or renewable energy systems. Additionally, high oil prices may increase the development of unconventional sources, such as tar sands, that have a higher emissions profile. One process that is gaining interest is a system for producing reduced carbon fuels though chemical looping technologies. An investigation of the implications of such a process using methane and carbon dioxide that is reformed to yield methanol has been done. An important aspect of the investigation is the use of off-the-shelf technologies to achieve the results. The ability of the process to yield reduced emissions fuels depends on the source for the feed and process heat. For the range of conditions considered, the emissions profile of methanol produced in this method varies from 0.475 to 1.645 moles carbon dioxide per mole methanol. The thermal load can be provided by methane, coal or carbon neutral (biogas). The upper bound can be lowered to 0.750 by applying CCS and/or using nonfossil heat sources for the reforming. The process provides an initial pathway to incorporate CO{sub 2} into fuels independent of electrolytic hydrogen or developments in other sectors of the economy. 22 refs., 1 fig., 3 tabs.

Frank Zeman; Marco Castaldi [Columbia University, New York, NY (United States). Department of Earth and Environmental Engineering

2008-04-15T23:59:59.000Z

163

[98e]-Catalytic reforming of gasoline and diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a fuel processor for converting liquid hydrocarbon fuels to a hydrogen-rich product suitable for a polymer electrolyte fuel cell stack. The processor uses an autothermal reformer to convert the feed to a mixture of hydrogen, carbon dioxide, carbon monoxide and water with trace quantities of other components. The carbon monoxide in the product gas is then converted to carbon dioxide in water-gas shift and preferential oxidation reactors. Fuels that have been tested include standard and low-sulfur gasoline and diesel fuel, and Fischer-Tropsch fuels. Iso-octane and n-hexadecane were also examined as surrogates for gasoline and diesel, respectively. Complete conversion of gasoline was achieved at 750 C in a microreactor over a novel catalyst developed at Argonne. Diesel fuel was completely converted at 850 C over this same catalyst. Product streams contained greater than 60% hydrogen on a dry, nitrogen-free basis with iso-octane, gasoline, and n-hexadecane. For a diesel fuel, product streams contained >50% hydrogen on a dry, nitrogen-free basis. The catalyst activity did not significantly decrease over >16 hours operation with the diesel fuel feed. Coke formation was not observed. The carbon monoxide fraction of the product gas could be reduced to as low as 1% on a dry, nitrogen-free basis when the water-gas shift reactors were used in tandem with the reformer.

Pereira, C.; Wilkenhoener, R.; Ahmed, S.; Krumpelt, M.

2000-02-29T23:59:59.000Z

164

Will Kentucky lead the way in synthetic fuels production? A history lesson  

SciTech Connect (OSTI)

At four times in the history of the United States, synthetic fuels have been used as the energy savior of the country, from the period immediately following the second World War to the mid 1980s when the Synthetic Fuels Corporation was unceremoniously demolished by the Reagan administration. The Center for Applied Energy Research at the University of Kentucky has been a major player in the game and the state of Kentucky has received much funding for synthetic fuels development since the 1970s. The article traces the history of developments in the field. The fate of the development has in the author's opinion been influenced by the misalignment of three 'spheres of influence' - in essence the political economy, environmental/regulatory issues, and the technological innovation process. Synthetic fuels can now become an integral part of what is called a 'multiplex energy strategy' and Kentucky again has the opportunity to build on its prior experience and embrace a new paradigm regarding how clean energy solutions based on gasification technologies can aid the USA. 4 photos.

Musulin, M.

2008-07-01T23:59:59.000Z

165

Synthetic fuels and the environment: an environmental and regulatory impacts analysis  

SciTech Connect (OSTI)

Since July 1979 when DOE/EV-0044 report Environmental Analysis of Synthetic Liquid fuels was published the synthetic fuels program proposals of the Administration have undergone significant modifications. The program year for which the development goal of 1.5 million barrels per day is to be reached has been changed from 1990 to 1995. The program plan is now proposed to have two stages to ensure, among other things, better environmental protection: an initial stage emphasizing applied research and development (R and D), including environmental research, followed by a second stage that would accelerate deployment of those synthetic fuel technologies then judged most ready for rapid deployment and economic operation within the environmental protection requirements. These program changes have significantly expanded the scope of technologies to be considered in this environmental analysis and have increased the likelihood that accelerated environmental R and D efforts will be successful in solving principal environmental and worker safety concerns for most technologies prior to the initiation of the second stage of the accelerated deployment plan. Information is presented under the following section headings: summary; study description; the technologies and their environmental concerns (including, coal liquefaction and gasification, oil shale production, biomass and urban waste conversion); regulatory and institutional analyses; and environmental impacts analysis (including air and water quaility analyses, impacts of carbon dioxide and acid rain, water availability, solid and hazardous wastes, coal mining environmental impacts, transportation issues, community growth and change, and regional impacts). Additional information is presented in seventeen appendixes. (JGB)

None

1980-06-01T23:59:59.000Z

166

The potential utilization of nuclear hydrogen for synthetic fuels production at a coal–to–liquid facility / Steven Chiuta.  

E-Print Network [OSTI]

??The production of synthetic fuels (synfuels) in coal–to–liquids (CTL) facilities has contributed to global warming due to the huge CO2 emissions of the process. This… (more)

Chiuta, Steven

2010-01-01T23:59:59.000Z

167

Metabolic engineering of microorganisms for biofuels production: from bugs to synthetic biology to fuels  

SciTech Connect (OSTI)

The ability to generate microorganisms that can produce biofuels similar to petroleum-based transportation fuels would allow the use of existing engines and infrastructure and would save an enormous amount of capital required for replacing the current infrastructure to accommodate biofuels that have properties significantly different from petroleum-based fuels. Several groups have demonstrated the feasibility of manipulating microbes to produce molecules similar to petroleum-derived products, albeit at relatively low productivity (e.g. maximum butanol production is around 20 g/L). For cost-effective production of biofuels, the fuel-producing hosts and pathways must be engineered and optimized. Advances in metabolic engineering and synthetic biology will provide new tools for metabolic engineers to better understand how to rewire the cell in order to create the desired phenotypes for the production of economically viable biofuels.

Kuk Lee, Sung; Chou, Howard; Ham, Timothy S.; Soon Lee, Taek; Keasling, Jay D.

2009-12-02T23:59:59.000Z

168

Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels  

SciTech Connect (OSTI)

Detailed chemical kinetic models are needed to simulate the combustion of current and future transportation fuels. These models should represent the various chemical classes in these fuels. Conventional diesel fuels are composed of n-alkanes, iso-alkanes, cycloalkanes and aromatics (Farrell et al. 2007). For future fuels, there is a renewed interest in Fischer-Tropsch (F-T) processes which can be used to synthesize diesel and other transportation fuels from biomass, coal and natural gas. F-T diesel fuels are expected to be similar to F-T jet fuels which are commonly comprised of iso-alkanes with some n-alkanes (Smith and Bruno, 2008). Thus, n-alkanes and iso-alkanes are common chemical classes in these conventional and future fuels. This paper reports on the development of chemical kinetic models of large n-alkanes and iso-alkanes to represent these chemical classes in conventional and future fuels. Two large iso-alkanes are 2,2,4,4,6,8,8-heptamethylnonane, which is a primary reference fuel for diesel, and isooctane, a primary reference fuel for gasoline. Other iso-alkanes are branched alkanes with a single methyl side chain, typical of most F-T fuels. The chemical kinetic models are then used to predict the effect of these fuel components on ignition characteristics under conditions found in internal combustion engines.

Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

2008-12-15T23:59:59.000Z

169

Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction  

SciTech Connect (OSTI)

The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

2007-09-15T23:59:59.000Z

170

Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

Rao, A. D.; Chen, Q.; Samuelsen, G. S.

2012-09-30T23:59:59.000Z

171

Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas  

SciTech Connect (OSTI)

Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews [Carnegie Mellon University, Pittsburgh, PA (USA). Civil and Environmental Engineering Department

2008-10-15T23:59:59.000Z

172

Coal liquefaction and gas conversion: Proceedings. Volume 2  

SciTech Connect (OSTI)

Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1993-12-31T23:59:59.000Z

173

NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form  

Broader source: Energy.gov (indexed) [DOE]

- 103111 Grand Forks, ND Fischer-Tropsch Fuels Development Construction of a cold-syngas cleanup reactor for the FT portion of the overall project that is designed to use...

174

Yosemite Waters Vehicle Evaluation Report: Final Results  

SciTech Connect (OSTI)

Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

Eudy, L.; Barnitt, R.; Alleman, T. L.

2005-08-01T23:59:59.000Z

175

E-Print Network 3.0 - aqueous-phase rh-norbos catalysts Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pt-99 wt.% Al2O3... Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation Source: Consortium for Fossil Fuel Science, C1...

176

A tribute to Tom Ziegler Biographical sketch --From Copenhagen to Calgary  

E-Print Network [OSTI]

with research on solid oxide fuel cells (SOFC) and Fischer­Tropsch synthesis, again with substantial support- lecular dynamics method that makes it possible to optimize transition-state structures on the free energy

Ziegler, Tom

177

The Prospects for Coal-To-Liquid Conversion: A General Equilibrium Analysis  

E-Print Network [OSTI]

We investigate the economics of coal-to-liquid (CTL) conversion, a polygeneration technology that produces liquid fuels, chemicals, and electricity by coal gasification and Fischer-Tropsch process. CTL is more expensive ...

Chen, Y.-H. Henry

178

CX-002358: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Fischer-Tropsch Fuels DevelopmentCX(s) Applied: B3.6Date: 05/10/2010Location(s): Grand Forks, North DakotaOffice(s): Fossil Energy, National Energy Technology Laboratory

179

CX-011112: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Innovative Gasification to Produce Fischer-Tropsch Jet and Diesel Fuel CX(s) Applied: A9 Date: 08/15/2013 Location(s): Iowa Offices(s): Golden Field Office

180

Environmentally based siting assessment for synthetic-liquid-fuels facilities. Final report  

SciTech Connect (OSTI)

A detailed assessment of the major environmental constraints to siting a synthetic fuels industry and the results of that assessment are used to determine on a regional basis the potential for development of such an industry with minimal environmental conflicts. Secondly, the ability to mitigate some of the constraining impacts through alternative institutional arrangements, especially in areas that are judged to have a low development potential is also assessed. Limitations of the study are delineated, but specifically, the study is limited geographically to well-defined boundaries that include the prime coal and oil shale resource areas. The critical factors used in developing the framework are air quality, water availability, socioeconomic capacity, ecological sensitivity, environmental health, and the management of Federally owned lands. (MCW)

None

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Overview of Aviation Fuel Markets for Biofuels Stakeholders  

SciTech Connect (OSTI)

This report is for biofuels stakeholders interested the U.S. aviation fuel market. Jet fuel production represents about 10% of U.S. petroleum refinery production. Exxon Mobil, Chevron, and BP top producers, and Texas, Louisiana, and California are top producing states. Distribution of fuel primarily involves transport from the Gulf Coast to other regions. Fuel is transported via pipeline (60%), barges on inland waterways (30%), tanker truck (5%), and rail (5%). Airport fuel supply chain organization and fuel sourcing may involve oil companies, airlines, airline consortia, airport owners and operators, and airport service companies. Most fuel is used for domestic, commercial, civilian flights. Energy efficiency has substantially improved due to aircraft fleet upgrades and advanced flight logistic improvements. Jet fuel prices generally track prices of crude oil and other refined petroleum products, whose prices are more volatile than crude oil price. The single largest expense for airlines is jet fuel, so its prices and persistent price volatility impact industry finances. Airlines use various strategies to manage aviation fuel price uncertainty. The aviation industry has established goals to mitigate its greenhouse gas emissions, and initial estimates of biojet life cycle greenhouse gas emissions exist. Biojet fuels from Fischer-Tropsch and hydroprocessed esters and fatty acids processes have ASTM standards. The commercial aviation industry and the U.S. Department of Defense have used aviation biofuels. Additional research is needed to assess the environmental, economic, and financial potential of biojet to reduce greenhouse gas emissions and mitigate long-term upward price trends, fuel price volatility, or both.

Davidson, C.; Newes, E.; Schwab, A.; Vimmerstedt, L.

2014-07-01T23:59:59.000Z

182

Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.  

SciTech Connect (OSTI)

The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is compatible with much of the existing fuel infrastructure.

Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

2009-01-01T23:59:59.000Z

183

Regional refining models for alternative fuels using shale and coal synthetic crudes: identification and evaluation of optimized alternative fuels. Annual report, March 20, 1979-March 19, 1980  

SciTech Connect (OSTI)

The initial phase has been completed in the project to evaluate alternative fuels for highway transportation from synthetic crudes. Three refinery models were developed for Rocky Mountain, Mid-Continent and Great Lakes regions to make future product volumes and qualities forecast for 1995. Projected quantities of shale oil and coal oil syncrudes were introduced into the raw materials slate. Product slate was then varied from conventional products to evaluate maximum diesel fuel and broadcut fuel in all regions. Gasoline supplement options were evaluated in one region for 10% each of methanol, ethanol, MTBE or synthetic naphtha in the blends along with syncrude components. Compositions and qualities of the fuels were determined for the variation in constraints and conditions established for the study. Effects on raw materials, energy consumption and investment costs were reported. Results provide the basis to formulate fuels for laboratory and engine evaluation in future phases of the project.

Sefer, N.R.; Russell, J.A.

1980-11-01T23:59:59.000Z

184

The Elephant in the Room: Dealing with Carbon Emissions from Synthetic Transportation Fuels Production  

SciTech Connect (OSTI)

Carbon dioxide (CO2), produced by conversion of hydrocarbons to energy, primarily via fossil fuel combustion, is one of the most ubiquitous and significant greenhouse gases (GHGs). Concerns over climate change precipitated by rising atmospheric GHG concentrations have prompted many industrialized nations to begin adopting limits on emissions to inhibit increases in atmospheric CO2 levels. The United Nations Framework Convention on Climate Change states as a key goal the stabilization of atmospheric CO2 at a level that prevents “dangerous anthropogenic interference” with the planet’s climate systems. This will require sharply reducing emissions growth rates in developing nations, and reducing CO2 emissions in the industrialized world to half current rates in the next 50 years. And ultimately, stabilization will require that annual emissions drop to almost zero.Recently, there has been interest in producing synthetic transportation fuels via coal-to-liquids (CTL) production, particularly in countries where there is an abundant supply of domestic coal, including the United States. This paper provides an overview of the current state of CTL technologies and deployment, a discussion of costs and technical requirements for mitigating the CO2 impacts associated with a CTL facility, and the challenges facing the CTL industry as it moves toward maturity.

Parker, Graham B.; Dahowski, Robert T.

2007-07-11T23:59:59.000Z

185

EARLY ENTRANCE CO-PRODUCTION PLANT - DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS  

SciTech Connect (OSTI)

Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the technoeconomic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from July 1, 2002 through September 30, 2002.

Unknown

2003-01-01T23:59:59.000Z

186

Alternative fuel and chemicals from synthesis gas  

SciTech Connect (OSTI)

Development of a reliable and cost-effective method of wax/catalyst separation is a key step toward a commercially viable slurry reactor process with iron oxide-based catalyst for Fischer-Tropsch (F-T) synthesis of hydrocarbon transportation fuels. Although a variety of suitable catalysts (including, for example, cobalt-based catalysts) are available, iron oxide-based catalysts are preferred for coal-derived, CO-rich syngas because, in addition to catalyzing the F-T reaction, they simultaneously catalyze the reaction stifling CO to H{sub 2}, obviating a separate shift process block and associated costs. Because of the importance of development of this wax/catalyst separation, a study was initiated in February 1991. P. Z. Zhou of Burns and Roe reviewed the status of F-T wax/catalyst separation techniques. This led to the selection of a filtration system for the separation. Pilot tests were conducted by Mott Porous Metal Products in 1992 to develop this system. Initial results were good, but problems were encountered in follow-up testing. As a result of the testing, a filter was selected for use on the pilot plant. In LaPorte, Texas, APCI has been operating a pilot plant for the development of various synthesis gas technologies with DOE and industry support. The APCI F-T program builds on the DOE-sponsored laboratory-scale work by Mobil, reported in the mid-1980s, which used an iron oxide catalyst to produce high-quality F-T liquids in relatively compact reactors. Separation of the catalyst solids from the wax still represents a challenge. In the summer of 1992, testing of the selected filter was begun as part of the pilot plant testing. The filter performed poorly. Separation of the catalyst was primarily by sedimentation. It was recommended that the wax/catalyst separation be developed further.

NONE

1996-05-01T23:59:59.000Z

187

EARLY ENTRANCE CO-PRODUCTION PLANT-DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS  

SciTech Connect (OSTI)

Waste Processors Management, Inc. (WMPI), along with its subcontractors entered into a Cooperative Agreement with the US Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) to assess the techno-economic viability of building an Early Entrance Co-Production Plant (EECP) in the US to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase 1 is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase 2 is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase 3 updates the original EECP design based on results from Phase 2, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from April 1, 2002 through June 30, 2002.

Unknown

2002-07-01T23:59:59.000Z

188

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles  

SciTech Connect (OSTI)

The morphological and chemical nature of ultrafine iron catalyst particles (3-5 nm diameters) during activation/FTS was studied by HRTEM, EELS, and Moessbauer spectroscopy. With the progress of FTS, the carbide re-oxidized to magnetite and catalyst activity gradually decreased. The growth of oxide phase continued and average particle size also increased simultaneously. The phase transformation occurred in a ''growing oxide core'' manner with different nano-zones. The nano-range carbide particles did not show fragmentation or attrition as generally observed in micrometer range particles. Nevertheless, when the dimension of particles reached the micrometer range, the crystalline carbide phase appeared to be sprouted on the surface of magnetite single crystal. In the previous reporting period, a design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. During the current reporting period, we have started construction of the new filtration system and began modifications to the 4 liter slurry bubble column reactor (SBCR) reactor. The system will utilize a primary wax separation device followed by a Pall Accusep or Membralox ceramic cross-flow membrane. As of this writing, the unit is nearly complete except for the modification of a moyno-type pump; the pump was shipped to the manufacturer to install a special leak-free, high pressure seal.

James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

2006-03-31T23:59:59.000Z

189

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles  

SciTech Connect (OSTI)

In the previous reporting period, modifications were completed for integrating a continuous wax filtration system for a 4 liter slurry bubble column reactor. During the current reporting period, a shakedown of the system was completed. Several problems were encountered with the progressive cavity pump used to circulate the wax/catalyst slurry though the cross-flow filter element and reactor. During the activation of the catalyst with elevated temperature (> 270 C) the elastomer pump stator released sulfur thereby totally deactivating the iron-based catalyst. Difficulties in maintaining an acceptable leak rate from the pump seal and stator housing were also encountered. Consequently, the system leak rate exceeded the expected production rate of wax; therefore, no online filtration could be accomplished. Work continued regarding the characterization of ultra-fine catalyst structures. The effect of carbidation on the morphology of iron hydroxide oxide particles was the focus of the study during this reporting period. Oxidation of Fe (II) sulfate results in predominantly {gamma}-FeOOH particles which have a rod-shaped (nano-needles) crystalline structure. Carbidation of the prepared {gamma}-FeOOH with CO at atmospheric pressure produced iron carbides with spherical layered structure. HRTEM and EDS analysis revealed that carbidation of {gamma}-FeOOH particles changes the initial nano-needles morphology and generates ultrafine carbide particles with irregular spherical shape.

James K. Neathery; Gary Jacobs; Amitava Sarkar; Adam Crawford; Burtron H. Davis

2006-09-30T23:59:59.000Z

190

Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems  

DOE Patents [OSTI]

A method for reducing catalyst attrition losses in hydrocarbon synthesis processes conducted in high agitation reaction systems; a method of producing an attrition-resistant catalyst; a catalyst produced by such method; a method of producing an attrition-resistant catalyst support; and a catalyst support produced by such method. The inventive method of reducing catalyst attrition losses comprises the step of reacting a synthesis gas in a high agitation reaction system in the presence of a catalyst. In one aspect, the catalyst preferably comprises a .gamma.-alumina support including an amount of titanium effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support which has been treated, after calcination, with an acidic, aqueous solution. The acidic aqueous solution preferably has a pH of not more than about 5. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support wherein the cobalt has been applied to the .gamma.-alumina support by totally aqueous, incipient wetness-type impregnation. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support with an amount of a lanthana promoter effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support produced from boehmite having a crystallite size, in the 021 plane, in the range of from about 30 to about 55 .ANG.ngstrons. In another aspect, the inventive method of producing an attrition-resistant catalyst comprises the step of treating a .gamma.-alumina support, after calcination of and before adding catalytic material to the support, with an acidic solution effective for increasing the attrition resistance of the catalyst. In another aspect, the inventive method of producing an attrition-resistant catalyst support comprises the step of treating calcined .gamma.-alumina with an acidic, aqueous solution effective for increasing the attrition resistance of the .gamma.-alumina.

Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

2001-01-01T23:59:59.000Z

191

Processes and palladium-promoted catalysts for conducting Fischer-Tropsch synthesis  

DOE Patents [OSTI]

A process for hydrocarbon synthesis comprising the step of reacting a synthesis gas in the presence of a cobalt catalyst promoted with palladium.

Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

2000-01-01T23:59:59.000Z

192

Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology  

E-Print Network [OSTI]

Industrial   &  engineering  chemistry  research,  2005.  Industrial   &   engineering   chemistry   research,  Industrial   &   engineering   chemistry  research,  1995.  

Li, Yang

2013-01-01T23:59:59.000Z

193

Development of a Fischer-Tropsch Gasoline Process for the Steam Hydrogasification Technology  

E-Print Network [OSTI]

aromatics production from syngas. Mo/HZSM-5 catalyst hadwith CO 2 containing syngas mixture. The product liquid isfor   biomass-­?derived  syngas,  2003,  DTIC  Document.  

Li, Yang

2013-01-01T23:59:59.000Z

194

Fischer-Tropsch synthesis in the slurry phase on iron catalysts  

E-Print Network [OSTI]

and noted that the iron catalyst produced more carbon dioxide than the cobalt catalyst, while the cobalt catalyst produced more water. Iron catalysts are also known to produce a higher yield of oxygenstes and offer the advantages of low cost and a wide... conductivity 40 minutes '0 O 0 0 0 o 2 0 '0 Ll 9 2 H 8. A o g Q Ni Valve Snitch Propane Propylene Iso-butane N-Butane I-Butane Isobutylene ~ Trans-2-butane Ctg-2-butane Valve Suicch Ethylene Ethane Valve Snitch 0 2 N CH...

Brown, Russell Floyd

1986-01-01T23:59:59.000Z

195

FischerTropsch synthesis on a model Co/SiO2 catalyst , Zhoujun Wang a  

E-Print Network [OSTI]

, although made vulnerable by the dramatic changes in crude oil prices, is still one of the few technologies and Texas A&M University, College Station, TX 77843, United States a r t i c l e i n f o Article history on crude oil, and much effort has been made to develop renewable energy technologies, such as solar, wind

Goodman, Wayne

196

Hydrodynamics of bubble columns with application to Fischer-Tropsch synthesis  

E-Print Network [OSTI]

produced hold-up vaiues similar to those of pure liquids, whereas. exper r rent, zvith parafiiu waxes (FT-200 ancl PT-:300) at 265 'C produced iigh hold- p values ar. d large aznounts of foam. But, at 200 'C lov; hold-up raiues were c'iitaired anc small... by the column diameter and superficial gas velocity. In the bubbly flow regime?bubbles may be small and spherical, or larger and non spherical because of the flow of liquid around them. As the superficial gas velocity is increased slug flov' is developed...

Raphael, Matheo Lue

1988-01-01T23:59:59.000Z

197

Technology Development for Iron and Cobalt Fischer-Tropsch Catalysts Quarterly Report  

E-Print Network [OSTI]

as an account of work sponsored by an agency of the United States Government. Neither the United States agency thereof. #12;2 Abstract CAER Tight control of catalyst distribution within SBCRs should . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Kentucky, University of

198

Safety and Techno-Economic Analysis of Solvent Selection for Supercritical Fischer-Tropsch Synthesis Reactors  

E-Print Network [OSTI]

of the fixed-bed reactor, among other disadvantages, is that the reaction is very exothermic, which is a concern in terms of safety hazards and also in terms of cost of heat removal. With the slurry reactor, a problem is that in the liquid media... at different lengths.4 After the reaction takes place, the amount of carbon monoxide consumed decreases and carbon dioxide is produced as a side product.9 The FTS reaction is an extremely exothermic process, which represents serious challenges...

Hamad, Natalie

2012-02-14T23:59:59.000Z

199

Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 1. Rate of Reaction  

SciTech Connect (OSTI)

With a reduced fused magnetite catalyst, the rate of reaction in the presence of phenanthrene is nearly twice that observed in the presence of n-octacosane even though the solubility of H/sub 2/ and CO is moderately less in phenanthrene. The rate in the presence of triphenylmethane was about the same as in n-octacosane. In the presence of a perfluoropolyether, the rate of reaction was markedly reduced, even though H/sub 2/ and CO solubilities are much higher than in hydrocarbons. This was attributed to substantial mass transfer resistances through an encapsulating hydrocarbon layer around the catalyst particles. The effect of the nature of a liquid on several other reactions is also discussed.

Satterfield, C.N.; Stenger, H.G.

1984-04-01T23:59:59.000Z

200

Effect of Liquid Composition on the Slurry Fischer-Tropsch Synthesis. 2. Product Selectivity  

SciTech Connect (OSTI)

With a reduced, fused magnetite catalyst, secondary reactions, consisting of olefin hydrogenation, olefin isomerization, and incorporation of ethylene and/or ethyl alcohol into product, were slightly greater in octacosane than in phenanthrene at 232/sup 0/C but essentially the same at 263/sup 0/C. This is attributed to competitiv adsorption effects with phenanthrene which adsorbs significantly onto the catalyst at 232/sup 0/C, but not at 263/sup 0/C. All secondary reactions are enhanced by conditions minimizing CO adsorption. Oxygenates were greatly diminished at high conversions. C/sub 2/ incorporation into product stops chain growth by a scavenging effect. In the presence of a perfluoropolyether (Fomblin), in which hydrocarbons are immiscible, catalyst is preferentially wetted by hydrocarbons and secondary reactions are greatly enhanced by mass transfer resistances.

Stenger, H.G.; Satterfield, C.N.

1984-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Optimal Simultaneous Production of Hydrogen and Liquid Fuels from Glycerol: Integrating the  

E-Print Network [OSTI]

of the ratio CO / H2 (bypass, PSA and water gas shift). Next, the removal of CO2 is performed by means of PSA and the syngas is fed to the Fischer - Tropsch reactor. The products obtained are separated while the heavy with the current automobile and gasoline supply chains. However, the profitability of biofuels depends heavily

Grossmann, Ignacio E.

202

Mobility chains analysis of technologies for passenger cars and light duty vehicles fueled with biofuels : application of the Greet model to project the role of biomass in America's energy future (RBAEF) project.  

SciTech Connect (OSTI)

The Role of Biomass in America's Energy Future (RBAEF) is a multi-institution, multiple-sponsor research project. The primary focus of the project is to analyze and assess the potential of transportation fuels derived from cellulosic biomass in the years 2015 to 2030. For this project, researchers at Dartmouth College and Princeton University designed and simulated an advanced fermentation process to produce fuel ethanol/protein, a thermochemical process to produce Fischer-Tropsch diesel (FTD) and dimethyl ether (DME), and a combined heat and power plant to co-produce steam and electricity using the ASPEN Plus{trademark} model. With support from the U.S. Department of Energy (DOE), Argonne National Laboratory (ANL) conducted, for the RBAEF project, a mobility chains or well-to-wheels (WTW) analysis using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model developed at ANL. The mobility chains analysis was intended to estimate the energy consumption and emissions associated with the use of different production biofuels in light-duty vehicle technologies.

Wu, M.; Wu, Y.; Wang, M; Energy Systems

2008-01-31T23:59:59.000Z

203

Testing Synthetic Fuels for Use in U.S. Army Ground Vehicles | Department  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy StrainClientDesignOffice -TemplateDavid L.Testing Subgroupof

204

Synthetic Design Microorganisms for Lignin Fuels and Chemicals Presentation for BETO 2015 Project Peer Review  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4SuperhardSuspectEngines | DepartmentandMarch

205

An assessment of carbon sources for the production of synthetic fuels from nuclear hydrogen  

E-Print Network [OSTI]

In the transportation sector, the current dependence on petroleum to satisfy large transportation fuel demand in the US is unsustainable. Oil resources are finite, and causing heavy US reliance on oil imports. Therefore, ...

Leung, MinWah

2007-01-01T23:59:59.000Z

206

LDRD final report on "fundamentals of synthetic conversion of CO2 to simple hydrocarbon fuels" (LDRD 113486).  

SciTech Connect (OSTI)

Energy production is inextricably linked to national security and poses the danger of altering the environment in potentially catastrophic ways. There is no greater problem than sustainable energy production. Our purpose was to attack this problem by examining processes, technology, and science needed for recycling CO{sub 2} back into transportation fuels. This approach can be thought of as 'bio-inspired' as nature employs the same basic inputs, CO{sub 2}/energy/water, to produce biomass. We addressed two key deficiencies apparent in current efforts. First, a detailed process analysis comparing the potential for chemical and conventional engineering methods to provide a route for the conversion of CO{sub 2} and water to fuel has been completed. No apparent 'showstoppers' are apparent in the synthetic route. Opportunities to improve current processes have also been identified and examined. Second, we have also specifically addressed the fundamental science of the direct production of methanol from CO{sub 2} using H{sub 2} as a reductant.

Maravelias, Christos T. (University of Wisconsin, Madison, WI); Kemp, Richard Alan; Mavrikakis, Manos (University of Wisconsin, Madison, WI); Miller, James Edward; Stewart, Constantine A.

2009-11-01T23:59:59.000Z

207

REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1  

E-Print Network [OSTI]

.6 US$/GJ, the H2 production price is estimated to 4.8 US$/GJ equivalent to 30 US$/barrel crude oil for manufacturing of synthetic diesel from synthesis gas using Fischer-Tropsch are being built due to the high oil price. The synthesis gas is made by steam refor

208

Separation of Fischer-Tropsch Wax from Catalyst Using Near-Critical Fluid Extraction: Analysis of Process  

E-Print Network [OSTI]

", can be produced from materials such as coal, natural gas, waste biomass, and petroleum coke. A great of coal and natural gas exist in many geographical regions that lack sufficient petroleum. Therefore

Kilpatrick, Peter K.

209

Síntese de Fischer-Tropsch sobre perovskitas LayCu0,4Fe0,6O3.  

E-Print Network [OSTI]

??A produção atual de 52 milhões mdia-1 de gás natural e os grandes projetos para esta expansão vem estabelecendo novas fronteiras para a indústria nacional… (more)

José Roberto de Souza

2010-01-01T23:59:59.000Z

210

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

[8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC is a remarkable proceeds on supported transition metal catalysts, Co or Fe on oxide supports generally Al2O3 or SiO2 [1 of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

211

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

of the metallic particles [8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC monoxide and hydrogen. FT synthesis proceeds on supported transition metal catalysts, Co or Fe on oxide of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

212

Chemistry of natural fuel: Use of wastes of synthetic fatty acid production for obtaining water-bitumen emulsions  

SciTech Connect (OSTI)

The possibility of producing water-emulsion waterproofing mastic and waterproofing coating based on bitumen, rubber crumb, and bottoms from production of synthetic fatty acids was studied. The physicochemical properties (softening point, ductility, sorptive properties, and friability) of the waterproofing coating based on a water-emulsion mastic were measured.

Syroezhko, A.M.; Antipova, E.I.; Paukku, A.N. [St. Petersburg Technological Inst. (Russian Federation)

1995-12-10T23:59:59.000Z

213

William W. Hay Railroad Engineering Seminar Freight Railroad Energy  

E-Print Network [OSTI]

(importance v difficulties) North American freight RRs (defining characteristics) Energy density of diesel fuel & alternatives (Btu's per gallon) Biodiesel, Fischer-Tropsch syn fuel & DME Liquefied natural of European RRs (lessons learned) Dual-mode locomotives ("electro-diesels") Unconventional alternatives

Barkan, Christopher P.L.

214

E-Print Network 3.0 - advanced heterogeneous catalysts Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Hydrogen Summary: Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation... Hexane Fischer-Tropsch Synthesis over an...

215

E-Print Network 3.0 - ammonia synthesis catalyst Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Hydrogen Summary: Fischer-Tropsch synthesis using Co and Ru supported on silica aerogels as catalysts 21 Metal impregnation... Hexane Fischer-Tropsch Synthesis over an...

216

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

SciTech Connect (OSTI)

The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure hydrogen and carbon nanotubes using binary Fe-based catalysts containing Mo, Ni, or Pd in a single step non-oxidative reaction. (7) Partial dehydrogenation of liquid hydrocarbons (cyclohexane and methyl cyclohexane) has been performed using catalysts consisting of Pt and other metals on stacked-cone carbon nanotubes. (8) An understanding of the catalytic reaction mechanisms of the catalysts developed in the CFFS C1 program is being achieved by structural characterization using multiple techniques, including XAFS and Moessbauer spectroscopy, XRD, TEM, NMR, ESR, and magnetometry.

Gerald P. Huffman

2003-09-30T23:59:59.000Z

217

OATAO is an open access repository that collects the work of Toulouse researchers and makes it freely available over the web where possible.  

E-Print Network [OSTI]

process simulation software ­ ProSimPlus® ­ to allow physical modeling as well as mass and energy balances is based on the gasification of the biomass followed by Fischer-Tropsch Synthesis (FTS), producing naphtha Sustainability assessment of an integrated High Temperature Steam Electrolysis - enhanced Biomass to Liquid Fuel

Mailhes, Corinne

218

Published on Web Date: December 01, 2010 r 2010 American Chemical Society 3451 DOI: 10.1021/jz1012627 |J. Phys. Chem. Lett. 2010, 1, 34513458  

E-Print Network [OSTI]

, methane, and ethylene with high current efficiency. These products can be used as feed- stocks dependence on imported pe- troleum, the development and expansion of natural gas to liquid (GTL) and coal monoxide, which is then converted into liquid fuels via the Fischer-Tropsch process,2,3 and both are well

Kenis, Paul J. A.

219

innovative research fa l l 2 0 0 6  

E-Print Network [OSTI]

, to make fuel cells, to cleanly liquefy coal, and to meet the dramatically increasing global demand of the Journal of Catalysis,two editions of the Handbook of Heterogeneous Catalysis, as well as a special issue control, methane com- bustion, selective hydrogenation, Fischer- Tropsch synthesis,methanol steam

New Mexico, University of

220

Engineering Project Solar-Boosted  

E-Print Network [OSTI]

at the Australian National University. #12;4 Abstract Solar gasification of biomass presents an attractive avenue fuels and chemicals derived via the Fischer-Tropsch process (Dry 2002). Supercritical water gasification (SCWG) has been shown to rapidly achieve char-free gasification, yielding a gas rich in H2, CH4, CO

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
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221

C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen  

SciTech Connect (OSTI)

Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

Gerald P. Huffman

2006-03-30T23:59:59.000Z

222

The Impact of Alternative Fuels on Combustion Kinetics  

SciTech Connect (OSTI)

The research targets the development of detailed kinetic models to quantitatively characterize the impact of alternative fuels on the performance of Navy turbines and diesel engines. Such impacts include kinetic properties such as cetane number, flame speed, and emissions as well as physical properties such as the impact of boiling point distributions on fuel vaporization and mixing. The primary focus will be Fischer-Tropsch liquids made from natural gas, coal or biomass. The models will include both the effects of operation with these alternative fuels as well as blends of these fuels with conventional petroleum-based fuels. The team will develop the requisite kinetic rules for specific reaction types and incorporate these into detailed kinetic mechanisms to predict the combustion performance of neat alternative fuels as well as blends of these fuels with conventional fuels. Reduced kinetic models will be then developed to allow solution of the coupled kinetics/transport problems. This is a collaboration between the Colorado School of Mines (CSM) and the Lawrence Livermore National Laboratory (LLNL). The CSM/LLNL team plans to build on the substantial progress made in recent years in developing accurate detailed chemical mechanisms for the oxidation and pyrolysis of conventional fuels. Particular emphasis will be placed upon reactions of the isoalkanes and the daughter radicals, especially tertiary radicals, formed by abstraction from the isoalkanes. The various components of the program are described. We have been developing the kinetic models for two iso-dodecane molecules, using the same kinetic modeling formalisms that were developed for the gasoline and diesel primary reference fuels. These mechanisms, and the thermochemical and transport coefficient submodels for them, are very close to completion at the time of this report, and we expect them to be available for kinetic simulations early in the coming year. They will provide a basis for prediction and selection of desirable F-T molecules for use in jet engine simulations, where we should be able to predict the ignition, combustion and emissions characteristics of proposed fuel components. These mechanisms include the reactions and chemical species needed to describe high temperature phenomena such as shock tube ignition and flammability behavior, and they will also include low temperature kinetics to describe other ignition phenomena such as compression ignition and knocking. During the past years, our hydrocarbon kinetics modeling group at LLNL has focused a great deal on fuels typical of gasoline and diesel fuel. About 10 years ago, we developed kinetic models for the fuel octane primary reference fuels, n-heptane [1] and iso-octane [2], which have 7 and 8 carbon atoms and are therefore representative of typical gasoline fuels. N-heptane represents the low limit of knock resistance with an octane number of 0, while iso-octane is very knock resistant with an octane number of 100. High knock resistance in iso-octane was attributed largely to the large fraction of primary C-H bonds in the molecule, including 15 of the 18 C-H bonds, and the high bond energy of these primary bonds plays a large role in this knock resistance. In contrast, in the much more ignitable n-heptane, 10 of its 16 C-H bonds are much less strongly bound secondary C-H bonds, leading to its very low octane number. All of these factors, as well as a similarly complex kinetic description of the equally important role of the transition state rings that transfer H atoms within the reacting fuel molecules, were quantified and collected into large kinetic reaction mechanisms that are used by many researchers in the fuel chemistry world.

Pitz, W J; Westbrook, C K

2009-07-30T23:59:59.000Z

223

Evaluation of synthetic-fuel character effects on rich-lean stationary gas-turbine combustion systems. Volume 2. Full-scale test program. Final report  

SciTech Connect (OSTI)

The effect of burner geometric scale on the emissions and performance produced by staged, rich lean combustors was investigated. Tests were conducted using a 25-cm diameter burner and the results obtained were compared with results previously obtained using a similar, but smaller (12.5-cm diameter) burner. The larger burner employed a convectively-cooled rich-burn section; the size of the burner is the size of the burner cans employed in the 25 Megawatt FT4 industrial gas turbine. Scale effects are of concern in staged rich/lean combustors because of the suspected critical importance of quench air jet penetration and fuel injector spray distribution, both processes being scaled dependent. Tests were conducted both with No. 2 petroleum distillate and with a nitrogen-bearing, middle-distillate synthetic fuel produced by the H-Coal process. Measurements of burner exit temperature profile, liner temperature, gaseous emission, and smoke emissions are presented and the results compared with subscale test results.

Kennedy, J.B.; McVey, J.B.; Rosfjord, T.J.; Russel, P.; Beal, G.

1983-05-01T23:59:59.000Z

224

EARLY ENTRANCE CO-PRODUCTION PLANT--DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS  

SciTech Connect (OSTI)

Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the technoeconomic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from January 1, 2003 through March 31, 2003. Phase I Task 6 activities of Preliminary Site Analysis were documented and reported as a separate Topical Report on February 2003. Most of the other technical activities were on hold pending on DOE's announcement of the Clean Coal Power Initiative (CCPI) awards. WMPI was awarded one of the CCPI projects in late January 2003 to engineer, construct and operate a first-of-kind gasification/liquefaction facility in the U.S. as a continued effort for the current WMPI EECP engineering feasibility study. Since then, project technical activities were focused on: (1) planning/revising the existing EECP work scope for transition into CCPI, and (2) ''jump starting'' all environmentally related work in pursue of NEPA and PA DEP permitting approval.

John W. Rich

2003-06-01T23:59:59.000Z

225

Structured catalyst bed and method for conversion of feed materials to chemical products and liquid fuels  

DOE Patents [OSTI]

The present invention is a structured monolith reactor and method that provides for controlled Fischer-Tropsch (FT) synthesis. The invention controls mass transport limitations leading to higher CO conversion and lower methane selectivity. Over 95 wt % of the total product liquid hydrocarbons obtained from the monolithic catalyst are in the carbon range of C.sub.5-C.sub.18. The reactor controls readsorption of olefins leading to desired products with a preselected chain length distribution and enhanced overall reaction rate. And, liquid product analysis shows readsorption of olefins is reduced, achieving a narrower FT product distribution.

Wang, Yong (Richland, WA), Liu; Wei (Richland, WA)

2012-01-24T23:59:59.000Z

226

Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production  

E-Print Network [OSTI]

to fuel range by hydrotreating[36]. These fuel products candistillate undergo hydrotreating to saturate the olefins.be used for further hydrotreating of some FT products like

Liu, Zhongzhe

2013-01-01T23:59:59.000Z

227

Moessbauer spectroscopy studies of iron-catalysts used in Fischer-Tropsch (FT) processes. Quarterly technical progress report, January--March, 1994  

SciTech Connect (OSTI)

The objective of this project is to carry out a Moessbauer spectroscopy study of Iron-based catalysts to identify iron phases present and correlate with water gas shift and FT activities. A total of 15 catalysts were evaluated so far. Results are presented on the amounts in each catalyst of the following phases: superparamagnetic phase, hematite ({alpha}-Fe{sub 2}O{sub 3}), magnetite (Fe{sub 3}O{sub 4}), Chi-carbide phase ({chi}-Fe{sub 5}C{sub 2}), and an epsilon-carbide phase ({var_epsilon}-Fe{sub 2.2}C).

Huffman, G.P.; Rao, K.R.P.M.

1994-12-31T23:59:59.000Z

228

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 9, October 1, 1992--December 31, 1992  

SciTech Connect (OSTI)

Figure 7 summarizes the carbon selectivities observed towards the main products. During Period IV, the main products observed were the heavy hydrocarbons, with selectivity for MTBE being less than 3--5%. The only time that high MTBE selectivity was noted was during period III, when the i-butylene feed was shut-off. The large amounts of heavy products and the low selectivity to MTBE were surprising in view of our previous experiments in the gas phase and the high methanol-to-i-butylene ratio used in these runs. In the gas-phase and with methanol/i-butylene = 0.5, over 95% selectivity to MTBE was observed with this catalyst at this temperature. The higher level of methanol used here would be expected to further improve the MTBE selectivity. Perhaps one reason for the poor MTBE selectivity relates to the relative solubilities of the reactants in the Synfluid changing the effective methanol/i-butylene ratio. Figure 8 shows the relative molar concentration of i-butylene during Period III. At 180 minutes, the gas supply of that reactant was shut-off, yet the analyses show that i-butylene continued to elute from the reactor for at least an additional 2 hours. It seems reasonable that the i-butylene is highly soluble in the Synfluid since they are both nonpolar hydrocarbons. Likewise, one would expect the methanol to not be quite as soluble and thus the methanol/i-butylene ratio in the liquid medium may be very low, favoring the oligomerization of i-butylene. Indeed, the only time that MTBE selectivity was high was after the i-butylene supply was shut-off. We intend to quantify these solubilities in future experiments.

Marcelin, G.

1993-06-30T23:59:59.000Z

229

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 8, July 1, 1992--September 30, 1992  

SciTech Connect (OSTI)

The initial work on the synthesis of MTBE during CO hydrogenation shows that MTBE cannot be formed directly on metal sites and likely requires the presence of an acid site. However, MTBE can be made successfully when an acid site, provided by the zeolites, is present in the vicinity of the methanol-synthesis metal sites. When i-butylene was added during CO hydrogenation over a composite catalyst consisting of Li-Pd/SiO{sub 2} and a hydrogen-zeolite, MTBE was formed in measurable amounts. The major by-product of this reaction scheme was isobutane and the dimer of i-butylene. In general, ZSM-5 was found to be superior to LZ210-12 HY zeolite. CO hydrogenation over a bifunctional PdNaY catalyst shows that branched hydrocarbons as well as MEOH can be made successfully at the same time. Addition of i-butylene over this catalyst only (i.e. without other zeolite) results in the formation of trace amounts of MTBE.

Marcelin, G.

1993-07-07T23:59:59.000Z

230

New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. [Aluminoferrisilicate  

SciTech Connect (OSTI)

A new method of combining the shape-selective characteristics of zeolites with a group VIII metal component is described. It involves the following sequence of steps: (1) synthesis of an aluminoferrisilicate (AFS) zeolite, having a crystal structure analogous to zeolite ZSM-5, but which incorporates ferric ions into the structure during synthesis; (2) removal of the organic base used as a template in crystallization of the AFS zeolite; (3) reaction of the AFS zeolite with a transition metal complex anion in aqueous solution to precipitate an inclusion compound in the AFS zeolite, and (4) reduction of the inclusion compound with hydrogen at elevated temperature.

Iton, L.E.; Beal, R.B.; Hodul, D.T.

1983-01-01T23:59:59.000Z

231

Synthetic chloroplasts  

SciTech Connect (OSTI)

The principal function of the chloroplast is to capture solar quanta and to store them in some stable form. We are in the process of trying to construct a totally synthetic system that would simulate some of the reactions of the two photosystems which occur in natural chloroplasts. Toward this end, we have demonstrated a number of the reactions required in separated systems. We have shown that it is possible to transfer electrons across an insulating membrane barrier with a surfactant photosensitizer. Others have shown, and we have confirmed, that it is possible to collect the two electrons necessary for the generation of molecular hydrogen on a heterogeneous catalyst suspended in water and similarly to collect the four holes on another heterogeneous catalyst suspended in water for the generation of molecular oxygen. A synthesis of some of these molecular catalysts for both these purposes is underway, with some partial success. When these partial reactions are assembled in a system, the resulting synthetic chloroplasts will not resemble the natural entity in detailed construction as they will contain no protein.

Calvin, M.

1980-06-01T23:59:59.000Z

232

Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production  

E-Print Network [OSTI]

J. Different types of gasifiers and their integration withCO 2 in a pressurized-gasifier-based process. Energ Fuel.fluidized bed biomass steam gasifier-bed material and fuel

Liu, Zhongzhe

2013-01-01T23:59:59.000Z

233

SLURRY PHASE IRON CATALYSTS FOR INDIRECT COAL LIQUEFACTION  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in indirect coal liquefaction. Specifically, they have studied the attrition behavior of iron Fischer-Tropsch catalysts, their interaction with the silica binder and the evolution of iron phases in a synthesis gas conversion process. The results provide significant insight into factors that should be considered in the design of catalysts for converting coal based syngas into liquid fuels.

Abhaya K. Datye

1998-11-19T23:59:59.000Z

234

Slurry Phase Iron Catalysts for Indirect Coal Liquefaction  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in indirect coal liquefaction. Specifically, we have studied the attrition behavior of Iron Fischer-Tropsch catalysts, their interaction with the silica binder and the evolution of iron phases in a synthesis gas conversion process. The results provide significant insight into factors that should be considered in the design of catalysts for the conversion of coal-derived synthesis gas into liquid fuels.

Abhaya K. Datye

1998-09-10T23:59:59.000Z

235

(Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs  

SciTech Connect (OSTI)

Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

None

1988-02-01T23:59:59.000Z

236

Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways  

SciTech Connect (OSTI)

PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.

None

2012-02-15T23:59:59.000Z

237

Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production  

E-Print Network [OSTI]

Higman C, Van der Burgt M. Gasification. Gulf Professionalkinetic analysis of coal char gasification reactions at highcoal pyrolysis and char gasification. Energ Fuel. 2007; 21:

Liu, Zhongzhe

2013-01-01T23:59:59.000Z

238

Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions  

SciTech Connect (OSTI)

Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

2008-11-01T23:59:59.000Z

239

Radiance: Synthetic Imaging System | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, search RAPIDColoradosource History ViewRadiance: Synthetic Imaging System

240

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

simulation model of a Battelle biomass-based gasification, Fischer–Tropsch liquefaction and combined-cycle power plant.

Lu, Xiaoming

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS  

SciTech Connect (OSTI)

This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced from any one of a variety of sources (including coal) for the production of a spectrum of alternative fuels (hydrocarbons and oxygenate fuels), octane enhancers, and chemicals and chemical intermediates. In particular, the data from the 1995 LPMEOH{trademark} campaign provided confirmation of assumptions used in the design of the catalyst reduction system at the Kingsport LPMEOH{trademark} Commercial Demonstration Project, and the alternate methanol catalyst has been in use there since late 1998. The kinetic model was also expanded to allow for more accurate prediction of methanol production and carbon dioxide (CO{sub 2}) conversion, and more accurate modeling of by-product formation for the alternate methanol catalyst. The outstanding performance results of the LPMEOH{trademark} Process at Kingsport can be attributed in large part to the body of work performed since 1981 in collaboration between the U.S. Department of Energy (DOE) and Air Products. In addition, a pilot-plant-tested LPDME{trademark} Process has been demonstrated, and the product cost of DME from coal-derived syngas can be competitive in certain locations and applications. The need for liquid fuels will continue to be a critical concern for this nation in the 21st century. Efforts are needed to ensure the development and demonstration of economically competitive, efficient, environmentally responsible technologies that produce clean fuels and chemicals from coal under DOE's Vision 21 concept. These liquids will be a component of the fuel mix that will provide the transition from the current reliance on carbon-based fuels to the ultimate use of H{sub 2} as a means of energy transport. Indirect liquefaction, which converts the syngas (H{sub 2} and CO) produced by the gasification of coal to sulfur- and nitrogen-free liquid products, is a key component of the Vision 21 initiative. The results from this current program provide continued support to the objectives for the conversion of domestic coal to electric power and co-produced clean liquid fuels and chemicals in an environmentally superior manner.

Peter J. Tijrn

2003-05-31T23:59:59.000Z

242

Vaporization of synthetic fuels. Final report. [Thesis  

SciTech Connect (OSTI)

The problem of transient droplet vaporization in a hot convective environment is examined. The main objective of the present study is to develop an algorithm for the droplet vaporization which is simple enough to be feasibly incorporated into a complete spray combustion analysis and yet will also account for the important physics such as liquid-phase internal circulation, unsteady droplet heating and axisymmetric gas-phase convection. A simplified liquid-phase model has been obtained based on the assumption of the existence of a Hill's spherical vortex inside the droplet together with some approximations made in the governing diffusion equation. The use of the simplified model in a spray situation has also been examined. It has been found that droplet heating and vaporization are essentially unsteady and droplet temperature is nonuniform for a significant portion of its lifetime. It has also been found that the droplet vaporization characteristic can be quite sensitive to the particular liquid-phase and gas-phase models. The results of the various models are compared with the existing experimental data. Due to large scattering in the experimental measurements, particularly the droplet diameter, no definite conclusion can be drawn based on the experimental data. Finally, certain research problems which are related to the present study are suggested for future studies.

Sirignano, W.A.; Yao, S.C.; Tong, A.Y.; Talley, D.

1983-01-01T23:59:59.000Z

243

Synthetic fuels summary. [1850 to 1979  

SciTech Connect (OSTI)

This report examines the federal government's experience in synfuels, the market potential of synfuels, the US energy resources base, and the numerous technologies available. Technologies and energy resources are reviewed and compared to provide the facts needed to understand existing energy-related problems. This introductory manual is an overview of synfuel technologies, and markets. It is not meant to be the sole source of information on which multi-billion dollar investment decisions for specific synfuel plants would be based. The report, published originally in August 1980, has been revised to incorporate appropriate corrections and clarifications. The intent behind these revisions is to present the best technical and programmatic information available as of the original publication date, August 1980. The original report included certain information about the relative costs of selected synfuels technologies. Economics are especially sensitive to recent events and updated information, and it would possibly be misleading to restate the original cost data in this report. It was felt that the original cost data needed major updating and reconciliation due to differences in project scope, basic assumptions, and costing methodologies. ESCOE believes that reliable economic comparisons require timely data and a recognition of any major differences in scope or methodology. Therefore, ESCOE, in a separate task, is undertaking an updated commercial scale economic comparison of selected synfuel processes, on a normalized basis. The results of this task will be published as a separate ESCOE report.

Not Available

1981-03-01T23:59:59.000Z

244

Catalyst for splitting water &Catalyst for splitting water & Synthetic Modeling of InorganicSynthetic Modeling of Inorganic  

E-Print Network [OSTI]

Importance Hydrogen technology in fuel cellsHydrogen technology in fuel cells As a combustion fuel, it producesCatalyst for splitting water &Catalyst for splitting water & Synthetic Modeling of Inorganic of evolution ·Optimized catalyst for water splitting in all oxygenic phototrophs S0 S4 S1 S2 S3 O2 2 H O2 e- e

Petta, Jason

245

DISTRIBUTED AND COLLABORATIVE SYNTHETIC ENVIRONMENTS  

E-Print Network [OSTI]

1 DISTRIBUTED AND COLLABORATIVE SYNTHETIC ENVIRONMENTS Chandrajit L. Bajaj and Fausto Bernardini with synthetic environments1,2,3,4,5,6 . A synthetic environment system is generally characterized and the synthetic environment generated by the computer. Several degrees of immersion are possible, ranging from

Texas at Austin, University of

246

SciTech Connect: Synthetic Biology and the U.S. Biotechnology...  

Office of Scientific and Technical Information (OSTI)

of Publication: United States Language: English Subject: 60 APPLIED LIFE SCIENCES; 09 BIOMASS FUELS; 29 ENERGY PLANNING, POLICY, AND ECONOMY synthetic biology, biotechnology...

247

Synthetic guide star generation  

DOE Patents [OSTI]

A system for assisting in observing a celestial object and providing synthetic guide star generation. A lasing system provides radiation at a frequency at or near 938 nm and radiation at a frequency at or near 1583 nm. The lasing system includes a fiber laser operating between 880 nm and 960 nm and a fiber laser operating between 1524 nm and 1650 nm. A frequency-conversion system mixes the radiation and generates light at a frequency at or near 589 nm. A system directs the light at a frequency at or near 589 nm toward the celestial object and provides synthetic guide star generation.

Payne, Stephen A. (Castro Valley, CA) [Castro Valley, CA; Page, Ralph H. (Castro Valley, CA) [Castro Valley, CA; Ebbers, Christopher A. (Livermore, CA) [Livermore, CA; Beach, Raymond J. (Livermore, CA) [Livermore, CA

2008-06-10T23:59:59.000Z

248

Biodegradable synthetic bone composites  

DOE Patents [OSTI]

The invention provides for a biodegradable synthetic bone composition comprising a biodegradable hydrogel polymer scaffold comprising a plurality of hydrolytically unstable linkages, and an inorganic component; such as a biodegradable poly(hydroxyethylmethacrylate)/hydroxyapatite (pHEMA/HA) hydrogel composite possessing mineral content approximately that of human bone.

Liu, Gao; Zhao, Dacheng; Saiz, Eduardo; Tomsia, Antoni P.

2013-01-01T23:59:59.000Z

249

Synthetic aircraft turbine oil  

SciTech Connect (OSTI)

Synthetic lubricating oil composition having improved oxidation stability comprising a major portion of an aliphatic ester base oil having lubricating properties, formed by the reaction of pentaerythritol and an organic monocarboxylic acid and containing a phenylnaphthylamine, a dialkyldiphenylamine, a polyhydroxy anthraquinone, a hydrocarbyl phosphate ester and a dialkyldisulfide.

Yaffe, R.

1982-03-16T23:59:59.000Z

250

Gasoline Jet Fuels  

E-Print Network [OSTI]

C4n= Diesel Gasoline Jet Fuels C O C5: Xylose C6 Fermentation of sugars Biofuel "Nanobowls" are inorganic catalysts that could provide the selectivity for converting sugars to fuels IACT Proposes Synthetic, Inorganic Catalysts to Produce Biofuels Current Process

Kemner, Ken

251

Guest Editors' Introduction: Synthetic Biology  

E-Print Network [OSTI]

+ undergraduate participants from around the world. Synthetic Biology had a global market which gene- rated $233 Tufts University h SYNTHETIC BIOLOGY IS trending, as evidenced by the recent achievements in biofuels

Densmore, Douglas

252

High temperature synthetic cement retarder  

SciTech Connect (OSTI)

A synthetic cement retarder which provides excellent retardation and compressive strength development has been synthesized. The response properties and temperature ranges of the synthetic retarder far exceed those of commonly used retarders such as lignosulfonates. The chemical nature of the new retarder is discussed and compared to another synthetic retarder.

Eoff, L.S.; Buster, D.

1995-11-01T23:59:59.000Z

253

Synthetic and Mechanistic Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout »LabSustainability

254

EARLY ENTRANCE COPRODUCTION PLANT  

SciTech Connect (OSTI)

The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, Inc., GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. During Phase I, a design basis for the Fischer-Tropsch Synthesis section was developed based on limited experience with the specified feed gas and operating conditions. The objective of this Task in Phase II RD&T work was to confirm the performance of the F-T reactor at the set design conditions. Although much of the research, development, and testing work were done by TES outside of this project, several important issues were addressed in this phase of the project. They included Rejuvenation/Regeneration of the Fischer-Tropsch Catalyst, online Catalyst Withdrawal and Addition from the synthesis reactor, and the Fischer-Tropsch Design Basis Confirmation. In Phase III the results from these RD&T work will be incorporated in developing the engineering design package. This Topical Report documents the Phase II RD&T work that was completed for this task.

David Storm; Govanon Nongbri; Steve Decanio; Ming He; Lalit Shah; Charles Schrader; Earl Berry; Peter Ricci; Belma Demirel; Charles Benham; Mark Bohn

2004-01-12T23:59:59.000Z

255

Synthetic and Mechanistic Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

several strategies being considered to create liquid fuel from different biomass feedstocks http:pearl1.lanl.govexternalResearchring-opening-article.shtml....

256

Synthetic and Mechanistic Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

several strategies being considered to create liquid fuel from different biomass feedstocks http:pearl1.lanl.govexternal Researchring-opening-article.shtml. *...

257

Synthetic and Mechanistic Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign Object Damage 3National LaboratoryX-rayand

258

Synthetic muscle developed with PPPL scientists' help ready for launch |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAbout »LabSustainabilitySynthetic fuel concept

259

STATEMENT OF CONSIDERATIONS REQUEST BY HEADWATERS TECHNOLOGY...  

Broader source: Energy.gov (indexed) [DOE]

a cooperative agreement for the performance of work entitled, "Production and Optimization of Coal-Derived High Hydrogen Content Fischer-Tropsch Liquids". The purpose of the...

260

Synthetic biology: Understanding biological design from synthetic circuits  

E-Print Network [OSTI]

An important aim of synthetic biology is to uncover the design principles of natural biological systems through the rational design of gene and protein circuits. Here, we highlight how the process of engineering biological ...

Mukherji, Shankar

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

DOE funds Bio-Inspired Solar Fuel Center at ASU  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The goal of ASU's new center is to design and construct a synthetic system that uses sunlight to convert water cheaply and efficiently into hydrogen fuel and oxygen....

262

DTU Synthetic Promoter Library Standard  

E-Print Network [OSTI]

The purpose of this RFC is to outline a method for generating a BioBrick compatible Synthetic Promoter Library (SPL) within bacteria in order to fine-tune the expression of BioBrick parts and devices.

Fortuna, Patrick

2010-12-04T23:59:59.000Z

263

Synthetic biology and crop engineering  

Broader source: Energy.gov [DOE]

Breakout Session 2: Frontiers and Horizons Session 2-A: Synthetic Biology and the Promise of Biofuels Jonathan Burbaum, Program Director, Department of Energy, Office of Science, ARPA–E

264

SYNTHETIC SLING FAILURE - EVALUATIONS & RECOMMENDATIONS  

SciTech Connect (OSTI)

The information and evaluations provided in this report were compiled to address the recurring problem of synthetic sling failure. As safety is the number one priority in all work aspects, a solution must be devised to prevent accidents from occurring. A total of thirteen cases regarding synthetic sling failure were evaluated in order to determine their causes, effects, and preventative measures. From the collected data, it was found that all cases in which the synthetic sling contacted the edge of its load resulted in sling failure. It is required that adequate synthetic sling protection devices be used to protect slings in any lift where the sling comes in direct contact with the edge or corner of its load. However, there are no consensus codes or standards stating the type, material, or purpose of the type of protective device used to protect the sling from being cut. Numerous industry standards and codes provide vague descriptions on how to protect synthetic slings. Without a clear, concise statement of how to protect synthetic slings, it is common for inadequate materials and sling protection devices to be used in an attempt to meet the intent of these requirements. The use of an inadequate sling protection device is the main cause of synthetic sling failure in all researched cases. Commercial sling protection devices come in many shapes and sizes, and have a variety of names, as well as advertised uses. 'Abrasion pads' and 'wear protectors' are two different names for products with the same intended purpose. There is no distinguishable way to determine the extent of sling protection which these devices will provide, or what specific scenarios they are made for. This creates room for error in a field where error is unacceptable. This report provides a recommended action for hoisting and rigging activities which require synthetic slings to contact a load, as well as recommended changes to industry standards which will benefit overall industry safety.

MACKEY TC; HENDERSON CS

2009-10-26T23:59:59.000Z

265

Subtask 4.4 - North Dakota Lignite Fuel Upgrading  

SciTech Connect (OSTI)

This project will add the capability for the Energy & Environmental Research Center (EERC) to conduct Fischer-Tropsch (FT) catalyst testing at a scale consistent with the benchscale continuous fluid-bed reactor. This capability will enable various vendors to test their FT catalysts on actual coal-derived syngas. The project goals were to also develop some EERC expertise with issues associated with FT liquid production. A study by Dr. Calvin Bartholmew at Brigham Young University (BYU) is further apparent that it is possible to build a single reactor (rather than multiple reactors of different sizes) consisting of three 1-inch-diameter, 10 foot-long tubes to accommodate the anticipated range of catalytic activities and process conditions. However, this single reactor should ideally be designed to operate over a significant range of recycle ratio (e.g., 1-10), temperature (25-400 C), pressure (10-25 bar), flow rate (1-6 scfm), and cooling duty (0.2-1.5 kW). It should have the flexibility of flowing gas to one, two, or three tubes. Based on the recommended design specifications provided by BYU while staying within the approved budget, the EERC decided to build a two fixed-bed reactor system with the capability to add a third reactor at a later time. This system was constructed to be modular and sized such that it can fit into the area around the EERC continuous fluid-bed reactor or also be located in explosion-rated areas such as the gasification tower next to the EERC pilot-scale transport reactor or in the National Center for Hydrogen Technology building high-bay area.

Michael Swanson

2009-03-15T23:59:59.000Z

266

3D CFD Model of High Temperature H2O/CO2 Co-electrolysis  

SciTech Connect (OSTI)

3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

2007-06-01T23:59:59.000Z

267

Synthetic LDL as targeted drug delivery vehicle  

DOE Patents [OSTI]

The present invention provides a synthetic LDL nanoparticle comprising a lipid moiety and a synthetic chimeric peptide so as to be capable of binding the LDL receptor. The synthetic LDL nanoparticle of the present invention is capable of incorporating and targeting therapeutics to cells expressing the LDL receptor for diseases associated with the expression of the LDL receptor such as central nervous system diseases. The invention further provides methods of using such synthetic LDL nanoparticles.

Forte, Trudy M. (Berkeley, CA); Nikanjam, Mina (Richmond, CA)

2012-08-28T23:59:59.000Z

268

Synthetic thermoelectric materials comprising phononic crystals  

DOE Patents [OSTI]

Synthetic thermoelectric materials comprising phononic crystals can simultaneously have a large Seebeck coefficient, high electrical conductivity, and low thermal conductivity. Such synthetic thermoelectric materials can enable improved thermoelectric devices, such as thermoelectric generators and coolers, with improved performance. Such synthetic thermoelectric materials and devices can be fabricated using techniques that are compatible with standard microelectronics.

El-Kady, Ihab F; Olsson, Roy H; Hopkins, Patrick; Reinke, Charles; Kim, Bongsang

2013-08-13T23:59:59.000Z

269

Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals  

SciTech Connect (OSTI)

A detailed study of the catalyst composition, preparation and activation protocol of Fe-based catalysts for the Fischer-Tropsch Synthesis (FTS) have been carried out in this project. We have studied the effects of different promoters on the catalytic performance of Fe-based catalysts. Specifically, we have focused on how their sequence of addition dramatically influences the performance of these materials in the Fischer-Tropsch synthesis. The resulting procedures have been optimized to improve further upon the already unprecedented rates and C{sub 5+} selectivities of the Fe-based catalysts that we have developed as part of this project. Selectivity to C{sub 5+} hydrocarbon was close to 90 % (CO{sub 2}-free basis) and CO conversion rate was about 6.7 mol h{sup -1} g-at Fe{sup -1} at 2.14 MPa, 508 K and with substoichiometric synthesis gas; these rates were larger than any reported previously for Fe-based FTS catalysts at these conditions. We also tested the stability of Fe-based catalysts during FTS reaction (10 days); as a result, the high hydrocarbon formation rates were maintained during 10 days, though the gradual deactivation was observed. Our investigation has also focused on the evaluation of Fe-based catalysts with hydrogen-poor synthesis gas streams (H{sub 2}/CO=1). We have observed that the Fe-based catalysts prepared in this project display also a high hydrocarbon synthesis rate with substoichiometric synthesis gas (H{sub 2}/CO=1) stream, which is a less desirable reactant mixture than stoichiometric synthesis gas (H{sub 2}/CO=2). We have improved the catalyst preparation protocols and achieved the highest FTS reaction rates and selectivities so far reported at the low temperatures required for selectivity and stability. Also, we have characterized the catalyst structural change and active phases formed, and their catalytic behavior during the activation process to evaluate their influences on FTS reaction. The efforts of this project led to (i) structural evolution of Fe-Zn oxide promoted with K and Cu, and (ii) evaluation of hydrocarbon and CH{sub 4} formation rates during activation procedures at various temperature and H{sub 2}/CO ratios. On the basis of the obtained results, we suggest that lower reactor temperature can be sufficient to activate catalysts and lead to the high FTS performance. In this project, we have also carried out a detailed kinetic and mechanistic study of the Fischer-Tropsch Synthesis with Fe-based catalysts. We have proposed a reaction mechanism with two CO activation pathways: unassisted and H-assisted. Both routes lead to the formation of the same surface monomers (CH{sub 2}). However, the oxygen removal mechanism is different. In the H-assisted route, oxygen is removed exclusively as water, while oxygen is rejected as carbon dioxide in the unassisted CO dissociation. The validity of the mechanism here proposed has been found to be in agreement with the experimental observation and with theoretical calculations over a Fe(110) surface. Also, we have studied the validity of the mechanism that we propose by analyzing the H{sub 2}/D{sub 2} kinetic isotope effect (r{sub H}/r{sub D}) over a conventional iron-based Fischer-Tropsch catalyst Fe-Zn-K-Cu. We have observed experimentally that the use of D{sub 2} instead of H{sub 2} leads to higher hydrocarbons formation rates (inverse kinetic isotopic effect). On the contrary, primary carbon dioxide formation is not influenced. These experimental observations can be explained by two CO activation pathways. We have also explored the catalytic performance of Co-based catalysts prepared by using inverse micelles techniques. We have studied several methods in order to terminate the silanol groups on SiO{sub 2} support including impregnation, urea homogeneous deposition-precipitation, or zirconium (IV) ethoxide titration. Although hydroxyl groups on the SiO{sub 2} surface are difficult to be stoichiometrically titrated by ZrO{sub 2}, a requirement to prevent the formation of strongly-interacting Co oxide species on SiO{sub 2}, modification of ZrO{

Enrique Iglesia; Akio Ishikawa; Manual Ojeda; Nan Yao

2007-09-30T23:59:59.000Z

270

Renewable Fuels and Lubricants (ReFUEL) Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

Not Available

2012-03-01T23:59:59.000Z

271

Synthetic and Mechanistic Chemistry publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign Object Damage 3National

272

Fossil fuels -- future fuels  

SciTech Connect (OSTI)

Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

NONE

1998-03-01T23:59:59.000Z

273

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network [OSTI]

Photovoltaic Produced Water Renewable Fuels Association ReliabilityFirst Corporation Reverse Osmosis Steam Assisted Gravity Drainage Soybean Meal Synthetic Crude Oil SERC Reliability

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

274

Renewable Energy from Synthetic Biology (LBNL Science at the Theater)  

ScienceCinema (OSTI)

Jay Keasling, co-leader of Berkeley Lab's Helios Project, is a groundbreaking researcher in the new scientific field of synthetic biology. In Helios, he directs the biology program, incorporating a range of approaches to increasing the efficacy and economy of plants and cellulose-degrading microbes to make solar-based fuels. He is a UC Berkeley professor of Chemical and Bioengineering, and founder of Amyris Biotechnologies, a company that was honored as a Technology Pioneer for 2006 by the World Economic Forum. Keasling has succeeded in using synthetic biology to develop a yeast-based production scheme for precursors of the antimalarial drug artemisinin in work funded by the Bill & Melinda Gates Foundation.

Keasling, Jay

2011-04-28T23:59:59.000Z

275

Cooperative Research in C1 Chemistry  

SciTech Connect (OSTI)

C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

Gerald P. Huffman

2000-10-27T23:59:59.000Z

276

DOE studies on coal-to-liquids  

SciTech Connect (OSTI)

The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

NONE

2007-07-01T23:59:59.000Z

277

Fracture of synthetic diamond M. D. Droty  

E-Print Network [OSTI]

Fracture of synthetic diamond M. D. Droty Ctystallume, 3506 Bassett Street, Santa Clara, California 1995) The fracture behavior of synthetic diamond has been investigated using indentation methods and by the tensile testing of pre-notched fracture-mechanics type samples. Specifically, the fracture toughness

Ritchie, Robert

278

Abstract The rapidly emerging field of synthetic biology  

E-Print Network [OSTI]

Abstract The rapidly emerging field of synthetic biology originated, as synthetic biology has expanded into mammalian systems, it is increasingly more. Biomaterials will play an important role in advancing synthetic biology

Reisslein, Martin

279

Gas turbine alternative fuels combustion characteristics  

SciTech Connect (OSTI)

An experimental investigation was conducted to obtain combustion performance and exhaust pollutant concentrations for specific synthetic hydrocarbon fuels. Baseline comparison fuels used were gasoline and diesel fuel number two. Testing was done over a range of fuel to air mass ratios, total mass flow rates, and input combustion air temperatures in a flame-tube-type gas turbine combustor. Test results were obtained in terms of released heat and combustion gas emission values. The results were comparable to those obtained with the base fuels with variations being obtained with changing operating conditions. The release of carbon particles during the tests was minimal. 22 refs., 12 figs., 2 tabs.

Rollbuhler, R.J.

1989-02-01T23:59:59.000Z

280

Fuel pin  

DOE Patents [OSTI]

A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

1987-11-24T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Computational optimization of synthetic water channels.  

SciTech Connect (OSTI)

Membranes for liquid and gas separations and ion transport are critical to water purification, osmotic energy generation, fuel cells, batteries, supercapacitors, and catalysis. Often these membranes lack pore uniformity and robustness under operating conditions, which can lead to a decrease in performance. The lack of uniformity means that many pores are non-functional. Traditional membranes overcome these limitations by using thick membrane materials that impede transport and selectivity, which results in decreased performance and increased operating costs. For example, limitations in membrane performance demand high applied pressures to deionize water using reverse osmosis. In contrast, cellular membranes combine high flux and selective transport using membrane-bound protein channels operating at small pressure differences. Pore size and chemistry in the cellular channels is defined uniformly and with sub-nanometer precision through protein folding. The thickness of these cellular membranes is limited to that of the cellular membrane bilayer, about 4 nm thick, which enhances transport. Pores in the cellular membranes are robust under operating conditions in the body. Recent efforts to mimic cellular water channels for efficient water deionization produced a significant advance in membrane function. The novel biomimetic design achieved a 10-fold increase in membrane permeability to water flow compared to commercial membranes and still maintained high salt rejection. Despite this success, there is a lack of understanding about why this membrane performs so well. To address this lack of knowledge, we used highperformance computing to interrogate the structural and chemical environments experienced by water and electrolytes in the newly created biomimetic membranes. We also compared the solvation environments between the biomimetic membrane and cellular water channels. These results will help inform future efforts to optimize and tune the performance of synthetic biomimetic membranes for applications in water purification, energy, and catalysis.

Rogers, David Michael; Rempe, Susan L. B.

2012-12-01T23:59:59.000Z

282

Molecular Interactions of Plutonium(VI) with SyntheticManganese...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite. Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite. Abstract:...

283

Iterative synthetic aperture radar imaging algorithms   

E-Print Network [OSTI]

Synthetic aperture radar is an important tool in a wide range of civilian and military imaging applications. This is primarily due to its ability to image in all weather conditions, during both the day and the night, ...

Kelly, Shaun Innes

2014-06-30T23:59:59.000Z

284

A modelling framework for Synthetic Biology  

E-Print Network [OSTI]

A modelling framework for Synthetic Biology Jakob Jakobsen Boysen Sune Mølgaard Laursen Kongens, 14-03-2014 Jakob Jakobsen Boysen & Sune Mølgaard Laursen #12;vi #12;Contents Summary (English) i

285

Synthetic analogs of bacterial quorum sensors  

DOE Patents [OSTI]

Bacterial quorum-sensing molecule analogs having the following structures: ##STR00001## and methods of reducing bacterial pathogenicity, comprising providing a biological system comprising pathogenic bacteria which produce natural quorum-sensing molecule; providing a synthetic bacterial quorum-sensing molecule having the above structures and introducing the synthetic quorum-sensing molecule into the biological system comprising pathogenic bacteria. Further is provided a method of targeted delivery of an antibiotic, comprising providing a synthetic quorum-sensing molecule; chemically linking the synthetic quorum-sensing molecule to an antibiotic to produce a quorum-sensing molecule-antibiotic conjugate; and introducing the conjugate into a biological system comprising pathogenic bacteria susceptible to the antibiotic.

Iyer, Rashi (Los Alamos, NM); Ganguly, Kumkum (Los Alamos, NM); Silks, Louis A. (Los Alamos, NM)

2011-12-06T23:59:59.000Z

286

Synthetic analogs of bacterial quorum sensors  

DOE Patents [OSTI]

Bacterial quorum-sensing molecule analogs having the following structures: ##STR00001## and methods of reducing bacterial pathogenicity, comprising providing a biological system comprising pathogenic bacteria which produce natural quorum-sensing molecule; providing a synthetic bacterial quorum-sensing molecule having the above structures and introducing the synthetic quorum-sensing molecule into the biological system comprising pathogenic bacteria. Further is provided a method of targeted delivery of an antibiotic, comprising providing a synthetic quorum-sensing molecule; chemically linking the synthetic quorum-sensing molecule to an antibiotic to produce a quorum-sensing molecule-antibiotic conjugate; and introducing the conjugate into a biological system comprising pathogenic bacteria susceptible to the antibiotic.

Iyer, Rashi S.; Ganguly, Kumkum; Silks, Louis A.

2013-01-08T23:59:59.000Z

287

Foundational platform for mammalian synthetic biology  

E-Print Network [OSTI]

The emergent field of synthetic biology is different from many other biological engineering efforts, in that its roots, design principles, and forward engineering perspective have been adopted from electrical engineering ...

Davidsohn, Noah (Noah Justin)

2013-01-01T23:59:59.000Z

288

Synthetic morphogenesis : space, time, and deformation  

E-Print Network [OSTI]

Synthetic biology has presented engineers with a fascinating opportunity: can we understand the principles of our origins { animal embryonic development - by re-engineering it in the laboratory? I investigate, from an ...

Brodsky, Micah Z. (Micah Zev)

2014-01-01T23:59:59.000Z

289

Synthetic heparin-binding growth factor analogs  

DOE Patents [OSTI]

The invention provides synthetic heparin-binding growth factor analogs having at least one peptide chain that binds a heparin-binding growth factor receptor, covalently bound to a hydrophobic linker, which is in turn covalently bound to a non-signaling peptide that includes a heparin-binding domain. The synthetic heparin-binding growth factor analogs are useful as soluble biologics or as surface coatings for medical devices.

Pena, Louis A.; Zamora, Paul; Lin, Xinhua; Glass, John D.

2007-01-23T23:59:59.000Z

290

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTourFrom3, 2015 7:00FuelFuelFuel

291

Conversion system overview assessment. Volume III. Solar thermal/coal or biomass derived fuels  

SciTech Connect (OSTI)

The three volumes of this report cover three distinct areas of solar energy research: solar thermoelectrics, solar-wind hybrid systems, and synthetic fuels derived with solar thermal energy. Volume III deals with the conversion of synthetic fuels with solar thermal heat. The method is a hybrid combination of solar energy with either coal or biomass. A preliminary assessment of this technology is made by calculating the cost of fuel produced as a function of the cost of coal and biomass. It is shown that within the projected ranges of coal, biomass, and solar thermal costs, there are conditions when solar synthetic fuels with solar thermal heat will become cost-competitive.

Copeland, R. J.

1980-02-01T23:59:59.000Z

292

Synthetic Datasets Rong Huang, Rada Chirkova, Yahya Fathi  

E-Print Network [OSTI]

Synthetic Datasets Rong Huang, Rada Chirkova, Yahya Fathi 1 Introduction Datasets may be generated will define symmetric synthetic dataset and two types of non-symmetric synthetic datasets that has some introduce symmetric synthetic dataset, its structure and the properties of the associated views. In Section

Young, R. Michael

293

Renewable Fuels and Lubricants Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

Not Available

2014-08-01T23:59:59.000Z

294

Fuel Economy  

Broader source: Energy.gov [DOE]

The Energy Department is investing in groundbreaking research that will make cars weigh less, drive further and consume less fuel.

295

Theoretical Cluster Studies on the Catalytic Sulfidation of MoO3 Xue-Rong Shi,,,  

E-Print Network [OSTI]

, State Key Laboratory of Coal ConVersion, Institute of Coal Chemistry, Chinese Academy of Sciences (HDN) processes and exhibit also high activity for methanation and for the Fischer-Tropsch synthesis and sulfur adsor- bates as well as hydrogen

296

Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.  

E-Print Network [OSTI]

??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

Balonek, Christine Marie

2011-01-01T23:59:59.000Z

297

CX-009372: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Small Scale Coal-Biomass to Liquids Using Highly Selective Fischer-Tropsch Synthesis CX(s) Applied: A9 Date: 09/17/2012 Location(s): California Offices(s): National Energy Technology Laboratory

298

Mobility with Hydrogen Fuel Cells Becomes Reality! 2Daimler AG / 09.02.2012  

E-Print Network [OSTI]

Bio-Mass Natural Gas Crude Oil Conventional fuels sulphur-free, free of aromatic compounds fuels system & stack Electric engine H2 tank system Infrastructure Hydrogen costs Reliable refueling technology Synthetic fuels (GTL) sulphur-free, free of aromatic compounds Natural Gas (CNG) 1. Gen. Bio-Fuels (Ethanol

California at Davis, University of

299

Transportation Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButler TinaContact-Information-TransmissionLaboratoryFuels

300

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note:Computing | ArgonnechallengingFryFuel

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

New Synthetic Methods for Hypericum Natural Products  

SciTech Connect (OSTI)

Organic chemistry has served as a solid foundation for interdisciplinary research areas, such as molecular biology and medicinal chemistry. An understanding of the biological activities and structural elucidations of natural products can lead to the development of clinically valuable therapeutic options. The advancements of modern synthetic methodologies allow for more elaborate and concise natural product syntheses. The theme of this study centers on the synthesis of natural products with particularly challenging structures and interesting biological activities. The synthetic expertise developed here will be applicable to analog syntheses and to other research problems.

Insik Jeon

2006-12-12T23:59:59.000Z

302

Synthetic heparin-binding factor analogs  

DOE Patents [OSTI]

The invention provides synthetic heparin-binding growth factor analogs having at least one peptide chain, and preferably two peptide chains branched from a dipeptide branch moiety composed of two trifunctional amino acid residues, which peptide chain or chains bind a heparin-binding growth factor receptor and are covalently bound to a non-signaling peptide that includes a heparin-binding domain, preferably by a linker, which may be a hydrophobic linker. The synthetic heparin-binding growth factor analogs are useful as pharmaceutical agents, soluble biologics or as surface coatings for medical devices.

Pena, Louis A. (Poquott, NY); Zamora, Paul O. (Gaithersburg, MD); Lin, Xinhua (Plainview, NY); Glass, John D. (Shoreham, NY)

2010-04-20T23:59:59.000Z

303

Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation  

E-Print Network [OSTI]

-SeparationUnit........................................................................18 3.4.3SyngasGeneration..........................................................................18 3.4.4Fischer-Tropsch(FT)Synthesis.....................................................20 viii CHAPTER Page 3.4.5Product...Description TherearethreestagesinvolvedintheconversionofnaturalgasintoGTLfuels-Syngas generation,Fischer-Tropsch(FT)synthesis,andProductupgrade.Adetailedresultofthe processmodelinginAspenPlusisincludedinAppendixB,whiletheactualprocessmap isshowninFigureA1inAppendixAandFigure3.1below. 17...

Adegoke, Adesola Ayodeji

2006-10-30T23:59:59.000Z

304

F-T process using an iron on mixed zirconia-titania supported catalyst  

DOE Patents [OSTI]

A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.

Dyer, Paul N. (Allentown, PA); Nordquist, Andrew F. (Whitehall, PA); Pierantozzi, Ronald (Macungie, PA)

1987-01-01T23:59:59.000Z

305

Biodiesel Fuel  

E-Print Network [OSTI]

publication 442-880 There are broad and increasing interests across the nation in using domestic, renewable bioenergy. Virginia farmers and transportation fleets use considerable amounts of diesel fuel in their operations. Biodiesel is an excellent alternative fuel for the diesel engines. Biodiesel can be produced from crops commonly grown in Virginia, such as soybean and canola, and has almost the same performance as petrodiesel. The purpose of this publication is to introduce the basics of biodiesel fuel and address some myths and answer some questions about biodiesel fuel before farmers and fleet owners use this type of fuel. ASTM standard for biodiesel (ASTM D6751) Biodiesel fuel, hereafter referred to as simply biodiesel,

unknown authors

306

Intelligibility enhancement of synthetic speech in noise  

E-Print Network [OSTI]

Intelligibility enhancement of synthetic speech in noise C´assia Valentini Botinh~ao TH E U N I V E of a hidden Markov model (HMM-) based speech synthesis system that allows for flexible enhancement strategies with noise-independent enhancement approaches based on the acoustics of highly intelligible speech

Edinburgh, University of

307

1 Synthetic Texturing 1.1 Introduction  

E-Print Network [OSTI]

1 Synthetic Texturing 1.1 Introduction This dissertation describes improved methods for computer of this, the top of Figure 1.1 shows a horse model with a white surface and the bottom shows this same-hocformulasforlightreflection Figure 1.1: Stripe texture created using reaction-diffusion. Top is an untextured horse and the bottom

Turk, Greg

308

Immobilization of radioiodine in synthetic boracite  

DOE Patents [OSTI]

A nuclear waste storage product is disclosed in which radioiodine is incorporated in a synthetic boracite. The boracite may be prepared by reacting a transition metal iodide with an alkali horate under mild hydrothermal conditions, drying the reaction product, and then hot pressing.

Babad, H.; Strachan, D.M.

1982-09-23T23:59:59.000Z

309

CO2 Capture with Enzyme Synthetic Analogue  

SciTech Connect (OSTI)

Project overview provides background on carbonic anhydrase transport mechanism for CO2 in the human body and proposed approach for ARPA-E project to create a synthetic enzyme analogue and utilize it in a membrane for CO2 capture from flue gas.

Harry Cordatos

2010-03-01T23:59:59.000Z

310

SYNTHETIC LUBRICANTS, INC 1411 Callaghan Drive  

E-Print Network [OSTI]

1 SYNTHETIC LUBRICANTS, INC 1411 Callaghan Drive Greenville, MI 48838 MATERIAL SAFETY DATA SHEET irritating and potentially toxic fumes containing oxides of nitrogen if exposed to extreme heat in air: (Conditions to Avoid) Stable under normal use conditions and in final use concentration. Incompatibility

Rollins, Andrew M.

311

SYNTHETIC LUBRICANTS, INC 1411 Callaghan Drive  

E-Print Network [OSTI]

1 SYNTHETIC LUBRICANTS, INC 1411 Callaghan Drive Greenville, MI 48838 MATERIAL SAFETY DATA SHEET. It will produce irritating and potentially toxic fumes containing oxides of nitrogen if exposed to extreme heat: (Conditions to Avoid) Stable under normal use conditions and in final use concentration. Incompatibility

Rollins, Andrew M.

312

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTourFrom3, 2015

313

Feedback control of flow separation using synthetic jets  

E-Print Network [OSTI]

The primary goal of this research is to assess the effect of synthetic jets on flow separation and provide a feedback control strategy for flow separation using synthetic jets. The feedback control synthesis is conducted based upon CFD simulation...

Kim, Kihwan

2006-04-12T23:59:59.000Z

314

Aspects of the political economy of development and synthetic biology  

E-Print Network [OSTI]

What implications might synthetic biology’s potential as a wholly new method of production have for the world economy, particularly developing countries? Theories of political economy predict that synthetic biology can ...

Wellhausen, Rachel

315

Department of Mechanical Engineering Spring 2012 Synthetic Cable Termination  

E-Print Network [OSTI]

PENNSTATE Department of Mechanical Engineering Spring 2012 Synthetic Cable Termination Overview to be grasped. The methods for terminating the metallic cable will not work with the synthetic cable, so a new termination method is needed. The synthetic cable is a new design that has yet to be successfully terminated

Demirel, Melik C.

316

Numerical Methods for the Valuation of Synthetic Collateralized Debt Obligations  

E-Print Network [OSTI]

Numerical Methods for the Valuation of Synthetic Collateralized Debt Obligations by Xiaofang Ma Methods for the Valuation of Synthetic Collateralized Debt Obligations Xiaofang Ma Doctor of Philosophy methods for synthetic CDO valuation are presented. iii #12;Acknowledgements Although many people have

Toronto, University of

317

Composition and Biodegradation of a Synthetic Oil Spilled on the  

E-Print Network [OSTI]

-AN8) as well as a total of 27 L of hydraulic fluid MIL-5605 and synthetic turbine oil Aeroshell 500 in January 2003 on the 5 m-thick perennial ice cover of Lake Fryxell, spilling synthetic turbine oil et al. (9). Here, we compare the initial chemical composition of the synthetic turbine lubricant

Priscu, John C.

318

HUTTON ET. AL.: PARAMETERIZED GENERATION OF SYNTHETIC COMBINATIONAL BENCHMARK CIRCUITS 1 Characterization and Parameterized Generation of Synthetic  

E-Print Network [OSTI]

HUTTON ET. AL.: PARAMETERIZED GENERATION OF SYNTHETIC COMBINATIONAL BENCHMARK CIRCUITS 1 Characterization and Parameterized Generation of Synthetic Combinational Benchmark Circuits Michael D. Hutton placement and routing algorithms. In this paper, we present a method and a tool for generating parameterized

Rose, Jonathan

319

Flow control via synthetic jet actuation  

E-Print Network [OSTI]

4.1 Wind Tunnel Model Showing SJA Drive Through Acrylic Access Panel ..........41 4.2 Cross Section of Trailing Edge Showing Original Plenum Design .....................41 4.3 Cross Section of Trailing Edge Showing Narrow Plenum Design.... ...........................................................48 1 1. INTRODUCTION General This thesis presents a study of the effects of flow control on a NACA0015 airfoil using Synthetic Jet Actuators (SJA) at different locations along the chord. The purpose of this research was to show...

Miller, Adam Cole

2005-02-17T23:59:59.000Z

320

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network [OSTI]

A. Miller (1980). "Oil Shales and Carbon Dioxide." Sciencefor CO2 evolved from oil shale." Fuel Processing TechnologyCTLs, or CTL synfuels), and oil shale-based synthetic crude

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Life Cycle Analysis of the Production of Aviation Fuels Using the CE-CERT Process  

E-Print Network [OSTI]

of Municipal Sewage Sludge to Produce Synthetic Fuels,5.4 million dry metric tons of sludge annually or 47pounds of sewage sludge (dry weight basis) for every

Hu, Sangran

2012-01-01T23:59:59.000Z

322

Synthetic Genomics Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty LtdSteen,Ltd Jump to: navigation,Open EnergyFacility | OpenEV Jump

323

Unconventional fuel: Tire derived fuel  

SciTech Connect (OSTI)

Material recovery of scrap tires for their fuel value has moved from a pioneering concept in the early 1980`s to a proven and continuous use in the United States` pulp and paper, utility, industrial, and cement industry. Pulp and paper`s use of tire derived fuel (TDF) is currently consuming tires at the rate of 35 million passenger tire equivalents (PTEs) per year. Twenty mills are known to be burning TDF on a continuous basis. The utility industry is currently consuming tires at the rate of 48 million PTEs per year. Thirteen utilities are known to be burning TDF on a continuous basis. The cement industry is currently consuming tires at the rate of 28 million PTEs per year. Twenty two cement plants are known to be burning TDF on a continuous basis. Other industrial boilers are currently consuming tires at the rate of 6.5 million PTEs per year. Four industrial boilers are known to be burning TDF on a continuous basis. In total, 59 facilities are currently burning over 117 million PTEs per year. Although 93% of these facilities were not engineered to burn TDF, it has become clear that TDF has found acceptance as a supplemental fuel when blending with conventional fuels in existing combustion devices designed for normal operating conditions. The issues of TDF as a supplemental fuel and its proper specifications are critical to the successful development of this fuel alternative. This paper will focus primarily on TDF`s use in a boiler type unit.

Hope, M.W. [Waste Recovery, Inc., Portland, OR (United States)

1995-09-01T23:59:59.000Z

324

BWR Fuel Assembly BWR Fuel Assembly PWR Fuel Assembly  

National Nuclear Security Administration (NNSA)

BWR Fuel Assembly BWR Fuel Assembly PWR Fuel Assembly PWR Fuel Assembly The PWR 17x17 assembly is approximately 160 inches long (13.3 feet), 8 inches across, and weighs 1,500 lbs....

325

A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry  

SciTech Connect (OSTI)

Production of liquid fuels and chemicals via gasification of kraft black liquor and woody residues (''biorefining'') has the potential to provide significant economic returns for kraft pulp and paper mills replacing Tomlinson boilers beginning in the 2010-2015 timeframe. Commercialization of gasification technologies is anticipated in this period, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are in most cases already commercially established today in the ''gas-to-liquids'' industry. These conclusions are supported by detailed analysis carried out in a two-year project co-funded by the American Forest and Paper Association and the Biomass Program of the U.S. Department of Energy. This work assessed the energy, environment, and economic costs and benefits of biorefineries at kraft pulp and paper mills in the United States. Seven detailed biorefinery process designs were developed for a reference freesheet pulp/paper mill in the Southeastern U.S., together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. Commercial (''Nth'') plant levels of technology performance and cost were assumed. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which would be refined to vehicle fuels at existing petroleum refineries), dimethyl ether (a diesel engine fuel or LPG substitute), or an ethanol-rich mixed-alcohol product. Compared to installing a new Tomlinson power/recovery system, a biorefinery would require larger capital investment. However, because the biorefinery would have higher energy efficiencies, lower air emissions, and a more diverse product slate (including transportation fuel), the internal rates of return (IRR) on the incremental capital investments would be attractive under many circumstances. For nearly all of the cases examined in the study, the IRR lies between 14% and 18%, assuming a 25-year levelized world oil price of $50/bbl--the US Department of Energy's 2006 reference oil price projection. The IRRs would rise to as high as 35% if positive incremental environmental benefits associated with biorefinery products are monetized (e.g., if an excise tax credit for the liquid fuel is available comparable to the one that exists for ethanol in the United States today). Moreover, if future crude oil prices are higher ($78/bbl levelized price, the US Department of Energy's 2006 high oil price scenario projection, representing an extrapolation of mid-2006 price levels), the calculated IRR exceeds 45% in some cases when environmental attributes are also monetized. In addition to the economic benefits to kraft pulp/paper producers, biorefineries widely implemented at pulp mills in the U.S. would result in nationally-significant liquid fuel production levels, petroleum savings, greenhouse gas emissions reductions, and criteria-pollutant reductions. These are quantified in this study. A fully-developed pulpmill biorefinery industry could be double or more the size of the current corn-ethanol industry in the United States in terms of annual liquid fuel production. Forest biomass resources are sufficient in the United States to sustainably support such a scale of forest biorefining in addition to the projected growth in pulp and paper production.

Eric D. Larson; Stefano Consonni; Ryan E. Katofsky; Kristiina Iisa; W. James Frederick

2007-03-31T23:59:59.000Z

326

Micro/nanofabricated environments for synthetic biology  

SciTech Connect (OSTI)

A better understanding of how confinement, crowding and reduced dimensionality modulate reactivity and reaction dynamics will aid in the rational and systematic discovery of functionality in complex biological systems. Artificial micro- and nanofabricated structures have helped elucidate the effects of nanoscale spatial confinement and segregation on biological behavior, particularly when integrated with microfluidics, through precise control in both space and time of diffusible signals and binding interactions. Examples of nanostructured interfaces for synthetic biology include the development of cell-like compartments for encapsulating biochemical reactions, nanostructured environments for fundamental studies of diffusion, molecular transport and biochemical reaction kinetics, and regulation of biomolecular interactions as functions of micro- and nanofabricated topological constraints.

Collier, Pat [ORNL; Simpson, Michael L [ORNL

2011-01-01T23:59:59.000Z

327

Fossil Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fossil Fuels A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Abu-Khamsin, Sidqi - Department of Petroleum Engineering, King Fahd University of Petroleum and Minerals...

328

Certification of alternative aviation fuels and blend components  

SciTech Connect (OSTI)

Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

Wilson III, George R. (Southwest Research Institute, 6220 Culebra Road, San Antonio, Texas 78238 (United States)); Edwards, Tim; Corporan, Edwin (United States Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States)); Freerks, Robert L. (Rentech, Incorporated, 1331 17th Street, Denver, Colorado 80202 (United States))

2013-01-15T23:59:59.000Z

329

Structural Characteristics of Synthetic Amorphous Calcium Carbonate  

SciTech Connect (OSTI)

Amorphous calcium carbonate (ACC) is an important phase involved in calcification by a wide variety of invertebrate organisms and is of technological interest in the development of functional materials. Despite widespread scientific interest in this phase a full characterization of structure is lacking. This is mainly due to its metastability and difficulties in evaluating structure using conventional structure determination methods. Here we present new findings from the application of two techniques, pair distribution function analysis and nuclear magnetic resonance spectroscopy, which provide new insight to structural aspects of synthetic ACC. Several important results have emerged from this study of ACC formed in vitro using two common preparation methods: (1) ACC exhibits no structural coherence over distances > 15 {angstrom} and is truly amorphous; (2) most of the hydrogen in ACC is present as structural H{sub 2}O, about half of which undergoes restricted motion on the millisecond time scale near room temperature; (3) the short- and intermediate-range structure of ACC shows no distinct match to any known structure in the calcium carbonate system; and (4) most of the carbonate in ACC is monodentate making it distinctly different from monohydrocalcite. Although the structure of synthetic ACC is still not fully understood, the results presented provide an important baseline for future experiments evaluating biogenic ACC and samples containing certain additives that may play a role in stabilization of ACC, crystallization kinetics, and final polymorph selection.

Michel, F. Marc; MacDonald, Jason; Feng, Jian; Phillips, Brian L.; Ehm, Lars; Tarabrella, Cathy; Parise, John B.; Reeder, Richard J. (SBU)

2008-08-06T23:59:59.000Z

330

Chemistry in Motion: Tiny Synthetic Motors  

E-Print Network [OSTI]

In this Account, we describe how synthetic motors that operate by self-diffusiophoresis make use of a self-generated concentration gradient to drive motor motion. A description of propulsion by self-diffusiophoresis is presented for Janus particle motors comprising catalytic and noncatalytic faces. The properties of the dynamics of chemically powered motors are illustrated by presenting the results of particle-based simulations of sphere-dimer motors constructed from linked catalytic and noncatalytic spheres. The geometries of both Janus and sphere-dimer motors with asymmetric catalytic activity support the formation of concentration gradients around the motors. Because directed motion can occur only when the system is not in equilibrium, the nature of the environment and the role it plays in motor dynamics are described. Rotational Brownian motion also acts to limit directed motion, and it has especially strong effects for very small motors. We address the following question: how small can motors be and still exhibit effects due to propulsion, even if only to enhance diffusion? Synthetic motors have the potential to transform the manner in which chemical dynamical processes are carried out for a wide range of applications.

Peter H. Colberg; Shang Yik Reigh; Bryan Robertson; Raymond Kapral

2014-11-03T23:59:59.000Z

331

Fuel cell-fuel cell hybrid system  

DOE Patents [OSTI]

A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

Geisbrecht, Rodney A.; Williams, Mark C.

2003-09-23T23:59:59.000Z

332

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel  

E-Print Network [OSTI]

collectors. In a Polymer Electrolyte Membrane (PEM) fuel cell, which is widely regarded as the most promisingFUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fuel Cells -- is the key to making it happen. Stationary fuel cells can be used for backup power, power for remote loca

333

Kinetics and thermodynamics of hydrotreating synthetic middle distillates  

SciTech Connect (OSTI)

Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

1987-04-01T23:59:59.000Z

334

Sorption-Enhanced Synthetic Natural Gas (SNG) Production from...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel...

335

A Synthetic Biology Framework for Programming Eukaryotic Transcription Functions  

E-Print Network [OSTI]

Eukaryotic transcription factors (TFs) perform complex and combinatorial functions within transcriptional networks. Here, we present a synthetic framework for systematically constructing eukaryotic transcription functions ...

Khalil, Ahmad S.

336

US Synthetic Corp (TRL 4 Component) - The Development of Open...  

Broader source: Energy.gov (indexed) [DOE]

Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines US Synthetic Corp (TRL 4 Component) - The Development of Open, Water Lubricated...

337

Synthetic nanotubes lay foundation for new technology: Artificial...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthetic nanotubes lay foundation for new technology: Artificial pores mimic key features of natural pores By Tona Kunz * July 17, 2012 Tweet EmailPrint Scientists have overcome...

338

Vehicle Technologies Office Merit Review 2014: Synthetic Solutions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

about synthetic solutions for correcting voltage fade in LMR-NMC cathodes. es190johnson2014o.pdf More Documents & Publications Cathode Synthesis and Voltage Fade: Designed...

339

Performance limits for Synthetic Aperture Radar.  

SciTech Connect (OSTI)

The performance of a Synthetic Aperture Radar (SAR) system depends on a variety of factors, many which are interdependent in some manner. It is often difficult to ''get your arms around'' the problem of ascertaining achievable performance limits, and yet those limits exist and are dictated by physics, no matter how bright the engineer tasked to generate a system design. This report identifies and explores those limits, and how they depend on hardware system parameters and environmental conditions. Ultimately, this leads to a characterization of parameters that offer optimum performance for the overall SAR system. For example, there are definite optimum frequency bands that depend on weather conditions and range, and minimum radar PRF for a fixed real antenna aperture dimension is independent of frequency. While the information herein is not new to the literature, its collection into a single report hopes to offer some value in reducing the ''seek time''.

Doerry, Armin Walter

2006-02-01T23:59:59.000Z

340

Directed evolution: an evolving and enabling synthetic biology tool  

E-Print Network [OSTI]

Directed evolution: an evolving and enabling synthetic biology tool Ryan E Cobb1 , Tong Si1 remains a valuable tool for synthetic biology, enabling the identification of desired functionalities from biological entity with the intent of identifying those with desired proper- ties. While a powerful tool

Zhao, Huimin

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

analogue synthetics coumarins: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

analogue synthetics coumarins First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Synthetic Analogues of...

342

Utilization of alternative fuels in diesel engines  

SciTech Connect (OSTI)

The important findings for a 41-month research grant entitled The Utilization of Alternate Fuels in Diesel Engines are summarized. The procedure followed was to collect performance and emission data for various candidate alternate fuels and compare these data to that for a certified petroleum-based number two Diesel fuel oil. The method of test-fuel introduction was either via fumigation or to use the engine stock injection system. Results for methanol, ethanol, four vegetable oils, two shale-derived oils, and two coal-derived oils are reported. Based upon this study, alcohol fumigation does not appear to be a practical method for utilizing low combustion quality fuels in a Diesel engine. The reasons being, the need for a complex fuel management system and a narrow operating range bounded by wet misfire on the low load end and by severe knock at medium to high loads. Also, it was misfire on the low load end and by severe knock at medium to high loads. Also, it was found that alcohol fumigation enhances the bioactivity of the emitted exhaust particles. Finally, this study showed that while it is possible to inject many synthetic fuels using the engine stock injection system, wholly acceptable performance is only obtained from a fuel whose specifications closely approach those of a finished petroleum-based Diesel oil.

Lestz, S.S.

1984-05-01T23:59:59.000Z

343

A Synthetic Resilin Is Largely Unstructured  

SciTech Connect (OSTI)

Proresilin is the precursor protein for resilin, an extremely elastic, hydrated, cross-linked insoluble protein found in insects. We investigated the secondary-structure distribution in solution of a synthetic proresilin (AN16), based on 16 units of the consensus proresilin repeat from Anopheles gambiae. Raman spectroscopy was used to verify that the secondary-structure distributions in cross-linked AN16 resilin and in AN16 proresilin are similar, and hence that solution techniques (such as NMR and circular dichroism) may be used to gain information about the structure of the cross-linked solid. The synthetic proresilin AN16 is an intrinsically unstructured protein, displaying under native conditions many of the characteristics normally observed in denatured proteins. There are no apparent {alpha}-helical or {beta}-sheet features in the NMR spectra, and the majority of backbone protons and carbons exhibit chemical shifts characteristic of random-coil configurations. Relatively few peaks are observed in the nuclear Overhauser effect spectra, indicating that overall the protein is dynamic and unstructured. The radius of gyration of AN16 corresponds to the value expected for a denatured protein of similar chain length. This high degree of disorder is also consistent with observed circular dichroism and Raman spectra. The temperature dependences of the NH proton chemical shifts were also measured. Most values were indicative of protons exposed to water, although smaller dependences were observed for glycine and alanine within the Tyr-Gly-Ala-Pro sequence conserved in all resilins found to date, which is the site of dityrosine cross-link formation. This result implies that these residues are involved in hydrogen bonds, possibly to enable efficient self-association and subsequent cross-linking. The {beta}-spiral model for elastic proteins, where the protein is itself shaped like a spring, is not supported by the results for AN16. Both the random-network elastomer model and the sliding {beta}-turn model are consistent with the data. The results indicate a flat energy landscape for AN16, with very little energy required to switch between conformations. This ease of switching is likely to lead to the extremely low energy loss on deformation of resilin.

Nairn, Kate M.; Lyons, Russell E.; Mulder, Roger J.; Mudie, Stephen T.; Cookson, David J.; Lesieur, Emmanuelle; Kim, Misook; Lau, Deborah; Scholes, Fiona H.; Elvin, Christopher M. (CSIRO/MSE); (CSIRO/MHT); (CSIRO/LI); (Aust. Synch.)

2008-11-03T23:59:59.000Z

344

Fuel Processing Valri Lightner  

E-Print Network [OSTI]

of Hydrogen · Fuel Processors for PEM Fuel Cells Nuvera Fuel Cells, Inc. GE Catalytica ANL PNNL University-Board Fuel Processing Barriers $35/kW Fuel Processor $10/kW Fuel Cell Power Systems $45/kW by 2010 BARRIERS · Fuel processor start-up/ transient operation · Durability · Cost · Emissions and environmental issues

345

Integrated Operation of INL HYTEST System and High-Temperature Steam Electrolysis for Synthetic Natural Gas Production  

SciTech Connect (OSTI)

The primary feedstock for synthetic fuel production is syngas, a mixture of carbon monoxide and hydrogen. Current hydrogen production technologies rely upon fossil fuels and produce significant quantities of greenhouse gases as a byproduct. This is not a sustainable means of satisfying future hydrogen demands, given the current projections for conventional world oil production and future targets for carbon emissions. For the past six years, the Idaho National Laboratory has been investigating the use of high-temperature steam electrolysis (HTSE) to produce the hydrogen feedstock required for synthetic fuel production. High-temperature electrolysis water-splitting technology, combined with non-carbon-emitting energy sources, can provide a sustainable, environmentally-friendly means of large-scale hydrogen production. Additionally, laboratory facilities are being developed at the INL for testing hybrid energy systems composed of several tightly-coupled chemical processes (HYTEST program). The first such test involved the coupling of HTSE, CO2 separation membrane, reverse shift reaction, and methanation reaction to demonstrate synthetic natural gas production from a feedstock of water and either CO or a simulated flue gas containing CO2. This paper will introduce the initial HTSE and HYTEST testing facilities, overall coupling of the technologies, testing results, and future plans.

Carl Marcel Stoots; Lee Shunn; James O'Brien

2010-06-01T23:59:59.000Z

346

Fuel reforming for fuel cell application.  

E-Print Network [OSTI]

??Fossil fuels, such as natural gas, petroleum, and coal are currently the primary source of energy that drives the world economy. However, fossil fuel is… (more)

Hung, Tak Cheong

2006-01-01T23:59:59.000Z

347

Synthetic aperture radar processing with tiered subapertures  

SciTech Connect (OSTI)

Synthetic Aperture Radar (SAR) is used to form images that are maps of radar reflectivity of some scene of interest, from range soundings taken over some spatial aperture. Additionally, the range soundings are typically synthesized from a sampled frequency aperture. Efficient processing of the collected data necessitates using efficient digital signal processing techniques such as vector multiplies and fast implementations of the Discrete Fourier Transform. Inherent in image formation algorithms that use these is a trade-off between the size of the scene that can be acceptably imaged, and the resolution with which the image can be made. These limits arise from migration errors and spatially variant phase errors, and different algorithms mitigate these to varying degrees. Two fairly successful algorithms for airborne SARs are Polar Format processing, and Overlapped Subaperture (OSA) processing. This report introduces and summarizes the analysis of generalized Tiered Subaperture (TSA) techniques that are a superset of both Polar Format processing and OSA processing. It is shown how tiers of subapertures in both azimuth and range can effectively mitigate both migration errors and spatially variant phase errors to allow virtually arbitrary scene sizes, even in a dynamic motion environment.

Doerry, A.W. [Sandia National Labs., Albuquerque, NM (United States). Synthetic Aperture Radar Dept.

1994-06-01T23:59:59.000Z

348

Motion Measurement for Synthetic Aperture Radar.  

SciTech Connect (OSTI)

Synthetic Aperture Radar (SAR) measures radar soundings from a set of locations typically along the flight path of a radar platform vehicle. Optimal focusing requires precise knowledge of the sounding source locations in 3 - D space with respect to the target scene. Even data driven focusing techniques (i.e. autofocus) requires some degree of initial fidelity in the measurements of the motion of the radar. These requirements may be quite stringent especially for fine resolution, long ranges, and low velocities. The principal instrument for measuring motion is typically an Inertial Measurement Unit (IMU), but these instruments have inherent limi ted precision and accuracy. The question is %22How good does an IMU need to be for a SAR across its performance space?%22 This report analytically relates IMU specifications to parametric requirements for SAR. - 4 - Acknowledgements Th e preparation of this report is the result of a n unfunded research and development activity . Although this report is an independent effort, it draws heavily from limited - release documentation generated under a CRADA with General Atomics - Aeronautical System, Inc. (GA - ASI), and under the Joint DoD/DOE Munitions Program Memorandum of Understanding. Sandia National Laboratories is a multi - program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of En ergy's National Nuclear Security Administration under contract DE - AC04 - 94AL85000.

Doerry, Armin W.

2015-01-01T23:59:59.000Z

349

Alternative Fuel Vehicle Resources  

Broader source: Energy.gov [DOE]

Alternative fuel vehicles use fuel types other than petroleum and include such fuels as electricity, ethanol, biodiesel, natural gas, hydrogen, and propane. Compared to petroleum, these...

350

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Grants and Rebates The Arkansas Alternative Fuels Development Program (Program) provides grants to alternative fuel producers, feedstock processors, and...

351

Alternative Fuel Implementation Toolkit  

E-Print Network [OSTI]

? Alternative Fuels, the Smart Choice: Alternative fuels ­ biodiesel, electricity, ethanol (E85), natural gas...........................................................................................................................................................................6 Trends and Fleet Examples: Alternative Fuel Decision Table

352

Saving Fuel, Reducing Emissions  

E-Print Network [OSTI]

would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

2009-01-01T23:59:59.000Z

353

Low Carbon Fuel Standards  

E-Print Network [OSTI]

in 1990. These many alternative-fuel initiatives failed tolow-cost, low-carbon alternative fuels would thrive. Theto introduce low-carbon alternative fuels. Former Federal

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

354

Hydrogen Fuel Cell Vehicles  

E-Print Network [OSTI]

Research Institute 1990 Fuel Cell Status," Proceedings ofMiller, "Introduction: Fuel-Cell-Powered Vehicle DevelopmentPrograms," presented at Fuel Cells for Transportation,

Delucchi, Mark

1992-01-01T23:59:59.000Z

355

Engine Materials Compatability with Alternative Fuels  

SciTech Connect (OSTI)

The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined were accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

Pawel, Steve [Oak Ridge National Laboratory; Moore, D. [USCAR

2013-04-05T23:59:59.000Z

356

Coal based fuels, fuel systems and alternative fuels  

SciTech Connect (OSTI)

The introduction of coal based fuel systems such as coal/air and coal water mixtures was an attempt to minimize the use of heavy fuel oils in large scale power generation processes. This need was based on forecasts of fuel reserves and future pricing of fuel oils, therefore economic considerations predominated over environmental benefits, if any, which could result from widespread use of these fuels. Coal continued as the major fuel used in the power generation industry and combustion systems were developed to minimize gaseous emissions, such as NOx. Increasing availability of natural gas led to consideration of its use in combination with coal in fuel systems involving combined cycle or topping cycle operations. Dual fuel coal natural gas operations also offered the possibility of improved performance in comparison to 100% coal based fuel systems. Economic considerations have more recently looked at emulsification of heavy residual liquid fuels for consumption in power generation boiler and Orimulsion has emerged as a prime example of this alternative fuel technology. The paper will discuss some aspects of the burner technology related to the application of these various coal based fuels, fuel systems and alternative fuels in the power generation industry.

Allen, J.W.; Beal, P.R.

1998-07-01T23:59:59.000Z

357

Coal based fuels, fuel systems and alternative fuels  

SciTech Connect (OSTI)

The introduction of coal based fuel systems such as coal/air and coal water mixtures was an attempt to minimise the use of heavy fuel oils in large scale power generation processes. This need was based on forecasts of fuel reserves and future pricing of fuel oils, therefore economic considerations predominated over environmental benefits, if any, which could result from widespread use of these fuels. Coal continued as the major fuel used in the power generation industry and combustion systems were developed to minimise gaseous emissions, such as NO{sub x}. Increasing availability of natural gas led to consideration of its use in combination with coal in fuel systems involving combined cycle or topping cycle operations. Dual fuel coal natural gas operations also offered the possibility of improved performance in comparison to 100% coal based fuel systems. Economic considerations have more recently looked at emulsification of heavy residual liquid fuels for consumption in power generation boiler and Orimulsion has emerged as a prime example of this alternative fuel technology. The next sections of the paper will discuss some aspects of the burner technology related to the application of these various coal based fuels, fuel systems and alternative fuels in the power generation industry.

Allen, J.W.; Beal, P.R. [ABB Combustion Services Limited, Derby (United Kingdom)

1998-04-01T23:59:59.000Z

358

Experimental Results for SimFuels  

SciTech Connect (OSTI)

Assessing the performance of Spent (or Used) Nuclear Fuel (UNF) in geological repository requires quantification of time-dependent phenomena that may influence its behavior on a time-scale up to millions of years. A high-level waste repository environment will be a dynamic redox system because of the time-dependent generation of radiolytic oxidants and reductants and the corrosion of Fe-bearing canister materials. One major difference between used fuel and natural analogues, including unirradiated UO2, is the intense radiolytic field. The radiation emitted by used fuel can produce radiolysis products in the presence of water vapor or a thin-film of water that may increase the waste form degradation rate and change radionuclide behavior. To study UNF, we have been working on producing synthetic UO2 ceramics, or SimFuels that can be used in testing and which will contain specific radionuclides or non-radioactive analogs so that we can test the impact of radiolysis on fuel corrosion without using actual spent fuel. Although, testing actual UNF would be ideal for understanding the long term behavior of UNF, it requires the use of hot cells and is extremely expensive. In this report, we discuss, factors influencing the preparation of SimFuels and the requirements for dopants to mimic the behavior of UNF. We have developed a reliable procedure for producing large grain UO2 at moderate temperatures. This process will be applied to a series of different formulations.

Buck, Edgar C.; Casella, Andrew M.; Skomurski, Frances N.; MacFarlan, Paul J.; Soderquist, Chuck Z.; Wittman, Richard S.; Mcnamara, Bruce K.

2012-08-22T23:59:59.000Z

359

Ultrafast thermally induced magnetic switching in synthetic ferrimagnets  

SciTech Connect (OSTI)

Synthetic ferrimagnets are composite magnetic structures formed from two or more anti-ferromagnetically coupled magnetic sublattices with different magnetic moments. Here, we report on atomistic spin simulations of the laser-induced magnetization dynamics on such synthetic ferrimagnets and demonstrate that the application of ultrashort laser pulses leads to sub-picosecond magnetization dynamics and all-optical switching in a similar manner as in ferrimagnetic alloys. Moreover, we present the essential material properties for successful laser-induced switching, demonstrating the feasibility of using a synthetic ferrimagnet as a high density magnetic storage element without the need of a write field.

Evans, Richard F. L., E-mail: richard.evans@york.ac.uk; Ostler, Thomas A.; Chantrell, Roy W. [Department of Physics, University of York, Heslington, York YO10 5DD (United Kingdom); Radu, Ilie [Institut für Methoden und Instrumentierung der Forschung mit Synchrotronstrahlung, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Rasing, Theo [Radboud University, Institute for Molecules and Materials, Heyendaalsewg 135, 6525 AJ Nijmegen (Netherlands)

2014-02-24T23:59:59.000Z

360

Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery  

SciTech Connect (OSTI)

HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

None

2011-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Reimagining liquid transportation fuels : sunshine to petrol.  

SciTech Connect (OSTI)

Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO{sub 2} + (x+1)H{sub 2}O {yields} C{sub x}H{sub 2x+2}(liquid fuel) + (1.5x+.5)O{sub 2} Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO{sub 2} and H{sub 2}O to CO and H{sub 2}, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO{sub 2} to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

Johnson, Terry Alan (Sandia National Laboratories, Livermore, CA); Hogan, Roy E., Jr.; McDaniel, Anthony H. (Sandia National Laboratories, Livermore, CA); Siegel, Nathan Phillip; Dedrick, Daniel E. (Sandia National Laboratories, Livermore, CA); Stechel, Ellen Beth; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Coker, Eric Nicholas; Staiger, Chad Lynn; Chen, Ken Shuang; Ermanoski, Ivan; Kellog, Gary L.

2012-01-01T23:59:59.000Z

362

Synthetic Nano-Low Density Lipoprotein as Targeted Drug Delivery Vehicle for Glioblastoma Multiforme  

E-Print Network [OSTI]

Synthetic Nano-Low Density Lipoprotein as Targeted Drugmicroemulsion; peptide; nano-low density lipoproteintherapeutic agents. A synthetic nano-LDL (nLDL) particle was

Nikanjam, Mina; Blakely, Eleanor A.; Bjornstad, Kathleen A.; Shu, Xiao; Budinger, Thomas F.; Forte, Trudy M.

2006-01-01T23:59:59.000Z

363

ADVANCED COMPUTATIONAL MODEL FOR THREE-PHASE SLURRY REACTORS  

SciTech Connect (OSTI)

In the second year of the project, the Eulerian-Lagrangian formulation for analyzing three-phase slurry flows in a bubble column is further developed. The approach uses an Eulerian analysis of liquid flows in the bubble column, and makes use of the Lagrangian trajectory analysis for the bubbles and particle motions. An experimental set for studying a two-dimensional bubble column is also developed. The operation of the bubble column is being tested and diagnostic methodology for quantitative measurements is being developed. An Eulerian computational model for the flow condition in the two-dimensional bubble column is also being developed. The liquid and bubble motions are being analyzed and the results are being compared with the experimental setup. Solid-fluid mixture flows in ducts and passages at different angle of orientations were analyzed. The model predictions were compared with the experimental data and good agreement was found. Gravity chute flows of solid-liquid mixtures is also being studied. Further progress was also made in developing a thermodynamically consistent model for multiphase slurry flows with and without chemical reaction in a state of turbulent motion. The balance laws are obtained and the constitutive laws are being developed. Progress was also made in measuring concentration and velocity of particles of different sizes near a wall in a duct flow. The technique of Phase-Doppler anemometry was used in these studies. The general objective of this project is to provide the needed fundamental understanding of three-phase slurry reactors in Fischer-Tropsch (F-T) liquid fuel synthesis. The other main goal is to develop a computational capability for predicting the transport and processing of three-phase coal slurries. The specific objectives are: (1) To develop a thermodynamically consistent rate-dependent anisotropic model for multiphase slurry flows with and without chemical reaction for application to coal liquefaction. Also establish the material parameters of the model. (2) To provide experimental data for phasic fluctuation and mean velocities, as well as the solid volume fraction in the shear flow devices. (3) To develop an accurate computational capability incorporating the new rate-dependent and anisotropic model for analyzing reacting and nonreacting slurry flows, and to solve a number of technologically important problems related to Fischer-Tropsch (F-T) liquid fuel production processes. (4) To verify the validity of the developed model by comparing the predicted results with the performed and the available experimental data under idealized conditions.

Goodarz Ahmadi

2001-10-01T23:59:59.000Z

364

ADVANCED COMPUTATIONAL MODEL FOR THREE-PHASE SLURRY REACTORS  

SciTech Connect (OSTI)

In the first year of the project, solid-fluid mixture flows in ducts and passages at different angle of orientations were analyzed. The model predictions are compared with the experimental data and good agreement was found. Progress was also made in analyzing the gravity chute flows of solid-liquid mixtures. An Eulerian-Lagrangian formulation for analyzing three-phase slurry flows in a bubble column is being developed. The approach uses an Eulerian analysis of gas liquid flows in the bubble column, and makes use of the Lagrangian particle tracking procedure to analyze the particle motions. Progress was also made in developing a rate dependent thermodynamically consistent model for multiphase slurry flows in a state of turbulent motion. The new model includes the effect of phasic interactions and leads to anisotropic effective phasic stress tensors. Progress was also made in measuring concentration and velocity of particles of different sizes near a wall in a duct flow. The formulation of a thermodynamically consistent model for chemically active multiphase solid-fluid flows in a turbulent state of motion was also initiated. The general objective of this project is to provide the needed fundamental understanding of three-phase slurry reactors in Fischer-Tropsch (F-T) liquid fuel synthesis. The other main goal is to develop a computational capability for predicting the transport and processing of three-phase coal slurries. The specific objectives are: (1) To develop a thermodynamically consistent rate-dependent anisotropic model for multiphase slurry flows with and without chemical reaction for application to coal liquefaction. Also to establish the material parameters of the model. (2) To provide experimental data for phasic fluctuation and mean velocities, as well as the solid volume fraction in the shear flow devices. (3) To develop an accurate computational capability incorporating the new rate-dependent and anisotropic model for analyzing reacting and nonreacting slurry flows, and to solve a number of technologically important problems related to Fischer-Tropsch (F-T) liquid fuel production processes. (4) To verify the validity of the developed model by comparing the predicted results with the performed and the available experimental data under idealized conditions.

Goodarz Ahmadi

2000-11-01T23:59:59.000Z

365

NUCLEAR POWERED CO2 CAPTURE FROM THE ATMOSPHERE  

SciTech Connect (OSTI)

A process for capturing CO{sub 2} from the atmosphere was recently proposed. This process uses a closed cycle of sodium and calcium hydroxide, carbonate, and oxide transformations to capture dilute CO{sub 2} from the atmosphere and to generate a concentrated stream of CO{sub 2} that is amenable to sequestration or subsequent chemical transformations. In one of the process steps, a fossil-fueled lime kiln is needed, which reduces the net CO{sub 2} capture of the process. It is proposed to replace the fossil-fueled lime kiln with a modified kiln heated by a high-temperature nuclear reactor. This will have the effect of eliminating the use of fossil fuels for the process and increasing the net CO{sub 2} capture. Although the process is suitable to support sequestration, the use of a nuclear power source for the process provides additional capabilities, and the captured CO{sub 2} may be combined with nuclear-produced hydrogen to produce liquid fuels via Fischer-Tropsch synthesis or other technologies. Conceivably, such plants would be carbon-neutral, and could be placed virtually anywhere without being tied to fossil fuel sources or geological sequestration sites.

Sherman, S

2008-09-22T23:59:59.000Z

366

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

of first and second generation biofuels: A comprehensiveP.M. , et al. , Second Generation Biofuels: High-Efficiencybiodiesel. The second–generation biofuels comprise of

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

367

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

Li, Y. , et al. , Biofuels from Microalgae. Biotechnol Prog,L. and P. Owende, Biofuels from microalgae—A review ofproduction of biofuels from microalgae. Int J Mol Sci, 2008.

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

368

Metabolic engineering of microorganisms for biofuels production: from bugs to synthetic biology to fuels  

E-Print Network [OSTI]

of microbial hosts for biofuels production. Metab Eng 2008,delivers next-generation biofuels. Nat Biotechnol 27.furfural (HMF). Biotechnol Biofuels 2008, 1:12. 40. Trinh

Kuk Lee, Sung

2010-01-01T23:59:59.000Z

369

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

et al. , Microalgae as a sustainable energy source forto maximize energy production from microalgae and leads toand dried microalgae and oil extraction requires energy. The

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

370

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

due to insufficient biomass feedstocks, land limitations,compared to other biomass feedstocks to produce biofuel,

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

371

The German plan for synthetic fuel self-sufficiency, 1933-1942  

E-Print Network [OSTI]

's hydrogenation develop- ment were not to gain surcease from their problems. On 31 May 1931 the first major blow of the oncoming economic crisis had hit Europe as the Kredit Anstalt, one of Germany's largest banks, failed. The Darmstadter National Bank... (Christ1an-National, Soc', alist, or Demo- cratic) and status (manual workers or salaried employees). Superimposed on th1s organizational edifice were the market-regu- lat1ng agents -- the combinations. Combinations of German business took several...

Tooley, Terry Hunt

1978-01-01T23:59:59.000Z

372

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

A comprehensive review. Renewable and Sustainable Energyapplications: A review. Renewable and Sustainable Energyof liquid biofuels from renewable resources. Progress in

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

373

THE POTENTIAL OF THE SOLID OXIDE ELECTROLYSER FOR THE PRODUCTION OF SYNTHETIC FUELS  

E-Print Network [OSTI]

the 1980'es. The discussions focussed on the use of heat from solar concentrators or waste heat from power to a potential of high electricity efficiency (60%) as compared to ordinary gas turbine power plants (30%- 40

374

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

Y. , Biodiesel from microalgae beats bioethanol. Trendsand N.S. Caetano, Microalgae for biodiesel production and6. Ahmad, A.L. , et al. , Microalgae as a sustainable energy

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

375

Feasibility of Steam Hydrogasification of Microalgae for Production of Synthetic Fuels  

E-Print Network [OSTI]

liqnocellulosic ethanol, hydrotreating oil [4-6]. First andoil can upgrade with hydrotreating or hydrocracking process

Suemanotham, Amornrat

2014-01-01T23:59:59.000Z

376

Synthetic Biology for Advanced Fuels (Opening Keynote Address - 2010 JGI User Meeting)  

ScienceCinema (OSTI)

Jay Keasling, CEO of the Joint BioEnergy Institute, delivers the opening keynote on March 24, 2010 at the 5th Annual DOE JGI User Meeting

Keasling, Jay

2011-04-28T23:59:59.000Z

377

DIESEL FUEL TANK FOUNDATIONS  

SciTech Connect (OSTI)

The purpose of this analysis is to design structural foundations for the Diesel Fuel Tank and Fuel Pumps.

M. Gomez

1995-01-18T23:59:59.000Z

378

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-EfficientAlternative Fuel

379

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel Vehicle (AFV)Fuel

380

Alternative Fuel Vehicle  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle & Fueling Infrastructure

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle & FuelingDo alternative

382

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle & FuelingDo

383

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle & FuelingDoAnnual Electric

384

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle & FuelingDoAnnual

385

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNationPlug-InFuel Dealer1,Alternative Fuel Vehicle

386

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNationPlug-InFuel Dealer1,Alternative Fuel

387

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew York VehicleAlternative Fuels TaxAlternative Fueling

388

What is Synthetic Biology? Application of engineering principles  

E-Print Network [OSTI]

to the design and construction of biological parts, devices, and systems with applications in energy, medicine;Biofuels from Algae CO -neutral2 1,000,000 gallons in 2008 18 #12;Synthetic Biology Biochemistry

Campbell, A. Malcolm

389

Synthetic polypeptide-based hydrogel systems for biomaterials  

E-Print Network [OSTI]

Hydrogels formed from synthetic polypeptides generated by ring opening polymerization (ROP) of a-amino acid N-carboxyanhydrides (NCAs) present a robust material for modeling the interaction between extracellular matrix ...

Martin, Mackenzie Marie

2014-01-01T23:59:59.000Z

390

applied synthetic auxin: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

within bacteria in order to fine-tune the expression of BioBrick parts and devices. Fortuna, Patrick 2010-12-04 112 Synthesizing Law for Synthetic Biology University of Kansas -...

391

Synthetic scaffolds and protein assemblies for engineering applications  

E-Print Network [OSTI]

S-layer proteins, which naturally self-assemble on the exterior of cells, provide an interesting basis for the creation of synthetic scaffolds. In this thesis, I created a plasmid which produces a recombinant form of a ...

Norville, Julie Erin, 1980-

2004-01-01T23:59:59.000Z

392

Retroactivity, modularity, and insulation in synthetic biology circuits  

E-Print Network [OSTI]

A central concept in synthetic biology is the reuse of well-characterized modules. Modularity simplifies circuit design by allowing for the decomposition of systems into separate modules for individual construction. Complex ...

Lin, Allen

2011-01-01T23:59:59.000Z

393

What rough beast? Synthetic Biology and the Future of Biosecurity  

E-Print Network [OSTI]

Synthetic biology seeks to create modular biological parts that can be assembled into useful devices, allowing the modification of biological systems with greater reliability, at lower cost, with greater speed, and by a ...

Mohr, Scott C.

394

Synthetic strategies for the design of platinum anticancer drug candidates  

E-Print Network [OSTI]

Chapter 1. The Synthetic Chemistry of Platinum Anticancer Agents Since the inception of cisplatin as a clinically approved anticancer agent, a large number of platinum compounds have been synthesized with the aim of finding ...

Wilson, Justin Jeff

2013-01-01T23:59:59.000Z

395

Synthetic environment employing a craft for providing user perspective reference  

DOE Patents [OSTI]

A multi-dimensional user oriented synthetic environment system allows application programs to be programmed and accessed with input/output device independent, generic functional commands which are a distillation of the actual functions performed by any application program. A shared memory structure allows the translation of device specific commands to device independent, generic functional commands. Complete flexibility of the mapping of synthetic environment data to the user is thereby allowed. Accordingly, synthetic environment data may be provided to the user on parallel user information processing channels allowing the subcognitive mind to act as a filter, eliminating irrelevant information and allowing the processing of increase amounts of data by the user. The user is further provided with a craft surrounding the user within the synthetic environment, which craft, imparts important visual referential an motion parallax cues, enabling the user to better appreciate distances and directions within the synthetic environment. Display of this craft in close proximity to the user's point of perspective may be accomplished without substantially degrading the image resolution of the displayed portions of the synthetic environment.

Maples, Creve (Albuquerque, NM); Peterson, Craig A. (Albuquerque, NM)

1997-10-21T23:59:59.000Z

396

Comprehensive chemical kinetic modeling of the oxidation of C8 and larger n-alkanes and 2-methylalkanes  

SciTech Connect (OSTI)

Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed and reduced chemical kinetic mechanism for singly methylated iso-alkanes (i.e., 2-methylalkanes) ranging from C{sub 8} to C{sub 20}. The mechanism also includes an updated version of our previously published C{sub 8} to C{sub 16} n-alkanes model. The complete detailed mechanism contains approximately 7,200 species 31,400 reactions. The proposed model is validated against new experimental data from a variety of fundamental combustion devices including premixed and nonpremixed flames, perfectly stirred reactors and shock tubes. This new model is used to show how the presence of a methyl branch affects important combustion properties such as laminar flame propagation, ignition, and species formation.

Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M; Togbe, C; Dagaut, P; Wang, H; Oehlschlaeger, M; NIemann, U; Seshadri, K; Veloo, P S; Ji, C; Egolfopoulos, F; Lu, T

2011-03-16T23:59:59.000Z

397

Catalysts allow CO and CO/sub 2/ comethanation  

SciTech Connect (OSTI)

Kyoto University researchers have developed a series of composite catalysts that permit simultaneous methanation of carbon monoxide and carbon dioxide in mixtures with hydrogen at temperatures as low as 270/sup 0/C. The procedure may provide considerable simplifications for Fischer-Tropsch synthesis; offer a long-sought route for the direct use of carbon dioxide as a recyclable material in industrial processes; and replace some synthetic procedures based on carbon monoxide which are hindered by the presence of carbon dioxide. The best comethanation catalysts are small amounts of lanthanide oxides on iron group substrates with platinum group metals as promoters, e.g., 5% Ni, 2.7% La/sub 2/O/sub 3/, and 0.6% Ru supported on 3 mm dia spherical silica pellets which have pores having a bimodal size distribution between 5 and 600 nm. Test reactions at 160/sup 0/-400/sup 0/C showed considerable variation with temperature and a very complex adsorption sequence. Carbon dioxide apparently enhances carbon monoxide methanation at higher temperatures. The mechanism is not understood but does not involve a water/carbon monoxide shift effect.

Not Available

1980-10-13T23:59:59.000Z

398

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Broader source: Energy.gov (indexed) [DOE]

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November...

399

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Presentation covers stationary fuel cells...

400

Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of EnergyAdministrative2 DOE Hydrogen andEnzymeAdvancedDepartment

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

California Fuel Cell Partnership: Alternative Fuels Research  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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402

Alternative Fuels Data Center: Ethanol Fueling Stations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAreSmartWayElectricity Fuel Basics to someone byEthanolFueling

403

Alternative Fuels Data Center: Hydrogen Fueling Stations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAreSmartWayElectricity Fuel Basics toWithHybridHydrogenFueling

404

Alternative Fuels Data Center: Propane Fueling Stations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mail Share Alternative Fuels Data Center:Basics toFueling

405

LMFBR fuel component costs  

SciTech Connect (OSTI)

A significant portion of the cost of fabricating LMFBR fuels is in the non-fuel components such as fuel pin cladding, fuel assembly ducts and end fittings. The contribution of these to fuel fabrication costs, based on FFTF experience and extrapolated to large LMFBR fuel loadings, is discussed. The extrapolation considers the expected effects of LMFBR development programs in progress on non-fuel component costs.

Epperson, E.M.; Borisch, R.R.; Rice, L.H.

1981-10-29T23:59:59.000Z

406

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuel Inefficient Vehicle

407

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuel Inefficient

408

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuel

409

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuelConnecticut joined

410

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuelConnecticut

411

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailer LicenseVehicleFuelConnecticutNew

412

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNew YorkLouisianaRetailerVoluntaryElectricNatural Gas Fueling

413

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirement All AFVs,HybridAlternative Fuel

414

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirement AllFleet UserAlternative Fuel

415

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-Efficient Vehicle Tax

416

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-Efficient Vehicle

417

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-Efficient VehicleProvision

418

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-Efficient

419

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test Requirementand Fuel-EfficientAlternative

420

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions Test RequirementandAnnualEthanolAlternative Fuel

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel Use The Missouri

422

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel Use The

423

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel Use

424

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel UseTax

425

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel UseTaxand

426

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel Fuel

427

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel FuelTax Rates

428

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel FuelTax

429

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestState Fleet Biodiesel FuelTaxLicense

430

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestStateBiofuels Tax Deduction AAlternative Fuel

431

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissions TestStateBiofuelsProduction TaxAlternative Fuel

432

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel Vehicle (AFV) and

433

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel Vehicle (AFV)

434

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel Vehicle

435

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel VehicleImmunity for

436

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel VehicleImmunity

437

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel VehicleImmunityRetail

438

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative Fuel

439

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative FuelDefinition Biodiesel is

440

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative FuelDefinition Biodiesel

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative FuelDefinition

442

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropane BoardAlternative FuelDefinitionRenewable

443

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropaneState EnergyIdle ReductionFuel Exclusivity

444

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropaneState EnergyIdle ReductionFuel

445

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeNewEmissionsPropaneStateLow-Speedand Methanol Tax EthylFuel

446

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program The Hawaii Department ofAlternative Fuel

447

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program The HawaiiDistributionHydrogen and Fuel Cell

448

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program The HawaiiDistributionHydrogen and Fuel

449

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program The HawaiiDistributionHydrogen and FuelClean

450

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program TheProduction TaxAlternative Fuel and

451

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program TheProduction TaxAlternative Fuel

452

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock Program TheProduction TaxAlternative FuelBiodiesel

453

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock ProgramPublic AccessStateRenewable Fuels Mandate One

454

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock ProgramPublic AccessStateRenewable Fuels Mandate

455

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock ProgramPublic AccessStateRenewable Fuels

456

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock ProgramPublic AccessStateRenewable FuelsAlternative

457

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy Feedstock ProgramPublicSchool BusInfrastructureBiofuelandFuel

458

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy FeedstockAuthorization forCompressed NaturalAlternative Fuel

459

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergy FeedstockAuthorizationExcisePlug-InSchoolBiodieselIdleFuel

460

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergyAuthorization for Plug-InHeavy-DutyAftermarketAlternative Fuel

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &

462

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &Plug-in Electric Vehicle

463

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &Plug-in Electric

464

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &Plug-in

465

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &Plug-inIncentives

466

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle &Plug-inIncentivesElectric

467

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel Vehicle

468

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas and Propane Tax

469

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas and Propane

470

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas and

471

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas andZero

472

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas

473

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas(AFV) and

474

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas(AFV)

475

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onAlternative Fuel VehicleNatural Gas(AFV)Loans

476

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNation November 1, 2000 hisAlternative Fuel and

477

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNation November 1, 2000 hisAlternative Fuel

478

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNation November 1, 2000Low Carbon Fuels Standard

479

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNation November 1, 2000Low Carbon Fuels

480

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageEmergingNation November 1, 2000Low Carbon FuelsLow

Note: This page contains sample records for the topic "fischer-tropsch synthetic fuel" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


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