National Library of Energy BETA

Sample records for firm secondary nominations

  1. Fellows' Nominations and Selections

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nominations and Selections Fellows' Nominations and Selections The Fellow appointment is an honor bestowed by the Director in recognition of unusual achievement by research and development (R&D) scientists and engineers. Fellows' nomination and selection process Definition The Fellow appointment is an honor bestowed by the Director in recognition of unusual achievement by research and development (R&D) scientists and engineers. It can be awarded to full-time R&D scientists, R&D

  2. Fellows' Prize Nominations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nominations Fellows' Prize Nominations Prize details and nomination procedures. Fellows' Prize for Outstanding Research in Science or Engineering and in Leadership Purpose of the Fellows Research Prize is: To commend individuals for outstanding unclassified or classified research performed at the Laboratory that was published or patented within the last 10 years and that has had a significant impact on its discipline and/or Laboratory mission. To recognize and stimulate high-quality

  3. SSRLUO EC Ballot Nominations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    28th Annual Stanford Synchrotron Radiation Laboratory Users' Meeting Menlo Park, California USA October 18-19, 2001 SSRLUO Executive Committee Ballot -- Nominations Due September...

  4. LANSCE | Users | Rosen Scholar | Call for Nominations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scholar - Call for Nominations Nomination and Selection Process Nominations for Rosen Scholar candidates are to be sponsored by at least one of LANSCE's Facilities: IPF (Isotope Production Facility), UCN (Ultra-Cold Neutron), pRad (Proton Radiography), Lujan Center, and WNR (Nuclear Science). The nomination package should include a two page research statement, a one page support letter from one of the sponsoring facilities and a recent CV. Call for Nominations 2016 - Closed Nominations were due

  5. Microsoft Word - fellows_nomination_reworked.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for each individual nomination Candidate Last Name: First Name: Middle Initial: Z Number: Organization: Phone: Mail Stop: Email Address: Nominator Last Name: First Name:...

  6. 2016 DOE Sustainability Awards Nominations Deadline!

    Broader source: Energy.gov [DOE]

    All nominations must be submitted through the DOE Sustainability Awards Database by January 22nd.  For more information, click here.

  7. Nominations Open for 2013 NERSC HPC Achievement Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nominations Open for 2013 NERSC HPC Achievement Awards January 1, 2013 by Richard Gerber Nominations are open for the 2013 NERSC Award for Innovative Use of High Performance...

  8. Federal Agency Energy Coordinators for Award Nominations | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Awards » Federal Agency Energy Coordinators for Award Nominations Federal Agency Energy Coordinators for Award Nominations Contact your agency coordinator in advance to discuss your Federal Energy and Water Management Award nomination. Agency coordinators are responsible for vetting nomination information and submitting approved nominations to the Federal Energy Management Program on behalf of the agencies. Each agency listed below is limited to 15 Federal Energy and Water Management

  9. Call for Nominations for 2016 NERSC Scientific Achievement Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Call for Nominations (2016) Call for Nominations for 2016 NERSC Scientific Achievement Awards Nominations are open for the 2016 NERSC Award for Innovative Use of High Performance Computing and the 2016 NERSC Award for High Impact Scientific Achievement. NERSC Principal Investigators, Project Managers, PI Proxies, and DOE Program Managers may nominate any NERSC user or collaboratory group. The deadline for nominations is Friday, March 4, 2016. Winners will be announced at the NERSC Users Group

  10. Alaska Rural Manager Panelists Call for Nominations

    Broader source: Energy.gov [DOE]

    The Alaska Rural Managers are seeking nominations for city, tribal, and utility managers to participate in several Anchorage focus group/workshops this April. Selected panelists will represent their profession and will help develop guidelines for the training and education of Alaska's Rural Managers.

  11. Aviation Management Professional Award Nomination for:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aviation Professional Nomination for Managerial/Official Award: Joseph M. Ginanni Aviation Manager US Department of Energy/National Nuclear Security Administration, Nevada Site Office Bio Joseph M. Ginanni Aviation Manager National Nuclear Security Administration Nevada Site Office Mr. Ginanni has worked for the Nevada Site Office (NSO) since 1991. For the past five years, he has served as the NSO Aviation Manager, managing and overseeing the Management and Operating contractor's aviation

  12. LANSCE | Users | Rosen Prize | Call for Nominations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rosen Prize | Call for Nominations | CLOSED Rosen Prize: Call for Submissions is now closed. The Los Alamos Neutron Science Center (LANSCE) is pleased to announce the call for submissions for the 24th Louis Rosen Prize. The Prize, consisting of $1000 and a plaque, is awarded for the most outstanding Ph.D. thesis based on experimental or theoretical research performed at LANSCE. Theses based on work in any area of science or technology at the Lujan Neutron Scattering Center, Weapons Neutron

  13. Nominal Performance Biosphere Dose Conversion Factor Analysis

    SciTech Connect (OSTI)

    Wasiolek, Maryla A.

    2000-12-21

    The purpose of this report was to document the process leading to development of the Biosphere Dose Conversion Factors (BDCFs) for the postclosure nominal performance of the potential repository at Yucca Mountain. BDCF calculations concerned twenty-four radionuclides. This selection included sixteen radionuclides that may be significant nominal performance dose contributors during the compliance period of up to 10,000 years, five additional radionuclides of importance for up to 1 million years postclosure, and three relatively short-lived radionuclides important for the human intrusion scenario. Consideration of radionuclide buildup in soil caused by previous irrigation with contaminated groundwater was taken into account in the BDCF development. The effect of climate evolution, from the current arid conditions to a wetter and cooler climate, on the BDCF values was evaluated. The analysis included consideration of different exposure pathway's contribution to the BDCFs. Calculations of nominal performance BDCFs used the GENII-S computer code in a series of probabilistic realizations to propagate the uncertainties of input parameters into the output. BDCFs for the nominal performance, when combined with the concentrations of radionuclides in groundwater allow calculation of potential radiation doses to the receptor of interest. Calculated estimates of radionuclide concentration in groundwater result from the saturated zone modeling. The integration of the biosphere modeling results (BDCFs) with the outcomes of the other component models is accomplished in the Total System Performance Assessment (TSPA) to calculate doses to the receptor of interest from radionuclides postulated to be released to the environment from the potential repository at Yucca Mountain.

  14. DOE Encourages Utility Sector Nominations to the Federal Communication...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commission's Communications, Security, Reliability, and Interoperability Council DOE Encourages Utility Sector Nominations to the Federal Communications Commission's...

  15. Nominations Open for 2013 NERSC HPC Achievement Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nominations Open for 2013 NERSC HPC Achievement Awards Nominations Open for 2013 NERSC HPC Achievement Awards January 1, 2013 by Richard Gerber Nominations are open for the 2013 NERSC Award for Innovative Use of High Performance Computing and the 2013 NERSC Award for High Impact Scientific Achievement. These are the first of what are planned to be annual awards. Current NERSC Principal Investigators, Project Managers, and PI Proxies may nominate any NERSC user or collaboratory group. The

  16. Federal Energy and Water Management Awards: Nomination Quick Reference

    Broader source: Energy.gov [DOE]

    Document offers a checklist of items needed to complete a nomination for the Federal Energy and Water Management Awards.

  17. Aviation Management Professional Award Nomination for: | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Aviation Management Professional Award Nomination for: Aviation Management Professional Award Nomination for: Aviation Management Professional Award Nomination for: (43.97 KB) More Documents & Publications FAQS Reference Guide - Aviation Manager FAQS Reference Guide - Aviation Safety Officer Type B Accident Investigation Board Report of the April 23, 1997, Helicopter Accident at Raton Pass, Raton Pass, Colorado

  18. DOE Under Secretary Nomination Announcement | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Under Secretary Nomination Announcement DOE Under Secretary Nomination Announcement March 12, 2009 - 12:00am Addthis WASHINGTON, DC - Today, President Barack Obama announced his intent to nominate the following individuals to key administration posts: Demetrios Marantis, Nominee for Deputy United States Trade Representative; Kristina M. Johnson, Nominee for Under Secretary of Energy; Gina McCarthy, Nominee for Assistant Administrator for Air and Radiation, Environmental Protection Agency; and

  19. SUSTAINABILITY NEWS EPA's 2013 Federal Electronics Challenge Accepting Nominations

    Energy Savers [EERE]

    EPA's 2013 Federal Electronics Challenge Accepting Nominations Nominations are currently being accepted for the Environmental Protection Agency's 2013 Federal Electronics Challenge (FEC). The FEC recognizes teams and individuals from across the Federal government who demonstrate a commitment to electronic stewardship through sustainable purchasing, management, and disposal of electronic assets. Last year, DOE won one-third of all FEC awards. The deadline for nominations is January 31, 2013. For

  20. Assets in Action Community Award nominations open until December 17

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assets in Action Community Award Nominations Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit Assets in Action Community Award nominations open until December 17 If you know people who support building a strong community for youth in Los Alamos, nominate them for an Assets in Action Community Award. January 1, 2013 dummy image Read our archives. Contacts Editor Linda Anderman Email

  1. DOE General Counsel Nomination Announcement | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    General Counsel Nomination Announcement DOE General Counsel Nomination Announcement March 18, 2009 - 12:00am Addthis WASHINGTON, DC - Today, President Barack Obama announced his intent to nominate the following individuals to key administration posts: Susan Burk, Special Representative of the President, with the rank of Ambassador, State Department; Raphael Bostic, Assistant Secretary for Policy Development and Research, Department of Housing and Urban Development; Michelle J. DePass, Assistant

  2. DOE Encourages Utility Sector Nominations to Commerce Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commerce Department's Spectrum Advisory Committee DOE Encourages Utility Sector Nominations to Commerce Department's Spectrum Advisory Committee December 14, 2010 - 5:40pm Addthis...

  3. Statement from Energy Secretary Samuel W. Bodman on the Nomination...

    Broader source: Energy.gov (indexed) [DOE]

    President announced his intention to nominate Thomas P. D'Agostino as Under Secretary for Nuclear Security and Administrator of the National Nuclear Security Administration (NNSA). ...

  4. Federal Energy and Water Management Awards: Nomination Quick...

    Broader source: Energy.gov (indexed) [DOE]

    Energy and Water Management Awards. PDF icon Download the 2016 Nomination Quick Reference fact sheet. More Documents & Publications Federal Energy and Water Management ...

  5. NREL's Grid Integration Lab Nominated for Prestigious Project...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Systems Integration Facility (ESIF) at the Energy Department's National Renewable Energy Laboratory (NREL) received a nomination as one of three international finalists for ...

  6. Last Call for 2016 DOE Sustainability Awards Nominations

    Broader source: Energy.gov [DOE]

    The nominations period for the 2016 DOE Sustainability Awards is coming to a close on January 22. 2016 DOE Sustainability Award Nominations may include DOE co-workers, teams, and sites that have demonstrated outstanding achievements in advancing the Departments sustainability mission, including excellence in energy, water, and vehicle fleet management.

  7. Nominations open for $250,000 Multimedia Clean Energy prizes...

    Open Energy Info (EERE)

    Nominations open for 250,000 Multimedia Clean Energy prizes Home > Groups > Utility Rate Graham7781's picture Submitted by Graham7781(2017) Super contributor 2 October, 2012 -...

  8. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...

    Open Energy Info (EERE)

    Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  9. Carlsbad Field Office Nominated for Employer Support Freedom Award

    Broader source: Energy.gov [DOE]

    EM’s Carlsbad Field Office (CBFO) was honored at a recognition event in Santa Fe this month for being nominated for the 2014 Secretary of Defense Employer Support Freedom Award.

  10. NREL's Grid Integration Lab Nominated for Prestigious Project Management

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Award | Department of Energy Grid Integration Lab Nominated for Prestigious Project Management Award NREL's Grid Integration Lab Nominated for Prestigious Project Management Award November 3, 2014 - 11:48am Addthis The new Energy Systems Integration Facility (ESIF) at the Energy Department’s National Renewable Energy Laboratory (NREL) is the nation's premier lab for testing how clean energy technologies interact on the grid at megawatt utility scale. The new Energy Systems Integration

  11. SUSTAINABILITY ANNOUNCEMENTS 2014 DOE Sustainability Awards Now Accepting Nominations

    Energy Savers [EERE]

    2014 DOE Sustainability Awards Now Accepting Nominations The Sustainability Performance Office (SPO) sponsors the DOE Sustainability Awards to recognize outstanding achievements of teams and individuals at DOE facilities across the country. The DOE Sustainability Awards celebrate programs, projects, and people that advance the Department's sustainability mission, including excellence in energy, water, and vehicle fleet management. The process for submitting nominations for the 2014 Awards is

  12. Maintenance & Cleaning Firm Earns Jefferson Lab's Small Business...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Maintenance & Cleaning Firm Earns Jefferson Lab's Small Business Award for 2013 Maintenance & Cleaning Firm Earns Jefferson Lab's Small Business Award for 2013 Prestige award ...

  13. 4-28-09_Final_Testimony_(Triay)_(Nomination).pdf

    Office of Environmental Management (EM)

    8, 2009 Good morning, Mr. Chairman, Senator McCain, members of the Committee. It is a great honor to appear before you today as President Obama's nominee to be the Assistant Secretary for Environmental Management at the United States Department of Energy. I thank Secretary Chu and President Obama for their support and confidence in recommending and nominating me. I also thank the Committee for considering my nomination. I would like to introduce my husband of 24 years, Dr. John Hall, and his

  14. Call for nominations for NERSC HPC Achievement Awards Due December 16

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nominations for NERSC HPC Achievement Awards Call for nominations for NERSC HPC Achievement Awards Due December 16 November 18, 2013 by Francesca Verdier Nominations are open for the 2014 NERSC Award for Innovative Use of High Performance Computing and the 2014 NERSC Award for High Impact Scientific Achievement. NERSC Principal Investigators, Project Managers, PI Proxies, and DOE Program Managers may nominate any NERSC user or collaboration. The deadline for nominations is Mon. Dec. 16, 2013.

  15. PROCESS STUDY OF NOMINAL 2 K REFRIGERATION RECOVERY

    SciTech Connect (OSTI)

    Knudsen, Peter; Ganni, Venkatarao

    2008-03-01

    There is an increased interest in the nominal 2-K helium refrigeration systems (below lambda) for various test stands and applications at the present time. This paper presents the process parameter choices and their influence on the system performance of various noncold compressor configurations. This study is intended to facilitate the adoption of this process in conjunction with commercially-available small 4.5-K helium liquefaction systems. By way of an introduction, the efficiency of some commonly employed (but inefficient) 2-K process configurations are analyzed. Then the analyses of three nominal 2-K refrigeration-recovery process configurations are presented. The effect of the process parameters, such as flow imbalance, heat-exchanger size, supply pressure and 4.5-K plant interaction location(s) are investigated so that the optimum conditions yielding the required performance can be determined.

  16. Process Options for Nominal 2-K Helium Refrigeration System Designs

    SciTech Connect (OSTI)

    Peter Knudsen, Venkatarao Ganni

    2012-07-01

    Nominal 2-K helium refrigeration systems are frequently used for superconducting radio frequency and magnet string technologies used in accelerators. This paper examines the trade-offs and approximate performance of four basic types of processes used for the refrigeration of these technologies; direct vacuum pumping on a helium bath, direct vacuum pumping using full or partial refrigeration recovery, cold compression, and hybrid compression (i.e., a blend of cold and warm sub-atmospheric compression).

  17. 2015 GreenGov Presidential Awards Nomination - LANL, U.S. DOE...

    Office of Environmental Management (EM)

    GreenGov Presidential Awards Nomination - LANL, U.S. DOE, NNSA for Climate Champion Award 2015 GreenGov Presidential Awards Nomination - LANL, U.S. DOE, NNSA for Climate Champion Award ...

  18. Nomination & Selection Guidelines | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nomination & Selection Guidelines The Enrico Fermi Award Fermi Award Home Nomination & Selection Guidelines Award Laureates Ceremony The Life of Enrico Fermi Contact Information The Enrico Fermi Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us Nomination & Selection Guidelines Print Text Size: A A A FeedbackShare Page Jump to: Nomination Guidelines | Fermi Award Assessment Criteria, Merit Review,

  19. Nomination & Selection Guidelines | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nomination & Selection Guidelines The Ernest Orlando Lawrence Award Lawrence Award Home Nomination & Selection Guidelines Award Laureates Ceremony The Life of Ernest Orlando Lawrence Contact Information The Ernest Orlando Lawrence Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us Nomination & Selection Guidelines Print Text Size: A A A FeedbackShare Page Jump to: Nomination Guidelines | Lawrence

  20. Exporting licensing regulations affecting US geothermal firms

    SciTech Connect (OSTI)

    Not Available

    1988-08-01

    This document presents a brief introduction and overview of the Department of Commerce's Export Administration Regulations which might affect potential US geothermal goods exporters. It is intended to make US geothermal firms officials aware of the existence of such regulations and to provide them with references, contacts and phone numbers where they can obtain specific and detailed information and assistance. It must be stressed however, that the ultimate responsibility for complying with the above mentioned regulations lies with the exporter who must consult the complete version of the regulations.

  1. Local firms benefit from Jefferson Lab upgrade | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Local firms benefit from Jefferson Lab upgrade Local firms benefit from Jefferson Lab upgrade Michael Schwartz, Staff Writer Inside Business, February 16, 2009 Just two months into the year, the $310 million upgrade at the U.S. Department of Energy's Thomas Jefferson National Accelerator Facility is already paying off for local companies. A $14.1 million contract awarded earlier this month to S.B. Ballard made the Virginia Beach-based construction company the second local firm to reap the

  2. Analysis of Firm Transportation Contracts: Results and Methodology

    Reports and Publications (EIA)

    1996-01-01

    Summary of Federal Energy Regulatory Commission (FERC) Index of Customers Data - Firm Transportation Capacity Under Contract as of April 1, 1996.

  3. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    suppliers, without the authority Control : SF 6432-FP Title: Standard Terms and Conditions for Firm-Fixed Price Contracts Owner: Procurement Policy Department Release...

  4. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of an export license, agreement, or Control : SF 6432-FP Title: Standard Terms and Conditions for Firm-Fixed Price Contracts Owner: Procurement Policy & Quality Dept Release...

  5. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    suppliers, without the authority Control : SF 6432-FP Title: Standard Terms and Conditions for Firm-Fixed Price Contracts Owner: Procurement Policy & Quality Dept Release...

  6. ISSUANCE 2015-06-08: Solicitation of Nominations for Membership on the Appliance Standards and Rulemaking Federal Advisory Committee

    Broader source: Energy.gov [DOE]

    Solicitation of Nominations for Membership on the Appliance Standards and Rulemaking Federal Advisory Committee

  7. Nominations Now Open: Mid-Career Women in Clean Energy Awards | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Nominations Now Open: Mid-Career Women in Clean Energy Awards Nominations Now Open: Mid-Career Women in Clean Energy Awards April 15, 2014 - 3:51pm Addthis Nominations Now Open: Mid-Career Women in Clean Energy Awards Caroline McGregor Policy Analyst, Office of International Affairs Nominations are now being accepted to honor mid-career women for outstanding work in clean energy. These annual awards are run by the MIT Energy Initiative (MITEI) as part of an overarching

  8. Open Nominations Call- Energy Department Employees, Join the Women @ Energy Series

    Office of Energy Efficiency and Renewable Energy (EERE)

    We are re-opening the call for nominations of outstanding women at the Department to share their story of their STEM career and offer advice and inspiration for others to explore a future in STEM. Send in your nomination of a Department of Energy employee to annemarie.horowitz@hq.doe.gov by Friday, June 5, 2014.

  9. U.S. Department of Energy Selects Venture Capital Firms to Accelerate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Venture Capital Firms to Accelerate Adoption of Advanced Energy Technologies U.S. Department of Energy Selects Venture Capital Firms to Accelerate Adoption of Advanced Energy ...

  10. Design Data Exchange Helps AIA and Member Firms Track and Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Data Exchange Helps AIA and Member Firms Track and Improve Design Performance Design Data Exchange Helps AIA and Member Firms Track and Improve Design Performance November ...

  11. EERE Success Story-Colorado Firm Develops Innovative Materials for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Systems | Department of Energy Colorado Firm Develops Innovative Materials for Geothermal Systems EERE Success Story-Colorado Firm Develops Innovative Materials for Geothermal Systems April 18, 2013 - 12:00am Addthis With support from EERE, Composite Technology Development, Inc. advanced several technologies related to geothermal energy extraction. The company developed materials designed to create and conserve geothermal reservoirs in harsh down-hole environments to produce

  12. President-Elect Obama Nominates Dr. Steven Chu as Energy Secretary |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy President-Elect Obama Nominates Dr. Steven Chu as Energy Secretary President-Elect Obama Nominates Dr. Steven Chu as Energy Secretary December 17, 2008 - 2:30pm Addthis Photo of Steven Chu. President-elect Barack Obama has nominated Dr. Steven Chu, the current director of DOE's Lawrence Berkeley National Laboratory (LBNL), to be the next Secretary of Energy. Dr. Chu won the Nobel Prize for physics in 1997 and has run LBNL since 2004. Prior to that time, he was a

  13. 2015 GreenGov Presidential Awards Nomination - LANL, U.S. DOE, NNSA for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Climate Champion Award | Department of Energy GreenGov Presidential Awards Nomination - LANL, U.S. DOE, NNSA for Climate Champion Award 2015 GreenGov Presidential Awards Nomination - LANL, U.S. DOE, NNSA for Climate Champion Award 2015 GreenGov Presidential Awards nomination for Climate Champions Award. LLNL/DOE/NNSA Long-term Strategy for Environmental Stewardship and Sustainability (LTSESS). LTSESS case study lays out the climate realities at LANL and serves as an example of how DOE and

  14. President-Elect Obama Nominates Dr. Steven Chu as Energy Secretary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steven Chu as Energy Secretary December 17, 2008 - 2:30pm Addthis Photo of Steven Chu. President-elect Barack Obama has nominated Dr. Steven Chu, the current director of DOE's ...

  15. Title 43 CFR 3203.12 What Fees Must I Pay to Nominate Lands?...

    Open Energy Info (EERE)

    .12 What Fees Must I Pay to Nominate Lands? Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 43 CFR...

  16. Nominate An Inspirational STEM Teacher for the Nation’s Highest Honors

    Broader source: Energy.gov [DOE]

    Nominations are now open for the nation’s highest honors for K-12 mathematics and science teachers. The Presidential Awards for Excellence in Mathematics and Science Teaching, or PAEMST, have been...

  17. Secondary Emission Calorimetry

    SciTech Connect (OSTI)

    Winn, David Roberts

    2015-03-24

    This report describes R&D on a new type of calorimeter using secondary emission to measure the energy of radiation, particularly high energy particles.

  18. Secondary fuel delivery system

    DOE Patents [OSTI]

    Parker, David M.; Cai, Weidong; Garan, Daniel W.; Harris, Arthur J.

    2010-02-23

    A secondary fuel delivery system for delivering a secondary stream of fuel and/or diluent to a secondary combustion zone located in the transition piece of a combustion engine, downstream of the engine primary combustion region is disclosed. The system includes a manifold formed integral to, and surrounding a portion of, the transition piece, a manifold inlet port, and a collection of injection nozzles. A flowsleeve augments fuel/diluent flow velocity and improves the system cooling effectiveness. Passive cooling elements, including effusion cooling holes located within the transition boundary and thermal-stress-dissipating gaps that resist thermal stress accumulation, provide supplemental heat dissipation in key areas. The system delivers a secondary fuel/diluent mixture to a secondary combustion zone located along the length of the transition piece, while reducing the impact of elevated vibration levels found within the transition piece and avoiding the heat dissipation difficulties often associated with traditional vibration reduction methods.

  19. Coverage of Independent Audits of For-Profit Firms

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    COVERAGE OF INDEPENDENT AUDITS FOR OTHER TRANSACTIONS (10 CFR 603) TABLE OF CONTENTS Part 1. General Information What is the purpose of this document? Why does the Federal Government need an audit? Can the audit be integrated with the regular audit of a firm's financial statements? What are the objectives of the audit? What is the source of the requirement for the audit? What should the IPA do if he or she finds that the Defense Contract Audit Agency is performing audits of the firm? Part 2.

  20. Mathematical model of a utility firm. Executive summary

    SciTech Connect (OSTI)

    Not Available

    1983-08-21

    The project was aimed at developing an understanding of the economic and behavioral processes that take place within a utility firm, and without it. This executive summary, one of five documents, gives the project goals and objectives, outlines the subject areas of investigation, discusses the findings and results, and finally considers applications within the electric power industry and future research directions. (DLC)

  1. Real Time Pricing and the Real Live Firm

    SciTech Connect (OSTI)

    Moezzi, Mithra; Goldman, Charles; Sezgen, Osman; Bharvirkar, Ranjit; Hopper, Nicole

    2004-05-26

    Energy economists have long argued the benefits of real time pricing (RTP) of electricity. Their basis for modeling customers response to short-term fluctuations in electricity prices are based on theories of rational firm behavior, where management strives to minimize operating costs and optimize profit, and labor, capital and energy are potential substitutes in the firm's production function. How well do private firms and public sector institutions operating conditions, knowledge structures, decision-making practices, and external relationships comport with these assumptions and how might this impact price response? We discuss these issues on the basis of interviews with 29 large (over 2 MW) industrial, commercial, and institutional customers in the Niagara Mohawk Power Corporation service territory that have faced day-ahead electricity market prices since 1998. We look at stories interviewees told about why and how they respond to RTP, why some customers report that they can't, and why even if they can, they don't. Some firms respond as theorized, and we describe their load curtailment strategies. About half of our interviewees reported that they were unable to either shift or forego electricity consumption even when prices are high ($0.50/kWh). Reasons customers gave for why they weren't price-responsive include implicit value placed on reliability, pricing structures, lack of flexibility in adjusting production inputs, just-in-time practices, perceived barriers to onsite generation, and insufficient time. We draw these observations into a framework that could help refine economic theory of dynamic pricing by providing real-world descriptions of how firms behave and why.

  2. Price of Cameron, LA Natural Gas LNG Imports (Nominal Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) (Nominal Dollars per Thousand Cubic Feet) Price of Cameron, LA Natural Gas LNG Imports (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 4.78 2010's 5.78 8.13 10.54 -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price of Liquefied Natural Gas

  3. Price of Cameron, LA Natural Gas LNG Imports from Qatar (Nominal Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) from Qatar (Nominal Dollars per Thousand Cubic Feet) Price of Cameron, LA Natural Gas LNG Imports from Qatar (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 4.51 2010's 5.97 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S.

  4. Price of Cove Point, MD Natural Gas LNG Imports from Egypt (Nominal Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Egypt (Nominal Dollars per Thousand Cubic Feet) Price of Cove Point, MD Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 11.66 7.83 7.22 7.46 4.20 2010's 5.49 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016

  5. Price of Elba Island, GA Natural Gas LNG Imports from Nigeria (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Nigeria (Nominal Dollars per Thousand Cubic Feet) Price of Elba Island, GA Natural Gas LNG Imports from Nigeria (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 11.69 -- -- 9.93 -- 2010's -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016

  6. Price of Everett, MA Natural Gas LNG Imports from Egypt (Nominal Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Egypt (Nominal Dollars per Thousand Cubic Feet) Price of Everett, MA Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 5.58 2010's 7.29 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price

  7. Price of Gulf of Mexico Natural Gas LNG Imports (Nominal Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    Thousand Cubic Feet) (Nominal Dollars per Thousand Cubic Feet) Price of Gulf of Mexico Natural Gas LNG Imports (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 8.87 7.31 8.36 -- -- 2010's -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price of Liquefied

  8. Price of Gulf of Mexico Natural Gas LNG Imports from Malaysia (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Malaysia (Nominal Dollars per Thousand Cubic Feet) Price of Gulf of Mexico Natural Gas LNG Imports from Malaysia (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 6.67 -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price of

  9. Price of Gulf of Mexico Natural Gas LNG Imports from Nigeria (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Nigeria (Nominal Dollars per Thousand Cubic Feet) Price of Gulf of Mexico Natural Gas LNG Imports from Nigeria (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 11.11 -- 8.29 -- -- 2010's -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016

  10. Price of Lake Charles, LA Natural Gas LNG Imports from Egypt (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Egypt (Nominal Dollars per Thousand Cubic Feet) Price of Lake Charles, LA Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- 9.73 6.60 6.64 7.14 3.29 2010's 3.93 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  11. Price of Northeast Gateway Natural Gas LNG Imports from Egypt (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Northeast Gateway Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Price of Northeast Gateway Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 6.71 2010's 5.11 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  12. Price of Savine Pass, LA Natural Gas LNG Imports from Egypt (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Savine Pass, LA Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Price of Savine Pass, LA Natural Gas LNG Imports from Egypt (Nominal Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 4.10 2010's -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next

  13. Carbon Fund for Spanish Firms FC2E | Open Energy Information

    Open Energy Info (EERE)

    Fund for Spanish Firms FC2E Jump to: navigation, search Name: Carbon Fund for Spanish Firms (FC2E) Place: Spain Sector: Carbon Product: String representation "Instituto de Cr ......

  14. Deadline for DOE Indian Country Working Group Nominations Extended to Aug. 24

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) is looking for nominations for elected tribal government officials (or designated tribal government employees with authority to act on behalf of the elected officials) to serve as members of the Indian Country Energy and Infrastructure Working Group (ICEIWG).

  15. Results from ORNL Characterization of Nominal 350 ?m NUCO Kernels from the BWXT 59344 batch

    SciTech Connect (OSTI)

    Hunn, John D; Kercher, Andrew K; Menchhofer, Paul A; Price, Jeffery R

    2005-01-01

    This document is a compilation of characterization data obtained on nominal 350 {micro}m natural enrichment uranium oxide/uranium carbide kernels (NUCO) produced by BWXT for the Advanced Gas Reactor Fuel Development and Qualification Program. These kernels were produced as part of a development effort at BWXT to address issues involving forming and heat treatment and were shipped to ORNL for additional characterization and for coating tests. The kernels were identified as G73N-NU-59344. 250 grams were shipped to ORNL. Size, shape, and microstructural analysis was performed. These kernels were preceded by G73B-NU-69300 and G73B-NU-69301, which were kernels produced and delivered to ORNL earlier in the development phase. Characterization of the kernels from G73B-NU-69300 was summarized in ORNL/CF-04/07 'Results from ORNL Characterization of Nominal 350 {micro}m NUCO Kernels from the BWXT 69300 composite'.

  16. PPPL awards coil contract to Pennsylvania firm | Princeton Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab awards coil contract to Pennsylvania firm By Kitta MacPherson August 11, 2011 Tweet Widget Google Plus One Share on Facebook The U.S. Department of Energy's Princeton Plasma Physics Laboratory (PPPL) has awarded an $800,000 contract to a Nazareth, Pa.-based magnet manufacturer that will enable the production of essential components designed for an advanced fusion experiment. The PPPL-designed components, known as "trim coils", will be manufactured by Everson Tesla, Incorporated

  17. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department Release Date: 11/17/15 Page 1 of 24 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SANDIA CORPORATION SF 6432-FP (11/2015) Section II STANDARD TERMS AND CONDITIONS FOR FIRM-FIXED PRICE CONTRACTS THE FOLLOWING CLAUSES APPLY TO THIS CONTRACT AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY SUPPLEMENTED OR AMENDED IN WRITING IN THE COVER PAGE OR SECTION I. (CTRL+CLICK ON A LINK BELOW TO ADVANCE DIRECTLY TO

  18. Primus Power Corporation Wind Firming EnergyFarm

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Primus Power Corporation Wind Firming EnergyFarm (tm) Project Description Primus Power is deploying a 25MW/75MWh EnergyFarm(tm) in the Modesto Irrigation District (MID) in California' central valley that consists of an array of 250kW EnergyPods(tm); plug-and-play zinc-flow battery modules and power electronics systems housed inside ISO shipping containers. The modular design and operation will be field tested at Pacific Gas & Electric with support from Sandia National Laboratories and the

  19. Firm develops own EMS built on Apple computer

    SciTech Connect (OSTI)

    Pospisil, R.

    1982-04-05

    Firestone Fibers and Textile Co. programmed a $2000 desktop Apple II computer and special electronic panels designed by the engineering staff to perform process control and other energy-management functions. The system should reduce natural gas consumption 40% and save the company up to $75,000 a year by reducing the amount of hot air exhausted from fabric-treating ovens. The system can be expanded to control lights and space-conditioning equipment. The company is willing to negotiate with other firms to market the panels. The Apple II was chosen because it has a high capacity for data acquisition and testing and because of the available software. (DCK)

  20. Enrico Fermi Award Nominations | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Security Administration | (NNSA) Enrico Fermi Achieves First Self Sustain Nuclear Chain Reaction Enrico Fermi Achieves First Self Sustain Nuclear Chain Reaction Chicago, IL Metallurgical Laboratory scientists led by Enrico Fermi achieve the first self-sustained nuclear chain reaction in pile constructed under the west grandstand at Stagg field in Chicago

    Enrico Fermi Award Nominations News News Home Featured Articles Science Headlines 2016 2015 2014 2013 2012 2011 2010 2009 2008

  1. Hanford Site Secondary Waste Roadmap

    SciTech Connect (OSTI)

    Westsik, Joseph H.

    2009-01-29

    Summary The U.S. Department of Energy (DOE) is making plans to dispose of 54 million gallons of radioactive tank wastes at the Hanford Site near Richland, Washington. The high-level wastes and low-activity wastes will be vitrified and placed in permanent disposal sites. Processing of the tank wastes will generate secondary wastes, including routine solid wastes and liquid process effluents, and these need to be processed and disposed of also. The Department of Energy Office of Waste Processing sponsored a meeting to develop a roadmap to outline the steps necessary to design the secondary waste forms. Representatives from DOE, the U.S. Environmental Protection Agency, the Washington State Department of Ecology, the Oregon Department of Energy, Nuclear Regulatory Commission, technical experts from the DOE national laboratories, academia, and private consultants convened in Richland, Washington, during the week of July 21-23, 2008, to participate in a workshop to identify the risks and uncertainties associated with the treatment and disposal of the secondary wastes and to develop a roadmap for addressing those risks and uncertainties. This report describes the results of the roadmap meeting in Richland. Processing of the tank wastes will generate secondary wastes, including routine solid wastes and liquid process effluents. The secondary waste roadmap workshop focused on the waste streams that contained the largest fractions of the 129I and 99Tc that the Integrated Disposal Facility risk assessment analyses were showing to have the largest contribution to the estimated IDF disposal impacts to groundwater. Thus, the roadmapping effort was to focus on the scrubber/off-gas treatment liquids with 99Tc to be sent to the Effluent Treatment Facility for treatment and solidification and the silver mordenite and carbon beds with the captured 129I to be packaged and sent to the IDF. At the highest level, the secondary waste roadmap includes elements addressing regulatory and

  2. Satellite power system (SPS). Rectenna siting: availability and distribution of nominally eligible sites

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Siting of 60 ground receiving stations (rectennas) for the SPS may pose a problem due to the large area per rectenna (15,000 hectares, 38,000 acres) and numerous siting constraints. This study analyzes areas potentially eligible for rectenna sites by mapping, at a national scale, those conditions which would preclude rectenna construction. These exclusion variables which reflect restricted lands, topography, safety, national policy and electromagnetic (microwave) effects, have been computer encoded and tabulated. Subsequent analysis of the nine electric power planning regions that make up the contiguous states indicate an apparently adequate number of nominally eligible sites in all regions in comparison to projected electrical generation. Eligibility in this context means only that areas were not excluded in this national level analysis; more detailed investigation may reveal purely local constraints or smaller scale exclusions. A second major qualification relates to small isolated eligible areas. Eliminating individual eligible clusters with less than nine times the area of one rectenna eliminates much of the Eastern US; a four-to-one adjacent eligible area test poses no such problem. An independant study of the placement of 60 nominal sites in relation to projected load centers reveals that, even with modest transmission distances, the supply of eligible areas is not a key constraint, except perhaps in the Mid-Atlantic (Electric Reliability) Council Region. Even when several less critical (potential) exclusions are considered, more than 19% of the US is eligible; every region except Mid-Atlantic has at least 50 times an many eligible sites as are required.

  3. Proposals in for Czech firms; cooperation likely with eastern Germany

    SciTech Connect (OSTI)

    Alperowicz, N.

    1993-02-10

    Two Western groups - Shell and a consortium made up of Agip, Conoco, and Total - have offered to buy the refining operations of Chemopetrol Litvinov and Kaucuk Kralupy, both in the Czech republic. Meanwhile, Amoco, Neste, and PCD are looking at the possibility of acquiring some of the plastics plants at Litvinov. Amoco is interested in the polypropylene operations, Neste in polyethylene, and PCD in both. The two Czech firms are included in the second wave of privatization, which will begin in midyear. So far, there have been no offers for the 80,000-m.t./year polystyrene and 60,000-m.t./year styrene butadiene rubber operations belonging to Kralupy, although Atochem representatives recently visited the plants. Litvinov is carrying out revamping operations at its core unit, a 12-year-old, 450,000-m.t./year ethylene plant. The plant, currently running at 400,000 m.t./year, supplies downstream plants, Neratovice, and sells on the export markets. An existing ethylene pipeline between Litvinov and Bohlen in eastern Germany, which used to supply an average 100,000 m.t./year of ethylene to Bohen in exchange for naphtha, is virtually unused. One proposal involves reactivating this exchange to secure ethylene feedstock for plants in eastern Germany. According to some sources, a preliminary decision has been made to shut down the 100,000-m.t./year ethylene plant at Leuna and possibly to expand the Bohlen cracker by 100,000 m.t./year, to 400,000 m.t./year by the late 1990s.

  4. Post Secondary Project Performance Benchmarks

    Broader source: Energy.gov [DOE]

    Reports five major performance metrics that can be used to benchmark proposed energy service company projects within post secondary education facilities, disaggregated and reported by major retrofit strategy. Author: U.S. Department of Energy

  5. Statement from Energy Secretary Samuel W. Bodman on the Nomination of Thomas P. D'Agostino as Under Secretary for Nuclear Security and Administrator of NNSA

    Broader source: Energy.gov [DOE]

    "Today the President announced his intention to nominate Thomas P. D'Agostino as Under Secretary for Nuclear Security and Administrator of the National Nuclear Security Administration (NNSA).

  6. SLAC Partners with Palo Alto Firm to Make Klystrons Much More Efficient:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New 'GREEN-RF' technology recycles energy that would otherwise go to waste in accelerating particles for science, medicine, industry | Department of Energy SLAC Partners with Palo Alto Firm to Make Klystrons Much More Efficient: New 'GREEN-RF' technology recycles energy that would otherwise go to waste in accelerating particles for science, medicine, industry SLAC Partners with Palo Alto Firm to Make Klystrons Much More Efficient: New 'GREEN-RF' technology recycles energy that would

  7. Fact Sheet: Wind Firming EnergyFarm (August 2013) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind Firming EnergyFarm (August 2013) Fact Sheet: Wind Firming EnergyFarm (August 2013) Primus Power is deploying a 25 MW/75 MWh EnergyFarm(TM) in California's Central Valley, comprising an array of 20 kW EnergyCell flow batteries combined with off-the-shelf components and power electronics housed inside a standard shipping container. For more information about how OE performs research and development on a wide variety of storage technologies, including batteries, flywheels, electrochemical

  8. JLab Recognizes Security Firm as Top Small Business Subcontractor for 2009

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Jefferson Lab Recognizes Security Firm as Top Small Business Subcontractor for 2009 JLab Recognizes Security Firm as Top Small Business Subcontractor for 2009 Small Business Mike Dallas, Jefferson Lab's chief operating officer, presents Nicole Stuart, Top Guard president with the Jefferson Science Associates/Jefferson Lab Outstanding Small Business Subcontractor Award for 2009. She is flanked by Chris Stuart, Top Guard vice president and Major Alton Dugger, Top Guard's site supervisor at

  9. Conduction below 100 °C in nominal Li6ZnNb4O14

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Yunchao; Paranthaman, Mariappan Parans; Gill, Lance W.; Edward W. Hagaman; Wang, Yangyang; Sokolov, Alexei P.; Dai, Sheng; Ma, Cheng; Chi, Miaofang; Veith, Gabriel M.; et al

    2015-09-15

    The increasing demand for a safe rechargeable battery with a high energy density per cell is driving a search for a novel solid electrolyte with a high Li+ or Na+ conductivity that is chemically stable in a working Li-ion or Na-ion battery. Li6ZnNb4O14 has been reported to exhibit a σ Li > 10-2 S cm-1 at 250 °C, but to disproportionate into multiple phases on cooling from 850 °C to room temperature. An investigation of the room-temperature Li-ion conductivity in a porous pellet of a multiphase product of a nominal Li6ZnNb4O14 composition is shown to have bulk σ Li 3.3more » x 10-5 S cm-1 at room temperature that increases to 1.4 x 10-4 S cm-1 by 50 °C. 7Li MAS NMR spectra were fitted to two Lorentzian lines, one of which showed a dramatic increase with increasing temperature. As a result, a test for water stability indicates that Li+ may move to the particle and grain surfaces to react with adsorbed water as occurs in the garnet Li+ conductors.« less

  10. Scenarios constructed for nominal flow in the presence of a repository at Yucca Mountain and vicinity

    SciTech Connect (OSTI)

    Barr, G.E.; Hunter, R.L.; Dunn, E.; Flint, A.

    1995-03-01

    Scenario development for the system performance assessment of the Yucca Mountain Site Characterization Project defines a scenario as a well-posed problem connecting an initiating event with radionuclide release to the accessible environment by a logical and physically possible combination or sequence of features, events, and processes. Drawing on the advice and assistance of the Project`s principal investigators (PIs), a collection of release scenarios initiated by the nominal ground-water flow occurring in the vicinity of the potential Yucca Mountain high-level-waste repository is developed and described in pictorial form. This collection of scenarios is intended to provide a framework to assist PIs in recognizing essential field and calculational analyses, to assist performance assessment in providing guidance to site characterization, and to continue the effort to exhaustively identify all features, events, and processes important to releases. It represents a step in the iterative process of identifying what details of the potential site are important for safe disposal. 67 refs.

  11. U.S. Nominal Cost per Crude Oil, Natural Gas, and Dry Well Drilled

    Gasoline and Diesel Fuel Update (EIA)

    (Thousand Dollars per Well) Oil, Natural Gas, and Dry Well Drilled (Thousand Dollars per Well) U.S. Nominal Cost per Crude Oil, Natural Gas, and Dry Well Drilled (Thousand Dollars per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 54.9 54.5 58.6 55.0 55.8 60.6 68.4 72.9 81.5 88.6 1970's 94.9 94.7 106.4 117.2 138.7 177.8 191.6 227.2 280.0 331.4 1980's 367.7 453.7 514.4 371.7 326.5 349.4 364.6 279.6 354.7 362.2 1990's 383.6 421.5 382.6 426.8 483.2

  12. U.S. Nominal Cost per Dry Well Drilled (Thousand Dollars per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Dry Well Drilled (Thousand Dollars per Well) U.S. Nominal Cost per Dry Well Drilled (Thousand Dollars per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 44.0 45.2 50.8 48.2 48.5 53.1 56.9 61.5 66.2 70.2 1970's 80.9 86.8 94.9 105.8 141.7 177.2 190.3 230.2 281.7 339.6 1980's 376.5 464.0 515.4 366.5 329.2 372.3 389.2 259.1 366.4 355.4 1990's 367.5 441.2 357.6 387.7 491.5 481.2 541.0 655.6 973.2 1,115.5 2000's 1,075.4 1,620.4 1,673.4 2,065.1 1,977.3 2,392.9

  13. U.S. Nominal Cost per Foot of Crude Oil Wells Drilled (Dollars per Foot)

    Gasoline and Diesel Fuel Update (EIA)

    Oil Wells Drilled (Dollars per Foot) U.S. Nominal Cost per Foot of Crude Oil Wells Drilled (Dollars per Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 13.22 13.11 13.41 13.20 13.12 13.94 15.04 16.61 18.63 19.28 1970's 19.29 18.41 20.77 22.54 27.82 34.17 37.35 41.16 49.72 58.29 1980's 66.36 80.40 86.34 72.65 66.32 66.78 68.35 58.35 62.28 64.92 1990's 69.17 73.75 69.50 67.52 70.57 78.09 70.60 90.48 108.88 156.45 2000's 125.96 153.72 194.55 221.13 298.45

  14. U.S. Nominal Cost per Foot of Crude Oil, Natural Gas, and Dry Wells Drilled

    Gasoline and Diesel Fuel Update (EIA)

    (Dollars per Foot) Oil, Natural Gas, and Dry Wells Drilled (Dollars per Foot) U.S. Nominal Cost per Foot of Crude Oil, Natural Gas, and Dry Wells Drilled (Dollars per Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 13.01 12.85 13.31 12.69 12.86 13.44 14.95 15.97 16.83 17.56 1970's 18.84 19.03 20.76 22.50 28.93 36.99 40.46 46.81 56.63 67.70 1980's 77.02 94.30 108.73 83.34 71.90 75.35 76.88 58.71 70.23 73.55 1990's 76.07 82.64 70.27 75.30 79.49 87.22

  15. U.S. Nominal Cost per Foot of Dry Wells Drilled (Dollars per Foot)

    Gasoline and Diesel Fuel Update (EIA)

    Dry Wells Drilled (Dollars per Foot) U.S. Nominal Cost per Foot of Dry Wells Drilled (Dollars per Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 10.56 10.56 11.20 10.58 10.64 11.21 12.34 12.87 12.88 13.23 1970's 15.21 16.02 17.28 19.22 26.76 33.86 36.94 43.49 52.55 64.60 1980's 73.70 90.03 104.09 79.10 67.18 73.69 76.53 51.05 66.96 67.61 1990's 67.49 83.05 67.82 72.56 86.60 84.60 95.74 115.09 157.79 182.99 2000's 181.83 271.63 284.17 345.94 327.91

  16. U.S. Nominal Cost per Foot of Natural Gas Wells Drilled (Dollars per Foot)

    Gasoline and Diesel Fuel Update (EIA)

    Natural Gas Wells Drilled (Dollars per Foot) U.S. Nominal Cost per Foot of Natural Gas Wells Drilled (Dollars per Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 18.57 17.65 18.10 17.19 18.57 18.35 21.75 23.05 24.05 25.58 1970's 26.75 27.70 27.78 27.46 34.11 46.23 49.78 57.57 68.37 80.66 1980's 95.16 122.17 146.20 108.37 88.80 93.09 93.02 69.55 84.65 86.86 1990's 90.73 93.10 72.83 83.15 81.90 95.97 98.67 117.55 127.94 138.42 2000's 138.39 172.05 175.78

  17. U.S. Nominal Cost per Natural Gas Well Drilled (Thousand Dollars per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Natural Gas Well Drilled (Thousand Dollars per Well) U.S. Nominal Cost per Natural Gas Well Drilled (Thousand Dollars per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 102.7 94.7 97.1 92.4 104.8 101.9 133.8 141.0 148.5 154.3 1970's 160.7 166.6 157.8 155.3 189.2 262.0 270.4 313.5 374.2 443.1 1980's 536.4 698.6 864.3 608.1 489.8 508.7 522.9 380.4 460.3 457.8 1990's 471.3 506.6 426.1 521.2 535.1 629.7 616.0 728.6 815.6 798.4 2000's 756.9 896.5 991.9

  18. Data summary for nominal 500 ?m DUO2 Kernels

    SciTech Connect (OSTI)

    Hunn, John D

    2004-04-01

    This document is a compilation of characterization data obtained on the nominal 500 {micro}m DUO{sub 2} kernels produced by ORNL for the Advanced Gas Reactor Fuel Development and Qualification Program to satisfy the FY03 WBS 3.1.2 task milestone No.2.2 kg of kernels were produced and combined in two composite lots. DUN-500 was a 1630 g composite sieved between 500 {+-} 2 {micro}m and 534 {+-} 2 {micro}m ASTM E161 electroformed sieves. DUN-482 was a 385.6 g composite sieved between 482 {+-} 2 {micro}m and 518 {+-} 2 {micro}m ASTM E161 electroformed sieves. Size, shape, density, and microstructural analysis were performed on a 100 g sublot (DUN-500-S-1) riffled from the DUN-500 composite. Size and shape were also measured on a 100 g sublot (DUN-482-S-1) riffled from the DUN-482 composite. For comparison, analysis was also performed on kernels extracted from the German reference fuel EUO 2358-2365 (AGR-06).

  19. Heavy and light hole transport in nominally undoped GaSb substrates

    SciTech Connect (OSTI)

    Kala, Hemendra; Umana-Membreno, Gilberto A.; Jolley, Gregory; Akhavan, Nima Dehdashti; Antoszewski, Jaroslaw; Faraone, Lorenzo; Patrashin, Mikhail A.; Akahane, Kouichi

    2015-01-19

    In this work, we report results of a study of electronic transport in nominally undoped p-type GaSb wafers typically employed as substrate material for the epitaxial growth of InAs/GaInSb type-II superlattices. Magnetic field dependent Hall-effect measurements and high-resolution mobility spectrum analysis clearly indicate p-type conductivity due to carriers in both the heavy and light hole bands. The extracted hole concentrations indicate a thermal activation energy of 17.8 meV for the dominant native acceptor-like defects. A temperature-independent effective mass ratio of 9.0 ± 0.8 was determined from the ratio of measured heavy and light hole concentrations. Over the 56 K–300 K temperature range, the light hole mobility was found to be 4.7 ± 0.7 times higher than the heavy hole mobility. The measured room temperature mobilities for the light and heavy holes were 2550 cm{sup 2}/Vs and 520 cm{sup 2}/Vs, respectively.

  20. Secondary recovery development in Ecuador

    SciTech Connect (OSTI)

    Arteaga, L.; Endara, J.; Alduja, F.

    1981-03-01

    The oil activity in Ecuador goes back to 1920 when the oil-bearing structures were discovered in the Peninsula of Santa Elena in the Ecuatorian coast. Since that time 2,700 oil wells have been drilled; at the present time, only 650 wells are still producing. Oil production has been decreasing in spite of artificial producing systems (sucker rod pumping, and gas lift). During the period of 1966 to 1969 a total of 8 pilot projects was performed to evaluate the possibility of using secondary recovery methods (waterflooding) in 3 different oil-bearing formations from 5 areas, and utilizing different injection patterns. The results from numerical simulation and pilot projects showed the convenience and easibility of the implmentation of secondary recovery systems (waterflooding) in the Shushufindi-Aguarico field. A detailed description is presented of the development of the secondary recovery methods in Ecuador - antecedents, pilot projects, results, etc.

  1. A Multiattribute Utility Analysis of Sites Nominated For Characterization For the First Radioactive Waste Repository- A Decision Aiding Methodology

    Broader source: Energy.gov [DOE]

    In December 1984, the Department of Energy (DOE) published draft environmental assessments (EAs) to support the proposed nomination of five sites and the recommendation of three sites for characterization for the first radioactive-waste repository. A chapter common to all the draft EAs (Chapter 7) presented rankings of the five sites against the postclosure and the preclosure technical siting guidelines. To determine which three sites appeared most favorable for recommendation for characterization, three simple quantitative methods were used to aggregate the rankings assigned to each site for the various technical guidelines. In response to numerous comments on the methods, the DOE has undertaken a formal application of one of them (hereafter referred to as the decision-aiding methodology) for the purpose of obtaining a more rigorous evaluation of the nominated sites.

  2. Energy Department Advances Market Access for U.S. Firms in Chinese Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Sector | Department of Energy Advances Market Access for U.S. Firms in Chinese Energy Efficiency Sector Energy Department Advances Market Access for U.S. Firms in Chinese Energy Efficiency Sector July 31, 2014 - 5:48pm Addthis Assistant Secretary Dr. Dave Danielson and Vice Chairman Xie Zhenhua (right) of China’s National Development and Reform Commission witness the MOU signing between the U.S.-China Energy Cooperation Program and the Chinese Society for Urban Studies.

  3. Jefferson Lab Awards $3.54 Million Contract To Pennsylvania Firm for 12 GeV

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project | Jefferson Lab 3.54 Million Contract To Pennsylvania Firm for 12 GeV Project Jefferson Lab Awards $3.54 Million Contract To Pennsylvania Firm for 12 GeV Project NEWPORT NEWS, Va., May 1, 2009 - A Pennsylvania company has been awarded a $3.54 million contract to provide 84 klystrons to the U.S. Department of Energy's Thomas Jefferson National Accelerator Facility. The 13 kW klystrons, devices which will generate the electromagnetic fields that will accelerate the CEBAF electron

  4. Jefferson Lab awards $7.3 million construction contract to Chesapeake firm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Jefferson Lab awards $7.3 million construction contract to Chesapeake firm This artist's rendering shows what the completed addition will look like. A print quality file of this graphic may be downloaded from JPIX. Jefferson Lab awards $7.3 million construction contract to Chesapeake firm June 15, 2004 Newport News, VA. - On June 7, the Department of Energy's Jefferson Lab awarded a $7.3 million construction project to Mid Eastern Builders, Inc. of Chesapeake, Va. The contract is to build

  5. Post Secondary Project Performance Benchmarks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Post Secondary Project Performance Benchmarks (All ASHRAE Zones) continued > We define an ESCO as a company that provides energy efficiency-related and other value-added services and that employs performance contracting as a core part of its energy efficiency services business. 1 For projects with electricity savings, we assume site energy conversion (1 kWh = 3,412 Btu). We did not estimate avoided Btus from gallons of water conserved. In general, we followed the analytical approach

  6. Secondary Energy Infobook Activities (19 Activities)

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Information about Secondary Energy Infobook, 19 student activities on energy basics for grades 5-8 and 9-12.

  7. A Downtown Denver Law Firm Leverages Tenant Improvement Funds to Cut Operating Expenses

    SciTech Connect (OSTI)

    2013-03-01

    Bryan Cave HRO (formerly Holme Roberts & Owen LLP, headquartered in Denver, Colorado), an international law firm, partnered with the U.S Department of Energy (DOE) to develop and implement solutions to retrofit existing buildings to reduce annual energy consumption by at least 30% versus pre-retrofit energy use as part of DOE’s Commercial Building Partnership (CBP) program.

  8. Secondary emission electron gun using external primaries

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni; Ben-Zvi, Ilan; Kewisch, Jorg; Chang, Xiangyun

    2007-06-05

    An electron gun for generating an electron beam is provided, which includes a secondary emitter. The secondary emitter includes a non-contaminating negative-electron-affinity (NEA) material and emitting surface. The gun includes an accelerating region which accelerates the secondaries from the emitting surface. The secondaries are emitted in response to a primary beam generated external to the accelerating region. The accelerating region may include a superconducting radio frequency (RF) cavity, and the gun may be operated in a continuous wave (CW) mode. The secondary emitter includes hydrogenated diamond. A uniform electrically conductive layer is superposed on the emitter to replenish the extracted current, preventing charging of the emitter. An encapsulated secondary emission enhanced cathode device, useful in a superconducting RF cavity, includes a housing for maintaining vacuum, a cathode, e.g., a photocathode, and the non-contaminating NEA secondary emitter with the uniform electrically conductive layer superposed thereon.

  9. Secondary emission electron gun using external primaries

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni; Ben-Zvi, Ilan

    2009-10-13

    An electron gun for generating an electron beam is provided, which includes a secondary emitter. The secondary emitter includes a non-contaminating negative-electron-affinity (NEA) material and emitting surface. The gun includes an accelerating region which accelerates the secondaries from the emitting surface. The secondaries are emitted in response to a primary beam generated external to the accelerating region. The accelerating region may include a superconducting radio frequency (RF) cavity, and the gun may be operated in a continuous wave (CW) mode. The secondary emitter includes hydrogenated diamond. A uniform electrically conductive layer is superposed on the emitter to replenish the extracted current, preventing charging of the emitter. An encapsulated secondary emission enhanced cathode device, useful in a superconducting RF cavity, includes a housing for maintaining vacuum, a cathode, e.g., a photocathode, and the non-contaminating NEA secondary emitter with the uniform electrically conductive layer superposed thereon.

  10. Flame tolerant secondary fuel nozzle

    SciTech Connect (OSTI)

    Khan, Abdul Rafey; Ziminsky, Willy Steve; Wu, Chunyang; Zuo, Baifang; Stevenson, Christian Xavier

    2015-02-24

    A combustor for a gas turbine engine includes a plurality of primary nozzles configured to diffuse or premix fuel into an air flow through the combustor; and a secondary nozzle configured to premix fuel with the air flow. Each premixing nozzle includes a center body, at least one vane, a burner tube provided around the center body, at least two cooling passages, a fuel cooling passage to cool surfaces of the center body and the at least one vane, and an air cooling passage to cool a wall of the burner tube. The cooling passages prevent the walls of the center body, the vane(s), and the burner tube from overheating during flame holding events.

  11. Highly charged ion secondary ion mass spectroscopy

    DOE Patents [OSTI]

    Hamza, Alex V.; Schenkel, Thomas; Barnes, Alan V.; Schneider, Dieter H.

    2001-01-01

    A secondary ion mass spectrometer using slow, highly charged ions produced in an electron beam ion trap permits ultra-sensitive surface analysis and high spatial resolution simultaneously. The spectrometer comprises an ion source producing a primary ion beam of highly charged ions that are directed at a target surface, a mass analyzer, and a microchannel plate detector of secondary ions that are sputtered from the target surface after interaction with the primary beam. The unusually high secondary ion yield permits the use of coincidence counting, in which the secondary ion stops are detected in coincidence with a particular secondary ion. The association of specific molecular species can be correlated. The unique multiple secondary nature of the highly charged ion interaction enables this new analytical technique.

  12. New Jersey firm creates jobs and vital components for world-leading

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experiment | Princeton Plasma Physics Lab Jersey firm creates jobs and vital components for world-leading experiment By John Greenwald July 10, 2012 Tweet Widget Google Plus One Share on Facebook This superconducting wire will become thin as a needle when Oxford Superconducting Technology finishes manufacturing it. (Photo by Elle Starkman, PPPL Office Of Communications) This superconducting wire will become thin as a needle when Oxford Superconducting Technology finishes manufacturing it.

  13. Controlling Wind Turbines for Secondary Frequency Regulation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Wind Turbines for Secondary Frequency Regulation: An Analysis of AGC ... Workshop on Large-Scale Integration of Wind Power Into Power Systems as Well as on ...

  14. Secondary Waste Forms and Technetium Management

    Office of Environmental Management (EM)

    Secondary Waste Forms and Technetium Management Joseph H. Westsik, Jr. Pacific Northwest ... liquid effluents under the Dangerous Waste Permit for disposal at the Integrated ...

  15. Primary & Secondary Navigation Menus (help/navigation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power Services Site Navigation Aids Primary & Secondary Navigation Menus The primary navigation menus are located in the black horizontal navigation bars at the top and bottom of...

  16. Prototype secondary mirror assembly design for the space infrared telescope facility

    SciTech Connect (OSTI)

    Stier, M.; Duffy, M.; Gullapalli, S.; Rockwell, R.; Sileo, F.; Krim, M.

    1989-02-01

    The authors describe their design of a liquid helium temperature prototype secondary mirror assembly (PSMA) under development for the NASA Space Infrared Telescope Facility (SIRTF) program. The SIRTF secondary mirror assembly must operate below 4 K and provide the functions of highly precise 2-axis dynamic tilting (chopping) in addition to the conventional functions needed by the SIRTF observatory. Their PSMA design employs a fused quartz mirror kinematically attached at its center to an aluminium cruciform. The mirror/cruciform assembly is driven in tilt about its combined center of mass using a unique flexure pivot and a four-actuator control system with feedback provided by pairs of differential position sensors. The voice coil actuators are mounted on a second flexure-pivoted mass enhancing servo system stability and isolating the telescope from vibration-induced disturbances. The mirror/cruciform and the reaction mass are attached to opposite sides of an aluminum mounting plate whose dimensional characteristics are nominally identical to that of the aluminum flexure pivot material. The mounting plate is connected to the outer housing by a six degree of freedom focus and centering mechanism using pivoted actuation levers driven by lead screw/harmonic drive/stepper motor assemblies.

  17. NREL Report Firms Up Land-Use Requirements of Solar - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report Firms Up Land-Use Requirements of Solar Study shows solar for 1,000 homes would require 32 acres July 30, 2013 The Energy Department's National Renewable Energy Laboratory (NREL) has published a report on the land use requirements of solar power plants based on actual land-use practices from existing solar facilities. "Having real data from a majority of the solar plants in the United States will help people make proper comparisons and informed decisions," lead author Sean Ong

  18. Y-12 cleaning technology licensed by local engineering firm | Y-12 National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Security Complex cleaning technology ... Y-12 cleaning technology licensed by local engineering firm Posted: October 31, 2012 - 10:00am MK Technologies CEO and founder Mike Carroll and director of strategic development and acquisition Chris Van Beke met Y-12 chemist and inventor Ron Simandl in his Y-12 laboratory to see the SIMWyPES® production process along with a sampling of its numerous applications. From left, Simandl shows Van Beke and Carroll two of a variety of items enhanced with

  19. STATUS OF DIAMOND SECONDARY EMISSION ENHANCED PHOTOCATHODE

    SciTech Connect (OSTI)

    RAO,T.; BEN-ZVI, I.; CHANG, X.; GRIMES, J.; GROVER, R.; ISAKOVIC, A.; SMEDLEY, J.; TODD, R.; WARREN, J.; WU, Q.

    2007-05-25

    The diamond secondary emission enhanced photocathode (SEEP) provides an attractive alternative for simple photo cathodes in high average current electron injectors. It reduces the laser power required to drive the cathode, simultaneously isolating the cathode and the FW cavity from each other, thereby protecting them from contamination and increasing their life time. In this paper, we present the latest results on the secondary electron yield using pulsed thermionic and photo cathodes as primary electron sources, shaping the diamond using laser ablation and reactive ion etching as well as the theoretical underpinning of secondary electron generation and preliminary results of modeling.

  20. Mathematical model of a utility firm. Final technical report, Part I

    SciTech Connect (OSTI)

    Not Available

    1983-08-21

    Utility companies are in the predicament of having to make forecasts, and draw up plans for the future, in an increasingly fluid and volatile socio-economic environment. The project being reported is to contribute to an understanding of the economic and behavioral processes that take place within a firm, and without it. Three main topics are treated. One is the representation of the characteristics of the members of an organization, to the extent to which characteristics seem pertinent to the processes of interest. The second is the appropriate management of the processes of change by an organization. The third deals with the competitive striving towards an economic equilibrium among the members of a society in the large, on the theory that this process might be modeled in a way which is similar to the one for the intra-organizational ones. This volume covers mainly the first topic.

  1. Hybrid-secondary uncluttered induction machine

    DOE Patents [OSTI]

    Hsu, John S.

    2001-01-01

    An uncluttered secondary induction machine (100) includes an uncluttered rotating transformer (66) which is mounted on the same shaft as the rotor (73) of the induction machine. Current in the rotor (73) is electrically connected to current in the rotor winding (67) of the transformer, which is not electrically connected to, but is magnetically coupled to, a stator secondary winding (40). The stator secondary winding (40) is alternately connected to an effective resistance (41), an AC source inverter (42) or a magnetic switch (43) to provide a cost effective slip-energy-controlled, adjustable speed, induction motor that operates over a wide speed range from below synchronous speed to above synchronous speed based on the AC line frequency fed to the stator.

  2. Creating Liquidity for Energy Efficiency Loans in Secondary Markets

    Office of Energy Efficiency and Renewable Energy (EERE)

    This webinar, held on Jan. 22, 2010, provides information on secondary markets in energy efficiency loans.

  3. Secondary lift for magnetically levitated vehicles

    DOE Patents [OSTI]

    Cooper, Richard K.

    1976-01-01

    A high-speed terrestrial vehicle that is magnetically levitated by means of magnets which are used to induce eddy currents in a continuous electrically conductive nonferromagnetic track to produce magnetic images that repel the inducing magnet to provide primary lift for the vehicle. The magnets are arranged so that adjacent ones have their fields in opposite directions and the magnets are spaced apart a distance that provides a secondary lift between each magnet and the adjacent magnet's image, the secondary lift being maximized by optimal spacing of the magnets.

  4. Integrated primary/secondary Pb smelting

    SciTech Connect (OSTI)

    Zunkel, A.D.; Taylor, J.C.

    1988-01-01

    The existing primary and secondary lead smelting processes have become uneconomic and cannot meet the current and proposed environmental standards. In the majority of plants retrofit programs will not solve the problems in the long term. A concept has been developed, however, which integrates the primary and secondary lead smelting operations in one plant - following the traditional approach used in the copper and nickel industries. The outlined processes provide an economic, environmentally acceptable method of returning scrap, particularly scrap batteries, to the circuit, thereby solving the growing and serious environmental problem facing most industrial nations.

  5. Secondary succession: insect-plant relationships

    SciTech Connect (OSTI)

    Brown, V.K.

    1984-12-01

    Botanists have dominated the study of secondary succession, and as a result, models and theories have focused on plants. Recent work, however, has revealed several complex relationships between plants and insects during succession, including adaptations of life-cycle strategies. Furthermore, insect herbivores play a key role in the course and rate of plant succession.

  6. Particle Physics Outreach to Secondary Education

    SciTech Connect (OSTI)

    Bardeen, Marjorie G.; Johansson, K.Erik; Young, M.Jean

    2011-11-21

    This review summarizes exemplary secondary education and outreach programs of the particle physics community. We examine programs from the following areas: research experiences, high-energy physics data for students, informal learning for students, instructional resources, and professional development. We report findings about these programs' impact on students and teachers and provide suggestions for practices that create effective programs from those findings. We also include some methods for assessing programs.

  7. Genome sequencing reveals complex secondary metabolome in themarine actinomycete Salinispora tropica

    SciTech Connect (OSTI)

    Udwary, Daniel W.; Zeigler, Lisa; Asolkar, Ratnakar; Singan,Vasanth; Lapidus, Alla; Fenical, William; Jensen, Paul R.; Moore, BradleyS.

    2007-05-01

    Recent fermentation studies have identified actinomycetes ofthe marine-dwelling genus Salinispora as prolific natural productproducers. To further evaluate their biosynthetic potential, we analyzedall identifiable secondary natural product gene clusters from therecently sequenced 5,184,724 bp S. tropica CNB-440 circular genome. Ouranalysis shows that biosynthetic potential meets or exceeds that shown byprevious Streptomyces genome sequences as well as other naturalproduct-producing actinomycetes. The S. tropica genome features ninepolyketide synthase systems of every known formally classified family,non-ribosomal peptide synthetases and several hybrid clusters. While afew clusters appear to encode molecules previously identified inStreptomyces species,the majority of the 15 biosynthetic loci are novel.Specific chemical information about putative and observed natural productmolecules is presented and discussed. In addition, our bioinformaticanalysis was critical for the structure elucidation of the novelpolyenemacrolactam salinilactam A. This study demonstrates the potentialfor genomic analysis to complement and strengthen traditional naturalproduct isolation studies and firmly establishes the genus Salinispora asa rich source of novel drug-like molecules.

  8. Development of a farm-firm modelling system for evaluation of herbaceous energy crops

    SciTech Connect (OSTI)

    English, B.C.; Alexander, R.R.; Loewen, K.H.; Coady, S.A.; Cole, G.V.; Goodman, W.R. . Dept. of Agricultural Economics and Rural Sociology)

    1992-01-01

    A complete analysis is performed to simulate biomass production incorporated into a realistic whole farm situation, including or replacing a typical crop mix. Representative farms are constructed to accommodate such simulation. Four management systems are simulated for each firm, with each simulation depicting a different crop mix and/or use of different farming technologies and production methods. The first simulation was a base farm plan in which the operator would maintain the historical crop mix for the area, participate in all price support programs, and not participate in either a conservative reserve or a biomass production program. In the second simulation, the operator would again maintain the historical crop mix, would not participate in a conservation reserve or biomass production program, and would be ineligible to participate in any price support system. The third simulation introduced the Conservation Reserve Program (CRP) and included participation in all price support programs. The fourth simulation introduced a biomass crop production enterprise (switchgrass) as an alternative to enrolling highly erodible cropland in the CRP and allowed participation in price support programs. Simulations were made for three farms, two in West Tennessee and on in South Georgia. Results indicate that erosion is likely to be reduced more by the diversion of cropland to permanent vegetative cover on farms similar to the more highly erodible West Tennessee farms than on the less erodible Tift County, Georgia farm. Equivalent reductions in erosion rates result from entering highly erodible cropland in the CRP and from production of switchgrass as a biomass energy crop. Both switchgrass and CRP farm plans result in decreased net returns from the base plan, although the biomass farm plans are, in general, more profitable than the CRP plans.

  9. PETROPHYSICAL INVESTIGATION OF THE SECONDARY RECOVERY POTENTIAL IN THE CHERRY CANYON FORMATION NE LEA FIELD LEA COUNTY, NEW MEXICO

    SciTech Connect (OSTI)

    T. Scott Hickman

    2002-06-01

    Read and Stevens has proposed the evaluation of the waterflood potential from the Cherry Canyon formation in the NE Lea Field in lea County, New Mexico. Much of the development in this area is approaching primary recovery limitations; additional recovery of remaining oil reserves by waterflood needs to be evaluated. The Cherry Canyon formation is composed of fine grained sandstone, containing clay material which results in high water saturation, and also has the tendency to swell and reduce reservoir permeability--the ability of fluid to flow through the rock pores and fractures. There are also abundant organic materials that interfere with obtaining reliable well logs. These complications have limited oil in place calculations and identification of net pay zones, presenting a challenge to the planned waterflood. Core analysis of the Cherry Canyon should improve the understanding of existing well logs and possibly indicate secondary recovery measures, such as waterflood, to enhance field recovery. Lacking truly representative core to provide accurate analyses, Read and Stevens will obtain and preserve fresh core. The consulting firm of T. Scott Hickman and Associates will then collaborate on special core analyses and obtain additional well logs for a more detailed analysis of reservoir properties. The log interpretation will be compared to the core analysis results, and the entire collected data set will be used to assess the potential and economic viability of successfully waterflooding the identified oil zones. Successful results from the project will improve accuracy of log interpretation and establish a methodology for evaluating secondary recovery by waterflood.

  10. Innovative secondary support technologies for western mines

    SciTech Connect (OSTI)

    Barczak, T.M.; Molinda, G.M.

    1996-12-01

    With the development of the shield support, the primary requirement for successful ground control in longwall mining is to provide stable gate road and bleeder entries. Wood cribbing has been the dominant form of secondary support. However, the cost and limited availability of timber, along with the poor performance of softwood crib supports, has forced western U.S. mines to explore the utilization of other support systems. The recent success of cable bolts has engendered much interest from western operators. Several innovative freestanding support systems have been developed recently including: (1) {open_quotes}The Can{close_quotes} support by Burrell Mining Products International, Inc., (2) Hercules and Link-N-Lock wood cribs and Propsetter by Strata Products (USA) Inc., (3) Variable Yielding Crib and Power Crib supports by Mountainland Support Systems, (4) the Confined Core Crib developed by Southern Utah Fuels Corporation; and (5) the MEGA prop by MBK Hydraulik. This paper assesses design considerations and compares the performance and application of these alternative secondary support systems.

  11. Prompt detonation of secondary explosives by laser

    SciTech Connect (OSTI)

    Paisley, D.L.

    1989-01-01

    Secondary high explosives have been promptly detonated by directing a laser beam of various wavelengths from 266 nanometers to 1.06 micron on the surface of the explosives. For this paper ''prompt'' means the excess transit time through an explosive charge is /approximately/250 nanoseconds (or less) less than the accepted full detonation velocity time. Timing between laser pulse, explosive initiation and detonation velocity and function time have been recorded. The laser parameters studied include: wavelength, pulse length, energy and power density, and beam diameter (spot size). Explosives evaluated include: PETN, HNS, HMX, and graphited PETN, HNS, and HMX. Explosive parameters that have been correlated with optical parameters include: density, surface area, critical diameter (spot size), spectral characteristics and enhance absorption. Some explosives have been promptly detonated over the entire range of wavelengths, possibly by two competing initiating mechanisms. Other explosives could not be detonated at any of the wavelengths or power densities tested. 8 refs., 12 figs., 1 tab.

  12. Secondary air injection system and method

    DOE Patents [OSTI]

    Wu, Ko-Jen; Walter, Darrell J.

    2014-08-19

    According to one embodiment of the invention, a secondary air injection system includes a first conduit in fluid communication with at least one first exhaust passage of the internal combustion engine and a second conduit in fluid communication with at least one second exhaust passage of the internal combustion engine, wherein the at least one first and second exhaust passages are in fluid communication with a turbocharger. The system also includes an air supply in fluid communication with the first and second conduits and a flow control device that controls fluid communication between the air supply and the first conduit and the second conduit and thereby controls fluid communication to the first and second exhaust passages of the internal combustion engine.

  13. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  14. Innovative secondary support systems for gate roads

    SciTech Connect (OSTI)

    Barczak, T.; Molinda, G.M.; Zelanko, J.C.

    1996-12-31

    With the development of the shield support, the primary requirement for successful ground control in longwall mining is to provide stable gate road and bleeder entries. Wood cribbing has been the dominant form of secondary and supplemental support. However, the cost and limited availability of timber, along with the poor performance of softwood crib supports, has forced western U.S. mines to explore the utilization of support systems other than conventional wood cribbing. The recent success of cable bolts has engendered much interest from western operators. Eastern U.S. coal operators are also now experimenting with various intrinsic and freestanding alternative support systems that provide effective ground control while reducing material handling costs and injuries. These innovative freestanding support systems include (1) {open_quotes}The Can{close_quotes} support by Burrell Mining Products International, Inc., (2) Hercules and Link-N-Lock wood cribs and Propsetter supports by Strata Products (USA) Inc., (3) Variable Yielding Crib and Power Crib supports by Mountainland Support Systems, (4) the Confined Core Crib developed by Southern Utah Fuels Corporation; and (5) the MEGA prop by MBK Hydraulik. This paper assesses design considerations and compares the performance and application of these alternative secondary support systems. Support performance in the form of load-displacement behavior is compared to conventional wood cribbing. Much of the data was developed through full-scale tests conducted by the U.S. Bureau of Mines (USBM) at the Strategic Structures Testing Laboratory in the unique Mine Roof Simulator load frame at the Pittsburgh Research Center. A summary of current mine experience with these innovative supports is also documented.

  15. Secondary electron yield of emissive materials for large-area...

    Office of Scientific and Technical Information (OSTI)

    Conference: Secondary electron yield of emissive materials for large-area micro-channel plate detectors: surface composition and film thickness dependencies Citation Details ...

  16. Microsoft PowerPoint - Secondary Revenue Public Process.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Secondary Energy Revenue Forecast Workshop October 22, 2015 Pre-Decisional. For Discussion Purposes Only. Agenda * Context * Going forward * Review of current methodology *...

  17. Texas Large Construction Site Notice for Secondary Operators...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Reference: Texas Large Construction Site Notice for Secondary Operators Published Texas Commission on Environmental...

  18. Comparison of Secondary Islands in Collisional Reconnection to Hall Reconnection

    SciTech Connect (OSTI)

    Shepherd, L. S.; Cassak, P. A.

    2010-07-02

    Large-scale resistive Hall-magnetohydrodynamic simulations of the transition from Sweet-Parker (collisional) to Hall (collisionless) magnetic reconnection are presented; the first to separate secondary islands from collisionless effects. Three main results are described. There exists a regime with secondary islands but without collisionless effects, and the reconnection rate is faster than Sweet-Parker, but significantly slower than Hall reconnection. This implies that secondary islands do not cause the fastest reconnection rates. The onset of Hall reconnection ejects secondary islands from the vicinity of the X line, implying that energy is released more rapidly during Hall reconnection. Coronal applications are discussed.

  19. A multiattribute utility analysis of sites nominated for characterization for the first radioactive-waste repository: A decision-aiding methodology

    SciTech Connect (OSTI)

    none,

    1986-05-01

    In December 1984, the Department of Energy (DOE) published draft environmental assessments (EAs) to support the proposed nomination of five sites and the recommendation of three sites for characterization for the first radioactive-waste repository. A chapter common to all the draft EAs (Chapter 7) presented rankings of the five sites against the postclosure and the preclosure technical siting guidelines. To determine which three sites appeared most favorable for recommendation for characterization, three simple quantitative methods were used to aggregate the rankings assigned to each site for the various technical guidelines. In response to numerous comments on the methods, the DOE has undertaken a formal application of one of them (hereafter referred to as the decision-aiding methodology) for the purpose of obtaining a more rigorous evaluation of the nominated sites. The application of the revised methodology is described in this report. The method of analysis is known as multiattribute utility analysis; it is a tool for providing insights as to which sites are preferable and why. The decision-aiding methodology accounts for all the fundamental considerations specified by the siting guidelines and uses as source information the data and evaluations reported or referenced in the EAs. It explicitly addresses the uncertainties and value judgments that are part of all siting problems. Furthermore, all scientific and value judgments are made explicit for the reviewer. An independent review of the application of the decision-aiding methodology has been conducted by the Board on Radioactive Waste Management of the National Academy of Sciences; the comments of the Board are included as an appendix to this report.

  20. Enumeration of Secondary Structure Element Bundles

    Energy Science and Technology Software Center (OSTI)

    2004-10-26

    A deterministic algorithm for enumeration of transmembrane protein folds is implemented. Using a set of sparse pairwise atomic distance constraints (such as those obtained from chemical cross-linking, FRET, or dipolar EPR experiments), the algorithm performs an exhaustive search of secondary structure element packing conformations distributed throughout the entire conformational space. The end result is a set of distinct protein conformations which can be scored and refined as part of a process designed for computational elucidationmore » of transmembrane protein structures. Algorithm Overview: The ESSEB algorithm works by dividing the conforrnational space of each secondary structure element (SSE) into a set of cells. For each cell there is a representative conformation and for each atom in the SSE for which a distance restraint is available, there is an associated internal error, The internal error for a distance restraint is the maximum distance that the atom, when positioned in any conformation within a cell, can be from the atom in the representative conformation. The algorithm works recursively by positioning one representative conformation of an SSE. AdI distance restraints are checked with a tolerance that includes both the experimental and internal error. If all restraints are satisfied, every representative conformation of the next SSE is checked, otherwise, the program moves on to the next representative conformation of the current SSE. In addition to the distance restraints, other constraints on protein conformation can be enforced. These include the distance of closest approach between SSE axes, a restraint which prevents the crossover of loops connecting adjacent SSEs, and a restriction on the minimum and maximum distances between axis end-points. Any protein conformation satisfying all of the restraints is enumerated for later scoring and possible refinement. Additionally, in order to make run-times feasible, a divide-and-conquer approach is used

  1. CARES Helps Explain Secondary Organic Aerosols

    SciTech Connect (OSTI)

    Zaveri, Rahul

    2014-03-28

    What happens when urban man-made pollution mixes with what we think of as pristine forest air? To know more about what this interaction means for the climate, the Carbonaceous Aerosol and Radiative Effects Study, or CARES, field campaign was designed in 2010. The sampling strategy during CARES was coordinated with CalNex 2010, another major field campaign that was planned in California in 2010 by the California Air Resources Board (CARB), the National Oceanic and Atmospheric Administration (NOAA), and the California Energy Commission (CEC). "We found two things. When urban pollution mixes with forest pollutions we get more secondary organic aerosols," said Rahul Zaveri, FCSD scientist and project lead on CARES. "SOAs are thought to be formed primarily from forest emissions but only when they interact with urban emissions. The data is saying that there will be climate cooling over the central California valley because of these interactions." Knowledge gained from detailed analyses of data gathered during the CARES campaign, together with laboratory experiments, is being used to improve existing climate models.

  2. CARES Helps Explain Secondary Organic Aerosols

    ScienceCinema (OSTI)

    Zaveri, Rahul

    2014-06-02

    What happens when urban man-made pollution mixes with what we think of as pristine forest air? To know more about what this interaction means for the climate, the Carbonaceous Aerosol and Radiative Effects Study, or CARES, field campaign was designed in 2010. The sampling strategy during CARES was coordinated with CalNex 2010, another major field campaign that was planned in California in 2010 by the California Air Resources Board (CARB), the National Oceanic and Atmospheric Administration (NOAA), and the California Energy Commission (CEC). "We found two things. When urban pollution mixes with forest pollutions we get more secondary organic aerosols," said Rahul Zaveri, FCSD scientist and project lead on CARES. "SOAs are thought to be formed primarily from forest emissions but only when they interact with urban emissions. The data is saying that there will be climate cooling over the central California valley because of these interactions." Knowledge gained from detailed analyses of data gathered during the CARES campaign, together with laboratory experiments, is being used to improve existing climate models.

  3. Simplified Hybrid-Secondary Uncluttered Machine And Method

    DOE Patents [OSTI]

    Hsu, John S [Oak Ridge, TN

    2005-05-10

    An electric machine (40, 40') has a stator (43) and a rotor (46) and a primary air gap (48) has secondary coils (47c, 47d) separated from the rotor (46) by a secondary air gap (49) so as to induce a slip current in the secondary coils (47c, 47d). The rotor (46, 76) has magnetic brushes (A, B, C, D) or wires (80) which couple flux in through the rotor (46) to the secondary coils (47c, 47d) without inducing a current in the rotor (46) and without coupling a stator rotational energy component to the secondary coils (47c, 47d). The machine can be operated as a motor or a generator in multi-phase or single-phase embodiments. A method of providing a slip energy controller is also disclosed.

  4. PPPC 4 DM secondary: a Poor Particle Physicist Cookbook for secondary radiation from Dark Matter

    SciTech Connect (OSTI)

    Buch, Jatan; Cirelli, Marco; Giesen, Gaëlle; Taoso, Marco

    2015-09-11

    We enlarge the set of recipes and ingredients at disposal of any poor particle physicist eager to cook up signatures from weak-scale Dark Matter models by computing two secondary emissions due to DM particles annihilating or decaying in the galactic halo, namely the radio signals from synchrotron emission and the gamma rays from bremsstrahlung. We consider several magnetic field configurations and propagation scenarios for electrons and positrons. We also provide an improved energy loss function for electrons and positrons in the Galaxy, including synchrotron losses in the different configurations, bremsstrahlung losses, ionization losses and Inverse Compton losses with an updated InterStellar Radiation Field.

  5. SECONDARY WASTE MANAGEMENT STRATEGY FOR EARLY LOW ACTIVITY WASTE TREATMENT

    SciTech Connect (OSTI)

    TW, CRAWFORD

    2008-07-17

    This study evaluates parameters relevant to River Protection Project secondary waste streams generated during Early Low Activity Waste operations and recommends a strategy for secondary waste management that considers groundwater impact, cost, and programmatic risk. The recommended strategy for managing River Protection Project secondary waste is focused on improvements in the Effiuent Treatment Facility. Baseline plans to build a Solidification Treatment Unit adjacent to Effluent Treatment Facility should be enhanced to improve solid waste performance and mitigate corrosion of tanks and piping supporting the Effiuent Treatment Facility evaporator. This approach provides a life-cycle benefit to solid waste performance and reduction of groundwater contaminants.

  6. Conduction below 100 °C in nominal Li6ZnNb4O14

    SciTech Connect (OSTI)

    Li, Yunchao; Paranthaman, Mariappan Parans; Gill, Lance W.; Edward W. Hagaman; Wang, Yangyang; Sokolov, Alexei P.; Dai, Sheng; Ma, Cheng; Chi, Miaofang; Veith, Gabriel M.; Manthiram, Arumugam; Goodenough, John B.

    2015-09-15

    The increasing demand for a safe rechargeable battery with a high energy density per cell is driving a search for a novel solid electrolyte with a high Li+ or Na+ conductivity that is chemically stable in a working Li-ion or Na-ion battery. Li6ZnNb4O14 has been reported to exhibit a σ Li > 10-2 S cm-1 at 250 °C, but to disproportionate into multiple phases on cooling from 850 °C to room temperature. An investigation of the room-temperature Li-ion conductivity in a porous pellet of a multiphase product of a nominal Li6ZnNb4O14 composition is shown to have bulk σ Li 3.3 x 10-5 S cm-1 at room temperature that increases to 1.4 x 10-4 S cm-1 by 50 °C. 7Li MAS NMR spectra were fitted to two Lorentzian lines, one of which showed a dramatic increase with increasing temperature. As a result, a test for water stability indicates that Li+ may move to the particle and grain surfaces to react with adsorbed water as occurs in the garnet Li+ conductors.

  7. Concrete as secondary containment for interior wall embedded waste lines

    SciTech Connect (OSTI)

    Porter, C.L.

    1993-10-01

    Throughout the Department of Energy (DOE) complex are numerous facilities that handle hazardous waste solutions. Secondary containment of tank systems and their ancillary piping is a major concern for existing facilities. The Idaho Division of Environmental Quality was petitioned in 1990 for an Equivalent Device determination regarding secondary containment of waste lines embedded in interior concrete walls. The petition was granted, however it expires in 1996. To address the secondary containment issue, additional studies were undertaken. One study verified the hypothesis that an interior wall pipe leak would follow the path of least resistance through the naturally occurring void found below a rigidly supported pipe and pass into an adjacent room where detection could occur, before any significant deterioration of the concrete takes place. Other tests demonstrated that with acidic waste solutions rebar and cold joints are not an accelerated path to the environment. The results from these latest studies confirm that the subject configuration meets all the requirements of secondary containment

  8. Hybrid-secondary uncluttered permanent magnet machine and method

    DOE Patents [OSTI]

    Hsu, John S.

    2005-12-20

    An electric machine (40) has a stator (43), a permanent magnet rotor (38) with permanent magnets (39) and a magnetic coupling uncluttered rotor (46) for inducing a slip energy current in secondary coils (47). A dc flux can be produced in the uncluttered rotor when the secondary coils are fed with dc currents. The magnetic coupling uncluttered rotor (46) has magnetic brushes (A, B, C, D) which couple flux in through the rotor (46) to the secondary coils (47c, 47d) without inducing a current in the rotor (46) and without coupling a stator rotational energy component to the secondary coils (47c, 47d). The machine can be operated as a motor or a generator in multi-phase or single-phase embodiments and is applicable to the hybrid electric vehicle. A method of providing a slip energy controller is also disclosed.

  9. Interconnecting PV on New York City's Secondary Network Distribution System

    SciTech Connect (OSTI)

    Anderson, K.; Coddington, M.; Burman, K.; Hayter, S.; Kroposki, B.; Watson, A.

    2009-12-01

    This study describes technical assistance provided by NREL to help New York City and Con Edison improve the interconnection of distributed PV systems on a secondary network distribution system.

  10. NREL: Measurements and Characterization - Dynamic Secondary Ion Mass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectrometry Dynamic Secondary Ion Mass Spectrometry SIMS Depth profile SIMS depth profiles of hydrogen for a series of a-Si films undergoing solid-phase recrystallization at different temperatures. Hydrogen loss is greater for higher temperatures; however, the rate of loss for a given temperature is also affected by the type of dopant and proximity to the surface. Dynamic Secondary Ion Mass Spectrometry (SIMS) uses a continuous, focused beam of primary ions to remove material from the

  11. Chemically Bonded Phosphate Ceramics: Stabilization of Secondary Wastes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Streams | Argonne National Laboratory Chemically Bonded Phosphate Ceramics: Stabilization of Secondary Wastes Streams Title Chemically Bonded Phosphate Ceramics: Stabilization of Secondary Wastes Streams Publication Type Book Chapter Year of Publication 2016 Authors Singh, D, Ganga, R, Gaviria, J, Yusufoglu, Y Book Title Engineered Ceramics: Current Status and Future Prospects Chapter 22 Publisher J. Wiley & Sons City Hoboken, NJ ISBN 978-1-119-10040-9 Abstract In this book project, all

  12. Pete_Lyons_Nomination_Testimony

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    remain strong and vigilant components of the Nation's integrated defenses against terrorism. I was a consistent voice for improving partnerships with international regulatory...

  13. CallforNominationLetter.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  14. Secondary Low-Level Waste Treatment Strategy Analysis

    SciTech Connect (OSTI)

    D.M. LaRue

    1999-05-25

    The objective of this analysis is to identify and review potential options for processing and disposing of the secondary low-level waste (LLW) that will be generated through operation of the Monitored Geologic Repository (MGR). An estimate of annual secondary LLW is generated utilizing the mechanism established in ''Secondary Waste Treatment Analysis'' (Reference 8.1) and ''Secondary Low-Level Waste Generation Rate Analysis'' (Reference 8.5). The secondary LLW quantities are based on the spent fuel and high-level waste (HLW) arrival schedule as defined in the ''Controlled Design Assumptions Document'' (CDA) (Reference 8.6). This analysis presents estimates of the quantities of LLW in its various forms. A review of applicable laws, codes, and standards is discussed, and a synopsis of those applicable laws, codes, and standards and their impacts on potential processing and disposal options is presented. The analysis identifies viable processing/disposal options in light of the existing laws, codes, and standards, and then evaluates these options in regard to: (1) Process and equipment requirements; (2) LLW disposal volumes; and (3) Facility requirements.

  15. Secondary beams and the synthesis of exotic nuclei

    SciTech Connect (OSTI)

    Nitschke, J.M.

    1985-09-01

    With the advent of modern fast cycling synchrotrons capable of delivering high intensity heavy ion beams up to uranium, the production of secondary radioactive ion beams (RIBs) with sufficient intensity has become feasible. The basic production mechanism is the fragmentation of near relativistic heavy ion beams on light targets. The physical facts underlying the efficient conversion of stable beams into RIBs are: (1) at beam energies of several 100 MeV/A thick conversion targets (1 to 10 g/cm/sup 2/) can be used, which, for nuclei near stability, convert on the order of .1 to 1% of the primary beam into secondary beams, (2) the secondary beams are emitted into a narrow phase space (small transverse and longitudinal emittances), and (3) these emittances are of the correct magnitude to match the acceptances of suitably designed storage and accumulator rings. 14 refs.

  16. Secondary Containment Design for a High Speed Centrifuge

    SciTech Connect (OSTI)

    Snyder, K.W.

    1999-03-01

    Secondary containment for high speed rotating machinery, such as a centrifuge, is extremely important for operating personnel safety. Containment techniques can be very costly, ungainly and time consuming to construct. A novel containment concept is introduced which is fabricated out of modular sections of polycarbonate glazed into a Unistrut metal frame. A containment study for a high speed centrifuge is performed which includes the development of parameters for secondary containment design. The Unistrut/polycarbonate shield framing concept is presented including design details and proof testing procedures. The economical fabrication and modularity of the design indicates a usefulness for this shielding system in a wide variety of containment scenarios.

  17. Method for detecting moisture in soils using secondary cosmic radiation

    DOE Patents [OSTI]

    Condreva, Kenneth

    2003-12-16

    Water content in a soil is determined by measuring the attenuation of secondary background cosmic radiation as this radiation propagates through a layer of soil and water. By measuring the attenuation of secondary cosmic radiation in the range of 5 MeV-15 MeV it is possible to obtain a relative measure of the water content in a soil layer above a suitable radiation detector and thus establish when and how much irrigation is needed. The electronic circuitry is designed so that a battery pack can be used to supply power.

  18. Secondary Waste Form Development and Optimization—Cast Stone

    SciTech Connect (OSTI)

    Sundaram, S. K.; Parker, Kent E.; Valenta, Michelle M.; Pitman, Stan G.; Chun, Jaehun; Chung, Chul-Woo; Kimura, Marcia L.; Burns, Carolyn A.; Um, Wooyong; Westsik, Joseph H.

    2011-07-14

    Washington River Protection Services is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF is a Resource Conservation and Recovery Act-permitted, multi-waste, treatment and storage unit and can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needs to be operational by 2018 to receive secondary liquid wastes generated during operation of the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The STU to ETF will provide the additional capacity needed for ETF to process the increased volume of secondary wastes expected to be produced by WTP.

  19. Scaling of Sweet-Parker reconnection with secondary islands

    SciTech Connect (OSTI)

    Cassak, P. A.; Shay, M. A.; Drake, J. F.

    2009-12-15

    Sweet-Parker (collisional) magnetic reconnection at high Lundquist number is modified by secondary islands. Daughton et al. [Phys. Rev. Lett. 103, 065004 (2009)] suggested the Sweet-Parker model governs the fragmented current sheet segments. If true, the reconnection rate would increase by the square root of the number of secondary islands. High Lundquist number resistive magnetohydrodynamic simulations are presented which agree, in a time-averaged sense, with the predicted scaling. This result may have important implications for energy storage before a solar eruption and its subsequent release.

  20. Development of a farm-firm modelling system for evaluation of herbaceous energy crops. Final project report

    SciTech Connect (OSTI)

    English, B.C.; Alexander, R.R.; Loewen, K.H.; Coady, S.A.; Cole, G.V.; Goodman, W.R.

    1992-01-01

    A complete analysis is performed to simulate biomass production incorporated into a realistic whole farm situation, including or replacing a typical crop mix. Representative farms are constructed to accommodate such simulation. Four management systems are simulated for each firm, with each simulation depicting a different crop mix and/or use of different farming technologies and production methods. The first simulation was a base farm plan in which the operator would maintain the historical crop mix for the area, participate in all price support programs, and not participate in either a conservative reserve or a biomass production program. In the second simulation, the operator would again maintain the historical crop mix, would not participate in a conservation reserve or biomass production program, and would be ineligible to participate in any price support system. The third simulation introduced the Conservation Reserve Program (CRP) and included participation in all price support programs. The fourth simulation introduced a biomass crop production enterprise (switchgrass) as an alternative to enrolling highly erodible cropland in the CRP and allowed participation in price support programs. Simulations were made for three farms, two in West Tennessee and on in South Georgia. Results indicate that erosion is likely to be reduced more by the diversion of cropland to permanent vegetative cover on farms similar to the more highly erodible West Tennessee farms than on the less erodible Tift County, Georgia farm. Equivalent reductions in erosion rates result from entering highly erodible cropland in the CRP and from production of switchgrass as a biomass energy crop. Both switchgrass and CRP farm plans result in decreased net returns from the base plan, although the biomass farm plans are, in general, more profitable than the CRP plans.

  1. T Plant secondary containment and leak detection upgrades

    SciTech Connect (OSTI)

    Carlson, T.A.

    1995-10-19

    The W-259 project will provide upgrades to the 2706-T/TA Facility to comply with Federal and State of Washington environmental regulations for secondary containment and leak detection. The project provides decontamination activities supporting the environmental restoration mission and waste management operations on the Hanford Site.

  2. Surface determination through atomically resolved secondary-electron imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ciston, J.; Brown, H. G.; D’Alfonso, A. J.; Koirala, P.; Ophus, C.; Lin, Y.; Suzuki, Y.; Inada, H.; Zhu, Y.; Allen, L. J.; et al

    2015-06-17

    We report that unique determination of the atomic structure of technologically relevant surfaces is often limited by both a need for homogeneous crystals and ambiguity of registration between the surface and bulk. Atomically resolved secondary-electron imaging is extremely sensitive to this registration and is compatible with faceted nanomaterials, but has not been previously utilized for surface structure determination. Here we show a detailed experimental atomic-resolution secondary-electron microscopy analysis of the c(6 x 2) reconstruction on strontium titanate (001) coupled with careful simulation of secondary-electron images, density functional theory calculations and surface monolayer-sensitive aberration-corrected plan-view high-resolution transmission electron microscopy. Our workmore » reveals several unexpected findings, including an amended registry of the surface on the bulk and strontium atoms with unusual seven-fold coordination within a typically high surface coverage of square pyramidal TiO5 units. Lastly, dielectric screening is found to play a critical role in attenuating secondary-electron generation processes from valence orbitals.« less

  3. Reconnection dynamics with secondary tearing instability in compressible Hall plasmas

    SciTech Connect (OSTI)

    Ma, Z. W. Wang, L. C.; Li, L. J.

    2015-06-15

    The dynamics of a secondary tearing instability is systematically investigated based on compressible Hall magnetohydrodynamic. It is found that in the early nonlinear phase of magnetic reconnection before onset of the secondary tearing instability, the geometry of the magnetic field in the reconnection region tends to form a Y-type structure in a weak Hall regime, instead of an X-type structure in a strong Hall regime. A new scaling law is found that the maximum reconnection rate in the early nonlinear stage is proportional to the square of the ion inertial length (γ∝d{sub i}{sup 2}) in the weak Hall regime. In the late nonlinear phase, the thin elongated current sheet associated with the Y-type geometry of the magnetic field breaks up to form a magnetic island due to a secondary tearing instability. After the onset of the secondary tearing mode, the reconnection rate is substantially boosted by the formation of the X-type geometries of magnetic field in the reconnection regions. With a strong Hall effect, the maximum reconnection rate linearly increases with the increase of the ion inertial length (γ∝d{sub i})

  4. Secondary Waste Cast Stone Waste Form Qualification Testing Plan

    SciTech Connect (OSTI)

    Westsik, Joseph H.; Serne, R. Jeffrey

    2012-09-26

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 56 million gallons of radioactive waste stored in 177 underground tanks at the Hanford Site. The WTP includes a pretreatment facility to separate the wastes into high-level waste (HLW) and low-activity waste (LAW) fractions for vitrification and disposal. The LAW will be converted to glass for final disposal at the Integrated Disposal Facility (IDF). Cast Stone – a cementitious waste form, has been selected for solidification of this secondary waste stream after treatment in the ETF. The secondary-waste Cast Stone waste form must be acceptable for disposal in the IDF. This secondary waste Cast Stone waste form qualification testing plan outlines the testing of the waste form and immobilization process to demonstrate that the Cast Stone waste form can comply with the disposal requirements. Specifications for the secondary-waste Cast Stone waste form have not been established. For this testing plan, Cast Stone specifications are derived from specifications for the immobilized LAW glass in the WTP contract, the waste acceptance criteria for the IDF, and the waste acceptance criteria in the IDF Permit issued by the State of Washington. This testing plan outlines the testing needed to demonstrate that the waste form can comply with these waste form specifications and acceptance criteria. The testing program must also demonstrate that the immobilization process can be controlled to consistently provide an acceptable waste form product. This testing plan also outlines the testing needed to provide the technical basis for understanding the long-term performance of the waste form in the disposal environment. These waste form performance data are needed to support performance assessment analyses of the long-term environmental impact of the secondary-waste Cast Stone waste form in the IDF

  5. Priority Firm Exchange .

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OR 1953 21 MW Black Canyon Payette, ID 1925 10 MW Boise River Diversion Boise, ID 1912 3 MW Bonneville Columbia, ORWA 1938 1,225 MW Chandler Yakima, WA 1956 12 MW Chief...

  6. Secondary hardening steel having improved combination of hardness and toughness

    DOE Patents [OSTI]

    Parker, Earl R.; Zackay, Victor F.; Bhat, Manjeshwar S.; Garrison, Jr., Warren M.

    1979-01-01

    A secondary hardening alloy steel composition consisting essentially of about 0.25-0.5% carbon, about 0.5-1.0% manganese, about 1.5-3.0% nickel, about 0-1.0% chromium, about 1.75-2.5% molybdenum, about 0-0.4% vanadium, and an additive selected from about 1-3% aluminum and a combination of at least about 1% aluminum and at least about 1% silicon for a combined Al+Si content of about 2-4%, the balance being iron and impurity elements. The present steel composition has the following characteristics: it exhibits a flat tempering response, it is hardenable upon tempering to a Rockwell C hardness of at least 50, and it has an improved combination of hardness vs. toughness properties after tempering in the secondary hardening range. A method of preparation is also described.

  7. Tank 241-AY-102 Secondary Liner Corrosion Evaluation - 14191

    SciTech Connect (OSTI)

    Boomer, Kayle D.; Washenfelder, Dennis J.; Johnson, Jeremy M.

    2014-01-07

    In October 2012, Washington River Protection Solutions, LLC (WRPS) determined that the primary tank of 241-AY-102 (AY-102) was leaking. A number of evaluations were performed after discovery of the leak which identified corrosion from storage of waste at the high waste temperatures as one of the major contributing factors in the failure of the tank. The propensity for corrosion of the waste on the annulus floor will be investigated to determine if it is corrosive and must be promptly removed or if it is benign and may remain in the annulus. The chemical composition of waste, the temperature and the character of the steel are important factors in assessing the propensity for corrosion. Unfortunately, the temperatures of the wastes in contact with the secondary steel liner are not known; they are estimated to range from 45 deg C to 60 deg C. It is also notable that most corrosion tests have been carried out with un-welded, stress-relieved steels, but the secondary liner in tank AY-102 was not stress-relieved. In addition, the cold weather fabrication and welding led to many problems, which required repeated softening of the metal to flatten secondary bottom during its construction. This flame treatment may have altered the microstructure of the steel.

  8. Secondary Waste Simulant Development for Cast Stone Formulation Testing

    SciTech Connect (OSTI)

    Russell, Renee L.; Westsik, Joseph H.; Rinehart, Donald E.; Swanberg, David J.; Mahoney, J.

    2015-04-01

    Washington River Protection Solutions, LLC (WRPS) funded Pacific Northwest National Laboratory (PNNL) to conduct a waste form testing program to implement aspects of the Secondary Liquid Waste Treatment Cast Stone Technology Development Plan (Ashley 2012) and the Hanford Site Secondary Waste Roadmap (PNNL 2009) related to the development and qualification of Cast Stone as a potential waste form for the solidification of aqueous wastes from the Hanford Site after the aqueous wastes are treated at the Effluent Treatment Facility (ETF). The current baseline is that the resultant Cast Stone (or grout) solid waste forms would be disposed at the Integrated Disposal Facility (IDF). Data and results of this testing program will be used in the upcoming performance assessment of the IDF and in the design and operation of a solidification treatment unit planned to be added to the ETF. The purpose of the work described in this report is to 1) develop simulants for the waste streams that are currently being fed and future WTP secondary waste streams also to be fed into the ETF and 2) prepare simulants to use for preparation of grout or Cast Stone solid waste forms for testing.

  9. Photovoltaic Systems Interconnected onto Secondary Network Distribution Systems – Success Stories

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report examines six case studies of photovoltaic (PV) systems integrated into secondary network systems. The six PV systems were chosen for evaluation because they are interconnected to secondary network systems located in four major Solar America Cities.

  10. Secondary Waste Form Down Selection Data Package – Ceramicrete

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Westsik, Joseph H.

    2011-08-31

    As part of high-level waste pretreatment and immobilized low activity waste processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed in the Integrated Disposal Facility. Currently, four waste forms are being considered for stabilization and solidification of the liquid secondary wastes. These waste forms are Cast Stone, Ceramicrete, DuraLith, and Fluidized Bed Steam Reformer. The preferred alternative will be down selected from these four waste forms. Pacific Northwest National Laboratory is developing data packages to support the down selection process. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilization and solidification of the liquid secondary wastes. The information included will be based on information available in the open literature and from data obtained from testing currently underway. This data package is for the Ceramicrete waste form. Ceramicrete is a relatively new engineering material developed at Argonne National Laboratory to treat radioactive and hazardous waste streams (e.g., Wagh 2004; Wagh et al. 1999a, 2003; Singh et al. 2000). This cement-like waste form can be used to treat solids, liquids, and sludges by chemical immobilization, microencapsulation, and/or macroencapsulation. The Ceramicrete technology is based on chemical reaction between phosphate anions and metal cations to form a strong, dense, durable, low porosity matrix that immobilizes hazardous and radioactive contaminants as insoluble phosphates and microencapsulates insoluble radioactive components and other constituents that do not form phosphates. Ceramicrete is a type of phosphate-bonded ceramic, which are also known as chemically bonded phosphate ceramics. The Ceramicrete

  11. Analysis of potential self-guarantee tests for demonstrating financial assurance by non-profit colleges, universities, and hospitals and by business firms that do not issue bonds

    SciTech Connect (OSTI)

    Bailey, P.; Dean, C.; Collier, J.; Dasappa, V.; Goldberg, W.

    1997-06-01

    The Nuclear Regulatory Commission (NRC) on December 29, 1993, promulgated self-guarantee requirements that materials licensees may use to demonstrate financial assurance for decommissioning costs. However, nonprofit colleges and universities, nonprofit hospitals, and for-profit firms that do not issue bonds are currently precluded, by their unique accounting and financial reporting systems, or by other features of their business practices, from using the financial tests for self-guarantors adopted by the NRC. This Report evaluates several alternative financial tests that might serve as the basis for self-guarantee by these three categories of licensees.

  12. Secondary waste form testing : ceramicrete phosphate bonded ceramics.

    SciTech Connect (OSTI)

    Singh, D.; Ganga, R.; Gaviria, J.; Yusufoglu, Y.

    2011-06-21

    The cleanup activities of the Hanford tank wastes require stabilization and solidification of the secondary waste streams generated from the processing of the tank wastes. The treatment of these tank wastes to produce glass waste forms will generate secondary wastes, including routine solid wastes and liquid process effluents. Liquid wastes may include process condensates and scrubber/off-gas treatment liquids from the thermal waste treatment. The current baseline for solidification of the secondary wastes is a cement-based waste form. However, alternative secondary waste forms are being considered. In this regard, Ceramicrete technology, developed at Argonne National Laboratory, is being explored as an option to solidify and stabilize the secondary wastes. The Ceramicrete process has been demonstrated on four secondary waste formulations: baseline, cluster 1, cluster 2, and mixed waste streams. Based on the recipes provided by Pacific Northwest National Laboratory, the four waste simulants were prepared in-house. Waste forms were fabricated with three filler materials: Class C fly ash, CaSiO{sub 3}, and Class C fly ash + slag. Optimum waste loadings were as high as 20 wt.% for the fly ash and CaSiO{sub 3}, and 15 wt.% for fly ash + slag filler. Waste forms for physical characterizations were fabricated with no additives, hazardous contaminants, and radionuclide surrogates. Physical property characterizations (density, compressive strength, and 90-day water immersion test) showed that the waste forms were stable and durable. Compressive strengths were >2,500 psi, and the strengths remained high after the 90-day water immersion test. Fly ash and CaSiO{sub 3} filler waste forms appeared to be superior to the waste forms with fly ash + slag as a filler. Waste form weight loss was {approx}5-14 wt.% over the 90-day immersion test. The majority of the weight loss occurred during the initial phase of the immersion test, indicative of washing off of residual unreacted

  13. Secondary plant succession on disturbed sites at Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Angerer, J.P.; Ostler, W.K.; Gabbert, W.D.; Schultz, B.W.

    1994-12-01

    This report presents the results of a study of secondary plant succession on disturbed sites created during initial site investigations in the late 1970s and early 1980s at Yucca Mountain, NV. Specific study objectives were to determine the rate and success of secondary plant succession, identify plant species found in disturbances that may be suitable for site-specific reclamation, and to identify environmental variables that influence succession on disturbed sites. During 1991 and 1992, fifty seven disturbed sites were located. Vegetation parameters, disturbance characteristics and environmental variables were measured at each site. Disturbed site vegetation parameters were compared to that of undisturbed sites to determine the status of disturbed site plant succession. Vegetation on disturbed sites, after an average of ten years, was different from undisturbed areas. Ambrosia dumosa, Chrysothamnus teretifolius, Hymenoclea salsola, Gutierrezia sarothrae, Atriplex confertifolia, Atriplex canescens, and Stephanomeria pauciflora were the most dominant species across all disturbed sites. With the exception of A. dumosa, these species were generally minor components of the undisturbed vegetation. Elevation, soil compaction, soil potassium, and amounts of sand and gravel in the soil were found to be significant environmental variables influencing the species composition and abundance of perennial plants on disturbed sites. The recovery rate for disturbed site secondary succession was estimated. Using a linear function (which would represent optimal conditions), the recovery rate for perennial plant cover, regardless of which species comprised the cover, was estimated to be 20 years. However, when a logarithmic function (which would represent probable conditions) was used, the recovery rate was estimated to be 845 years. Recommendations for future studies and site-specific reclamation of disturbances are presented.

  14. Secondary solvent cleanup using activated alumina: Laboratory development

    SciTech Connect (OSTI)

    Mailen, J.C.

    1987-01-01

    The primary cleanup of PUREX solvent removes short-chain acidic organic degradation products effectively but leaves a variety of degradation products. These materials cause problems with phase separation and retention of cations. A process using activated alumina to remove secondary degradation products received laboratory development at Oak Ridge National Laboratory using Savannah River Plant and Idaho Chemical Processing plant solvents, was further developed at Savannah River Laboratory using SRP solvent, and was tested at full scale at SRP. This paper describes the development at ORNL. 6 refs., 1 fig., 1 tab.

  15. One-dimensional modeling of secondary clarifiers for wastewater treatment

    SciTech Connect (OSTI)

    Watts, R.W.; Svoronos, S.A.; Koopman, B.

    1996-12-31

    A one-dimensional model of activated sludge secondary clarifiers with a variable dispersion coefficient dependent on concentration and feed velocity was developed. Data collected from a full-scale clarifier at the Kanapaha Water Reclamation Facility in Gainesville, FL were used to evaluate this model. Data from three experimental periods demonstrated the ability of the model to predict steady state sludge blanket levels as well as clarifier failure. The variable dispersion coefficient model outperformed other well-known models in predicting clarifier overloading. 15 refs., 1 fig., 3 tabs.

  16. NREL: Measurements and Characterization - Static Time-of-Flight Secondary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ion Mass Spectrometry (SIMS) Static Time-of-Flight Secondary Ion Mass Spectrometry (SIMS) Image of high mass resolution and mass accuracy provided by TOF SIMS We used the high mass resolution and mass accuracy of TOF SIMS to study surface cleanliness of in-oxide-coated glass after different types of isolation scribes and cleaning processes. Not all processes were equal. As-received in tin oxide was heavily contaminated with silicone oils (not shown). An acidic wash resulted in contamination

  17. Electrochemistry of Magnesium Electrolytes in Ionic Liquids for Secondary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research 23, 2014, Research Highlights Electrochemistry of Magnesium Electrolytes in Ionic Liquids for Secondary Batteries Cyclic voltammograms of neat DEME-BF4 (light gray) and 100 mM Mg(BH4)2 in DEME-BF4 (black). CV scan limits are chosen to represent the electrochemical stability window. Inset: magnified view with voltage range restricted to -1.5 to 1.5 V vs. Mg/Mg2+. Scientific Achievement Ionic liquids (ILs) have wide electrochemical stability

  18. Secondary Electron Emission from Dust and Its Effect on Charging

    SciTech Connect (OSTI)

    Saikia, B. K.; Kakati, B.; Kausik, S. S. [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur-782402, Assam (India); Bandyopadhyay, M. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar-382 428 (India)

    2011-11-29

    Hydrogen plasma is produced in a plasma chamber by striking discharge between incandescent tungsten filaments and the permanent magnetic cage [1], which is grounded. The magnetic cage has a full line cusped magnetic field geometry used to confine the plasma elements. A cylindrical Langmuir probe is used to study the plasma parameters in various discharge conditions. The charge accumulated on the dust particles is calculated using the capacitance model and the dust current is measured by the combination of a Faraday cup and an electrometer at different discharge conditions. It is found Secondary electron emission from dust having low emission yield effects the charging of dust particles in presence of high energetic electrons.

  19. A subsea pipeline comprising secondary containment and leak detection

    SciTech Connect (OSTI)

    Kaempen, C.E.

    1996-09-01

    This paper introduces a corrosion-resistant double-wall composite subsea pipe that provides the pipe with secondary containment and leak detection capability. Tables are presented that describe the pressures attainable with the mechanically coupled double-wall composite subsea pipe illustrated in several figures. A description is provided of the construction of the composite subsea pipe and the mechanical coupling assembly used to rapidly connect it during ocean deployment. The paper concludes with a series of questions and answers that provide cost and production information useful for feasibility studies that evaluate factors relating to the replacement of steel subsea pipe with one that promises improved performance.

  20. Dynamic and other secondary benefits of compressed air energy storage

    SciTech Connect (OSTI)

    Allen, R.D.; Doherty, T.J.

    1984-05-01

    Dynamic benefits of compressed air energy storage include load following, voltage regulation, provision for emergency power, and spinning reserve. Other secondary benefits include environmental acceptability and economic feasibility within the spectrum of potential energy storage methods. Geologic reservoir candidates are salt cavities, hard rock caverns and water-bearing permeable formations occurring as structural traps; the compatibility of solution-mined salt cavities with desired dynamic benefits is illustrated by positive results at Huntorf, West Germany. Air injection into and withdrawal from an aquifer has been conducted successfully at Pittsfield, Illinois. Environmental impacts are believed to be less important than corresponding impacts in rival storage technologies.

  1. TCMS Examples

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BPA - Firm NT BPA Direct Connect Load Figure 2 BPA - Secondary NT BPA Figure 3 3 rd Party - Firm PTP BPA - NT (Firm or Secondary) BPA 3 rd Party Transferor Transfer Load Figure 5...

  2. GOTHIC MODEL OF BWR SECONDARY CONTAINMENT DRAWDOWN ANALYSES

    SciTech Connect (OSTI)

    Hansen, P.N.

    2004-10-06

    This article introduces a GOTHIC version 7.1 model of the Secondary Containment Reactor Building Post LOCA drawdown analysis for a BWR. GOTHIC is an EPRI sponsored thermal hydraulic code. This analysis is required by the Utility to demonstrate an ability to restore and maintain the Secondary Containment Reactor Building negative pressure condition. The technical and regulatory issues associated with this modeling are presented. The analysis includes the affect of wind, elevation and thermal impacts on pressure conditions. The model includes a multiple volume representation which includes the spent fuel pool. In addition, heat sources and sinks are modeled as one dimensional heat conductors. The leakage into the building is modeled to include both laminar as well as turbulent behavior as established by actual plant test data. The GOTHIC code provides components to model heat exchangers used to provide fuel pool cooling as well as area cooling via air coolers. The results of the evaluation are used to demonstrate the time that the Reactor Building is at a pressure that exceeds external conditions. This time period is established with the GOTHIC model based on the worst case pressure conditions on the building. For this time period the Utility must assume the primary containment leakage goes directly to the environment. Once the building pressure is restored below outside conditions the release to the environment can be credited as a filtered release.

  3. Preconception maternal polychlorinated biphenyl concentrations and the secondary sex ratio

    SciTech Connect (OSTI)

    Taylor, Kira C. [Division of Epidemiology, Statistics and Prevention Research, National Institutes of Child Health and Development (NICHD), NIH, DHHS, 6100 Executive Blvd, Room 7B03, Rockville, MD 20852 (United States); Department of Epidemiology, 1518 Clifton Road, NE Atlanta, GA 30322 (United States); Jackson, Leila W. [Department of Epidemiology and Biostatistics, WG37, Case Western Reserve University School of Medicine, 10900 Euclid Avenue Cleveland, OH 44106-4945 (United States); Lynch, Courtney D. [Division of Epidemiology, Statistics and Prevention Research, National Institutes of Child Health and Development (NICHD), NIH, DHHS, 6100 Executive Blvd, Room 7B03, Rockville, MD 20852 (United States); Kostyniak, Paul J. [Toxicology Research Center, 134 Cary Hall, University at Buffalo, State of New York, 3434 Main St., Buffalo, NY 14214-3000 (United States); Buck Louis, Germaine M. [Division of Epidemiology, Statistics and Prevention Research, National Institutes of Child Health and Development (NICHD), NIH, DHHS, 6100 Executive Blvd, Room 7B03, Rockville, MD 20852 (United States)]. E-mail: louisg@mail.nih.gov

    2007-01-15

    The secondary sex ratio is the ratio of male to female live births and historically has ranged from 102 to 106 males to 100 females. Temporal declines have been reported in many countries prompting authors to hypothesize an environmental etiology. Blood specimens were obtained from 99 women aged 24-34 prior to attempting pregnancy and quantified for 76 polychlorinated biphenyl (PCB) congeners using dual column gas chromatography with electron capture detection. Women were prospectively followed until pregnancy or 12 cycles of trying. The odds of a male birth for three PCB groupings (total, estrogenic, anti-estrogenic) controlling for maternal characteristics were estimated using logistic regression. Among the 50 women with live births and PCB data, 26 female and 24 male infants were born (ratio 0.92). After adjusting for age and body mass index, odds of a male birth were elevated among women in the second (OR=1.29) and third (OR=1.48) tertiles of estrogenic PCBs; odds (OR=0.70) were reduced among women in the highest tertile of anti-estrogenic PCBs. All confidence intervals included one. The direction of the odds ratios in this preliminary study varied by PCB groupings, supporting the need to study specific PCB patterns when assessing environmental influences on the secondary sex ratio.

  4. A lithium electrode with a zinc substrate for secondary batteries

    SciTech Connect (OSTI)

    Matsuda, Y.; Katsuma, H.; Morita, M.

    1983-03-01

    The development of a lithium secondary battery using an organic electrolyte has been actively pursued in recent years. An efficient Li electrode is required to realize such rechargeable batteries. Some Li negatives with metal substrates have been proposed in order to obtain good efficiency of chargedischarge cycling. Especially, it is worth noting that high coulombic efficiency was achieved with an Al substrate, which forms an alloy with deposited Li during the charging period. Previously, the authors pointed out the importance of the correlation between the alloy formation of the substrate metal and the charge-discharge efficiency on the substrate. It was also found that Zn, as well as Al, is a promising substrate for secondary lithium electrodes. This paper shows the charge-discharge characteristics of the Li electrode with a Zn substrate in propylene carbonate solution containing lithium tetrafluoroborate (LiBF/sub 4/) or lithium perchlorate (LiClO/sub 4/). The results are briefly discussed by comparing the characteristics with those for the Al substrate.

  5. Method and apparatus for secondary and tertiary recovery of hydrocarbons

    SciTech Connect (OSTI)

    Rivas, N.; Beichel, R.

    1987-07-07

    This patent describes an apparatus for secondary and tertiary recovery of hydrocarbons from oil fields comprising: a. a bipropellant generator capable of producing exhaust gases at supercritical pressures and temperatures; b. transport means for carrying the exhaust gases into a well bore, at least a portion of the well bore extending into a hydrocarbon bearing formation from which hydrocarbons are to be recovered; c. means for introducing water into the transport means; and d. a water cooling jacket extending into at least the upper portion of the well bore, the center of the cooling jacket receiving the exhaust gases from the transport means, means being provided for the introduction of chemical additives through a portion of the cooling jacket. A process is described for secondary and tertiary recovery of hydrocarbons from geological formations comprising: a. providing a well bore extending at least into the strata of the geologic formation containing the hydrocarbons to be recovered; b. providing at least the upper portion of the well bore with a cooling jacket, the cooling jacket being provided with a central, open portion; c. generating gases at supercritical temperatures and pressures; d. introducing water into the supercritical gases to form steam; e. forcing the mixture of supercritical combustion gases and steam through the central open portion of the cooling jacket and the well bore into the hydrocarbon strata; and f. adding chemical additives to the mixture of combustion gases and steam below the cooling jacket.

  6. Restoration of Secondary Containment in Double Shell Tank (DST) Pits

    SciTech Connect (OSTI)

    SHEN, E.J.

    2000-10-05

    Cracks found in many of the double-shell tank (DST) pump and valve pits bring into question the ability of the pits to provide secondary containment and remain in compliance with State and Federal regulations. This study was commissioned to identify viable options for maintain/restoring secondary containment capability in these pits. The basis for this study is the decision analysis process which identifies the requirements to be met and the desired goals (decision criteria) that each option will be weighed against. A facilitated workshop was convened with individuals knowledgeable of Tank Farms Operations, engineering practices, and safety/environmental requirements. The outcome of this workshop was the validation or identification of the critical requirements, definition of the current problem, identification and weighting of the desired goals, baselining of the current repair methods, and identification of potential alternate solutions. The workshop was followed up with further investigations into the potential solutions that were identified in the workshop and through other efforts. These solutions are identified in the body of this report. Each of the potential solutions were screened against the list of requirements and only those meeting the requirements were considered viable options. To expand the field of viable options, hybrid concepts that combine the strongest features of different individual approaches were also examined. Several were identified. The decision analysis process then ranked each of the viable options against the weighted decision criteria, which resulted in a recommended solution. The recommended approach is based upon installing a sprayed on coating system.

  7. Secondary structure of rat and human amylin across force fields

    SciTech Connect (OSTI)

    Hoffmann, Kyle Quynn; McGovern, Michael; Chiu, Chi -cheng; de Pablo, Juan J.; Paci, Emanuele

    2015-07-29

    The aggregation of human amylin has been strongly implicated in the progression of Type II diabetes. This 37-residue peptide forms a variety of secondary structures, including random coils, α-helices, and β-hairpins. The balance between these structures depends on the chemical environment, making amylin an ideal candidate to examine inherent biases in force fields. Rat amylin differs from human amylin by only 6 residues; however, it does not form fibrils. Therefore it provides a useful complement to human amylin in studies of the key events along the aggregation pathway. In this work, the free energy of rat and human amylin was determined as a function of α-helix and β-hairpin content for the Gromos96 53a6, OPLS-AA/L, CHARMM22/CMAP, CHARMM22*, Amberff99sb*-ILDN, and Amberff03w force fields using advanced sampling techniques, specifically bias exchange metadynamics. This work represents a first systematic attempt to evaluate the conformations and the corresponding free energy of a large, clinically relevant disordered peptide in solution across force fields. The NMR chemical shifts of rIAPP were calculated for each of the force fields using their respective free energy maps, allowing us to quantitatively assess their predictions. We show that the predicted distribution of secondary structures is sensitive to the choice of force-field: Gromos53a6 is biased towards β-hairpins, while CHARMM22/CMAP predicts structures that are overly α-helical. OPLS-AA/L favors disordered structures. Amberff99sb*-ILDN, AmberFF03w and CHARMM22* provide the balance between secondary structures that is most consistent with available experimental data. In contrast to previous reports, our findings suggest that the equilibrium conformations of human and rat amylin are remarkably similar, but that subtle differences arise in transient alpha-helical and beta-strand containing structures that the human peptide can more readily adopt. We hypothesize that these transient states enable

  8. Secondary structure of rat and human amylin across force fields

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hoffmann, Kyle Quynn; McGovern, Michael; Chiu, Chi -cheng; de Pablo, Juan J.; Paci, Emanuele

    2015-07-29

    The aggregation of human amylin has been strongly implicated in the progression of Type II diabetes. This 37-residue peptide forms a variety of secondary structures, including random coils, α-helices, and β-hairpins. The balance between these structures depends on the chemical environment, making amylin an ideal candidate to examine inherent biases in force fields. Rat amylin differs from human amylin by only 6 residues; however, it does not form fibrils. Therefore it provides a useful complement to human amylin in studies of the key events along the aggregation pathway. In this work, the free energy of rat and human amylin wasmore » determined as a function of α-helix and β-hairpin content for the Gromos96 53a6, OPLS-AA/L, CHARMM22/CMAP, CHARMM22*, Amberff99sb*-ILDN, and Amberff03w force fields using advanced sampling techniques, specifically bias exchange metadynamics. This work represents a first systematic attempt to evaluate the conformations and the corresponding free energy of a large, clinically relevant disordered peptide in solution across force fields. The NMR chemical shifts of rIAPP were calculated for each of the force fields using their respective free energy maps, allowing us to quantitatively assess their predictions. We show that the predicted distribution of secondary structures is sensitive to the choice of force-field: Gromos53a6 is biased towards β-hairpins, while CHARMM22/CMAP predicts structures that are overly α-helical. OPLS-AA/L favors disordered structures. Amberff99sb*-ILDN, AmberFF03w and CHARMM22* provide the balance between secondary structures that is most consistent with available experimental data. In contrast to previous reports, our findings suggest that the equilibrium conformations of human and rat amylin are remarkably similar, but that subtle differences arise in transient alpha-helical and beta-strand containing structures that the human peptide can more readily adopt. We hypothesize that these transient states

  9. Secondary ion collection and transport system for ion microprobe

    DOE Patents [OSTI]

    Ward, James W.; Schlanger, Herbert; McNulty, Jr., Hugh; Parker, Norman W.

    1985-01-01

    A secondary ion collection and transport system, for use with an ion microprobe, which is very compact and occupies only a small working distance, thereby enabling the primary ion beam to have a short focal length and high resolution. Ions sputtered from the target surface by the primary beam's impact are collected between two arcuate members having radii of curvature and applied voltages that cause only ions within a specified energy band to be collected. The collected ions are accelerated and focused in a transport section consisting of a plurality of spaced conductive members which are coaxial with and distributed along the desired ion path. Relatively high voltages are applied to alternate transport sections to produce accelerating electric fields sufficient to transport the ions through the section to an ion mass analyzer, while lower voltages are applied to the other transport sections to focus the ions and bring their velocity to a level compatible with the analyzing apparatus.

  10. Apparatus and method for controlling the secondary injection of fuel

    DOE Patents [OSTI]

    Martin, Scott M.; Cai, Weidong; Harris, Jr., Arthur J.

    2013-03-05

    A combustor (28) for a gas turbine engine is provided comprising a primary combustion chamber (30) for combusting a first fuel to form a combustion flow stream (50) and a transition piece (32) located downstream from the primary combustion chamber (30). The transition piece (32) comprises a plurality of injectors (66) located around a circumference of the transition piece (32) for injecting a second fuel into the combustion flow stream (50). The injectors (66) are effective to create a radial temperature profile (74) at an exit (58) of the transition piece (32) having a reduced coefficient of variation relative to a radial temperature profile (64) at an inlet (54) of the transition piece (32). Methods for controlling the temperature profile of a secondary injection are also provided.

  11. Project W320 heel jet secondary catch mechanism lateral load test - test report

    SciTech Connect (OSTI)

    Bellomy, J.R.

    1994-12-01

    This test report summarizes testing activities and documents the results of the lateral load test performed on the Heel Jet Secondary Catch Mechanism.

  12. DOE Announces Webinars on Teaching Energy in Post-Secondary Education...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Teaching Energy in Post-Secondary Education, Energy Efficiency in Restaurants, and More DOE ... July 10: Live Webinar on Better Buildings Challenge: Multifamily Update Webinar ...

  13. Natural Gas Transportation Resiliency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stations - Capacity firm versus peak day - Redundancy - Reliability * Pipeline(s) - Nominal Design Capacity (FERC 567) - Load factor by segment - Age and type of pipe - Level ...

  14. Secondary electron emission from lithium and lithium compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Capece, A. M.; Patino, M. I.; Raitses, Y.; Koel, B. E.

    2016-07-06

    In this work, measurements of electron-induced secondary electron emission ( SEE) yields of lithium as a function of composition are presented. The results are particularly relevant for magnetic fusion devices such as tokamaks, field-reversed configurations, and stellarators that consider Li as a plasma-facing material for improved plasma confinement. SEE can reduce the sheath potential at the wall and cool electrons at the plasma edge, resulting in large power losses. These effects become significant as the SEE coefficient, γe, approaches one, making it imperative to maintain a low yield surface. This work demonstrates that the yield from Li strongly depends onmore » chemical composition and substantially increases after exposure to oxygen and water vapor. The total yield was measured using a retarding field analyzer in ultrahigh vacuum for primary electron energies of 20-600 eV. The effect of Li composition was determined by introducing controlled amounts of O2 and H2O vapor while monitoring film composition with Auger electron spectroscopy and temperature programmed desorption. The results show that the energy at which γe = 1 decreases with oxygen content and is 145 eV for a Li film that is 17% oxidized and drops to less than 25 eV for a fully oxidized film. This work has important implications for laboratory plasmas operating under realistic vacuum conditions in which oxidation significantly alters the electron emission properties of Li walls. Published by AIP Publishing.« less

  15. Control of cerium oxidation state through metal complex secondary structures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Levin, Jessica R.; Dorfner, Walter L.; Carroll, Patrick J.; Schelter, Eric J.

    2015-08-11

    A series of alkali metal cerium diphenylhydrazido complexes, Mx(py)y[Ce(PhNNPh)4], M = Li, Na, and K, x = 4 (Li and Na) or 5 (K), and y = 4 (Li), 8 (Na), or 7 (K), were synthesized to probe how a secondary coordination sphere would modulate electronic structures at a cerium cation. The resulting electronic structures of the heterobimetallic cerium diphenylhydrazido complexes were found to be strongly dependent on the identity of the alkali metal cations. When M = Li+ or Na+, the cerium(III) starting material was oxidized with concomitant reduction of 1,2-diphenylhydrazine to aniline. Reduction of 1,2-diphenylhydrazine was not observedmore » when M = K+, and the complex remained in the cerium(III) oxidation state. Oxidation of the cerium(III) diphenylhydrazido complex to the Ce(IV) diphenylhydrazido one was achieved through a simple cation exchange reaction of the alkali metals. As a result, UV-Vis spectroscopy, FTIR spectroscopy, electrochemistry, magnetic susceptibility, and DFT studies were used to probe the oxidation state and the electronic changes that occurred at the metal centre.« less

  16. State waste discharge permit application: 400 Area secondary cooling water

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This document constitutes the Washington Administrative Code 173-216 State Waste Discharge Permit Application that serves as interim compliance as required by the Consent Order DE 91NM-177, for the 400 Area Secondary Cooling Water stream. As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permitting Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered in to Consent Order DE 91NM-177. The Consent Order DE 91NM-177 requires a series of permitting activities for liquid effluent discharges.

  17. Characterization of secondary phases in modified vertical bridgman growth czt

    SciTech Connect (OSTI)

    Duff, Martine

    2009-07-10

    CdZnTe or 'CZT' crystals are highly suitable for use as a room temperature based spectrometer for the detection and characterization of gamma radiation. Over the last decade, the methods for growing high quality CZT have improved the quality of the produced crystals however there are material features that can influence the performance of these materials as radiation detectors. For example, various structural heterogeneities within the CZT crystals, such as twinning, pipes, grain boundaries (polycrystallinity), and secondary phases (SP) can have a negative impact on the detector performance. In this study, a CZT material was grown by the modified vertical Bridgman growth (MVB) method with zone leveled growth without excess Te in the melt. Visual observations of material from the growth of this material revealed significant voids and SP. Three samples from this material was analyzed using various analytical techniques to evaluate its electrical properties, purity and detector performance as radiation spectrometers and to determine the morphology, dimension and elemental/structural composition of one of the SP in this material. This material was found to have a high resistivity but poor radiation spectrometer performance. It had SP that were rich in polycrystalline aluminum oxide (Al{sub 2}O{sub 3}), metallic Te and polycrystalline CdZnTe and 15 to 50 {micro}m in diameter. Bulk elemental analyses of sister material from elsewhere in the boule did not contain high levels of Al so there is considerable elemental impurity heterogeneity within the boule from this growth.

  18. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  19. SECONDARY WASTE MANAGEMENT FOR HANFORD EARLY LOW ACTIVITY WASTE VITRIFICATION

    SciTech Connect (OSTI)

    UNTERREINER BJ

    2008-07-18

    More than 200 million liters (53 million gallons) of highly radioactive and hazardous waste is stored at the U.S. Department of Energy's Hanford Site in southeastern Washington State. The DOE's Hanford Site River Protection Project (RPP) mission includes tank waste retrieval, waste treatment, waste disposal, and tank farms closure activities. This mission will largely be accomplished by the construction and operation of three large treatment facilities at the Waste Treatment and Immobilization Plant (WTP): (1) a Pretreatment (PT) facility intended to separate the tank waste into High Level Waste (HLW) and Low Activity Waste (LAW); (2) a HLW vitrification facility intended to immobilize the HLW for disposal at a geologic repository in Yucca Mountain; and (3) a LAW vitrification facility intended to immobilize the LAW for shallow land burial at Hanford's Integrated Disposal Facility (IDF). The LAW facility is on target to be completed in 2014, five years prior to the completion of the rest of the WTP. In order to gain experience in the operation of the LAW vitrification facility, accelerate retrieval from single-shell tank (SST) farms, and hasten the completion of the LAW immobilization, it has been proposed to begin treatment of the low-activity waste five years before the conclusion of the WTP's construction. A challenge with this strategy is that the stream containing the LAW vitrification facility off-gas treatment condensates will not have the option of recycling back to pretreatment, and will instead be treated by the Hanford Effluent Treatment Facility (ETF). Here the off-gas condensates will be immobilized into a secondary waste form; ETF solid waste.

  20. Investigation of polymeric solid-electrolyte cells, carried out during a nominal three-year period, focused on the rechargeable lithium battery. Final report, 15 July 1985-30 October 1988

    SciTech Connect (OSTI)

    Owens, B.B.

    1989-01-23

    The present study investigated solid state secondary lithium cell systems, especially Li/PEO,LiCF/sub 3/SO/sub 3//V/sub 6/O/sub 13/. The material necessary to fabricate thin film (100-200 micron) cells were characterized and the behavior of the cells was investigated as a function of cycle number, humidity, overcharge, temperature and rate. Cell performance looked promising with continued cycling. Results were reported in twenty-one technical publications.

  1. Property:Nominal Voltage | Open Energy Information

    Open Energy Info (EERE)

    Farms + 480 + Distributed Generation StudyPatterson Farms CHP System Using Renewable Biogas + 480 + Distributed Generation StudySUNY Buffalo + 480 + Distributed Generation...

  2. FinalTestimonyLaneNominationStatement.pdf

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    STATEMENT OF JEFF LANE, NOMINEE TO BE AN ASSISTANT SECRETARY OF ENERGY, CONGRESSIONAL AND INTERGOVERNMENTAL AFFAIRS, DEPARTMENT OF ENERGY MARCH 17, 2010 Chairman Bingaman, Ranking...

  3. Fact #729: May 28, 2012 Secondary Household Vehicles Travel Fewer Miles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 9: May 28, 2012 Secondary Household Vehicles Travel Fewer Miles Fact #729: May 28, 2012 Secondary Household Vehicles Travel Fewer Miles When a household has more than one vehicle, the secondary vehicles travel fewer miles than the primary vehicle. In a two-vehicle household, the second vehicle travels less than half of the miles that the primary vehicle travels in a day. In a six-vehicle household, the sixth vehicle travels fewer than five miles a day. Daily Vehicle

  4. Interconnecting PV on New York City's Secondary Network Distribution System

    SciTech Connect (OSTI)

    K. Anderson; M. Coddington; K. Burman; S. Hayter; B. Kroposki; and A. Watson

    2009-11-30

    The U.S. Department of Energy (DOE) has teamed with cities across the country through the Solar America Cities (SAC) partnership program to help reduce barriers and accelerate implementation of solar energy. The New York City SAC team is a partnership between the City University of New York (CUNY), the New York City Mayor s Office of Long-term Planning and Sustainability, and the New York City Economic Development Corporation (NYCEDC).The New York City SAC team is working with DOE s National Renewable Energy Laboratory (NREL) and Con Edison, the local utility, to develop a roadmap for photovoltaic (PV) installations in the five boroughs. The city set a goal to increase its installed PV capacity from1.1 MW in 2005 to 8.1 MW by 2015 (the maximum allowed in 2005). A key barrier to reaching this goal, however, is the complexity of the interconnection process with the local utility. Unique challenges are associated with connecting distributed PV systems to secondary network distribution systems (simplified to ???¢????????networks???¢??????? in this report). Although most areas of the country use simpler radial distribution systems to distribute electricity, larger metropolitan areas like New York City typically use networks to increase reliability in large load centers. Unlike the radial distribution system, where each customer receives power through a single line, a network uses a grid of interconnected lines to deliver power to each customer through several parallel circuits and sources. This redundancy improves reliability, but it also requires more complicated coordination and protection schemes that can be disrupted by energy exported from distributed PV systems. Currently, Con Edison studies each potential PV system in New York City to evaluate the system s impact on the network, but this is time consuming for utility engineers and may delay the customer s project or add cost for larger installations. City leaders would like to streamline

  5. Secondary PDZ domain-binding site on class B plexins enhances...

    Office of Scientific and Technical Information (OSTI)

    Title: Secondary PDZ domain-binding site on class B plexins enhances the affinity for PDZ-RhoGEF Authors: Pascoe, Heath G. ; Gutowski, Stephen ; Chen, Hua ; Brautigam, Chad A. ; ...

  6. TOXICOLOGICAL AND STRUCTURAL CONSEQUENCES FROM SODIUM-WATER REACTION IN CELL CONTAINING THE SECONDARY SODIUM TANK

    SciTech Connect (OSTI)

    MARUSICH RM

    2008-06-25

    The analysis will show the consequences should the solid sodium in the Secondary Sodium Tank react with a presumed layer of water in the cell. The Peer Review Checklist is attached.

  7. An overview of the geology and secondary mineralogy of the high...

    Open Energy Info (EERE)

    the geology and secondary mineralogy of the high temperature geothermal system in Dixie Valley, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  8. Small-angle X-ray scattering: a bridge between RNA secondary...

    Office of Scientific and Technical Information (OSTI)

    Small-angle X-ray scattering: a bridge between RNA secondary structures and three-dimensional topological structures Prev Next Title: Small-angle X-ray scattering: a bridge ...

  9. DOE Announces Webinars on Teaching Energy in Post-Secondary Education,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency in Restaurants, and More | Department of Energy Teaching Energy in Post-Secondary Education, Energy Efficiency in Restaurants, and More DOE Announces Webinars on Teaching Energy in Post-Secondary Education, Energy Efficiency in Restaurants, and More June 26, 2014 - 8:31am Addthis EERE offers webinars to the public on a range of subjects, from adopting the latest energy efficiency and renewable energy technologies, to training for the clean energy workforce. Webinars are

  10. Dereplicating and spatial mapping of secondary metabolites from fungal cultures in situ

    SciTech Connect (OSTI)

    Kertesz, Vilmos; Van Berkel, Gary J.; Sica, Vincent P.; Raja, Huzefa A.; El-Elimat, Tamam; Oberlies, Nicholas H.; Pearce, Cedric J.

    2015-07-30

    Ambient ionization techniques coupled to mass spectrometry have recently become prevalent in natural product research due to their ability to examine secondary metabolites in situ. Identifying, mapping, and monitoring secondary metabolites directly on an organism provides invaluable spatial and temporal details that are lost through traditional extraction processes. Most ambient ionization techniques do not collect mutually supportive data, such as chromatographic retention times and/or UV/VIS spectra, and this can limit the ability to identify certain metabolites, such as differentiating isomers. To overcome this, the droplet liquid microjunction surface sampling probe (droplet LMJ SSP) was coupled with UPLC PDA HRMS MS/MS, thus providing separation, retention times, and UV/VIS data used in traditional dereplication protocols. By capturing these mutually supportive data, the identity of secondary metabolites could be confidently and rapidly assigned in situ. Using the droplet LMJ SSP, a protocol was constructed to analyze the secondary metabolite profile of fungal cultures directly without any sample preparation. The results demonstrate that fungal cultures can be dereplicated from the Petri dish, thus identifying secondary metabolites, including isomers, and confirming them against reference standards. As a result, heat maps, similar to mass spectrometry imaging, can be used to ascertain the location and relative concentration of secondary metabolites directly on the surface and/or surroundings of a fungal culture.

  11. Secondary island formation in collisional and collisionless kinetic simulations of magnetic reconnection

    SciTech Connect (OSTI)

    Dayton, William S; Roytershteyn, Vadim; Gary, Peter; Yin, L; Albright, B J; Bowers, K J; Karimabadi, H

    2009-01-01

    The evolution of magnetic reconnection in large-scale systems often gives rise to extended current layers that are unstable to the formation of secondary magnetic islands. The role of these islands in the reconnection process and the conditions under which they form remains a subject of debate. In this work, we benchmark two different kinetic particle-in-cell codes to address the formation of secondary islands for several types of global boundary conditions. The influence on reconnection is examined for a range of conditions and collisionality limits. Although secondary islands are observed in all cases, their influence on reconnection may be different depending on the regime. In the collisional limit, the secondary islands playa key role in breaking away from the Sweet-Parker scaling and enabling faster reconnection. In the collisionless limit, their formation is one mechanism for controlling the length of the diffusion region. In both limits, the onset of secondary islands leads to a time dependent behavior in the reconnection rate. In all cases considered, the number of secondary islands increases for larger systems.

  12. Dereplicating and spatial mapping of secondary metabolites from fungal cultures in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kertesz, Vilmos; Van Berkel, Gary J.; Sica, Vincent P.; Raja, Huzefa A.; El-Elimat, Tamam; Oberlies, Nicholas H.; Pearce, Cedric J.

    2015-07-30

    Ambient ionization techniques coupled to mass spectrometry have recently become prevalent in natural product research due to their ability to examine secondary metabolites in situ. Identifying, mapping, and monitoring secondary metabolites directly on an organism provides invaluable spatial and temporal details that are lost through traditional extraction processes. Most ambient ionization techniques do not collect mutually supportive data, such as chromatographic retention times and/or UV/VIS spectra, and this can limit the ability to identify certain metabolites, such as differentiating isomers. To overcome this, the droplet liquid microjunction surface sampling probe (droplet LMJ SSP) was coupled with UPLC PDA HRMS MS/MS,more » thus providing separation, retention times, and UV/VIS data used in traditional dereplication protocols. By capturing these mutually supportive data, the identity of secondary metabolites could be confidently and rapidly assigned in situ. Using the droplet LMJ SSP, a protocol was constructed to analyze the secondary metabolite profile of fungal cultures directly without any sample preparation. The results demonstrate that fungal cultures can be dereplicated from the Petri dish, thus identifying secondary metabolites, including isomers, and confirming them against reference standards. As a result, heat maps, similar to mass spectrometry imaging, can be used to ascertain the location and relative concentration of secondary metabolites directly on the surface and/or surroundings of a fungal culture.« less

  13. Imaging survey of subsystems in secondary components to nearby southern dwarfs

    SciTech Connect (OSTI)

    Tokovinin, Andrei

    2014-10-01

    To improve the statistics of hierarchical multiplicity, secondary components of wide nearby binaries with solar-type primaries were surveyed at the SOAR telescope for evaluating the frequency of subsystems. Images of 17 faint secondaries were obtained with the SOAR Adaptive Module that improved the seeing; one new 0.''2 binary was detected. For all targets, photometry in the g', i', z' bands is given. Another 46 secondaries were observed by speckle interferometry, resolving 7 close subsystems. Adding literature data, the binarity of 95 secondary components is evaluated. We found that the detection-corrected frequency of secondary subsystems with periods in the well-surveyed range from 10{sup 3} to 10{sup 5} days is 0.21 ± 0.06—same as the normal frequency of such binaries among solar-type stars, 0.18. This indicates that wide binaries are unlikely to be produced by dynamical evolution of N-body systems, but are rather formed by fragmentation.

  14. Effect of secondary emission on the argon plasma afterglow with large dust density

    SciTech Connect (OSTI)

    Denysenko, I. B.; Azarenkov, N. A.; Burmaka, G. P.; Stefanovi?, I.

    2015-02-15

    A zero-dimensional, space-averaged model for argon plasma afterglow with large dust density is developed. In the model, three groups of electrons in the plasma afterglow are assumed: (i) thermal electrons with Maxwellian distribution, (ii) energetic electrons generated by metastable-metastable collisions (metastable pooling), and (iii) secondary electrons generated at collisions of ions with the electrodes, which have sufficiently large negative voltages in the afterglow. The model calculates the time-dependencies for electron densities in plasma afterglow based on experimental decay times for metastable density and electrode bias. The effect of secondary emission on electron density in the afterglow is estimated by varying secondary emission yields. It is found that this effect is less important than metastable pooling. The case of dust-free plasma afterglow is considered also, and it is found that in the afterglow the effect of secondary emission may be more important than metastable pooling. The secondary emission may increase thermal electron density n{sub e} in dust-free and dusty plasma afterglows on a few ten percentages. The calculated time dependencies for n{sub e} in dust-free and dusty plasma afterglows describe well the experimental results.

  15. Review of Potential Candidate Stabilization Technologies for Liquid and Solid Secondary Waste Streams

    SciTech Connect (OSTI)

    Pierce, Eric M.; Mattigod, Shas V.; Westsik, Joseph H.; Serne, R. Jeffrey; Icenhower, Jonathan P.; Scheele, Randall D.; Um, Wooyong; Qafoku, Nikolla

    2010-01-30

    Pacific Northwest National Laboratory has initiated a waste form testing program to support the long-term durability evaluation of a waste form for secondary wastes generated from the treatment and immobilization of Hanford radioactive tank wastes. The purpose of the work discussed in this report is to identify candidate stabilization technologies and getters that have the potential to successfully treat the secondary waste stream liquid effluent, mainly from off-gas scrubbers and spent solids, produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Down-selection to the most promising stabilization processes/waste forms is needed to support the design of a solidification treatment unit (STU) to be added to the Effluent Treatment Facility (ETF). To support key decision processes, an initial screening of the secondary liquid waste forms must be completed by February 2010.

  16. Note: A simple charge neutralization method for measuring the secondary electron yield of insulators

    SciTech Connect (OSTI)

    Weng, Ming Cao, Meng; Zhao, Hong-Juan; Zhang, Hai-Bo

    2014-03-15

    We report on a simple and effective charge neutralization method for measuring the total electron-induced secondary electron yield of insulators in a measurement system with a single pulsed electron gun. In this method, the secondary electron collector is negatively biased with respect to the sample to force some emitted secondary electrons to return to the sample surface and therefore to neutralize positive charges accumulated in the sample during the previous measurement. The adequate negative bias is determined and the equilibrium state of negative charging is discussed. The efficacy of the method is demonstrated by the measured electron yields in the cases with and without charge neutralization and by comparison with existing electron yield data of polyimide.

  17. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  18. SU-E-T-304: Study of Secondary Neutrons From Uniform Scanning Proton Beams

    SciTech Connect (OSTI)

    Islam, M; Zheng, Y; Benton, E

    2014-06-01

    Purpose: Secondary neutrons are unwanted byproducts from proton therapy and exposure from secondary radiation during treatment could increase risk of developing a secondary cancer later in a patient's lifetime. The purpose of this study is to investigate secondary neutrons from uniform scanning proton beams under various beam conditions using both measurements and Monte Carlo simulations. Methods: CR-39 Plastic Track Nuclear Detectors (PNTD) were used for the measurement. CR-39 PNTD has tissue like sensitivity to the secondary neutrons but insensitive to the therapeutic protons. In this study, we devised two experimental conditions: a) hollow-phantom; phantom is bored with a hollow cylinder along the direction of the beam so that the primary proton passes through the phantom without interacting with the phantom material, b) cylindrical-phantom; a solid cylinder of diameter close to the beam diameter is placed along the beam path. CR-39 PNTDs were placed laterally inside a 60X20X35 cm3 phantom (hollow-phantom) and in air (cylindrical-phantom) at various angles with respect to the primary beam axis. We studied for three different proton energies (78 MeV, 162 MeV and 226 MeV), using a 4 cm modulation width and 5cm diameter brass aperture for the entire experiment and simulation. A comparison of the experiment was performed using the Monte Carlo code FLUKA. Results: The measured secondary neutron dose equivalent per therapeutic primary proton dose (H/D) ranges from 2.1 ± 0.2 to 25.42 ± 2.3 mSv/Gy for the hollow phantom study, and 2.7 ± 0.3 to 46.4 ± 3.4 mSv/Gy for the cylindrical phantom study. Monte Carlo simulations predicated neutron dose equivalent from measurements within a factor of 5. Conclusion: The study suggests that the production of external neutrons is significantly higher than the production of internal neutrons.

  19. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, Robert H. (Bethany, CT); Brown, Stephen H. (East Haven, CT)

    1989-01-01

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  20. DuraLith Alkali-Aluminosilicate Geopolymer Waste Form Testing for Hanford Secondary Waste

    SciTech Connect (OSTI)

    Gong, W. L.; Lutz, Werner; Pegg, Ian L.

    2011-07-21

    The primary objective of the work reported here was to develop additional information regarding the DuraLith alkali aluminosilicate geopolymer as a waste form for liquid secondary waste to support selection of a final waste form for the Hanford Tank Waste Treatment and Immobilization Plant secondary liquid wastes to be disposed in the Integrated Disposal Facility on the Hanford Site. Testing focused on optimizing waste loading, improving waste form performance, and evaluating the robustness of the waste form with respect to waste variability.

  1. Method for detecting water equivalent of snow using secondary cosmic gamma radiation

    DOE Patents [OSTI]

    Condreva, K.J.

    1997-01-14

    Water equivalent of accumulated snow determination by measurement of secondary background cosmic radiation attenuation by the snowpack. By measuring the attenuation of 3-10 MeV secondary gamma radiation it is possible to determine the water equivalent of snowpack. The apparatus is designed to operate remotely to determine the water equivalent of snow in areas which are difficult or hazardous to access during winter, accumulate the data as a function of time and transmit, by means of an associated telemetry system, the accumulated data back to a central data collection point for analysis. The electronic circuitry is designed so that a battery pack can be used to supply power. 4 figs.

  2. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, R.H.; Brown, S.H.

    1989-10-17

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  3. Method for detecting water equivalent of snow using secondary cosmic gamma radiation

    DOE Patents [OSTI]

    Condreva, Kenneth J.

    1997-01-01

    Water equivalent of accumulated snow determination by measurement of secondary background cosmic radiation attenuation by the snowpack. By measuring the attentuation of 3-10 MeV secondary gamma radiation it is possible to determine the water equivalent of snowpack. The apparatus is designed to operate remotely to determine the water equivalent of snow in areas which are difficult or hazardous to access during winter, accumulate the data as a function of time and transmit, by means of an associated telemetry system, the accumulated data back to a central data collection point for analysis. The electronic circuitry is designed so that a battery pack can be used to supply power.

  4. Secondary materials: Engineering properties, environmental consequences, and social and economic impacts. Final report

    SciTech Connect (OSTI)

    Breslin, V.; Reaven, S.; Schwartz, M.; Swanson, L.; Zweig, M.; Bortman, M.; Schubel, J.

    1993-08-01

    This report investigates two secondary materials, plastic lumber made from mixed plastic waste, and cement blocks and structures made with incinerator ash. Engineering properties, environmental impacts, and energy costs and savings of these secondary materials are compared to standard lumber products and cement blocks. Market capacity and social acceptance of plastic lumber and stabilized ash products are analyzed. These secondary materials apparently have potential markets; however, their economic value is primarily that they will not take up landfill space. For plastic lumber and stabilized incinerator ash products, marine and highway construction seem ideal public works applications. Incinerator ash may be suitable to use in seawalls, jetties, fishing reefs, highway barriers, and roadbed applications. Docks, piers, highway sound barriers, parking stops, and park furniture may all be made from plastic lumber. To encourage public acceptance and improve the market potential of secondary materials, these activities could be beneficial: industry should emphasize developing useful, long-lived products; industry and governments should create product performance criteria; government should provide rigorous testing and demonstration programs; and government and industry should cooperate to improve public outreach and educational programs.

  5. Optical Properties of Mixed Black Carbon, Inorganic and Secondary Organic Aerosols

    SciTech Connect (OSTI)

    Paulson, S E

    2012-05-30

    Summarizes the achievements of the project, which are divided into four areas: 1) Optical properties of secondary organic aerosols; 2) Development and of a polar nephelometer to measure aerosol optical properties and theoretical approaches to several optical analysis problems, 3) Studies on the accuracy of measurements of absorbing carbon by several methods, and 4) Environmental impacts of biodiesel.

  6. A bipolar integrator for secondary emission profile monitors at the SSCL

    SciTech Connect (OSTI)

    Datte, P.; Beechy, D.; Webber, R.

    1994-01-01

    Many invasive techniques for monitoring beam profile and intensity require secondary emission signals in order to make the measurement. Signal acquisition and processing can take many forms. This paper describes a bipolar integration technique which uses the Burr-Brown ACF2101 Dual Switched Integrator chip and applications for accelerator beam instrumentation.

  7. Emission of secondary particles from metals and insulators at impact of slow highly charged ions

    SciTech Connect (OSTI)

    Schenkel, T.

    1996-10-31

    Emission of secondary electrons and ions from clean Au, CxHy-Au, and SiO{sub 2} surfaces at impact of slow (v{approx}0.3 v{sub Bohr}) ions were measured as function of incident ion charge for 1+{le}q{le}75+. Electron yields from thermal SiO{sub 2} films (150 mm on Si) were found to be lower than those from the other two for q>3+. Yields of negative secondary ions from SiO{sub 2} and CxHy-Au were recorded in parallel with electron emission data and exhibit a q{sub 4} dependency on incident ion charge. Direct comparison of collisional and electronic contributions to secondary ion production from SiO{sub 2} films using a beam of charge state equilibrated Xe (at 2.75 keV/u) shows positive and negative secondary ion yield increases with incident ion charge of >400. Results are discussed in relation to key signatures of electronic sputtering by Coulomb explosions.

  8. Direct and secondary nuclear excitation with x-ray free-electron lasers

    SciTech Connect (OSTI)

    Gunst, Jonas; Wu, Yuanbin Kumar, Naveen; Keitel, Christoph H.; Pálffy, Adriana

    2015-11-15

    The direct and secondary nuclear excitation produced by an x-ray free electron laser when interacting with a solid-state nuclear target is investigated theoretically. When driven at the resonance energy, the x-ray free electron laser can produce direct photoexcitation. However, the dominant process in that interaction is the photoelectric effect producing a cold and very dense plasma in which also secondary processes such as nuclear excitation by electron capture may occur. We develop a realistic theoretical model to quantify the temporal dynamics of the plasma and the magnitude of the secondary excitation therein. Numerical results show that depending on the nuclear transition energy and the temperature and charge states reached in the plasma, secondary nuclear excitation by electron capture may dominate the direct photoexcitation by several orders of magnitude, as it is the case for the 4.8 keV transition from the isomeric state of {sup 93}Mo, or it can be negligible, as it is the case for the 14.4 keV Mössbauer transition in {sup 57}Fe. These findings are most relevant for future nuclear quantum optics experiments at x-ray free electron laser facilities.

  9. Metallic sulfide additives for positive electrode material within a secondary electrochemical cell

    DOE Patents [OSTI]

    Walsh, William J.; McPheeters, Charles C.; Yao, Neng-ping; Koura, Kobuyuki

    1976-01-01

    An improved active material for use within the positive electrode of a secondary electrochemical cell includes a mixture of iron disulfide and a sulfide of a polyvalent metal. Various metal sulfides, particularly sulfides of cobalt, nickel, copper, cerium and manganese, are added in minor weight proportion in respect to iron disulfide for improving the electrode performance and reducing current collector requirements.

  10. Shielding implications for secondary neutrons and photons produced within the patient during IMPT

    SciTech Connect (OSTI)

    DeMarco, J.; Kupelian, P.; Santhanam, A.; Low, D.

    2013-07-15

    Purpose: Intensity modulated proton therapy (IMPT) uses a combination of computer controlled spot scanning and spot-weight optimized planning to irradiate the tumor volume uniformly. In contrast to passive scattering systems, secondary neutrons and photons produced from inelastic proton interactions within the patient represent the major source of emitted radiation during IMPT delivery. Various published studies evaluated the shielding considerations for passive scattering systems but did not directly address secondary neutron production from IMPT and the ambient dose equivalent on surrounding occupational and nonoccupational work areas. Thus, the purpose of this study was to utilize Monte Carlo simulations to evaluate the energy and angular distributions of secondary neutrons and photons following inelastic proton interactions within a tissue-equivalent phantom for incident proton spot energies between 70 and 250 MeV.Methods: Monte Carlo simulation methods were used to calculate the ambient dose equivalent of secondary neutrons and photons produced from inelastic proton interactions in a tissue-equivalent phantom. The angular distribution of emitted neutrons and photons were scored as a function of incident proton energy throughout a spherical annulus at 1, 2, 3, 4, and 5 m from the phantom center. Appropriate dose equivalent conversion factors were applied to estimate the total ambient dose equivalent from secondary neutrons and photons.Results: A reference distance of 1 m from the center of the patient was used to evaluate the mean energy distribution of secondary neutrons and photons and the resulting ambient dose equivalent. For an incident proton spot energy of 250 MeV, the total ambient dose equivalent (3.6 Multiplication-Sign 10{sup -3} mSv per proton Gy) was greatest along the direction of the incident proton spot (0 Degree-Sign -10 Degree-Sign ) with a mean secondary neutron energy of 71.3 MeV. The dose equivalent decreased by a factor of 5 in the

  11. A preliminary categorization of end-of-life electrical and electronic equipment as secondary metal resources

    SciTech Connect (OSTI)

    Oguchi, Masahiro; Murakami, Shinsuke; Sakanakura, Hirofumi; Kida, Akiko; Kameya, Takashi

    2011-09-15

    Highlights: > End-of-life electrical and electronic equipment (EEE) as secondary metal resources. > The content and the total amount of metals in specific equipment are both important. > We categorized 21 EEE types from contents and total amounts of various metals. > Important equipment types as secondary resources were listed for each metal kind. > Collectability and possible collection systems of various EEE types were discussed. - Abstract: End-of-life electrical and electronic equipment (EEE) has recently received attention as a secondary source of metals. This study examined characteristics of end-of-life EEE as secondary metal resources to consider efficient collection and metal recovery systems according to the specific metals and types of EEE. We constructed an analogy between natural resource development and metal recovery from end-of-life EEE and found that metal content and total annual amount of metal contained in each type of end-of-life EEE should be considered in secondary resource development, as well as the collectability of the end-of-life products. We then categorized 21 EEE types into five groups and discussed their potential as secondary metal resources. Refrigerators, washing machines, air conditioners, and CRT TVs were evaluated as the most important sources of common metals, and personal computers, mobile phones, and video games were evaluated as the most important sources of precious metals. Several types of small digital equipment were also identified as important sources of precious metals; however, mid-size information and communication technology (ICT) equipment (e.g., printers and fax machines) and audio/video equipment were shown to be more important as a source of a variety of less common metals. The physical collectability of each type of EEE was roughly characterized by unit size and number of end-of-life products generated annually. Current collection systems in Japan were examined and potentially appropriate collection methods

  12. Tracking multiple generation and suppression of secondary electrons on periodic triangular surface

    SciTech Connect (OSTI)

    Li, S.; Wang, J. G.; Zhu, M.; Peng, J. C.; Xie, J. L.; Wu, X. L.; Guo, L. T.; Chang, C.; Xiong, Z. F.; Department of Engineering Physics, Tsinghua University, Beijing 10084

    2013-12-15

    To research the dynamic course of multipactor suppression on the periodically patterned surface, tens of electron collision processes are tracked by numerical calculation. The influences of microwave frequency, amplitude of RF electric field, slope angle, the local field enhancement, and the tilted incident electric field on the multipactor suppression are studied by tracking multi-generation electrons' trajectories, hopping and flight time, collision energy, and secondary emission yield. Meanwhile, the dynamic processes of secondary electrons on the periodic surface are analyzed by particle-in-cell (PIC) simulation. The PIC results are consistent with the analytical results in which the electrons fly reciprocatingly between the slopes and impact on the slopes; the methods of increasing the slope angle, enlarging the RF field, and lowering the frequency in a certain range are helpful to enhance the multipactor suppression steadily and persistently.

  13. Time-of-flight secondary ion mass spectrometry of deuterated linear poly(dimethylsiloxane)

    SciTech Connect (OSTI)

    Zhang, X.K.; Stuart, J.O.; Clarson, S.J. ); Sabata, A. ); Beaucage, G. )

    1994-08-29

    Mass spectrometry (MS) has previously proved to be very valuable for characterizing the thermal decomposition of poly-(dimethylsiloxane) (PDMS) via pyrolysis-MS. Secondary ion mass spectrometry (SIMS) has also been applied to identify the various fragments characteristic of PDMS and thus give fingerprint'' spectra for identification purposes. This paper describes the characterization of deuterated linear PDMS -[(CD[sub 3])[sub 2]SiO][sub n]- using time-of-flight secondary ion mass spectrometry. The work is part of a program investigating the conformations and interactions of deuterated siloxanes in isotopic blends -[(CD[sub 3])[sub 2]SiO][sub n]-/-[CH[sub 3][sub 2]SiO][sub n]- using small-angle neutron scattering. It is therefore clearly important to demonstrate that no deuterium/hydrogen exchanges occurred during the synthetic methodology used.

  14. Detection of a MoSe{sub 2} secondary phase layer in CZTSe by spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Demircioğlu, Özden; Riedel, Ingo; Gütay, Levent; Mousel, Marina; Redinger, Alex; Rey, Germain; Weiss, Thomas; Siebentritt, Susanne

    2015-11-14

    We demonstrate the application of Spectroscopic Ellipsometry (SE) for identification of secondary phase MoSe{sub 2} in polycrystalline Cu{sub 2}ZnSnSe{sub 4} (CZTSe) samples. A MoSe{sub 2} reference sample was analyzed, and its optical constants (ε{sub 1} and ε{sub 2}) were extracted by SE analysis. This dataset was implemented into an optical model for analyzing SE data from a glass/Mo/CZTSe sample containing MoSe{sub 2} at the back side of the absorber. We present results on the n and k values of CZTSe and show the extraction of the thickness of the secondary phase MoSe{sub 2} layer. Raman spectroscopy and scanning electron microscopy were applied to confirm the SE results.

  15. Effect of hexafluoroisopropanol on the thermodynamics of peptide secondary structure formation

    SciTech Connect (OSTI)

    Andersen, N.H.; Dyer, R.B.; Fesinmeyer, R.M.; Gai, F.; Liu, Z.; Neidigh, J.W.; Tong, H.

    1999-10-27

    This report provides additional evidence for the importance of hydrophobic interactions in peptide secondary structure formation. For the hydrophobically driven {beta} hairpin formation examined, the addition of HFIP to the 8% level increases hairpin formation and increases {Delta}C{sub p} by nearly a factor of 3. Surprisingly, {alpha} helices bearing a few non-interacting hydrophobic residues can display even larger {Delta}C{sub p} values. The initial phase of secondary structure induction during fluoroalcohol titrations of peptides appears to be largely the result of these effects rather than differential stabilization (or destabilization) of the folded versus coil conformation by alcohol/peptide binding interactions, as the latter would be reflected predominantly in the enthalpy term. The addition of limited quantities of fluoroalcohol may mimic the early hydrophobic collapse stage of protein folding.

  16. Predicting the Risk of Secondary Lung Malignancies Associated With Whole-Breast Radiation Therapy

    SciTech Connect (OSTI)

    Ng, John; Shuryak, Igor; Xu Yanguang; Clifford Chao, K.S.; Brenner, David J.; Burri, Ryan J.

    2012-07-15

    Purpose: The risk of secondary lung malignancy (SLM) is a significant concern for women treated with whole-breast radiation therapy after breast-conserving surgery for early-stage breast cancer. In this study, a biologically based secondary malignancy model was used to quantify the risk of secondary lung malignancies (SLMs) associated with several common methods of delivering whole-breast radiation therapy (RT). Methods and Materials: Both supine and prone computed tomography simulations of 15 women with early breast cancer were used to generate standard fractionated and hypofractionated whole-breast RT treatment plans for each patient. Dose-volume histograms (DVHs) of the ipsilateral breast and lung were calculated for each patient on each plan. A model of spontaneous and radiation-induced carcinogenesis was used to determine the relative risks of SLMs for the different treatment techniques. Results: A higher risk of SLMs was predicted for supine breast irradiation when compared with prone breast irradiation for both the standard fractionation and hypofractionation schedules (relative risk [RR] = 2.59, 95% confidence interval (CI) = 2.30-2.88, and RR = 2.68, 95% CI = 2.39-2.98, respectively). No difference in risk of SLMs was noted between standard fractionation and hypofractionation schedules in either the supine position (RR = 1.05, 95% CI = 0.97-1.14) or the prone position (RR = 1.01, 95% CI = 0.88-1.15). Conclusions: Compared with supine whole-breast irradiation, prone breast irradiation is associated with a significantly lower predicted risk of secondary lung malignancy. In this modeling study, fractionation schedule did not have an impact on the risk of SLMs in women treated with whole-breast RT for early breast cancer.

  17. Planck CMB anomalies: astrophysical and cosmological secondary effects and the curse of masking

    SciTech Connect (OSTI)

    Rassat, A.; Starck, J.-L.; Paykari, P.; Sureau, F.; Bobin, J. E-mail: jstarck@cea.fr E-mail: florent.sureau@cea.fr

    2014-08-01

    Large-scale anomalies have been reported in CMB data with both WMAP and Planck data. These could be due to foreground residuals and or systematic effects, though their confirmation with Planck data suggests they are not due to a problem in the WMAP or Planck pipelines. If these anomalies are in fact primordial, then understanding their origin is fundamental to either validate the standard model of cosmology or to explore new physics. We investigate three other possible issues: 1) the trade-off between minimising systematics due to foreground contamination (with a conservative mask) and minimising systematics due to masking, 2) astrophysical secondary effects (the kinetic Doppler quadrupole and kinetic Sunyaev-Zel'dovich effect), and 3) secondary cosmological signals (the integrated Sachs-Wolfe effect). We address the masking issue by considering new procedures that use both WMAP and Planck to produce higher quality full-sky maps using the sparsity methodology (LGMCA maps). We show the impact of masking is dominant over that of residual foregrounds, and the LGMCA full-sky maps can be used without further processing to study anomalies. We consider four official Planck PR1 and two LGMCA CMB maps. Analysis of the observed CMB maps shows that only the low quadrupole and quadrupole-octopole alignment seem significant, but that the planar octopole, Axis of Evil, mirror parity and cold spot are not significant in nearly all maps considered. After subtraction of astrophysical and cosmological secondary effects, only the low quadrupole may still be considered anomalous, meaning the significance of only one anomaly is affected by secondary effect subtraction out of six anomalies considered. In the spirit of reproducible research all reconstructed maps and codes will be made available for download here http://www.cosmostat.org/anomaliesCMB.html.

  18. "A New Paradigm for Secondary Eyewall Formation in Tropical Cyclones",

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chun-Chieh Wu (National Taiwan University) | Princeton Plasma Physics Lab July 27, 2012, 12:00pm to 1:15pm Geophysical Fluid Dynamics Laboratory Smagorinsky Seminar Room Geophysical Fluid Dynamics Laboratory Princeton University Forrestal Campus 201 Forrestal Road Princeton, NJ 08540-6649 "A New Paradigm for Secondary Eyewall Formation in Tropical Cyclones", Chun-Chieh Wu (National Taiwan University) Contact Information Website: Website

  19. Unidirectional resonance modes supported by secondary islands in a microcavity comprised of two half-ellipses

    SciTech Connect (OSTI)

    Lee, Jinhyung; Rim, Sunghwan; Cho, Jinhang; Kim, Chil-Min [Acceleration Research Center for Quantum Chaos Applications, Sogang University, Seoul 121-742 (Korea, Republic of)

    2011-03-15

    We propose a simple and robust mechanism to achieve unidirectional emission in a microcavity comprised of two half-ellipses. The microcavity has two geometrical parameters, two eccentricities, which permit a control of the directional emissions. For the microcavity with two small eccentricities, the positions of secondary islands near primary islands in the survival probability distributions determine the directionality of emissions. We obtain the optimized values of the eccentricities for unidirectional emission.

  20. Secondary Network Distribution Systems Background and Issues Related to the Interconnection of Distributed Resources

    SciTech Connect (OSTI)

    Behnke, M.; Erdman, W.; Horgan, S.; Dawson, D.; Feero, W.; Soudi, F.; Smith, D.; Whitaker, C.; Kroposki, B.

    2005-07-01

    This document addresses the technical considerations associated with the interconnection of distributed resources (DR) with secondary network distribution systems. It provides an overview of the characteristics of distribution systems and interconnection requirements and identifies unique issues specific to network interconnections. It also identifies the network-specific interconnection issues for which test protocols should be developed. Recommended criteria and requirements for the interconnection of DR with network distribution systems are presented.

  1. Benchmark of numerical tools simulating beam propagation and secondary particles in ITER NBI

    SciTech Connect (OSTI)

    Sartori, E. Veltri, P.; Serianni, G.; Dlougach, E.; Hemsworth, R.; Singh, M.

    2015-04-08

    Injection of high energy beams of neutral particles is a method for plasma heating in fusion devices. The ITER injector, and its prototype MITICA (Megavolt ITER Injector and Concept Advancement), are large extrapolations from existing devices: therefore numerical modeling is needed to set thermo-mechanical requirements for all beam-facing components. As the power and charge deposition originates from several sources (primary beam, co-accelerated electrons, and secondary production by beam-gas, beam-surface, and electron-surface interaction), the beam propagation along the beam line is simulated by comprehensive 3D models. This paper presents a comparative study between two codes: BTR has been used for several years in the design of the ITER HNB/DNB components; SAMANTHA code was independently developed and includes additional phenomena, such as secondary particles generated by collision of beam particles with the background gas. The code comparison is valuable in the perspective of the upcoming experimental operations, in order to prepare a reliable numerical support to the interpretation of experimental measurements in the beam test facilities. The power density map calculated on the Electrostatic Residual Ion Dump (ERID) is the chosen benchmark, as it depends on the electric and magnetic fields as well as on the evolution of the beam species via interaction with the gas. Finally the paper shows additional results provided by SAMANTHA, like the secondary electrons produced by volume processes accelerated by the ERID fringe-field towards the Cryopumps.

  2. Neutrophils and monocytes transport tumor cell antigens from the peritoneal cavity to secondary lymphoid tissues

    SciTech Connect (OSTI)

    Terasawa, Masao; Nagata, Kisaburo [Division of Molecular Medicine, Department of Biomolecular Science, Faculty of Science, Toho University, 2-2-1, Miyama, Funabashi (Japan); Kobayashi, Yoshiro [Division of Molecular Medicine, Department of Biomolecular Science, Faculty of Science, Toho University, 2-2-1, Miyama, Funabashi (Japan)], E-mail: yoshiro@biomol.sci.toho-u.ac.jp

    2008-12-12

    Antigen-transporting cells take up pathogens, and then migrate from sites of inflammation to secondary lymphoid tissues to induce an immune response. Among antigen-transporting cells, dendritic cells (DCs) are believed to be the most potent and professional antigen-presenting cells that can stimulate naive T cells. However, the cells that transport antigens, tumor cell antigens in particular, have not been clearly identified. In this study we have analyzed what types of cells transport tumor cell antigens to secondary lymphoid tissues. We show that neutrophils, monocytes and macrophages but not DCs engulf X-irradiated P388 leukemic cells after their injection into the peritoneal cavity, and that neutrophils and monocytes but not macrophages migrate to the parathymic lymph nodes (pLN), the blood, and then the spleen. The monocytes in the pLN comprise Gr-1{sup -} and Gr-1{sup +} ones, and some of these cells express CD11c. Overall, this study demonstrates that neutrophils and monocytes transport tumor cell antigens from the peritoneal cavity to secondary lymphoid tissues.

  3. Radionuclide Retention Mechanisms in Secondary Waste-Form Testing: Phase II

    SciTech Connect (OSTI)

    Um, Wooyong; Valenta, Michelle M.; Chung, Chul-Woo; Yang, Jungseok; Engelhard, Mark H.; Serne, R. Jeffrey; Parker, Kent E.; Wang, Guohui; Cantrell, Kirk J.; Westsik, Joseph H.

    2011-09-26

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate candidate stabilization technologies that have the potential to successfully treat liquid secondary waste stream effluents produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). WRPS is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF, a multi-waste, treatment-and-storage unit that has been permitted under the Resource Conservation and Recovery Act (RCRA), can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needs to be operational by 2018 to receive secondary liquid waste generated during operation of the WTP. The STU will provide the additional capacity needed for ETF to process the increased volume of secondary waste expected to be produced by WTP. This report on radionuclide retention mechanisms describes the testing and characterization results that improve understanding of radionuclide retention mechanisms, especially for pertechnetate, {sup 99}TcO{sub 4}{sup -} in four different waste forms: Cast Stone, DuraLith alkali aluminosilicate geopolymer, encapsulated fluidized bed steam reforming (FBSR) product, and Ceramicrete phosphate bonded ceramic. These data and results will be used to fill existing data gaps on the candidate technologies to support a decision-making process that will identify a subset of the candidate waste forms that are most promising and should undergo further performance testing.

  4. Nitrogen availability as a control mechanism of secondary succession within a semiarid shrubland ecosystem

    SciTech Connect (OSTI)

    Redente, E.F.; McLendon, T.

    1992-09-25

    Three experiments were conducted within a semiarid shrubland to test the role of nitrogen availability as a control mechanism in secondary succession. Secondary succession patterns were documented for seven years and effects of increased and decreased N availability levels, fumigation, and competition by early-seral species were tested. Differential responses by seral species were determined and related to successional patterns. Nitrogen availability was found to be a primary mechanism controlling the rate of succession. Relative growth rate was an important factor determining which species initially dominated and N availability became the primary control factor by the third year. As N availability increased, the rate of succession decreased. Conversely, as N availability was decreased, the rate of succession increased. The abundance of annuals was increased and abundance of perennials decreased by increased N availability. Tissue N concentration was related to lifeform and seral position, and these relationships were important in the transition from early- to mid-seral stages. Decomposer subsystem dynamics were correlated with seral community dynamics. The effect of fumigation was minimized by initially planting with late-seral species. A conceptual model of secondary succession is presented based on N availability, relative growth rate, lifeform, and decomposition dynamics.

  5. State waste discharge permit application 400 Area secondary cooling water. Revision 2

    SciTech Connect (OSTI)

    1996-01-01

    This document constitutes the Washington Administrative Code 173-216 State Waste Discharge Permit Application that serves as interim compliance as required by Consent Order DE 91NM-177, for the 400 Area Secondary Cooling Water stream. As part of the Hanford Federal Facility Agreement and Consent Order negotiations, the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site that affect groundwater or have the potential to affect groundwater would be subject to permitting under the structure of Chapter 173-216 of the Washington Administrative Code, the State Waste Discharge Permitting Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order DE 91NM-177. The Consent Order DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. Based upon compositional and flow rate characteristics, liquid effluent streams on the Hanford Site have been categorized into Phase 1, Phase 2, and Miscellaneous streams. This document only addresses the 400 Area Secondary Cooling Water stream, which has been identified as a Phase 2 stream. The 400 Area Secondary Cooling Water stream includes contribution streams from the Fuels and Materials Examination Facility, the Maintenance and Storage Facility, the 481-A pump house, and the Fast Flux Test Facility.

  6. Pinoresinol reductase 1 impacts lignin distribution during secondary cell wall biosynthesis in Arabidopsis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Qiao; Zeng, Yining; Yin, Yanbin; Pu, Yunqiao; Jackson, Lisa A.; Engle, Nancy L.; Martin, Madhavi Z.; Tschaplinski, Timothy J.; Ding, Shi-You; Ragauskas, Arthur J.; et al

    2014-08-05

    In this paper, pinoresinol reductase (PrR) catalyzes the conversion of the lignan (-)-pinoresinol to (-)-lariciresinol in Arabidopsis thaliana, where it is encoded by two genes, PrR1 and PrR2, that appear to act redundantly. PrR1 is highly expressed in lignified inflorescence stem tissue, whereas PrR2 expression is barely detectable in stems. Co-expression analysis has indicated that PrR1 is co-expressed with many characterized genes involved in secondary cell wall biosynthesis, whereas PrR2 expression clusters with a different set of genes. The promoter of the PrR1 gene is regulated by the secondary cell wall related transcription factors SND1 and MYB46. The loss-of-function mutantmore » of PrR1 shows, in addition to elevated levels of pinoresinol, significantly decreased lignin content and a slightly altered lignin structure with lower abundance of cinnamyl alcohol end groups. Stimulated Raman scattering (SRS) microscopy analysis indicated that the lignin content of the prr1-1 loss-of-function mutant is similar to that of wild-type plants in xylem cells, which exhibit a normal phenotype, but is reduced in the fiber cells. Finally, together, these data suggest an association of the lignan biosynthetic enzyme encoded by PrR1 with secondary cell wall biosynthesis in fiber cells.« less

  7. Simulation study on number of secondary particles in extensive air showers using CORSIKA code

    SciTech Connect (OSTI)

    Halataei, S. M. H.; Bahmanabadi, M.; Samimi, J.; Ghomi, M. Khakian

    2008-04-15

    We have simulated more than 10{sup 5} extensive air showers (EAS) by CORSIKA code, with a proton as the primary particle. The range of energy for primary particles was selected from 50 TeV to 5 PeV, with differential flux given by dN/dE{proportional_to}E{sup -2.7}. Using the secondary charged particles produced of these EASs, we obtained the function dN{sub sp}({theta},X)/d{theta}, where N{sub sp}({theta},X) is the number of secondary charged particles in EASs as a function of atmosphere depth, X, and zenith angle, {theta}. A sin{theta}cos{sup n(X)}{theta} distribution was obtained for zenith angle distribution of the number of secondary charged particles, where power index, n(X), is a function of atmosphere depth, X. We obtained n(X)=3.02+0.003XlnX-8.28x10{sup -9}X{sup 3}-1.35lnX. We have compared our results with the experimental data of various observatories.

  8. Performance and cost benefits associated with nonimaging secondary concentrators used in point-focus dish solar thermal applications

    SciTech Connect (OSTI)

    O'Gallagher, J.; Winston, R.

    1987-09-01

    Using nonimaging secondary concentrators in point-focus applications may permit the development of more cost-effective concentrator systems by either improving performance or reducing costs. Secondaries may also increase design flexibility. The major objective of this study was to develop as complete an understanding as possible of the quantitative performance and cost effects associated with deploying nonimaging secondary concentrators at the focal zone of point-focus solar thermal concentrators. A performance model was developed that uses a Monte Carlo ray-trace procedure to determine the focal plane distribution of a paraboloidal primary as a function of optical parameters. It then calculates the corresponding optimized concentration and thermal efficiency as a function of temperature with and without the secondary. To examine the potential cost benefits associated with secondaries, a preliminary model for the rational optimization of performance versus cost trade-offs was developed. This model suggests a possible 10% to 20% reduction in the cost of delivered energy when secondaries are used. This is a lower limit, and the benefits may even be greater if using a secondary permits the development of inexpensive primary technologies for which the performance would not otherwise be viable. 20 refs., 15 figs., 3 tabs.

  9. Primary and secondary organics in tropical Amazonian rainforest aerosols: Chiral analysis of 2-methyltetrols

    SciTech Connect (OSTI)

    Gonzalez, Nelida; Borg-Karlson, Anna-Karin; Artaxo, Paulo; Guenther, Alex B.; Krejci, R.; Noziere, Barbara; Noone, Kevin

    2014-06-01

    This work presents the application of a newly developed method to facilitate the distinction between primary and secondary organic compounds in ambient aerosols based on their chiral analysis. The organic constituents chosen for chiral analysis are the four stereomers of the 2-methyltetrols, (2R,3S)- and (2S,3R)- methylerythritol and (2S,3S)- and (2R,3R)- methylthreitol. Ambient PM10 aerosol samples were collected between June 2008 and June 2009 near Manaus, Brazil, in a remote tropical rainforest environment of central Amazonia. The samples were analyzed for the presence of these four stereomers because qualitatively, in a previous study, they have been demonstrated to have partly primary origins. Thus the origin of these compounds may be primary and secondary from the biosynthesis and oxidation processes of isoprene within plants and also in the atmosphere. Using authentic standards, the quantified concentrations were in average 78.2 and 72.8 ng m-3 for (2R,3S)- and (2S,3R)- methylerythritol and 3.1 and 3.3 ng m-3 for (2S,3S)- and (2R,3R)- methylthreitol during the dry season and 7.1, 6.5, 2.0, and 2.2 ng m-3 during the wet season, respectively. Furthermore, these compounds were found to be outside the confidence interval for racemic mixtures (enantiomeric fraction, Ef = 0.5 -0.01) in nearly all the samples, with deviations of up to 32 % (Ef = 0.61) for (2R,3S)-methylerythritol and 47 % (Ef = 0.65) for (2S,3S)-methylthreitol indicating (99% confidence level) biologically-produced 2-methyltetrols. The minimum primary origin contribution ranged between 0.19 and 29.67 ng m-3 for the 2-methylerythritols and between 0.15 and 1.2 ng m-3 for the 2-methylthreitols. The strong correlation of the diatereomers (racemic 2-methylerythritol and 2-methylthreitol) in the wet season implied a secondary origin. Assuming the maximum secondary contribution in the dry season, the secondary fraction in the wet season was 81-99 % and in the dry season, 10 - 95 %. Nevertheless, from the

  10. INFLUENCE OF TEMPERATURE ON THE CORROSION POTENTIAL OF THE 241-AN-102 MULTI PROBE CORROSION MONITORING SYSTEM SECONDARY REFERENCE ELECTRODES

    SciTech Connect (OSTI)

    EDGEMON GL; TAYLOR TM

    2008-09-30

    A test program using 241-AN-102 waste simulants and metallic secondary reference electrodes similar to those used on the 241-AN-102 MPCMS was performed to characterize the relationship between temperature and secondary reference electrode open-circuit corrosion potential. This program showed that the secondary reference electrodes can be used to make tank and tank steel corrosion potential measurements, but that a correction factor of approximately 2 mV per degree Celsius of temperature difference must be applied, where temperature difference is defined as the difference between tank temperature at the time of measurement and 30 C, the average tank temperature during the first several months of 241-AN-102 MPCMS operation (when the corrosion potentials of the secondary reference electrodes were being recorded relative to the primary reference electrodes).

  11. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    DOE R&D Accomplishments [OSTI]

    Molina, Luisa T.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavala, Miguel; Velasco, Erik; Molina; Mario J.

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation.

  12. Trps1 deficiency inhibits the morphogenesis of secondary hair follicles via decreased Noggin expression

    SciTech Connect (OSTI)

    Sun, Yujing; Nakanishi, Masako; Sato, Fuyuki; Oikawa, Kosuke; Muragaki, Yasuteru; Zhou, Gengyin

    2015-01-16

    Highlights: • The number of secondary hair follicles is reduced by half in Trps1 KO embryonic skin compared to wild-type skin. • Noggin expression is significantly decreased and BMP signaling is promoted in Trps1 KO embryonic skin. • Treatment with a Noggin or BMP inhibitor rescued the decreased number of hair follicles in Trps1 KO skin graft cultures. • Cell proliferation and apoptosis of the epidermis were normalized by Noggin treatment. - Abstract: A representative phenotype of patients with tricho-rhino-phalangeal syndrome (TRPS) is sparse hair. To understand the developmental defects of these patient’s hair follicles, we analyzed the development of hair follicles histologically and biochemically using Trps1 deficient (KO) mice. First, we compared the numbers of primary hair follicles in wild-type (WT) and KO embryos at different developmental stages. No differences were observed in the E14.5 skins of WT and KO mice. However, at later time points, KO fetal skin failed to properly develop secondary hair follicles, and the number of secondary hair follicles present in E18.5 KO skin was approximately half compared to that of WT skin. Sonic hedgehog expression was significantly decreased in E17.5 KO skin, whereas no changes were observed in Eda/Edar expression in E14.5 or E17.5 skins. In addition, Noggin expression was significantly decreased in E14.5 and E17.5 KO skin compared to WT skin. In parallel with the suppression of Noggin expression, BMP signaling was promoted in the epidermal cells of KO skins compared to WT skins as determined by immunohistochemistry for phosphorylated Smad1/5/8. The reduced number of secondary hair follicles was restored in skin graft cultures treated with a Noggin and BMP inhibitor. Furthermore, decreased cell proliferation, and increased apoptosis in KO skin was rescued by Noggin treatment. Taken together, we conclude that hair follicle development in Trps1 KO embryos is impaired directly or indirectly by decreased Noggin

  13. Determination of carbon distributions in quenched and partitioned microstructures using nanoscale secondary ion mass spectroscopy

    SciTech Connect (OSTI)

    Choi, Kyoo Sil; Zhu, Zihua; Sun, Xin; De Moor, Emmanuel; Taylor, Mark D.; Speer, John; Matlock, David K.

    2015-04-20

    A multi-modal characterization technique, which combines nanoscale secondary ion mass spectroscopy (Nano-SIMS) with a spatial resolution of ~100 nm and electron back scatter diffraction (EBSD) to determine carbon distributions in austenite and martensite in a quenched and partitioned (Q&P) Fe-0.29C-2.95Mn-1.59Si steel is presented. Significant carbon enrichment of austenite was measured with decreased levels of carbon in martensite, supporting the carbon partitioning mechanism. Fresh untempered martensite could be identified, and different degrees of enrichment were observed for blocky and lath austenite.

  14. Secondary heat exchanger design and comparison for advanced high temperature reactor

    SciTech Connect (OSTI)

    Sabharwall, P.; Kim, E. S.; Siahpush, A.; McKellar, M.; Patterson, M.

    2012-07-01

    Next generation nuclear reactors such as the advanced high temperature reactor (AHTR) are designed to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. This study considers two different types of heat exchangers - helical coiled heat exchanger and printed circuit heat exchanger - as possible options for the AHTR secondary heat exchangers with distributed load analysis and comparison. Comparison is provided for all different cases along with challenges and recommendations. (authors)

  15. Secondary treatment of films of colloidal quantum dots for optoelectronics and devices produced thereby

    DOE Patents [OSTI]

    Semonin, Octavi Escala; Luther, Joseph M; Beard, Matthew C; Chen, Hsiang-Yu

    2014-04-01

    A method of forming an optoelectronic device. The method includes providing a deposition surface and contacting the deposition surface with a ligand exchange chemical and contacting the deposition surface with a quantum dot (QD) colloid. This initial process is repeated over one or more cycles to form an initial QD film on the deposition surface. The method further includes subsequently contacting the QD film with a secondary treatment chemical and optionally contacting the surface with additional QDs to form an enhanced QD layer exhibiting multiple exciton generation (MEG) upon absorption of high energy photons by the QD active layer. Devices having an enhanced QD active layer as described above are also disclosed.

  16. Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

    SciTech Connect (OSTI)

    Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S.

    2014-04-15

    The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50?Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

  17. Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell

    DOE Patents [OSTI]

    Otto, Neil C.; Warner, Barry T.; Smaga, John A.; Battles, James E.

    1983-01-01

    The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

  18. Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell

    DOE Patents [OSTI]

    Otto, N.C.; Warner, B.T.; Smaga, J.A.; Battles, J.E.

    1982-07-07

    The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

  19. Metabolic profiling reveals altered sugar and secondary metabolism in response to UGPase overexpression in Populus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Payyavula, Raja S.; Tschaplinski, Timothy J.; Jawdy, Sara; Sykes, Robert; Tuskan, Gerald A.; Kalluri, Udaya C.

    2014-10-07

    Background: UDP-glucose pyrophopharylase (UGPase) is a sugar metabolizing enzyme (E.C. 2.7.7.9) that catalyzes a reversible reaction of UDP-glucose and pyrophosphate from glucose-1-phosphate and uridine triphosphate glucose. UDP-glucose is a key intermediate sugar that is channeled to multiple metabolic pathways. The functional role of UGPase in woody plants such as Populus is poorly understood. Results: We characterized the functional role of UGPase in Populus deltoides by overexpressing a native gene. Overexpression of the native gene resulted in increased leaf area and leaf-to-shoot biomass ratio but decreased shoot and root growth. Metabolomic analyses showed that manipulation of UGPase results in perturbations inmore » primary as well as secondary metabolism resulting in reduced sugar and starch levels and increased phenolics such as caffeoyl- and feruloyl conjugates. While cellulose and lignin levels in the cell walls were not significantly altered, the syringyl-to-guaiacyl ratio was significantly reduced. Conclusions: These results demonstrate that UGPase plays a key role in the tightly coupled primary and secondary metabolic pathways and perturbation in its function results in pronounced effects on growth and metabolism outside of cell wall biosynthesis of Populus.« less

  20. Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K. M.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2015-07-24

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form secondary organic aerosol (SOA) from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx under different oxidizing conditions. The effects of the oxidizing condition on organic aerosol (OA) composition, mass yield, volatility, and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state (OSc), and mass yield. The OA oxidation state generally increased duringmore » photo-oxidation, and the final OA OSc ranged from -0.29 to 0.16 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have a significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  1. Secondary Protection for 70 MPa Fueling - A White Paper from the Hydrogen Safety Panel

    SciTech Connect (OSTI)

    Weiner, Steven C.; Kallman, Richard A.

    2009-07-06

    In developing a 70 megapascal (MPa) fueling infrastructure, it is critical to ensure that a vehicle equipped with a lower service pressure fuel tank is never filled from a 70 MPa fueling source. Filling of a lower service pressure vehicle at a 70 MPa fueling source is likely to result in a catastrophic event with severe injuries or fatalities. The Hydrogen Safety Panel recommends that DOE undertake a two‐step process to address this issue: 1. Perform an independent risk analysis of a 70MPa dispenser filling a lower pressure vehicle tank and develop different approaches for prevention and mitigation to meet an acceptable level of safety. Cost effectiveness, reliability, advantages and disadvantages are among the factors that should be evaluated for each approach considered. 2. Until such time as this analysis is complete and any recommended actions implemented, communicate the potential risk to responsible parties and strongly encourage those parties to add a secondary layer of protection to the existing system of mechanically non‐interchangeable nozzles/receptacles. This will reduce the probability of a pressure mismatch during this developmental phase for hydrogen fuel cell vehicles and infrastructure. This step can be reassessed after further analysis is completed and the need and effectiveness of secondary protection methods are evaluated. This paper provides background discussion of the problem, current safety systems and strategy and examples of potential future solutions to support the above recommendations.

  2. Increasing Gas Hydrate Formation Temperature for Desalination of High Salinity Produced Water with Secondary Guests

    SciTech Connect (OSTI)

    Cha, Jong-Ho; Seol, Yongkoo

    2013-10-07

    We suggest a new gas hydrate-based desalination process using water-immiscible hydrate formers; cyclopentane (CP) and cyclohexane (CH) as secondary hydrate guests to alleviate temperature requirements for hydrate formation. The hydrate formation reactions were carried out in an isobaric condition of 3.1 MPa to find the upper temperature limit of CO2 hydrate formation. Simulated produced water (8.95 wt % salinity) mixed with the hydrate formers shows an increased upper temperature limit from -2 °C for simple CO2 hydrate to 16 and 7 °C for double (CO2 + CP) and (CO2 + CH) hydrates, respectively. The resulting conversion rate to double hydrate turned out to be similar to that with simple CO2 hydrate at the upper temperature limit. Hydrate formation rates (Rf) for the double hydrates with CP and CH are shown to be 22 and 16 times higher, respectively, than that of the simple CO2 hydrate at the upper temperature limit. Such mild hydrate formation temperature and fast formation kinetics indicate increased energy efficiency of the double hydrate system for the desalination process. Dissociated water from the hydrates shows greater than 90% salt removal efficiency for the hydrates with the secondary guests, which is also improved from about 70% salt removal efficiency for the simple hydrates.

  3. Source category survey: secondary copper smelting and refining industry. Final report Oct 79-Jan 80

    SciTech Connect (OSTI)

    Snyder, M.K.; Shobe, F.D.

    1980-05-01

    This report presents the results of a survey of the secondary copper smelting and refining industry to determine the probable impact of the development of new source performance standards under Section 111 of the Clean Air Act. The surveyed industry processes copper scrap to produce pure copper or copper alloy, other than brass and bronze. Secondary copper foundries, which melt and cast high-quality copper scrap without refining it, are excluded. Primary copper smelters and refiners, which produce copper from ore, are also excluded, although they also process copper scrap. Process, emissions, and economic data were gathered by literature searches, contacts with representatives of the industry, trade associations, federal government agencies, and state and local air pollution control agencies, and visits to two plants. The industry's production processes, actual and allowable air emissions, and emission control systems are described. State and local emission regulations are compared. Production and capacity are projected to 1989 and the impact of new source performance standards is assessed.

  4. 340 Facility Secondary Containment and Leak Detection Project W-302 Functional Design Criteria

    SciTech Connect (OSTI)

    Stordeur, R.T.

    1995-03-01

    This functional design criteria for the upgrade to the 340 radioactive liquid waste storage facility (Project W-302) specifically addresses the secondary containment issues at the current vault facility of the 340 Complex. This vault serves as the terminus for the Radioactive Liquid Waste System (RLWS). Project W-302 is necessary in order to bring this portion of the Complex into full regulatory compliance. The project title, ``340 Facility Secondary Containment and Leak Detection``, illustrates preliminary thoughts of taking corrective action directly upon the existing vault (such as removing the tanks, lining the vault, and replacing tanks). However, based on the conclusion of the engineering study, ``Engineering Study of the 300 Area Process Wastewater Handling System``, WHC-SD-WM-ER-277 (as well as numerous follow-up meetings with cognizant staff), this FDC prescribes a complete replacement of the current tank/vault system. This offers a greater array of tanks, and provides greater operating flexibility and ease of maintenance. This approach also minimizes disruption to RLWS services during ``tie-in``, as compared to the alternative of trying to renovate the old vault. The proposed site is within the current Complex area, and maintains the receipt of RLWS solutions through gravity flow.

  5. Metabolic profiling reveals altered sugar and secondary metabolism in response to UGPase overexpression in Populus

    SciTech Connect (OSTI)

    Payyavula, Raja S.; Tschaplinski, Timothy J.; Jawdy, Sara; Sykes, Robert; Tuskan, Gerald A.; Kalluri, Udaya C.

    2014-10-07

    Background: UDP-glucose pyrophopharylase (UGPase) is a sugar metabolizing enzyme (E.C. 2.7.7.9) that catalyzes a reversible reaction of UDP-glucose and pyrophosphate from glucose-1-phosphate and uridine triphosphate glucose. UDP-glucose is a key intermediate sugar that is channeled to multiple metabolic pathways. The functional role of UGPase in woody plants such as Populus is poorly understood. Results: We characterized the functional role of UGPase in Populus deltoides by overexpressing a native gene. Overexpression of the native gene resulted in increased leaf area and leaf-to-shoot biomass ratio but decreased shoot and root growth. Metabolomic analyses showed that manipulation of UGPase results in perturbations in primary as well as secondary metabolism resulting in reduced sugar and starch levels and increased phenolics such as caffeoyl- and feruloyl conjugates. While cellulose and lignin levels in the cell walls were not significantly altered, the syringyl-to-guaiacyl ratio was significantly reduced. Conclusions: These results demonstrate that UGPase plays a key role in the tightly coupled primary and secondary metabolic pathways and perturbation in its function results in pronounced effects on growth and metabolism outside of cell wall biosynthesis of Populus.

  6. Effect of Secondary Electron Emission on Electron Cross-Field Current in EB Discharges

    SciTech Connect (OSTI)

    Yevgeny Raitses, Igor D. Kaganovich, Alexander Khrabrov, Dmytro Sydorenko, Nathaniel J. Fisch and Andrei Smolyakov

    2011-02-10

    This paper reviews and discusses recent experimental, theoretical, and numerical studies of plasma-wall interaction in a weakly collisional magnetized plasma bounded with channel walls made from different materials. A lowpressure ExB plasma discharge of the Hall thruster was used to characterize the electron current across the magnetic field and its dependence on the applied voltage and electron-induced secondary electron emission (SEE) from the channel wall. The presence of a depleted, anisotropic electron energy distribution function with beams of secondary electrons was predicted to explain the enhancement of the electron cross-field current observed in experiments. Without the SEE, the electron crossfield transport can be reduced from anomalously high to nearly classical collisional level. The suppression of SEE was achieved using an engineered carbon velvet material for the channel walls. Both theoretically and experimentally, it is shown that the electron emission from the walls can limit the maximum achievable electric field in the magnetized plasma. With nonemitting walls, the maximum electric field in the thruster can approach a fundamental limit for a quasineutral plasma.

  7. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in Mexico City

    SciTech Connect (OSTI)

    Dr. Charles E. Kolb Dr. Douglas R. Worsnop Dr. Manjula R. Canagaratna Dr. Scott C. Herndon Dr. John T. Jayne Dr. W. Berk Knighton Dr. Timothy B. Onasch Dr. Ezra C. Wood Dr. Miguel Zavala

    2008-03-31

    This project was one of three collaborating grants designed to understand the atmospheric chemistry and aerosol particle microphysics impacting air quality in the Mexico City Metropolitan Area (MCMA) and its urban plume. The overall effort, titled MCMA- 2006, focused on: 1) the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles and 2) the measurement and analysis of secondary oxidants and secondary fine particular matter (PM) production, with particular emphasis on secondary organic aerosol (SOA). MCAM-2006 pursued it goals through three main activities: 1) performance and publication of detailed analyses of extensive MCMA trace gas and fine PM measurements made by the collaborating groups and others during earlier MCMA field campaigns in 2002 and 2003; 2) deployment and utilization of extensive real-time trace gas and fine PM instrumentation at urban and downwind MCMA sites in support of the MAX-Mex/MILAGRO field measurements in March, 2006; and, 3) analyses of the 2006 MCMA data sets leading to further publications that are based on new data as well as insights from analysis and publication of the 2002/2003 field data. Thirteen archival publications were coauthored with other MCMA-2003 participants. Documented findings included a significantly improved speciated emissions inventory from on-road vehicles, a greatly enhanced understanding of the sources and atmospheric loadings of volatile organic compounds, a unique analysis of the high fraction of ambient formaldehyde from primary emission sources, a much more extensive knowledge of the composition, size distributions and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models, and evaluations of significant errors that can arise from standard air quality monitors for ozone and nitrogen

  8. Waste Acceptance Testing of Secondary Waste Forms: Cast Stone, Ceramicrete and DuraLith

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Westsik, Joseph H.; Chung, Chul-Woo; Lindberg, Michael J.; Parker, Kent E.

    2011-08-12

    To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions has initiated secondary-waste-form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is conducting tests on four candidate waste forms to evaluate their ability to meet potential waste acceptance criteria for immobilized secondary wastes that would be placed in the IDF. All three waste forms demonstrated compressive strengths above the minimum 3.45 MPa (500 psi) set as a target for cement-based waste forms. Further, none of the waste forms showed any significant degradation in compressive strength after undergoing thermal cycling (30 cycles in a 10 day period) between -40 C and 60 C or water immersion for 90 days. The three leach test methods are intended to measure the diffusion rates of contaminants from the waste forms. Results are reported in terms of diffusion coefficients and a leachability index (LI) calculated based on the diffusion coefficients. A smaller diffusion coefficient and a larger LI are desired. The NRC, in its Waste Form Technical Position (NRC 1991), provides recommendations and guidance regarding methods to demonstrate waste stability for land disposal of radioactive waste. Included is a recommendation to conduct leach tests using the ANS 16.1 method. The resulting leachability index (LI) should be greater than 6.0. For Hanford secondary wastes, the LI > 6.0 criterion applies to sodium leached from the waste form. For technetium and iodine, higher targets of LI > 9 for Tc and LI > 11 for iodine have been set based on early waste-disposal risk and performance assessment analyses. The results of these three leach tests conducted for a total time between 11days (ASTM C1308) to 90 days (ANS 16.1) showed: (1) Technetium diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that

  9. Statistical analysis of the dynamics of secondary electrons in the flare of a high-voltage beam-type discharge

    SciTech Connect (OSTI)

    Demkin, V. P.; Mel'nichuk, S. V.

    2014-09-15

    In the present work, results of investigations into the dynamics of secondary electrons with helium atoms in the presence of the reverse electric field arising in the flare of a high-voltage pulsed beam-type discharge and leading to degradation of the primary electron beam are presented. The electric field in the discharge of this type at moderate pressures can reach several hundred V/cm and leads to considerable changes in the kinetics of secondary electrons created in the process of propagation of the electron beam generated in the accelerating gap with a grid anode. Moving in the accelerating electric field toward the anode, secondary electrons create the so-called compensating current to the anode. The character of electron motion and the compensating current itself are determined by the ratio of the field strength to the concentration of atoms (E/n). The energy and angular spectra of secondary electrons are calculated by the Monte Carlo method for different ratios E/n of the electric field strength to the helium atom concentration. The motion of secondary electrons with threshold energy is studied for inelastic collisions of helium atoms and differential analysis is carried out of the collisional processes causing energy losses of electrons in helium for different E/n values. The mechanism of creation and accumulation of slow electrons as a result of inelastic collisions of secondary electrons with helium atoms and selective population of metastable states of helium atoms is considered. It is demonstrated that in a wide range of E/n values the motion of secondary electrons in the beam-type discharge flare has the character of drift. At E/n values characteristic for the discharge of the given type, the drift velocity of these electrons is calculated and compared with the available experimental data.

  10. Spitzer and z' secondary eclipse observations of the highly irradiated transiting brown dwarf KELT-1b

    SciTech Connect (OSTI)

    Beatty, Thomas G.; Gaudi, B. Scott; Collins, Karen A.; Kielkopf, John F.; Fortney, Jonathan; Knutson, Heather; Bruns, Jacob M.; Showman, Adam P.; Eastman, Jason; Pepper, Joshua; Siverd, Robert J.; Stassun, Keivan G.

    2014-03-10

    We present secondary eclipse observations of the highly irradiated transiting brown dwarf KELT-1b. These observations represent the first constraints on the atmospheric dynamics of a highly irradiated brown dwarf, the atmospheres of irradiated giant planets at high surface gravity, and the atmospheres of brown dwarfs that are dominated by external, rather than internal, energy. Using the Spitzer Space Telescope, we measure secondary eclipse depths of 0.195% ± 0.010% at 3.6 μm and 0.200% ± 0.012% at 4.5 μm. We also find tentative evidence for the secondary eclipse in the z' band with a depth of 0.049% ± 0.023%. These measured eclipse depths are most consistent with an atmosphere model in which there is a strong substellar hotspot, implying that heat redistribution in the atmosphere of KELT-1b is low. While models with a more mild hotspot or even with dayside heat redistribution are only marginally disfavored, models with complete heat redistribution are strongly ruled out. The eclipse depths also prefer an atmosphere with no TiO inversion layer, although a model with TiO inversion is permitted in the dayside heat redistribution case, and we consider the possibility of a day-night TiO cold trap in this object. For the first time, we compare the IRAC colors of brown dwarfs and hot Jupiters as a function of effective temperature. Importantly, our measurements reveal that KELT-1b has a [3.6] – [4.5] color of 0.07 ± 0.11, identical to that of isolated brown dwarfs of similarly high temperature. In contrast, hot Jupiters generally show redder [3.6] – [4.5] colors of ∼0.4, with a very large range from ∼0 to ∼1. Evidently, despite being more similar to hot Jupiters than to isolated brown dwarfs in terms of external forcing of the atmosphere by stellar insolation, KELT-1b appears to have an atmosphere most like that of other brown dwarfs. This suggests that surface gravity is very important in controlling the atmospheric systems of substellar mass bodies.

  11. Controlling the secondary flow in a turbine cascade by three-dimensional airfoil design and endwall contouring

    SciTech Connect (OSTI)

    Duden, A.; Fottner, L.; Raab, I.

    1999-04-01

    A highly loaded turbine cascade has been redesigned with the objective to reduce the secondary flow by applying endwall contouring and three-dimensional airfoil design in the endwall regions. The overall loading and the axial area ratio of the cascade have been kept constant. With the tools of a three-dimensional design environment, a systematic study has been carried out regarding several features of the endwall pressure distribution and their influence on the secondary flow. Two optimized configurations have been investigated in a high-speed cascade wind tunnel. The flow field traverses showed improvements concerning the radial extent of the secondary flow and a decrease in secondary loss of 26%. Unfortunately this reduction was counterbalanced by increased profile losses and higher inlet losses due to increased blockage. The striking feature of the cascade with endwall contouring and three-dimensional airfoil design was a significant reduction of the exit flow angle deviations connected with the secondary flow. The predictions obtained by the three-dimensional Navier-Stokes solver TRACE{_}S showed a remarkable agreement with the experimental results.

  12. Understanding catalyst behavior during in situ heating through simultaneous secondary and transmitted electron imaging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Howe, Jane Y.; Allard, Jr., Lawrence Frederick; Demers, Hendrix; Bigelow, Wilbur C.; Steven H. Overbury

    2014-11-14

    In situ heating study via a simultaneous secondary electron (SE) and transmitted electron (TE) microscopy is extremely insightful because information from the surface (SE) and bulk (TE) can be readily obtained. The leached Au/Fe2O3 catalyst has voids on the surface of Fe2O3. Upon heating to 500 °C, voids shrank and disappeared, while internal Au species diffused to the surface to form new nanoparticles. Heating in vacuum reduced Fe2O3 to Fe3O4. Heating at 700 °C caused coalescence and growth of Au particles and formation of faceted Fe3O4 surfaces. We achieved 1.1 nm resolution in SE imaging during in situ heating.

  13. Laser-driven miniature flyer plates for shock initiation of secondary explosives

    SciTech Connect (OSTI)

    Paisley, D.L.

    1989-01-01

    Miniature flyer plates (<1-mm diameter X <5-micron thick) of aluminum and other materials are accelerated by a 10-ns pulsed Nd:YAG laser to velocities >5 km/s. Velocity profiles are recorded by velocity interferometry (VISAR) techniques and impact planarity by electronic streak photography. Techniques for improving energy coupling from laser to flyer plate will be discussed. Flyer plate performance parameters will be compared with material properties. The P/sup n/t criteria for shock initiation of explosives will be compared for various flyer materials, pressure, and pulse duration. Performance of secondary explosives (PETN, HNS, HMX, various PBX, others) will be reported. These data will detail the experimental effect of t (in P/sup n/t) approaching values of a few nanoseconds. 9 refs., 5 figs.

  14. Comparison endpoint study of process plasma and secondary electron beam exciter optical emission spectroscopy

    SciTech Connect (OSTI)

    Stephan Thamban, P. L.; Yun, Stuart; Padron-Wells, Gabriel; Hosch, Jimmy W.; Goeckner, Matthew J.

    2012-11-15

    Traditionally process plasmas are often studied and monitored by optical emission spectroscopy. Here, the authors compare experimental measurements from a secondary electron beam excitation and direct process plasma excitation to discuss and illustrate its distinctiveness in the study of process plasmas. They present results that show excitations of etch process effluents in a SF{sub 6} discharge and endpoint detection capabilities in dark plasma process conditions. In SF{sub 6} discharges, a band around 300 nm, not visible in process emission, is observed and it can serve as a good indicator of etch product emission during polysilicon etches. Based on prior work reported in literature the authors believe this band is due to SiF{sub 4} gas phase species.

  15. Secondary Electron Yield Measurements of Fermilab?s Main Injector Vacuum Vessel

    SciTech Connect (OSTI)

    Scott, D.J.; Capista, D.; Duel, K.L.; Zwaska, R.M.; Greenwald, S.; Hartung, W.; Li, Y.; Moore, T.P.; Palmer, M.A.; Kirby, R.; Pivi, M.; /SLAC

    2012-05-01

    We discuss the progress made on a new installation in Fermilab's Main Injector that will help investigate the electron cloud phenomenon by making direct measurements of the secondary electron yield (SEY) of samples irradiated in the accelerator. In the Project X upgrade the Main Injector will have its beam intensity increased by a factor of three compared to current operations. This may result in the beam being subject to instabilities from the electron cloud. Measured SEY values can be used to further constrain simulations and aid our extrapolation to Project X intensities. The SEY test-stand, developed in conjunction with Cornell and SLAC, is capable of measuring the SEY from samples using an incident electron beam when the samples are biased at different voltages. We present the design and manufacture of the test-stand and the results of initial laboratory tests on samples prior to installation.

  16. Campaign 1.7 Pu Aging. Development of Time of Flight Secondary Ion Mass Spectroscopy

    SciTech Connect (OSTI)

    Venhaus, Thomas J.

    2015-09-09

    The first application of Time-of-Flight Secondary Ion Mass Spectroscopy (ToF-SIMS) to an aged plutonium surface has resulted in a rich set of surface chemistry data, as well as some unexpected results. FY15 was highlighted by not only the first mapping of hydrogen-containing features within the metal, but also a prove-in series of experiments using the system’s Sieverts Reaction Cell. These experiments involved successfully heating the sample to ~450 oC for nearly 24 hours while the sample was dosed several times with hydrogen, followed by an in situ ToF-SIMS analysis. During this year, the data allowed for better and more consistent identification of the myriad peaks that result from the SIMS sputter process. In collaboration with the AWE (U.K), the system was also fully aligned for sputter depth profiling for future experiments.

  17. Method of forming components for a high-temperature secondary electrochemical cell

    DOE Patents [OSTI]

    Mrazek, Franklin C. (Hickory Hills, IL); Battles, James E. (Oak Forest, IL)

    1983-01-01

    A method of forming a component for a high-temperature secondary electrochemical cell having a positive electrode including a sulfide selected from the group consisting of iron sulfides, nickel sulfides, copper sulfides and cobalt sulfides, a negative electrode including an alloy of aluminum and an electrically insulating porous separator between said electrodes. The improvement comprises forming a slurry of solid particles dispersed in a liquid electrolyte such as the lithium chloride-potassium chloride eutetic, casting the slurry into a form having the shape of one of the components and smoothing the exposed surface of the slurry, cooling the cast slurry to form the solid component, and removing same. Electrodes and separators can be thus formed.

  18. Method of forming components for a high-temperature secondary electrochemical cell

    DOE Patents [OSTI]

    Mrazek, F.C.; Battles, J.E.

    1981-05-22

    A method of forming a component for a high-temperature secondary electrochemical cell having a positive electrode including a sulfide selected from the group consisting of iron sulfides, nickel sulfides, copper sulfides and cobalt sulfides, a negative electrode including an alloy of aluminum and an electrically insulating porous separator between said electrodes is described. The improvement comprises forming a slurry of solid particles dispersed in a liquid electrolyte such as the lithium chloride-potassium chloride eutectic, casting the slurry into a form having the shape of one of the components and smoothing the exposed surface of the slurry, cooling the cast slurry to form the solid component, and removing same. Electrodes and separators can be thus formed.

  19. Estimations and prospects of secondary recovery through conventional gas and waterflooding

    SciTech Connect (OSTI)

    Araujo, J.B.

    1981-03-01

    Conventional waterflooding and/or gas injection have been used extensively for the production of additional hydrocarbons, preferably in light and medium oil reservoirs, and in a lesser extent in heavy oil reservoirs. There are 182 active projects of secondary recovery distributed in Venezuela as follows: 113 projects of gas injection, 64 of waterflooding, and 5 projects of simultaneous injection of gas and water. The daily production by using these methods is 800,000 bpd (40% of national production), and it is expected that 6,000 million bbl of additional oil will be recovered. An objective estimation of the active projects of gas injection and/or waterflooding performed at the present in Venezuela is presented based on statistical data and relevant results. The future prospects also are predicted and quantified.

  20. Method for producing a secondary lithium cell comprising a heat-sensitive protective mechanism

    DOE Patents [OSTI]

    Ullrich, Matthias; Bechtold, Dieter; Rabenstein, Heinrich; Brohm, Thomas

    2003-01-01

    A method for producing a secondary lithium cell which has at least one lithium-cycling negative electrode, at least one lithium-intercalating positive electrode, at least one separator disposed between the positive and the negative electrode, and a nonaqueous lithium ion-conducting electrolyte. The method is carried out by the electrodes and/or the separator being coated, by means of electrostatic powder coating, with wax particles which are insoluble in the electrolyte and have a melting temperature of from about 50 to about 150 .degree. C. and a mean particle size of from about 6 to about 20 .mu.m, the amount of wax being between about 0.5 and about 2.5 mg/cm.sup.2 of electrode area.

  1. Disparity of secondary electron emission in ferroelectric domains of YMnO{sub 3}

    SciTech Connect (OSTI)

    Cheng, Shaobo; Deng, S. Q.; Yuan, Wenjuan; Yan, Yunjie; Zhu, Jing; Li, J.; Li, J. Q.

    2015-07-20

    The applications of multiferroic materials require our understanding about the behaviors of domains with different polarization directions. Taking advantage of the scanning electron microscope, we investigate the polar surface of single crystal YMnO{sub 3} sample in secondary electron (SE) mode. By slowing down the scanning speed of electron beam, the negative surface potential of YMnO{sub 3} can be realized, and the domain contrast can be correspondingly changed. Under this experimental condition, with the help of a homemade Faraday cup, the difference of intrinsic SE emission coefficients of antiparallel domains is measured to be 0.12 and the downward polarization domains show a larger SE emission ability. Our results indicate that the total SE emission of this material can be altered by changing the ratio of the antiparallel domains, which provide an avenue for device design with this kind of materials.

  2. Formation mechanism of the secondary building unit in a chromium terephthalate metal-organic framework

    SciTech Connect (OSTI)

    Cantu Cantu, David; McGrail, B. Peter; Glezakou, Vassiliki Alexandra

    2014-09-18

    Based on density functional theory calculations and simulation, a detailed mechanism is presented on the formation of the secondary building unit (SBU) of MIL-101, a chromium terephthalate metal-organic framework (MOF). SBU formation is key to MOF nucleation, the rate-limiting step in the formation process of many MOFs. A series of reactions that lead to the formation of the SBU of MIL-101 is proposed in this work. Initial rate-limiting reactions form the metal cluster with three chromium (III) atoms linked to a central bridging oxygen. Terephthalate linkers play a key role as chromium (III) atoms are joined to linker carboxylate groups prior to the placement of the central bridging oxygen. Multiple linker addition reactions, which follow in different paths due to structural isomers, are limited by the removal of water molecules in the first chromium coordination shell. The least energy path is identified were all linkers on one face of the metal center plane are added first. A simple kinetic model based on transition state theory shows the rate of secondary building unit formation similar to the rate metal-organic framework nucleation. The authors are thankful to Dr. R. Rousseau for a critical reading of the manuscript. This research would not have been possible without the support of the Office of Fossil Energy, U.S. Department of Energy. This research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and the PNNL Institutional Computing (PIC) program located at Pacific Northwest National Laboratory.

  3. Decommissioning of the secondary containment of the steam generating heavy water reactor at UKAEA-Winfrith

    SciTech Connect (OSTI)

    Miller, Keith; Cornell, Rowland; Parkinson, Steve; McIntyre, Kevin; Staples, Andy

    2007-07-01

    Available in abstract form only. Full text of publication follows: The Winfrith SGHWR was a prototype nuclear power plant operated for 23 years by the United Kingdom Atomic Energy Authority (UKAEA) until 1990 when it was shut down permanently. The current Stage 1 decommissioning contract is part of a multi-stage strategy. It involves the removal of all the ancillary plant and equipment in the secondary containment and non-containment areas ahead of a series of contracts for the decommissioning of the primary containment, the reactor core and demolition of the building and all remaining facilities. As an outcome of a competitive tending process, the Stage 1 decommissioning contract was awarded to NUKEM with operations commencing in April 2005. The decommissioning processes involved with these plant items will be described with some emphasis of the establishment of multiple work-fronts for the production, recovery, treatment and disposal of mainly tritium-contaminated waste arising from its contact with the direct cycle reactor coolant. The means of size reduction of a variety of large, heavy and complex items of plant made from a range of materials will also be described with some emphasis on the control of fumes during hot cutting operations and establishing effective containments within a larger secondary containment structure. Disposal of these wastes in a timely and cost-effective manner is a major challenge facing the decommissioning team and has required the development of a highly efficient means of packing the resultant materials into mainly one-third height ISO containers for disposal as LLW. Details of the quantities of LLW and exempt wastes handled during this process will be given with a commentary about the difficulty in segregating these two waste streams efficiently. (authors)

  4. Nano-Scale Secondary Ion Mass Spectrometry - A new analytical tool in biogeochemistry and soil ecology

    SciTech Connect (OSTI)

    Herrmann, A M; Ritz, K; Nunan, N; Clode, P L; Pett-Ridge, J; Kilburn, M R; Murphy, D V; O'Donnell, A G; Stockdale, E A

    2006-10-18

    Soils are structurally heterogeneous across a wide range of spatio-temporal scales. Consequently, external environmental conditions do not have a uniform effect throughout the soil, resulting in a large diversity of micro-habitats. It has been suggested that soil function can be studied without explicit consideration of such fine detail, but recent research has indicated that the micro-scale distribution of organisms may be of importance for a mechanistic understanding of many soil functions. Due to a lack of techniques with adequate sensitivity for data collection at appropriate scales, the question 'How important are various soil processes acting at different scales for ecological function?' is challenging to answer. The nano-scale secondary ion mass spectrometer (NanoSIMS) represents the latest generation of ion microprobes which link high-resolution microscopy with isotopic analysis. The main advantage of NanoSIMS over other secondary ion mass spectrometers is the ability to operate at high mass resolution, whilst maintaining both excellent signal transmission and spatial resolution ({approx}50 nm). NanoSIMS has been used previously in studies focusing on presolar materials from meteorites, in material science, biology, geology and mineralogy. Recently, the potential of NanoSIMS as a new tool in the study of biophysical interfaces in soils has been demonstrated. This paper describes the principles of NanoSIMS and discusses the potential of this tool to contribute to the field of biogeochemistry and soil ecology. Practical considerations (sample size and preparation, simultaneous collection of isotopes, mass resolution, isobaric interference and quantification of the isotopes of interest) are discussed. Adequate sample preparation avoiding biases in the interpretation of NanoSIMS data due to artifacts and identification of regions-of interest are of most concerns in using NanoSIMS as a new tool in biogeochemistry and soil ecology. Finally, we review the areas of

  5. Secondary Heat Exchanger Design and Comparison for Advanced High Temperature Reactor

    SciTech Connect (OSTI)

    Piyush Sabharwall; Ali Siahpush; Michael McKellar; Michael Patterson; Eung Soo Kim

    2012-06-01

    The goals of next generation nuclear reactors, such as the high temperature gas-cooled reactor and advance high temperature reactor (AHTR), are to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. The need for efficiency, compactness, and safety challenge the boundaries of existing heat exchanger technology, giving rise to the following study. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more efficient conversion cycles, such as the Rankine super critical and subcritical cycles. This study considers two different types of heat exchangers—helical coiled heat exchanger and printed circuit heat exchanger—as possible options for the AHTR secondary heat exchangers with the following three different options: (1) A single heat exchanger transfers all the heat (3,400 MW(t)) from the intermediate heat transfer loop to the power conversion system or process plants; (2) Two heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants, each exchanger transfers 1,700 MW(t) with a parallel configuration; and (3) Three heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants. Each heat exchanger transfers 1,130 MW(t) with a parallel configuration. A preliminary cost comparison will be provided for all different cases along with challenges and recommendations.

  6. SPITZER IRAC SECONDARY ECLIPSE PHOTOMETRY OF THE TRANSITING EXTRASOLAR PLANET HAT-P-1b

    SciTech Connect (OSTI)

    Todorov, Kamen; Deming, Drake; Harrington, Jospeph; Stevenson, Kevin B.; Bowman, William C.; Nymeyer, Sarah; Fortney, Jonathan J.; Bakos, Gaspar A.

    2010-01-01

    We report Spitzer/IRAC photometry of the transiting giant exoplanet HAT-P-1b during its secondary eclipse. This planet lies near the postulated boundary between the pM and pL-class of hot Jupiters, and is important as a test of models for temperature inversions in hot Jupiter atmospheres. We derive eclipse depths for HAT-P-1b, in units of the stellar flux, that are: 0.080% +- 0.008% [3.6 mum], 0.135% +- 0.022% [4.5 mum], 0.203% +- 0.031% [5.8 mum], and 0.238% +- 0.040% [8.0 mum]. These values are best fit using an atmosphere with a modest temperature inversion, intermediate between the archetype inverted atmosphere (HD 209458b) and a model without an inversion. The observations also suggest that this planet is radiating a large fraction of the available stellar irradiance on its dayside, with little available for redistribution by circulation. This planet has sometimes been speculated to be inflated by tidal dissipation, based on its large radius in discovery observations, and on a non-zero orbital eccentricity allowed by the radial velocity data. The timing of the secondary eclipse is very sensitive to orbital eccentricity, and we find that the central phase of the eclipse is 0.4999 +- 0.0005. The difference between the expected and observed phase indicates that the orbit is close to circular, with a 3sigma limit of |e cos omega| < 0.002.

  7. Contrasting diversity patterns of soil mites and nematodes in secondary succession

    SciTech Connect (OSTI)

    Kardol, Paul; Newton, Jeffrey S.; Bezemer, T Martijn; Maraun, Mark; van der Putten, Wim H.

    2009-01-01

    Soil biodiversity has been recognized as a key feature of ecosystem functioning and stability. However, soil biodiversity is strongly impaired by agriculture and relatively little is known on how and at what spatial and temporal scales soil biodiversity is restored after the human disturbances have come to an end. Here, a multi-scale approach was used to compare diversity patterns of soil mites and nematodes at four stages (early, mid, late, reference site) along a secondary succession chronosequence from abandoned arable land to heath land. In each field four soil samples were taken during four successive seasons. We determined soil diversity within samples ({alpha}-diversity), between samples ({beta}-diversity) and within field sites ({gamma}-diversity). The patterns of {alpha}- and {gamma}-diversity developed similarly along the chronosequence for oribatid mites, but not for nematodes. Nematode {alpha}-diversity was highest in mid- and late-successional sites, while {gamma}-diversity was constant along the chronosequence. Oribatid mite {beta}-diversity was initially high, but decreased thereafter, whereas nematode {beta}-diversity increased when succession proceeded; indicating that patterns of within-site heterogeneity diverged for oribatid mites and nematodes. The spatio-temporal diversity patterns after land abandonment suggest that oribatid mite community development depends predominantly on colonization of new taxa, whereas nematode community development depends on shifts in dominance patterns. This would imply that at old fields diversity patterns of oribatid mites are mainly controlled by dispersal, whereas diversity patterns of nematodes are mainly controlled by changing abiotic or biotic soil conditions. Our study shows that the restoration of soil biodiversity along secondary successional gradients can be both scale- and phylum-dependent.

  8. Secondary Waste Form Screening Test ResultsCast Stone and Alkali Alumino-Silicate Geopolymer

    SciTech Connect (OSTI)

    Pierce, Eric M.; Cantrell, Kirk J.; Westsik, Joseph H.; Parker, Kent E.; Um, Wooyong; Valenta, Michelle M.; Serne, R. Jeffrey

    2010-06-28

    PNNL is conducting screening tests on the candidate waste forms to provide a basis for comparison and to resolve the formulation and data needs identified in the literature review. This report documents the screening test results on the Cast Stone cementitious waste form and the Geopolymer waste form. Test results suggest that both the Cast Stone and Geopolymer appear to be viable waste forms for the solidification of the secondary liquid wastes to be treated in the ETF. The diffusivity for technetium from the Cast Stone monoliths was in the range of 1.2 10-11 to 2.3 10-13 cm2/s during the 63 days of testing. The diffusivity for technetium from the Geopolymer was in the range of 1.7 10-10 to 3.8 10-12 cm2/s through the 63 days of the test. These values compare with a target of 1 10-9 cm2/s or less. The Geopolymer continues to show some fabrication issues with the diffusivities ranging from 1.7 10-10 to 3.8 10-12 cm2/s for the better-performing batch to from 1.2 10-9 to 1.8 10-11 cm2/s for the poorer-performing batch. In the future more comprehensive and longer term performance testing will be conducted, to further evaluate whether or not these waste forms will meet the regulation and performance criteria needed to cost-effectively dispose of secondary wastes.

  9. Simulation investigation of multipactor in metal components for space application with an improved secondary emission model

    SciTech Connect (OSTI)

    Li, Yun E-mail: cuiwanzhao@126.com; Cui, Wan-Zhao E-mail: cuiwanzhao@126.com; Wang, Hong-Guang

    2015-05-15

    Effects of the secondary electron emission (SEE) phenomenon of metal surface on the multipactor analysis of microwave components are investigated numerically and experimentally in this paper. Both the secondary electron yield (SEY) and the emitted energy spectrum measurements are performed on silver plated samples for accurate description of the SEE phenomenon. A phenomenological probabilistic model based on SEE physics is utilized and fitted accurately to the measured SEY and emitted energy spectrum of the conditioned surface material of microwave components. Specially, the phenomenological probabilistic model is extended to the low primary energy end lower than 20 eV mathematically, since no accurate measurement data can be obtained. Embedding the phenomenological probabilistic model into the Electromagnetic Particle-In-Cell (EM-PIC) method, the electronic resonant multipacting in microwave components can be tracked and hence the multipactor threshold can be predicted. The threshold prediction error of the transformer and the coaxial filter is 0.12 dB and 1.5 dB, respectively. Simulation results demonstrate that the discharge threshold is strongly dependent on the SEYs and its energy spectrum in the low energy end (lower than 50 eV). Multipacting simulation results agree quite well with experiments in practical components, while the phenomenological probabilistic model fit both the SEY and the emission energy spectrum better than the traditionally used model and distribution. The EM-PIC simulation method with the phenomenological probabilistic model for the surface collision simulation has been demonstrated for predicting the multipactor threshold in metal components for space application.

  10. Electron Flood Charge Compensation Device for Ion Trap Secondary Ion Mass Spectrometry

    SciTech Connect (OSTI)

    Appelhans, Anthony David; Ward, Michael Blair; Olson, John Eric

    2002-11-01

    During secondary ion mass spectrometry (SIMS) analyses of organophosphorous compounds adsorbed onto soils, the measured anion signals were lower than expected and it was hypothesized that the low signals could be due to sample charging. An electron flood gun was designed, constructed and used to investigate sample charging of these and other sample types. The flood gun was integrated into one end cap of an ion trap secondary ion mass spectrometer and the design maintained the geometry of the self-stabilizing extraction optics used in this instrument. The SIMION ion optics program was used to design the flood gun, and experimental results agreed with the predicted performance. Results showed the low anion signals from the soils were not due to sample charging. Other insulating and conducting samples were tested using both a ReO4- and a Cs+ primary ion beam. The proximity of the sample and electron source to the ion trap aperture resulted in generation of background ions in the ion trap via electron impact (EI) ionization during the period the electron gun was flooding the sample region. When using the electron gun with the ReO4- primary beam, the required electron current was low enough that the EI background was negligible; however, the high electron flood current required with the Cs+ beam produced background EI ions that degraded the quality of the mass spectra. The consequences of the EI produced cations will have to be evaluated on a sample-by-sample basis when using electron flood. It was shown that the electron flood gun could be intentionally operated to produce EI spectra in this instrument. This offers the opportunity to measure, nearly simultaneously, species evaporating from a sample, via EI, and species bound to the surface, via SIMS.

  11. Report of the Snowmass T4 working group on particle sources: Positron sources, anti-proton sources and secondary beams

    SciTech Connect (OSTI)

    N. Mokhov et al.

    2002-12-05

    This report documents the activities of the Snowmass 2001 T4 Particle Sources Working Group. T4 was charged with examining the most challenging aspects of positron sources for linear colliders and antiproton sources for proton-antiproton colliders, and the secondary beams of interest to the physics community that will be available from the next generation of high-energy particle accelerators. The leading issues, limiting technologies, and most important R and D efforts of positron production, antiproton production, and secondary beams are discussed in this paper. A listing of T4 Presentations is included.

  12. Secondary Waste Form Down-Selection Data Package—DuraLith

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Westsik, Joseph H.

    2011-09-15

    This data package developed for the DuraLith wasteform includes information available in the open literature and from data obtained from testing currently underway. DuraLith is an alkali-activated geopolymer waste form developed by the Vitreous State Laboratory at The Catholic University of America (VSL-CUA) for encapsulating liquid radioactive waste. A DuraLith waste form developed for treating Hanford secondary waste liquids is prepared by alkali-activation of a mixture of ground blast furnace slag and metakaolinite with sand used as a filler material. Based on optimization tests, solid waste loading of {approx}7.5% and {approx}14.7 % has been achieved using the Hanford secondary waste S1 and S4 simulants, respectively. The Na loading in both cases is equivalent to {approx}6 M. Some of the critical parameters for the DuraLith process include, hydrogen generation and heat evolution during activator solution preparation using the waste simulant, heat evolution during and after mixing the activator solution with the dry ingredients, and a working window of {approx}20 minutes to complete the pouring of the DuraLith mixture into molds. Results of the most recent testing indicated that the working window can be extended to {approx}30 minutes if 75 wt% of the binder components, namely, blast furnace slag and metakaolin are replaced by Class F fly ash. A preliminary DuraLith process flow sheet developed by VSL-CUA for processing Hanford secondary waste indicated that 10 to 22 waste monoliths (each 48 ft3 in volume) can be produced per day. There are no current pilot-scale or full-scale DuraLith plants under construction or in operation; therefore, the cost of DuraLith production is unknown. The results of the non-regulatory leach tests, EPA Draft 1313 and 1316, Waste Simulant S1-optimized DuraLith specimens indicated that the concentrations of RCRA metals (Ag, Cd, Cr, Hg, and Pb) in the leachates were well below the Universal Treatment Standard limits in 40 CFR 268

  13. Cathodes for secondary electrochemical power-producing cells. [layers of porous substrates impregnated with S alternate with layers containing electrolyte

    DOE Patents [OSTI]

    Cairns, E.J.; Kyle, M.; Shimotake, H.

    1973-02-13

    A secondary electrochemical power-producing cell includes an anode containing lithium, an electrolyte containing lithium ions, and a cathode containing sulfur. The cathode comprises plates of a porous substrate material impregnated with sulfur alternating with layers (which may also comprise porous substrate plates) containing electrolyte.

  14. Decommissioning of the secondary containment of the steam generating heavy water reactor at UKAEA Winfrith

    SciTech Connect (OSTI)

    Miller, K.D.; Cornell, R.M.; Parkinson, S.J.; McIntyre, K.; Staples, A.

    2007-07-01

    The Winfrith SGHWR was a prototype nuclear power plant operated for 23 years by the United Kingdom Atomic Energy Authority (UKAEA) until 1990 when it was shut down permanently. The current Stage 1 decommissioning contract is part of a multi-stage strategy. It involves the removal of all the ancillary plant and equipment in the secondary containment and non-containment areas ahead of a series of contracts for the decommissioning of the primary containment, the reactor core and demolition of the building and ail remaining facilities. As an outcome of a competitive tending process, the Stage 1 decommissioning contract was awarded to NUKEM with operations commencing in April 2005. The decommissioning processes involved with these plant items will be described with some emphasis of the establishment of multiple work-fronts for the production, recovery, treatment and disposal of mainly tritium-contaminated waste arising from its contact with the direct cycle reactor coolant. The means of size reduction of a variety of large, heavy and complex items of plant made from a range of materials will also be described with some emphasis on the control of fumes during hot cutting operations and establishing effective containments within a larger secondary containment structure. Disposal of these wastes in a timely and cost-effective manner is a major challenge facing the decommissioning team and has required the development of a highly efficient means of packing the resultant materials into mainly one-third height IS0 containers for disposal as LLW. Details of the quantities of LLW and exempt wastes handled during this process will be given with a commentary about the difficulty in segregating these two waste streams efficiently. The paper sets out to demonstrate the considerable progress that has been made with these challenging decommissioning operations at the SGHWR plant and to highlight some of the techniques and processes that have contributed to the overall success of the

  15. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) bothmore » significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the

  16. Low Dose Gamma Irradiation Potentiates Secondary Exposure to Gamma Rays or Protons in Thyroid Tissue Analogs

    SciTech Connect (OSTI)

    Green, Lora M

    2006-05-25

    We have utilized our unique bioreactor model to produce three-dimensional thyroid tissue analogs that we believe better represent the effects of radiation in vivo than two-dimensional cultures. Our thyroid model has been characterized at multiple levels, including: cell-cell exchanges (bystander), signal transduction, functional changes and modulation of gene expression. We have significant preliminary data on structural, functional, signal transduction and gene expression responses from acute exposures at high doses (50-1000 rads) of gamma, protons and iron (Green et al., 2001a; 2001b; 2002a; 2002b; 2005). More recently, we used our DOE funding (ending Feb 06) to characterize the pattern of radiation modulated gene expression in rat thyroid tissue analogs using low-dose/low-dose rate radiation, plus/minus acute challenge exposures. Findings from these studies show that the low-dose/low-dose rate priming exposures to radiation invoked changes in gene expression profiles that varied with dose and time. The thyrocytes transitioned to a primed state, so that when the tissue analogs were challenged with an acute exposure to radiation they had a muted response (or an increased resistance) to cytopathological changes relative to un-primed cells. We measured dramatic differences in the primed tissue analogs, showing that our original hypothesis was correct: that low dose gamma irradiation will potentiate the repair/adaptation response to a secondary exposure. Implications from these findings are that risk assessments based on classical in vitro tissue culture assays will overestimate risk, and that low dose rate priming results in a reduced response in gene expression to a secondary challenge exposure, which implies that a priming dose provides enhanced protection to thyroid cells grown as tissue analogs. If we can determine that the effects of radiation on our tissue analogs more closely resemble the effects of radiation in vivo, then we can better estimate the

  17. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    SciTech Connect (OSTI)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) both significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly

  18. IMG-ABC. A knowledge base to fuel discovery of biosynthetic gene clusters and novel secondary metabolites

    SciTech Connect (OSTI)

    Hadjithomas, Michalis; Chen, I-Min Amy; Chu, Ken; Ratner, Anna; Palaniappan, Krishna; Szeto, Ernest; Huang, Jinghua; Reddy, T. B. K.; Cimermančič, Peter; Fischbach, Michael A.; Ivanova, Natalia N.; Markowitz, Victor M.; Kyrpides, Nikos C.; Pati, Amrita

    2015-07-14

    In the discovery of secondary metabolites, analysis of sequence data is a promising exploration path that remains largely underutilized due to the lack of computational platforms that enable such a systematic approach on a large scale. In this work, we present IMG-ABC (https://img.jgi.doe.gov/abc), an atlas of biosynthetic gene clusters within the Integrated Microbial Genomes (IMG) system, which is aimed at harnessing the power of “big” genomic data for discovering small molecules. IMG-ABC relies on IMG’s comprehensive integrated structural and functional genomic data for the analysis of biosynthetic gene clusters (BCs) and associated secondary metabolites (SMs). SMs and BCs serve as the two main classes of objects in IMG-ABC, each with a rich collection of attributes. A unique feature of IMG-ABC is the incorporation of both experimentally validated and computationally predicted BCs in genomes as well as metagenomes, thus identifying BCs in uncultured populations and rare taxa. We demonstrate the strength of IMG-ABC’s focused integrated analysis tools in enabling the exploration of microbial secondary metabolism on a global scale, through the discovery of phenazine-producing clusters for the first time in lphaproteobacteria. IMG-ABC strives to fill the long-existent void of resources for computational exploration of the secondary metabolism universe; its underlying scalable framework enables traversal of uncovered phylogenetic and chemical structure space, serving as a doorway to a new era in the discovery of novel molecules. IMG-ABC is the largest publicly available database of predicted and experimental biosynthetic gene clusters and the secondary metabolites they produce. The system also includes powerful search and analysis tools that are integrated with IMG’s extensive genomic/metagenomic data and analysis tool kits. As new research on biosynthetic gene clusters and secondary metabolites is published and more genomes are sequenced, IMG

  19. IMG-ABC. A knowledge base to fuel discovery of biosynthetic gene clusters and novel secondary metabolites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hadjithomas, Michalis; Chen, I-Min Amy; Chu, Ken; Ratner, Anna; Palaniappan, Krishna; Szeto, Ernest; Huang, Jinghua; Reddy, T. B. K.; Cimermančič, Peter; Fischbach, Michael A.; et al

    2015-07-14

    In the discovery of secondary metabolites, analysis of sequence data is a promising exploration path that remains largely underutilized due to the lack of computational platforms that enable such a systematic approach on a large scale. In this work, we present IMG-ABC (https://img.jgi.doe.gov/abc), an atlas of biosynthetic gene clusters within the Integrated Microbial Genomes (IMG) system, which is aimed at harnessing the power of “big” genomic data for discovering small molecules. IMG-ABC relies on IMG’s comprehensive integrated structural and functional genomic data for the analysis of biosynthetic gene clusters (BCs) and associated secondary metabolites (SMs). SMs and BCs serve asmore » the two main classes of objects in IMG-ABC, each with a rich collection of attributes. A unique feature of IMG-ABC is the incorporation of both experimentally validated and computationally predicted BCs in genomes as well as metagenomes, thus identifying BCs in uncultured populations and rare taxa. We demonstrate the strength of IMG-ABC’s focused integrated analysis tools in enabling the exploration of microbial secondary metabolism on a global scale, through the discovery of phenazine-producing clusters for the first time in lphaproteobacteria. IMG-ABC strives to fill the long-existent void of resources for computational exploration of the secondary metabolism universe; its underlying scalable framework enables traversal of uncovered phylogenetic and chemical structure space, serving as a doorway to a new era in the discovery of novel molecules. IMG-ABC is the largest publicly available database of predicted and experimental biosynthetic gene clusters and the secondary metabolites they produce. The system also includes powerful search and analysis tools that are integrated with IMG’s extensive genomic/metagenomic data and analysis tool kits. As new research on biosynthetic gene clusters and secondary metabolites is published and more genomes are sequenced, IMG

  20. Risk Factors Associated With Secondary Sarcomas in Childhood Cancer Survivors: A Report From the Childhood Cancer Survivor Study

    SciTech Connect (OSTI)

    Henderson, Tara O.; Rajaraman, Preetha; Stovall, Marilyn; Constine, Louis S.; Olive, Aliza; Smith, Susan A.; Mertens, Ann; Meadows, Anna; Neglia, Joseph P.; Hammond, Sue; Whitton, John; Inskip, Peter D.; Robison, Leslie L.; Diller, Lisa

    2012-09-01

    Purpose: Childhood cancer survivors have an increased risk of secondary sarcomas. To better identify those at risk, the relationship between therapeutic dose of chemotherapy and radiation and secondary sarcoma should be quantified. Methods and Materials: We conducted a nested case-control study of secondary sarcomas (105 cases, 422 matched controls) in a cohort of 14,372 childhood cancer survivors. Radiation dose at the second malignant neoplasm (SMN) site and use of chemotherapy were estimated from detailed review of medical records. Odds ratios (ORs) and 95% confidence intervals were estimated by conditional logistic regression. Excess odds ratio (EOR) was modeled as a function of radiation dose, chemotherapy, and host factors. Results: Sarcomas occurred a median of 11.8 years (range, 5.3-31.3 years) from original diagnosis. Any exposure to radiation was associated with increased risk of secondary sarcoma (OR = 4.1, 95% CI = 1.8-9.5). A dose-response relation was observed, with elevated risks at doses between 10 and 29.9 Gy (OR = 15.6, 95% CI = 4.5-53.9), 30-49.9 Gy (OR = 16.0, 95% CI 3.8-67.8) and >50 Gy (OR = 114.1, 95% CI 13.5-964.8). Anthracycline exposure was associated with sarcoma risk (OR = 3.5, 95% CI = 1.6-7.7) adjusting for radiation dose, other chemotherapy, and primary cancer. Adjusting for treatment, survivors with a first diagnosis of Hodgkin lymphoma (OR = 10.7, 95% CI = 3.1-37.4) or primary sarcoma (OR = 8.4, 95% CI = 3.2-22.3) were more likely to develop a sarcoma. Conclusions: Of the risk factors evaluated, radiation exposure was the most important for secondary sarcoma development in childhood cancer survivors; anthracycline chemotherapy exposure was also associated with increased risk.

  1. Mineral Dissolution and Secondary Precipitation on Quartz Sand in Simulated Hanford Tank Solutions Affecting Subsurface Porosity

    SciTech Connect (OSTI)

    Wang, Guohui; Um, Wooyong

    2012-11-23

    Highly alkaline nuclear waste solutions have been released from underground nuclear waste storage tanks and pipelines into the vadose zone at the U.S. Department of Energys Hanford Site in Washington, causing mineral dissolution and re-precipitation upon contact with subsurface sediments. High pH caustic NaNO3 solutions with and without dissolved Al were reacted with quartz sand through flow-through columns stepwise at 45, 51, and 89C to simulate possible reactions between leaked nuclear waste solution and primary subsurface mineral. Upon reaction, Si was released from the dissolution of quartz sand, and nitrate-cancrinite [Na8Si6Al6O24(NO3)2] precipitated on the quartz surface as a secondary mineral phase. Both steady-state dissolution and precipitation kinetics were quantified, and quartz dissolution apparent activation energy was determined. Mineral alteration through dissolution and precipitation processes results in pore volume and structure changes in the subsurface porous media. In this study, the column porosity increased up to 40.3% in the pure dissolution column when no dissolved Al was present in the leachate, whereas up to a 26.5% porosity decrease was found in columns where both dissolution and precipitation were observed because of the presence of Al in the input solution. The porosity change was also confirmed by calculation using the dissolution and precipitation rates and mineral volume changes.

  2. Waste Heat Recovery from the Advanced Test Reactor Secondary Coolant Loop

    SciTech Connect (OSTI)

    Donna Post Guillen

    2012-11-01

    This study investigated the feasibility of using a waste heat recovery system (WHRS) to recover heat from the Advanced Test Reactor (ATR) secondary coolant system (SCS). This heat would be used to preheat air for space heating of the reactor building, thus reducing energy consumption, carbon footprint, and energy costs. Currently, the waste heat from the reactor is rejected to the atmosphere via a four-cell, induced-draft cooling tower. Potential energy and cost savings are 929 kW and $285K/yr. The WHRS would extract a tertiary coolant stream from the SCS loop and pump it to a new plate and frame heat exchanger, from which the heat would be transferred to a glycol loop for preheating outdoor air supplied to the heating and ventilation system. The use of glycol was proposed to avoid the freezing issues that plagued and ultimately caused the failure of a WHRS installed at the ATR in the 1980s. This study assessed the potential installation of a new WHRS for technical, logistical, and economic feasibility.

  3. Effects of magnetization on fusion product trapping and secondary neutron spectra

    SciTech Connect (OSTI)

    Knapp, Patrick F.; Schmit, Paul F.; Hansen, Stephanie B.; Gomez, Matthew R.; Hahn, Kelly D.; Sinars, Daniel Brian; Peterson, Kyle J.; Slutz, Stephen A.; Sefkow, Adam B.; Awe, Thomas James; Harding, Eric; Jennings, Christopher A.; Desjarlais, M. P.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Geissel, Matthias; Harvey-Thompson, Adam James; Porter, John L.; Rochau, Gregory A.; Rovang, Dean C.; Ruiz, Carlos L.; Savage, Mark E.; Smith, Ian C.; Stygar, William A.; Herrmann, Mark

    2015-05-14

    In magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, we found that the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used to infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ?R, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner InertialFusion experiments conducted on the Z machine at Sandia National Laboratories. Furthermore, we show that in these experiments BR ? 0.34(+0.14/-0.06) MG cm, a ~ 14 increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. Lastly, this is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.

  4. 9 M.y. record of southern Nevada climate from Yucca Mountain secondary minerals

    SciTech Connect (OSTI)

    Whelan, J.F.; Moscati, R.J.

    1998-12-01

    Yucca Mountain, Nevada, is presently the object of intense study as a potential permanent repository for the Nation`s high-level radioactive wastes. The mountain consists of a thick sequence of volcanic tuffs within which the depth to water table ranges from 500 to 700 meters below the land surface. This thick unsaturated zone (UZ), which would host the projected repository, coupled with the present day arid to semi-arid climate, is considered a favorable attribute of the site. Evaluation of the site includes defining the relation between climate variability, as the input function or driver of site- and regional-scale ground-water flow, and the possible future transport and release of radionuclides to the accessible environment. Secondary calcite and opal have been deposited in the UZ by meteoric waters that infiltrated through overlying soils and percolated through the tuffs. The oxygen isotopic composition ({delta}{sup 18}O values) of these minerals reflect contemporaneous meteoric waters and the {delta}{sup 13}C values reflect soil organic matter, and hence the resident plant community, at the time of infiltration. Recent U/Pb age determinations of opal in these occurrences, coupled with the {delta}{sup 13}C values of associated calcite, allow broadbrush reconstructions of climate patterns during the past 9 M.y.

  5. Prompt laser ignition and transition to detonation in a secondary explosive

    SciTech Connect (OSTI)

    Setchell, R.E.; Trott, W.M.

    1995-05-01

    A two-stage approach to achieving detonation in a secondary explosive was developed in previous studies in which ignition resulted from low-energy hot wires or from laser diodes. In the current study, this approach was examined in some detail for the case of ignition by a pulsed, solid-state (rod) laser. An initial series of experiments used Nd/glass, Nd/YAG, and Ti/sapphire lasers to investigate the ignition of graphite-doped HMX in highly confined optical fixtures that incorporated a fast piezoelectric pressure transducer. Experimental parameters included the laser power history and the explosive column length. The results of these experiments guided a second series of experiments in which the ignition column explosive was terminated by a thin rupture disc in contact with a transition column of low-density HMX or some other material. The transition column was terminated with a piezoelectric time-of-arrival detector for determining overall function times. Parameters investigated included different laser sources, rupture disc thicknesses, and the transition column explosive characteristics. Overall function times less than 50 microseconds were obtained, and trends established by the various parameter studies indicate that further reductions in function time can be achieved.

  6. Excitation-emission spectra and fluorescence quantum yields for fresh and aged biogenic secondary organic aerosols

    SciTech Connect (OSTI)

    Lee, Hyun Ji; Laskin, Alexander; Laskin, Julia; Nizkorodov, Sergey A.

    2013-05-10

    Certain biogenic secondary organic aerosols (SOA) become absorbent and fluorescent when exposed to reduced nitrogen compounds such as ammonia, amines and their salts. Fluorescent SOA may potentially be mistaken for biological particles by detection methods relying on fluorescence. This work quantifies the spectral distribution and effective quantum yields of fluorescence of SOA generated from two monoterpenes, limonene and a-pinene, and two different oxidants, ozone (O3) and hydroxyl radical (OH). The SOA was generated in a smog chamber, collected on substrates, and aged by exposure to ~100 ppb ammonia vapor in air saturated with water vapor. Absorption and excitation-emission matrix (EEM) spectra of aqueous extracts of aged and control SOA samples were measured, and the effective absorption coefficients and fluorescence quantum yields (~0.005 for 349 nm excitation) were determined from the data. The strongest fluorescence for the limonene-derived SOA was observed for excitation = 420+- 50 nm and emission = 475 +- 38 nm. The window of the strongest fluorescence shifted to excitation = 320 +- 25 nm and emission = 425 +- 38 nm for the a-pinene-derived SOA. Both regions overlap with the excitation-emission matrix (EEM) spectra of some of the fluorophores found in primary biological aerosols. Our study suggests that, despite the low quantum yield, the aged SOA particles should have sufficient fluorescence intensities to interfere with the fluorescence detection of common bioaerosols.

  7. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M.; Peng, Marcus Y.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard C.

    1996-01-01

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  8. Effects of magnetization on fusion product trapping and secondary neutron spectra

    SciTech Connect (OSTI)

    Knapp, P. F.; Schmit, P. F.; Hansen, S. B.; Gomez, M. R.; Hahn, K. D.; Sinars, D. B.; Peterson, K. J.; Slutz, S. A.; Sefkow, A. B.; Awe, T. J.; Harding, E.; Jennings, C. A.; Desjarlais, M. P.; Chandler, G. A.; Cooper, G. W.; Cuneo, M. E.; Geissel, M.; Harvey-Thompson, A. J.; Porter, J. L.; Rochau, G. A.; and others

    2015-05-15

    By magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used to infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ρR, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner Inertial Fusion experiments conducted on the Z machine at Sandia National Laboratories. We show that in these experiments BR ≈ 0.34(+0.14/−0.06) MG · cm, a ∼ 14× increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. This is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.

  9. Criteria for optimization of recycling processes of primary and secondary copper

    SciTech Connect (OSTI)

    Dusts, S.; Piret, N.L.

    1995-12-31

    Primary and secondary copper smelting dusts are being generated in varying quantities with very dissimilar characteristics due to the different compositions of feed materials and the type of process utilized. After categorizing the multitude of dust types, the criteria for on-site and off-site recycling of smelter dust in terms of type and concentrations of the accompanying elements are established. Thereby, consideration is given to the important aspects of: optimization of copper recovery; quality of copper product; valorization of accompanying elements; elimination and disposal of deleterious impurities; minimization of impact on operation; effects on operating costs; and environmental impacts of dust treatment on overall process. Existing commercial, emerging and proposed copper smelting dusts, pyrometallurgical as well as hydrometallurgical, treatment schemes are reviewed and evaluated technically, economically and environmentally in an attempt to streamline the vast number of proposed options. Thereby, the high selectivity achievable in hydrometallurgical dust processing due to it being complementary to the smelting process, is expected to be given increased consideration. 81 refs., 11 figs., 11 tabs.

  10. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  11. Secondary economic impact of acid deposition control legislation in six coal producing states: Final report

    SciTech Connect (OSTI)

    Scott, M.J.; Guthrie, S.J.

    1988-12-01

    Among the difficult policy questions on the US environmental agenda is what to do about emissions to the earth's atmosphere of pollutants that may result in ''acid rain''. The Congress has considered several pieces of legislation spelling out potential approaches to the problem and setting goals for emission reduction, mostly emphasizing the control of oxides of sulfur and nitrogen. Significant policy concern is the dollar costs to the nation's economy of achieving the intended effects of the legislation and the potential impacts on economic activity---in particular, losses of both coal mining and secondary service sector employment in states and regions dependent on the mining of high sulfur coal. There are several direct economic effects of regulations such as the acid rain control legislation. One of the more obvious effects was the switching from high sulfur coal to low sulfur coal. This would result in increases in employment and coal business procurements in low sulfur coal mining regions, but also would result in lower employment and lower coal business procurements in high sulfur coal mining areas. The potential negative effects are the immediate policy concern and are the focus of this report. 15 refs., 1 fig., 17 tabs.

  12. Effects of magnetization on fusion product trapping and secondary neutron spectra

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knapp, Patrick F.; Schmit, Paul F.; Hansen, Stephanie B.; Gomez, Matthew R.; Hahn, Kelly D.; Sinars, Daniel Brian; Peterson, Kyle J.; Slutz, Stephen A.; Sefkow, Adam B.; Awe, Thomas James; et al

    2015-05-14

    In magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, we found that the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used tomore » infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ρR, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner InertialFusion experiments conducted on the Z machine at Sandia National Laboratories. Furthermore, we show that in these experiments BR ≈ 0.34(+0.14/-0.06) MG · cm, a ~ 14× increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. Lastly, this is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.« less

  13. Characterization of Interlayer Cs+ in Clay Samples Using Secondary Ion Mass Spectrometry with Laser Sample Modification

    SciTech Connect (OSTI)

    G. S. Groenewold; R. Avci; C. Karahan; K. Lefebre; R. V. Fox; M. M. Cortez; A. K. Gianotto; J. Sunner; W. L. Manner

    2004-04-01

    Ultraviolet laser irradiation was used to greatly enhance the secondary ion mass spectrometry (SIMS) detection of Cs+ adsorbed to soil consisting of clay and quartz. Imaging SIMS showed that the enhancement of the Cs+ signal was spatially heterogeneous: the intensity of the Cs+ peak was increased by factors up to 100 for some particles but not at all for others. Analysis of standard clay samples exposed to Cs+ showed a variable response to laser irradiation depending on the type of clay analyzed. The Cs+ abundance was significantly enhanced when Cs+-exposed montmorillonite was irradiated and then analyzed using SIMS, which contrasted with the behavior of Cs+-exposed kaolinite, which displayed no Cs+ enhancement. Exposed illitic clays displayed modest enhancement of Cs+ upon laser irradiation, intermediate between that of kaolinite and montmorillonite. The results for Cs+ were rationalized in terms of adsorption to interlayer sites within the montmorillonite, which is an expandable phyllosilicate. In these locations, Cs+ was not initially detectable using SIMS. Upon irradiation, Cs+ was thermally redistributed, which enabled detection using SIMS. Since neither the illite nor the kaolinite is an expandable clay, adsorption to inner-layer sites does not occur, and either modest or no laser enhancement of the Cs+ signal is observed. Laser irradiation also produced unexpected enhancement of Ti+ from illite and kaolinite clays that contained small quantities of Ti, which indicates the presence of microscopic titanium oxide phases in the clay materials.

  14. Imaging the Solar Cell P-N Junction and Depletion Region Using Secondary Electron Contrast

    SciTech Connect (OSTI)

    Heath, J. T.; Jiang, C. S.; Al-Jassim, M. M.

    2011-01-01

    We report on secondary electron (SE) images of cross-sectioned multicrystalline Si and GaAs/GaInP solar cell devices, focusing on quantifying the relationship between the apparent n{sup +}-p contrast and characteristic electronic features of the device. These samples allow us to compare the SE signal from devices which have very different physical characteristics: differing materials, diffused junction versus abrupt junction, heterojunction versus homojunction. Despite these differences, we find that the SE image contrast for both types of sample, and as a function of reverse bias across the diode, closely agrees with PC1D simulations of the bulk electrostatic potential in the device, accurately yielding the depletion edge and width. A spatial derivative of the SE data shows a local maximum at the metallurgical junction. Such data are valuable, for example, in studying the conformity of a diffused junction to the textured surface topography. These data also extend our understanding of the origin of the SE contrast.

  15. Brominated Tyrosine and Polyelectrolyte Multilayer Analysis by Laser Desorption VUV Postionization and Secondary Ion Mass Spectrometry

    SciTech Connect (OSTI)

    University of Illinois at Chicago; Blaze, Melvin M. T.; Takahashi, Lynelle; Zhou, Jia; Ahmed, Musahid; Gasper, Gerald; Pleticha, F. Douglas; Hanley, Luke

    2011-03-14

    The small molecular analyte 3,5-dibromotyrosine (Br2Y) and chitosan-alginate polyelectrolyte multilayers (PEM) with and without adsorbed Br2Y were analyzed by laser desorption postionization mass spectrometry (LDPI-MS). LDPI-MS using 7.87 eV laser and tunable 8 ? 12.5 eV synchrotron vacuum ultraviolet (VUV) radiation found that desorption of clusters from Br2Y films allowed detection by≤8 eV single photon ionization. Thermal desorption and electronic structure calculations determined the ionization energy of Br2Y to be ~;;8.3?0.1 eV and further indicated that the lower ionization energies of clusters permitted their detection at≤8 eV photon energies. However, single photon ionization could only detect Br2Y adsorbed within PEMs when using either higher photon energies or matrix addition to the sample. All samples were also analyzed by 25 keV Bi3 + secondary ion mass spectrometry (SIMS), with the negative ion spectra showing strong parent ion signal which complemented that observed by LDPI-MS. The negative ion SIMS depended strongly on the high electron affinity of this specific analyte and the analyte?s condensed phase environment.

  16. Effects of magnetization on fusion product trapping and secondary neutron spectra

    SciTech Connect (OSTI)

    Knapp, Patrick F.; Schmit, Paul F.; Hansen, Stephanie B.; Gomez, Matthew R.; Hahn, Kelly D.; Sinars, Daniel Brian; Peterson, Kyle J.; Slutz, Stephen A.; Sefkow, Adam B.; Awe, Thomas James; Harding, Eric; Jennings, Christopher A.; Desjarlais, M. P.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Geissel, Matthias; Harvey-Thompson, Adam James; Porter, John L.; Rochau, Gregory A.; Rovang, Dean C.; Ruiz, Carlos L.; Savage, Mark E.; Smith, Ian C.; Stygar, William A.; Herrmann, Mark

    2015-05-14

    In magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, we found that the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used to infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ρR, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner InertialFusion experiments conducted on the Z machine at Sandia National Laboratories. Furthermore, we show that in these experiments BR ≈ 0.34(+0.14/-0.06) MG · cm, a ~ 14× increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. Lastly, this is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.

  17. Evidence for an unsaturated-zone origin of secondary minerals in Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Whelan, Joseph F.; Roedder, Edwin; Paces, James B.

    2001-04-29

    The unsaturated zone (UZ) in Miocene-age welded tuffs at Yucca Mountain, Nevada, is under consideration as a potential site for the construction of a high-level radioactive waste repository. Secondary calcite and silica minerals deposited on fractures and in cavities in the UZ tuffs are texturally, isotopically, and geochemically consistent with UZ deposition from meteoric water infiltrating at the surface and percolating through the UZ along fractures. Nonetheless, two-phase fluid inclusions with small and consistent vapor to liquid (V:L) ratios that yield consistent temperatures within samples and which range from about 35 to about 80 C between samples have led some to attribute these deposits to formation from upwelling hydrothermal waters. Geochronologic studies have shown that calcite and silica minerals began forming at least 10 Ma and continued to form into the Holocene. If their deposition were really from upwelling water flooding the UZ, it would draw into question the suitability of the site as a waste repository.

  18. Prompt laser ignition and transition to detonation in a secondary explosive

    SciTech Connect (OSTI)

    Setchell, R.E.; Trott, W.M.

    1994-05-01

    A two-stage approach to achieving detonation in a secondary explosive was developed in previous studies in which ignition resulted from low-energy hot wires or from laser diodes. In the current study, this approach was examined in some detail for the case of ignition by a pulsed, solid-state (rod) laser. An initial series of experiments used Nd/glass, ND/YAG, and Ti/sapphire lasers to investigate the ignition of graphite-doped HMX in highly confined optical fixtures that incorporated a fast piezoelectric pressure transducer. Experimental parameters included the laser power history and the explosive column length. The results of these experiments guided a second series of experiments in which the ignition column explosive was terminated by a thin rupture disc in contact with a transition column of low density HMX or some other material. The transition column was terminated with a piezoelectric time-of-arrival detector for determining overall function times. Parameters investigated included different laser sources, rupture disc thicknesses, and the transition column explosive characteristics. Overall function times less than 50 microseconds were obtained, and trends established by the various parameter studies indicate that further reductions in function time can be achieved.

  19. Comparative Genome Structure, Secondary Metabolite, and Effector Coding Capacity across Cochliobolus Pathogens

    SciTech Connect (OSTI)

    Condon, Bradford J.; Leng, Yueqiang; Wu, Dongliang; Bushley, Kathryn E.; Ohm, Robin A.; Otillar, Robert; Martin, Joel; Schackwitz, Wendy; Grimwood, Jane; MohdZainudin, NurAinlzzati; Xue, Chunsheng; Wang, Rui; Manning, Viola A.; Dhillon, Braham; Tu, Zheng Jin; Steffenson, Brian J.; Salamov, Asaf; Sun, Hui; Lowry, Steve; LaButti, Kurt; Han, James; Copeland, Alex; Lindquist, Erika; Barry, Kerrie; Schmutz, Jeremy; Baker, Scott E.; Ciuffetti, Lynda M.; Grigoriev, Igor V.; Zhong, Shaobin; Turgeon, B. Gillian

    2013-01-24

    The genomes of five Cochliobolus heterostrophus strains, two Cochliobolus sativus strains, three additional Cochliobolus species (Cochliobolus victoriae, Cochliobolus carbonum, Cochliobolus miyabeanus), and closely related Setosphaeria turcica were sequenced at the Joint Genome Institute (JGI). The datasets were used to identify SNPs between strains and species, unique genomic regions, core secondary metabolism genes, and small secreted protein (SSP) candidate effector encoding genes with a view towards pinpointing structural elements and gene content associated with specificity of these closely related fungi to different cereal hosts. Whole-genome alignment shows that three to five of each genome differs between strains of the same species, while a quarter of each genome differs between species. On average, SNP counts among field isolates of the same C. heterostrophus species are more than 25 higher than those between inbred lines and 50 lower than SNPs between Cochliobolus species. The suites of nonribosomal peptide synthetase (NRPS), polyketide synthase (PKS), and SSP encoding genes are astoundingly diverse among species but remarkably conserved among isolates of the same species, whether inbred or field strains, except for defining examples that map to unique genomic regions. Functional analysis of several strain-unique PKSs and NRPSs reveal a strong correlation with a role in virulence.

  20. Study on the thermal resistance in secondary particles chain of silica aerogel by molecular dynamics simulation

    SciTech Connect (OSTI)

    Liu, M. [Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing100190 (China); Department of Physics, University of Chinese Academy of Sciences, Beijing 100049 (China); Qiu, L., E-mail: qiulin111@sina.com, E-mail: jzzhengxinghua@163.com; Zheng, X. H., E-mail: qiulin111@sina.com, E-mail: jzzhengxinghua@163.com; Zhu, J.; Tang, D. W. [Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing100190 (China)

    2014-09-07

    In this article, molecular dynamics simulation was performed to study the heat transport in secondary particles chain of silica aerogel. The two adjacent particles as the basic heat transport unit were modelled to characterize the heat transfer through the calculation of thermal resistance and vibrational density of states (VDOS). The total thermal resistance of two contact particles was predicted by non-equilibrium molecular dynamics simulations (NEMD). The defects were formed by deleting atoms in the system randomly first and performing heating and quenching process afterwards to achieve the DLCA (diffusive limited cluster-cluster aggregation) process. This kind of treatment showed a very reasonable prediction of thermal conductivity for the silica aerogels compared with the experimental values. The heat transport was great suppressed as the contact length increased or defect concentration increased. The constrain effect of heat transport was much significant when contact length fraction was in the small range (<0.5) or the defect concentration is in the high range (>0.5). Also, as the contact length increased, the role of joint thermal resistance played in the constraint of heat transport was increasing. However, the defect concentration did not affect the share of joint thermal resistance as the contact length did. VDOS of the system was calculated by numerical method to characterize the heat transport from atomic vibration view. The smaller contact length and greater defect concentration primarily affected the longitudinal acoustic modes, which ultimately influenced the heat transport between the adjacent particles.

  1. Data Package for Secondary Waste Form Down-Selection—Cast Stone

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Westsik, Joseph H.

    2011-09-05

    Available literature on Cast Stone and Saltstone was reviewed with an emphasis on determining how Cast Stone and related grout waste forms performed in relationship to various criteria that will be used to decide whether a specific type of waste form meets acceptance criteria for disposal in the Integrated Disposal Facility (IDF) at Hanford. After the critical review of the Cast Stone/Saltstone literature, we conclude that Cast Stone is a good candidate waste form for further consideration. Cast stone meets the target IDF acceptance criteria for compressive strength, no free liquids, TCLP leachate are below the UTS permissible concentrations and leach rates for Na and Tc-99 are suiteably low. The cost of starting ingredients and equipment necessary to generate Cast Stone waste forms with secondary waste streams are low and the Cast Stone dry blend formulation can be tailored to accommodate variations in liquid waste stream compositions. The database for Cast Stone short-term performance is quite extensive compared to the other three candidate waste solidification processes. The solidification of liquid wastes in Cast Stone is a mature process in comparison to the other three candidates. Successful production of Cast Stone or Saltstone has been demonstrated from lab-scale monoliths with volumes of cm3 through m3 sized blocks to 210-liter sized drums all the way to the large pours into vaults at Savannah River. To date over 9 million gallons of low activity liquid waste has been solidified and disposed in concrete vaults at Savannah River.

  2. EIS-0370: Windy Gap Firming Project, Colorado

    Broader source: Energy.gov [DOE]

    This EIS, prepared by the Department of the Interior (Bureau of Reclamation, Great Plains Region), with DOE's Western Area Power Administration as a cooperating agency, evaluates the environmental impacts of a proposal to construct new water storage reservoir capacity southwest of Loveland, Colorado. Western has jurisdiction over the transmission line that would be relocated if the proposed action is implemented and would market additional power that may be generated as a result of the project.

  3. Mexican firms commit to responsabilidad integral

    SciTech Connect (OSTI)

    Wood, A.

    1992-12-09

    With the prospect of Mexico joining the North American Free Trade Agreement (NAFTA), eyes are on the environmental performance of that country's chemical industry. Its image has already been dented directly by pollution problems at certain maquiladora plants on the U.S. border, and indirectly by the April explosions at Guadalajara, blamed on gasoline leaks from state oil group Petroleos Mexicanos, (Pemex). NAFTA has drown the issue into focus, since the pact could encourage companies to build plants in Mexico to take advantage of cheaper labor costs. Concerned that laxer environmental provisions could also play a part, environmentalists are pressuring Washington to ensure that NAFTA puts Mexico on a par with the rest of North America. But chemical markers assert that Mexico's environmental legislation is already similar to that of the US. And, under the administration of President Carlos Salinas Gortari, the Ministry of Social Development has upped enforcement, fined a number of producers, and closed down some chemical units for failing to meet environmental regulations.

  4. Firms still chasing C. I. S. deals

    SciTech Connect (OSTI)

    More fields to open

    1992-06-01

    Foreign companies' pursuit of oil and gas ventures in the Commonwealth of Independent States continues unabated. This paper reports that Total has signed its third cooperation agreement with Russian partners, this one with Komineft to act as operator in development of Khariaga oil field in the Timan Pechora basin near the Arctic Circle west of the Urals. Amoco Eurasia Petroleum Co. officials have made progress in negotiations with the Azerbaijan republic on contracts to develop the Caspian Sea's giant Azeri oil field. Meanwhile, the Turkmenistan government has outlined plans to open more of the former Soviet republic's oil and gas fields to bids for joint development.

  5. 4 oil firms turn secret on reserves

    SciTech Connect (OSTI)

    Schaffer, P.

    1980-04-14

    US oil companies are complying with Saudi Arabia's and Indonesia's request by not revealing the companies' shares of oil reserves, adding to supply uncertainties and increasing the power of the producing countries. The information blackout reduces the reserve estimates filed by Exxon, Mobil, Standard Oil of California, and Texaco with the Securities and Exchange Commission, which plans to deal with the reporting problem on a case-by-case basis. Unless the companies decide the information can be disclosed to DOE's Financial Reporting System, a legal battle will ensue. A summary of reserve reports indicates a trend in declining production relative to new discoveries as well. (DCK)

  6. Audits for For-Profit Firms FAQ

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... under the OMB Circular A-133 Compliance Supplement (Part 3) and include the following: activities allowed or unallowed, allowable costscost principles, cash management, ...

  7. National toxicology program chemical nomination and selection process

    SciTech Connect (OSTI)

    Selkirk, J.K.

    1990-12-31

    The National Toxicology Program (NTP) was organized to support national public health programs by initiating research designed to understand the physiological, metabolic, and genetic basis for chemical toxicity. The primary mandated responsibilities of NTP were in vivo and vitro toxicity testing of potentially hazardous chemicals; broadening the spectrum of toxicological information on known hazardous chemicals; validating current toxicological assay systems as well as developing new and innovative toxicity testing technology; and rapidly communicating test results to government agencies with regulatory responsibilities and to the medical and scientific communities. 2 figs.

  8. Open Nominations Call - Energy Department Employees, Join the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Economic Impact and Diversity started Women @ Energy, an online feature of women who work in science, technology, engineering, and mathematics (STEM) at the Energy Department. ...

  9. Deadline for DOE Indian Country Working Group Nominations Extended...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Forum Julia Bovey, First Wind; Tracey LeBeau; Neil Kiely, First Wind; and Bob Springer (NREL) at First Wind's new Rollins project near Lincoln, Maine. Tackling Energy ...

  10. EERE Efficiency Expert Nominated for American Service Award

    Broader source: Energy.gov [DOE]

    Here at EERE, within our Building Technologies Office, the Appliance Standards Program works to save American consumers money while reducing energy use and greenhouse gas emissions by overseeing minimum energy conservation standards for 60 categories of appliances. The man who has led these efforts since 2010 is John Cymbalsky, who was recently recognized for his efforts as a finalist for the 2014 Science and Environment Medal at the Samuel J. Heyman Service to America Medals, commonly known as the Sammies.

  11. Student Employee of the Year nominations sought | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application deadline is February 5, 2016. For further information contact Erin Schwartz at 294-0102 eschwart@iastate.edu or Julie Arnold at 294-0103 jaarnol@iastate.edu....

  12. 2016 Federal Energy and Water Management Awards - Nomination...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at an installation or facility; "Program" for overall management approaches that effectively instituted new strategies or policies; or "Contracting" for efforts to award energy ...

  13. 4-28-09_Final_Testimony_(Triay)_(Nomination).pdf

    Office of Environmental Management (EM)

    Alamos National Laboratory in New Mexico and mentored by giants in the field of nuclear science; was asked to direct the beginning of the operational phase of the Waste Isolation...

  14. NREL's Grid Integration Lab Nominated for Prestigious Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facility (ESIF) at the Energy Departments National Renewable Energy Laboratory (NREL) is the nation's premier lab for testing how clean energy technologies interact on the...

  15. Call for nominations for NERSC HPC Achievement Awards Due December...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This award will recognize work that has, or is expected to have, an exceptional impact on scientific understanding, engineering design for scientific facilities, andor a...

  16. 12-8-11FinalMajumdarNominationTestimony.pdf

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an honor and privilege that I will cherish for the rest of my life. In ARPA-E's short existence, we have stood up an organization with a philosophy of excellence in everything we...

  17. 4-23-09_Final_Nomination_Testimony_(Triay).pdf

    Office of Environmental Management (EM)

  18. Hanford Advisory Board (HAB or Board) Membership Nomination and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and at least one alternate member to ensure adequate representation of the interest group or organization. Membership of the HAB includes: Seven representatives of local...

  19. Nominate Your Mentor for the Presidential Award in Science, Math...

    Energy Savers [EERE]

    The President had special words for students who majored in the STEM disciplines, saying "If you earned your degree in areas where we need more women -- like computer science or ...

  20. Origins of secondary silica within Yucca Mountain, Nye County, southwestern Nevada

    SciTech Connect (OSTI)

    Moscati, R.J.; Whelan, J.F.

    1996-09-01

    The accuracy of predictions of the hydrologic response of Yucca Mountain to future climate depends largely on how well relations between past climate and hydrology can be resolved. To advance this reconstruction, secondary minerals in and near Yucca Mountain, deposited by ground waters that originated both as surficial recharge at Yucca Mountain and from regional aquifers, are being studied to determine past ground-water sources and chemistries. Preliminary data on stable oxygen isotopes indicate that, although silica (opal, quartz, and chalcedony) and calcite and have formed in similar settings and from somewhat similar fluids, the authors have found no compelling evidence of coprecipitation or formation from identical fluids. If verified by further analyses, this precludes the use of silica-calcite mineral pairs for precise geothermometry. The preliminary data also indicate that opal and calcite occurrences in pedogenic and unsaturated-zone settings are invariably compatible with formation under modern ambient surface or subsurface temperatures. Silica and calcite stable-isotope studies are being integrated with soil geochemical modeling. This modeling will define the soil geochemical condition (climate) leading to opal or calcite deposition and to the transfer functions that may apply at the meteorologic soil unsaturated-zone interfaces. Additional study of pedogenic and unsaturated-zone silica is needed to support these models. The hypothesis that the transformation of vapor-phase tridymite to quartz requires saturated conditions is being tested through stable oxygen-isotope studies of lithophysal tridymite/quartz mixtures. Should this hypothesis be verified, mineralogic analysis by X-ray diffraction theoretically would permit reconstruction of past maximum water-table elevations.

  1. Limited effect of anthropogenic nitrogen oxides on secondary organic aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-12-08

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but it can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR (National Center for Atmospheric Research) Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product volatility basis set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. Small differences are found for themore » no-aging VBS and 2-product schemes; large increases in SOA production and the SOA-to-OA ratio are found for the aging scheme. The predicted organic aerosol amounts capture both the magnitude and distribution of US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of 2 compared to aerosol mass spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different regions and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9–5.6, 6.4–12.0 and 0.9–2.8 % for global, southeast US and Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to a limited shift in chemical regime, to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  2. Bio-processing of solid wastes and secondary resources for metal extraction - A review

    SciTech Connect (OSTI)

    Lee, Jae-chun; Pandey, Banshi Dhar

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Review focuses on bio-extraction of metals from solid wastes of industries and consumer goods. Black-Right-Pointing-Pointer Bio-processing of certain effluents/wastewaters with metals is also included in brief. Black-Right-Pointing-Pointer Quantity/composition of wastes are assessed, and microbes used and leaching conditions included. Black-Right-Pointing-Pointer Bio-recovery using bacteria, fungi and archaea is highlighted for resource recycling. Black-Right-Pointing-Pointer Process methodology/mechanism, R and D direction and scope of large scale use are briefly included. - Abstract: Metal containing wastes/byproducts of various industries, used consumer goods, and municipal waste are potential pollutants, if not treated properly. They may also be important secondary resources if processed in eco-friendly manner for secured supply of contained metals/materials. Bio-extraction of metals from such resources with microbes such as bacteria, fungi and archaea is being increasingly explored to meet the twin objectives of resource recycling and pollution mitigation. This review focuses on the bio-processing of solid wastes/byproducts of metallurgical and manufacturing industries, chemical/petrochemical plants, electroplating and tanning units, besides sewage sludge and fly ash of municipal incinerators, electronic wastes (e-wastes/PCBs), used batteries, etc. An assessment has been made to quantify the wastes generated and its compositions, microbes used, metal leaching efficiency etc. Processing of certain effluents and wastewaters comprising of metals is also included in brief. Future directions of research are highlighted.

  3. Secondary oil recovery from selected Carter sandstone oilfields--Black Warrior Basin, Alabama. Final report

    SciTech Connect (OSTI)

    Anderson, J.C.

    1995-02-01

    Producibility problems, such as low reservoir pressure and reservoir heterogeneity, have severely limited oil production from the Central Bluff and North Fairview fields. Specific objectives for this project were: To successfully apply detailed geologic and engineering studies with conventional waterflood technologies to these fields in an effort to increase the ultimate economic recovery of oil from Carter sandstone fields; To extensively model, test and evaluate these technologies; thereby, developing a sound methodology for their use and optimization; and To team with Advanced Resources International and the US DOE to assimilate and transfer the information and results gathered from this study to other oil companies to encourage the widespread use of these technologies. At Central Bluff, water injection facilities were constructed and water injection into one well began in January 1993. Oil response from the waterflood has been observed at both producing wells. One of the producing wells has experienced early water breakthrough and a concomitant drop in secondary oil rate. A reservoir modeling study was initiated to help develop an appropriate operating strategy for Central Bluff. For the North Fairview unit waterflood, a previously abandoned well was converted for water injection which began in late June 1993. The reservoir is being re-pressurized, and unit water production has remained nil since flood start indicating the possible formation of an oil bank. A reservoir simulation to characterize the Carter sand at North Fairview was undertaken and the modeling results were used to forecast field performance. The project was terminated due to unfavorable economics. The factors contributing to this decision were premature water breakthrough at Central Bluff, delayed flood response at North Fairview and stalled negotiations at the South Bluff site.

  4. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovation??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  5. Viscosity of α-pinene secondary organic material and implications for particle growth and reactivity

    SciTech Connect (OSTI)

    Renbaum-Wolff, Lindsay; Grayson, James W.; Bateman, Adam P.; Kuwata, Mikinori; Sellier, Mathieu; Murray, Benjamin J.; Shilling, John E.; Martin, Scot T.; Bertram, Allan K.

    2013-05-14

    Particles composed of secondary organic material (SOM) are abundant in the lower troposphere and play important roles in climate, air quality, and health. The viscosity of these particles is a fundamental property that is presently poorly quantified for conditions relevant to the lower troposphere. Using two new techniques, namely a bead-mobility technique and a poke-flow technique, in conjunction with simulations of fluid flow, we measure the viscosity of the watersoluble component of SOM produced by α-pinene ozonolysis. The viscosity is comparable to that of honey at 90% relative humidity (RH), comparable to that of peanut butter at 70% RH and greater than or comparable to that of bitumen for ≤ 30% RH, implying that the studied SOM ranges from liquid to semisolid/solid at ambient relative humidities. With the Stokes-Einstein relation, the measured viscosities further imply that the growth and evaporation of SOM by the exchange of organic molecules between the gas and condensed phases may be confined to the surface region when RH ≤ 30%, suggesting the importance of an adsorption-type mechanism for partitioning in this regime. By comparison, for RH ≥ 70% partitioning of organic molecules may effectively occur by an absorption mechanism throughout the bulk of the particle. Finally, the net uptake rates of semi-reactive atmospheric oxidants such as O3 are expected to decrease by two to five orders of magnitude for a change in RH from 90% to ≤ 30% RH, with possible implications for the rates of chemical aging of SOM particles in the atmosphere.

  6. LUNAR DUST GRAIN CHARGING BY ELECTRON IMPACT: COMPLEX ROLE OF SECONDARY ELECTRON EMISSIONS IN SPACE ENVIRONMENTS

    SciTech Connect (OSTI)

    Abbas, M. M.; Craven, P. D.; LeClair, A. C.; Spann, J. F.; Tankosic, D.

    2010-08-01

    Dust grains in various astrophysical environments are generally charged electrostatically by photoelectric emissions with radiation from nearby sources, or by electron/ion collisions by sticking or secondary electron emissions (SEEs). The high vacuum environment on the lunar surface leads to some unusual physical and dynamical phenomena involving dust grains with high adhesive characteristics, and levitation and transportation over long distances. Knowledge of the dust grain charges and equilibrium potentials is important for understanding a variety of physical and dynamical processes in the interstellar medium, and heliospheric, interplanetary/planetary, and lunar environments. It has been well recognized that the charging properties of individual micron-/submicron-size dust grains are expected to be substantially different from the corresponding values for bulk materials. In this paper, we present experimental results on the charging of individual 0.2-13 {mu}m size dust grains selected from Apollo 11 and 17 dust samples, and spherical silica particles by exposing them to mono-energetic electron beams in the 10-200 eV energy range. The dust charging process by electron impact involving the SEEs discussed is found to be a complex charging phenomenon with strong particle size dependence. The measurements indicate substantial differences between the polarity and magnitude of the dust charging rates of individual small-size dust grains, and the measurements and model properties of corresponding bulk materials. A more comprehensive plan of measurements of the charging properties of individual dust grains for developing a database for realistic models of dust charging in astrophysical and lunar environments is in progress.

  7. Limited effect of anthropogenic nitrogen oxides on Secondary Organic Aerosol formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Y.; Unger, N.; Hodzic, A.; Emmons, L.; Knote, C.; Tilmes, S.; Lamarque, J.-F.; Yu, P.

    2015-08-28

    Globally, secondary organic aerosol (SOA) is mostly formed from emissions of biogenic volatile organic compounds (VOCs) by vegetation, but can be modified by human activities as demonstrated in recent research. Specifically, nitrogen oxides (NOx = NO + NO2) have been shown to play a critical role in the chemical formation of low volatility compounds. We have updated the SOA scheme in the global NCAR Community Atmospheric Model version 4 with chemistry (CAM4-chem) by implementing a 4-product Volatility Basis Set (VBS) scheme, including NOx-dependent SOA yields and aging parameterizations. The predicted organic aerosol amounts capture both the magnitude and distribution ofmore » US surface annual mean measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network by 50 %, and the simulated vertical profiles are within a factor of two compared to Aerosol Mass Spectrometer (AMS) measurements from 13 aircraft-based field campaigns across different region and seasons. We then perform sensitivity experiments to examine how the SOA loading responds to a 50 % reduction in anthropogenic nitric oxide (NO) emissions in different regions. We find limited SOA reductions of 0.9 to 5.6, 6.4 to 12.0 and 0.9 to 2.8 % for global, the southeast US and the Amazon NOx perturbations, respectively. The fact that SOA formation is almost unaffected by changes in NOx can be largely attributed to buffering in chemical pathways (low- and high-NOx pathways, O3 versus NO3-initiated oxidation) and to offsetting tendencies in the biogenic versus anthropogenic SOA responses.« less

  8. Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

    SciTech Connect (OSTI)

    Wang, Bingbing; O'Brien, Rachel E.; Kelly, Stephen T.; Shilling, John E.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2015-05-14

    Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and ?-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO? particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO? from reacted aerosol particles may have important implications for atmospheric chemistry.

  9. Effect of Hydrophobic Primary Organic Aerosols on Secondary Organic Aerosol Formation from Ozonolysis of α-Pinene

    SciTech Connect (OSTI)

    Song, Chen; Zaveri, Rahul A.; Alexander, M. Lizabeth; Thornton, Joel A.; Madronich, Sasha; Ortega, John V.; Zelenyuk, Alla; Yu, Xiao-Ying; Laskin, Alexander; Maughan, A. D.

    2007-10-16

    Semi-empirical secondary organic aerosol (SOA) models typically assume a well-mixed organic aerosol phase even in the presence of hydrophobic primary organic aerosols (POA). This assumption significantly enhances the modeled SOA yields as additional organic mass is made available to absorb greater amounts of oxidized secondary organic gases than otherwise. We investigate the applicability of this critical assumption by measuring SOA yields from ozonolysis of α-pinene (a major biogenic SOA precursor) in a smog chamber in the absence and in the presence of dioctyl phthalate (DOP) and lubricating oil seed aerosol. These particles serve as surrogates for urban hydrophobic POA. The results show that these POA did not enhance the SOA yields. If these results are found to apply to other biogenic SOA precursors, then the semi-empirical models used in many global models would predict significantly less biogenic SOA mass and display reduced sensitivity to anthropogenic POA emissions than previously thought.

  10. The influence of the secondary electron induced asymmetry on the electrical asymmetry effect in capacitively coupled plasmas

    SciTech Connect (OSTI)

    Korolov, Ihor; Derzsi, Aranka; Donkó, Zoltán; Schulze, Julian

    2013-08-05

    In geometrically symmetric capacitive radio-frequency plasmas driven by two consecutive harmonics, a dc self-bias can be generated as a function of the phase shift between the driving frequencies via the Electrical Asymmetry Effect (EAE). Recently, the Secondary Electron Asymmetry Effect (SEAE) was discovered (Lafleur et al., J. Phys. D: Appl. Phys. 46, 135201 (2013)): unequal secondary electron emission coefficients at both electrodes were found to induce an asymmetry in single-frequency capacitive plasmas. Here, we investigate the simultaneous presence of both effects, i.e., a dual-frequency plasma driven by two consecutive harmonics with different electrode materials. We find that the superposition of the EAE and the SEAE is generally non-linear, i.e., the asymmetries generated by each individual effect do not simply add up at all phases. The control ranges of the dc self-bias and the mean ion energy can be enlarged, if both effects are combined.

  11. 1984 Workshop on secondary-side stress corrosion cracking and intergranular corrosion of PWR steam generator tubing. Proceedings

    SciTech Connect (OSTI)

    Partridge, M.J.

    1986-03-01

    The contractors' meeting on ''Secondary Water Initiated IGC of Alloy 600'' was organized in an effort to give those working in this area an opportunity to share their results, ideas and plans. Topics discussed included: (1) transport phenomena and crevice chemistry; (2) correlations and models of electrochemical and isothermal tests; (3) chemistry of carbides and surface films; (4) model boiler and heat transfer studies; and (5) summary experience and test results regarding IGA/IGSCC rates.

  12. Effect of surface produced secondary electrons on the sheath structure induced by high-power microwave window breakdown

    SciTech Connect (OSTI)

    Cheng Guoxin; Liu Lie

    2011-03-15

    Dielectric window breakdown, whose mechanism is not thoroughly understood, is a major factor of limiting the transmission and radiation of high-power microwave on the order of 1 GW. In this paper, a one-dimensional fluid-like sheath model is developed to investigate the sheath structures formed at different gas pressures. The dominant processes during the surface flashover are isolated by this model. In vacuum, electron multipactor is self-sustained by secondary electron emission, a positive space-charge potential is formed on the dielectric surface. With increasing gas pressure, electron-neutral ionization prevails against secondary electron emission. The multipactor effect is suppressed by the shielding of plasma electrons. This leads to the sheath potential changing gradually from a positive space-charge potential to a negative space-charge potential. For argon gas pressure lower than 14 Torr, the sheath is space charge limited. A potential minimum could be formed in front of the dielectric which traps secondary electrons emitted from the wall. With the higher argon gas pressure, the number density of ions becomes comparable to that of electrons, all surface produced electrons are accelerated toward the presheath region. Therefore, the normal sheath is formed and the resulting surface flashover on the dielectric surface becomes rf-driven volumetric breakdown.

  13. In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palm, B. B.; Campuzano-Jost, P.; Ortega, A. M.; Day, D. A.; Kaser, L.; Jud, W.; Karl, T.; Hansel, A.; Hunter, J. F.; Cross, E. S.; et al

    2015-11-04

    Ambient air was oxidized by OH radicals in an oxidation flow reactor (OFR) located in a montane pine forest during the BEACHON-RoMBAS campaign to study biogenic secondary organic aerosol (SOA) formation and aging. High OH concentrations and short residence times allowed for semi-continuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative time scales of condensation of low volatility organic compounds (LVOCs) onto particles, condensational loss to the walls, and further reaction to produce volatile, non-condensing fragmentation products. MoremoreSOA production was observed in the OFR at nighttime (average 4 ?g m-3 when LVOC fate corrected) compared to daytime (average 1 ?g m-3 when LVOC fate corrected), with maximum formation observed at 0.41.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene + p-cymene concentrations, including a substantial increase just after sunrise at 07:00 LT. Higher photochemical aging (> 10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 6 times more SOA was formed in the reactor from OH oxidation

  14. Technology Development Roadmap for the Advanced High Temperature Reactor Secondary Heat Exchanger

    SciTech Connect (OSTI)

    P. Sabharwall; M. McCllar; A. Siahpush; D. Clark; M. Patterson; J. Collins

    2012-09-01

    This Technology Development Roadmap (TDRM) presents the path forward for deploying large-scale molten salt secondary heat exchangers (MS-SHX) and recognizing the benefits of using molten salt as the heat transport medium for advanced high temperature reactors (AHTR). This TDRM will aid in the development and selection of the required heat exchanger for: power production (the first anticipated process heat application), hydrogen production, steam methane reforming, methanol to gasoline production, or ammonia production. This TDRM (a) establishes the current state of molten salt SHX technology readiness, (b) defines a path forward that systematically and effectively tests this technology to overcome areas of uncertainty, (c) demonstrates the achievement of an appropriate level of maturity prior to construction and plant operation, and (d) identifies issues and prioritizes future work for maturing the state of SHX technology. This study discusses the results of a preliminary design analysis of the SHX and explains the evaluation and selection methodology. An important engineering challenge will be to prevent the molten salt from freezing during normal and off-normal operations because of its high melting temperature (390°C for KF ZrF4). The efficient transfer of energy for industrial applications depends on the ability to incorporate cost-effective heat exchangers between the nuclear heat transport system and industrial process heat transport system. The need for efficiency, compactness, and safety challenge the capabilities of existing heat exchanger technology. The description of potential heat exchanger configurations or designs (such as printed circuit, spiral or helical coiled, ceramic, plate and fin, and plate type) were covered in an earlier report (Sabharwall et al. 2011). Significant future work, much of which is suggested in this report, is needed before the benefits and full potential of the AHTR can be realized. The execution of this TDRM will focuses

  15. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun; Fisk, William J.

    2011-05-01

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives

  16. Gallium composition dependence of crystallographic and thermoelectric properties in polycrystalline type-I Ba{sub 8}Ga{sub x}Si{sub 46-x} (nominal x=14-18) clathrates prepared by combining arc melting and spark plasma sintering methods

    SciTech Connect (OSTI)

    Anno, Hiroaki; JST, CREST, 5 Sanbancho, Chiyoda-ku, Tokyo 102-0075 ; Yamada, Hiroki; Nakabayashi, Takahiro; Hokazono, Masahiro; Shirataki, Ritsuko; JST, CREST, 5 Sanbancho, Chiyoda-ku, Tokyo 102-0075

    2012-09-15

    The gallium composition dependence of crystallographic and thermoelectric properties in polycrystalline n-type Ba{sub 8}Ga{sub x}Si{sub 46-x} (nominal x=14-18) compounds with the type-I clathrate structure is presented. Samples were prepared by combining arc melting and spark plasma sintering methods. Powder x-ray diffraction, Rietveld analysis, scanning electron microscopy, and energy-dispersive x-ray spectroscopy show that the solubility limit of gallium in the type-I clathrate phase is close to x=15, which is slightly higher than that for a single crystal. The carrier concentration at room temperature decreases from 2 Multiplication-Sign 10{sup 21} cm{sup -3} to 4 Multiplication-Sign 10{sup 20} cm{sup -3} as the Ga content x increases. The Seebeck coefficient, the electrical conductivity, and the thermal conductivity vary systematically with the carrier concentration when the Ga content x varies. The effective mass (2.0m{sub 0}), the carrier mobility (10 cm{sup 2} V{sup -1} s{sup -1}), and the lattice thermal conductivity (1.1 W m{sup -1} K{sup -1}) are determined for the Ga content x=14.51. The dimensionless thermoelectric figure of merit ZT is about 0.55 at 900 K for the Ga content x=14.51. The calculation of ZT using the experimentally determined material parameters predicts ZT=0.8 (900 K) at the optimum carrier concentration of about 2 Multiplication-Sign 10{sup 20} cm{sup -3}. - Graphical abstract: The gallium composition dependence of crystallographic and thermoelectric properties is presented on polycrystalline n-type Ba{sub 8}Ga{sub x}Si{sub 46-x} with the type-I clathrate structure prepared by combining arc melting and spark plasma sintering methods. The thermoelectric figure of merit ZT reaches 0.55 at 900 K due to the increase in the Ga content (close to x=15), and a calculation predicts further improvement of ZT at the optimized carrier concentration. Highlights: Black-Right-Pointing-Pointer Crystallographic properties of Ba{sub 8}Ga{sub x}Si{sub 46

  17. Secondary Waste Considerations for Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center FY-2001 Status Report

    SciTech Connect (OSTI)

    Herbst, A.K.; Kirkham, R.J.; Losinski, S.J.

    2002-09-26

    The Idaho Nuclear Technology and Engineering Center (INTEC) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes from the melter off-gas clean up systems. Projected secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  18. Secondary Waste Considerations for Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Techology and Engineering Center FY-2001 Status Report

    SciTech Connect (OSTI)

    Herbst, Alan Keith; Kirkham, Robert John; Losinski, Sylvester John

    2001-09-01

    The Idaho Nuclear Technology and Engineering Center (INTEC) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes from the melter off-gas clean up systems. Projected secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  19. Regulation of secondary cell wall biosynthesis by poplar R2R3 MYB transcription factor PtrMYB152 in Arabidopsis

    SciTech Connect (OSTI)

    Wang, Shucai; Li, Eryang; Porth, Ilga; Chen, Jin-Gui; Mansfield, Shawn D.; Douglas, Carl

    2014-05-23

    Poplar has 192 annotated R2R3 MYB genes, of which only three have been shown to play a role in the regulation of secondary cell wall formation. Here we report the characterization of PtrMYB152, a poplar homolog of the Arabidopsis R2R3 MYB transcription factor AtMYB43, in the regulation of secondary cell wall biosynthesis. The expression of PtrMYB152 in secondary xylem is about 18 times of that in phloem. When expressed in Arabidopsis under the control of either 35S or PtrCesA8 promoters, PtrMYB152 increased secondary cell wall thickness, which is likely caused by increased lignification. Accordingly, elevated expression of genes encoding sets of enzymes in secondary wall biosynthesis were observed in transgenic plants expressing PtrMYB152. Arabidopsis protoplast transfection assays suggested that PtrMYB152 functions as a transcriptional activator. Taken together, our results suggest that PtrMYB152 may be part of a regulatory network activating expression of discrete sets of secondary cell wall biosynthesis genes.

  20. Analysis of long-term flows resulting from large-scale sodium-water reactions in an LMFBR secondary system

    SciTech Connect (OSTI)

    Shin, Y.W.; Chung, H.; Choi, U.S.; Wiedermann, A.H.; Ockert, C.E.

    1984-07-01

    Leaks in LMFBR steam generators cannot entirely be prevented; thus the steam generators and the intermediate heat transport system (IHTS) of an LMFBR must be designed to withstand the effects of the leaks. A large-scale leak which might result from a sudden break of a steam generator tube, and the resulting sodium-water reaction (SWR) can generate large pressure pulses that propagate through the IHTS and exert large forces on the piping supports. This paper discusses computer programs for analyzing long-term flow and thermal effects in an LMFBR secondary system resulting from large-scale steam generator leaks, and the status of the development of the codes.

  1. Restricting lignin and enhancing sugar deposition in secondary cell walls enhances monomeric sugar release after low temperature ionic liquid pretreatment

    SciTech Connect (OSTI)

    Scullin, Chessa; Cruz, Alejandro G.; Chuang, Yi -De; Simmons, Blake A.; Loque, Dominique; Singh, Seema

    2015-07-04

    Lignocellulosic biomass has the potential to be a major source of renewable sugar for biofuel production. Before enzymatic hydrolysis, biomass must first undergo a pretreatment step in order to be more susceptible to saccharification and generate high yields of fermentable sugars. Lignin, a complex, interlinked, phenolic polymer, associates with secondary cell wall polysaccharides, rendering them less accessible to enzymatic hydrolysis. Herein, we describe the analysis of engineered Arabidopsis lines where lignin biosynthesis was repressed in fiber tissues but retained in the vessels, and polysaccharide deposition was enhanced in fiber cells with little to no apparent negative impact on growth phenotype.

  2. Secondary ligand-directed assembly of Co(II) coordination polymers based on a pyridine carboxylate ligand

    SciTech Connect (OSTI)

    Cao, Ke-Li; Zhang, Yi-Ping; Cai, Yi-Ni; Xu, Xiao-Wei; Feng, Yun-Long

    2014-07-01

    To investigate the influence of hydrogen bonds and secondary ligands on the structures and properties of the resulting frameworks, five new Co(II) compounds have been synthesized by the reactions of Co(II) salts and 3,5-bis(pyridin-4-ylmethoxy)benzoic acid (HL) with four rationally selected dicarboxylic acid ligands. Without secondary ligand, we got one compound [CoL{sub 2}(H{sub 2}O){sub 2}]{sub n}·2nH{sub 2}O (1), which possesses a 1D chain structure. In the presence of ancillary ligands, namely, 1,3-adamantanedicarboxylic acid (H{sub 2}adbc), terephthalic acid (H{sub 2}tpa), thiophene-2,5-dicarboxylic acid (H{sub 2}tdc) and 1,4-benzenedithioacetic acid (H{sub 2}bdtc), four 3D structures [Co{sub 2}L{sub 2}(adbc)]{sub n}·nH{sub 2}O (2), [Co{sub 2}L{sub 2}(tpa)]{sub n} (3), [Co{sub 2}L{sub 2}(tdc)]{sub n} (4), [Co{sub 2}L{sub 2}(bdtc)(H{sub 2}O)]{sub n} (5) were obtained, respectively. It can be observed from the architectures of 1–5 that hydrogen bonds and secondary ligands both have great effects on the spatial connective fashions, resulting in the formation of various dimensional compounds. The XRPD, TGA data of title polymers and the magnetic properties for 2 and 5 have also been investigated. - Graphical abstract: The structural differences show that the ancillary ligands have great effects on the spatial connective fashions, resulting in the formation of various dimensional compounds. - Highlights: • Five new Co(II) coordination polymers have been synthesized by solvothermal reactions based on 3,5-bis(pyridin-4-ylmethoxy)benzoic acid (HL). • The long-flexible ligand (HL) is a good candidate to produce interpenetrating architectures. • The secondary dicarboxylic acid ligands play important roles in the spatial connective fashions and the formation of various dimensional compounds. • The magnetism studies show that both 2 and 5 exhibit antiferromagnetic interactions.

  3. Secondary Startup Neutron Sources as a Source of Tritium in a Pressurized Water Reactor (PWR) Reactor Coolant System (RCS)

    SciTech Connect (OSTI)

    Shaver, Mark W.; Lanning, Donald D.

    2010-02-01

    The hypothesis of this paper is that the Zircaloy clad fuel source is minimal and that secondary startup neutron sources are the significant contributors of the tritium in the RCS that was previously assigned to release from fuel. Currently there are large uncertainties in the attribution of tritium in a Pressurized Water Reactor (PWR) Reactor Coolant System (RCS). The measured amount of tritium in the coolant cannot be separated out empirically into its individual sources. Therefore, to quantify individual contributors, all sources of tritium in the RCS of a PWR must be understood theoretically and verified by the sum of the individual components equaling the measured values.

  4. Secondary heat recovery from low-permeability high-temperature reservoir: A possible project in the Larderello Field, Italy

    SciTech Connect (OSTI)

    Gianelli, G.; Squarci, P.; Capocecera, P.

    1997-12-31

    A project of fracture stimulation and secondary heat recovery from the metamorphic reservoir of the Larderello geothermal field could be developed in a next future. Geological and geophysical data suggest that the stimulation can enhance permeability and that the water injection can be recovered as steam. In particular, the area of the project is characterized by the presence of an important seismic reflector which has been explained assuming the presence of fractured rocks filled with high pressure fluids. Extensional and hydraulic fractures can present at temperatures of 300-350{degrees}C, and this makes the experiment of extreme interest.

  5. Restricting lignin and enhancing sugar deposition in secondary cell walls enhances monomeric sugar release after low temperature ionic liquid pretreatment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scullin, Chessa; Cruz, Alejandro G.; Chuang, Yi -De; Simmons, Blake A.; Loque, Dominique; Singh, Seema

    2015-07-04

    Lignocellulosic biomass has the potential to be a major source of renewable sugar for biofuel production. Before enzymatic hydrolysis, biomass must first undergo a pretreatment step in order to be more susceptible to saccharification and generate high yields of fermentable sugars. Lignin, a complex, interlinked, phenolic polymer, associates with secondary cell wall polysaccharides, rendering them less accessible to enzymatic hydrolysis. Herein, we describe the analysis of engineered Arabidopsis lines where lignin biosynthesis was repressed in fiber tissues but retained in the vessels, and polysaccharide deposition was enhanced in fiber cells with little to no apparent negative impact on growth phenotype.

  6. PCS UtiliData | Open Energy Information

    Open Energy Info (EERE)

    A control system integration firm specialising in power system and automation and energy conservation. Secondary emphasis on systems for metals industry. Coordinates:...

  7. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Molina, Luisa T.; Molina, Mario J.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavaka, Miguel; Velasco, Erik

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on

  8. Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  9. Pairwise covariance adds little to secondary structure prediction but improves the prediction of non-canonical local structure

    SciTech Connect (OSTI)

    Bystroff, Christopher; Webb-Robertson, Bobbie-Jo M.

    2009-05-06

    Amino acid sequence probability distributions, or profiles, have been used successfully to predict secondary structure and local structure in proteins. Profile models assume the statistical independence of each position in the sequence, but the energetics of protein folding is better captured in a scoring function that is based on pairwise interactions, like a force field. I-sites motifs are short sequence/structure motifs that populate the protein structure database due to energy-driven convergent evolution. Here we show that a pairwise covariant sequence model does not predict alpha helix or beta strand significantly better overall than a profile-based model, but it does improve the prediction of certain loop motifs. The finding is best explained by considering secondary structure profiles as multivariant, all-or-none models, which subsume covariant models. Pairwise covariance is nonetheless present and energetically rational. Examples of negative design are present, where the covariances disfavor non-native structures. Measured pairwise covariances are shown to be statistically robust in cross-validation tests, as long as the amino acid alphabet is reduced to nine classes. We present an updated I-sites local structure motif library and web server that provide sequence covariance information for all types of local structure in globular proteins.

  10. Radiobiologic comparison of helical tomotherapy, intensity modulated radiotherapy, and conformal radiotherapy in treating lung cancer accounting for secondary malignancy risks

    SciTech Connect (OSTI)

    Komisopoulos, Georgios; Mavroidis, Panayiotis; Rodriguez, Salvador; Stathakis, Sotirios; Papanikolaou, Nikos; Nikiforidis, Georgios C.; Sakellaropoulos, Georgios C.

    2014-01-01

    The aim of the present study is to examine the importance of using measures to predict the risk of inducing secondary malignancies in association with the clinical effectiveness of treatment plans in terms of tumor control and normal tissue complication probabilities. This is achieved by using radiobiologic parameters and measures, which may provide a closer association between clinical outcome and treatment delivery. Overall, 4 patients having been treated for lung cancer were examined. For each of them, 3 treatment plans were developed based on the helical tomotherapy (HT), multileaf collimator-based intensity modulated radiation therapy (IMRT), and 3-dimensional conformal radiation therapy (CRT) modalities. The different plans were evaluated using the complication-free tumor control probability (p{sub +}), the overall probability of injury (p{sub I}), the overall probability of control/benefit (p{sub B}), and the biologically effective uniform dose (D{sup }). These radiobiologic measures were used to develop dose-response curves (p-D{sup } diagram), which can help to evaluate different treatment plans when used in conjunction with standard dosimetric criteria. The risks for secondary malignancies in the heart and the contralateral lung were calculated for the 3 radiation modalities based on the corresponding dose-volume histograms (DVHs) of each patient. Regarding the overall evaluation of the different radiation modalities based on the p{sub +} index, the average values of the HT, IMRT, and CRT are 67.3%, 61.2%, and 68.2%, respectively. The corresponding average values of p{sub B} are 75.6%, 70.5%, and 71.0%, respectively, whereas the average values of p{sub I} are 8.3%, 9.3%, and 2.8%, respectively. Among the organs at risk (OARs), lungs show the highest probabilities for complications, which are 7.1%, 8.0%, and 1.3% for the HT, IMRT, and CRT modalities, respectively. Similarly, the biologically effective prescription doses (D{sub B}{sup }) for the HT

  11. Secondary Energy Infobook and Secondary Infobook Activities ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    school, save energy and reduce costs Collection of science-based, climate education resources and programs, aligned to national science education standards. Find info on the...

  12. Vacuum ultra-violet emission of plasma discharges with high Xe partial pressure using a cathode protective layer with high secondary electron emission

    SciTech Connect (OSTI)

    Zhu, Di; Song, Le; Zhang, Xiong; Kajiyama, Hiroshi

    2014-02-14

    In this work, the mechanism of the vacuum ultra-violet (VUV) emission of plasma discharges, with high Xe partial pressure and high ion-induced secondary electrons emission protective layer, is studied by measuring the VUV light emission directly and comparing it with two-dimensional simulations. From the panel measurement, we find that the high intensity of excimer VUV mainly contributes to the high luminous efficacy of SrCaO-plasma display panels (PDP) at a low sustain voltage. The unchanged Xe excitation efficiency indicates that the electron temperature is not decreased by the high secondary electrons emission protective layer, even though the sustain voltage is much lower. From the two-dimensional simulations, we can find that the ratio of excimer VUV to resonant VUV, which is determined by the collision rate in the discharge, is only significantly affected by the Xe partial pressure, while it is independent of the sustain voltage and the secondary-electrons-emission capability of protective layer. The unchanged average electron energy at the moment when the electric field becomes maximum confirms that the improvement of the VUV production efficiency mainly is attributed to the increase in electron heating efficiency of a PDP with high ion-induced secondary electrons emission protective layer. Combining the experimental and the simulation results, we conclude about the mechanism by which the VUV production is improved for the plasma display panel with a high Xe partial pressure and a cold cathode with high ion-induced secondary electrons emission.

  13. Abnormal electron-heating mode and formation of secondary-energetic electrons in pulsed microwave-frequency atmospheric microplasmas

    SciTech Connect (OSTI)

    Kwon, H. C.; Research and Development Division, SK Hynix Semiconductor Inc., Icheon 467-701 ; Jung, S. Y.; Kim, H. Y.; Won, I. H.; Lee, J. K.

    2014-03-15

    The formation of secondary energetic electrons induced by an abnormal electron-heating mode in pulsed microwave-frequency atmospheric microplasmas was investigated using particle-in-cell simulation. We found that additional high electron heating only occurs during the first period of the ignition phase after the start of a second pulse at sub-millimeter dimensions. During this period, the electrons are unable to follow the abruptly retreating sheath through diffusion alone. Thus, a self-consistent electric field is induced to drive the electrons toward the electrode. These behaviors result in an abnormal electron-heating mode that produces high-energy electrons at the electrode with energies greater than 50?eV.

  14. IMG-ABC: An Atlas of Biosynthetic Gene Clusters to Fuel the Discovery of Novel Secondary Metabolites

    SciTech Connect (OSTI)

    Chen, I-Min; Chu, Ken; Ratner, Anna; Palaniappan, Krishna; Huang, Jinghua; Reddy, T. B.K.; Cimermancic, Peter; Fischbach, Michael; Ivanova, Natalia; Markowitz, Victor; Kyrpides, Nikos; Pati, Amrita

    2014-10-28

    In the discovery of secondary metabolites (SMs), large-scale analysis of sequence data is a promising exploration path that remains largely underutilized due to the lack of relevant computational resources. We present IMG-ABC (https://img.jgi.doe.gov/abc/) -- An Atlas of Biosynthetic gene Clusters within the Integrated Microbial Genomes (IMG) system1. IMG-ABC is a rich repository of both validated and predicted biosynthetic clusters (BCs) in cultured isolates, single-cells and metagenomes linked with the SM chemicals they produce and enhanced with focused analysis tools within IMG. The underlying scalable framework enables traversal of phylogenetic dark matter and chemical structure space -- serving as a doorway to a new era in the discovery of novel molecules.

  15. The light curve shapes as a key to resolving the origin of long secondary periods in red giant stars

    SciTech Connect (OSTI)

    Soszyński, I.; Udalski, A. E-mail: udalski@astrouw.edu.pl

    2014-06-10

    We present a study of Optical Gravitational Lensing Experiment light curves of red giant stars exhibiting long secondary periods (LSPs)—an enigmatic phenomenon commonly observed in stars on the upper red giant branch and asymptotic giant branch. We show that the light curves of LSP stars are essentially identical to those of the spotted variables with one dark spot on their photospheres. Such behavior can be explained by the presence of a dusty cloud orbiting the red giant together with a low-mass companion in a close, circular orbit. We argue that the binary scenario is in agreement with most of the observational properties of LSP variables, including non-sinusoidal shapes of their radial velocity curves.

  16. Modified theory of secondary electron emission from spherical particles and its effect on dust charging in complex plasma

    SciTech Connect (OSTI)

    Misra, Shikha [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi-110016 (India); Mishra, S. K. [Institute for Plasma Research, Gandhinagar-382428 (India); Sodha, M. S. [Department of Education Building, University of Lucknow, Lucknow-226007 (India)

    2013-01-15

    The authors have modified Chow's theory of secondary electron emission (SEE) to take account of the fact that the path length of a primary electron in a spherical particle varies between zero to the diameter or x{sub m} the penetration depth depending on the distance of the path from the centre of the particle. Further by including this modified expression for SEE efficiency, the charging kinetics of spherical grains in a Maxwellian plasma has been developed; it is based on charge balance over dust particles and number balance of electrons and ionic species. It is seen that this effect is more pronounced for smaller particles and higher plasma temperatures. Desirable experimental work has also been discussed.

  17. Design and test of a trumpet secondary concentrator for a faceted stretched membrane primary in a dish-Stirling application

    SciTech Connect (OSTI)

    O`Gallagher, J.J.; Winston, R.; Diver, R.B.; Mahoney, A.R.

    1995-11-01

    A ``trumpet`` type nonimaging secondary concentrator has been designed and a prototype fabricated for test with the Cummins Power Generation (CPG) 7.5 kW{sub e} dish-Stirling system. Trumpets are families of hyperbolae of revolution which can be characterized by three parameters, the exit aperture radius, the asymptotic angle, and the truncation height. The test prototype unit was designed using a detailed ray trace code to simulate the radiation distribution from the primary and modeling the performance across a range of these trumpet design parameters. The unit is 26.7 cm (10.5 in.) deep by about 69 cm (27 in.) wide, and has a geometric concentration of 1.7X. The test units were fabricated from polished copper spinnings, overcoated with vapor deposited aluminum and aluminum oxide layers and are water cooled. The objectives and test procedures for the experiments are reviewed.

  18. Note: Ion-induced secondary electron emission from oxidized metal surfaces measured in a particle beam reactor

    SciTech Connect (OSTI)

    Marcak, Adrian; Corbella, Carles Keudell, Achim von; Arcos, Teresa de los

    2015-10-15

    The secondary electron emission of metals induced by slow ions is characterized in a beam chamber by means of two coaxial semi-cylindrical electrodes with different apertures. The voltages of the outer electrode (screening), inner electrode (collector), and sample holder (target) were set independently in order to measure the effective yield of potential and kinetic electron emissions during ion bombardment. Aluminum samples were exposed to quantified beams of argon ions up to 2000 eV and to oxygen atoms and molecules in order to mimic the plasma-surface interactions on metallic targets during reactive sputtering. The variation of electron emission yield was correlated to the ion energy and to the oxidation state of Al surfaces. This system provides reliable measurements of the electron yields in real time and is of great utility to explore the fundamental surface processes during target poisoning occurring in reactive magnetron sputtering applications.

  19. PSTAR: Primary and secondary terms analysis and renormalization: A unified approach to building energy simulations and short-term monitoring

    SciTech Connect (OSTI)

    Subbarao, K.

    1988-09-01

    This report presents a unified method of hourly simulation of a building and analysis of performance data. The method is called Primary and Secondary Terms Analysis and Renormalization (PSTAR). In the PSTAR method, renormalized parameters are introduced for the primary terms such that the renormalized energy balance equation is best satisfied in the least squares sense, hence, the name PSTAR. PSTAR allows extraction of building characteristics from short-term tests on a small number of data channels. These can be used for long-term performance prediction (''ratings''), diagnostics, and control of heating, ventilating, and air conditioning systems (HVAC), comparison of design versus actual performance, etc. By combining realistic building models, simple test procedures, and analysis involving linear equations, PSTAR provides a powerful tool for analyzing building energy as well as testing and monitoring. It forms the basis for the Short-Term Energy Monitoring (STEM) project at SERI.

  20. MULTI-WAVELENGTH EMISSION FROM THE FERMI BUBBLE. II. SECONDARY ELECTRONS AND THE HADRONIC MODEL OF THE BUBBLE

    SciTech Connect (OSTI)

    Cheng, K.-S.; Chernyshov, D. O.; Dogiel, V. A.; Ko, C.-M.

    2015-01-20

    We analyze the origin of the gamma-ray flux from the Fermi Bubbles (FBs) in the framework of the hadronic model in which gamma-rays are produced by collisions of relativistic protons with the protons of the background plasma in the Galactic halo. It is assumed in this model that the observed radio emission from the FBs is due to synchrotron radiation of secondary electrons produced by pp collisions. However, if these electrons lose their energy through synchrotron and inverse-Compton emission, the spectrum of secondary electrons will be too soft, and an additional arbitrary component of the primary electrons will be necessary in order to reproduce the radio data. Thus, a mixture of the hadronic and leptonic models is required for the observed radio flux. It was shown that if the spectrum of primary electrons is ∝E{sub e}{sup −2}, the permitted range of the magnetic field strength is within the 2-7 μG region. The fraction of gamma-rays produced by pp collisions can reach about 80% of the total gamma-ray flux from the FBs. If the magnetic field is <2 μG or >7 μG the model is unable to reproduce the data. Alternatively, the electrons in the FBs may lose their energy through adiabatic energy losses if there is a strong plasma outflow in the GC. Then, the pure hadronic model is able to reproduce characteristics of the radio and gamma-ray flux from the FBs. However, in this case the required magnetic field strength in the FBs and the power of CR sources are much higher than those following from observations.

  1. Studies of Secondary Melanoma on C57BL/6J Mouse Liver Using 1H NMR Metabolomics

    SciTech Connect (OSTI)

    Feng, Ju; Isern, Nancy G.; Burton, Sarah D.; Hu, Jian Z.

    2013-10-31

    NMR metabolomics, consisting of solid state high resolution (hr) magic angle spinning (MAS) 1H NMR (1H hr-MAS), liquid state high resolution 1H-NMR, and principal components analysis (PCA) has been used to study secondary metastatic B16-F10 melanoma in C57BL/6J mouse liver . The melanoma group can be differentiated from its control group by PCA analysis of the absolute concentrations or by the absolute peak intensities of metabolites from either 1H hr-MAS NMR data on intact liver tissues or liquid state 1H-NMR spectra on liver tissue extracts. In particular, we found that the absolute concentrations of alanine, glutamate, creatine, creatinine, fumarate and cholesterol are elevated in the melanoma group as compared to controls, while the absolute concentrations of succinate, glycine, glucose, and the family of linear lipids including long chain fatty acids, total choline and acylglycerol are decreased. The ratio of glycerophosphocholine to phosphocholine is increased by about 1.5 fold in the melanoma group, while the absolute concentration of total choline is actually lower in melanoma mice. These results suggest the following picture in secondary melanoma metastasis: Linear lipid levels are decreased by beta oxidation in the melanoma group, which contributes to an increase in the synthesis of cholesterol, and also provides an energy source input for TCA cycle. These findings suggest a link between lipid oxidation, the TCA cycle and the hypoxia-inducible factors (HIF) signal pathway in tumor metastases. Thus this study indicates that the metabolic profile derived from NMR analysis can provide a valuable bio-signature of malignancy and cell hypoxia in metastatic melanoma.

  2. Apportionment of ambient primary and secondary fine particulate matter during a 2001 summer intensive study at the CMU Supersite and NETL Pittsburgh Site

    SciTech Connect (OSTI)

    Delbert J. Eatough; Nolan F. Mangelson; Richard R. Anderson

    2007-10-15

    Gaseous and particulate pollutant concentrations associated with five samples per day collected during a July 2001 summer intensive study at the Pittsburgh Carnegie Mellon University (CMU) Supersite were used to apportion fine particulate matter (PM2.5) into primary and secondary contributions using PMF2. Input to the PMF2 analysis included the concentrations of PM2.5 nonvolatile and semivolatile organic material, elemental carbon (EC), ammonium sulfate, trace element components, gas-phase organic material, and NOx, NO{sub 2}, and O{sub 3} concentrations. A total of 10 factors were identified. These factors are associated with emissions from various sources and facilities including crustal material, gasoline combustion, diesel combustion, and three nearby sources high in trace metals. In addition, four secondary sources were identified, three of which were associated with secondary products of local emissions and were dominated by organic material and one of which was dominated by secondary ammonium sulfate transported to the CMU site from the west and southwest. The three largest contributors to PM2.5 were secondary transported material (dominated by ammonium sulfate) from the west and southwest from sources including coal-fired power plants, coke processing plants and steel mills, (49%), secondary material formed during midday photochemical processes (24%), and gasoline combustion emissions (11%). The other seven sources accounted for the remaining 16% of the PM2.5. Results obtained at the CMU site were comparable to results previously reported at the National Energy Technology Laboratory (NETL), located approximately 18 km south of downtown Pittsburgh. The major contributor at both sites was material transported from the west and southwest. Some difference in nearby sources could be attributed to meteorology as evaluated by HYSPLIT model back-trajectory calculations. 27 refs., 16 figs., 1 tab.

  3. SU-E-T-519: Emission of Secondary Particles From a PMMA Phantom During Proton Irradiation: A Simulation Study with the Geant4 Monte Carlo Toolkit

    SciTech Connect (OSTI)

    Lau, A; Chen, Y; Ahmad, S

    2014-06-01

    Purpose: Proton therapy exhibits several advantages over photon therapy due to depth-dose distributions from proton interactions within the target material. However, uncertainties associated with protons beam range in the patient limit the advantage of proton therapy applications. To quantify beam range, positron-emitting nuclei (PEN) and prompt gamma (PG) techniques have been developed. These techniques use de-excitation photons to describe the location of the beam in the patient. To develop a detector system for implementing the PG technique for range verification applications in proton therapy, we studied the yields, energy and angular distributions of the secondary particles emitted from a PMMA phantom. Methods: Proton pencil beams of various energies incident onto a PMMA phantom with dimensions of 5 x 5 x 50 cm3 were used for simulation with the Geant4 toolkit using the standard electromagnetic packages as well as the packages based on the binary-cascade nuclear model. The emitted secondary particles are analyzed . Results: For 160 MeV incident protons, the yields of secondary neutrons and photons per 100 incident protons were ~6 and ~15 respectively. Secondary photon energy spectrum showed several energy peaks in the range between 0 and 10 MeV. The energy peaks located between 4 and 6 MeV were attributed to originate from direct proton interactions with 12C (~ 4.4 MeV) and 16O (~ 6 MeV), respectively. Most of the escaping secondary neutrons were found to have energies between 10 and 100 MeV. Isotropic emissions were found for lower energy neutrons (<10 MeV) and photons for all energies, while higher energy neutrons were emitted predominantly in the forward direction. The yields of emitted photons and neutrons increased with the increase of incident proton energies. Conclusions: A detector system is currently being developed incorporating the yields, energy and angular distributions of secondary particles from proton interactions obtained from this study.

  4. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan K.

    2002-01-02

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  5. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan Keith

    2002-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  6. Secondary oil recovery from selected Carter sandstone oilfields, Black Warrior basin, Alabama. [Annual] yearly report, December 1, 1992--November 30, 1993

    SciTech Connect (OSTI)

    Anderson, J.C.

    1994-03-01

    In this Class I PON, Anderman/Smith Operating Company is targeting three Carter sandstone oilfields (Black Warrior basin) for secondary recovery. Waterfloods are underway in two of the areas -- Central Bluff and North Fairview units. For the third area, South Bluff, negotiations are underway to unitize the field. Once South Bluff is unitized, waterflooding will commence.

  7. Beyond the material grave: Life Cycle Impact Assessment of leaching from secondary materials in road and earth constructions

    SciTech Connect (OSTI)

    Schwab, Oliver; Bayer, Peter; Juraske, Ronnie; Verones, Francesca; Hellweg, Stefanie

    2014-10-15

    Highlights: • We model environmental impacts of leaching from secondary construction material. • Industrial wastes in construction contain up to 45,000 t heavy metals per year (D). • In a scenario, 150 t are leached to the environment within 100 years after construction. • All heavy metals but As, Sb and Mo are adsorbed by 20 cm subsoil in this scenario. • Environmental impacts depend on material, pollutant, construction type, and geography. - Abstract: In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors

  8. The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

    SciTech Connect (OSTI)

    Maher, K.; Steefel, C. I.; White, A.F.; Stonestrom, D.A.

    2009-02-25

    In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka marine terrace chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized (White et al., 2008, GCA) and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisser and [2006] or the aluminum inhibition model proposed by Oelkers et al. [1994], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site. Observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO{sub 2}(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total

  9. Proposal for secondary enclosure setup for experiments to expose plasma facing materials to tritiated plasma in VISIONI

    SciTech Connect (OSTI)

    Broeckx, W.E.K.; Dylst, K.; Bornea, A.; Zamfirache, M.

    2015-03-15

    VISIONI is an equipment at SCK-CEN that allows the exposure of candidate plasma facing materials to tritium - deuterium plasmas at ITER first wall conditions. VISIONI itself, being a vacuum setup, acts as primary confinement. To protect operators against exposure to a tritiated atmosphere VISIONI must be placed in a secondary confinement. The current Tritium lab at SCK-CEN has a walk-in process cell which can be used to enclose the plasma chamber and diagnostics of the VISIONI setup, which have a limited tritium inventory. This allows easy accessibility to the setup in a well-ventilated environment. Routine operations should be conducted from outside the process cell and maintenance operations can be conducted from within the process cell with proper protections. The tritium storage and supply can be enclosed in a glove box with a dedicated air detritiation system which is activated during an experiment or in case of an incident. The detritiation system will oxidize tritium and capture it on molecular sieves. By using this confinement approach it is possible to expose materials to a tritiated plasma while maintaining good accessibility of the VISIONI setup. This paper describes the proposed confinement system and compares it to the most common approach where the entire system is enclosed into one large glovebox.

  10. Numerical study of effect of secondary electron emission on discharge characteristics in low pressure capacitive RF argon discharge

    SciTech Connect (OSTI)

    Liu, Qian; Liu, Yue, E-mail: liuyue@dlut.edu.cn; Samir, Tagra; Ma, Zhaoshuai [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-08-15

    Based on the drift and diffusion approximation theory, a 1D fluid model on capacitively coupled RF argon glow discharge at low pressure is established to study the effect of secondary electron emission (SEE) on the discharge characteristics. The model is numerically solved by using a finite difference method and the numerical results are obtained. The numerical results indicate that when the SEE coefficient is larger, the plasma density is higher and the time of reaching steady state is longer. It is also found that the cycle-averaged electric field, electric potential, and electron temperature change a little as the SEE coefficient is increased. Moreover, the discharge characteristics in some nonequilibrium discharge processes with different SEE coefficients have been compared. The analysis shows that when the SEE coefficient is varied from 0.01 to 0.3, the cycle-averaged electron net power absorption, electron heating rate, thermal convective term, electron energy dissipation, and ionization all have different degrees of growth. While the electron energy dissipation and ionization are quite special, there appear two peaks near each sheath region in the discharge with a relatively larger SEE coefficient. In this case, the discharge is certainly operated in a hybrid ?-?-mode.

  11. Protective spin-labeled fluorenes maintain amyloid beta peptide in small oligomers and limit transitions in secondary structure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Altman, Robin; Ly, Sonny; Hilt, Silvia; Petrlova, Jitka; Maezawa, Izumi; Kálai, Tamás; Hideg, Kálmán; Jin, Lee-Way; Laurence, Ted A.; Voss, John C.

    2015-12-01

    Alzheimer’s disease is characterized by the presence of extracellular plaques comprised of amyloid beta (Aβ) peptides. Soluble oligomers of the Aβ peptide underlie a cascade of neuronal loss and dysfunction associated with Alzheimer's disease. Single particle analyses of Aβ oligomers in solution by fluorescence correlation spectroscopy (FCS) were used to provide real-time descriptions of how spin-labeled fluorenes (SLFs; bi-functional small molecules that block the toxicity of Aβ) prevent and disrupt oligomeric assemblies of Aβ in solution. The FCS results, combined with electron paramagnetic resonance spectroscopy and circular dichroism spectroscopy, demonstrate SLFs can inhibit the growth of Aβ oligomers and disruptmore » existing oligomers while retaining Aβ in a largely disordered state. Furthermore, while the ability of SLF to block Aβ toxicity correlates with a reduction in oligomer size, our results suggest the conformation of Aβ within the oligomer determines the toxicity of the species. Attenuation of Aβ toxicity, which has been associated primarily with the soluble oligomeric form, can be achieved through redistribution of the peptides into smaller oligomers and arrest of the fractional increase in beta secondary structure.« less

  12. Controlling Wind Turbines for Secondary Frequency Regulation: An Analysis of AGC Capabilities Under New Performance Based Compensation Policy: Preprint

    SciTech Connect (OSTI)

    Aho, J.; Pao, L. Y.; Fleming, P.; Ela, E.

    2015-02-01

    As wind energy becomes a larger portion of the world's energy portfolio there has been an increased interest for wind turbines to control their active power output to provide ancillary services which support grid reliability. One of these ancillary services is the provision of frequency regulation, also referred to as secondary frequency control or automatic generation control (AGC), which is often procured through markets which recently adopted performance-based compensation. A wind turbine with a control system developed to provide active power ancillary services can be used to provide frequency regulation services. Simulations have been performed to determine the AGC tracking performance at various power schedule set-points, participation levels, and wind conditions. The performance metrics used in this study are based on those used by several system operators in the US. Another metric that is analyzed is the damage equivalent loads (DELs) on turbine structural components, though the impacts on the turbine electrical components are not considered. The results of these single-turbine simulations show that high performance scores can be achieved when there is sufficient wind resource available. The capability of a wind turbine to rapidly and accurately follow power commands allows for high performance even when tracking rapidly changing AGC signals. As the turbine de-rates to meet decreased power schedule set-points there is a reduction in the DELs, and the participation in frequency regulation has a negligible impact on these loads.

  13. Aging of secondary organic aerosol from small aromatic VOCs. Changes in chemical composition, mass yield, volatility and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2014-12-12

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form and transform SOA from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx. The effects of chemical aging on organic aerosol (OA) composition, mass yield, volatility and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state OSC) and mass yield. The OA oxidation state generally increased during photo-oxidation, and the final OA OSmore » C ranged from -0.29 to 0.45 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  14. Secondary Revenues Public Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preference Loads (net of Slice) Industrial Intra - Regional Transfers - (Out) Exports USB Obligations Month Pref. Loads L. Follow Risk Pref. Loads n DSI Transfers Ex USB Fed....

  15. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2014-12-20

    Four different parameterizations for the formation and evolution of secondary organic aerosol (SOA) are evaluated using a 0-D box model representing the Los Angeles Metropolitan Region during the CalNex 2010 field campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA formed only from the oxidation of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generationmore » oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model-measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model/measurement agreement for mass concentration. When comparing the three parameterizations, the Grieshop et al. (2009) parameterization more accurately reproduces both the SOA mass concentration and oxygen-to-carbon ratio inside the urban area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the observed SOA concentrations in Pasadena. All the parameterizations over-predict urban SOA formation at long

  16. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides

  17. Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry

    SciTech Connect (OSTI)

    Meusinger, Carl; Johnson, Matthew S. [Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Joel, E-mail: jsavarino@lgge.obs.ujf-grenoble.fr [Univ. Grenoble Alpes, LGGE, F-38000 Grenoble (France); CNRS, LGGE, F-38000 Grenoble (France)

    2014-06-28

    Post-depositional processes alter nitrate concentration and nitrate isotopic composition in the top layers of snow at sites with low snow accumulation rates, such as Dome C, Antarctica. Available nitrate ice core records can provide input for studying past atmospheres and climate if such processes are understood. It has been shown that photolysis of nitrate in the snowpack plays a major role in nitrate loss and that the photolysis products have a significant influence on the local troposphere as well as on other species in the snow. Reported quantum yields for the main reaction spans orders of magnitude apparently a result of whether nitrate is located at the air-ice interface or in the ice matrix constituting the largest uncertainty in models of snowpack NO{sub x} emissions. Here, a laboratory study is presented that uses snow from Dome C and minimizes effects of desorption and recombination by flushing the snow during irradiation with UV light. A selection of UV filters allowed examination of the effects of the 200 and 305nm absorption bands of nitrate. Nitrate concentration and photon flux were measured in the snow. The quantum yield for loss of nitrate was observed to decrease from 0.44 to 0.003 within what corresponds to days of UV exposure in Antarctica. The superposition of photolysis in two photochemical domains of nitrate in snow is proposed: one of photolabile nitrate, and one of buried nitrate. The difference lies in the ability of reaction products to escape the snow crystal, versus undergoing secondary (recombination) chemistry. Modeled NO{sub x} emissions may increase significantly above measured values due to the observed quantum yield in this study. The apparent quantum yield in the 200nm band was found to be ?1%, much lower than reported for aqueous chemistry. A companion paper presents an analysis of the change in isotopic composition of snowpack nitrate based on the same samples as in this study.

  18. Secondary Malignancies From Prostate Cancer Radiation Treatment: A Risk Analysis of the Influence of Target Margins and Fractionation Patterns

    SciTech Connect (OSTI)

    Dasu, Alexandru; Toma-Dasu, Iuliana; Franzen, Lars; Widmark, Anders; Nilsson, Per

    2011-03-01

    Purpose: This study explores the implications for cancer induction of treatment details such as fractionation, planning target volume (PTV) definition, and interpatient variations, which are relevant for the radiation treatment of prostate carcinomas. Methods and Materials: Treatment planning data from 100 patients have been analyzed with a risk model based on the United Nations Scientific Committee on the Effects of Atomic Radiation competition model. The risk model can account for dose heterogeneity and fractionation effects characteristic for modern radiotherapy. Biologically relevant parameters from clinical and experimental data have been used with the model. Results: The results suggested that changes in prescribed dose could lead to a modification of the risks for individual organs surrounding the clinical target volume (CTV) but that the total risk appears to be less affected by changes in the target dose. Larger differences are observed for modifications of the margins between the CTV and the PTV because these have direct impact onto the dose level and dose heterogeneity in the healthy tissues surrounding the CTV. Interpatient anatomic variations also have to be taken into consideration for studies of the risk for cancer induction from radiotherapy. Conclusions: The results have shown the complex interplay between the risk for secondary malignancies, the details of the treatment delivery, and the patient heterogeneity that may influence comparisons between the long-term effects of various treatment techniques. Nevertheless, absolute risk levels seem very small and comparable to mortality risks from surgical interventions, thus supporting the robustness of radiation therapy as a successful treatment modality for prostate carcinomas.

  19. Primary and secondary battery consumption trends in Sweden 1996–2013: Method development and detailed accounting by battery type

    SciTech Connect (OSTI)

    Patrício, João; Kalmykova, Yuliya; Berg, Per E.O.; Rosado, Leonardo; Åberg, Helena

    2015-05-15

    Highlights: • Developed MFA method was validated by the national statistics. • Exponential increase of EEE sales leads to increase in integrated battery consumption. • Digital convergence is likely to be a cause for primary batteries consumption decline. • Factors for estimation of integrated batteries in EE are provided. • Sweden reached the collection rates defined by European Union. - Abstract: In this article, a new method based on Material Flow Accounting is proposed to study detailed material flows in battery consumption that can be replicated for other countries. The method uses regularly available statistics on import, industrial production and export of batteries and battery-containing electric and electronic equipment (EEE). To promote method use by other scholars with no access to such data, several empirically results and their trends over time, for different types of batteries occurrence among the EEE types are provided. The information provided by the method can be used to: identify drivers of battery consumption; study the dynamic behavior of battery flows – due to technology development, policies, consumers behavior and infrastructures. The method is exemplified by the study of battery flows in Sweden for years 1996–2013. The batteries were accounted, both in units and weight, as primary and secondary batteries; loose and integrated; by electrochemical composition and share of battery use between different types of EEE. Results show that, despite a fivefold increase in the consumption of rechargeable batteries, they account for only about 14% of total use of portable batteries. Recent increase in digital convergence has resulted in a sharp decline in the consumption of primary batteries, which has now stabilized at a fairly low level. Conversely, the consumption of integrated batteries has increased sharply. In 2013, 61% of the total weight of batteries sold in Sweden was collected, and for the particular case of alkaline manganese

  20. How the main condition of phase stability can explain the effect of the velocity deviation of secondary electrons in DC-biased single-sided multipactors

    SciTech Connect (OSTI)

    Mostajeran, M.

    2014-11-15

    In this work, a main condition for phase stability has been employed to investigate the effects of the velocity deviation of the electrons in DC-biased single-sided multipactors (MPs). In a previous study [M. Mostajeran, Phys. Plasmas 21, 053108 (2014)], a stability equation was derived, where the secondary electron was assumed to have zero initial velocity and the phase deviation from the resonant phase was considered. In this work, both deviations in phase and velocity from the resonant condition are taken into account, assuming nonzero initial velocity for the secondary electrons. Using the main condition for stability, it is shown that MP discharge can rise in situations, where large velocity deviations from initial velocity and large phase deviations from resonant phase exist. This is contrary to what can be predicted on the basis of the simple stability condition. This result is further confirmed by numerical simulations.

  1. Evidence for biological activity in mineralization of secondary sulphate deposits in a basaltic environment: implications for the search for life in the Martian subsurface

    SciTech Connect (OSTI)

    C. Doc Richardson; Nancy W. Hinman; Jill R. Scott

    2013-10-01

    Evidence of microbial activity associated with mineralization of secondary Na-sulphate minerals (thenardite, mirabilite) in the basaltic subsurface of Craters of the Moon National Monument (COM), Idaho were examined by scanning electron microscopy, X-ray diffraction, laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD-FTICR-MS), Fourier transform infrared spectroscopy (FTIR) and isotope ratio mass spectrometry. Peaks suggestive of bio/organic compounds were observed in the secondary Na-sulphate deposits by LD-FTICR-MS. FTIR provided additional evidence for the presence of bio/organic compounds. Sulphur fractionation was explored to assist in determining if microbes may play a role in oxidizing sulphur. The presence of bio/organic compounds associated with Na-sulphate deposits, along with the necessity of oxidizing reduced sulphur to sulphate, suggests that biological activity may be involved in the formation of these secondary minerals. The secondary Na-sulphate minerals probably form from the overlying basalt through leached sodium ions and sulphate ions produced by bio-oxidation of Fe-sulphide minerals. Since the COM basalts are one of the most comparable terrestrial analogues for their Martian counterparts, the occurrence of biological activity in the formation of sulphate minerals at COM has direct implications for the search for life on Mars. In addition, the presence of caves on Mars suggests the importance of these environments as possible locations for growth and preservation of microbial activity. Therefore, understanding the physiochemical pathways of abiotic and biotic mineralization in the COM subsurface and similar basaltic settings has direct implications for the search for extinct or extant life on Mars.

  2. Using multiple secondary fusion products to evaluate fuel ρR, electron temperature, and mix in deuterium-filled implosions at the NIF

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rinderknecht, H. G.; Rosenberg, M. J.; Zylstra, A. B.; Lahmann, B.; Séguin, F. H.; Frenje, J. A.; Li, C. K.; Gatu Johnson, M.; Petrasso, R. D.; Berzak Hopkins, L. F.; et al

    2015-08-25

    In deuterium-filled inertial confinement fusion implosions, the secondary fusion processes D(3He,p)4He and D(T,n)4He occur, as the primary fusion products 3He and T react in flight with thermal deuterons. In implosions with moderate fuel areal density (~ 5–100 mg/cm2), the secondary D-3He reaction saturates, while the D-T reaction does not, and the combined information from these secondary products is used to constrain both the areal density and either the plasma electron temperature or changes in the composition due to mix of shell material into the fuel. The underlying theory of this technique is developed and applied to three classes of implosionsmore » on the National Ignition Facility: direct-drive exploding pushers, indirect-drive 1-shock and 2-shock implosions,and polar direct-drive implosions. In the 1- and 2-shock implosions, the electron temperature is inferred to be 0.65 x and 0.33 x the burn-averaged ion temperature, respectively. The inferred mixed mass in the polar direct-drive implosions is in agreement with measurements using alternative techniques.« less

  3. Using multiple secondary fusion products to evaluate fuel ρR, electron temperature, and mix in deuterium-filled implosions at the NIF

    SciTech Connect (OSTI)

    Rinderknecht, H. G.; Rosenberg, M. J.; Zylstra, A. B.; Lahmann, B.; Séguin, F. H.; Frenje, J. A.; Li, C. K.; Gatu Johnson, M.; Petrasso, R. D.; Berzak Hopkins, L. F.; Caggiano, J. A.; Divol, L.; Hartouni, E. P.; Hatarik, R.; Hatchett, S. P.; Le Pape, S.; Mackinnon, A. J.; McNaney, J. M.; Meezan, N. B.; Moran, M. J.; Bradley, P. A.; Kline, J. L.; Krasheninnikova, N. S.; Kyrala, G. A.; Murphy, T. J.; Schmitt, M. J.; Tregillis, I. L.; Batha, S. H.; Knauer, J. P.; Kilkenny, J. D.

    2015-08-25

    In deuterium-filled inertial confinement fusion implosions, the secondary fusion processes D(3He,p)4He and D(T,n)4He occur, as the primary fusion products 3He and T react in flight with thermal deuterons. In implosions with moderate fuel areal density (~ 5–100 mg/cm2), the secondary D-3He reaction saturates, while the D-T reaction does not, and the combined information from these secondary products is used to constrain both the areal density and either the plasma electron temperature or changes in the composition due to mix of shell material into the fuel. The underlying theory of this technique is developed and applied to three classes of implosions on the National Ignition Facility: direct-drive exploding pushers, indirect-drive 1-shock and 2-shock implosions,and polar direct-drive implosions. In the 1- and 2-shock implosions, the electron temperature is inferred to be 0.65 x and 0.33 x the burn-averaged ion temperature, respectively. The inferred mixed mass in the polar direct-drive implosions is in agreement with measurements using alternative techniques.

  4. Using multiple secondary fusion products to evaluate fuel ρR, electron temperature, and mix in deuterium-filled implosions at the NIF

    SciTech Connect (OSTI)

    Rinderknecht, H. G. Rosenberg, M. J.; Zylstra, A. B.; Lahmann, B.; Séguin, F. H.; Frenje, J. A.; Li, C. K.; Gatu Johnson, M.; Petrasso, R. D.; Berzak Hopkins, L. F.; Caggiano, J. A.; Divol, L.; Hartouni, E. P.; Hatarik, R.; Hatchett, S. P.; Le Pape, S.; Mackinnon, A. J.; McNaney, J. M.; Meezan, N. B.; Moran, M. J.; and others

    2015-08-15

    In deuterium-filled inertial confinement fusion implosions, the secondary fusion processes D({sup 3}He,p){sup 4}He and D(T,n){sup 4}He occur, as the primary fusion products {sup 3}He and T react in flight with thermal deuterons. In implosions with moderate fuel areal density (∼5–100 mg/cm{sup 2}), the secondary D-{sup 3}He reaction saturates, while the D-T reaction does not, and the combined information from these secondary products is used to constrain both the areal density and either the plasma electron temperature or changes in the composition due to mix of shell material into the fuel. The underlying theory of this technique is developed and applied to three classes of implosions on the National Ignition Facility: direct-drive exploding pushers, indirect-drive 1-shock and 2-shock implosions, and polar direct-drive implosions. In the 1- and 2-shock implosions, the electron temperature is inferred to be 0.65 times and 0.33 times the burn-averaged ion temperature, respectively. The inferred mixed mass in the polar direct-drive implosions is in agreement with measurements using alternative techniques.

  5. Nitrogen availability as a control mechanism of secondary succession within a semiarid shrubland ecosystem. Final report, October 1, 1990--June 27, 1992

    SciTech Connect (OSTI)

    Redente, E.F.; McLendon, T.

    1992-09-25

    Three experiments were conducted within a semiarid shrubland to test the role of nitrogen availability as a control mechanism in secondary succession. Secondary succession patterns were documented for seven years and effects of increased and decreased N availability levels, fumigation, and competition by early-seral species were tested. Differential responses by seral species were determined and related to successional patterns. Nitrogen availability was found to be a primary mechanism controlling the rate of succession. Relative growth rate was an important factor determining which species initially dominated and N availability became the primary control factor by the third year. As N availability increased, the rate of succession decreased. Conversely, as N availability was decreased, the rate of succession increased. The abundance of annuals was increased and abundance of perennials decreased by increased N availability. Tissue N concentration was related to lifeform and seral position, and these relationships were important in the transition from early- to mid-seral stages. Decomposer subsystem dynamics were correlated with seral community dynamics. The effect of fumigation was minimized by initially planting with late-seral species. A conceptual model of secondary succession is presented based on N availability, relative growth rate, lifeform, and decomposition dynamics.

  6. Molecular Characterization of Brown Carbon (BrC) Chromophores in Secondary Organic Aerosol Generated From Photo-Oxidation of Toluene

    SciTech Connect (OSTI)

    Lin, Peng; Liu, Jiumeng; Shilling, John E.; Kathmann, Shawn M.; Laskin, Julia; Laskin, Alexander

    2015-09-28

    Atmospheric Brown carbon (BrC) is a significant contributor to light absorption and climate forcing. However, little is known about a fundamental relationship between the chemical composition of BrC and its optical properties. In this work, light-absorbing secondary organic aerosol (SOA) was generated in the PNNL chamber from toluene photo-oxidation in the presence of NOx (Tol-SOA). Molecular structures of BrC components were examined using nanospray desorption electrospray ionization (nano-DESI) and liquid chromatography (LC) combined with UV/Vis spectroscopy and electrospray ionization (ESI) high-resolution mass spectrometry (HRMS). The chemical composition of BrC chromophores and the light absorption properties of toluene SOA (Tol-SOA) depend strongly on the initial NOx concentration. Specifically, Tol-SOA generated under high-NOx conditions (defined here as initial NOx/toluene of 5/1) appears yellow and mass absorption coefficient of the bulk sample (MACbulk@365nm = 0.78 m2 g-1) is nearly 80 fold higher than that measured for the Tol-SOA sample generated under low-NOx conditions (NOx/toluene < 1/300). Fifteen compounds, most of which are nitrophenols, are identified as major BrC chromophores responsible for the enhanced light absorption of Tol-SOA material produced in the presence of NOx. The integrated absorbance of these fifteen chromophores accounts for 40-60% of the total light absorbance by Tol-SOA at wavelengths between 300 nm and 500 nm. The combination of tandem LC-UV/Vis-ESI/HRMS measurements provides an analytical platform for predictive understanding of light absorption properties by BrC and their relationship to the structure of individual chromophores. General trends in the UV/vis absorption by plausible isomers of the BrC chromophores were evaluated using theoretical chemistry calculations. The molecular-level understanding of BrC chemistry is helpful for better understanding the evolution and behavior of light absorbing aerosols in the atmosphere.

  7. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2015-01-06

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOCs) in the gas phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the WRF-Chem regional chemistry transport model, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48 and 63% respectively over the continental US. Dry deposition ofmore » gas-phase SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40 vs. −8% for anthropogenics, and −52 vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas phase (61% for anthropogenics and 76% for biogenics). Results are sensitive to assumptions made in the dry deposition scheme, but gas-phase deposition of SVOCs remains crucial even under conservative estimates. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We consider this a lower bound for the effect of gas-phase SVOC removal on SOA concentrations. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility

  8. The effect of dry and wet deposition of condensable vapors on secondary organic aerosols concentrations over the continental US

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knote, C.; Hodzic, A.; Jimenez, J. L.

    2014-05-26

    The effect of dry and wet deposition of semi-volatile organic compounds (SVOC) in the gas-phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility information. The water solubility of SVOCs was implemented as a function of their volatility distribution within the regional chemistry transport model WRF-Chem, and simulations were carried out over the continental United States for the year 2010. Results show that including dry and wet removal of gas-phase SVOCs reduces annual average surface concentrations of anthropogenic and biogenic SOA by 48% and 63% respectively over the continental US Dry deposition of gas-phasemore » SVOCs is found to be more effective than wet deposition in reducing SOA concentrations (−40% vs. −8% for anthropogenics, −52% vs. −11% for biogenics). Reductions for biogenic SOA are found to be higher due to the higher water solubility of biogenic SVOCs. The majority of the total mass of SVOC + SOA is actually deposited via the gas-phase (61% for anthropogenics, 76% for biogenics). A number of sensitivity studies shows that this is a robust feature of the modeling system. Other models that do not consider dry and wet removal of gas-phase SVOCs would hence overestimate SOA concentrations by roughly 50%. Assumptions about the water solubility of SVOCs made in some current modeling systems (H* = 105 M atm−1; H* = H* (HNO3)) still lead to an overestimation of 25% / 10% compared to our best estimate. A saturation effect is observed for Henry's law constants above 108 M atm−1, suggesting an upper bound of reductions in surface level SOA concentrations by 60% through removal of gas-phase SVOCs. Considering reactivity of gas-phase SVOCs in the dry deposition scheme was found to be negligible. Further sensitivity studies where we reduce the volatility of organic matter show that consideration of gas-phase SVOC removal still reduces average SOA concentrations by 31% on average. We

  9. Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lambe, A. T.; Chhabra, P. S.; Onasch, T. B.; Brune, W. H.; Hunter, J. F.; Kroll, J. H.; Cummings, M. J.; Brogan, J. F.; Parmar, Y.; Worsnop, D. R.; et al

    2015-03-18

    We performed a systematic intercomparison study of the chemistry and yields of secondary organic aerosol (SOA) generated from OH oxidation of a common set of gas-phase precursors in a Potential Aerosol Mass (PAM) continuous flow reactor and several environmental chambers. In the flow reactor, SOA precursors were oxidized using OH concentrations ranging from 2.0 × 108 to 2.2 × 1010 molec cm-3 over exposure times of 100 s. In the environmental chambers, precursors were oxidized using OH concentrations ranging from 2 × 106 to 2 × 107 molec cm-3 over exposure times of several hours. The OH concentration in themore » chamber experiments is close to that found in the atmosphere, but the integrated OH exposure in the flow reactor can simulate atmospheric exposure times of multiple days compared to chamber exposure times of only a day or so. In most cases, for a specific SOA type the most-oxidized chamber SOA and the least-oxidized flow reactor SOA have similar mass spectra, oxygen-to-carbon and hydrogen-to-carbon ratios, and carbon oxidation states at integrated OH exposures between approximately 1 × 1011 and 2 × 1011 molec cm-3 s, or about 1–2 days of equivalent atmospheric oxidation. This observation suggests that in the range of available OH exposure overlap for the flow reactor and chambers, SOA elemental composition as measured by an aerosol mass spectrometer is similar whether the precursor is exposed to low OH concentrations over long exposure times or high OH concentrations over short exposure times. This similarity in turn suggests that both in the flow reactor and in chambers, SOA chemical composition at low OH exposure is governed primarily by gas-phase OH oxidation of the precursors rather than heterogeneous oxidation of the condensed particles. In general, SOA yields measured in the flow reactor are lower than measured in chambers for the range of equivalent OH exposures that can be measured in both the flow reactor and chambers. The influence of

  10. Modeling the formation and aging of secondary organic aerosols in Los Angeles during CalNex 2010

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hayes, P. L.; Carlton, A. G.; Baker, K. R.; Ahmadov, R.; Washenfelder, R. A.; Alvarez, S.; Rappenglück, B.; Gilman, J. B.; Kuster, W. C.; de Gouw, J. A.; et al

    2015-05-26

    Four different literature parameterizations for the formation and evolution of urban secondary organic aerosol (SOA) frequently used in 3-D models are evaluated using a 0-D box model representing the Los Angeles metropolitan region during the California Research at the Nexus of Air Quality and Climate Change (CalNex) 2010 campaign. We constrain the model predictions with measurements from several platforms and compare predictions with particle- and gas-phase observations from the CalNex Pasadena ground site. That site provides a unique opportunity to study aerosol formation close to anthropogenic emission sources with limited recirculation. The model SOA that formed only from the oxidationmore » of VOCs (V-SOA) is insufficient to explain the observed SOA concentrations, even when using SOA parameterizations with multi-generation oxidation that produce much higher yields than have been observed in chamber experiments, or when increasing yields to their upper limit estimates accounting for recently reported losses of vapors to chamber walls. The Community Multiscale Air Quality (WRF-CMAQ) model (version 5.0.1) provides excellent predictions of secondary inorganic particle species but underestimates the observed SOA mass by a factor of 25 when an older VOC-only parameterization is used, which is consistent with many previous model–measurement comparisons for pre-2007 anthropogenic SOA modules in urban areas. Including SOA from primary semi-volatile and intermediate-volatility organic compounds (P-S/IVOCs) following the parameterizations of Robinson et al. (2007), Grieshop et al. (2009), or Pye and Seinfeld (2010) improves model–measurement agreement for mass concentration. The results from the three parameterizations show large differences (e.g., a factor of 3 in SOA mass) and are not well constrained, underscoring the current uncertainties in this area. Our results strongly suggest that other precursors besides VOCs, such as P-S/IVOCs, are needed to explain the

  11. A High Temperature (400 to 650oC) Secondary Storage Battery Based on Liquid Sodium and Potassium Anodes

    SciTech Connect (OSTI)

    Tao, Greg; Weber, Neill

    2007-06-08

    This STTR Phase I research program was on the development of high temperature (400 to 650 C), secondary batteries with roundtrip efficiency > 90% for integration with a 3 to 10 kW solid oxide fuel cell (SOFC) system. In fulfillment of this objective, advanced planar high temperature rechargeable batteries, comprised of an alkali metal ion conducting, highly refractory, beta'' alumina solid electrolyte (BASE) sandwiched between liquid sodium (or potassium) anode and liquid metal salt cathode, were developed at MSRI. The batteries have been successfully demonstrated at a working temperature as high as 600 C. To our knowledge, so far no work has been reported in the literature on planar rechargeable batteries based on BASE, and results obtained in Phase I for the very first time demonstrated the viability of planar batteries, though relatively low temperature tubular-based sodium-sulfur batteries and ZEBRA batteries have been actively developed by very limited non U.S. companies. The results of this Phase I work have fulfilled all the goals and stated objectives, and the achievements showed much promise for further, substantial improvements in battery design and performance. The important results of Phase I are briefly described in what follows: (1) Both Na-BASE and K-BASE discs and tubes have been successfully fabricated using MSRI's patented vapor phase process. Ionic conductivity measurements showed that Na-BASE had higher ionic conductivity than K-BASE, consistence with the literature. At 500 C, Na-BASE conductivity is 0.36 S/cm, which is more than 20 times higher than 8YSZ electrolyte used for SOFC at 800 C. The activation energy is 22.58 kJ/mol. (2) CuCl{sub 2}, FeCl{sub 2}, ZnCl{sub 2}, and AgCl were identified as suitable salts for Na/metal salt or K/metal salt electrochemical couples based on thermochemical data. Further open circuit voltage measurements matched those deduced from the thermochemical data. (3) Tubular cells with CuCl{sub 2} as the cathode and

  12. SU-E-T-290: Secondary Dose Monitoring Using Scintillating Fibers in Proton Therapy of Prostate Cancer: A Geant4 Monte Carlo Simulation

    SciTech Connect (OSTI)

    Tesfamicael, B; Gueye, P; Lyons, D; Avery, S; Mahesh, M

    2014-06-01

    Purpose: To monitor the secondary dose distribution originating from a water phantom during proton therapy of prostate cancer using scintillating fibers. Methods: The Geant4 Monte Carlo toolkit version 9.6.p02 was used to simulate prostate cancer proton therapy based treatments. Two cases were studied. In the first case, 8 × 8 = 64 equally spaced fibers inside three 4 × 4 × 2.54 cmm{sup 3} DuPont™ Delrin blocks were used to monitor the emission of secondary particles in the transverse (left and right) and distal regions relative to the beam direction. In the second case, a scintillating block with a thickness of 2.54 cm and equal vertical and longitudinal dimensions as the water phantom was used. Geometrical cuts were used to extract the energy deposited in each fiber and the scintillating block. Results: The transverse dose distributions from secondary particles in both cases agree within <5% and with a very good symmetry. The energy deposited not only gradually increases as one moves from the peripheral row fibers towards the center of the block (aligned with the center of the prostate) but also decreases as one goes from the frontal to distal region of the block. The ratio of the doses from the prostate to the ones in the middle two rows of fibers showed a linear relationship with a slope (−3.55±2.26) × 10−5 MeV per treatment Gy. The distal detectors recorded a very small energy deposited due to water attenuation. Conclusion: With a good calibration and the ability to define a good correlation between the dose to the external fibers and the prostate, such fibers can be used for real time dose verification to the target.

  13. Imaging dose in breast radiotherapy: does breast size affect the dose to the organs at risk and the risk of secondary cancer to the contralateral breast?

    SciTech Connect (OSTI)

    Batumalai, Vikneswary; Quinn, Alexandra; Jameson, Michael; Delaney, Geoff; Holloway, Lois

    2015-03-15

    Correct target positioning is crucial for accurate dose delivery in breast radiotherapy resulting in utilisation of daily imaging. However, the radiation dose from daily imaging is associated with increased probability of secondary induced cancer. The aim of this study was to quantify doses associated with three imaging modalities and investigate the correlation of dose and varying breast size in breast radiotherapy. Planning computed tomography (CT) data sets of 30 breast cancer patients were utilised to simulate the dose received by various organs from a megavoltage computed tomography (MV-CT), megavoltage electronic portal image (MV-EPI) and megavoltage cone-beam computed tomography (MV-CBCT). The mean dose to organs adjacent to the target volume (contralateral breast, lungs, spinal cord and heart) were analysed. Pearson correlation analysis was performed to determine the relationship between imaging dose and primary breast volume and the lifetime attributable risk (LAR) of induced secondary cancer was calculated for the contralateral breast. The highest contralateral breast mean dose was from the MV-CBCT (1.79 Gy), followed by MV-EPI (0.22 Gy) and MV-CT (0.11 Gy). A similar trend was found for all organs at risk (OAR) analysed. The primary breast volume inversely correlated with the contralateral breast dose for all three imaging modalities. As the primary breast volume increases, the likelihood of a patient developing a radiation-induced secondary cancer to the contralateral breast decreases. MV-CBCT showed a stronger relationship between breast size and LAR of developing a radiation-induced contralateral breast cancer in comparison with the MV-CT and MV-EPI. For breast patients, imaging dose to OAR depends on imaging modality and treated breast size. When considering the use of imaging during breast radiotherapy, the patient's breast size and contralateral breast dose should be taken into account.

  14. Secondary neutron spectrum from 250-MeV passively scattered proton therapy: Measurement with an extended-range Bonner sphere system

    SciTech Connect (OSTI)

    Howell, Rebecca M.; Burgett, E. A.

    2014-09-15

    Purpose: Secondary neutrons are an unavoidable consequence of proton therapy. While the neutron dose is low compared to the primary proton dose, its presence and contribution to the patient dose is nonetheless important. The most detailed information on neutrons includes an evaluation of the neutron spectrum. However, the vast majority of the literature that has reported secondary neutron spectra in proton therapy is based on computational methods rather than measurements. This is largely due to the inherent limitations in the majority of neutron detectors, which are either not suitable for spectral measurements or have limited response at energies greater than 20 MeV. Therefore, the primary objective of the present study was to measure a secondary neutron spectrum from a proton therapy beam using a spectrometer that is sensitive to neutron energies over the entire neutron energy spectrum. Methods: The authors measured the secondary neutron spectrum from a 250-MeV passively scattered proton beam in air at a distance of 100 cm laterally from isocenter using an extended-range Bonner sphere (ERBS) measurement system. Ambient dose equivalent H*(10) was calculated using measured fluence and fluence-to-ambient dose equivalent conversion coefficients. Results: The neutron fluence spectrum had a high-energy direct neutron peak, an evaporation peak, a thermal peak, and an intermediate energy continuum between the thermal and evaporation peaks. The H*(10) was dominated by the neutrons in the evaporation peak because of both their high abundance and the large quality conversion coefficients in that energy interval. The H*(10) 100 cm laterally from isocenter was 1.6 mSv per proton Gy (to isocenter). Approximately 35% of the dose equivalent was from neutrons with energies ≥20 MeV. Conclusions: The authors measured a neutron spectrum for external neutrons generated by a 250-MeV proton beam using an ERBS measurement system that was sensitive to neutrons over the entire

  15. JLab Recognizes Security Firm as Top Small Business Subcontractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Business Mike Dallas, Jefferson Lab's chief operating officer, presents Nicole ... Stuart accepted the award plaque from Mike Dallas, Jefferson Lab's chief operating ...

  16. Waste gas to save steel firm $160,000/mo

    SciTech Connect (OSTI)

    Barber, J.

    1982-07-19

    An Armco Inc. plant at Houston will save $160,000 a month in avoided fuel costs by burning waste gas produced in its blast furnace. The $5.3 million Schack boiler system will have a three-year payback and a 25% return on investment. Armco will apply both the 10% business investment and the 10% energy-conservation tax credits. Armco decided not to renew a natural gas contract after prices rose to over $4 per thousand cubic feet. There will be no economic benefits, however, until improvements in the economy warrant restarting the blast furnace, which has been idle since mid-June. (DCK)

  17. Coverage of Independent Audits of For-Profit Firms

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    COVERAGE OF INDEPENDENT AUDITS FOR OTHER TRANSACTIONS (10 CFR 603) TABLE OF CONTENTS Part 1. ... income? The standards for program income are in section 603.835 of 10 CFR part 603.

  18. Firm eyes savings from tires-to-fuel system

    SciTech Connect (OSTI)

    Barber, J.

    1983-01-31

    A $600,000 pyrolysis system to convert tire scraps into methane will eliminate a tire retreading company's landfill and boiler fuel costs and achieve a five-year payback. The process also yields steel belts, fibers, and carbon black byproducts that can be sold for additional revenue. Heat from the hot exhaust gases will be recycled to the combustion chamber. A 10% federal energy tax credit and a 10% investment tax credit lowered the capital costs for $480,000. (DCK)

  19. Maintenance & Cleaning Firm Earns Jefferson Lab's Small Business Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Maintaining Your Air Conditioner Maintaining Your Air Conditioner Replacing or cleaning air conditioner filters is a critical maintenance task. | Photo courtesy of ©iStockphoto/firemanYU. Replacing or cleaning air conditioner filters is a critical maintenance task. | Photo courtesy of ©iStockphoto/firemanYU. An air conditioner's filters, coils, and fins require regular maintenance for the unit to function effectively and efficiently throughout its years of service. Neglecting necessary

  20. Colorado Firm Develops Innovative Materials for Geothermal Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The company developed materials designed to create and conserve geothermal reservoirs in harsh down-hole environments to produce energy. Composite used an innovative polymer ...

  1. NREL and Colombian Oil Firm Unlocking Agricultural Waste Feedstocks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... greenhouse gases and reducing reliability on foreign sources of oil, Elander said. The experience gained in processing these two biomass feedstocks will be directly applicable to ...

  2. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... premises are subject to search. (e) Contractor shall ... Control : SF 6432-FP Title: Standard Terms and Conditions ...

  3. EIS-0370: Windy Gap Firming Project, Colorado | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    a cooperating agency, evaluates the environmental impacts of a proposal to construct new water storage reservoir capacity southwest of Loveland, Colorado. Western has jurisdiction...

  4. FirmGreen Energy Inc FGE | Open Energy Information

    Open Energy Info (EERE)

    an integrated energy company participating in virtually all aspects of the global green energy business. Coordinates: 41.837752, -79.268594 Show Map Loading map......

  5. New research contract links LANL and robotics firm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inc. July 11, 2012 rom left, David Pesiri and David Seigel of the LANL Technology Transfer office, and Andrew Borene, Andrew Drenner, and Patrick McKinney of ReconRobotics. Los...

  6. EIS-0370: Windy Gap Firming Project; North Central Colorado

    Broader source: Energy.gov [DOE]

    This EIS, prepared by the Department of the Interior (Bureau of Reclamation, Great Plains Region), with DOE's Western Area Power Administration as a cooperating agency, evaluates the environmental impacts of a proposal to construct new water storage reservoir capacity southwest of Loveland, Colorado. Western has jurisdiction over the transmission line that would be relocated if the proposed action is implemented and would market additional power that may be generated as a result of the project.

  7. Utility Sector Leaders Make Firm Commitment to Energy Efficiency

    Broader source: Energy.gov [DOE]

    More than 80 energy, environmental and other organizations announced commitments and public statements in support of the National Action Plan for Energy Efficiency (NAPEE), released today, which provides energy consumers and providers information on policies and techniques to save money as well as protect the environment. By adopting the plan's recommendations on low-cost, under-used energy efficiency, Americans could save hundreds of billions of dollars on their gas and electric utility bills, cut greenhouse gas emissions, and lower the costs for energy and pollution controls.

  8. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... National Fire Protection Association (NFPA), Standard of Mechanical Engineers (ASME), ... APPLY TO CONTRACTS AT ANY VALUE FAR 52.203-99 Prohibition on Contracting with Entities ...

  9. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... premises are subject to search. (e) Contractor will ... Control : SF 6432-FP Title: Standard Terms and Conditions ...

  10. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... SF 6432-FP Title: Standard Terms and Conditions for ... premises are subject to search. (e) Contractor shall ...

  11. The Formation of Pioneer Plant Projects in Chemical Processing Firms

    Office of Environmental Management (EM)

    Framework for Project Development and Key Concepts Project Development Process: What Is It? * Framework based on experience * Focuses on key decision points * Shows that project development is iterative * Emphasizes that delaying or deciding against a project that does not meet current goals is a viable outcome and option 2 Project Uncertainty/Capitol at Risk 3 Unknowns Investment Revenue pays off invested $ Project Operation Financial Close Step 1, Step 2, Step 3 Step 4 Step 5 Construction

  12. SF6432-FP (02-01-12) Firm Fixed Price

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF POTENTIAL DELAY ORDER OF PRECEDENCE PAYMENT PERFORMANCE EVALUATION PROGRAM PRICING OF ... court and a listing of the agreement numbers for which final payment has not been made. ...

  13. Two firms to win three products from whey

    SciTech Connect (OSTI)

    Not Available

    1981-12-14

    A joint venture between Corning Glass Works and Kroger Co. is reported that will convert whey into hydrolyzed lactose. Part of the sweet syrup will be converted into bakers' yeast while the rest of the syrup will be used by Kroger as-such, and so will a byproduct, whey-protein concentrate. A 35,000 sq. ft. plant will be built at Winchester, Ky and is due for operation in 1983.

  14. Zero discharge firmly entrenched as a powerplant design strategy

    SciTech Connect (OSTI)

    Strauss, S.D.

    1994-10-01

    This article describes how, drawing on a variety of options, this environmentally friendly practice has become a fact of life for new powerplant projects. Driven by regulatory restrictions and penalties for withdrawals from the nation's watercourses, powerplant designers have focused strongly on recycling water to minimize flows both into and outside plant boundaries. Quality of, and proximity to, water sources are a major environmental factor in the siting stage and process design. Thereafter, wastewater discharge draws primary emphasis. Cooling-tower blowdown and other waste streams are now processed to recycle water while converting remaining dissolved solids (TDS) to a disposable cake. The available techniques involve mechanical evaporation, side-stream softening, crystallization or spray drying, membrane treatment, and staged cooling. Space limitations, water quality, and other variables determine the best choice for any plant. While each offers certain advantages, none provides a panacea without attendant challenges, ranging from capital cost to pretreatment requirements to equipment operating difficulties.

  15. EERE Success Story-Colorado Firm Develops Innovative Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development, Inc. advanced several technologies related to geothermal energy extraction. ... the hot rock heated the fluid to sufficient temperatures for geothermal energy production. ...

  16. Fact Sheet: Wind Firming EnergyFarm (October 2012)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The EnergyFarm will displace a planned 73 million natural-gas-fired power plant intended to ... EnergyFarm Project Benefits * Enables integration of renewable energy technologies, ...

  17. Firm turns trash to steam, saves $60,500

    SciTech Connect (OSTI)

    Cohn, L.

    1982-05-17

    An incinerator/boiler system that the Ingersoll-Rand Co. uses to burn trash and produce steam for heating and parts cleaning saved the company $60,500 in avoided fuel and trash-disposal costs last year. Replacing a natural gas-fired boiler, the new system reduces the demand for gas by 14%. Heat recovered from the trash burning is transferred to the boiler to make steam. No smoke is emitted. (DCK)

  18. Historical Average Priority Firm Power Rates (rates/previous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (A to Z) - - - - - - - - - - - - - Account Executives Administrator's RODs Aluminum Industry Study (2000-01) Billing Procedures Customer Service Centers Daily Notice Document...

  19. Benchmarked analyses of neutron and secondary gamma rays for a spent-fuel shipping cask using MORSE-CGA-PC and the DABL69 cross sections

    SciTech Connect (OSTI)

    Golshani, M.; Reichert, P.T. )

    1992-01-01

    The potential neutron radiation dose rates around a spent-fuel shipping cask are a fundamental consideration for the design of such a cask. Neutron radiation from spent fuel is predominantly from decay of {sup 242}Cm and{sup 244}Cm. Secondary gamma can be produced during neutron transport. The combination of the MORSE-SGC computer program and a 32-neutron-group, 18-gamma-group, P5 library derived from ENDF/B-IV could reasonably predict the neutron transport and secondary gamma production and transport, based on actual experimental data. The experimental cask was designed to contain three pressurized water reactor (PWR) or seven boiling water reactor fuel assemblies. The neutron source employed in the experiment was {sup 252}Cf, whose spectrum is similar to the fission spectrum expected from PWR spent fuel. This paper discusses analyses of the same experimental data using the MORSE-CGA program, the DABL69 cross-section set, and a surface crossing estimator. The DLC-130/DABL69 cross-section was employed as the most suitable, readily available, broad-group library. The DABL69 contains 46-neutron and 23-gamma-ray energy groups and the Legendre expansion coefficient for angular distribution is 5(P5). Furthermore, this analysis was done using a personal computer (PC) version of MORSE-CGA, with runs taken to the point of reducing fractional standard deviations to 10% or less. The purpose of this paper is to compare calculated radiation dose rate with available measured data.

  20. Setting and stiffening of cementitious components in Cast Stone waste form for disposal of secondary wastes from the Hanford waste treatment and immobilization plant

    SciTech Connect (OSTI)

    Chung, Chul-Woo; Chun, Jaehun, E-mail: jaehun.chun@pnnl.gov; Um, Wooyong; Sundaram, S.K.; Westsik, Joseph H.

    2013-04-01

    Cast Stone is a cementitious waste form, a viable option to immobilize secondary nuclear liquid wastes generated from the Hanford Waste Treatment and Immobilization Plant. However, no study has been performed to understand the flow and stiffening behavior, which is essential to ensure proper workability and is important to safety in a nuclear waste field-scale application. X-ray diffraction, rheology, and ultrasonic wave reflection methods were used to understand the specific phase formation and stiffening of Cast Stone. Our results showed a good correlation between rheological properties of the fresh mixture and phase formation in Cast Stone. Secondary gypsum formation was observed with low concentration simulants, and the formation of gypsum was suppressed in high concentration simulants. A threshold concentration for the drastic change in stiffening was found at 1.56 M Na concentration. It was found that the stiffening of Cast Stone was strongly dependent on the concentration of simulant. Highlights: A combination of XRD, UWR, and rheology gives a better understanding of Cast Stone. Stiffening of Cast Stone was strongly dependent on the concentration of simulant. A drastic change in stiffening of Cast Stone was found at 1.56 M Na concentration.

  1. Setting and Stiffening of Cementitious Components in Cast Stone Waste Form for Disposal of Secondary Wastes from the Hanford waste treatment and immobilization plant

    SciTech Connect (OSTI)

    Chung, Chul-Woo; Chun, Jaehun; Um, Wooyong; Sundaram, S. K.; Westsik, Joseph H.

    2013-04-01

    Cast stone is a cementitious waste form, a viable option to immobilize secondary nuclear liquid wastes generated from Hanford vitrification plant. While the strength and radioactive technetium leaching of different waste form candidates have been reported, no study has been performed to understand the flow and stiffening behavior of Cast Stone, which is essential to ensure the proper workability, especially considering necessary safety as a nuclear waste form in a field scale application. The rheological and ultrasonic wave reflection (UWR) measurements were used to understand the setting and stiffening Cast Stone batches. X-ray diffraction (XRD) was used to find the correlation between specific phase formation and the stiffening of the paste. Our results showed good correlation between rheological properties of the fresh Cast Stone mixture and phase formation during hydration of Cast Stone. Secondary gypsum formation originating from blast furnace slag was observed in Cast Stone made with low concentration simulants. The formation of gypsum was suppressed in high concentration simulants. It was found that the stiffening of Cast Stone was strongly dependent on the concentration of simulant. A threshold concentration for the drastic change in stiffening was found at 1.56 M Na concentration.

  2. Effect of secondary structure on the potential of mean force for poly-L-lysine in the alpha-Helix and beta-sheet conformations

    SciTech Connect (OSTI)

    Grigsby, J.J.; Blanch, H.W.; Prausnitz, J.M.

    2001-10-30

    Because poly-L-lysine (PLL) can exist in the {alpha}-helix or {beta}-sheet conformation depending on solution preparation and solution conditions, PLL is a suitable candidate to probe the dependence of protein interactions on secondary structure. The osmotic second virial coefficient and weight-average molecular weight are reported from low-angle laser-light scattering measurements for PLL as a function of NaCl concentration, pH, and {alpha}-helix or {beta}-sheet content. Interactions between PLL molecules become more attractive as salt concentration increases due to screening of PLL charge by salt ions and at low salt concentration become more attractive as pH increases due to decreased net charge on PLL. The experimental results show that interactions are stronger for the {beta}-sheet conformation than for the {alpha}-helix conformation. A spherically-symmetric model for the potential of mean force is used to account for specific interactions not described by DLVO theory and to show how differences in secondary structure affect PLL interactions.

  3. Diagenesis and secondary porosity enhancement from dissolution of analcime cement in reservoir sandstones: The Upper Permian Pingdiquan Formation, Junggar basin, northwest China

    SciTech Connect (OSTI)

    Zhaohui, T.; Longstaffe, F.J.; Parnell, J.

    1996-12-31

    The Junggar Basin is one of the largest and most important oil-producing basins in China, in which Upper Permian lacustrine oil shales are among the thickest and richest petroleum source rocks in the world. The Upper Permian Pingdiquan Formation was deposited predominantly in fan-delta sequences within a lacustrine setting. The Pingdiquan Formation sandstones constitute the principal oil reservoirs, whereas the interbedded black shales are the predominant oil source rocks. The early diagenetic mineral assemblage in the sandstones comprises siderite, pyrite, analcime, albite, calcite and authigenic quartz as well as trace amount of halite; By contrast, the late diagenetic minerals are characterized by authigenic K-feldspar, ankerite, and minor amounts of mixed-layer clay minerals. Petrographic, mineralogical and available paleoecological data suggest that early authigenic minerals in the sandstones were controlled by alternating periodic fresh water and saline/alkaline water episodes in a lacustrine environment. The cementation of siderite, analcime, calcite and albite occluded the substantial porosity in the sandstones at an early diagenetic stage. However, extensive dissolution of analcime cement and labile detrital feldspars occurred during burial diagenesis, resulting in a significant secondary porosity enhancement in the sandstones and making them very good quality oil reservoirs. The origin of secondary porosity is related to the generation of various organic acids due to organic maturation of the interbedded exceptionally organic-rich oil shales.

  4. Diagenesis and secondary porosity enhancement from dissolution of analcime cement in reservoir sandstones: The Upper Permian Pingdiquan Formation, Junggar basin, northwest China

    SciTech Connect (OSTI)

    Zhaohui, T.; Longstaffe, F.J. ); Parnell, J. )

    1996-01-01

    The Junggar Basin is one of the largest and most important oil-producing basins in China, in which Upper Permian lacustrine oil shales are among the thickest and richest petroleum source rocks in the world. The Upper Permian Pingdiquan Formation was deposited predominantly in fan-delta sequences within a lacustrine setting. The Pingdiquan Formation sandstones constitute the principal oil reservoirs, whereas the interbedded black shales are the predominant oil source rocks. The early diagenetic mineral assemblage in the sandstones comprises siderite, pyrite, analcime, albite, calcite and authigenic quartz as well as trace amount of halite; By contrast, the late diagenetic minerals are characterized by authigenic K-feldspar, ankerite, and minor amounts of mixed-layer clay minerals. Petrographic, mineralogical and available paleoecological data suggest that early authigenic minerals in the sandstones were controlled by alternating periodic fresh water and saline/alkaline water episodes in a lacustrine environment. The cementation of siderite, analcime, calcite and albite occluded the substantial porosity in the sandstones at an early diagenetic stage. However, extensive dissolution of analcime cement and labile detrital feldspars occurred during burial diagenesis, resulting in a significant secondary porosity enhancement in the sandstones and making them very good quality oil reservoirs. The origin of secondary porosity is related to the generation of various organic acids due to organic maturation of the interbedded exceptionally organic-rich oil shales.

  5. Case hardenable nickel-cobalt steel

    SciTech Connect (OSTI)

    Qian, Yana; Olson, Gregory B.

    2012-04-17

    An advanced secondary hardening carburized Ni--Co steel achieves an improved case hardness of about 68-69 Rc together with nominal core hardness of about 50 Rc.

  6. Synthesis, characterizations and catalytic studies of a new two-dimensional metal−organic framework based on Co–carboxylate secondary building units

    SciTech Connect (OSTI)

    Bagherzadeh, Mojtaba; Ashouri, Fatemeh; Đaković, Marijana

    2015-03-15

    A metal–organic framework [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}] was synthesized and structurally characterized. X-ray single crystal analysis revealed that the framework contains a 2D polymeric chain through coordination of 1,4-benzenedicarboxylic acid linker ligand to cobalt centers. The polymer crystallize in monoclinic P2{sub 1}/n space group with a=13.989(3) Å, b=9.6728(17) Å, c=16.707(3) Å, and Z=2. The polymer features a framework based on the perfect octahedral Co–O6 secondary building units. The catalytic activities of [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}]{sub n} for olefins oxidation was conducted. The heterogeneous catalyst could be facilely separated from the reaction mixture, and reused three times without significant degradation in catalytic activity. Furthermore, no contribution from homogeneous catalysis of active species leaching into reaction solution was detected. - Graphical abstract: A metal–organic framework of [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}] was synthesized by hydrothermal method. This 2D-periodic framework is constructed from the infinite Co–O–C secondary building units and crystallizes in the monoclinic P2{sub 1}/n space group based on Co(II)–carboxylate units. The catalytic oxidation of various olefins was effectively carried out with [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}]{sub n} catalyst by TBHP as oxidant. - Highlights: • A metal–organic framework of [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}] is prepared by hydrothermal method. • The [Co{sub 3}(BDC){sub 3}(DMF){sub 2}(H{sub 2}O){sub 2}]{sub n} is constructed from Co–carboxylate secondary building units. • This coordination polymer displayed high catalytic activity for olefin oxidation reactions. • The catalytic reaction is heterogeneous and catalyst can be simply separated. • The heterogeneous catalyst can be reused several times without significant loss of catalytic activity.

  7. A Metal-Organic Framework Containing Unusual Eight-Connected Zr–-Oxo Secondary Building Units and Orthogonal Carboxylic Acids for Ultra-sensitive Metal Detection

    SciTech Connect (OSTI)

    Carboni, Michaël; Lin, Zekai; Abney, Carter W.; Zhang, Teng; Lin, Wenbin

    2015-08-21

    Two metal-organic frameworks (MOFs) with Zr-oxo secondary building units (SBUs) were prepared by using p,p'-terphenyldicarboxylate (TPDC) bridging ligands pre-functionalized with orthogonal succinic acid (MOF-1) and maleic acid groups (MOF-2). Single-crystal X-ray structure analysis of MOF-1 provides the first direct evidence for eight-connected SBUs in UiO-type MOFs. In contrast, MOF-2 contains twelve-connected SBUs as seen in the traditional UiO MOF topology. These structural assignments were confirmed by extended X-ray absorption fine structure (EXAFS) analysis. The highly porous MOF-1 is an excellent fluorescence sensor for metal ions with the detection limit of <0.5 ppb for Mn2+ and three to four orders of magnitude greater sensitivity for metal ions than previously reported luminescent MOFs.

  8. An economic and technical assessment of black-dross and salt-cake-recycling systems for application in the secondary aluminum industry

    SciTech Connect (OSTI)

    Karvelas, D.; Daniels, E.; Jody, B.; Bonsignore, P.

    1991-12-01

    The secondary aluminum industry annually disposes of large amounts of dross residues and salt cake, which are by-products from the processing of scrap aluminum for reuse. These wastes contain as much as 50% salts and are presently disposed of in conventional landfills. As the costs of landfill space increase and the availability of landfill space decreases, disposal of the residues will increasingly compromise the economics of recycling aluminum. Alternative processes exist by which the major constituents of the various drosses and salt cakes can be recovered for recycling. In this study, we review available recycling technologies and processes relevant to the recycling of black dross and salt cake and discuss new concepts that have the potential to improve the cost-effectiveness of recycling technologies.

  9. PROSPECTS FOR DETECTION OF SYNCHROTRON EMISSION FROM SECONDARY ELECTRONS AND POSITRONS IN STARLESS CORES: APPLICATION TO G0.216+0.016

    SciTech Connect (OSTI)

    Jones, D. I.

    2014-09-01

    We investigate the diffusion of cosmic rays into molecular cloud complexes. Using the cosmic-ray diffusion formalism of Protheroe et al., we examine how cosmic rays diffuse into clouds exhibiting different density structures, including a smoothed step-function, as well as Gaussian and inverse-r density distributions, which are well known to trace the structure of star-forming regions. These density distributions were modeled as an approximation to the Galactic center cloud G0.216+0.016, a recently discovered massive dust clump that exhibits limited signs of massive star formation and thus may be the best region in the Galaxy to observe synchrotron emission from secondary electrons and positrons. Examination of the resulting synchrotron emission, produced by the interaction of cosmic-ray protons interacting with ambient molecular matter producing secondary electrons and positrons reveals that, due to projection effects, limb-brightened morphology results in all cases. However, we find that the Gaussian and inverse-r density distributions show much broader flux density distributions than step-function distributions. Significantly, some of the compact (compared to the 2.''2 resolution, 5.3GHz Karl G. Jansky Very Large Array (JVLA) observations) sources show non-thermal emission, which may potentially be explained by the density structure and the lack of diffusion of cosmic rays into the cloud. We find that we can match the 5.3 and 20GHz flux densities of the non-thermal source JVLA 1 and 6 from Rodrguez and Zapata with a local cosmic-ray flux density, a diffusion coefficient suppression factor of ? = 0.1-0.01 for a coefficient of 3 10{sup 27}cm{sup 2}s{sup 1}, and a magnetic field strength of 470 ?G.

  10. Nominate Your Mentor for the Presidential Award in Science, Math, and Engineering Mentoring

    Broader source: Energy.gov [DOE]

    Editor's Note: This blog was originally posted by the White House Office of Science and Technology Policy. 

  11. CONCEPTUAL DESIGN AND ECONOMICS OF A NOMINAL 500 MWe SECOND-GENERATION PFB COMBUSTION PLANT

    SciTech Connect (OSTI)

    A. Robertson; H. Goldstein; D. Horazak; R. Newby

    2003-09-01

    Research has been conducted under United States Department of Energy Contract DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant, called a Second Generation Pressurized Fluidized Bed Combustion Plant (2nd Gen PFB), offers the promise of efficiencies greater than 48 percent, with both emissions and a cost of electricity that are significantly lower than those of conventional pulverized coal-fired (PC) plants with wet flue gas desulfurization. The 2nd Gen PFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed boiler, and the combustion of carbonizer syngas in a gas turbine combustor to achieve gas turbine inlet temperatures of 2300 F and higher. A conceptual design and an economic analysis was previously prepared for this plant. When operating with a Siemens Westinghouse W501F gas turbine, a 2400psig/1000 F/1000 F/2-1/2 in. Hg. steam turbine, and projected carbonizer, PCFB, and topping combustor performance data, the plant generated 496 MWe of power with an efficiency of 44.9 percent (coal higher heating value basis) and a cost of electricity 22 percent less than a comparable PC plant. The key components of this new type of plant have been successfully tested at the pilot plant stage and their performance has been found to be better than previously assumed. As a result, the referenced conceptual design has been updated herein to reflect more accurate performance predictions together with the use of the more advanced Siemens Westinghouse W501G gas turbine. The use of this advanced gas turbine, together with a conventional 2400 psig/1050 F/1050 F/2-1/2 in. Hg. steam turbine increases the plant efficiency to 48.2 percent and yields a total plant cost of $1,079/KW (January 2002 dollars). The cost of electricity is 40.7 mills/kWh, a value 12 percent less than a comparable PC plant.

  12. Price of Freeport, TX Natural Gas LNG Imports from Egypt (Nominal...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- 4.24 2010's -- 12.23 -- -- --

  13. E. O. Lawrence Award Nominations | U.S. DOE Office of Science...

    Office of Science (SC) Website

    Condensed Matter and Materials Sciences, Energy Science and Innovation, Fusion and Plasma Sciences, High Energy and Nuclear Physics, and National Security and Nonproliferation. ...

  14. DOE Encourages Utility Sector Nominations to Commerce Department's Spectrum Advisory Committee

    Broader source: Energy.gov [DOE]

    Because of the role wireless technologies will play in the evolution toward a smarter national grid, one of the recommendations in DOE’s report, The Communications Requirements of Smart Grid...

  15. U.S. Nominal Cost per Crude Oil Well Drilled (Thousand Dollars per Well)

    Gasoline and Diesel Fuel Update (EIA)

    Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 142,243 194,185 258,468 267,309 296,968 259,652 2000's 295,916 341,084 358,397 356,964 340,537 378,485 370,756 400,244 440,262 459,330 2010's 510,691 532,893 465,005 492,143 634,045 607,148

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's -19,376 5,419 -12,622 6,367 -21,639 -569 2000's 24,200 -47,490 4,864 -25,973 22,970 -33,755 -18,935 20,001 -42,044 -56,010 2010's

  16. DOE Encourages Utility Sector Nominations to the Federal Communications Commission's Communications, Security, Reliability, and Interoperability Council

    Broader source: Energy.gov [DOE]

    Because of the role communications technologies will play in the evolution toward a smarter national grid, DOE recommended in its October 2010 report, The Communications Requirements of Smart Grid...

  17. Price of Elba Island, GA Natural Gas LNG Imports from Egypt (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.21 3.67 4.14 4.29 4.22 3.22 2012 2.52

  18. Price of Freeport, TX Natural Gas LNG Imports from Egypt (Nominal Dollars

    U.S. Energy Information Administration (EIA) Indexed Site

    per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 12.23

  19. Price of Freeport, TX Natural Gas LNG Imports from Other Countries (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2010's --

  20. Price of Freeport, TX Natural Gas LNG Imports from Other Countries (Nominal

    U.S. Energy Information Administration (EIA) Indexed Site

    Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014

  1. Enterprise Assessments Targeted Review of the Safety System Management of the Secondary Confinement System and Power Distribution Safety System at the Y-12 National Security Complex Highly Enriched Uranium Materials Facility … December 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Targeted Review of the Safety System Management of the Secondary Confinement System and Safety Significant Power Distribution System at the Y-12 National Security Complex Highly Enriched Uranium Materials Facility December 2015 Office of Nuclear Safety and Environmental Assessments Office of Environment, Safety and Health Assessments Office of Enterprise Assessments U.S. Department of Energy i Table of Contents Acronyms

  2. Technical Information on the Carbonation of the EBR-II Reactor, Summary Report Part 1: Laboratory Experiments and Application to EBR-II Secondary Sodium System

    SciTech Connect (OSTI)

    Steven R. Sherman

    2005-04-01

    Residual sodium is defined as sodium metal that remains behind in pipes, vessels, and tanks after the bulk sodium metal has been melted and drained from such components. The residual sodium has the same chemical properties as bulk sodium, and differs from bulk sodium only in the thickness of the sodium deposit. Typically, sodium is considered residual when the thickness of the deposit is less than 5-6 cm. This residual sodium must be removed or deactivated when a pipe, vessel, system, or entire reactor is permanently taken out of service, in order to make the component or system safer and/or to comply with decommissioning regulations. As an alternative to the established residual sodium deactivation techniques (steam-and-nitrogen, wet vapor nitrogen, etc.), a technique involving the use of moisture and carbon dioxide has been developed. With this technique, sodium metal is converted into sodium bicarbonate by reacting it with humid carbon dioxide. Hydrogen is emitted as a by-product. This technique was first developed in the laboratory by exposing sodium samples to humidified carbon dioxide under controlled conditions, and then demonstrated on a larger scale by treating residual sodium within the Experimental Breeder Reactor II (EBR-II) secondary cooling system, followed by the primary cooling system, respectively. The EBR-II facility is located at the Idaho National Laboratory (INL) in southeastern Idaho, U.S.A. This report is Part 1 of a two-part report. It is divided into three sections. The first section describes the chemistry of carbon dioxide-water-sodium reactions. The second section covers the laboratory experiments that were conducted in order to develop the residual sodium deactivation process. The third section discusses the application of the deactivation process to the treatment of residual sodium within the EBR-II secondary sodium cooling system. Part 2 of the report, under separate cover, describes the application of the technique to residual sodium

  3. BdCESA7, BdCESA8, and BdPMT utility promoter constructs for targeted expression to secondary cell-wall-forming cells of grasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petrik, Deborah L.; Cass, Cynthia L.; Padmakshan, Dharshana; Foster, Cliff E.; Vogel, John P.; Karlen, Steven D.; Ralph, John; Sedbrook, John C.

    2016-02-04

    Utility vectors with promoters that confer desired spatial and temporal expression patterns are useful tools for studying gene and cellular function and for industrial applications. To target the expression of DNA sequences of interest to cells forming plant secondary cell walls, which generate most of the vegetative biomass, upstream regulatory sequences of the Brachypodium distachyon lignin biosynthetic gene BdPMT and the cellulose synthase genes BdCESA7 and BdCESA8 were isolated and cloned into binary vectors designed for Agrobacterium-mediated transformation of monocots. Expression patterns were assessed using the β-glucuronidase gene GUSPlus and X-glucuronide staining. All three promoters showed strong expression levels inmore » stem tissue at the base of internodes where cell wall deposition is most active, in both vascular bundle xylem vessels and tracheids, and in interfascicular tissues, with expression less pronounced in developmentally older tissues. In leaves, BdCESA7 and BdCESA8 promoter-driven expression was strongest in leaf veins, leaf margins, and trichomes; relatively weaker and patchy expression was observed in the epidermis. BdPMT promoter-driven expression was similar to the BdCESA promoters expression patterns, including strong expression in trichomes. The intensity and extent of GUS staining varied considerably between transgenic lines, suggesting that positional effects influenced promoter activity. Introducing the BdPMT and BdCESA8 Open Reading Frames into BdPMT and BdCESA8 utility promoter binary vectors, respectively, and transforming those constructs into Brachypodium pmt and cesa8 loss-of-function mutants resulted in rescue of the corresponding mutant phenotypes. This work therefore validates the functionality of these utility promoter binary vectors for use in Brachypodium and likely other grass species. Lastly, the identification, in Bdcesa8-1 T-DNA mutant stems, of an 80% reduction in crystalline cellulose levels confirms that the

  4. Secondary Energy Infobook and Secondary Infobook Activities (19 Activities)

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    The teacher's infobook contains dozens of fact sheets about the major energy sources, electricity, energy efficiency, energy conservation, transportation, and emerging technologies. Detailed information covers an introduction to energy, the forms of energy, global climate change, the history of electricity, and information about the major energy sources. The companion book of student activities reinforces the vocabulary, concepts, and facts about energy. Answer keys are provided.

  5. Preparation of LiMn{sub 2}O{sub 4} cathode thin films for thin film lithium secondary batteries by a mist CVD process

    SciTech Connect (OSTI)

    Tadanaga, Kiyoharu; Yamaguchi, Akihiro; Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro; Duran, Alicia; Aparacio, Mario

    2014-05-01

    Highlights: LiMn{sub 2}O{sub 4} thin films were prepared by using the mist CVD process. An aqueous solution of lithium and manganese acetates is used for the precursor solution. The cell with the LiMn{sub 2}O{sub 4} thin films exhibited a capacity of about 80 mAh/g. The cell showed good cycling performance during 10 cycles. - Abstract: LiMn{sub 2}O{sub 4} cathode thin films for thin film lithium secondary batteries were prepared by using so-called the mist CVD process, employing an aqueous solution of lithium acetate and manganese acetate, as the source of Li and Mn, respectively. The aqueous solution of starting materials was ultrasonically atomized to form mist particles, and mists were transferred by nitrogen gas to silica glass substrate to form thin films. FE-SEM observation revealed that thin films obtained by this process were dense and smooth, and thin films with a thickness of about 750 nm were obtained. The electrochemical cell with the thin films obtained by sintering at 700 C exhibited a capacity of about 80 mAh/g, and the cell showed good cycling performance during 10 cycles.

  6. Shielding experiments by the JASMIN Collaboration at Fermilab (II) - radioactivity measurement induced by secondary particles from the anti-proton production target

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hiroshi, Yashima; Norihiro, Matsuda; Yoshimi, Kasugai; Hiroshi, Nakashima; Yukio, Sakamoto; Hiroshi, Matsumura; Hiroshi, Iwase; Norikazu, Kinoshita; David, Boehnlein; Gary, Lautenschlager; et al

    2011-08-01

    The JASMIN Collaboration has performed an experiment to conduct measurements of nuclear reaction rates around the anti-proton production (Pbar) target at the Fermi National Accelerator Laboratory (FNAL). At the Pbar target station, the target, consisting of an Inconel 600 cylinder, was irradiated by a 120 GeV/c proton beam from the FNAL Main Injector. The beam intensity was 3.6 x 1012 protons per second. The samples of Al, Nb, Cu, and Au were placed near the target to investigate the spatial and energy distribution of secondary particles emitted from it. After irradiation, the induced activities of the samples were measured bymore » studying their gamma ray spectra using HPGe detectors. The production rates of 30 nuclides induced in Al, Nb, Cu, Au samples were obtained. These rates increase for samples placed in a forward (small angle) position relative to the target. The angular dependence of these reaction rates becomes larger for increasing threshold energy. These experimental results are compared with Monte Carlo calculations. The calculated results generally agree with the experimental results to within a factor of 2 to 3.« less

  7. A New Real-Time Method for Determining Particles Sphericity and Density: Application to Secondary Organic Aerosol Formed by Ozonolysis of alpha-Pinene

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Yang, Juan; Song, Chen; Zaveri, Rahul A.; Imre, Dan G.

    2008-11-01

    Particle volumes are most often obtained by measuring particle mobility size distributions and assuming that the particles are spherical. These volumes are then converted to mass loads by using particle densities that are commonly either assumed or estimated from the measured mobility and vacuum aerodynamic diameters assuming again that the particles are spherical. Depending on the system, these assumptions can introduce significant errors. We present a new method that can be applied to any particle system to determine in real-time whether the particles are spherical or not. We use our 2nd generation single particle mass spectrometer (SPLAT II) to measure with extremely high precision the vacuum aerodynamic size distributions of particles classified by differential mobility analyzer (DMA) and demonstrate that the line shape of these distributions provide a way to unambiguously distinguish between spherical and aspherical particles. Moreover, the very same experimental system is used to obtain in addition to individual particle size, its density, composition and dynamic shape factor. We illustrate the application of this method to secondary organic aerosols formed as a result of ozonolysis of ?-pinene in the presence and absence of an OH scavenger and find these particles to be spherical with densities of 1.1980.004 gcm-3 and 1.2130.003 gcm-3 respectively.

  8. Design and performance of a combined secondary ion mass spectrometry-scanning probe microscopy instrument for high sensitivity and high-resolution elemental three-dimensional analysis

    SciTech Connect (OSTI)

    Wirtz, Tom; Fleming, Yves; Gerard, Mathieu; Gysin, Urs; Glatzel, Thilo; Meyer, Ernst; Wegmann, Urs; Maier, Urs; Odriozola, Aitziber Herrero; Uehli, Daniel

    2012-06-15

    State-of-the-art secondary ion mass spectrometry (SIMS) instruments allow producing 3D chemical mappings with excellent sensitivity and spatial resolution. Several important artifacts however arise from the fact that SIMS 3D mapping does not take into account the surface topography of the sample. In order to correct these artifacts, we have integrated a specially developed scanning probe microscopy (SPM) system into a commercial Cameca NanoSIMS 50 instrument. This new SPM module, which was designed as a DN200CF flange-mounted bolt-on accessory, includes a new high-precision sample stage, a scanner with a range of 100 {mu}m in x and y direction, and a dedicated SPM head which can be operated in the atomic force microscopy (AFM) and Kelvin probe force microscopy modes. Topographical information gained from AFM measurements taken before, during, and after SIMS analysis as well as the SIMS data are automatically compiled into an accurate 3D reconstruction using the software program 'SARINA,' which was developed for this first combined SIMS-SPM instrument. The achievable lateral resolutions are 6 nm in the SPM mode and 45 nm in the SIMS mode. Elemental 3D images obtained with our integrated SIMS-SPM instrument on Al/Cu and polystyrene/poly(methyl methacrylate) samples demonstrate the advantages of the combined SIMS-SPM approach.

  9. Targeted technology applications for infield reserve growth: A synopsis of the Secondary Natural Gas Recovery project, Gulf Coast Basin. Topical report, September 1988--April 1993

    SciTech Connect (OSTI)

    Levey, R.A.; Finley, R.J.; Hardage, B.A.

    1994-06-01

    The Secondary Natural Gas Recovery (SGR): Targeted Technology Applications for Infield Reserve Growth is a joint venture research project sponsored by the Gas Research Institute (GRI), the US Department of Energy (DOE), the State of Texas through the Bureau of Economic Geology at The University of Texas at Austin, with the cofunding and cooperation of the natural gas industry. The SGR project is a field-based program using an integrated multidisciplinary approach that integrates geology, geophysics, engineering, and petrophysics. A major objective of this research project is to develop, test, and verify those technologies and methodologies that have near- to mid-term potential for maximizing recovery of gas from conventional reservoirs in known fields. Natural gas reservoirs in the Gulf Coast Basin are targeted as data-rich, field-based models for evaluating infield development. The SGR research program focuses on sandstone-dominated reservoirs in fluvial-deltaic plays within the onshore Gulf Coast Basin of Texas. The primary project research objectives are: To establish how depositional and diagenetic heterogeneities cause, even in reservoirs of conventional permeability, reservoir compartmentalization and hence incomplete recovery of natural gas. To document examples of reserve growth occurrence and potential from fluvial and deltaic sandstones of the Texas Gulf Coast Basin as a natural laboratory for developing concepts and testing applications. To demonstrate how the integration of geology, reservoir engineering, geophysics, and well log analysis/petrophysics leads to strategic recompletion and well placement opportunities for reserve growth in mature fields.

  10. Application of multivariate statistical analysis methods for improved time-of-flight secondary ion mass spectrometry depth profiling of buried interfaces and particulate

    SciTech Connect (OSTI)

    Lloyd, K. G.

    2007-07-15

    Buried irregular interfaces and particulate present special challenges in terms of chemical analysis and identification, and are critical issues in the manufacture of electronic materials and devices. Cross sectioning at the right location is often difficult, and, while dual-beam scanning electron microscopy/focused ion beam instruments can often provide excellent visualization of buried defects, matching chemical analysis may be absent or problematic. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) depth profiling, with its ability to acquire spatially resolved depth profiles while collecting an entire mass spectrum at every 'voxel,' offers a way to revisit the problem of buried defects. Multivariate analysis of the overwhelming amount of data can reduce the output from essentially a depth profile at every mass to a small set of chemically meaningful factors. Data scaling is an important consideration in the application of these methods, and a comparison of scaling procedures is shown. Examples of ToF-SIMS depth profiles of relatively homogeneous layers, severely inhomogeneous layers, and buried particulate are discussed.

  11. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  12. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, S.J.; Liu, M.; DeJonghe, L.C.

    1992-11-10

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145 C (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium trifluorate (PEO[sub 8]LiCF[sub 3]SO[sub 3]), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS)[sub n], and carbon black, dispersed in a polymeric electrolyte. 2 figs.

  13. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, Steven J.; Liu, Meilin; DeJonghe, Lutgard C.

    1992-01-01

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145.degree. C. (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium triflate (PEO.sub.8 LiCF.sub.3 SO.sub.3), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS).sub.n, and carbon black, dispersed in a polymeric electrolyte.

  14. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic

  15. Mechanism of the hydroxy radical oxidation of methacryoyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere

    SciTech Connect (OSTI)

    Nguyen, Tran B.; Bates, Kelvin H.; Crounse, J. D.; Schwantes, Rebecca H.; Zhang, Xuan; Kjaergaard, Henrik G.; Surratt, Jason D.; Lin, Peng; Laskin, Alexander; Seinfeld, John H.; Wennberg, P. O.

    2015-01-01

    Methacryoyl peroxynitrate (MPAN), the acylperoxyl nitrate of methacrolein, has been suggested to be an important secondary organic aerosol (SOA) precursor from isoprene oxidation. Yet, the mechanism by which MPAN produces SOA via reaction with the hydroxyl radical (OH) is unclear. We systematically evaluate three proposed mechanisms in controlled chamber experiments and provide the first experimental support for the theoretically-predicted lactone formation pathway from the MPAN + OH reaction, producing hydroxymethyl-methyl-?-lactone (HMML). The decomposition of the MPAN-OH adduct yields HMML + NO3 (~ 75%) and hydroxyacetone + CO + NO3 (~ 25%), out-competing its reaction with atmospheric oxygen. The production of other proposed SOA precursors, e.g., methacrylic acid epoxide (MAE), from MPAN and methacrolein are negligible (< 2 %). Furthermore, we show that the beta-alkenyl moiety of MPAN is critical for lactone formation. Alkyl radicals formed via OH abstraction nstead of addition are thermalized; thus, even if they are structurally identical to the MPAN-OH adduct, they do not decompose to HMML. The SOA formation from HMML, via polyaddition of the lactone to organic compounds, is close to unity under dry conditions. However, the SOA yield is sensitive to particle liquid water and solvated ions. In hydrated sulfate-containing particles, HMML reacts primarily with H2O and aqueous sulfate, producing monomeric 2-methylglyceric acid (2MGA) and the associated organosulfate. 2MGA, a tracer for isoprene SOA, is semivolatile and its volatility increases with decreasing pH in the aerosol water. Conditions that enhance the production of neutral 2MGA will suppress SOA mass from the HMML channel. Considering the liquid water content and pH ranges of ambient particles, MGA may exist largely as a gaseous compound in some parts of the atmosphere.

  16. Incidence and Predictive Factors of Pain Flare After Spine Stereotactic Body Radiation Therapy: Secondary Analysis of Phase 1/2 Trials

    SciTech Connect (OSTI)

    Pan, Hubert Y.; Allen, Pamela K.; Wang, Xin S.; Chang, Eric L.; Rhines, Laurence D.; Tatsui, Claudio E.; Amini, Behrang; Wang, Xin A.; Tannir, Nizar M.; Brown, Paul D.; Ghia, Amol J.

    2014-11-15

    Purpose/Objective(s): To perform a secondary analysis of institutional prospective spine stereotactic body radiation therapy (SBRT) trials to investigate posttreatment acute pain flare. Methods and Materials: Medical records for enrolled patients were reviewed. Study protocol included baseline and follow-up surveys with pain assessment by Brief Pain Inventory and documentation of pain medications. Patients were considered evaluable for pain flare if clinical note or follow-up survey was completed within 2 weeks of SBRT. Pain flare was defined as a clinical note indicating increased pain at the treated site or survey showing a 2-point increase in worst pain score, a 25% increase in analgesic intake, or the initiation of steroids. Binary logistic regression was used to determine predictive factors for pain flare occurrence. Results: Of the 210 enrolled patients, 195 (93%) were evaluable for pain flare, including 172 (88%) clinically, 135 (69%) by survey, and 112 (57%) by both methods. Of evaluable patients, 61 (31%) had undergone prior surgery, 57 (29%) had received prior radiation, and 34 (17%) took steroids during treatment, mostly for prior conditions. Pain flare was observed in 44 patients (23%). Median time to pain flare was 5 days (range, 0-20 days) after the start of treatment. On multivariate analysis, the only independent factor associated with pain flare was the number of treatment fractions (odds ratio = 0.66, P=.004). Age, sex, performance status, spine location, number of treated vertebrae, prior radiation, prior surgery, primary tumor histology, baseline pain score, and steroid use were not significant. Conclusions: Acute pain flare after spine SBRT is a relatively common event, for which patients should be counseled. Additional study is needed to determine whether prophylactic or symptomatic intervention is preferred.

  17. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore »and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  18. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore » and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  19. Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; et al

    2015-07-16

    We measured a large suite of gas- and particle-phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gas andmore » particle phases, the latter being detected by temperature-programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO–HR-ToF-CIMS are highly correlated with, and explain at least 25–50 % of, the organic aerosol mass measured by an Aerodyne aerosol mass spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from high molecular weight organics and/or oligomers (i.e., multi-phase accretion reaction products). Approximately 50 % of the HR-ToF-CIMS particle-phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption-temperature-based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas-particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the

  20. Proficiency Testing as a tool to monitor consistency of measurements in the IAEA/WHO Network of Secondary Standards Dosimetry Laboratories

    SciTech Connect (OSTI)

    Meghzifene, Ahmed; Czap, Ladislav; Shortt, Ken

    2008-08-14

    The International Atomic Energy Agency (IAEA) and the World Health Organization (WHO) established a Network of Secondary Standards Dosimetry Laboratories (IAEA/WHO SSDL Network) in 1976. Through SSDLs designated by Member States, the Network provides a direct link of national dosimetry standards to the international measurement system of standards traceable to the Bureau International des Poids et Mesures (BIPM). Within this structure and through the proper calibration of field instruments, the SSDLs disseminate S.I. quantities and units.To ensure that the services provided by SSDL members to end-users follow internationally accepted standards, the IAEA has set up two different comparison programmes. One programme relies on the IAEA/WHO postal TLD service and the other uses comparisons of calibrated ionization chambers to help the SSDLs verify the integrity of their national standards and the procedures used for the transfer of the standards to the end-users. The IAEA comparisons include {sup 60}Co air kerma (N{sub K}) and absorbed dose to water (N{sub D,W}) coefficients. The results of the comparisons are confidential and are communicated only to the participants. This is to encourage participation of the laboratories and their full cooperation in the reconciliation of any discrepancy.This work describes the results of the IAEA programme comparing calibration coefficients for radiotherapy dosimetry, using ionization chambers. In this programme, ionization chambers that belong to the SSDLs are calibrated sequentially at the SSDL, at the IAEA, and again at the SSDL. As part of its own quality assurance programme, the IAEA has participated in several regional comparisons organized by Regional Metrology Organizations.The results of the IAEA comparison programme show that the majority of SSDLs are capable of providing calibrations that fall inside the acceptance level of 1.5% compared to the IAEA.

  1. Impact of chamber wall loss of gaseous organic compounds on secondary organic aerosol formation: Explicit modeling of SOA formation from alkane and alkene oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    La, Y. S.; Camredon, M.; Ziemann, P. J.; Valorso, R.; Matsunaga, A.; Lannuque, V.; Lee-Taylor, J.; Hodzic, A.; Madronich, S.; Aumont, B.

    2016-02-08

    Recent studies have shown that low volatility gas-phase species can be lost onto the smog chamber wall surfaces. Although this loss of organic vapors to walls could be substantial during experiments, its effect on secondary organic aerosol (SOA) formation has not been well characterized and quantified yet. Here the potential impact of chamber walls on the loss of gaseous organic species and SOA formation has been explored using the Generator for Explicit Chemistry and Kinetics of the Organics in the Atmosphere (GECKO-A) modeling tool, which explicitly represents SOA formation and gas–wall partitioning. The model was compared with 41 smog chambermore » experiments of SOA formation under OH oxidation of alkane and alkene series (linear, cyclic and C12-branched alkanes and terminal, internal and 2-methyl alkenes with 7 to 17 carbon atoms) under high NOx conditions. Simulated trends match observed trends within and between homologous series. The loss of organic vapors to the chamber walls is found to affect SOA yields as well as the composition of the gas and the particle phases. Simulated distributions of the species in various phases suggest that nitrates, hydroxynitrates and carbonylesters could substantially be lost onto walls. The extent of this process depends on the rate of gas–wall mass transfer, the vapor pressure of the species and the duration of the experiments. Furthermore, this work suggests that SOA yields inferred from chamber experiments could be underestimated up a factor of 2 due to the loss of organic vapors to chamber walls.« less

  2. Formation of voids and secondary-phase precipitates in the Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si steel under high-doze neutron irradiation and during post-irradiation annealing

    SciTech Connect (OSTI)

    Portnykh, I. A. Kozlov, A. V.; Shcherbakov, E. N.; Asiptsov, O. I.

    2009-12-15

    The effect of high-dose neutron irradiation on the structural changes in Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si austenitic steel have been investigated. Samples irradiated at temperatures of 390, 500, and 600{sup o} to damage doses of 46, 86, and 46 dpa, respectively, were analyzed by electron microscopy and dilatometry. The quantitative characteristics of radiation voids and secondary-phase precipitates formed under neutron irradiation are obtained. Their behavior upon heating to 700{sup o}C and annealing at this temperature for 2 h is studied. It is shown that annealing leads to the dissociation of small voids, which is accompanied by the growth of large ones. The secondary-phase precipitates are partially dissolved upon annealing, and their volume fraction decreases.

  3. Nitrogen termination of single crystal (100) diamond surface by radio frequency N{sub 2} plasma process: An in-situ x-ray photoemission spectroscopy and secondary electron emission studies

    SciTech Connect (OSTI)

    Chandran, Maneesh E-mail: choffman@tx.technion.ac.il; Shasha, Michal; Michaelson, Shaul; Hoffman, Alon E-mail: choffman@tx.technion.ac.il

    2015-09-14

    In this letter, we report the electronic and chemical properties of nitrogen terminated (N-terminated) single crystal (100) diamond surface, which is a promising candidate for shallow NV{sup −} centers. N-termination is realized by an indirect RF nitrogen plasma process without inducing a large density of surface defects. Thermal stability and electronic property of N-terminated diamond surface are systematically investigated under well-controlled conditions by in-situ x-ray photoelectron spectroscopy and secondary electron emission. An increase in the low energy cut-off of the secondary electron energy distribution curve (EDC), with respect to a bare diamond surface, indicates a positive electron affinity of the N-terminated diamond. Exposure to atomic hydrogen results in reorganization of N-terminated diamond to H-terminated diamond, which exhibited a negative electron affinity surface. The change in intensity and spectral features of the secondary electron EDC of the N-terminated diamond is discussed.

  4. SUSTAINABLE DEVELOPMENT IN KAZAKHASTAN: USING OIL AND GAS PRODUCTION BY-PRODUCT SULFUR FOR COST-EFFECTIVE SECONDARY END-USE PRODUCTS.

    SciTech Connect (OSTI)

    KALB, P.D.; VAGIN, S.; BEALL, P.W.; LEVINTOV, B.L.

    2004-09-25

    /l in the Toxicity Characteristic Leaching Procedure). The research and development to deploy Kazakhstan recycled sulfur for secondary applications described in this paper is being conducted with support from the International Science and Technology Center (ISTC) and the U.S. Department of Energy Initiatives for Proliferation Prevention (DOE IPP).

  5. Chemical characterization of biogenic secondary organic aerosol generated from plant emissions under baseline and stressed conditions: inter- and intra-species variability for six coniferous species

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faiola, C. L.; Wen, M.; VanReken, T. M.

    2015-04-01

    The largest global source of secondary organic aerosol (SOA) in the atmosphere is derived from the oxidation of biogenic emissions. Plant stressors associated with a changing environment can alter both the quantity and composition of the compounds that are emitted. Alterations to the biogenic volatile organic compound (BVOC) profile could impact the characteristics of the SOA formed from those emissions. This study investigated the impacts of one global change stressor, increased herbivory, on the composition of SOA derived from real plant emissions. Herbivory was simulated via application of methyl jasmonate (MeJA), a proxy compound. Experiments were repeated under pre- andmore » post-treatment conditions for six different coniferous plant types. Volatile organic compounds (VOCs) emitted from the plants were oxidized to form SOA via dark ozone-initiated chemistry. The SOA chemical composition was measured using a Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-AMS). The aerosol mass spectra of pre-treatment biogenic SOA from all plant types tended to be similar with correlations usually greater than or equal to 0.90. The presence of a stressor produced characteristic differences in the SOA mass spectra. Specifically, the following m/z were identified as a possible biogenic stress AMS marker with the corresponding HR ion(s) shown in parentheses: m/z 31 (CH3O+), m/z 58 (C2H2O2+, C3H6O+), m/z 29 (C2H5+), m/z 57 (C3H5O+), m/z 59 (C2H3O2+, C3H7O+), m/z 71 (C3H3O2+, C4H7O+), and m/z 83 (C5H7O+). The first aerosol mass spectrum of SOA generated from the oxidation of the plant stress hormone, MeJA, is also presented. Elemental analysis results demonstrated an O : C range of baseline biogenic SOA between 0.3 and 0.47. The O : C of standard MeJA SOA was 0.52. Results presented here could be used to help identify a biogenic plant stress marker in ambient data sets collected in forest environments.« less

  6. Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols

    SciTech Connect (OSTI)

    Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

    2012-06-13

    The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was

  7. Characterization of a real-time tracer for Isoprene Epoxydiols-derived Secondary Organic Aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, W. W.; Campuzano-Jost, P.; Palm, B. B.; Day, D. A.; Ortega, A. M.; Hayes, P. L.; Krechmer, J. E.; Chen, Q.; Kuwata, M.; Liu, Y. J.; et al

    2015-04-16

    Substantial amounts of secondary organic aerosol (SOA) can be formed from isoprene epoxydiols (IEPOX), which are oxidation products of isoprene mainly under low-NO conditions. Total IEPOX-SOA, which may include SOA formed from other parallel isoprene low-NO oxidation pathways, was quantified by applying Positive Matrix Factorization (PMF) to aerosol mass spectrometer (AMS) measurements. The IEPOX-SOA fractions of OA in multiple field studies across several continents are summarized here and show consistent patterns with the concentration of gas-phase IEPOX simulated by the GEOS-Chem chemical transport model. During the SOAS study, 78% of IEPOX-SOA is accounted for the measured molecular tracers, making itmore » the highest level of molecular identification of an ambient SOA component to our knowledge. Enhanced signal at C5H6O+ (m/z 82) is found in PMF-resolved IEPOX-SOA spectra. To investigate the suitability of this ion as a tracer for IEPOX-SOA, we examine fC5H6O ( fC5H6O = C5H6O+/OA) across multiple field, chamber and source datasets. A background of ~ 1.7 ± 0.1‰ is observed in studies strongly influenced by urban, biomass-burning and other anthropogenic primary organic aerosol (POA). Higher background values of 3.1 ± 0.8‰ are found in studies strongly influenced by monoterpene emissions. The average laboratory monoterpene SOA value (5.5 ± 2.0‰) is 4 times lower than the average for IEPOX-SOA (22 ± 7‰). Locations strongly influenced by isoprene emissions under low-NO levels had higher fC5H6O (~ 6.5 ± 2.2‰ on average) than other sites, consistent with the expected IEPOX-SOA formation in those studies. fC5H6O in IEPOX-SOA is always elevated (12–40‰) but varies substantially between locations, which is shown to reflect large variations in its detailed molecular composition. The low fC5H6O (< 3‰) observed in non IEPOX-derived isoprene-SOA indicates that this tracer ion is specifically enhanced from IEPOX-SOA, and is not a tracer for all SOA

  8. Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ortega, Amber M.; Hayes, Patrick L.; Peng, Zhe; Palm, Brett B.; Hu, Weiwei; Day, Douglas A.; Li, Rui; Cubison, Michael J.; Brune, William H.; Graus, Martin; et al

    2016-06-15

    Field studies in polluted areas over the last decade have observed large formation of secondary organic aerosol (SOA) that is often poorly captured by models. The study of SOA formation using ambient data is often confounded by the effects of advection, vertical mixing, emissions, and variable degrees of photochemical aging. An oxidation flow reactor (OFR) was deployed to study SOA formation in real-time during the California Research at the Nexus of Air Quality and Climate Change (CalNex) campaign in Pasadena, CA, in 2010. A high-resolution aerosol mass spectrometer (AMS) and a scanning mobility particle sizer (SMPS) alternated sampling ambient andmore » reactor-aged air. The reactor produced OH concentrations up to 4 orders of magnitude higher than in ambient air. OH radical concentration was continuously stepped, achieving equivalent atmospheric aging of 0.8 days–6.4 weeks in 3 min of processing every 2 h. Enhancement of organic aerosol (OA) from aging showed a maximum net SOA production between 0.8–6 days of aging with net OA mass loss beyond 2 weeks. Reactor SOA mass peaked at night, in the absence of ambient photochemistry and correlated with trimethylbenzene concentrations. Reactor SOA formation was inversely correlated with ambient SOA and Ox, which along with the short-lived volatile organic compound correlation, indicates the importance of very reactive (τOH ~ 0.3 day) SOA precursors (most likely semivolatile and intermediate volatility species, S/IVOCs) in the Greater Los Angeles Area. Evolution of the elemental composition in the reactor was similar to trends observed in the atmosphere (O : C vs. H : C slope ~ –0.65). Oxidation state of carbon (OSc) in reactor SOA increased steeply with age and remained elevated (OSC ~ 2) at the highest photochemical ages probed. The ratio of OA in the reactor output to excess CO (ΔCO, ambient CO above regional background) vs. photochemical age is similar to previous studies at low to moderate ages and

  9. Apparatus and method for routing a transmission line through a downhole tool

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Briscoe, Michael; Reynolds, Jay

    2006-07-04

    A method for routing a transmission line through a tool joint having a primary and secondary shoulder, a central bore, and a longitudinal axis, includes drilling a straight channel, at a positive, nominal angle with respect to the longitudinal axis, through the tool joint from the secondary shoulder to a point proximate the inside wall of the centtral bore. The method further includes milling back, from within the central bore, a second channel to merge with the straight channel, thereby forming a continuous channel from the secondary shoulder to the central bore. In selected embodiments, drilling is accomplished by gun-drilling the straight channel. In other embodiments, the method includes tilting the tool joint before drilling to produce the positive, nominal angle. In selected embodiments, the positive, nominal angle is less than or equal to 15 degrees.

  10. Study of secondary neutron interactions with 232 Th, 129 I, and 127 I nuclei with the uranium assembly " QUINTA " at 2, 4, and 8 GeV deuteron beams of the JINR Nuclotron accelerator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adam, J.; Chilap, V. V.; Furman, M. G.; Khushvaktov, J.; Pronskikh, V. S.; Solnyshkin, A. A..; Stegailov, V. I.; Suchopar, M.; Tsoupko-Sitnikov, V. M.; Tyutyunnikov, S. I.; et al

    2016-06-01

    The natural uranium assembly, "QUINTA", was irradiated with 2, 4, and 8 GeV deuterons. The 232 Th, 127 I, and 129 I samples have been exposed to secondary neutrons produced in the assembly at a 20-cm radial distance from the deuteron beam axis. The spectra of gamma rays emitted by the activated 232 Th, 127 I, and 129 I samples have been analyzed and several tens of product nuclei have been identified. For each of those products, neutron-induced reaction rates have been determined. The transmutation power for the 129 I samples is estimated. Experimental results were compared to those calculatedmore » with well-known stochastic and deterministic codes.« less

  11. Study of secondary neutron interactions with 232Th, 129I, and 127I nuclei with the uranium assembly “QUINTA” at 2, 4, and 8GeV deuteron beams of the JINR Nuclotron accelerator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adam, J.; Chilap, V. V.; Furman, V. I.; Kadykov, M. G.; Khushvaktov, J.; Pronskikh, V. S.; Solnyshkin, A. A.; Stegailov, V. I.; Suchopar, M.; Tsoupko-Sitnikov, V. M.; et al

    2015-11-04

    The natural uranium assembly, “QUINTA”, was irradiated with 2, 4, and 8 GeV deuterons. The 232Th, 127I, and 129I samples have been exposed to secondary neutrons produced in the assembly at a 20-cm radial distance from the deuteron beam axis. The spectra of gamma rays emitted by the activated 232Th, 127I, and 129I samples have been analyzed and several tens of product nuclei have been identified. For each of those products, neutron-induced reaction rates have been determined. The transmutation power for the 129I samples is estimated. Furthermore, experimental results were compared to those calculated with well-known stochastic and deterministic codes.

  12. Top physics: measurement of the tt-bar production cross section in p anti-p collisions at s**(1/2) = 1.96 tev using lepton + jets events with secondary vertex b-tagging

    SciTech Connect (OSTI)

    Acosta, D.; The CDF Collaboration

    2005-04-07

    We present a measurement of the t{bar t} production cross section using events with one charged lepton and jets from p{bar p} collisions at a center-of-mass energy of 1.96TeV. In these events, heavy flavor quarks from top quark decay are identified with a secondary vertex tagging algorithm. From 162 pb{sup -1} of data collected by the Collider Detector at Fermilab, a total of 48 candidate events are selected, where 13.5 {+-} 1.8 events are expected from background contributions. We measure a t{bar t} production cross section of 5.6{sub -1.1}{sup _1.2}(stat.){sub -0.6}{sup +0.9}(syst.)pb.

  13. Characterisation of amorphous silica in air-oxidised Ti3SiC2 at 500-1000 °C using secondary-ion mass spectrometry, nuclear magnetic resonance and transmission electron microscopy

    SciTech Connect (OSTI)

    Pang, W K; Low, I M; Hanna, J V

    2010-05-18

    In this paper we have described the use of secondary-ion mass spectrometry (SIMS), solid state {sup 29}Si magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) to detect the existence of amorphous silica in Ti{sub 3}SiC{sub 2} oxidised at 500-1000 C. The formation of amorphous SiO{sub 2} and growth of crystalline TiO{sub 2} with temperature was monitored using dynamic SIMS and synchrotron radiation diffraction. A duplex structure with an outer TiO{sub 2}-rich layer and an inner mixed layer of SiO{sub 2} and TiO{sub 2} was observed. Results of NMR and TEM verified for the first time the direct evidence of amorphous silica formation during the oxidation of Ti{sub 3}SiC{sub 2} at the temperature range 500-1000 C.

  14. A Measurement of the production cross section of top-antitop pairs in proton-antiproton collisions at a center of mass of 1.96 TeV using secondary vertex b-tagging.

    SciTech Connect (OSTI)

    Bachacou, Henri

    2004-12-01

    A measurement of the t{bar t} pair production cross section is presented using 162 pb{sup -1} of data collected by the CDF experiment during Run II at the Tevatron. t{bar t} events in the lepton+jets channel are isolated by identifying electrons and muons, reconstructing jets and transverse missing energy, and identifying b jets with a secondary vertex tagging algorithm. The efficiency of the algorithm is measured in a control sample using a novel technique that is less dependent on the simulation. For a top quark mass of 175 GeV/c{sup 2}, a cross section of {sigma}{sub t{bar t}} = 5.6{sub -1.1}{sup +1.2}(stat.){sub -0.6}{sup +0.9}(syst.)pb is measured.

  15. Identification of a classical mutant in the industrial host Aspergillus niger by systems genetics: LaeA is required for citric acid production and regulates the formation of some secondary metabolites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Niu, Jing; Arentshorst, Mark; Nair, P. Deepa S.; Dai, Ziyu; Baker, Scott E.; Frisvad, Jens C.; Nielsen, Kristian F.; Punt, Peter J.; Ram, Arthur F. J.

    2015-11-13

    The asexual filamentous fungus Aspergillus niger is an important industrial cell factory for citric acid production. In this study, we genetically characterized a UV-generated A. niger mutant that was originally isolated as a nonacidifying mutant, which is a desirable trait for industrial enzyme production. Physiological analysis showed that this mutant did not secrete large amounts of citric acid and oxalic acid, thus explaining the nonacidifying phenotype. As traditional complementation approaches to characterize the mutant genotype were unsuccessful, we used bulk segregant analysis in combination with high-throughput genome sequencing to identify the mutation responsible for the nonacidifying phenotype. Since A. nigermore » has no sexual cycle, parasexual genetics was used to generate haploid segregants derived from diploids by loss of whole chromosomes. We found that the nonacidifying phenotype was caused by a point mutation in the laeA gene. LaeA encodes a putative methyltransferase-domain protein, which we show here to be required for citric acid production in an A. niger lab strain (N402) and in other citric acid production strains. The unexpected link between LaeA and citric acid production could provide new insights into the transcriptional control mechanisms related to citric acid production in A. niger. Interestingly, the secondary metabolite profile of a ΔlaeA strain differed from the wild-type strain, showing both decreased and increased metabolite levels, indicating that LaeA is also involved in regulating the production of secondary metabolites. As a result, we show that our systems genetics approach is a powerful tool to identify trait mutations.« less

  16. Identification of a classical mutant in the industrial host Aspergillus niger by systems genetics: LaeA is required for citric acid production and regulates the formation of some secondary metabolites

    SciTech Connect (OSTI)

    Niu, Jing; Arentshorst, Mark; Nair, P. Deepa S.; Dai, Ziyu; Baker, Scott E.; Frisvad, Jens C.; Nielsen, Kristian F.; Punt, Peter J.; Ram, Arthur F. J.

    2015-11-13

    The asexual filamentous fungus Aspergillus niger is an important industrial cell factory for citric acid production. In this study, we genetically characterized a UV-generated A. niger mutant that was originally isolated as a nonacidifying mutant, which is a desirable trait for industrial enzyme production. Physiological analysis showed that this mutant did not secrete large amounts of citric acid and oxalic acid, thus explaining the nonacidifying phenotype. As traditional complementation approaches to characterize the mutant genotype were unsuccessful, we used bulk segregant analysis in combination with high-throughput genome sequencing to identify the mutation responsible for the nonacidifying phenotype. Since A. niger has no sexual cycle, parasexual genetics was used to generate haploid segregants derived from diploids by loss of whole chromosomes. We found that the nonacidifying phenotype was caused by a point mutation in the laeA gene. LaeA encodes a putative methyltransferase-domain protein, which we show here to be required for citric acid production in an A. niger lab strain (N402) and in other citric acid production strains. The unexpected link between LaeA and citric acid production could provide new insights into the transcriptional control mechanisms related to citric acid production in A. niger. Interestingly, the secondary metabolite profile of a ΔlaeA strain differed from the wild-type strain, showing both decreased and increased metabolite levels, indicating that LaeA is also involved in regulating the production of secondary metabolites. As a result, we show that our systems genetics approach is a powerful tool to identify trait mutations.

  17. Monte Carlo semi-empirical model for Si(Li) x-ray detector: Differences between nominal and fitted parameters

    SciTech Connect (OSTI)

    Lopez-Pino, N.; Padilla-Cabal, F.; Garcia-Alvarez, J. A.; Vazquez, L.; D'Alessandro, K.; Correa-Alfonso, C. M.; Godoy, W.; Maidana, N. L.; Vanin, V. R.

    2013-05-06

    A detailed characterization of a X-ray Si(Li) detector was performed to obtain the energy dependence of efficiency in the photon energy range of 6.4 - 59.5 keV, which was measured and reproduced by Monte Carlo (MC) simulations. Significant discrepancies between MC and experimental values were found when the manufacturer parameters of the detector were used in the simulation. A complete Computerized Tomography (CT) detector scan allowed to find the correct crystal dimensions and position inside the capsule. The computed efficiencies with the resulting detector model differed with the measured values no more than 10% in most of the energy range.

  18. Charts and graphs: NUKEM Uranium price ange data; NUKEM Uranium historical price graph; U.S. DOE & euratom average contract prices for natural uranium; NUKEM SWU historical price graph; NUKEM SWU spot/secondary price range; U.S. DOE separative work prices data

    SciTech Connect (OSTI)

    1996-04-01

    This article is the uranium market data summary. It contains data for the following subjects: (1) March 1996 transactions, (2) Uranium price range data, (3) Historical uranium price range data, (4) DOE and Euratom average contract prices for natural uranium, (5) SWU historical price data, (6) SWU/spot/secondary price range data, and (7) DOE SWU prices data.

  19. Oral administration of drugs with hypersensitivity potential induces germinal center hyperplasia in secondary lymphoid organ/tissue in Brown Norway rats, and this histological lesion is a promising candidate as a predictive biomarker for drug hypersensitivity occurrence in humans

    SciTech Connect (OSTI)

    Tamura, Akitoshi Miyawaki, Izuru; Yamada, Toru; Kimura, Juki; Funabashi, Hitoshi

    2013-08-15

    It is important to evaluate the potential of drug hypersensitivity as well as other adverse effects during the preclinical stage of the drug development process, but validated methods are not available yet. In the present study we examined whether it would be possible to develop a new predictive model of drug hypersensitivity using Brown Norway (BN) rats. As representative drugs with hypersensitivity potential in humans, phenytoin (PHT), carbamazepine (CBZ), amoxicillin (AMX), and sulfamethoxazole (SMX) were orally administered to BN rats for 28 days to investigate their effects on these animals by examinations including observation of clinical signs, hematology, determination of serum IgE levels, histology, and flow cytometric analysis. Skin rashes were not observed in any animals treated with these drugs. Increases in the number of circulating inflammatory cells and serum IgE level did not necessarily occur in the animals treated with these drugs. However, histological examination revealed that germinal center hyperplasia was commonly induced in secondary lymphoid organs/tissues in the animals treated with these drugs. In cytometric analysis, changes in proportions of lymphocyte subsets were noted in the spleen of the animals treated with PHT or CBZ during the early period of administration. The results indicated that the potential of drug hypersensitivity was identified in BN rat by performing histological examination of secondary lymphoid organs/tissues. Data obtained herein suggested that drugs with hypersensitivity potential in humans gained immune reactivity in BN rat, and the germinal center hyperplasia induced by administration of these drugs may serve as a predictive biomarker for drug hypersensitivity occurrence. - Highlights: We tested Brown Norway rats as a candidate model for predicting drug hypersensitivity. The allergic drugs did not induce skin rash, whereas D-penicillamine did so in the rats. Some of allergic drugs increased inflammatory

  20. Influence of secondary phases on phase and microwave dielectric properties of new Ca{sub 2}Ce{sub 2}Ti{sub 5}O{sub 16} ceramics

    SciTech Connect (OSTI)

    Manan, Abdul E-mail: samiullah685@yahoo.com; Khan, Sami Ullah E-mail: samiullah685@yahoo.com; Qazi, Ibrahim

    2014-11-05

    Ca{sub 2}Ce{sub 2}Ti{sub 5}O{sub 16} ceramics processed via mix oxide route was investigated. Phase composition and microwave dielectric properties were measured using X-ray diffraction and a cavity method, respectively. CeO{sub 2} and another unidentified phase (that vanishes at ≥1400°C) existed as secondary phases along with the parent Ca{sub 2}Ce{sub 2}Ti{sub 5}O{sub 16} phase. The amount of the parent Ca{sub 2}Ce{sub 2}Ti{sub 5}O{sub 16} phase increased with increasing sintering temperature from 1350°C to 1450 °C accompanied by a decrease in the apparent density. The density decreased but ε{sub r} and Qufo increased with sintering temperature. An ε{sub r} ∼87.2, Qufo ∼5915 GHz and τ{sub f} ∼219 GHz was achieved for the sample sintered at 1450°C.